Advanced IGCC with Partial Carbon Capture · CO2 Removal CO2 Raw Syngas Nitrogen Shifted Syngas...

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Advanced IGCC with Partial Carbon Capture Presented at: GTC Conference October 2013 Jacobs 1500 Hughes Way, Pod B Suite 400 Long Beach, CA 90810 www.jacobs.com

Transcript of Advanced IGCC with Partial Carbon Capture · CO2 Removal CO2 Raw Syngas Nitrogen Shifted Syngas...

Advanced IGCC with Partial Carbon Capture Presented at:

GTC Conference

October 2013

Jacobs1500 Hughes Way, Pod B Suite 400Long Beach, CA 90810www.jacobs.com

Slide 2

Introduction to Jacobs

• Safety is key to everything we do• A global leader in technical professional services• 65,000 professional staff at 200+ locations in 25

countries• $11 billion in revenue• $16 billion in backlog• Publicly traded on NY stock exchange• Sound financial base• Business model is long term client alliances

Slide 3

Who Is the CCPC?

The CCPC is an association of Canadian and U.S. coal and coal-fired electricity producers, government agencies and research organizations

Industry participants include: Alberta Innovates – Energy and Environment Solutions Capital Power Corporation Electric Power Research Institute (EPRI) Nova Scotia Power Inc. Sherritt International Corporation SaskPower TransAlta Corporation

The CCPC's mandate is to research technologies with the goal of developing and advancing commercially viable solutions that lower coal power plant emissions

Slide 4

Introduction

Canadian and US Government have new regulations limiting the emissions from new Fossil Fuel power plants to below 500 kg CO2/MWh.

This equates to about 60% carbon capture. Most published work on carbon capture has focused on

capturing over 90% of the carbon emitted with a limited number of processes and configurations.

Limiting the level of carbon captured enables alternative technologies and process configurations to be used.

Significant increase in overall plant efficiency and reduced capital cost.

Slide 5

Base Case – Unit Operations

Gasification

ASU

Sour Shift & Gas Cooling

SulphurRemoval

CombinedCycle

Oxygen

Coal

Sulphur

Electricity

CO2 Removal

CO2

Raw Syngas

Nitrogen

Shifted Syngas

ConditionedFuel Gas

Slide 6

Base Cases

Unit Operation

Technology

Air Separation • Cryogenic • Cryogenic

Gasifier • AR (Aerojet Rocketdyneformerly PWR)

• SES U-Gas

Shift • Sour• Full

• Sour• Full

Sulphur Removal

• Selective Selexol • Selective Selexol

CO2 Removal • Selective Selexol • Selective Selexol

Sulphur Recovery

• Claus • Claus

Gas Turbine • 2 x GE 7 F • 2 x GE 7 F

Slide 7

Technologies Identified for EvaluationUnit Operation

Technology

Air Separation • Cryogenic • Air Products ITM

Gasifier • AR • SES U-Gas

Shift • Sweet• Full

• Sour• Partial

Sulphur Removal

• RTI WGCU • Selective Solvent

CO2 Removal • CO2 Selective Membrane• High Recovery PSA• Selective Solvent

• Non-selective solvent• H2 selective membrane• Cryogenics

Sulphur Recovery

• Claus• Wet Sulphuric Acid

• RTI Direct Sulphur Recovery Process (DSRP)

• LoCat

Slide 8

Option Matrix

AR

Partial

RTI Warm Gas

ClausSelective SelexolSour Shift

SES

Full

Modified Claus

Sweet Shift

Sour High Recovery

PSA

H2 membrane

CO2 membrane

RTI DSRP

Partial

Full

Sweet High Recovery

PSA

Sour H2 membrane

Sour CO2 membrane

Wet Sulphuric Acid

ITM

Cryogenic

Low Pressure

LoCat

High Pressure

LoCat

High Pressure

LoCat

H2 membrane

CO2 membrane

Sweet High Recovery

PSA

Non-Selective Solvent

Cryogenic Separation

Cryogenic Separation

Sulphur Recovery

CO2 Removal

Sulphur RemovalShift ExtentShiftGasifierASU

Non-Selective Solvent

Non-Selective Solvent

Slide 9

Selected Configurations (1) Case 1 2 3

ASU Cryogenic Cryogenic Cryogenic

Feed Preparation Dry Milling Dry Milling Dry Milling

Gasification AR AR AR

Shift & Gas Cooling Double Sour Shift Double Sour Shift Double Sour Shift

Sulphur Removal LoCat LoCat LoCat

CO2 Removal Partial Condensation with by-pass

High Recovery PSA with by-pass

CO2 Membrane with by-pass

CO2 Compression & Drying

Pumped Liquid CO2, Included with CO2Removal

CO2 Compressor CO2 is compressed, Liquefied, then Pumped

Sulphur Recovery Unit

LoCat LoCat LoCat

Power Block 2 x 1 7F Syngas no airside integration

2 x 1 7F Syngas no airside integration

2 x 1 7F Syngas no airside integration

Slide 10

Selected Configurations (2)

Case 4 5-2 5-4

ASU Cryogenic ITM ITM

Feed Preparation Dry Crushing Dry Milling Dry Crushing

Gasification SES U-Gas AR SES U-Gas

Shift & Gas Cooling Double Sour Shift, partial by-pass

Double Sour Shift Double Sour Shift, partial by-pass

Sulphur Removal LoCat LoCat LoCat

CO2 Removal Non-selective solvent High Recovery PSA with by-pass

Non-selective solvent

CO2 Compression & Drying

CO2 Compressor CO2 Compressor CO2 Compressor

Sulphur Recovery Unit

LoCat LoCat LoCat

Power Block 2 x 1 7F Syngas no airside integration

2 x 1 7F Syngas airside integration

2 x 1 7F Syngas airside integration

Slide 11

Overall Summary of AR CasesBase Case Case 1 Case 2 Case 3 Case 5-2

Gasifier Technology AR AR AR AR ARAir Separation Cryo Cryo Cryo Cryo ITMSulphur Capture Selexol LoCat LoCat LoCat LoCat

CO2 Capture SelexolPartial

Condensation PSA Membrane PSA

Coal Feed (AR) t/d 6,881 7,011 7,053 6,994 7,948CO2 Produced t/d 12,509 12,740 12,817 12,711 14,443CO2 Captured t/d 11,626 7,544 7,280 7,752 7,844CO2 Released t/d 883 5,196 5,537 4,959 6,599

CO2 Intensity kg/MWh 80.0 418.0 417.9 418.9 416.3

Gross Power Produced MW 656.4 681.1 693.7 678.8 653.1Total Power Consumed MW 230.9 163.2 171.3 186.8 24.7Net Power Output MW 425.5 517.9 522.4 492.0 628.4

Heat Rate LHV kJ/kWh 12,159 10,178 10,152 10,688 9,510Efficiency LHV % 29.61 35.37 35.42 33.68 37.86

Capital Cost (USCG) MM USD 2,303 2,107 2,126 2,108 2,616Specific Cost $/kW 5,461 4,068 4,070 4,283 4,163

Slide 12

Overall Summary of SES CasesBase Case Case 4 Case 5-4

Gasifier Technology SES SES SESAir Separation Cryo Cryo ITMSulphur Capture Selexol LoCat LoCatCO2 Capture Selexol Selexol CO2 Selexol CO2

Coal Feed (AR) t/d 6,401 6270.4 7,591CO2 Produced 11,067 10,838 13,122CO2 Captured t/d 8,711 5,796 6,766CO2 Released t/d 2,356 5,042 6,356

CO2 Intensity kg/MWh 212.0 417.2 416.7

Gross Power Produced MW 604.7 639.1 584.5

Total Power Consumed MW 163.0 156.2 -27.1Net Power Output MW 441.8 482.9 611.6

Heat Rate LHV kJ/kWh 10,894 9,763 9,334Efficiency LHV % 33.05 36.88 38.57

Capital Cost (USCG) MM USD 2,129 1,892 2,238Specific Cost $/kW 4,838 3,917 3,660

Slide 13

Cost of Electricity – First Year

0

25

50

75

100

125

150

175

Cost of E

lectric

ity ($

/MWh) 

Transmission

O & M

Fuel Costs

Capex

Slide 14

Cost of CO2 Capture – First Year

0

20

40

60

80

100

120

140

160

180

200

Cost of C

O2 Ca

ptured

 ($/M

O & M

Fuel Costs

Capex

Slide 15

Avoided Cost of CO2 – First Year

0

50

100

150

200

250

300

Avoide

d Co

st of C

O2 ($/M

T)

O & M

Fuel Costs

Capex

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