29 Paper Battery

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Page | 1 Seminar Report on PAPER BATTERY DEPARTMENT OF MECHANICAL ENGINEERING DECEMBER 2014

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Transcript of 29 Paper Battery

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    Seminar Report on

    PAPER BATTERY

    DEPARTMENT OF MECHANICAL ENGINEERING

    DECEMBER 2014

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    ABSTRACT

    In this paper the use of self-rechargeble paper thin film batteries, their performance and

    applications has been presented. The Glucose activated paper battery based on glucose

    oxidised enzyme using a simple and cheap plastic laminating technology has been

    demonstrated. The enzyme and glucose concentration can be optimized to gear up the power

    requirement. Ultra fast all polymer paper based batteries are an option with some short

    comings yet such as low cycling stabilities and functional discharge rate. Also integration

    secondary battery with the paper battery is also shown to improve the power.

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    CONTENTS

    CHAPTERS PAGE NO

    1 INTRODUCTION..6

    2 LITERATURE SURVEY....................................................................................7

    2.1 Literature Survey............................................................................................7

    2.2 Objectives......................................................................................................7

    3 PAPER BATTERY8

    3.1 Glucose activated Laminated Battery.9

    3.2 Polymer based paper battery..11

    3.3 Li-ion paper battery...13.

    4 FABRICATION METHODS .17..

    4.1 Doctor blade process.17

    4.2 Lamination....18

    5 DURABILITY.19

    6 USE..20

    7 CONCLUSION21

    REFERENCES

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    LIST OF FIGURES

    No. Title Page no.

    Figures

    3.1.1 Fabrication 10

    3.1.2 Glucose-activated laminated battery 11

    3.2.1 Cell voltage vs time graph, 12

    3.2.2 Charge capacity vs charge current 12

    3.3.1 Fabrication of li ion battery on paper 14

    3.3.2 Cycling performance of LTO nanopowder (C/5, 0.063ma)

    half cells 15

    3.3.3 Li ion paper battery energy increased through stacking

    16

    4.1 Doctor blade 17

    4.2 Roll laminator 18

    Tables

    3 Influence of electrode thickness in electrical

    characteristics of devices

    9

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    CHAPTER 1

    INTRODUCTION

    Paper can turn quite an interesting material to produce very cheap disposable electronic

    devices with the great advantage of being environment friendly. The possibility to produce

    large scale low cost disposable electronic devices has been opened like never before with

    revolution of paper transistors, transparent thin film transistors based on semiconductor

    oxides and paper memory. The common material of all these recent electronic devices is

    cellulose fibre-based paper as active material in opposition to other Ink-jet printed active

    matrix display. This emphasises the need of the use of cheap yet reliable material for the

    fabrication of electronic devices. Many modifications of the prime model have been brought

    out from time to time to keep up with the challenges and demands of the present world.

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    CHAPTER 2

    LITERATURE SURVEY

    2.1 LITERATURE SURVEY

    The literature survey conducted are as follows

    1.Gustav NystroM, Aamir Razaq, Maria Strmme, Leif Nyholm, AND Albert Mihranyan

    studied ultrafast all-polymer paper-based batteries. In the process they tried to replace the

    metal/metal oxide with polymer. The preparation of novel redox polymer and electronically

    conducting polymer-based electrode materials is essential.Conducting polymers are

    particularly interesting materials as devices based on these materials could be used as

    adaptable energy storage devices due to their inherent fast redox switching, high

    conductivity, mechanical flexibility, low weight and possibility to be integrated into existing

    production processes.

    2. Liangbing Hu, Hui Wu, Fabio La Mantia, Yuan Yang, and Yi Cui investigated about Thin

    Flexible Secondary Li-Ion Paper Batteries. They tried to integrate Li-ion battery onto a paper battery. They integrated all of the components of a Li-ion battery into a single sheet of

    paper with a simple lamination process. Due to the intrinsic porous structure of the paper, it

    functions effectively as both a separator with lower impedance than commercial separators

    and has good cyclability.

    3. Ki Bang Lee studied about the Urine Activated Paper Batteries. A simple and cheap

    fabrication process for the paper batteries, compatible to the existing plastic laminating

    technologies or plastic moulding techniques was developed by him. A paper battery is tested

    and it can deliver a power greater than 1.5mw.

    2.2 OBJECTIVES

    To study the following:

    1. The use of self-rechargeable paper thin film batteries, their performance and

    application.

    2. The Glucose activated paper battery based on glucose oxidised enzyme.

    3. Ultra fast all polymer paper based batteries.

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    CHAPTER 3

    PAPER BATTERY

    A paper battery is a flexible, ultra-thin energy storage and production device formed by

    combining carbon nanotube with a conventional sheet of cellulose-based paper. A paper

    battery acts as both a high-energy battery and supercapacitor , combining two components

    that are separate in traditional electronics . This combination allows the battery to provide

    both long-term, steady power production and bursts of energy. Non-toxic, flexible paper

    batteries have the potential to power the next generation of electronics, medical devices and

    hybrid vehicles, allowing for radical new designs and medical technologies.

    Paper batteries may be folded, cut or otherwise shaped for different applications without any

    loss of integrity or efficiency . Cutting one in half halves its energy production. Stacking

    them multiplies power output. Early prototypes of the device are able to produce 2.5 volt s of

    electricity from a sample the size of a postage stamp.

    The devices are formed by combining cellulose with an infusion of aligned carbon nanotubes

    that are each approximately one millionth of a centimetre thick. The carbon is what gives the

    batteries their black colour.

    Cellulose based paper is a natural abundant material, biodegradable, light, and recyclable

    with a well-known consolidated manufacturing process. Here, we expect to contribute to the

    first step of an incoming disruptive concept related to the production of self-sustained paper

    electronic systems where the power supply is integrated in the electronic circuits to fabricate

    fully self sustained disposable, flexible, low cost and low electrical consumption systems

    such as tags, games or displays.

    In achieving such goal we have fabricated batteries using commercial paper as electrolyte and

    physical support of thin film electrodes. A thin film layer of a metal or metal oxide is

    deposited in one side of a commercial paper sheet while in the opposite face a metal or metal

    oxide with opposite electrochemical potential is also deposited. The simplest structure

    produced is Cu/paper/Al but other structures such as Al paper WO3/ TCO were also tested,

    leading to batteries with open circuit voltages varying between 0.50 and 1.10 V. On the other

    hand, the short current density is highly dependent on the relative humidity (RH), whose

    presence is important to recharge the battery. The set of batteries characterized show stable

    performance after being tested by more than 115 hours, under standard atmospheric

    conditions [room temperature, RT (22 C) and 60% air humidity, RH].

    The thicknesses of the metal electrodes varied between 100 and 500 nm. The Al/paper/Cu

    thin batteries studied involved the use of three different classes of paper: commercial copy

    white paper (WP: 0.68 g/cm , 0.118 mm thick); recycled paper (RP:0.70 g/cm , 0.115 mm

    thick); tracing paper (TP: 0.58 g/cm ,0.065 mm thick). The role of the type of paper and

    electrodes thickness on the electrical parameters of the battery, such as the Voc and Jsc are

    indicated in Table I

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    The thickness of the metal layer does not play a remarkable role on electrical characteristics

    of the batteries. Considering that the tracing paper is less dense and thinner than white and

    recycled paper, the difference on the current density observed can be related to ions

    recombination either due to impurities inside the foam/mesh-like paper structure or charge

    annihilation by vacant sites associated to the surface of the paper fibers, existing in thicker

    papers. Other possible explanation is that the adsorption of water vapor is favored in less

    dense paper. We conclude that this type of battery is a mixture of a secondary battery and a

    fuel cell where the fuel is the water vapor and so its application requires environment with

    40%.

    Batteries able to supply a Voc=.70V and Jsc > 100 nA/cm at Relative humidity=60% were

    fabricated using respectively as anode and cathode thin metal films of Al and Cu as thin as

    100 nm.

    3.1 Glucose activated Laminated Battery

    Now lets consider the case of glucose activated laminated, which is the modification of the

    previous work.

    Fabrication of above is shown below.

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    Figure2.1.1: Fabrication

    Fabrication process for the paper battery: the whole assembly consisting of copper, enzyme-

    doped special paper, Magnesium sandwiched between two laminating plastics is bound

    together while passing through rollers.

    In order to obtain a glucose-activated battery, we modify the urine-activated paper batteries

    that include Copper Chloride (CuC1) as the cathode in paper. Instead of Copper Chloride in

    the paper, we tried to use the glucose-oxidase (GOD) for the glucose-activated battery.

    Fig. 1 shows the detailed lamination process for the fabrication of battery. This whole stack

    consisting of the magnesium, enzyme-doped special paper, copper sandwiched between two

    plastic films into a roller which bounds the whole assembly together is laminated into a paper

    battery. A 0.10mm-thick lower transparent plastic film with an adhesive (Fig. la) is used as a

    substrate to fabricate the battery. A 0.2-thick copper layer are deposited (or taped) and

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    patterned for the positive electrode (Fig. la). After taping a 0.2-thick aluminium layer (Fig. 1

    b), the aluminium layer is patterned to provide electrical connection and electrodes. In Figs.

    l(c) and (d), 0.2-thick glucose-oxidase enzyme doped paper and magnesium layer are

    stacked on the copper layer. After placing the upper transparent plastic film with an adhesive

    layer on the stack (Fig. le), the whole layers are laminated into the micro-battery while

    passing through the heating rollers. Glucose supply slit and air exhalation slit are made on the

    upper plastic film in Fig. l(e).

    Fig. 2 shows the schematic diagram of a glucose-activated laminated battery consisting of a

    glucose-oxidase coated paper sandwiched between magnesium and copper layers.

    FIGURE 2.1.2 Glucose-activated laminated battery

    We can conclude that higher enzyme concentration results in faster oxidation of glucose, and

    hence better voltage and power are achieved. Thus we prefer for that. The first glucose-

    activated battery fabricated by a plastic lamination technology has been demonstrated for

    ondemand bio-applications and disposal usages. Basic concept of the battery is presented and

    the prototype battery can be fabricated by simple lamination processes using thin plastic film.

    3.2 Polymer based paper battery

    Now we try to replace the metal/metal oxide with polymer. In this process, the preparation of

    novel redox polymer and electronically conducting polymer-based electrode materials is

    essential. While it has recently been shown that it is possible to manufacture redox polymer

    based electrodes and batteries with high-capacities and very good cycling performances, the

    corresponding development within the field of electronically conducting polymers is

    ongoing. Conducting polymers are particularly interesting materials as devices based on these

    materials could be used as adaptable energy storage devices due to their inherent fast redox

    switching, high conductivity, mechanical flexibility, low weight and possibility to be

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    integrated into existing production processes. While conductive polymers are more

    environmentally friendly and cost-efficient than most metal containing electrode materials,

    the insufficient cycle stabilities and the high self-discharge rates have so far been limiting

    their applicability in commercial battery systems.

    In the past, several attempts have been made to produce energy storage devices consisting of

    entirely non-metal components. One way to improve the performance of nonmetal-based

    energy storage devices would be to use composite electrode materials of conductive

    polymers, for example, polypyrrole (PPy).

    Figure 3.2.1 Cell voltage vs time graph, Figure 3.2.2 charge capacity vs charge current

    In Figure 1a, the galvanostatic charge-discharge curves are shown for the battery based on the

    use of different charge and discharge currents. In these experiments, the cell was cycled for

    10 cycles at each current, and the results of the seventh of these cycles are depicted in the

    figure. To avoid problems due to overoxidation27 of the PPy coating, the charging of the cell

    was interrupted at a voltage just below the potential where this was found to take place for

    the different currents.The results in Figure 1a clearly show that the PPy coatings could be

    reversibly oxidized and reduced continuously even at very high rates. It can thus be seen that

    it was possible to decrease the charging time from 8 min at 10 mA to only 11.3 s at a current

    of 320 mA . As these currents correspond to rates of 7.5 and 320 C (i.e., charge/discharge

    within 1/7.5 and 1/320 of an hour), respectively, the results are in excellent agreement with

    the expected behaviour for an electrode material composed of a thin electro active layer on a

    large surface area substrate.

    Figure 1b shows the charge capacities calculated from the charge curves in Figure 2a, after

    normalizing with respect to the total weight of the composite material. It is seen that 72% of

    the electrode capacity obtained with a current of 10 mA was maintained when increasing the

    current to 320 mA.This demonstrates the outstanding ability of the material to undergo rapid

    oxidation and reduction. For comparison, most currently employed commercial rechargeable

    batteries generally require at least an hour to completely recharge because hastened charging

    increases the demands on the robustness of electrode reactions and shortens the cycling

    lifetime of the electrode.28 As is seen in Figure 2b, the charge capacities obtained at 10 and

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    320 mA were about 33 and 25 mAh g-1.This means that the capacity for this particular cell

    containing 37.5 mg conductive paper was approximately 1.2 and 0.9 mAh, respectively.

    Thus,the presented PPy-cellulose composite material is mechanically robust, lightweight, and

    flexible. It can be molded into various shapes and its thin sheets can be rolled to make very

    compact energy storage devices. The widespread availability of cellulose and the

    straightforward manufacturing of the composite are key factors for producing cost-efficient

    and fully recyclable paper-based batteries on a large industrial scale. Whereas the system

    described herein is limited in terms of the delivered cell potential, at least when compared

    with Li-ion batteries, the present battery holds great promise for applications in areas where

    Li-ion batteries are difficult to use, for example, in inexpensive large-scale devices or flexible

    energy storage devices to be integrated into textiles or packaging materials. The present

    paper-based battery system has also been shown to be compatible with very high charging

    rates. Together with the good cycling stability this makes the PPy-cellulose composite highly

    suitable for inclusion in future high-performance energy storage systems.

    3.3 Li-ion paper battery

    Secondary Li-ion batteries are key components in portable electronics due to their high

    powerand energy density and long cycle life. So we are trying to integrate Li-ion battery onto

    a paper battery.

    We integrated all of the components of a Li-ion battery into a single sheet of paper with a

    simple lamination process. Free-standing, lightweight CNT thin films (0.2 mg/cm2) were

    used as current collectors for both the anode and cathode and were integrated with battery

    electrode materials through a simple coating and peeling process. The double layer films

    were laminated onto commercial paper, and the paper functions as both the mechanical

    support and Li-ion battery membrane Due to the intrinsic porous structure of the paper, it

    functions effectively as both a separator with lower impedance than commercial separators

    and has good cyclability (no degradation of Li-ion battery after 300 cycles of recharging).

    After polymer sealing, the secondary Li-ion battery is thin (300 um), mechanically flexible,

    and has a high energy density. Such flexible secondary batteries will meet many application

    needs in applications such as interactive packaging, radio frequency sensing, and electronic

    paper. The CNT ink was applied to the SS substrate with a doctor blade method. A dried film

    with a thickness of 2.0 um was formed after drying the CNT ink on the SS substrate at 80 C

    for 5 min. Slurries of battery materials, Li4Ti5O12 (LTO) and LiCoO2 (LCO) (Predmaterials

    & LICO), were prepared. The battery slurries were applied to CNT/SS with the same doctor

    blade method. The slurries were dried at 100 C for 0.5 h. The battery electrode material on

    the CNT film forms a double layer film, where CNT films function as the current collectors.

    As shown in Figure 2a, the double layer LCO/CNT or LTO/CNT film was lifted off by

    immersing the SS in DI water followed by peeling with tweezers. Figure 2b shows a

    LTO/CNT film with a size of 7.5 cm *12.5 cm on a SS substrate (left) being peeled off in

    water (middle) and in a free-standing form (right). Previously, CNT thin films have been

    coated mainly on plastic substrate for use as transparent electrodes in various device

    applications, including solar cells and light emitting diodes. In this study, we found that

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    CNTs have weaker interaction with metal substrates when compared with plastic or paper

    substrates, which allows us to fabricate free-standing films with integrated current collector

    and battery electrodes. The double layer films obtained with this method are lightweight, with

    0.2 mg/cm2 CNT and 2~10 mg/cm2 electrode material. The free-standing double layer film

    shows a low sheet resistance (~5 Ohm/sq) and excellent flexibility, without any change in

    morphology or conductivity after bending down to 6 mm (Mandrel). Due to the excellent

    mechanical integrity of the double layer film and the loose interaction between the CNT film

    and SS, peeling off the double layer film from the SS is highly reproducible. After integrating

    the battery electrode materials on the lightweight CNT current collectors, a lamination

    process was used to fabricate the Li-ion paper batteries on paper. A solution of

    polyvinylidene fluoride (PVDF) polymer was coated on the paper substrate with an effective

    thickness of 10 um. The wet PVDF functions as a glue to stick the double layer films on

    paper. As shown in Figure 2c, the double layer films were laminated on the paper while the

    PVDF/ NMP was still wet. During this process, a metal rod rolls over the films to remove air

    bubbles trapped between films and the paper separator. After laminating LTO/CNT on one

    side of the paper, the same process was used to put LCO/CNT on the opposite side of the

    paper to complete the Li-ion battery fabrication. Figure 3.3.3 shows the scheme and a final

    device of the Li-ion paper battery prior to encapsulation and cell testing.

    Figure 3.3.1 Fabrication of li ion battery on paper

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    Although a paper-like membrane has been used as the separator for other energy storage

    systems including supercapacitors, it is the first demonstration of the use of commercial paper

    in Li-ion batteries, where paper is used as both separator and mechanical support. Xerox

    paper lacks microsize holes, which makes it an excellent separator for Li-ion batteries with

    the laminated electrode films. We tried coating battery electrode materials with the same

    slurries directly onto either side of Xerox paper, and we found occasional shorting of the

    device due to the leakage of battery electrode materials through paper. The lamination

    process provides an efficient approach for solving the leakage problem by using Xerox paper

    as a separator because the battery electrode forms a solid film and is integrated with the CNT

    film. CNT thin films form continuous mechanical supports and serve as electrical current

    collectors for the electrodes. The sheet resistance of the CNT thin film can be further

    decreased with acid doping such as with HNO3 or SOCl2.

    To evaluate the performance of paper as an effective separator membrane for Li-ion batteries,

    its stability in the electrolyte and the effect of the impurities. cells were fabricated with CNT

    films as cathodes, Li-metal as anodes, and Xerox paper as the separators. Cells were

    fabricated with CNT films as cathodes, Li-metal as anodes, and Xerox paper as the

    separators. paper shows low resistivity in the electrolyte.

    Figure3.3.2 Cycling performance of LTO nanopowder (C/5, 0.063ma) half cells

    To test the feasibility of using Xerox paper as the separator in Li-ion batteries with the

    lamination process, half cells were made with CNT/LTO or CNT/LCO with lithium foil as a

    counter electrode. Voltage profiles closely match those with metal current collectors and no

    apparent voltage drop was observed.

    Full cells with integrated current collectors and battery electrodes onto a single sheet or paper

    are fabricated with the lamination process. The laminated Li-ion paper battery has the

    structure illustrated in Figure 3.3.3. After the CNT/LCO and CNT/LTO films were laminated

    onto the two sides of Xerox paper, the whole device was sealed. The Li-ion paper battery

    is thin.

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    Due to the small thickness and the great flexibilities of current collectors using CNT thin

    films, the whole device shows excellent flexibility. No failure was observed for the paper

    battery after manually bending the device down to 6 mm for 50 times. The self-discharge

    performance could be further improved through device fabrication process modifications

    such as better sealing, longer vacuum baking times, and lower moisture levels by using

    standard dry rooms.

    Figure 3.3.3 Li ion paper battery energy increased through stacking

    The CNT weight in our device is less, therefore, the CNT cost is negligible. One method for

    increasing the total energy for the Li-ion paper battery is through stacking layer upon layer,

    as in Figure 4, where conductive CNT films function as current collectors, and extended

    metal strips at the edge serve as connections to the external circuit.

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    CHAPTER 4

    FABRICATION METHODS

    Doctor blade and lamination process were termed quite often. Now lets discuss about the two

    process:

    4.1 DOCTOR BLADE PROCESS

    Generic term for any steel, rubber, plastic, or other type of blade used to apply or remove a

    liquid substance from another surface, such as those blades used in coating paper. The term

    "doctor blade" is believed to be derived from the name of a blade used in conjunction with

    ductor rolls on letterpress presses. The term "ductor blade" eventually mutated into the term

    "doctor blade."

    Figure 4.1: Doctor Blade

    The doctor blade is fixed firmly in place by a doctor blade assembly, the amount of blade

    protruding from the holder being known as the blade extensiongenerally recommended to be K:H inch. It is set at certain optimum angles to ensure minimal blade and/or cylinder wear.

    The angle at which the blade contacts the cylinder (called the contact angle) is generally

    55:65, with 60 being most manufacturers' specified contact angle. The angle can be varied

    to correct various cylinder defects and/or inking problems. The contact angle also affects the

    distance between the blade and the nip between the gravure cylinder and the impression

    roller. This distance needs to be small enough to prevent drying-in, the undesirable drying of

    ink in the gravure cylinder cells. Many doctor blades oscillate across the width of the cylinder

    as a means of preventing cylinder wear and to remove solid bits of debris that can collect on

    the surface of the cylinder of the rear of the blade itself. The force or pressure with which the

    blade contacts the cylinder should be as minimal as possible, or should wipe the cylinder

    effectively but not contribute to blade and/or cylinder wear. (The process of setting the

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    contact angle and blade contact pressure is known as running in or toning in.) A related

    consideration is the unavoidable deflection of the blade during the print run, or, in other

    words, a slight curvature of the blade caused by the rotating cylinder. The contact angle and

    blade pressure should take into account deflection. The edge of the blade itself comes in a

    variety of configurations, either pre-honed by the manufacturer or honed in-house by the

    printer. Regardless of the configuration, the important considerations are effective wiping and

    the minimization of wear. Surface roughness of the cylinder is important for doctor blade

    lubrication. Gravure cylinders that are too smooth will increase doctor blade wear and

    cylinder damage. On some packaging presses, scavenger marks are deliberately etched into

    non-image areas corresponding to non-printing regions of the substrate (and which can be

    removed during finishing operations, such as trimming) to facilitate the removal of particles

    of ink or other debris from beneath the doctor blade.

    4.2 LAMINATION

    Lamination is the technique of manufacturing a material in multiple layers, so that the

    composite material achieves improved strength, stability, appearance or other properties from

    the use of differing materials. A laminate is usually permanently assembled by heat, pressure,

    welding, or adhesives.

    Roll laminator is used as high speed laminating machine. Lamination supplies for these

    laminators should be in roller form. This lamination process is very cost effective and time

    for making laminate is less. Bulk lamination is done by roll laminating machines.

    Laminating film passes over a big roller. Roll

    laminators can be divided into two types

    based on lamination process.

    Hot roll laminator

    Cold roll laminator

    Thermal laminating films are used in hot roll

    laminator. These lamination supplies have one

    side heat sensitive. This film is passed over

    heated roll and laminating adhesive starts

    melting. In the next step film with print goes

    between nip rolls and due to pressure and

    temperature it laminates. Figure 4.2 Roll Laminator

    Cold roll laminator don't use heat in lamination process. Laminating is done due to the effect

    of pressure. Film has one side with pressure sensitive adhesive. We use cold roll laminators

    where media have some heat sensitive characteristics. Laminate can be given different look

    like matte, glossy or satin finish by using various lamination supplies.

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    CHAPTER 5

    DURABILITY

    The use of carbon nanotubes gives the paper battery extreme flexibility, the sheets can

    be rolled, twisted, folded or cut into numerous shapes with no loss of integrity or

    efficiency, or stacked, like printer paper(or a voltaic pile),to boost total output. As well,

    they can be made in a variety of sizes, from postage stamp to broadsheet. It is essentially

    a regular piece of paper, but it is made in a very intelligent way, said Linhardt, We are

    not putting pieces together-it is a single, integrated device, he said. The components

    are molecularly attached to each other .The carbon nanotube is embedded in the paper,

    and the electrolyte is soaked into the paper. The end result is a device that looks, feels,

    and weighs the same as paper.

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    CHAPTER 6

    USE

    The paper-like quality of the battery combined with the structure of the nanotubes embedded

    within gives them their light weight and low cost, making them attractive for portable

    electronics, aircraft, automobiles, and toys, while their ability to use electrolytes in blood make

    them potentially useful for medical devices such as pacemakers. The medical uses are

    particularly attractive because they do not contain any toxic materials and can be biodegradable;

    a major drawback of chemical cells. However, Professor Sperling cautions that commercial

    applications may be a long way away, because nanotubes are still relatively expensive to

    fabricate. Currently they are making devices a few inches in size. In order to be commercially

    viable, they would like to be able to make them newspaper size; a size which, taken all together

    would be powerful enough to power a car.

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    CHAPTER 7

    CONCLUSION

    The Glucose activated battery fabricated by a plastic lamination technology has been

    demonstrated for on demand bio-application and disposal usages. Many different techniques

    are available to harvest raw energy to power wearable electronics, but the amount of raw

    energy and surface area or net mass that the wearable device permits limit the power yield.

    Thus all the different aspects of paper based battery fabrication technology with a

    modification like glucose based paper battery, polymer based paper battery, Li based paper

    battery have been studied.

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    REFERENCE

    1. Gustav Nystrom, Aamir Razaq, Maria Strmme, Leif Nyholm, and Albert

    Mihranyan; Nanotechnology and Functional Materials, Department of Engineering

    Sciences, The ngstrom Laboratory, Uppsala University, Box 534, 751 21 Uppsala, Sweden,

    and Department of Materials Chemistry, The ngstrom Laboratory, Uppsala University,

    Box 538, 751 21 Uppsala, Sweden: Ultrafast All-Polymer Paper-Based Batteries.

    2. Ki Bang Lee, Institute Of Bioengineering And Nanotechnology, Urine Activated Paper

    Batteries

    3. Liangbing Hu, Hui Wu, Fabio La Mantia, Yuan Yang, and Yi Cui; Department of

    Materials Science and Engineering, Stanford University, Stanford, California 94305. These

    authors contributed equally to this work: Thin, Flexible Secondary Li-Ion Paper

    Batteries.

    4. www.wikipedia.org

    5. www.pediain.com

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    QUESTIONS AND ANSWERS

    1. What is the width of the nanotube used?

    The width of the nanotube is 10-40 nm.

    2. What is Voc ?

    Voc stands for open circuit voltage.

    3. What is open circuit voltage ?

    Open circuit voltage is the voltage obtained when the load applied is zero.

    4. Whether paper battery can be used in automobiles?

    If paper battery is of the size of a newspaper, then it can be used in a car.

    5. What is LTO ?

    Li4Ti5O12

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