2-Jan Kollmus-Siemens Carbon Capture Technologies – Successful Technology Development From Pilot...

Copyright Siemens AG 2012. November 2012

SIEMENS GASIFICATION TECHNOLOGY

SIEMENS CARBON CAPTURE TECHNOLOGIES SUCCESSFULL

DEVELOPMENT & INDUSTRIAL COMMERCIALIZATION

Dr. Jan KollmusSiemens Gasification China

Energy Sector Siemens Fuel Gasification TechnologyCopyright Siemens AG 2008. All rights reserved.

Content

1. Coal still an energy resource ?

2. Siemens PostCap Technology

3. Siemens Gasification Technology

4. Siemens gasification technology application in Chinese large scale coal to SNG plants

5. Siemens gasification technology in IGCC projects

6. Summary


The demand for energy will continue to grow Fossil fuels remain the backbone of the energy mix

Coal

Oil

Gas

Nuclear

Hydro

Renewables

2030Bright Green Scenario

35.7

30%

3%

22%

14%

15%

17%

2030Base Case

36.7

34%

3%

21%

14%

15%

13%

2010

42%

5%

21%

13%

15%4%

1317%

3430%68%

58%

2020Base Case

29.3

38%

3%

22%

12%

15%

9%

+2.8% p.a.

+9.6% p.a.

21.0


World energy demand expands by 45% between now and 2030 with coal accounting for more than a third of the overall rise with China as the main driver

World Primary Energy Demand and Main Driver

Ageing power plant fleets and growing electricity demand

CO2 emissions / CO2 reduction targets Volatile fuel prices Limited Oil and Gas resources

Clean Coal (CCS) and Energy Mix

14%

020004000600080001000012000140001600018000

1980 1990 2000 2010 2020 2030

M

t

o

e

OtherrenewablesHydroNuclearBiomassGasCoalOil

Worldwide Energy Demand Worldwide Electricity Demand

2005 2030

18.000 TWh

37.000 TWh

2.7 % p.a.

Fossil fuels

62%67%

7%

16%15%

20%

40%

Hydro13%

Nuclear 13%

Coal36%

Renewable14%

2%

Oil 3%

Gas 21%


Coal World Energy backbone

... Gasification applies sustainable resources ...


Industry Infrastructure & Cities Energy Healthcare

Industry Automation Drive Technologies Service

Power Distribution/Smart Grid Applications

Building Technologies Mobility

Fossil Power Generation- Fuel Gasification Technology Renewable Energy Power Transmission Oil & Gas Energy Service

Imaging & Therapy Clinical Products Diagnostics Customer Solutions

Industry Solutions Osram Power Distribution

OsramBuilding Technologies

Mobility

Siemens AG


Siemens Energy Innovations for Low Carbon Future

HVDC-Trans-mission and HVDC Grids

Smart Grid incl. Energy Storage,

E-Mobility

Pipeline Trans-portation and

Gas Liquefaction

Offshore and Subsea

Oil & Gas

Highly Efficient Solar Power Generation

New Generation of Wind Turbines

Highly Efficient Coal- & Gas-fired

Power PlantsCarbon Capture

and StorageGasification


CO2 Reduction Potential through CCSSiemens New Technology Portfolio


SIEMENS Post Combustion Carbon Capturefor Fossil Fuel fired Power Plants


SIEMENS CO2 Capture Processbased on Amino Acid Salts


Successful Upscaling and Industrial CommerzialisationPilot Plant at EON SPP Staudinger, Germany


SIEMENS PostCapTM Technology Key Benefits


MASDAR CCS Project in Abu DhabiCO2 for Enhanced Oil Recovery


Gasification ? ... is not combustion ...

Combustion is full oxidation: 2 (CH2) + 3 O2 2 CO2 + 2 H2O

Gasification is partial oxidation: 2 (CH2) + O2 2 CO + 2 H2- optimized use of coal- conversion of coal into syngas- processed into hydrogen and carbon monoxide

H H

Hydrogen

HH

O

Water / Steam

Syngas ( H2 + CO + CO2 )

Coal is ... Carbon Ash Hydrogen Oxygen Nitrogen Trace Elements O

Oxygen

O

Carbondioxid

Carbonmonoxid

O O

O

C

C


Chemicals

Alternative Transportation Fuels

RefineryHydrogen

Power

e.g. Methanol, Ammonia, Plastics

high-quality diesel from FT*-synthesis (CTL**)

Fuels with higher biomass content

for upgrading products in refineries or

in oil sands processing

IGCC alternative to STP

C

h

e

m

i

c

a

l

s

I

G

C

C

Competitive CtC plants will remain the market with the highest short term growth potential, especially in China

Recent EU legislation decision (100% CO2 auctioning beginning 2013) increases demand for CO2 capture and storage solutions

* FT-synthesis: Fischer-Tropsch synthesis**CTL coal-to-liquids

Increasing demand for cleaner and lighter fuels arethe drivers for higher H2 consumption within refineries

Volatile oil & gas prices, security of supply concerns and climate protection cause search for alternative fuel sources

Market trends and opportunities for Gasification


Coal to Liquids( FT Synthesis )

Coal to Chemicals

Refinery

Transportation fuels

Methanol

Applications Fields for Gasification

Combined Cycle

Syngas

(CO + H2)

Power

Blends

(I)GCC

Fuel Gas Island Applications

Fuel preparation

Petcoke

Air Separation Unit

Gasification Island

Gasifier

CO Shift

Sulfur Removal CO2 Removal

LiquidRefinery residues

Biomass

Gasification is able to meet the strictest environmental regulations: Low emission of particulate matter, organic compounds and easy disposal of Sulfur

Possibility of capturing and storing or sequestering CO2

Coal

Slag (incl. V, Ni)

Ammonia

Oxochemicals

Hydrogenfor Hydro-processing

MTBEFormaldehyde

UreaAmmonia Nitrate

ButanolEthylhexanol

SNG (Synthetic Natural Gas)

Steel Industry, Pulp&Paper,

Supply of key gasification equipment Sinopec PDP for Gasification Island

Combined Cycle turnkey or GT, ST products


Siemens Gasification Island Engineering Battery Limits

Equipment SupplyFeeder Vessel, Reactor, Burner

Engineering PackagesPDP, BEDP

Black WaterTreatment

Dry coal

CO2/N2

Steam

Oxygen

LP Steam

Granulated Slag

Raw Gas

Waste Water

Filter Cake

Off Gases

QuenchWater

Slag Handling

ReactorFeeding System

Mechanical Raw Gas Treatment

Bunker

Lock Hopper

Feeder Vessel

Slag crusher

Slag hopper

Conveyor

VenturiScrubber

Raw Gask/o Drum

Quench WaterVessel

CO2/N2

Gas Condensate

Make up water

Flash System

Pilot Burner Gas

LP Boiler Feed Water

Reactor1300 to1800C

Quench

Reactor1300 to1800C

Quench

Coalescer

HP NozzleSystem

JetScrubber

Flash 1Flash 2

Black WaterBuffer


Siemens Fuel Gasification Technology: Cooling screen reactor

FeaturesSFG Cooling Screen Gasifier

Fuel flexibility Lignite, bituminous & sub-bituminous coal, hard coal, pet-coke

(w/wo fluxant), biomass

Dry feeding high efficiency (>80%), high carbon conversion rate (> 98%),

significantly higher burner life time

Cooling screen short start-up / shut-down (~ 2h) Significantly higher lifetime compared to refractory high availabilityFull quench simple and reliable ideal for CO sour shiftSingle main burner with integral pilot burner Eliminates the need to dis-assemble start-up burner(s) Facilitates maintenance (downtime for burner change one day)Selective ESD sequencing increased availability

Pressurized water inlet Pressurized wateroutlet

Fuel Oxygen, steam

Cooling screen

Quenchwater

Granulated slag

Gas outlet

Burner

Reactor1300 to1800C

Quench

Pressurized water inlet Pressurized wateroutlet

Fuel Oxygen, steam

Cooling screen

Quenchwater

Granulated slag

Gas outlet

Burner

Reactor1300 to1800C

Quench


Larger Gasifiers for improved Plant Economics

SFG-850 SFG-1200

SFG-500SFG-200

Optimized Family of Gasifier Sizes for Todays and Future Scale of Gasification based Projects

Commercial Offering !

SFG 850 MW classSFG 1200 MW class

~ 20% capex reduction

3 burner application

proven design featuresof 500MW class gasifierretained


History of Siemens Fuel Gasification

DBI

Future Energy / Sustec

Siemens Fuel Gasification Technology

1978

1990

2000

2012

More than 20 years of successful operating experience

initial technology development with focus on low-rank, high-ash lignite

first commercial plant with start-up in 1984, operated on lignite, coal and various residuals

Own test plants (5 MWth gasifier, feeding system, fuel analysis)

total head count 100, ~ 60 process engineers

2006

Preussag Noell

Babcock Borsig Power

Feed SystemTest Rig

5 MWthGasificationTest Plant

Office


Lignite roots of GSP Siemens technology

Gaskombinat Schwarze Pumpewas founded on 23 June 1955 by Eastern Germanys Ministerial Council

1955

employing more then 46000 employees

1970 19781960

Development of entrained flow, dry coal feeding, cooling screen, full quench gasification technology

1984

First industrial application of GSP 200 MW gasifierwith cooling screen & full quench design

Lausitzer Revier open cut mine2000

Erection of 5 MW Gasification Test Plant in Freiberg, Saxony

2006


Development of Gasification Technologies

Source : Ronald W. Breault, NETL-US DOE, Energies 2010, 3, 216-240, ISSN 1996-1073

Driver of technical development

enviromental protection

safe resources (water, coal)

improved coal consumption

increased carbon conversion

larger capacity per gasifier unit

comprehensive design / layout

PAST FUTURECOALCLEAN

Source : HTW Gasifier in LEUNA, Dr. Fritz, Linde AG Munich


9 SFG-500 Gasifiers shipped / installed for 3 projects32 SFG-500 Gasifiers contracted within the last 12 months

SFGT main Project Landscape

Siemens OfficesOperating UnitsCurrent ProjectsTechnology Selected

HQ FreibergTest Facility

JinChengAmmonia

Shenhua Ningxia Coal GroupPolypropylene

COD 2011

Secure Energy Transportation Fuel

Capital PowerPower

AEC Ammonia

Summit PowerPower + Ammonia

GSP China Beijing

VresovaPower

COD 2008

Schwarze PumpeSyngas for Chemical Industry

1984 - 2007

Tenaska Inc. SNG/Power

Ukraine ClientSyngas for

Chemical Industry

Syngas Ltd.Transportation Fuel

Orlando

Korean ClientSNG

Japanese ClientChemicals

Shanghai

CPI SNG


Siemens Fuel Gasification Technology | Test Facility

Gasifier with cooling screen, 5 MWth Dry coal feeding system (400 kg/h) Gas treatment

- Desulphurization unit (Sulferox)- COS hydrolysis- HCN hydrolysis

Waste water treatment

Over 60 feedstocks tested in over 100 testsprovides valuable design data for better FEEDs

Rotational slag viscosity device to validate slag behaviour and to determine optimized gasification temperature

Test of dust flow measurements

Investigation of fluidization properties

Optimization of Lock Hopper Cycling

Test of alternative feeding system


Siemens Fuel Gasification Technology: Business Model

Service

Technical Field Assistance

Construction

Proprietary Equipment Supply

Licensing

Detailed Engineering

Gasification Tests Engineering Packages(Process Design & Basic Engineering

Design Package)

Feasibility Studies

Start-up and OperationProject ExecutionProject Evaluation &

Technology Selection

FG Offer and ProductsOutside FG scope

OEM for key components (proprietary equipment

Process engineering/license and basic engineering service provider

Service provider (parts only through full O+M) for gasifier islandscope, utilising the Siemens Energy service organisation / infrastructure


Milesstones NCPP gasifier roll out March 2008

SFG 500 MW class gasifier:

Coal Capacity: ~ 2.000 t/dVessel Length: ~ 19 mVessel Diameter: ~ 4,5 mVessel Weight: ~ 240 t


China Projects | Coals | Products

CPI Yinan Xinjiang 6 Nm3 SNG / a ProjectFirst Phase 2 Nm3 SNG / aSyngas capacity 1,040,000 Nm3/h (CO+H2) Gasification Plant 8 x SFG 500 MW class gasifiersdry coal capacity 8 x 80 t / h (utilizing old lignite)

Shenhua Ningxia Coal Industry Group 4 Mio t FT /a CTL ProjectSyngas capacity 2,800,000 Nm3/h (CO+H2) Gasification Plant 22+2 x SFG 500 MW class gasifiers

SNCG Coal to 1,67 Mio t Methanol / 500kt PP / a ProjectSyngas capacity 540.000 Nm3/h (CO+H2) Gasification Plant 5 x SFG 500 MW class gasifiersdry coal capacity 5 x 85 t/h (utilizing Sub- Bituminous Coal)

Shanxi Lanhua Group 300 kt Ammonia ProjectSyngas capacity 120.000 Nm3/h (CO+H2) Gasification Plant 1+1 x SFG 500 MW class gasifiersdry coal capacity 2 x 75 t/h (utilizing Shanxi anthracite)


NCPP Project Ningxia Coal to Polypropylene

Scope of SFGT:Engineering:

Supply of SIEMENS Proprietary Equipment:

Process Design Package (PDP) and BED Review

5 x 500 MW standard Gasifier, 5 x Feeder Vessel, 5 x Burners + 5 Back-Up Burners,* Coal Dense Flow Measurement Devices, * Feeding Internals, * DCS / SIS Logic diagrams and Documentation

Technical Field Assistance (TFA) as Advisory Service for Erection, Commissioning and Test Run

540.000 Nm3/h (CO+H2) Coal Gasification Plant (5 Gasifiers)Dry coal capacity 5 x 85 t/h (utilizing Sub- Bituminous Coal)Client & Location:Client: Shenhua Ningxia Coal Industry Group Co., Ltd.

Integrated Project Management Team consisting of SNCG and AMEC

Location: Ningxia Autonomous Province, PR China

Schedule:Start Erection (SIEMENS Proprietary Equipment) January 2009TFA Service Start July 2009Mechanical Completion End of August 2010Commissioning period for all gasifiers October 2010 April 2011


Site View NCPP ProjectGasifier buildings

Gasifier buildings

Total Plant View


CPI Yinan Xinjiang 2SNG Project

Scope of SFGT:Engineering:

Supply of SIEMENS Proprietary Equipment:

Process Design Package (PDP), BED by ECEC and BED / DED Review

8 x 500 MW standard Gasifier, 8 x Feeder Vessel, 8 x Burners + 8 Back-Up Burners,* Coal Dense Flow Measurement Devices, * Feeding Internals, 8 x DCS / SIS hardware and Logic diagrams / Documentation

Technical Field Assistance (TFA) as Advisory Service for Erection, Commissioning and Test Run

1,040.000 Nm3/h (CO+H2) Coal Gasification Plant (8 Gasifiers)Dry coal capacity 8 x 80 t / h (utilizing old lignite)Client & Location:

Client: China Power Investment Corporation location: Yinan, Xinjiang Province, PR China

Schedule:Start PDP September 2011Final PDP Februar 2012Final BED April 2012Equipment Supply expect. March 2013


Energy Efficiency and Consumption Requirements in Chinese 12th 5 year plan

ProductsEfficiency Cons.Standard Coal Water Cons.

Basic Siemens Basic Siemens Basic Siemens

CTL 42% 45% 3.6 t/t oil product 3.5 t/t oil product 2.75 t/tce 2.2 t/tceSNG 56% 57% 2.3 t/kNm3SNG 2.1 t/kNm3SNG 3.0 t/tce 2.8 t/tceMTO/MTP 40% 43% 5.3 t/t Olefin 3.84 t/t Olefin 4.0 t/tce 2.5 t/tce

Targets:

- Save local coal resources

- save water resources

- enviromental protection by strict emissions levels

- increased efficiency requirements means CO2 reduction measure

- establish state of the art clean coal industry


Standard CCPP

GasIsland

CO2 for sequestration

Water/Steam

Integrated Gasification Combined CycleIGCC-CCS

H2-rich SG

(Air to ASU)Diluent N2

Syngas/H2CCPP

GasIsland

Gasification Combined CycleGCC-CCS

H2-rich SG

GasIsland

incl. Methanation

Synthetic Natural Gas Combined CycleSNG-CC

SNG



(CO2)

(CO2)

CO2

NaturalGas Net

Real low-CO2 option (capture up to ~90%) High efficiency (especially in context with a raw gas

heat utilization system) Water/steam-side integration low challenging No or partial air-side integration with Siemens GT

Immanent partial CO2 capture for optional retrofit(capture up to ~50%)

High operational flexibility as a proven standard CC High product flexibility and thus capacity utilization

(power and/or SNG)

Real low-CO2 option (capture up to ~90%) Only one interface lower complexity Clear responsibilities (project execution) Option for phased construction

(power from NG from beginning)

Flexibility

Established technology

Coal-to-power-

efficiency

CO2 capture Attractive for European power market with its CO2 regulations and potential funding options

Attractive when setting up SNG infrastructure and for intermediate load power generation

Attractive also in connection with polygeneration

Different technology routes enable the best fit to the market.

Siemens Fuel

Gasifier(SFG)

broadvariety of

feedstocks

Gasification Based Low-CO2 Power Production Applying High Efficient Gas Turbine Technology

Syngas/H2CCPP(lower

interfaces)


~770 MW aux. power**Excluding utility systems

CO2 to EOR

Polygeneration Plant Concept for Mega SNG

SFG-Gasifier with full quench system robust and cost-effective

SFG-Gasifier with radiant cooler high efficient

High feedstock flexibility Optimized water consumption Superheated IP-Steam to steam turbine E-class gas turbine

Net efficiency* (LHV): >0,56*without power export

(GJ SNG)/ (GJ Raw Coal)

Superheated IP-Steam

Raw Coal SNG

Power

4 billion Nm/a

16 x SFG-500

Saturated IP-Steam

Alternative concept

Superheated IP-Steam to ASU Mechanical drives

Sulphur


Polygeneration Plant Concept

Gasifier CoalCO,

H2 (deficit) H2,CO,CO2

CO2Compression

(potentially)

CO, H2(optimally stoichiometric)

MeOH

O2

CO2

Products1. Basic chemicals: MeOH, NH3, SNG, FT (main product)2. Power (by-product)

Power

CCPP oversized for internal use only Power export possibleProduct distribution market controlled Power demand chemical productionNo additional investment for carbon capture needed Economical CO2 sequestration possible

Saturated IP-Steam


IGCC projects using Siemens Fuel Gasification Technology

IGCC Concept with H2 fired Gas Turbine

Summit Texas Clean Energy Project

Customer: Summit Power Group, Inc.Washington, USA

Location / Fuel: Midland Odessa, Texas, USA / PRBPower output: 400 MW (gross) and 270k t/a NH3Siemens scope: PowerBlock (1 x SGCC6-5000F)

2 x SFG-500 GasifierCCS capture rate: appr. 90% used for EOR

(off take agreement)

Funding support: 450 USD (DOE)

Total plant invest: appr. 2 USD

IGCC Concept with H2 fired GTand NH3 co-production

Tenaska Taylorville Energy Center

Customer: Tenaska Inc.Omaha, USA

Location / Fuel: Illinois, USA / Illinois coal #6Power output: 700 MW (gross)Siemens scope: 2 x SFG-500 Gasifier and

1x SGT6-5000F CCS capture rate: 65% CCS in saline aquifers

Funding support: 22 USD loan guarantee (DOE) 417 Invest Tax Credit

Total plant invest: appr. 3.5 USD

PROJ

ECT o

n HOL

D


Summit Texas Clean Energy Project

with courtesy of Summit / GTC 2012 Washington


Siemens offers gasifiers from 200 MW class, 500 MW class up to 1000 MWth / 4000 tons coal / days (solid feedstocks)

Gasification Summary

Drivers

Energy security - By making better use of locally abundant available energy resources such as coal, gasification can reduce the need to rely on fuel imports

Gasification enables to convert local coal and other low-grade fuels into high-value products in high efficient and environmentally friendly manner

Siemens Gasifier Portfolio

multi-fuel capability, highest availability, lowest maintenance costs feedstock flexibility - increases the economic value of usable resources and lowers costs by

providing industry with a broader range of feedstock options and their blends

Gasification testing using customers feedstock in dedicated test facility in Freiberg to confirm gasification is possible for high- ash/high- fluid temperature feed stocks and blends of feed stocks

Test rig feeding systemCustomer Benefits

Lets develop together the Clean Coal Future & Low Carbon Society !


For further information:

Dr. Jan Kollmus [email protected]: +86 139 1109 7914

Thank you!Thank you!

Siemens Fuel Gasification Technology GmbH & Co. KGHalsbruecker Str. 3409599 FreibergGermany

Siemens Ltd. China7, Wanggjing Zhonghuan NanluChaoyang DistrictBeijing 100102P.R. China

Siemens PostCap Technology

Dr. Gernot Schneider Director Marketing and SalesCarbon Capture and Sequestration (CCS)

Siemens AG, Energy Sector, Fossil Power GenerationFreyeslebenstr. 1, 91058 Erlangen, Germany Tel.: +49 (9131) 18-82281 Fax: +49 (9131) 18-89761 Mobile: +49 (173) 7049-186

Siemens Gasification Technology

Mr. Rolf Rsseler Director Marketing and SalesSiemens Gasification Technology (FG)

Siemens AG, Energy Sector, Fossil Power GenerationHalsbrcker Strasse 34, 09599 Freiberg, Germany Tel.: +49 (3731) 785-311 Fax: +49 (3731) 785-383 Mobile: +49 (170) 6345004


Disclaimer

This document contains forward-looking statements and information that is, statements related to future, not past, events. These statements may be identified either orally or in writing by words as expects, anticipates, intends, plans, believes, seeks, estimates, will or words of similar meaning. Such statements are based on our current expectations and certain assumptions, and are, therefore, subject to certain risks and uncertainties. A variety of factors, many of which arebeyond Siemens control, affect its operations, performance, business strategy and results and could cause the actual results, performance or achievements of Siemens worldwide to be materially different from any future results, performance or achievements that may be expressed or implied by such forward-looking statements. For us, particular uncertainties arise, among others, from changes in general economic and business conditions, changes in currency exchange rates and interest rates, introduction of competing products or technologies by other companies, lack of acceptance of new products or services by customers targeted by Siemens worldwide, changes in business strategy and various other factors. More detailed information about certain of these factors is contained in Siemens filings with the SEC, which are available on the Siemens website, www.siemens.com and on the SECs website, www.sec.gov. Should one or more of these risks or uncertainties materialize, or should underlying assumptions prove incorrect, actual results may vary materially from those described in the relevant forward-looking statement as anticipated, believed, estimated, expected, intended, planned or projected. Siemens does not intend or assume any obligation to update or revise these forward-looking statements in light of developments which differ from those anticipated.

Trademarks mentioned in this document are the property of Siemens AG, its affiliates or their respective owners.

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