3800 - Conductive Nickel Coating · 3800 - Conductive Nickel Coating ... Vapours can form explosive...

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3800 - Conductive Nickel Coating

www.hollandshielding.com Jacobus Lipsweg 124NL-3316BP, The Netherlands

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Revision date: 27-6-2016

1. Identificationofthesubstance/mixtureandofthecompany/undertakingProduct Detail : 3801 Conductive Nickel Coating.Application of the substance / the preparation For use as a conductive coating. For professional use only.Manufacturer / supplier: Holland Shielding Systems B.V. Jacobus Lipsweg 124 3316 BP Dordrecht the Netherlands phone + 31 78 6 13 13 66 fax + 31 78 6 14 95 85 www.hollandshielding.com [email protected]. Hazardsidentification2.1Classificationofthesubstanceormixture

2.1.1.ClassificationaccordingtoRegulation(EU)1272/2008

CLP-Classification This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP].Aerosol 1 H222;H229

Skin Irrit. 2 H315Skin Sens. 1 H317

Carc. 2 H351Repr. 2 H361

STOT SE 3 H336STOT RE 1 H372

Aquatic Chronic 3 H412Full text of H-phrases: see section 16

2.1.2.ClassificationaccordingtoEUDirectives67/548/EECor1999/45/ECThe product is classified as dangerous in accordance with Directive 1999/45/EC.Carc.Cat.3; R40 Repr.Cat.3; R63 T; R48/23 Xn; R20/21Xi; R38 R43R52/53 F+; R12Full text of R-phrases: see section 16

2.2.Labelelements2.2.1.LabellingaccordingtoRegulation(EU)1272/2008

Hazard pictograms GHS02 GHS07 GHS08

Signal word Danger

Contains

Toluene Nickel powder Acetone N-butyl acetate

Hazard statements

H222 - Extremely flammable aerosol H229 - Pressurised container: May burst if heated H315 - Causes skin irritation H317 - May cause an allergic skin reaction H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer H361 - Suspected of damaging fertility or the unborn child H372 - Causes damage to organs through prolonged or repeated exposure H412 - Harmful to aquatic life with long lasting effects

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Precautionary statements

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P211 - Do not spray on an open flame or other ignition sourceP251 - Do not pierce or burn, even after useP201 - Obtain special instructions before useP308+P313 - IF exposed or concerned: Get medical advice/attentionP410+P412 - Protect from sunlight. Do no expose to temperatures exceeding 50°C/122°F.

2.2.2.LabellingaccordingtoDirectives(67/548-1999/45)Not relevant

2.3.OtherhazardsOther hazard : Vapours can form explosive mixtures with air. PBT/vPvB data : This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

3. Composition/informationoningredients

3.1.SubstancesNot applicable

3.2.Mixtures

Substancename Productidentifier % ClassificationaccordingtoDirective67/548/EEC

ClassificationaccordingtoRegulation(EC)No.1272/2008[CLP]

Dimethyl ether(CAS No.) 115-10-6(EC No) 204-065-8

(EC Index) 603-019-00-825 - 50 F+; R12 Flam. Gas 1, H220

Press. Gas

Nickel powder(CAS No.) 7440-02-0 (EC No) 231-111-4

(EC Index) 028-002-00-725 - 50

Carc.Cat.3; R40T; R48/23

R43R52/53

Skin Sens. 1, H317 Carc. 2, H351

STOT RE 1, H372 Aquatic Chronic 3, H412

XyleneCAS No.) 1330-20-7 (EC No) 215-535-7

(EC Index) 601-022-00-910 - 25

R10Xn; R20/21

Xi; R38

Flam. Liq. 3, H226Acute Tox. 4 (Dermal), H312

Acute Tox. 4 (Inhalation), 332 Skin Irrit. 2, H315

Toluene(CAS No.) 108-88-3(EC No) 203-625-9

(EC Index) 601-021-00-32,5 - 10

F; R11Repr.Cat.3; R63

Xn; R65Xn; R48/20

Xi; R38R67

Flam. Liq. 2, H225 Repr. 2, H361d

Asp. Tox. 1, H304 STOT RE 2, H373 Skin Irrit. 2, H315 STOT SE 3, H336

N-butyl acetate(CAS No.) 123-86-4(EC No) 204-658-1

(EC Index) 607-025-00-12,5 - 10

R10R66R67

Flam. Liq. 3, H226 STOT SE 3, H336

Acetone(CAS No.) 67-64-1(EC No) 200-662-2

(EC Index) 606-001-00-8< 2,5

F; R11Xi; R36

R66R67

Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336

2-methoxy-1-methylethyl acetate

(CAS No.) 108-65-6(EC No) 203-603-9

(EC Index) 607-195-00-7< 2,5 R10 Flam. Liq. 3, H226

Full text of R- and H-phrases: see section 16 Identification of the substance or mixture: Mixture

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4. Firstaidmeasures4.1.Descriptionoffirstaidmeasures

Inhalation

Provide fresh air. Keep warm and in a quiet place. If breathing is irregular or stopped, administer artificial respiration. Get medical advice/attention.

Skin contact

Wash with plenty of water. Take off all contaminated clothing immediately. Wash contaminated clothing before reuse. When in doubt or if symptoms are observed, get medical advice.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.

Ingestion Rinse mouth immediately and drink plenty of water. Do NOT induce vomiting. When in doubt or if symptoms are observed, get medical advice.

Additional advice

First aider: Pay attention to self-protection! See also section 8. Never give anything by mouth to an unconscious person or a person with cramps. Show this safety data sheet to the doctor in attendance. Treat symptomatically. When in doubt or if symptoms are observed, get medical advice.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Inhalation May cause drowsiness or dizziness.Skin contact Causes skin irritation. May cause an allergic skin reaction.Eye contact May cause eye irritation.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea

Other adverse effects Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure.

4.3.IndicationofanyimmediatemedicalattentionandspecialtreatmentneededNo data available

5. Firefightingmeasures5.1.Extinguishingmedia

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Sand.Extinguishing media which

must not be used for safety reasons

Strong water jet.

5.2.Specialhazardsarisingfromthesubstanceormixture

Fire hazard Aerosol: Extremely flammable

Specific hazards

The pressure in sealed containers can increase under the influence of heat. Aerosol cans may rupture and become projectiles. In use, may form flammable/explosive vapour-air mixture.Vapours are heavier than air and may spread along floors. Vapours can travel considerable distances to a source of ignition where they can ignite, flash back, or explode. Hazardous decomposition products COx. Do not allow run-off from fire-fighting to enter drains or water courses. Dispose according to legislation.

5.3.Adviceforfirefighters

Advice for firefighters

Special protective equipment for firefighters. In case of fire: Wear self-contained breathing apparatus. Hose down gases, fumes and/or dust with water. Use water spray jet to protect personnel and to cool endangered containers.

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6. Accidentalreleasemeasures6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

For non-emergency personnel

Evacuate area. Stay upwind/keep distance from source. Use personal protective equipment as required. See also section 8. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray. Provide adequate ventilation. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

For emergency responders Ensure procedures and training for emergency decontamination and disposal are in place. Personal protection equipment: see section 8 .

6.2.Environmentalprecautions

Environmental precautions Do not allow to enter into surface water or drains. Prevent product from entering drains.

6.3.Methodsandmaterialforcontainmentandcleaningup

Methods for cleaning up

Ensure adequate ventilation, especially in confined areas. Dam up. Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Collect in closed and suitable containers for disposal. Clean contaminated areas thoroughly.

6.4.ReferencetoothersectionsPersonal protection equipment: see section 8. Disposal: see section 13.

7. Handlingandstorage7.1.Precautionsforsafehandling

Handling

Provide adequate ventilation. Use personal protective equipment as required. See also section 8. Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray.The product causes narcotic-like effects. Take precautionary measures against static discharges. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not burn, or use a cutting torch on, the empty drum. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not smoke. After use replace the closing cap immediately. Ensure proper process control to avoid excess waste discharge (temperature, concentration, pH, time). Do not allow to enter into surface water or drains. Take any precaution to avoid mixing with incompatible materials. See also section 10 .

Advices on general occupational hygiene

Use only in area provided with appropriate exhaust ventilation. When using do not eat, drink or smoke. Wash hands and face before breaks and immediately after handling of the product. Keep work clothes separately. Take off contaminated clothing. Keep good industrial hygiene.

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7.2.Conditionsforsafestorage,includinganyincompatibilities

Storage

Flammable aerosols. Keep container tightly closed in a cool, well-ventilated place. Do not store near or with any of the incompatible materials listed in section 10. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Ensure that the equipment is adequately grounded.VCI Storage class (LGK): 2B

Packaging materials Do not pierce or burn, even after use. Do not burn, or use a cutting torch on, the empty drum.

7.3Specificenduse(s)No data available

8. Exposurecontrols/personalprotection8.1.Controlparameters

Exposure limit values

dimethyl ether (115-10-6)EU IOELV TWA (mg/m³) 1920 mg/m³EU IOELV TWA (ppm) 1000 ppm

Austria MAK (mg/m³) 1910 mg/m³Austria MAK (ppm) 1000 ppmAustria MAK Short time value (mg/m³) 3820 mg/m³Austria MAK Short time value (ppm) 2000 ppm

Belgium Limit value (mg/m³) 1920 mg/m³Belgium Limit value (ppm) 1000 ppmBulgaria OEL TWA (mg/m³) 1920 mg/m³Bulgaria OEL TWA (ppm) 1000 ppm

Cyprus OEL TWA (mg/m³) 1920 mg/m³Cyprus OEL TWA (ppm) 1000 ppmFrance VME (mg/m³) 1920 mg/m³ (indicative limit)France VME (ppm) 1000 ppm (indicative limit)

Germany TRGS 900 Occupational exposure limit value (mg/m³) 1900 mg/m³Germany TRGS 900 Occupational exposure limit value (ppm) 1000 ppmGibraltar OEL TWA (mg/m³) 1920 mg/m³Gibraltar OEL TWA (ppm) 1000 ppm

Greece OEL TWA (mg/m³) 1920 mg/m³Greece OEL TWA (ppm) 1000 ppm

Italy OEL TWA (mg/m³) 1920 mg/m³Italy OEL TWA (ppm) 1000 ppm

Latvia OEL TWA (mg/m³) 1920 mg/m³Latvia OEL TWA (ppm) 1000 ppmSpain VLA-ED (mg/m³) 1920 mg/m³ (indicative limit value)Spain VLA-ED (ppm) 1000 ppm (indicative limit value)

Switzerland VME (mg/m³) 1910 mg/m³Switzerland VME (ppm) 1000 ppm

Netherlands MAC TGG 8H (mg/m³) 950 mg/m³Netherlands MAC TGG 15MIN (mg/m³) 1500 mg/m³

United Kingdom WEL TWA (mg/m³) 766 mg/m³United Kingdom WEL TWA (ppm) 400 ppmUnited Kingdom WEL STEL (mg/m³) 958 mg/m³United Kingdom WEL STEL (ppm) 500 ppm

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dimethyl ether (115-10-6) dimethyl ether (115-10-6)Czech Republic Expoziční limity (PEL) (mg/m³) 1000 mg/m³

Denmark Grænseværdie (langvarig) (mg/m³) 1920 mg/m³Denmark Grænseværdie (langvarig) (ppm) 1000 ppm

Finland HTP-arvo (8h) (mg/m³) 2000 mg/m³Finland HTP-arvo (8h) (ppm) 1000 ppm

Hungary AK-érték 1920 mg/m³Hungary CK-érték 7680 mg/m³

Ireland OEL (8 hours ref) (mg/m³) 1920 mg/m³Ireland OEL (8 hours ref) (ppm) 1000 ppm

Lithuania IPRV (mg/m³) 1920 mg/m³Lithuania IPRV (ppm) 1000 ppmLithuania TPRV (mg/m³) 2280 mg/m³Lithuania TPRV (ppm) 1500 ppm

Malta OEL TWA (mg/m³) 1920 mg/m³Malta OEL TWA (ppm) 1000 ppm

Norway Gjennomsnittsverdier (AN) (mg/m³) 384 mg/m³Norway Gjennomsnittsverdier (AN) (ppm) 200 ppmNorway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 480 mg/m³Norway Gjennomsnittsverdier (Korttidsverdi) (ppm) 250 ppmPoland NDS (mg/m³) 1000 mg/m³

Romania OEL TWA (mg/m³) 1920 mg/m³Romania OEL TWA (ppm) 1000 ppmSlovakia NPHV (priemerná) (mg/m³) 1920 mg/m³Slovakia NPHV (priemerná) (ppm) 1000 ppmSweden nivågränsvärde (NVG) (mg/m³) 950 mg/m³Sweden nivågränsvärde (NVG) (ppm) 500 ppmSweden kortidsvärde (KTV) (mg/m³) 1500 mg/m³Sweden kortidsvärde (KTV) (ppm) 800 ppm

Xylene (1330-20-7)EU IOELV TWA (mg/m³) 221 mg/m³ (pure)EU IOELV TWA (ppm) 50 ppm (pure)EU IOELV STEL (mg/m³) 442 mg/m³ (pure)EU IOELV STEL (ppm) 100 ppm (pure)

Austria MAK (mg/m³) 221 mg/m³ (all isomers)Austria MAK (ppm) 50 ppm (all isomers)Austria MAK Short time value (mg/m³) 442 mg/m³ (all isomers)Austria MAK Short time value (ppm) 100 ppm (all isomers)

Belgium Limit value (mg/m³) 221 mg/m³Belgium Limit value (ppm) 50 ppmBelgium Short time value (mg/m³) 442 mg/m³Belgium Short time value (ppm) 100 ppmBulgaria OEL TWA (mg/m³) 221,0 mg/m³ (pure)Bulgaria OEL TWA (ppm) 50 ppm (pure)Bulgaria OEL STEL (mg/m³) 442 mg/m³ (pure)Bulgaria OEL STEL (ppm) 100 ppm (pure)

Cyprus OEL TWA (mg/m³) 221 mg/m³Cyprus OEL TWA (ppm) 50 ppmCyprus OEL STEL (mg/m³) 442 mg/m³Cyprus OEL STEL (ppm) 100 ppmFrance VLE (mg/m³) 442 mg/m³ (restrictive limit)France VLE (ppm) 100 ppm (restrictive limit)France VME (mg/m³) 221 mg/m³ (restrictive limit)France VME (ppm) 50 ppm (restrictive limit)

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Xylene (1330-20-7)Germany TRGS 900 Occupational exposure limit value (mg/m³) 440 mg/m³ (all isomers)Germany TRGS 900 Occupational exposure limit value (ppm) 100 ppm (all isomers)Germany TRGS 903 (BGW) 1,5 mg/l (Medium: whole blood - Time: end of

shift - Parameter: Xylene (all isomers) 2000 mg/l (Medium: urine - Time: end of shift - Parameter: Methylhippuric(tolur-)acid (all isomers)

Gibraltar OEL TWA (mg/m³) 221 mg/m³ (pure)Gibraltar OEL TWA (ppm) 50 ppm (pure)Gibraltar OEL STEL (mg/m³) 442 mg/m³ (pure)Gibraltar OEL STEL (ppm) 100 ppm (pure)

Greece OEL TWA (mg/m³) 435 mg/m³Greece OEL TWA (ppm) 100 ppmGreece OEL STEL (mg/m³) 650 mg/m³Greece OEL STEL (ppm) 150 ppm

Italy - Portugal - USA ACGIH ACGIH TWA (ppm) 100 ppmItaly - Portugal - USA ACGIH ACGIH STEL (ppm) 150 ppm

Italy OEL TWA (mg/m³) 221 mg/m³ (pure)Italy OEL TWA (ppm) 50 ppm (pure)Italy OEL STEL (mg/m³) 442 mg/m³ (pure)Italy OEL STEL (ppm) 100 ppm (pure)

Latvia OEL TWA (mg/m³) 221 mg/m³Latvia OEL TWA (ppm) 50 ppmSpain VLA-ED (mg/m³) 221 mg/m³ (indicative limit value)Spain VLA-ED (ppm) 50 ppm (indicative limit value)Spain VLA-EC (mg/m³) 442 mg/m³Spain VLA-EC (ppm) 100 ppm

Switzerland VLE (mg/m³) 870 mg/m³Switzerland VLE (ppm) 200 ppmSwitzerland VME (mg/m³) 435 mg/m³Switzerland VME (ppm) 100 ppm



Czech Republic Expoziční limity (PEL) (mg/m³) 200 mg/m³Denmark Grænseværdie (langvarig) (mg/m³) 109 mg/m³Denmark Grænseværdie (langvarig) (ppm) 25 ppm

Finland HTP-arvo (8h) (mg/m³) 220 mg/m³Finland HTP-arvo (8h) (ppm) 50 ppmFinland HTP-arvo (15 min) 440 mg/m³Finland HTP-arvo (15 min) (ppm) 100 ppm


Ireland OEL (8 hours ref) (mg/m³) 221 mg/m³Ireland OEL (8 hours ref) (ppm) 50 ppmIreland OEL (15 min ref) (mg/m3) 442 mg/m³Ireland OEL (15 min ref) (ppm) 100 ppm


Malta OEL TWA (mg/m³) 221 mg/m³ (pure)Malta OEL TWA (ppm) 50 ppm (pure)

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Xylene (1330-20-7)Malta OEL STEL (mg/m³) 442 mg/m³ (pure)Malta OEL STEL (ppm) 100 ppm (pure)

Norway Gjennomsnittsverdier (AN) (mg/m³) 108 mg/m³Norway Gjennomsnittsverdier (AN) (ppm) 25 ppmNorway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 135 mg/m³Norway Gjennomsnittsverdier (Korttidsverdi) (ppm) 37,5 ppmPoland NDS (mg/m³) 100 mg/m³

Romania OEL TWA (mg/m³) 221 mg/m³Romania OEL TWA (ppm) 50 ppmRomania OEL STEL (mg/m³) 442 mg/m³Romania OEL STEL (ppm) 100 ppmSlovakia NPHV (priemerná) (mg/m³) 221 mg/m³Slovakia NPHV (priemerná) (ppm) 50 ppmSlovakia NPHV (Hraničná) (mg/m³) 442 mg/m³Sweden nivågränsvärde (NVG) (mg/m³) 221 mg/m³Sweden nivågränsvärde (NVG) (ppm) 50 ppmSweden kortidsvärde (KTV) (mg/m³) 442 mg/m³Sweden kortidsvärde (KTV) (ppm) 100 ppm

Toluene (108-88-3)EU IOELV TWA (mg/m³) 192 mg/m³EU IOELV TWA (ppm) 50 ppmEU IOELV STEL (mg/m³) 384 mg/m³EU IOELV STEL (ppm) 100 ppm

Austria MAK (mg/m³) 190 mg/m³Austria MAK (ppm) 50 ppmAustria MAK Short time value (mg/m³) 380 mg/m³Austria MAK Short time value (ppm) 100 ppm

Belgium Limit value (mg/m³) 77 mg/m³Belgium Limit value (ppm) 22 ppmBelgium Short time value (mg/m³) 384 mg/m³Belgium Short time value (ppm) 100 ppmBulgaria OEL TWA (mg/m³) 192,0 mg/m³Bulgaria OEL TWA (ppm) 50 ppmBulgaria OEL STEL (mg/m³) 384,0 mg/m³Bulgaria OEL STEL (ppm) 100 ppm

Cyprus OEL TWA (mg/m³) 192 mg/m³Cyprus OEL TWA (ppm) 50 ppmCyprus OEL STEL (mg/m³) 384 mg/m³Cyprus OEL STEL (ppm) 100 ppmFrance VLE (mg/m³) 384 mg/m³ (restrictive limit)France VLE (ppm) 100 ppm (restrictive limit)France VME (mg/m³) 76,8 mg/m³ (restrictive limit)France VME (ppm) 20 ppm (restrictive limit)

Germany TRGS 900 Occupational exposure limit value (mg/m³)190 mg/m³ (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed)

Germany TRGS 900 Occupational exposure limit value (ppm) 50 ppm (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed)

Germany TRGS 903 (BGW)

600 μg/l (Medium: whole blood - Time: end of shift - Parameter: Toluene) 1,5 mg/l (Medium: urine - Time: end of several shifts - Parameter: o-Cresol (after hydrolysis; for long-term exposures)

Gibraltar OEL TWA (mg/m³) 192 mg/m³

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Toluene (108-88-3)Gibraltar OEL TWA (ppm) 50 ppmGibraltar OEL STEL (mg/m³) 384 mg/m³Gibraltar OEL STEL (ppm) 100 ppm

Greece OEL TWA (mg/m³) 192 mg/m³Greece OEL TWA (ppm) 50 ppmGreece OEL STEL (mg/m³) 384 mg/m³Greece OEL STEL (ppm) 100 ppm

Italy - Portugal - USA ACGIH ACGIH TWA (ppm) 20 ppmItaly OEL TWA (mg/m³) 192 mg/m³Italy OEL TWA (ppm) 50 ppm

Latvia OEL TWA (mg/m³) 50 mg/m³Latvia OEL TWA (ppm) 14 ppm

Spain VLA-ED (mg/m³) 192 mg/m³ (indicative limit value; manufacturing, commercialization, and use restrictions under REACH)

Spain VLA-ED (ppm) 50 ppm (indicative limit value; manufacturing, commercialization, and use restrictions under REACH)

Spain VLA-EC (mg/m³) 384 mg/m³Spain VLA-EC (ppm) 100 ppm

Switzerland VLE (mg/m³) 760 mg/m³Switzerland VLE (ppm) 200 ppmSwitzerland VME (mg/m³) 190 mg/m³Switzerland VME (ppm) 50 ppm



Czech Republic Expoziční limity (PEL) (mg/m³) 200 mg/m³Denmark Grænseværdie (langvarig) (mg/m³) 94 mg/m³Denmark Grænseværdie (langvarig) (ppm) 25 ppm

Finland HTP-arvo (8h) (mg/m³) 81 mg/m³Finland HTP-arvo (8h) (ppm) 25 ppmFinland HTP-arvo (15 min) 380 mg/m³Finland HTP-arvo (15 min) (ppm) 100 ppm


Ireland OEL (8 hours ref) (mg/m³) 192 mg/m³Ireland OEL (8 hours ref) (ppm) 50 ppmIreland OEL (15 min ref) (mg/m3) 384 mg/m³Ireland OEL (15 min ref) (ppm) 100 ppm


Malta OEL TWA (mg/m³) 192 mg/m³Malta OEL TWA (ppm) 50 ppmMalta OEL STEL (mg/m³) 384 mg/m³Malta OEL STEL (ppm) 100 ppm

Norway Gjennomsnittsverdier (AN) (mg/m³) 94 mg/m³Norway Gjennomsnittsverdier (AN) (ppm) 25 ppmNorway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 141 mg/m³Norway Gjennomsnittsverdier (Korttidsverdi) (ppm) 37,5 ppmPoland NDS (mg/m³) 100 mg/m³

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Toluene (108-88-3)Poland NDSCh (mg/m³) 200 mg/m³

Romania OEL TWA (mg/m³) 192 mg/m³Romania OEL TWA (ppm) 50 ppmRomania OEL STEL (mg/m³) 384 mg/m³Romania OEL STEL (ppm) 100 ppmSlovakia NPHV (priemerná) (mg/m³) 192 mg/m³Slovakia NPHV (priemerná) (ppm) 50 ppmSlovakia NPHV (Hraničná) (mg/m³) 384 mg/m³Sweden nivågränsvärde (NVG) (mg/m³) 192 mg/m³Sweden nivågränsvärde (NVG) (ppm) 50 ppmSweden kortidsvärde (KTV) (mg/m³) 384 mg/m³Sweden kortidsvärde (KTV) (ppm) 100 ppm

N-butyl acetate (123-86-4)Austria MAK (mg/m3) 480 mg/m3 (all isomers except tert-Butyl acetate)Austria MAK (ppm) 100 ppm (all isomers except tert-Butyl acetate)Austria MAK Short time value (mg/m3) 480 mg/m3 (all isomers except tert-Butyl acetate)Austria MAK Short time value (ppm) 100 ppm (all isomers except tert-Butyl acetate)

Belgium Limit value (mg/m3) 723 mg/m3Belgium Limit value (ppm) 150 ppmBelgium Short time value (mg/m3) 964 mg/m3Belgium Short time value (ppm) 200 ppmBulgaria OEL TWA (mg/m3) 710 mg/m3Bulgaria OEL STEL (mg/m3) 950 mg/m3

France VLE (mg/m3) 940 mg/m3France VLE (ppm) 200 ppmFrance VME (mg/m3) 710 mg/m3France VME (ppm) 150 ppm

Germany TRGS 900 Occupational exposure limit value (mg/m3)300 mg/m3 (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed)


Greece OEL TWA (mg/m3) 710 mg/m3Greece OEL TWA (ppm) 150 ppmGreece OEL STEL (mg/m3) 950 mg/m3Greece OEL STEL (ppm) 200 ppm

Italy - Portugal - USA - ACGIH ACGIH TWA (ppm) 150 ppmItaly - Portugal - USA - ACGIH ACGIH STEL (ppm) 200 ppm

Latvia OEL TWA (mg/m3) 200 mg/m3Spain VLA-ED (mg/m3) 724 mg/m3Spain VLA-ED (ppm) 150 ppmSpain VLA-EC (mg/m3) 965 mg/m3Spain VLA-EC (ppm) 200 ppm

Switzerland VLE (mg/m3) 960 mg/m3Switzerland VLE (ppm) 200 ppmSwitzerland VME (mg/m3) 480 mg/m3Switzerland VME (ppm) 100 ppm

United Kingdom WEL TWA (mg/m3) 724 mg/m3United Kingdom WEL TWA (ppm) 150 ppmUnited Kingdom WEL STEL (mg/m3) 966 mg/m3United Kingdom WEL STEL (ppm) 200 ppm

Czech Republic Expoziční limity (PEL) (mg/m3) 950 mg/m3

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N-butyl acetate (123-86-4)Denmark Grænseværdie (langvarig) (mg/m3) 710 mg/m3Denmark Grænseværdie (langvarig) (ppm) 150 ppm

Finland HTP-arvo (8h) (mg/m3) 720 mg/m3Finland HTP-arvo (8h) (ppm) 150 ppmFinland HTP-arvo (15 min) 960 mg/m3Finland HTP-arvo (15 min) (ppm) 200 ppm

Hungary AK-érték 950 mg/m3Hungary CK-érték 950 mg/m3

Ireland OEL (8 hours ref) (mg/m3) 710 mg/m3Ireland OEL (8 hours ref) (ppm) 150 ppmIreland OEL (15 min ref) (mg/m3) 950 mg/m3Ireland OEL (15 min ref) (ppm) 200 ppmPoland NDS (mg/m3) 200 mg/m3Poland NDSCh (mg/m3) 950 mg/m3

Romania OEL TWA (mg/m3) 715 mg/m3 (regulated under Butyl acetate)Romania OEL TWA (ppm) 150 ppm (regulated under Butyl acetate)Romania OEL STEL (mg/m3) 950 mg/m3Romania OEL STEL (ppm) 200 ppmSlovakia NPHV (priemerná) (mg/m3) 480 mg/m3Slovakia NPHV (priemerná) (ppm) 100 ppmSlovakia NPHV (Hraničná) (mg/m3) 700 mg/m3Sweden nivågränsvärde (NVG) (mg/m3) 500 mg/m3Sweden nivågränsvärde (NVG) (ppm) 100 ppmSweden kortidsvärde (KTV) (mg/m3) 700 mg/m3Sweden kortidsvärde (KTV) (ppm) 150 ppm

Acetone (67-64-1)EU IOELV TWA (mg/m3) 1210 mg/m3EU IOELV TWA (ppm) 500 ppm

Austria MAK (mg/m3) 1200 mg/m3Austria MAK (ppm) 500 ppmAustria MAK Short time value (mg/m3) 4800 mg/m3Austria MAK Short time value (ppm) 2000 ppm

Belgium Limit value (mg/m3) 1210 mg/m3Belgium Limit value (ppm) 500 ppmBelgium Short time value (mg/m3) 2420 mg/m3Belgium Short time value (ppm) 1000 ppmBulgaria OEL TWA (mg/m3) 600 mg/m3Bulgaria OEL STEL (mg/m3) 1400 mg/m3

Cyprus OEL TWA (mg/m3) 1210 mg/m3Cyprus OEL TWA (ppm) 500 ppmFrance VLE (mg/m3) 2420 mg/m3 (restrictive limit)France VLE (ppm) 1000 ppm (restrictive limit)France VME (mg/m3) 1210 mg/m3 (restrictive limit)France VME (ppm) 500 ppm (restrictive limit)

Germany TRGS 900 Occupational exposure limit value (mg/m3) 1200 mg/m3Germany TRGS 900 Occupational exposure limit value (ppm) 500 ppm

Germany TRGS 903 (BGW) 80 mg/l (Medium: urine - Time: end of shift - Parameter: Acetone)

Gibraltar OEL TWA (mg/m3) 1210 mg/m3Gibraltar OEL TWA (ppm) 500 ppm

Greece OEL TWA (mg/m3) 1780 mg/m3Greece OEL STEL (mg/m3) 3560 mg/m3

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Acetone (67-64-1)Italy - Portugal - USA

ACGIH ACGIH TWA (ppm) 500 ppm

Italy - Portugal - USAACGIH ACGIH STEL (ppm) 750 ppm

Italy OEL TWA (mg/m3) 1210 mg/m3Italy OEL TWA (ppm) 500 ppm

Latvia OEL TWA (mg/m3) 1210 mg/m3Latvia OEL TWA (ppm) 500 ppmSpain VLA-ED (mg/m3) 1210 mg/m3 (indicative limit value)Spain VLA-ED (ppm) 500 ppm (indicative limit value)


Netherlands MAC TGG 8H (mg/m3) 1210 mg/m3Netherlands MAC TGG 15MIN (mg/m3) 2420 mg/m3

United Kingdom WEL TWA (mg/m3) 1210 mg/m3United Kingdom WEL TWA (ppm) 500 ppmUnited Kingdom WEL STEL (mg/m3) 3620 mg/m3United Kingdom WEL STEL (ppm) 1500 ppm

Czech Republic Expoziční limity (PEL) (mg/m3) 800 mg/m3Denmark Grænseværdie (langvarig) (mg/m3) 600 mg/m3Denmark Grænseværdie (langvarig) (ppm) 250 ppm



Ireland OEL (8 hours ref) (mg/m3) 1210 mg/m3Ireland OEL (8 hours ref) (ppm) 500 ppm

Lithuania IPRV (mg/m3) 1210 mg/m3Lithuania IPRV (ppm) 500 ppmLithuania TPRV (mg/m3) 2420 mg/m3Lithuania TPRV (ppm) 1000 ppm

Malta OEL TWA (mg/m3) 1210 mg/m3Malta OEL TWA (ppm) 500 ppm

Norway Gjennomsnittsverdier (AN) (mg/m3) 295 mg/m3Norway Gjennomsnittsverdier (AN) (ppm) 125 ppmNorway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 368,75 mg/m3Norway Gjennomsnittsverdier (Korttidsverdi) (ppm) 156,25 ppmPoland NDS (mg/m3) 600 mg/m3Poland NDSCh (mg/m3) 1800 mg/m3

Romania OEL TWA (mg/m3) 1210 mg/m3Romania OEL TWA (ppm) 500 ppmSlovakia NPHV (priemerná) (mg/m3) 1210 mg/m3Slovakia NPHV (priemerná) (ppm) 500 ppmSlovakia NPHV (Hraničná) (mg/m3) 2420 mg/m3Sweden nivågränsvärde (NVG) (mg/m3) 600 mg/m3Sweden nivågränsvärde (NVG) (ppm) 250 ppmSweden kortidsvärde (KTV) (mg/m3) 1200 mg/m3Sweden kortidsvärde (KTV) (ppm) 500 ppm

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2-methoxy-1-methylethyl acetate (108-65-6)EU IOELV TWA (mg/m3) 275 mg/m3EU IOELV TWA (ppm) 50 ppmEU IOELV STEL (mg/m3) 550 mg/m3EU IOELV STEL (ppm) 100 ppm

Austria MAK (mg/m3) 275 mg/m3Austria MAK (ppm) 50 ppmAustria MAK Short time value (mg/m3) 550 mg/m3Austria MAK Short time value (ppm) 100 ppm

Belgium Limit value (mg/m3) 275 mg/m3Belgium Limit value (ppm) 50 ppmBelgium Short time value (mg/m3) 550 mg/m3Belgium Short time value (ppm) 100 ppmBulgaria OEL TWA (mg/m3) 275,0 mg/m3Bulgaria OEL TWA (ppm) 50 ppmBulgaria OEL STEL (mg/m3) 555,0 mg/m3Bulgaria OEL STEL (ppm) 100 ppm

Cyprus OEL TWA (mg/m3) 275 mg/m3Cyprus OEL TWA (ppm) 50 ppmCyprus OEL STEL (mg/m3) 550 mg/m3Cyprus OEL STEL (ppm) 100 ppmFrance VLE (mg/m3) 550 mg/m3 (restrictive limit)France VLE (ppm) 100 ppm (restrictive limit)France VME (mg/m3) 275 mg/m3 (restrictive limit)France VME (ppm) 50 ppm (restrictive limit)

Germany TRGS 900 Occupational exposure limit value (mg/m3) 270 mg/m3 (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed)


Gibraltar OEL TWA (mg/m3) 275 mg/m3Gibraltar OEL TWA (ppm) 50 ppmGibraltar OEL STEL (mg/m3) 550 mg/m3Gibraltar OEL STEL (ppm) 100 ppm

Greece OEL TWA (mg/m3) 275 mg/m3Greece OEL TWA (ppm) 50 ppmGreece OEL STEL (mg/m3) 550 mg/m3Greece OEL STEL (ppm) 100 ppm

Italy OEL TWA (mg/m3) 275 mg/m3Italy OEL TWA (ppm) 50 ppmItaly OEL STEL (mg/m3) 550 mg/m3Italy OEL STEL (ppm) 100 ppm

Latvia OEL TWA (mg/m3) 275 mg/m3Latvia OEL TWA (ppm) 50 ppmSpain VLA-ED (mg/m3) 275 mg/m3 (indicative limit value)Spain VLA-ED (ppm) 50 ppm (indicative limit value)Spain VLA-EC (mg/m3) 550 mg/m3Spain VLA-EC (ppm) 100 ppm


Netherlands MAC TGG 8H (mg/m3) 550 mg/m3United Kingdom WEL TWA (mg/m3) 274 mg/m3United Kingdom WEL TWA (ppm) 50 ppmUnited Kingdom WEL STEL (mg/m3) 548 mg/m3United Kingdom WEL STEL (ppm) 100 ppm

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2-methoxy-1-methylethyl acetate (108-65-6)Czech Republic Expoziční limity (PEL) (mg/m3) 270 mg/m3

Denmark Grænseværdie (langvarig) (mg/m3) 275 mg/m3Denmark Grænseværdie (langvarig) (ppm) 50 ppm



Ireland OEL (8 hours ref) (mg/m3) 275 mg/m3Ireland OEL (8 hours ref) (ppm) 50 ppmIreland OEL (15 min ref) (mg/m3) 550 mg/m3Ireland OEL (15 min ref) (ppm) 100 ppm

Lithuania IPRV (mg/m3) 250 mg/m3Lithuania IPRV (ppm) 50 ppmLithuania TPRV (mg/m3) 400 mg/m3Lithuania TPRV (ppm) 75 ppm

Malta OEL TWA (mg/m3) 275 mg/m3Malta OEL TWA (ppm) 50 ppmMalta OEL STEL (mg/m3) 550 mg/m3Malta OEL STEL (ppm) 100 ppm

Norway Gjennomsnittsverdier (AN) (mg/m3) 270 mg/m3Norway Gjennomsnittsverdier (AN) (ppm) 50 ppmNorway Gjennomsnittsverdier (Korttidsverdi) (mg/m3) 337,5 mg/m3Norway Gjennomsnittsverdier (Korttidsverdi) (ppm) 75 ppmPoland NDS (mg/m3) 260 mg/m3Poland NDSCh (mg/m3) 520 mg/m3

Romania OEL TWA (mg/m3) 275 mg/m3Romania OEL TWA (ppm) 50 ppmRomania OEL STEL (mg/m3) 550 mg/m3Romania OEL STEL (ppm) 100 ppmSlovakia NPHV (priemerná) (mg/m3) 275 mg/m3Slovakia NPHV (priemerná) (ppm) 50 ppmSlovakia NPHV (Hraničná) (mg/m3) 550 mg/m3Sweden nivågränsvärde (NVG) (mg/m3) 250 mg/m3Sweden nivågränsvärde (NVG) (ppm) 50 ppmSweden kortidsvärde (KTV) (mg/m3) 400 mg/m3Sweden kortidsvärde (KTV) (ppm) 75 ppm

Recommended monitoring procedures: Concentration measurement in air Personal air monitoring

8.2.Exposurecontrols

Personal protection equipment

The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Full face mask (EN 136) (EN136). Half-face mask (DIN EN 140) (EN140). Filter type: AP (EN141).

Hand protection

Wear chemically resistant gloves (tested to EN374). Neoprene rubber (HNBR) / Butyl caoutchouc (butyl rubber) Breakthrough time (maximum wearing time) >8h, Thickness of the glove material >0,3mm. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. The selection of specific gloves for a specific application and time of use in a working area, should also take into account other factors on the working space, such as (but not limited to): other chemicals that are possibly used, physical requirements (protection against cutting/drilling, skill, thermal protection), and the instructions/specification of the supplier of gloves. The exact break through time can be obtained from the protective glove producer and this has to be observed.

Eye protection Wear eye glasses with side protection according to EN 166.

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Body protection Flame retardant antistatic protective clothing

Engineering control measures

Provide adequate ventilation. Use only in area provided with appropriate exhaust ventilation. A washing facility/water for eye and skin cleaning purposes should be present. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Eye wash bottle with pure water. Organisational measures to prevent/limit releases, dispersion and exposure : See also section 7.

Environmental exposure controls

Do not allow to enter into surface water or drains. Comply with applicable Community environmental protection legislation.

9. Physicalandchemicalproperties9.1.Informationonbasicphysicalandchemicalproperties

Appearance AerosolColour VariousOdour Characteristic

Odour threshold Not determinedpH Not determined

Melting point/freezing point Not determinedBoiling point/boiling range -24 °C

Flash point -42 °CEvaporation rate Not applicable

Flammability (solid, gas) Not applicableUpper/lower flammability or

explosive limitsLEL: 1,1 vol % UEL: 18,6 vol %

Vapour pressure 5200 hPa (@ 20°C)Vapour density Not determined

Density 1,028 g/cm³ (@ 20°C)Relative density Not determinedWater solubility Immiscible

Partition coefficient: n-octanol/water not determined

Autoignition temperature 235 °C Ignition temperature in °CDecomposition temperature Not determined

Viscosity Not determined

Explosive propertiesNot applicableThe study does not need to be conducted because there are no chemical groups associated with explosive properties present in the molecule. Vapours can form explosive mixtures with air.

Oxidising propertiesNot applicableThe classification procedure needs not to be applied because there are no chemical groups present in the molecule which are associated with oxidising properties.

9.2.Otherinformation

Volatile organic compounds (VOC) content in percent by weight 61,4 %

Other information Solids content in % : 38,6 %

10. Stabilityandreactivity10.1.Reactivity

Reactivity Extremely flammable. See also section 10.5

10.2.Chemicalstability

Stability The product is stable under storage at normal ambient temperatures.

10.3.Possibilityofhazardousreactions

Possibility of hazardous reactions None under normal processing.

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10.4.Conditionstoavoid

Conditions to avoidKeep away from sources of heat (e.g. hot surfaces), sparks and open flames. Exposure to sunlight. See also section 7. Handling and storage .

10.5.Incompatiblematerials

Incompatible materials Incompatible with strong acids and oxidizing agents. See also section 7: Handling and storage.

10.6.Hazardousdecompositionproducts

Hazardous decomposition products

Burning produces noxious and toxic fumes. Carbon oxides.

11. Toxicologicalinformation

Acute toxicity: Not classified (Based on available data, the classification criteria are not met.)

dimethyl ether (115-10-6)LC50/inhalation/4h/rat 308,5 mg/l/4h

Nickel powder (7440-02-0)LD50/oral/rat > 9000 mg/kg

Xylene (1330-20-7)LD50/oral/rat 4300 mg/kg

LC50/inhalation/4h/rat 47635 mg/l/4hLC50/inhalation/4h/rat (ppm) 6350 ppm (EU B.2)

ATE CLP (dermal) 1100,000 mg/kg bodyweightATE CLP (gases) 4500,000 ppmv/4h

ATE CLP (vapours) 11,000 mg/l/4hATE CLP (dust,mist) 1,500 mg/l/4h

Additional information LD50, acute, oral, mouse: > 5251 mg/kg bw (EU B.1)

Toluene (108-88-3)LD50/oral/rat 636 mg/kg

LD50/dermal/rabbit 8390 mg/kgLC50/inhalation/4h/rat 12,5 mg/l/4h

LC50/inhalation/4h/rat (ppm) > 26700 ppm/1h

ATE CLP (dermal) 12267,000 mg/kg bodyweight

N-butyl acetate (123-86-4)LD50/dermal/rabbit > 17600 mg/kg

LC50/inhalation/4h/rat 23,4 mg/l (OECD 403; In Vivo; Aerosol)LC50/inhalation/4h/rat (ppm) 390 ppm/4h

Acetone (67-64-1)LD50/dermal/rat > 15800 mg/kg

LC50/inhalation/4h/rat 50100 mg/m³ (Exposure time: 8 h)

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2-methoxy-1-methylethyl acetate (108-65-6)LD50/oral/rat 8532 mg/kg

LD50/dermal/rabbit > 5 g/kgATE CLP (oral) 8532 mg/kg bodyweight

Skin corrosion/irritationCauses skin irritation.CAS 1330-20-7, CAS 108-88-3 : Causes skin irritation.pH: not determined

Serious eye damage/eye irritation

Not classified (Based on available data, the classification criteria are not met.)pH: not determined

Respiratory or skin sensitisation

May cause an allergic skin reaction.CAS 7440-02-0 : May cause an allergic skin reaction.

Germ cell mutagenicity Not classified (Based on available data, the classification criteria are not met.)

Carcinogenicity Suspected of causing cancer.CAS 7440-02-0 : Suspected of causing cancer.

Reproductive toxicity Suspected of damaging fertility or the unborn child.CAS 108-88-3 : Suspected of damaging fertility or the unborn child.

STOT-single exposure May cause drowsiness or dizziness.CAS 108-88-3, CAS 123-86-4, CAS 67-64-1 : May cause drowsiness or dizziness.

STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.CAS 7440-02-0 : Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard Not classified (Based on available data, the classification criteria are not met.)

OtherinformationSymptoms related to the physical, chemical and toxicological characteristics: see section 4.2. . 12. Ecologicalinformation12.1.Toxicity

Nickel powder (7440-02-0)LC50 fish 1 > 100 mg/l (Brachydanio rerio)

Xylene (1330-20-7)LC50 fish 1 13,4 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow- through])

EC50 Daphnia 1 3,82 mg/l (Exposure time: 48 h - Species: water flea)LC50 fish 2 2,661 - 4,093 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])

EC50 Daphnia 2 0,6 mg/l (Exposure time: 48 h - Species: Gammarus lacustris)ErC50 (algae) (73h) 4,36 mg/l

NOEC (chronic) > 1,3 mg/l Oncorhynchus mykiss (Rainbow trout)

Additional information IC50, Acute, daphnia: 1 mg/l NOAEC, aquatic invertebrates, Ceriodaphnia Dubia (water flea): 0.96 mg/l

Toluene (108-88-3)LC50 fish 1 15,22 - 19,05 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])

EC50 Daphnia 1 5,46 - 9,83 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])LC50 fish 2 12,6 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])

EC50 Daphnia 2 11,5 mg/l (Exposure time: 48 h - Species: Daphnia magna)EC50 other aquatic

organisms 212,5 mg/l (Exposure time: 72 h - Species: Pseudokirchneriella subcapitata [static])

N-butyl acetate (123-86-4)LC50 fish 1 100 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])LC50 fish 2 17 - 19 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow- through])

Toxicity Harmful to aquatic life with long lasting effects. Information given is based on data on the components and the ecotoxicology of similar products.

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Acetone (67-64-1)LC50 fish 1 4,74 - 6,33 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)

EC50 Daphnia 1 10294 - 17704 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])LC50 fish 2 6210 - 8120 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])

EC50 Daphnia 2 12600 - 12700 mg/l (Exposure time: 48 h - Species: Daphnia magna)

2-methoxy-1-methylethyl acetate (108-65-6)LC50 fish 1 161 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])

EC50 Daphnia 1 > 500 mg/l (Exposure time: 48 h - Species: Daphnia magna)

12.2.Persistenceanddegradability

Persistence and degradability No data available

12.3.Bioaccumulativepotential

Bioaccumulation No data availablePartition coefficient:

n-octanol/water Not determined

12.4.Mobilityinsoil

Mobility No data available

12.5.ResultsofPBTandvPvBassessment

PBT/vPvB data This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

12.6.Otheradverseeffects

Other information No information available

13. Disposalconsiderations13.1.Wastetreatmentmethods

Waste from residues / unused products

Handle with care. Safe handling: see section 7 : Handling and storage . Do not allow to enter into surface water or drains. Dispose according to legislation. Refer to manufacturer/supplier for information on recovery/recycling. Collect and dispose of waste product at an authorised disposal facility.

Contaminated packagingDo not burn, or use a cutting torch on, the empty drum. Do not puncture or incinerate. Delivery to an approved waste disposal company.

List of proposed waste codes/waste designations in

accordance with EWC

Classified as hazardous waste according to European Union regulations. The following Waste Codes are only suggestions: 160504 - gases in pressure containers (including halons) containing dangerous substances. Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

14. Transportinformation14.1.UNnumber

UN-No. 1950

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14.2.UNpropershippingname

Proper Shipping Name AEROSOLSProper shipping name IATA/IMDG AEROSOLS flammable

14.3.Transporthazardclass(es) 14.3.1.Overlandtransport

Class(es) 2 - GasesClassification code 5F

ADR/RID-Labels 2.1 - Flammable gases

14.3.2.Inlandwaterwaytransport(ADN)

Class (UN) 2

14.3.3.Transportbysea

Class or Division 2.1 - Flammable gases

14.3.4.Airtransport

Class or Division 2.1 - Flammable gases

14.4.Packinggroup

Packing group -

14.5.Environmentalhazards

Other information No supplementary information available.

14.6SpecialprecautionsforuserNo data available

14.7TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCodeNo data available

15. Regulatoryinformation15.1.Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

15.1.1.EU-RegulationsThe following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006 :

3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out inAnnex I to Regulation (EC) No 1272/2008 : Conductive coating 3801

3.a. Hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F : 2-methoxy-1-methylethyl acetate

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27. Nickel : Nickel powder

40. Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. : Conductive coating 3801

48. Toluene : TolueneThis product contains an ingredient according to the candidate list of Annex XIV of the REACH Regulation 1907/2006/EC. : noneAuthorisations : not applicableVolatile organic compounds (VOC) content in percent by weight : 61,4 %Comply with below indicated regulations, relevant updatings and amendments, as applicable: 75/324/EEC.

15.1.2.Nationalregulations

DE WGK 2DE German storage class (LGK) LGK 2B - AerosolsDE Technische Regeln für Gefahrstoffe (TRGS) applicableDE Risk classification according to VbF A I - Liquids with a flashpoint below 21°CFR Installations classées 141x 143x

NL ABM 8 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. (A)

NL NeR (Nederlandse emissie Richtlijn) Organic substances in vapour or gaseous form

NO Produktforskriften (FOR 2004-06-01 nr 922) Paragraph 2-30.

15.2.ChemicalsafetyassessmentChemical Safety Assessment: No chemical safety assessment has been carried out

16. Otherinformation

Full text of R-, H- and EUH-phrases:Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4Aerosol 1 Aerosol, Category 1Aquatic Chronic 3 Hazardous to the aquatic environment - chronic hazard category 3Asp. Tox. 1 Aspiration hazard, Category 1Carc. 2 Carcinogenicity, Category 2Eye Irrit. 2 Serious eye damage/eye irritation Category 2Flam. Gas 1 Flammable gases, hazard category 1Flam. Liq. 2 Flammable liquids, Category 2Flam. Liq. 3 Flammable liquids, Category 3Press. Gas Gases under pressureRepr. 2 Reproductive toxicity, Hazard Category 2Repr. 2 Reproductive toxicity, Hazard Category 2Skin Irrit. 2 Skin corrosion/irritation, Category 2Skin Sens. 1 Skin sensitisation, hazard category 1STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, NarcosisH220 Extremely flammable gas.H222 Extremely flammable aerosol.H225 Highly flammable liquid and vapour.

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Full text of R-, H- and EUH-phrases:H226 Flammable liquid and vapour.H229 Pressurised container. May burst if heated.H304 May be fatal if swallowed and enters airways.H312 Harmful in contact with skin.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H332 Harmful if inhaled.H336 May cause drowsiness or dizziness.H351 Suspected of causing cancer.H361 Suspected of damaging fertility or the unborn child.H361d Suspected of damaging the unborn child.H372 Causes damage to organs through prolonged or repeated exposure.H373 May cause damage to organs through prolonged or repeated exposure.H412 Harmful to aquatic life with long lasting effects.R10 Flammable.R11 Highly flammable.R12 Extremely flammable.R20/21 Harmful by inhalation and in contact with skin.R36 Irritating to eyes.R38 Irritating to skin.R40 Limited evidence of a carcinogenic effect.R43 May cause sensitisation by skin contact.R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R63 Possible risk of harm to the unborn child.R65 Harmful: may cause lung damage if swallowed.R66 Repeated exposure may cause skin dryness or cracking.R67 Vapours may cause drowsiness and dizziness.F Highly flammableF+ Extremely flammableT ToxicXi IrritantXn Harmful

Key literature references and sources for data:European Chemicals Bureau (http://esis.jrc.ec.europa.eu) SDS from supplier '3801 Conductive Nickel Coating'

Other information Abbreviations and acronyms:Calculation method,CLP Article 9

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Abbreviationsandacronyms

ADN Accord Européen relatif au Transport International des Marchandises Dangereuses par voie de Navigation du RhinADR Accord européen relatif au transport international des marchandises Dangereuses par RouteCLP Classification, Labelling and Packaging Regulation according to 1272/2008/EC IATA International Air Transport AssociationIMDG International Maritime Dangerous Goods CodeLEL Lower Explosive Limit/Lower Explosion LimitUEL Upper Explosion Limit/Upper Explosive LimitREACH Registration, Evaluation, Authorisation and Restriction of ChemicalsEC50 Median Effective ConcentrationLC50 Median lethal concentrationLD50 Median lethal doseTLV Threshold limitsTWA time weighted averageSTEL Short term exposure limit

persistent, bioaccumulating and toxic (PBT).vPvB very persistent and very bioaccumulatingWGK Wassergefährdungsklasse (Water Hazard Class under German Federal Water Management Act)

3800 - Conductive Nickel Coating · 3800 - Conductive Nickel Coating ... Vapours can form explosive...

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