410 - link.springer.com
Transcript of 410 - link.springer.com
INDEX
Acetic anhydride cyclodehydration agent, 220
Acetoamides synthesis, 277
Acetone polyanhydride solvent, 193
Acetone cyanohydrin azlactone raw material, 225
a-Acetoxypropionic acid ring closure to lactone, 443
Acetyl acetone, 464 manganese decarbonyl coordi
nating agent, 300 Acetyl chloride
coumalic acid reaction, 61 polystyrene living particle
reaction, 400 Acetylene carbonyls
amine condensations, 276 Acrolein
acetal formation, 62, 74 Acrylamide
hydrophilic grafts on polymers, 293
functionalized oligomers, 205, 211, 215-217
ORTEP plots, 212 purification, 308 telechelic oligomers, 203
Acrylamides, bis type amine reaction, 215
Acrylamides, telechelic characterization, 208 synthesis from azlactones,
219, 221 Acrylates, alkyl
anionic polymerization, 327 alkali metal alkoxides
polymerization, 327 group transfer polymerization,
327 Acrylates, perfluoroalkyl
methacryloyl polystyrene macromer copolymerization, 463
Acrylic acid biomer polymer activity, 309
Acrylonitrile purification, 409 sodium naphthalene polymerized,
410 N-Acryloyl-a-aminoisobutyrate
synthesis, 225 N-Acryloylmethylalanine
ethyl chloroformate reaction, 206 Activation energy
styrene anoinic dispersion polymerization, 392, 296
a-Acylamino-a-aminopropionic acid conversion to a-lactone, 445
N-Acylurea, 307 Adhesives, hot melt
synthesis concept, 480 Adipic acid, 192 Adipic acid, metal salts
phosphorus acid chloride condensation, 195
Aldehydes anionic polymerization, 322
Alkenes triazolinedione ene reaction, 2
Alkenyl azalactone amine oligomer reaction, 208,
210, 211 2-Alkenyl-2-oxazoline-5-ones
amine reactions, 205, 211 Alkoxides
catalyst for oxazolidone formation, 252
Alkoxides, polymeric ethylene oxide polymerization,
330 Alkyl ketones
cycloaddition reaction, 1 Alkyllithium
anionic polymerization initiator, 335
Alkyllithium, anionic initiators copolymerization reactivity
ratios, 335
517
Allyl chloride N-(2-hydroxyethyl) amide
reaction, 240 Allyltrimethylsilane triazoline
dione reaction, 2 Aluminum chloride
benzene-sulfur reaction catalyst, 176
Friedel-Crafts catalysts, 159-162, 164, 166, 167
Aluminum trichloride S-propiolactone polymerization
catalyst, 450, 451 Amides, N-halo derivative
polymer halogenation agents, 295 Amines
acetylene carbonyl reaction, 276 1, 3-dicarbonyl reaction, 276
Amines, primary benzoxazine synthesis, 27, 28,
48 Amines, titration
perchloric acid/glacial acetic acid method, 206, 207, 208
Amino acids alkaloids preparation, 425 diacid chloride reaction, 220 optically active enantiomers,
resolution, 425, 438 Aminoalkylation
phenols, 29, 48 p-Aminobenzoic acid
polyphosphonamide monomer, 190 polyamino acid monomer, 190
Antibiotics polypeptide containing, 419
Aromatic polymers interfacial polymerization
production procedure, 54, 59
Arrhenius equation benzoxazine polymerization, 41
Arrhenius plot methyl methacrylate radical
polymerization, 511 styrene anionic dispersion
polymerization, 392, 396 Arsenic pentafluoride
PPS dopant, 182 Arsenic trifluoride
PPS dopant, 182 Arterial prosthesis
poly(ether-urethane) based, 309 (-)-Asparagine
conversion to optically active S-propiolactone, 445
Aspergillus flavus, 277 Aspergillus niger, 277
518
Azlactones alkenyl oligomers, 203 amine oligomer reactions, 203 amine reactions, 217, 219 bis-thio reaction, 225 n-butylamine reaction, 231 2-cyanoethyl methylamine
reaction, 231 mercaptan reactions, 219 nucleophilic attack, 231
ring-opening, zwitterionic reaction, 205
synthesis, 225 Azlactones, alkenyl
amine oligomer reaction, 221 1, 2-ethanediol addition reaction,
221, 222 ethylene-bis (3-mercaptopro-
pionate) reaction, 221 Jeffamine reaction, 229, 230 Michael addition reaction, 229 Mercaptan reaction, 229 Nucleophilic reactions, 219, 232 polymerization reactions, 232 polythiol reaction, 223, 224 synthesis procedure, 221
Azalactones, isopropenyl substituted nucleophilic reaction, 219
Azalactones, multifunctional applications, 232 characterization, 224 curing mechanism, 232 expansion polymerization, 232 Michael addition, 232 Nucleophilic addition, 219, 220,
232 ring opening polymerization, 231,
232 synthesis, 221, 223, 224
Azalactones, vinyl substituted amine reaction, 229, 230 bis-mercaptan reaction product
identification, 226 characterization, 227, 228 mercaptan Michael addult, 226-229 nucleophilic reactions, 219
Azobisisobutyromitrile radical polymerization catalyst,
507-511, 514
Benzene iron trichloride catalyzed
sulfur monochloride reaction, 177
sulfur-aluminum chloride polymerized, 160, 170
sulfur reaction, 159-162, 164, 170, 171
Benzenesulfonamide-a-propiolactones, a-(p-substituted)
optically active monomer synthesis, 445
Benzophenone photosensitizer, 125
Benzoxazines amine containing phenolic
resins, 48 antioxidant uses, 48 applications, 47 bulk polymerization, 29 C14 labeled, 48 carbon substrate grafting, 29, 48 characteristics, 27, 29, 48 complexing agents, 48 2,4-dimethylphenol reaction, 32 2,6-dimethylphenol reaction, 32 2,4-ditert-butylphenol polymeri-
zation rate, 39-41, 43 2,6-ditert-butylphenol reaction,
31 epoxy resin crosslinker, 47 fiber reinforced laminate uses,
47 oligomer applications, 47, 48 oligomerization reactions, 47, 48 ortho and para substituted, 48 phenol activation energy, 30-32 phenol initiated polymerization,
33-37, 47, 48 phenol reaction, 28-31, 33, 34,
48 phenol reaction rate constants,
30, 31, 33 phenolic resin uses, 47 polymerization activation
energy, 41 polymerization kinetics, 35-37,
48 polymerization mechanism, 37-39 polymerization rate constants,
40, 41 polymerization rate equation,
37-39 polymerization routes, 35 polymer molecular weights, 37,
38, 47 polymer structure, 35 ring opening polymerization,
27-29, 33-36, 48 synthesis, 28, 48 thermal initiated
polymerization, 34, 42, 43 thermal polymerization kinetics,
43-47 thermal polymerization
mechanism, 45 thermal properties, 31, 34
Benzoyl peroxide radical polymerization
initiator, 510, 511 Benzyl bromide
N-(2-hydroxyetnyl) amide reaction, 240
Bernoullian statistics poly (a-propiolactones), 453 poly (a-trichloromethyl
a-propiolactone), 447 a-substituted poly
(a-propiolactones), 447 Biomer
bromination, 310-312 chlorination, 310-312 REMA grafted, 313 REMA palmitate ester grafting,
313-315 methyl methacrylate grafted, 313 prosthesis materials, 309-311 vinyl monomer grafting, 315
Biopolymers cellulosic type, 405 protein type, 405 starch type, 405
Biphenols bisphenate complex, 115 bisphenate synthesis, 114, 115 dihaloalkane polyetherification,
143 etherification mechanism, 143 Schotten-Baumann reaction, 189
4,4'-Biphenol polyether synthesis, 98, 99,
101, 105, 108, 109 purification, 97
Biphenols, sodium salts aryl halide reactions, 114-116
N,N'-Bis(acetacetyl)-1,4-piperazine p-n-butylamine model compound,
283, 285 p-N-butylaniline reaction, 280 1,10-decamethylenediamine
condensation, 282 diamine reaction product
characterization 281, 284 Jeffamine polycondensation, 286 p-phenylenediamine condensation,
282 poly(amide enamine) monomer, 279 synthesis, 280 m-xylxylenediamine condensation,
282 Bis(acetylacetone) ethylenediamine
tautomeric forms, 276 Bis-acetylacetylarenes
diamine polycondensation, 278
519
2,2-Bis(4-amino cyclohexyl) propane polyamide monomer 59, 60, 65-70,
80-83, 85-88 purification, 72
Bisazlactones applications, 220, 221 diamine polymerization, 220 epoxy resin alternative, 231 isocyanate resin alternative, 231 Michael-type reaction mechanism,
223 oligomeric materials, 229 polyamine reactions, 231, 232 polymerization rates, 231 polyols reaction, 231 synthesis procedure, 220
1,4-Bis(3-p-n-butylanilino-2-butenoyl) piperzine
synthesis, 280 1,2-Bis-(4-carboxyphenoxy) ethane
dibasic acid chloride condensation, 188
monomer for polyester, 188 1,3-Bis(4-carboxyphenoxy) propane,
192 Bis(1,3-diketone)
diamine condensations, 278 Bis(dimethylamino benzophenone)
anionic living polystyrene reaction, 401
1,8-Bis-(dimethylamino)naphthalene, 69, 87
1,6-Bis-(3,5-dioxo-1,2,4-triazoline-4-yl)hexane
synthesis, 8, 10, 18 Bis-(p-3,5-dioxo-1,2,4-triazoline-
4-yl-phenyl)methane copolymerization reaction, 13 synthesis, 10, 11, 18
2,2-Bis[p-(2,3-epoxypropyl)phenyl j propane
2,4-toluene diisocyanate reaction, 252
2, 2-Bis (4-hydroxyphenyl) propane 4,4'-dichlorodiphenyl sulfone
reaction, 239 polyarylate monomer, 94, 95 polyether monomer, 94-96 polyester comonomer, 54, 59, 60,
65-68, 70, 79-81, 83, 88 purification, 72 tetramethyl derivative, 113
Bis-ketoesters diamine polycondensations, 276
Bis-(methyl-4-N-phenylene carbamate) methane
N,N-diglycidylaniline reaction, 258
diisocyanate copolymerization, 265
520
Bis(methylurethane) epoxide reaction, 265
Bisoxazoline dicarboxylic acid
copolymeriztion, 236 ring opening polycondensations,
235 Bis(phenylthio)benzene
synthesis, 169 Bis-triazolinediones
copolymerization, 19 copolymer thermal properties, 23 B-dicarbonyl compound reactions,
2 Diels-Alder Copolymerizations, 19 Diels-Alder reaction, 1 Diene reactions, 2 identification, 18, 19 ene reaction, 1 synthesis, 18, 19
Bisurethanes diepoxides polymerization, 256
Boron trifluoride, diethyl etherate oxazoline polymerization
catalyst, 238, 239 thiol-azlactone reaction
catalyst, 229 B-Bromobutyric acid
D-(+)-B-butyrolactone conversion, 445
1-Bromopentane, 136 polyether terminator, 145, 146
N-Bromosuccinimide poly(aryl ether sulfone)
bromination, 118 2-Bromoterephthalic acid, 192 4-Bromothiophenol
PPS intermediate, 175 copper salt/pyridine
polymerized, 175 Brucine
amino acid resolving agent, 425, 427
chiral base, 446 Butadiene
anionic polymerization polystyryl anion, 322, 347
s-butyllithium polymerization, 333, 334
diphenylethylene dilithium polymerized, 325
isoprene copolymerization, 336 isoprene stereospecific
copolymerization, 483 polymerization mechanism, 502
1,4-Butanediol polyester monomer, 53, 56
n-Butoxylithium epoxide-isocyanate reaction
catalyst, 252 Butyl acrylate
methacryloyl polystyrene macromer copolymerization, 463
p-n-Butylaniline, 279 N,N'-bis(acetacetyl)-1,4-
piperazine reaction, 280 Butyl lithium
anioinc polymerization initiator, 322, 325, 382, 383, 396, 464, 467
s-Butyl lithium s-butyl methacrylate anioinc
polymeriztion, 352 diamine complexes for polymer
metalation reactions, 336 diphenylethylene adduct 325,
348, 349 oxazolinium triflate salt
reaction, 248 polystyryl monocarbanion
synthesis, 410 n-Butyl lithium
diphenylmethane reaction, 367 styrene polymerization, 464,
467, 468 iso-Butyl methacrylate
anionic polymerization, 352 s-Butyl methacrylate
high conversion polymerization, 513
t-Butyl methacrylate anionic polymerization, 347, 351
t-Butyl peroxypivalate radical polymerization
initiator, 506 n-Butylphosphorodichloridate, 192 D-(+)-~-Butyrolactone
synthesis procedure, 445 t-Butylstyrene
styrene diblock copolymerization, 382, 383
1,4-Butynediol polyester monomer, 53
Calcium chloride methyl methacrylate
purification, 356 Calcium hydride
methyl methacrylate purification, 356
monomer drying agent, 348 Camphor sulfonic acid
amino acid resolution agent, 427
Carbon black benzoxazine grafting, 29, 48
Carbon dioxide carbonation of carbanionic
polymers, 327-329 Carbon tetrachloride
metal redox reaction, 294 N-Carbobenzoxy-trans-3-ethylproline
brucine resolution, 427 quinine resolution, 427
N-Carbobenzoxy-2-methyl pipe colic acid
quinine resolution, 427 N-Carbobenzoxy-2-methylproline
quinine resolution, 427 a-Carboxy-o-anisic acid, 192 N-Carboxyanhydrides
ring opening polymerization, 428, 429
triethylamine polymerization, 428, 429
5-(6-Carboxyhexyl)-1-(3-cyclohexyl-3-hydroxypropyl)hydantoin
attachment to poly(ether-urethane), 295, 267
bioactivity, 305 esterification reaction, 301 mass spectrum analysis, 302,
303, 305 methacrylic acid reaction, 296 methacrylate ester grafting, 297 NMR characterization, 304, 305 trichloroethylester character-
ization, 305, 306 tritium labeled, 296 vinyl ester bioactivity, 318 vinyl ester characterization,
305, 307 vinyl ester platelet aggregation
prevention, 317, 318 Carboxylic acid chlorides
a-amino acid reaction, 220 p-Carboxyphenoxyacetic acid, 192 Catalysts
ethylimidazole, 259 hydrogenation of dienes, 335 lanthanide coordination type, 483 tetraethylammonium bromide, 259
Catalysts, organometallic anionic initiators, 327
Catalysts, phase transfer type, 189, 190, 195, 240, 242, 243
etherification reaction, 134 Cellulosates, alkali metal
anionic polymerization initiator, 407
521
Cellulose acetic anhydride reaction, 409 acetylation procedure, 409 anionic living polymer reaction,
407, 408 electrophilic group
modification, 408, 410 free radical monomer grafting,
406 graft polymerization, 406, 408 grafting anionic prepared living
polymers, 416 leaving group attachment, 408 oxidation method, 409 polystyrene grafted, 405 polystyrene grafted,
characterization, 411 rubber grafted, 405 sodium metaperiodate oxidation,
410 triacetate synthesis, 413 vinyl monomers anionic grafting
polymerization, 407 Cellulose acetate
characterization, 414, 415 graft copolymer
characterization, 413 grafting procedure, 409 living polymer grafting, 410 polyacrylonitrile grafted, 413 polystyrene grafted, 413 synthesis procedure, 409
Cellulose, oxidized grafting reactions, 408
Cellulose, polystyrene grafted thermal properties, 411
Chelates enamine carbonyl based, 275
Chloral ketene reaction to lactone. 446
Chloroacetone phenol condensation, 135
Chlorobenzene, 149 2-Chlorobutadiene
Diels-Alder reaction, 1 Chloroform
polyamide solvent, 69 Chloromethylsilane
coupling to polydienes, 338 l-Chloronaphthalene, 168
PPS solvent, 179 4-Chlorophenyl phosphoro
dichloridate, 192 Chloroprene, 502 6-Chloropropionaldehyde diethyl
acetal
522
conversion to 4,4'-diethoxybutyronitrile, 62, 74
6-Chloropropionaldehyde diethyl acetal (continued)
sodium cyanide reaction, 62, 74 synthesis procedure, 62, 74
6-Chloropropionic acid ring closure to lactone, 443
Cinchonidine optically active acid
resolution, 444 Citraconic acid, 192 Coatings, powder
bisazlactones use, 220 Cobalt octoate
diene hydrogenation catalyst, 335
Composites biopolymer containing, 405 grafted cellulose reinforcement,
406 grafted synthetic polymer
containing, 405 Copolyesterification
mesogens with various spacers, 146
Copolyesters crystallization-induced
reactions, 134 isotropization temperature, 146 linear random type, 153 liquid crystalline type, 148 mesogenic phases, 146 microstructure, 134 reorganization, 134 smectic mesomorphism exhibiting,
153 thermal behavior, 146, 147 thermotropic type, 153
Copolyetherification 4,4'-dihydroxybiphenyl, 154
Copolyethers characterization, 144, 152, 153 4,4-dihydroxy-a-methylstilbene
contining, 138-147 liquid crystalline properties,
146, 148, 149 synthesis, 138, 139, 144, 152 thermotropic type, 133
Copolyethers, liquid crystalline 4,4'-dihydroxybiphenyl based,
152, 154 Copolymerization
anionic methods, 338, 339 cationic methods, 339 Diels-Alder mechanism, 12 free radical methods, 339 mesogenic monomers, 134
Copolymerization, anionic butadiene-isoprene reactivity
ratios, 335, 335
Copolymerization, anionic (continued)
butadiene-styrene rate constants, 335
butadiene-styrene reactivity ratios, 335, 336
macromer grafting reaction, 463 styrene-t-butylstyrene
reactivity ratios, 336 styrene-p-methylstyrene
reactivity ratios, 336 Copolymerization, anionic grafting
initiation site synthesis, 336 Copolymerization, cationic
oxazolines mixed 239 Copolymerization, coordination
macromer grafting reaction, 463 Copolymerization, radical
macromer grafting reaction, 463 Copolymers
alternating segmented synthesis, 93, 94, 96, 104-108, 139
block type 93-96 electrophilic functionalities
grafting, 337 hydrophilic-hydrophobic grafts,
463, 478 morphologies, 93-96 polysulfone-terephthalate type,
109 random block type, 94, 96, 106 stereoblock type tacticities, 364 triblock type, 139
Copolymers, AB block poly(methyl methacrylate), 375-
378 sequential anionic
polymerization, 366 Copolymers, ABA block
bifunctional anionic initiator use, 366
styrene-butadiene-styrene, 93 Copolymers, alternating, 1-3, 134
bis-triazolinedione containing, 19
Copolymers, amphiphilic grafted synthesis procedures, 407
Copolymers, block alkyl methacrylates mixed, 358 amphipathic graft type, 381 anionic polymerization, 322, 353 living anionic polymerization
method 342, 351, 353 methacrylate containing, 326, 361 mixed methacrylate synthesis, 361 model polymerization methods, 342 2-oxazoline derived, 235 poly(styrene-co-ethylene oxide),
478
Copolymers, block (continued) styrene-butadiene-styrene, 93
Copolymers, branched synthesis methods, 331
Copolymers, comb-type synthesis procedures, 336 tailor made synthetic polymers,
407 Copolymers, diblock
styrene-t-butylstyrene containing, 382
Copolymers, graft amphiphilic type, 407 anionic polymerization methods,
335-337 cellulosic type, 405 comb-type synthesis, 335, 339 emulsifying properties, 480 ethylene oxide-polystyrene epoxy
ether copolymerization, 465, 470, 471-475
hydrophilic linked polymer, 407 macromonomer synthesis method,
342 mechanisms for grafting, 406, 408 model polymerization methods, 342 2-oxazoline derived, 235, 238 radical polymerization methods,
336 synthesis procedure 236, 238,
239, 339 N-vinylpyrrolidone-hydroxyethyl
methacrylates, 316 N-vinylpyrrolidone-methacrylate
on Pellethane, 313, 315 water absorbing properties, 480
Copolymers, hydrophobic hydrophilic polymer grafted, 407
Copolymers, segmented mechanical properties, 108, III thermal properties, 108-110
Copolymers, triblock type, 134 Cotton, 405 Coumalic acid
acid chloride synthesis, 60 diazomethane reaction, 61 methylation reaction, 61 synthesis procedure, 60, 61, 72,
73 Coumalyl chloride
production procedure, 61 m-Cresol, 279
polyamide solvent, 69, 70 15-Crown-5 ether
phase transfer catalysts, 197 18-Crown-6 ether
phase transfer catalysts, 197, 199, 200
polyetherification catalyst, 143
523
Cyanoacrylates, alkyl anionic polymerization, 322, 327 tertiary amine polymerization,
327 phosphine polymerization, 327 polymerization inhibitors, 327
Cyclodepsipeptide roseotoxin B, 420
1,3-Cyclohexadiene lithium naphthalene polymerized,
325 Cyclohexane
styrene polymerization solvent, 392
Cyclohexene Diels-Alder reaction, 1
Cyclohexylphosphonic dichloride, 192
DABCO triethylene diamine, 267-269,
271, 272 Dacron
vascular grafts modification, 292 1,10-Decamethylenediamine, 279
N,N'-bis(acetacetyl)-1,4-piperazine condensation, 280, 282
Decamethylenedioxydianiline, 279, 282
Dental impression materials triazolinedione containing, 3
Diallyldimethyl silane triazolinedione reaction, 2
Diamides diepoxide reactions, 254
Diamines bis-ketoester reactions, 276
Diazetidine synthesis, 2
Dibenzoyl tartaric acid amino acid resolution agent, 427
Dibenzoyltartaric acid, (+) or (-) ethyl 2-ethyl-2-phenyl-3-amino
propionate diastereoisomeric salts, 444
Dibenzoyl-D-tartaric acid, (+) isomer
3-ethylproline optical isomers resolution, 438
a,w-Dibromoakanes biphenol etherifications, 134,
136-138 4,4'-Dihydroxybiphenyl reaction,
138 a,w-Di (bromoalkoxy) copolyethers
4,4'-dihydroxybiphenyl containing, 138
4,4'-dihydroxy-a-methyl stilbene containing, 137
524
a,~-Di(bromoalkoxy)copolyethers (continued)
synthesis procedure, 137 a,w-Di(bromoalkoxy)polyethers
4,4'-dihydroxybiphenyl containing, 137
synthesis procedure, 136 Dibromo-bis(triphenylphosphine)
nickel catalyst for PPS synthesis, 178
1,4-Dibromobutane polyetherification, 143
1,2-Dibromoethane, 143 polyethermonomer, 139
1,7-Dibromoheptane 4,4'-dihydroxybiphenyl reaction,
138 polyether monomer, 136-138
144, 147, 151-154 1,9-Dibromononane
4,4-dihydroxybiphenyl reaction, 138, 152-154
1,5-Dibromopentane polyether monomers, 136-138, 147
1,3-Dibromopropane polyether monomer, 141 polyetherification, 143
Dibromoxylene carbanionic polymer reaction,
332, 333 a,a'-Dibromo-p-xylene
diphenol reaction, 239 Dibutyl magnesium
hydrocarbon monomer purification agent, 247, 248
monomer drying agent, 348 water reaction, 347
Di-t-butyl sulfide chain transfer agent, 514, 515 degradative chain transfer
effects, 515 1,3-Dicarbonyls
amine polycondensations, 276, 288 Dicarboxylic acids
bisoxazoline copolymerization, 236
Dicarboxylic acids, salts organophosphorus dichloride
reactions, 192 o-Dichlorobenzene, 149, 258
isocyanate-epoxide reaction solvent, 252
polyetherification solvent, 136, 137
polymerization solvent, 139 1,4-Dichlorobenzene
arylene sulfide polymer intermediate 175, 176
reaction with sulfur, 175, 176 sodium sulfide reaction, 173
1,4-Dichloro-2-butene, cis isomer diphenol rea~tion, 239
Dichlorodiphenyl sulfone bisphenate reaction, 114 chlorine hydrolysis, 114
4,4-Dichlorodiphenyl sulfone diphenol reaction, 239 polyether formation, 98 purification, 97
B-l,I-Dichloroethyl-B-propiolactone chiral europium salt complex
resolution, 447 Dichloromethane, 225 B-Dichloromethyl-B-propiolactone,
racemic enantiomeric excess assay, 448 enantiomers separation, 448
1,4-Dicyanobutane polymerization solvent, 69, 86
Dicyclohexyl carbodiimide N-acryloyl-a-aminoisobutyrate
cyclodehydration, 225, 226 esterification agent, 301 N-methacryloylmethylalanine
reaction, 206 Diels-Alder reaction
bis-triazolinediones, 1,2, 15, 17, 18, 20
1,3-Dienes anionic polymerization, 321,
322, 324, 333 dibutyl magnesium water removal,
348 polymerization mechanism, 502 stereospecific polymerization,
483, 484 Dienophiles, 1 Diepoxides
diisocyanates copolymerization, 265
diisocyanate reaction products, 254
Diethylaluminum chloride porphyrin adduct B-propiolactone
polymerization, 451 Diethyl N-benzyloxycarbonylamino
malonate 2-pentenal reaction adduct, 420 synthesis route, 420, 421, 438
Diethylene glycol dimethacrylate, 301
Diethyl ethoxymethylene malonate diamine reaction, 277
Diethyl 3,4-Furan dicarboxylate hexamethylene diamine
polycondensation, 57 Diethyl methylmalonate
ethyl iodide coupline, 444
Diethyl 3,4-thiophene dicarboxylate hexamethylene diamine
polycondensation, 57 Diethyl zinc, water cocatalyst, 451
B-propiolactone polymerization catalyst, 451
1,6-Diethoxy-l,5-hexadiene-3,4-dione dianiline reaction, 278
4,4-Diethoxybutyronitrile ethyl oxalate reaction, 63 synthesis procedure, 62, 63, 74
Difluorobenzophenone bisphenate reaction, 114
Diglycidyl aniline, 257 Diglycidyl ether bisphenol A, 257
4,4'-diisocyanatodiphenyl methane reaction, 258, 259, 265-269
4,4'-diamodiphenylene methane cured, 271
Diglycolic acid, 192 2H-3,4-Dihydro-l,3-benzoxazine
production raw materials, 48 structure, 27 synthesis, 27, 48
4,4'-Dihydroxybiphenyl copolyethers synthesis, 149 a,w-dibromoalkane reaction, 134,
137, 138 polyethers synthesis, 148, 149,
151 polyether thermodynamic data, 150
4,4'-Dihydroxy-a-methylstilbene copolyethers contianing, 146-148 a,w-dibromoalkane reaction,
134-138, 144 polyethers containing, 138,
146-149, 153 synthesis, 135
a,w-Di(hydroxyphenyl)polyether synthesis procedure, 136
Diisocyanates allophanate reaction, 204, 205 diepoxide reaction products,
254, 265 oligomeric diol reaciton, 204
4,4'-Diisocyanatodiphenylene methane
bis(methyl urethane), 265 diglycidyl ether bisphenol A
polymerization, 264 phenyl glycidyl ether reaction,
257-259, 261, 262 trimerization reaction, 263
Diketene, 279 diamine polycondensation, 277 Jeffamine polycondensation, 282,
286, 287
525
Dilithium naphthalene synthesis procedure, 325
a,w-Dilithiumpolyisoprene ethylene oxide reaction, 329
N,N-Dimethylacetamide bromine solution for
halogenation, 298 4-Dimethylaminopyridine
esterification catalyst, 301 N,N-Dimethylaniline, 464
polyanhydride solvent, 193 tri-isobutyl aluminum catalyst
modifier, 472 2,2-Dimethylbutane
dispersion polymerization solvent, 386, 296
2,3-Dimethyl-1,3-butadiene lanthanide stereoregular
polymerization, 483, 484, 495
polymerization mechanism, 502 Dimethyldichlorosilane
carbanionic polymer reaction, 332 3,6-Dimethyl-3,4-dihydro-2H-1,3-
benzoxazine polymerization kinetics, 34, 35
N,N-Dimethyl formamide bromine solution for
halogenation, 298 polyamide solvent, 69
Dimethyl 2,5-furan dicarboxylate catalysts for transesterifica
tions, 53 ethylene glycol melt transester
ification, 52, 53 ethylene glycol polyester, 52 hexamethylene diamine poly
condensation, 55 hexamethylene glycol polyester,
53 terephthalic copolyester, 53 tetramethylene glycol polyester,
53 trimethylene glycol polyester, 53
2,5-Dimethyl-2,4-hexadiene, 502 2,4-Dimethyl-1,3-pentadiene, 502 2,4-Dimethylphenol
benzoxazine reaction, 32 2,6-Dimethylphenol
benzoxazine reaction, 32 biphenol conversion, 119
2,5-Dimethylpiperazine polyamides with thiofuran rings,
55, 56 2,5-Dimethylpiperazine, trans
3,4-furan dicarbonyl chloride polymerization, 56
526
Dimethyl 3,5-pyrazole dicarboxylate ethylene glycol polyester, 52
Dimethylsiloxane cyclic trimer trimethylsiloxylithium
polymerized, 462 Dimethyl sulfoxide
polyanhydride solvent, 193 polymerization solvent, 143 polysulfone synthesis solvent,
115 Dimethyl terephthalate
1,4-butanediol polyester, 53 copolyester synthesis, 53 ethylene glycol polyester, 53
Dimethyl terephthalic acid triethylamine salt, 194
Dimethyl 2,5-thiophene carboxylate ethylene glycol polyester, 52
1, 1 '-(3,4-Dioxo-1,5-hexadienylene) di-2-pyrrolidone
dianiline reaction, 278 a,w-Di(pentoxy) polyether
synthesis procedure, 136 Dipeptides
synthesis, 190 Diphenic acid, 192 a,w-Diphenols
bromobenzyl functionalized, 240 cis-1,4-dichloro-2-butene
reaction, 239 methylene chloride etherification, 243
a,w-Di[2-(p-phenoxy)-2-oxazoline] characterization, 242
N,N'-Diphenylbenzidine 1,2,5-thiadiazole dicarbonyl
chloride copolymerization, 56
1,4-Diphenylbutadiene, 502 Diphenyl disulfide
synthesis, 160, 162, 169, 170, 177
1,1-Diphenylethane lithium metal reaction, 367
Diphenyl ether, 161 sulfur dichloride reaction, 178
Diphenylethylene butyllithium adduct, 325 s-butyllithium reaction, 348,
349, 352 living polymer capping, 461
Diphenylethylene dilithium anionic polymerization
initiator, 32~ Diphenylhexyl lithium
anionic polymerization initiator, 347, 355, 359, 360
Diphenylhexyl lithium (continued) anionic polymerization
initiator, 347, 355, 359, 360
ethyl methacrylate polymerization, 353
synthesis procedure, 348, 349, 352
Diphenylmethane n-butyllithium adduct formation,
367 4,4'-Diphenylmethane-bis
semicarbazide synthesis, 10
4,4'-Diphenylmethane diisocyanate ethyl carbazate reaction, 10
4,4'-(4,4'-Diphenyl methylene)bis-urazole
synthesis, 11 Diphenylmethyllithium
preparation procedure, 367 Diphenylmethyl methacrylate
anionic homopolymerizationmonofunctional initiator, 371
anionic polymerization, 364, 368 diphenylmethyllithium
polymerized, 371 purification, 367 sequential anionic
copolymerization, 368 trityl methacrylate anionic
copolymerization, 373-377 N,N'-Diphenyl-1,4-phenylene diamine
polyamides produces from, 56 Diphenyl sulfide
synthesis, 160, 162, 169-171, 177 4,4'-Diphenyl sulfone
poly(aryl ether sulfone) monomer, 121, 122
Diphenyl trisulfide synthesis, 162, 171
1,2-Dipiperidinoethane anionic polymerization modifier,
334 Dispersing agents
diblock polymers, 382, 383, 387 2,4-Ditertbutylphenol
benzoxazine polymerization initiator, 35-37, 39, 41, 42
benzoxazine reaction, 34-39 3,6,8-trimethyl-3,4-dihydro-2H-
1,3-benzoxazine reaction, 34, 35
2,6-Ditert-butylphenol benzoxazine reaction, 31-33
Ditriethylammonium adipate phenylphosphonic dichloride
reaction product, 194
Ditriethylammonium adipate (continued)
phosphorus acid chloride condensation, 200
Ditriethylammonium terephthalate phenylphosphonic dichloride
reaction product, 194 phosphorus acid chloride conden
sation, 195-197, 199 Diurethanes
diepoxide reactions, 254 Divinylbenzene
anionic prepared polystyrene dispersion crosslinker, 400
living anionic polymer reaction, 332
1,12-Dodecanediol hydroxyalkyl methacrylate
synthesis, 301 Dow process
PPS synthesis, 175
Elastomers rubber grafted cellulose as
reinforcement, 405 polystyrene dispersion polymer
reinforcement, 400, 401 Elastomers, thermoplastic, 2
segmented copolymers, 93 synthesis concept, 480
Emulsifying agent polystyrene macromer - ethylene
oxide copolymer, 463 Enamine carbonyls
electrophilic compound chelation, 275
synthesis methods, 276 tautomeric equilibria, 276 structure, 276
Ene reaction bis-triazolinediones,
1, 2, 18, 20 triazolinediones, 2
Enophiles, 1 Epichlorohydrin
polystyrene anion reaction, 463-465, 467-470, 480
Epoxides anionic polymerization, 321,
322 homopolymerization, 252 lithium bases polymerized, 330 nucleophilic reactions, 217
Epoxy resins, 219, 231 2,2-Bis (4-hydroxyphenyl)
propane containing, 59 cured with isocyanates, 266 curing process, 251 diisocyanate reaction, 259
527
Epoxy resins (continued) isocyanate reaction, 251, 256 MY750 type 258, 271, 272 oxazolidone conversion, 251 properties, 251
Epoxy resins, cured crosslink density, 267 oxazolidone ring containing
254, 266 Ethane sulfonic acid
azlactone-thio reaction catalyst, 223, 224, 227, 228
Etherification phase transfer catalyzed, 134
Ethylazodicarboxylate Diels-alden reaction, 1
Ethyl-3-carbonyl-2-furan carboxylate
conversion to 2,3-furandicarboxylic acid, 63, 76
synthesis procedure, 63, 76 Ethyl carbazate
1,6 - hexane diisocyanate reation, 8
isocyanate reaction, 10 Ethyl chloroformate, 229
N-acryloylmethylalanine reaction, 206
cyclodehydration agent with triethylamine, 223
Ethyl 2-ethyl-2-phenyl-3-aminopropionate
optical resolution D, L mixture, 444
3-Ethyl-5-hydroxy-N-benzyloxypyrrolidine
hydrogenolysis, 420 synthesis procedure, 420
Ethyl imidazole isocyanate trimerization
catalyst, 266-268, 271, 272
Ethylene potassium alcoholate
polymerization, 462 Ethylene azidohydrin
aldehyde reaction, 237 Ethylene-bis (3-mercaptopropionate)
azlactone addition reaction 221, 223
synthesis, 223 1,2-Ethylenediamine, 279
., N,N'- (acetacetyl)-I, 4-piperazine reaction, 280
4,4'-(Ethylenedioxy) dibenzoic acid, 192
Ethylene glycol 2,5-furancarboxylic acid
polyester, 52, 53, 56
528
Ethylene glycol dimethacrylate crosslinking agent, 301
Ethylene oxide living carbonionic polymer
terminator, 329 living polymer macromer
production, 461 phenoxy anion polymerized, 238 polystyrene anion
polymerization, 478 polystyrene macromer
polymerization, 463 purification, 464
2-Ethyl mercaptoethyl methacrylate methyl methacrylate
copolymerization, 514 Ethyl methacrylate
anionic polymerization,352, 358 characterization, 358 living anionic polymerization,
358 Ethyl 2-methyl-2-ethylmalonic acid
bromoacid synthesis, 444 cinchonidine resolution, 444 lactone transformation, 444, 445 quinine resolution, 444
2-Ethyl-4-methylimidazole, 257 oxazolidone formation catalyst
258, 259, 261-265 a-Ethyl-a-methyl-a-propiolactone
optically active monomer resolution, 445
Ethyl 2-oxo-3-cyano-5,5-diethoxypentantoate
synthesis procedure, 63, 75, 76 Ethyl-2-phenyl-2- cyanoacetate
ethyl bromide alkylation, 443 ethyl bromide adduct
hydrogenation, 443 a-Ethyl-a-phenyl-a-propiolactone
optically pure monomer synthesis, 443
3-Ethylproline N-carboxyanhydride, trans
racemic mixture polymerization, 429
3-Ethylproline-N-carboxyanhydride, trans D (+) and L (-)
polymerization with triethylamine, 429
polymer characterization, 430 sodium methoxide polymerization,
429 5-Ethylproline, cis isomer
L-(+)-tartaric acid resolution, 427
5-Ethylproline, cis and trans NMR characterization, 426
3-Ethylpyroline, cis and trans isomers
diastereoisomers separation, 423 diastereoisomers stereochemical
assignments, 423 methyl ester isomers, 422 polymerization, 419 synthesis and separation, 419,
421, 438 5-Ethylproline, trans isomer
L-(+)-tartaric acid resolution, 427
3-Ethylproline ethyl ester, (D) or (L)
optically active hydorchloride salt, 427
3-Ethylproline, ethyl ester, trans isomer
D(-) and L (+)-tartanic acid resolution, 427, 438
3-Ethylproline hydrochloride, cis- and trans
dibenzoyl tartaric acid resolution, 428
synthesis method, 422 3-Ethylproline, trans (D) and (L)
enantiomers optical purity, 428 ring opening polymerization, 428 tris-[3-(heptafluoropropyl-
hydroxy-methylene)-dcampohorato] europhium III resolution, 428
3-Ethylproline, trans D(+) and L(-) --
optical isomers resolution, 438 3-Ethylproline, trans isomer
N-carboxyanhydride polymerization, 429
(-)-dibenzoyl-L-tartaric acid resolution, 427, 438
optical resolution, 425, 438 phosgene conversion to
N-carboxyanhydride, 428 3-Ethylproline, trans D (+) isomer
resolution method, 426 3-Ethylproline, trans L (-) isomer
resolution method, 426 Eugenol
vanillin reaction, 13, 14 Europhium salt, chiral
optically active a-propiolactone resolution, 444, 445, 447, 448
Flory-Huggins theory optically active polymers
application, 455 Formaldehyde
benzoxazine synthesis, 27, 28, 48
Formamidines isocyanate-DMR reaction product,
266 Formic Acid
polyamide solvent, 69 Friedel-Crafts Catalysts
aluminum chloride, 159-161 Friedel Crafts reaction
benzene with sulfur, 176 Fumaric acid, 192 Fur an
aromaticity, 57 reactivity, 57
2,3-Furan dicarbonyl chloride anilino reaction, 78, 85 diamine polymerization reactions,
86-88 diphenol polymerization
reactions, 86, 87 2,4-Furan dicarbonyl chloride
aniline reaction, 78 diamine reactions, 85 diphenol reactions, 84 intercarbonyl distance, 71 phosphorus pentochloride
reaction, 64 polyamide monomer, 69, 71, 85 synthesis procedure, 64, 77
2,5-Furan dicarbonyl chloride 2,2-bis(4-hydroxyphenyl) propane
interfacial copolymerization, 55, 59
decamethylene diamine interfacial polycondensation, 55
diamine reaction, 80, 81 diphenol polyesterification,
79, 80, 83 glycol interfacial polymerization,
54, 59 hexamethylene diamine interfacial
polycondensation, 55 octamethylenediamine interfacial
polycondensation, 55 Furan Dicarboxylic Acids
polyamide monomers, 51, 52 polyester monomers, 51, 52
2,3-Furan dicarboxylic acid acid chloride synthesis, 64, 76,
78 crystallographic dimensions, 58,
71 ester derivative, 51 intercarbonyl distance, 71 phosphorus pentachloride
reaction, 60, 64, 78 synthesis procedure, 62, 63, 76
2,4-Furan dicarboxylic acid acid chloride synthesis, 60, 64,
77
529
2,4-Furan dicarboxylic acid (continued)
crystallographic dimensions, 58, 71
ester derivatives, 51 n,w-glycol polyesterification,
53 production reactions, 60 synthesis procedure, 61, 74
2,5-Furan dicarboxylic acid acid chloride synthesis, 60, 64,
78 crystallographic dimensions, 58
71 dehydromucic acid, 60 ester derivatives, 51 ethylene glycol polyester, 52 hexamethylene-diammonium salt
polycondensation, 55 hexamethylene glycol polyesters,
53 intercarbonyl distance, 71 phosphorus pentachloride
reaction, 64 synthesis procedure, 72 terephthalic acid-ethylene
glycol copolyester, 54 tetromethylene glycol
polyesters, 53 trimethylene glycol polyesters,
53 3,4-Furan dicarboxylic acid
acid chloride synthesis, 60, 64 77
crystallographic dimensions, 58, 71
ester derivative, 51 intercarbonyl distance, 71 phosphorous pentachloride
reaction, 64 physical properties, 62
2,5-Furan dicarbonyl chloride polyamide formation, 80,81 synthesis procedure, 76
3,4-Furandicarbonyl chloride diamine reactions, 82, 83 diphenol polyesterification,
81,82 polyamides produced from, 56, 71 synthesis procedure, 64, 77
Glass transition temperatures poly (alkyl methacrylates), 359,
360, 363, 506-509, 512, 513, 516
polyethers, 135, 138, 144-147 polyoxazolidones, 270, 271 poly (1,3-pentadiene), 485, 490,
491, 495, 500 poly (B-propiolactones), 453
530
Glass transition temperatures (continued)
polystyrene living polymer, 388, 389
segmented polysulfone,polyarylates, 109, 110, 118
Glycidyl methacrylate oligomers prepared from, 203
Grafting antiplatelet agents on polymers,
291-293 manganese de carbonyl reaction
mechanism, 300 photochemical initiated, 299,
300 thermal initiated, 299
4-Halophenol polymerization with metal salts,
178 4-Halothiophenol
alkali metal salt polymerized, 175
Heparin grafted on poly (ether
urethanes), 293 Heptane
dispersion polymerization solvent, 386
HEXA polyoxazolidone synthesis
catalyst, 267-269, 271, 272 2,4-Hexadiene, trans, trans
cobalt catalyst polymerized, 494 lanthanide stereospecific
polymerization, 483, 491, 503
polymerization mechanism, 502 sterical hinderance, 503 titanium catalyst polymerized,
494 Hexafluoroisoprapanol
isotatic poly(B-propiolactones) solvent, 451
polyamide solvent, 70 Hexamethylphosphoramide
polyanhydride solvent, 193 Hexamethylene diamine
polyamide monomer, 57 purification, 72
Hexamethylene glycol 2,5-furandicarboxylic acid
polyester, 53 Hexamethylene tetramine
oxazolidone formation catalyst, 259
Hexane dispersion polymerization
solvent, 386, 396
1,6-Hexane-bis-semicarbazide, 8 1,6-Hexane-bis-urazole
synthesis, 8, 9 1,6-Hexane diisocyanate, 8 Hormones
polypeptide based, 419 Hydrogen sulfide
PPS synthesis biproduct, 160-162, 164
Hydroquinone polyether monomer, 94, 96-99,
108 segmeted copolymer momomer, 109
Hydroxy alkyl methacrylate oligomers produced from, 204
p-Hydroxybenzaldehyde ethylene azidohydrin reaction,
1 237 1 p, P -Hydroxy-2, 2 -dimethyl
benzalazine liquid crystalline polymer
segment, 133 N-(2-hydroxyethyl) amides
oxazoline hydrolysis product, 240 N-(2-Hydroxyethyl)-p-hydroxy
benzamide p-hydroxyphenyl-2-oxazoline
hydrolysis product, 238, 244
thionyl chloride cyclization, 238 2-Hydroxylethyl methacrylate
esterification with hydantoin acid derivative, 301
esterification reaction, 307 grafting on Pellethane, 315 methacryloyl polystyrene
macromer copolymerization, 463
5-Hydroxymethyl-2-furoic acid polyesters, 54
Hydroxynapthones tautomeric forms, 276
m-Hydroxyphenyl-2-oxazoline chlorohydrate product, 237, 238 disalt synthesis, 248, 249 hydrolysis, 238 synthesis procedure, 237, 238
p-Hydroxyphenyl-2-oxazoline chlorohydrate product, 237, 238 chloromethylstyrene
etherification, 244 a,w-di(electrophilic) polyether
sulfone reaction, 240 etherification with methylene
chloride, 243 hydrolysis, 238 lithia ted with butyllithium, 238 methyl trifluoromethane
sulfonate reaction, 248 phenoxy anion product, 238
p-Hydroxyphenyl-2-oxazoline (continued)
polyformal end capping monomer, 243, 244
synthesis procedure, 237, 248 p-Hydroxyphenyl-2-oxazoline,
di-salts ring opening polymerization, 249 synthesis procedure, 248
p-Hydroxyphenyl-2-oxazoline, lithium salt
epoxide polymerization initiaton, 238
p-Hydroxyphenyl-2-oxazoline, vinyl benzyl ethers
NMR characterization, 244, 245 polymer characterization, 244 radical polymerization, 244
3-Hydroxy proline, 424 B-Hydroxypropionic acid
ring closure to lactone, 443 12-Hydroxysteric acid, 307 Hydroquinone
polyester monomer, 54
Imines structure, 276
Iminoamines, 1,3 crystallographic data, 276 IR characterization, 276
Imino-l,3-dioxolane, N-substituted isomerization to oxazolidone,
253 2-Imino-l,3-dioxolane, phenyl
substituted isomerization to oxazolidone,
253 Initiators, electrophilic
2-oxazoline polymerization, 235 Initiators, radical polymerization
kinetics influence, 508 Iodine-thiosulfate
titration of polystryrene peroxide, 400
Ionophores polypeptide based, 419
Isobutylene cationic polymerization, 462 inifer polymerization method,
462 Isoeugenol
bis-triazolinedione reaction, 14
methyl isocyanate reaction, 5, 14
Isoprene anionic polymerization, 347 s-butyllithium polymerization,
333, 334
531
butadiene stereospecific copolymerization, 483
dilithium initiator polymerization, 347
polymerization mechanism, 502 Isothianthrene
synthesis, 162 Isocyanates, 219, 231
alcohol reaction, 266 epoxide reaction to oxazolidone,
251, 259 formation reaction, 261 nucleophilic reaction, 217 trimerization, 254, 259, 266
Isocyanurates isocyanate trimerization, 254,
259, 261, 262 kinetics of formation, 264
Isophthalic acid crystallographic dimensions, 58 a,w-glycol polyesterification,
53, 56 polyamide monomers, 57 polyester monomer, 53, 56, 58-60
Isophthaloyl chloride 1 ,2-bis-(4-carboxyphenoxy) ethane
polycondensation, 188 copolyamides, 60 diamine polycondenation, 60 polyarylate synthesis, 94-96 purification, 97 4,4-sulponyldiphenol polyester,
59, 60 2-Isopropenyl-4, 4-dimethylazalac-
tone Jeffamine reaction, 212 ORTEP plots, 211 synthesis procedure,206
2-Isopropenyl-2-oxazoline free radical polymerization, 237
ISOX isocyanurate-oxazolidone
containing polymers, 256 oxazolidone resins, 272
Jeffamines, 279, 282, 286 alkenyl azlactone reaction, 211,
212, 215 N,N'-bis(acetacetyl)-1,4-piper
azine condensation, 280 diketene reaction, 282 polyoxyalkylene oligomers, 206,
207, 211 urea reaction, 207, 208
Kelley-Bueche equation methyl methacrylate
polymerization application, 512
532
Kemamine 36-carbon diamine, 208
Ketenes carbonyl compound reaction,
443, 445, 457 chloral conversion to lactone,
446 enamine derivative, 275
Lactones anionic polymerization, 321, 322,
441, 447 cationic polymerization, 441, 447 coordination polymerization, 441,
447 ring opening polymerization, 441
8-Lactones diastereoisomer complex
resolution, 446 optically active chiral base
synthesis, 446 racemic mixtures, 446
Lactones, bicyclic tetrahydrofuran ring containing,
54 Lanthanides
coordination capabilities, 483 rare earth metal catalysts, 483,
502 Lanthanides, catalysts
classification types, 484 diene polymerization catalysts,
483 - 503 organic chemical complex
catalysts, 483 Lauroyl peroxide
polystyrene macromer polymerization, 463
Lead oxide esterification catalyst, 53
Lekutherm N,N-diglycidylanilin, 258 epoxide resin, 265
Lewis acid, 191 tetrahydrofuran anionic
polymerization modifier, 396
Lewis bases, 191, 192, 194, 195 anionic polymerization modifier,
333-335 radical anion stabilizers, 323
Linoleic acid clay catalyzed dimerization, 208 Diels-Alder reaction, 208
Lithium alkoxides epoxide polymerization, 330
Lithium but oxide catalyst for oxazolidone
formation, 252
Lithium but oxide (continued) isocyanate-epoxide reaction
catalyst, 264 polyoxazolidone synthesis
catalyst, 267 Lithium chloride
oxazolidone formation catalyst, 265
Lithium naphthalene styrene reaction, 324
Lithium triflate oxazolinium di-salt
polymerization biproduct, 249
2,6-Lutidine, 428
Macallum Polymerization dichlorobenzene-sulfur reaction,
175, 176 Macromers
copolymerization to graft copolymers, 463
epoxy ether terminated polystyrenes, 463-469
graft copolymerization efficiency, 471, 472, 474-476, 478
graft copolymer use, 461 homopolymerization, 463 methacryloyl terminated
polytetrahydrofurans, 463 poly (dimethyl siloxane) based,
462 polyisobutylene based, 462 polymerizable macromolecular
monomer, 461 polyoxyethylene type, 462 poly (methyl methacrylate) based,
462 polystyrene based, 462 synthetic techniques, 134 p-vinylbenzyl capped
polystyrene, 461 Macromer, epoxy ether terminated
ethylene oxide copolymerization, 480
synthesis procedures, 461 Macromers, methacryloyl terminated
polyoxyethylene based, 462 Macromers, polystyrene
epoxy ether terminated, 461 Macromers, production
anionic polymerization method, 462
cationic polymerization method, 462
radical polymerization method, 462
Macromonomers copolymerization, 339 grafting onto polymers, 336 methacrylate terminated
oligomers, 339, 340 oligomers with polymerizable
end-group, 339 polymerizable oligomers, 339 polymerizations, 335 reactivity ratios, 339, 340 synthesis procedures, 339-341
Macromonomers, poly (4-bromosytrene) vinyl styrene terminated, 341
Mac romonomers, poly (ethylene oxide) methacrylate terminated, 340 a-methylstyryl terminated, 340 oxazoline terminated, 238, 340,
341 p-vinylstyryl terminated, 341
Macromonomers, poly (methyl methacrylate)
a-methylstyryl terminated, 341 Macromonomer, oxazoline terminated
cationic ring opening polymerization, 238, 239
Macromonomers, polystyrene anionic living polymerization
synthesis, 340 p-vinylstyryl terminated
Macromonomers, poly(vinyl pyridine) methacrylate terminated, 341 p-a-methylstyryl terminated, 341
MacTomonomers, siloxane methacrylate terminated, 341 p-vinylstyryl terminated, 341
Maleic anhydride Diels-Alder reaction, 1
Malic acid conc. sulfuric acid reaction, 60 fuming sulfuric acid reaction, 60
Manganese decacarbonyl grafting catalyst, 299, 300 purification, 308
Mayo-Lewis equation applied to macromonomers, 339
Mercaptans alkenyl azlactone ractions, 224 vinyl azlactone reaction, 227-229
3-Mercaptopropionic acid ethylene glycol esterification,
223 Mesogens
conjugated electron donor type, 134
Methacrylamide functionalized oligomers, 205,
210, 211 Methacrylates, alkyl
alkali metal alkoxides polymenization, 327
533
Methacrylates, alkyl (continued) anionic polymerization, 321, 322,
347, 348 carbonyl side reactions-anionic
polyerization, 347 dibutyl magnesium polymerization,
348 diphenylethylene anionic
initiators, 351, 352 group transfer polymerization,
327 high conversion polymerization,
50S, 512-514 molar volumes, 513 photoinitiation polymerization,
354 polymerization kinetics, 50S,
506, 508-513 polymerization kinetics, model
509, 510, 516 purification procedures, 358,
361, 367 radical polymerization, 50S, 512 sequential anionic
polymerization, 366 trialkyl aluminum purification,
348, 350, 354 Methacrylonitrile
anionic polymerization, 322 Methacryloyl hexafluorantimonate
tetrahydrofuran polymerization to macromer, 462
N-Methacryloylmethylalanine N, N-dicyclohexyl carbodiimide
reaction, 206 p-Methoxyphenol
methacrylate stablizier, 305 2-Methoxy-4-propenylphenyl
methyl-carbamate bis-triazolinedione raction, 19 1,6-Bis-(3,5-dioxo-l,2,4,
triazoline-4-yl) hexane reation, 12
copolymerization reaction, 13 Diels-Alder derivative, IS
2-Methoxy-4-propenylphenol methyl isocyanate reaction,S, 14 methyl triazolinedione reaction,
14 4-methyl-l,2,4-triazoline-3,5-
dione reaction, 6 synthesis, 5
Methyl bromocoumalate synthesis procedure, 61, 74
Methyl 3-bromo-2-oxopyran-5 carboxylate
synthesis procedure, 61, 73, 74 Methyl coumalate
bromonation reaction, 61 production procedure, 60, 61, 73
534
Methyl coumalate pyridinium bromide perbromide
reaction, 61 Methylene chloride
p-Hydroxyphenyl-2-oxazoline reaction, 243
Methylenedianiline, 279 diethyl ethoxymethylene malonate
polycondensation, 277 a-Methyl-a-ethyl-S-propiolactone
optically active monomer synthesis, 444
a-Methyl-a-ethyl-S-propiothiolactone optically active monomer
proparation, 445 a-Methyl-a-m-propyl-S-propiolactone
chiraal initiator polymerization, 443
Methyl m-hydroxybenzoate ethanolamine reaction, 238
Methyl isocyanate isoeugenol reaction, 5
Methyl 3-mercaptopropionate vinyl azlactone reaction, 227, 228
Methyl methacrylate acetone-cyanohydrin process, 355 alcohol doped purification, 352 anionic bifunctional initiator
polymerized, 373 anionic polymerization, 323,
325-327, 347, 352,360-362, 372, 373, 462
anionic tactic polymerization, 365
butyl lithium polymerized, 326 celing temperature, 507 chain transfer polymerization,
514 14 C labeled, 308 diffusion hindered
polymerization 508-510 diphenyl hexyl lithium
polymerization, 355 diphenylmethyllithium
polymerized, 371 2-ethyl mercaptoethyl
methacrylate copolymerization, 514
grafting on Pellethane, 315 high conversion polymerization
kinetics, 506-510, 516 initiator influence on
polymerization, 508, 511 isothermal polymerization, 508 methoxide anion polymerization,
327, 328 polymerization kinetics, 508-516 polymerization solvent effects,
360
Methyl methacrylate (continued) polymerization temperature
influence 507 purification, 367 radical polymerized, 507-510 termination rate constant, 509 transesterification, 348 trialkyl aluminum alcohol
removal, 355 trialkyl aluminum purification,
348, 355, 356 2-Methyl-2-oxazoline
hydroxyphenyl-2-oxazolinium salt polymerized, 248
Methyl 2-oxopyran-5-carboxylate production procedure, 60, 73
4-Methyl-1,3-pentadienes, 502 2-Methyl-1,3-pentadiene, trans
Lanthanide sterospecific polymerization, 484, 500
polymerization mechanism, 502 3-Methylproline, 424
3-Methyl-L-proline, cis isomer isolation from bottromycin
antibiotic peptide, 420 synthesis routes, 420
5-Methylproline, cis and trans mixture
L-(+)-tartaric acid resolution, 427
3-Methyl-L-proline, trans isomer isolation from mycotoxin,
roseotoxin B, 420 synthesis route, 420
Methane sulfonic acid polyamide solvent, 69
Methyl triazolinedione synthesis, 14
4-Methyl-1,2,4-triazoline-3,5-dione allyltrimethylsilane reaction, 2 Diels-Alder reaction, 1, 15 2-methoxy-4-propenylphenylmethyl
carbamate reaction, 6 N-Methylpyrrolidone, 279
polyamide solvent, 69 polyether synthesis solvent, 143 PPS production solvent, 173 polysulfone synthesis solvent,
115, 116 Methyl trifluoromethane sulfonate
oxazoline triflate formation reaction, 248
Michael addition reaction aklenyl azlactones, 210, 215, 217 Amines, 215 2-pentenal-substituted diethyl
malonate, 420, 438 thio-acrylates, 222-224 thio-acrylamides, 222, 223
Molybdenum hexacarbonyl grafting catalyst, 229
Monomers dinelectrophilic, 138 dinucleophilic, 138 radio-labelled, 308
Monomers, mesogenic copolymerization, 134
Monomers, optically active enantiomeric excess measurement,
446-448 Monomers, polar
polymerization, 325, 326, 342, 347 Monomers, vinyl hydrophilic
biomer effects, 309 Monomers, vinyl
cellulose grafting methods, 407, 408
grafting on poly (ether-urethanes), 299
Mucic acid fuming hydrobromic acid realtion,
60, 72 MY 750
epoxide resin, 258, 259 Myrcene, 502
Nitrobenzene, 136-138, 149 Nitroterephthatic acid, 192
Oligomers benzene-sulfur containing,
169,171, 175, 177 crosslinking reactions, 205 a,w-dielectrophilic chain ends,
139 functionalized for crosslinking,
203 hydrogen bonding chain ends, 138 macromonomers with reactive
end-groups, 339 methacnylate functionalized, 203,
204 reactive macromonomers, 339 synthesis procedures, 339, 340 unsaturated, 204
Oligomers, acrylamide terminated synthesis from azlactones, 213,
217, 219, 232 characterization, 209-211, 213,
215, 216 Oligomers, amine terminated, 206,
207 alkenyl azlactone reactions,
217, 221 azalactone reaction, 203, 205,
211, 217, 219 urea reaction, 207, 208
Oligomers, azlactone terminated synthesis, 225, 232
535
Oligomers, bromobenzyl substituted etherification with phenolic
oxazolines, 243 Oligomers, a,w-di (bromobenzyl)
substituted characterization, 241
Oligomers,a,w-di(electrophilic) substituted
macromonomer starting materials, 239
Oligomers, a,w-diphenol substituted characterization, 241
Oligomers, hydroxy terminated alkenyl azlactone reaction, 221
Oligomers, liquid azlactone functionalized, 232
Oligomers, oxazoline terminated characterization, 242, 243 poly(phenylene sulfide) based,
237 synthesis, 241-243 thermally reactive, 248
Oligomers, polyether hydroxyphenyl terminated, 145
Oligomers, polyether sulfone oxazoline terminated, 240
Oligomers, telechelic azlactone functionalized, 232
Organometallic dihalides dicarboxylic acid condensation,
195 dicarboxylic acid polymerization,
187, 189, 195 Organophosphorus dichlorides
p-aminobenzoic acid condensation, 190
amino acid reactions, 190 dicarboxylic acid
polycondensation, 189 polypeptide reaction, 191
Organophosphorus (v) polyesters, 192 Oxazolidone
catalyst for formation, 261, 262 epoxide-isocyanate reaction
product, 263 formation kinetic parameters, 264 formation reaction
characterization, 262,-263 formation study by DSC, 267, 268 heat of formation, 263 isocyanate-epoxide reaction
mechanism, 253 mechanism of formation, 252, 253 ring isomers, 254
2-0xazolidones N-subtituted iminc-2,3-dixolane
isomerization product, 253 Oxazolidone resins
isocyanurate containing, 266 thermal properties, 266
536
2-0xazoline-5-ones ring opening reactions, 219 Nucleophilic reactions, 219
2-0xazolines boron trifluoride polymerized,
238, 239 cationic polymerization, 235,
236, 238, 248 carboxylic acid ring openings
reaction, 235 hydrolysis to amides, 240, 242 phenol ring opening reactions,
235, 236 thiophenol ring opening reaction,
235 2-0xazolines, m-hydroxyphenyl
substituted polymers produced from 235, 237
2-0xazolines, p-hydroxyphenyl substituted
polymers produced from 235, 237 2-0xazolines, phenoxy substituted
NMR characterization, 242 2-0xazolines, vinyl substituted
radical polymerization, 237 Oxazolinium triflates
oxazoline polymerization agents, 248
Oxiranes chiral initiator polymerization,
442 2-0xopyran-5-carboxylic acid
coumalic acid, 60 production method, 60
2-0xopyran-5-carboxylic acid synthesis procedures, 72, 73
Oxycellulose polystyryldicarbanion grafting,
410, 411 synthesis procedures, 409
4,4'-(2,2'-Oxydiethoxy)-dibenzoic acid, 192
Palmitic acid, 307 hydroxyethyl methacrylate
derivative, 307 t.ritiated, 307
Pelle thane BEMA palmitate ester
photografting, 314 poly (ether-urethane)
bromination, homogeneous, 298, 310, 311
vinyl monomer grafting, 315 N-vinylpyrrolidone-methacrylate
ester grafted, 316 1,3-Pentadiene, cis, 485, 503 1,3-Pentadiene, trans isomer
lanthanide stereospecific polymerization, 484, 485
1,3-Pentadiene, trans isomer (continued)
polymerization mechanism, 484, 502 Pentane
dispersion polymerization solvent, 386, 396
1,5-Pentanediol hydroxy alkyl methacrylate
synthesis, 301 2-Pentenal
diethyl N-benzyloxycarbonylaminomalonate adduct, 420, 438
synthesis method 420, 422 Peroxides, polymeric
synthesis procedure, 331 Phenol
benzoxazine condensation mechanism, 32-35
benzoxazine reaction rate constant, 33
benzoxazine synthesis, 27, 28, 48
potassium cargonate neutralization, 116
Phenol-formaldehyde resins phenolic monomers, 59
Phenolic resins synthesis route, 27, 28, 48
N-(4-Phenylbenzyloxycarbonyl-cis-6-methyl pipecolic acid
quinine resolution, 427 2,2'-p-Phenylene-bis-(4-ethoxy
methylene-5-oxazolone) dianiline reaction, 278
p-Phenylenediamine N,N'-bis(acetaacetyl)-1,4-piper
azine condensation, 282 a-Phenylethyl potassium
ethylene oxide polymerization catalyst, 478
a-Phenyl-a-ethyl-S-propiolactone enantiomeric resolution, 444 chiral europium salt resolution,
444, 445 Phenyl glycidyl ether, 257
diisocyanate reaction, 259 4,4'diisocyanatodiphenyl methane
reaction, 258, 259, 266-268 diisocyanate reaction
characterization, 259-262 Phenylisocyanate
trimerization, 263 Phenylphosphonic dichloride, 192
polyamide prepared from, 194 Phenylphosphonothioic dichloride,
192 Phenylphosphoro dichloridate, 192 Phenylthiothianthrene
synthesis, 162, 169
Phenyltriazolinedione synthesis, 74
4-Phenyl-1,2,4-triazoline-3,5-dione, 1
Diels-Alder adduct, 15 2-methoxy-4-propenylphenylmethyl
carbamate reaction, 7 olefin reaction, 7
Phosphorus acid chloride diamine polymerization, 189 diphenol polymerization, 189 hydrolysis, 189, 195
Phosphorus anhydrides synthesis, 190
Phosphorus pentachloride, 76 Phosphotungstic acid
sulfided hydrogenation catalyst, 161
Phthalic acid crystallographic dimensions, 58 polyamide monomers, 57 polyester monomer, 60
PIO oxazolidone containing resins,
256 Piperazine, 279
diketene reaction, 280 Piperlene, trans
lanthanide stereospecific polymerization, 483
Plastics, engineering poly(phenylene sulfide), 173
Polyacetylene chemical doping, 182
Poly(N-acetyl-ethyleneimine)s phenolic hydroxyl terminated, 248 telechelic materials, 248
Polyacrylonitrile, 414 Polyacrylonitrile, carbanion
grafting to cellulose acetate, 413
Poly(acrylonitrile), "living" polymer
synthesis procedure, 410 Poly(N-acylethyleneimine)s
2-oxazoline derived, 235 reactions on polymer, 235 synthesis procedure, 240
Poly-alcanoates liquid crystalline polymers, 133
Poly(alkyl methacrylate) anionic copolymeriza'tion, 348 anionic polymerization, 348, 349 anionic polymerized molecular
weights, 366 bulk polymer production, 505, 516 casting processes, 505 characterization, 350, 352, 353 controlled anionic
polymerization, 358
537
Poly(alkyl methacrylate) (continued)
controlled molecular weight, 361 isotactic polymer synthesis, 348 physical properties, 363 purification method, 350, 351 synthesis conditions, 347, 351 synthesis of controlled
molecular weight, 348 synthesis using pure monomer, 361
Poly(Alkyl methacrylate), tactic copolymer, 347 physical association, 363, 365 synthesis, 347, 363-366 stereocomplex network
structures, 365 Poly(alkyl methacrylate), living
polymer termination with acetic
acid/methanol, 350 Poly(amide-enamines), 275
biodegradable polymers, 275, 277 N,N'-bis(acetacetyl)-1,4-piper
azine based, 279 piperazine containing, 288 synthesis, 277
Poly(amide enamine ether) adhesive potential, 286 characterization, 286, 287 metal chelating ability, 286-289 synthesis method, 280, 282
Poly(amide-ester)s synthesis procedure, 236
Poly(amide-ether) lithium phenoxide-oxazolinium
salt terminated, 249 Polyamides
acidic proton reaction, 337 furan dicarboxylic acid
containing, 51, 52, 64-69 furan ring containing, 55, 59 halogenation reaction, 295 head-to-tail type, 220 heteroaromatic ring containing,
57, 58, 60 heterogeneous halogenation, 298 metalated with sodium, 337 mixed amide type, 59, 60 phenolic hydroxyl terminated, 249 phosphorus containing, 192 redox oxidation initiated
grafting, 292, 293 tail-to-tail, 220 vinyl monomer grafting, 295
Polyamides, furan containing intrinsic viscosities, 70 properties, 56, 57, 68, 69, 71 solvents, 69 synthesis procedure, 80-82, 84,
85 thermal properties, 70, 71
538
Polyamides, metalated ethylene oxide grafting, 337 ethylene sulfide grafting, 337
Polyamides, phosphorus containing synthesis procedure, 192
Polyamines, antimony containing synthesis procedure, 189
Polyanhydrides phosphorus containing, 187, 189,
190, 194, 195 synthesis procedures, 187-190,
194, 195 Polyanhydrides, phosphorus
containing amide modified, 190 characterization, 193, 194 synthesis conditions, 193
Polyarylesters bisphenol-A based, 94, 95
Poly(aryl ethers) characterization, 118 cyano group terminated, 118, 119 engineering materials, 113 ketone modified, 118, 119 physical and chemical properties,
113, 118 synthesis procedures, 118
Poly(arylene ether ketones) synthesis procedures, 113
Poly(aryl ethers), methyl substituted
crosslinking reactions, 119, 122 Poly(aryl ether sulfones)
bromination reaction, 118 characterization, 102-104,
106-109 hydroxyl terminated oligomers,
114 structures, 113, 114, 117-119,
122 synthesis procedures, 96, 97,
100, 104, 107, 113-117, 122 thermal properties, 118
Poly(arylene ether sulfone)-poly-(arylene terephthalate)
characteristics, 95, 96, 106-111 random block type, 94 segmented copolymer synthesis,
93, 95, 97, 107-111 Poly(L-azetidine-2-carboxylic acid)
poly(L-proline) comparison, 438 Polyazomethines
liquid crystalline polymers, 133 Poly (N-benzoylethyleneimine)
poly(ethylene oxide) grafted, 238, 239
Poly[I,4-bis(3-decanamino-2-butenoyl)]piperazine
synthesis method, 280, 282
Poly[I,4-bis(3-ethylenamino-2-butenoyl)]piperazine
synthesis method, 280 Poly[I,4-bis(3-p-phenylenediamino-
2-butenoyl)]piperazine synthesis method, 282
Poly[I,4-bis(3-m-xylylamino-2-butenoyl)]piperazine
characterization, 284-286 synthesis method, 282
Polybutadiene alkyl dilithium initiated, 323 chloromethylsilane grafting, 338 cis-l,4-microstructure
modification, 333, 334 dilithio derivative, 323 high cis content, 483 metalated with alkyllithium-
diamine complexes, 336 polymer microstructure, 502 synthesis procedure, 334
Polybutadiene, chloromethylsilane grafted
poly (a-methylstyryl) lithium coupling, 338
poly(styryl)lithium coupling, 338 Polybutadiene, living polymer
macromer formation, 461 Poly (butadienyl) lithium
anionic polymerization initiator, 334
Poly(butadiene-co-ethylene oxide) water absorbing property, 479
Poly (butadiene-co-isoprene) high cis content, 483
Poly (butadiene-b-isoprenebutadiene)
selective hydrogenation, 335 Poly (butadiene-a-polystyrene)
synthesis procedure, 338 Poly{m-butyl methacrylate)
purification, 351 Poly(s-butyl methacrylate)
characterization, 352 Poly(t-butyl methacrylate)
purification, 351 Poly (t-butylstyrene-b-styrene)
dispersion agent power, 388, 389 polymeric dispersion agent, 382,
383 polystyrene dispersion agent,
387-389 Poly(t-butyl thiirane)
chiral stereocomplex blends, 457 Poly(a-butyrolactams)
physical properties, 453 Polycarbonates,
monomers, 59
Poly(cellulose acetate-a-polyacrylonitrile)
characterization, 414, 415 Poly (cellulose-a-polyacrylonitrile)
synthesis procedure, 410, 413, 414
Poly(cellulose acetate-a-polystyrene)
characterization, 415 synthesis procedure, 413-415
Poly(cis-5-ethylproline) conformational energy, 420 conformational forms, 420
Poly (cis-5-ethyl-D-proline) conformational forms, 420
Poly (3 ,4-dehydro-L-proline) helices stability, 438
Polydienes bis-triazolinedione
crosslinking, 3 hydrogenated products, 334 living anionic polymerization
method, 342 microstructure, 323, 333, 334 synthesis, 2, 3
Polydienes, branched carbanionic end-linking
reactions, 332 Poly(2,3-dimethyl-l,3-butadiene)
emulsion produced polymer, 495 IR characterization, 498 NMR characterization, 497, 499 polymer microstructure, 502 polymer properties, 495, 499, 500 thermal properties, 496 x-ray diffraction, 498, 499
Poly(2,6-dimethyl-l,4-Phenylene oxide)
bromination reaction, 244 bromomethyl group substituted,
246 p-hydroxyphenyl-2-oxazoline
reaction, 246 oxazoline substituted, 246
Poly(dimethyl siloxane) macromer synthesis, 462
Poly(diphenylmethyl methacrylate) hydrolysis with esterification,
365, 366 syndiotactic polymer synthesis,
364 Poly(diphenylmethyl methacrylate
co-trityl methacrylate) ABA stereoblock synthesis, 379
Poly(diphenylmethyl methacrylate), tactic
conversion to poly(methyl methacrylate), 371
539
Poly (enamines) liquid crystalline polymers,
133, 134 thermooxidative stability, 134
Poly(enamine esters) synthesis procedure, 276
Poly(enamine ketones) synthesis, 277, 278
Poly(ester-amides) synthesis procedure, 52
Polyesters aromatic heterocycle containing,
52, 59 aromatic phenolic monomers, 59,
60 characterization, 141, 142 crystalline structures, 56 4,4'-dihydroxybiphenyl
containing, 151 furan dicarboxylic acid
containing, 51, 52, 64, 68 heteroaromatic ring containing,
57-60 hydrolytic stability, 134 interfacial polymerization
synthesis, 188-192 isotropizaton temperature, 134 liquid crystalline type, 140 mesogenic biphenol containing,
141 metal containing, 195 mixed aromatic ring type, 60 polydimethylsiloxane modified,
148 thermotropic type, 149, 150 properties of heteroaromatic
containing, 59 reduction, 54 structure-aromatic type, 56 thermal transitions, 151
Polyesters, furan containing intrinsic viscosities, 70 properties, 69, 71 solubility characteristics, 69,
70 synthesis procedure, 79-83 thermal properties, 70, 71
Polyesters, hydroxy terminated bislactone chain extension, 221
Polyesters, liquid crystalline carboxylic acid terminated, 145 characterization, 134 thermal properties, 154
Polyetherification 4,4'-dihydroxybiphenyl, 154 kinetics, 143 phase transfer catalyzed, 134,
136, 138, 139 reaction mechanism, 144
540
Polyethers allyl ether side chains, 141, 143 bromoalkoxy terminated, 145 bromopentane, chain ends, 143 carboxylic acid terminated, 145,
148 characterization, 141, 142,
144-149 crystalline, 149 4,4'-dihydroxybiphenyl
containing, 151, 152 4,4'-dihydroxy-a-methylstilbene
containing, 138-140 diketene-Jeffamine based, 287,
288 glass transition temperature,
138, 139 hydroxyphenyl terminated, 144-146 liquid crystalline type, 140 mesogenic biphenol containing,
141 mesomorphic behavior, 144 phase transfer catalyzed, 143 phenol terminated, 136 physical properties, 134 synthesis procedure, 136, 138,
144 thermal transitions, 151 thermotropic type, 133
Polyethers, liquid crystalline, 134 characterization, 134 thermal properties, 154
Poly(ether-urethanes) acrylamide grafted, 293 antiplatelet action, 309 antiplatelet agent grafted, 291,
295, 296 aprotic base treated, 293, 294 biomer evaluation, 309 brominated
hydantoin monomers grafting, 312
hydrophilic monomers grafting, 312
photografting vinyl monomers, 313
bromination reaction, 298 chemical modification, 291-293 free radical grafting, 294 functionalization reactions,
293, 294 grafted
arterial prosthesis evaluation, 309
bioactivities, 301 grafting reactions, 292, 295,
298-300, 308, 312 swelling behavior, 309
halogenated characterization, 298
Poly (ether-urethanes) (continued) molybdenum carbonyl reaction,
299 potassium iodide treated, 298 production procedures, 310, 311
halogenation reaction, 295, 298, 300, 308, 310-312
heparin grafted, 293 hydantoin methacrylate grafted,
299 irradiation with monomer, 292 isocyana~e treated, 293 long chain alkyl halide grafted,
293, 294 methacrylates grafting, 297 photografting method, 308 physical properties, 310 potassium hypobromite treatment,
298 properties, 291 prosthesis uses, 291 redox reactions, 294 mechanism of grafting, 294, 295 segmented type, 291 sodium hypochlorite treatment,
298 tritiated palmitic ester
grafted, 307 vinyl monomer grafted, 294, 295
Poly(ether sulfones), aromatic a,w-di(bromobenzyl) substituted,
239 a,w-di(chloroallyl) substituted,
239 oxazoline terminated, 239 synthesis procedure, 239
Poly(ethyl methacrylate) characterization 353, 358 living anionic polymer, 358 purification, 351
Polyethylene hydrogenated polybutadiene, 335
Polyethylene glycol bis(mercaptoacetate) derivative,
225 bis(mercaptopropionate) deriva
tive, 225 thio derivatives, 228, 229
Poly(ethylene oxide) oxazoline terminated, 238, 239
Poly(ethylene oxide-~-polystyrene) polymer characterization, 476 polymer properties, 478 synthesis procedure, 465-475 water absorbency, 478
Poly(ethylene-co-propylene) synthesis procedure, 335
Poly(ethylene terephthalate) crystallinity, 179 properties, 54
Polyformals aromatic containing, 139 characterization, 140 4,4'-dihydroxy-a-methylstilbene
containing, 136, 140 synthesis, 140
Polyformals, aromatic p-hydroxyphenyl-2-oxazoline end
capping, 243 Polyformals, oxazoline terminated
synthesis procedure, 243 Poly(2,3-furandiylcarbonylimino-
1,4-cyclohexylenedimethyl methylene-l,4-cyclohexyleneimino carbonyl)
synthesis procedure, 87 Poly(2,3-furandiylcarbonylimino-
1,4-cyclohexylenemethylene-1,4-cyclohexyleneiminocarbonyl)
synthesis procedure, 87 Poly(2,3-furandiylcarbonyloxy-l,4-
phenylenedimethylmethylene-1,4-phenyleneoxycarbonyl)
synthesis procedure, 85 Poly(2,3-furandiylcarbonyloxy-l,4-
phenylenedioxothio-l,4-phenyleneoxycarbonyl)
synthesis procedure, 86 Poly(2,3-furandiylcarbonyloxy-l,4-
phenylenethio-l,4-phenyleneoxycarbonyl)
synthesis procedure, 87 Poly (2, 4-furandiylcarbonylimino-
1,4-cyclohexylene-dimethYlene-l,4-cyclohexyleneiminocarbonyl)
structure, 67 synthesis and properties, 69
Poly (2, 4-furandiylcarbonylimino-1,4-cyclohexylenedimethylmethylene-l,4-cyclohexyleneiminocarbonyl)
synthesis procedure, 85 Poly(2,4-furandiylcarbonylimino-
1,4-cyclohexylenemethylene-1,4-cyclohexyleneiminocarbonyl)
structure, 67 synthesis and properties, 69, 85
Poly(2,4-furandiylcarbonyloxy-l,4-phenylenedioxothio-l,4-phenyleneoxycarbonyl)
synthesis procedure, 84 Poly(2,4-furandiylcarbonyloxy-l,4-
phenylenedimethylmethylene-1,4-phenyleneoxycarbonyl)
synthesis procedure, 83
541
Poly(2,4-furandiylcarbonyloxy-l,4-phenylenethio-l,4-phenyleneoxycarbonyl)
synthesis procedure, 84 Poly(2,5-furandiylcarbonylimino-
1,4-cyclohexylenedimethylmethylene-l,4-cyclohexyleneiminocarbonyl)
synthesis procedure, 80 Poly (2, 5-furandiylcarbonylimino-
1,4-cyclohexylenemethylene-1,4-cyclohexyleneiminocarbonyl)
synthesis procedure, 81 Poly(2,5-furandiylcarbonyloxy
ethyleneoxycarbonyl) synthesis conditions, 52
Poly(2,5-furandiylcarbonyloxy-l,4-phenylenedimethylmethylene-1,4-phenyleneoxycarbonyl)
polymerization techniques, 55 properties, 55
Poly(2,5-furandiylcarbonyloxy-l,4-phenylenedimethylmethylene-1,4-phenyleneoxycarbonyl)
synthesis procedure, 79 Poly(2,5-furandiylcarbonyloxy-l,4-
phenylenedioxothio-l,4-phenyleneoxycarbonyl)
synthesis procedure, 79 Poly(2,5-furandiylcarbonyloxy-l,4-
phenylenethio-l,4-phenyleneoxycarbonyl)
synthesis procedure, 79 Poly(3,4-furandiylcarbonylimino-
1,4-cyclohexylenedimethylmethylene-l,4-cyclohexyleneiminocarbonyl)
synthesis procedure, 82 Poly (3, 4-furandiylcarbonylimino-
1,4-cyclohexylenemethylene-l,4-cyclohexyleneiminocarbonyl)
synthesis procedure, 83 Poly(3,4-furandiylcarbonyloxy-l,4-
phenylenedimethylmethylene-1,4-phenyleneoxycarbonyl)
synthesis procedure, 81 Poly(3,4-furandiylcarbonyloxy-l,4-
phenylenedioxothio-1,4-phenyleneoxycarbonyl)
synthesis procedure, 82 Poly(3,4-furandiylcarbonyloxy-l,4-
phenylenethio-l,4-phenyleneoxycarbonyl)
synthesis procedure, 82 Poly (p-halomethylstyrene)
poly(styryl)lithium coupling, 338
542
Poly (2, 4-hexadiene) IR characterization, 493 NMR characterization, 492 physical properties, 491, 494 polymer microstructure, 491, 502 x-ray diffraction characteriza-
tion, 493, 494 threo and erythro configurations,
494 thermal properties, 496
Poly (S-hydroxybutyrate) optically active, 445 synthesis procedure, 445
Poly (4-hydroxy-L-proline) ordered conformation disruption,
438 Poly(iso-butyl methacrylate)
glass transition temperature, 359 isotactic stereochemistry, 359 polymerization solvents, 359 purification, 351 syndiotactic stereochemistry, 359 thermal properties, 359
Polyisocyanates, 231 Poly (isocyanurate-oxazolidone)
resin properties, 256 Polyisoprene
cis-1,4-microstructure, 333, 334 high cis content, 483 metalated with alkyllithium-
diamine complexes, 336 polymer microstructure, 502
Polyisoprene, block copolymer hydrogenation, 335
Polyisoprene, grafting polystyrene branches, 337
Polyisoprene, living polymer macromer formation, 461
Poly(isoprene-i-styrene) synthesis procedure by metalation
reaction, 336, 337 Poly (isoprenyl) lithium
aldimine trimethylsilyl reaction, 330
anionic polymerization initiator, 334
carbon dioxide reaction, 329 Poly(lactide), 442 Poly (DL-lactide)
crystallinity, 442 Poly(L-lactide)
crystallinity, 442 Poly (L-lactide-co-D-lactide)
crystallinity, 442 Poly(lactones)
high optical purity polymers, 442 optically active synthesis, 441
Polymer, blends anionic prepared polymers as
component, 342
Polymer, blends (continued) compatiblizer synthesis, 463 tactic poly(methyl methacrylate),
363, 364 Polymerization
amphi-ionic type, 248 anionic type, 321, 322, 327, 462 benzene with sulfur, 159, 171 cationic method, 462 chain termination, 321, 322 chain transfer, 321, 322 group transfer method, 327 high temperature melt method, 191 inifer method, 462 living ionic method, 339 optically active S-propio-
lactones, 449 particle producing type, 381 radical procedure, 462 ring opening type, 27, 28, 33, 48 stereospecific type, 323
Polymerization, anionic, 381 alkyllithium initiators, 382, 383 butadiene, 347 controlled method, 325, 361 dienes, 333-335 dispersion type kinetics, 390-396 ethylene oxide-polystyrene epoxy
ether macromer, 465, 470-475
isoprene, 347 lactones, 441, 447, 450 methacrylate molecular weight
control, 361 methacrylates, alkyl, 347 methacryloyl terminated
polystyrenes, 463 polar solvent effects, 360 polymer grafting tool, 406 poly(a-methylstyryl) lithium, 338 poly(styryl) lithium, 338 styrene, 347 styrene dispersion, 381-388,
391, 392 styrene rate constants, 392-395 vinyl monomers grafting, 407
Polymerization, cationic lactones, 441, 447, 450 macromer production, 462 macromonomer initiators, 239 tetrahydrofuran, 462
Polymerization, coordination lactones, 441, 447, 450
Polymerization, dispersion, 381-383, 387, 389, 392
anionic dispersion polymerization mechanism, 384, 385, 394, 395
diblock copolymer uses, 382, 383, 389
Polymerization, dispersion, (continued)
kinetics for anionic, 390-392 solvent effects, 386
Polymerization, emulsion, 831 2,3-dimethyl-1,3-butadiene, 495
Polymerization, grafting methods available, 406, 408 synthetic biopolymers, 405
Polymerization, interfacial dicarboxylic acid salts-organo
metallic halides, 187, 188, 191, 192, 194
polyamides production, 56 polyarylates production, 97, 105 polyester production, 54, 64 polysulfones synthesis, 97, 101,
104 Polymerization, living anionic
styrene-t-butylstyrene diblock, 382, 383
Polymerization, radical dispersion type, 382 macromers, 463 polystyrene macromer production,
462 Polymerization, step-growth
anchimeric assisted, 143 Polymerization, stereospecific
1,3-dienes, 483-485 Polymerization, suspension, 381 Polymers
acid terminated, 328, 329 amine terminated, 330 anionic chain ends, 321 anionic grafting, 336, 337 anionic produced, 321, 322 antiplatelet grafted, 291 benzene-sulfur containing, 14 159-161, 163-168, 170
c labeling, 295 carbanionic chain ends, 323 carbonation reaction, 328, 329 chain end functionalization, 328 diene containing, 483-503 difunctional growing ends, 324 drug carrier, 293 electrical properties, 134 electrophilic functionality
grafting sites, 337, 338 enamine carbonyl-ring
containing, 388 flocculation prevention, 381 functional telechelic, 203 grafting from, 336, 406-408 grafting onto, 336, 406-408 greese thickeners, 382, 401 hydroxyl terminated, 329, 330 network type, 236 organic fillers, 382
543
Polymers (continued) oxazolidone containing, 251, 254 oxazoline pendent groups, 236,
237 oxazoline terminal groups, 236 pigments use, 382, 401 radical generation on surface,
295 surface active particle uses, 382 surface radicals containing,
292, 293 thrombogenicity, 292 vinyl monomer grafting by redox
formed radicals, 293, 299 Polymers, anionic
functionalization reactions, 327-329
Polymers, carbanionic coupling reactions, 332 linking reactions, 332
Polymers, carbanionic chain ended electrophilic reagent reactions,
328, 329 Polymers, comb-like
poly(ethylene oxide) branches, 238, 239
Polymers, compatiblizers polystyrene macromer-ethylene
oxide copolymer, 463 Polymers, cyclic
formation reaction, 332, 333 Polymers, dianion terminated
dibromoxylene reaction, 332, 333 dichlorodimethylsilane reaction,
332 Polymers, a,w-dilithium substituted
ethylene oxide reaction, 329 Polymers, epoxide functionalized
poly(styryl)lithium coupling, 338 Polymers, functional
oxazoline based, 235 oxazoline chain ended, 238, 239,
244 oxazoline reactive groups, 236
Polymers, grafted bioactivity, 318 polymeric carbanion use, 338
Polymers, halogenated grafting attempts, 338 transition metal reaction, 299
Polymers, hydroxy substituted bisazlactone crosslinking, 220
Polymers, liquid crystalline engineering properties, 134 glass transition temperature, 135 isotropization temperature, 135 lyotropic type, 275 main chain type, 133 mesogenic units, 133, 275 mesomorphic properties, 148
544
Polymers, liquid crystalline (continued)
microstructure, 134 physical properties, 134 poly(azomethines) type, 133 polyenamine type, 133, 134 polyester type, 133 spacer groups, 134 thermal characterization, 135 thermotropic type synthesis,
133, 148, 158, 275, 278, types, 134
Polymers, living anionic aId imine trimethylsilyl reaction,
330 divinylbenzene end linking
reaction, 332 Polymers, living carbanionic
ethylene oxide termination, 329 Polymers, living type
anionic synthesis methods, 408 carbanionic chain ended, 326 grafting to anionic sites, 407
Polymers, methacrylate anionic synthesis methods, 347
Polymers, optically active poly(8-propiolactones), 450-455 8-propiolactone polymers, 450 stereocomplex blends, 455
Polymers, a,w-2-oxazoline substituted
synthesis procedures, 243 Polymers, phase separated
anionic prepared polymers as component, 342
Polymers, preformed coupling reactions, 337
Polymers, radical derivatives mechanism for reaction, 299
Polymers, stereoblock isotactic-atactic-isotactic, 364 molecular complexes, 364 poly(methyl methacrylate) inter-
molecular association, 364 properties, 364 segmented molecular weights, 371 syndiotactic-atactic-syndio-
tactic, 364 tacticities differences, 364, 369
Polymers, stereocomplexes tactic methacrylate thermal
properties, 363 Polymers, sulfur containing
characterization, 165, 166, 170, 171
sulfonation, 165 thermal properties, 165, 171
Polymers, tactic stereocomplex formation, 363, 364 helix blends, 363, 364
Polymers, telechelic functional oligomers, 219 phenolic hydroxyl terminated, 248 preparation methods, 324
Poly (N-methyl-L-alanine) cis- and trans-amide helices, 438
Poly(a-methylbenzyl methacrylate) chiral stereocomplex blends, 457
Poly (a-methyl-a-ethyl-S-propio-lac tones)
Bernouillian statistics, 447 crystal structure-unit cell,
451-453, 455 isotactic polymer, 447 isotactic polymer stereo
complexes, 455-457 physical properties, 451-453,
455-458 racemate polymer blends, 455-457 stereocomplex blends physical
properties, 455-458 triad sequence distribution, 447
Poly(methacrylic acid), isotactic diazomethane reaction, 368 trityl methacrylate polymer
hydrolysis, 368 Poly(methyl methacrylate)
ABA stereoblock polymer, 378, 379 anionic polymerization,
syndiotactic content, 365 atactic form, 363 bifunctional initiator formed,
373 characterization, 358 glass transition temperature,
360, 361, 363, 508 Grignard tactic segments, 364 halogen terminated, 462 high conversion polymer,
506-510, 514 homopolymer stereoblock type, 364 hydrolysis with esterification,
365, 366 isotactic glass transition, 363 methyl methacrylate dispersions,
388 macromer synthesis, 462 molecular weight studies, 369,
370 NMR stereochemistry study, 369 polymer tacticity, 372, 373 purification, 351 standard characterization, 357 stereoblock polymer characteri-
zation, 363 stereoblock polymer synthesis,
363 stereochemistry, 373 syndiotactic glass transition,
363
Poly(methyl methacrylate) (continued)
syndiotactic polymer, 365 synthesized from diphenylmethyl
methacrylate, 372 synthesized from trityl
methacrylate, 372 radical polymerization method,
360 tactic polymer complexes glass
transition temperature, 363 thermal properties, 360 time conversion plots,511
Poly(methyl methacrylate-b-butadiene-b-methyl methacrylate)
synthesis procedure, 323 Poly(methyl methacrylate-co-trityl
methacrylate) AB stereoblock synthesis, 377,
378 Poly(methyl methacryla~e), A-B
stereoblock defined isotactic-syndiotactic
segments, 364 Poly(methyl methacrylate), atactic
synthesis, 375 Poly(methyl methacrylate),
isotactic syndiotactic poly(methyl methacrylate) stereocomplexes, 363, 364
synthesis from trityl methacrylate, 365, 366
Poly(methyl methacrylate), syndiotactic
isotactic poly(methyl methacrylate) intermolecular association, 364
synthesis from diphenylmethyl methacrylate, 365, 366
Poly(methyl methacrylate), tactic diphenylmethyl methacrylate
polymer conversion, 371 synthesis path molecular weight
variations, 372 tacticity stability analysis, 371 tacticity variation evaluation,
371 trityl methacrylate polymer
conversion, 371 Poly(2-methyl-1,3-pentadiene)
NMR characterization, 501 polymer microstructure, 500, 502 polymer properties, 500 tacticity, 500
Poly(S-methyl-S-propiolactone) synthesis procedure, 445
Poly (a-methyl-a-m-propyl-S-propiolactone)
polymer optical purity, 443
545
Poly(a-methylstyryl) lithium chloromethylsilanated polymer
coupling, 338 Poly (2-methylproline)
disordering transition mechanism, 438
ethyl group substitution, 420 solution properties, 437
Poly (2-methyl-L-proline) helices stability, 438
Poly (oxazolidones) branchin~ during formation, 254 catalysts for synthesis, 271 characterization, 254-256 crosslinking, 254 epoxide-isocyanate reaction
product, 254 film preparation, 258 glass transition temperature 270,
271 IR characterization 266, 269, 270 linear polymer synthesis, 258,
259, 263 properties, 267 synthesis conditions, 252, 267,
271, 272 Poly(oxazolidones), linear
properties, 264, 265 synthesis, 265
Poly(oxycellulose-~-polystyrene) characterization, 411, 412, 415
Polyoxyethylenes methacryloyl terminated
macromers, 462 polymer extraction, 465, 475
Polyoxyethylene, graft copolymer emulsifying property, 465 mechanical properties, 465 water-absorbing property, 465
Polyoxyethylene, macromer grafted characterization, 475 emulsifying property, 478 purification method, 475 water absorbing property, 478
Polyoxyethylene, polystyrene grafted
emulsifying property, 480 microphase separation, 480 water absorbing property, 480
Poly(1,3-pentadiene) cis, trans-content, 485 characterization, 485, 489, 490 polymer microstructure, 485,
489, 502 Polypeptides
circular dichroism characterization, 420, 438
conformational behavior, 419, 438 degree of polymerization, 429 halogenation reaction, 295
546
Polypeptides (continued) molecular weight, 428 mutarotation, 438 oligomers synthesis, 190 vinyl monomer grafting, 295
Poly(p-phenoxy-phenyl sulfide) synthesis procedure, 177, 178
Polyphenylene chemical doping, 182
Poly(phenylene sulfide) benzene-sulfur monochloride
reaction path, 177 chemical resistance, 182, 183 chlorobenzene-sulfur reaction
product, 175, 176 crystallinity, 179 engineering plastic, 173 flow and solution properties, 179 hydrogenation, 161, 167 infrared spectrum, 165, 166 molecular weight, 179, 180 oxazoline terminated oligomers,
237 Phillips process, 178, 179 Schmidt polymerization method,
175 sulfur-aluminum chloride
treatment, 167, 178 synthesis conditions, 159, 161,
171, 177 thermal properties, 178, 179, 181 toxicity properties, 183
Poly (a-phenyl-a-ethyl B-propiolactone)
isotactic physical properties, 451
racemic physical properties, 451 Polyphosphate amides
synthesis procedure, 188, 192 Polyphosphate esters
synthesis procedure, 188 uses, 190
Polyphosphonamides synthesis, 190, 192
Polyphosphonoanhydrides synthesis from dicarboxylic
acids, 195-200 Polyphosphonates
synthesis, 188 uses, 190
Poly(L-pipecolic acid) poly(L-proline) comparison, 438
Polypiperylene IR characterization, 486 NMR characterization, 487, 488 physical properties, 489, 490
Polyproline conformational structure, 419 ordered conformation, 419
Poly (L-proline) circular dichroism
characterization, 430, 433 cis and trans forms, 419 helices stability, 438 mutarotation, 420 ordered conformation disruption,
439 Poly(B-propiolactones)
isotactic polymers, 442 optically active polymer, 441,
442, 445 racemic, 441 synthesis, 441 thermal properties, 442
Poly(B-propiolactones), Ct.-substituted
physical properties, 451-453 Poly(B-propiolactones), Ct.-disub
stituted, 442 crystallization properties, 453,
454 Poly(B-propiolactones), Ct.- and B
substituted, 442 optically active polymer
synthesis, 457 physical properties, 457
Polyproylene, isotactic properties, 499
Polystyrene, 5, 410 amine terminated synthesis, 330,
331 anionic dispersion polymer
characterization, 398, 399, 403
anionic dispersion polymers as elastomer reinforcement, 400
anionic dispersion polymer rheological properties, 399
anionic polymerized particle analysis, 397, 398
applications dispersion polymer, 398-401, 403
dimer formation reaction, 331 dispersion flocculation
prevention, 387, 388 dispersion prepared molecular
weights, 386 epoxy ether terminated, 461,
464-469, 480 ethylbenzene diffusion
constants, 516 glass transition temperatures,
390 grafting on cellulose, 405 living anionic polymerization
method, 342 living dispersion polymer
particles, 398
Polystyrene (continued) living polymer synthesis, 383,
386, 388 macromer grafting effici.ency,
471-474 methacryloyl terminated
macromer~, 339, 340, 462, 463, 465, 470
molecular weight standards, 134 peracetate functionalized, 400 peroxide formation, 331 polymer properties, 398 polystyrene grafted cellulose
reinforced, 405 prostacyclin grafted, 293 vinyl macromer synthesis, 461
Polystyrene, branched synthesis procedure, 332
Polystyrene, carbanion grafting to cellulose, 410, 411,
413 Polystryrene, dilithium derivative
methoxyamine/methyl lithium reaction, 331
perparative procedure, 324 Polystyrene, hydroperoxide
synthesis procedure, 331 Poly(styrene-B-butadiene-B-styrene)
thermoplastic elastomer synthesis, 322, 323
Poly(styrene-b-t-butylstyrene) diblock copolymer synthesis,
382, 383 Poly(styrene-co-ethylene oxide)
synthesis procedure, 478 water absorbing property, 478
Poly(styrene-b-isoprenyl) lithium carbon dioxIde reaction, 329
Poly(styryl) lithium aId imine trimethylsilyl
reaction, 330 anionic polymerization
initiator, 334 carbon dioxide reaction, 329 chloromethylsilanated polymer
coupling, 338 ketone dimer formation, 329 methoxyamine/methyllithium
reaction, 330, 331 molecular oxygen reaction, 331 N,N,N',N'-tetramethylethylene
diamine complex oxidation reaction, 331
Polystyrene, epoxy ether terminated epichlorohydrin copolymerization,
480 ethylene oxide copolymerization,
463-466, 470-475, 478 macromers production, 463,
466-469
547
Polystyrene, epoxy ether terminated propylene oxide copolymerization,
480 Polystyrene, living polymer
active chain ends, 389 acetyl chloride reaction, 400 bis(dirnethylamino benzophenone)
capping reaction, 401 crosslinked lithium stearate
greese additive, 401, 403 diisocyanate capping reaction,
401, 403 1,1-diphenylethylene reaction,
470 dispersion polymerization
mechanism, 403 epichlorohydrin reaction,
463-470, 480 ethylene oxide termination, 463,
470, 480 hydroperoxide conversion, 400 leuco dye/pigment conversion,
401, 402 macromer formation, 461 oxygen termination, 400 reactive chain ends
availability, 403 synthesis procedure, 410 telechelic dispersion particles,
399, 403 trimethyl chlorosilane
terminating agent, 388 p-vinylbenzyl chloride reaction,
461 Polystyrene, macromer
epoxy group terminated, 480 Polystyrene, metacryloyl terminated
butyl acrylate copolymerization, 463
2-hydroxyethyl methacrylate copolymerization, 463
Polysulfone oligomers, 108 synthesis, 96, 97, 106
Poly(sulfone-ester) characterization, 102, 103,
106-108 segmented copolymer synthesis,
99-109 Polysulfone, oligomers
characterization, 98-103, 106 hydroxy terminated, 96, 97,
101-103, 105-109 segmented copolymers, 108, 109 synthesis, 97, 98, 100-105, 109 terephthaloyl chloride reaction,
99, 100, 106-108 Polytetrahydrofuran
macromer use, 462
548
Polytetrahydrofuran, methacryloyl terminated
radical homopolymerization, 463 Poly(tetramethyl bisphenol A-ether
ketone) crosslinking reaction, 123 crosslinking mechanism, 130 synthesis procedure, 122
Poly(tetramethyl bisphenol A sulfone)
crosslinking reaction, 124-128 Poly(thianthrylene sulfide)
synthesis, 171, 177 Poly(trans-3-ethylproline)
rotational isomerism, 420 Poly (D-trans-3-ethylproline)
synthesis procedure, 428 Poly(L-trans-3-ethylproline)
synthesis procedure, 428 Poly(trans-3-ethyl-D-proline)
circular dichroism characterization, 430-437
conformational studies, 419 helices stability, 438 mutarotation, 437 synthesis procedure, 419, 438
Poly(trans-3-ethyl-L-proline) synthesis, 438
Poly (trans-5-ethylproline) helices stability, 438
Poly (trans-5-ethyl-D-proline) conformational forms, 420
Poly(trityl methacrylate) conversion to poly(methyl
methacrylate), 372 high molecular weight polymer,
372 hydrolysis to acid polymer, 372 isotactic polymer synthesis,
364-366 Poly(trityl methacrylate),
isotactic hydrolysis, 368
Poly(trityl methacrylate), tactic conversion to poly(methyl
methacrylate), 371 Poly(trity] methacrylate-co-di
phenyl methyl methacrylate) AB stereoblock synthesis, 376,
377 synthesis, 373-375 stereochemistry, 374-377
Poly(S-trichloromethyl S-propiolactone)
crystallization properties, 454 optically active polymer, 451 thermal properties, 454
Poly (6-trifluoromethyl-6-methyl 6-propiolactone)
crystallization properties, 454 thermal properties, 454
Polyurethanes acidic proton reactions, 337 metalated with sodium, 337 momomers, 59
Polyurethanes, metalated ethylene oxide grafting, 337 ethylene sulfide grafting, 337
Poly(vinyl acetate) vinyl acetate dispersions, 388
Poly(vinyl alcohol) polymeric suspending agent, 381
Porphyrin diethylaluminum chloride adduct
catalyst, 451 Potassium acetate
Crown ether cocatalyst, 451 PPO
bromomethylated product, 246 NMR characterization, 247 oxazoline group substituted, 246 thermal characterization, 247
PPS compounding, 180 Dow process, 175 electrical properties, 181, 182 Macallum polymer, 175 mechanical properties, 180-182 molecular weights, 174 poly(phenylene sulfide), 160,
162, 167 preparation from 4-halophenol,
178 properties, 174 Schmidt, polymers, 175 synthesis routes, 174 uses, 174
L-Proline protein structure contribution,
419 6-Propiolactones
anionic ring opening polymerization, 457
cationic polymerization, 457 coordination catalyst polymeri
zation, 457 ketene-carbonyl reaction
product, 445 synthesis routes, 443
6-Propiolactones, enantiomer mixture
enantioelective polymerization, 442
stereoelective polymerization, 442
6-Propiolactones, mono- and disubstituted
enantiomeric excess assay, 446 6-Propiolactones, optically active
anionic polymerization, 450 ring opening polymerization,
449, 450 6-Propiolactones, a- and 6-
substituted chiral europium salt complexes,
447 high pruity monomer synthesis,
442-447 6-Propiolactones, 6-substituted
polymerization with configuration retention, 450
racemization polymerization, 450 ring opening polymerization
mechanisms, 450 synthesis procedures, 457
Propionyl hexafluoroantimonate tetrahydrofuran polymerization
to macromer, 462 Prostacyclin
grafted on polystyrene, 293 synthesis, 293
Prostaglandin, analogue platelet aggregation inhibitor,
296 Proteins
halogenation reaction, 295 macromolecule interactions, 419 redox oxidation initiated
grafting, 294 vinyl monomer grafting, 295
Pyridine anionic polymerization modifier,
360 anionic polymer coordinating
agent, 326 carbanionic species interaction,
326 polyanhydride synthesis
catalyst, 188 Pyridinium bromide perbromide
methyl coumalate reaction, 61, 73 Pyridine dicarboxylic acid
polyester monomers, 52 Pyrocatechol
polyester monomer, 54 Pyrrole dicarboxylic acids
polyester monomers, 52
Quaternary ammonium halides isocyanate-epoxide reaction
catalyst, 252 Quinidine
amino acid resolving agent, 425 chiral base, 446
549
Quinine amino acid resolving agent, 425,
427 optically active acid
resolution, 444
Rayon, 405 Reaction injection molding
azlactone oligomers, 232 Reactivity ratios
butadiene-styrene monomers, 336 butyllithium copolymerizations,
336 styrene-t-butylstyrene monomers,
336 styrene-p-methylstyrene monomers,
336 Redox oxidation systems
polymers with mobile protons, 292, 293
Resorcinol polyester monomer, 54
Rhenium decacarbonyl grafting catalyst, 299 purification, 308
Reseotoxin B cycloclepsipeptide mycotoxin, 420
Ryton aluminum chloride degraded, 168 poly(phenylene sulfide), 167,
168, 173 properties, 179
SBR polystyrene dispersion polymer
reinforcement, 400, 401 Schotten-Baumann reaction
acid chloride-phenol reaction, 189
Siloxanes anionic polymerization, 322
Silver methacrylate trityl chloride reaction, 367
Sodium liquid ammonium polymer
metalation, 337 Sodium acetate
B-propiolactone polymerization catalyst, 451
Sodium benzil methyl methacrylate
purification,354 Sodium ethoxide
Michael addition catalyst, 420 Sodium hydride
polymer metalation reaction, 337 Sodium methylsulfinyl carbanion
polymer metalation reagent, 337
550
Sodium naphthalene polymer metalation reaction, 337 polystyryl dicarbanion synthesis
agent, 410 Sodium sulfide hydrate, 173 Styrene
alkyllithium polymerized, 326 anionic copolymerization, 335 anionic dispersion polymeriza-
tion, 381-392 anionic dispersion polymeriza
tion kinetics, 390-396 anionic dispersion polymeriza
tion rate constants, 384, 392, 394
anionic polymerization rates, 390-396
anionic solution polymerization, 321, 322, 326, 347, 392, 394
bis-triazolinedione reaction, I, 2
butyllithium polymerized, 322, 323
s-butyllithium polymerized, 410 t-butylstyrene copolymerization,
335 t-butylstyrene diblock copolymer
ization, 382, 383 dibutyl magnesium water removal,
348 living polymerization, 322, 323 p-methylstyrene copolymerization,
335 purification, 408, 464 sodium naphthalene polymerized,
410 sodium napthalene reaction, 324
Styryl hydroperoxide lithium salt, 400 synthesis procedures, 400
Subtilisin enzyme catalyst, 277
4,4'-Sulfonyl diphenol polyester comonomer, 59, 65-68,
80, 82, 84, 86, 88 purification, 72
Tartaric Acid amino acids resolution agent, 427
Tartaric acid, L-(+) isomer amino acid resolution agent, 427
Telechelics synthetic techniques, 134
1,2,5-Thiadiazole-3,4-dicarbonyl dichloride
polyamides produced from, 55, 56 Thianthrene
benzene-sulfur reaction intermediate, 170, 177
Thianthrene (continued) phenylene sulfide biproduct,
159-162, 169, 170 PPS synthesis intermediate, 175
Thiiranes chiral initiators polymerization,
442 4,4'-Thiodiphenol
polyester comonomer, 59, 65, 67-70, 79, 82, 84, 87, 88
purification, 72 3,4-Thiofurazan dicarbonyl
dichloride polyamide monomer, 55
Thionyl chloride, 72 Thiophenol
PPS production intermediate, 176, 177
synthesis, 160, 162, 170, 171 thionyl chloride condensation,
177 2,4-Thiophene dicarboxylic acid
polyester monomers, 52 Terephthalic acid, 192, 194
adipoyl chloride copolymerization, 188
crystallographic dimensions, 58 a,w-glycol polyesterification,
53, 56 polyamide monomers, 57 polyester monomer, 53, 56, 58-60 sebacyl chloride copolymeriza-
tion, 188 Terephthalic acid, metal salts
phosphorus acid chloride condensation, 195
Terephthaloyl chloride copolyamides, 60 diamine polycondensation, 60 dicarboxylic acid
polymerization, 188 polyarylate synthesis, 94-96,
99-101, 106-109 purification, 97 4,4'-sulfonyldiphenol polyester,
59, 60 Tetrabutylammonium hydrogen sulfate
phase transfer catalyst, 136-138 Tetrabutylammonium iodide
cyanoacrylates initiator, 327 Tetracyanoethylene
Diels-Alder reaction, 1 2,2,3,3-Tetrachloro-l,4-butanediol
polyester monomer, 53 1,1,2,2-Tetrachloroethane, 97, 246
polyamide solvent, 69, 70 Tetraethylammonium bromide, 257,
261, 264, 265 isocyanate epoxide reaction
catalyst, 259, 262
Tetraethylammonium bromide (continued)
isocyanate trimerization catalyst, 266, 267
oxazolidone formation catalyst, 258
Tetraethyleneglycol dimethacrylate, 301
Tetrafluoroethylene glow d1.scharge medium, 292
Tetrahydrofuran, 139 anionic Lewis base modifier,
335, 396 anionic polymerization solvent,
329, 464, 468 cationic polymerization, 462 Lewis base, 324 polymerization solvent, 324, 325
Tetrahydrofuroic acid polyesters, 54
1,3,4-Tetrahydrooxadiazine ring synthesis, 1
Tetrakis-(triphenylphosphine) palladium
catalyst for PPS synthesis, 178 Tetramethyl bisphenol A
IR analysis, 120 NMR analysis, 120 mass spectrum, 121 poly(arylether) monomer, 188 synthesis procedure, 119
Tetramethylbisphenol A, ketone, 125 N,N,N',N'-Tetramethylethylene
diamine alkyllithium complexes for
polymer methalation, 336, 337
anionic polymerization modifier, 334
polyisoprene microstructure modifier, 334
N,N,N',N'-Tetramethylethylenediamine complex
poly(styryl)lithium oxidation agent, 331, 336
Tetramethylene glycol 2,5-furandicarboxylic acid
polyester, 53 1,1,4,4-Tetraphenylbutane, lithium
dianion anionic bifunctional initiator,
373, 379 synthesis procedure, 367
Tetraphenyl porphyrin diethylaluminum chloride complex
lactone polymerization, 450 2,4-Toluene diisocyanate
anionic living polystyrene reaction, 401
epoxide reaction, 252
551
p-Toluenesulfonic acid bisazlactone reaction catalyst.
220. 227 catalyst. 280 monohydrate. 279. 282
p-toluene sulfonylhydrazide diene hydrogenation catalyst. 335
N-(p-Toluene sulfonyl)-cis-3-ethylproline. methyl ester
base saponification. 438 NMR characterization. 424. 425
N-(p-Toluenesulfonyl)-3-ethylproline. cis and trans. methyl esters
NMR characterization. 424-426 separation procedure. 423
N-(p-Toluenesulfonyl)-trans-3-ethyl-proline. methyl ester
base saponification. 438 brucine resolution. 427 quinine resolution. 427 NMR characterization. 424. 425
Toxins polypeptides. 419
Trialkyl aluminum alcohol reactions. 355 methacrylate monomer
purification. 361 methyl methacrylate complex.
354. 355 monomer purification reagent. 326 rare earth chloride complex
catalysts. 483. 484 Triazolinedione
alkene ene reaction. 2 B-Dicarbonyl compound adducts. 2 hydroxyl group reaction. 14 chain extenders. 3. 13 crosslinking agent. 3. 13 reactions. 3 solvents. 2 styrene reaction. 1 vinyl ether reactions. 1
1.2.4-Trichlorobenzene. 161. 163. 164. 167. 168. 170. 171
PPS trifunctional comonomer. 174 polydiene solvent. 495
B-Trichloromethyl-B-propiolactone optically active monomer
preparation. 446 polymer produced from. 447 polymerization to optically
active polymer. 451 Triethyl aluminum
alkyl methacrylate treatment agent. 350
B-propiolactone polymerization. 450. 451
methacrylate monomer purification. 354. 356-358
552
Triethylaluminum hydrate B-propiolactone polymerization
catalyst. 450 Triethylamine. 69. 71. 225
N-carboxyanhydrides polymerization catalyst. 428
B-propiolactone polymerization catalyst. 451
Triethylenediamine isocyanate-epoxide reaction
catalyst. 267-269 oxazolidone formation catalyst.
270-272 Triethyloxonium tetrafluoroborate
tetrahydrofuran polymerization catalyst. 462
Triethylphosphate polyanhydride solvent. 193
Triethylphosphine cyanoacrylates initiator. 327
Trifluoroacetic acid. 279 3-ethylproline polymer solvent.
429. 430, 433. 436. 437 isotactic poly(B-propiolactone)
solvent, 451 polyamide solvent, 69
s-2,2.2-Trifluoro-(anthryl-9)-1-ethanol
B-lactone diastereoisomer complex resolution, 446
2. 2. 2-Trifluoroethanol 3-ethylproline polymer solvent,
429, 430. 434. 437 isotactic poly(B-propiolactone)
solvent. 451 Trifluoromethanesulfonic acid
cyanoacrylate polymerization inhibitor, 327
Triisobutyl aluminum, 464. 470-472 active hydrogen scavenger, 473 epoxide polymerization catalyst,
465, 470. 471 Trimethyl aluminum
inifer polymerization catalyst, 462
Trimethylchlorosilane anionic living polymer
terminating agent, 388 3,6,8-Trimethyl-3.4-dihydro-2H-1,3-
benzoxazine phenol reactions, 29 2.4-ditert-butylphenol reaction,
34, 35 Trimethylene glycol
2,5-furanedicarboxylic acid polyester, 53, 56
Trimethylsiloxy lithium cyclic siloxane polymerization
catalyst. 462
Tri-n-octyl aluminum alkyl methacrylate treatment
agent, 350 methyl methacrylate purification
agent. 355. 357 Tripeptides
synthesis. 190 Triphenyl phosphite. 72 Tris-[3-hepta fluoropropyl)hydroxy
methylene)-d-camphorato] europium III
substituted a-propiolactone optical resolution. 447
Trityl methacrylate anionic polymerization. 364.
368, 371-373 diphenylmethyllithium
polymerized, 371 diphenylmethyl methacrylene
anionic copolymerization. 373-377
purification. 367 silver methacrylate reaction, 367 sequential polymerization. 366,
368 synthesis procedure. 367
Trommsdorff effect methacrylates polymerization, 506
Vandenberg catalyst bimetallic-oxo-alkoxides, 480
Van der Walls radii t-butyl group. 388
Vanillin manufacture. 14
Vinylazlactone bismercaptane product
characterization, 226 Michael addition reaction. 224 synthesis, 225
Vinylbenzyl chloride p-hydroxyphenyl-2-oxazoline
etherification, 244
m-Vinylbenzyl ether p-hydroxyphenyl-2-oxazoline
substituted, 244 p-Vinylbenzyl ether
p-hydroxyphenyl-2-oxazoline substituted. 244
2-Vinyl-4.4-dimethylazlactone Jeffamine reaction. 213-216 ORTEP plots. 211 synthesis procedure, 206
Vinyl esters bis-triazolinedione reaction. 2 triazolinedione reactions. 2
Vinyl ethers triazolinediones reaction. 1
Vinyllithium polymerization initiator. 461 polystyrene catalyst. 461
2-Vinyl-2-oxazoline free radical polymerization. 237
Vinyl pyridine anionic polymerization, 322.
326. 327 N-Vinylpyrrolidone. 307
grafting on Pellethane, 315 hydroxyethyl methacrylate co
polymerization details. 316
polymerization with haloesters, 17
Vrentas-Duda free volume theory methyl methacrylate
polymerization system, 515
Williamson reaction etherification of phenol substi
tuted oxazoline. 242. 243
m-Xylylenediamine, 279. 282, 284
Zwitterionic molecules, 1
553