Alcohol reactions
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Transcript of Alcohol reactions
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Alcohol reactions
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Alcohols – reactions
• Addition of alkene to form alcohol.• Elimination of alcohol to form
alkene.• Halogenation (substitution) of
alcohol to form haloalkane.• Oxidation of alcohol to form
aldehyde/ketone and carboxylic acid.
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Alkene to alcohol• Addition – Adding water to alkene gives an alcohol.• this occurs when we heat the alcohol with 50% sulfuric
acid.• The hydrogen and the OH of the water is added to the
alkene around the double bond.
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Alcohol to alkene• Elimination – removing water from an alcohol
produces an alkene (by conc H2SO4)
• The removal of 2 atoms or groups is known as an elimination reaction
• The –OH and hydrogen from the neighbouring atom are removed.
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Alcohol and oxygen• Combustion: Alcohol of low molar mass burn easily in
the presence of oxygen, to form carbon dioxide and water.
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Alcohols - Elimination
• Or dehydration –removal of the hydroxyl group and hydrogen atom of the neighbouring carbon
• conc H2SO4/heat
CH3CH(OH)CH3 CH3CH=CH2 + H2O
propan-2-ol propene
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Alcohols – Halogenation (substitution)
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Alcohols - substitution• Or halogenation: –OH replaced by halogen atom
forms a haloalkane– PCl5 – phosphorus pentachloride– SOCl2 – thionyl chloride(These things put chloride on and kick off –OH group)
• Performed under reflux – increases the rate of substitution
• These can be used to substitute the –OH group in an alcohol with a –Cl:
CH3OH + PCl5 CH3Cl + POCl3 + HCl
CH3OH + SOCl2 CH3Cl + SO2 + HCl
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Lucas reagent• Lucas reagent – anhydrous Zinc chloride (ZnCl2)
and conc HCl.• The Lucas reagent is used to primary, secondary
and tertiary alcohols• The zinc chloride is a catalyst for the substitution
reaction between the alcohol and HCl.• The chloroalkane (haloalkane) formed is a cloudy
suspension in water as they are insoluble. • The rates at which different alcohols react make it
possible to classify them.
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Alcohols - Substitution
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Alcohols - Oxidation• Back in Level 2 organic chemistry we learnt that alcohols come in
three main forms:– Primary– Secondary – Tertiary
• We also found out that primary alcohols can be oxidised to form carboxylic acids
• Later we will discover that primary alcohols can be partially oxidised to form a group called aldehydes. Then the aldehydes can be oxidised further to form carboxylic acids:
• This year we will also discover that secondary alcohols can be oxidised to form ketones:
OH
CH3 CH CH3
O
CH3 C CH3
OHCH3 C
O
OHCH3 CH2
O
CH3 CH
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Alcohols - Oxidation
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Alcohols - Oxidation