Advanced+Cleaning+Product+Formulations+Volume5[1]

ADVANCED CLEANING RODUCT FORMULATIONS

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ADVANCED

CLEANING

PRODUCT

FOR M U LATl ONS Volume 5

Ernest W. Flick

NOYES PUBLICATIONS WILLIAM ANDREW PUBLISHING, LLC

Nomich, New York, U.S.A.

Copyright 0 1999 by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without permission in writing from the Publisher.

Library of Congress Catalog Card Number: 89-30274

Printed in the United States ISBN: 0-8155-1431-X

Published in the United States of America by Noyes Publications/William Andrew Publishing, LLC 13 Faton Avenue, Norwich, New York 13815

10 9 8 7 6 5 4 3 2

Library of Congress Cataloging-in-Publication Data (Revised for vol. 5)

Flick, Ernest W. Advanced cleaning product formulations

Includes bibliographical references and index. 1. Cleaning compounds. I. Title

TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4) ISBN 0-8155-1431-X (v. 5)

To

the late Ernie and Jeanne

and

Allyn and Barbara

and

Chris and Rachel

V

reface

ohme 5) presents more than 423 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2, 3 and 4 published earlier.

~ ~ ~ ~ ~ a ~ ~ o ~ in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria.

The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):

H. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (9) 2. 3. Degreasers (9) 4. Dishwashing Detergents (34) 5. General Purpose Cleaners (31) 6. Glass CleanersPoiishes (12)

8. Laundry Products (55) 9. 10. Oven, Grill and Hot Plate Cleaners (9) 11. Polishes, Coatings and Finishes (6) 12. Rinse Aids (2) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (33) 14. Miscellaneous (33)

Dairy, Food and General Industrial Cleaners (27)

ard Surface Cleaners (21)

Metal Cleaners and Polishes (72)

vii

viii Preface

11. Transportation Cleaners and Polishes 15. 16. 17. Whitewall Tire Cleaners (3) 18. Miscellaneous (12)

Auto Cleaners and Polishes (6) Car and Truck Wash Compounds (49)

Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader.

111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description rand the supplier's name. The specifications which each raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials.

Each formulation in the book lists the following information, as available, in the manufacturer's own words:

Description of end use and most outstanding properties.

The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure.

Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.

The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company andlor the primary source's publication title, or both. A formula number is included, if applicable.

The table of contents is organized in such a way as to serve as a subject index.

My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials.

Newburyport, Massachusetts July 1999

Ernest W. Flick

NOTICE

To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determination of the suitability of any information or product for use contemplated by any user. We recommend that anyone intending to rely on any recommendation of materials QB

procedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards.

X

ntents and Subject Index

SECTION I

CLEANERS AND POLISHES OUSEHOLD AND INDUSTRIAL

B OM CLEANERS: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

athroom Cleaner with Disinfectant . . . . . . . . . . . . . . . . . . . . . . . 4 Heavy Duty Acid Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . 4 Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 ~ o w ~ ~ ~ l d e w Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Tile Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . . . 6 Tub and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover . . . 6 Toilet Bowl Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . 7

2. . FOOD AND GENERAL INDUSTRIAL CLEANERS . . . . . 8

Oxalic Acid Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 ust Removal Jelly . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

Acid Industrial and Household Cleaners

Cleaners for Industrial Application Desinfecting Cleaner. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Dipping Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

sphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 uced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 11

Zero phosphate. powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Baking Pan Cleaner

phosphate. powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Heavy Duty Cleaners

BBll Purpose-Food Process Plant . . . . . . . . . . . . . . . . . . . . . . 13 Hard Surface Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Destainer

xi

xii Contents and Subject Index

High Foaming Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 14 Heavy Duty Alkaline Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . 44 Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

Cleaner, Strongly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Cleaner. Weakly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Cleaner. Strongly Alkaline (Phosphate-Free) Cleaner. Weakly Alkaline (Phosphate-Free) . . . . . . . . . . . . . . 45

(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 17

Economy Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Premium Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Enzyme Prespotter for Oily/Smutty Soils . . . . . . . . . . . . . . . . IS

(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19


Industrial and High Pressure Cleaners

. . . . . . . . . . . . . 15

Metal Cleaner

Food Industry Cleaner

Milk Can Cleaner

Powdered Enzyme Presoaks

Sanitizing Cleaner

Sanitizing Agent

3 . DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 Aqueous Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

d-Limonene Microemulsion . . . . . . . . . . . . . . . . . . . . . . . . . 21 Water Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

Degreaser Concentrate (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . 22 Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . . 22 Solvent Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 Solvent Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . 24

Aqueous Degreaser

4 . DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . 25

(Zero Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 26

(Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 26

(Phosphate. Solid Block . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27

Automatic Dishwash Detergent-Consumer

Automatic Dishwash Detergent-Consumer

Automatic Dishwash Detergent-Industrial & Institutional

Automatic Dishwashing Detergent-Industrial & Institutional (Liquid~7

Contents and Subject Index xiii

Automatic Dishwash Detergent-Industrial & Institutional (Zero.Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 28

Automatic Dishwash Detergent-Industrial & Institutional (Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 28

Automatic Dishwashing Gel with Chlorine Bleach . . . . . . . . . . . . 29 Clear. Colorless Manual Dish Wash . . . . . . . . . . . . . . . . . . . . . . 30 Powder Stainless Silverware Pre-Soak . . . . . . . . . . . . . . . . . . . . 30 Low Alkaline Warewashing Block . . . . . . . . . . . . . . . . . . . . . . . 30 Dish Washing Agents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

sh w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . . . 33 Dish Wash w l h i n e Oxide/LABS/ALES . . . . . . . . . . . . . . . . . . 33 Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Foam Booster: E-14-5 in Hand Dishwashing Liquids

Economy Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Standard Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 90% Premium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Rernium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

Hand Dish Detergent Formulations Clear Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35

Pearlescent Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 Rand Dishwashing Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Light Duty Liquid. Premium Hand Dishwash . . . . . . . . . . . . . . . 38 Light Duty Liquid Low Cost Hand Dishwash . . . . . . . . . . . . . . . 38 Liquid Automatic Dishwasher Detergent . . . . . . . . . . . . . . . . . . . 39 Manual Dishwashing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 Manual Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Now-Chlorinated Machine Dishwashing Compound. Liquid . . . . . 42 Chlorinated Machine Dishwashing Compound. Powder . . . . . . . . 42 Non-Chlorinated Machine Dishwashing Compound. Powder . . . . 42 Premium Hand Dishwashing Detergent . . . . . . . . . . . . . . . . . . . . 43 Dish Washing Agents for Manual Use . . . . . . . . . . . . . . . . . . . . 43

5 . GEN LEANERS . . . . . . . . . . . . . . . . . . . . . . . 44 Abrasive Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . 45

rasive Cleaner Without Bleach . . . . . . . . . . . . . . . . . . . . . . . . 46 Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47

All Purpose Cleaner - No Rinse . . . . . . . . . . . . . . . . . . . . . . . . . 48 AB1-Purpose Disinfectant Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 49 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 &alp Purpose Cleaner w/Amide/€’hosphate Ester . . . . . . . . . . . . . . 50 A1 Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50

xiv Contents and Subject Index

All Purpose Cleaner Concentrate (Phosphate. Liquid. Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . 51

All Purpose Concentrate

Calcium Carbonate Abrasive Cleaner Without Bleach . . . . . . . . . 52 Citric Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53

(Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5%

General Purpose Cleaner

General Purpose Cleaner (Consumer Low Alkaline. Non-Phosphate Powder) . . . . . . . . 54

(Consumer High Alkaline. Non-Phosphated Powder) . . . . . . . 54 General Purpose Spray & Wipe Cleaner . . . . . . . . . . . . . . . . . . . 55 General Purpose Spray & Wipe . . . . . . . . . . . . . . . . . . . . . . . . . 56 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Hypochlorite Vertical Surface Cleaner . . . . . . . . . . . . . . . . . . . . 57 Pump Spray All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 57 Liquid Cleanser with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Disinfecting Cleaner. Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Sodium Bicarbonate Abrasive Cleaner Without Bleach . . . . . . . . 60

6 . GLASS CLEANERS/POLISHES . . . . . . . . . . . . . . . . . . . . . . . . . . 61 Anti.Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . . 62 Glass Cleaner. Ready to Use . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 Glass Cleaner Concentrate (Non-Ammoniated) . . . . . . . . . . . . . . 63 Glass Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Glass and Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . 65 Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Windows/Glass

Glass Cleaner (Concentrate) . . . . . . . . . . . . . . . . . . . . . . . . . 66 Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . 66 Windshield Washer Concentrate (Low VOC) . . . . . . . . . . . . . . . . 66

7 . HARD SURFACE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 58 Hard Surface Cleaner Concentrate (All Purpose Type) . . . . . . . . . 68 Concentrated Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . 69 Hard Surface Cleaner-Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 Pine Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70

Contents and Subject Index xv

Bard Surface Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . 71 Hard Surface Cleaner Concentrate w/d’Limonene . . . . . . . . . . . . . 71 Bard Surface Cleaner Concentrate (Phosphate. Liquid) . . . . . . . . . 72 Hard Surface Spray Cleaner (Phosphate. Liquid) . . . . . . . . . . . . . 72 Hard Surface Cleaner Concentrate wmipentene . . . . . . . . . . . . . . 73 Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Liquid Abrasive Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Tile and Sanitary Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Liquid Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Hard Surface Cleaner-All Purpose . . . . . . . . . . . . . . . . . . . . . . . 75

old and Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76

PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 gent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78

Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 Heavy Duty Laundry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 1 h 1 Liquid Laundry Detergent with Enzyme & Optical . . . . . . . 80

Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . . 80 . . . . . . . . . . . . . . . . . . . . 81

Industrial Laundry Detergents

Surfactant Rich Detergent for Nursing Homes . . . . . . . . . . . . . . . 80

dustrial Heavy Duty Laundry Liquid

High Caustic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 82

Laundry Detergent-Consumer (Liquid) . . . . . . . . . . . . . . . . . . . . 83

Mixed Builder Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Washing Paste with Bleaching Agent . . . . . . . . . . . . . . . . . . . . . 82

Laundry Detergent-Consumer



bundry Break-Industrial & Institutional

Laundry Break-Industrial & Institutional

Laundry Detergent-Industrial & Institutional




(Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 83

(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 84

phosphate. Powder) ............................... 84

(Liquid. Phosphate) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85

(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85

(NTAJZeolite. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86



(Sodium Carbonate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . 87

mi Contents and Subject Index






Laundry Detergant-Industrial & Institutional

Laundry Detergent-Industrial and Institutional

Laundry Detergent-Industrial and Institutional



Laundry Builder-Industrial & Institutional

Laundry Detergent-Industrial & Institutional . . . . . . . . . . . . . . . . . 93

Laundry Prespotter Sprayable Gel . . . . . . . . . . . . . . . . . . . . . . . . 94 Laundry Prespotter Sprayable Liquid . . . . . . . . . . . . . . . . . . . . . 95 Light Duty Liquid Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . 96

Calsoft LAS-99 Based . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 Dry Cleaner: Pre Spot-Water Soluble . . . . . . . . . . . . . . . . . . . . . 99 Wool Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Two Part Industrial Laundry Detergents

Break Formulations Highly Alkaline Break . . . . . . . . . . . . . 5100 Mixed Builder Break . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 Detergent Additive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100

Ultra Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . . . . . . . 101 Fine Fabric Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1641

phosphate. Powder. High Alkalinity)

(Zero Phosphate Powder. High Alkalinity . . . . . . . . . . . . . . . . 88

. . . . . . . . . . . . . . . . . . 88

(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 89

(NTA, Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89

(Sodium Carbonate with Flow Aid. Powder) . . . . . . . . . . . . . . 90

(Phosphate. Solid Block) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 964



(Phosphate Built. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . 92

(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92

(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93

(Zeolite Built. Zero Phosphate. Liquid)

9 . METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 802 Acid Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . p03

Dipping Cleaner for Silver . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103 Aluminum CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . 104 Powdered Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . 104 Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1104

Contents and Subject Index xvii

Aluminum Cleaner Concentrate F-498 . . . . . . . . . . . . . . . . . . . 105 Aluminum Wash F-499 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105

ffing Compound Remover . . . . . . . . . . . . . . . . . . . . . . . . . . 106 t Alkaline Paint Stripper Concentrate . . . . . . . . . . . . . . . . . . 106

Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . 106 Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 Semi-synthetic Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 General Purpose Machine Cleaner . . . . . . . . . . . . . . . . . . . . . . 110 Aircraft Cleaner Type IV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110 General Purpose Synthetic Fluid (A) . . . . . . . . . . . . . . . . . . . . . 111 General Purpose Synthetic Fluid (€3) . . . . . . . . . . . . . . . . . . . . . 111 Copper Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 General Purpose Synthetic Fluid (C) . . . . . . . . . . . . . . . . . . . . . 112 General Purpose Synthetic Fluid @) . . . . . . . . . . . . . . . . . . . . . 112 Metal Cleaner

(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113 Aluminum Cleaner

phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113

phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 115

Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 116 Alkaline Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 Semi Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 Silver and Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 Soluble Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 Soluble Oil Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . 122 Synthetic Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123 Synthetic DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . 124 Oil Based DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . 124 Spray Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . . . . 124 Synthetic Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 Synthetic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Universal Scouring Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Water Soluble Stamping Fluid . . . . . . . . . . . . . . . . . . . . . . . . . 134

-40 Type Lubricant Concentrate . . . . . . . . . . . . . . . . . . . . 134 Penetrating Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134 Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134

eta1 Cleaner

xviii Contents and Subject Index

10 . OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . 135 Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136 Non-Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . B36 High Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 137 Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 Aerosol Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139 Heavy Duty Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139 Oven Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . 140 Oven Cleaner wphosphate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140

11 . POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . 141 Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142 LeatherPlastic Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Marble Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Rust Removing Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Scratched Wood Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . . 145

12 . RINSE AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.46 Rinse Aid. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147

13 . RUG. FLOOR, CARPET. UPHOLSTERY SHAMPOOS AND CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . n48

Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Low Foam Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Steam Rug Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Steam Rug Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Carpet Cleaners for the Spray-Extraction Process . . . . . . . . . . . 150 Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150

(Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1151 Rug Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151 Carpet Shampoo. High Foam . . . . . . . . . . . . . . . . . . . . . . . . . . 152 Carpet Spot Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1152 Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 153 Vinyl Dressing (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 154 Liquid Steam Carpet Cleaner For Hard Water Systems . . . . . . . 154 Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Liquid Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Heavy-Duty Floor Scrubber . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Household Carpet Freshenedhtistat . . . . . . . . . . . . . . . . . . . . 156

Contents and Subject Index xix

Pump Spray Carpet Antistat . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Leather. Vinyl. and Plastic Cleaner and Restorer . . . . . . . Liquid Leather. Vinyl. and Plastic Cleaner . . . . . . . . . . . . . . . . 157 Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . . .

156 157

158 Premium. Medium Duty Steam Extraction Carpet Cleaner . . . . . 158

uty Steam Extraction Carpet Cleaner . . . . . . . . . . . . . . 158 aming Carpet Extractor Detergent . . . . . . . . . . . . . . . . . 159

No Rinse Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 Heavy Duty Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 No-Rinse Floor Cleaner Degreaser ...................... 160 Wax Stripper (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161

ax Stripper (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161 Concentrated Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . 161

m Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 159

CEELANEQUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162 acteriostatic Concentrate w/Pine Oil . . . . . . . . . . . . . . . . . . . . 163

General Disinfectant Solution . . . . . . . . . . . . . . . . . . . . . . . . . . 163 Hospital Disinfectant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163 Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 Concrete Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 White Wall Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 d ' lhonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . 165 Paste Nand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Dipentene Microemulsion Formulations

-alkaline Formulations . . . . . . . . . . . . . . . . . . . . . . . . . 166 line Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167

Emsol D-110 Formulations . . . . . . . . . . . . . . . . . . . . . . . . 168 Isopar M Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169

h w Viscosity Silicone Emulsion Using Pemulen Resins . . . . . . 170 Luminizing Pet conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . 171 Pea Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171

iao-Emulsions with d-Limonene . . . . . . . . . . . . . . . . . . . . . 172 Micro-Emulsions with Pine Oil . . . . . . . . . . . . . . . . . . . . . . . . 173 Plastic Bottle Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 Bottle Wash Formulations

w Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 oderate Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174

Concentrated Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 176

Hydrocarbon Solvent Microemulsions

Terpene Microemulsions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175

Wax Emulsion Using Pemulen Resins . . . . . . . . . . . . . . . . . . . .

xx Contents and Subject Index

SECTION 11 TRANSPORATION CLEANERSl

AND POLISHES

15 . AUTO CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . . 11’9’8 Chrome Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 Liquid Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180 Liquid Spray Cleaner for Aluminum Trucks . . . . . . . . . . . . . . . 181 Aluminum Cleanermrightener . . . . . . . . . . . . . . . . . . . . . . . . . 181 Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 1181 Mild Abrasive Automobile Polish . . . . . . . . . . . . . . . . . . . . . . . 182

16 . CAR AND TRUCK WASH COMPOUN S . . . . . . . . . . . . . . . . %83

Automobile Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . 184 Car Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184

Car Wash (Calsoft LAS-99-Based) . . . . . . . . . . . . . . . . . . . . . 185 Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 185 Car Wash (Calsoft T-60-Based) . . . . . . . . . . . . . . . . . . . . . . . 185

Paste Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186 Car Wash w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 187 Windshield Washer Formulation . . . . . . . . . . . . . . . . . . . . . . . . 187 Car Wash Concentrate w/Alcohol Ethoxylate . . . . . . . . . . . . . . 133 Car and Truck Wash Formula . . . . . . . . . . . . . . . . . . . . . . . . . 189 Car Wash powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189 Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 189

Car Shampoo with Water-Repellent Effect . . . . . . . . . . . . . 190 Rinse-off Agent (Water Repellent) . . . . . . . . . . . . . . . . . . . 190

Windshield-Cleaner (Summer) . . . . . . . . . . . . . . . . . . . . . . 190 Windshield-Cleaner (Winter) . . . . . . . . . . . . . . . . . . . . . . . 19B Insect Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 Wheel Cleaner, Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 Tar Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191

Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Auto Wipe & Shine Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Concentrated Traffic Film Removers . . . . . . . . . . . . . . . . . . . . 193 Foamy Brush Car Wash, Liquid . . . . . . . . . . . . . . . . . . . . . . . . 194 Low Cost Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194 General Purpose Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 Liquid Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195

CarWash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186

Car Wash and Care

Rinse-off Agent (Water-Repellent) Without Hydrocarbons . ~ 190

Contents and Subject Index xxi

Boat Wash & Car Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 Heavy Duty Truck Wash. Liquid . . . . . . . . . . . . . . . . . . . . . . . 196 Heavy Duty Truck Wash. Powder . . . . . . . . . . . . . . . . . . . . . . . 196 Premium Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 197 Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Auto Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Touchless Vehicle Wash Detergent

(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 198 Vehicle Wash Detergent (Low pH)

(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 198 Tmck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Economy Tnuck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Car Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Car Wash and Wax Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . .

(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 (Liquid. low foam) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200

(Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 201

(Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 201

199 Vehicle Wash Detergent

Vehicle Wash Detergent (Low pH)

Touchless Vehicle Wash Booster/Additive

ITEWALL TIRE CLEANERS . . . . . . . . . . . . . . . . . . . . . . 202

(Zero Phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 203 phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203 (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203

Mitewall Tire Cleaner

n SCEEUNEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204

(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . 205 (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205

Auto Care: Hnterior/Exterior Rubber & Vinyl Protectant

Concrete CIeanerDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Garage Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Acid Rust Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 ConcreteDriveway Cleaners

For Other Stains . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209 Heavy Duty Concrete Cleaner (Phosphate Free) Formula 1C . . . 209 Vinyl Dressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210

ressing (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210

Aircraft Cleaner

. . . . . . . 206 Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207

xxii Contents and Subject Index

SECTION III: TRADEMARKED RAW MATE s . . . . . . . . . . . 2nn

SECTION IV: SUPPLIERS' ADDRESSES . . . . . . . . a . . . . . . ~ . . . ~ 229

ection I Household and Industrial

Cleaners and Polishes

1

1. Bathroom Cleaner

a

Bathroom Cleaners 3

A c i d i c Toilet Bowl Cleaner

Carbopol r e s i n s a r e used t o t h i c k e n t h i s a c i d i c t o i l e t bowl c leaner f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p rov ides v e r t i c a l c l i n g t o inc rease t h e con tac t t i m e o f t h e de tergent on t h e s o i l e d su r face and enhance consumer convenience.

I n s r e d i e n t : DI Water Carbopol 674 ( 1 ) C i t r i c Ac id (50%) A l k y l benzene s u l f o n i c a c i d Sodi um dodecyl d i pheny lox i de

Brookf i e l d v i scos i t y (RVT Product pH: 1 .O-2.0 Product C l a r i t y : C lear

( 1 ) BFGoodrich

5 43.00

2 . 0 0 50.00

97%) ( 2 ) 2.00 d i s u l f ona te (45%) ( 3 ) 3.00

20 rpm): 4,000 cps

i2j Stepan Co.: B i o s o f t 5-100 ( 3 ) Dow Chemical Co.: Dowfax 2A1

Procedure: 1 . Mix t h e D I water and c i t r i c a c i d s o l u t i o n toge the r . 2. Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '

M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e w a t e r / c i t r i c a c i d sol- u t i o n . Mix t h e s l u r r y f o r approx imate ly 30 minutes. The produc t w i l l become i n c r e a s i n g l y t h i c k e r w i t h t i m e - hea t ing t o 40-50C w i l l hasten t h e process.

s u r f a c t a n t .

room temperature.

3 . Add t h e s u l f o n i c a c i d and t h e d ipheny lox ide d i s u l f o n a t e

4 . Add c o l o r and f ragrance, as des i red . Cool t h e produc t t o

To ta l Ac t i ves : C i t r i c a c i d : 25.00 A l k y l benzene s u l f o n i c ac id : 1.94 Dodecyl d ipheny lox ide d i s u l f o n a t e : 1.35

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-351

4 Advanced Cleaning Product Formulatioris

Bathroom Cleaner with Disinfectant

Inqredi ents: A: Veegum T, Magnesium Aluminum Silicate

Rhodopol 23, Xanthan Gum Deionized Water

B: Diatomaceous Earth (Super Floss) Tetrasodium EDTA (Hampene 100) Sodium o-Phenylphenate (Dowicide A) Sodi um A1 kyl benzene Sul fonate (Cal soft L-40) Butyl Cellosolve

Wt .%* 1 .oo 0.35 86.65

5.00 2.75 0.25 3.00 1 .oo

Procedure: 1 . Dry blend the Veegum T and Rhodopol 23 and add them to the

water while stirring with an homogenizer at 5000 rpm. Continue mixing for 30 minutes.

each for 5 minutes. * A s received basis

2. Slowly add the Part 8 ingredients in the order shown, mixing

SOURCE: R.T. Vanderbilt Co., Inc.: Formulation No. 363

Heavy Duty Acid Bathroom Cleaner

Inqredi ents: Hydroxyacetic acid Sulfamic acid Ammonyx LO Water, D.I.

Wt% 5.0 5.0 10.0 80.0

Mixing Procedure:

homogeneous.

Properties:

Add ingredients to water in the order given and mix until

Appearance: Clear liquid pH, as is: 1.0 Solids, %: 1 4 . 0 Density, lbs/gal: 8.7

Use Instructions:

or polished aluminum. Use gloves. Do not mix with bleach.

Storage Stability:

Use as is o r dilute as needed. Do not use on natural marble

Formulation is freeze/thaw stable through 3 cycles. Formulation is stable for 3 weeks @ 50C.

SOURCE: Stepan Co.: Formulation No. 200

Bathroom Cleaners 5

M i 1 dew Remover

I n g r e d i e n t s : Van Gel 0 D e i o n i z e d Water Sodium Hydrox ide , 50% S o l u t i o n Sodium H y p o c h l o r i t e , 10% S o l u t i o n (Hypure N ) Vanseal NALS-30

Wt%* 3 .00

85 .55 0 . 4 5

10 .00 1 . o o

P rocedure : 4 . S l o w l y s p r i n k l e t h e Van Gel 0 i n t o w a t e r a t room t e m p e r a t u r e

w h i l e m i x i n g w i t h a homogenizer o r d i s p e n s e r o p e r a t i n g a t 5000 rpm. C o n t i n u e m i x i n g f o r 40 m i n u t e s .

Slow t h e m i x e r t o 1000 rpm o r l e s s .

u n i f o r m .

2 . Add sodium h y d r o x i d e and m ix u n t i l u n i f o r m l y d i s s o l v e d .

3 . Add t h e Vanseal NALS-30. A v o i d a i r en t rapmen t . M ix u n t i l

F o r m u l a t i o n No. 458

Bowl /Mi 1 dew C1 eaner

I n g r e d i e n t s : A : Veegum T , Magnesium Aluminum S i l i c a t e

Te t rasod ium Pyrophosphate (TSPP) Water

8 : Sodium H y p o c h l o r i t e , 5 .25% Sodium M e t a s i l i c a t e , Anhydrous

5 . 0 0 0 . 2 5

50 .75

34.00 10 .00

P rocedure : 1 . D ry b l e n d t h e Veegum T and TSPP. S l o w l y add t h e w a t e r w h i l e

2 . Add P a r t B i n g r e d i e n t s s l o w l y i n t h e o r d e r shown, m i x i n g


a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e u n t i l smooth.

a f t e r each a d d i t i o n u n t i l smooth and u n i f o r m .

*As r e c e i v e d b a s i s

SOURCE: R.T. V a n d e r b i l t Co. , I n c . : Suggested F o r m u l a t i o n s

6 Advanced Cleaning Product Formulations

T i l e , P o r c e l a i n and Bathroom C leaner , A c i d

I n g r e d i e n t s : Water , D . I . 75 .5 Xanthan Gum 0 . 5 P e t r o BAF Powder 2 . 0 Phosphor i c Ac id , 75% 1 2 . 0 H y d r o x y a c e t i c A c i d , 70% 1 0 . 0 Perfume, Dye q .s . B l e n d i n g Procedure:

t o m ix u n t i l m a t e r i a l t h i c k e n s . Add r e m a i n i n g i n g r e d i e n t s i n o r d e r l i s t e d . I f p rob lems deve lop a d d i n g Xanthan Gum t o w a t e r , p remix t h e Xanthan Gum i n some i s o p r o p a n o l b e f o r e a d d i n g t o w a t e r .

Add Xanthan Gum s l o w l y t o w a t e r w i t h h i g h speed m i x i n g . A l l o w

Formula 529

Tub and T i l e C leaner

I n g r e d i e n t : Water , D . I . 6 7 . 4 Phosphor i c A c i d , 86% 17.6 H y d r o c h l o r i c A c i d , 37% 1 3 . 5 Rewote r i c AM TEG 0 . 5 V a r o n i c T202 SR 1 . o B l e n d i n g P rocedure :

each a d d i t i o n . T y p i c a l P r o p e r t i es:

V i s c o s i t y , cps : 293 S o l i d s : 16.3% pH: 1 . 7

Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between

Formula 530

H y p o c h l o r i t e Tub and T i l e C leaner and M i l * S t a i n R e m o z

I n g r e d i e n t s : Water, D . I . 4 4 . 9 Sodium H y d r o x i d e (30%) 1 . o Varox 365 1 . 5 Sodi urn H y p o c h l o r i t e (5 .7%) 5 2 . 6 B l e n d i n g P rocedure :

each add i t i on. T y p i c a l P r o p e r t i e s :

V i s c o s i t y , c p s : 4 S o l i d s : 3.8% pH: 13 .5

Formula 531

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s


Bathroom Cleaners 7

T o i l e t Bowl C leaner w i t h B l e a c h

Carbopol r e s i n s a r e used t o t h i c k e n t h i s t o i l e t bowl w i t h c h l o r i n e b l e a c h f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s v e r t i c a l c l i n g t o i n c r e a s e d e t e r g e n t on t h e s o i l e d s u r f a c e and

t h e c o n t a c t t i m e o f t h e enhance consumer convenience.

I nq r e d i-w D I Water Carbopol 676 ( 1 ) P o t a s s i um h y d r o x i d e (45%) 2 . l r Potass ium s i l i c a t e (39%) ( 2 ) Potass ium c a r b o n a t e Sodium h y p o c h l o r i t e (12.50%) Amine Oxide (30%) ( 3 )

B r o o k f i e l d v i s c o s i t y (RVT-20rpm) : 2,500 cps P roduc t pH: 12-13 P roduc t c l a r i t y : Opaque

( 1 ) BFGoodri ch ( 2 ) PQ Corp. ( 3 ) Lonza, I n c . : B a r l o x 12

P rocedure :

W t % 60.75

1 . 2 5 5 . 0 0 5 . 0 0 5 . 0 0 8 . 0 0

10 .00

1 .

2 .

3 .

4 . 5 .

U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r sc reen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M ix t h e s l u r r y f o r a p p r o x i m a t e l y 15 m inu tes o r u n t i l t h e s l u r r y i s homogeneous. W i t h c o n s t a n t a g i t a t i o n , add t h e p o t a s s i u m h y d r o x i d e and t h e po tass ium s i l i c a t e . M ix u n t i l homogeneous. C o n t i n u e a g i t a t i o n and add t h e po tass ium c a r b o n a t e f o l l o w e d by t h e b l e a c h . Add t h e amine o x i d e s u r f a c t a n t and m ix u n t i l homogeneous. Add c o l o r and f r a g r a n c e , as d e s i r e d .

T o t a l A c t i v e s : S i l i c a t e ( a s S i 0 2 ) : 1 . 3 2 Carbonate (as Na2C03): 3 .84 A v a i l a b l e C h l o r i n e : 1 . O O Amine Ox ide : 3 . 0 0

SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-350

2. Dairy, Food and General Industrial Cleaner

8

Daiq , Food and General Industrial Cleaners 9

A c i d I n d u s t r i a l and Household Cleaners O x a l i c Ac id Gel

I n q r e d i e n t s : W t .%* Water 53.70 Van Gel B 2.50 Rhodopol 2 3 0.80 Oxa l i c Ac id D ihydra te , 12.59n Aqueous S o l u t i o n 40 .00 Po lysorbate 40 (Tween 40) 3 . 0 0

Procedure: 1 . Dry b lend t h e Van Gel €3 and Rhodopol 2 3 and add them t o t h e

water w h i l e m ix ing w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm. Cont inue mix ing f o r 60 minutes.

s low ly add the o x a l i c a c i d s o l u t i o n .

and mix u n t i l un i fo rm.

2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t vo r tex and

3 . When a l l t h e a c i d has been added, add the Po lysorbate 40

Formula t ion No. 466

Rust Removal J e l IY

I n s r e d i en ts : Water Van Gel B Rhodopol 2 3 Phosphoric Aci d, 50% Aqueous Sol u t i on Octoxynol-9

WtD/ou 5 3 . 2 0

3 . 0 0 0 . 8 0

40 00 3 00

Procedure: 1 . Dry b lend the Van Gel 0 and Rhodopol 2 3 and add them t o

water w h i l e mix ing w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm. Cont inue mix ing f o r 60 minutes.

s low ly add t h e Phosphoric Ac id s o l u t i o n .

and mix u n t i l un i fo rm.

*As rece ived bas i s

2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t vo r tex and

3 . A f t e r a l l t he a c i d has been added, add t h e Octoxynol-9

Formula t ion No. 467

SOURCE: R . T . Vanderb i l t Co., I n c . : Suggested Formulat ions

he


C l e a n e r s f o r I n d u s t r i a l A p p l i c a t i o n

D e s i n f e c t i n q C leaner , A c i d

I n s ed i en t s : w a t e r Phosphor i c a c i d (85Oh) S u l p h u r i c a c i d (98%) P r o p e t a l 241 Dodigen 226

Formula CT 06-06-01

D i ppi n q C1 eaner

I n r e d i e-n-t-sL itatger T e t r a p o t a s s i u m py rophospha te C a u s t i c soda D i p r o p y l e n e g l y c o l monomethyl e t h e r S u l f e t a l 4069 Zusol a t 1008/85

Formula CT 07-03-01

Spray C 1 eaner

I n s r e d i e n t s : Water Cublen D50 T r i e t h a n o l ami ne S u l f e t a l 4105 P r o p e t a l 241 Z u s o l a t l005/85 P h o s f e t a l 201 B u t y l g l y c o l C i t r u s t e r p e n e I n h i b i t o r 4000

Formula CT 07-06-01

I n g r e d i e n t s w a t e r Sul f e t a l 4105 P r o p e t a l 99 Z u s o l a t 1005/85 B u t y l g l y c o l Orange t e r p e n e

Formula CT 07-06-03

wts/, 4 8 . 0 2 4 . 0

5 . 0 3 . 0

2 0 . 0

Wt% 7 5 . 5 1 0 . 0

1 . 5 5 . 0 5 . 0 3 . 0

Q 5 8 . 0

3 . 0 3 . 0 4 . 0 2 . 0 0 . 5 2 . 0 5 . 0 0 . 5

2 2 . 0

8 6 . 0 6 . 0 3 . 0 0 . 5 4 . 0 0 . 5

SOURCE: Zschimmer & Schwarz GmbH 8, Co. : Genera l F o r m u l a t i o n s

Dairy, Food and General Industrial Cleaners I1

D e s t a i n e r (Phosphate, Powder)

S o i l - O r g a n i c s t a i n s : f ood , mold and g rass Surface-Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Method-Brush Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

Compos i t to^ *STPP Metso Beads 2048 Sodium S u l f a t e PQ Epsom S a l t * *Oc ty lphenoxy P o l y e t h o x y e t h a n o l , 9- Sodium P e r b o r a t e , Monohydrate

Use D i l u t i o n : 2 .3 -4 .5% bw (3-6 oz/ga

* FMC ** Rhone Poulenc I g e p a l CA-630

0 Moles EO

i o n )

D e s t a i n e r (Reduced Phosphate, Powder)

S o i l - O r g a n i c s t a i n s : f ood , mold and g r a s s Surface-Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Methods-Brush Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

Composi t i on: *STPP Metso Beads 2048 Sodi um S u l f a t e PQ Epsom S a l t **Octy lphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO V a l f o r 100 Z e o l i t e A Sodium P e r b o r a t e , Monohydrate

Use L e v e l : 3-6 o z / g a l l o n

* FMC ** Rhone-Poulenc I g e p a l CA-630

SOURCE: PQ Corp.: D e t e r g e n t F o r m u l a t i o n Guide

Wt% 25.0 2 5 . 0

8 . 0 2 .0 2 . 0 38.0

&% 10 .0 2 5 . 0

8 .0 2 . 0 2 . 0

1 5 . 0 3 8 . 0


Eaa Cleaner L x o phosphatS?,.powder)

Soi 1 - P r o t e i n Sur face-Egg and egg h a n d l i n g equipment A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manu fac tu re -Dry b l e n d

Composi t i on : Sodium Carbonate Metso Beads 2048 Sodium S u l f a t e V a l f o r 100 Z e o l i t e A *Sodi urn D i c h l o r o i socyanura te 2H20 **Sodi um A1 k y l a r y l S u l f o n a t e Powder (90%)

Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 o z / g a l l o n )

* O l i n Chemical * * W i t c o

Bgki-ng Pan C l e a n e r (Phosphate,- Powder)

S o i l - A n i m a l f a t and grease, v e g e t a b l e o i l Sur face-A1 umi num and s t e e l A p p l i c a t i o n Method-Irnmersion/brush Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

C O ~ ~ S l t 1 on : *Sodium Carbonate *STPP **Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles €0 Metso Pentabead 2 0

Use D i l u t i o n . 1 .5% bw ( 2 o z / g a l l o n )

* FMC ** Rhone-Poulenc I g e p a l CO-630

SOURCE: PQ C o r p . . D e t e r g e n t F o r m u l a t i o n Guide

W t % 3 0 . 0 20 .0 1 2 . 0 3 0 . 0

3 . 0 5 . 0

W t % 3 5 . 0 1 2 . 0 3 . 0

5 0 . 0

Dairy, Food and General Industrial Cleaners 13

Heavv D u t v C l e a n e r s A l l Purpose-Food Process P l a n t

I n g r e d i e n t s : Water EDTA ( E t h y l e n e d i a m i n e t e t r a c e t i c A c i d ) TKPP ( T e t r a Potass ium Pyrophosphate) P i l o t SXS-40 KOH, 45% Calamide C

Weight% 74.00

2.00 4 .00 5 .00

10.00 5 . 0 0

Comments abou t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n o r d e r l i s t e d . 2 . Water and EDTA g i v e a m i l k y w h i t e s o l u t i o n . 3 . Upon a d d i n g t h e o t h e r i n g r e d i e n t s t h e s o l u t i o n i s c l e a r . 4. EDTA can be s u b s t i t u t e d w i t h Na4EDTA t o make a c l e a r f i n a l

5 . T h i s i s a heavy d u t y c l e a n e r f o r f o o d p r o c e s s i n g p l a n t s . 6 . Use l e v e l . 2-4 o z p e r g a l l o n .

s o l u t i o n .

F o r m u l a t i o n HDC-004-01

Hard S u r f a c e Spray C leaner

- I n q r e d i e n t s : Water TKPP ( T e t r a Potass ium Pyrophosphate) E t h y l e n e G l y c o l Monobuty l E t h e r Calsuds 81 NH40H, 28%

Weight% 89.00

1 .oo 3 . 0 0 4 .00 3 . 0 0

Comments abou t t h i s f o r m u l a : 1 . I n g r e d i e n t Water and TKPP when mixed a r e c l e a r . 2 . Hazy s o l u t i o n when E t h y l e n e G l y c o l Monobuty l E t h e r i s added. 3 . W i t h t h e a d d i t i o n o f Calsuds 81 t h e s o l u t i o n t u r n s c l e a r and

4 . When iUH40H i s added, t h e pH i n c r e a s e s t o 12 . has a pH o f 9.

F o r m u l a t i o n HDC-002-01

SOURCE: P i 1 o t Chemical Co. : Suggested Formul a t i ons


H i qh Foaming A1 k a l i ne Cleaner

Monater ic EH c o n t r i b u t e s t o detergency and e f f e c t i v e l y con- t r o l s bo th t h e k r a f f t and c loud p o i n t i n t h i s h igh foaming fo rmu la t i on .

Water 76.0 I n n r e d i e n t s : Wt9/o

Sodium Hydroxide (50%) 10 .0 Sodium M e t a s i l i c a t e (Pentahydrate) 2 . 0 Dodecyl benzenesul f o n i c a c i d 2 . 0 Monater ic EH 8 . 0 Nonoxynol -1 0 2 . 0 Procedure:

Recommened Use D i l u t i o n : 1 : 2 0 w i t h water Formula t ion F-768

Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Package.

Heavy Duty A l k a l i n e Degreaser

Monater ic EH a i d s i n the removal o f o i l y s o i l s w i thou t emul- s i f i c a t i o n . I t e a s i l y d i sp laces o i l y s o i l s f rom hard sur faces and keeps them from redepos i t i ng . I n g r e d i e n t s : Wt% Water 65.0 Sodi u m Hydroxi de (50%) 2 0 . 0 Sodium M e t a s i l i c a t e (Pentahydrate) 3 . 0 Monater ic EH 1 0 . 0 Nonoxynol -1 0 2 . 0 Procedure:

Recommended Use D i l u t i o n : 1 :20 w i t h water . Formula t ion F-769

Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Package.

Steam C1 eaner

Mona NF-20 c o n t r i b u t e s the non-foaming and detergency proper - t i e s i n t h i s fo rmu la t i on .

Water 65.00 Potassi um Hydroxide 3 . 0 0

I n a r e d i en ts : WtO/o

Sodium M e t a s i l i c a t e (Anhydrous) 1 0 . 0 0 Te t rapotass i um Pyrophosphate 10 .00 Mona NF-20 1 2 . 0 0 Procedure:

Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . T y p i c a l P r o p e r t i e s :

Cloud P o i n t : 75C K r a f f t P o i n t : t O C

Recommended Use D i l u t i o n : 4-6 oz . /ga l . Formula t ion F-762

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ions


I n q r e d i e n t s : Water Cublen D 50 T e t r a p o t a s s i u m py rophospha te C a u s t i c soda Sodi um metas i 1 i c a t e S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 B u t y l g l y c o l

Formula CT 06-13-01

I n d u s t r i a l and Hiqh Pressure Cleaners - C1 eaner. Strong1 y A1 Kal i ne

yw% 76.5

1 . o 4 .0 0 . 6 4 . 9 4 . 0 2 .0 2 . 0 5 . 0

C1 eaner, Weakly A1 k a l i ne I n g r e d i e n t s : Water Cublen D 50 T e t r a p o t a s s i u m py rophospha te T r i e t h a n o l ami ne S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 B u t y l g l y c o l

Formula CT 06-13-02

Cleaner, Stronqly A1 ka l i n e (Phosphate-Free) I n g r e d i e c Water Cublen D50 Sodi um metas i 1 i c a t e C a u s t i c soda S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 B u t y l g l y c o l

Formula CT 06-13-03

@1 eaner, Weak1 y A1 k a l i ne ( Phosphate-Free1 I n g r e d i e n t s : Water Cublen D 50 T r i sod i um c i t r a t e S u l f e t a l 4105 Zusol a t 1008/85 P h o s f e t a l 201 B u t y l g l y c o l T r i e t h a n o l ami ne

Formula CT 06-13-04

Wt% 8 0 . 4

1 . o 2 . 0 3 . 6 4 .0 2 .0 2 . 0 5 . 0

Wt% 8 0 . 5

1 . o 4 .9 0 . 6 4 .0 2 .0 2 . 0 5 .0

Wt% 80 .4

1 . o 2 . 0 4 . 0 2 .0 2 . 0 5 . 0 3 . 6

SOURCE: Zschimmer & Schwarz GmbH & Co. : Genera l F o r m u l a t i o n s


M e t a l C l e a n e r (m S o i l - P e t r o l e u m and animal o i l and g rease S u r f a c e - M e t a l : S t e e l Appl i c a t i on Method-Immersi on Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Composi ti on : Water S t a r Sodi um S i 1 i c a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO)

Use D i l u t i o n : 2%-5% b v

* Rhone-Poulenc Rhodafac RE-610 ** Rhone-Poulenc Rhodasur f 91-6

w.t% 65 .6 1 5 . 6 6 . 3 5 . 0 7 . 5

Food Indus try C l e a n e r (W

Soi l -Heavy f o o d grease, o i l and p r o t e i n Sur face -Meta l , ce ramic , p o l y m e r i c , g l a s s A p p l i c a t i o n Method-Wipe, mop o r b r u s h Manu fac tu re -M ix t a n k w i t h p r o o e l l e r s t i r r e r

Compos i t i on : Wt% Water 74 .0 TKPP (60%) 3 .0 N C l e a r Sodium S i l i c a t e 7 . 0

*Phosphate E s t e r 2 .5 * * E t h y l e n e G l y c o l n - B u t y l E t h e r 5 . 0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 6 . 5 Moles € 0 ) 5 . 0

Use D i l u t i o n : 6-12% bw (8-16 o z / g a l l o n )

* Rhone-Poulenc Rhodafac RE-600 ** Dow Chemical , Union Carb ide *** Rhone-Poulenc Rhodasur f LA-7

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide

Sodi um H y d r o x i d e (50%) 3 . 5


M i l k Can C l e a n e r (Phosphat_e, Powder)

Sol 1 -Fa t and p r o t e i n Sur face -Meta l A p p l i c a t i o n Method-Wipe o r b r u s h Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

Compo_sit ion’ *STPP Metso Beads 2048 *Sod1 u m Carbonate +*Sod1 um D i c h l o r o i socyanura te , 2H20 ***Sodium A1 k y l a r y l S u l f o n a t e Powder, (90%)

Use D i l u t i o n 0 . 7 5 - 1 5% bw (1-2 o z / g a l l o n )

* FMC ** O l i n Chemical * ** w 1 t c o

M i l k Can CLea-ner (Zeco Phosphate, Powder)

S o l 1 - F a t and p r o t e i n S u r f ace-Meta l A p p l i c a t i o n Method-Wipe o r b r u s h Manu fac tu re -Dry b l e n d

Composi t i on : Val f o r 100 Z e o l i t e A Metso Pentabead 20 Sodium Carbonate *Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 **Sod1 um A1 k y l a r y l Sul f o n a t e Powder, (90%)

Use Leve l : 1 - 2 o z / g a l l o n

* O l i n Chemical ** Stepan, W i t co


WX/, 3 0 . 0 3 0 . 0 35.0 3.0 2.0

W t % 20.0 40.0 3 5 . 0

3 . 0 2 . 0


Powdered Enzyme Presoaks Economy Presoak

Component: Soda Ash Sodium Metasilicate Pentahydrate Sodium Dodecylbenzenesulfonate Powder Burcosperse AP Powder Burcotase EP-60

Premi um Presoak

Component: Soda Ash STPP Neodol 25.7 Sodium Metasi 1 icate Pentahydrate Sodium Dodecylbenzenesulfonate Powder Burcosperse AP Powder Burcotase EP-60

Wt% 8 0 . 0 1 0 . 0

5 . 0 3 . 0 2 . 0

5

35. n 4 0 . 0

5 . 0 1 0 . 0

5 . 0 3 . 0 2 . 0

The recommended use concentration o f these products i s 1 - 4 g/1 in the presoak bath. For optimum results, the presoak temperature should be 130-15OF.

Enzyme Prespotter f o r Oilv/Smuttv Soils

Component: Water Propyl ene G1 ycol Dodecyl benzenesul foni c Acid

Burco TME Nonionic Surfactant* Burcotase LL-100

TEA-85

wtD/, 4 9 . 0 1 0 . 0 1 0 . 0 2 0 . 0

5 . 0 5 . 0 1 . o

*An HLB of 9 . 5 - 1 0 . 0 i s preferred. Alcohol ethoxylates are preferred.

Add components in the order listed. Blend until uniform between each addition. Cool before adding the enzyme.

SOURCE: Burlington Chemical Go., Inc. : Suggested Formulations


S a n i t i z i n s C leaner (Phosphate, Powder)

S o i l - H o s p i t a l s o i l : sebum, b lood , u r i n e , e t c . Su r face -Meta l , ce ramic , p o l y m e r i c A p p l i c a t i o n Method-Wipe o r b r u s h Manu fac tu re -Dry B lend

Composi t 1 1 0 ~

Metso Beads 2048 *Sodium Carbonate *STPP **Sodi urn D i c h l o r o i socyanura te , 2H20 ***Sod; um A1 k y l a r y l Sul f o n a t e Powder (99%)

Use D i l u t i o n : 0 .75-1.5% bw (1-2 o z / g a l l o n )

* FMC ** 01 i n Chemical *** w i t c o

Wt% 2 0 . 0 35 .0 30.0 10 .0

5 .0

Sani t i z i na Aaen t (Phosphate, Powder)_

S o i l - H o s p i t a l s o i l : sebum, b lood , u r i n e , e t c . Su r face -Meta l , ce ramic , p o l y m e r i c A p p l i c a t i o n Method-Wipe, b r u s h Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

Composi t i on : Wt% *STPP 30 .0 *Sodi um Carbonate 2 5 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl6; 12 Moles EO) 1 0 . 0 Metso Pentabead 20 30 .0 Qua te rna ry Germ ic ide 5 .0


* FMC ** Rhone-Poulenc Rhodasur f LA-12

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a r y Guide

3. Degreaser

20

Degreasers 21

Aqueous Desreaser

I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 P i l o t SXS-40 Cal o x y l a t e N-9 TKPP ( T e t r a Po tass ium Pyrophosphate) Sodium Metas i 1 i c a t e E t h y l e n e G l y c o l Monobuty l E t h e r

Comments abou t t h i s f o r m u l a : D i s s o l v e t h e s a l t s i n t h e wa te r f i r s t . F o r m u l a t i o n DEG-001-01

Aqueous Deqreaser d -L i monene M i croemul s i o n

I n g r e d i e n t s : d - L i monene Calsuds CD-6 Cal i mu1 se PRS D i e t h y l e n e G l y c o l n - B u t y l E t h e r Water

Wei qh t% 60.80

2 . 0 0 9.40 8 . 7 0 4 .60 4 .70 6.60 3.20

Weight% 9.90 9 . 8 0 2 . 4 4 4 .93

73.00

Comments abou t t h i s f o r m u l a : 1 . A d d i t i o n a l Calsuds CD-6 may be needed t o c l a r i f y t h e sample. 2 . Add t h e w a t e r s l o w l y .

F o r m u l a t i o n DEG-002-01

Water Based Deareaser

I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 P i lot SXS-40 Na4EDTA Cal o x y l a t e N-9 E t h y l e n e G l y c o l Monobuty l E the r Sodi urn Me tas i 1 i c a t e

Weight% 68.50

2 . 0 0 7 .00 7 .50 2 .00 5 .00 3 . 0 0 5 .00

Comments abou t t h i s f o r m u l a : 1 . There i s a phosphate v e r s i o n where 3 .5% sodium t r i p h o s p h a t e

2 . Use w a t e r t o b a l a n c e i n g r e d i e n t s . i s s u b s t i t u t e d f o r t h e sodium m e t a s i l i c a t e and Na4EDTA.


SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s

22 Advanced Cleaning Product Formulatiorrs

m r e a s e r C o n c e n t r a t e ( L i qui d)

S o i l - G r e a s e , o i l Su r face -Pa i n t , p o l y m e r i c , me ta l A p p l i c a t i o n Method-Spray o r w ipe Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : Water Metso Beads 2048 *Sodi urn Pol y a c r y l a t e (40%) **Phosphate E s t e r * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C l l ; 6 Moles EO) * * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO)

Use D i l u t i o n : Normal Duty-1.5% bw ( 2 o z / g a l l o n ) Heavy Du ty -3 .0% bw ( 4 o z / g a l l o n )

* Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%) ** Rhone-Poulenc Rhodafac R E - 6 1 0 *** Rhone-Poulenc Rhodasur f 91-6 **** Rhone-Poulenc Rhodasur f A-24

M e t a l D e - O i l i n g L i q u i d C o n c e n t r a t e ( L i quid )

Soi 1-Petro leum-based o i 1 S u r f a c e - M e t a l : S t e e l , copper , aluminum, e t c . Appl i c a t i o n Method-Spray and /o r immersi on Manu fac tu re : M i x t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : Water S t a r s o Sodi urn S i 1 i c a t e EDTA, Te t rasod ium (37%) Sodium Xy lene S u l f o n a t e (40%) * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11

Use D i l u t i o n : 2%-4% bv

* Rhone-Poulenc Rhodasur f 91-6 ** Rhone-Poulenc Rhodasur f A-24

SOURCE: PQ Corp. : D e t e r g e n t Fo rmu la t

6 Moles EO) 2 .5 Moles EO)

on Guide

wt"/o

6 7 . 0 8 . 0 5 . 0

10 .0 5 . 0 5.0

W B 4 2 . 0 1 2 . 0 1 6 . 0 2 0 . 0

3 .0 7.0

aegreasers 23

Solvent Denreaser

Carbopol r e s i n s a re used t o emu ls i f y and s t a b i l i z e t h i s d-limonene o i l based emulsion. I n a d d i t i o n , t h e use o f t h e r e s i n p rov ides v e r t i c a l c l i n g t o inc rease t h e con tac t t ime o f t h e de tergent on t h e s o i l e d su r face and enhance consumer convenience.

I n q r e d i en t : D I Water Carbopol ETD 2623 ( 1 ) d-Limonene (2 ) Propylene g l y c o l methyl e the r (3 ) Alkylbenzene s u l f o n i c a c i d ( 4 ) C12-13 l i n e a r a l coho l , 6.5 moles EO ( 5 ) Isopropanol Sodium hydrox ide (50%)

9 81.18

0.32 10.00 2.00 2.00 1.50 2.50 0.50

Brookf i e l d v i scosi t y (RVT-20 rpm) : 750 cps Product pH: 9.5-10 Product C1 a r i t y : Opaque

( 1 ) BFGoodrich ( 2 ) Arylessence, I n c . : H-7892 d-limonene ( 3 ) Dow Chemical : Dowanol PM ( 4 ) Stepan C o . : B i o s o f t S-100 ( 5 ) S h e l l Chemical: Neodol 23-6.5

Procedure: 1 . Using moderate a g i t a t i o n (800 rpm) p rov ided by a L i g h t n i n '

Mixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approximately 15 minutes o r u n t i l t h e s l u r r y i s homogeneous.

2 . Add t h e d-limonene w i t h good a g i t a t i o n and mix u n t i l homogene-

3 . Reduce a g i t a t i o n and add t h e g l y c o l e the r , s u l f o n i c ac id , and

4 . Add t h e isopropanol . 5 . Add t h e sodium hydrox ide u n t i l t h e t a r g e t pH range i s

6. Add c o l o r , as des i red .

T o t a l Actives:

ous.

a l coho l e thoxy l a t e .

reached.

d-l imonene: 10.0 Propylene g l y c o l methyl e t h e r : 2.0 Sodium a1 kylbenzene su l fona te : 2 .2 Psopropanol : 1 .5 C12-13 l i n e a r a l coho l , 6 .5 moles EO: 2 .5



S o l v e n t Based Deqreaser

I n s r e d i e n t s : Kerosene A r i s t o n a t e M P i n e O i l T a l l O i l F a t t y A c i d C a l o x y l a t e N-9 Hexyl ene G1 y c o l

Comments about t h i s f o r m u l a : 1 . Use a low odor g rade o f t a l l o i l f a t t y a c i d . 2 . Add i n g r e d i e n t s i n t h e o r d e r i n d i c a t e d . 3. A r i s t o n a t e L can be s u b s t i t u t e d f o r A r i s t o n a t e M~


S o l v e n t Based Degreaser

I n g r e d i e n t s : A r i s t o n a t e M T r i t o n X-45 T r i t o n N-101 Kerosene

Comments about t h i s f o r m u l a : 1 . Kerosene can be s u b s t i t u t e d w i t h Aromat ic Naphtha. 2 . A r i s t o n a t e M can be s u b s t i t u t e d w i t h A r i s t o n a t e L.


Enqine C leaner and Deqreaser

I n g r e d i e n t s : Water M I PA Cal i mu1 se PRS Dowanol DPM Na4EDTA

Comments about t h i s f o r m u l a : C l e a r , p a l e y e l l o w produc t F o r m u l a t i o n DEG-005-01

SOURCE: P i 1 o t Chemi c a l Co. : Suggested Formul a t i ons

Wei ghP% 72.85

3.00 10.00 10 .06

3 . 0 2 1 . 0 6

We i g h t % 5 . 1 0 5 . 0 0 2 .99

86.93

Weight% 58.94 20.33

5 . 0 8 45 .24

0.41

lshwashing Detergents

25


A u t o m a t i c Dishwash Deteraent-Consumer (Ze ro Phosohate. C h l o r i n e Free. Powder1

S o i l - F o o d grease, o i l and p r o t e i n Sur face -Meta l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manu fac tu re -Dry B lend /Agg lomera t i on

Composi t i on : Sodi urn C i t r a t e D i h y d r a t e * B r i t e s i l H20 Hydrous P o l y s i l i c a t e Sodi urn Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) ***Acusol 445ND Sodi um Pol y a c r y l a t e (92% sol i d s ) ****Sodium P e r b o r a t e Monohydrate V a l f o r 100 Z e o l i t e A Sodium S u l f a t e

1 0 . 0 2 0 . 0 2 3 . 0

3 . 0 4 . 0

1 0 . 0 15.0 15 .0

* 2 . 0 w e i g h t r a t i o powder w i t h 17.5% wa te r ** Rhone-Poulenc A n t a r o x BL-330 *** Rohm & Haas; o r use a c o m b i n a t i o n o f Acusol 445ND and Acusol

**** O r use Sodium D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r - 479ND ( 2 w t . % each)

i n e ) a t 2 w t % . Balance w i t h s u l f a t e .

Au tomat i c Dishwash Detersent-Consumer (Phosphate, C h l o r i n e Free, Powder)

Soi 1-Food grease, o i 1 and p r o t e i n Sur face -Meta l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

Composi t i on : RU L i q u i d Sodium S i l i c a t e *Sodium Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) ***Acusol 445ND Sodi um Pol y a c r y l a t e (92% so l i ds) ****Sodium P e r b o r a t e Monohydrate *STPP Sodi u m S u l f a t e

15 .0 2 3 . 0

3 . 0 4 . 0

1 0 . 0 30 .0 1 5 . 0

* FMC ** Rhone-Poulenc A n t a r o x BL-330 *** Rohm & Haas; O r use a c o m b i n a t i o n o f Acusol 445ND and

**** O r use Sodi u m D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r - Acusol 479ND ( 2 w t . % each)

i n e ) a t 2 w t %. Ba lance w i t h s u l f a t e .

SOURCE: PO Corp. : D e t e r g e n t F o r m u l a t i o n Guide

Dishwashing Detergents 27

A u t o m a t i c Dishwash D e t e r c i e n t - I n d u s t r i a l & I n s t i t u t i o n a l (Phosphate, S o l i d Block)

S o i l - F o o d grease, o i l and p r o t e i n Sur face -Meta l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) M a n u f a c t u r e - S o l i d b l o c k

Composi t i on : Metso Beads 2048 NaOH (50% S o l u t i o n ) *STPP *Sodi um Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15)

* FMC ** Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r

S h e l l Chemical Neodol 25-7

Wt% 2 5 . 0 2 5 . 0 3 5 . 0 12.0 3.0

A u t o m a t i c D i shwashi ng D e t e r g e n t - I n d u s t r i a1 & I n s t i t u t i o n a l ( L i q u i d )

S o i l - F o o d grease, o i l and p r o t e i n S u r f a c e - M e t a l , ce ramic and g l a s s A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Compos i t i on : Water * A c r y s o l ASE 108 ( A c r y l i c Polymer) * * T r i t o n DF-16 ( N o n i o n i c S u r f a c t a n t ) P o t a s s i um H y d r o x i d e (45%)

N C l e a r Sodium S i l i c a t e TKPP (60%)

Wt% 50.9

6 . 9 3 . 0 1 . 2

25.0 13 .0

Use D i l u t i o n : 0 .15-0.30% bw ( 0 . 2 - 0 . 4 o z / g a l l o n )

* Rohm & Haas; o r Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e ( 4 0 % ) ** Rohm & Haas; o r Rhone-Poulenc A n t a r o x EL-330


28 Advarrced Clearring Product Formulatiorls

A u t o m a t i c Dishwash D e t e r g e n t T I n d u s t r i a l - &- I n s t i ~ ! . ! t i g n ~ j (Zero-Phosphate, C h l o r i n e Free, Powde_rj

S o i l - F o o d grease, oil and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manuf a c t u r e - D r y B1 end /Agg lomera t i on

Composi t i on : Metso Pentabead 20 Sod1 um Carbonate * L i q u i d N o n i o n i c S u r f a c t a n t (7 -9 Moles € 0 ; C12-15) **Acusol 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) ***Sodium P e r b o r a t e Monohydrate B leach Val f o r 100 Z e o l i t e A Sodium S u l f a t e

W t % 3 0 . 0 2 6 . 0 3.0 4 . 0

1 0 . 0 1 5 . 0 1 2 . 0

* Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r

* * Rohm & Haas; O r use a comb ina t ion o f Acusol 445ND and Acusol

*** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e )


479ND ( 2 w t % e a c h ) .

a t 2 w t % . Balance w i t h s u l f a t e .

A u t o m . a t i c P ~ h w a ~ h _ D e t e ~ e _ n ~ . ~ I ~ d - u Stri-a 1. _&-Ins t_ii-tluti_ o?e_a_8 L Phospha te_ ,Ch l_or ine _Free- Pow_s1ec)

S o i l - F o o d grease, o i l and p r o t e i n Sur face -Meta l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manu fac tu re -Dry B lend /Agg lomera t i on

C o m p o s i t i o n : Wt% G t s o Pentabead 20 3 0 . 0 *STPP 25 .0 *Sodi um Carbonate 2 8 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (7 -9 Moles EO; C12-15) 3 . 0 ***Acusol 445ND Sodi um Pol y a c r y l a t e (92% sol i d s ) 4 . 0 ****Sodium P e r b o r a t e Monohydrate B leach 1 0 . 0

* FMC ** Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r

*** Rohm & Haas; O r use a c o m b i n a t i o n o f Acusol 445ND and

**** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s

S h e l l Chemical Neodol 2 5 - 7

Acusol 479ND ( 2 w t % each)

c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .

SOURCE: PP Corp . : D e t e r g e n t F o r m u l a t i o n Guide


A u t o m a t i c D i shwashi ng Gel w i tJ1_..Chlori n e B1 each

Carbopol r e s i n s a r e used t o t h i c k e n t h e p r o d u c t t o reduce s p l a s h i n g , p r o v i d e cup r e t e n t i o n i n t h e d i shwasher , and c r e a t e a s t a b l e suspens ion o f i n s o l u b l e s ( i . e . phosphate b u i l d e r s ) i n t h i s AOL f o r m u l a t i o n c o n t a i n i n g c h l o r i n e b l e a c h .

I n q r e d i e n t : 01 wa te r Carbopol 672 ( 1 ) P o t a s s i um h y d r o x i d e (45%) 2 . l r p o t a s s i u m s i l i c a t e (39%) ( 2 ) P o t a s s i urn c a r b o n a t e ( 3 ) Sodium t r i p o l y p h o s p h a t e ( 4 ) Sodi um h y p o c h l o r i t e ( 1 2 . 5 C 0 h ) Sodium n -decy l d i p h e n y l o x i d e d i s u l f o n a t e ( 4 5 % ) ( 5 )

W t % 4 4 . 7 5

1 . 2 5 5 . 0 0

15 .00 5 . 0 0

2 0 . 0 0 8 . 0 0 1 . o o

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 15,000 cps P roduc t p H : 12-13 P roduc t c l a r i t y : Opaque

( 1 BFGoodri ch ( 2 The PO Corp. ( 3 Armand ( 4 FMC Corp. ( 5 ) O o w Chemica l : Dowfax 382

Procedure : 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an

impe l 1 e r s u i t a b 1 e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s . Screen t h e Carbopol r e s i n i n t . 0 t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x u n t i l homogeneous and f r e e o f po lymer lumps.

u n t i l homogeneous. The p r o d u c t w i l l become v e r y t h i c k a t t h i s p o i n - t .

3 . Add t h e po tass ium c a r b o n a t e and phosphate. M ix u n t i l t h e r e a r e no more phosphate p a r t i c l e s . H e a t i n g t o 50-60C w i l l speed t h i s p r o c e s s .

4 . Add t h e b l e a c h and t h e n t h e s u r f a c t a n t . M i x u n t i l homogeneous. A d j u s t t h e pH t o 12-13 u s i n g KOH. 00 n o t u s e a c i d t o reduce t h e pH, e s p e c i a l l y a f t e r t h e a d d i t i o n o f t h e b l e a c h .

be low 30C t o a v o i d e x c e s s i v e b l e a c h decompos i t i on .

2 . Add i n t h e po tass ium h y d r o x i d e and p o t a s s i u m s i l i c a t e . M i x

5 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Cool t h e p r o d u c t t o

T o t a l A c t i v e s : Phosphorous c o n t e n t : 5 . 0 S i l i c a t e ( a s S i 0 2 ) : 3 . 9 Carbonate ( a s Na2CO3): 3 . 8 Ava i 1 a b 1 e c ti 1 o r i ne : 1 . o

SOURCE: BFGoodrich S p e c i a l t y Chemica ls : DET-100


Clear, Co lo r less Manual -D ish Wash

I n s r e d i e n t s : Water, D . I. W i t c o l a t e ES-3 Rewoteric AM 8-14 Ethanol Sodium Ch lo r ide

Wt% 57 .5 34 .2 5.0 3.0 3 . 3

B lend ing Procedure:

between each a d d i t i o n .

Comment:

Blend i n g r e d i e n t s i n t h e order l i s t e d . D isso lve comple te ly

Rewoteric AM 8-14: Grease c u t t e r and foam booster . Formula 132

Powder S t a i n l e s s S i l ve rware Pre-Soak

I n q r e d i en ts : Sodium Carbonate (Soda Ash) Pet ro BAF Powder DeSonic 11N T r i sodi um Phosphate, Anhydrous Caust ic Soda Beads

61 endi ng Procedure:

Use D i 1 u t u i on : 1 oz/gal

Blend i n g r e d i e n t s i n t h e order l i s t e d

Formula 127

Low A1 k a l i ne Warewashi nq Block

I n q r e d i en ts : Water, D . I . R .U . S i l i c a t e DeSoni c LFD-97 Sodium Carbonate (Soda Ash) Sodium Tr ipolyphosphate Code 185


produced, pour i n t o molds and a l l o w t o harden. Blend i n g r e d i e n t s i n the order l i s t e d . When s l u r r y i s

Formula 129

SOURCE: Witco Corp . : Suggested Formulat ions

Wt% 6 7 . 0

5 . 0 11 . o 2 . 0

2 5 . 0

W B 1 6 . 0 29.0

2 . 0 2 3 . 0 3 0 . 0


Dish Washi nq Agents clear, liquid, 25% WAS

alkanesulphonate:ethersulphate=4:l

I n g r e d i e m A : Hostapur SAS 60

Genapol Z R O l i q u i d

B: Water P r e s e r v a t i v e DY e Perfume

T e s t s : v i s c o s i t y (rnPas) : 75 C loud p o i n t : <-5C

I n q r e d i e n t s : A : Hos tapur SAS 60

Genapol ZRO l i q u i d

B: Water P r e s e r v a t i ve DY e Perfume Genagen LAB

T e s t s : V i s c o s i t y (mPas): 100 Cloud p o i n t : <-5C

I n q r e d i e n t s : A : Hostapur SAS 60

Genapol ZRO l i q u i d

B: Water P r e s e r v a t i v e DY e Perfume Genagen LAB

T e s t s : V i s c o s i t y (mPas): 2 3 0 Cloud p o i n t : <-5c

M a n u f a c t u r i n g : One a f t e r a n o t h e r , t h e components o f B a r e added t o A

3 3 . 3 0 1 7 . 9 0

48.50 0 . 1 0

0 . 2 0 q . s .

Wto/, 3 3 . 3 0 1 7 . 9 0

47 .50 0 . 1 0

0 . 2 0 1 . o o

q . s .

3 3 . 3 0 17.90

44.50 0 . 1 0

0 . 2 0 4 .00

9 , s .

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s


D i s h Washi nq Agen ts C l e a r , liquid, 30% WAS

a1 kanesulphonate:ethersulphate=4: 1

I n s r e d i e n t s : A : Hos tapur SAS 60


€3: Water P r e s e r v a t i v e DY e Perfume Genagen LAB

T e s t s : V i s c o s i t y (mPas) : 380 C loud p o i n t : <-5C

I n q r e d i e n t s : A: Hos tapur SAS 60


0: Water P r e s e r v a t i v e DY e Perfume Hoe S 3924

T e s t s : V i s c o s i t y (mPas) : 420 C loud p o i n t : <-5C

I n g r e d i e n t s : A: Hos tapur SAS 60


El: Water P r e s e r v a t i ve DY e Perfume Hoe S 3924

T e s t s : V i s c o s i t y (mPas) : 61 0 C loud p o i n t : <-5C

W B 40 .00 21 . 4 0

37 .30 0 . 1 0

0 . 2 0 1 . o o

q . s .

wtsl, 40 .00 2 1 . 4 0

37.30 0 . 1 0

0 . 2 0 1 .oo

q . s .

wt./, 40 .00 21 .40

34.30 0 . 1 0

0 . 2 0 4 . 0 0

q . s .

M a n u f a c t u r i n g :


One a f t e r a n o t h e r , t h e components o f 8 a r e added t o A .


l n g r e d i e n t s : Water, D . I . W i t c o n a t e 1240 Varox 1770 W i t c o l a t e SE-5

D i s h Wash w/Am&e Oxide/LABS/SLES

Wtl 6 6 . 3 10.3

5 . 3 18.1

81 end i ng P rocedure :

between each a d d i t i o n . Add e t h a n o l as needed t o l o w e r v i s c o s i t y .

T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 620 S o l i d s : 16.8% pH: 9.12 Formula 117

Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y

D i sh Wash w/Ami ne Oxi de/LABS/ALES

I n g r e d i e n t s 1 Water, D.I. W i t c o n a t e 1240 Varox 1770 W i t c o l a t e LES-6OA E thano l

70 .0 13.8

3 . 1 8 . 2 5 . 0

B1 end? ng Procedure:

each a d d i t i o n . A c i d i f y w i t h C i t r i c A c i d t o pH=6.5.

T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 4 S o l i d s : 10.1% pH: 6 . 6 8 Formula 118


_ _ Hand Di shwashi ng L i sui d

I n g r e d i e n t s : Water W i t c o n a t e AOS W i t cami de 128T W i t c o l a t e LES-6OC

K% 6 0 . 0 26 .0

4 . 0 1 0 . 0

B l e n d j n g I n s t r u c t i o n s :

add i t i ons . Add a l l i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g w e l l between

Formula 106



Foam Boos te r : Ez-4-5 i n Hand D i shwashi na L i q u i d s

L i q u i d d i s h f o r m u l a t o r s a r e c h a l l e n g e d t o p roduce l o w c o s t q u a l i t y p r o d u c t s . Hand d i s h d e t e r g e n t s a r e expec ted t o foam i n t h e p resence o f f o o d s o i l s , c u t grease and c l e a n . I n a d d i t i o n , a e s t h e t i c s , s k i n m i l d n e s s , and env i ronmen ta l impac t a r e a l s o ma jo r p r o d u c t c o n s i d e r a t i o n s . The f o l l o w i n g d a t a i l l u s t r a t e d how E-14-5 can be used t o f o r m u l a t e c o s t e f f e c t i v e p r o d u c t s s u i t a b l e f o r t h e v a r i o u s l i q u i d d i s h soap market segments. O p t i m i z e d l i q u i d d i s h d e t e r g e n t s c o n t a i n i n g E-14-5 p r o v i d e t h e optimum i n c o s t pe r fo rmance when compared t o a l l o t h e r t y p e s o f foam b o o s t e r s . A l t h o u g h i t p e r f o r m s w e l l a l o n e , E-14-5 s y n e r g i s t i c a l l y enhances t h e pe r fo rmance o f most t r a d i t i o n a l foam b o o s t e r s as i l l u s t r a t e d below w i t h Coco d i e t h a n o l a m i d e .

Economy Eormul a t i on

I n g r e d i e n t s : D e i o n i z e d w a t e r Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) E t h y l a l c o h o l Tomah E-14-5 Coco d i e t h a n o l ami de

S tandard F o r m u l a t i o n

I n g r e d i e m D e i o n i z e d w a t e r Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (60% s o l i d s ) E t h y l a l c o h o l Tomah E-14-5 Coco d i e t h a n o l ami de

90% Premi u m Formul a t i on

I n q r e d i e n t s : D e i o n i z e d w a t e r Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s )

e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) L a u r y i a l c o h o E t h y l a l c o h o l Tomah E-14-5 Coco d i e thano ami de

_ _ _ _ ~ - ~ Premi urn F o r m u l a t i o n

I n q r e d i en& D e i o n i z e d wa te r Dodecyl benzene s u l f o n a t e , sod i um s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (6O0h s o l i d s ) E t h y l a l c o h o l Tomah E-14-5 Coco d i e t h a n o l ami de SOURCE: Tomah Produc ts , I n c . : Suggested F o r m u l a t i o n s

Wt.% 59.7 2 5 . 9 ( 15)

8 . 4 ( 5 ) 0 3 3

wt> 52.9 31 . 0 ( 1 8 ) 1 0 . l ( 6 )

1 . 5 3 3

Wt.% 3 8 . 6 3 8 . 8 ( 2 2 . 5 ) 1 2 . 6 ( 7 . 5 )

4 3

Wt.% 2 8 . 3 46.6( 27 ) 15 .1 ( 9 )

4 3 3


Hand D i s h D e t e r a e n t F o r m u l a t i o n s C l e a r D i shwash

IngredienPs 1 Water SXS (4O%j C12 A i f a O i e f i n s u i f o n a t e (28.75% s o i i d s j L a u r y l e t h e r s u l f a t e - 3 E 0 (27 .5% s o l i d s ) Tomah AO-728 S p e c i a l NaCl*

M i x i ng I n s t r u c t i o n s : Add t h e i n g r e d i e n t s i n t h i s o r d e r . M ix u n t i l homogeneous a f t e r each a d d i t i o n

\N t % 1 2 . 3 0 8 . 0 0

52.50 18 .20 6 . 0 0 3 . 0 0

SpG 2 0 / 2 0 C : 1 .05 pH: 6 V i s c o s i t y : 505 cps ( B r o o k f i e i d LVT 30 rpm s p i n d l e number 2)

NOTES: *Add more Nacl t o i n c r e a s e v i s c o s i t y .

P e a r i escen t U i shwash __

i n g r e d i e n t s : Water Dodecyibenzene s u i f o n a t e (60% s o l i d s ) Caury i e t h e r s u l f a t e - 4 E 0 (60% s o i i d s j O p a c i f i e r La tex (4OWja P e a r l i z i n g Agent ( 4 7 % j * * Tomah A0-728 S p e c i a i Tomah Amphoter ic L

M i x i n g I n s t r u c t i o n s : Add t h e i n g r e d i e n t s i n t h i s o r d e r . M ix u n t i i homogeneous a f t e r each a d d i t i o n .

WLL7O 5 4 . 4 0 25.00

8 . 30 0 . 0 4 2 . 3 0 4 . 0 0 6 . 0 0

SpG 2 0 / 2 0 C : 1 . 03

V i s c o s i t y : 1363 cps ( B r o o k f i e l d LVT, 12 rpm, s p i n d l e number PH: 6 . 5

NOTES: * L y t r o n 295 Mortor! i n t e r n a t i o n a l * * Euper ian PK-771, Henkei

SOURCE: Tomah P r o d u c t s , f n c . : Suggested F o r m u l a t i o n s


Hand Dishwashing L i q u i d

Carbopol r e s i n s can be used t o b u i l d r h e o l o g y i n p l a c e o f u s i n g h i g h e r s u r f a c t a n t l e v e l s . T h i s w i l l improve t h e s k i n f e e l and m i l d n e s s . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e , t h e use o f Carbopol r e s i n s w i l l i n c r e a s e foam s t a b i l i t y .

I n q r e d i e n t : D I Water Carbopol ETD 2623 ( 1 ) 5800 MW p o l y a c r y l i c a c i d ( 2 ) A lpha s u l f o methy l e s t e r (37%) ( 3 ) TEA (99%) Sodium l a u r y l e t h e r s u l f a t e (28%) ( 4 ) Coconut d i e t h a n o l ami de ( 5 )

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 400-600 cps Produc t pH: 6.0-7.0 Produc t c l a r i t y : C l e a r

( 1 ) BFGoodrich ( 2 ) BFGoodrich: Good-Rite K-7058 ( 3 ) Stepan Co.: A lphas tep ML-40 ( 4 ) Henkel C o r p . : Standapol ES-3 ( 5 ) Stepan Co. : N i n o l 11-CM

Q 38.11

0 .70 4 . 0 0

27.03 5 . 5 0

17 .86 2 .00

1 .

2 .

3 .

4 . 5 .

Procedure: Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r genera l m i x i n g and b l e n d i n g o p e r a t i o n s Preheat t h e water t o 40-5OC. Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g water (800 rpm). A l l o w t o mix f o r a t l e a s t 15 minu tes o r u n t i l homogeneous and f r e e o f po lymer lumps. Add i n t h e low m o l e c u l a r we igh t p o l y a c r y l a t e w i t h c o n s t a n t m i x i n g . Add i n t h e ASME s u r f a c t a n t w i t h a low l e v e l o f a g i t a t i o n t o a v o i d excess ive foam g e n e r a t i o n . Add i n t h e TEA, l a u r y l e t h e r s u l f a t e , and coconut DEA. A d j u s t t h e pH u s i n g TEA t o reach t h e t a r g e t range. Add c o l o r and per fume, as d e s i r e d . Cool b a t c h t o room tempera ture .

T o t a l A c t i v e s : A lpha s u l f o methy l e s t e r : 10.00 Sodium l a u r y l e t h e r s u l f a t e : 5 . 0 0 Coconut d i e t h a n o l a m i d e : 2 . 0 0 5800 MW p o l y a c r y l i c a c i d : 2 . 0 0

SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-I10


Hand Dishwashina Paste

Carbopol r e s i n s a r e used t o t h i c k e n and suspend i n s o l u b l e s i n t h i s hand dishwashing pas te . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d value, t h e use o f Carbopol r e s i n s w i l l i nc rease t h e foam s t a b i 1 i t y .

I n a r e d i en t : D I water Carbopol 672 ( 1 ) Alkylbenzene s u l f o n i c a c i d (9796) ( 2 ) Sodi um hydrox ide (50%) 2 .4 r sodium s i l i c a t e (52%) (3 ) Sodium t r i po l yphospha te ( 4 ) Sodium carbonate Sodium o l e f i n s u l f o n a t e (40%) (5)

Wt% 41.50

1 .oo 17.00

5.00 7.50

15.00 5 . 0 0 8.00

B rook f i e l d v i scosi t y (RVT-20 rpm) : 75,000 cps Product pH: 10-11 Product c l a r i t y : Opaque

( 1 ) BFGoodri ch ( 2 ) Stepan Co.: B i o s o f t S-100 (3 ) The PO Corp. ( 4 ) FMC Corp. ( 5 ) Stepan Go.: E io te rge AS-40

Procedure: 1 . Use a L i g h t n i n ’ M ixer o r s i m i l a r v a r i a b l e speed u n i t and

i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g water (800 r p m ) . A l low t o mix u n t i l homogeneou and f r e e o f polymer lumps.

2. Add t h e s u l f o n i c a c i d w i t h cont inuous a a i t a t i o n .

an ons.

3 . Add t h e sodium hydrox ide and sodium s i l i c a t e w i t h cont inuous ag i t a t i on. M i x u n t i 1 homogeneous.

4 . Slowly, add t h e phosphate. Mix u n t i l homogeneous and f r e e o f phosphate p a r t i c l e s . Heat ing t h e produc t t o 50-60C w i l l speed up t h i s process.

homogeneous. 5 . Add t h e sodium carbonate and o l e f i n su l fona te . Mix u n t i l

6 . A d d c o l o r and fragrance, as des i red .

T o t a l A c t i ves : Phosphorous con ten t : 3.7 S i l i c a t e (as S i02) : 2.7 Carbonate (as Na2C03): 5 .0 Sodium o l e f i n su l fona te : 3.2 Sodium alkylbenzene su l fona te : 17 .6

SOURCE: BFGoodrich Spec ia l t y Chemicals: DET-111

1


L i g h t Du ty L i q u i d , Premium Hand Dishwash

I n g r e d i e n t s : Water , D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t cami de 128T P e t r o LBA L i q u i d Sodium S u l f a t e E thano l Formal i n Perfume, Dye

Wt% 30 .2 21 .7 3 6 . 7

5 . 0 1 . 9 2 .6 1 . 8 0 . 1 9 , s .

81 e n d i n g P rocedure :

u s i n g C i t r i c A c i d .

T y p i c a l P r o p e r t i e s :

B lend i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH t o 6 . 5 - 7 . 0

V i s c o s i t y , cps : 230 Appearance: C1 ea r L i q u i d Formula 113

L i g h t D u t y L i q u i d Low Cos t Hand Dishwash

I n g r e d i e n t s : . Water, D . I. W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t cami de 128T P e t r o LBA L i q u i d Sodium C h l o r i d e Formal i n Perfume, Dye

81 . 5 5.5 9 .2 1 . 2 0 . 5 2 .0 0 . 1 q . s .

B l e n d i n g P rocedure :

u s i n g C i t r i c A c i d .


B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH=6 .5 -7 .0

V i s c o s i t y , c p s : 170 Appearance: C l e a r L i q u i d Formula 116

SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s


Liquid A u t o m a t i c Dishwasher D e t e r q e n t

T h i s f o r m u l a t i o n f e a t u r e s Van Gel ES, magnesium aluminum s i l i c a t e , as a suspending agen t and r h e o l o g y m o d i f i e r . The sodium h y p o c h l o r i t e f u n c t i o n s as a d i s i n f e c t a n t , c l e a n i n g agen t and b l e a c h . Sodium m e t a s i l i c a t e a d j u s t s t h e f o r m u l a pH. The phosphate b l e n d p r o v i d e s de te rgency and t h e s u r f a c t a n t s c o n t r i b u t e e x c e l l e n t r i n s a b i l i t y .

I n q r e d i e n t s : A : Van Gel ES

D e i o n i z e d Water

Wt% 4 .00

53.00

B : T e t r a p o t a s s i u m Pyrophosphate, t e c h n i c a l powder 10.00 Sodi um T r i po l yphospha te , t e c h n i c a l powder 20.00

C : Sodium M e t a a s i l i c a t e . Anhydrous Sodium H y p o c h l o r i t e , 12.5% s o l n .

D : Sodium X y l e n e s u l f o n a t e Deceth-4-Phosphate

2.00 8 .00

2.25 0 .75

P rocedure : P rehea t t h e w a t e r t o 55 t o 60C. H y d r a t e t h e Van Gel ES

s l o w l y by a d d i n g i t t o t h e a v a i l a b l e w a t e r u s i n g a h i g h speed d i s p e r s e r . P reb lend B i n g r e d i e n t s , A d d B t o A s l o w l y w i t h m i x i n g . M i x u n t i l u n i f o r m . Add C i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g u n t i l d i s s o l v e d . C o n t i n u e m i x i n g w h i l e c o o l i n g r a p i d l y t o 25C. F i n a l l y , combine D i n g r e d i e n t s and add w h i l e m i x i n g s l o w l y u n t i l smooth and u n i f o r m ( a v o i d i n c o r p o r a t i o n o f a i r ) .

C o n s i s t e n c y and pH:

LVT, S p i n d l e 4 a t 60 rpm measured a t room t e m p e r a t u r e a f t e r 30 days ag ing ; pH a p p r o x i m a t e l y 12 .5 .

Suggested Packaging: Squeeze b o t t l e o r pump.

SOURCE: R.T. V a n d e r b i l t Co., I n c . : F o r m u l a t i o n No. 438

Pumpable l i q u i d , V i s c o s i t y 1300-1800 cps , B r o o k f i e l d Model


Manual D i shwashi nq Gel

F u n c t i o n s & B e n e f i t s : Carbopol EX-473: * v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent

* p r o v i d e s h i g h c l a r i t y a c r o s s s u r f a c t a n t l e v e l * i m p a r t s y i e l d v a l u e f o r suspens ion o f , f o r i n s t a n c e , encap-

* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems *easy- to-use, o d o r l e s s , l i q u i d f o r m

o f s u r f a c t a n t t y p e

s u l a t e d a c t i v e s

i n i r e d l e n t : DI w a t e r Carbopol EX-473 ( 3 0 % ) * Sodium c i t r a t e Sodium h y d r o x i d e (18%) Ammonium l a u r y l s u l f a t e (30%)** Sodium l a u r y l e t h e r s u l f a t e (30%)***

W t % 37.50 10 .00

0 . 5 0 2 . 0 0

2 5 . 0 0 2 5 . 0 0

* V i s c o s i t y modi f i e r : BFGoodrich * * A n i o n i c s u r f a c t a n t : Standapol A : Stepan Chemical

* * * A n i o n i c s u r f a c t a n t : Standapol ES-3: Stepan Chemical

P h y s i c a l P r o p e r t i es : B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 8 ,000 C P P roduc t pH: 6 . 5 - 7 . 0 P roduc t c l a r i t y : c l e a r

P rocedure : 1 . Us ing s l o w a g i t a t i o n ( 2 0 0 rpm) p r o v i d e d by a L i g h - t n i n ' m i x e r

o r s i m i l a r v a r i a b l e speed u n - i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i ng o p e r a t i o n s , add t h e Carbopol EX-473 r e s i n i n t o t h e D I w a t e r . M ix u n t i l u n i f o r m and homogeneous.

2 . Add t h e sodium c i t r a t e . M ix u n t i l t h e sodium c i t r a t e i s c o m p l e t e l y d i s s o l v e d .

3 . A d j u s t t h e pH w i t h sodium h y d r o x i d e t o d e s i r e d pH. 4. Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s

w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n . 5 . Check pH, r e a d j u s t w i t h a d d i t i o n a l sodium h y d r o x i d e i f

necessa ry . 6 . Add f r a g r a n c e and c o l o r , as d e s i r e d .



__ Manual D i shwashi nq L iqu id

F u n c t i o n s B B e n e f i t s : Carbopol E X - 4 7 3 : * v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent

* p r o v i d e s h i g h c l a r i t y a c r o s s s u r f a c t a n t l e v e l * i m p a r t s y i e l d v a l u e f o r suspens ion o f , f o r i n s t a n c e , encap-

* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems *easy- to-use, o d o r l e s s , l i q u i d f o r m

o f s u r f a c t a n t t y p e

s u l a t e d a c t i v e s

I n g r e d i en t . D I w a t e r Carbopol EX-473 ( 3 0 % ) Ammonium l a u r y l s u l f a t e (30%)* Sodium l a u r y l e t h e r s u l f a t e ( 3 0 % ) * + Sodium c i t r a t e Sodium h y d r o x i d e (18%)

y t% 4 3 . 0 0

5 . 5 0 2 5 . 0 0 2 5 . 0 0

0 . 5 0 I . oo

* A n i o n i c s u r f a c t a n t : Star idapol A : Stepari Chemical * * A n i o n i c s u r f a c t a n t : Standapol ES-3: Stepan Chemical

P h y s i c a l P r o p e r t i e s : B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 500 CP Produc t p H : 6 .5 -7 .0 P roduc t c l a r i t y : C l e a r

P rocedure : 1 . U s i n g s l o w a g i t a t i o n ( 2 0 0 r p m ) p r o v i d e d by a L i g h t n i n ' M i x e r

o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , add t h e Carbopol EX-473 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m and homogeneous.

2 . Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n .

3 . Add t h e sodium c i t r a t e , M ix u n t i l t h e sodium c i t i - a t e i s c o m p l e t e l y d i s s o l v e d .

4 . A d j u s t t h e pH w i t h sodium h y d r o x i d e . 5 . Add f r a g r a n c e and c o l o r , as d e s i r e d .



Non-Ch lo r ina ted Machine D ishwash inq Compound, L i q u i d

I n Q r e d i e n t s : Water , D . I . Sodi um T r i p o l yphosphate Versene 220, Powder Sodi um G1 ucona te Sodium M e t a s i l i c a t e , Pen tahyd ra te C a u s t i c Soda 50% P e t r o ULF L i q u i d

\Mt% 7 9 . 5

2 . 0 1 . o 1 . o 7 . 0 8.5 1 . o

81 end i ng Procedure :

add i t i ons . Add a l l components i n t h e o r d e r shown, m i x i n g w e l l between

Formula 109

C h l o r i n a t e d Machine D i shwashi n q Compound, Powder

I n g r e d i e n t s : Sodi um Carbonate (Soda Ash) , L i g h t D e n s i t y Sodi um T r i p o l yphosphate (STPP) , L i g h t D e n s i t y DeSoni c LFD-97 Sodium M e t a s i l i c a t e , Anhydrous C a u s t i c Soda Beads CDB C l e a r o n

3 0 . 0 2 5 . 0

1 . o 30 .0 10 .0

4 . 0

B l e n d i n g P rocedure : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g t h o r o u g h l y w i t h

each a d d i t i o n . Formula 111

Non-Ch lo r i n a t e d Machine D i shwashi ng Compound. Powder

I n q r e d i e n t s : Sodi um Carbonate (Soda Ash) , L i g h t D e n s i t y Sodium T r i p o l y p h o s p h a t e (STPP), L i g h t D e n s i t y DeSoni c LFD-97 Sodium Metas i l i c a t e , Anhydrous C a u s t i c Soda Beads

Wt% 33.0 2 5 . 0

2 . 0 3 0 . 0 1 0 . 0


w i t h each a d d i t i o n . B lend i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g t h o r o u g h l y

Formula 112



Premi um Hand D i shwashi ng D e t e r q e n t

I n q r e d i e n t s : Water , D . I . A1 pha-Step MC-48 S t e o l CS-330 N i n o l 30-LL o r N i n o l 40-CO Sodium C h l o r i d e

Wt% 6 .9

56.0 30.0

5 . 6 1 . 5

P r o p e r t i es : Appearance: C l e a r y e l l o w l i q u i d pH, as i s : 6 .5 -7 .5 V i s c o s i t y @ 25 deg. C , cps: 220 S o l i d s , %: 39-40 D e n s i t y , l b s / g a l : 8 . 8 Freeze/ thaw, 3 c y c l e s : Pass C o l d s t o r a g e @ 4 deg. C . , 2 weeks: Pass F l a s h p o i n t , deg. F: >200

M i x i n g P rocedure : CHarge w a t e r . Add MC-48 and CS-330 and m i x . Add 30-LL o r 40-CO

and mix u n t i l homogeneous. S l o w l y add sodium c h l o r i d e t o t h i c k e n . M ix u n t i l c l e a r . A d j u s t p H w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e as necessa ry .

Comment :

o leochemica l r e s o u r c e s and a r e b i o d e g r a d a b l e .

SOURCE: Stepan C o . : F o r m u l a t i o n No. 173

The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m

D i s h Washina Aqents f o r Manual Use

I n q r e d i e n t s : Water Lumorol 4154 Z e t e s o l NL Zusol a t 1008/85 Sodium c h l o r i d e F o r m u l a t i o n CT 02-01-04

m e d i en t s : Water Z e t e s o l 2056 Amphotensid B 4 Zusol a t 1008/85 P u r t o n CFD F o r m u l a t i o n CT-02-01-05

7 9 . 0 12.0 6 . 0 1 . o

app rox . 2 . 0

Wt% 76.5 20.0

2 . 0 1 . o 0 .5

SOURCE: Zschimmer & Schwarz GmbH & C o . : Suggested F o r m u l a t i o n s

5. General Purpose

44

General Purpose Cleaners 45

Abrasive Cleaner w i t h Bleach

Carbopol r e s i n s a r e used t o achieve a s t a b l e suspension o f t h e ca l c ium carbonate abras ive o a r t i c l e s i n t h e presence o f c h l o r i n e b leach

l n q r e d i e n t : DI[ Water Carbopol 674 o r 691* Good-Rite K-7058 (50%)** Sodi um hydrox ide (50%) 2 . 4 ~ sodium s i l i c a t e (52%) Sodium h y p o c h l o r i t e (14%) Calc i urn carbonate*** Sodium n-decyl d ipheny lox ide d i s u l f o n a t e (45%

*Suspension a i d : BFGoodrich * *An t i - redepos i t i on : BFGoodrich

+*+Abrasive: White #8 (Georgia Marble) ****Anionic s u r f a c t a n t : Dowfax 382 (Dow Chemi

Physi ea9 Proper t i es : B r o o k f i e l d RVT v i s c o s i t y - 20 rpm: 3,960 cp

Product c l a r i t y : Opaque Product pH: 12-13

Wt% 53.76 0.80 2.00 2.80 2.50 7.14

30.00 **** 1 .oo

~ ~ ~ ~ ~ d ~ r ~ ~ 1 . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '

M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t - ab le for general m ix ing and b lend ing opera t ions , d isperse o r screen t h e Carbopol r e s i n i n t o t h e D I water . Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogeneous

2 . Add t h e low molecular weight p o l y a c r y l a t e polymer fo l l owed by t h e sodium hydrox ide and sodium s i l i c a t e . Mix u n t i l homogeneous.

(The produc t w i l l drop i n v i s c o s i t y a t t h i s p o i n t . )

cons tan t a g i t a t i o n . Mix u n t i l homogeneous.

3 . Reduce a g i t a t i o n speed and add t h e sodium h y p o c h l o r i t e bleach.

4. Add t h e ca lc ium carbonate and f i n a l l y t h e s u r f a c t a n t w i t h

5 . Add f ragrance, as des i red .

FGoedrich S p e c i a l t y Chemicals: DET-343


Abras ive Cleaner Wi thout B1 each

Carbopol r e s i n s a re used i n t h i s f o r m u l a t i o n t o achieve a s t a b l e suspension o f t h e h igh l oad ing o f ca lc ium carbonate abras ives . I n s r e d i e n t : D I Water Ethanol Carbopol 674 ( 1 ) Sodium hydrox ide (50%) Sodium b icarbonate Calcium carbonate ( 2 ) C12-15 1 i near a1 coho1 , Coconut d i ethanol ami de

3 moles EO ( 3 ) (4 )

Wt% 62.10

2 . 0 0 0.60 1 .00 1 . 2 0

30.00 2.50 0.60

Brookf i e l d v i scosi t y (RVT-20 rpm) : 4,500 cps Product pH: 8-10 Product c l a r i t y : Opaque

( 1 ) BFGoodr i ch ( 2 ) Georgia Marble Co.: Georgia Marble White #8 (3 ) S h e l l Chemical: Neodol 25-3 ( 4 ) Stepan Co.: N ino l 11-CM

1 .

2 .

3 .

4 .

5 .

Procedure: Add t h e ethanol t o t h e water - h o l d i n g back 10 p a r t s o f water f o r s t e p #3. Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n ’ Mixer or s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e D I water/ethanol m ix tu re . M i x t h e s l u r r y for approximately 15 minutes o r u n t i l t h e s l u r r y i s homogeneous. Prepare a n e u t r a l i z i n g s o l u t i o n o f t h e 10 p a r t s o f water w i t h t h e sodium hydrox ide and sodium b icarbonate . Add t h i s t o t h e m ix tu re formed above and mix u n t i l homogeneous. Add t h e ca l c ium carbonate, a lcoho l e thoxy la te and coconut QEA. Mix u n t i l homogeneous. Add fragrance, as des i red .

To ta l Ac t i ves : Ca lc i um carbonate: 30.0 C12-15 l i n e a r a l coho l , 3 moles EO: 2 .5 Coconut DEA: 0 .6



A l l Purpose C l e a n e r

I n g r e d i e n t s : Urea Na4EOTA Water 2990 Ammonia C a l s o f t L-40 C a l o x y l a t e N-9

Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-001-01


I n g r e d i e n t s : Na4EDTA Water, Perfume Dowanol DPnB C a l s o f t L-40

Wei q h t % 2.00 2.00

88 .00 1 . o o 5 .00 2 . 0 0

Wei q h t % 4 .00

84 .00 4.00 8 . 0 0

Comments abou t t h i s f o r m u l a : Compare t o M r . C lean , a t rademark o f P r o c t o r & Gamble. F o r m u l a t i o n APC-002-01

A l l Purpose C leaner

I n q r e d i e n t s : d - L i monene Calamide C Calamide CWT Cal i mu1 se PRS Water

Comments abou t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s f i r s t and m i x . 2 . Add w a t e r s l o w l y . 3 . M ix u n t i l homogeneous.

F o r m u l a t i o n APC-005-01


I n q r e d i e n t s : Water Calamide CWT

Comments abou t t h i s f o r m u l a : Formula t h i c k e n s e f f e c t i v e l y . F o r m u l a t i on APC-003-01


Wei qh t% 40.00

4 .00 4 . 0 0

1 0 . 0 0 42.00

Weight% 85.00 15 .00



I n q r e d i e n t s : Na4EDTA Water Calamide C Calamide CWT P i l o t SXS-40 Laurami ne Oxide

Comments about t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-006-01


I n q r e d i e n t s : Na4EDTA Water 50% NaOH Cal s o f t LAS-99 P i l o t SXS-40 Calamide C Calamide CWT

Comments about t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-007-01

A l l Purpose C leaner - No Rinse

I n q r e d i e n t s : Water C a l f a x 1OL-45 Na4 EDTA E t h y l e n e G l y c o l Monobutyl E t h e r Calamide CWT

Comments about t h i s f o r m u l a : Spray as i s , t h e n wipe w i t h a paper t o w e l . F o r m u l a t i o n APC-008-01

SOURCE: P i l o t Chemical Co.: Suggested F o r m u l a t i o n s

Wei q h t % 5.00

77 .50 2 . 5 0 2.50 2 . 5 0

1 0 . 0 0

Wei q h t % 5.00

76.10 0 .80 2 . 8 0 5 . 3 0 5 . 0 0 5 . 0 0

Weight% 89.00

3 .00 3 . 0 0 3 . 0 0 2 . 0 0


A1 1 -Purpose C1 eaner

Composi t i on : Ke lzan xanthan gum A1 i p a l CD-128 Gafamide CDD 518 B u t y l C e l l o s o l ve Sodi urn Metas i 1 i c a t e T r i s o d i urn Phosphate Water , Perfume

0.3 1 . 7 0 . 5 3 . 5 1 . 7 1 . o

91 .3

P rocedure : P repare wa te r s o l u t i o n o f Ke lzan xan than gum by add ing t h e

powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n . Add o t h e r i n g r e d i e n t s as i n d i c a t e d . Fo r a e r o s o l use, cha rge w i t h a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t Genetron 1 2 .

- A l l - P u r p o s e D i s i n f e c t a n t C leaner

Composi ti= Ke lzan xan than gum Makon 10 Sodium T r i p o l y p h o s p h a t e Versene 100 Hyarnine 1OX Water

Q 0.5

1 0 . 0 3 . 0 3 . 0 1 . o

82 .5

P rocedure : P repare w a t e r s o l u t i o n o f Ke lzan xan than gum by add ing t h e

powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n . Add o t h e r i n g r e d i e n t s as i n d i c a t e d . F o r a e r o s o l use, charge w i t h a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t Genetron 1 2 .

SOURCE: Monsanto Per formance M a t e r i a l s : Ke lzan Suggested F o r m u l a t i o n s


l n q r e d i en& Rhodaterge SMC STPP Water

SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : Suggested F o r m u l a t i o n s

Wt% 1 0 2

88


A l l Purpose C leaner w/Amide/Phosphate E s t e r

I n n r e d i e n t s : Water , D.I. T e t r a p o t a s s i u m Pyrophosphate Varami de A-1 0 Emphos 5AP

Wt% 8 3 . 0

5 . 0 1 0 . 0

2 . 0


each a d d i t i o n . T y p i c a l P r o p e r t i e s :

V i s c o s i t y , cps : 145 S o l i d s : 17 .0% pH: 8 . 8


Formula 514


I n g r e d i e n t s : Water W i t c o n a t e 1260 S1 u r r y Wi tcamide 6445

B l e n d i n g P rocedure : B1 end i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .

T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 670 Sol i d s : 33 .0% pH, as i s : 9 . 2

Formula 520

A1 1 Purpose C l e a n e r

I n g r e d i e n t s : Water Sodi um T r i p o l yphosphate C a u s t i c Soda, 50% W i t c o 12988 W i t cami de 6445 Perfume, Dye


Typ i c a l P r o p e r t i es : B lend i n g r e d i e n t s i n o r d e r l i s t e d .

Speci f i c G r a v i t y : 1 . 0 2 0 6 W t . / G a l . l b s . : 8 . 5 pH, as i s : 9 .12 V i s c o s i t y , cps : 107 C o l o r : Be ige

Use D i l u t i o n : 1 -2 o z . / G a l . Formula 535 SOURCE: W i t c o Corp. : Suggested F o r m u l a t i o n s

wto/, 5 6 . 0 3 8 . 5

5 . 5

W S 9 0 . 0

2 . 0 0 . 5 2 . 0 5 . 0 q . s .


A l l Purpose C leaner C o n c e n t r e (Phosphate, - L i q u i d , Foam)

Soi 1 -Grease and o i 1 S u r f a c e - P a i n t , p o l y m e r i c , me ta l A p p l i c a t i o n Method-Spray Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t ion: Water Metso Beads 2048

*Phosphate E s t e r * * D i p r o p y l e n e G l y c o l Monomethyl E t h e r * * *Oc ty lphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO ****Octy lphenoxy P o l y e t h o x y e t h a n o l , 5 Moles EO

Use D i l u t i o n : Normal Duty-1.5% bw ( 2 o z / g a l l o n )

TKPP (60%)

Heavy Duty-2.5% b w ( 3 . 3 o z / g a l 1 on) Tough Duty-as s u p p l i e d

* Rhone-Poulenc Rhodafac RE-610 **( Dow, A rc0 Chemical *** Rhone-Poulenc I g e p a l CA-630 **** Rhone-Poulenc I g e p a l CA-520

A l l Purpose C o n c e n t r a t e (Phosphate, L i q u i d 1

Soi 1-Grease and o i 1 S u r f a c e - P a i n t , p o l y m e r i c , me ta l A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : Water Metso Beads 2048 TKPP Sodium Xy lene S u l f o n a t e , 40% * E t h y l e n e G l y c o l n - B u t y l E t h e r P i n e O i l * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3, 6 . 5 Moles EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5, 3 Moles EO)

Use D i 1 u t i on: 1 .5-3.0% bw (2 -4 o z / g a l l on )

* Dow Chemical , Union C a r b i d e *l Rhone-Poul enc Rhodasur f LA-7 * S * Rhone-Poulenc Rhodasur f A-24


Wt% 78 .1

2 .4 3 . 0 3 . 0 6 . 0 5 . 0 2 . 5

wto/, 78.75

1 . o o 3.00 3 . 5 0 6 . 0 0 0 . 2 5 5 . 0 0 2 .50


Calcium Carbonate Abras ive Cleaner Wi thout Bleach

Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o achieve a s t a b l e suspension o f t h e h igh l oad ing o f ca lc ium carbonate abras ives . I n q r e d i en t : D I Water Carbopol ETD 2623 ( 1 ) Sodium hydrox ide (50%) C12-I5 l i n e a r a l coho l , 3 moles EO (2 ) Sodium a l k y l benzene su l fona te ( 3 ) Calcium carbonate ( 4 )

62.10 0 . 2 5 0 .20 1 .50 0.50

30.00

Phys ica l Proper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 7,500 cp Product pH: 8-10 Product C l a r i t y : Opaque

Raw M a t e r i a l Supp l i e rs : ( 1 ) BFGoodrich ( 2 ) S h e l l Chemical Co.: Neodol 25-3 (3 ) Stepan Co. : Nacconol SQG ( 4 ) Georgia Marble C o . : Georgia Marble White #8

Procedure: 1 . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '

M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t - ab le f o r general m i x i ng and b l endi ng opera t ions , d i sperse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approximately 15 minutes or u n t i l t h e s l u r r y i s homogeneous.

w i l l become ve ry t h i c k a t t h i s p o i n t .

ac tan ts . Mix u n t i l homogeneous.

2. Add t h e sodium hydrox ide t o reach t a r g e t pli. The produc t

3 . Add t h e a l coho l e thoxy la te and alkylbenzene s u l f o n a t e surf-

4 . Add t h e ca lc ium carbonate. Mix u n t i l homogeneous. 5. Add fragrance, as des i red .

To ta l Ac t i ves : Calcium carbonate: 30.00 C12-15 l i n e a r a l coho l , 3 moles EO: 1.50 Sodium a1 kylbenzene su l fona te : 0 . 5 0

SOURCE: BFGoodrich Spec ia l t y Chemicals: BET-341


C i t r i c A c i d Cleaner

Functiane 8 B e n e f i t s : Carbopol ETD 2623: *Provides low p H t h i c k e n i n g v i a hydrogen bonding w i t h s u r f -

* Impar ts y i e l d va lue f o r suspension o f abras ive p a r t i c l e s *Provides v e r t i c a l c l i n g f o r inc reased su r face con tac t t i m e *Shear t h i n n i n g rheology f o r easy d ispens ing through t r i g g e r

*Easy-to-disperse r e s i n f o r improved and eas ie r f u l l - s c a l e

ac tan t

sprayer o r nozz le

p rocess ing

Inqiredi en t : Wt% DI Water 78.40 Carbopo? ETD 2623 Resin* C12-15 l i n e a r a l coho l , 3 moles EO** C12-13 l i n e a r a l coho l , 6 .5 moles EO*** Alkylbenzene s u l f o n i c acid**** C i t r i c A c i d (50%)

0.10 5.00 2.50 2.00

12.00

*V i scos i t y modi f i e r : BFGoodr i ch s W o n i o n i c s u r f a c t a n t : Neodol 25-3: She1 1 Chemical

>N**Nonionic s u r f a c t a n t : Neodol 23-6.5: She l l Chemical * * r *An ion ic s u r f a c t a n t : B i o s o f t 5-100: Stepan

P h y s i c a l P r o p e r t i ee: Storage Temperature

B r o o k f i e l d RVT v i scos i t y -20 rpm: I n i t i a l : 50cP 50cP

Age-Up V i s c o s i t y : Week 2 : 170cP 400cP Week 4: 250cP 600cP Week 6: 350cP 400cP

Product pH: 1 . 4 Product c l a r i t y : T rans lucent

-. 25C 5oc

Procedurw: 4 . Using J marine b lade p r o p e l l e r and r a p i d a g i t a t i o n (800 rpm)

prov ided by a L i g h t n i n ' M ixer o r s i m i l a r v a r i a b l e speed u n i t , s p r i n k l e t h e Carbopol ETD 2623 r e s i n i n t o t h e v o r t e x . A l l ow t o hyd ra te f o r 15-20 minutes or u n t i l no lumps a r e present . Warming t h e de ion ized water t o 30C w i l l decrease t h e h y d r a t i o n t i m e and improve t h e d i s p e r s i b i l i t y o f t h e Carbopol powder.

needed) t o ensure homogeneity. A d d w i t h moderate m ix ing (300 rpm). A l low t o mix u n t i l un i fo rm and smooth.

a l l o w t o mix u n t i l un i fo rm and smooth.

u n t i l smooth and un i fo rm.

2 . M i x t h e Neodol 25-3 and Neodol 23-6.5 ( o r warm s l i g h t l y i f

3. Add t h e B i o s o f t S-100 w i t h moderate (300 rpm) mix ing and

4. S ~ O W ~ Y add t h e C i t r i c Ac id w i t h s low m ix ing (200 r p m ) . M i x

5 . Add f ragrance and c o l o r , as des i red .

SOURCE: BFGoodr ick S p e c i a l t y ChemicaJs: DET-352


Genera l Purpose C1 eaner (Consumer Low Alkaline, Non-Phasphate Powder)

S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and grease, c l a y

Sur face -Hard s u r f a c e , i . e . , m e t a l , p l a s t i c , ce ramic , c o n c r e t e ,

Appl i c a t i on Method-Wi pe o r Brush Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

and p a r t i c u l a t e s o i l

and a s p h a l t

Composi t i on : Wt% Sodi um Carbonate ( 1 i g h t d e n s i t y ) 3 0 . 0 * B r i t e s i 1 C20 Hydrous P o l y s i 1 i c a t e 1 0 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5; 9 Moles EO) 15.0 V a l f o r 100 Z e o l i t e A 30 .0 ***Acusol 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0 . 5 Sodi um S u l f a t e 1 4 . 5


* 2.0 w e i g h t r a t i o s i l i c a t e powder, 82.5% s o l i d s ** Rhone-Poulenc Rhodasur f LA-9 *** Rohm & Haas

Genera l Purpose C l e a n e r (Consumer H i g h A1 k a l i ne, Non-Phosphated Powder1

Soi -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and grease, c l a y

Sur ace-Hard s u r f a c e , i . e . , m e t a l , p l a s t i c , ce ramic , c o n c r e t e ,

App i c a t i o n Method-Wipe o r b r u s h Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

and p a r t i c u l a t e s o i l

and a s p h a l t

Composi t i o n 1 Wt% Sodium S u l f a t e 1 4 . 5 Sodi um Carbonate ( 1 i g h t d e n s i t y ) 3 0 . 0 * L i q u i d N o n i o n i c S u r f a c t a n t ( C 1 2 - C l 5 ; 9 Moles EO) 1 5 . 0 V a l f o r 100 Z e o l i t e A 3 0 . 0 Metso Beads 2048 1 0 . 0 **Acusol 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0 . 5


* Rhone-Poulenc Rhodasur f LA-9 ** Rohm & Haas

SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n Guide


Genera l Purpose Spray & Wipe C l e a n e r

Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g i n v e r t i c a l c l i n g when sprayed on a v e r t i c a l s u r f a c e . T h i s " n o - d r i p " a c t i o n w i l l i n c r e a s e t h e c o n t a c t t i m e o f t h e d e t e r g e n t on t h e s o i l e d s u r f a c e as w e l l as enhance consumer conven ience .

I n g r e d i e n t : D I Water Carbopol ETD 2 6 9 1 ( 1 ) EDTA ( t e t r a sodium s a l t ) Sodium m e t a s i l i c a t e , anhydrous P r o p y l ene g l y c o l me thy l e t h e r ( 2 ) C12-15 l i n e a r a l c o h o l , 7 moles EO ( 3 )

wto/, 9 0 . 7 0

0 . 2 0 2 . 0 0 2 . 3 0 3 . 0 0 1 . 5 0

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 120 cps P roduc t p H : 12-13 P roduc t C l a r i t y : C l e a r t o hazy

( 1 ) BFGoodri ch ( 2 ) Dow Chemical : Dowanol DPM ( 3 ) S h e l l Chemical : Neodol 25-7

P rocedure : 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '

M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r sc reen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m inu tes or u n t i l t h e s l u r r y i s homogeneous.

2 . Under s l i g h t a g i t a t i o n , add t h e EDTA and M e t a s i l i c a t e . 3 . C o n t i n u e a g i t a t i o n and add t h e g l y c o l e t h e r and a l c o h o l

4 . Add c o l o r and f r a g r a n c e , as d e s i r e d .

T o t a l A c t i v e s :

e t hoxy 1 a t e .

P ropy lene g l y c o l me thy l e t h e r : 3 . 0 C12-I5 l i n e a r a l c o h o l , 7 moles EO: 1 . 5



Genera l Purpose Spray & Wipe

I n g r e d i e n t s : Water, D.I. Sodi um C i t r a t e A1 pha-Step MC-48 S tepano l WA-Extra N i n o l 11-CM

Wt% 79.0

2 . 0 1 0 . 0

7 . 0 2 . 0

M i x i n g Procedure:

m ix u n t i 1 homogeneous.

Typ i c a l P r o p e r t i es :

Charge w a t e r and s u r f a c t a n t s and m i x . Add sodium c i t r a t e and

Appearance: C l e a r c o l o r l e s s l i q u i d pH, as i s : 9 .4 V i s c o s i t y I3 25 deg. C : Very t h i n S o l i d s , %: 1 0 . 0 D e n s i t y , l b s / g a l : 8 .54 Co ld s t o r a g e @ 4 deg. C, 1 day: pass Freeze/ thaw, 3 c y c l e s : pass

Per formance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :

Commercial P r o d u c t - 66% s o i l removed f r o m t i l e s Above f o r m u l a t i o n - 82%' s o i l removed f r o m t i l e s Above f o r m u l a t i o n p e r f o r m s b e t t e r t h a n commerc ia l p r o d u c t .

Use I n s t r u c t i o n s : Use as i s

Comment :

o leochemica l r e s o u r c e s and a r e b i o d e g r a d a b l e .

SOURCE: Stepan Co. : Suggested F o r m u l a t i o n No. 575


A1 1 -Purpose C1 eaner

I n g r e d i e n t s : Water Z e t e s o l 2056 Z u s o l a t 1008/85

8 2 . 0 14 .0 4 . 0

SOURCE: Zschimmer & Schwarz GmbH & Co. : F o r m u l a t i o n CT 02-04-02


H y p o c h l o r i t e V e r t i c a l S u r f a c e C l e a n e r

Monatrope 1250 i s a h y p o c h l o r i t e s t a b l e s u r f a c t a n t t h a t c o n t r i b u t e s t o w e t t i n g and foaming c h a r a c t e r i s t i c s .

I n q r e d i e n t s : Monatrope 1250 Sodium C14-17 A l k y l Sec S u l f o n a t e (60%) Laurami ne Oxide (30%) Potass ium H y d r o x i d e (45%) Sodi um T r i p o l y p h o s p h t e Sodium H y p o c h l o r i t e 5.25%)

Wt% 2 . 0 2 .0

1 0 . 0 15.0

5 . 0 6 6 . 0

P rocedure : Add i n g r e d i e n t s w

T y p i c a l P r o p e r t i e s : Appearance: C l e a r p H : 13

t h a g i t a t i o n .

y e l l o w l i q u i d

Recommended Use D i l u t i o n : 1:lO w i t h w a t e r Formul a t i on F-783

Pump Sprav A l l Purpose C l e a n e r

A f a s t a c t i o n sp ray and w ipe f o r m u l a t i o n . S u r f a c e s w i l l d r y s t r e a k - f r e e .

I n q r e d i e n t s : Water Monaterge 779 (DEA-Laureth S u l f a t e ) P ropy lene G l y c o l B u t y l E t h e r

Wt% 94 .0

3 . 0 3 . 0

P rocedure : Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.

T y p i c a l P r o p e r t i e s : Appearance: C l e a r l i q u i d

Recommended Use D i 1 u t i o n : As i s

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


L i q u i d C1 eanser w i t R B1 each

I n t h i s f o r m u l a Van Gel B i s used t o suspend t h e a b r a s i v e and t o a d j u s t t h e v i s c o s i t y . The sodium carbonate b u f f e r h e l p s m a i n t a i n a pH o f about 11, necessary f o r t h e s t a b i l i t y o f t h e h y p o c h l o r i t e . T h i s l i q u i d c l e a n s e r o f f e r s t h e advantage o f m i l d - ness i n use and g r e a t e r ease and e f f e c t i v e n e s s on v e r t i c a l s u r f a c e s as compared t o powders.

I n g r e d i e n t s : A : Van Gel B

Water

6 : Diatomaceous E a r t h Sodium c a r b o n a t e Sodium h y p o c h l o r i t e , 5 .25% s o l n . Sodium L a u r y l S u l f a t e , 29% s o l n .

2 . 2 5 6 2 . 2 5

'10.00 4.50

2 0 . 0 0 1 . o o

Procedure:

a v a i l a b l e shear . Cont inue m i x i n g u n t i l smooth. Add remain ing i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n .

Cons is tency : Medium v i s c o s i t y l i q u i d .

Suggested Packaging: P l a s t i c squeeze b o t t l e .

SOURCE: R.T. V a n d e r b i l t Co. , I n c . : F o r m u l a t i o n N o . 391

S l o w l y add Van Gel B t o t h e water w h i l e a g i t a t i n g a t maximum

I n g r e d i e n t s : A: Hostapur SAS 60

Genapol ZRO 1 i q u i d Genapol UD-080

B : Water Perfume P r e s e r v a t i v e Dye

A l l Purpose C leaner C l e a r , l i q u i d

W t %

0 . 0 - 4 . 0 1 . 0 - 3 . 0

10.0-15.0

ad 1 0 0 . 0 0 . 2 0 . 1 q . s .

M a n u f a c t u r i n g : Add one a f t e r a n o t h e r , t h e components o f B t o A .

Modern s t a n d a r d f o r m u l a t i o n s a r e based on a lkansu lphonates and non i o n i c s . E t h e r s u l p h a t e s a r e used i n r a r e cases. Phosphates, sodium carbonate and ammonia a r e n o t common any 1 onger . The above g u i d e f o r m u l a t i o n c o v e r s t h e common european p r o d u c t s .

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n

I n g r e d i e n t s : P i n e o i l N i n o l 11-CM Makon 12 Ammonyx LO B i o - S o f t S-1 00 I s o p r o p a n o l Water, D . I .


P i n e O i l Cleaner C o n c e n t r a t e

g 20 .0

9 . 0 5 . 0 0 . 5 2 .0

1 0 . 0 5 3 . 5

M i x i ng Procedure :

w a t e r s l o w l y w h i l e under a g i t a t i o n . M i x u n t i l c l e a r . P r o p e r t i e s :

Combine p i n e o i l , s u r f a c t a n t s and IPA . M i x u n t i l c l e a r . Add

Appearance: C l e a r y e l l o w l i q u i d Odor: P i n e V i s c o s i t y @ 25C, cps: 50 pH (as i s ) : 8 . 1 D e n s i t y 1 b s / g a l : 8 . 0 6 Freeze/Thaw ( 3 c y c l e s ) : Pass 50 C oven ( 1 week): Pass

Use I n s t r u c t i o n s : D i l u t e 1-2 o z s i n t o one g a l l o n Per formance:

Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t : Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s Commercial f o r m u l a t i o n : 55.5% s o i l removed f r o m t i l e s

SOURCE: Stepan Co.: F o r m u l a t i o n No. 208

D i s i n f e c t i n g Cleaner , A l k a l i n e

I n g r e d i e n t s : Water C i t r i c a c i d Z u s o l a t 1008/85 Lumorol 4192 T r i l o n A l i q u i d Lonzabac-1230 I n g r e d i e n t s : Water Disodium t e t r a b o r a t e decahydra te Sodi um b i c a r b o n a t e Burdac-114 Zusol a t '1008/85 I n g r e d i e n t s : Water T r i l o n A l i q u i d C i t r i c a c i d Su l f e t a l 4069 Zusol a t 1008/85 Lonrabac-1230

Wt% 57.5

2 . 0 3 .5 5 . 0 7 . 0

25 .0 Wt%

6 9 . 0 0 . 5 1 . 0

20 .0 9 . 5 g

57 .5 7 .0 2 . 0 5 . 0 3 .5

2 5 . 0

SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n s CT 06-09-01, CT 06-09-02, CT 06-09-03

60 Advanced Cleaning Product Formulatiorrs

Sodi urn B i c a r b o n a t e A b r a s i v e C leaner W i t h o u t B leach

Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a s t a b l e suspens ion o f t h e h i g h l o a d i n g o r sodium b i c a r b o n a t e a b r a s i v e s .

- I n g r e d i e n t : D I Water Carbopol ETD 2691 ( 1 ) A l k y l benzene s u l f o n i c a c i d ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 moles € 0 ( 3 ) Sodium h y d r o x i d e (50%) Sodium b i c a r b o n a t e ( 4 ) :

Grade 1 : Grade 5 :

wtsl, 44.25

0 . 5 0 0 . 7 5 2 .50 2 . 0 0

2 0 . 0 0 3 0 . 0 0

P h y s i c a l P r o p e r t i e s : B r o o k f i e l d V i s c o s i t y (RVT-20 rprn): 6 ,000 c p P roduc t p H : 8 . 5 0 P roduc t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan Co.: B i o s o f t 5-100 ( 3 ) S h e l l Chemical Co.: Neodol 23-6.5 ( 4 ) Church & Dwight

Procedure: 1 . U s i n g moderate a g i t a t i o n ( 8 0 0 r p m ) p r o v i d e d by a L i g h t n i n '

M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e or sc reen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous.

e t h o x y l a t e . M i x u n t i l homogeneous.

t o 8 . 5 0 p r i o r t o t h e n e x t s t e p .

M ix u n t i l smooth, homogeneous, and f r e e o f b i c a r b o n a t e lumps. Re-check pH and a d j u s t , i f necessa ry .

2 . Add t h e a l k y l b e n z e n e s u l f o n i c a c i d f o l l o w e d by t h e a l c o h o l

3 . Add t h e sodium h y d r o x i d e . M i x u n t i l homogeneous. A d j u s t pH

4 . W i t h m in ima l a g i t a t i o n , s l o w l y add t h e sodium b i c a r b o n a t e .

5 . Add c o l o r and f r a g r a n c e , as d e s i r e d .

T o t a l A c t i ves : Sodi um b i c a r b o n a t e : 5 0 . 0 0 C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: 2 . 5 0 Sodium a1 k y l benzene s u l f o n a t e : 0 . 9 0


leaners/Polishes

61


A n t i -Foggi ng , A n t i -Stat i c G lass C l eaner

I n g r e d i e n t s : Water I s o p r o p y l A l c o h o l Adogen 66 Varox 365 Emcol 4500

MIBo/o 9 0 . 0

9 . 0 0 . I 0 . 5 0 . 4

B l e n d i n g I n s t r u c t i o n s :

I f p r o d u c t i s hazy, a d d i t i o n a l I s o p r o p y l A l c o h o l can be used t o c l a r i f y t h e s o l u t i o n . G e n t l y h e a t i n g can be used t o f a c i l i t a t e m i x i n g o f t h e Emcol 4500.

Use I n s t r u c t i o n s :

w ipe o n t o t h e g l a s s . A l l o w t o d r y .

P roduc t I n f o r m a t i o n : P r o d u c t : B e n e f i t : Varox 365 W e t t i n g agen t , deg reaser and d e t e r g e n t Adogen 66 A n t i - s t a t i c agen t Emcol 4500 W e t t i n g agen t , c o u p l e r and d e t e r g e n t

Combine i n g r e d i e n t s i n t h e o r d e r shown and mix t h o r o u g h l y .

App ly f i n i s h e d p r o d u c t t o a t o w e l l e t e (Kimwipe, e t c . ) and

T h i s f o r m u l a t i o n p r e s e n t s a t h i n b a r r i e r between t h e w a t e r vapor ( f o g , steam, e t c . ) and t h e g l a s s wh ich w i l l p r e v e n t f ogg ing . The a b i l i t y t o l o w e r t h e s u r f a c e t e n s i o n o f t h e w a t e r p r e v e n t s t h e c l i n g i n g o f i n d i v i d u a l w a t e r d r o p l e t s t o t h e g l a s s ; t h e r e f o r e l i g h t i s n o t s c a t t e r e d as much as i t i s when p a s s i n g t h r o u g h i n d i v i d u a l d r o p l e t s .

Formula 708

G lass C leaner , Ready t o Use

I n g r e d i e n t s : Water, D . I . P e t r o BAF L i q u i d I s o p r o p a n o l E t h y l e n e G l y c o l Monobuty l E t h e r Dye

B l e n d i ng P rocedure : B l e n d i n g r e d i e n t s i n t h e o r d e r 1 i s t e d . Formula 705

SOURCE: W i t c o Corp. : Suggested F o r m u l a t i o n s

84 .9 0 . 1

1 0 . 0 5 .0 q . s .

Glass CleanerslPolishes 63

Glass C l e a n e r C o n c e n t r a t e (Non-Ammoniated)

I n g r e d i e n t s : Water , D . I. I s o p r o p a n o l , 99% P e t r o LBA Powder Monoethanol ami ne Perfume, Dye

K% 7 . 5

82 .0 1 . o 0 . 5 q. s

B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .

T h i s c o n c e n t r a t e s h o u l d be mixed w i t h n i n e p a r t s of w a t e r t o one p a r t c l e a n e r t o be ready t o use . T h i s p r o d u c t r e q u i r e s a r e d l a b e l .

Formula 702

G l a s s C leaner C o n c e n t r a t e

I n q r e d i e n t s : Water, D . I . P e t r o BAF L i q u i d DeSonic 5 N Ammonia, 29% Dye


Use D i l u t i o n : 1 p a r t c o n c e n t r a t e t o 50 p a r t s w a t e r . Formula 703

Amrnoniated G lass C leaner

m r e d i e n t s : Water W i t c o l a t e 231 0 B u t y l C e l l o s o l ve Aqua Ammonia, 26 Be '

B l e n d i n g Procedure: B lend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Formula 704


Wt% 7 7 . 0 20 .0

1 . o 2 .0 q . s .

Wt% 9 4 . 0

3 . 0 2 . 0 2.0


Glass and Window Cleaner

Carbopol r e s i n s a r e used t o inc rease t h e y i e l d va lue r e s u l t i n g i n v e r t i c a l c l i n g when sprayed on a v e r t i c a l sur face . T h j s "no-dr ip " a c t i o n w i l l i nc rease t h e con tac t t i m e o f t h e de tergent on t h e s o i l e d su r face as w e l l as enhance consumer convenience.

I n a r e d i e n t : D I Water Carbopol ETD 2623 Isopropanol Ammonium hydrox ide Alkylbenzene s u l f o n i c a c i d (97%) (2 ) Propylene g l y c o l methyl e the r (3)

wel 92 * 45

(4.10 5.00 0.20 0 .25 2.00

Phys ica l P roper t i es : Brookf i e l d V i scosi t y (RVT-20 rpm) : 200 cp Product pH: 9.5-10.0 Product C l a r i t y : Clear

Raw Mate r i a1 Suppl i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan Chemical: B i o s o f t 5-100 (3 ) Dow Chemical: Dowanol PM


M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e D I water . Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogeneous.

2 . Add t h e isopropano l . 3 . Add t h e ammonium hydrox ide . M i x u n t i l homogeneous. 4 . Add t h e s u l f o n i c a c i d and g l y c o l e the r w i t h minimal a g i t a t i o n

5 . Add a d d i t i o n a l ammonium hydroxide, i f necessary, t o reach the

6 . Add c o l o r and fragrance, as des i red .

To ta l Ac t i ves :

t o a v o i d excessive foaming.

t a r g e t pH range.

Ammonium alkylbenzene su l fona te : 0 . 3 0 Propylene g l y c o l methyl e the r : 2 .00 Isopropano l : 5.00


Glass CleanerslPolishes 65

Household Window C leaner

I n q r e d i e n t s : Water . D . I . I s o p r o p a n o l Varox 365 Me thy lene B l u e

Wt% 89 .3 1 0 . 0

0 .7 q . s .


each a d d i t i o n .

T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 4 S o l i d s : 0 . 2 % pH: 7 . 4


Formula 706

Bremi u m Household W i ndow C1 eaner

I n g r e d i e n t s : Water , D . I . I s o p r o p a n o l Varox 1770 Methy lene B l u e

Q 89.4 1 0 . 0

0 . 6 q. s

81 end i ng Procedure :

each add i t i on.

T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 4 So l i d s : 0.23% pH: 6 . 2


Formula 707

GI ass @1 eaner

I n g r e d i e n t s : Water . D . I . I s o p r o p a n o l Dowanol EB R e w o t e r i c AM V

Wt% q . s . 6.0 4 . 0 0 .85

81 endi ng Procedure :

ween each a d d i t i o n . Formula 709

SQURCE: W i t c o Gorp . : Suggested F o r m u l a t i o n s

B l e n d i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g t h o r o u g h l y b e t -


W i n d o w s / G l ass

Gl-ass Cl gangr CConcentrate)

I n g r e d i e n t s : Water E t h y l e n e G l y c o l Monobuty l E the r I s o p r o p y l A l c o h o l Ammonia, 29.4% Cal foam SLS-30

Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d F o r m u l a t i o n WIN-001-01

W i n-dzhield Washer C c n c e n t r a t e

Ingredients : Water I s o p r o p y l A l c o h o l Calsuds 81

Comments abou t t h i s f o r m u l a : Use 4 0 2 . o f t h e c o n c e n t r a t e p e r g a l l o n . F o r m u l a t i o n WIN-002-01

W i ndshjeld-pWashec Concen tya te (Low VOC)

I ng r e d i-en t s : Water P r o p y l ene G1 y c o l Calsuds 81

Comments abou t t h i s f o r m u l a Use l e v e l : 2-4 o z p e r g a l l o n . F o r m u l a t i o n WIN-003-01

SOURCE: P i l o t Chemical Co . : Suggested F o r m u l a t i o n s

We i s h t YO 10 .04 21.34 53 .30

2 . 3 5 5 . 0 0

Weigh_% 47.66 47.30

5 .10

We i gh ts/, 62.20 33.80

4.02

ard Surface Cleaners

67


A l k a l i n e Hard S u r f a c e C leaner

I n g r e d i e n t s : Water, D . I . Sodi um Metas i 1 i c a t e Varami de A-83 W i t c o n a t e 30DS W i t c o n a t e SXS L i q u i d

3 4 . 0 8 . 0

1 2 . 0 40.0

8 . 0

81 end ing Procedure:

each a d d i t i on.

T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 205 Sol i ds : 34 .4% pH: 12.5

Formula 516


Hard S u r f a c e CleaEer C o n c e n t r a t e ( A l l Purpose Type)

I n g r e d i e n t s : Water, D . I . T e t r a s p o t a s s i u m Pyrophosphate, Anhydrous W i t cami de 1 PET Emphos 5AP W i t c o 1298SA

\Ne% 8 2 . 0 1 0 . 0

1 . o 4 .0 3 . 0


a d d i t i o n .


B l e n d i n g r e d i e n t s i n o r d e r l i s t e d , m i x i n g w e l l a f t e r each

S p e c i f i c G r a v i t y : 1 .085 Wt . /Ga l . l b s : 9 . 0 4 pH, as i s : 7 .57 V i s c o s i t y , cps : 94 3 Freeze/Thaw c y c l e s : Passed 1 Week @ 52C: Passed 4 Weeks Room Temp: Passed S o l i d s : 17.8% Appearance: C 1 e a r L i q u i d

Use D i l u t i o n : 1-3 o z . / g a l . Formula 540


Hand Surface Cleaners 69

C o n c e n t r a t e d Hard S u r f a c e C l e a n e r

I n g r e d i e n t s : Deodor i zed Kerosene Calamide CWT Cal o x y l a t e N-9 E t h y l e n e G l y c o l Monobuty l E t h e r Water N a4 E DTA Comments abou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 1-2 o z p e r g a l l o n . F o r m u l a t i o n HSC-009-01

Wei qh t% 2 5 . 0 0 16 .30

9 .00 9 . 0 0

41 .30 0.40

Hard S u r f a c e Cleaner-Spray

I n q r e d i e n t s : Wei qh t% Water 86.50 Ammonia, 29% 3 . 0 0 Na4EDTA 0 . 5 0 E t h y l e n e G l y c o l Monobuty l E t h e r 5 . 0 0 Calsuds 81 5.00 Comments abou t t h i s f o r m u l a : 1 . A f t e r a d d i t i o n o f E t h y l e n e G l y c o l Monobuty l E t h e r , t h e

2 . It becomes c l e a r w i t h t h e a d d i t i o n o f Calsuds 81 . m i x t u r e i s c l o u d y .

F o r m u l a t i o n HSC-008-01

P i n e Cleaner

I n q r e d i e n t s : P i n e O i l I PA Calamide CWT Cal o x y l a t e N-9 Cal s o f t LAS-99 Water Comments abou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . Use a t 1-2 o z p e r g a l l o n . F o r m u l a t i o n HSC-004-01

- P i n e C leaner

I n g r e d i e n t s : P i n e O i l Calsuds CD-6 C a l o x y l a t e N-9 I P A Water Comments abou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HSC-007-01

~~~~~~~ P i l o t Chemical Co. : Suggested F o r m u l a t i o n s

Weight% 20.00 10.00

9.00 5 .00 2 . 0 0

54.00

Weight% 15 .00 10.00

8 .00 1 0 . 0 0 57.00

70 Advanced Cleatiing Product Formulations

Hard S u r f a c e Cleanerc

I n g r e d i e n t s : Water Sodi um Metas i 1 i c a t e Na4EDTA Dowanol PnB P i l o t SXS-40 C a l o x y l a t e N-9 P i n e 01 1 Comments about t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d F o r m u l a t i o n HSC-001-01

Hard-Surface-C1 @anex

I n g r e d i e n t s : Water Sodi um Metas i 1 i c a t e Na4EDTA P i l o t SXS-40 Cal i mu1 se PRS Dowanol PnB Cal o x y l a t e N - 9 Comments sbou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HSC-002-01

Hard S u r f a c e Cle&ne_r

I n g r e d i s n t s : Water Sodi um Metas i 1 i c a t e Na4EDTA P i l o t SXS-40 Calamide CWT Comments abou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 1 - 4 o z p e r g a l l o n . F o r m u l a t i o n HSC-005-01

Hardsu.!-33Cs~_ec1 eane r Irns r e d i en t-s 1 Water Sodi um C i t r a t e Soda Ash Ammonia, 29% P i l o t SXS-40 Calamide CWT Comments abou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 2-4 oz p e r g a l l o n . F o r m u l a t i o n HSC-006-01


w e i g h t % 7 5 . 2 5

2 . 0 0 2 . 0 0 6 . 0 0 9 . 0 0 5 . 5 0 0 . 2 5

Wi q h t 9 6 7 4 . 5 0

2 . 0 0 2 . 0 0 7 . 0 0 3 . 0 0 5 . 0 0 6 . 5 0

Weisht_"L. 79.30

5 . 2 0 2 . 5 0 5 . 0 0 8 . 0 0

We i_ph t % 58.50 1 5 . 0 0

5 . 0 0 3 . 5 0 8 . 0 0

1 O . D O

Hand Sqface Cleaners 71

Hard S u r f a c e C leaner w/Amphoter ic

I n q r e d i e n t s : Water, D . I . Sodi um Carbonate Rewote r i c AM KSF-40 Dowanol DPM Versene 100 W i t c o n a t e SXS (40%)

Wt% 75 .0

4 .0 10.0

5.0 2 .0 4.0



Typ i c a l P r o p e r t i es :


V i s c o s i t y , cps : 4 S o l i d s : 10.2% pH: 1 0 . 8

Formula 507

Hard S u r f a c e C leaner C o n c e n t r a t e w/d'Limonene

I n g r e d i e n t s : Phase I: I s o p r o p a n o l O l e i c A c i d .Varoni c K205 d ' L i monene

Phase 11: Water , D . I . Potass ium H y d r o x i d e (87%)

10.0 8.8 5 . 0

12.0

62 .2 2 . 0

B1 end i ng Procedure :

I 1 i n g r e d i e n t s and m ix t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase 11.

T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 75 S o l i d s : 13.8% pH: 1 0 . 2

Formula 508


Combine Phase I i n g r e d i e n t s and m ix t h o r o u g h l y . Combine Phase


Hard S u r f a c e C leaner C o n c e n t r a t e IPhospha te . L i q u i d )

S o i l - F o o d grease, o i l and p r o t e i n , p e t r o l e u m g rease and o i l Su r face -Meta l , ce ramic , p o l y m e r i c , g l a s s A p p l i c a t i o n Method-Wipe, mop o r s p r a y ( d i l u t e d ) Manufacture-Mi x t a n k w i t h p r o p e l 1 e r s t i r r e r

ComDosi t ion A : Water 71.4 TSP 1 . 6 S t a r s o Sodium S i l i c a t e 14.0 Sodium H y d r o x i d e (50%) 4 . 0 *Phosphate E s t e r 5 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C l l ; 6 Moles EO) 2 .8 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 2 . 5 Moles EO) 1 .2

Compos i t i on B : Water TSP S t a r s o Sodi um S i 1 i c a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl1; 6 Moles EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 .5 Moles EO)

Use D i l u t i o n : 3-6% bw (4-8 o z / g a l l o n )

* Rhone-Poulenc Rhodafac RE-600 ** Rhone-Poulenc Rhodasur f 91-6 *** Rhone-Poulenc Rhodasur f A-24

Wt% 6 5 . 4

1 . 6 18.0

5 . 0 6 . 0 2 . 8 1 . 2

Hard S u r f a c e Spray C leaner LPhosphate, L iqu id )

S o i l - F o o d grease, o i l and p r o t e i n , p e t r o l e u m g rease and o i l Sur face -Meta l , ce ramic , p o l y m e r i c , g l a s s A p p l i c a t i o n Method-Spray and wipe Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

W t % Composi t i on : ~- Water 90 .00 TKPP 2.00 N C l e a r Sodium S i l i c a t e 1 . 8 8 Sodium H y d r o x i d e (50%) 0 .12 * D i p r o p y l ene G1 y c o l Monomethyl E t h e r 5 . 0 0 **Octy lphenoxy P o l y e t h o x y e t h a n o l , 12-13 Moles EO 1 .00

Use: As i s , sp ray

* Dow Chemical * * Rhone-Poulenc I g e p a l CA-720


Hand Surface Cleaners 73

Hard Sur face Cleaner Concentrate w/Dipentene

I nnredi en t s : Phase I: Isopropanol O l e i c Ac id Varonic K205 D i pentene

Phase 11: Water, D . I . Potassium Hydroxide (87%)

Wt%

10.0 8 . 8 5 .0

12.0

62.2 2 . 0


I 1 i n g r e d i e n t s and mix thorough ly . Whi le mix ing , add Phase I t o Phase XI ~

T yp i ca l P r o p e r t i e s : V i s c o s i t y , cps: 50 Solids: 13.8% pH: 10.1

Formula 509

Combine Phase I i n g r e d i e n t s and mix thorough ly . Combine Phase

A1 k a l i ne Hard Sur face Cleaner

I n q r e d i en ts : Water, D . I . Sodi um Metasi 1 i c a t e Varami de A-83 \ M i t cona te 3 0 D S W i t cona te SXS L i q u i d

Wt% 62.7

3 . 0 5.0 6 . 8 2 .5



Typ ica l P r o p e r t i e s : V i s c o s i t y , cps: 32 S o l i d s : 1 1 .O% pH: 12.0

Formula 515

SOURCE: Witco Corp.: Suggested Formulat ions

Add i n g r e d i e n t s i n o rder shown and d i s s o l v e comple te ly between


L i q u i d A b r a s i v e C1 eanser

I n q r e d i e n t s : Water, t a p Ca lc ium ca rbona te , 100 mesh Sodium t a l l o w soap, f l a k e s A lpha -S tep MC-48 N i n o l 11-CM Sodi um C h l o r i d e

Wt% 48.5 42.5

2 . 0 2 . 5 2 .0 2 .5

M i x i ng P rocedure :

Add soap and m ix u n t i l d i s p e r s e d . Add MC-48 and 11-CM and m ix u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n .

P r o p e r t i es :

Charge warm w a t e r and add c a l c i u m c a r b o n a t e w h i l e m i x i n g .

Appearance: Opaque, o f f - w h i t e creamy l i q u i d pH, as i s : 9 . 3 V i s c o s i t y @ 25 deg C . : t h i x o t r o p i c

s p i n d l e #3, 6 rpm, B r o o k f i e l d : 4520 cps s p i n d l e #3, 12 rpm, B r o o k f i e l d : 3840 cps s p i n d l e #3, 30 rpm, B r o o k f i e l d : 3060 cps

S o l i d s , % : 50 D e n s i t y , l b s / g a l : 11.69 S t o r a g e a t ambient temp, 1 week: N o s e p a r a t i o n

Use I n s t r u c t i o n s : Use as i s

Per formance:

t i l e s s i m i 1 a r t o commerci a1 p r o d u c t s .

SOURCE: Stepan Co. : F o r m u l a t i o n No. 314

Cleans grease p e n c i l , s c u f f marks and l i p s t i c k f r o m v i n y l

T i l e and Sani t a r v C l e a n e r s

I n q r e d i e n t s : Zusol a t 1008/85 Water Xanthan Gum C i t r i c a c i d

I n q r e d i e n t s : Amphotensid B 4 Water C i t r i c a c i d

Wt% 5 . 0

7 9 . 6 0 . 4

1 5 . 0

Wt% 3 0 . 0 6 0 . 0 1 0 . 0

SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested F o r m u l a t i o n s CT 02-10-03 and CT 02-10-04

Hand Sutface Cleaners 75

L i q u i d Hard S u r f a c e C leaner

I n g r e d i e n t s : Wt%* A : Van Gel ES, Magnesium Aluminum S i l i c a t e 4.00

Rhodopol 23, Xanthan Gum 0 .50 D e i o n i z e d Water 68.50

0 : Cocamide DEA (Monamid 150-ADD) A1 k o x y l a t e d F a t t y A l c o h o l (P1 u r a f a c C-17) T e t r a p o t a s s i um Pyrophosphate Potass ium Phosphate T r i b a s i c D e i o n i z e d Water

0 .50 2 .50 1 .25 0 . 7 5

21 .oo

C: Ammonium Hydrox ide , 28% 1 . o o

Procedure: 1 . D ry b l e n d t h e Van Gel ES and Rhodopol 23 and s l o w l y add them

t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 r p m . C o n t i n u e m i x i n g f o r 40 m i n u t e s .

2. Combine t h e P a r t B i n g r e d i e n t s w i t h s l o w s t i r r i n g . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o

4. Add P a r t I3 t o P a r t A, mix f o r 5 m i n u t e s and t h e n add P a r t C


produce a s l i g h t v o r t e x .

and m i x f o r 5 m i n u t e s .

Hard S u r f a c e C l e a n e r - A l l Purpose

I n g r e d i e n t s : A : Veegum, Magnesi um A1 umi num S i 1 i c a t e

Rhodopol 23, Xanthan Gum D e i o n i z e d Water

W t .%* 1 .20 0 .40

48.40

B : Ca lc ium Carbonate 40.00

C : C12-CI3 L i n e a r P r imary A l c o h o l E t h o x y l a t e (Neodol 23-6.5)

Cocamide DEA ( N i n o l 40-CO) P r e s e r v a t i v e , Dye, F rag rance

9.00 1 .oo q . s .

Procedure : 1 . Dry b l e n d t h e Veegum and Rhodopol 23 and s l o w l y add t h e b l e n d

t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 rpm. C o n t i n u e m i x i n g f o r 20 m i n u t e s .

2 . Add P a r t B and m ix f o r 10 m inu tes . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o

4. Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5

F o r m u l a t i o n f r o m S h e l l Chemical Co.

p roduce a s l i g h t v o r t e x .

m i n u t e s a f t e r each a d d i t i o n .

AS r e c e i v e d b a s i s

SOURCE: R.T. V a n d e r b i l t Co., I n c . : Van Gel and Veegum i n Hard S u r f a c e C leaners and Pol i s h e s : Suggested F o r m u l a t i o n s


Mold and Mildew Remover

Carbopol r e s i n s a r e used t o reduce sp lash ing and t o p r o v i d e v e r t i c a l c l i n g when sprayed on a v e r t i c a l su r face . Th is "no-dr ip " a c t i o n w i l l i nc rease t h e con tac t t i m e o f t h e de te r - gent on t h e s o i l e d su r face and enhance consumer convenience.

I n p r e d i e n t : D I water Carbopol 672 ( 1 ) Sodium hydrox ide (50%) Sodium m e t a s i l i c a t e , pentahydrate Pr imary alkane s u l f o n a t e (40%) ( 2 ) Sodium h y p o c h l o r i t e (15.00%)

\Rlt% 84.50

1 . 0 0 2 . 0 0 0 . 5 0 5 . 0 0 7.00

Brookf i e l d v i scosi t y (RVT-PO rpm) : 120 cps Product pH: 12-13 Product c l a r i t y : Opaque

( 1 ) BFGoodrich ( 2 ) Stepan Co.: Bio-Terge PAS-8S

Procedure : 1 . Using moderate a g i t a t i o n (800 rpm) p rov ided by a L i g h t n i n '

Mixer or s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m i x i ng and b l endi ng opera t i ons , d i sperse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogeneous.

m e t a s i l i c a t e . 2. Under moderate a g i t a t i o n , add t h e sodium hydrox ide and t h e

3. Add t h e alkane su l fona te . 4. Under low a g i t a t i o n , add t h e sodium h y p o c h l o r i t e b leach. 5 . Add c o l o r and f ragrance, as des i red .

To ta l Ac t i ves : Pr imary alkane su l fona te : 2.0 A v a i l a b l e c h l o r i n e : 1 . 0


Laundry Products

77


D e t e r g e n t f o r F i n e F a b r i c s - 1 Powder

I n p r e d i e n t s : Genapol OA-080 DDBS-Na* Thermphos NW T a l l o w soap, Powder Sodi um d i s i 1 i c a t e Sokalan CP 5 Sokalan HP 22 A q u a m o l l i n BC Powder Perfume Sodi um s u l p h a t e

Q 3.0 15.0 25.0

1 .O-3.0 3.0 1 . o 1 . o 0.5 q.s.

ad 1 0 0 . 0


b e employed i n f o r m o f a sp ray d r i e d powder. DDBS-Na p a s t e i s n o t s u i t a b l e .

To be p r e p a r e d by s p r a y mix p rocess . T h e r e f o r e DDBS-Na must

*DDBS=Dodecyl Benzene Su lphona te

D e t e r g e n t f o r F i n e F a b r i c s - 2 Powder

I n q r e d i e n t s : Genapol OA-080 DDBS-Na* Z e o l i t h A ( W e s s a l i t h T a l l o w soap, Powder Sodi um d i s i 1 i c a t e Soka lan CP 5 Sokalan HP 22 Aquamoll i n BC Powder Perfume Sodium s u l p h a t e

Wt% 3.0 15.0

20.0-25.0 1.0- 3.0

3.0 2.0- 3.0

1 . o 0.5 q . s .

ad 100.0


be employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s n o t s u i t a b l e .

To be p r e p a r e d by s p r a y mix p r o c e s s . T h e r e f o r e DDBS-Na must

*DDBS=Dodecyl Benzene Sul f o n a t e


Laundry Products 79

Heavy Duty Laundry

I n g r e d i e n t s : Wei q h t % Water 28.90 Sodi um Hydrox ide , 50% 6.60 Calamide C 7.00 Pi l o t SXS-40 12.50 Cal s o f t LAS-99 40 .00 Cal o x y l a t e N-9 5 . 0 0 Comments about t h i s f o r m u l a : Add C a l o x y l a t e N-9 a f t e r 50% o f LAS-99 has been n e u t r a l i z e d .

F o r m u l a t i o n HDL-001-01

Heavy Duty Laundry

I n q r e d i e n t s : Water P i l o t SXS-40 Calamide CWT Sodium S i l i c a t e ( S o l i d ) C a l s o f t L-60 EDTA (Ethylenediaminetetraacetic A c i d ) Comments about t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HDL-006-01

Heavv Duty Laundry

I nqred i e n t s : Water C a l f a x DB-45 C a l o x y l a t e N-9 P r o p y l ene G1 y c o l TKPP ( T e t r a P o t a s s i um Pyrophosphate) Comments about t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HDL-007-01

Wei oh t% 42.50 22.50

4.00 3 .01

18.00 2 . 5 0

Weight% 78.50

7 .00 7 .00 2 . 5 0 5 .00

Heavv Duty Laundry

I n q r e d i e n t s : Wei q h t % Water 42.00 TKPP ( T e t r a Potass ium Pyrophosphate) 15.00 Sodium S i l i c a t e ( S o l i d ) 10 .00 C a l s o f t L-60 18.00 P i l o t SXS-40 10.00 Calamide CWT 5 . 0 0 Comments about t h i s f o r m u l a :

May need t o be heated t o s o l u b i l i z e t h e s u r f a c t a n t . F o r m u l a t i o n HDL-008-01

SOURCE: P i 1 o t Chemical Co. : Suggested Formul a t i ons


I & I L i q u i d Laundrv D e t e r g e n t w i t h Enzyme & O p t i c a l

Components: Water T r i e t h a n o l ami ne 85% D i e t h y l ene G1 y c o l B u r c o l 117 B u r c o l LAF-6 Burcowi t e BBH-PO Burco tase SL-160

% by Weisht 50 .00

3 . 2 5 20.00 1 0 . 0 0 10 .00

1 . 2 5 0.50

Burco LAF-6 i s used t o c o n t r o l foam as w e l l as t o p r o v i d e w e t t i n g and d e t e r g e n c y .

P rocedure : Charge 1 /2 o f w a t e r I3 120F. Add 1 ,2 ,3 , & 4 and b l e n d . Add

r e m a i n i n g w a t e r . Cool t o 1OOF. Add 5 and 6 . B lend u n t i l u n i f o r m .

1% pH: 9 . 5 % s o l i d s : 26 Lbs /ga l : 8 . 6 6

S u r f a c t a n t R i c h D e t e r g e n t f o r N u r s i n o Homes

I n g r e d i e n t s : Water TKPP Sodium M e t a s i l i c a t e Pen tahyd ra te B u r c o t e r g e DG-40 Burco NPS-876 SXS-40%

% bv Weiqht 30

5 5

40 10 10

6-8 ounces p e r 100 pounds o f l a u n d r y . Heavy s o i l s may r e q u i r e s l i g h t l y h i g h e r l e v e l s .

SOURCE: B u r l i n g t o n Chemical Co.: Suggested F o r m u l a t i o n s

Powder f o r A u t o m a t i c D ishwash inn Machines

I n g r e d i e n t s : A Genapol 2908 B Sodium metas i 1 i c a t e x 5H20 C Sodium c a r b o n a t e

Sodi um d i c h l o r o i socyanura te Thermphos NW

YO by Weiqht 1 . o o

52.00 10 .00

2 . 0 0 35.00

M a n u f a c t u r i n g : I Spray A on B . I 1 One a f t e r a n o t h e r , t h e components o f C a r e added t o 1 A p p l i c a t i o n : 1-29 d e t e r g e n t / L d i shwash ing l i q u o r


Laundry Products 81

IndustriaT Heavy Duty Laundry L i q u i d

Carbopol ETD 2691 is t o p rov ide product phase s t a b i l i z a t i o n i n t h i s h igh a l k a l i n i t y i n d u s t r i a l s t reng th c leaner .

I nsred i en t : D I water Carbopol ETD 2691 ( 1 ) 612-15 l i n e a r a lcoho l , 7 moles EO ( 2 ) Sodium alkylbenzene su l fona te (60%) ( 3 ) Potassium hydrox ide (45%) Sodium m e t a s i l i c a t e , anhydrous Tetrapotassium pyrophosphate

Wt% 49.00

0.50 18.00 5.50 2 .00 5.00

20.00

Phys ica l Pi-opert i es: B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 900 Product pH: 14 Product C l a r i t y : Opaque

Raw M a t e r i a l Supp l i e rs : (1 ) BFGoodrich ( 2 ) S h e l l Chemical Co.: Neodol 25-7 ( 3 ) Stepan Co.: B i o s o f t D-62

PP.0cedure: I . Use a b i g h t n i n ' Mixer o r s i m i l a r v a r i a b l e speed u n i t and an

i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions . Screen t h e Carbopol r e s i n i n t o t h e vo r tex o f t h e r a p i d l y a g i t a t i n g water (800 rpm). Al low t o mix u n t i l homogeneous and f r e e o f polymer lumps.

benzene su l fona te s u r f a c t a n t s .

s i l i c a t e .

entrapment.

2 . Wi th s low mixing, add i n t h e a lcoho l e thoxy la te and a l k y l -

3 . Continue a g i t a t i n g and add t h e potassium hydroxide and meta-

4. Add i n t h e pyrophosphate w i t h minimal a g i t a t i o n t o avo id a i r

5. Add dyes and fragrance, as des i red .

Total Wcti ves : Sodi um a1 k y l benzene sul fona te : 3 .30 C12-15 l i n e a r a l coho l , 7 moles EO: 18.00 Tetrapotassium pyrophosphate: 20.00



I n d u s t r i a l Laundry Deteraents High Caust ic Formula-

Components: Burco NPS-816 Burcosperse LP B u r c o l i t e BSGH-255 Dequest 2000 50% NaOH

% bv Weiaht 15 .0 10 .0 5 .0 5 . 0

65.0

Procedure:

a g i t a t i o n . Keep temperature below 160F du r ing t h e e n t i r e a g i t a t i o n .

Blend a l l components except 50% NaOH. S lowly add NaOH w i t h

Mixed B u i l d e r Formula t ion

Components: Water 45% KOH Burcosperse LP TKPP Burco NPS-816 S ta r Grade Sodium S i l i c a t e

% by Weight 3 1 . 5 2 3 . 5 1 0 . 0 1 0 . 0 1 5 . 0 1 0 . 0

Procedure: D isso lve KOH i n water . S lowly add Burcosperse LP w h i l e

a g i t a t i n g . Keep temperature below 160F. Add TKPP and s t i r u n t i l d i sso l ved . Add Burco NPS-816, then S t a r Grade Sodium S i l i c a t e and b lend u n t i l un i fo rm.

Use l e v e l s a re 6-12 ounces per 100 pounds, depending on s o i l load ing , temperature, e t c .

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ions

Washi np Paste w i t h 81 eachi n g A g e n t

I n g r e d i e n t s : Water Sodium t r i po l yphospha te Sodium d i t h i o n i t Xanthan Gum Whi t e - s p i r i t Lumorol 4154 Zusol a t 1005/85

% by Weiaht 39 .0

3 . 0 12.0 2 . 0

1 0 . 0 30 .0

5 . 0

SOURCE: Zschimmer & Schwarz GmbH & Co.: Formula t ion CT 07-06-01

Laundry Products 83

Laundry Deteraent-Consumer ( L i q u i d )

S o i l - B o d y o i l and p e r s p i r a t i o n , body waste. make-up, f o o d s o i l S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n Method-Household washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Compos i t i on : Water F l u o r e s c e n t B r i g h t e n e r C a r b o x y m e t h y l c e l l u l o s e (CMC) * A c r y s o l A S E - I 08 **Nonylphenoxy P o l y e t h o x y e t h a n o l Potass ium H y d r o x i d e (45%) ***Sodium C i t r a t e (and /o r C i t r i c K a s i l #6 Potass ium S i l i c a t e EDTA Enzymes ( P r o t e a s e )

Wt% 37 .6

0 . 2 0 . 5 6 .0

, 9-10 Moles €0 10.0 2 .2

A c i d ) 25 .0 1 2 . 5

5 . 0 1 . o

x( Rohm & Haas; o r Rhone-Poulenc C o l l o i d 225/35 P o l y a c r y l a t e

* * Rhone-Poul enc I g e p a l CO-630 *** A d j u s t p H w i t h c i t r i c a c i d t o m a i n t a i n pH f o r e f f e c t i v e

(40%)

enzyme pe r fo rmance ( i . e . 8 . 5 - 9 . 5 pH).

Laundry Detergent-Consumer I Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d )

S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, food s o i l , make-up S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r A p p l i c a t i o n Method-Household washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Compos i t i on : Water Carbopol 674 D L i q u i d Sodium S i l i c a t e *Acusol 445ND Sodium P o l y a c r y l a t e Sodium Carbonate V a l f o r 100 Z e o l i t e A * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-

Wt% 5 2 . 6

0 . 5 8 . 1

(92% s o l i d s ) 0 .9 9 . 1

24.5 .13, EO 6 . 5 Mo les ) 4 . 3

t: Rohm & Haas ** S h e l l Chemical Neodol 23-6.5

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a r y Guide


Laundry Detergent-Consumer (Zero Phosphate, Powder)

S o i l - A c i d i c food f a t , o i l grease, blood, sebum and body waste Surface-Cotton and co t ton -po lyes te r A p p l i c a t i o n Method-Household Washing Machine Manufacture-Dry Blend/Agglomeration

Composit ion: Sodi um Carbonate B r i t e s i l H20 Hydrous P o l y s i l i c a t e *Acusol 445ND Sodium Po lyac ry la te (92% s o l i d s ) * *L inear A1 k y l benzene Sul f ona te (LAS) * * * L i q u i d Nonionic Sur fac tan t (7-9 moles EO; C12-15) V a l f o r 100 Z e o l i t e A Sodi um S u l f a t e O p t i c a l B r igh tener , Perfume

Use Level : 1000 ppm detergent d e l i v e r e d t o wash ( 1 gram d e t e r g e n t / l i t e r o f water )

* Rohm & Haas

Wt9/o 30.0 10.0

2 . 0 1 0 . 0

5 . 0 3 0 . 0 1 2 . 5 0.5

** Stepan Nacconol 9OG (90% a c t i v e ; powder) *** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

Laundry Detergent-Consumer (Phosphate, Powder)

S o i l - A c i d i c food f a t and p r o t e i n , body p e r s p i r a t i o n , grass and

Sur face-Po lyes ter , co t ton /po lyes te r , c o t t o n A p p l i c a t i o n Method-Household washing machine Manufacture-Dry blend/agglomerat ion

d i r t

Composi t i on : B r i t e s i l H20 Hydrous P o l y s i l i c a t e *STPP *Sodium Carbonate Sodi um S u l f a t e * *L inear A1 k y l benzene Sul f ona te (LAS) * * *L iqu id Nonionic Sur fac tan t (7-9 Moles EO; C12-15) O p t i c a l B r igh tener , Perfume

Q 1 0 . 0 30 .0 30.0 14.5 1 0 . 0 5.0 0.5

Use Leve l : 1000 ppm detergent d e l i v e r e d t o wash ( 1 g r a m / l i t e r o f water )

* FMC ** Stepan Nacconol 90G (90% a c t i v e ; powder) *** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Co. Neodol 25-7

SOURCE: PQ Corp.: Detergent Formula t ion Guide

Laundry Products 85

Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l ( L i q u i d , Phosphate1

S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body

S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

was te

Compos i t i on A : Water TKPP P o t a s s i urn H y d r o x i d e (45%) S t a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%)

Compos i t i on B: Water TKPP Po tass ium H y d r o x i d e (45%) S t a r Sodi um S i 1 i c a t e Sodium H y d r o x i d e (50%)

3 4 . 1 1 0 . 0 30 .4 1 8 . 0

7 .5

wts/, 25 .6 10 .0 30.4 24.0 10 .0

Use D i l u t i o n : L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 100 l b s 1 aundry

Medium t o Heavy S o i l : 0.25%-0.50% by w e i g h t o r 1-2

No te : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t l b s p e r 100 l b s l a u n d r y

( u n b u i l t ) a t 2-4 p a r t s o f b u i l d e r t o 1 p a r t d e t e r g e n t .

Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l ( L i q u i d )

S o i l - P e t r o l e u m o i l and grease, g r a p h i t e and c o l o r e d p igment S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Compos i t i on : Water N C l e a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%)

% 0-20

70-90 10-20

Use D i l u t i o n : L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 100 l b s

Medium/Heavy S o i l : 0.25%-0.50% by w e i g h t o r 1-2 1 aundry

l b s p e r 100 l b s l a u n d r y No tes : B l e n d t h i s b u i l d e r s o l u t i o n t o 1 . 7 - 2 . 0 r a t i o S i02 /Na20 b w

f o r b e s t s t a b i l i t y and i n d u s t r i a l de te rgency . D o r BJ-120 sodium s i l i c a t e s can a l s o be used as b u i l d e r s o l u t i o n s w i t h o u t b l e n d i n g . Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t .


86 Advanced Cleaning Product Formulatiom

Laundry D e t e r s e n t - I n d u s t r i a l & I n s t i t u t i o n a l (NTA/Zeol i t e , P o w d e d


S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

was te

Composi t i on : Metso Beads 2048 25 .0 Sodi um Carbonate 3 8 . 0 NTA 1 5 . 0 * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 12.0 V a l f o r 100 Z e o l i t e A 10 .0

Use L e v e l : L i g h t Soi l -O.25% by w e i g h t o r 1 l b p e r 100 l b s 1 aundry

Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s

Heavy S o i l - 0 . 7 5 % by w e i g h t o r 3 l b s p e r 100 l b s 1 aundry

1 aundry

No te : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y or f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n - c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

* Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

Laundry B r e a k - I n d u s t r i a1 & I n s t i t u t i o n a l ( Z e r o Phosphate, Powder)

S o i l - P e t r o l e u m o i l and grease, g r a p h i t e and c o l o r e d p igment S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Use as r e c e i v e d

Composi t i on : Metso Beads 2048

Wt46 100.0

Use D i l u t i o n : L i g h t Soi l -O.25% by w e i g h t o r 1 l b p e r 100 l b s 1 aundry

Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s 1 aundry-

Heavy So i l -O .75% by w e i g h t o r 3 l b s p e r 100 I b s 1 aundry

Note: Use i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s b w o f b u i l d e r w i t h 1 p a r t d e t e r g e n t .

SOURCE: PQ Corp. : Detergent Formula t ion Guide

Laundqi Products 87

Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Phosphate, Powder)

S o i l - A c i d i c f o o d f a t , o i l and grease; b lood, sebum and body

Sur face-Cot ton and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry b lend/Agg lomera t ion

waste

Compos i t ion : WtO/o Metso Beads 2048 25.0 *Sodium Carbonate 35.0 *STPP 30.0

Use Leve l : L i g h t Soi 1-0.25% by we igh t or 1 l b p e r 100 l b s l a u n d r y * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 1 0 . 0

Medium So i l -O.50% by we igh t o r 2 l b s p e r 100 l b s

Heavy Soi l -O.75% b y w e i g h t o r 3 l b s p e r 100 l b s 1 aundry

1 aundry Note: Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y

o r f u l l y , i f lower a l k a l i n i t y i s d e s i r e d and more suspend- i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adosrbency o f d e t e r g e n t b l e n d .

x< FMC ** Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r


Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Sodium Carbonate, Powder)


Sur face-Cot ton and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry b lend/Agg lomera t ion

waste

Composi t i on : Q Metso Beads 2048 25.0 Sodium Carbonate 55.0 Sodi um S u l f a t e 10.0 * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 1 0 . 0 Use Leve l : L i g h t Soi 1-0.25% by we igh t o r 1 l b p e r 100 l b s l a u n d r y

Medium S o i l - 0 . 5 0 % by we igh t o r 2 l b s p e r 100 l b s

Heavy Soi l -O.75% by w e i g h t o r 3 l b s p e r 100 l b s 1 aundry

1 aundry Note: Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r

f u l l y , i f lower a l k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n - c rease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

'k Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

SQURCE: PQ G o r p . : Detergent F o r m u l a t i o n Guide


Laundry B reak - Indus t r i a l & I n s t i t u t i o n a l (Phosphate. Powder, High A l k a l i n i t y )

S o i l - A c i d i c food f a t , o i l and grease; blood, sebum and body

Surface-Cotton and co t ton /po lyes te r A p p l i c a t i o n Method- Indus t r ia l washing machine Manufacture-Dry b l end/Agglomeration

waste

Composit ion A : Metso Beads 2048

Wt% 6 0 . 0

Sodium Hydroxide Beads 40 .0 Composit ion 8: Wt% Metso Beads 2048 30 .0 *STPP 2 0 . 0 *Sodium Carbonate 2 8 . 0 Carboxymethy lce l lu lose 2 .0 Sodium Hydroxide Beads 2 0 . 0 Use D i l u t i o n : L i g h t So i l -0 .25% by weight o r 1 l b per 100 l b s

1 aundry Medium So i l -0 .50% by weight o r 2 l b s per 100 I b s 1 aundry Heavy So i l -0 .75% by weight o r 3 l b s pe r 1 0 0 lbs 1 aundry

Note: Use these a l k a l i b u i l d e r s i n con junc t i on w i t h laundry de tergent ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r w i t h 1 p a r t de tergent

* FMC

Laundrv B reak - Indus t r i a1 8, I n s t i t u t i o n a l (Zero Phosphate Powder, H i ah A1 k a l i n i t v )


Surface-Cotton and co t ton /po lyes te r A p p l i c a t i o n Method- Indus t r ia l washing machine Manufacture-Dry blend/Agglomerat ion

waste

Composi t i on A : Wt% Metso Beads 2048 6 0 . 0 Sodium Hydroxide Beads 4 0 . 0 Composit ion 8: W S Metso Beads 2048 3 0 . 0 Sodi um Carbonate 28.0 Carboxymethylcel l u l o s e 2.0 Sodium Hydroxide Beads 2 0 . 0 V a l f o r 100 Z e o l i t e A 20.0 Use Leve l : L i g h t So i l -0 .25% by weight o r 1 l b per 100 l b s laundry

Medium So i l -0 .50% by weight o r 2 l b s per 100 I b s 1 aundry

Heavy Soi l -O.75% by weight o r 3 l b s per 1 aundry

Note: Use these a l k a l i b u i l d e r s i n con junc t i on w i t h e rgent ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r w de tergent

SOURCE: PQ C o r p . : Detergent Formula t ion Guide

00 l b s

laundry de t - t h 1 p a r t

Laundry Products 89

Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Reduced Phosphate, Powder)


S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

was te

Compos i t i on : Wt% Metso Beads 2048 25.0 *Sodium Carbonate 35 .0 *STPP 2 0 . 0 % * L i q u i d N o n i o n i c S u r f a c t a n t (7 -9 moles EO; C12-15) 10.0 V a l f o r 100 Z e o l i t e A 10 .0 Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y

Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s

Heavy So i l -O .75% by w e i g h t o r 3 l b s p e r 100 l b s 1 aundry

1 aundry No te : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y

o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspend- i ng /emu ls i f y i ng power i s needed. B r i t e s i 1 H20 w i 11 a1 so i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

96 FMC dc* Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r


Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l (NTA, Powder)


S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washi ng machine Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

waste

Composi ti on : Wt% Metso Beads 2048 25.0 Sodium Carbonate 40.0 NTA 25.0

Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 1 0 . 0

Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s


1 aundry No te : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r

f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l also i n - c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

*Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

SOURCE: PQ C s r p . : D e t e r g e n t F o r m u l a t i o n Guide


Laundry De te rqen t - Indus t r i a l B I n s t i t u t i o n a l (Sodium Carbonate w i t h Flow A i d . Powder)


Surface-Cotton and co t ton /po lyes te r Appl i c a t i on Method-I ndust r i a1 wash i ng mach i ne Manufacture-Dry blend/agglomerat ion

waste

Composi t i on : Wt% Metso Beads 2048 20.0 Sodium Carbonate 55.0 Sodi um S u l f a t e 10 .0 * L i q u i d Non ion ic Sur fac tan t (7-9 moles EO; C 1 2 - 1 5 ) 1 0 . 0 V a l f o r 100 Z e o l i t e A 5 . 0

Use Leve l : L i g h t S o i l : 0.25% by weight o r 1 l b per 100 l b s 1 aundry

Medium S o i l : 0 .50% by weight o r 2 l b s per 100 l b s

Heavy S o i l : 0.75% by weight o r 3 l b s per 100 l b s 1 aundry

1 aundry

Note: Use B r i t e s i l H20 i n p lace o f Metso Beads 2048, p a r t i a l l y o r f u l l y , i f lower a l k a l i n i t y i s des i red and more suspend ing /emuls i fy ing power i s needed. B r i t e s i l H20 w i l l a l s o inc rease t h e s u r f a c t a n t adsorbency o f de tergent b lend.

* Rhone-Poulenc Rhodasurf LA-7 o r LA-9 or She l l Chemical Neodol 25-7

Laundry De te rgan t - Indus t r i a l & I n s t i t u t i o n a l IPhosphate, S o l i d Block)


Surface-Cotton and co t ton /po lyes te r A p p l i c a t i o n Method-Industr i a1 washing machine Manufacture-Sol i d b lock

waste

Composi t i on : Metso Beads 2048 NaOH (50% S o l u t i o n ) *STPP *Sodium Carbonate * *L iqu id Nonionic Sur fac tan t (7-9 Moles EO; C12-15)

* FMC ** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r


SOURCE: PQ Corp.: Detergent Formula t ion Guide

Wt% 2 5 . 0 2 5 . 0 3 5 . 0 12.0 3.0

Laundry Products 91

Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l (Zero Phosphate, Powder)

S o i l - A c i d i c f o o d f a t , o i l grease, b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -Dry B lend /Agg lomera t i on

Compos i t i on : Wt% Sodi um Carbonate 35 .0 * L i q u i d N o n i o n i c S u r f a c t a n t (7 -9 moles €0; C12-15) 15.0 V a l f o r 100 Z e o l i t e A 2 5 . 0 Metso Beads 2048 25.0 Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y

Medium So i l -O .50% by w e i g h t o r 2 l b s p e r 100 l b s



f u l l y , i f l o w e r a1 k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g powder i s needed. B r i t e s i l H20 w i l l a l s o i n - c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

*Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l ( Z e r o Phosphate, Powder)

S o i l - P e t r o l e u m o i l and grease, g r a p h i t e and c o l o r e d p igment S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry B1 end/Aggl omera t i on

Composi t i on : Wt% Sodium Carbonate 4 4 . 5 * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 18.0 V a l f o r 100 Z e o l i t e A 3 0 . 0 **Acusol 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 2 . 5 Metso Beads 2048 5 . 0 Use L e v e l : L i g h t S o i 1-0.25% by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y

Medium So i l -O .50% b y w e i g h t o r 2 l b s p e r 100 l b s

Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1 aundry


f u l l y , i f lower a l k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n - c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

** Rohm & Haas

SOURCE: PQ Corp. : De te rgen t F o r m u l a t i o n Guide


Laundry D e t e r q e n t - I n d u s t r i a l & I n s t i t u t i o n a l [Phosphate Bu i 1 t , L i q u i d )

S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, make-up, f o o d s o i l Su r face -Co t ton and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Compos i t i on A : Water TKPP Potass ium H y d r o x i d e (45%) S t a r s o Sodium S i l i c a t e Sodi um H v d r o x i d e ( 5 0 % )

Wt% 5 4 . 5

4 . 6 1 3 . 7 1 5 . 0

4 . 2 , . *PhosphaGe E s t e r 5 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 7-9 Moles € 0 ) 3 . 0

Compos i t i on B: Wt% Water 5 9 . 1 Potass ium H y d r o x i d e (45%) 13 .7 S t a r s o Sodi um S i 1 i c a t e 1 5 . 0 Sodium H y d r o x i d e (50%) 4 . 2 *Phosphate E s t e r 5 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 9 Moles EO) 3 . 0 Use D i l u t i o n : 0 .25%-0.50% by w e i g h t or 1-2 l b s p e r 100 l b s

* Rhone-Poulenc Rhodafac RE-610 ** Rhone-Poulenc Rhodasur f LA-7 o r LA-9

1 aundry

Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l ( L i quid)

Soi 1-Body o i 1 and p e r s p i r a t i o n , body waste, make-up, f o o d s o i 1 S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

Compos i t i on : Water

wts/, 2 8 . 7

F1 u o r e s c e n t B r i g h t e n e r 0 . 1

**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-1 0 Moles EO 10 .0 P o t a s s i um H y d r o x i d e (45%) 2 . 2

C a r b o x y m e t h y l c e l l u l o s e (CMC) 0 . 5 * A c r y s o l ASE-108 ( A c r y l i c Polymer) 6 . 0

TKPP (60%) 40 .0 Kasi 1 #6 P o t a s s i um S i 1 i c a t e 1 2 . 5 Use D i l u t i i o n : 0.25%-0.50% by w e i g h t or 1-2 l b s p e r 100 I b s

* Rohm & Haas; or Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%) **Rhone-Poulenc I g e p a l CO-630

SOURCE: PQ Corp . : D e t e r g e n t Fo rmu la ry Guide

1 aundry

Laundry Products 93

Laundry B u i l d e r - I n d u s t r i a l & I n s t i t u t i o n a l ( L i q u i d )

S o i l - A c i d i c food, f a t , o i l and grease; b lood, sebum and body

S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

waste

Composi t ion A : Potass ium Hydrox ide (45%) iU C l e a r o r E Sodium S i l i c a t e

Compos i t ion B: Water Potass ium Hydrox ide ( S o l i d ) N C l e a r or E Sodium S i l i c a t e

Compos i t ion C : Water Potass ium Hydrox ide ( S o l i d ) N C l e a r o r E Sodium S i l i c a t e Sodium Hydrox ide ( S o l i d )

Wt% 35-45 55-65

Wt% 1 1 . 0 37 .0 52.0

Wt% 6 . 0

28.0 52 .0 1 4 . 0

Use D i l u t i o n : L i g h t S o i l : 0.25% by we igh t o r 1 l b p e r 100 l b s 1 aundry

Medium t o Heavy S o i l : 0.25%-0.50% by we igh t o r 1-2 l b s p e r 100 l b s l a u n d r y

Note: Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t

Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l ( Z e o l i t e B u i l t , Zero Phosphate, L i q u i d )

So i l -Body o i l and p e r s p i r a t i o n , body waste, f o o d s o i l , make-up Sur face-Cot ton and. c o t t o n - p o l y e s t e r - A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing Manufacture-Mix t a n k w i t h p r o p e l l e r s t

Compos i t ion : Water Carbopol 674 Metso Beads 2048 *Acusol 445N Sodi um P o l y a c r y Sodium Carbonate V a l f o r 100 Z e o l i t e A * * L i q u i d N o n i o n i c S u r f a c t a n t

8 Rohm 8: Haas

a t e (45% s o l

a c h i ne r r e r

d s )

WtO/o 57.06

0 .5 2 . 7 1 . 0 4 9 . 1

24.5 (C12-13; EO 6 . 5 Moles) 4 . 3

* * S h e l l Chemical Neodol 23-6.5

SOURCE: PQ Corp. : Detergent F o r m u l a t i o n Guide


Laundry Presoot te r Sprayable Gel

Carbopol ETD 2623 i s used i n t h i s fo rmu la t i on t o cos t e f f e c - t i v e l y t h i c k e n t h e su r fac tan t system i n t o a ge l form - which can be app l i ed t o t h e f a b r i c by brush o r sprayed on due to Carbopal 's shear t h i n n i n g na ture .

I na red i en t : D I water Carbopol ETD 2623 ( 1 ) C12-15 l i n e a r a l coho l , 3 moles €0 (2 ) C12-13 l i n e a r a lcoho l , 6 . 5 males €0 (3 ) EDTA ( t e t r a sodium s a l t ) Sodium hydrox ide (18%)

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 8,300 cps Product pH: 7.0-8.0 Product c l a r i t y : Opaque

(1) BFGoodrich (2 ) She l l Chemical Co.: Neodol 25-3 (3) She l l Chemical C o . : Neodol 23-6.5

83.75 0.20

10.00 5.00 0.50 0.55

1.

2.

3. 4 . 5.

Procedure: Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n ' Mixer o r s i m i l a r v a r i a b l e speed u n i t and an impe l l e r s u i t a b l e f o r general m i x i ng and b lend ing opera t ions , d isperse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approximately 15 minutes o r u n t i l t h e s l u r r y i s homogeneous. Add i n bo th o f t h e a lcoho l e thoxy la te su r fac tan ts . Mix u n t i l homogeneous. Add i n t h e EDTA. Add i n t h e sodium hydroxide u n t i l t h e pH i s a t t a i n e d . Add c o l o r and fragrance, as des i red .

To ta l Ac t i ves : C12-15 l i n e a r a l coho l , 3 moles EO ( 2 ) : 10.0 C12-13 l i n e a r a lcoho l , 6.5 moles EO (3 ) : 5.0


Laundry Products 95

Laundry Presootter Sorayable Liquid

Carbopol ETD 2623 i s used i n t h i s f o r m u l a t i o n t o s l i g h t l y t h i c k e n t h e s u r f a c t a n t system and enable the produc t t o s tay i n con tac t w i t h t h e s o i l longer by reduc ing seepage through t h e f a b r i c .

I n s r e d i en t : D I water Carbopol ETO 2623 ( 1 ) C12-15 l i n e a r a l coho l , 3 moles €0 ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 moles €0 ( 3 ) EOTA ( t e t r a sodium s a l t ) Sodi um hydrox ide (18%)

Wt% 84.30

0.05 10.00

5 . 0 0 0 .50 0 . 1 5

B rook f i e l d v i s c o s i t y (RVT-20 rpm) : 250 cps Product pH: 7.0-8.0 Product c l a r i t y : Opaque

( 1 ) BFGoodri ch ( 2 ) S h e l l Chemical Co.: Neodol 25-3 ( 3 ) She l l Chemical Co.: Neodol 23-6.5

Procedure: I . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '

Mixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t i ons , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogen-

2 . Add i n bo th o f t h e a lcoho l e thoxy la te s u r f a c t a n t s . Mix u n t i l homogeneous.

3 . Add i n t h e EDTA. 4 . Add i n t h e sodium hydrox ide u n t i l t h e pH i s a t t a i n e d . 5 . Add c o l o r s o l u t i o n and fragrance, as des i red .

T o t a l Ac t i ves :

eous.

C12-15 l i n e a r a l coho l , 3 moles EO: 1 0 . 0 C12-13 l i n e a r a l coho l , 6 . 5 moles EO: 5 .0



L i g h t Du ty L i q u i d D e t e r g e n t

I n g r e d i e n t s : Water P i l o t SXS-40 C a l s o f t L-60 Calamide C Cal foam EA-603 Cal s o f t LAS-99 C i t r i c A c i d Sodium C i t r a t e Comments about t h i s f o r m u l a : 1 . pH=7.1 2 . Add C i t r i c A c i d i f pH i s h i g h o r Sodium C i t r a t e if 3 . V i s c o s i t y s h o u l d be 300 cPs.

F o r m u l a t i o n LDL-001-01

w e j - g h s 4 8 . 4 5

7 .50 30.00

5 . 0 0 8 . 3 0 0 . 6 0 0 . 1 0 0 . 0 5

pH i s l o w .

L i s h t Duty L i q u i d D e t e r g e n t

I n g r e d i e n t s : Water C a l s o f t L-60 P1 l o t s x s - 4 0 Calamide C Cal foam EA-603 Cal s o f t LAS-99 Opaci f i e r Sod1 um C i t r a t e Comments abou t t h i s f o r m u l a : 1 . Add e i t h e r C i t r i c A c i d or

2 . S o l i d s 45%. 3 . S u b s t i t u t i n g C a l s o f t L-40

p r o d u c t s o l i d s t o 42%. F o r m u l a t i o n LDL-002-01

7.0-7.2.

Weight% 22.31 39 .70 2 2 . 1 0

7 . 0 6 7 .35 0 . 5 6 0 . 8 8 0 . 0 4

C a l s o f t LAS-99 t o a d j u s t pH t o

f o r C a l s o f t L-60 w i l l l o w e r

I n g r e d i e n t s : Water Calsuds A Cal foam ES-303 Perfume Kathon CG Opaci f i e r Comments abou t t h i s f o r m u l a : 1 . I f o p a c i f i e r i s t o be added, w i t h h o l d 5% o f t h e w a t e r 2 . Add t h e o p a c i f i e r t o t h e w a t e r p r i o r t o a d d i n g t o t h e

d e t e r g e n t . F o r m u l a t i o n LDL-004-01

L i g h t D u t y L i q u i d D e t e r g e n t

Weight% 1 8 . 8 0 70 .00 1 0 . 0 0

0 . 1 0 0 . 1 0 1 . o o

SOURCE: P i l o t Chemical Co . : Suggested F o r m u l a t i o n s

Laundry Products 97

L i g h t -Duty L i q u i d D e t e r g e n t

I n g r e d i e n t s : Water Calsuds CD-6 P i l o t SXS-40 Cal foam EA-603 Cal s o f t LAS-99

Weight% 50.20 2 5 . 0 0

6 . 8 0 1 0 . 0 0

6 . 0 0

Comments abou t t h i s f o r m u l a : 1 . I n g r e d i e n t s s h o u l d be added i n t h e o r d e r l i s t e d t o a i d i n

2. Sodium C i t r a t e / C i t r i c A c i d s h o u l d be added f o r pH ad jus tmen t

3 . S a l t (Sodium o r Ammonium C h l o r i d e ) w i l l r a i s e t h e v i s c o s i t y .

b l e n d i n g .

t o 7 + .



I n g r e d i e n t s : Water P i l o t SXS-40 C a l s o f t T-60 Cal foam ES-303 Calamide C P r e s e r v a t i ve Sodi um C h l o r i d e

Comments about t h i s f o r m u l a : V i s c o s i t y 2 7 5 cPs. Sol i d ~ = 3 2 - 3 3 % pH=6.2 F o r m u l a t i o n LOI-007-01


I n g r e d i e n t s : Water P i l o t s x s - 4 0 L i nea r A1 coho1 E t h o x y l a t e NaOH, 50% D i e t h a n o l am1 ne Cal s o f t LAS-99

Comments abou t t h i s f o r m u l a : So l 1 ds=30% Good f o r g reasy a p p l i c a t i o n s . F o r m u l a t i o n IDL-006-01

SOURCE: P i l o t Chemical Co : Suggested F o r m u l a t i o n s

Weight% 36.90

5 . 0 0 4 0 . 0 0 15 .00

2 . 0 0 0 . 1 0 1 . 0 0

Weight% 65.16

6 .29 2.52 2 .81 0 . 4 3

19 .77



I n g r e d i ent -s l Water Ammonium C h l o r i d e P i l o t sxs-40 C a l s o f t L-60 Cal foam ES-303 Calamide C C i t r i c A c i d P r e s e r v a t i ve

Weight% 13 .90

2 . 4 0 19.60 4 4 . 1 0 1 5 . 8 0 4 . 0 0 0 . 1 0 0 . 1 0

Comments about t h i s f o r m u l a : 1 . “As i s ” pH=8.0. 2 . Add C i t r i c A c i d i n p l a c e o f Sodium C i t r a t e t o l o w e r pH.


Ligh-t- Du ty L i q u i d D e t e r q e n t Ca l s o f t LAS-99 Based

I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 P i l o t SXS-40 Cal foam ES-303 Cal o x y l a t e N-9 C i t r i c A c i d Opaci f i e r P r e s e r v a t i v e

Comments abou t t h i s f o r m u l a : A d d i n g r e d i e n t s i n o r d e r 1 i s t e d . F o r m u l a t i o n LDL-011-01

L i g h t D u t y L i q u i d D e t e r g e n t Cal s o f t LAS-99 Based

I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam ES-303 C a l o x y l a t e N-9 C i t r i c A c i d Opaci f i e r

Comments abou t t h i s f o r m u l a : A d d i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n LDL-012-01


Weight% 43.60

5 . 8 0 21 .70 1 6 . 7 0

3 . 0 0 8 . 0 0 0 . 1 0 1 . o o 0 . 1 0

Weight% 5 2 . 4 0

4 . 4 0 16 .30

5 . 0 0 1 2 . 5 0

2 . 2 0 6 .00 0 . 1 0 1 . o o

Laundry Products 99

a h t Du ty L i q u i d D e t e r g e n t __ C a l s o f t LAS-99 Based

I n a r e d i e n t s ; Water Cal s o f t LAS-99 NaOH, 50% A l c o h o l E t h o x y l a t e Calamide C P i l o t SXS-40 Perfume P r e s e r v a t i ve Comments abou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . Formul a t i on LDL-014-01

Weight% 54.60 16.30

4 .35 10.00 2 . 0 5

12.50 0 . 1 0 0 . 1 0

L i g h t D u t L L C q u i d D e t e r E n t D r y Cleaner : Pre-Spot-Water S o l u b l e

I n g r e d i e n t s : Weight% Water 75 .70 Calamide C 2 .00 C a l o x y l a t e N-9 1 1 . 0 0 C a l i mu1 se PRS 1 1 . o o C i t r i c A c i d 0 . 2 0 Perfume & C o l o r 0 . 1 0 Comments abou t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n o r d e r 1 i s t e d . V i s c o s i t y i n c r e a s e s as

2 . A c l e a r p r o d u c t i s o b t a i n e d when a l l i n g r e d i e n t s a r e mixed

3 . D e t e r g e n t f r a g r a n c e R-1264 can be used i n t h i s f o r m u l a . 4 . Use l e v e l : d i l u t e 8 : l w i t h w a t e r .

C a l o x y l a t e N-9 i s added.

t o g e t h e r .

F o r m u l a t i o n LDY-001-01

Li-ght D u t y Li.qu2d D e t e r g e n t Wool _Wash

I c g r e d i ents-: C a l s o f t T-60 Cal ami de CW-100 Cal foam ES-303 C i t r i c A c i d Comments abou t t h i s f o r m u l a :

The room t e m p e r a t u r e v i s c o s i t y i s abou t 520 cPs. F o r m u l a t i o n LDY-002-01

-- L i g h t D u t E L i q u j d D e t e r g e n t Wool Wash

I ng r e d i g n t s : Calsuds A Water Comments abou t t h i s f o r m u l a :

The room t e m p e r a t u r e v i s c o s i t y i s abou t 25 cPs. F o r m u l a t i o n LDY-004-01

SOURCE: P i l o t Chemical Co. : Stiggested F o r m u l a t i o n s

Wei g h t % 14 .15

5 . 4 8 39 .64

0 . 1 3

We1 g h t % 50 .06 49.93


Two Part Industri a1 Laundry Deteraents Break Formulations

Hi q h l v A1 kal i ne Break

Components: Water Burcosperse LP Burcolite BSGH-255 Dequest 2000 50% NaOH

Mixed Builder Break

Components: Water 45% KOH Burcosperse LP TKPP Sodi um Si 1 i cate (Star Grade)

% by Weight 5 10 5 5 75

% by Weight 4 0 . 0 27.5 10 .0 10.0 12.5

Procedure:

between each addition. Keep temperature below 160F during bl endi ng.

Add components in the order listed. Blend until homogeneous

Detergent Additive

Components: Water Burco NPS-816 Neodol 25-7 Dodecylbenzenesulfonic Acid TEA-85

% by Weight 60.00 10.00 12.50 11.65 5.85

Procedure:

between each addition.

Use Level:

Add components in the order listed. Blend until homogeneous

Break: 4-12 ounces/100 pounds Detergent: 2-4 ounces/100 pounds

SOURCE: Burlington Chemical Co., Inc.: Suggested Formulations

Laundry Products 101

U l t r a L i q u i d Laundrv D e t e r q e n t I n g r e d i e n t s : Wt% Alpha-Step MC-48 2 9 . 0 Sodi urn 01 e a t e 5 .0 A l c o h o l , E t h o x y l a t e , 7 19.0 Borax 1 . 3 3A A l c o h o l 0 . 5 P r o p y l ene G1 y c o l 5 .0 PVP K-15 0 . 8 Water , f r a g r a n c e & dye Q.S. t o 100.0 M i x i n g P rocedure :

Combine Alpha-Step MC-48, p r o p y l e n e g l y c o l , a l c o h o l e t h o x y - l a t e and w a t e r w h i l e m i x i n g u n t i l s o l u t i o n i s homogeneous. Heat t o a p p r o x i m a t e l y 50 deg. C, add sodium o l e a t e and m ix u n t i l s o l u t i o n and i s a g a i n homogeneous. A l l o w m i x t u r e t o c o o l t o room t e m p e r a t u r e and add t h e r e m a i n i n g i n g r e d i e n t s w i t h m i x i n g . A d j u s t p H w i t h c a u s t i c soda o r c i t r i c a c i d i f necessa ry . T y p i c a l F o r m u l a t i o n P r o p e r t i e s :

F o r m u l a t i o n D e s c r i p t i o n : SME/Soap pfl : 8-10 V i s c o s i t y : 200-350 cps D e n s i t y : 8 . 6 Appearance: C l e a r , l i g h t y e l l o w 1 Use I n s t r u c t i o n s : Use 1/3 cup p e r

Comment:

Based HDL

q u i d normal s i z e washload

Alpha-Step MC-48 i s an e x c e l l e n t oap s o l u b i l i z e r t h a t can make h i g h soap l e v e l s p o s s i b l e i n f i n i s h e d p r o d u c t s . F o r m u l a t i o n No. 658

F i n e F a b r i c Wash I n g r e d i e n t s : Wt% Water , D . I . 43.4 Alpha-Step MC-48 46.0 N i n o l 30-LL 4 .6 Sodi um c h l o r i de 6 .0 M i x i n g P rocedure :

homogeneous. Add sodium c h l o r i d e t o t h i c k e n . A d j u s t pH w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e as necessa ry . P r o p e r t i e s :

Charge w a t e r and MC-48 and m i x . Add 30-LL and m ix u n t i l

Appearance: C l e a r y e l l o w l i q u i d pH, as i s : 7 . 5 V i s c o s i t y @ 25 deg. C, cps: 220 S o l i d s , %: 29.0 Freeze/ thaw, 3 c y c l e s : pass C o l d s t o r a g e @ 4 deg. C, 1 week: pass H igh temp. s t o r a g e @ 50 deg. C, 1 week: pass D e n s i t y , l b s / g a l : 0 . 6

Use s m a l l amount f o r hand washing o r 1 / 4 cup f o r machine Use I n s t r u c t i o n s :

washing. Comment :

o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e . F o r m u l a t i o n No. 358 SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s


9. Metal Cleaners and Polish

Metal Cleaners and Polishes 103

A c i d M e t a l C leaner*

The combina t ion o f Veegum and Rhodopol 23 suspends t h a abra- s i v e and p r o v i d e s a s t a b l e , f r e e f l o w i n g c l e a n e r w i t h good v e r t i c a l s u r f a c e c l i n g . Veegum i s p r o t e c t e d a g a i n s t f l o c c u l a t i o n i n t h i s pH 1 c o m p o s i t i o n t h r o u g h base exchange w i t h t h e i m i d - a z o l i n e . Te t rasod ium EDTA f a c i l i t a t e s t h i s exchange. Veegum and Rhodopol p r o v i d e s y n e r g i s t i c t h i c k e n i ng w i t h b e t t e r v i s c o s i t y s t a b i l i t y and i n h i b i t i o n o f s y n e r e s i s t h a n i s p o s s i b l e w i t h e i t h e r t h i c k e n e r a l o n e . Diatomaceous E a r t h p r o v i d e s good c l e a n s - i n g and p o l i s h i n g .

I n q r e d i e n t s : A : Veegum

Rhodopol 23 Water

y& 0.8 0 . 4

72.1

6: Tet rasod ium EDTA 0 .9 1 - H y d r o x y e t h y l - 2 - c a p r y l i m i d a z o l i i ne Phosphor ic a c i d Diatomaceous E a r t h

Procedure: B lend Veegum and Rhodopol

a g i t a t i ng a t maximum ava i 1 ab smooth. Add B i n g r e d i e n t s i n a d d i t i o n u n t i l smooth and un

Cons is tency : Whi te , p o u r a b l e

0 . 8 1 5 . 0 10 .0

S l o w l y add them t o t h e water w h i l e e shear . Cont inue m i x i n g u n t i l o r d e r , m i x i n g w e l l a f t e r each f o r m ( a v o i d i n c o r p o r a t i o n o f a i r ) . l i q u i d .

Suggested Packaging: P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y l a b e l i n g f o r a c i d .

*U.S. P a t e n t No. 4,302,253

SOURCE: R.T. V a n d e r b i l t Co., I n c . : F o r m u l a t i o n No. 392

D i ppi ns C1 eaner f o r S i 1 v e r

I n g r e d i e n t s : Zusol a t 1008/85 2 .5 Th iourea 8 . 0 H y d r o c h l o r i c a c i d 3 .0 Water 8 6 . 5

SOURCE: Zschimmer & Schwarz GmbH & Co. : F o r m u l a t i o n CT 02-15-02


A1 umi num C1 eaner /Br i ghtener

T r a d i t i o n a l l y , a n i o n i c s u r f a c t a n t s have o f f e r e d b e t t e r d e t - ergency then non ion ics , bu t were no t compat ib le i n a c i d systems. Th is f o r m u l a t i o n uses Avanel S-70, an a n i o n i c molecule which performs even a t very low pH's and a i d s i n t h e removal o f sur face o i l s and depos i ts . U n l i k e non ion ics , Avanel 5-70 w i l l d i s s o l v e r e a d i l y i n t o the fo rmu la t i on w i thou t fo rming gel p a r t i c l e s thus e l i m i n a t i n g t h e need f o r excessive a g i t a t i o n . T h i s f o r m u l a t i o n can be used f o r over- the-road aluminum t r a i l e r s , w i r e wheels on automobiles o r i n t h e p repara t i on o f aluminum f o r anod iz ing and c l eani ng.

I n q r e d i e n t s : Dei on i zed Water Phosphoric Ac id ( 8 5 % ) C i t r i c Ac id ( 5 0 % ) N i t r i c Ac id (70%) Avanel S-70

Wt% 8 3 . 0

6 . 0 8 . 0 1 . o 2 . 0

Procedure: Charge t h e water t o a mix ing vesse l . Under slow a g i t a t i o n and

w i t h due care, add t h e ac ids t o t h e water. Add t h e Avanel S-70 and m i x 10 minutes. NOTE: I f a d d i t i o n a l b r i g h t e n i n g i s requ i red , t h e n i t r i c a c i d concen t ra t i on may be increased t o 1.5%.

Formula t ion CM-101

Powdered Metal Cleaning Concentrate

I n a r e d i en ts : Sodi um Hydroxide Sodium Carbonate STPP Avanel 5-70

Procedure: Add i n g r e d i e n t s as l i s t e d .

A1 u m i num C1 eaner

I n g r e d i e n t s : Deionized Water Avanel S-70 Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate C a r b i t o l Solvent

Wt% 5 8 . 5 13.5 2 0 . 0

8 . 0

8 5 . 0 6 . 0 5 . 0 1 . o 3.0

Procedure:

e r a t e a g i t a t i o n . NOTE: Other Avanel p roduc ts cou ld be used i n t h i s f o r m u l a t i o n t o achieve d i f f e r e n t s u r f a c t a n t c h a r a c t e r i s t i c s .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions

Charge vessel w i t h i n g r e d i e n t s i n the order l i s t e d us ing mod-


A1 umi num Cleaner Concentrate F-498

Water Sodium M e t a s i l i c a t e (Anhydrous) Te t ra Potassium Pyrophosphate (Powder) Mona NF-10

U h W e i g h t 75 10

5 10

Procedure:

i n water w i t h mix ing , then add Mona NF-10.

Typ ica l P roper t i es : Appearance : Clear 1 i q u i d Cloud P o i n t : 8 8 C

Recommended Use D i l u t i o n : 1 t o 4 oz/gal

D isso lve sodium m e t a s i l i c a t e and t e t r a potassium pyrophosphate

Aluminum Wash F-499

Water Sodium M e t a s i l i c a t e (Anhydrous) Te t ra Sodium Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona N F - I 0

% By Weiaht 88

2 3 2 5

Procedure:

i n water, then add Bu ty l C a r b i t o l and Mona NF-10.

Typ ica l P roper t i es :

D isso lve sodium m e t a s i l i c a t e and t e t r a sodium pyrophosphate

Appearance: Clear 1 i qu id pH: 1 2 . 8

Recommended Use D i l u t i o n : 1 : l O w i t h water



B u f f i nq Compound Remover

Component: Water TEA B u r c o t r o p e 1250 Burcosperse LP Borax Burco TME Burco LAF-6

% 42.5 20 .0 1 2 . 5 1 2 . 5

5 .0 5 . 0 5 . 0

Add components i n o r d e r l i s t e d . B l e n d u n t i l homogeneous between each a d d i t i o n .

H o t A1 k a l i n e P a i n t S t r i p p e r C o n c e n t r a t e

Comp o n e n t s : 45% KOH K a s i l #1 Burco HCS-50 NF

a 67 3 2

1

Add components i n t h e o r d e r l i s t e d . B l e n d u n t i l homogeneous between each a d d i t i o n .

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s

M e t a l De-Oi 1 i ng L iqu id C o n c e n t r a t e ( L i q u i d )

S o i l - Petro leum-based o i l S u r f a c e - M e t a l : S t e e l , copper , aluminum, e t c . A p p l i c a t i o n Method - Spray and/or immers ion Manu fac tu re - Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : Water S t a r s o EDTA, Te t rasod ium (37%) Sodi um X y l ene Sul f o n a t e (40%) C9-C11 L i n e a r A l c o h o l , 6 Moles EO C9-C11 L i n e a r A l c o h o l , 2.5 Moles EO

Use D i l u t i o n : 2%-4% bv

SOURCE: The PQ Corp . : Suggested F o r m u l a t i o n

wtu/, 4 2 . 0 1 2 . 0 16.0 20.0

3 . 0 7 . 0


C u t t i n g O i l

Monalube 215 p r o v i d e s e x c e l l e n t l u b r i c i t y , and ex t reme p r e s s - u r e p r o p e r t i e s . T h i s f o r m u l a t i o n i s used i n mach in ing , s tamp ing and d r a w i n g f e r r o u s and n o n f e r r o u s m e t a l s . I n n r e d i e n t s : Wt% 100 P a l e O i l 9 5 . 0 Monalube 215 5 . 0 P rocedure :

Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. T y p i c a l P r o p e r t i e s :

Appearance: C1 e a r Amber L i q u i d V i s c o s i ty/4OC: 24 CS

Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /56 I n . -Lbs . Draw Bead E f f i c i e n c y : 95 Draw Bead E f f i c i e n c y Re fe rence O i l : 115

Per formance Data:

Formul a t i on F-791

C u t t i n g O i 1

I n q r e d i e n t s : 100 P a l e O i l 90 .0 Monalube 205 5 . 0 Monalube 215 5 . 0 P rocedure :


Appearance: C l e a r Amber L i q u i d V i s c o s i t y (40C): 25 CS Fa1 ex : 2250 Lbs . /60 I n . -Lbs .

Appl i c a t i ons: Fo r machi n i ng s tamp ing and d raw i ng . F o r m u l a t i o n F-792

C u t t i n g O i l

I n q r e d i e n t s : 100 P a l e O i l

Wt% 8 5 . 0

Monalube 205 5 . 0 Monalube 215 5 . 0 Monalube 225 5 . 0 Procedure:


Appearance: C1 e a r Amber L i q u i d V i s c o s i ty /40C: 30 CS

Per formance Data: F a l e x ( D i r e c t S c a l e ) : 2750 Lbs . /70 I n . . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y Re fe rence O i l : 115

Appl i c a t i ons: Heavy d r a w i n g and s tamp ing F o r m u l a t i o n F-793 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Cut t i ng O i l

I n g r e d i e n t s : 100 P a l e O i l Monalube 215 Monalube 225

&% 9 0 . 0

5 . 0 5 .0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.

Typ i c a l P r o p e r t i es : Appearance: C l e a r Amber L i q u i d V i s c o s i t y 40C: 27 CS

F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./6O I n . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y Reference O i l : 115

Performance Data:


C u t t i n a O i l

I n s r e d i e n t s : 100 Pa le O i l Monalube 225

WtO/o 95 .0

5 .0

Procedure:


Performance Data:

Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.

Appearance: C1 ear Amber L i q u i d V i s c o s i t y 40C: 24 CS

F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./6O I n . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y Reference O i l : 115


C u t t i n g O i 1

I n q r e d i e n t s : 100 P a l e O i l Monalube 215 Monalube 325

Wt% 9 0 . 0

5 .0 5 .0

Procedure:


Per formance Data:

F o r m u l a t i o n F-796


Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.

Appearance: C l e a r Dark Brown L i q u i d V i s c o s i t y 40C: 22 CS

F a l e x ( D i r e c t S c a l e ) : 2250 Lbs. /55 I n . - L b s .


I n g r e d i e n t s : A r i s t o n a t e M-LF O l e i c A c i d TEA P r o p y l ene G l y c o l Water

C u t t i n g O i l s

S e m i - S y n t h e t i c - C u t t i n g O i 1

Wei qh t% 1 7 . 7 7

2 . 9 8 2 . 7 5

15 .04 61.48

Comments abou t t h i s f o r m u l a : 1 . M i x a l l of t h e i n g r e d i e n t s , excep t t h e P ropy lene G l y c o l . 2 . Add t h e w a t e r SLOWLY. 3 . Add t h e P ropy lene G l y c o l l a s t .

F o r m u l a t i o n SOF-001-01

C u t t i n g O i 1 C o n c e n t r a t e

I n g r e d i e n t s : A r i s t o n a t e M D r e s i n a t e 91 I g e p a l CO-430

O l e i c A c i d , Emersol 213 O l e i c A c i d D i e t h y l e n e G l y c o l Water

KOH, 45%

Wei g h t % 60 .60 2 0 . 2 0

0 . 1 0 1 . 2 5 8 . 2 5 7 . 1 0 2 . 5 0

Comments abou t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . Emuls ion - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r .

F o r m u l a t i o n SOL-001-01

C u t t i n g O i 1 C o n c e n t m e

I ny, ,ed i e n t s : A r i s t o n a t e M Neodol 25-3 TEA, 85% O l e i c A c i d D i e t h y l ene G1 y c o l Water

Weight% 5 1 . 8 0 2 1 . 6 0

4 . 5 0 8 . 5 0 8 . 6 0 5 . 0 0

Comments abou t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . Emu ls ion - D i l u t e 4 :76 w i t h 160 ppm h a r d w a t e r .



I 1 0 Advanced Cleaning Product Formulations

Genera l Purpose Machine C leaner

T h i s i s an e x c e l l e n t a l l - p u r p o s e c l e a n e r f o r c l e a n i n g a l l t y p e s o f f e r r o u s p a r t s and machine s u r f a c e s . Monacor 4000 i s i n c o r p o r a t e d f o r added c o r r o s i o n p r o t e c t i o n .

I n g r e d i e n t s : Water T r i e thanolami ne Monacor 4000 Monami ne CF-1 OOM M o n a t e r i c CyNa-50 Tet rasod ium EDTA (40%) T r i a d i n e 10 ( P r e s e r v a t i v e ) Procedure:

between each a d d i t i o n a t moderate speed. T y p i c a l P r o p e r t i e s :

M i x t h e i n g r e d i e n t s i n o r d e r a t ambient

Appearance: C l e a r amber l i q u i d S p e c i f i c G r a v i t y : 1 .06 pH Concent ra te : 10.2 pH o f a 1:10 s o l u t i o n : 9 . 8

Recommended Use D i l u t i o n : 1 :10 w i t h water Cast I r o n B l o c k : Pass C o r r o s i o n T e s t : 1 :10 D i l u t i o n F o r m u l a t i o n F-770

69.00 4 . 0 0 3 .50 6 .00 6 . 0 0

10.00 I .50

tempera ture . M i x we1 1

A i r c r a f t Cleaner Type I V

The f o l l o w i n g f o r m u l a t i o n uses Monamulse 653-838 as an emul- s i f i e r i n a m i l i t a r y s p e c i f i c a t i o n (MIL-C-855706) f o r m u l a t i o n .

I n a r e d i e n t : P a r t A: Monamulse 653-0313 Monami ne 1-76 Aromat ic 150 I s o p a r M (Odor less M i n e r a l S p i r i t s ) D i e t h y l e n e G l y c o l B u t y l E t h e r Decanol

vvts/,

7 . 0 2 . 7 7 . 5 7 .5 3 . 5 1 . 6

P a r t B:

Water 55.1 P l u r o n i c F98 1 .8 Hycar 1422 1 0 . 6 Procedure:

Add P a r t B t o P a r t A. A g i t a t e u n t i l u n i f o r m . T y p i c a l P r o p e r t i e s :



T r i s o d i u m Phosphate (Dodecahydrate) 2 . 7

Add i n g r e d i e n t s o f P a r t A & P a r t 8 s e p a r a t e l y w i t h a g i t a t i o n .

Appearance: C1 ear L i q u i d


General Purpose Syn the t i c F l u i d ( A )

I n g r e d i e n t s : Mas l i p 501 Bas= Maphos 8135 Mazon R I 4 A Tr ie thano lamine, 85% B i o c i de Water

Wt96 5.0 8 . 0 8.0 12.0 0.5

Balance

Procedure: 4 . Add i n g r e d i e n t s as l i s t e d . 2. Th is f l u i d i s f o r f e r r o u s meta ls . The concent ra te should be

f u r t h e r d i l u t e d from 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased and s t a i n p r o t e c t i o n , inc rease t h e amount o f Mazon R I 4 A . For inc reased l u b r i c i t y inc rease t h e amount o f l u b r i c a n t o r extreme pressure a d d i t i v e .

General Purpose Syn the t i c F l u i d (BZ

I n g r e d i e n t s : Mas l i p 500 Mazon R I 8 B Propyl ene G1 yco l T o l y t r i a z o l e (Cl imax) T r i ethanolami ne, 85% 8 i o c i de Water

Wt% 38.0 12.0 2.5 2.5 10.0 0.5

Balance

Procedure: 1 . Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s meta ls . The concent ra te should be

f u r t h e r d i l u t e d from 1:lO (heavy d u t y ) t o 1:40 ( l i g h t du ty ) w i t h water t o form a ready-to-use f l u i d . For increased r u s t and s t a i n p r o t e c t i o n , inc rease t h e amount o f Mazon R I 8 B . For increased l u b r i c i t y inc rease t h e amount o f l u b r i c a n t o r extreme pressure a d d i t i v e .

Copper Machinina F l u i d I n g r e d i e n t s : Macol 5100 Mazon R I 6 Maphos 8135 Potassi um Hydroxide B i o c i de Water



Wt% 15.0 8.0 7.0 6.0 0.5

Balance


Genera l Purpose S y n t h e t i c F l u i d (C )

I n g r e d i e n t s : M a s l i p 501 A Mazon R I 8 B Maphos 58 T r i e t h a n o l ami ne, 85% B i o c i de Water

Mle9/0 3 0 . 0 12.0

6 . 0 7.0 0 . 5

5al ance

Procedure: 1. Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e

f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1 : 4 0 ( l i g h t d u t y ) w i t h w a t e r t o f o r m a ready - to -use f l u i d . F o r i n c r e a s e d r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 8. F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount of l u b r i c a n t o r ext reme p r e s s u r e a d d i t i v e .

Genera l Purpose S y n t h e t i c F l u i d (D)

I n s r e d i e n t s : M a s l i p 501 Base Mazon R I 8 A Maphos 8135 T r i e t h a n o l ami n e , 85% B i o c i de Water

Wt% 12 .0 2 5 . 0

5 . 0 1 2 . 0

0 . 5 5 a l ance

Procedure: 1 . Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be

f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1 : 4 0 ( l i g h t d u t y ) w i t h w a t e r t o f o r m a ready - to -use f l u i d . F o r i n c r e a s e d r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 A . For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r ext reme p r e s s u r e a d d i t i v e .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


M e t a l C leaner (Phosphate, Powder)

Soi 1 -Drawing l u b r i c a n t , an imal f a t and grease S u r f a c e - S t e e l A p p l i c a t i o n Method-Spray Manufacture-Dry b lend/Agglomerat

Composi t i on : *STPP *Sodi um Carbonate * * A l k o x y l a t e d l i n e a r a l c o h o l non ion

( 1 ow foam) Metso Beads 2048 Sodi um Hydrox ide Beads

on

10.0 25.0

5 . 0 30 .0 30.0

c s u r f a c t a n t

Use: Heavy d u t y low- foaming meta l c l e a n e r wh ich i s good f o r a

Use D i l u t i o n : 0.8-1.5% bw (1-2 o z / g a l l o n ) spray c l e a n i n g p r o c e s s .

FMC ** O l i n P o l y t e r g e n t S-305LF o r

Rhone-Poulenc I g e p a l CO-530

A1 umi num C1 eaner (Phosphate, Powder)

Soi 1 - L i g h t d rawing o i 1 Surface-Aluminum A p p l i c a t i o n Method-Spray washer Manufacture-Dry b l end/Aggl omera t i on

Composi t i on : Metso Beads 2048 *STPP *Sodi um B i c a r b o n a t e **Sodium P o l y a c r y l a t e ***Octy lphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO

Use D i l u t i o n : 1.5-3.036 bw (2-4 o z / g a l )

* FMC ** Rohm 8, Haas Acusol 445ND (92% s o l i d s ) *** Rhone-Poul enc I g e p a l CA-630

SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide

Wt% 45.0 30.0 20 .0

3 .0 2 . 0


M e t a l C1 eaner (Phosphate. Powder2

S o i l - O i l , d r a w i n g l u b r i c a n t , an imal f a t Sur face-Stee l A p p l i c a t i o n Method-Immersion ManufacturekDry b lend/Agg lomera t ion

Composi t i o m *Sodium Carbonate *STPP **Octy lphenoxy P o l y e t h o x y e t h a n o l ( 6 Moles € 0 ) Metso Beads 2048 Sodi um Hydrox ide Beads


* FMC ** Rhone-Poulenc I g e p a l CA-630

and grease

2 0 . 0

Meta l C1 eaner (Phosphate, Powder)

S o i l - O i l , d rawing l u b r i c a n t , animal f a t and grease S u r f a c e - S t e e l A p p l i c a t i o n Method-Immersion/electrolytic c l e a n i n g Manufacture-Dry b lend/Agg lornera t ion

Com o s i t i o n :

TSP Metso Beads 2048 Sodium Carbonate *Octy lphenoxy P o l y e t h o x y e t h a n o l (12-13 Moles EO) Sodium H y d r o x i d e Beads

Use D i l u t i o n : 2 . 3 - 4 . 5 % bw (3-6 o z / g a l )

* Rhone-Poulenc I g e p a l CA-720

SOURCE: PO C o r p . : Detergent F o r m u l a t i o n Guide

TSPF

8 . 0 2 . 0

3 0 . 0 40 .0

Wt% 1 5 . 0

5 . 0 3 5 . 0 28.0

2 . 0 1 5 . 0


M e t a l C leaner I Phosphate, Powder 1

So i 1 -0i 1, f a t , p r o t e i n S u r f a c e - S t a i n l e s s s t e e l A p p l i c a t i o n Method-Cleaning i n p l a c e Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

Composi t i o n A : *STPP *Sodium Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 3 Moles EO) Metso Beads 2048 Sodi um H y d r o x i d e Beads

- Compos i t i on 0 : *STPP *Sodium Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 3 Moles EO) Metso Pentabead 20

Use D i l u t i o n : 1 .5-3.0% bw (2 -4 o z / g a l l o n )

* FMC ** Rhone-Poluenc Rhodasur f A-24

M e t a l C1 eaner ( Z e r o Phosphate, Powder)

Soi 1-Oi 1 , d r a w i n g l u b r i c a n t , animal f a t and g rease S u r f a c e - S t e e l A p p l i c a t i o n Method-Immersion Manu fac tu re -Dry b lend /Agg lo rne ra t i on

Composi t i on: V a l f o r 100 Z e o l i t e A Sodium Carbonate *Oc ty lphenoxy P o l y e t h o x y e t h a n o l (9-10 Moles EO) Metso Pentabead 20 Acusol 445ND Sodi um P o l y a c r y l a t e


g Rhone-Poulenc I g e p a l CA-630

SOURCE: PB C o r p . : D e t e r g e n t F o r m u l a t i o n Guide

40.0 12.0

3 . 0 2 5 . 0 20.0

WtO/o 40 .0 12 .0

3 . 0 45.0

WtO/o 15.0 38.0

2 .0 43.0

2 . 0


Non-Phosphorous Aluminum Cleaner

Th is i s a t o t a l l y o rgan ic , phosphate-free aluminum c leaner t h a t p rov ides excel 1 en t c l eani ng and b r i gh ten i ng o f a1 umi num. The Avanel S-70 p rov ides f o r removal o f o rgan ic su r face depos i t s and, by su r face tens ion reduc t i on , b e t t e r con tac t between the aluminum sur face and t h e organ ic ac ids . I n a d d i t i o n t o i n d u s t r i a l a p p l i c a t i o n s l i k e c lean ing over- the-road aluminum t r a i l e r s and aluminum p r i o r t o anodiz ing, t h i s c leaner may also be used i n household a p p l i c a t i o n s such as c lean ing aluminum f l a s h i n g , windows and door f i x t u r e s . Depending on the app l i ca - t i o n , t h i s p roduc t may be used i n a Dressure wash, pump spray o r d i p tank .

I n q r e d i e n t s : C i t r i c Acid, 50% Gluconic Acid, 50% Avanel S-70 Deionized Water, Dye

w.e-l 12.0 8 . 0 3.0

Balance

Procedure: Charge t h e water, c i t r i c ac id , g lucon c a c i d and Avanel S-70

Mix w e l l . If dye i s t o be added, p a r t o f t he water should be he out; and t h e dye added t o t h i s water w i t good a g i t a t i o n . The d i sso l ved dye can then be added t o t h e ba tch . NOTE: Ce r ta in dyes may n o t be s t a b l e under these c o n d i t i o n s . Consequently, s h e l f s t a b i l i t y t e s t s should be performed.


d

A1 k a l i ne A1 u m i num C1 eaner

I n a r e d i e n t s : Dei on i zed Water Avanel S-70 Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Macol 48

pH (as i s ) : 11.5-12.5 Appearance: C lear , water -wh i te l i q u i d S p e c i f i c G r a v i t y : 1 .05

8 7 . 0 4 .0 5.0 1 . o 3 . 0

Procedure: Charge t h e water and d i s s o l v e t h e b u i l d e r s a l t s under a g i t -

a t i o n . When d i sso l ved , charge t h e remaining i n g r e d i e n t s . Cont inue m ix ing f o r a t l e a s t 15 minutes. NOTE: Th i s a l k a l i n e aluminum c leaner has shown excel l e n t c l eani ng p r o p e r t i e s w i thou t chemical a t t a c k o f t h e meta l . Th i s f o r m u l a t i o n may be c u t -!:I w i t h water t o p repare a m i l d hard-sur face c leaner .



Metal Cleaners and Polishes 11 7

Semi S y n t h e t i c

T h i s f o r m u l a t i o n i s p a r t i c u l a r l y u s e f u l f o r heavy mach in ing and l i g h t d r a w i n g f o r f e r r o u s and s t a i n l e s s s t e e l .

I n g r e d i e n t s : 100 P a l e O i l Monalube 320 Monalube 610 Monalube 205 Monalube 215 T r i e t h a n o l ami ne (99%) Monacor BE Water

P rocedure : Combi ne i n g r e d i e n t s w i t h a g i t a t i o n .


Per formance Data (5% i n W a t e r ) : Appearance: C l e a r Amber L i q u i d

Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. /50 I n . -Lbs. Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Appearance: C l e a r pH: 9 . 6



I n Q r e d i e n t s : 100 P a l e O i 1 Monalube 320 Monalube 610 Monalube 220 T r i e t h a n o l a m i n e (99%) Monacor BE Water

wt9j0 9 . 0 9 . 0 13.6 0.8 0.8 3.2 5.0

58.6

wt9j0 9 . 0 9 . 0 13.6 1.6 3.2 5.0 58.6

Procedure:

c o n c e n t r a t e t o 95% w a t e r fo rms m i c r o e m u l s i o n . F o r m u l a t i o n can be used f o r g r i n d i n g and l i g h t mach in ing .

T y p i ca9 P r o p e r t i es : Appearance : C1 e a r Amber L i q u i d

Per formance Data ( 5 % i n Wate r ) : Appearance: C l e a r L i q u i d p H : 9.5 S u r f a c e Tens ion (dynes/cm): 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./45 I n . - L b s .

M i x i t e m s 1,2, and 3 u n t i l c l e a r . Add i t e m s 4,5, and 6 . 5% o f



I18 Advanced Cleaning Product Forniulations


I n a r e d i e n t s : 100 P a l e O i l Monalube 225 TEA Monalube 610 Water


Per formance Data ( 5 % i n w a t e r ) : Appearance: C1 e a r L i q u i d pH: 9 .0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t Sca l e ) : 2750 Lbs. /55 I n . -Lbs .

Appearance: C 1 e a r Amber L i q u i d

For mach in ing l i g h t s tamp ing and d r a w i n g . F o r m u l a t i o n F-799


I n q r e d i e n t s : 100 P a l e O i l Monalube 320 Monalube 610 Monalube 205 T r i e t h a n o l a m i n e (99%) Monacor BE Water

y& 1 0 . 0

5 .5 7.5

25.0 47 .5

Wt% 9 . 0 9 . 0

13 .6 1 . 6 3 .2 5 . 0

5 8 . 6

P rocedure :

5% o f c o n c e n t r a t e added t o w a t e r fo rms m i c r o e m u l s i o n . Suggested f o r g r i n d i n g and mach in ing f o r b o t h f e r r o u s and n o n f e r r o u s m e t a l s .


M i x i t e m s 1 , 2, and 3 u n t i l c l e a r . Add i t e m s 4 and 5 t h e n 6 .

Appearance: C l e a r Amber L i q u i d

Per formance Data ( 5 % i n Wate r ) : Appearance: C l e a r L i q u i d p H : 9 .5 S u r f a c e Tens ion : 2 7 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. /57 I n . -Lbs .




Silver and Metal Polish

I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended ~ The r e s i n a1 so prevents "creami ng" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .

I n s r e d i e n t : SF96 S i l i c o n e F l u i d (350) ( 1 ) Dow Corninp 20 Release Coat ing (2 ) Stoddard Solvent (3) P r i f a c 2922 Laur i c Ac id D I Water Morphol i ne Carbopol EZ-2 ( 4 ) Ammoni um hydroxide bgopg l i e Kao l i Clay (5)

ysp c a f Proper€+ es. B r o o k f i e l d V i s c o s i t y (RVT-20 rpm):

Wt% 1 .oo 2 . 0 0

20.00 2.00

43.48 0.86 0.35 0.31 14.00

10,000 cps Product pH: 8.50 Product C l a r i t y : Paste

Raw Ma te r ia l Supp l ie rs : ( 1 ) General E l e c t r i c ( 2 ) Dow Corning Corp. ( 3 ) Exxon Corp. ( 4 ) BFGoodrich (5) Kaopo l i te , I n c .

Procedure: 4 . Add t h e s i l i c o n e f l u i d , re lease coat ing , so lvent , and l a u r i c

a c i d P o a vesse l . Mix us ing a h igh shear mixer. 2 . Continue t o mix, and add t h e water (43.48 p a r t s ) and t h e

morphol i ne. 3 . Disperse t h e Carbopol i n t o t h e water (16.00 p a r t s ) by s imply

"dumping" i t i n . The polymer w i l l wet ou t i n a few minutes. Add t h e d i spe rs ion t o t h e above m ix tu re w i t h good a g i t a t i o n .

4. Add t h e ammonium hydroxide t o reach t h e t a r g e t pH. 5. Add t h e c l a y and mix u n t i l uni form.

T o t a l Act i ves : S i l i c o n e f l u i d : 1 .oo Stoddard so l ven t : 20.00 Re1 ease c o a t i ng : 2.00 Abras i vet 14.00

FGoodrich Spec ia l t y Chemicals: DET-563


So lub le O i 1

I n g r e d i e n t s : 100 Pale O i l Monalube 605 P a r o i l 160

WtO/o 8 0 . 0 20 .0 2 0 . 0

Procedure: Combine a l l i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.

Typi c a l P roper t i es : Appearance: C lear Dark Brown

Performance Data (5% i n water ) : Appearance: M i 1 ky L i q u i d pH: 8 . 5 Falex ( D i r e c t Sca le ) : 2750 Lbs./60 In . -Lbs .

Above f o r m u l a t i o n f o r heavy du ty machining and drawing f o r use on s t a i n l e s s s t e e l and fe r rous meta ls . Formula t ion F-803

Soluble O i 1

I n g r e d i e n t s : 100 Pale O i l Monalube 605

Wt% 85.0 1 5 . 0

Procedure: Combine above i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 5 0 C .

Typ ica l P roper t i es : Appearance: Clear L i g h t Brown L i q u i d

Performance Data (5% i n wa te r ) : Appearance: M i 1 ky Emulsion pH: 8 . 8 Cast I r o n B lock Cor ros ion Tes t : Pass Falex ( D i r e c t Sca le ) : 1750 Lbs./47 In . -Lbs .

Appl i c a t i on:


SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ions

For g r i n d i n g and very l i g h t machining.


S o l u b l e Qi 1

I n a r e d i e n t s : 100 P a l e O i l

Wt% 78.0

Monalube 605 Wonalube 215 T EA

1 5 . 0 5 . 0 2 . 0

P rocedure :

u t i o n i s s l i g h t l y hazy, a d j u s t w i t h t a l l o i l f a t t y a c i d . M i x above i n g r e d i e n t s w i t h a g i t a t i o n . Warm t o 12OF. I f s o l -

T y p i c a l P r o p e r t i e s : Appearance: M i l k y Emuls ion

Per formance Data (5% i n Wate r ) : Appearance: M i 1 ky Emu1 s i o n pH: 8 . 0 Cas t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs . /55 I n . -Lbs .

The above f o r m u l a t i o n i s suggested f o r g r i n d i n g and l i g h t mach in ing . F o r m u l a t i o n F-805

S o l u b l e O i 1

I n g r e d i e n t s : 100 P a l e O i l Monalube 605 Monalube 215

Procedure : Combine i n g r e d i e n t s w i t h a g i

T y p i c a l P r o p e r t i e s : Appearance: C l e a r Amber L i q u

Per formance Data (5% i n W a t e r ) : Aooearance: M i 1 kv Emuls ion

Wt% 8 5 . 0 1 0 . 0

5 . 0

a t i o n w h i l e warming t o 50C.

d

. . pH: 8 . 0 F a l e x ( D i r e c t S c a l e ) : 1250 L b s . / 4 5 I n . - L b s .

The above f o r m u l a t i o n i s suggested f o r g r i n d i n g and l i g h t mach in ing . F o r m u l a t i o n F-806



S o l u b l e O i l M a c h i n i n g F l u i d

Monalube 225 p r o v i d e s l u b r i c i t y , and EP p r o p e r t i e s i n t h i s mach in ing f l u i d . T h i s f o r m u l a t i o n was des igned f o r mach in ing ca rbon s t e e l , b r a s s , b ronze copper and s t a i n l e s s s t e e l .

I n g r e d i e n t s : Naph then ic O i l (lOOSUS/lOO) Monalube 225 Monalube 605 T r i e t h a n o l a r n i n e (99%)

Procedure : Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .

F a l e x EP T e s t : D i r e c t Load S c a l e : 2750 l b s Torque: 47 i n c h pounds

Use D i l u t i o n s : G r i n d i n g : I -2% i n w a t e r L i g h t M a c h i n i n g : 3-5% i n wa te r Moderate Mach in ing : 5-7% i n wa te r Heavy M a c h i n i n g : 8-10% i n wa te r

Formula F-764

Wt% 72 .0

5 . 0 20.0

3 . 0

S y n t h e t i c M a c h i n i n q F l u i d

T h i s f o r m u l a t i o n i s i d e a l f o r mach in ing ca rbon s t e e l , b r a s s , bronze, copper , aluminum and s t a i n l e s s s t e e l .

I n g r e d i e n t s : Monalube 225 T r i e t h a n o l a m i n e (99%) Water

Procedure: Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .

F a l e x EP T e s t P rocedure : C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n D i r e c t Load S c a l e 3000 l b s . Torque 60 i n c h pounds



wto/, 1 5 . 0 3 0 . 0 5 5 . 0


S v n t h e t i c

I n g r e d i e n t s : Monalube 210 T r i e t h a n o l a m i n e (99%) Water A n t i foam

Procedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .

T y p i c a l P r o p e r t i e s : Appearance: C l e a r Amber L i q u i d

Per formance Data ( 5 % i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 5 S u r f a c e Tens ion : 42 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /56 I n . - L b s .

Wt% 16.6 33.3 50.0 0.1

The f o r m u l a t i o n i s des igned f o r f e r r o u s and n o n f e r r o u s m e t a l s p r i m a r i l y f o r g r i n d i n g . Formul a t i on F-819

S y n t h e t i c

I n q r e d i e n t s : Monalube 210 Monalube 315 T r i e t h a n o l a m i n e (99%) Water

Procedure.: Combine i n g r e d i e n t s w i t h a g i t a t i o n .


Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d p H : 8 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /56 I n . - L b s .


K% 1 2 . 5 1 2 . 5 2 5 . 0 5 0 . 0

F o r m u l a t i o n i s des igned f o r b o t h f e r r o u s and n o n f e r r o u s systems p r i m a r i l y f o r g r i n d i n g . F o r m u l a t i o n F-820



S y n t h e t i c Drawing/Stampinp F l u i d

T h i s f o r m u l a t i o n i s i d e a l f o r s tamp ing h o t o r c o l d r o l l e d s t e e l .

I n g r e d i e n t s : Monalube 225 T r i e t h a n o l a m i n e (99%) Monalube 315 Water

P rocedure : Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .

F a l e x EP T e s t P rocedure : C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n D i r e c t Load S c a l e 3000 l b s . Torque 55 i n c h pounds


1 5 . 0 30.0 20.0 35 .0

O i 1 Based Drawi ng/Stampi ng F1 ui d

Monalube 225 p r o v i d e s l u b r i c i t y , EP and c o n t r i b u t e s t o t h e c o r r o s i o n p r o t e c t i o n p r o p e r t i e s i n t h i s heavy -du ty s tamping/ d raw i ng f 1 u i d.

I n g r e d i e n t s : P a r a f f i n i c O i l (300SUS/lOO) Monalube 225

Procedure: B lend Monalube 225 i n t o t h e o i l

F a l e x EP T e s t : D i r e c t Load S c a l e : 3000 l b s Torque 57 i n c h pounds


Spray M e t a l C1 ean i ng C o n c e n t r a t e

I n g r e d i e n t s : Water Sodi um Metas i 1 i c a t e Sodium Carbonate Sodi um H y d r o x i d e Monatrope 1250 A l k y l P o l y a l k y l e n e E t h e r

Procedure:

i n g r e d i e n t i s d i s s o l v e d b e f o r e n e x t a d d i t i o n . F o r m u l a t i o n F-751


Add i n o r d e r l i s t e d w i t h a g i t a t i o n , making s u r e each

Wt% 9 0 . 0 1 0 . 0

75.00 3 . 0 0 4 . 0 0 5 .00

11 .00 2.00



S y n t h e t i c Formula

W y t 5 . 0

10.0 30 .0 55.0

P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .

T y p i c a l P r o p e r t i e s : Appearance: C1 e a r Amber L i q u i d

Per formance Data (5% i n Wate r ) : Appearance: C l e a r L i q u i d p H : 8.7 S u r f a c e Tens ion : 27 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /47 I n . - L b s .

T h i s f o r m u l a t i o n i s des igned f o r b o t h f e r r o u s and n o n f e r r o u s systems f o r a r e a s o f mach in ing and g r i n d i n g a t 10% f o r m i l d s tampi ng. F o r m u l a t i o n F-813


I n q r e d i e n t s : Monalube 205 Monalube 210 Monalube 315 T r i e t h a n o l ami ne (99%) Water

wt% 5 . 0

10.0 10.0 30 .0 45 .0


T y p i c a l P r o p e r t i e s : Appearance: C1 e a r Amber L i q u i d

Per formance Data ( 5 % i n Wate r ) : Appearance: C1 e a r L i q u i d pH: 8 .0 S u r f a c e Tens ion : 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 Lbs. /57 I n . - L b s .

T h i s f o r m u l a t i o n i s des igned f o r b o t h f e r r o u s and n o n f e r r o u s systems f o r a reas o f mach in ing and g r i n d i n g a t 10% f o r m i l d s tampi ng. F o r m u l a t i o n F-814

SOURCE: Mona I n d u s t r i e s , I n c , : Suggested F o r m u l a t i o n s


Syn the t i c Formula

I n q r e d i e n t s : Monalube 2 0 5 Monalube 220 Tr ie thano lamine (99%) Monalube 315 Water

w%% 4.5 9 . 0

2 7 . 0 2 0 . 0 39.5

Procedure: Mix i tems 1, 2 , 3, and 4 . Add water and mix u n t i l homogeneous.


Performance Data (5% i n Water) :

Appearance: C lear Amber L i q u i d

Appearance: Trans lucent S o l u t i o n pH: 9 .0 Surface Tension: 32 Cast I r o n B lock Corrosion Tes t : Pass Falex ( D i r e c t Sca le ) : 2500 Lbs./47 In . -Lbs .

Formula t ion F-815


Clear product designed f o r f e r r o u s g r i n d i n g .

I n g r e d i e n t s : Monalube 210 Mona1 ube 110 Water

Procedure: Combine i ngredi en ts w i t h a g i t a t i o n .

Typ ica l P r o p e r t i e s : Appearance: C1 ear Sol u t i on

Performance Data (5% i n Water) : Appearance: C1 ear L i qu id pH: 7 . 5 Falex ( D i r e c t Sca le ) : 2500 Lbs./45 In . -Lbs .

15.0 40.0 4 5 . 0

Note: No TEA needed. Excess DEA i n Monalube 110 n e u t r a l i z e s PE. Formula t ion F-816




P roduc t d e s i gned f o r g r i n d i ng and 1 i g h t mach in ing

I n g r e d i e n t s : Monalube 210 T r i e t h a n o l a m i n e (99%) Monalube 315 Water



Per formance Data (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 8 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /45 I n . - L b s .



I n a r e d i e n t s : Monalube 215 T r i e t h a n o l ami ne (99%) A n t i foam Water



Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 5 S u r f a c e Tens ion : 42 F a l e x ( D i r e c t S c a l e ) : 2500

Produc t des igned f o r machi n A l s o some v e r y l i g h t s tamp ing . F o r m u l a t i o n F-818

SOURCE: Mona I n d u s t r i e s , I n c . :

Wt% 15 .0 30.0 10 .0 45.0

Wt% 16.6 3 3 . 3

0 . 1 50.0

b s . / 4 4 I n . - L b s .

ng f e r r o u s and n o n f e r r o u s m e t a l .

Suggested F o r m u l a t i o n s



I n g r e d i e n t s : Monalube 210 Monoethanol ami ne Water

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n .


Performance Data (5% i n Water): Appearance: C lear L i q u i d pH: 1 1 Cast I r o n B lock Cor ros ion Test: Pass Fa1 ex (Di r e c t Scal e) : 2250 Lbs. /58 In. -Lbs.

Appearance: C lear Amber L i q u i d

Formulated f o r g r i n d i n g a p p l i c a t i o n s . Ferrous metals on l y . Formula t ion F-821


Ing red ien ts : Monalube 205 Tr ie thano lamine (99%) A n t i foam Water

Procedure: Combi ne i ngredi en ts w i t h a g i t a t i o n .

Typ ica l P r o p e r t i es :

Performance Data (5% i n Water): Appearance: C1 ear L i q u i d pH: 8 . 3 Sur face Tension (dynes/cm): 24 Cast I r o n B lock Corrosion Test: Pass Fa1 ex (D i r e c t Scale) : 2500 Lbs . / 5 5 In. -Lbs .

Appearance: Clear Amber L i q u i d

Q 1 6 . 6 3 3 . 3 50.4

1 6 . 6 3 3 . 3

0 . 1 50.0

Th is i s t h e most un i ve rsa l formula s ince i t can be used on all meta l l u rgy a t 1% t o 2%. I t a l s o can be used f o r g r i n d i n g a t 5% t o 8% f o r machining and a t 8% t o 15% f o r r e a l heavy machining. Formula t ion F-822

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ions


Svnthet i c Formul a

I n a r e d i e n t s : Monalube 205 Monalube 110 Water


T y p i c a l P r o p e r t i e s : Appearance: C l e a r S o l u t i o n

Per formance Data (5% i n Wate r ) : Appearance: C1 e a r L i q u i d ptl: 8 . 0 S u r f a c e Tens ion : 28 Cast I r o n B l o c k C o r r o s i o n F a l e x ( D i r e c t S c a l e ) : 2250

Fo r use i n mach in ing and 1 n o n f e r r o u s m e t a l s . NOTE: Excess DEA i n Monalube

phosphate e s t e r . F o r m u l a t i o n F-823

Wt% 10 .0 30.0 6 0 . 0

e s t : Pass Lbs./5O I n . - L b s .

g h t s tamp ing f o r f e r r o u s and

10 i s enough t o n e u t r a l i z e t h e

* t h e t i c Formula

I n g r e d i e n t s : Monalube 205 Monoethanol ami ne Water



Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d p H : 10 Cast I r o n B l o c k : Pass Fa1 ex ( D i r e c t Sca l e ) : 2000 Lbs. /50 I n . -Lbs.


Fo r f e r r o u s systems f o r mach in ing and g r i n d i n g . Formul a t i on F-824


25.0 25 .0 5 0 . 0


S y n t h e t i c F o r m u l a t i o n

I n q r e d i e n t s : Monalube 210 Monalube 225 TEA Water


T y p i c a l P r o p e r t i es :

Per formance Data (5% i n Wate r ) : Appearance: C1 e a r L i q u i d pH: 8 . 5 S u r f a c e Tens ion (dynes/cm): 42 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /46 I n

F o r mach in ing , f o r m i n g , and s tamp ing a l l Forrnul a t i on F-807


S y n t h e t i c F o r m u l a t

I n q r e d i e n t s : Monalube 225 Monalube 310 T r i e t h a n o l ami ne (99%) Water

P rocedure :

M i x u n t i l c l e a r , t h e n add w a t e r .


Per formance Data (5% i n Wate r ) : Appearance: C l e a r L i q u i d pH: 8 . 6 S u r f a c e Tens ion : 41 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./55 I n .

M ix Monalube 225 w i t h t r i e t h a n o l a m i n e

Appearance: C l e a r C o n c e n t r a t e

10.0 10.0 40 ~ 0 4 0 . 0

-Lbs.

m e t a l s

15.0 2 5 . 0 30.0 30.0

and add Monalube 315.

-Lbs

Fo r heavy d u t y s tamp ing o f f e r r o u s m e t a l s a t 10 t o 20% i n w a t e r . F o r m u l a t i o n F-808


I n g r e d i en t s : Monalube 205 Monalube 210 Monalube 220 T r i e t h a n o l a m i n e (99%) Water


S v n t h e t i c F o r m u l a t i o n

5 . 0 10.0 10.0 50.0 2 5 . 0

Procedure : M i x i t e m s 1, 2, 3 , and 4 . Then add w a t e r .

T y p i c a l P r o p e r t i e s : Appearance: C l e a r L i q u i d

Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d p H : 9 . 0 S u r f a c e Tens ion : 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 Lbs . /57 I n . - L b s

Fo r s tamping, d r a w i n g and b r o a c i n g 10 t o 20% i n w a t e r . Formul a t i on F-809



P rocedure : M ix i t e m s 1 , 2, 3, and 4 , t h e n add w a t e r and m i x .


Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 7 S u r f a c e Tens ion : 35 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 1 I n . - L b s .

Appearance: C1 e a r Amber L i q u i d

A p p l i c a t i o n :

and s tamp ing . F o r m u l a t i o n F-810

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formu

F o r f e r r o u s and n o n f e r r o u s systems f o r mach

wtsl, 5 . 0

10 .0 30 .0 5 5 . 0

n i ng, f o r m i n g ,

a t i ons






Per formance Data (5% i n Wate r ) : Appearance: C l e a r L i q u i d pH: 9 . 0 S u r f a c e Tens ion : 42 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. /47 I n . -Lbs


Wt% 9 . 0 9 . 0

36 .0 4 6 . 0

Use i n mach in ing and s tamp ing f o r b o t h f e r r o u s and n o n f e r r o u s m e t a l l u r g y . F o r m u l a t i o n F-811




Typ i c a l P r o p e r t i es : Appearance: C1 e a r Amber L i q u i d

Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 0.7 S u r f a c e Tens ion : 35 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /35 I n . - L b s .

Fo r mach in ing , f o r m i n g , and s tamp ing f o r a1 1 me ta l 1 u r g y F o r m u l a t i o n F-812


5 . 0 1 0 . 0 3 0 . 0 5 5 . 0


Uni ve rsa1 S c o u r i na Pas te

I n q r e d i e n t s : WtO/o A : T y l o s e CBR 10000 5 .00

5: Water (50C) 51 .80

C : Hos tapur SAS 60 Genapol ZRO 1 i q u i d Genapol U D - 0 3 0 Komperlan KD NaCl

21.80 10.70

2 . 0 0 0 .70 0.00

0: P r e s e r v a t i v e , Perfume q . s .

Manufacku r i ng: I. A, wh ich i s added by c o n t i n u i n g s t i r r i n g , s h o u l d s w e l l ,

u n t i l a homogeneous g e l f r e e o f lumps has been o b t a i n e d I I . Add one a f t e r a n o t h e r , t h e components o f C t o I. 1 1 1 . F i n a l l y D i s added.

T e s t s : V i s c o s i t y (B rook

SOURCE: Hoeckst A k t

i e l d RVT, sp. 6, 10 min -1, 25C): 49b00 mPas

e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n

A1 u m i n u m C 1 eaner

Comoosi t i on: Ke lzan xan than gum B u t y l C e l l o s o l v e T e r g i t o l NP Phosphor i c A c i d (85%) C i t r i c A c i d Sodi um D ich romate Water

Wt% 1 .o 4 . 0 3 . 0 3 . 0 4 . 0

t r a c e 85 .0

Procedure: D i s s o l v e Ke lzan xanthan gum i n w a t e r . Add t h e c i t r i c and

p h o s p h o r i c a c i d s f o l l o w e d by 5 u t y l C e l l o s o l v e and T e r g i t o l NP. To use, sp read e v e n l y on t h e s u r f a c e t o be c l e a n e d and a l l o w s u f f i c i e n t t i m e f o r t h e c l e a n i n g a c t i o n t o be accompl ished.

SOURCE: Monsanto Performance M a t e r i a l s : Ke lzan Suggested F o r m u l a t i o n


Water Sol u b l e Stampi ng F1 u i d

I n g r e d i e n t s : \nit% Mas l i p 501 Base 3 0 . 0 Mazon R I 8 B 1 2 . 0 D i ethanol ami ne 8 .8 Propyl ene G1 yco l 1 . 2 Tr iethanolamine, 85% 1 0 . 0 Water Balance Procedure:

Add i n g r e d i e n t s as l i s t e d . I f more l u b r i c i t y i s requ i red , add Macol 5100. I f more co r ros ion i n h i b i t o r i s requ i red , add more Mazon R I 8 8. Use 1O:l d i l u t i o n r a t e f o r heavy du ty a p p l i c a t i o n .

WD-40 Type Lubr i can t Concentrate

I nq red i en t s : S-Maz 80 Mazawet 77 H i t e c E-515 ( E t h y l ) Pa lmet ic Ac id S h e l l f l e x 213 She l l Sol 135 Procedure: Add i n g r e d i e n t s as l i s t e d .

I n a r e d i en ts : S-Maz 80 Mazon R I 6 Masi l SF-10 Nekal WT-27 Gafac RE-40 Indopol H-100 Odor1 ess M i nera Procedure:

Pene t ra t i ng O i l

S p i r i t s

W 3 . 7 1 . Q 5 . 2 0 . 7

1 0 . 5 70 .9

Wt% 2- 6 7-1 2 0- 1 0- 1 0- 1 0 - 6

11 ance

Add i n g r e d i e n t s as l i s t e d . NOTE: A p o r t i o n o f t h e mineral s p i r i t s may be de le ted and s u b s t i t u t e d w i t h a naphthenic o i l (5-1 5%).

Burn i sh ins Compound

I n g r e d i e n t s : Mazamide 65 Mafo 1 3 MOD 1 Mazon R I 4 A T r i sodi um Phosphate EDTA Water Procedure: Add i n g r e d i e n t s as l i s t e d .


Wt% 1 0 . 0

7 . 0 5 . 0 7 . 0 1 . o

7 0 . 0

10. Oven, Grill and Hot Plate Cleaners


C a u s t i c Oven C l e a n e r

I n a r e d i e n t s : A: Van Gel C, 4 .8% Aqueous D i s p e r s i o n

Dei o n i zed Water

Wt%* 62.50 45.75

B: Sodium Hydrox ide , 50% S o l u t i o n 5.00

C : B u t y l C a r b i t o l Aminomethyl Propanol (AMP-95) Sodium Cocoamphoacetate ( M o n a t e r i c CM-36s)

'10.00 1 . 5 0 0 .25

D . Sodium Hydrox ide , 50% S o l u t i o n 5 . 0 0

Procedure: 1 . Make t h e 4.8% Van Gel C d i s p e r s i o n by s l o w l y add ing 4 . 8 p a r t s

by w e i g h t o f Van Gel C i n t o 95 .2 p a r t s by w e i g h t o f w a t e r o f a t room t e m p e r a t u r e , w h i l e m i x i n g w i t h a homogenizer a t 5000 rpm. C o n t i n u e m i x i n g f o r 60 m inu tes . Add t h e r e m a i n i n g P a r t A w a t e r t o t h e i n d i c a t e d amount o f d i s p e r s i o n and m ix u n t i l u n i f o r m .

t o a c h i e v e good m i x i n g o f e n t i r e b a t c h .

u n t i l u n i f o r m . A v o i d ent rapment o f a i r and g e n e r a t i o n o f foam.

2 . S l o w l y add P a r t B and a d j u s t homogenizer speed as r e q u i r e d

3 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g each

4. S l o w l y add P a r t D and m ix u n t i l u n i f o r m . F o r m u l a t i o n No. 461

Non-Caust ic Oven C leaner

I n q r e d i e n t s : A : Water

Van Gel C, Magnesium Aluminum S i l i c a t e Rhodopol 50MD, Xanthan Gum

Wt%* 55 .00

0 . 7 5 0 . 2 5

6 : D i e t h a n o l ami ne 5 . 0 0 T r i e t h a n o l a m i n e 5 . 0 0 T r i p r o p y l enegl y c o l Me thy l E t h e r (Dowanol TPM) 5 .00 Po tass ium Carbonate, 25% Aqueous S o l u t i o n 28 .00 Vanseal NACS-30, Sodium L a u r o y l S a r c o s i n a t e 1 . o o

P rocedure : 1 . D ry b l e n d t h e Van Gel C and Rhodopol 50MD and add t h e m i x t u r e

t o t h e w a t e r w h i l e s t i r r i n g w i t h a homogenizer o p e r a t i n g a t 5000 r p m . C o n t i n u e m i x i n g f o r 30 m i n u t e s .

each f o r 5 m i n u t e s . Package.


2 . S l o w l y add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r shown. M i x


SOURCE: R.T. V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s

Oven, Grill and Hot Plate Cleaners 137

H i g h Caust ic Oven Cleaner

Carbopol r e s i n s a r e used t o t h i c k e n t h i s h i g h c a u s t i c form- u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p rov ides v e r t i c a l c l i n g t o inc rease t h e con tac t t ime o f t h e de tergent on t h e s o i l e d su r face and enhance consumer convenience.

I n a r e d i e n t : D I Water Carbopol 674 ( 1 ) Potassium hydrox ide (45%) Propylene g l y c o l methyl e the r ( 2 ) C8-16 a l k y l po l yg l ycos ide (50%) (3 )

Wei Qht Percent 71.03 69.78 0.75 2.00

22.22 22.22 3 .00 3 .00 3.00 3.00

Brookf i e l d v i s c o s i t y (RVT-20 rpm) : 250 5,000 CPS CPS

Product p H : 13-14 13-14 Product c l a r i t y : C lear C lear

( 1 ) 8FGoodrich ( 2 ) Dow Chemical : Dowanol PM ( 3 ) Henkel Corp.: Glucopon 425CS


M ixer or s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e DI water . Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogeneous.

2 . Add t h e potassium hydrox ide w i t h cont inuous m ix ing . 3 . Add t h e g l y c o l e t h e r . 4 . Add t h e APG s u r f a c t a n t . Mix u n t i l homogeneous. 5. Add f ragrance, as des i red .

To ta l Ac t i ves : Potassium hydrox ide : 10.00 Propylene g l y c o l methyl e t h e r : 3.00 C8-16 a l k y l po l yg l ycos ide : 1.50

FGoodrich S p e c i a l t y Chemicals: OET-360


Oven C leaner

I n g r e d i e n t s : A : Veegum T, Magnesium Aluminum S i l i c a t e

Rhodopol 23, Xanthan Gum D e i o n i z e d Water

B : Sodium Hydrox ide , 50% Deceth-4 Phosphate (Rhodafac RA-600)

VVt%* 0 . 4 0 1 . 2 0

80 .40

8 . 0 0 1 0 . 0 0

Procedure: 1 . Weigh t h e w a t e r , h e a t i t t o 85-9OC and m ix w i t h an homogenizer

2 . D ry b l e n d t h e Veegum T and Rhodopol 23 and s l o w l y add them t o

3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o

4 . Add t h e P a r t B i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5

a t 5000 rpm.

t h e w a t e r . C o n t i n u e m i x i n g f o r 20 m i n u t e s .

p roduce a s m a l l v o r t e x . Cool t o 55C.

m i n u t e s a f t e r each a d d i t i o n . NOTE: I t i s p a r t i c u l a r l y i m p o r t a n t t h a t t h e Sodium H y d r o x i d e s o l u t i o n be added v e r y s l o w l y w i t h good m i x i n g o f t h e e n t i r e b a t c h .

F o r m u l a t i o n f r o m Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s

A e r o s o l Oven C1 eaner


Dei o n i zed Water

W t . %* 1 .50

74.25

8 : n-Methy l P y r r o l i d o n e (M-Py ro l ) 20.00

Nonoxynol ( I g e p a l CO-630) 1 . o o D isod ium Cocoamphodipropionate ( M i r a n o l C2M-SF Conc.) 3.25

P rocedure : 1 . Weigh w a t e r and p l a c e on homogenizer . 2 . D i s p e r s e t h e Veegum T i n t h e w a t e r u s i n g a homogenizer a t

5000 r p m . Con t inue m i x i n g for 20 m inu tes , w h i l e h e a t i n g t o 70C.

3 . Combine t h e i n g r e d i e n t s o f P a r t 8, h e a t t o 70C. 4 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed

5 . Add P a r t B t o P a r t A and c o o l w h i l e m i x i n g t o 30C. 6 . Package i n a e r o s o l can u s i n g Propane/Butane p r o p e l l a n t . F o r m u l a t i o n f r o m I n t e r n a t i o n a l S p e c i a l t y P r o d u c t s .

t o p r o v i d e a s l i g h t v o r t e x .


SOURCE: R.T. V a n d e r b i l t Co . , I n c . : Suggested F o r m u l a t i o n s

Oven, Grill and Hot Plate Cleaners 139

Oven C leaner

Compos i t i on : K e l z a n xan than gum T r i sod i um Phosphate Sodi urn me tas i 1 i c a t e Sul f o n a t e OA5 B r i j 96 S i 1 i cone 200 F l u i d 3 5 0 c s Hexane Water

0 . 1 3 . 2 1 . l 2 . 1 3 . 2 4 . 0 4 . 2

8 2 . 1

Procedure : P repare wa te r s o l u t i o n o f Ke lzan xan than gum as b e f o r e and

add n e x t t h r e e i n g r e d i e n t s . M ix t h e B r i j 96, S i l i c o n e and hexane s e p a r a t e l y . Then add w a t e r s o l u t i o n t o t h e s i l i c o n e / h e x a n e m ix w i t h c o n s t a n t a g i t a t i o n . Fo r a e r o s o l use cha rge w i t h 90% conc- e n t r a t e and 10% Genetron 1 2 .

Heavy D u t y Oven C leaner

Compos i t i on : Ke lzan xan than g u m A n t a r o n FC-34 Sodi um h y d r o x i d e Water

Wt% 0.3 2 . 0

1 0 . 0 8 7 . 0

Procedure :

S e p a r a t e l y , p r e p a r e t h e 40% sodium h y d o x i d e s o l u t i o n and s l o w l y add t o m i x . Fo r a e r o s o l use cha rge w i t h 80% m i x t u r e and 20% o f 1 : l mix o f Genetron 1 2 and 114.

SOURCE: Monsanto Per formance M a t e r i a l s : T e c h n i c a l B u l l e t i n 1-20:

P repare w a t e r s o l u t i o n o f Kelzan xanthan gum t h e n add A n t a r o n .

K e l zan Formul a t i ons


Oven C1 eaner w/Amphoter ic

I n g r e d i e n t s : Water, D.I . Sodi urn C i t r a t e Sodi um Metas i 1 i c a t e Sodium Hydrox ide , 40% Monoethanol ami ne Dowanol PM R e w o t e r i c AM HC W i t c o 1298SA DeSonic 9 N


each add i t i on.


Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y

V i s c o s i t y , cps: 96 pH: 1 3 . 9

Formula 1114

- Oven C leaner w/Phosphate

I n g r e d i e n t s : Phase I : Water , D . I . Carbopol 940 Phase 11: Water, D.I. Potass ium Hydrox ide , 87% T e t r a p o t a s s i u m Pyrophosphate Phase 111: Rewote r i c AM HC

\Mt96 71 . 6

2 . 1 4 . 2 6.5 4 . 2 3 . 1 3 . 1 3 . 1 2 . 1

between

71 . 4 1 . 3

1 5 . 4 2 .4 3 . 6

5 . 9


Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e vesse l and m ix t h o r - o u g h l y . W h i l e m i x i n g , pou r Phase I1 i n t o Phase I . M i x t h o r o u g h l y t h e n add Phase 11. Formula 1115


Combine Phase I i n g r e d i e n t s and m ix u n t i l homogeneous.

dishes, Coatings and Finishes

141


F u r n i t u r e Pol i sh

I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abras ives , t o become permanently suspended. The r e s i n a1 so prevents "creaming" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .

I n q r e d i e n t : Pa r t A: D I Water Carbopol EZ-2 ( 1 ) TEA

Par t B: Cardis 36 Wax (2 ) Hoechst Wax S ( 3 ) O l e i c Ac id Morphol i ne D I Water

Pa r t C : SM2133 S i l i c o n e Emulsion ( 4 ) SM2135 S i l i c o n e Emulsion ( 4 )

Phys ica l P roper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 9,500 cps Product pH: 7 .00 Product C l a r i t y : P o l i s h

Raw M a t e r i a l Supp l i e rs : ( 1 ) BF Goodrich (2 ) P e t r o l i t e S p e c i a l t y Polymers ( 3 ) Hoechst Celanese ( 4 ) General E l e c t r i c

wp9b

91.10 0 . 2 0 0 .20

0.25 0.25 0 . 0 8 0.10 1 .82

4 . 0 0 2 . 0 0

Procedure: 1. Disperse t h e Carbopol i n t o t h e water by s imp ly "dumping" i t

2. Add t h e TEA. Mix u n t i l homogeneous. 3. Prepare P a r t B. Add t h e Card is Wax, Hoechst Wax S, and o l e i c

a c i d t o a vesse l . Wi th m i l d s t i r r i n g , b r i n g t h e temperature up t o 96-IOOC. When melted, add t h e morphol ine u n t i l t h e m i x t u r e i s homogeneous. Add t h e water a t 95C. Continue s t i r r i n g u n t i l t h e temperature reaches 45C. Cool t o room temperature.

i n . The polymer w i l l wet ou t i n a few minutes.

4. Add Par t B. 5. Add i n t h e s i l i c o n e emulsions w i t h m i l d m ix ing .

T o t a l Ac t i ves : T o t a l Wax : 0 .50 T o t a l S i l i c o n e : 6.00


Polishes, Coatings and Finishes 143

Lea the r /P las t i c P o l i s h

I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended. The r e s i n a1 so prevents "creami ng" o r phase separ- a t i o n by suspending and separa t i ng t h e o i l d r o p l e t s .

I n q r e d i e n t : DI Water Renex 20 ( 1 ) Morphol i ne SF96 S i l i c o n e F l u i d (350) ( 2 ) O l e i c Ac id Minera l S p i r i t s 01 Water Carbopol EZ-2 (3 )

Wt% 5 0 . 0 0

2 . 0 0 1 .oo 5.00 2.00

20.00 19.60 0 .40

Phys ica l P roper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 cps Product pH: 8 .5 Product C l a r i t y : Opaque

Raw M a t e r i a l Supp l i e rs : ( 1 ) I C I Su r fac tan ts ( 2 ) General E l e c t r i c ( 3 ) BFGoodrich

Procedure: 1 . Disso lve t h e Renex 20 and morphol ine i n t h e water w i t h m i l d

2 . D i sso l ve t h e s i l i c o n e f l u i d and t h e o l e i c a c i d i n t h e minera l

3 . I n a separate vessel , d i spe rse 0.40 p a r t s o f Carbopol i n t o

a g i t a t i o n .

s p i r i t s . Add t o t h e above m ix tu re w i t h good a g i t a t i o n .

49.60 p a r t s o f water by s imp ly "dumping" t h e polymer i n t o t h e water . I n j u s t a few minutes, t h e polymer w i l l completely wet o u t . Add t h i s d i spe rs ion t o t h e above m ix tu re .

4 . Mix u n t i l homogeneous.

Total A c t i wes: S i l i c o n e F l u i d : 5.00 Minera l S p i r i t s : 20.00



Marble Pol i sh

I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abras ives , t o become permanently suspended. The r e s i n a1 so prevents "creami ng" o r phase separ- a t i o n by suspending and separa t i ng t h e o i l d r o p l e t s . I n g r e d i e n t : we% D I Water 74.80 Carbopol EZ-2 ( 1 ) 0.20 Minera l S p i r i t s 15.00 Igepa l 630 (2 ) 3.70 Diatomaceous e a r t h (3 ) 8.00 T r i ethanol ami ne 0.30 Phys ica l P roper t i es :

Brookf i e l d V i scos i t y (RVT-20 rpm) : 1 I , 700 cp Product pH: 7 .50 Product C l a r i t y : Opaque

Raw M a t e r i a l Supp l i e rs : ( 1 ) BFGoodrich (2 ) Rhone-Poul enc (3 ) Kaopo l i t e

Procedure: 1. Disperse t h e Carbopol i n t h e water by s imp ly "dumping" i t

i n . The polymer w i l l wet ou t i n a few minutes. Add t h e s u r f - ac tan t w h i l e m ix ing under moderate a g i t a t i o n .

homogeneous. 2. Add t h e minera l s p i r i t s . Mix u n t i l t h e emulsion becomes

3. Add t h e TEA. Mix u n t i l smooth. 4 . Add t h e diatomaceous ea r th . Mix u n t i l homogeneous. DET-552

Rust Removing P o l i s h

Carbopol r e s i n s a r e used i n t h i s fo rmula t o t h i c k e n t h e g luc - o n i c a c i d t o enable improved a p p l i c a t i o n e f f i c a c y . The polymer w i l l a l s o impar t v e r t i c a l c l i n g t o enable a p p l i c a t i o n s on v e r t - i c a l o r angled sur faces . I n q r e d i en t : Wt% D I Water 44.64 Carbopol €2-2 ( 1 ) 1 - 7 9 Sodium hydrox ide (50%) 35.71 Gluconic a c i d s o l u t i o n (50%) ( 2 ) 17.86 Phys ica l P roper t i es :

B r o o k f i e l d V i s c o s i t y (RVT-20 r p m ) : 3,000 cp Product pH: 13.90 Product C l a r i t y : T rans lucent

Procedure: 1. Disperse t h e Carbopol i n t o t h e water. 2. A d d t h e sodium hydrox ide w i t h a g i t a t i o n . Th icken ing will occur

3. Add t h e g lucon ic a c i d s o l u t i o n . Mix u n t i l homogeneous.

SOURCE: BFGoodrich S p e c i a l t y Chemicals: Suggested Formulations

i mmedi a t e l y . DET-560

Polishes, Coatings and Finishes 145

S c r a t c h e d Wood P o l i s h


Dei o n i zed Water

B: S t e a r i c A c i d Carnauba Wax Beeswax, Ye1 1 ow

C : T r i e t h a n o l ami ne, 99% M i n e r a l Spi r i t s

Wt% 1 . 5 0

31 .25

4 .50 1 6 . 5 0 16 .50

2 .75 27 .00

D: P r e s e r v a t i v e , Dye, F rag rance q . s

Procedure : 1 . Weigh t h e w a t e r and m ix w i t h a p r o p e l l e r m i x e r a t 1800 rpm. 2 . S l o w l y add t h e Veegum T and m ix f o r 20 m i n u t e s w h i l e

3. Combine t h e P a r t B i n g r e d i e n t s and h e a t t o 9OC. 4 . Add t h e P a r t C i n g r e d i e n t s t o t h e P a r t B m i x t u r e i n t h e

5 . Add P a r t B+C t o P a r t A and m i x f o r 10 m i n u t e s . 6 . Cool t h e b a t c h t o 35C, add P a r t D, and m ix u n t i l u n i f o r m .

h e a t i n g t o 9OC.

o r d e r shown, m i x i n g each f o r 10 m i n u t e s .


SOURCE: R . T . V a n d e r b i l t Co., I n c . : F o r m u l a t i o n No. 2 1 0

H i qh Gloss, D e t e r q e n t Resi s t a n t Pol i sh

A wax - f ree p o l i s h , wh ich p r o v i d e s a h i g h - g l o s s , d e t e r g e n t r e s i s t a n t f i n i s h on non-porous s u b s t r a t e s . S imp le a p p l i c a t i o n , w i t h o u t hard r u b b i n g o r b u f f i n g , r e s u l t s i n b o t h d e p t h o f g l o s s and d e t e r g e n t r e s i s t a n c e f o r ex tended p r o t e c t i o n .

I n g r e d i e n t s : ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-RA-159 S i l i c o n e P o l i s h A d d i t i v e ( 3 ) S toddard S o l v e n t ( 4 ) M i n e r a l S p i r i t s ( O d o r l e s s ) ( 5 ) GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n ( 6 ) K a o p o l i t e SF ( 7 ) S o f t Water ( 8 ) B a c t e r i c i d e

Wt% 9 . 0 1 . 5 3 . 5 3 . 5 9 . 0 3 . 4

70.0 0 . 1

Combine i n o r d e r shown w i t h h i g h shear m i x i n g u n t i l t h i c k e n i n g o c c u r s . M i x u n t i l homogeneous and package.

F o r m u l a t i o n P r o p e r t i e s : C o n t a i n s no wax Non-smeari ng H igh g l o s s Cost e f f i c i e n t D e t e r g e n t r e s i s t a n t Co ld b l e n d (On ly m i x i n g r e q u i r e d ) Easi 1 y app l i ed R e s i s t a n t t o wash-o f f

SQURCE: Genesee Polymers C o r p . : Formula 20-12

12. Rinse Aids

146

Rinse Aids 147

R i nse A i d , A c i d

I n q r e d i e n t s : Water, D . I . P e t r o 22 Powder DeSoni c LFD-97 H y d r o x y a c e t i c A c i d , 70%

B l e n d i n g P rocedure : 51 end i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .

T y p i c a l P r o p e r t i e s : S p e c i f i c G r a v i t y : 1 .105 Wt/Gal, l b s : 9 . 2 1 V i s c o s i t y , cps: 85 Cloud P o i n t , C : 59 S o l i d s , %: 40

Formula 131

R i nse A i d

I n g r e d i e n t s : Water , D . I . P e t r o 22 Powder DeSoni c LFD-97

T y p i c a l P r o p e r t i e s : S p e c i f i c G r a v i t y : 1 .029 Wt/Gal. l b s : 8 .58 pH, as i s : 6 . 4 V i s c o s i t y , cps : 80 Cloud P o i n t , C : 68 S o l i d s : 40%

Formula 130

SOURCE; W i t c o Corp. : Suggested Formul a t i ons

Wt9/o 5 0 . 0

5.0 3 5 . 0 1 0 . 0

Wt% 60 .0

5 .0 3 5 . 0

13. Rug, Floor, Carpet, Upholstery Shampoos an

148

I nq r e d i e n t s : Water T r i s o d i urn Phosphate T e t r a p o t a s s i u m Pyrophosphate P l u r a f a c D-25 A1 i p a l CO-436 Mazawet 77 EDTA ( T e t r a s o d i u m S a l t ) T i n o p a l 5 BM

Procedure : Add i n g r e d i e n t s as l i s t e d .

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 149

C a r p e t C1 eaner

Low Foam Carpe t Shampoo

I n g r e d i e n t s : Macol 2LF E t h y l e n e G l y c o l M e t h y l E the r Sodi urn T r i po l yphospha te Sodi urn X y l ene Su l f o n a t e Mazu DF 210 SX Water ( s o f t )

P rocedure : Add i n g r e d i e n t s as l i s t e d .

Steam Rua Cleaner-A

I n g r e d i e n t s : Macol OP 10 SP Sodium S i l i c a t e Sodi urn X y l ene Su l f o n a t e Water


S t e a m Rug Cleaner -8

I n q r e d i e n t s : Macol OP 10 SP Sodi um S i 1 i c a t e Sodium Xy lene S u l f o n a t e Water

Procedure: Add i n g r e d i e n t s as l i s t e d


wt% 56.0 15 .0 10 .0

7 . 0 10 .0

1.25 0 . 5 0 .25

Wt% 6.0

10 .0 1 . o 1 . o 0 .5

81 .5

wa 5.0

10 .0 5 . 0

8 0 . 0

Wt% 3 .0

1 0 . 0 3 .0

8 4 . 0


C a r p e t C l e a n e r s f o r t h e S p r a y - E x t r a c t i o n P rocess

I n q r e d i e n t s : Cublen 0 50 T e t r a p o t a s s i u m py rophospha te P r o p e t a l 241 P r o p e t a l 281 S u l f e t a l 4105 I s o p r o p a n o l Water

Formula CT 02-08-01

I n g r e d i e n t s : Water Soap S u l f e t a l 4105 P r o p e t a l 99 Cont raspum 300 U b a t o l TR 1138 I s o p r o p a n o l

Formula C T 02-08-02

W S 1 . o 5 . 0 2 .0 3 . 0 4 . 0 4 . 0

81 . o

Wt% 7 5 . 0

1 . o 5 . 0 5 . 0 1 . o 3 . 0

1 0 . 0

SOURCE: Zschimmer & Schwarz GmbH & C o . : Genera l F o r m u l a t i o n s

C a r p e t Shampoo L iqu id , t r a n s p a r e n t

I n g r e d i e n t s : A : Hostapur 0s l i q u i d

Med ia lan KA conc.

B: Water , P r e s e r v a t i v e

wtu/, 25 .00

3 . 0 0

Manu f a c t u r i ng : One a f t e r a n o t h e r , t h e components o f A a r e added t o 8 .


72.00


C a r p e t Shampoo I Phosphate, L i quid)

S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and grease, c l a y

S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method-Rug sc rubber Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r

and p a r t i c u l a t e

Composi t i on : Water *TSP *STPP Kasi 1 #6 P o t a s s i um S i 1 i c a t e **Phosphate E s t e r ***Sodi um A1 k y l naphtha1 ene Su l f o n a t e ****Octy lphenoxy P o l y e t h o x y e t h a n o l , 7-8 Moles EO

Use D i l u t i o n : 0 .8 -1 .5% bw (1 -2 o z / g a l l o n )

* FMC ** Rhone-Poulenc Rhodafac RE-610 *** DeSoto **** Rhone-Poulenc I g e p a l CA-620

RUQ Steam C leaner

Soi 1 -Food ( f a t and p r o t e i n ) , p e t r o l e u m

S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method-Rug s c r u b b e r Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t

and p a r t i c u l a t e

Composi t i on : Water Wetso Beads 2048 Sodi um X y l ene Sul f o n a t e , 40% * M i r a n o l JEM C o n c e n t r a t e (34%)

Wt% 6 2 . 5

2 .0 5 . 0

2 0 . 0 3 . 0 3 . 5 4 .0

o i l and grease, c l a y

r r e r

84 .0 5 . 0 6 .0 5 . 0

Use D i l u t i o n : 4 .7-9.4% b w (6-12 o z / g a l l o n )

*Rhone-Poul enc; o r She1 1 Chemical Neodol 25-1 2



C a r p e t Shampoo, H i s h Foam

I n Q r e d i e n t s : Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA

WtS/o 78.3

5 . 0 16.7

B1 end i ng P rocedure : B1 end i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .

P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , reduces t h e l o w t e m p e r a t u r e c l o u d p o i n t , g i v i n g e x c e l l e n t f r e e z e / t h a w p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e .

Formula 908

Carpe t Shampoo, H i g h Foam

I n q r e d i e n t s : Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA

B l e n d i n g P rocedure : B 2nd i n g r e d i e n t s i n t h e o r d e r

Use L e v e l : 1 t o 2 ounces p e r g a l l o n .

i s

Wt% 7 1 . 1

6 . 7 2 2 . 2

I

Comments : P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , reduces

t h e low t e m p e r a t u r e c l o u d p o i n t , g i v i n g e x c e l l e n t f r e e z e / t h a w p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e .

Formula 910

Carpe t Spo t Remover

I n q r e d i e n t s : Water, 13.1. W i t c o l a t e WAC-LA P e t r o BA L i q u i d G l y c o l E t h e r DPM G l y c o l E t h e r PM FC-129 (1% S o l i d s )


T y p i c a l P r o p e r t i e s : S p e c i f i c G r a v i t y : 0 .999 Wt./Gal. l b s . : 8 .33 pH: 10 .35

Use D i l u t i o n : Use as i s

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s Formula 945

Wt% 9 0 . 3

3.3 0 . 5 3 .5 2 . 3 0 . 1


Carpet 8 Upho ls te ry Cleaner Th is oeneral Duroose s t a i n remover f o r m u l a t i o n i s o a r t i c u l a r l v

e f f e c t i v e i n removing o i l s t a i n s . I n g r e d i e n t : Wt% Deionized Water ( h o t ) 37.0 SMA-2625 Resin 2.4 Aqua Ammonia 0.7 W i t c o l a t e WACLA 18.0 Witconate 60T L i q u i d 4 . 0 Avanel 5-70 4 . 0 Dei on i zed Water 34 .0 Dye, Fragrance, e t c . (2.5.

pH (as i s ) : 8.0-9.0 Appearance: C lear l i q u i d S p e c i f i c G r a v i t y : 1.016

Procedure: 1. Charge t h e ho t water t o a m ix ing vessel and s t a r t a g i t a t i o n .

S lowly s i f t i n t h e SMA-2625 Resin t o avo id c lumping. Add t h e Aqua Ammonia, app ly coo l i ng , and mix w e l l u n t i l t h e r e s i n i s d i sso l ved .

2 . Reduce a g i t a t i o n and add t h e remaining i n g r e d i e n t s . Stop a g i t a t i o n t o pe rm i t deaera t i on o f t h e produc t p r i o r t o f i l l i n g o f f .

3 . If t h i s p roduc t i s t o be co lo red , a p o r t i o n o f t h e f i n a l water should be reserved f o r d i s s o l v i n g t h e dye. A f t e r t h e dye is thorough ly mixed, t h e dye s o l u t i o n may be added NOTE: Use "as i s " on ca rpe t ing . D i l u t e 1O: l and 5 : l w i t h water f o r upho ls te ry .

V i n y l Dress ing ( 8 ) I n g r e d i e n t : Wt% Par t A : Mas i l EM 250 C 18 .0 Mas i l EM 10,000 C 10 .0 Dei on i zed Water 30.0 Par t B: Macol OP-10 SP 2.0 G1 y c e r i ne 1 . o Deioni r e d Water 38 .0 Sodium Benzoate 1 . o Procedure: 1. To a m ix ing vesse l , charge t h e Mas i l EM 250 C and Mas i l

EM 10,000 C. S t a r t g e n t l e a g i t a t i o n . Slowly add t h e water so as no t t o break t h e emulsion.

g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l components a re d isso lved, and t h e s o l u t i o n i s f r e e o f " f i s h eyes". Charge t h e sodium benzoate and mix u n t i l d i sso l ved .

3. Under g e n t l e a g i t a t i o n , add Par t 0 t o Par t A. Cont inue m ix ing g e n t l y t o avo id a i r entrapment. NOTE: Th i s formula i s designed to be used "as i s " . I f des i red , UV absorbers and o the r compon- en ts may be added t o t h e fo rmu la t i on .

2. I n a separate m ix ing vesse l , charge t h e Macol OP-10 SP and

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formula t ions


Carpe t & U p h o l s t e r y C l e a n e r

I n g r e d i e n t s : Dei o n i zed Water ( H o t ) SMA-2625 Res in Aqua Ammonia Sodi um L a u r y l S u l f a t e R i chami de 5725 Avanel 5-70 Dei o n i zed Water Dye, Fragrance, E t c .

p H ( a s i s ) : 8 . 0 - 9 . 0 Appearance: C l e a r l i q u i d S p e c i f i c G r a v i t y : 1 .016

Wt% 37.0

2 . 3 7 0 . 6 7

1 8 . 0 4 . 0 4 . 0

33 .96 As d e s i r e d

Procedure:

S l o w l y s i f t i n t h e SMA-2625 r e s i n t o a v o i d c l u m p i n g . Add t h e Aqua Ammonia, a p p l y c o o l i n g and mix w e l l u n t i l t h e r e s i n i s d i s s o l v e d . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s . I f t h e p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l w a t e r s h o u l d be r e s e r v e d f o r d i s s o l v i n g t h e dye. A f t e r t h e dye i s t h o r o u g h l y mixed, t h e dye s o l u t i o n may be added t o t h e p r o d u c t . S top a g i t a t i o n t o p e r m i t d e a e r a t i o n o f t h e p r o d u c t p r i o r t o f i l l i n g o f f .

Notes :

i s p a r t i c u l a r l y e f f e c t i v e a t removing o i l s t a i n s . Use a s - i s on c a r p e t i n g . D i l u t e 1O: l and 5 : l w i t h w a t e r f o r u p h o l s t e r y . N o t e : The dye s h o u l d b e t h o r o u g l y screened t o a v o i d f a b r i c s t a i n i n g .

Charge t h e h o t w a t e r t o t h e m i x i n g v e s s e l and s t a r t a g i t a t i o n .

T h i s i s a g e n e r a l pu rpose o i l y s t a i n remover. T h i s f o r m u l a t i o n

F o r m u l a t i o n CP-101

L i q u i d Steam Carpe t C1 eaner F o r Hard Water Systems

I n g r e d i e n t s : Sodium Metas i 1 i c a t e A T e t r a p o t a s s i u m Pyrophosphate Emphos PS-331 Macol NP 11 D e i o n i z e d Water



Wt% 7 . 5

12.5 4 . 0 1 . o

7 6 . 0


F1 oor C leaner

I n g r e d i e n t s : M a z a m i de 1281 Sodi urn T r i p o l y p h o s p h a t e Tet rapotass ium Pyrophosphate Water


L i q u i d F l o o r C leaner

I n g r e d i e n t s : Macol NP 9 . 5 Sodi urn T r i p o l yphosphate T r i sod i urn Phosphate Sodi urn Metas i 1 i c a t e Pentahydra te Maphos 60A Water

Procedure: A d d i n g r e d i e n t s as l i s t e d . NOTE: T h i s f o r m u l a t i o n i s s t a b l e t o 120F.

F l o o r Scrubber

I n g r e d i e n t s : Sodi urn Metas i 1 i c a t e Tet rasod ium Pyrophosphate Emphos PS-331 De ion ized Water Mazami de 1281 Sodium Hydrox ide , 50%

Procedure :


Add i n g r e d i e n t s as l i s t e d .

wtsl, 8.0 2.0 2 .0

8 8 . 0

Q 7 . 0 8 . 0 2 . 0 2 . 0 3 . 0

78 .0

2 . 0 18.0 1 5 . 0 53.95

6 . 0 5 .05


Household C a r p e t F r e s h e n e r / A n t i s t a t

I n Q r e d i e n t s : P a r t A : P u f f e d Borax (10 l b s / c u f t ) F rag rance Sodi um B i c a r b o n a t e L a r o s t a t 519

P a r t 6: Sodi um B i c a r b o n a t e

Wt%

1 . 8 0 . 2

1 5 . 0 3 . 0

8 0 . 0

P rocedure :

f i r s t p o r t i o n o f sodium b i c a r b o n a t e . S t a r t m i x i n g and s l o w l y add t h e f r a g r a n c e . A f t e r a l l o f t h e f r a g r a n c e has been added, c o n t i n u e m i x i n g f o r 5 m inu tes t o comp le te a b s o r p t i o n . Add t h e L a r o s t a t 519 and t h e r e m a i n i n g sodium b i c a r b o n a t e . M i x f o r 15 m i n u t e s more.

Notes : T h i s i s a powdered c o m b i n a t i o n consumer f r e s h e n e r / a n t i s t a t .

The p r o d u c t i s des igned t o be shaken o n t o t h e c a r p e t , l i g h t l y rubbed i n t o t h e c a r p e t and t h e n t h e excess removed by vacuuming.

I n a r i b b o n m i x e r o r V-b lender , cha rge t h e p u f f e d bo rax and

F o r m u l a t i o n SP-I01

Pump Spray Carpe t A n t i s t a t

I n g r e d i e n t s : P a r t A : Water I s o p r o p y l A l c o h o l L a r o s t a t 264 A

Appearance: C l e a r , w a t e r - w h i t e t o p a l e - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 0.98

94.3 5 . 0 0 . 7

P rocedure :

p y l a l c o h o l and L a r o s t a t 88. M i x u n t i l c l e a r .

Notes : T h i s i s a non -ae roso l , pump sp ray c a r p e t a n t i s t a t f o r t h e

removal o f n u i s a n c e s t a t i c . T o remove s t a t i c f r o m c a r p e t i n g and o t h e r s u r f a c e s , s p r a y l i g h t l y w i t h t h i s f o r m u l a t i o n . I t i s n o t necessa ry t o s a t u r a t e t h e s u r f a c e . I f a d d i t i o n a l p r o t e c t i o n i s needed, i t i s p r e f e r a b l e t o have r e p e a t a p p l i c a t i o n s r a t h e r t h a n one, t o i n s u r e even t r e a t m e n t .

T o a m i x i n g v e s s e l , cha rge t h e w a t e r , f o l l o w e d by t h e i s o p r o -

F o r m u l a t i o n SP-102



h i qlai d L e a t h e r . V i nv l , and P l a s t i c C leaner and R e s t o r e r

I n q r e d i e n t s : DeSonic 9N Dowanol PM G l y c o l E t h e r I s o p r o p y l A l c o h o l Amy1 A c e t a t e Water

Wt% 1 0 . 0

5 . 0 2 . 5 1 . o

81 . 5

B l e n d i n g I n s t r u c t i o n s : Combine i n g r e d i e n t s i n t h e o r d e r shown and mix t h o r o u g h l y .

Use I n s t r u c t i o n s : App ly f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . )

and w i p e o n t o t h e s u r f a c e t o be c leaned , t h e n r i n s e . A l t e r n a t i v e - l y , sp ray o n t o t h e s u r f a c e t o be c leaned , a l l o w t o s e t a few m i n u t e s , t h e n r i n s e or hose o f f .

P roduc t I n f o r m a t i o n : P r o d u c t : B e n e f i t : DeSonic 9N D e t e r g e n t and degreaser Dowanol PM G l y c o l E t h e r S o l v e n t and c o u p l i n g agen t Amyl A c e t a t e S o l v e n t I s o p r o p y l A l c o h o l Sol v e n t

Formula 1000

L i q u i d Leather, V i n y l , and P l a s t i c C leaner

I n Q r e d i e n t s : W i t c o n o l NP-100 Dowanol PM G l y c o l E t h e r I s o p r o p y l A l c o h o l Amy1 A c e t a t e Water

Wt% 1 0 . 0

5 . 0 2 . 5 1 . o

8 1 . 5

B l e n d i n g I n s t r u c t i o n s : Combine i n g r e d i e n t s i n t h e o r d e r shown and mix t h o r o u g h l y .

Use I n s t r u c t i o n s : App ly f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . )

and w ipe o n t o t h e s u r f a c e t o be c leaned , t h e n r i n s e . A l t e r n a t i v e - l y , sp ray o n t o t h e s u r f a c e t o be c leaned , a l l o w t o s e t a few m inu tes , t h e n r i n s e o r hose o f f .

P roduc t I n f o r m a t i o n : B e n e f i t : W i t c o n o l N P - 1 0 0 D e t e r g e n t and degreaser Dowanol PM G l y c o l E t h e r S o l v e n t and c o u p l i n g agen t Amyl A c e t a t e So l v e n t I s o p r o p y l A1 coho1 Sol v e n t

Formula 1001



Low Cost E x t r a c t i o n C a r p e t C leaner

I n g r e d i e n t s : Water, D . I . P e t r o 22 Powder EDTA Powder Perfume

81 end ing P rocedure : B1 end i n g r e d i e n t s i n t h e o r d e r 1 i steci.

Use D i l u t i o n : 1-2 o z / g a l of w a t e r Formula 901

91 . o 5 . 0 4 . 0 q. s .

Premium, Medium Du ty Steam E x t r a c t i o n C a r p e t C leaner

I n q r e d i e n t s : Sodi um T r i p o l y p h o s p h a t e , L i g h t D e n s i t y Sodi urn Metas i 1 i c a t e , Pen tahyd ra te P e t r o 22 Powder O p t i c a l B r i g h t e n e r

B l e n d i n g P rocedure : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .

Use D i l u t i o n : 1-2 o z / g a l Formula 904

Heavy Du ty Steam E x t r a c t i o n C a r p e t C leaner

I n q r e d i e n t s : Sodium Carbonate (Soda Ash) T r i s o d i u m Phosphate, C r y s t a l Sodium M e t a s i l i c a t e , Pen tahyd ra te Sodium S u l f a t e ( S a l t Cake) P e t r o 22 Powder

B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d

Use D i l u t i o n : 1-2 o z / g a l Formula 905


6 5 . 0 29.5

5 . 0 0 .5

W t % 1 0 . 0 10 .0 20 .0 56.0

4 . 0


Low Foaming C a r p e t E x t r a c t o r D e t e r g e n t

Component: Sodi um B i c a r b o n a t e STPP Burco LAF-6 Burco SZS Burcosperse AP Powder B u r c o t a s e SP-60 ( i f d e s i r e d ) F rag rance

Wt% t o 100% t o t a l

47 .0 2 . 5 0 .25 2 . 5 1 . o

as d e s i r e d

Procedure:

u n t i l absorbed. Add Burco SZS, t h e n Sodium B i c a r b o n a t e and b l e n d u n t i l u n i f o r m . Add Burcosperse A P Powder (and i f d e s i r e d ) Bu rco tase SP-60. B l e n d u n t i 1 u n i f o r m .

Use C o n c e n t r a t i o n :

Spray LAF-6 (and i f d e s i r e d ) f r a g r a n c e o n t o STPP and b l e n d

2-3 ounces p e r g a l l o n i n e x t r a c t o r .

SOURCE: B u r l i n g t o n Chemical Co. , I n c . : Suggested F o r m u l a t i o n s

RUQ Steam C l e a n e r ( L i q u i d )

S o i l - Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and grease, c l a y and p a r t i c u l a t e

S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method - Rug sc rubber Manu fac tu re - M i x t a n k w i t h p r o p e l l e r s t i r r e r

Compos i t i on : Water Metso Beads 2048 Sodium Xy lene S u l f o n a t e , 40% C12-Cl5 L i n e a r A l c o h o l , 12 Moles EO

Use D i 1 u t i on : 4 .7-9.4% bw (6 -1 2 o z / g a l 1 o n )

SOURCE: The PQ C o r p . : Suggested F o r m u l a t i o n

Wt% 7 9 . 6

7 . 0 6 . 7 3 .9


No Rinse F loor Cleaner

I npred i ent s : Water, D.I. Sodi um Carbonate Rewoteric AM 8-14 Versene 100 Butyl Cel losolve

\Mt% 79.0 4.0 10.0 2.0 5 . 0

Blending Procedure:

each addi t i on. Formula 932

Add ingredients i n order shown and d isso lve completely between

Heavy D u t y F loor Cleaner

Ingredients : Water, D.I. Varami de A-1 2 T r i sodi um Phosphate Sodium Tripolyphosphate

Wt% 78.0 7.0 10.0 5.0

81 end$ ng Procedure:

each add i t i on .

Typical Propert i es : Sol ids: 22.0%

Formula 933


No-Rinse Floor Cleaner Deareaser

Ingredients : Deionized water Sodium carbonate Rewoteric AM V Versene 100 Buty l Cel losolve

WtO/o 79.0 4.0 10.0 2.0 5.0

Blending Procedure:

each add i t i on .

Typical Proper t ies: Sol ids: 8.1% pH: 10.9 V iscos i t y : 4 cps

Formula 951

SOURCE: Witco Corp. : Suggested Formulations



Wax S t r i p p e r ( A )

I n q r e d i e n t s : O l e i c Ac id Monoethanol ami ne Avanel S-74 Potassium Hydroxide, 45% Sodi um Hydroxide, 50% Versene 100 Dowanol TBA Water


Wax S t r i p p e r (B)

I n a r e d i e n t s : O l e i c Ac id Monoethanolamine Avanel S-74 Potassium Hydroxide, 45% Sodi um Hydroxide, 50% Versene 100 Ethylene G1 yco l Monobutyl Ether Water


Concentrated Wax S t r i p p e r

I n a r e d i e n t s : Sodium Hydroxide, 50% Macol NP 9 . 5 EDTA, 40% Mazox LDA Barquat MB-50 Monoethanolami ne Water

Wt% 7.0 2.0 2.0 1 . o 1 . o 1 . o 5 . 0

81 . o

7 .0 2.0 2.0 1 . o 1 . o 1 . o

81 . o 5.0

WtO/o 6 . 5 1 . o 0.5 1 . o 1 . o 8.5 81 .5

Procedure:

Mac01 NP 10 .5 can be s u b s t i t u t e d f o r t h e Macol NP 9 . 5 . Mafo CB-40 can be s u b s t i t u t e d f o r t h e Mazox LDA.


Add i n g r e d i e n t s as l i s t e d . To use, d i l u t e 1:lO t o 1:30.

14. Miscellaneous

1 fi7

Miscellaneous 163

B a c t e r i o s t a t i c C o n c e n t r a t e w/Pine 021 I n q r e d i e n t s : Wt% Phase I : I s o p r o p a n o l 1 0 . 0 O l e i c A c i d 8 . 8 Varox 1770 5 . 0 P i n e O i 1 12 .0 Phase 11: Water, D . I . 62 .2 P o t a s s i um H y d r o x i d e (87%) 2 .0 81 end i ng Procedure :

Combine Phase I i n g r e d i e n t s and m ix t h o r o u g h l y . Combine Phase I T i n g r e d i e n t s and m ix t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase 11. T y p i c a l P r o p e r t i es :

V i s c o s i t y , c p s : 5 S o l i d s : 10.6% pH: 9 . 3

Formula 302

_ ~ ~ _ _ _ _ _ _ _ _ ~ ~ Genera l D i s i n f e c t a n t S o l u t i o n I n g r e d i e n t s : Water . D . I .

wtsl, 68 .0

Varquat 50 MC 10 .0 G1 y o x a l (40%) 5 . 0 R e w o t e r i c AM DML-35 1 7 . 0 B l e n d i n g P rocedure :

each add1 t i on, T y p i c a l P r o p e r t i e s :

V l s c o s l t y , c p s : 4 Sol 1 ds: 13.0% pH: 7 . 1

Add i n g r e d i e n t s 1 n o r d e r shown and d i s s o l v e c o m p l e t e l y between

Formula 303

H o s p i t a l D i s i n f e c t a n t -~ I n g r e d i e n t s : Wt% Water , D . I . 84 .2 V a r i q u a t 50 MC 9 . 6 Varox 365 4 . 0 Versene 100 1 . 5 Sod1 urn H y d r o x i d e (30%) 0 . 7 B l e n d i n g P rocedure :

each a d d i t i o n . T y p i c a l P r o p e r t i e s :

V i s c o s i t y , c p s : 4 S o l i d s : 6 .7% pH: 12.2

Formula 304

SOURCE: W i t c o C o r p , : Suggestecl F o r m u l a t i o n s


I64 Advanced Cleaning Product Formulations

C u t t i n g O i l C o n c e n t r a t e

I n g r e d i e n t s : Wei s h t % A r i s t o n a t e M 36 .00 I g e p a l CO-430 20 .00 TEA, 85% 8 . 0 0 O l e i c A c i d 8 .00 100 SUS Naph then ic O i l 2 8 . 0 0 Comments abou t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . Emuls ion - D i l u t e 4:76 w i t h 160 ppm h a r d w a t e r .


C u t t i n g O i 1

I n g r e d i e n t s : A r i s t o n a t e M TEA, 85% T a l l O i l A c i d , A c t i n o l FA-1 Calamide SM 100 SUS Naph then ic O i l Water Comments abou t t h i s f o r m u l a :

Emuls ion - D i l u t e 4:76 w i t h 160 ppm h a r d w a t e r . F o r m u l a t i o n SOL-004-01

Wei q h t % 10.50

0.90 1 . 2 0 1 .65

8 5 . 0 0 0 . 7 5

C o n c r e t e C1 eaner

I n g r e d i e n t s : Weight% C a l s o f t F-90 5 .00 Sodi um S i 1 i c a t e 30.00 Sodium Carbonate 30.00 Sodi um H y d r o x i d e 25 .00 Sodi um T r i phosphate 10.00 Comments abou t t h i s f o r m u l a :

G r i n d m i x t u r e t o g e t h e r t o y i e l d a s l i g h t l y t a c k y w h i t e powder. F o r m u l a t i o n CON-001-01

W h i t e W a l l C l e a n e r

I n s r e d i e n t s : Wei s h t % Water 60.20 C a l s o f t L-40 29 .30 P i l o t SXS-40 2 . 2 0 Na4 EDTA 1.30 Cal o x y l a t e N-9 7 .00 Comments abou t t h i s f o r m u l a :

V i s c o s i t y o f t h e p r o d u c t i s abou t 160 cPs a t room t e m p e r a t u r e . F o r m u l a t i o n TIR-001-01


Miscellaneous 165

d L i monene Water1 ess Hand C1 eaner

I n g r e d i e n t s : Phase I : Water, D . I . T r i s o d i u m Phosphate Sodium C i t r a t e G l y c e r i n

Phase 11: d - L i monene DeSonic 9N V a r o n i c T202

Wt%

81 . O 1 .o 2 . 0 2 . 0

7 . 0 5.0 2 . 0

B l e n d i n g Procedure: I n v e s s e l fit1 combine Phase I i n g r e d i e n t s and mix t h o r o u g h l y .

Heat t o 140F. Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l and m ix t h o r o u g h l y . Heat t o 140F. W h i l e m i x i n g r a p i d l y , add Phase 11 Po Phase I. Cool q u i c k l y t o s t a b i l i z e emu ls ion .

T y p i c a l P r o p e r t i e s : Appearance, Room Temp.: Heavy Cream S o l i d s : 12.0% pH: 10 .4

Formula 1120

Pas te Hand C leaner

I n g r e d i e n t s : Water, D . I . Varami de MA-1 Rewote r i c AM 8-15 W i t c o l a t e S E - 5

WtS/o 70 .0 10 .0 10.0 10 .0

81 e n d i n g Procedure:

each a d d i t i on.

T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 6360 S o l i d s : 19.5% pH: 8 . 7

Formula 1121




Dipen tene M i c r o e m u l s i o n F o r m u l a t i o n s

D ipen tene i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i n e o i l s c o n t a i n i n g r e l a t e d monocyc l i c t e r p e n e hyd roca rbons , predomi- n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same as l i m - onene. D-l imonene i s one o f t h e 2 o p t i c a l i somers o f d i p e n t e n e . ) O the r components o f commercial d i p e n t e n e i n c l u d e ca rene and a l p h a - and b e t a - p i n e n e .

N o n - a l k a l i n e F o r m u l a t i o n s

I n g r e d i e n t s : D i pen tene 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t Water

CPL, c : 1 1 CPH, C : 30 E m u l s i f i e r / D i p e n t e n e R a t i o : 1 .60

I n g r e d i e n t s : D i pen tene 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a Water

CPL, c : CPH, C : Emu1 s i f

i S u r f a c t a n t

11 50 e r / D i p e n t e n e R a t i o : 1 . 1 0

I n a r e d i e n t s : D i pen tene 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t Water

CPL, c : 19 CPH, C : 41 E m u l s i f i e r / D i p e n t e n e R a t i o : 0.90

&% 5 .00 6 . 4 0 0 .80 0 . 8 0

87 ~ 00

VVt.% 10 .00

8 . 8 0 1 . 1 0 1 . 1 0

79.00

Wt.% 20 .00 1 4 . 4 0

1 . 8 0 1 . 8 0

62.00

Add and m ix t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and emuls- i f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g .

t e m p e r a t u r e c l o u d p o i n t " .

SOURCE: Tomah Produc ts , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s

CPL i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h

Miscellaneous 167

D i pen tene M i c roemul s i on Formul a t i ons (Con t i nued)

D i pen tene i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i ne o i l s c o n t a i n i n g r e l a t e d monocyc l i c t e r p e n e hyd roca rbons , predom- i n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same as l i m o n - ene. D-l imonene i s one o f t h e 2 o p t i c a l i somers o f d i p e n t e n e . ) O the r components o f commercial d i p e n t e n e i n c l u d e ca rene and a l p h a - and b e t a - p i n e n e .

A l k a l i n e F o r m u l a t i o n s

I n g r e d i e n t s : D i pen tene 122 E-14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e Pen tahyd ra te

CPL, C : 15 CPH, C : 44 E m u l s i f i e r / D i p e n t e n e R a t i o : 2 .00

I n g r e d i e n t s : D i pen tene 122 E-14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e Pen tahyd ra te

CPL, c : 20 CPH, C : 46 E m u l s i f i e r / D i p e n t e n e R a t i o : 1 . 5 0

I n g r e d i e n t s : D i pentene 122 E- 14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e Pen tahyd ra te

Wt.96 5.00 8 . 0 0 0.50 1 . 50

83 .30 1 . 7 0

Wt.% 1 0 . 0 0 12 .00

0 . 7 5 2 . 2 5

73.50 1 . 5 0

Wt.% 20 .00 17 .60

1 . 1 0 3 . 3 0

56.80 1.20

CPL, C : 18 CPH, C : 43 E m u l s i f i e r / D i p e n t e n e R a t i o : 1 .I0 Add and mix t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and e m u l s i -

f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g .

t e m p e r a t u r e c l o u d p o i n t " .

SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s

CPL i s " l ow t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h


Hydrocarbon S o l v e n t M i croemul s i ons

Developed i n o r d e r t o o f f e r rep lacemen ts f o r expens ive d- l imonene and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have f l a s h p o i n t s above I O O C and l o w VOC c o n t e n t .

Formula A: I n g r e d i e n t s :

Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S o f t Water

Exxso l D-110

Formula 8 : I n a r e d i e n t s :


Exxso l D-110

Formula C : I n q r e d i e n t s :


Exxsol D-110

Exxso l D - I 1 0 F o r m u l a t i o n s

S u r f a c t a n t

S u r f a c t a n t

S u r f a c t a n t

\Nt.% 20 .0 11.9

5 . 4 4 . 3

5 8 . 4

Wt.% 30.0 17.9 8 . 1 6 . 5

3 7 . 5

Wt.% 4 0 . 0 2 3 . 9 1 0 . 8

8 . 7 1 6 . 6

Add each component i n t h e o r d e r g i v e n and m ix u n t i l homogeneous b e f o r e add ing t h e n e x t component. Add t h e w a t e r i n p o r t i o n s w i t h m i x i n g .

These m i c r o e m u l s i o n s s h o u l d be c l e a r and s t a b l e i n t h e temp- e r a t u r e range f r o m 20-37C. O u t s i d e t h a t range t h e y may c l o u d or separa te , b u t w i l l r e g a i n c l a r i t y upon r e t u r n i n g t o room temp- e r a t u r e . I f i t i s necessary t o r a i s e t h e c l o u d p o i n t t empera tu re , a s m a l l amount o f a d d i t i o n a l Tomah A l k a l i S u r f a c t a n t s h o u l d be added.

SOURCE: Tomah Produc ts , I n c . : Suggested F o r m u l a t i o n s

Miscellaneous 169

Hydrocarbon S o l v e n t M i c r o e m u l s i o n s ( C o n t i n u e d l

Developed i n o r d e r t o o f f e r rep lacemen ts f o r expens ive d- l imonene and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have f l a s h p o i n t s above 1OOC and l o w VOC c o n t e n t .

Isopar M F o r m u l a t i o n s

I s o p a r M can be s u b s t i t u t e d d i r e c t l y f o r t h e Exxso l D-110 i n t h e above f o r m u l a t i o n s . I n a d d i t i o n , two f o r m u l a t i o n s w i t h l ower s o l v e n t c o n t e n t have been deve loped .

Unbui 1 t : Component: S o f t Water Sodium Metas Tomah E-14-2 Tomah E-14-5 Tomah A1 k a l i I s o p a r Wi

l i c a t e Pen tahyd ra te

S u r f a c t a n t

L i g h t l y b u i 1 t : Component: S o f t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S u r f a c t a n t I s o p a r M

Wt.% 83 .0

0 . 0 4 . 7 4 .7 1 . 6 6 . 0

Wt.% 7 9 . 0

1 . o 5 . 6 5 . 6 1 . a 7 . 0

S t a r t by d i s s o l v i n g t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r . Then add t h e E-14-2, E-14-5, and A l k a l i S u r f a c t a n t . M ix u n t i l homogeneous. F i n a l l y add t h e I s o p a r M i n p o r t i o n s w i t h m i x i n g . The m i x t u r e w i l l c l o u d , t h e n s h o u l d c l e a r as t h e l a s t o f t h e I s o p a r M i s added. These m i c r o e m u l s i o n s w i l l be c l e a r and s t a b l e i n t h e t e m p e r a t u r e range f r o m 20-5OC. The c l o u d p o i n t can be r a i s e d f u r t h e r by add ing a sma l l amount o f a d d i t i o n a l A l k a l i S u r f a c t a n t .

SOURCE: Tomah Produc ts , I n c . : Suggested F o r m u l a t i o n s


Lo!. . V i_s_cosi_tv_s_jlicon ..Emu 1- si- o~n-UsinxPemulen s resins

S i l i c o n e o i l can b e e m u l s i f i e d and s t a b i l i z e d v i a t h e use o f Pemulen r e s i n s . The r e s i n s s t a b i l i z e emu ls ions v i a e l e c t r o s t a t i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e e k i n g an approp- r i a t e s u r f a c t a n t e m u l s i f i e r .

I n y c e d i e n t l D I Water Pemulen 1622 ( 1 ) Makon 10 ( 2 ) Dow 200 S i l i c o n e F l u i d ( 3 ) T r i e t h a n o l a m i n e

W t"/. 8 3 . 8 0

0 . 2 0 0 . 7 0

1 5 . 0 0 0 . 3 0

P h y s i c a l P r o p e r t i e s : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm) : 1,000 cp P roduc t p H : 7 . 3 P roduc t C l a r i t y : Opaque

Raw M a t e r i a1 Suppl i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan C o . ( 3 ) Dow C o r n i n g

P rocedure : 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an

i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s Screen t h e Pemuleri r e s i n int.o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o mix u n t i l homogeneous and f r e e o f po l ymer lumps.

2 . Add t h e Makon 10 and mix u n t i l homogeneous. 3 . Add t h e s i l i c o n e o i l w i t h v i g o r o u s a g i t a t i o n . M ix u n t i l

4 . Add t h e T E A . M i x u n t i l smoot.h.

T o t a l A c t i v e s :

u n i f o r m .

S i l i c o n e O i l : 1 5 . 0 0 %


Miscellaneous 171

Lumi n i z i n g P e t C o n d i t i o n e r

P h o s p h o l i p i d EFA adds s h i n e and a s i l k y t e x t u r e t o t h e a n i m a l ' s c o a t o r mane. The Monaquat TG p r o v i d e s body b u i l d i n g c o n d i t i o n i n g and d e t a n g l i n g w h i l e l e a v i n g a s o f t smooth f e e l . Monaquat I S I E S i s an e f f e c t i v e l o n g l a s t i n g a n t i s t a t t h a t c o n t r o l s d i r t a t t r a c t i o n .

I n a r e d i e n t s : Wt% Water 85.2 H y d r o x y e t h y l C e l l u l o s e 0 . 8 S t e a r i c a c i d 2.0 S t e a r y l a l c o h o l 2 . 0 Monaquat TG 7 . 0 Monaquat I S I E S ( I s o s t e a r y l E thy lm idon ium E t h o s u l f a t e ) 0 . 5 P h o s p h o l i p i d EFA ( L i n o l e a m i d o p r o p y l PG-Dimonium C h l o r i d e

Phosphate) 2 . 0 Sodium C h l o r i d e 0 .5

P rocedure :

l o s e and t u r n h e a t on. A t 50-60C add s t e a r i c a c i d , s t e a r y l a l c o h o l , Monaquat TG, Monaquat ISIES, P h o s p h o l i p i d EFA, and sodium c h l o r i d e . Heat and mix t o 70-75C ( a smooth creme). Cool t o 40C. A d j u s t pH t o 4 .5 -5 .0 . A d d c o l o r , f r a g r a n c e and p r e s e r v - a t i ve . Package.


Change w a t e r w i t h a g i t a t i o n , s p r i n k l e i n h y d r o x y e t h y l c e l l u -

Appearance: Opaque v i s c o u s l o t i o n Recommended Use D i l u t i o n : As i s


Pe t Shampoo

A h i g h foaming, m i l d d e t e r g e n t wh ich w i l l l e a v e you r p e t f r e s h and c l e a n .

I n g r e d i e n t s : Water Monaterge 779 d -L i monene

Wt% 70.0 25 .0

5 .0

P rocedure :

pH t o 7 . 0 . Add c o l o r and p r e s e r v a t i v e . Package.


Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t

Appearance: C l e a r y e l l o w l i q u i d

Recommended Use D i l u t i o n : 1 :50 w i t h w a t e r F o r m u l a t i o n F-774



M i cro-Emu1 s i ons with d-Li monene

The f o l l o w i n g c o n c e n t r a t e s a r e c l e a r , m ic ro-emuls ions o f imonene and w a t e r . These f o r m u l a s a r e g e n e r a l l y used by u t i n g i n water a r e v e r y e f f e c t i v e f o r removing many o i l y

. .I r e s i n o u s s o i l s . The f o r m u l a themselves a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n .

Formula I

I n q r e d i e n t s : d - L i monene Monamul se dL-1273 Water

I n q r e d i e n t s : d -L i monene Monamulse dL-1273 Isopropano l Water

I n g r e d i e n t s : d -L i monene Monamul se dL-1273 Water

Formula I1

Formula I11

Wt% 10 .0 18 .0 62.0

Wt% 35.0 28.0

5 . 0 32.0

Wt% 6 5 . 0 23 .0 12 .0

Procedure:

Add o t h e r i n g r e d i e n t s except w a t e r . M i x u n t i l homogeneous. Add water s l o w l y w i t h s t i r r i n g .

Recommended Use D i l u t i o n : 1 :10 w i t h water

SOURCE: Mona I n d u s t r i e s , I n c . : F o r m u l a t i o n F-786

I n a l l cases, mix s u r f a c t a n t w i t h d-Limonene u n t i l d i s s o l v e d .

Miscellaneous 173

M i cro-Emu1 s i ons w i t h P i ne O i 1

The fol 1 owi ng f o r m u l a s a r e c l ear m i c roemul s i ons o f p i ne o i 1 and w a t e r . They r e p r e s e n t t h e range o f p i n e o i l and w a t e r concen- t r a t i o n s commonly used. The f o r m u l a s themse lves a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n .

Formula 1

I n a r e d i e n t s : P i n e O i l Monamulse TRP Water Appearance: C l e a r D i l u t i o n (1% i n t a p w a t e r ) : Blooms

Formula 2

I n g r e d i e n t s : P i n e O i l Monamul se TRP I s o p r o p a n o l Water Appearance: C1 e a r D i l u t i o n (1% i n t a p w a t e r ) : Blooms

Formula 3

I n g r e d i e n t s : P i n e O i l Monamul se TRP I s o p r o p a n o l Water Appearance: C1 e a r D i l u t i o n (1% i n t a p w a t e r ) : Blooms

Formula 4

I n q r e d i e n t s : P i n e O i l Monamul se TRP Water Appearance: C l e a r D i l u t i o n (1% i n t a p w a t e r ) : C l e a r

&y& 35.0 2 0 . 0 45 .0

WtO/o 2 0 . 0 2 0 . 0 5.0

5 5 . 0

Wt% 9 . 0

10 .0 1 0 . 0 71 .O

WtO/o 2 . 0 5 . 0 93.0

Procedure : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package Recommended Use D i l u t i o n : 1:lO w i t h w a t e r

Formula F-785



P l a s t i c B o t t l e Wash S t a b l e i n h a r d w a t e r

I n q r e d i e n t s : Water

K a s i l # I STPP Burco HCS-5ONF

KOH-45%

% S o l i d s : 31.0

Wt% 2 6 . 5 1 9 . 5 39.0

8 . 0 7 . 0

Add components i n o r d e r l i s t e d . B l e n d between a d d i t i o n s .

To f o r m u l a t e a l o w e r a c t i v i t y p r o d u c t , keep t h e r a t i o of t h e components t h e same, so t h a t t h e b a l a n c e o f t h e f o r m u l a t i o n i s n o t d e s t r o y e d . End use c o n c e n t r a t i o n s w i l l depend o n degree o f s o i l t o be removed. Norma l l y , a 2% end use c o n c e n t r a t i o n i s s u f f i c i e n t f o r b o t t l e c l e a n i n g .

A s l i g h t s i l i c a t e p r e c i p i t a t e may o c c u r upon l o n g s t a n d i n g .

B o t t l e Wash F o r m u l a t i o n s Low Foam

I n q r e d i e n t s : 50% NaOH Burco BSGH-270 Burco HCS-50NF

Add BSGH-270 and HCS-50 NF t o 50% NaOH.

Moderate Foam

I n q r e d i e n t s : 50% NaOH Burco BSGH-270 Burco NPS-225 Water

y& To 100% T o t a l

2 .5-5.0% 0.5-2.5%

W O

To 100% T o t a l 2 .5 -5 .0% 0.5-2.5% 3.0-7.5%

I t i s recommended t h a t t h e BSGH-270 and NPS-225 b e d i s s o l v e d i n an equa l amount o f wa te r and t h e c a u s t i c added t o t h a t p r e m i x . To defoam t h i s f o r m u l a t i o n use a 3/1 r a t i o o f NPS-225/Burco LAF-I 25.

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s

Miscellaneous 175

Teroene M i croemul s i ons

The f o r m u l a t i o n s g i v e n h e r e w i l l p roduce c l e a r s t a b l e m i c r o -

G l i d s o l 180 ( f r o m SCM G l i d c o Organ ics C o r p . ) , a p i n e o i l emu ls ions c o n t a i n i n g f r o m 15% t o 40% d - l imonene .

d e r i v a t i v e can be s u b s t i t u t e d f o r d- l imonene i n t h e f o r m u l a t i o n s t o g i v e a f l a s h p o i n t above 140F. N o t e t h a t o t h e r p i n e o i l s may n o t work i n t h e s e f o r m u l a t i o n s . Formula A : D-Limonene 40 .0 Tomah E-14-5 2 2 . 4 Tomah E-14-2 2 . 8 Tomah A l k a l i S u r f a c t a n t 2.8 Water 3 2 . 0

% t o t a l s u r f a c t a n t : 28.0% Emul s i f i e r /Te rpene r a t i 0: 0 .700

Formula 5: Wt.9/o D-Li monene 30 .0 Tomah E-14-5 19 .2 Tomah E-14-2 2 . 4 Tomah A l k a l i S u r f a c t a n t 2 . 4 Water 4 6 . 0

% t o t a l s u r f a c t a n t : 24.0% Emul s i f i er /Te rpene r a t i 0: 0 .800

Formula C : Wt.% D-Li monene 2 0 . 0 Tomah E-14-5 1 2 . 8 Tomah E-14-2 1 . 6 Tomah A l k a l i S u r f a c t a n t 1 . 6 Water 64 .0

% t o t a l s u r f a c t a n t : 16.0% E m u l s i f i e r / T e r p e n e r a t i o : 0 .800

Formula D : Wt.o/a D-Li monene 15 .0 Tomah E-14-5 1 2 . 0 Tomah E-14-2 1 . 5 Tomah A l k a l i S u r f a c t a n t 1 . 5 Water 7 0 . 0

% t o t a l s u r f a c t a n t : 15 .0% E m u l s i f i e r / T e r p e n e r a t i o : 1 . 0 0 0 Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogen-

eous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s w i t h m i x i n g .

1-2% d - l imonene a t use l e v e l i s u s u a l l y s u f f i c i e n t . Heavy g rease would r e q u i r e a h i g h e r c o n c e n t r a t i o n o f d - l imonene .

C o n c e n t r a t e d Formula Formula: D-Limonene 70 .0 Tomah E-14-5 1 4 . 0 Monamid 705 4 . 0 T a l l O i l F a t t y A c i d 1 . 6 Monoethanolamine 0 .4 Water 1 0 . 0 SOURCE: Tomah Produc ts , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s

A t y p i c a l use l e v e l would b e a t 10/1 t o 40/1 w i t h w a t e r . About


Wax Emulsion Using Pemulen Resins

Th is wax emulsion can be c rea ted and s t a b i l i z e d v i a t h e use o f Pemulen r e s i n s . The r e s i n s s t a b i i z e emulsions v i a e l e c t r o s t a t - i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e l e c t i n g an approp r ia te s u r f a c t a n t e m u l s i f i e r .

I n g r e d i e n t : Bareco C-36 Wax (1) Hoechst Wax E ( 2 ) Pemulen 1622 (3 ) 01 Water Morphol i ne

vytsb 12.00

8 . 0 0 0.30 79 ~ 50

0 . 2 0

Phys ica l P roper t i es :

Raw M a t e r i a l Supp l i e rs :

Product C l a r i t y : Opaque

(1 ) P e t r o l i t e Corp. ( 2 ) American Hoechst Corp. ( 3 ) BFGoodrich

Procedure: 1. Me l t t h e waxes together i n a vesse l , approx imate ly a t 9 0 C . 2 . Use a L i g h t n i n ' M ixer o r s i m i l a r v a r i a b l e speed u n i t and an

i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions Screen t h e Pemulen r e s i n i n t o t h e vo r tex o f t h e r a p i d l y a g i t a t i n g water (800 rpm). A l low t o mix u n t i l homogeneous and f r e e o f polymer lumps.

3. Heat t h e Pemulen d i spe rs ion t o 9OC. Add t h e Pemulen d i spe r - s i o n t o t h e mel ted wax w i t h v igorous a g i t a t i o n .

4 . Add t h e morphol ine and cool q u i c k l y .

T o t a l Ac t i ves : T o t a l Wax: 20.00%


Section I I sportation Cleaners

and Polishes

177

15. Auto Cleaners and Polis

1 78

Auto Cleaners and Polishes 179

Chrome P o l i s h

I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended. The r e s i n a l s o prevents "creaming" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .

I n g r e d i e n t : D I Water Morphol i ne Pumice Snow F loss SFSB S i l i c o n e F l u i d (350) ( 1 ) Yarmor 302 P ine O i l ( 2 ) O l e i c Ac id Minera l S p i r i t s TEA l a u r y l s u l f a t e ( 3 ) Cocamide DEA (4 ) D I Water Carbopol EZ-2 (5 )

39.25 1.39

14.00 9 . 2 5 1.85 0.46 1.85

24.50 2.30 0.50 4.46 0.19

Phys ica l P roper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 10,800 cp Product pH: 9 .0 Product C l a r i t y : Opaque

Raw M a t e r i a l Supp l i e rs : ( 1 ) General E l e c t r i c (2 ) Hercules ( 3 ) Rhone-Poul enc ( 4 ) Henkel: Standamid PO ( 5 ) BFGoodri ch

Procedure: 1 . D isso lve t h e morphol ine i n t h e water . 2 . Wi th r a p i d a g i t a t i o n , add t h e pumice and Snow F loss . 3 . D i sso l ve t h e s i l i c o n e o i l , p i n e o i l , and o l e i c a c i d i n t h e

minera l s p i r i t s . S lowly add i n t o t h e above m ix tu re w i t h r a p i d a g i t a t i o n .

4 . Add i n t h e TEA l a u r y l s u l f a t e and Standamid PD. Blend t h o r - oughl y .

5. I n a separate vessel , d i spe rse 0.19 p a r t s o f Carbopol i n t o 4.48 p a r t s o f water by s imp ly "dumping" t h e polymer i n t o t h e water. I n j u s t a few minutes, t h e polymer w i l l comple te ly wet o u t . Add t h i s d i spe rs ion t o t h e above m ix tu re . Blend thorough1 y .

T o t a l Asti ves : S i l i c o n e F l u i d : 1 .85 T o t a l Su r fac tan t : 4.65 Minera l S p i r i t s : 24.50 T o t a l Abrasives: 23.25

FGoodrich Spec ia l t y Chemicals: DET-551


L i q u i d Car Polish

I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d value a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended. The r e s i n a l s o prevents "creaming" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .

I n s r e d i e n t : D I Water T r i ethanol ami ne Wax Emulsion ( 1 ) Morphol i ne SF90 S i l i c o n e F l u i d (350) (2 ) O l e i c Ac id Kerosene Minera l S p i r i t s D I Water Carbopol EZ-2 (3 ) Isopropanol Minera l S p i r i t s SF1706 React ive Amine Polymer ( 4 ) SF1705 React ive Amine Polymer ( 4 ) Kaopo l i t e k a o l i n c l a y ( 5 )

Wt96 37.80

8.20 2.50 2.00 1 * 50 2.50

10.00 8.00 49.70 0.30 0 . 4 0 5 .00 1.50 2.10 8.50

Physical P roper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 cps Product pH: 8-9 Product C l a r i t y : Opaque

Raw M a t e r i a l Supp l ie rs : (1 ) see EiFGoodrich L i t e r a t u r e DET-501 ( 2 ) General E l e c t r i c (3) BFGoodrich ( 4 ) General E l e c t r i c ( 5 ) Kaopo l i te , I n c .

Procedure: 1. Mix together t h e water, TEA, wax emulsion, and t h e morpholine 2 . I n a separate vessel , mix t h e s i l i c o n e f l u i d , o l e i c ac id ,

kerosene and t h e mineral s p i r i t s t oge the r . Add t h i s t o t h e above m ix tu re w i t h v igorous a g i t a t i o n .

3. I n a separate vessel, d isperse 0.30 p a r t s o f Carbopol i n t o 19.70 p a r t s o f water by s imp ly "dumping" i t i n . The polymer w i l l wet ou t i n a few minutes. Add t h i s d i spe rs ion t o t h e above m ix tu re . Mix u n t i l homogeneous.

4 . I n a separate vessel , mix t h e isopropanol , m inera l s p i r i t s , and t h e two r e a c t i v e amine polymers toge the r . Add t o t h e above m ix tu re . Mix u n t i l homogeneous.

5. Slowly add i n t h e c l a y . Mix u n t i l homogeneous. To ta l Ac t i ves :

To ta l Wax : 0.50 S i l i c o n e F l u i d : 1.50

React i ve Ami ne Polymer : 3.60 Abrasive: 8.50

Minera l S p i r i t s : 11 .oo

SOURCE: BFGoodrich Spec ia l t y Chemicals: DET-BOO

Auto Cleaners and Polishes 181

Liquid Spray Cleaner f o r A luminum Trucks

Bngredi en ts : Water Phosphoric Acid, 75% C i t r i c Ac id Macol 48 Ammoni um B i f 1 u o r i de Avanel S-30

- W t % 5 0 . 0 20.0 1 0 . 0 4 . 0 3.0 3.0

~ r ~ c ~ d U r ~ ~

w i t h f i v e p a r t s water t o use. Add i n g r e d i e n t s i n order as l i s t e d . D i l u t e one p a r t c leaner

A1 umi num Cleaner/Br i nhtener

Pnaredi en t : Phosphoric Acid, 85% C i t r i c Acid, 50% N i t r i c Acid, 70% Avanel S-70 Water

Wt% 6.0 8.0 1 .o 2.0

83.0

Procedure:

and w i t h due care, add t h e ac ids t o t h e water. Add t h e Avanel S-70 and mix f o r 10 minutes. Note: I f a d d i t i o n a l b r i g h t e n i n g i s requ i red , t h e n i t r i c a c i d may be increased t o 1.5%.

Charge t h e water t o t h e mix ing vesse l . Under slow a g i t a t i o n

Formulat ion CM-101

Non-Phosphorous A l u m i n u m Cleaner

Ina red i en t : C i t r i c Acid, 50% Gluconic Acid, 50% Avanel 5-70 Water, Dye

Wt% 12.0 8.0 3.0

77.0

PPOC@dUr&?: Charae t h e water, c i t r i c ac id , g lucon ic a c i d and Avanel S-70

t o t h e Gix ing vessei . M i x w e l l . I f - d y e i s t o be added, p a r t of t h e water should be h e l d ou t . Add t h e dye t o t h e water w i t h good a g i t a t i o n and then add t h e water t o t h e batch.

Formu 1 a t i on CM- 102

UWCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions


M i l d Abrasive Automobile Polish

I n q r e d i e n t : Par t A : Masi 1 SF 1,000 O l e i c Ac id Carnauba Wax #1 Yel low Isopar M Mazami de SS-1 0

Pa r t B: I sopar M Mas i l 123

Par t C : I sopar M Morphol i ne

Par t D: Water Kaopo l i t e SF

pH (as i s ) : 7 . 5 - 8 . 5 Appearance: Cream-Colored Paste

Wt%

4 . 0 2 . 0 6 . 0

14 .5 0 . 7 5

1 2 . 0 2.0

2 . 5 1 . 1

45.15 1 0 . 0

Procedure: 1 . Charge t h e components i n Pa r t A t o a steam-heated mix ing

vessel equipped w i t h a g i t a t i o n . S t a r t a g i t a t i o n and heat t o 9QC.

When Par t A reaches 9OC and a l l t h e wax has melted, add Par t B t o t h e vessel f o l l owed by Par t C . Apply c o o l i n g .

3 . I n a separate vessel , prepare Par t D by adding t h e Kaopoldte SF t o t h e water under a g i t a t i o n . Add Par t D t o Pa r t A and con t inue c o o l i n g . NOTE: The f i n i s h e d produc t i s a pas te . A s t i f f e r pas te can be prepared by i nc reas ing t h e o l e i c a c i d charge.

2 . I n separate vesse ls , charge Par t B and Par t C components.

SOURCE: PPG I n d u s t r i e s , I n c . : Formula t ion S A - 1 0 1

0 r and Truck Wash Compounds

183


Car Shampoo Concentrate

Th is fo rmu la t i on produces copious amounts o f foam w h i l e c lean ing automot ive f i n i s h e s . I t i s m i l d t o bo th t h e user and t h e automot ive f i n i s h .

I n g r e d i e n t : Pa r t A : Dei on i zed Water Sodi um C i t r a t e

Wt%

30 .0 0 . 5

Par t 8: Mafo CSB-50 5.0 Witconate 60 T L i q u i d 7 .5 Macol TD-12 4 . 0 T r i ethanol ami ne, 85% 1 . o Deionized Water 52.0

pH (as i s ) : 8 . 0 - 9 . 0 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.00

Procedure: 1 . Charge t h e f i r s t p o r t i o n o f water t o a m ix ing vessel and

d i s s o l v e t h e sodium c i t r a t e i n i t . 2 . Add t h e remaining i n g r e d i e n t s i n t h e order l i s t e d . Stop

a g i t a t i o n and pe rm i t t h e produc t t o deaerate p r i o r t o f i l l i n g o f f . NOTE: Use concen t ra t i on i s 1-2 ounces per g a l l o n o f warm water.

Automat ic Car Wash Concentrate

I n a r e d i e n t s : Dei on i zed Water Maphos 60-A Potassi um Hydroxide Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Anhydrous Macol LF 120 Mazamide 00 Sodium Xylene Su l fonate , 40% Macol 48 Deionized Water

pH (as i s ) : 12.5-13.5 Appearance: C lear , l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 .06

Procedure: Charge t h e f i r s t p o r t i o n o f water t o t h e m ix ing vessel and

s t a r t a g i t a t i o n . Add t h e i n g r e d i e n t s i n the order l i s t e d and mix u n t i l c l e a r . NOTE: Th is i s a h i g h l y a l k a l i n e c leaner designed t o be used i n commercial au tomat ic car washes a t a d i l u t i o n r a t e o f 1-2 ounces per g a l l o n . Do no t use d i r e c t l y on automot ive f i n i s h e s

Formula t ion CA-102

w.t% 50.0

6 . 0 3.0 2 .0 2 . 0 2 . 0 2 . 0 3 .0 3 . 0

27.0


1

Car and Truck Wash Compounds 185

I n g r e d i e n t s : Water NaOH, 50% D i e t h a n o l ami ne Cal s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam EA-603

Car Wash ( C a l s o f t LAS-gg-Basedl Weight%

72.50 2.40 0 .50

10 .10 3 .70 7.00 2.80

Ammonium C h l o r i d e Comments abou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-008-01

Car Wash ( C a l s o f t LAS-99-Based) I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam EA-603 Cal o x y l a t e N-9 Comments abou t t h i s f o r m u l a :

Add i n g r e d i e n t s i n o r d e r 1 i s t e d F o r m u l a t i o n CWC-007-01

Car Wash (Ca lsuds A-Based) I n g r e d i e n t s : Water Calsuds A Cal foam EA-603 Calsuds CD-6 Ammonium C h l o r i d e Comments abou t t h i s f o r m u l a :


Car Wash ( C a l s o f t T-60-Based) I n g r e d i e n t s : Water C a l s o f t T-60 Pi l o t sxs-40 Cal o x y l a t e N-9 Comments abou t t h i s f o r m u l a :


SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s

1 . o o

Wei q h t % 59.80

4 . 3 5 16.30

2 . 0 5 12 .50

3 .00 2 .00

Wei a h t % 64.20 28.00

2 . 8 0 4 .00 1 . o o

Weight% 70.00 20.00

5 . 0 0 5 . 0 0


Car Wash

Readi l y removes a wide v a r i e t y o f r o a d s o i 1 s .

I n g r e d i e n t s : Water 70 .0 Monaterge ALX-100s (Cocamide DEA (and) DEA Dodecyl -

benzenesu l fonate (and) D ie thano lamine) 3 0 . 0

Procedure:

t o 7 . 0 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e . Package. Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t pH

Typ i c a l P r o p e r t i e s : Appearance: C l e a r y e l l o w l i q u i d Recommnded Use D i l u t i o n : 1 :20 w i t h water


Paste Car Wax

T h i s e a s i l y a p p l i e d au tomobi le p a s t e wax f o r m u l a w i l l p r o v i d e improved c l e a n i n g , depth o f g l o s s , l a s t i n g beauty and s h i n e t o new and o l d e r a u t o m o b i l e f i n i s h e s . Monas i l PCA w i l l p r o v i d e s h i n e and d e t e r g e n t r e s i s t a n c e t o any p a s t e wax f o r m u l a .

I n g r e d i e n t s : P a r t I: Monas i l PCA Dimeth icone (12,500 c s t ) Carnauba Wax #1 Y e l l o w T a l l O i l F a t t y A c i d I s o p a r K Kaopol i t e 11 52

P a r t 11: Water TEA (99%)

Procedure: Prepare each phase s e p a r a t e l y , h e a t t o 70C.

s l o w l y t o P a r t I w i t h good a g i t a t i o n . S t i r coo package. F o r m u l a t i o n F-826

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formu

We96

4 . 5 2 .0 6 . 0 3 . 0

24 .0 1 0 . 0

5 0 . 0 0 . 5

Add P a r t II t o 40-50C and

a t i o n s


Car Wash w/Amphoter ic

I n g r e d i e n t s : Water, D . I . Sodi um T r i po l yphospha te R e w o t e r i c AM 8-14 Varon i c DM-55 Sodi um Hydrox ide , 30% W i t c o 1298SA

wt% 5 5 . 0

4 . 0 10.0 2 . 0 9 . 0

20 .0

B1 end i ng P rocedure :


T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 290 S o l i d s : 29.5% pH: 8 . 9

Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e compl e t e l y between

Formula 630

I n g r e d i e n t s : Water, D . I . I s o p r o p a n o l P e t r o BAF Powder DeSophos 5AP EDTA, 38%

W i n d s h i e l d Washer C o n c e n t r a t e

Wt% 5 6 . 0 30.0

1 . o 0 .5 2 . 5


Use "as i s " i n w i n t e r ; d i l u t e up t o 2 9 : l f o r summer use.

Formula 666

W i n d s h i e l d Washer F o r m u l a t i o n

I n q r e d i e n t s : W i t c o n a t e 1240 I s o p r o p a n o l Water


Formula 867


D i s s o l ve W i t c o n a t e 1240 i n wa te r , t h e n add i sopropanol

Wt% 1 . o

39.0 6 0 . 0


Car Wash C o n c e n t r a t e w /A lcoho l E t h o x y l a t e

I n q r e d i e n t s : Water , D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t cami de 128T

B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d

T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 210 A c t i v e s , %: 23 .7

Formula 61 1


I n g r e d i e n t s : Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t cami de 128T

B l e n d i n g P rocedure : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .

Typ i c a l P r o p e r t i es : V i s c o s i t y , c p s : 335 A c t i v e s , %: 37.5

Formula 611


I n a r e d i e n t s : Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t cami de 128T

B l e n d i n g P rocedure : B1 end i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .

T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 315 A c t i v e s , %: 43.0

Formula 611


64 .9 8 . 3

1 6 . 7 1 . 3 5 . 0 3 . 8

W S 4 3 . 3 13 .9 2 7 . 8

5 . 0 7 .0 3 . 0

3 6 . 0 15.0 30 .0

6 . 0 8 . 0 5 . 0

I n g r e d i e n t s : C a l f a x DB-45 C a l s o f t L-40 T r i s o d i um Phosphate Water


C a r and T r u c k Wash Formula

Wei q h t % 19 .83 24.95 10.02 45.18

Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-001-01

Car and T r u c k Wash Formula

I n g r e d i e n t s : C a l f a x DB-45 C a l s o f t L-40 D i s o d i um Phosphate Water

Comments abou t t h i s f o r m u l a : 1 . T h i s i s l o w e r p H f o r m u l a t h e n CWC-001-01. 2 . H e a t i n g i s necessa ry t o homogenize.

F o r m u l a t i o n CWC-002-01

Car Wash [Powder)

I n g r e d i e n t s : Sodi um T r i po l yphospha te C a l s o f t F-90 Cal o x y l a t e N-9


C a r Wash (Calsuds A-Based)

I n q r e d i e n t s : Calsuds A Cal foam EA-603 C a l o x y l a t e N-9 Water


SOURCE: B1 i o t Chemi c a l Co. : Suggested F o r m u l a t i o n s

Wei qh t% 20 .00 25.17 10.04 44.76

Wei q h t % 85.00

5.00 10.00

Wei g h t % 50.00

3.00 2.00

45.00


Car Wash and Care

Car Shampoo with Water-Repellent Effect

Ingredients: Autopur WK 4332 Amphotensid 0 4 Water

Formula CT 04-03-02

Rinse-off ARent (Water-Repellent)

Ingredients: Autopoon GK 4004 Mulsifan RT 1 Produkt 2058 Pine oil Butyl di glycol Water

Formula CT 04-05-07

Wt% 4 5 . 0

5 . 0 5 0 . 0

wtu/, 1 7 . 0 6 . 0 6 . 0 3 . 0 8 . 0

6 0 . 0

Rinse-off Aqent (Water-Repellent) Without Hydrocarbons

Ingredients: Autopoon GK 4008 Mulsifan RT 1 Produkt 2058 Butyl di glycol Water

Formula CT 04-05-03

Windshield-Cleaner (Summer)

Inqredi ents: Water Ethanol Zusol at 1005/85 Zusolat 1008/85

Formula CT 04-06-01

Innredi ents: Water Zetesol NL Zusol at 1008/85 Isopropanol

Formula CT 04-06-04

Wt% 17 .0

6 . 0 6 . 0 8 . 0

63 .0

Wt% 6 7 . 9 2 0 . 0

5 . 2 6 .9

Wt% 2 3 . 7 6 4 . 0

1 . 3 11 . o

SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested Formulations


Car Wash and Care

Windsh ie ld -C leaner ( W i n t e r )

I n g r e d i e n t s : Water I s o p r o p a n o l Z e t e s o l 2056

Formula CT 04-06-07

I n s e c t Remover

I n q r e d i e n t s : S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 T r i l o n A l i q u i d Monoethanol ami ne B u t y l d i g l y c o l Water

Formula CT 04-07-01

Wheel C1 eaner . A1 k a l i n e

I n g r e d i e n t s : Water T e t r a p o t a s s i u m py rophospha te Lumorol 4192 Zusol a t 1005/85 B u t y l d i g l y c o l Orange t e r p e n e

Formula CT 04-11-04

T a r Remover

I n q r e d i e n t s : M u l s i f a n K 326 S p e z i a l Whi t e - s p i r i t n -bu tano l O l e i c a c i d Water

Formula CT 04-13-02

Wtl 29.5 70.0

0 . 5

Wt% 4 .0 2 .0 2 . 0 4 . 0 4 . 0 5 . 0

79 .0

Wt% 77.5

3 . 0 1 0 . 0

4.0 5 . 0 0 . 5

Wt% 1 5 . 0 6 0 . 0

7 . 0 3 . 0

15.0

SOURCE: Zschimmer & Schwarz GmbH & Co. : Genera l F o r m u l a t i o n s


Car Wax

I n g r e d i e n t : Pa r t A : Morphol i ne Water

Pa r t B: Wax S O l e i c Ac id Minera l Spi r i t s Kerosene

Par t C : Mas i l EM 250 C Mas i l EM 10,000 C Snow F loss Kaopol i t e SF Carbopol 941 ( 1 % i n water )

Wt%

0 .8 44.2

8.0 1 . o

18.0 9.0

10.0 3.0 3.0 3.0

As needed

Procedure: 1 . Add t h e morphol ine t o the water w i t h h igh speed mix ing . 2 . I n Pa r t B, add the o l e i c ac id , m inera l s p i r i t s , kerosene,

and Wax S w i t h h igh speed m ix ing . Add Par t B t o Pa r t A w i t h h i g h shear m ix ing .

3. Add t h e Mas i l EM 250 C and Mas i l EM 10,000 C from Par t C t o t h e concent ra te w i t h slow mix ing . Add t h e Snow F l o s s and Kaopo l i t e SF. Thicken w i t h t h e Carbopol 941 s o l u t i o n .

Auto Wipe B Shine P o l i s h

I n g r e d i e n t ; Pa r t A : Mas i l SF 100

O l e i c Ac id Minera l O i 1 , 70 SUS

Par t 0 : Morphol i ne Carbopol 934 Tr ie thano lamine Water

A-C 617A 3 . 5 2 . 0 1 . 5 5.6

1.4 0.2 0 .2

8 5 . 6

Procedure: 1 . Add t h e i n g r e d i e n t s i n Pa r t A as l i s t e d and heat t o 9OC. 2 . For Pa r t B, heat t h e water t o 85C. Disperse t h e Carbopol 934

i n t h e water. When comple te ly d i sso l ved , add t h e t r i e t h a n o l - amine. Then, add t h e morphol ine.

3. Add P a r t A t o P a r t 0 and b lend .



Concentrated T r a f f i c F i lm Removers

Two f o r m u l a t i o n s were developed w h i c h c o n t a i n 50% t o t a l w a t e r , i n c l u d i n g t h e w a t e r i n t h e sodium m e t a s i l i c a t e p e n t a h y d r a t e . One c o n t a i n s n o n i o n i c , t h e o t h e r has no n o n i o n i c b u t has more AO-14-2 and A l k a l i S u r f a c t a n t , t h e c o m b i n a t i o n o f w h i c h s h o u l d do as w e l l as t h e n o n i o n i c f o r h a r d s u r f a c e c l e a n i n g .

M ix i n t h e o r d e r g i v e n : Formula 1 : Component: Water Versene 100 Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah A l k a l i S u r f a c t a n t Tomah AO-14-2 Tomah Q-17-2

% anhydrous b u i l d e r : 19.00 S u r f a c t a n t / b u i l d e r r a t i o : 1 .68

M i x i n t h e o r d e r g i v e n : Formula 2 : Component: Water Versene 100 Sodium M e t a s i l i c a t e Pen tahyd ra te Tomah A l k a l i S u r f a c t a n t Tomah AO-14-2 Tomah Q-17-5 Noni o n i c NP-9.5

Wt% 22.00 38.00

8.00 16.00 8.00 8.00

Wt.% 36.20 19 .70 4 .10

1 0 . 0 0 10.00 10 .00 10.00

% anhydrous b u i l d e r : 9 .82% S u r f a c t a n t / b u i l d e r r a t i o : 4 .07

Note t h a t sodium m e t a s i l i c a t e p e n t a h y d r a t e i s a c t u a l l y about 57% sodium m e t a s i l i c a t e on an anhydrous b a s i s . Versene 100 i s abou t 38% t e t r a s o d i u m EDTA on an anhydrous b a s i s . Thus t h e s e f o r m u l a t i o n s a r e about 50% t o t a l w a t e r when c a l c u l a t e d on an anhydrous b u i l d e r b a s i s . The s u r f a c t a n t s were c o n s i d e r e d on an a s - i s b a s i s , and n o t c o r r e c t e d f o r t h e w a t e r c o n t e n t . Anhydrous sodium m e t a s i l i c a t e and anhydrous t e t r a s o d i u m EDTA a r e r e a d i l y a v a i l a b l e ; anhydrous ampho te r i cs and amine o x i d e s a r e n o t .

These f o r m u l a t i o n s were made up and found t o be f reeze - thaw s t a b 1 e.

Formula 1 was d i l u t e d 1/20 w i t h w a t e r t o 2.5% a c t i v e s , and t e s t e d by s p r a y i n g on a d i r t y c a r . It was compared w i t h Formula- t i o n T-107 T r a f f i c F i l m Remover a l s o a t 2.5% a c t i v e s . No s i g - n i f i c a n t d i f f e r e n c e s were seen, so t h e absence o f n o n i o n i c d i d n o t a d v e r s e l y a f f e c t t h e pe r fo rmance o f t h e c o n c e n t r a t e d f o r m u l a t i on. SOURCE: Tomah Products, I n c . : Suggested F o r m u l a t i o n s


Foamy Brush Car Wash, L i q u i d

I n q r e d i e n t s : Water, D . I . * C a u s t i c Soda, 50% W i t c o 1298SA W i t c o l a t e SE-5 P e t r o BAF L i q u i d W i t cami de 128T Formal i n Sodi um C h l o r i d e

Wtg 79.75

1.40 5 . 0 0 7 . 0 0 3 . 0 0 3.00 0 . 1 0 0.75


used t o a d j u s t v i s c o s i t y o f t h e p r o d u c t .


B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . Sodium C h l o r i d e i s

S p e c i f i c G r a v i t y : 1 .015 Wt . /Ga l . l b s . : 8 . 4 6 pH, as i s : 9 . 8 V i s c o s i t y , cps : 410

D i l u t i o n R a t i o a t Wand=l : 4 0 * I f u n s o f t e n e d t a p w a t e r i s used, add 0 .25% l i q u i d EDTA, 40%

t o c o u n t e r a c t ha rdness . Formula 621

Low Cost Car=

I n g r e d i e n t s : Water . D . I . P e t r o LBA Powder W i t c o l a t e SE-5 W i t cami de 128T Formal i n Sodi um C h l o r i d e Perfume, Dye

Wt% 8 9 . 9

1 . o 6 . 0 3 . 0 0 . 1 4 . s . 4 . s .


pH=7.5-8.0. The Sodium C h l o r i d e i s used t o a d j u s t t h e v i s c o s i t y o f t h e f i n a l p r o d u c t .

B lend t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t t h e

Formula 609

SOURCE: W i t c o Corp.: Suggested F o r m u l a t i o n s


Genera l Purpose C a r Wash

T h i s i s a cop ious - foaming , a l l - p u r p o s e c a r wash f o r m u l a t e d t o be s a f e on c a r f i n i s h e s , y e t e f f e c t i v e i n t h e removal o f r o a d g r i m e and o t h e r s o i l s .

I n s r e d i e n t : D e i o n i z e d Water Mazon 98 Macol TD-3 W i t c o l a t e WACLA Mazamide 80 Macol 48 T r i e t h a n o l a m i n e , D e i o n i z e d Water

85%

w b 5 0 . 0

9 . 5 1 . 5 2 . 5 3 . 0 1 . o 1 . 5

31 . O

pH ( a s i s ) : 8 . 5 - 9 . 5 Appearance: C l e a r , l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 . 0 2

P rocedure :

s t a r t s l o w a g i t a t i o n ( e x c e s s i v e a g i t a t i o n w i l l p roduce a foaming p r o b l e m ) . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix u n t i l c l e a r . NOTE: Use c o n c e n t r a t i o n i s 1-2 ounces p e r g a l l o n o f warm w a t e r .

Charge t h e f i r s t p o r t i o n o f wa te r t o a m i x i n g v e s s e l and

F o r m u l a t i o n CA-103

L i q u i d Car Wash

I n g r e d i e n t : Water W i t c o n a t e 60 T L i q u i d Macol OP-10 SP Mazamide 80 Hexyl C a r b i t o 1 Methanol

P rocedure : Add i n g r e d i e n t s i n o r d e r as l i s t e d .

~ Boa t ~~ Wash ~~~~ & CarPCleaner

I n g r e d i e n t : Water Mazamide 80 Macol NP 9 .5 W i t c o n a t e 60 T L i q u i d

P rocedure : Add i n g r e d i e n t s i n o r d e r as l i s t e d .


N t S 3 4 . 0 30 .0 10.0

6 . 0 1 0 . 0 1 0 . 0

v v t % 3 9 . 0 11 . o

5 . 0 45.0

196 Advanced Cleaning Product Formulatiom

Heavy Duty T r u c k Wash, L i q u i d

I n q r e d i e n t s : Water , D . I . T r i s o d i um Phosphate, C r y s t a l C a u s t i c Soda Beads W i t c o 1298 S o f t A c i d P e t r o BAF L i q u i d Sodium S i l i c a t e 40 Be' ( S t a r ) W i t c o l a t e SE-5 E t h y l e n e G l y c o l Monobuty l E t h e r (EB) Emcol 6744

B l e n d i n g P rocedure : B lend i n g r e d i e n t s i n o r d e r 1 i s t e d .

T y p i c a l P r o p e r t i e s : S p e c i f i c G r a v i t y : 1 .042 Wt . /Ga l . l b s . : 8 . 6 9 pH, as i s : 1 2 . 7

D i l u t i o n Ra te : D i l u t e 1 : 4 0 a t Wand Formula 603

Heavy Duty T r u c k Wash, Powder

I n q r e d i e n t s : Sodi um Carbonate (Soda Ash) , L i g h t D e n s i t y Sodium T r i p o l y p h o s p h a t e , L i g h t D e n s i t y DeSophos 5AP DeSonic 9N Sodium M e t a s i l i c a t e , Anhydrous Sodium S u l f a t e ( S a l t Cake) C a u s t i c Soda Beads Dye*

70.0 2 . 0 2 .0

1 0 . 0 3 . 0 3 . 0 3 . 0 3 .0 4 . 0

wtd/, 47.25 55.00

2 . 9 0 7 . 5 0 5 .00

1 0 . 0 0 2.30 0 .05

B1 end i ng P rocedure : Premix Soda Ash and T r i p o l y t o g e t h e r and s l o w l y add DeSophos

5AP w h i l e m i x i n g . M i x u n t i l p r o d u c t i s u n i f o r m i n appearance. Add DeSonic 9N w h i l e m i x i n g . M ix u n t i l t h e p r o d u c t l o o k s d r y ( 4 - 5 m i n u t e s ) . Add M e t a s i l i c a t e , S a l t Cake and t h e n C a u s t i c Soda beads.

* I f dye i s used, m ix w i t h t h e DeSonic 9N. Formula 604



Premium Car Wash C o n c e n t r a t e

I n g r e d i e n t s : Water , D . I . E thano l Varox 1770 W i t c o n a t e AOS L i q u i d W i t c o l a t e SE-5

Wt% 11 .7

5 .9 17.6 4 6 . 8 17.6

B l endi ng Procedure:

d i s s o l v e completel ’y between each a d d i t i o n . Add W i t c o l a t e SE-5 l a s t i n s m a l l a l i q u o t s a l l o w i n g complete d i s s o l u t i o n between a d d i t i o n s .

T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 160 Sol i d s : 35.4% p H : 8 . 4

Add a l l i n g r e d i e n t s except W i t c o l a t e SE-5, i n o r d e r shown and

Formula 629

I n g r e d i e n t s : Water T e t r a p o t a s s i um W i t cami de 6445

Car Wash

Pyrophosphate, 60%

51ending Procedure: B lend i n g r e d i e n t s i n o r d e r l i s t e d .

Typ i c a l P r o p e r t i es : V i s c o s i t y , cps: 2100 S o l i d s : 6 .8% pH, as i s : 9 .3

Formula 615

A u t o Shampoo Concent ra te

P ngred i e n t s : Water, D . I . Rewoter ic AM KSF-40 W i t c o l a t e SE-5

Wt% 91.67

3.33 5 .00

Wt% 80.0 15 .0

5 . 0

B l e n d i n g Procedure:


T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 4 . 0 S o l i d s : 9 .0% ptl : 9 . 5

Add i n g r e d i e n t s i n o r d e r shown and d i s s o l ve c o m p l e t e l y between

Formula 628 SOURCE: W i t c o Corp. : Suggested F o r m u l a t i o n s


Touch less V e h i c l e Wash D e t e r a e n t l Z e r o Phosphate, Powder)

So i l -Grease , o i l , s a l t , w a t e r d e p o s i t s , c l a y , p a r t i c u l a t e s ,

S u r f a c e - P a i n t e d me ta l s u r f a c e , P o l y m e r i c A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manu fac tu re -Dry B1 end/Aggl o m e r a t i on

r o a d f i l m

Compos i t i on : \nrt36

*Sodium P o l y a c r y l a t e (92% s o l i d s ) 1 . 0 - 3 . 0

Sodium Carbonate 25-30 Metso Beads 2048 20-25

S u r f a c t a n t 5-1 0 T u r b o b r i t e A1 umi n o s i 1 i c a t e 25-35 F i 1 l e r s Ba lance

D i l u t i o n : 1 .0-2.0% by w e i g h t ( 0 . 1 - 0 . 2 p o u n d s / g a l l o n ) Add 0 . 1 - 0 . 2 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o

t h e sp ray n o z z l e . M ix powder d e t e r g e n t i n t a n k and me te r i n t o c a r wash system. M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash systems f o r removing o i l and w a t e r d e p o s i t s , p a r t i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s .

suspended. Cons tan t a g i t a t i o n i n t a n k i s necessa ry t o keep T u r b o b r i t e

V e h i c l e Wash D e t e r g e n t (Low pH) ( Z e r o Phosphate. Powder)

So i l -Grease , o i l , s a l t , w a t e r d e p o s i t s , c l a y , p a r t i c u l a t e s ,

S u r f a c e - P a i n t e d me ta l s u r f a c e , P o l y m e r i c A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n

r o a d f i l m .

Composi t i on : Wt% Sodium Carbonate 27.9 B r i t e s i 1 H20 Hydrous Sodi um P o l y s i 1 i c a t e 21 . o *Acusol 445ND Sodi um Pol y a c r y l a t e (92% s o l i ds) 3 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t 1 2 . 0 V a l f o r 100 Z e o l i t e A 3 6 . 1

Add 0 .125 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o * D i l u t i o n : 1 .5% by w e i g h t (0 .125 p o u n d s / g a l l o n )

t h e s p r a y n o z z l e . D i s s o l v e powder d e t e r g e n t i n t a n k and me te r i n t o c a r wash system. M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f V a l f o r 100 i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash systems f o r removing o i l and w a t e r d e p o s i t s , p a r t - i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s .

Cons tan t a g i t a t i o n i n t a n k i s necessa ry t o keep V a l f o r 100 suspended i n s o l u t i o n . * Rohm & Haas ** Low Foam: Rhone-Poulenc A n t a r o x BL-330 ( 3 moles EO)

H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7

SOURCE: PQ Corp . : D e t e r g e n t F o r m u l a t i o n Guide


Truck/Bus Wash

Components: Burco TME Burcosolv TM Neodol 91-6 TEA 85% Burcene 100 Water

% by Weight 7 5

20 5 2

8a l ance

D i l u t e 50:l t o 1OO:l depending on degree o f s o i l t o be removed

Economy Truck/Bus Wash

Components: Water Burco TME Meodol 1.5 C i t r i c Ac id L i q u i d 50% KOH. 45% Ammonyx LO TEA 85%

% by Weight 76

D i l u t e 20:l t o 50:l depending on degree o f s o i l t o be removed.

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulat ions

Car Shampoo

I ngred i en t s : Zetesol 2056 Lumo WW 75 Zusolat 1008/85 Purton CFD Water

Formula D 1 1 / 1 0

I n g r e d i e n t s : Zusol a t 1008/85 Wachsemul s i on 1864 Isopropanol Water, p r e s e r v a t i v e

Formula D 12/2

% by Wei ah t 15.0 1 0 . 0 3.0 1 . o

7 5 . 0

Car Wash and Wax Shampoo

% by Weiqht 10 .0 1 0 . 0

2 . 0 q . s . t o make 100 .0

SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested Formulat ions

200 Advanced Cleaniris Product Formulations

V e h i c l e Wash D e t e r g e n t e h o s p h a t e . Powder1

So i l -Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,

S u r f a c e - P a i n t e d meta l s u r f a c e , Po lymer ic A p p l i c a t i o n Method-High p r e s s u r e spray Manufacture-Dry b lend/Agg lomera t ion

r o a d f i l m

Composi t ion A : We9/0 Metso Beads 2048 20 .0 *STPP 4 0 . 0 *TSP 5 . 0 *Sodi um Carbonate 2 0 . 0 **Sodium A 1 k y l a r y l Sul f o n a t e Powder (90%) 5 . 0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-10; 6 Moles EO) 1 0 . 0 Composi t ion 8 : Wt% Metso Pentabead 20 30.0

0 0 0 0 0 0

*STPP 44. *Sodi um Carbonate 1 0 . CMC 1 **Sodium A l k y l a r y l S u l f o n a t e Powder (90%) 5 ****Octy lphenoxy P o l y e t h o x y e t h a n o l , 7-8 Moles EO 5 *****Octy lphenoxy Po lye thoxyethano l , 5 Moles EO 5

Use D i l u t i o n : 1 .5% by w e i g h t (0 .125 pounds/ga l lon) D i s s o l v e i n s t o c k t a n k and meter i n t o wash system. Compos

6 can be u t i l i z e d i n h i g h p r e s s u r e spray carwash systems and s u p p l i e s adequate s o i l remova l . * FMC ** W i t c o *** Rhone-Poulenc Rhodasurf 91-6 **** Rhone-Poulenc I g e p a l CA-620 ***** Rhone-Poulenc I g e p a l CA-520

P i on

V e h i c l e Wash D e t e r g e n t ( L i q u i d , low foam)

So i l -Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,

Sur face-Pa in ted meta l s u r f a c e , Po lymer ic A p p l i c a t i o n Method: H igh p r e s s u r e spray (700-1400 p s i ) Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

r o a d f i l m

Composi t i on : Wt% Water 79.0 Metso Beads 2048 2 . 0 *Sodium P o l y a c r y l a t e (40%) 5 . 0 **Sodium Xylene S u l f o n a t e (40%) 8 . 0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO) 3.0 * * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl l ; 2 . 5 Moles € 0 ) 3.0

* Rhone-Poulenc C o l l o i d 226/35 (40%) ** Stepan, W i t c o *** Rhone-Poulenc Rhodasur f 91-6 **** Rhone-Poulenc Rhodasurf A-24 SOURCE: PQ Corp . : Detergent F o r m u l a t i o n Guide

Use D i l u t i o n : 10% bw (13 o z / g a l l o n )


Veh ic le Wash Detergent (Low PH) (Zero Phosphate, L i q u i d )

Soi l-Grease, o i l , s a l t , water depos i ts , c lay , p a r t i c u l a t e s ,

Surface-Painted metal sur face , Polymeric Appl i c a t i on Method-Hi gh pressure spray (700-1400 p s i ) Manufacture-Mix tank w i t h p r o p e l l e r spray

road f i l m

Composi t i on : Wt% Water 51.66 Carbopol 674 0 . 5 D L i q u i d Sodium S i l i c a t e 8 .1 *Acusol 445N Sodi um Po lyac ry l a t e (45% s o l i d s ) 1.84 Sodium Carbonate 9 . 1 Turbobr i t e A1 umi nosi 1 i ca te 24.5 * * L i q u i d Nonionic Sur fac tan t 4.3

D i l u t e l i q u i d de tergent w i t h water ( 1 g a l l o n de tergent : 64 g a l l o n s water ) and d e l i v e r t o h igh pressure spray wash system.

M i l d abras ive c lean ing and p o l i s h i n g e f f e c t o f Tu rbobr i t e i s extremely e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s , water depos i t s , and haze from body p a r t s and w indsh ie ld . * Rohm & Haas ** Low Foam: Rhone-Poulenc Antarox BL-240

High Foam: She l l Chemical Neodol 23-6.5 o r Neodol 25-7

Touchless Veh ic le Wash Boos te r /Add i t i ve LZero Phosphate, L i q u i d )

Soi l-Grease, o i l , s a l t , water depos i ts , c l a y , p a r t i c u l a t e s ,

Surface-Painted metal sur face , Polymeric A p p l i c a t i o n Method-High pressure spray (700-1400 p s i ) Manufacture-Mix tank w i t h p r o p e l l e r s t i r r e r

road f i l m

Composit ion: Wt%

S1 u r r y ) 100.0 T u r b o b r i t e L (25 w t . % a c t i v e Tu rbobr i t e A l u m i n o s i l i c a t e

D i l u t e l i q u i d Tu rbobr i t e L a t h igh pressure pump w i t h water ( 1 g a l l o n de tergent : 128 g a l l o n s water) and d e l i v e r t o h igh pressure spray wash system.

i s extremely e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s ( c lays , carbon b lack , brake d u s t ) , water depos i ts , and haze from body p a r t s and w indsh ie ld .

T u r b o b r i t e L can be used as an a d d i t i v e o r boos ter f o r conven t iona l touch less , h i g h pressure carwash o r f lee twash d e t e r - gents.

O r make a de tergent by b lend ing Tu rbobr i t e L w i t h 1-2% low- foaming non ion ic s u r f a c t a n t t o make f o r best c lean ing r e s u l t s . D i l u t e T u r b o b r i t e L / su r fac tan t b lend a t h igh pressure pump w i t h water (128: 1 ) .

i ng produc ts .

SOURCE: PQ Corp. : Detergent Formula t ion Guide

M i l d abras ive c lean ing and p o l i s h i n g e f f e c t o f Tu rbobr i t e

T u r b o b r i t e L a l s o works i n waxes, po l i shes , and o the r d e t a i l -

17. Whitewall Tire Cleaners

202

Whi tena 1 1 Ti.r&C!ean.ey 1 z e r o .P.b-s phate -?.w&cl

Soil-Clay, p a r t i c u l a t e , o i l , grease S u r f a c e - W h i t e w a l 1 t i r e s Application Method-High pressure spray/brush/wipe Manufact tire - Dry b 1 end/Agg 1 omerat i On

Nt% c_q.m3os i t i . on l *Acusol 4 4 5 N D Sodium Polyacrylate ( 9 2 % Solids) 2 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cll; 6 M o l e s E D ) 8 . 0 Sodium Alkylaryl S u l f o n a t e 1 0 . 0 M e t s o Beads 2048 3 5 . 0

35.0 Valfor 100 Zeolite A

S o d i u m Carbonate 12.0 * Rohm & Haas ** Rhone-Pou 1 enc Rhodasurf 91 -6

wi j. t. ew an -T i. r,e C L Y C ~ e 1: 1 Pbes?batePowde.!’l

Soil-Clay, p a r t i c u l a t e , o i l , g r e a s e Surface-Whi tewal1 t i r e s Application Methods-High p r e s s u r e s p r a y / b r u s h / w i p e M a n u f a c t u r e - D r y b l e n d

Cs-mmeo s. i. t j P.V :. *STPP * * t i q u i d N o n i n n i c S u r f a c t a n t (C9-Cll; 6 nroles € 0 ) GTSP Sodium Alkylaryl Sulfonate Met50 Beads 2048 * FMC * a Rhone-Poulenc Rhodasurf 91 -6

WRitewal..1..Ti re,&!ea_n_er (.Lictuj.d).

Soil-Clay, particulate, o i l , p r e a s e Surface-Whi tewall tires A p p l i c a t i o n Method-High pressur’e spray/brush/wipe Manufacture-Mi x t a n k w i t h propeller s t i r r e r

Comq.~S !.f.bn: Water Potassium H y d r o x i d e 145%) N Clear o r S t a r Sodium Silicate Sodi uni A 1 k y l a r y l Sulfonate (60%) * L i q u i d Nonionic S u r f a c t a n t (CS-Cll; 6 moles E O ) *Rhone-Poul e m R h o d a s u r f 91 -6

S O U R C E : FQ Corp. : D e t e r g e n t F o r m u l a t i o n Guide

Y!t.% 4 5 . 0

5 . 0 1 0 . 0 1 0 . 0 30.0

flL?b 7 0 . 0 1 6 . 0 1 0 . 0

2 . 0 2 . 0

18. Miscellaneous

204

Miscellaneous 205

A i r c r a f t Cleaner (Reduced Phosphate. Powder)

Soi 1 -Par t i cu la tes , carbon b lack , pe t ro leum o i 1 and grease Surface-Aluminum, metal A p p l i c a t i o n Method-High pressure spray (700-1400 p s i ) Manufacture-Dry blend/Agglomerat i on

Composi t i on : Metso Pentabead 20 V a l f o r 100 Z e o l i t e A Ammoni u m B i f 1 uor i de TSPP *Sodi um A1 k y l naphtha1 ene Sul f ona te **Sodium A l k y l a r y l Su l fona te Powder (90%)

Use D i l u t i o n : 1.5-6.096 bw (2-8 oz /ga l l on )

* Rhone-Poulenc Suprag i l N K ** Witco

Note: Constant a g i t a t i o n i s requ i red i n s tock tank t o keep V a l f o r 100 suspended i n s o l u t i o n . May use 0.25% w t Carbopol 647 (BFGoodrich) as a suspending agent.

Wt% 3 0 . 0 30 .0 8.0

20.0 8.0 4 . 0

A i r c r a f t 61 eaner (Phosphate, Powder)

S o i l - P a r t i c u l a t e s , carbon b lack , pe t ro leum o i l and grease Surface-Metal A p p l i c a t i o n Method-High pressure spray (700-1400 p s i ) Manufacture-Dry b l end/Aggl omerati on

Composi t i on : Metso Pentabead 20 *STPP Ammonium B i f l u o r i d e *TSPP **Sodium A1 kylnaphthalene Su l fonate ***Sodi um A1 k y l a r y l Sul fonate Powder (90%)

Use D i l u t i o n : 1.5-6.0% bw (2-8 oz /ga l l on )

* FMC ** DeSoto, I n c . *%Xc Witco

OURCE: PQ Corp . : Detergent Formula t ion Guide

Wt% 3 0 . 0 3 0 . 0 8.0

20.0 8 . 0 4 .0


Auto Care: I n t e r i o r / E x t e r i o r Rubber B V i n y l P ro tec tan t

Funct i ons 8 Benef i t s : Pemul an 1622 :

*Primary e m u l s i f i e r f o r s i l i c o n e o i l *NO s u r f a c t a n t s and no so l ven ts r e q u i r e d equals zero VOC * Impar ts y i e l d va lue f o r v e r t i c a l c l i n g *Exce l l en t w e t t i n g f o r "spray and no-wipe" a p p l i c a t i o n s *Improved d u r a b i l i t y and water-res stance

Good-Rite K-752: *Reduction i n emu1 s i on v i s c o s i t y w

I n q r e d i en t : D I water Pemulen 1622* 1000 cSt s i l i c o n e o i l * *

T r ie thano lamine (99%) Good-Rite K-752 (63%)****

DC Q2-5211***

* E m u l s i f i e r : BFGoodrich

t h o u t l o s s i n s t a b i l i t y

Wtl 78.55 0.20

20.00 0.50 0.25 0.50

* *Pro tec tan t : DC 200 F l u i d : Dow Corning ***Super-wett ing agent: DC (12-5211: Dow Corning

* * * *V iscos i t y reduc t i on : BFGoodrich

Phys ica l P roper t i es : B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 150 CP Product pH: 5.5-6.0 Product C l a r i t y : Opaque


M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Pemulen r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approx ima te l y 15 minutes o r u n t i l t h e s l u r r y i s homogeneous.

2. Add t h e s i l i c o n e f l u i d w i t h good a g i t a t i o n . 3. Add t h e DC Q2-5211 super -wet t ing agent w i t h moderate a g i t a t i o n 4. Add t h e t r i e thano lamine w i t h moderate a g i t a t i o n . 5 . Reduce a g i t a t i o n and add t h e Good-Rite K-752 polymer. The

v i s c o s i t y w i l l d rop from about 3,000 CP t o <200 CP w i t h t h i s a d d i t i o n .

6. Adjus t t h e pH w i t h a d d i t i o n a l t r i e thano lamine , i f necessary. 7 . Add f rag rance and c o l o r , as des i red .


Miscellaneous 207

Boat Polish

I n a d d i t i o n t o th icken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended. The r e s i n a l s o prevents "creaming" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .

I nq red i en t : #I Water Carbopol EZ-2 ( 1 ) Morphol i ne SF96 S i l i c o n e F l u i d (350) ( 2 ) V i s c a s i l F l u i d (10,000) ( 2 ) O l e i c Ac id Minera l S p i r i t s Hoechst Wax E (3) Mineral Spi r i t s SF1 706 React i ve Ami ne Polymer Kaopo l i t e k a o l i n c l a y ( 4 )

Wt% 37.80

0.20 2.50 2.00 1.50 2 .50

10.00 6.00 5.00 1.50 8 . 5 0

Physical P roper t i es : Brookf i e l d V i scosi t y (RVT-20 rpm) : 7,200 cps Product pH: 9.00 Product C l a r i t y : Opaque

Raw M a t e r i a l Supp l ie rs : (1 ) BFGoodrich (2 ) General E l e c t r i c ( 3 ) Hoechst Celanese ( 4 ) Kaopo l i te , I n c .

Procedure: 4 . Disperse t h e Carbopol i n t o t h e water by s imp ly "dumping" i t

2. Add t h e morpholine, mix w i t h good a g i t a t i o n . Heat t o 60-65C. 3 . I n a separate vessel , combine t h e s i l i c o n e f l u i d , V i s c a s i l ,

o l e i c ac id , and t h e wax i n t h e minera l s p i r i t s . Heat t o 90-95C u n t i l t h e wax me l t s and t h e m ix tu re appears homogeneous. Add to t h e above m ix tu re w i t h good mix ing .

r e a c t i v e amine polymer. Add t o t h e above m ix tu re w i t h h igh shear mix ing .

i n . The polymer w i l l wet ou t i n a few minutes.

4 . When homogeneous, coo l t o 60-65C. 5. I n a separate vessel , combine t h e minera l s p i t i t s and t h e

6. S lowly add i n t h e c l a y . Mix u n t i l homogeneous.

To ta l Ac t i ves : To ta l Wax : 1.50 To ta l S i l i c o n e F l u i d : 4.50 React i ve Ami ne Polymer : 2.00 Minera l S p i r i t s : 13.00 Abrasive: 12.00

$ ~ ~ ~ ~ ~ : BFGoodrich Spec ia l t y Chemicals: DET-520


Concrete Cleaner/Deqreaser

I n g r e d i en ts : Water, D . I . Sodium Tr ipo lyphosphate T r i sodi um Phosphate Varami de A-83 Varonic DM55

WtB 81 . O

2.0 1 . o 6 . 0

1 0 . 0


each addi t i on.

Typ ica l P r o p e r t i es : V i s c o s i t y , cps: 0 S o l i d s : 19.0%

Formula 937

Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between

Garage F loo r C1 eaner

I n s r e d i en ts : Water T r i sodi um Phosphate Emphos PS-236 Witconate 45 L i q u i d

Wt% 8 2 . 0

8 . 0 4 . 0 6 . 0

Blend ing Procedure:

b lend ing between a d d i t i o n s . Formula 941

Blend i n g r e d i e n t s i n the order l i s t e d . A l low f o r complete

Ac id Rust Remover

I n q r e d i en ts : Water, D . I . Phosphoric Ac id , 86% C i t r i c Ac id Varox 365

\Me% 81 . O 15 .0

3 . 0 1 . o



T y p i c a l Proper t i es :

Add i n g r e d i e n t s i n o rder shown and d i s s o l v e completely between

V i s c o s i t y , cps: 4 S o l i d s : 16.2% pH: 1.3

Formula 1116

SOURCE: Witco Corp.: Suggested Formulat ions

Miscellaneous 209

Concrete/Dr iveway C l e a n e r s

F o r l e a f and o t h e r t a n n i n s t a i n s - use as i s . Wet s p o t . S p r i n k l e FB Sodium Perca rbona te o n t o s p o t . Scrub i n and r i n s e w i t h hose when s p o t i s removed.

For O t h e r S t a i n s

Component: Soda Ash (Dense) B r i t e s i 1 H-24 TSP Anhydrous Burcosperse AP Powder Dry S u r f a c t a n t * FB-Sodi um Perca rbona te

Wt% 25 15 20

5 5

30

Wet s p o t . S p r i n k l e c l e a n e r o n t o a r e a . Scrub i n and a l l o w t o

*Sodium L a u r y l S u l f a t e , Sodium Dodecylbenzene S u l f o n a t e o r s t a n d . R i n s e w i t h hose.

Sodium Cocoyl T a u r a t e s can be used.

SOURCE: B u r l i n g t o n Chemical Co . : Suggested F o r m u l a t i o n

Neavv Duty C o n c r e t e C l e a n e r (Phosphate F ree )

Water, D . I . EDTA, 38% Sodium Metas i l i c a t e , P e n t a h y d r a t e Sodium Carbonate (Soda Ash) W i t cami de S-780 W i t c o n o l NP-120 B u t y l Cel l o s o l v e M i n e r a l S p i r i t s KOH, 45% W i t c o n a t e SXS L i q u i d P i n e O i l

Formula 1C

Wt% 75.0

0 . 5 2 . 0 1 .5 6 .5 1 . 5 3 . 0 4 .0 2 . 5 1 . 5 2 . 0


a d d i t i o n .


B lend i n g r e d i e n t s i n o r d e r l i s t e d , m i x i n g w e l l a f t e r each

S p e c i f i c G r a v i t y : 1 .022 Wt . /Ga l . I b s . : 8 . 5 2 pH, as i s : 13.18 3 Freeze/Thaw C y c l e s : Passed 1 Week @ 52C: Passed 4 Weeks Room Temp: Passed S o l i d s : 13.5%

Use D i l u t i o n : As s t r o n g as needed, depending on t y p e o f s o i l .

SOURCE: W i t c o C o r p . : Formula 949


__ Vinyl Dressing

I ng r e d i & P a r t A : M a s i l EM 250 C Dei o n i zed Water

P a r t 8 : Macol NP 9 . 5 G1 y c e r i ne D e i o n i z e d Water Sodium Benzoate

~- W t %

3 0 . 0 3 0 . 0

1 . 5 1 . 5

3 6 . 9 0 . 1

Procedure: 1 . To a m i x i n g v e s s e l , cha rge t h e M a s i l EM 250 C and s t a r t

g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r so as n o t t o b reak t h e emu1 s i on.

g l y c e r i n e t o t h e w a t e r . M i x w i t h g e n t l e a g i t a t i o n u n t i l a l l components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h eyes " . Charge t h e sodium benzoate and m i x u n t i l d i s s o l v e d .

m i x i n g g e n t l y t o a v o i d a i r en t rapmen t . NOTE: T h i s f o r m u l a i s des igned t o be used "as i s " as a d r e s s i n g f o r r u b b e r and v i n y l p r o d u c t s . I f d e s i r e d , UV abso rbe rs and o t h e r components may be added t o t h e f o r m u l a t i o n . F o r m u l a t i o n SV-101

2 . I n a s e p a r a t e m i x i n g v e s s e l , cha rge t h e Macol NP 9 .5 and

3 . Under g e n t l e a g i t a t i o n , cha rge P a r t B t o P a r t A . C o n t i n u e

I n q r e d i e n t : M a s i l EM 10,000 C M a s i l EM 250 C Macol NP 9 . 5 G l y c e r i n e Barquat MB-50 Water

&% 10 .0 18 .0

2 . 0 1 . 5 0 . 1

6 8 . 4

Procedure: Add t h e s i l i c o n e emu ls ion t o a b l e n d e r . S l o w l y add a p o r t i o n

o f t h e w a t e r and a g i t a t e . Add t h e Macol NP 9 . 5 and g l y c e r i n e . M ix f o r 10 m i n u t e s . Add t h e ba lance o f t h e w a t e r and mix f o r 15 m i n u t e s .


Section Ill demarked Raw Materials

211

21 2 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION A-C 617A P o l y e t h y l e n e

A c i d Th ickener C a t i o n i c s u r f a c t a n t

A c r y s o l AS€-108 P o l y a c r y l a t e (40%)

A c t i n o l FA-I T a l l o i l f a t t y a c i d

Acusol 445ND Sodium p o l y a c r y l a t e (92% s o l i d s )

Acusol 479ND Sodium p o l y a c r y l a t e

Adogen 66 A n t i - s t a t i c agent

A1 i p a l CO-128 A n i o n i c s u r f a c t a n t

A1 i p a l CO-436 A n i o n i c s u r f a c t a n t

A l k y l a r y l S u l f o n i c A c i d (98%)

Alpha-Step MC-48 Alpha s u l f o methy l e s t e r

A 1 pha-Step ML-40 Alpha s u l f o methy l e s t e r (37%)

Ammonyx LO Amine o x i d e

AMP-95 A m i nomethyl p ropano l

Amphotensid 84 Amphoter ic s u r f a c t a n t

Amphoteri c SC Amphoter ic (35% a c t i v e )

Amphoter ic TC Hydro t rope

Antaron FC-34 Amphoter ic s u r f a c t a n t



Antarox BL-240 L i q u i d non ion

Antarox BL-330 L i q u i d non ion

Antarox LF-330 S u r f a c t a n t

Aquamoll i n BC Powder

A r i s t o n a t e M

A r i s t o n a t e M-LF

Aromat ic 150

Pet ro leum s u l f o n a t e (61%)

Pet ro leum s u l f o n a t e

Sol v e n t

SOURCE A l l i e d

Tomah

Rohm&

A r i zon

Rohm&

RohmB

W i t c o

Rho ne -

Rhone-

W i t c o

Stepan

Stepan

Stepan

Angus

Zschim

Tomah

Tomah

Rhone-

Rhone-

Rhone-

Rhone-

P i l o t

P i l o t

Exxon

Trademarked Raw Materials 213

RAW MATERIAL Autopoon GK4004

Autopoon GK4008

Autopur WK4332

Avanel S-30

Avanel S-70

Avanel S-74

B i o te rge

B i o te rge

83-120 b

B r i j 96

B r i t e s i 1

B r i t e s i I

B r i t e s i 1

5;mr lOX 12

Barquat NIB-50

BiQSOft D-62

B i o s o f t s-100

AS-40

PAS-8S

CHEMICAL DESCRIPTION SOURCE Blend o f s u r f a c t a n t s Zschim

Blend o f s u r f a c t a n t s Zschim

Blend o f s u r f a c t a n t s Zschim

An ion ic s u r f a c t a n t PPGMaz

Sodium l i n e a r a l k y l po l ye the r PPGMaz

An ion ic s u r f a c t a n t PPGMaz

q u i d Sodi um S i 1 i ca te

Sur fac tan t

c20 Hydrous sodium p o l y s

H20 Hydrous sodium po lys

H24 Hydrous sodium p o l y s

Burcene I00

Burco BSGH-270

Burco WCS-SONF

Amine ox ide (30%) Lonza

Quaternary ammonium compound Lonza

Sodium a l k y l benzene sul fonate(60%) Stepan

Alkylbenzene s u l f o n i c ac id , l i n e a r Stepan

Sodium o l e f i n s u l f o n a t e (40%) Stepan

Pr imary alkane s u l f o n a t e (40%) Stepan

PO

ICI

1 i c a t e PQ

1 i c a t e PQ

1 i c a t e PQ

Bur l i n

P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n

P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n

NPS-225 P r o p r i e t a r y t e x t i l e a u x i l i a r y B u r l i n

NPS-816 P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n

SZS P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n

LAF-6 P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n

21 4 Advanced Cleaning Product Formulations

RAW MATERIAL B u r c o l 117

B u r c o l i t e BSGH-255

B u r c o s o l v TM

Burcosperse AP Powder

Burcosperse LP

Burcosperse SP-60

Burco tase LL-100

Burco tase EP-60

Burco tase SL-160

B u r c o t e r g e DG-40

Burco TME

B u r c o t r o p e 1250

B u r c o w h i t e BBH-20

Burdac-114

B u t y l C a r b i t o 1

B u t y l C e l l o s o l v e

Calamide C

Calamide CW-100

Calamide CWT

Calamide SM

C a l f a x DB-45

Cal f a x 1 OL-45

Cal foam EA-603

CHEMICAL DESCRIPTION P r o p r i e t a r y t e x t i l e a u x i l i a r y

Water s o l u b l e s o l v e n t m i x t u r e

Sodi um p o l y a c r y l a t e

Sodium p o l y a c r y l a t e s o l u t i o n

Sodium p o l y a c r y l a t e

P r o p r i e t a r y d e t e r g e n t enzyme



D e t e r g e n t c o n c e n t r a t e

P r o p r i e t a r y t e x t i l e a u x i l i a r y

SOURCE B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

I n d u s t r i a1 s o l v e n t UnCarb

E t h y l e n e g l y c o l monobuty l e t h e r UnCarb

Coconut d e r i ved ami de P i l o t

Coconut d i e t h a n o l a m i d e 100% P i l o t

Super ami de P i l o t

Non-DEA 1 i q u i d ami de P i l o t

Sodium a l k y l (b ranched) d i p h e n y l Mona o x i d e d i s u l f o n a t e 45%

Sodi um a1 k y l ( 1 i n e a r ) d i pheny l Mona o x i d e d i s u l f o n a t e 45%

L i q u i d d e t e r g e n t P i l o t


RAW MATERIAL Cal foam ES-303

Cal foam SLS-30

Gal i mu1 se PRS

Ca loxy la te M - 9

C a l s o f t F-90

C a l s o f t L-40

C a l s o f t L-60

Cal s o f t LAS-99

C a l s o f t T-60

Calsuds A

Calsuds CD-6

Calsuds 81

Carbi t o 1

Carbopol

Carbopol

Carbopo 1

Ca rbopo l

Ca rbopo 1

Carbopol

Carbopol

Carbopol

Ca rbopol

So lvent

672

674

676

69 1

934

940

941

ETD 2623

ETD 2691

CHEMICAL DESCRIPTION SOURCE Sodium l a u r y l e the r s u l f a t e (30%) P i l o t

Sodium l a u r y l s u l f a t e 30% P i l o t

Emu1 s i f i e r P i l o t

Nonyl phenol e t h o x y l a t e ( 9 Mole EO) P i l o t

P i l o t

P i l o t

P i l o t

L inear a1 k y l a t e s u l fonate

Sodi um 1 i near a1 k y l benzene s u l f ona te 1 i q u i d 40%

Sodi um 1 i near a1 k y l benzene s u l f o n a t e pas te 60%

L inear a1 k y l benzene s u l f on a c i d 99%

TEA l i n e a r a l k y l benzene su 60%

C P i l o t

f ona te P i l o t

Conc. b lend o f a n i o n i c de tergents P i l o t and amides

M o d i f i e d coconut diethanolamidelOO% P i l o t

Conc. b lend o f a n i o n i c de tergents P i l o t and amides

I n d u s t r i a l so l ven t UnCarb

Th icken ing agent BFGood

Thickening agent BFGood


Suspension a i d BFGood




Resin v i scosi t y m o d i f i e r BFGood

Resin v i s c o s i t y m o d i f i e r BFGood


RAW MATERIALS Carbopol EX-473 (30%)

Carbopol EZ-2

Card is 36 Wax

CDB Clearon

C o l l o i d 225/35

Col 1 o i d 226/35

Contraspum 300

Cublen D50

CHEMICAL DESCRIPTION V i scosi t y modi f i e r

V i scosi t y modi f i e r

Oxidized m i c r o c r y s t a l l i n e wax

Ch lor ina ted i socyanurate

Po lyac ry la te (40%)

Po lyac ry la te (40%)

G lyco l e ther defoamer

DC (22-5211

Decanol

Dequest 2000

DeSonic LFD-97

DeSonic 5N

DeSonic 9N

DeSonic 11N

DeSonic 81-6

DeSophos 5AP

Diatomaceous Ear th

D L i q u i d Sodium S i l i c a t e

Dipropylene Glyco l Monoethyl Ether Solvent

Super-wett ing agent

Organophosphorous product

Nonionic s u r f a c t a n t

Nonioni c s u r f a c t a n t

Detergent/degreaser



Phosphate es te r

Dodigen 226

Dowanol DPM Glyco l e ther

Dowanol DPnB Glyco l e ther

SOURCE: BF600d

BFGood

P e t r o l

01 i n

RAOPa@

Rhone

Zschi e

DowCor

I\iiCN7san

DeSoto

DeSoto

DeSoto

DeSoto

DeSoto

DeSoto

Kaopol

PQCorp

Dow or Arc0

D o w

Bow

Trademarked Raw Materials 21 7

RAW MATERIAL CHEMICAL DESCRIPTION Dowanol EB E t h y l e n e g l y c o l n - b u t y l e t h e r

Dowanol PM Propy lene g l y c o l methy

Dowanol PnB G l y c o l e t h e r

Dowanol TBA G l y c o l e t h e r

Dowanol TPM T r i p r o p y l e n e g l y c o l me

Dow C o r n i n g 20 Release C o a t i n g

e t h e r

Dowfax 382 Sodi um n -decy l d i pheny lox d i s u l f o n a t e (45%)

Dow ic ide A Sodium o-Phenylphenate

Dow 200 S i l i c o n e F l u i d (1000 c S t )

e t h e r

de

Dowfax 2A1 Sodi um dodecy l d i p h e n y l o x i de d i s u l f o n a t e (45%)

Dowfax 382 A n i o n i c s u r f a c t a n t

D r e s i n a t e 91 Ros in soap

E L i q u i d Sodium

Emcol 4500

Emcol 6744

Emersol 213

Emphos PS-236

Emphos PS-331

Emphos 5AP

E m u l s i f i e r Four

S i l i c a t e

W e t t i n g agent

S u r f a c e - a c t i v e agen t

O l e i c a c i d

Phosphate e s t e r s u r f a c t a n t



HF D i a1 k y l q u a t e r n a r y (75% a c t i v e )

SOURCE Dow

Dow

Dow

Dow

Dow

DowCor

Dow

Dow

DowCor

Dow

Dow

H e r c u l

PQ

W i t c o

W i t c o

Henkel

W i t c o

W i t c o

W i t c o

Tomah

Emul s i f i e r 827 M ixed d i a l k y l q u a t e r n a r y (75% a c t ) Tomah

Emul s i o n C340 Tomah

Epsom S a l t PQ


RAW MATERIAL CHEMICAL DESCRIPTION SOURCE Ethylene G lyco l n-Butyl Ether Solvent Dow or Union @arb

Euperlan PK-771 Pear l i z i ng agent (47%) Henkel

Foam Booster 14 Def oamer Tornah

Gafac RE-40 An ion ic s u r f a c t a n t

Gafamide CDD 518 Ethanolamide

Genagen LAB C12C14 a l k y l d i m e t h y l b e t a i n e

Genapol OA-80 Alcohol e thoxy la te

Genapol UD-030 C11 0x0 ethoxy a t e ( 3 moles EO)

Genapol UD-080 A lcoho l ethoxy a t e

Genapol ZRO l i q u i d A l k y l t r i g l y c o l e the r s u l f a t e so ln

Genapol 2908 A lcoho l e t h o x y l a t e

Georgia Marble White #8 ca lc ium carbonate

Gluconic Ac id S o l u t i o n (50%)

G1 ucopon 425CS C8-16 a l k y l po l yg l ycos ide (50%)

G lyco l E ther DPM

G lyco l E ther PM

Good-Ri t e K-752 V i s c o s i t y reducer

Good-Rite K-7058 5800 MW p o l y a c r y l i c a c i d

GP-RA-159 S i 1 i cone Pol i sh A d d i t i v e

GP-121 S i l i c o n e P o l i s h A d d i t i v e

GP-227 S i l i c o n e Sur fac tan t S o l u t i o n

Rhone

Rhone

Hoechs

Hoechs

H Q ~ C ~ S

Hoechs

Hoechs

Hoechs

GaMarb

Ashlan

Henkel

BFGood

BFGood

Genes

Genes

Genes


RAW MATERIAL H-7892 d-Limonene

Hampene 100

Hexyl C a r b i t o 1

H i t e c E-515

Hoe S3924

Hoechst Wax E

Hoechst Wax S

Hostapur 0s L i q u i d

Hostapur SAS6O

Hyamine 1 O X

Hypure N

Igepa l CA-520

Igepa l CA-620

Pgepal CA-630

Igepa l CA-720

Igepa l CO-430

Igepa l CO-530

Igepa l 60-630

Pndopol H-100

I n h i b i t o r 4000

Isopar K

I sopar M

CHEMICAL DESCRIPTION

Tet rasod i um EDTA

I ndust r i a1 s o l vent

Wax

Wax

Secondary a lkane s u l f o n a t e

Quaternary ammonium compound

Secondary h y p o c h l o r i t e , 10% s o l n

SOURCE A r y l es

Grace

UnCarb

E t h y l

Hoechs

Hoechs

Hoechs

Hoechs

Hoechs

Lonza

Octylphenoxy po lye thoxyethano l .5 EO Rhone-

Octylphenoxy po lye thoxyethano l ,8 EO Rhone-

Octylphenoxy polyethoxyethano1,g EO Rhone-

Octylphenoxy po lye thoxyethano l , Rhone- 12-13 moles EO

Nonionic e thoxy la te s u r f a c t a n t Rhone-

A1 koxy l a ted 1 i near a1 coho1 Rhone- non ion i c s u r f a c t a n t (low foam)

Nonylphenoxy po lye thoxyethano l , Rhone- 9-10 moles €0

Viscous polybutene Amoco

A1 kanolami ne b o r a t e

I s o p a r a f f i n so l ven t

Zschim

Exxon

I s o p a r a f f i n so l ven t Exxon


RAW MATERIAL CHEMICAL DESCRIPTION Kaopol i t e K a o l i n c l a y

K a o p o l i t e SF Anhydrous a lum i num s i 1 i c a t e

Kaopol i t e 11 52 Anhydrous aluminum s i 1 i c a t e

K a s i l #1 P o t a s s i um s i 1 i c a t e

K a s i l #6 P o t a s s i um s i 1 i c a t e

Kathon CG F u n g i c i d e ( b i o c i d e )

Kel zan Xan

Kerr-McGee M i n e r a l Seal O i

Komperlan KD

L a r o s t a t 88 Ant

han gum

s t a t

L a r o s t a t 264A A n t i s t a t

L a r o s t a t 519 A n t i s t a t

Laundry A d d i t i v e LA-5

Lonzabac-1230

Lumo WW 75

Lumorol 4154 S u r f a c t a n t b l e n d

Lumorol 4192 S u r f a c t a n t b l e n d

L y t r o n 295 O p a c i f i e r . P o l y s t y r e n e emu ls ion

Macol NP 9 . 5 & NP-11 & P o l y o x y e t h y l e n e f a t t y e t h e r OPlOSP & TD-3 & TD-12 & 2LF & 48 & 5100

Mafo CSB Amphoter ic s u r f a c t a n t

Mafo 13 MOD 1 Amphoter ic s u r f a c t a n t

SOURCE Kaopol

Kaopol

Kaopol

PQ

PQ

Rohrn&

Kel co

K e r r -

PPGMaz

PPGMaz

PPGMaz

Tomah

Lonza

Zschim

Zschirn

Zschim

Mor ton

PPGMaz

PPGMaz

PPGMaz


RAW MATERIAL CHEMICAL DESCRIPTION Makon 10 A l k y l phenol e the r

Makon 12 A lky? pheno7 e the r

Maphos 58 Phosphate e s t e r

Maphos 60A Phosphate es te r

Maphos 8135 Phosphate es te r

Mas i l EM250C & S i l i c o n e f l u i d s EM10,OOOC & SF-10 & SF-100 & SF-1,000 & 123

Mas l i p 500 & 501A & Syn the t i c l u b r i c a n t a d d i t i v e s 501 Base

Mazamide SS-10 & 65 & Spec ia l t y alkanolamides 80 & 1281

Mazawet 77 Sur fac tan t

Mazon R I 4A & R I 6 & Spec ia l t y p r o p r i e t a r i e s RI 8A & R I 88 & 98

Mazox LDA F a t t y amine ox ide

Mazu DF 210 SX Def oamer

Medialan KA Conc.

Metso Beads 2048 Anhydrous sodium m e t a s i l i c a t e

Metso Pentabead 20 Sodium m e t a s i l i c a t e pentahydrate

M i rano l CPM-SF Conc. D i sodi um cocoamphodi p rop i onate

Mi rano l JEM Conc.(34%) Sodium mixed C8-amphocarboxylate

Monacor BE Corrosion i n h i b i t o r

Monacor 4000 Corrosion i nh i b i t o r

Monalube 110 & 205 & Syn the t i c l u b r i c a n t s 210 & 215 & 220 & 225 & 310 & 315 & 320 & 325 Ik 605 & 610

Monamid 150-ADD Cocamide DEA

SOURCE Stepan

Stepan

PPGMaz

PPGMaz

PPGMaz

PPGMaz

PPGMaz

PPGMaz

PPGMaz

PPGMaz

PPGMaz

PPGMaz

PQ

PQ

Rhone-

Rhone-

Mona

Mona

Mona

Mona


RAW MATERIAL Monamine CF-100M &

1-76

Monamulse dL-1273

Mona NF-10 & NF-20

Monamulse TRP & 653-83D

Monaquat I S I E S

Monayuat TG

M o n a s i l PCA

Monaterge ALX-100s

Monaterge 779

Mona te r i c CM-36s

M o n a t e r i c CyNa-50

M o n a t e r i c EH

Monat rope 1250

M-Pyro l

M u l s i f a n K326 S p e z i a l

M u l s i f a n RTI

Nacconol 9 0 G

CHEMICAL DESCRIPTION SOURCE 2 : 1 f a t t y a1 kanolamides Mona

P r o p r i e t a r y emu1 s i f i e r / s o l u b i 1 i z e r s Mona

S u r f a c t a n t s

L i q u i d e m u l s i f i e r and s o l u b i l i z e r

I s o s t e a r y l e t h y l d i m o n i urn e t h o - s u l f a t e

Qua te rna ry p h o s p h o l i p i d compound

Cocami de DEA & DEA-Dodecyl benzene- s u l f o n a t e & d i e t h a n o l a m i n e

DEA-Laureth s u l f a t e

Sodium cocoamphoacetate

1 -Hydroxye thy l ene -2 -cap ry l i m i d - a z o l i fie ( 5 0 % a c t i ve)

M i I d ampho te r i c d e t e r g e n t / e m u l - s i f i e r

n - M e t h y l - 2 - p y r r o l i d o n e

E m u l s i f i e r f o r s o l v e n t s

F a t t y a c i d e t h o x y l a t e . E m u l s i f i e r .

L i n e a r a l k y l b e n z e n e s u l f o n a t e ( L A S )

N C l e a r Sodium S i l i c a t e Sodium m e t a s i l i c a t e

Nekal WT-27 A n i o n i c w e t t i n g agent

Mona

Mona

Mona

Mona

Mona

Mona

Mona

Mona

Mona

Mona

Mona

I S P

Zschim

Zschim

Stepan

PQ

Rhone-

Neodol 1 . 5 E t h o x y l a t e . L i n e a r p r i m a r y a l c o h o l S h e l l


RAW MATERIAL Neodol 23-6.5

Neodol 25-3

Neodol 25-7

Neodol 25-12

Neodol 91-6

N ino l 11-CWI

N ino l 30-LL

N ino l 40-CO

CHEMICAL DESCRIPTION C12-13 l i n e a r a l coho l .6 .5 moles EO

Cf2-15 l i n e a r a l coho l .3 moles EO

C12-15 l i n e a r a l coho l .7 moles EO

L inear p r imary a l coho l

L inear p r imary a l c o h o l . E thoxy la te

Coconut diethanolamide, mod i f i ed

A1 ky lo lamide

Cocamide DEA

P a r o i l 160 Chlor

Pemulen 1622 Resin

Pe t ro BW L i q u d & BAF Anion L i q u i d & BAF Powder & LBA L i q u i d & LBA Powder & ULF L i q u i d & 22 Powder

na ted p a r a f f i n

c s u r f a c t a n t / d

SOURCE Shel 1

Shel 1

Shel 1

Shel 1

Shel 1

Stepan

Stepan

Stepan

spersant

Dover

BFGood

DeSoto

Phosfe ta l 201

Phosphol i p i d EFA

P i l o t SXS-40

Plu ra fac C-17

P lu ra fac 0-25

Po ly te rgen t S-305LF

PQ Epsom S a l t

P r i f a c 2922

Produkt 2058

Propeta l 99

Phosphoric a c i d e s t e r Zschi m

L i ndeamidopropyl PE-Dimoni um Mona c h l o r i d e phosphate

Sodi um xy lene s u l f ona te 40% P i l o t

A1 koxy l a ted f a t t y a1 coho1 BAS F

L inear a l coho l e thoxy la te . MW:930 BASF

A lkoxy la ted l i n e a r a l coho l non ion i c O l i n s u r f a c t a n t ( l ow foam)

PQ

Laur i c a c i d Uni che

F a t t y a l coho l f a t t y a c i d e s t e r Zschi m

A1 k y l p o l y a l ky lene g l y c o l e the r Zschi m


RAW MATERIAL Propetal 241

Propetal 281

Purton CFD

PVP K-15

Renex 20

Rewoteric AM 8-14

Rewoteric AM B-15 & AM DML 35 & AM HC & AM KSF 40 & AM TEG & AMV

Rhodafac RA-600

Rhodafac RE-600

Rhodafac RE-61 0

Rhodasurf A-24

Rhodasurf LA-7

Rhodasurf LA-9

Rhodasurf LA-12

Rhodasurf 91 -6

Rhodaterge SMC

Rhodopol 23

Rhodopol 50MD

R i chami de 5725

CHEMICAL DESCRIPTION A1 k y l p o l y a l ky lene g l y c o l e the r

A1 k y l p o l y a l ky lene g l y c o l e ther

F a t t y a c i d alkanolamide

Po lyv iny lpy r ro l i done polymer

Sur fac tan t

Grease c u t t e r & foam booster

Su r fac tan ts

L inear a lcoho l e thoxy la te

Phosphate es te r

Phosphate es te r

L i q u i d non ion ic su r fac tan t . 2.5 moles EO

L i q u i d non ion ic s u r f a c t a n t . 7-9 moles EO

L i q u i d non ion ic s u r f a c t a n t . 9 moles EO



Cleaner concent ra te

Xanthan gum

Xanthan gum

RU L i q u i d Sodium S i l i c a t e co r ros ion i n h i b i t o r

SOURCE Zschirn

Eschirn

Zschi m

Rhone-

ICI

Wi t c o

w i eco

RhOne-

RhOn@-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Richar

PO


RAW MATERIAL CHEMICAL DESCRIPTION SOURCE SF96 S i l i c o n e F l u i d Polydimethyl s i l i c o n e f l u i d GE

S F I 705 React i ve S i 1 i cone Polymer GE

SF I 706 React ive S i 1 i cone Polymer GE

S h e l l f e x 213 Rubber process o i l Shel 1

She l l Sol 135 Solvent

SM2133 S i 1 i cone Emu1 s i on

SM2135 S i l i c o n e Emulsion

SMA-2625 Resin Cop01 ymer r e s i n

S-Mar 80 Sorb i tan f a t t y e s t e r

Snow F loss Minera l f i 1 l e r

Sodium A l k y l a r y l Su l fonate Powder (99%)

Sodium Alkylnaphthalene Su l fonate

Sodium Bicarbonate (Grades 1 & 5 )

Sodium Carbonate

Shel 1

GE

GE

Arco

PPGMaz

J M

W i t c o

DeSoto

Church

FMC

Sodium Dich lo ro isocyanura te , 2H20 O l i n

Sodi um T r i pol yphosphate

Sodium Xylene Su l fonate (40%)

Sokalan CP5 B HP22

Standamid PD Cocamide DEA

FMC

Stepan, W i t c o

Hen ke l

Standapol A An ion ic s u r f a c t a n t . Ammonium Stepan l a u r y l s u l f a t e (30%)

Standapol ES-3 An ion ic s u r f a c t a n t . Sodium l a u r y l Stepan e the r s u l f a t e (30%)

S t a r Sodium s i 1 i c a t e 4QBe' PQ

S t a r s o L i q u i d sodium s i l i c a t e PO

Steal CS-330 Alcohol e ther s u l f a t e Stepan


RAW MATERIAL Stepanol WA-Extra

Stoddard So lvent

STPP

S u l f e t a l 4069

S u l f e t a l 4105

Sul f ona te OA5

Super F loss

Suprag i l NK

Su r fon i c N-150

CHEMICAL DESCRIPTION Hydrotrope

F a t t y a l coho l s u l f a t e . An ion ic s u r f a c t a n t

F a t t y a l coho l s u l f a t e . An ion i c s u r f a c t a n t

Wet t ing agent

Diatomaceous e a r t h

Sodium a lky lnaphtha lene s u l f o n a t e

Surface a c t i v e agent

TEA Laury l S u l f a t e

T e r g i t o l NP

Thermphos

Thermphos NW

T inopa l 5BM

Nonoxynol

F luorescent wh i ten ing agent

Tomah A l k a l i Su r fac tan t Amphoteric (35% a c t i v e )

Tomah Amphoteric L M i I d s u r f a c t a n t

Tomah AO-14-2 Ether amine ox ide (50% a c t i v e

Tomah A0-728 Special Amine ox ide-h igh foaming (50%

Tomah Q-14-2 Quaternary

Tomah Q-17-2 Quaternary

T r i l o n A L i q u i d

T r i t o n DF-16 & N-101 Non ion ic s u r f a c t a n t s & x-45

ac t 1

SOURCE Stepan

Exxon

FMC

Zschim

Zschim

Tennes

JM

Rhone-

Texaco

Rhone-

UnCarb

Hoechs

Hoechs

C i ba-

Toma h

Tomah

Tomah

Tomah

Toma h

Tomah

Zschim

Rohm


R A W MATERIAL Tur bobr i t e

Tu rbobr i t e L

Tween 40

Ty lose CBR 10000

Ubatol TR1138

CHEMICAL DESCRIPTION A l u m i n o s i l i c a t e

A l u m i n o s i l i c a t e s l u r r y

Po lysorbate 40

V a l f o r 100 Z e o l i t e A b u i l d e r

Van Gel B & C & ES & 0 Magnesium aluminum s i l i c a t e s

Vanseal NACS-30 Sodi um 1 auroy l sarcos i na te

Vanseal NALS-30

Varami de A-1 0 & A-1 2 Detergent a1 kanolami des & A-83 & MA-1

Varonic DM-55 & K205 Nonionic w e t t i n g agents 8 T202 & T202SR

Varox 365 8 1770 Wet t ing agents

Varquat 50MC S p e c i a l t y quaternary, germic ide

Veegum & Veegum T Magnesi um a1 umi num s i 1 i ca tes

Versene 100 & 220 Che la t i ng agents

V i scas i a F l u i d ( 1 0 , O O O ) S i 1 i cone

Wachsemulsion 1864

Witcamide S-780 & 128T Alkanolamide s u r f a c t a n t s & 6445

Witco 12986

Witco 1298SA S o f t a c i d

W i t c o l a t e ES-3 & S u l f a t e d s u r f a c t a n t s LES-6OA & LES-6OC & SE-5 & WAC-LA & 2310

SOURCE PO

PQ

I C I

PQ

RTVan

RTVan

RTVan

W i t c o

w i t C O

W i t c o

w i t c o

RTVan

Dow

GE

Zschim

W i t c o

W i t c o

W i t c o

w i t c o


RAW MATERIAL CHEMICAL DESCRIPTION Witconate AOS & SXS Sur fac tan ts

& 30DS & 45 L i q u i d & 60T L i q u i d & 1240 & 1260 S l u r r y

W i t cono l NP-100 Detergents & degreasers & NP-120

Wessa l i th P Z e o l i t h P

SOUWGE \ M i ~ C O

w i tco

Ya rmor 3 02 Pine o i l Hercul

Zetesol 2056 F a t t y a l coho l e the r s u l f a t e Zschim

Zetesol NL F a t t y a l coho l e t h e r s u l f a t e Pschi I

Zusol a t 1005/85 A1 k y l po l ye thy lene g l y c o l e the r Zschim

Zusol a t 1008/85 A l k y l po l ye thy lene g l y c o l e the r Zschi rn

2 . l r Potassium s i l i c a t e (39%)

2 . 4 r Sodium s i l i c a t e (52%)

PQ

BQ

Section IV

pliers' Addresses


A1 1 i ed-Si gnal , I n c . P.O. Box 2332R Morr istown, NJ 07962

Amoco Chemical Co. 200 E. Randolph D r . Chicago, I L 60601

(201)-455-2000/(800)-526-0717

(312)-856-3200/(800)-621-8888

Angus Chemical Co. 2211 Sanders Rd. Northbrook, I L 60062

Arco Chemical Co. 3801 West Chester P ike Newtown Square, PA 19073

(708)-498-6700/(800)-323-6209

(215)-359-2000

A r i zona Chemical Co. 1001 E . Business Hwy 98 Panama C i t y , FL 32401 (904)-785-6700/(800)-526-5294

Ash1 and Chemical Co. P . O . Box 2219 Columbus, OH 43216

BASF Corp. 100 Cherry H i l l Rd. Parsippany, N J 07054

(614)-889-3333/(800)-848-7485

(201)-316-3000/(800)-526-1072

B u r l i n g t o n Chemical Co. I n c . P .O. Box 1 1 1 615 Huffman M i l l Rd. Bu r l i ng ton , NC 27215 (919)-584-0111/(800)-672-5888

C i ba-Gei gy Corp. 7 S k y l i n e D r i v e Hawthorne, NY 10532 (914)-374-4700/(800)-431-1900

DeSoto I n c . 1700 S. M t . Prospect Rd. Des P la ines , I L 60018 (312)-391-9000

Dover Chemical Corp W15 & Davis P.O. Box 40 Dover, OH 44622 (800) -321 -8805

Dow Chemical USA Midland, M I 48674 (800)-258-CHEM

Dow Corning Corp. Box 0994 Midland, M I 48686 (51 7)-496-4000

Ethy l Corp. 451 F l o r i d a Baton Rouge, LA 70801 (504)-388-7556/(800)-535-3030

Exxon Chemical Americas 13501 Katy Frwy Houston, TX 77079 (713)-870-6000/(800)-231-6f333

FMC Corp. 2000 Market S t . Ph i l ade lph ia , PA 19103 (215)-299-6000/(800)-526-3649

GE S i l i c o n e s 260 Hudson R ive r Rd. Waterford, NY 12188 (518)-237-3330/(800)-255-8886

Genesee Polymers Corp. Fenton Rd./P.O. Box 7047 F l i n t , M I 48507 (313)-238-4966

Georgia Marble C o . 1201 Roberts B l vd . Kennesaw, GA 30144 (404)-421-6500

B.F. Goodrich G o . 991 1 Brecksv i 1 1 e Rd , B r e c k s v i l l e , OH 44141 (216)-447-5000/(800)-331-1~44

Suppliers' Addresses 231

W.R. Grace 8 Co. 55 Hayden Ave. Lexington, MA 02173 (61 7 ) -861 -6600

Henkel Corp. 5325 S . N i n t h Ave. LaGrange, I L 60525 (708)-530-7300/(800)-543-7370

blercul es I n c . Hercules P1 aza Wilmington, DE 19894 (800)-247-4372

Woechst Celanese Corp. 801 Water S t . Portsmouth, VA 23704 (804)-393-3100/(800)-368-2822

I C I S p e c i a l t i e s Concord P ike & New Murphy Rd. W i 1 m i ngton , DE 19897 (302)-886-3000/(800)-822-8215

Johns-Manvi 11 e Ken Cary l Ranch Denver, CO 80217

Kaopo l i te , I n c . 2444 M o r r i s Ave. Union, W J 07083 (9081-789-0609

Kel co D i v i s i on Merck & Co., I n c . 8355 Aero D r i v e San Diego, CA 92123 (61 9)-292-4900

Kerr-McGee Chemical Corp. Kerr-McGee C t r . P.O. 80x 25861 Oklahoma C i t y , OK 73125 (405)-270-1313/(800)-654-3911

Lonfa I n c . 1717 Rta 208 F a i r Lawn, NJ 07410 (201)-794-2400/(800)-777-1875

Mona I n d u s t r i e s I n c . 76 E . 24 S t . P . O . Box 425 Paterson, N3 07544 (201)-345-8220/(800)-553-6662

Monsanto Chemical Co. 800 N. Lindbergh B lvd . S t . Lou is , MO 63167 (314)-694-1000/(800)-325-43

Morton I n t e r n a t i o n a l 100 N. R i v e r s i d e Plaza Chicago, I L 60606 (312)-807-2000/(800)-367-33

O l i n Corp. 120 Long Ridge Rd. P . O . Box 1355 Stamford, CT 06904 (203)-356-2000/(800)-243-9171

P e t r o l i t e Corp. 6910 E. 14 S t . Tulsa, OK 74112 (918)-836-1601

P i l o t Chemical Co. 11756 Burke S t . Santa Fe Spr ings, CA 90670 (310)-723-0036

PPG/Mazer One PPG Place P i t t sbu rgh , PA 15272 (412)-434-3131/(800)-243-6774

PQ Corp. P . O . Box 840 Va l l ey Forge, PA 19482 (215)-293-7200

Quest I n t e r n a t i o n a l Fragrances 400 I n t e r n a t i o n a l D r i v e Mount O l i v e , NJ 07828 (201 )-691-7100


Rhone-Poul enc Prospect P l a i n s Rd. Cranbury, N J 08512 (609)-860-4000/(800)-626-2613

Richardson Co. 2400 East Devon Ave. Des P la ines , I L 60018

Rohm & Haas Co. Independence Ma l l West Ph i l ade lph ia , PA 19105 (215)-592-3000

She l l Chemical Co. P .O. Box 2463 Houston, TX 77252 (713)-241-6161

Stepan Co. 22 W . Frontage Rd. N o r t h f i e l d , IL 60093 (708)-446-7500/(800)-745-7837

Tennessee Chemical Co. 3400 Peachtree Rd NE A t lan ta , GA 30326 (404)-239-6700/(800)-241-1912

Texaco Chemical Co. 3040 Post Oak 8 l v d . Houston, TX 77056 (713)-961-3711

3M 3M Center S t . Paul, MN 55144 (612)-733-5454

Tomah Products, I n c . 1012 Te r ra D r i v e M i 1 ton , W I 53563

Uni chema Chemicals I n c . 4650 S. Racine Ave. Chicago, IL 60609

(608)-868-68l l / (800)-441-0708

(312)-376-9000/(800)-833-2884

Union Carbide Corp. 39 Old Ridgebury Rd. Danbury, CT 06817 (203)-794-2000

R . T . Vanderb i l t Co., I n c . P.O. Box 5150 30 W i n f i e l d S t . Norwalk, CT 06856

Witco Corp. 520 Madison Ave. New York, NY 10022

(203)-853-1400/(800)-243-6084

(212)-605-3941/(800)-634-4010

Zschimmer & Schwarz Max-Schwarz-Strabe 3-5 D-56112 Lahnstei n/RH D 26 21/120

Advanced+Cleaning+Product+Formulations+Volume5[1]

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