AFLAS Fluoroelastomers

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AGC Chemicals Americas, Inc. Your Global Source for Fluorochemicals | 2013

description

Technical overview of AGC's AFLAS Fluoroelastomers, including performance analysis, competitor comparisons and examples of applications. For more information, go to www.AGCChem.com, call 800-424-7833 and follow us on Twitter @AGCChem_Amer

Transcript of AFLAS Fluoroelastomers

Page 1: AFLAS Fluoroelastomers

AGC  Chemicals  Americas,  Inc.  Your  Global  Source  for  Fluorochemicals  |  2013  

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Page 2: AFLAS Fluoroelastomers

Posi4oning  Map  of  Fluoroelastomer  

75 100 125 150  175 200 225 250 275  300 Heat Resistance (°C)

0

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ACM  

HNBR  

FKM,FEPM

CR  

NR  EPDM  

VMQ  

Oil

Res

ista

nce

(△V 

%, A

STM

No.

3 O

il) Fluoroelastomers  

AFLAS  

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FEPM  =  AFLAS  

-­‐(CF2-­‐CF2)p-­‐(CH2-­‐CH)q-­‐  

CH3  

TFE    

Pr    

FKM  =  Viton,  etc.  

-­‐(CH2-­‐CF2)l-­‐(CF2-­‐CF)m-­‐  

CF3  

VdF   HFP    

-­‐(CF2-­‐CF2)n-­‐  TFE    

Deteriora4on  by  Base  

Polymer  Structure    

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Characteris4cs  of  AFLAS    1:  Base  Resistance  

                        AFLAS         FKM  terpolymer                                                   FKM  dipolymer                                    Peroxide  cure           Peroxide  cure                                        Bisphenol  cure          

       AFLAS                           FKM  terpolymer                                                              FKM  dipolymer                                          Peroxide  cure                                                                  Peroxide  cure                                                                    Bisphenol  cure      

28%  Aq.  Ammonia  (168  hrs.  at  25  ℃)  

Ethylene  Diamine  (70  hrs.  at  25  ℃)  

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150   200  Volume  Resis4vity     (Ω・㎝)

1016   1015  

Dielectric  constant  (1  kHz)  

3   6  

Dielectric  strength  (kV/mm)

23   16  

FKM  

1013  

10  

20  

EPDM   Silicone  

1016   1016  

2   4  

40   25  

AFLAS  

Characteris4cs  of  AFLAS  2:  Electrical  Resis4vity  

AFLAS  has  both  excellent  electrical  resis4vity  and    heat  resistance  

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Characteris4cs  of  AFLAS  3:  Steam  Resistance  

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Heat  Resistance  

Acid  Resistance  

Base  Resistance  

Steam  Resistance  

Electrical  Resis4vity  

Volume  Swell  in  Non-­‐polar  Solvents    

Flexibility  at  Low  Temp  

Brible  Point  

FKM   AFLAS  

AFLAS has various advantages over FKM

Comparison  between  AFLAS  and  FKM  

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Automotive lubricants contain many amine additives

Base oils

Others Antioxidants Abrasion Inhibitors

Dispersants

Viscosity Index Improvers

Example  of  AFLAS  Molded  Parts  

Oil  seal  for  automo4ve  

•  Oil  resistance  •  Heat  resistance  •  Base  resistance  

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0

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0 200 400 600 800 1000Immersion Time (h)

Ret

entio

n (%

)

AFLAS-Tensile

FKM-Tensile

AFLAS-Elongation

FKM-Elongation

Immersion  at  175  OC  

AFLAS  and  FKM  in  SJ  Engine  Oil  

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AFLAS  and  FKM  in  SJ  Engine  Oil  

Vulcanizates  a=er  immersion  in  SJ  Engine  Oil    at  175  ℃  for  240  hours  

AFLAS   FKM  

Crack

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Example  of  AFLAS  Molded  Parts  

Wire  &  Cable  

•  Heat  resistance  •  Chemical  resistance  •  Chemical  resis4vity  

•  Robots  

•  Express  train,  automo4ve  

•  Cable  for  furnace    

 

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Example  of  AFLAS  Molded  Parts  

Oil  Field  (oil  rig  parts)  

•  Oil  resistance  •  H2S  resistance  •  High  strength    

AFLAS  has  long  been  used  for  oil  field  applica4ons  

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Example  of  AFLAS  Molded  Parts  

LCD  –  Semiconductor  Process  

•  Chemical  resistance  for  these  processes:    

•  TMAH,  NMP,  NaOH,    Aq  Ammonia,  etc.  

•  Plasma  resistance    

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Example  of  AFLAS  Molded  Parts  

Food  &  Beverage  Produc4on  Process  

 •  Resistance  to  steriliza4on  

•  Steam,  sodium  hypochlorite  (NaCIO),  peroxyace4c  acid  are  typical  

•  Low  odor  aier  contact    

AFLAS        Silicone HNBR       EPDM  O

dor I

ndex

(Orange juice 30% soaked 80 °C 24hr)

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AFLAS  Products  

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Strategy  of  AFLAS  R&D  

No.  1  supplier  of  fluoroelastomer  with    highest  base  resistance    

Fluo

rine  Techno

logy  

Base    Resistant  

Fluoroelastomer  

PolymerizaPon  Technology  

FormulaPon  Technology  

Analysis  Technology  

Technical  Support  

High  Durability  

Processabilty  

 Higher    fluorinated  

Automo4ve  

Wire  &  Cable    

Oil  Field  

Semiconductor    

Foods  &  Pharma  

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AFLAS  Lab  –  Two  Roll  Mill  

•   Applica4on  and  formula4on  development  •   Press  •   Haake  Rheomix    mixing  bowl  and  torque  rheometer  

•   Includes  cam,  roller,  sigma  &  Banbury  rotors  

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AFLAS  Lab  –  Injec4on  Molding    

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AFLAS  Lab  -­‐  Tes4ng    

Aluminum  block  aging  ovens  (chemical  compa4bility  –  all  products)    

Rubber  Process  Analyzer  

Custom  Pressure  Vessel  

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AGC  Chemicals  Americas,  Inc.  

   For  More  Informa4on  

Go  to:    www.agcchem.com    

Or  call:    800-­‐424-­‐7833    

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AGC  Chemicals  Americas,  Inc.  

Intelligent  resins  Custom  compounds  Smart  chemistry  soluPons  

Rev  01  06/13