Amination of Arenes Through Electron-Deficient Reaction Cascades of Aryl Epoxyazides.

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2004 Pyrrole derivatives Pyrrole derivatives R 0120 Amination of Arenes Through Electron-Deficient Reaction Cascades of Aryl Ep- oxyazides. — The Lewis-acid mediated electron-deficient reaction cascades of aryl ep- oxyazides are described. High yields of aromatic amination products are derived from cascades such as epoxide opening/ electrophilic amination of an arene/ and hydride or alkyl shifts. — (LANG, S.; KENNEDY, A. R.; MURPHY*, J. A.; PAYNE, A. H.; Org. Lett. 5 (2003) 20, 3655-3658; Dep. Pure Appl. Chem., Univ. Strathclyde, Glasgow G1 1XL, UK; Eng.) — Bartels 05- 087

Transcript of Amination of Arenes Through Electron-Deficient Reaction Cascades of Aryl Epoxyazides.

Page 1: Amination of Arenes Through Electron-Deficient Reaction Cascades of Aryl Epoxyazides.

2004 Pyrrole derivatives

Pyrrole derivativesR 0120 Amination of Arenes Through Electron-Deficient Reaction Cascades of Aryl Ep-

oxyazides. — The Lewis-acid mediated electron-deficient reaction cascades of aryl ep-oxyazides are described. High yields of aromatic amination products are derived from cascades such as epoxide opening/ electrophilic amination of an arene/ and hydride or alkyl shifts. — (LANG, S.; KENNEDY, A. R.; MURPHY*, J. A.; PAYNE, A. H.; Org. Lett. 5 (2003) 20, 3655-3658; Dep. Pure Appl. Chem., Univ. Strathclyde, Glasgow G1 1XL, UK; Eng.) — Bartels

05- 087