ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March...

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ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009

Transcript of ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March...

Page 1: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

ALGAE TO ETHANOL: Using algae fermentation to

produce ethanol

4th AFRICAN BIOFUEL CONFERENCE

March 2009

Page 2: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Algae!

Page 3: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Why Algae?

• Fast growers relative to other plants and animals– can double their weight every day

• High carbohydrate/low lignin content• Gallons of oil per acre per year

– corn 18

– soybeans 48

– sunflower 102

– rapeseed 127

– oil palm 635

– micro algae 5 000 - 15 000

Page 4: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Process Selection Objectives…

• Must be simple• The process itself must be “bullet proof”• Must have low maintenance• A labourer must be able to look after algae production• A semi-skilled labourer must be able to run conversion• Must have low operating costs

– little or no nutrient cost

– little or no energy cost

Page 5: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Why ethanol and not oil for biodiesel?

Page 6: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Why Algae to Ethanol…

• Wild algae– have to be fast growers to survive in nature

– generally contain <10% oil (lipid)

– generally contain high carbohydrate >50%

– can be grown in open raceways without fear of contamination

• Equipment– raceways are low cost installations ($75 000/ha)

– raceways consume very little power (10 kW/ha)

– starch to ethanol conversion plant is relatively expensive and energy intensive (distillation)

Page 7: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Why Algae to Ethanol…

• High oil producing algae – are slower growers than wild algae – double every 2-3 days

– can be selected for maximum oil content – 50% not unusual

– need to be grown in protected environment – typically PBR’s

– most algae oil can be used for biodiesel production

• Photobioreactors (PBR’s)– allow tight control of growing environment

– optimise light usage

– are capital intensive

– are generally power intensive (300 kW/ha?)

Page 8: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

General Processing Steps

Algae to Ethanol

Page 9: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

oxygensunlight

CO2

Page 10: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

dlute slurry

liquid

oxygensunlight

CO2

Page 11: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

dlute slurry

liquid

Hydrolysis

acidconcentrated slurry

heat

oxygensunlight

CO2

Page 12: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

liquid

Hydrolysis

concentrated slurry

Fermentation

alkali

heat cooling

dlute slurry

acid

oxygensunlight

CO2

yeast

Page 13: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

liquid

Hydrolysis

concentrated slurry

Fermentation

alkali

heat cooling

Distillation

“beer”

ethanol

dlute slurry

acid

oxygensunlight

CO2

yeast

Page 14: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

liquid

Hydrolysis

concentrated slurry

Fermentation

alkali

heat cooling

Distillation

“beer”

Digestion

stillageethanol

dlute slurry

acid

oxygensunlight

CO2

yeast

Page 15: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

liquid

Hydrolysis

concentrated slurry

Fermentation

alkali

heat cooling

Distillation

“beer”

Digestion

stillage

liquid digestate

ethanol

solid digestate

dlute slurry

acid

oxygensunlight

CO2

biogas

yeast

Page 16: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

liquid

Hydrolysis

concentrated slurry

Fermentation

alkali

heat cooling

Distillation

“beer”

Digestion

stillage

liquid digestate

ethanol

solid digestate

dlute slurry

acid

oxygensunlight

CO2

CO2

biogas

yeast

Page 17: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

liquid

Hydrolysis

concentrated slurry

Fermentation

alkali

heat cooling

Distillation

“beer”

Digestion

stillage

liquid digestate

ethanol

solid digestate

biogas

dlute slurry

acid

oxygensunlight

CO2

CO2

CO2

CO2

yeast

Page 18: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Processing Steps

Algae

Concentration

liquid

Hydrolysis

concentrated slurry

Fermentation

alkali

heat cooling

Distillation

“beer”

Digestion

stillage

liquid digestate

ethanol

solid digestate

biogas

dlute slurry

acid

oxygensunlight

CO2

CO2

CO2

CO2

CHPCO2 ~

yeast

Page 19: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 20: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

• Components– 20m2 raceway with 0.55 kW paddle drive

– solar panels to supply heat to the digester

Page 21: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 22: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

PilotPlant

Page 23: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 24: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

• Components– 20m2 raceway with 0.55 kW paddle drive

– solar panels to supply heat to the digester

– digester

Page 25: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 26: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

• Components– 20m2 raceway with 0.55 kW paddle drive

– solar panels to supply heat to the digester

– digester

– “compost tea” maker

Page 27: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 28: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

• Components– 20m2 raceway with 0.55 kW paddle drive

– solar panels to supply heat to the digester

– digester

– “compost tea” maker

– DAF container to make “white water”

Page 29: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 30: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 31: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 32: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

• Components– 20m2 raceway with 0.55 kW paddle drive

– solar panels to supply heat to the digester

– digester

– “compost tea” maker

– DAF container to make “white water”

– stainless steel pressure cooker

Page 33: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 34: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

• Components– 20m2 raceway with 0.55 kW paddle drive

– solar panels to supply heat to the digester

– digester

– “compost tea” maker

– DAF container to make “white water”

– stainless steel pressure cooker

– plastic fermenter

Page 35: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 36: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

• Components– 20m2 raceway with 0.55 kW paddle drive

– solar panels to supply heat to the digester

– digester

– “compost tea” maker

– DAF container to make “white water”

– stainless steel pressure cooker

– plastic fermenter

– electrically operated stainless steel batch still

Page 37: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 38: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

• Components– 20m2 raceway with 0.55 kW paddle drive

– solar panels to supply heat to the digester

– digester

– “compost tea” maker

– DAF container to make “white water”

– stainless steel pressure cooker

– plastic fermenter

– electrically operated stainless steel batch still

– various tanks, pumps, drums and buckets

Page 39: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant

Page 40: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Pilot Plant Results

• Main Production Results

– algae density 4 gram/litre

– growth 140 g/m2/day

– oil recovery negligible

– ethanol production 50 - 70 ml ethanol/m2/day

Page 41: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Moving Toward Commercialisation

Page 42: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Production Plant Projection

Item Units 500 l/day 5000 l/day

Pond area ha 1.0

Installed power kW 30

Capital cost $ 600k

Variable cost $/litre 0.05

Fixed costs $/year 17.5k

Selling price $/litre 0.50

Sales $ 85k

Gross profit $ 59k

Page 43: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Production Plant Projection

Item Units 500 l/day 5000 l/day

Pond area ha 1.0 10

Installed power kW 30 150

Capital cost $ 600k 2.75m

Variable cost $/litre 0.05 0.1

Fixed costs $/year 17.5k 35k

Selling price $/litre 0.50 0.50

Sales $ 85k 850k

Gross profit $ 59k 645k

Page 44: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Commercial Production

• Physical requirements– relatively level site

Page 45: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Commercial Size Site

Page 46: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Commercial Size Site

Page 47: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Commercial Size Site

Page 48: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Commercial Production

• Physical requirements– relatively level site

– water

– power to drive paddles

• Potential deployment for “emerging farmers”– can be deployed to tribal areas

– relatively low cost for ponds ~ R75/m2

– centralized conversion plant: • can use a tanker for moving algae nutrient and concentrate to and

from algae ponds to centralized plant• better economy of scale for larger plant• better process and inventory control

Page 49: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Challenges to Commercialization

• Oil price stability• High capital cost• Limited markets at small volumes• Theft of product• Challenges to tribal area deployment

– Power for paddles: solar?

– Theft and vandalism – cables, tanks and pumps are vulnerable

Page 50: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Summary

• Production of algae to produce ethanol is economically viable• Wild algae production does not require a lot of attention• Can be rolled out for emerging farmers• Conversion plant operation requires semi-skilled expertise

Page 51: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Growing algae in the snow!

Page 52: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Growing algae in the snow!

Page 53: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

Growing algae in the snow!

Page 54: ALGAE TO ETHANOL: Using algae fermentation to produce ethanol 4 th AFRICAN BIOFUEL CONFERENCE March 2009.

QUESTIONS?

[email protected]