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    ABSTRACT

    Many exhaust gas analyzers only calculate the Air Fuel Ratio

    (AF) based on equations derived for the special case of

    combustion without exhaust gas recirculation (EGR), and

    therefore do not represent the combustion AF during lean

    operation with EGR. Equations that are not subject to this

    limitation will be presented. Using these equations to provide

    measurements of the combustion AF and total inert EGR is

    encouraged as they relate more directly to what governs the

    combustion process.

    INTRODUCTION

    Many test facilities utilize exhaust gas analysis equations thatare deduced from the combustion reaction equation for a

    general hydrocarbon fuel that may contain oxygen and does

    not include EGR:

    (1)

    An example of literature using this equation is [1]. Other

    literature investigating variations on this equation are [2,3,4].

    This paper presents the derivations for Air Fuel Ratio (AF)

    and EGR concentration calculations based on the general

    combustion equation including EGR:

    (2)

    The implications of the revised equations are relevant for lean

    operation and especially for simultaneous lean and EGR

    operation and thought advantageous as they relate more

    closely to what governs the combustion process. This type ofoperation is relevant for diesel engines and more recently the

    advent of direct injection gasoline engines and Homogenous

    Charge Compression Ignition (HCCI) engines. Furthermore

    equations for inert EGR and exhaust inert concentration are

    given. Finally, the calculation of carbon balanced exhaust

    oxygen concentration is given as a good complement to the

    actual exhaust oxygen measurement.

    It is suggested that ideally these new measurements be made

    readily available by commercial exhaust analyzers.

    It should be noted that the reaction equation (2) used as a

    basis in this paper is still somewhat idealized. For example, idoes not consider the effects of humidity, assumes no water

    in the fuel, ignores water drop out in cooled EGR systems

    and ignores the effect of measurement disturbance from the

    finite samples of the analyzers. Some discussion of these

    effects are included in [2,3,4].

    THEORETICAL ANALYSIS &

    RESULTS

    The data illustrated in the following was obtained on a Direc

    Injection Gasoline engine running both stratified and

    homogeneous lean combustion as well as homogeneous

    stoichiometric combustion. The measurements of intake andexhaust constituents were done with industry standard

    emissions analyzers typical in vehicle emission laboratories

    (VEL) of ULEV2 accuracy.

    General Air Fuel Ratio and EGR Definitions and

    their Calculation from Emissions

    2010-01-1285

    Published

    04/12/2010

    Martin MllerDelphi Corp.

    Copyright 2010 SAE Internationa

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    AIR/FUEL RATIO (AF) EQUATIONS &

    DEFINITIONSThe oxygen and carbon balanced AF for the general

    combustion reaction equations of (2) becomes:

    (3)

    (4)

    where

    (5)

    As opposed to the special case equations for (1), the general

    equations for (2) contain an EGR dependency. They becomeidentical for EGR=0. The AF that is calculated depends on

    which EGR is used in the equation as shown in Table 2. This

    means that the AF that is commonly reported by emission

    benches and Wide Range Air Fuel Ratio (WRAF) sensors is

    the fresh airflow AF, also referred to as the throttle AF, since

    it does not account for any EGR. The ratio between the

    throttle AF and combustion AF is shown vs. throttle AF and

    total EGR in Figure 2, and is seen to differ up to 30% during

    lean operation with significant EGR. It can be argued that the

    combustion process relates more closely to the combustion

    AF and inert EGR, which is why providing those

    measurements is advantageous.

    The practical implications of this are the required additional

    measurements of EGR when measuring combustion, or intake

    port, AF as compared to the common practice when

    measuring throttle (fresh air) AF. External EGR is measured

    by CO2 in the intake and exhaust and is commonly available.

    Until recently measuring internal EGR was impractical, but a

    new more practical technique was recently described in [5,6].

    Figure 1. Lean operation results in several AF

    definitions. They all co-incide for stoichiometric

    operation. The WRAF sensor AF and common emission

    bench calculated AF are both measurements of throttle

    (= fresh) AF which only accounts for the fresh airflow

    which has not been recycled.

    Table 2. AF definitions and their EGR dependencies.

    Table 3. Relation between AF definitions.

    Table 1. Editorial notes

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    Figure 2. AF-X / AF-Throttle = f(AF-Throttle, EGR-Y)

    where X = Intake Port for Y = external and X =Combustion for Y = Total. The surface is a curve fit of

    the measured data points obtained by post-processing

    measured exhaust concentrations usingequations (3)

    and(4).

    The AF calculations derived for (1) are identical to (3) and

    (4) with EGR = 0. The AF dependency on EGR is purely a

    multiplicative effect on the exhaust oxygen term and is most

    clearly apparent in the oxygen balanced form, equation (3).

    As a special case, this means that its absence in the non-

    general equations is not of consequence for stoichiometric

    and rich operation.

    The Throttle AF is calculated when ignoring recycled

    exhaust. The Combustion and Throttle AF ratio relate as:

    (6)

    Stoichiometric combustion utilizes all oxygen, leaving the

    exhaust gas practically oxygen free, . For this

    special case , and a distinction between throttle

    and combustion AF is irrelevant. This special case is the

    common current practice. Not including EGR dependence is

    essentially not properly accounting for the air (oxygen and

    nitrogen) that is present in the exhaust due to recycling. For

    lean operation the distinction becomes necessary, e.g. for

    diesel engines or direct injection gasoline engines running

    stratified combustion.

    The data points in all the figures were obtained on a Direct

    Injection Gasoline engine running both stratified and

    homogeneous lean combustion as well as homogeneous

    stoichiometric combustion under a wide range of speed, load

    AF and EGR conditions. All the following figures with meas

    points as independent axis have AF and Intake EGR vs

    measurement point number ordered as shown in Figure 3.

    Figure 3. Combustion AF and Intake EGR vs.

    measurement points illustrated in the following figures.

    ENGINE MANAGEMENT SYSTEMS

    (EMS) IMPLICATIONSIn order to take full advantage of providing the new AF and

    EGR measurements, EMS control algorithms should in

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    concert convert to these units. This may be done relatively

    easily by implementing an EGR estimation model in the EMS

    and using this together with Throttle AF measured by a

    WRAF sensor to look up for example the combustion AF in a

    tabulation of the surface shown in Figure 2.

    EGR EQUATIONS AND DEFINITIONSThe following EGR definitions are used:

    (7)

    (8)

    (9)

    (10)

    (11)

    This is a total of 8 EGR definitions when applying (11) to(7,8,9,10), and the equations for their calculation from

    exhaust and intake constituent measurements are listed

    below. The measurement most commonly provided by

    emission bench measurements is an approximation of

    . However, it can be argued that the Total Inert

    EGR concentration is what most directly affects

    combustion. [7] includes an example of such a discussion.

    Total EGR

    The oxygen and carbon balanced EGR equations for (2)

    becomes:

    (12)

    where

    (13)

    The coefficients A,B and C are specific of the balancing

    method.

    Oxygen balanced

    (14)

    (15)

    (16)

    (17)

    (18)

    Carbon balanced

    (19)

    (20)

    (21)

    (22)

    (18)

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    The exhaust measurement is corrected for the water not

    reaching the exhaust analyzer:

    (23)

    It is assumed that the water in the intake sample is negligible,

    giving:

    (24)

    Inert EGR and Exhaust Inert concentration

    During lean operation only part of the recycled gas is inert.

    Therefore does not represent the inert dilution of the

    combustion fresh charge as is the case for stoichiometric andrich operation. Inert EGR affects combustion most directly,

    which is why it should be readily available as a measurement.

    It is the product of total EGR and inert percentage of the

    exhaust. The exhaust inert percentage measurement should

    also be made readily available.

    (25)

    where

    (26)

    (27)

    and the coefficients A,B, E and F are specific of

    the balancing method.

    Oxygen balancing

    : measured is corrected to a wet basis

    using (37).

    , are given by (14) and (15).

    (28)

    (29)

    Carbon balancing

    : carbon balanced is corrected to a

    wet basis using (37).

    , are given by (19) and (20).

    (30)

    (31)

    is given by (35). It is the carbon balanced exhaus

    oxygen concentration.

    The implemented exhaust inert percentage calculationsshould be truncated to 100%.

    It is interesting to note that only depends on

    AF and not on , and it is not very different to that of air

    Therefore, the ratio of the molar weights of air and exhaust

    gas varies slightly with air fuel ratio. Since the calculations

    describing this variation are rather complex, and the variation

    from unity is small, it is natural to investigate how wel

    approximates unity. Figure 4 shows

    approximation errors of 5% for lean operation, which would

    be considered significant enough for its inclusion. Howeverapparent measurement errors cause the measured exhaus

    molar weights to be too low, so the real approximation errors

    are less than 5% and the approximation of = 1

    is reasonable.

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    Plots a,b,c are all ordered with respect to lambda illustrated in

    plot c (right y-axis). Plot c shows how well

    approximates unity. The approximation errors are small, and

    decrease with lean operation as expected.

    Plots b,d show that these errors are reduced when calculating

    and instead increase with lean operation

    due to the multiplicative effect of .

    Plot b shows less than 100% for

    stoichiometric operation due to some measured exhaust

    oxygen content (see Figure 6).

    External EGR

    The definition gives:

    (32)

    Intake EGR

    For a non-zero residual fraction, , the

    external EGR is not equal to the intake EGR. Intake EGR

    relates the externally recycled mass (flow) to the total mass

    that the cylinder inducts from the intake manifold. External

    EGR relates the externally recycled mass (flow) to the total

    cylinder mass, which includes residuals.

    (33)

    Internal EGR (residuals)

    Until recently, measuring internal EGR was very difficult, but

    a new practical technique was recently described in [5-6]

    [5-6] presented the Residual Estimation Tool (RET) which

    provides on-line residual estimation. It does so by adjusting

    key parameters of a crank-angle resolved combustion mode

    until its behavior matches quantities that can more easily be

    measured. Required measurements include crank angle

    resolved cylinder pressure and combustion boundary

    conditions such as average intake and exhaust pressures and

    temperatures as well as air flow. The residual estimate of the

    converged model is the provided virtual measurement. The

    key advantage of this approach is that it does not rely on in-

    cylinder gas sampling nor crank-angle resolved boundary

    pressures, which keeps the equipment requirement relatively

    simple and the convergence time low enough to run on-line.

    Residual measurement was not performed during collection

    of the data shown in this paper as the technique of [5-6] was

    not available at the time. Since the engine used for data

    collection did not have cam-phasing, the very coarse

    approximation of the theoretical relationship between

    geometrical compression ratio and internal EGR was

    assumed, which was 8%. Clearly this is a coarse

    approximation since any valve overlap at low load will have

    significantly higher residuals. However, it is sufficient to

    Figure 4. Illustration of the impact of approximating .

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    illustrate the influence of residuals on the various definitions

    presented here.

    Comparison with commonly used calculation

    Commonly implemented calculations do not distinguish

    between intake and external EGR as the effect of residuals is

    not included. The commonly used approximation of external/

    intake EGR is:

    (34)

    The error of the approximation is illustrated below, and is

    found to be relatively small.

    Figure 5. Illustration of the error when calculating

    intake and external EGR as the ratio of intake to exhaust

    dry concentrations.

    MISCELLANIOUS CALCULATIONS

    Carbon balanced exhaust oxygen concentration

    calculation

    A sanity check of the measured exhaust concentration can

    be made with that calculated through the measurements ofother exhaust species. Carbon balancing gives:

    (35)

    is on the same wet, dry or partially wet basis as

    the other concentrations.

    Note that it is not EGR dependent.

    Figure 6. Comparison of measured exhaust oxygen

    concentration with that calculated by carbon

    balancing shows good correspondence.

    Several regions show apparent erroneous

    measurements. This illustrates the advantage of

    as a check on measurements. Note the effect

    of measurement errors on for example AF as seenin Figure 3.

    (H2O) calculation

    is calculated by assuming a fixed value for the water/

    gas equilibrium constant, K, which relates the concentrations

    of , , and water vapor under equilibrium

    conditions:

    (36)

    where is on the same wet, dry or partially dry basis as

    the other concentrations. According to [1] K=3.8 is

    recommended.

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    Converting exhaust emission concentrations to a

    wet basis

    Usually, the exhaust sample passes through an ice bath that

    removes any water present so that the analyzers measure a

    dry sample, in which case . When the wet

    concentration is needed the following correction should be

    applied, exemplified for the constituent XX:

    (37)

    SUMMARY/CONCLUSIONS

    Emission analyzers today typically only provide a

    measurement of Throttle (=Fresh) Air Fuel Ratio (AF) and an

    approximation of External EGR. However, the combustion

    process relates more directly to the Combustion AF and TotalInert EGR concentration, and is especially relevant for diesel

    engines and direct-injection gasoline engines running

    stratified combustion and most recently Homogeneous

    Charge Compression Ignition (HCCI) engines. The two AF

    definitions may for example differ by 30% during typical

    stratified operation.

    In response, this paper presents the several AF and EGR

    definitions that exist for the general combustion reaction

    which includes EGR. Their definitions and calculation from

    exhaust and intake constituent measurements have been

    presented. It is encouraged that exhaust analysis equipment

    should provide this expanded list of measurements that relate

    more closely to what governs the combustion process. It is

    acknowledged that adding AF and EGR definitions increases

    complexity and that the additional AF measurements are

    more involved in practice as they require simultaneous

    measurements of EGR. This is particularly challenging when

    measuring internal EGR (residuals) although recent advances

    reported in the literature are making this substantially easier.

    Nevertheless, providing these new measurements may prove

    worthwhile especially for sensitive combustion processes

    such as HCCI.

    It should be noted that Engine Management System (EMS)control algorithms may relatively easily be converted to such

    new AF and EGR units. This includes the conversion of

    measured Throttle AF by the WRAF sensor by using an EGR

    estimation model and a tabulated relationship.

    Finally, it is found prudent to sanity check the measured

    exhaust oxygen with that calculated from Carbon-balancing.

    REFERENCES1. General Motors Automotive Engine Test Code, For

    Spark Ignition Engines, Seventh Edition, The Engine Test

    Code Committee, 1994.

    2. Chan, S. H., Zhu, J., Exhaust Emissions Based Air-Fuel

    Ratio Model (I): Literature Reviews and Modelling, SAE

    Technical Paper 961020, 1996.3. Silvis, W. M., An Algorithm for Calculating the Air/Fuel

    Ratio from Exhaust Emissions, SAE Technical Paper

    970514, 1997.

    4. Jones, J. C. P., Muske, K. R., A Generalized Chemical

    Balance Analysis Tool for Combustion and Catalytic

    Reactions, SAE Technical Paper 2005-01-0680, 2005.

    5. Sinnamon, J. F., Sellnau, M. C., A New Technique for

    Residual Gas Estimation and Modelling in Engines, SAE

    Technical Paper 2008-01-0093, 2008.

    6. Sellnau, M., Sinnamon, J., Oberdier, L., Dase, C., Viele,

    M., Quillen, K., Silvestri, J., Papadimitriou, I., Development

    of a Practical Tool for Residual Gas Estimation in ICEngines, SAE Technical Paper 2009-01-0695, 2009.

    7. Schppe, D., Geurts, D., Balland, J., Schreurs, B.,

    Integrated Strategies for Boost and EGR Systems for Diesel

    Engines to achieve most stringent Emission Legislation,

    10th Supercharging Conference 2005, Technische

    Universitaet Dresden.

    DEFINITIONS/ABBREVIATIONS

    f, fuel

    f signifies fuel per carbon atom. Note f(uel) refers to f.

    :concentration of XX, concentration type described by

    sub- and super-scripts. The partially wet super-script is

    implied if nothing else included. Unit in [%].

    :special case o

    This is equivalent to the exhaust concentrationmeasurements. Note that this could be on a wet, dry or

    partially wet basis why this super-script is n

    included.

    :Nitrogen / Oxygen ratio of air, 3.774 used in order to

    account for trace amounts of argon, , , etc in

    atmospheric air, according to [1].

    http://www.sae.org/technical/papers/2009-01-0695http://www.sae.org/technical/papers/2008-01-0093http://www.sae.org/technical/papers/2005-01-0680http://www.sae.org/technical/papers/970514http://www.sae.org/technical/papers/961020
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    K

    :water/gas equilibrium constant. Use 3.8 according to

    [1].

    :percentage of theoretical exhaust water content that

    reaches exhaust analyzers. Usually 0. Unit in [%].

    y

    :Hydrogen / Carbon ratio of fuel

    z

    :Oxygen / Carbon ratio of fuel

    n

    :moles (in general) or molar coefficient for air in

    combustion reaction equation

    :effective number of carbon atoms per fuel molecule

    :molar weight

    :cylinder content before combustion

    :oxygen balanced

    :carbon balanced

    stoich

    :stoichiometric

    tot

    :total

    int

    :intake manifold

    exh

    :exhaust

    (xxx)

    :equation xxx

    [xxx]

    :reference xxx

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    APPENDIX

    INTRODUCTIONThe chemical combustion equation including EGR for a

    general hydrocarbon fuel that may contain oxygen is:

    (A1)

    This is to be compared to the combustion equation used in [1]

    which does not include EGR:

    (A2)

    Note that both combustion reaction equations have been

    normalized by the effective number of carbon atoms in a fuel

    molecule, .

    PREPARATORY DERIVATIONS

    (a). Normalized combustion reaction equation

    The combustion reaction equation of (A1) origins from:

    (A3)

    Normalizing with gives:

    (A4)

    where

    (A5)

    and

    (A6)

    (b). Relationship of molar coefficients to measured

    concentrations

    is used as an example:

    (A7)

    differs from by the moles of tha

    are removed from the exhaust sample before reaching the

    exhaust analyzers. The sample may be wet, dry or partially

    wet.

    The concentration measured by the emissions bench in

    volume percent is:

    (A8)

    The rightmost term in (A7) is found by relating the number of

    moles of fuel to the number of carbon-containing species

    through a carbon balance:

    (A9)

    Substituting using (A8) and its equivalent for and

    into (A9) results in:

    (A10)

    (A7), (A8) and (A10) now gives:

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    (A11)

    and similarly for the other molar coefficients:

    (A12)

    (A13)

    (A14)

    (A15)

    (A16)

    (c). , and exhaust concentrations

    expressed through other measured species

    As the concentrations of and are not measured, their

    molar coefficients are expressed by measured molar

    coefficients of other species.

    Hydrogen balancing gives:

    (A17)

    Nitrogen balancing gives:

    (A18)

    There are several reasons for expressing exhaust

    concentration through the measurement of other exhaus

    species.

    measurement not available

    As a check of measured concentration

    As a replacement of erroneous measurements

    As will be seen in the following sections, both the AF and

    derivations can be solved either using or not using

    measured . Derivations using measured are based on

    oxygen balancing while derivations not using measured

    are based on carbon balancing. As an example, it is found

    that AF=f( ). Therefore, four types of AF calculations are

    possible depending on the combination of oxygen and carbon

    based derivations. For consistency the following convention

    is assumed unless explicitly stated otherwise:

    O-bal = oxygen balance based derivation = measured

    used in all calculations

    C-bal = carbon balance based derivation = measured no

    used in any calculations

    Expressing the molar coefficient of by measured species

    is found through oxygen balancing:

    (A19)

    where is used (derived below).

    (d). (H2O) calculation

    is calculated by assuming a fixed value for the water/

    gas equilibrium constant, K, which relates the concentrations

    of , , and water vapor under equilibrium

    conditions:

    (A20)

    Substituting e with (A17) and applying (A11,A12,A13) and

    (A16) gives:

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    (A21)

    Finally, inserting N of (A10) results in:

    (A22)

    where is on the same wet, dry or partially dry basis as

    the independent terms. According to [1] K=3.8 is

    recommended.

    (e). Converting exhaust emission concentrations to

    a wet basis

    The molar coefficients of the combustion reaction equation

    are wet, meaning they relate to the total mol amount which

    includes water vapor. Usually, the exhaust sample passes

    through an ice bath that removes any water present so that the

    analyzers measure a dry sample, in which case .

    The correction is exemplified for :

    (A23)

    where is the theoretical number of moles of water in theexhaust calculated by conserving species in the combustion

    equation.

    Combining (A10) and (A16) gives:

    (A24)

    which inserted into (A23) applying

    and (A12) results in:

    (A25)

    This conversion applies to any species.

    AIR/FUEL RATIO DERIVATIONSAF is defined as:

    (A26)

    The basis for intake air is

    Air is defined as having the molar relation :

    Cylinder air amount is therefore :

    Which gives:

    (A27)

    can be expressed through either oxygen or carbon

    balancing.

    Oxygen balancing

    Oxygen balancing gives:

    (A28)

    Substituting a,b,d,f,g and N gives:

    (A29)

    Inserting (A10), (A15) and (A29) in (A27) gives:

    (A30)

    and finally using (A26) results in:

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    (A31)

    It is noted that . However, the influence ofis only present for exhaust containing oxygen, why the

    dependency effectively disappears for stoichiometric

    and rich operations. The difference between

    derived for the two combustion reaction equations is that the

    term has the multiplier for (A1) but not

    for (A2). Not including EGR dependence is essentially not

    properly accounting for the air (oxygen and nitrogen) that is

    present in the exhaust due to recycling.

    Carbon balancing

    was obtained through carbon balancing (see (A10)).

    An alternative expression for is:

    (A32)

    where is the percentage of water reaching the exhaust

    analyzers.

    Substituting , and results in:

    (A33)

    (A34)

    Substituting N, b,c and g gives:

    (A35)

    Combining (A19) and (A27) gives:

    (A36)

    Inserting gives after some

    rearranging:

    (A37)

    where

    (A38)

    and finally using (A26) results in:

    (A39)

    Note that for the special case of =0 (A39) becomes:

    (A40)

    which is identical to stated in [1].

    Stoichiometric Air/Fuel ratio

    Stoichiometric air/fuel ratio is calculated for completecombustion yielding only , and . The

    combustion equation becomes:

    (A41)

    The AF definition is restated:

    (A42)

    Intake air amount is :

    Which gives:

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    (A43)

    Oxygen balancing gives:

    (A44)

    Carbon balancing gives :

    (A45)

    Hydrogen balancing gives :

    (A46)

    Combining (A42,A43,A44,A45,A46) results in:

    (A47)

    EGR DERIVATIONS

    Total EGR

    is defined as the percentage of exhaust mass recycled.

    Recycling happens both internally (residuals) and externally:

    (A48)

    (A49)

    (A50)

    Assuming atmospheric air is free, all CylPreComb

    is from recycling:

    (A51)

    (A52)

    Solving for EGR using (A52) would involve measuring the

    concentration in the cylinder during the crank angle

    interval where the intake valves are shut and combustion has

    not yet begun. Such a measurement is in general no

    available. Instead, (A52) is written as:

    (A53)

    In the following, the residual fraction, , is

    assumed known.

    The rightmost term of (A53) is rewritten as:

    (A54)

    The rightmost term of (A54) is:

    (A55)

    where

    (A56)

    and

    (A57)

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    Applying (A6) and (A11,A12,A13,A14,A15,A16) results in:

    (A58)

    where

    (A59)

    Inserting (A56),(A58) and (A48) into (A55) gives:

    (A60)

    The numerator of the first term is named:

    (A61)

    and are given by (A29) respectively (A35).

    The remaining term to be solved is .

    Oxygen balancing

    Substituting and in (A56) gives:

    (A62)

    Substituting a,c,d,f,g gives:

    (A63)

    where

    (A64)

    (A65)

    (A66)

    Combining (A53),(A54), (A60),(A63) and (A66) results in:

    (A67)

    (A68)

    where

    (A69)

    and

    are measured.

    The exhaust measurement is corrected for the water no

    reaching the exhaust analyzer, using (A25):

    (A70)

    It is assumed that the water in the intake sample is negligible

    giving:

    (A71)

    Carbon balancing

    Subtituting e,h and f in (A56) gives:

    (A72)

    (A73)

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    where

    (A74)

    (A75)

    (A76)

    Equivalent to oxygen balancing, one gets:

    (A77)where

    (A78)

    INERT EGR DERIVATIONDuring lean operation only part of the recycled gas is inert.

    Therefore does not represent the inert dilution of the

    combustion fresh charge as is the case for stoichiometric and

    rich operation. Inert EGR affects combustion most directlywhy it should be readily available as a measurement.

    The two EGR definitions are:

    Total EGR :

    Inert EGR :

    Introducing the exhaust inert mass percent:

    (A79)

    and

    (A80)

    and applying continuity:

    (A81)

    results in:

    (A82)

    Likewise for and .

    It is defined that the exhaust can be purely partitioned into air

    and inert, which gives:

    (A83)

    where

    (A84)

    and

    (A85)

    which is measured.

    The term remains to be solved.

    (A86)

    Inserting (A11,A12,A13,A14,A15,A16) gives

    (A87)

    Oxygen balancing

    From (A63):

    (A88)

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    The numerator of (A87) is solved by substituting e,h given by

    (A17),(A18) and then substituting a,b,c,d,g given by

    (A11,A12,A13,A14) and (A16), resulting in:

    (A89)

    where

    (A90)

    (A91)

    Combining the numerator (A89) with the denominator (A88)

    cancels the EGR dependency:

    (A92)

    It is interesting to note that only depends on

    AF and not on . Since the molar weight of air and inert

    are very similar and is in between, it is natural to

    investigate the possible simplification of =1.

    See Figure 4 in main report for evaluation of

    approximation.

    Carbon balancing

    Equivalent to oxygen balancing, one gets:

    (A93)

    where the only difference between and is

    that the exhaust oxygen measurement of is replaced

    with that calculated by carbon balancing, .

    is derived in section Carbon balanced exhaust

    oxygen concentration derivation.

    Therefore:

    (A94)

    (A95)

    INTAKE EGR

    For a non-zero residual fraction, , the

    external EGR is not equal to the intake EGR.

    Intake EGR relates the externally recycled mass (flow) to the

    total mass that the cylinder inducts from the intake manifold.

    External EGR relates the externally recycled mass (flow) to

    the total cylinder mass, which includes residuals.

    (A96)

    (A97)

    They are seen to relate as:

    (A98)

    The rightmost term can be rewritten as (applying

    ) :

    (A99)

    Finally, it is noted that and relate

    equivalently.

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    CARBON BALANCED EXHAUST

    OXYGEN CONCENTRATION

    DERIVATIONAs discussed in section Preparatory derivations there are

    several reasons for expressing exhaust concentration

    through the measurement of other exhaust species.

    Equaling the two expressions for , (A15) and (A19), gives:

    (A100)

    Substituting and , (A10) and (A35) respectively,

    results in:

    (A101)

    is on the same wet, dry or partially dry basis as

    the other concentrations.

    The Engineering Meetings Board has approved this paper for publication. It has

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    ISSN 0148-7191

    doi:10.4271/2010-01-1285

    Positions and opinions advanced in this paper are those of the author(s) and not

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    http://dx.doi.org/10.4271/2010-01-1285