2....impressed current -cathodic protection

144
Delta consulting Delta consulting 1 1 12-16 November, 2006

description

cathodic protection

Transcript of 2....impressed current -cathodic protection

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Delta consultingDelta consulting 11

12-16 November, 2006

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Corrosion Control Techniques5.Cathodic Protection

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Corrosion Control Techniques5.Cathodic Protection

2- Impressed current system

DC source Ground bed

FeAnode

DC

Drain Point

I

Umbrella

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Corrosion Control Techniques5.Cathodic Protection

Basics of Impressed current system

Steel nails fixed to dry battery terminals

The steel nails immersed in saline water

Results: 1- The nail at +ve terminal Corrodes 2- The nail at –ve terminal remains Uncorroded

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Corrosion Control Techniques5.Cathodic Protection

Impressed current system

Nothing happens since the nails are in different electrolytes

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Corrosion Control Techniques5.Cathodic Protection

Transformer Rectifiers (T/R)

• AC inputVoltage, Single/ three phase, Frequency

• DC maximum output Amp, Volt

• Air Cooled: with sun-shadeOil Cooled: with thermometer

• Location: according to area classification • Explosion proof (hazardous area)• Non-explosion proof (non-hazardous area)

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Corrosion Control Techniques5.Cathodic Protection

Transformer Rectifiers

T/R with sun-shade

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Corrosion Control Techniques5.Cathodic Protection

Transformer Rectifiers

Explosion-proof Wall-mounted/indoors Pole-mounted

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Corrosion Control Techniques5.Cathodic Protection

Transformer Rectifier

Alternating Current Direct Current

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Corrosion Control Techniques5.Cathodic Protection

Mixed Metal Oxide (MMO)

Platinized

Graphite

Common Impressed current anodes:

Si – Fe

Si – Cr – Fe

Consumable AnodesConsumable Anodes Non Consumable AnodesNon Consumable Anodes

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Corrosion Control Techniques5.Cathodic Protection

Common Impressed current anodes:

Si – Fe

Si – Cr – Fe

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Are the most common impressed current anodesAre the most common impressed current anodes

Are used in soil, water or sea waterAre used in soil, water or sea water

Come in two grades; FeSi and FeSiCr for sea water Come in two grades; FeSi and FeSiCr for sea water applicationsapplications

Cable connection to anode shall be handled with great Cable connection to anode shall be handled with great care.care.

Fe Si Anodes

Corrosion Control Techniques5.Cathodic Protection

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Corrosion Control Techniques5.Cathodic Protection

Common Impressed current anodes:

Mixed Metal Oxide (MMO) Anodes

Solid Titanium Core

Titanium Substrate with a Copper Core

Titanium Tubular

Titanium Substrate Mesh

Titanium Substrate Ribbon

MMO is an electrically conductive coating that is applied onto a Titanium substrate in order to make it act as an Anode

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Corrosion Control Techniques5.Cathodic Protection

Common Impressed current anodes:

Mixed Metal Oxide (MMO) Anodes

MMO Coating

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Corrosion Control Techniques5.Cathodic Protection

Common Impressed current anodes:

Graphite Anodes

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Corrosion Control Techniques5.Cathodic Protection

Common Impressed current anodes:

Platinized Anodes

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Impressed current anodes are Impressed current anodes are some timessome times packaged packaged with the with the Carbonaceous backfill.Carbonaceous backfill.

Corrosion Control Techniques5.Cathodic Protection

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Corrosion Control Techniques5.Cathodic Protection

Impressed Current CP Systems

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Corrosion Control Techniques5.Cathodic Protection

Types of ground beds:

• Deep-well GB• Horizontal shallow GB• Distributed Anodes

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Corrosion Control Techniques5.Cathodic Protection

Deep well > 50m depth

Carbonaceous backfill Carbonaceous backfill for anodes sectionfor anodes section

Sand toppingSand topping

Non-metallic vent tube

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Property218-L4518

   Resistivity, ohm-inch

0.020.01

   Resistivity, ohm-cm

0.05  0.03

   Carbon (L.O.I. method)

99.099.9%

   Moisture0.10%0.02%

   Ash0.35%0.10%

   VCM0.30%  0/22%

   Sulfur3.75%  4.3%

   Bulk Density (lbs/ft3)

46-5062-66

   General Sizing   + 4 Mesh   + 8 Mesh   - 8 Mesh

   +4M < 10%+8M > 90%-8M < 10%

   4M 10%

+20M > 80%-20M 10%

Corrosion Control Techniques5.Cathodic Protection

Carbonaceous backfill

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Deep-well ground beds

Corrosion Control Techniques5.Cathodic Protection

Non-metallic Perforated Casing

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Corrosion Control Techniques5.Cathodic Protection

Shallow Bed

Depth 3 – 5 m

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Corrosion Control Techniques5.Cathodic Protection

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Corrosion Control Techniques5.Cathodic Protection

Distributed Impressed Current Anodes Arrangement

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Corrosion Control Techniques5.Cathodic Protection

Anode Connection :

Anodes cables are connected to anode / positive junction box

Each anode can be connected via a variable resistance to control the current output

A header cable connects the PJB to e +ve terminal of T/R

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Corrosion Control Techniques5.Cathodic Protection

Anode Connection :

Direct connection to +ve bus bar

An

od

e C

able

s fr

om

GB

Main Cable to +ve Terminal of T/R

Positive Junction Box

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Corrosion Control Techniques5.Cathodic Protection

Anode Connection :

Connection via variable resistance

An

od

e C

able

s fr

om

GB

Main Cable to +ve Terminal of T/R

Positive Junction Box

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Corrosion Control Techniques5.Cathodic Protection

Typical Impressed Current System Arrangement

Gro

un

d B

ed

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Corrosion Control Techniques5.Cathodic Protection

Positive current flux through soil to buriedpipeline and resulting distribution of current density on pipe wall

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Corrosion Control Techniques5.Cathodic Protection

Pipeline attenuation and multiple ground beds

V v

s C

SE

GB1 GB2 GB3

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Corrosion Control Techniques5.Cathodic Protection

Typical Under-Tank Cathodic ProtectionSystem for New Tanks

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Corrosion Control Techniques5.Cathodic Protection

Under tank cathodic protection

MMO anode grid

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Corrosion Control Techniques5.Cathodic Protection

Main Problem with Under-Tank CP Systems

The protective +ve CP current causes decomposition of water

Since water content of the soil underneath the tank is very limited

As a result, the GB dries up – i.e. no electrolyte – and the CP system is aborted

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Corrosion Control Techniques5.Cathodic Protection

Laser Slotted PVC Tubes

Solution Installation of Under-Tank Watering System

Concrete Ring

Slotted PVC Pipes

Compacted

Soil

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Corrosion Control Techniques5.Cathodic Protection

Installation of Under-Tank Watering System

ICCP Anode Grit

Tank

PV

C W

ater

ing

Pip

e

To T/R

Compacted Soil

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Corrosion Control Techniques5.Cathodic Protection

Peripheral Anode Cathodic Protection System for Existing Tanks

Horizontal GBMMO strip anode

Existing Tank

Protecting outermost bottom

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Corrosion Control Techniques5.Cathodic Protection

Distributed Anode Cathodic Protection

System

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Corrosion Control Techniques5.Cathodic Protection

Cathodic protectioninstallation for a well

casing

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Corrosion Control Techniques5.Cathodic Protection

Hanging ICCP anode

Impressed Current Cathodic Protection for Tank Internals

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Corrosion Control Techniques5.Cathodic Protection

Impressed Current Cathodic Protection for Tank Internals

ICCP anodePVC Support

Anode Cable extended to outside along vent tube

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Corrosion Control Techniques5.Cathodic Protection

ICCP for jackets

1- Hanging Anodes

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Corrosion Control Techniques5.Cathodic Protection

ICCP for jackets

2- Sub-sea Sleds

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Corrosion Control Techniques5.Cathodic Protection

Pourbaix diagram showing the theoretical conditions for corrosion, passivation, and immunity of iron in water and dilute aqueous solutions

Cathodic Protection Criteria

7 14P

ote

nti

al

2.01.6

0.81.2

-0.4

0.40.0

-1.6

-0.8-1.2

0

Immunity

Fe3+

Passivity

Corrosion

pH

Fe2+

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Corrosion Control Techniques5.Cathodic Protection

Fe-to-Soil Potential in Low Resistivity Soils

showing the degree of corrosion

The value – 850 mV is the CP criterion for protecting steel in aggressive soils

DescriptionPotential vs Cu/CuSO4

mV

-500

Free Corrosion-700

Zone of Cathodic ProtectionZone of Cathodic Protection-900

Intense Corrosion-600

Sever Over-Protection

Problems

Sever Over-Protection

Problems-1200

Increased Over-Protection-1100

Some Over-Protection-1000

Some Protection-800

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Corrosion Control Techniques5.Cathodic Protection

Excessive negative potentials can cause :

Cathodic Disbonding : i.e. loss of adhesion between the coating and the metal surface

Hydrogen Damage : due hydrogen evolution at –ve potentials

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Corrosion Control Techniques5.Cathodic Protection

Potential criteria for cathodic protection of some metals and alloys at 25º C (1)

(1) According to British code of practice No. CP 1021, August 1973.(2) But not more negative than about -1.2 Volts.

Metal/ AlloyPotential criterion (mV)

vs Cu/ Cu SO4

Iron, steel, stainless steel :

Aerobic conditions

Anaerobic conditions

-850

-950

Lead -600

Copper-500

Aluminum -950 )2(

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Corrosion Control Techniques5.Cathodic Protection

According to ISO 15589-1 Part 1, 2003 concerning the CP protection criteria of On-Land Pipelines :

“The CP system shall be capable of :

polarizing all parts of the buried pipeline to potentials more negative than – 850 mV referred to CSE,

&

to maintain such potentials throughout the design life of the pipeline”.

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Corrosion Control Techniques5.Cathodic Protection

“For pipelines operating in soils with very resistivity, a protection potential more positive than – 850 mV referred to CSE may be considered, e.g. as follows”:

- 750 mV for 10,000 < p < 100,000 ohm.cm

- 650 mV for p 100,000 ohm.cm>

According to ISO 15589-1 Part 1, 2003 concerning the CP protection criteria of On-Land Pipelines :

i.e., the value of – 850 mV is only for soils with p < 10,000 ohm.cm

p = Soil Resistivity

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Corrosion Control Techniques5.Cathodic Protection

Cathodic protection monitoring

Potential Measurement

Structure/Electrolyte Potential is measure by means of a reference electrode :

Copper / Copper Sulfate Soil

Silver / Silver Chloride Sea Water

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5252

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Corrosion Control Techniques5.Cathodic Protection

Copper / Copper Sulfate reference electrode

Portable Type

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Corrosion Control Techniques5.Cathodic Protection

Copper / Copper Sulfate reference electrode

In order to measure the structure – to – soil potential , the CSE must become part of the soil

This is fulfilled by inter-mixing of the CSE content with the soil content due to diffusion down a concentration gradient

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Corrosion Control Techniques5.Cathodic Protection

H2O (

SO42-

SO42-

Soil)

Copper RodCuSO4 Saturated

Water molecules

migrate into CSE

Sulfate ions migrate

from CSE to soil

Porous Disc

AVO meter

Typical Arrangement for Pipe – to – Soil Measurement

Solution

HIGH WATER CONTENT

HIGH SO42- IONS

CONTENT

Pipe

Cu

Cu2+

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Corrosion Control Techniques5.Cathodic Protection

Typical Arrangement for Pipe – to – Soil Measurement

Icp umbrella

Icp umbrella

CSE

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Corrosion Control Techniques5.Cathodic Protection

Voltmeter

IR error

Ep

CP current

CSE @ soil surface

Coating

Eon Reading

Eon = Ep + IR Error

Voltmeter

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Corrosion Control Techniques5.Cathodic Protection

Voltmeter

Ep

CSE @ soil surface

Coating

Eoff Reading , instantaneous

Eoff = Ep

Voltmeter

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Corrosion Control Techniques5.Cathodic Protection

Permanent Copper / Copper Sulfate reference electrode

Prepackaged CSEBackfill :Gypsum +Bentonite clay +Sodium sulfate

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Corrosion Control Techniques5.Cathodic Protection

Test Posts for CP Monitoring

Flush – to – ground

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Corrosion Control Techniques4.Cathodic Protection

Electrode Placement

For pipelines : on-the-line @ every 1- 2 Km destination For tanks : preferred under tank or closest

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Corrosion Control Techniques5.Cathodic Protection

CP Permanent Monitoring ( Test ) Point consists of :-

Permanent Reference Electrode ( or Portable type )

Test Post : for pipelines : @ every 1- 2 Km intervals for tanks : near the tank

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Corrosion Control Techniques5.Cathodic Protection

Structure-to-Soil potential measurement using Voltmeter.

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Corrosion Control Techniques5.Cathodic Protection

Permanently Installed Reference Electrode & Test Post

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Corrosion Control Techniques5.Cathodic Protection

Permanent Monitoring forUnder Tank Cathodic

Protection

Tank Diameter (m)No. of Electrodes Required

5-101

10-232

23-363

45 and above4

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Corrosion Control Techniques5.Cathodic Protection

Reference Electrodes Locations for Under - Tank CP Systems

1/4D1/6D

2/6D2/8D

3/8D

1/8D

D=45m and above D=23-36m D=10.5-22.5m D=5-10m

Key : Reference Electrode

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Corrosion Control Techniques5.Cathodic Protection

PVC pipe installed through the concrete ring @ different locations for CSE placement.

Concrete Ring

Under Tank Soil

PVC Pipe – See Details

Top View

PVC Pipe

Under Tank Soil

Co

ncr

ete

Rin

g

CSE

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Corrosion Control Techniques5.Cathodic Protection

CSEPerforated PVC Pipe Filled with Water

Tank

Perforated PVC Pipe Installed for Reference Electrode Placement

AVO

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Corrosion Control Techniques5.Cathodic Protection

Correct method for measuring structure potentials when surface is covered with concrete or asphalt.

AVOCSE in Wet Soil

Buried Pipe

Concrete / Asphalt

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Corrosion Control Techniques5.Cathodic Protection

For monitoring tank’s internal CP system use:

Hanging RE ( from roof )

Plug RE ( fixed on shell )

RE

RE

Hanging Reference Electrodes

Plug RE

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Corrosion Control Techniques5.Cathodic Protection

Diver with portable reference electrode

Potential Measurement of jackets / platform legs

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Corrosion Control Techniques5.Cathodic Protection

Transponder CP monitoring

Potential Measurement of jackets / platform legs

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Corrosion Control Techniques5.Cathodic Protection

Potential plot after data analysis

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Corrosion Control Techniques5.Cathodic Protection

Potential Measurement of subsea pipelines

Trailing-wire potential survey

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Corrosion Control Techniques5.Cathodic Protection

TP-3TP-1 TP-2

wellTP

TP-3 TP-4

- 850 mV Min. protection levelUn protected

area

Pip

e to

soi

l pot

entia

l-

mV

What about the potential at any point ?

Buried pipeline ( 1.2 meter deep)

Well casing8000 feet deep

The criterion most widely used on pipelines is based on measurementsof potential differences between the pipeline and its environment

.ie: more negative than ( - 850 mv) reference to Cu/Cu So4 cell

Potential Measurement of well casing

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Corrosion Control Techniques5.Cathodic Protection

Potential Measurement of well casing

Up hole

Upper Centralizer

Upper Contactors

Spacer Bare

Lower Contactors

Lower Centralizer

Sinker Weight

Leng

th b

etw

een

c ont

acto

rs5

to 7

met

ers

V

Casing

Tool inside Casing

CASING POTENTIAL PROFILE TOOLSPECIFICATIONS

8.5 m using 5.0 contactor spacing10 m using 6.0 contactor spacing

length

Diameter 2.5/8 in. ( 6.5 cm) maximum

weight 440 lb.* (199.6 kg)

Max. temp. 300 deg.F (154 deg.C)

Max.Pressure

10,000 psi (69 Mpa)

CasingSize

4.5 in (11.4 cm) to 13.3/8 in (34 cm)

Hoistingspeed

80 ft/min (24.38 m/minRecommended

Loggingreading

Stationary readings; average speed 25ft/min (7.6 m/min) at 50 ft intervals

Loggingenvirnment

Must be dray

LimitationsNot recommended for use in fresh

water

Typical Casing Potential Profile Tool (Courtesy of Atlas Industries, Inc.)

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Corrosion Control Techniques5.Cathodic Protection

Potential Measurement of well casing

+ -T RvOUTPUT CURRENT

= ( I )

( I )

( i1 )

( i 2 )

( i3 )

( I-i1 )

( I-i1-i2 )

( I-i1-i2 -i3)

U1

U2

U3

Casing to soilpotential= (v)

Cu/Cu So4 cell v

U1

U2

U3

-700 -850 -900 -1000

Dep

th in

feet -8

50 m

v m

i n. p

rot e

ctio

n le

vel

R

R

R Ohm’s Low: V = I x R U = Voltage drop = I x R pipe

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Cable – to - cable connection

Cable – to - pipe connection

Cable – to - structure connection

Corrosion Control Techniques5.Cathodic Protection

Cable Connections

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Splice Kit : for cable-to-cable connection

Corrosion Control Techniques5.Cathodic Protection

Cable Connections

1 2

Araldite is poured & let to dry

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For cable-to-pipe connection :

1- Thermite ( Cad / Exothermic ) Welding

2- Pin Brazing

3- Mechanical connection ( for gas pipelines )

Corrosion Control Techniques5.Cathodic Protection

Cable Connections

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For cable-to-pipe connection

1- Thermite Welding :

Corrosion Control Techniques5.Cathodic Protection

Cable Connections

Crucible

DisksCartridge

Spark Flint

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Corrosion Control Techniques5.Cathodic Protection

Thermite WeldmentPrior to welding :

The coating must be removed at welding point ( 5x5 cm square )

Metal surface to be polished and cleaned

Thermite Welding

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Corrosion Control Techniques5.Cathodic Protection

Self-adhesive Handy-cap

1 2 3

Protecting the Thermite Weldment

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Corrosion Control Techniques5.Cathodic Protection

Cable Connections

For cable-to-pipe connection

2- Pin Brazing : emits less heat output

Pin Brazing Unit

Pistol / Gun

Pins & Ferrules

Lug

Grinder

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Corrosion Control Techniques5.Cathodic Protection

Cable Connections

For cable-to-pipe connection

2- Pin Brazing

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Corrosion Control Techniques5.Cathodic Protection

Cable Connections

For cable-to-pipe connection

2- Pin Brazing

1 Clean the surface2 Load gun with

pin & ferrule3 pin braze

4 Test connection

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Corrosion Control Techniques5.Cathodic Protection

Cable Connections

For cable-to-pipe connection

3- Mechanical Connection : recommended for drain point connection of gas pipelines

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Corrosion Control Techniques5.Cathodic Protection

Cable Connections

Terminal Lugs :

for cable-to-structure ( tank ) connection

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Electrical isolation is made by :

Isolating flange kit ( IFK )

IFK is installed @ Aboveground / Underground Interface

Corrosion Control Techniques4.Cathodic Protection

Electrical Isolation Isolation

Structures to be protected shall be electrically isolated from portions which do not require protection.

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Isolating flange kit ( IFK )

Corrosion Control Techniques4.Cathodic Protection

Electrical Isolation Isolation

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Corrosion Control Techniques4.Cathodic Protection

Isolating flange kits

In hazardous areas , IFK’s are

protected by means of Spark Gaps

Spark Gap FittedSpark Gap Fitted

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Monolithic Blocks

Corrosion Control Techniques4.Cathodic Protection

Electrical Isolation

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Monolithic Blocks

+ Polarization Cell

Corrosion Control Techniques4.Cathodic Protection

The monolithic blocks are protected against electrostatic charges and lightening by charges and lightening by polarization cell polarization cell

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Casings for Road Crossings

Corrosion Control Techniques4.Cathodic Protection

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Casings for Road Crossings

There should NOT be any contact between the pipe & casing

Test posts usually installed @ crossings to monitor the potential of pipe and casing separately

Corrosion Control Techniques5.Cathodic Protection

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Corrosion Control Techniques4.Cathodic Protection

Clamp MeterClamp Meter

Clamp Meters are used to check:

electric cables integrity

current output of each anode

Clamp Meter

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Corrosion Control Techniques5.Cathodic Protection

Pipeline & Cable Warning Markers

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Corrosion Control Techniques5.Cathodic Protection

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Corrosion Control Techniques5.Cathodic Protection

There are numerous codes and references that shall beThere are numerous codes and references that shall bereferred to when dealing with cathodic protection among referred to when dealing with cathodic protection among these are:these are:

NACE RP 0169NACE RP 0169NACE RP 0176NACE RP 0176NACE RP 177NACE RP 177NACE RP 575NACE RP 575

ISO 15589-1, PART I – 2003, “On-land Pipelines”ISO 15589-1, PART I – 2003, “On-land Pipelines” ISO 15589-2, PART II – 2004, “Offshore Pipelines”ISO 15589-2, PART II – 2004, “Offshore Pipelines”

DnV RP B 401DnV RP B 401API 651API 651J. Morgan, “Cathodic Protection”J. Morgan, “Cathodic Protection”A.W. Peabody, “Control of Pipeline Corrosion”A.W. Peabody, “Control of Pipeline Corrosion”

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Terms & Definitions

Natural Potential:Is potential of structure to be protected whenever no cathodic protection system is applied.

Protection Potential:Is the potential of structure to be protected whenever corrosion rate is insignificant.

Anode Backfill:Materials with low resistivity surrounding buried anode, may be moisture retaining materials, used for decrease anode to electrolyte resistance and prevent anode polarization.

Corrosion Control Techniques5.Cathodic Protection Design

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Terms & Definitions

Drain Point:Location of negative cable connection to the structure to be protected through which the cathodic protection current returns to its source.

Coating Break-down Factor:Is the ration between the current density required to polarize coated surface and density required to polarize bare surface.

Initial Current DensityEstimated current density required for polarization of structure to be protected at the start of the lifetime.

Final Current Density:Estimated current density required to maintain polarization at the end of the lifetime.

Corrosion Control Techniques5.Cathodic Protection Design

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Terms & Definitions

Mean Current Density:Estimated current density for the entire of the lifetime

Anode Electro-chemical Capacity:The amount of electricity expressed by (Amper.Hour/kg) that is produced due to anode consumption.

Cathodic Protection Criteria:Limits of protection potentials.

Corrosion Control Techniques5.Cathodic Protection Design

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Corrosion Control Techniques5.Cathodic Protection

CP System Design :

Basic information for design considerations1. Type of electrolyte (environment)

• Soil• Fresh/ saline water.

2. Availability of power supply3. Temperature 4. Type of coating5. For pipelines:

• Pipeline route• Crossings (foreign pipeline, roads, rivers, etc.)• Presence of high transmission power lines• Presence of foreign metallic structures.

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Corrosion Control Techniques5.Cathodic Protection

Soil resistivity

Soil represents the electrolyteSoils with low resistivity have high conductivity; i.e.

corrosive

NACE ranking :

Soil resistivity (ohm.cm)Corrosivityup to 1,000Severely corrosive

1,000-5,000Corrosive

5,000-10,000Moderately corrosive

10,000-20,000Slightly corrosive

20,000 and aboveNon-corrosive

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Corrosion Control Techniques5.Cathodic Protection

Four-Terminals (Wenner) Method :For Measurement of Soil Resistivity.

Kit

Power Unit

Stainless Steel Pins

Cables

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Corrosion Control Techniques5.Cathodic Protection

4-Terminals Arrangement

Ohm’s Low : R = V/I

R : Resistance (ohm)V : Applied Voltage I : Recorded Amperage

a a a

Depth = a

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Current demand for CP:

Current density : it is the current required to polarize (1 meter)2 of bare steel in a given electrolyte.

Corrosion Control Techniques5.Cathodic Protection Design

Current density increases with increasing temperature

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Corrosion Control Techniques5.Cathodic Protection Design

Temperature : current demand shall be increased by 25% per every 10º C incremental rise above 30º C. This requirement is described by the following equation:

i = i0 + [i0 x 0.25 (t - t0)] / 10

Where,i = current density at operating temperature, Amp/m2

i0 = base current density at standard temperature t = operating temperature ºC

t0 = standard temperature (30ºC)

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Corrosion Control Techniques5.Cathodic Protection

Current density determined in mA/m2 is dependant on the

media aggressivity.

Therefore if soil resistivity is low then current density shall be

high

MediaCurrent Density

mA/m2

Aggressive Soil10

Normal soil5

Sea water90

Fresh water30

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Corrosion Control Techniques5.Cathodic Protection

Power Supply :

The T/R is fed with AC current from the nearest power supply.

If there is no power supply available, Solar Units to be used instead of T/R.

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Corrosion Control Techniques5.Cathodic Protection

240 Watt Solar Array0-24 Volt

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Corrosion Control Techniques5.Cathodic Protection

GB Pipe to be protected

Converter

Regulator

Batteries

Junction Box

Solar ModulesStructure(-)(+)

Typical Arrangement for ICCP Using Solar Energy

Sun

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Corrosion Control Techniques5.Cathodic Protection

Typical Coating Resistances for various coating qualities

Coating qualityRange of specific leakage resistance

(RC), ohm.m2

Poor1,000-2,500

Fair5,000-10,000

good25,000-50,000

Excellent 100,000-500,000

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Corrosion Control Techniques5.Cathodic Protection

Typical Coating Breakdown ValuesTypical Coating Breakdown Values

Coating type %breakdown

Initial Mean Final

Thick coating ≤ 1510

Epoxy coal tar≤ 25-1010-20

Fusion bonded epoxy

1-25-105-20

Polypropylene (25 yrs)

0.525

Polyethylene (25 yrs)0.513

CP

curren

t

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Corrosion Control Techniques5.Cathodic Protection

Recommended potential limits for different coatingsto avoid coating disbondment

Coating typeVolt (vs Cu/ CuSO4)

Asphalt Enamel-2

Epoxy coal tar-1.5

Fusion bonded epoxy-1.5

Tape wrap-1.5

Polyethylene -1.0

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Corrosion Control Techniques5.Cathodic Protection

Pipeline Route

Cross-country P/L’s pass through different types of soils, i.e. different electrolytes

Presence of high voltage power transmission lines

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Corrosion Control Techniques5.Cathodic Protection

Pipeline Route

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Corrosion Control Techniques5.Cathodic Protection

Pipeline AC interference from electromagnetic field

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For protection against stray current

from high tension lines, zinc ribbon

and polarization cells are used

Corrosion Control Techniques5.Cathodic Protection

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In case of pipe-crossing of cathodically protected pipelines BONDING is required by means of :

Solid boning, or

Resistance bonding

Corrosion Control Techniques5.Cathodic Protection

Stray current interference

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Stray-current corrosion

Corrosion Control Techniques5.Cathodic Protection

Pipeline potential shifts in anodic direction ( more positive values )

Possibility of high anodic current densities , i.e. high corrosion rates

Pipeline potential shifts in cathodic direction ( more negative values )

Possibility of coating disbondment and hydrogen damage

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Corrosion Control Techniques5.Cathodic Protection

Stray-current corrosion

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Corrosion Control Techniques5.Cathodic Protection

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CP Current Requirement

CD= S CD= S xx a a xx CBDC CBDC

Corrosion Control Techniques5.Cathodic Protection

CD : Current Demand (A) S : Design Current Density (A/m2) a : Surface Area (m2)

CBDF : Coating Break-down Factor % Current Rating : (1.5 times final CD)

Temperature (°C) 50 Initial Average Final

Current Density (mA/m2) 5 CBDF (%) 0.01 2 3

Design Density (mA/m2) 7.5 Current Demad (A) 0.0 5.7 8.6

Pipeline Length (km) 30Pipeline Diameter (inch) 16 Current Rating (A) 13

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Anodes Weight & Quantity Requirement

Corrosion Control Techniques5.Cathodic Protection

# of Anodes Required

Wt = Weight per anode (kg) Wt = 27.2 kgCR = Consumption rate (kg/amp-year) CR = 0.34 kg/A-yrDL = Desired life (years) DL = 20 yrs

Current = Current required (amps) Current = 5.70 AUF = Utilization factor UF = 0.60

# anodes = 3.00

# of Anodes Required Based on Current Discharge

* from anode manufacturer dataMD = Maximum discharge per anode (amps) MD = 1.50 A

Current = Current required (amps) Current = 5.70 A# anodes = 4.00

Impressed Current (On-land) Systems

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CP Circuit Resistance : (ICCP systems)

Corrosion Control Techniques5.Cathodic Protection

R Gbed = Ground-bed resistance (ohms)

R C = Cable resistance (ohms)

R S = Pipeline/structure to earth resistance (ohms) 0.00 ohms

R T = Total circuit resistance (ohms) 0.00 ohms

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CP Ground-Bed Resistance :

Corrosion Control Techniques5.Cathodic Protection

1) Dwight's Equation for Single Vertical Anode

ρ = Resistivity of backfill material (or earth) in ohm-cm 1,000 ohm-cmL = Length of backfill (or anode) in meters 2.00 md = Diameter of backfill (or anode) in meters 0.30 m

R v = Resistance of one vertical anode to earth in ohms 2.366 ohms

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Corrosion Control Techniques5.Cathodic Protection

2) Dwight's Equation for Multiple Vertical Anodes in Parallel

ρ = Soil (or Backfill) resistivity in ohm-cm 1,000 ohm-cmN = Number of anodes in parallel 4 eachL = Length of backfill (or anode) in meters 2.0 md = Diameter of backfill (or anode) in meters 0.3 mS = Anode spacing in meters 3.0 mR = Resistance of vertical anodes in parallel to earth in ohms 0.8 ohms

CP Ground-Bed Resistance (cont’) :

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Corrosion Control Techniques5.Cathodic Protection

3) Modified Dwight's Equation for Single (or Multiple) Anodes Installed Horizontally

ρ = Resistivity of Soil or (backfill) material 1,000 ohm-cmL = Length of backfill (or anode) in meters 8.00 m

S = Twice depth of anode in meters 3.0 md = Diameter of backfill (or anode) in meters 0.3 m

RH = Resistance of horizontal anode (or multiple) to earth 0.9 ohms

CP Ground-Bed Resistance (cont’) :

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CP Ground-Bed Resistance :

Corrosion Control Techniques5.Cathodic Protection

4) Dwight's Equation for Deep-Well Anodes

ρ = Effective Resistivity of earth in ohm-cm 1,000 ohm-cmL = Length of backfill (or anode) in meters 8.00 md = Diameter of backfill (or anode) in meters 0.30 m

R v = Resistance of deep-well anode to earth in ohms 0.867 ohms

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Corrosion Control Techniques5.Cathodic Protection

Cable Resistance

R CABLE = Resistance per km 0.833 ohms/km

L CABLE = Length in meters (sum of positive and negative cables) 150 m

R C = Cable resistance 0.125 ohms

CP Cables Resistance :

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CP Circuit Resistance & Driving Voltage : (ICCP systems)

Corrosion Control Techniques5.Cathodic Protection

Driving Voltage = Max. Current x RT

R Gbed = Ground-bed resistance (ohms) 0.90 ohms

R C = Cable resistance (ohms) 0.125 ohms

R S = Pipeline/structure to earth resistance (ohms) 0.00 ohms

R T = Total circuit resistance (ohms) 1.03 ohms

Max. current (A) 13Driving Voltage (v) 13.3

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Transformer/Rectifier (T/R) Rating:

Corrosion Control Techniques5.Cathodic Protection

Max. current (A) 13.0Driving Voltage (v) 13.3

T/R Output Rating:

Select near standard T/R rating:

(e.g. 12V, 24V, 36V, 48V, 5A, 10A, 15A, 20A…etc)

T/R output: 15A/24V DC

T/R Input Characteristics:

Check available electrical power characteristics:

Either 3PH, 400V AC, 50Hz Or 1PH, 230V AC, 50Hz

T/R Input: 3PH, 400V AC, 50Hz

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CP Current Attenuation (Spread) Check

(for Pipelines)

Corrosion Control Techniques5.Cathodic Protection

En (v) Pipeline Natural Potential -0.55

∆Ea/∆Em = Cosh(αL) Ea (v) Pipeline Protective Potential at Drain Point -1.3

∆Ea (v) Pipeline Potential Shift at Drain Point -0.75

∆Ea = Ea - En Em (v) Pipeline Protective Potential at Distance (L) -0.95

∆Em = Em - En ∆Em (v) Pipeline Potential Shift at Distance (L) -0.4

α (m-1) Attenuation Constant 3.1623E-05

α = √ (Rs/Rlf) Rlf (ohm.m) Linear Coating Insulation Resistivity (final) 15664.8566

Rf (ohm.m2) Coating Insualtion Resistivity (final) 20000

Rlf = Rf/(π * D) Rs (ohm/m) Linear Pipeline Steel Conductivity 1.5665E-05

Rs = ρs/ (π * D * t) ρs (ohm.m) Pipeline Steel Specific Resistivity 0.00000019

D (m) Pipeline Diameter 0.4064

t (m) Pipeline Wall Thickness 0.0095

L (Km) Attenuation Distance 39.26

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Corrosion Control Techniques5.Cathodic Protection

Typical Coating Resistance (for various coating qualities)

Coating qualityRange of specific leakage resistance

(Rl), ohm.m2

Poor1,000-2,500

Fair5,000-10,000

good25,000-50,000

Excellent 100,000-500,000

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CP Current Requirement

CD= S CD= S xx a a xx CBDC CBDC

Corrosion Control Techniques5.Cathodic Protection

S : Design Current Density (A/m2) a : Surface Area (m2)

CBDF : Coating Break-down Factor %

Temperature (°C) 50 Initial Mean Final

Current Density (mA/m2) 90 CBDF (%) 0.01 2 3

Design Density (mA/m2) 135 Current Demad (A) 0.5 103.4 155.1

Pipeline Length (km) 30Pipeline Diameter (inch) 16

Coating 3PP

Sacrificial Anode SystemsSacrificial Anode Systems

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Anode Material & Dimensions Selection

Anode Material Selection

Corrosion Control Techniques5.Cathodic Protection

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Anodes Weight & Quantity Requirement

Corrosion Control Techniques5.Cathodic Protection

Total Mass Required

Icm = Mean Current Demand (A) 103.40 Atdl = Design Lifetime (Year) 20 yrsu = Utilization factor 0.80ε = Design Electrochemical Capacity (A.hr/kg) 2500 A-hr/kg

m = Total Mass of Anodes (kg) 9057.8 kg

# of Anodes Required Based on Total Required Mass

m a = Standard Net Anode Mass (kg) 100.0 kg

n = Anodes Qty # anodes = 91

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Sacrificial Sacrificial VSVS Impressed Current CP Impressed Current CP

Sacrificial Impressed current

No need for external power sourceRequires an external power source

Easy to design and installRequires skillful design and installation

uncontrollableCan be controlled

Used only for limited surface areas and well coated structures

Can be used for uncoated surfaces and used for any surfaces

Has no detrimental effectsCan cause serious problems if not handled carefully

Is limited to low resistivitycan be used at any resistivity

Low maintenanceHigh maintenance

Corrosion Control Techniques4.Cathodic Protection

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Corrosion Control Techniques5.Cathodic Protection

Sacrificial VS Impressed Current CP

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Thank You and Good Luck