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Page 1: hwbdocuments.env.nm.gov Alamos National Labs/General/14040.pdf... '- G! Los Alamos. National Laboratory UNIVERSITYOF CALIFORNIA 'k - - Mr. Ted Taylor Departmeni of Ener cn . tos Alamos

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Page 2: hwbdocuments.env.nm.gov Alamos National Labs/General/14040.pdf... '- G! Los Alamos. National Laboratory UNIVERSITYOF CALIFORNIA 'k - - Mr. Ted Taylor Departmeni of Ener cn . tos Alamos

. . . '-

G! Los Alamos. National Laboratory

UNIVERSITYOF CALIFORNIA 'k -

- Mr. Ted Taylor cn Departmeni of Ener Q . tos Alamos Area 0 i? ice, MS A31 6

10s Alamos, NM 87545

SUBJEm INTEGWTED MODELING DELIVERABLESIN SUPPORT OF PERFORMANCE MEASURE 8.32

Performance Measure E3.2, Integrated Modeling, for Frscal Year 1998 requiresthat these elements be delivered to DOE-LUO by September 1.7999:.

, e Letter-report summarizing t h e parameters and results of Los Alamos Canyon subsurface water ff ow a n d contaminant transport. and document Documentation of R-well data and modeling integration, specifying modeling input to- siting of characterimtion borehole a n d decrsions regarding which water-beanng zones to monitor *

A memo to support WOO baseline assumptions a n d resources, reflecting the integration of modeling results into baseline planning. The initial version of Hydrogeologic Atlas for the Pajarito Plateau,

The first three elements are attached to this transmittal letter. The H y d r o g e o l o g i c ~ a s was delivered to DOE-MA0 August 31.1999, (uER99-248). The 10s AIamos Canyon modeling is a brief report The documentation referred to in the P a n d 3"d bullet is provided in a n internal Laboratory memorandum from N t n Domes to Karen West (E/ER:99:251)

As always, we are confident that that the documents submitted under this transm'w meet the specifications of t he performance measure. We are hopeful that they meet your expectations, and Iwk forward to receiving your comments within 10 days of receipt. If you have any questions or comments please provide them to Alison Domes at (505) 6656952 no later than September 16, 'i 999.

L.

. . . Sincerely.

Page 3: hwbdocuments.env.nm.gov Alamos National Labs/General/14040.pdf... '- G! Los Alamos. National Laboratory UNIVERSITYOF CALIFORNIA 'k - - Mr. Ted Taylor Departmeni of Ener cn . tos Alamos

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. . . . . . . . . ' ' .Enclosure:. ' I) ;'LosAlarnosCanyon Subsurface Water Flow and Contaminant

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t

Karen West EIER99-251 . .

-2- August 37, t999

Finally, a model was successfully developed to visualize field data in three dimensions, specifically to graphically desaibe the nature and extent of the volatile- organic compound (VOC) plume at MDA L The use of data in each modeGng adiviry, specfically, is summarized here.

2 1 The FEHM model that was developed by EES-5 to calculate the flaw of waterfrom altuviat system through the vadose zone a n d into the regional aquifer utrued the following data: - PRS data from FIMAD and the ER contaminant database,

stratigraphic contacts from regional groundwater welk R-9, R-12, R-25. and R-75 0 hydrogeologic data from R-9, R-72, R-25, a n d R-15,

alluvial well contamination data from FIMAD a n d ESH-78 and ESH-19, streamflow data from csT-7.

Los Atamos Canyon Groundwater Model

Los Alamos canyon results suggest that contaminant migration in the vadasezone may require decades or more to travel time. This information is key to the long-term monitoring stratew for Los Alamos Canyon, which is a planned WOO adhity. Ultimately. the groundwa?erflow a n d transport mode! developed for Los Abrnos Canyon will provide a standard. or reference, model that will be used as appropriate for modeling (or scaling) groundwater transpoR in other canyons a n d watersheds.

The L o s Alamos canyon modeling is detailed in a letter repoR submitted to the DOE on September t , 1999.

22 The SPLASH model is an event-based surface water flow mode!. Eventually. this process model will be used to support cumulative-risk calculations for rnultipfe sources of soluble contaminants within a watershed. In FY99, t h e ER Project suppofied a successful pilot application of SPLAH, focusing on t h e North Ancho Canyon aggregate. The SPLASH model of North Ancho Canyon was developed using data directly from FIMAD. The FIMAD data included: - Digital elevation maps, w Soil distribution maps, and

Vegetation coverage maps.

In addition, ESH-18 a n d EES-I5 provided precipitation data.

Based on SPIASH modeling of runoff and inteflow in the North Ancho canyon area, PRS’s that are vulnerable to runoff a n d interflow can be identified and ranked. This will be important t h e future CMS activities for that area conducted by the Remedial Actions Focus Area, a n d in assessing cumulative impacts on watersheds across the Pajarito Plateau. The pilot application of SPLASH to the North Ancho Canyon watershed ag regate is detailed in a report from EES-15 to the Analysis and

No& Ancho Canyon Sufiace Water M o d e l

Assessment ; ocus Area.

. .I ,

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7 ~ ~ s Karen West, EIPPC,.MS.J552 F e - Alison Dorries, EES-73. MS M 9 9 2 3 n h A k . t

Los Narnos NATf ONAL LABORATORY

Memorandum 7-0aow5-4747 Envfronmaiscienc-~W#t,~.chno~oW(~ symbo(: UER99-251

August31, I999 Envf-R..- EIER

SlJWECT: BASEUNE

INTEGRATION OF MODEUNG INTO WORK ELEMENTS-IN THE W O O

-Lo m The purpose of this memorandum is to document how: - exish'ng corred*vwdions data were used to develop computational models of

contaminant flow and contaminant transport in FY99, and model results were used to support decisions for correctbadon activities in W99 and FYOO,

This teport fulfills partial completion of Performance Measure Bi3.2, Integrated Modeling, for Fiscal Year 7999, by meeting the requirement for documentation of the integration of deep-welt data and modeling, and documentation of input to siting of characterization boreholes and decisions regarding which water-bearing zones to rnonitort This document also reports on other accomplishments of N99, which reflect further integration of modeling, data, and decisions.

Section 2 (below) summarkes data use in models and progress through FY99, and %ion 3 summarizes how model results has influenced ER baseline planning decisions.

,

20 LlsedmainModek There were t h r e e activities completed in R99 that successfully integrated existing field data into mathematical models of water flow and contaminant transport These were: - Subsurface groundwater modeling of Los Alamos Canyon, using the FEHM

Surface water modeling of North Ancho Canyon, using the SPlASH code Surface water erosion modeling of the main drainage off of Mesita del Buey (at MDA G) into Pajarit0 Canyon

The models, daZaa, and results for each of these activities are detailed in final retained by the ER ProjecL

Three other modeling activities that were initiated but not completed in fT99 (and have therefore not been fulIy documented yet) are indicative of the successful integration of field data into contaminant fate and transport models. These are: a Preliminary subsurface groundwater modeling of MOA AB,

Preliminary subsurface vapor diffusion modeling of MDA L, and e Preliminary sediment-reach erosion and contaminant transpoe modeling of 10s

+ AIamos Canyon.

Page 6: hwbdocuments.env.nm.gov Alamos National Labs/General/14040.pdf... '- G! Los Alamos. National Laboratory UNIVERSITYOF CALIFORNIA 'k - - Mr. Ted Taylor Departmeni of Ener cn . tos Alamos

. r * Karen West EER.99-251

e' '

August 3% t999

23 The KINEROS model is a process model that simulates erosion resulting from surface water runoff. This model can be used to integrate the erosion caused by multiple sequential runoff events, storing moisture between events in neaf-surface soils, Eventually, this model will be used to support decisions regarding corrective actions in the context of their impact on site erodability, and to couple mesa-top a n d hillside PRSs with canyon reach= to investigate cumulative effects of partialate (sediment- bound) contamination within a n aggregate. In addition, thb model may be used to couple surface and groundwater models. The ER Project funded a successful pilot application of the KINEROS in N99. The model was calibrated using data from t h e EES-75 surface-process pilot studies funded by t h e Analysis and Assessment a n d MDA Focus Areas. The calibrated model was applied at the major draina e from MDA G to Lower Pajafito Canyon, The results of project.

2.4 MDA AB Groundmter Model In early FY99, the project was mnsidering implementing P h a s e 2 FFI sampling atTA- 49. The purpose of the Phase 2 sampling was to characterize the hydrogeologic setting and to bound the extent of subsurface contamination. These objediveswefe to be met by the drilling, coring. and sampling of o n e or more boreholes around Area 2 of MDAAB. In keeping with the evolving MDA Core D m m e n t strategy. preliminary groundwater transport modeling of contaminants in the MDAAB inventory was tnitiated by EES-5 under t h e support of the ER Project The cbjec?ives of integration of data and modeling are:

Mesib del Buey Surface-Water Erosion Model

t h e pilot application of KIN z ROS are included in a final report from EES-fS to the

Development of a 2-0 numerical grid a n d flow model for t h e Area 2 subsurface, calibrated to in situ moisture data from 3 boreholes and are data from existing boreholes.

e Calculation of expected transport of plutonium, uranium a n d cesium (from the tracer shot), using t h e calibrated flow model. Interpretation of results ofthe transport calculations in determining depth of vertical borehole through shaft 2A-O.

0 Revision of the flow and transport model as necessary to reflect core and moishtre data from borehole through shaft 2A-O.

e Interpretation of results for siting d i r ~ i o n a l l y d r i l l e d horizontal trorehole(s) to bind contaminant extent a n d to presenre the basal surge deposit at the base of Unit4.

This work will be completed in accordance with the prioritydriven schedule and baseline. To date, prefiminary flow and transport calculations have be% conducted for cesium, uranium, a n d plutonium

2.5 lo complete the corrective action process at MDA L it Will be necessary to understand the nature, extent, and environmental fate of theVOC plume beneath MOA L While the existjng groundwater flow and contaminant transport. model (FEHM based) of MDA G is sufficient to model the environmental fa:e of soluble contaminar;ts, at MOA L, it cannot model the environmental fate of volatile contaminants. To develop a full multi-phase transport model for mesa-top MDAs, the

MDA L Vapor Diffusion Mode)

Page 7: hwbdocuments.env.nm.gov Alamos National Labs/General/14040.pdf... '- G! Los Alamos. National Laboratory UNIVERSITYOF CALIFORNIA 'k - - Mr. Ted Taylor Departmeni of Ener cn . tos Alamos

t

MDA Focus Area suppofied the development of a vapordiffusion model for Mesita del Buey. Once completed, the multi-phase subsurface transport model developed for Mesita del Buey wiH provide the standart! framework for modeling or scaling subsurface contaminant fate and transport at other mesa-top MDAs.

The data from MDA L used to develop the model are reported in a n attachmentto the RFI Repor& for MOAS G, H, and L, and the concep:ual model interpreting the data as a basisfor numen'eal modeling isdescribed in a report prepared by ESH-18 for under support from *e ER Pmjed. *

2 6 Lo3 Alamos Canyon Sediment-Reach Erosion Model The SPLASH model (discussed above) is used to simulate waterflow at large (Le., watershed) scales. a n d will be useful in calculating cumulative riskfrom soluble contaminants within a watershed, ?he KINEROS model (also discussed above) is used to simulate surface-water erosion over a relatively small scale (i.e.* aggregate or subaggregate), a n d will be useful in coupling particulate contaminants from mesa-top and hillside PRSs to canyon reaches. A different model is. needed to calculate ?he long-term effecS of eroston on a watershed scale, which is needed to calculate cumulative risk from contaminated reaches within watersheds. Such a model is currently underdevelopment by EES-1. The model is using data from the ER Project surface invw'igations that support surface aggregate characterization. These data provide a calibration of the model under development

27 MDA L VOC Plume Visualbation ' I

The Laboratory (incluciins tbe ER Project) has been monitoring the subsurface contaminant plume beneath MDA L at TA-54 since the late 7 9805. Sufficient data now exist to demonsirale that t he nature and extent of contamination have been characterized, as necessary to complete the RFI for that site in W99. In addition, t he Citizens Advisa 8oard (048) made two inquiries regarding the MDA 1 VOE plume in

meet the requirements forthe RFI, and to provide accessible information to Zhe CAB. A summary of the data used to develop the visualization model is included as an attachment to the RF1 Report of MDAs G, H, and L (under development).

3.0 LkeofMocMResultFinpbmedddMties There were three ad*vkks completed in -99 ~atsuccessfuIly,in:egrated model results into the decisionsnaking resarding future activities in the correctiveaction process. Thesewere: - Preliminary regional grounbwater results used in siting and/or completing R-6* R-

24. and R-26. * &os Alamos Canyon groundwater results used in developing the tracer test in DP

anyom 0 Groundwater transport models of MOA G used to support recommendations for CMS at MDAs G, ti, and 1,

N99, The ER r rojed developed a three-dimensional model ofthe MOA L plume to

3.T Groundwater transport modeling supported &y the ER Project bas identified several data needs forthe conceptual hydmeo log ic model of t h e Pajarito Plateau. Ultimately, design, implementation, prioritization, and scheduling of data collection activities will be determined by the Groundwater Integration Team (GIT) in accordance

R-Well Siring and Data N e e d s

Page 8: hwbdocuments.env.nm.gov Alamos National Labs/General/14040.pdf... '- G! Los Alamos. National Laboratory UNIVERSITYOF CALIFORNIA 'k - - Mr. Ted Taylor Departmeni of Ener cn . tos Alamos

c a

'Karen West -5- August 31,1999 ETER99-251

: with the Hydrogeologic Work Plan. These *hues have been put forth to the GlTfor . consideration:

Regional aquifer modeling conducted by E E S 5 using FEHM reinforced the need for R-wells (24 and 26) in the vicinity of the Pajarito fauh The lack of field data on hydrologic conditions imposes a large uncertainty on a potem*ally important flaw

I path in the model.

Modeling of Los Alamos canyon indicates that R-6 should be dnied on the u p thrown side ofthe Pajariflo fault to evaluate recharge on the western partion of the

' Laboratory.

F EHM modeling of transient flow in the regional aquifer system was found to be , quite sensithe to porosity data for the sedimenta un'rts. Few data are currently

available, and the modeling supports collection o 7 facies-based porosity . infomation.

0 Regional aquifer modeling has also shown the need for bettervertical resolution of hydraulic head data. In addition, the need for largescale hydraulic propertieswas . identified. To address this data need, the GIT has planned for rnuttiple screens in future R-wells :o make multiple water-level measurements, at various depths, which will be used to construct vertical hydraulic head distributions.

I = FEHM modeling also suggests the need for improved groundwater dating to provide for bener testing of r e s u l t s and improved model calibration,

The documentation of discussions of modeling results and their hiemretation in the context of data needs from the Monitoring Well Installation Program is contained in GIT meeting minutes, which are prepared and retained by ESh-f8.

32 DP Tracer Test Atracertest is designed to confirm conceptual model for fate and transport of contaminated alluvial groundw$er within the DPAA canyon aggregate, This aflwial system is considered to b e representative of other alluvial systems under investigation by the ER Project, therefore data from this test will support deveJopmerrt of a standard alluvial groundwater model. In particular, the tracer test will provide d3ta on water residence time, dispt3rsivh-y. conductivity, e t c , which ate necessary parameters for groundwater flaw models.

3.3 The draft RFI Report for MDAs G, H, and L completed in FY99 by the ER Project and submitted to DOE-tAAO fully documents the data and infomation used tc model features, events, and processes related to contaminant fate in em*fonmental med'a Using the RIP computer code, a systems model was developed to cal~~late contaminant concentrations in soil, biota, and groundwater overa period of ?O,OOO years, which were lhe basis of future risk assessments conducted forthe RFl. 7??e

MDA G, MDA H, and MDA L RFI Recommendations

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. . . .

. . . . . . . . . . , . ,

, . . . . . . . . . ,-. , . , . . ' " ' . . %:". .' ' ' i I .. resulk of the"R1P &lculations and' risk assessments wer& us&'to.support a

.recommendation. for a streamlined CMS at MOAS 6;: H,. and. L '

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of the.RJP model'application and results are reponed' in Appendix F of the RFI Report . . . . , . . .

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.L Numerical Model of Flow and Tranmort

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Page 11: hwbdocuments.env.nm.gov Alamos National Labs/General/14040.pdf... '- G! Los Alamos. National Laboratory UNIVERSITYOF CALIFORNIA 'k - - Mr. Ted Taylor Departmeni of Ener cn . tos Alamos

htmductlon and rnotlvalon

1 .o Introduction and motivation

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2 0 Site-wide examination of hydroteqic proptrtiesand . - recharge through the Otowi member

21 Spatial variability on the Pajarito PIatcsu

?hc m Orowi Fomrion wggm a common origin of rhc gcnerk Ik~IclicrTuff of which i t is cornprkd Gcoloj$cai history (Akclc. 1981) suggests thjt thc Otowi Mm-

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from CDBM-1. twc, from mBM-?, five from MM-S.9A four fm X-I. six fmm LADP-3. and h i m fom LADP4. Minimum-mimum pairs arc g h in Table I fw rk40 sarrrpk. and Table 2 I d s thc plartingsymbolsand the data s0urc.c~

TABLE 2

6 of 126

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21.1 Summary af thb analysis technique

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Sito-wido axamination of hydrolagk proporrles snd recharge through me Otowi

. . . . .

of 3 small uarrslucnrt cubc having c d p in thc d i d o n s ~y..;urd z king omervtd with one cyc. If thc cubc is f x a w y and rowtcd just right. only rhc x and y edges wilI bt visiblc; dl infomation in the z directjon appears piled on top of itself. This is3 pro*- tion onto x-y spacc. If that cuk is romicd about tht y axis by 90 ctcgms then rhe t and yedgmWill bcvisibleandthcxinfotnwtion blctsl.Ifthecu!xknot fuawy.asimik situation ctccurs with mpect to informarion piled on top of othcr information, but w h s is viewed is 3 n m h q y a p h i c nubdimcnsiorml pmjcction.Wc rclroict ar;rsclm to onhogmphic proJcdons in throe and higkdimmsictn.. companding todirsant cuba bewusc hey m simpler mthamtically and conccpaully.

Supposein thraedimensionsIh;Uthacareanumberofpinainati~td~011thC x 4 face of thc cube and motherdrntcrof poinhon rhe x t l faceasshown in FigurcZ k two clutcn might appciu to o m h p a h othcr w b looking only at they yrd t value as shown on rhe Idt. Howewer if the cube hewing thcx p i n s k rotated so hat the x . = O p a i n t s a r c ~ a d f r o m thex=l painnasshornon therightitbccomesclesr hcrc arc two sspmtc clusters T h w w c s a that in t h r a dimenions oug dimemid v i m a n pvc us infomdon a. to the oEiaencc of scp3mc scts of points q c c k d l y if all psihlc rotations of the sccofpoina isallowcd. It shauld nwcomeasa surprirthjt if wc can scc thc distinct unobwsuctod points in 511 specified two dimarSiond odm- graphic views (in fact wc mal only two such vi- if we ux a la of rnah-), we hve thc 53me informmian 3s seeing t!! infomtion in throt dimcmions. Wsrrr w - c - u k l y attuned to this condition btcausc each of our nu0 yes scc I twodimenSiorul pm- jcction of a t h r u dimensional world Thus our two ya M dhinyish thc rn of points in the two clustms as k ing distinct. and this rcsult is aidtd and xhicmblc by only one eye if the cuk is properly nHJtcd

ScO of points th31 arc confuscd in a nvodjmcnsional pojtction might k sepmble in J

higherdimension.Ifby mutionrofthc set ofpints in the h i ~ d i m c n s i o n d s m w c find aprojcction in t w o d i m e n s i o n s t h 3 t ~ ~ a s e p Y J t i o h ~ l y w e ~ ~ r h a s t p i n t ! ilfe scpantcd in rhc higher dimensional sp;re. If thc p i n s arc e l c by ;1 linc in twodimcnsionsas in thccmmornght mostprojc&ondFigurc2,wtstylyiisa 1incardiscrimin;ttw. i.c. a mc5m by a linc to tell which phs;tre in tach of twodistinct set*. The method of describing this linear discrimination in hc highcrdimmsiod !+ace is quitc s h g h t f d In three dimensions wh3t 3ppcms to be 3 line in thc nud dimensional orthopphic pjdm when cmbcddcd in rhc rhrtc dimensional space, is LI plane. If the plane. like il sheet of ppcr. is so orien~ed that only ib edge is visible. o line sqrncnt is produced in the projection. In the right-mort Pr0jtct;on of Fiyrc 2, Ihc plane is thc y-r p h M3; in the m t m projection. the p k edge is shown snd planc is less s)mmrnic Because thc projection piles d1 infomtion in the Projeatd dircction on top of itself. &n p~sallcl lines in thc phncall pile on top of thcmsclvcc. Thus. if in three dirncnnsiom GO sets of p i n t s arc *epanble by a p k snd if we chooscsny line oftha pl;tnc:irs a Projcnion dimion.wcmn mkcthsrlincqpcarasa point try looking down the bore of thc line, 'Ihen the nu0 dimensional prajeCt;on will project the plane LS a line and a l i m s discrirniriation is achicvah The sunc shahn holds in highcr dirncnsion: if we can sec J sepYa;tion by a linc in a twodirncn4d orthographic projection,;r hypcrphnc sqxmws thc dam in thc higher dimcmional space (= Eyre 3).

Givenasetofpointsin t h r t e d i ~ i o m . w e c a n ~ ~ k t h e q u t s t i o n o f v ~ a n y s p c b - ficd point is imide rho given sa orouuidc If wc have four n m - p k pain% we M

8 of 126

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An onhopphk projcdon has 3 patkuhr propary that makes it useful with rsptcr to thor points derived by B wdghted mmge of the outennosf poim. TIC projecdon of a d c r i d point ~ s n be conmvcrod in two ways: 1) it M be compltcd first as a dcrivcd point in the full spaccas ifn novpointthcrr,and then projcckdtotkmbahhl space (the W i m c n s i o n d phe): or 2) the projection of involvcd out~most poinrs of thc hull M cach be projected IO rhe cmbcddcd space. and then thc dcrkc! point in thc cmbcddcd space M k computed in Ihc prajdon using the s ~ m e weighs as those used in finding the dcrivcd point in tbc full space. The fmhmand * propeniccfollow from the ssociative h w fwmultiplic3tion. that a r d a o f mdtipliaticm mkts nodiffa- cwc in computing LL product. Simply put if o point is half way hawetfi wo points in thc full s p a c . ~ it m i n s half way bctwccn in thc ofihoSnphic praliacdoh

From this it follous that if point?; lie within a convex hull in a twodimcmiorul m- tion wtmc boundvy is a given polygon, hey will lie within o polytbpc some of w b faces or cdga arc rclarrd IO thc cdges of tk polygon, in Figure 4. E3ch cdgc of thc

Rajcction of polybt+d U p p u S d ~ O f J pinu onto ii plane wrth MI po1y-n in pmcnct of a foreign point

FIGURE4

10 of 126

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ouwidc M be established by projection. In panicular if a forrign point is outride r hiphcrdimcnsional hull.aprojccdoncan kdKKcn WmpsthcfJcc~ta the fbP- eign point into s line of the OnhOgJphic pr0jtCt;on In Figure 4. rhe fact is n ~ l quite mappcd cnta a&gh line, but by a d l c h p in obscrv;?tion dimxion &e rhrtc pains of the face will fall onto a str;lipht line. lhar fm-gn pint tbcn musz a p p r art- side the polygon of tht pmjaed convcx huIL

212 Application to the Otwl hydrologic deta

Wc now apply the mahods d i h in thc p i o u s subuction tothe hydrologic d m for the Orowi member. 7hc well algorithm is as follows. In the six dimensional spjcc dcscribcd previously, construct 2D CO(IVD; hulls in thc spxc fbr LADP-3 as in Figure 5

\""

FIGURE 5.

and MM-S.9 clam. No points of my other well l i s ~r&lc Qitba of thac polygom; Thus in he rUn spxc no points of he ohm wells arc inside the highcrdimcnsiond c o r n hufls of LADP-3 ;Lnd MCuI-59. As noted, the c o w huIl5 ind& JII of tbe points 'Slat un be rt3chtd by interpolation, tht d 1 O d inSidc points, ix, awdghd sum of thc q o n d values with positive weights thas sum to unity, but not by exmpolo- tion. By use of thesc hulls we move thcst twg portions of spxc kcJusc tbq ;vt

assigned to thc two wells. I f we ye given my point from oncof the two specified Mils wc M clolry identify it by whcthcrm not it is inside OM of tht two a m hulls

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a Unsaturated Conductivity

dH q = A- &

onit@ent driving fa for fluid pac0lr.h. lhtrrfors

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16d126

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Stte-wide examiMtion of hydralogk -and rsdurgatfvaugh thtotowl

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poinasppca to have morcvyiylccwhcn plaatdm a log d e in Figure 13.thisisaos so.

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Stratlgraphlc mod41 and gdd genumtlon

Tshiqc m c m k of the Bmddia Tuff

3.0 Stratigraphic model and grid generation

Unit 5 Q b 6

3.1 Smigmphy of the Los Atamaj canyon model

T ~ w i F b ~ i c c

Groupfirmiition I Unit Name

QbR

1 v3por-pk d t d mcmbcr of unit 1 1 Qbtlv I

CcrroToledo h t d of the Banddim Tuff

Ccrro Toldo

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4.0 Summary of Wzter Budget Study for Los Alamos Canyon

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5.1 Contaminant Release Shes

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6.0 Two-dimensional flaw model results

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7.0 Three-dimensional flow model results

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3D IIco641-Wdl R-9

R-9

c

"K t800 &

- 7 \\ 1

m I *

0.0 0.j 42 0 5 V d Water Co%

. . FIGURE 57.

. .

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: . . , , FIGURE 58.

. . . . .

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8.0 Transport Model R e s u l t s

Although P m m compktc modeling of thc mjgmtion of connmimts in the Lm Ala- mm canyon study a m is plmncd for rhc funac, his &on sumnwks rcsdtr of ini- rialsimul~tionsofmtiummn~Tritirm~inthcform ofnitistedvntcr,is;unongrbc simplcst c h i c a l constituents to model bccJusc its chemical s ~ t c as a wJtcrmalcculc implies that ir is a uacm for W. Orha contaminants m y u d a p sorption. pip i ta - tion, and complex speciation ptaccascs hat complicate the m p o n simuljtian.Tbcm- fore. its was dm*dtd to fceus mention on ttrc simulation of tritium rr;msposc m pait of thc o u d l flow m&l dcvclcpncnt. Combining the results of flow modeling with sim- uhions of tritium tranzp~n provides rhc foundation for r u m modcling c f f o n s d ~ + ing the migmion of moE cotnpla conmimts.

8.1 Transport M o d e l impkmentatlon issues

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I .

93of 126

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J m w 23,1993

August 2,1999

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Transport Model R e s u l t s

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August 1,1999

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la301726

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70.0 References

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I " . ..l.

'21 c * 11.0 Appenlfrxf-Summary of effluentsoweesand *4

2 contarn'mants to to$ Alamos and DP Canyons -

. . I

. . . . . ' . . ' I

. . . .. I . 2 . : ::, I

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Appendix 1, Summary of eZnwnt sources and tantaminantsto tc#Alamos &nd

d u e n t volume rqxmd.

PRS 1601KY - ~ - ~ c d T L J B u i l d j n g f r a m c a r l y 19505 until removed in 196j.Disch;ycd toHiilsidc 140 tributiuy. Suspected contaminants: mium, m e ~ l s 'j'CS. No dffucnt volumcs tepond

-?7 - T A 1 7 6 n b n i n n c t W - - -drained Wychousc4m (used fornon-rad, non-hazstm$c).Pmba- bly dischxgcd to Hillside 140 tributary. tow Id U contamination found in ouddl during 1974-1976 survey (sros alpha max 54 pCi/g). Suspcctcd contaminants m i u m . So effluent volumes reponed.

pRs) - T.4- 1 -75. -76 SrMmDrain.nnd..Outfa1l - dnincd anabctwan Wmhouse4an.d thcJ W o n A n n a Probably dixtuqcd to Hillside 140 mbutuy. 19741976 s u ~ c y found 3mnium conmimhn'ncsrthc smm drain out- fall that was believed to haw Origiinotcd from h TU and "-1 Building. Suspccttd cantomiMnrs uranium No dIlucnt volume rrpancd

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IMMh) TAl-6- . . - - -served D Building (plutonium processing-edmcnodplutbaim ninvc solution into a purificd merallic form) and dirdurgbd tu Los Ahm Canyon Them id qr~mr t i c r of fluids handled b y t h i s d n i n 1 i n c ~ u n ~ S u s p t c t t d c o n t u n i n ; m t s : Z l g p p ~ .

-served WYthousc 13 (Zia Company Opcntions site) from approximately CuIy19405 until mid to late 1950s and dischiqcd to Lar Ahnos Canyon (or mort likcly. to thc W l tributary to LI?S Alarm Can- yon in this m). h t i o n is war stmgc building south of present day Sonic Drivc-In. Bulldoled into t r i i of LQS AImos Canyon prior 10 1974976 clonup. So contaminants auspecttd No f l u e n t volumes repormi

109 of 126

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. . . . ,.

. . 110 of 326

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In May 1963.1OOO gallons of liquid from the resin bod qencmion ws discharged. It conuincd sharx-livcd radionu- clide and L5 mCi of %ln.

In 1970.0, monironng repon sutbd that water from thc a5d pic (ITS 244I.(c)] was pumped into the ucck thtwgh I con- m c wench. Before dcconmmination, radintjon Icvcls as high as 30 mRlh w a c m d in tht umzh

nt dl26

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Thc following summaries cue from thf RFZ Hod Plan for Openabk Unit / O f / W12 1993, =ID 7667) chapters 3.5 and 6 - O~tfo l l~ .

112 of 126

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I 7 3 ai l26

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TA-26, &Site. W~LF enwblishcd for CMR division: opernted from 1% to appmximrcly 1965; stdwcd d i d v c ma- 01s in o mnmc stonp mull b t c d w u ~ u of East Gate on SR W2 on mcsil cdgc Canyon. S u m m i c s arc from thc RFX Work P h for Optmblr Unir /07I (LAXL 199- EFt ID 7667) ch;lptcrr 3.5 a d 6 - Outfdls.

- --consis& of debris from a fiwe-nxxn comctc stomp vault that wiu dccammis- sioned and dismantled in 1966 and possibly a septic tank A prcdecammiruoning s u ~ e y found alphaconmni&on oa the smcturc of up IO 10,060 cpm: eontmimts suspected to bc &chad % snd 3%J and pascibly plutonium No information documenting he disposition of the radioactive m t d s s l d in thcwult afe qxrtcd.

1M. Sysrem wzs asswk~tcd with the highly conmirmcd south Ccnmmm of the slmgc wult and is W IO bc contaminated with dionuclidcs and possibly acids. Consisted of a callcction sump ;md 0uda.U fordischarge into Los Alamos Canyon. No cft3ucnt volumes rrpond

W M 7 - - consisted of 250 gal ml tank and wtldl for disc- to Los Ahnos Canyon. Tt sbved sanitaryfacilitiesIou~Cdin thce;~ctr00rnofthc~3ultfrom IWto I965.Bcnuscmdi6activc~tsrnin;uion~foundin vault. it is porsiblc that contaminants were introduced to thc sysmn.T..k my have bxn disposcd overthe edgedong with the vault debris. No dnuem volumes repnod.

nonh rim of Los &mos

. .

t9-s- thrY3Ult I . - o p t e d fram 3pproxim1dy 1935 to

TA-Z DPSik

114 of126

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Appendix 1, Summary of f l u e n t w u m s and contamiM&to fos Alamos and

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3 c

2 1 - ( r ~ ) c o n s i s s o f w n k ~ - ~ I - l 9 5 ~ l o c i n t t d ~ n lincsJnba lwchfield that motcd swage from TA.21-209 (high-tcmpcnnrrcchcmisuy building) fmm 3pprou'matcfytbc IpioI until 1966.Ihe Iachficld waq locatal nmr thc rnw d g c above La Aljmos Canyon. Potcnhl contsminana include d o n u - Elides, opnics, mctals and common labomtory chemicals. B.orehala werednllcd and m p t c d in 1993, howcuerthcdam was not rcccivcd in timc for inclusion in the Phase Report f C TA-ZI Oprmbk Unit RCRA F a d @ I m n i g a z i a - Ou#.al& Imesription, (WivL 1994, ER TD?). thcrcf~n no data is reponed

W : ! f l ) - -dd liquid WE from the floordrain of tht rnccbid mom in TA-21-21. which W;LE formcrly u s d as P vault that srorcd plutonium and unnium d s . Thc ourfdl linc rn nonh tMvYd DPGn- yon. 1992 RFI soil sampling detected to be present h e background crt only one of six locations below the6urfXl. 38Pu was dctcctcd of IL concenmtion of 121 PCJg at thc 0-6 in. intavpl . Asoil sample was collected in 1988 at 3 l a - tion that my not rcpmcnt Ihe outfdl: the data a m reporled in PharcRcpot~IC TA-21 Opmzbk L.'nirRCR.l Fariliry Inuesrigarion. Ourfolrs Invmigarion. ("LtVSL 1994, ER ID?. Chp 8). Na d f l m t volumcs rep4ncd

- - m o d TA-21-46 (old diere1 plant which VJZ~ famncd to a wa&ousc benvsn 1957 and 1964) and discharges south into Lor Alarnm Canyon. Additional hiuoriol information (cg.. opcmcion a) not reponed The following SVOC constituents ( m a conmm'ons) wcrc damcd in 1992 RFI soil synplcr collcctcd bclw thc outfdl from two loc3dons and primarily fmm rhe 0 4 in. in&: knm(b)flumthnre (580 ug/s). benzoic acid (2450 udg). diethyl phWatc (19,OOO ug/& fluomthcnc (500 ug/s), phcnanchmc (410 ads), phcnol(1100 ud& and pyrenc (580 in the Phase Repom I C . TA-2f Opmbk Unit RCRA Fmifity Invcsriffariotc Orylallr Invmigation. (Lk\' 1994, ER KD?. Chp 8). No effluent volumes rrpontd

'

19xR a i l sample &CB indioting law c a r n a t i o n s of inognnics and ndionwtidcr are

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11901726

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. . 120 of 126

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0.0241 0 . W 0.0169 0.0162 0.0lbx 0.0159 0.olr 0.0211 --------- 19g3 a m ~ a m 0.0167 0 . m 6 o.miE awn a , ~ 0.015~

I ~ M 0,0193 o , o r ~ o.o i f~ 0 . m 0.m a m a m 0.01s

1985 0.0153 0.0153 0.01% 0.0ln 0 . W 0.m 0.0MQ 0.0104 0 l o 0 0

1986 0 0 0 1 0 0 0 0.0124 0 0 0 0.- aoou

I 1990 10.031 I o m I a w Io.0058 I a m I o l o l o I o l o I a . o c o l o I

198'7 0.0075

19a 0

IOU9 I 0,0106

0.009 O.b?of O.ooo8 0 0 0 0 0 0 0 0

0 0.013 0.oOcR 0.4595 0 0 0 0 0 0 0.01 c6

0.w 0,ms 0 0 0 0 0 0 0 0 0

121 of726

1991

IW-

~ ~~~~

0.0142 0.0912 0 . m 0 0 0 0.039 0.0109 0 . m 0 0 0

0 . m 0.01~4 0 . m 0.0065 a . w 0.00s 0 . m 0 . m 0 . m 0.m 0 ~ ~ 1 6 3 ami

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7 h c LASL did not dischqc any subsmtisl quantities of =Pu untn 1967 (?'u discharged prior to his -1. So mu- tine anaIysc5 wcrc m& on thc diffcrcntiatioo bctwm >'Pu and % until 1971 at which timaboa W a f tbe plum nium was 3*Pu. This ntio had continuad to i n c m s c until % is now (written in 1973) sbout9S5Si. of tht total plutonium relawd.- (Chrisrcnson, 1973, ER ID?)

122 of 126

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..

5

I

1 zinc 1. cyanide ’ 1

Bromoform 16

,. ,

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* 4

Appendix 1. Summy of dllwnt swmuand commln.nts to Lor A l r m urd

. , . . , . . .

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- 5 . 124 of 126

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. . I .

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. ..