33 Sodium Hypochlorite and Chlorine Gas

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    Sodium Hypochlorite andSodium Hypochlorite andChlorine Gas:Chlorine Gas:

    Design, Handling, and StorageDesign, Handling, and StorageIssuesIssues

    Presented By:Presented By:

    Water Treatment Practices CommitteeWater Treatment Practices CommitteeAWWA Michigan SectionAWWA Michigan SectionSpringSpring RegionalsRegionals -- 20062006

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    OverviewOverview Individual Look at Both ChemicalsIndividual Look at Both Chemicals

    Chemical PropertiesChemical Properties

    Materials for HandlingMaterials for Handling StorageStorage

    CostCost

    SafetySafety

    Some ComparisonsSome Comparisons

    Safety is Important, but Not the MainSafety is Important, but Not the MainFocus of This PresentationFocus of This Presentation

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    ChlorineChlorine -- Beneficial UsesBeneficial Uses

    Automot iveAutomot ivenn Foam SeatingFoam Seatingnn PaintsPaintsnn Plastic BumpersPlastic Bumpers

    MoldingMoldingInstrumentsInstruments

    nn Floor MatsFloor Matsnn FabricFabricnn Seat BeltsSeat Beltsnn Tire CordsTire Cordsnn DashboardsDashboards

    nn HosesHoses

    ConstructionConstructionnn CarpetingCarpetingnn UpholsteryUpholsterynn Wire InsulationWire Insulationnn PipesPipesnn SidingSidingnn FlooringFlooringnn PaintsPaintsnn CoatingsCoatings

    DefenseDefensenn BulletBullet--Proof VestsProof Vestsnn HelmetsHelmetsnn ParachutesParachutesnn Water Repellant FibersWater Repellant Fibersnn ShatterShatter--Resistant GlassResistant Glassnn Titanium AircraftTitanium Aircraftnn Jet EnginesJet Enginesnn MissilesMissiles

    ElectronicsElectronicsnn SemiconductorsSemiconductorsnn Computer DisksComputer Disksnn Wire InsulationWire Insulation

    Food Producti on &Food Producti on &HandlingHandling

    nn HerbicidesHerbicidesnn Vitamins B1 & B6Vitamins B1 & B6

    nn CleanersCleanersnn DisinfectantsDisinfectantsnn Thermal InsulationThermal Insulationnn Sterile PackagingSterile Packaging

    Health CareHealth Carenn ElectronicElectronic

    InstrumentsInstrumentsnn Sterile PackagingSterile Packagingnn Surgical EquipmentSurgical Equipmentnn Cleaning CompoundsCleaning Compoundsnn Prescription EyePrescription Eye

    WearWearnn Laboratory ReagentsLaboratory Reagentsnn AntibioticsAntibiotics

    Pulp and PaperPulp and Paper

    MedicinesMedicinesnn Cancer TreatmentCancer Treatmentnn Pain RelieversPain Relieversnn Local AnestheticsLocal Anestheticsnn AntihistaminesAntihistaminesnn DecongestantsDecongestants

    Metal ProductionMetal Productionnn MagnesiumMagnesium

    nn NickelNickelnn BismuthBismuthnn TitaniumTitaniumnn ZirconiumZirconiumnn ZincZinc

    OutdoorOutdoorRecreationRecreation

    nn Neoprene Wet SuitsNeoprene Wet Suitsnn Inflatable RaftsInflatable Raftsnn Golf GripGolf Gripnn Surf BoardsSurf Boardsnn Nylon RopesNylon Ropesnn TentsTentsnn Sleeping BagsSleeping Bagsnn CoatsCoatsnn BackpacksBackpacksnn Waterproof ClothingWaterproof Clothing

    Water TreatmentWater Treatmentnn Safe Drinking WaterSafe Drinking Water

    nn WastewaterWastewaterTreatmentTreatment

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    Chlorine = DisinfectionChlorine = DisinfectionPrimary use of Chlorine is for thePrimary use of Chlorine is for theManufacture of PlasticsManufacture of Plastics

    But, in the U.S. Water Industry,But, in the U.S. Water Industry,

    Chlorine isChlorine is thethe Primary DisinfectantPrimary Disinfectant

    Common Forms Used in WaterCommon Forms Used in WaterTreatment are Chlorine Gas and LiquidTreatment are Chlorine Gas and LiquidSodium Hypochlorite (Bleach)Sodium Hypochlorite (Bleach)

    XX

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    Disinfection & FiltrationDisinfection & Filtration

    DisinfectionDisinfectionnn Essential part of waterEssential part of water

    treatmenttreatment

    nn CryptoCrypto resists traditionalresists traditionaldisinfectantsdisinfectants

    FiltrationFiltrationnn Most surface water systems filterMost surface water systems filter

    nn Physical process can removePhysical process can remove CryptoCrypto

    nn Disinfection still necessaryDisinfection still necessary

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    Chlorine/Sodium HypochloriteChlorine/Sodium Hypochlorite

    Use in MichiganUse in Michigan

    nn Approximately 540 Public WaterApproximately 540 Public Water

    Systems Add Chlor ineSystems Add Chlor ine

    nn 90 Use Chlor ine Gas90 Use Chlor ine Gas

    nn 450 Use Sodium Hypochlor it e450 Use Sodium Hypochlor it e

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    Chlorine GasChlorine Gas

    MSDS FactsMSDS Facts Chem ical Formula: ClChemical Formula: Cl 22 Boiling Point :Boiling Point : -- 29.429.4FF Freezing Poin t :Freezing Poin t : -- 150F150F

    Appearance:Appearance:Gas is Greenish in ColorGas is Greenish in ColorHas St rong, Pungent OdorHas St rong, Pungent Odor

    Dry Cl Dry Cl22 is nonis non-- corrosivecorrosive Wet is highly corrosive t o metals Wet is highly corrosive t o metals

    (Wet Cl(Wet Cl22 has > 150has > 150 ppmppm water)water) Chlorine + Water = ACI DChlorine + Wat er = ACI D

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    More Chlorine Gas MSDSMore Chlorine Gas MSDS Heavier than airHeavier t han air

    Specif ic Volume: 1 lb = 4.99 cubic ftSpecif ic Volume: 1 lb = 4.99 cubic ft

    (150 lb cylinder can fi l l a 10 ft x 10 ft x 7.5 ft(150 lb cylinder can fi l l a 10 ft x 10 ft x 7.5 ftroom w ith 100% Cl2 gas, displacing all theroom w it h 100% Cl2 gas, displacing all the

    air)air)

    pH: AcidicpH: Acidic

    Non Combust ible, but Suppor t sNon Combust ible, but Suppor t s

    CombustionCombustion React s Violent ly w it h Many ChemicalsReact s Violent ly w it h Many Chemicals

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    More Chlorine Gas MSDSMore Chlorine Gas MSDSACUTE HEALTH EFFECTS: CHLORINE IS A POTENT IRRITANT TO THE MUCOUSMEMBRANES OF THE EYES, NOSE AND THROAT, AND TO THE LININGS OF THEENTIRE RESPIRATORY TRACT. THE EXTENT OF INJURY DEPENDS UPONCONCENTRATION AND DURATION OF EXPOSURE. DEATH MAY OCCUR UNDERSEVERE EXPOSURE. IN HIGH CONCENTRATIONS, CHLORINE MAY CAUSE SKINIRRITATION, WITH SENSATIONS OF BURNING AND PRICKLING, INFLAMMATION

    AND BLISTER FORMATION. LIQUID CHLORINE MAY CAUSE SERIOUS DIRECT AND

    EYE BURNS ON CONTACT.

    CHRONIC HEALTH EFFECTS: CHRONIC EXPOSURE TO CHLORINE GAS CAN CAUSECORROSION OF THE TEETH, DISEASES OF THE LUNG, AND MAY PREDISPOSE THEINDIVIDUAL TO LUNG INFECTIONS, INCLUDING TUBERCULOSIS.

    INHALATION: MAY CAUSE SEVERE IRRITATION TO THE RESPIRATORY TRACTFOLLOWED BY COUGHING, BURNING, CHEST PAIN, VOMITING, HEADACHE,

    ANXIETY AND FEELING OF SUFFOCATION. SEVERE EXPOSURE MAY CAUSEPNEUMONITIS AND PULMONARY EDEMA. REPEATED EXPOSURE TO CHLORINE MAYRESULT IN REDUCED PULMONARY CAPACITY AND DENTAL EROSION.

    DIRECT CONTACT: MAY CAUSE BURNS, BLISTERING AND TISSUE DESTRUCTION

    EYE CONTACT: LIQUID AND OR HIGH CONCENTRATIONS OF CHLORINE GAS INCONTACT WITH THE EYES WILL CAUSE EXTREME IRRITATION AND OR BURNS

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    Chlorine Feed SystemChlorine Feed System

    Key Design ConsiderationsKey Design Considerationsnn Cur rent General Design Pract ice is t oCur rent General Design Pract ice is t o

    Have Gas Under Vacuum to Carr ierHave Gas Under Vacuum to Carr ierWater St reamWater St ream

    nn Carr ier Water Flow ThroughCarr ier Water Flow Through EductorEductor ,,Opens Vacuum Regulator Allow ing GasOpens Vacuum Regulator Allow ing GasFlowFlow

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    Chlorine Feed SystemChlorine Feed System

    Key Design ConsiderationsKey Design Considerationsnn Some Large I nstallat ions Use PressureSome Large I nstallat ions Use Pressure

    ManifoldsManifolds

    nn Some Very Large I nstallat ions UseSome Very Large I nstallat ions UseLiqu id Chlor ine Evaporators for HighLiquid Chlorine Evaporat ors for HighWit hdraw al Requirements (1,000s ofWit hdraw al Requirements (1,000s oflbs/ day)lbs/ day)

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    Gas Chlorine Feed Schematic

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    Gas Chlorine Feed SystemGas Chlorine Feed System

    Key Design ConsiderationsKey Design Considerations

    nn May Need Booster Pumping for ProperMay Need Booster Pumping for Proper

    I nj ect ion PressureI nj ect ion Pressure

    nn Gas Wit hdraw al Rate fr om Cylinder isGas Wit hdraw al Rate fr om Cylinder isLim it ed at Standard Temp., Pres.Lim it ed at Standard Temp., Pres.nn

    70 lbs/ 24 hrs for 150 lb cylinders70 lbs/ 24 hrs for 150 lb cylindersnn 560 lbs/ 24 hrs for t on cylinders560 lbs/ 24 hrs for t on cylinders

    nn Any Fast er and Freezing Wi ll OccurAny Faster and Freezing Wil l Occur

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    Gas Chlorine Feed SystemGas Chlorine Feed System

    Key Design ConsiderationsKey Design Considerations

    nn Schedule 80 PVC Piping is Good ChoiceSchedule 80 PVC Piping is Good Choice

    for Chlor ine Solut ion ( Solvent Welded)for Chlor ine Solut ion ( Solvent Welded)

    nn Other Compat ible MaterialsOther Compatible Materialsnn PVDFPVDF -- PolyvinylidenePolyvinylidene FluorideFluoride

    nn PTFEPTFE -- PolytetrafluoroethylenePolytetrafluoroethylene (Teflon)(Teflon)

    nn CPVCCPVC -- Chlorinated PolyvinylchlorideChlorinated Polyvinylchloride

    nn Titanium ( for component hardware)Titanium ( for component hardware)nn 316L Stainless Steel316L Stainless Steel

    nn Piping I dent if icat ion:Piping I dent if icat ion:

    nn ColorColor -- YellowYellow

    nn LabelsLabels

    nn Flow Arrow sFlow Arrow s

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    Gas Chlorine Feed SystemGas Chlorine Feed System

    Key Design ConsiderationsKey Design Considerations

    nn Ent rance t o Chlor ine Room FromEnt rance t o Chlor ine Room FromExt erior OnlyExt erior Only

    nn View ing Window to Room Required inView ing Window to Room Required inI nt erior SpaceI nt erior Spacenn Gas detector and scale readout sGas detector and scale readouts

    nn HVACHVACnn I nt ake Duct Near Floor ( Gas is Heavier t hanI nt ake Duct Near Floor (Gas is Heavier t han

    Air)Air)

    nn Exhaust Discharge AWAY From Ent ranceExhaust Discharge AWAY From Ent rance

    nn Chlor ine Gas Monit oring RequiredChlor ine Gas Monit oring Required

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    Chlorine Gas RegulatoryChlorine Gas Regulatory

    ConsiderationsConsiderations

    nn Clean Air Act Sect ion 112( r) :Clean Air Act Sect ion 112( r) :Prevent ion of Accident al ReleasesPrevent ion of Accidental Releasesnn Over 2,500 lb Threshold Quant it y RequiresOver 2,500 lb Threshold Quanti t y Requires

    a Risk Managem ent Plan ( RMP)a Risk Management Plan ( RMP)

    nn SARA Tit le I I I (Emergency PlanningSARA Tit le I I I (Emergency Planningand Comm unit y Rightand Comm unit y Right -- toto--Know Act )Know Act )

    nn Threshold Planning Quant it y: 100 lbsThreshold Planning Quant it y: 100 lbs

    nn Not ify State Emergency ResponseNot if y State Emergency ResponseComm ission and Local Emergency PlanningComm ission and Local Emergency Planning

    CommitteeCommittee

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    Gas Chlorine Accident PreventionGas Chlorine Accident Prevention

    nn ContainmentContainmentnn Available for Ton CylindersAvailable for Ton Cylinders

    and 150 lb Cylindersand 150 lb Cylindersnn Aut omati c Cylinder Shut OffAut omati c Cylinder Shut Off

    ValvesValves

    nn ScrubbersScrubbers

    nn Wet TypeWet Typenn Dry TypeDry Type

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    Gas Chlorine Feed SystemGas Chlorine Feed System

    Storage ConsiderationsStorage Considerations

    nn Keep Cyl inders CoolKeep Cyl inders Coolnn Pressure Relief Plugs Melt at 158Pressure Relief Plugs Melt at 158FF

    nn Store Above Ground in Dry AreaStore Above Ground in Dry Area

    nn Secure Cylinders f rom MovementSecure Cyl inders f rom Movement

    nn Act ive Cylinders on Scale to Monit orAct ive Cylinders on Scale to Monit orUseUse

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    Sodium HypochloriteSodium Hypochlorite

    MSDS FactsMSDS Facts Chemical Formula:Chemical Formula: NaOClNaOCl

    Commercially Available:Commercially Available:

    Typically 10%Typically 10% -- 15% by Wt .15% by Wt . Often Referred to as Bleach , butOft en Referred to as Bleach , but

    is Much St ronger t han theis Much St ronger t han theHousehold VarietyHousehold Variety

    pH = 11pH = 11 1313

    Freezing Poin t :Freezing Point : -- 11F @ 12.5%11F @ 12.5%

    Boil ing Poin t : > 212F @ 12.5%Boil ing Point : > 212F @ 12.5%

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    More Sodium Hypochlorite MSDSMore Sodium Hypochlorite MSDS

    Specific Gravit y: 1.2Specific Gravit y: 1.2

    Bulk Density: 9.8 lb/ galBulk Density: 9.8 lb/ gal

    Solubil it y in Water: CompleteSolubili t y in Water: Complete Appearance:Appearance:

    Yellow Colored LiquidYellow Colored Liquid

    Chlor ine OdorChlor ine Odor

    CorrosiveCorrosive

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    More Sodium Hypochlorite MSDSMore Sodium Hypochlorite MSDS

    Health Hazards Acute & Chronic:SKIN:MAY CAUSE SEVERE IRRITATION &/OR BURNS. PROLONGED EXPOSURE MAYCAUSE DESTRUCTION OF THE DERMIS W/ IMPAIRMENT OF THE SKIN. BURNS MAYNOT BE IMMEDIATELY APPARENT. EYES:SEVERE IRRITATION &/OR BURNS CANOCCUR. CONTACT MAY CAUSE IMPAIRMENTOF VISION & CORNEAL DAMAGE.

    INHALATION:IRRITATING TO NOSE, MOUTH, THROAT, & LUNGS. MAY CAUSEBURNS TO THE RESP. TRACT W/ THE PRODUCTION OF LUNG EDEMA. INHALATIONOF HIGH CONC. OF MIST CAN RESULT IN PERM. LUNG DAMAGE.INGESTION:IRRITATION &/OR BURNS CAN OCCUR TO THE ENTIREGASTROINTESTINAL TRACT. CHRONIC: MAY CAUSE LUNG DAMAGE, TISSUEDESTRUCTION, & EYE BURNS. MAY ACT AS A SENSITIZER.

    Signs & Symptoms of Overexposure:

    SKIN: REDNESS, SWELLING AND SCAB FORMATION. EYES: SEVERE IRRITATION.INHALATION: SHORTNESS OF BREATH, WHEEZING, CHOKING, CHEST PAIN.INGESTION:NAUSEA, VOMITING, DIARRHEA, ABDOMINAL PAIN, BLEEDING AND/ORTISSUE ULCERATION.

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    Sodium Hypochlorite Feed SchematicBulk System

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    Sodium Hypochlorite Feed Schematic

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    NaOClNaOCl Feed SystemFeed System

    Key Design ConsiderationsKey Design Considerations

    nn Perist alt ic Pum ps are a GoodPerist alt ic Pum ps are a GoodChoice for Pumping SodiumChoice for Pum ping Sodium

    HypochloriteHypochlorite

    nn Smooth Delivery of ChemicalSmooth Delivery of Chemical

    nn No Wet ted Part sNo Wet ted Part s

    nn Less Concern w it hLess Concern w it h OffgasingOffgasing

    nn Need t o Change Tubing Frequent ly t oNeed t o Change Tubing Frequent ly t oAssure Consistent Chemical DeliveryAssure Consistent Chemical Delivery

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    NaOClNaOCl Feed SystemFeed System

    Key Design ConsiderationsKey Design Considerations

    nn Motor Driven or Solenoid DrivenMotor Driven or Solenoid DrivenDiaphragm PumpsDiaphragm Pumpsnn

    Common, ProvenCommon, Provennn Need Pulsat ion DampeningNeed Pulsation Dampening

    nn May be More Concern w it hMay be More Concern w it hOffgasingOffgasing

    nn 44--Way Funct ion ValvesWay Funct ion Valves

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    NaOClNaOCl Feed SystemFeed System

    Key Design ConsiderationsKey Design Considerations

    nn Storage Tank Material:Storage Tank Mat erial:

    nn Fiberglass Reinforced Plast icFiberglass Reinforced Plast ic

    (FRP)(FRP)nn CrossCross-- Linked PolyethyleneLinked Polyethylene

    nn Limit ed in Design Flexibilit yLim it ed in Design Flexibilit y

    nn Bulk Tanks (FRP) :Bulk Tanks (FRP) :nn Properl y Sized Vent for Truck UnloadingProperl y Sized Vent for Truck Unloading

    nn SideSide ManwayManway or No Sideor No Side ManwayManway??nn Slope Bot tom f or Posit ive Drainage forSlope Bot tom f or Posit ive Drainage for

    CleaningCleaning

    nn Load Cells or Level Measurement t oLoad Cells or Level Measurement t oTrack Usage and I nventoryTrack Usage and I nventory

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    NaOClNaOCl Feed SystemFeed System

    Key Design ConsiderationsKey Design Considerations

    nn Schedule 80 PVC is Good Choice forSchedule 80 PVC is Good Choice for

    Piping and ValvesPiping and Valves

    nn Diaphragm Valves are Recommended;Diaphragm Valves are Recommended;True Union PVC Ball Valves are a Low erTrue Union PVC Ball Valves are a Low erCost Alt ernat iveCost Alt ernat ive

    nn Piping I dent if icat ion:Piping I dent if icat ion:

    nn ColorColor -- YellowYellow

    nn LabelsLabels

    nn Flow Arrow sFlow Arrow s

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    NaOClNaOCl Feed SystemFeed System

    Key Design ConsiderationsKey Design Considerations

    nn Secondary Cont ainmentSecondary Cont ainm ent -- 100% of100% of

    Largest Cont ainer Stored in AreaLargest Cont ainer Stored in Areann (6,000 gal tank = 16 ft x 16 ft x 3 ft )(6,000 gal tank = 16 ft x 16 ft x 3 ft )

    nn 330 gal . tote = (10 f t x 10 f t x f t)330 gal . tote = (10 f t x 10 f t x f t)

    nn 55 gal . drum = (4 f t x 4 f t x f t )55 gal . drum = (4 f t x 4 f t x f t )

    nn

    Consider Need for SecondaryConsider Need for SecondaryContainment for Out door ChemicalCont ainment f or Out door ChemicalUnloading AreasUnloading Areas

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    NaOClNaOCl Feed SystemFeed System

    Key Design ConsiderationsKey Design Considerations

    nn Storage Volume: 30 Days PlusStorage Volume: 30 Days PlusDelivery I s Comm onDelivery I s Comm on

    nn Product Degradat ion:Product Degradat ion:nn 12.5%12.5% NaOClNaOCl May Degrade To 10% I nMay Degrade To 10% I n

    6 t o 8 Weeks, Then Degradation Rate6 t o 8 Weeks, Then Degradation RateSlowsSlows

    nn Can Dilut e Product Upon Delivery ToCan Dilute Product Upon Delivery ToLess Than 10% I f Adequate StorageLess Than 10% I f Adequate StorageAvailable; Adj ust pH To 11Available; Adjust pH To 11 -- 1313

    nn Store Chemical in a Cool , DarkStore Chem ical in a Cool, DarkArea to Minim ize Degradat ionArea to Minimize Degradat ion

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    Other ConsiderationsOther Considerations

    nn Want t o Get Fresh ChemicalWant t o Get Fresh ChemicalFrom Suppl iers to Maximize ShelfFrom Suppliers t o Maxim ize ShelfLifeLife

    nn AWWA has a Specif icat ion forAWWA has a Specif icat ion forNaOClNaOCl

    nn Need To Consider Chem icalNeed To Consider Chem icalSt rengt h When Set t ing DoseSt rengt h When Sett ing Dose

    nn Laboratory Test ing Procedures AndLaboratory Test ing Procedures AndTest Kit s (HACH) Avai lable ToTest Kit s (HACH) Available ToVerif y And Moni t or ChemicalVerif y And Moni t or ChemicalStrengthStrength

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    Other ConsiderationsOther Considerations

    nn HACH Test Kit : Hypochlor it e,HACH Test Kit : Hypochlor it e,Model CNModel CN--HRDT, 100 Tests,HRDT, 100 Tests,

    Digit al Tit rat ionDigit al Tit rat ionnn Good for 5% to 15% solutionGood for 5% t o 15% solution

    nn Test Kit : $181 for 100 t estsTest Kit : $181 for 100 t ests

    nn DigitalDigital TitratorTitrator : $112 one t ime: $112 one t imepurchasepurchase

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    Maintenance ConsiderationsMaintenance Considerations

    nn Common Problem w it hComm on Problem w it h NaOClNaOClSystems isSystems is OffgasingOffgasing

    nn Vinegar Soak t o Clean Assembl iesVinegar Soak t o Clean Assembl ies

    nn May need soft ened Water forMay need soft ened Water forCarr ier Water t o Avoid ScalingCarr ier Water t o Avoid Scaling

    nn Can also Add Phosphat e t o PreventCan also Add Phosphat e t o PreventScalingScaling

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    Bulk Chemical DeliveryBulk Chemical Delivery

    nn Make Sure Fil l NozzlesMake Sure Fil l Nozzlesare Clearly I denti fiedare Clearly I denti fied

    nn Bulk lines need t o beBulk lines need t o belocked or ot herw iselocked or ot herw ise

    securedsecurednn Shut off Valve Dow nShut off Valve Dow n

    St ream of t he FillSt ream of t he FillPointPoint

    nn An Operat or ShouldAn Operat or Should

    Be Present WheneverBe Present Whenevera Tanker isa Tanker isDownloadingDownloading

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    Gas Chlorine CostsGas Chlorine Costs

    1 Ton Cylinder1 Ton Cylinder $0.36/lb Cl$0.36/lb Cl22

    150 lb Cylinder150 lb Cylinder $1.01/lb Cl$1.01/lb Cl22

    Notes:Notes:

    Includes freightIncludes freightPrices are for 2Prices are for 2 5 cylinders5 cylinders

    The more you buy, the less per lbThe more you buy, the less per lb

    Prices do not including cylinder depositPrices do not including cylinder deposit

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    Sodium Hypochlorite CostsSodium Hypochlorite Costs

    BulkBulk $0.70/gal$0.70/gal(+ freight)(+ freight)

    330 gal totes,330 gal totes,55 gal drums55 gal drums $1.40/gal$1.40/gal

    Notes:Notes:Bulk = >1,000 gallonsBulk = >1,000 gallonsFreight typically varies from $500 to $1,500Freight typically varies from $500 to $1,500

    The more you buy, the lower the cost per gallonThe more you buy, the lower the cost per gallon

    1 gal 12.5%1 gal 12.5% NaOClNaOCl solution containssolution contains 1 lb Chlorine 1 lb Chlorine

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    Cost ComparisonCost Comparison

    Cost to feed 1 mg/L to 1 million gallons:Cost to feed 1 mg/L to 1 million gallons:

    1 mg/L x 1 MG x 8.34 =1 mg/L x 1 MG x 8.34 = 8.348.34 lb/MGlb/MG

    12.5%12.5% NaOClNaOCl:: = 8.34 gal @ $0.85/gal (w/freight)= 8.34 gal @ $0.85/gal (w/freight)(bulk)(bulk) == $ 7.09/MG$ 7.09/MG

    12.5%12.5% NaOClNaOCl:: = 8.34 gal @ $1.40/gal (w/freight)= 8.34 gal @ $1.40/gal (w/freight)(drums)(drums) == $ 11.68/MG$ 11.68/MG

    Gas ClGas Cl22 = 8.34 lb @ $0.36/lb= 8.34 lb @ $0.36/lb(ton(ton cylcyl.).) == $ 3.00/MG$ 3.00/MG

    Gas ClGas Cl22 = 8.34 lb @ $1.01/lb= 8.34 lb @ $1.01/lb(150#(150# cylcyl.).) == $ 8.42/MG$ 8.42/MG

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    SummarySummary

    nn Gas Chlor ine And Sodium Hypochlor it eGas Chlorine And Sodium Hypochlor it eAre Cr it ical To A Safe Water SupplyAre Cri t ical To A Safe Water Supply

    nn Both Have Advantages andBoth Have Advantages and

    Disadvant ages Regarding Safet y, Cost ,Disadvant ages Regarding Safet y, Cost ,and Operat ionsand Operat ions

    nn Use of Sodium Hypochlor it e Simpli fiesUse of Sodium Hypochlor it e Simpli fiesRegulatory Compl iance, But is NOTRegulatory Compl iance, But is NOTWit hout Safety HazardsWit hout Safety Hazards

    nn Good Design Pract ices and GoodGood Design Pract ices and GoodOperat ional Pract ices Assure Effect iveOperat ional Pract ices Assure Ef fect iveTreatment and Minimize Safety RisksTreatment and Minimize Safety Risks

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    Water Treatment PracticesWater Treatment Practices

    CommitteeCommitteeGimmicks and Gadgets ContestGimmicks and Gadgets Contest

    vvEntries are due by June 1, 2006Entries are due by June 1, 2006vvYou can eYou can e--mail (preferred), US Mail or fax your entry:mail (preferred), US Mail or fax your entry:

    vvemail:email: wtpcomm@[email protected]

    vvmail:mail: Water Treatment Practices CommitteeWater Treatment Practices Committeec/o Michigan Section AWWAc/o Michigan Section AWWAPO Box 16337PO Box 16337

    Lansing, MI 48901Lansing, MI 48901--63376337

    vvfax:fax: (616) 942(616) 942--57875787

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    Questions and CommentsQuestions and Comments

    Water Treatment Practices CommitteeWater Treatment Practices Committee

    AWWAAWWA -- Michigan SectionMichigan Section