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Transcript of alkali tanah lagi
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Episode :EARTH ALKALINE
CeniaaIneezz Hunii Amii
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General Introduction
Hello, I am a group of metals that lies in
group IIA. My friends call me Earth
Alkaline. I am consist of Beryllium,
Magnesium, Calcium, Strontium,
Barium, Radium.
It is difficult for some people to
remember what metals involved me. So,
people created donkey bridge system
for easily memorizing :
Bebek Mangan Cacing Seret
Banget RasaneBemo Mogok Carena Sering
Bayar Ragu-ragu
Bety Megang Cabe Saru Banget
Raisin
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I am so famous
• Paparazzi : Hello, why people calling you earth alkaline metal???
• Me : Xie xie, Firstly, I am called metal because I have some metal characteristics such glossy or shiny solid type. I also have good capability in transferring heat and electricity
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I am so famous
• Paparazzi : Then, what do you mean by alkaline?
• Me : Another Xie xie. I am alkaline because I have alkaline characters when I react with my acid and base friends.
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I am so famous
• Paparazzi : Okeeh, can you explain the “earth” terms??
• Me : The terms “earth” is used by the chemical experts because of some reasons. My oxidize is hard to be solute in water, beside I am easy to be found on the earth crust’s rocks
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Name by Name
• Beryllium comes from Greece “beryllos” means mineral
• Magnesium comes from “Magnesia”, town in Greece• Calcium comes from Latin “calx/calcis” means lime• Strontium comes from word “Strontian”, town in
Scotland• Barium comes from Greece “barys” means heavy /
solid • Radium comes from Latin “radius” means light / ray
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Where do you can find me???Unsure Earth Crust Percentage Naturally
Beryllium - Beryl mineral and crysoberyl
Magnesium 7th mostly found (1.9 %) MgCl2 compound in the water sea
Calcium 5th mostly found (3.4 %) Carbonate, phosphate, sulphate compound
Strontium 0.03 % Selestite and strontianite mineral
Barium 0.04 % Baritine and Witerite mineral
Radium 0.33 ppm Pitchlende (Uranium ore)
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Beryllium
Radium Barium
StrontiumCalcium
Magnesium
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BerylliumSymbol: Be Atomic Number: 4 Atomic Mass: 9.012182 Melting Point: 1278.0 °C Boiling Point: 2970.0 °C Number of Protons/Electrons: 4 Number of Neutrons: 5 Crystal Structure: Hexagonal Density @ 293 K: 1.8477 g/cm3 Color: gray
Date of Discovery: 1798 Discoverer: Fredrich Wohler
Number of Energy Levels: 2First Energy Level: 2 Second Energy Level: 2
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Beryllium
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MagnesiumSymbol: Mg Atomic Number: 12 Atomic Mass: 24.305 Melting Point: 650.0 °C Boiling Point: 1107.0 °C Number of Protons/Electrons: 12 Number of Neutrons: 12 Crystal Structure: Hexagonal Density @ 293 K: 1.738 g/cm3 Color: grayishDate of Discovery: 1808 Discoverer: Sir Humphrey Davy
Number of Energy Levels: 3First Energy Level: 2 Second Energy Level: 8 Third Energy Level: 2
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Magnesium
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Calcium
Symbol: Ca Atomic Number: 20 Atomic Mass: 40.078 Melting Point: 839.0 °C Boiling Point: 1484.0 °C Number of Protons/Electrons: 20 Number of Neutrons: 20 Crystal Structure: Cubic Density @ 293 K: 1.55 g/cm3 Color: Silvery
Date of Discovery: 1808
Discoverer: Sir Humphrey Davy
Number of Energy Levels: 4First Energy Level: 2 Second Energy Level: 8 Third Energy Level: 8 Fourth Energy Level: 2
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Calcium
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Strontium
Symbol: Sr Atomic Number: 38 Atomic Mass: 87.62 Melting Point: 769.0 °C Boiling Point: 1384.0 °C Number of Protons/Electrons: 38 Number of Neutrons: 50 Crystal Structure: Cubic Density @ 293 K: 2.54 g/cm3 Color: yellowishDate of Discovery: 1790 Discoverer: A. Crawford
Number of Energy Levels: 5First Energy Level: 2 Second Energy Level: 8 Third Energy Level: 18 Fourth Energy Level: 8 Fifth Energy Level: 2
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Strontium
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BariumSymbol: Ba Atomic Number: 56 Atomic Mass: 137.327 Melting Point: 725.0 °C Boiling Point: 1140.0 °C Number of Protons/Electrons: 56 Number of Neutrons: 81 Crystal Structure: Cubic Density @ 293 K: 3.51 g/cm3 Color: SilverDate of Discovery: 1808 Discoverer: Sir Humphrey Davy
Number of Energy Levels: 6First Energy Level: 2 Second Energy Level: 8 Third Energy Level: 18 Fourth Energy Level: 18 Fifth Energy Level: 8 Sixth Energy Level: 2
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Barium
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Radium
Symbol: Ra Atomic Number: 88 Atomic Mass: (226.0) Melting Point: 700.0 °C Boiling Point: 1737.0 °C Number of Protons/Electrons: 88 Number of Neutrons: 138 Crystal Structure: Cubic Density @ 293 K: 5.0 g/cm3 Color: silverish
Date of Discovery: 1898
Discoverer: Pierre and Marie Curie
Number of Energy Levels: 7First Energy Level: 2 Second Energy Level: 8 Third Energy Level: 18 Fourth Energy Level: 32 Fifth Energy Level: 18 Sixth Energy Level: 8 Seventh Energy Level: 2
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Radium
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My Physical Characteristics
Atomic Characteristics
Generally & Physically
What’s increasing & What’s decreasing
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My Physical Characteristics
In the room temperature, earth alkaline metals are in solid type. Mostly are white metallic colored, but quickly turn in to dark when contact with air and water.
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My Physical Characteristics
Element Metal’s radius(pm)
Ionic radius (pm)
1st Ionisation energy (kJ/mol)
2nd Ionisation energy kJ/mol)
Electronegativity
Oxidation number
Berilium 110 27 900 1757 1.5 +2
Magnesium 160 72 738 1451 1.2 +2
Calsium 200 100 590 1145 1.0 +2
Stronsium 220 113 550 1064 1.0 +2
Barium 220 136 503 965 0.7 +2
Radium - 162 509 978 0.9 +2
Alkaline earth metal’s atomic characteristics
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My Physical Characteristics
• Increasing atomic radius from Beryllium to Barium
• Decreasing ionization energy from Beryllium to Radium
• Decreasing electro negativity from Beryllium to Radium
• Maximum oxidation number equal with +2
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My Physical Characteristics
Element Density (kg/m3)
Hardness (Mohs)
Melting point (ºC)
Boiling point (ºC)
Hfus (kJ/mol)
Hv (kJ/mol) Heat conductivity
Electroconductivity
Be 1850 5.5 1278 2970 12.2 292 2 0.313
Mg 1740 2.5 649 1107 8.95 127 1.56 0.226
Ca 1540 1.75 839 1484 8.54 154 2.0 0.298
Sr 2620 1.5 769 1384 8.30 144 0.353 0.076
Ba 3510 1.25 725 1643 7.75 142 0.184 0.030
Ra 5000 - 700 1140 - - 0.186 -
Alkaline earth metal’s physical characteristics
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My Physical Characteristics
• The increasing of density from Be to Ra.• The decreasing of hardness from Be to Ra.• The decreasing of melting point and Hfus from
Be to Ra.• The decreasing of boiling point and Hv from Be
to Ra.• The decreasing of electroconductivity and
heatconductivity from Be to Ra.
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My Chemical Characteristics
ElementsElectron
ConfigurasiBerilium [He] 2s2
Magnesium [Ne] 3s2
Kalsium [Ar] 4s2
Stronsium [Kr] 5s2
Barium [Xe] 6s2
Radium [Rn] 7s2
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• Every atomic of alkali earth metal has 2 electron valence on sub skin s (the outest)
• Alkali earth metal are reactive if the value of ionization is low
• Reactivity of alkali earth metal increase from Be to Ra
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Compound Solubility
• The compound of alkali earth metal has small solubility. It is caused by the bigger charge of ion, and also the ionic bound
• The example of alkali earth metal that easy to solute are Nitrate (NO3) and Chloride (Cl-)
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I like to make a relationship with….
• My reaction with water• My reaction with oxygen• My reaction with nitrogen• My reaction with halogen • My reaction with hydrogen
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Me & Water
• FormulaM + 2H2O M(OH)2 + H2
Resulting hydroxide compound
Ca + 2H2O Ca(OH)2 + H2
Mg + 2H2O Mg(OH)2 + H2
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Me & O2
• Formula :2M + O2 2MO
M + O2 MO2
Resulting oxide and superoxide compound
2Be + O2 2BeO
Ra + O2 RaO2
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Me & Nitrogen
• Formula :3M + N2 M3N2
Resulting Nitride compound
3Mg + N2 Mg3N2
3Ba + N2 Ba3N2
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Me & Halogen
• Formula :M + X2 MX2
Resulting halide compound
Be + Cl2 BeCl2
Ca + F2 CaF2
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Me & Hydrogen
• Formula :M + H2 MH2
Resulting Hydride compound
Mg + H2 MgH2
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Extraction process of Earth Alkaline
Reduction Method– Reduction BeF2 by Mg
BeF2 + Mg MgF2 + Be
– Reduction CaO by Al
6CaO + 2Al 3Ca + Ca3Al2O6
Electrolysis Method– Electrolysis of BeCl2 molten
Cathode : Be2+ + 2e BeAnode : 2Cl- Cl2 + 2e
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Application of Earth Alkaline Metal
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Beryllium
• When it combines with other metal, it will create stronger but lighter metal combination
• 17 times better than aluminum for transmitting X ray
• Fire flameless designed
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Magnesium• Neutralizes the mouth acid and preventing
from damaging teeth• Neutralizes the stomach acid• Giving the bright white beam in Fireworks • Layering the firebox
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Calcium
• Most important unsure for teeth and bones. Calcium was mostly found in the milk
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Strontium• Tube glass production for the colored TV and
computer
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Barium
• Giving the bright green color in fireworks• Examining the digestion system in our body
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Radium
• Radium is used to produce “bright in the dark” paint
• Cancer therapy in medical science
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HARD WATER
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• The Meaning Of Hard Water• The Kinds Of Hard Water• The Advantages Of Hard Water• The Disadvantages Of Hard• The Way To Disappear The Hardness
Water
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HARD WATER
>>> Water that contains many calsium ion (Ca2+) and magnesium ion (Mg2+), and also anion like Cl-, SO4
2-, HCO3- .
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The Kinds Of Hard Water
Hard Water
Temporary Hardness Permanent Hardness
The hardness that losebecause the heating.
It’s caused by hydrogencarbonat salts, like
Ca(HCO3)2 and Mg(HCO3)2
The hardness that not losewith the heating of water.It’s caused by calsium saltand magnesium salt,like
calsium sulfate (CaSO4) andmagnesium sulfate (MgSO4)
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The Advantages Of Hard Water
The Advantages
Provide calsium that need by the body,for the example to form bone and tooth
Have the vlafor that more deliciousthan soft water
Timbel compound (from water pipe) isharder to solute in hard water. Timbel
is toxin for body
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The Disadvantages Of Hard Water
The Disadvantages
Wastefull uses of soap
Scum can leave the stain inthe clothes
Form the corral on kettle andwater pipe / radiator pipe
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The Way to Clear The Hardness
METHOD EXPLANATION
Distilation It’s relative expensive
Boiling Can disappear temporaray hardness. At high
temperature, Ca(HCO3)2 will loose in order to ion Ca2+ will precipitate as CaCO3
Add natrium carbonate or washing soda
Washing Soda (Na2CO3.10H2O) that added to hard water that contain of Ca(HCO3)2 can precipitate ion Ca2+ became CaCO3
Use soft water substance
Natrium Heksametafosfat / Na2[Na4(PO3)6] can use to change ion Ca2+ and Mg2+ become complecs ion that easy to solute in order to can’t join with stearat ion from the soap
Use resinchanger ion
The function is to tie all of anion and cation in hard water. There are 2 kinds of resin :>Cation Resin Changer : contain negative group that tie H+ ion>Anion Resin Changer : contain positive group that tie OH+ ion
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Uwis ahKesel jee
Sing meh takon ngadeg !!!