2011 SOPAC Meeting Fiji Petersen

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    Modern SeafloorMassive Sulfide

    Deposits

    S. Petersen

    Seafloor Massive Sulfides (SMS)Seafloor Massive Sulfides (SMS)

    Global characteristics, distribution,Global characteristics, distribution,and regional Pacific potentialand regional Pacific potential

    Sven PetersenSven Petersen

    (IFM-GEOMAR)(IFM-GEOMAR)

    SPC-EU EDFDeep Sea Minerals Workshop,

    Nadi, Fiji, 06.-08. June 2011

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    Modern SeafloorMassive Sulfide

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    influx of cold seawater (recharge)

    H2O = H+ + OH-

    Mg2+ + OH- = Mg(OH)2precipitation

    excess H+ pH drop to ~ 4-5heating of seawater to > 400C

    leaching of Cu, Zn, Fe, Au, S etc. from

    the surrounding rockformation of hydrothermal precipitates

    due to mixing of hot fluid with seawater

    150C

    375C

    Reaction Zone

    Gabbro

    DikeSection

    Extrusives

    Magma

    Recharge

    Discharge

    >30% water

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    Modern SeafloorMassive Sulfide

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    S. PetersenHydrothermal sites in theSouth Atlantic

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    distribution of seafloor hydrothermal systems in the world ocean

    Where do they form ?

    latest discoveries:Cayman TroughWallis & FutunaNorthern MatasPiterskoe

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    Modern SeafloorMassive Sulfide

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    distribution of seafloor hydrothermal systems in the world ocean

    Russian exploration claim area

    Chinese exploration claim area

    Manafe & DFI

    mining liscence

    Nautilusmining liscence

    massive sulfides as aresource ?

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    Modern SeafloorMassive Sulfide

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    Examples are known in very different tectonicExamples are known in very different tectonicsettingssettings::

    mid-ocean ridges(superfast, fast, intermediate, slow, ultraslow spreading centers)

    off-axis volcanoes

    intracontinental rifts & rifted margins

    intraoceanic back-arc basins

    intracontinental back-arc basinsvolcanic island arcs

    (Hannington et al., 2005)

    Basic Facts

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    Modern SeafloorMassive Sulfide

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    other factors: water depth, distance to land, EEZ ?

    massive sulfides as aresource ?

    how many ?

    grade ?

    tonnage?

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    Modern SeafloorMassive Sulfide

    Deposits

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    S

    ource:SOE

    ST(Hawaii)

    >80 % look like this !

    NOAA

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    at fast-spreading ridgesat fast-spreading ridges

    short lived hydrothermal activityshort lived hydrothermal activity

    cyclic volcanic and hydrothermal activitycyclic volcanic and hydrothermal activity

    quick burial by extrusivesquick burial by extrusives

    90% of the metals lost to the plume90% of the metals lost to the plume

    massive sulfides atmid-ocean ridges

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    Modern SeafloorMassive Sulfide

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    1 cm

    pyrite - chalcopyrite - sphalerite

    1 cmisocubanite -

    pyrrhotite - wurtzite

    average geochemistry of MORB-

    hosted massive sulfides

    mainly pyrite with5 % Cu9 % Zn

    0.3 ppm Au

    (strong bias due to sampling of chimneys)

    massive sulfides atmid-ocean ridges

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    systems at slow-spreadingsystems at slow-spreadingridges tend to be larger !ridges tend to be larger !

    commonly located off-axiscommonly located off-axis

    deep penetrating faults allowdeep penetrating faults allowlong-lasting fluid flowlong-lasting fluid flow

    some sites associated withsome sites associated with

    mantle rocksmantle rocks

    massive sulfides atmid-ocean ridges

    ne

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    Modern SeafloorMassive Sulfide

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    N

    0 5 10 km

    1520'

    Nfrac

    turezo

    ne

    basaltic lava floor

    mantle rocks

    Logatchev

    Logatchev hydrothermal field2 hydrothermally active fields

    largest field 800x300 m

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    Logatchev hydrothermal field

    1 cm

    64ROV-11D

    hosted in mantle rockswater depth 3000mvery high Cu and Au grades !

    23 % Cu

    4 % Zn

    11 ppm Au

    Is it possible to utilize this ?

    atth

    esurf

    ace

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    -u rich chimneyu rich chimney

    wasteaste

    massive sulfides as aresource ?

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    Modern SeafloorMassive Sulfide

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    S. Petersenmassive sulfides inback arc basins

    Hydrothermal sites in

    Papua New Guinea

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    PacManus samples

    10.3 % Cu

    22.6 % Zn

    0.5 % Pb

    205 ppm Ag

    14 ppm Au

    PACMANUS hydrothermal field

    host rocks: volcanic suite from basalt to rhyolithewater depth: 1650m

    Yeats (CSIRO)

    atth

    esurf

    ace

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    Modern SeafloorMassive Sulfide

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    58-GTVA

    altered dacitealtered dacite

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    exploring companies: exploring countries:Nautilus South KoreaBluewater, and others Russia China

    (France/Germany)

    PacManus

    20102010

    Susu Knolls

    =1. mine site ?

    massive sulfides as aresource ?

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    NOAA

    massive sulfides atisland arc volcanoes

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    mid-ocean ridges island/back arcsbasalt exposed mantle interm. - felsic

    Fe, Cu, Zn Cu, Fe Cu, Zn, Pb, Ba

    Co Au, Co, Ni, Sn As, Hg, Sb, Au, Ag~1 ppmAu 3-10 ppmAu 530 ppm Au!

    deep water deep water shallow water

    source: geochemical differences in the rocks themselves+ additional factors (magmatic input, biology, zone refining, ... )

    massive sulfides as aresource ?

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    high grade (CuAuZn) or large deposits

    massive sulfides as aresource ?

    TAG

    Middle Valley

    Manus

    Suiyo

    KrasnovSemyenov

    Kairei

    13N, EPR

    Atlantis II

    Logatchev

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    Will these deposits by of commercial interest ?

    massive sulfides as aresource ?

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    Uchaly + Novo Uchaly (>220 Mio t)

    compared to those on land ?

    Gay (>380 Mio t)

    massive sulfides as aresource ?

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    NOAA

    Kelley et al., 2001

    (C

    )Nationa

    lGeograph

    ic1

    992

    MARUM

    massive sulfides as aresource ?

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    typical EPR chimneys 0.x Mio t

    Atlantis II Deep (Red Sea) 94 Mio t drilledore mud from brine pool

    Middle Valley (JFR) 8-10 Mio t drilledlarge sulfide lenses in sediments (Fe dominated)

    13N Seamount (EPR) 5-10 Mio t ?

    Krasnov, Semyenov ~ 15 Mio t ?large pyrite mounds (Fe dominated)

    TAG (MAR) 4 Mio t drilled(low grade in interior)

    Suzu Knolls; Manus Basin >2 Mio t drilled(indicated + inferred)

    massive sulfides as aresource ?

    M d S fl

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    high grade or large deposits

    XX

    XFe-only

    Xtoo small

    X

    too deep ?

    size ?

    X

    too deep ?low grade ?

    X

    too small

    size ?

    TAG

    Middle Valley

    Manus

    Suiyo

    KrasnovSemyenov

    Kairei

    13N, EPR

    Atlantis II

    Logatchev

    massive sulfides as aresource ?

    M d S fl

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    Mining seafloor massiveMining seafloor massivesulfides needs:sulfides needs:

    2 mio tonnes of ore /year

    (~ 200x200x20m)life-time of 10 years(= 20 mio t of ore !)(may be contained in several orebodies !)

    Currently not known !

    Will mining of seafloor massive sulfides replace land mining?Will mining of seafloor massive sulfides replace land mining?

    massive sulfides as aresource ?

    M d S fl

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    Modern SeafloorMassive Sulfide

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    worldwide VMS Districts (>> 6 billion tonnes)

    GSC

    massive sulfides as aresource ?

    50 % in only 50 deposits of >50 mio t

    M d S fl

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    a snapshotin time

    At most the modern oceans contain only 175 million years worth of metal !Current exploration is considering only young crust !One giant deposit every 200 mio years !

    Why is the geologic record so well endowed?

    massive sulfides as aresource ?

    M d S fl

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    Most seafloor sites:Most seafloor sites:

    are too small

    are of low grade

    occur too deep

    are too far from land

    occur in the Area (politics)

    or are active and too hot

    but: mining of few sites might beeconomically feasible

    massive sulfides as aresource ?

    Modern Seafloor

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    Modern SeafloorMassive Sulfide

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    S. Petersenregional Pacific potential

    Modern Seafloor

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    Modern SeafloorMassive Sulfide

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    S. Petersenregional Pacific potential

    Modern Seafloor

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    Opportunities:

    There is still a large potential for newdiscoveries using regional surveys!

    regional Pacific potential

    Modern Seafloor

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    Back-arc spreading centers still have large potential todiscover new sites ! By far most of those will be small.

    Intra-plate volcanoes are underexplored but have limitedpotential for sulfide deposits.

    Island-arc volcanoes have large potential, but frequent

    eruptions and shallow water depth may limit sulfidepotential near the seafloor.

    Where are the large deposits

    in the Pacific region ?

    regional Pacific potential

    Modern Seafloor

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    Modern SeafloorMassive Sulfide

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    Current research and exploration ismainly related to active deposits at ornear spreading axis.

    many deposits are buried underneathsediments or lava.

    Systematic surveys for hidden depositsare lacking.

    Regional geological and geophysicalexploration using towed systems orAUVs is necessary to define resource

    potential.

    seafloor hydrothermal systemsseafloor hydrothermal systems

    Challenges

    Modern Seafloor IFM GEOMAR

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    6000m depth rating, 4Kn max. speed24 h station timeturbidity sensor (ECO), Eh-sensor (NIST

    Japan), CTD, 120/410 kHz side-scansonar (Edgetech), ADCP

    3 konfigurations200/400 kHz multibeam (RESON 7125D)or sub-bottom profileror b/w digital camera + flash

    underwater navigation:transponder (LBL, USBL)inertial navigation (Kearfott)

    IFM-GEOMARsAUV ABYSS

    Modern Seafloor

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    central part= 65 km !

    Reson Seabat 7125400 kHz

    AUV-basedbathymetry

    Modern Seafloor

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    S. PetersenAUV-basedbathymetry

    Modern Seafloor

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