210 Catalyst

Product Name210 CATALYST 21000210NumberUpdate Date Mar 02,2015

Mar 01,2014

Additive for printing inkSafety Data Sheet Mar 02,2015Update date

Create Date

1.PRODUCT AND COMPANY IDENTIFICATION210 CATALYSTPRODUCT NAMETeikoku printing Inks Mfg.Co.,Ltd.COMPANY IDENTIFICATION8-43-2 Nishi-Ogu,Arakawa-Ku,Tokyo 116-0011,Japan ADDRESSTHE LABORATORY OFFICE. MANUFACTURER'S NAME81-3-3800-9911 TELEPHONE NUMBER FOR

INFORMATION81-3-3800-9919 FAX NUMBER FOR [email protected] MAIL ADDRESS+81-3-3800-6760THE LABORATORY OFFICE.) EMERGENCY TELEPHONE NUMBERAdditive for printing ink.RECOMMENDED USES AND

RESTRICTIONS ON USE21000210NUMBER

2.HAZARDS IDENTIFICATION(GHS CLASSIFICATION)

Category 4ACUTETOXICITY(Inhalation;Vapours)GHS LABEL ELEMENTS SYMBOL

Warning SIGNAL WORDH332 Harmful if inhaled. HAZARD STATEMENT

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.PRECAUTIONARY STATEMENTSSAFETY PRECAUTIONARYSTATEMENTS

P271 Use only outdoors or in a well-ventilated area.P312 Call a doctor if you feel unwell.FIRST-AID PRECAUTIONARY

STATEMENTSP304P340 IF INHALED: Remove person to fresh air and keepcomfortable for breathing.P403P235 Store in a well-ventilated place. Keep cool.STORAGE PRECAUTIONARY

STATEMENTSP501 Dispose of contents/container in accordance withlocal/regional/national/international regulations.

DISPOSAL PRECAUTIONARYSTATEMENTS

3.COMPOSITION/INFORMATION ON INGREDIENTSMIXTURE.SINGLE OR MIXTURE

Chemical Name Wt Cas No. Application of LawHexamethylene diisocyanate 1.0 822-06-0 Functional polyisocyanate 90.0-100.0 -

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Korea "Toxic Chemicals Control Law" applicable to the observational chemicalsIndustrial Safety and Health LawDangerous and Harmful Substances Subject to IndicateIndustrial Safety and Health LawDangerous and Harmful Substances Subject to NotifyOrdinance on Prevention of Organic Solvent PoisoningFirst-class organic solventOrdinance on Prevention of Organic Solvent PoisoningSecond-class organic solventOrdinance on Prevention of Organic Solvent PoisoningThird-class organic solventLaw concerning Pollutant Release and Transfer Register Class 1 Designated ChemicalSubstancesLaw concerning Pollutant Release and Transfer Register Class 2 Designated ChemicalSubstancesPoisonous and Deleterious Substances Control Act Chemical Substances Subject

4.FIRST-AID MEASURESRemove person immediately to fresh air. Keep warm andcomfortable for breathing. Immediately call a doctor.

INHALATIONTake off immediately all contaminated clothing.Wash with plentywater. Continue rinsing. If skin irritation or rash occurs: Getmedical advice/attention.

SKIN CONTACT

Immediately rinse with plenty water or warm water for 15minutes. Get medical advice/attention.

EYE CONTACTRinse mouth. Do NOT induce vomiting. Immediately call a doctor.INGESTION

5.FIRE-FIGHTING MEASURESNonhazardous materials.SPECIFIC HAZARDSSince combustion gas contain toxic gases such as carbonmonoxide, avoid smoke inhalation at the time of fire fighting.Use Form , Dry chemical , CO2 , proper fire-extinguishers. Donot use straight stream of water for the extinguishing media.

EXTINGUISHING METHODS ANDEXTINGUISHING MEDIA

Extinguish a fire from the windward.In case of fire in the periphery, move movable container to thesafe place immediately.Prohibit unauthorized person's entry to the periphery of thefire site.Lead unauthorized persons to the safe place.Use fire-extinguishing powder, fire-extinguishing foam, carbondioxide (CO2), and sand for fire fighting.Spray water for cooling the container.Be sure to wear suitable protective equipment (protectivegloves/eye protection/face protection, etc.) at fire fighting .

FIRE EXTINGUISHING NOTES ANDFIRE FIGHTING MEASURES

6.ACCIDENTAL RELEASE MEASURESEvacuate personnel to safe area. Evacuate non-essentialpersonnel. Shut off all sources of ignition. No flares, smokingor flame in area. Wear proper protective equipment.

PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT, ANDEMERGENCY PROCEDURES

Do not wash away spills into sewer, watercourse or river.ENVIRONMENTAL PRECAUTIONSFor small spill, absorb spills with inert materials( e.g. drysand or earth), then place in a chemical waste containers.For large spill, dike for later disposal, cover spills withfoam, then place in a chemical waste container usingnon-sparking tools.Wipe off residual spill by using paper.

METHODS AND MATERIALS FORCONTAINMENT AND METHODS ANDMATERIALS FOR CLEANING UP

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7.HANDLING AND STORAGE PRECAUTIONSUse only outdoors or in a well-ventilated area.Do not handleuntil all safety precautions have been read and understood.Wearprotective gloves/protective clothing/eye protection/faceprotection.Keep away from heat/sparks/open flames/hot surfaces.No smoking.Use explosion-proof electrical/ventilating/lightingequipment.Use only non-sparking tools.Do not get in eyes, onskin, or on clothing. Avoid breathingdust/fume/gas/mist/vapours/spray. Wash hands thoroughly afterhandling.

HANDLING

Store locked up.Store in a well-ventilated place. Keep cool.Keepcontainer tightly closed.

STORAGE

8.EXPOSURE CONTROLS AND PERSONAL PROTECTIONNot Classified.CONTROL PARAMETERSUse this product only in a totally enclosed systems or localexhaust ventilation. Make available in the work area withemergency shower and eyes washer. Ground/bond container andreceiving equipment.Use explosion-prooflectrical/ventilating/lighting equipment.Use only non-sparkingtools.Take precautionary measures against static discharge.

ENGINEERING MEASURE

Wear respiratory protection.RESPIRATORY PROTECTIONWear eye protection/face protection.EYE PROTECTIONWear protective gloves/protective clothing/eye protection/faceprotection.

SKIN AND BODY PROTECTIONWear protective gloves.HAND PROTECTIONThe adsorption in the masks is exchanged at regularity or eachuse.

OTHER PROTECTION

9.PHYSICAL AND CHEMICAL PROPERTIESLiquid.APPEARANCE (Form)Light-YelllowAPPEARANCE (color)Odour of Organic Solvent.ODOURNo information is available.pHNo information is available.MELTING POINTNo information is available.BOILING POINT()225.0FLASHPOINT()0.9-9.5Hexamethylene diisocyanate)UPPER/LOWER FLAMMABILITY OR

EXPLOSIVE LIMITSNo information is available.VAPOUR PRESSURENo information is available.VAPOUR DENSITY1.1-1.2SPECIFIC GRAVITY (Relative

Density)Not soluble in water.SOLUBILITYSoluble in organic solvents.No information is available.n-OCTANOL/WATER PARTITION

COEFFICIENTNo information is available.AUTO-IGNITION TEMPERATURE()No information is available.DECOMPOSITION TEMPERATURE()

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10.STABILITY AND REACTIVITYIt stabilizes under the normal temperature.STABILITYStrong oxidizing agents.INCOMPATIBLE MATERIALSHeat, flames and sparks.High temperature and humidity.CONDITIONS TO AVOIDNo information is available.HAZARDOUS REACTIONSOCCURRING

UNDER SPECIFIC CONDITIONSThe harmful gases such as CO and NOx.HAZARDOUS DECOMPOSITION

PRODUCTS

11.HAZARD INFORMATIONHexamethylene diisocyanate Oral LD50747mg/kg(Rat) Dermal LD50593mg/kg(Rabbit) Inhalation Vapours LC5020ppm(Rat) Inhalation DustMist Classification not possible.

ACUTE TOXICITY

Hexamethylene diisocyanate Category 1A1C(Rabbit)SKIN IRRITATION/CORROSIONHexamethylene diisocyanate Category 1(Rabbit)SERIOUS EYE DAMAGE/IRRITATIONHexamethylene diisocyanate RESPIRATORYCategory 1(Human) SKIN SENSITIZATIONCategory 1(Cavy)

RESPIRATORY OR SKINSENSITIZATION

Hexamethylene diisocyanate Category 1Respiratory organs(Rat)

SPECIFIC TARGET ORGANTOXICITY-SINGLE EXPOSURE

Hexamethylene diisocyanate Category 1Respiratory organs(Human)

SPECIFIC TARGET ORGANTOXICITY-REPEATED EXPOSURE

12.ECOLOGICAL INFORMATIONNo information is available.ECOTOXICITYNo information is available.PERSISTENCE AND DEGRADABILITYNo information is available.BIOACCUMULATIVE POTENTIALNo information is available.MOBILITY IN SOILNo information is available.HAZARD TO THE OZONE LAYER

13.NOTES ON DISPOSALDo processing such as detoxification, stabilization, andneutralization to lower hazard level as much as possible beforedisposal.

WASTE FROM RESIDUES

Disposal of container and contents must be entrusted to wastedisposer authorized by local authorities.Clean the container for recycling or appropriately dispose underthe related laws and regulations and the standard of localgovernment.

CONTAMINATED CONTAINER ANDCONTAMINATED PACKAGING

In case of disposal of empty container, remove the contentscompletely.

14.TRANSPORT INFORMATIONIt is not classified in the definition.UN NUMBERIt is not classified by definition.NAME OF PRODUCT (UN PROPER

SHIPPING NAME)

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This product is not classified in the definition.UN CLASSIFICATION (TRANSPORTHAZARD CLASS)

It is not classified by definition.PACKING GROUP

NoMARINE POLLUTANT (Y/N)171INDICATION NUMBER FOR

EXTINCTION IN JAPANIt is necessary to retain yellow card at the time oftransport. Do not transport with food and feed.For transportation, avoid direct sunlight, load withoutcontainer damage, corrosion, and leakage and ensure preventionof load shift.Do not load heavy goods on top of it.

PRECAUTIONS

15.REGULATORY INFORMATIONPlease refers national measures that may be relevant.All materials for this product are registered in the CAS, TSCA,EINECS(ELINCS).

REGULATIONS RULE

Industrial Safety and Health Law.Law concerning Pollutant Release and Transfer Register.Road Act (dangerous articles transportation on the tunnels underthe water,long tunnels and else for loading limitation)Dangerous article ship transportation and storing rule4th group Dangerous Substance 4th group petroleum under theJapanese Fire Defense Law.Poisonous and Deleterious Substances Control Act.

16.OTHER INFORMATION1)ACGIH2010)2)Japan society for occupational health.(2012-2013)3)ICSC CARD http//:nihs.go.jp/ICSC4)Kanagawa environmental research center date base.5)Nite incorporated administrative agency national institute oftechnology and evaluation.6)Raw material safety data sheet.7)Guideline of GHS(Japan Chemical Industry Association)8)JIS Z 7252-20099)JIS Z 7253-201210)IARCvol.185)

REFERENCE

This information is furnished without warranty, express orimplied, except that it is accurate to the best knowledge ofTeikoku Printing Inks Mfg. Co., Ltd. It relates only to thespecific material designated herein, does not relate to use incombination with any other material or in any process. TeikokuPrinting Inks Mfg. Co., Ltd. assumes no legal responsibility foruse of or reliance upon this information.

CHANGE IN CONTENTS OFDESCRIPTION, ETC.

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210 Catalyst

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