2. Resin R3X1080_material Safety Data Sheet_Part B

MSDS

Date : 05/01/2013 R3X1080 Part B 3X ENGINEERING

Page: 1/5 selon 91/155/CEE

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1.0 Identification of the substance / preparation and society

1.1 Identification of the chemical: R3X1080 Part B

1.2 Entity responsible for marketing: 3X ENGINEERING S.A.M 9 avenue Albert II 98000 MONACO Tl. : +377 92 05 79 81

1.3 Emergency number: ORFILA : 01.45.42.59.59

2 .0 Composition / Information of components

Description of chemicals : Cycloaliphatic amine.

Informations of hazardous components :

N CAS Dsignation % Ident. Phrases R 2855-13-2 Isophoronediamine 100 C R21/22, R34, R43, R52/53

3.0 Hazard identification

Classification

Corrosive

Indications of risk to humans and the environment

Hazards to humans: Cause burns. Harmful by inhalation, skin contact and by ingestion. May cause sensitization by skin contact.

Physical and chemical hazards: No Not classified as flammable but can burn.

Environmental Effects: Very toxic to aquatic organisms. May cause adverse long-term to the aquatic environment.

4. 0 First aid

4.1 If inhaled : Move to fresh air. If the person does not recover quickly, consult a doctor or hospital. 4.2 In case of contact with skin : DO NOT WAIT. Remove immediately clothing and shoes. Rinse immediately with plenty of water and soap if possible for at least 10 minutes. If symptoms persist, consult a doctor or hospital. 4.3 In case of eye contact : DO NOT WAIT. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult immediately a doctor. 4.4 If swallowed : DO NOT WAIT. Do not induce vomiting. If swallowed, immediately consult a doctor or hospital.

5.0 Mesures against fire

5.1 Means of non-extinction appropriate : Water jet. 5.2 Extinguishing media recommended : Alcohol resistant foam, water spray or fog. 5.3 During the fight against fire : Not classified as flammable but can burn. Clearance possible carbon monoxide, nitrogen oxides if incomplete combustion. Coll containers nearby with water spray. 5.4 Protective equipment : Apparel comprehensive protection and breathing apparatus autonomously.

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6.0 Action accidental release

6.1 Precautions: Avoid contact with skin, eyes, clothing. Completely ventilate the contaminated area. Do not breathe vapors. Immediately remove all contaminated clothing. 6.2 Precautions for environmental protection : Prevent contamination of soil and water. Prevent any infiltration or runoff into sewers, gutters or rivers by using sand or soil or other suitable. If the product reaches the sewers, it must be pumped in a shell not closed. You can call emergency services to assist in the operation. 6.3 Methods of cleaning/recovering : Absorb or retain the liquid with sand, earth or limiting any subject spraying. Recovering in a container labeled, closed, to proceed to a safe disposal. Scrub contaminated surfaces with detergent solution Keep washing water as contaminated waste. Place containers prevarication in a barrel or even an over-labeled

7.0 Storage and handling

7.1 Handling precautions : Comply with local regulations. Avoid contact with skin, eyes and clothing. Do not breathe mists, aerosols, vapors. 7.2 Criteria storage : Store according to local regulations. Keep container tightly closed and protected from humidity. Keep only in original container. Keep container in a well ventilated. Keep away from direct sunligth. Keep away from heat. 7.3 Storage : Ambient.

8.0 Monitoring the exposure of workers, personal protective equipment

8.1 Technical control : Use a local extraction ventilation air. 8.2 Components with limit values that require monitoring at work :

Components with limit

values that require

monitoring at work

Updated

regulations

Term

exposureValue Note

Benzyl alcohol ACGIH No established value

Isophoronediamine ACGIH No established value

Cycloaliphatic amine

adduct with BPA

polymer

ACGIH No established value

8.3 Personal protection measure : Respiratory: Having a self-contained breathing apparatus ready for use if necessary. In the premises or the product is pulverized, workers should avoid contact with aerosols containing the agent treatment with control methods, such as exhaust ventilation or suitable protective equipment such as respirators mask full and air supply, gloves and protective suits. Wear a respirator if ventilation is inadequate. Hands: nitrile rubber. In an emergency, wear waterproof gloves with cuffs to prevent the spread of material to the area above the wrists. Neoprene gloves. Butyl rubber. Nitrile rubber. The time Waterproofing gloves chosen must be longer than the period of use. Eyes: In places or treatment agent may come into contact with eyes, workers should wear goggles and a mask projections. People working near the equipment, within range of potential exposure must also wear goggles plastic. Workers should not touch their eyes or skin with contaminated hands by the treatment agent.

8.4 Special protection measures and hygiene : Discard leather contaminated. Provide eye wash stations and safety showers. Wash at the end of each work period and before eating, smoking or using the toilet.

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8.5 General protection measures and hygiene: Trying to prevent the penetration of material into sewers or waterways. Keep out of surface water or sewage systems. Build a retaining wall to prevent the dispersion of liquids.

9.0 Proprits Physico-chimiques

9.1 Physical condition : Clear liquid

9.2 Odor : Amine odor

9.3 Typical temperatures : Flash point : 112C. Boiling point : 247C Temperature self-flammability : 380C.

9.4 Solubility : No

9.5 Gravity: 1,04 (at 25C)

9.6 pH : Ca. 11,6

10.0 Stability of product et reactivity :

10.1 Conditions to avoid : Exposure to water vapor. 10.2 Hazardous reactions : Stable under normal conditions of use. Reacts with strong oxidizing agents. Strong acids. Hygroscopic. 10.3 Hazardous decomposition : Not to our knowledge.

11.0 Toxicologic informations

11.1 Acute : Ingestion : Moderatly toxic, 200

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13.0 About the possibility of waste disposal :

13.1 Product : Putting the collection of toxic waste or make to the dump for hazardous waste

13.2 Packaging non cleaned : Evacuation accordance with legal requirements.

14 .0 Transport details :

UN: 2735

Class: 8

Classification: C7

PG: III

No. Labelling:

No risk: 80

Shipping Name : AMINES, LIQUID, CORROSIVE, NOS (ISOPHORONEDIAMINE,

cycloaliphatic AMINES MODIFIED))

Marine Pollutant : Yes. Mark Marine pollutant required.

15.0 Regulatory informations

15.1 Labelling to EEC Directives

Symbol of danger : C, Corrosive

15.2 Phrases R : R21/22 Harmful by contact with skin and if swallowed.

R34 May cause burns

R43 May cause sensibilising after contact with skin.

R52/53 Harmful to aquatic organisms may cause adverse long term to the aquatic environment.

15.3 Phrases S :

26 In case of contact with eyes, rinse immediately and thoroughly with water and consult a specialist.

28A After contact with skin, wash immediately and thoroughly with soap and water.

36/37/39 Wear suitable protective clothing, gloves and a protective equipment for eye and face.

45 In case of accident or illness, consult a doctor immediately (where possible the label).

57 Use appropriate container to avoid contamination of the environment.

61 Avoid release into the environment.

Pays List Notification

USA TSCA Listed

EU EINECS Listed

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Canada DSL Listed

Australia AICS Listed

Japan ENCS Listed

South Korea ECL Listed

China SEPA Listed

Philippines PICCS Listed

16.0 Other informations :

Ensure that all national or local regulations are respected. Risk phrase

Harmful in contact with skin and if swallowed. Causes burns. May cause sensitization by skin contact. Harmful to aquatic organisms, may cause effects long term harmful to the aquatic environment.

This Safety Data Sheet has been established according to European Directives in force and shall apply to all countries that have translated the Directives into national law. This profile is based on the current state of our knowledge, but does not guarantee about the properties of the product and does not give rise to a legal contract.

2. Resin R3X1080_material Safety Data Sheet_Part B

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