2. Cement Lecturegag

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    Concrete Technology

    VCB 2023

    Cement

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    Learning Outcome

    To evaluate the properties of concreteconstituent materials.

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    Definition

    In BS EN 197-1, cement is defined as:

    A hyd raul ic bind er, i .e. a f inely ground inorganicmater ial which , when m ixed w ith water, forms apaste which sets and hardens by means ofhydraul ic react ions and processes and which,after hardening, retains i ts s trength and s tabi l i tyeven under water.

    Factory produced EN 197 cements are given thedesignation CEM

    In British Standards, mixer combinations are giventhe designationCnot CEM

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    History of Cement

    In 1824, Joseph Aspdin, a British

    (Leeds) stone mason, obtained a

    patent for a cement he produced in his

    kitchen.

    The inventor heated a mixture of finely

    ground limestone and clay in his

    kitchen stove and ground the mixtureinto a powder create a hydraulic

    cement-one that hardens with the

    addition of water.

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    History of Cement

    Aspdin named the product Portland

    cement because it resembled a stone

    quarried on the Isle of Portland off the

    British Coast.

    With this invention, Aspdin laid the

    foundation for today's Portland cement

    industry.

    Cement is so fine that one kg of cement contains more

    than 300 billion grains

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    Basic Composition

    The raw materials required to produce Portland cement

    are found and exploited in nearly all parts of the world,which is a significant reason for its universal importance

    as a building material.

    Table 1 indicates the standard mineralogical composition

    of Portland cement and Table 2 indicates its standard

    chemical composition.

    http://sres-associated.anu.edu.au/fpt/cfb/cement.htmlhttp://sres-associated.anu.edu.au/fpt/cfb/cement.htmlhttp://sres-associated.anu.edu.au/fpt/cfb/cement.htmlhttp://sres-associated.anu.edu.au/fpt/cfb/cement.htmlhttp://sres-associated.anu.edu.au/fpt/cfb/cement.htmlhttp://sres-associated.anu.edu.au/fpt/cfb/cement.htmlhttp://sres-associated.anu.edu.au/fpt/cfb/cement.htmlhttp://sres-associated.anu.edu.au/fpt/cfb/cement.html
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    Basic Composition

    Chemical NameCommon

    NameChemical Notation

    Abbreviated

    Notation

    Mass Contents

    (%)

    tricalcium silicate alite 3CaO.SiO2 C3S 38-60

    dicalcium silicate belite 2CaO.SiO2 C2S 15-38

    tricalcium

    aluminatebelite 3CaO.Al2O3 C3A 7-15

    tetracalcium

    aluminoferite celite 4CaO.Al2O3.Fe2O3 C4AF 10-18

    pentacalcium

    trialuminatecelite 5CaO.3Al2O3 C4AF 1-2

    calcium sulphate

    dihydrategypsum CaSO4.2H2O CSH2 2-5

    Table 1 Mineralogical Composition of Portland Cements (Brandt, 1995)

    http://sres-associated.anu.edu.au/fpt/cfb/references.htmlhttp://sres-associated.anu.edu.au/fpt/cfb/references.html
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    Basic Composition

    Tricalcium Silicate

    (50%)

    Dicalcium Silicate

    (25%)

    Tricalcium Aluminate

    (12%)

    Tetracalcium Aluminoferrite

    (8%)

    Gypsum

    (3.5%) Other

    (1.5%)

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    Basic Composition

    Chemical

    NameCommon Name

    Chemical

    Notation

    Abbreviated

    Notation

    Mass

    Contents(%)

    calcium oxide lime CaO C 58-66

    silicon dioxide silica SiO2 S 18-26

    aluminium

    oxidealumina Al2O3 A 4-12

    ferric oxides iron Fe2O3 + FeO F 1-6

    magnesium

    oxidemagnesia MgO M 1-3

    sulphur

    trioxide

    sulphuric

    anhydriteSO3 S 0.5-2.5

    alkaline oxides alkalis K2O and NaO2 K + N

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    Manufacturing of Cement

    Producing a cement that meets specific chemicaland physical specifications requires carefulcontrol of the manufacturing process.

    The first step in the Portland cement

    manufacturing process is obtaining rawmaterials. Generally, raw materials consisting ofcombinations of limestone, shells or chalk, andshale, clay, sand, or iron ore are mined from aquarry near the plant. At the quarry, the rawmaterials are reduced by primary and secondarycrushers.

    Stone is first reduced to 5-inch size (125-mm),then to 3/4-inch(19 mm). Once the raw materialsarrive at the cement plant, the materials areproportioned to create a cement with a specificchemical composition.

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    Manufacturing of Cement

    Type of Manufacturing

    Wet Process

    Dry Process - 74% of cement produced

    Preheater/Precalciner Process

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    Manufacturing of Cement

    Dry Process

    In the dry process, dry raw materials are

    proportioned, ground to a powder, blendedtogether and fed to the kiln in a dry state.

    In the wet process, a slurry is formed by addingwater to the properly proportioned raw materials.

    The grinding and blending operations are thencompleted with the materials in slurry form. Afterblending, the mixture of raw materials is fed intothe upper end of a tilted rotating, cylindrical kiln.

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    Manufacturing of Cement

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    Manufacturing of Cement

    In the dry process, dry raw materials areproportioned, ground to a powder, blendedtogether and fed to the kiln in a dry state.

    In the wet process, a slurry is formed byadding water to the properly proportionedraw materials. The grinding and blendingoperations are then completed with thematerials in slurry form.

    After blending, the mixture of raw materialsis fed into the upper end of a tilted rotating,cylindrical kiln. The mixture passes throughthe kiln at a rate controlled by the slope androtational speed of the kiln.

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    Manufacturing of Cement

    Burning fuel consisting of powdered coal ornatural gas is forced into the lower end of thekiln.

    Inside the kiln, raw materials reachtemperatures of 1430oC to 1650oC. At1480oC, a series of chemical reactions causethe materials to fuse and create cementclinker-grayish-black pellets, often the size ofmarbles.

    Clinker is discharged red-hot from the lowerend of the kiln and transferred to varioustypes of coolers to lower the clinker tohandling temperatures.

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    Manufacturing of Cement

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    The Cement is Ready for Market

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    Cement Standards

    BS EN 197-1:2000 (Inc. Amendment No.1:2004)

    Composition, specifications and conformity criteria for

    common cements

    BS EN 197-4:2004

    Composition, specifications and conformity criteria for

    low early strength blast furnace cements

    BS EN 196-series

    Methods of testing cement

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    Cement Standards

    Cements are factory produced materials primarilyconforming to BS EN 197-1 or BS EN 197-4

    Some cements, such as Sulphate-resisting Portlandcement (SRPC) are however, still covered by residualBritish Standards

    There is a wide range of cements ranging from simplePortland cement to Composite cements containing upto three major constituents

    Cements may be produced by inter-grinding or blendingthe constituents at the cement works

    Cements can be CE marked against BS EN 197standards using BS EN 197-2 Conformity evaluation

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    Types of Portland Cement

    Different types of Portland cement are manufactured to

    meet various physical and chemical requirements.

    The American Society for Testing and Materials (ASTM)

    Specification C-150 provides for eight types of Portland

    cement.

    BS EN 197-1 specified Five main classes of Portland

    cement

    However, Both BS EN and ASTM specified some other

    types of cements for special functions.

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    Types of BS EN 197-1Portland

    Cement

    Composite cementsCEM V

    Pozzolanic cements (CEM IV/A, CEM IV/B)CEM IV

    Blastfurnace cements (CEM III/A, CEM III/B)CEM III

    Portland-composite cements including:

    -Portland-fly ash cement (CEM II/A-V, CEM II/B-V)

    -Portland-slag cement (CEM II/A-S, CEM II/B-S)

    -Portland-limestone cement (CEM II/A-L (LL),CEM II/B-L (LL)

    CEM II

    Portland cementCEM I

    DescriptionDesignation

    Composite cementsCEM V

    Pozzolanic cements (CEM IV/A, CEM IV/B)CEM IV

    Blastfurnace cements (CEM III/A, CEM III/B)CEM III

    Portland-composite cements including:

    -Portland-fly ash cement (CEM II/A-V, CEM II/B-V)

    -Portland-slag cement (CEM II/A-S, CEM II/B-S)

    -Portland-limestone cement (CEM II/A-L (LL),CEM II/B-L (LL)

    CEM II

    Portland cementCEM I

    DescriptionDesignation

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    How are Cements Designated

    Example: CEM II/A-LL 42,5 NExample: CEM II/A-LL 42,5 N

    CEM II: Portland composite cement

    A-LL: A signifies low proportion ofsecond constituent (6-20% in this case)

    L orLL signifies limestone as the

    second main constituent (LL signifies

    high purity limestone)42,5 N: Cement strength class 42,5

    Normal strength development

    Portland-limestone cementPortland-limestone cement

    Example: CEM II/A-LL 42,5 NExample: CEM II/A-LL 42,5 N

    CEM II: Portland composite cement

    A-LL: A signifies low proportion ofsecond constituent (6-20% in this case)

    L orLL signifies limestone as the

    second main constituent (LL signifies

    high purity limestone)42,5 N: Cement strength class 42,5

    Normal strength development

    Portland-limestone cementPortland-limestone cement

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    Portland Cement

    Portland cement is CEM I

    NOT

    Ordinary Portland cement, OPC or

    PC

    BUT

    CEM I

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    Cement strength Classes (I)

    There are three cement strength classes,based on the minimum 28 day mortar prismstrength

    32,5

    42,552,5

    Each class can be subdivided based on earlystrength development

    L: Low early strength

    N: Normal strength development

    R: High early strength

    Note: Use of

    comma ratherthan decimal point

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    Cement strength Classes (II)

    -52,5-2052,5 N

    -52,5-3052,5 R

    62,542,5-2042,5 R

    62,542,5-1042,5 N

    52,532,5-1032,5 R52,532,516-32,5 N

    Max.

    28Day

    Min.

    28Day

    Min.

    7 Day

    Min.

    2 Day

    StrengthClass

    -52,5-2052,5 N

    -52,5-3052,5 R

    62,542,5-2042,5 R

    62,542,5-1042,5 N

    52,532,5-1032,5 R52,532,516-32,5 N

    Max.

    28Day

    Min.

    28Day

    Min.

    7 Day

    Min.

    2 Day

    StrengthClass

    These classes apply to all CEM

    cements

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    Cement strength Classes (II)

    -52,5-1052,5 L

    62,542,516-42,5 L

    52,532,512-32,5 L

    Max.

    28Day

    Min.

    28Day

    Min.

    7 Day

    Min.

    2 Day

    StrengthClass

    -52,5-1052,5 L

    62,542,516-42,5 L

    52,532,512-32,5 L

    Max.

    28Day

    Min.

    28Day

    Min.

    7 Day

    Min.

    2 Day

    StrengthClass

    These low early strength classes apply

    only to BS EN 197- 4 CEM III cements

    These low early strength classes apply

    only to BS EN 197- 4 CEM III cements

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    Low Heat Cement

    BS EN 197-1: 2000 (inc. Amendment 1:2004)now covers some low heat cements

    Low Heat is defined as a characteristic heatof hydration not exceeding 270 J/g(measured at 7 days (EN 196-8) or 41 hrs (EN196-9))

    Low heat cements carry an LH suffix ie:

    Example: CEM III/B 32,5N - LH

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    Minor Additional Constituents (I)

    BS EN 197-1 allows for the inclusion of up to 5% bymass of a minor additional constituent (or mac) in alltypes of cement

    A mac is defined as: special ly selected ino rganicnatural m ineral mater ials, inorganic m ineral mater ials

    derived from the cl inker product ion process o r

    [speci f ied cement] cons t i tuents unless they are

    [al ready] included as m ain const i tuents in the cement

    Materials typically used as a mac include: Finely ground limestone

    Fly Ash

    Cement kiln dust (CKD)

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    Minor Additional Constituents (II)

    Cement containing a mac has to meet the sameperformance criteria as the same cement type andclass without a mac

    Setting timeStrength

    Soundness/Chemical requirements

    In specification terms a CEM cement with a macis considered to be identical to the same CEM

    cement without a mac

    A CEM I Portland cement with 5% mac is still a

    Portland cement and will perform in the same

    way as a similar cement without a mac !

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    Other Cements

    Sulfate-resisting Portland cement: still coveredby residual British Standard BS 4027

    Low early strength blastfurnace cements:

    covered by British Standard BS 146:2002 (tobe withdrawn Jan 2006)

    High-alumina cement: still covered by residualBritish Standard BS 915

    These standards will eventually be replaced by

    new European Standards, but progress on a

    standard for sulfate-resisting cement is slow

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    Hydration of Cement

    When Portland cement is mixed with water its chemicalcompound constituents undergo a series of chemicalreactions that cause it to harden (or set).

    These chemical reactions all involve the addition of water tothe basic chemical compounds. This chemical reaction withwater is called "hydration". Each one of these reactionsoccurs at a different time and rate. Together, the results ofthese reactions determine how Portland cement hardensand gains strength.

    Tricalcium silicate (C3S). Hydrates and hardens rapidly andis largely responsible for initial set and earlystrength. Portland cements with higher percentages of C3Swill exhibit higher early strength.

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    Hydration of Cement

    Dicalcium silicate (C2S). Hydrates and hardens slowly and islargely responsible for strength increases beyond one week.

    Tricalcium aluminate (C3A). Hydrates and hardensquickest. Liberates a large amount of heat almostimmediately and contributes somewhat to earlystrength. Gypsum is added to Portland cement to retard C3Ahydration. Without gypsum, C3A hydration would causePortland cement to set almost immediately after adding water.

    Tetracalcium aluminoferrite (C4AF). Hydrates rapidly butcontributes very little to strength. Its use allows lower kilntemperatures in Portland cement manufacturing. MostPortland cement colour effects are due to C4AF.

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    Hydration of Cement

    The result of the two silicate hydrations is the

    formation of a calcium silicate hydrate (often written

    C-S-H because of is variable stoichiometry). C-S-H

    makes up about 1/2 - 2/3 the volume of the hydratedpaste (water + cement) and therefore dominates its

    behavior (Mindess and Young, 1981).

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    Physical Properties of Cement

    Portland cements are commonly characterized by

    their physical properties for quality control

    purposes. Their physical properties can be usedto classify and compare Portland cements.

    The challenge in physical property

    characterization is to develop physical tests that

    can satisfactorily characterize key parameters.

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    Physical Properties of Cement

    Keep in mind that these tests are, in general, performed on"neat" cement pastes - that is, they only include Portlandcement and water.

    Neat cement pastes are typically difficult to handle and testand thus they introduce more variability into the results.

    Cements may also perform differently when used in a"mortar" (cement + water + sand).

    Over time, mortar tests have been found to provide a betterindication of cement quality and thus, tests on neat cementpastes are typically used only for research purposes(Mindess and Young, 1981).

    However, if the sand is not carefully specified in a mortartest, the results may not be transferable.

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    Physical Properties of Cement

    Fineness

    Fineness, or particle size of Portland cement affects hydration rate andthus the rate of strength gain. The smaller the particle size, the greaterthe surface area-to-volume ratio, and thus, the more area available for

    water-cement interaction per unit volume. The effects of greater finenesson strength are generally seen during the first seven days (PCA, 1988).

    Fineness can be measured by several methods: AASHTO T 98 and ASTM C 115: Fineness of Portland Cement by the

    Turbidimeter.

    AASHTO T 128 and ASTM C 184: Fineness of Hydraulic Cement by the150-mm (No. 100) and 75-mm (No. 200) Sieves

    AASHTO T 153 and ASTM C 204: Fineness of Hydraulic Cement by AirPermeability Apparatus

    AASHTO T 192 and ASTM C 430: Fineness of Hydraulic Cement by the45-mm (No. 325) Sieve

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    Physical Properties of Cement

    Soundness

    When referring to Portland cement, "soundness" refers to the ability of ahardened cement paste to retain its volume after setting without delayeddestructive expansion (PCA, 1988). This destructive expansion is causedby excessive amounts of free lime (CaO) or magnesia (MgO). Most

    Portland cement specifications limit magnesia content and expansion. Thetypical expansion test places a small sample of cement paste into anautoclave (a high pressure steam vessel).

    The autoclave is slowly brought to 2.03 MPa (295 psi) then kept at thatpressure for 3 hours. The autoclave is then slowly brought back to roomtemperature and atmospheric pressure. The change in specimen lengthdue to its time in the autoclave is measured and reported as a

    percentage. ASTM C 150, Standard Specif icat ion for Port land Cementspecifies a maximum autoclave expansion of 0.80 percent for all Portlandcement types. The standard autoclave expansion test is: AASHTO T 107 and ASTM C 151:

    Autoclave Expansion of Portland Cement

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    Physical Properties of Cement

    Setting Time

    Cement paste setting time is affected by a number of itemsincluding: cement fineness, water-cement ratio, chemical content(especially gypsum content) and admixtures. Setting tests are used

    to characterize how a particular cement paste sets. Forconstruction purposes, the initial set must not be too soon and thefinal set must not be too late. Additionally, setting times can givesome indication of whether or not a cement is undergoing normalhydration (PCA, 1988). Normally, two setting times are defined(Mindess and Young, 1981):

    Init ial set. Occurs when the paste begins to stiffen considerably.

    Final set. Occurs when the cement has hardened to the point atwhich it can sustain some load.

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    Physical Properties of Cement

    These particular times are just arbitrary points used to

    characterize cement, they do not have any fundamental

    chemical significance. Both common setting time tests,

    the Vicat needle and the Gillmore needle, define initialset and final set based on the time at which a needle of

    particular size and weight either penetrates a cement

    paste sample to a given depth or fails to penetrate a

    cement paste sample. The Vicat needle test is morecommon and tends to give shorter times than the

    Gillmore needle test. Table 3.14 shows ASTM C 150

    specified set times.

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    Physical Properties of Cement

    Test Method Set Type Time Specification

    VicatInitial 45 minutes

    Final 375 minutes

    Gillmore Initial 60 minutesFinal 600 minutes

    The standard setting time tests are:

    AASHTO T 131 and ASTM C 191: Time of Setting of Hydraulic Cement

    by Vicat Needle

    AASHTO T 154: Time of Setting of Hydraulic Cement by GillmoreNeedles

    ASTM C 266: Time of Setting of Hydraulic-Cement Paste by Gillmore

    Needles

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    Physical Properties of Cement

    StrengthCement paste strength is typically defined in three ways:

    compressive, tensile and flexural. These strengths can be

    affected by a number of items including: water-cement ratio,

    cement-fine aggregate ratio, type and grading of fine

    aggregate, manner of mixing and molding specimens,

    curing conditions, size and shape of specimen, moisture

    content at time of test, loading conditions and age (Mindess

    and Young, 1981). Since cement gains strength over time,

    the time at which a strength test is to be conducted must bespecified. Typically times are 1 day (for high early strength

    cement), 3 days, 7 days, 28 days and 90 days (for low heat

    of hydration cement). When considering cement paste

    strength tests, there are two items to consider:

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    Physical Properties of Cement

    Cement mortar strength is not directly related to concrete

    strength. Cement paste strength is typically used as a

    quality control measure.

    Strength tests are done on cement mortars (cement + water +sand) and not on cement pastes.

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    Physical Properties of Cement

    Comp ressive Strength

    The most common strength test, compressive strength, is carried out on

    a 50 mm (2-inch) cement mortar test specimen. The test specimen is

    subjected to a compressive load (usually from a hydraulic machine) until

    failure. This loading sequence must take no less than 20 seconds and

    no more than 80 seconds. Following Table shows ASTM C 150

    compressive strength specifications.

    The standard cement mortar compressive strength test is:

    AASHTO T 106 and ASTM C 109: Compressive Strength of HydraulicCement Mortars (Using 50-mm or 2-in. Cube Specimens)

    ASTM C 349: Compressive Strength of Hydraulic Cement Mortars

    (Using Portions of Prisms Broken in Flexure)

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    Physical Properties of Cement

    Portland Cement TypeCuring

    Time I IA II IIA III IIIA IV V

    1 day - - - -12.4

    (1800)

    10.0

    (1450)- -

    3 days12.4

    (1800)

    10.0

    (1450)

    10.3

    (1500)

    8.3

    (1200)

    24.1

    (3500)

    19.3

    (2800)-

    8.3

    (1200)

    7 days19.3

    (2800)

    15.5

    (2250)

    17.2

    (2500)

    13.8

    (2000)- --

    6.9

    (1000)

    15.2

    (2200)

    28 days - - - - - -17.2

    (2500)

    20.7

    (3000)

    Note: Type II and IIA requirements can be lowered if either an optional heat of

    hydration or chemical limit on the sum of C3S and C3A is specified

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    Physical Properties of Cement

    Tens i le Streng th

    Altho ugh st i l l speci f ied by ASTM, the direct tension test

    does no t prov ide any useful insight into the conc rete-

    making propert ies of cements. It persis ts as a specif ied

    test because in the early years o f cement manufactu re,

    i t used to be the mos t common test since it was di f f icul t

    to f ind machines that could compress a cement sample

    to failure.

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    Physical Properties of Cement

    Flexural Streng th

    Flexural strength (actual ly a measure of tensi le strength inbend ing ) is carr ied ou t on a 40 x 40 x 160 mm (1.57-inch x 1.57-inc hx 6.30-inch) cement mo rtar beam. The beam is then loaded at itscenter point unt i l fa i lure.

    The standard cement mortar f lexu ral strength test is: ASTM C 348: Flexu ral Streng th o f Hydraul ic Cement Mor tars

    Specif ic Gravi ty Test

    Speci f ic gravi ty is normal ly used in mixture propor t ion ingcalculat ions. The specif ic gravi ty of Port land cement is general ly

    around 3.15 whi le the specif ic gravi ty of Port land -blast-furnace-slag and Po rt land -pozzolan c ements m ay have specif ic g ravi t iesnear 2.90 (PCA, 1988).

    The standard specif ic gravi ty test is:

    AASHTO T 133 and ASTM C 188: Dens ity o f Hydraul ic Cement

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    Physical Properties of Cement

    Heat of Hydrat ion

    The heat of hydrat ion is the heat generated when water and

    Port land cement react. Heat of hydrat ion is mos t inf luenced by the

    propo r t ion of C3S and C3A in th e cement, but is also inf luenced by

    water-cement rat io, f ineness and cu r ing temperature. As each one

    of th ese factors is inc reased, heat of h ydrat ion in creases.

    In large mass con crete struc tures such as gravi ty dams , hyd rat ion

    heat is produced signi f icant ly faster than it can be dissipated

    (especial ly in the center of large con crete masses), which can

    create high temperatures in the center of these large con crete

    masses that, in turn, may cause undesirable stresses as theconc rete coo ls to ambient temperature. Conversely, the heat of

    hydrat ion can help maintain favorable cur ing temperatures dur ing

    w in ter (PCA, 1988).

    The standard heat of hy drat ion test is:

    ASTM C 186: Heat of Hyd rat ion o f Hydrau l ic Cement

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    Physical Properties of Cement

    Loss on Igni t ion

    Loss on igni t ion is calculated by heat ing up a cement

    sample to 900 - 1000C (1650 - 1830F) un ti l a cons tan t

    weight is obtained. The weight loss of the samp le due to heat ing is th en

    determ ined. A high loss on igni t ion can indicate pre-

    hydrat ion and carbonation, wh ich may be caused by

    imp roper and p rolonged storage or adul terat ion du r ing

    transpo rt o r trans fer (PCA, 1988).

    The standard loss on igni t ion test is con tained in:

    AASHTO T 105 and ASTM C 114: Chemical Analysis of

    Hydraul ic Cement

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    Application of Different Types

    of Cement

    Portland Cement CEM I

    CEM I is the cement that has been most

    commonly used throughout the world incivil engineering and building works.

    Concretes and mortars made using CEM

    I are versatile, durable and forgiving of

    poor construction practice.

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    Application of Different Types

    of Cement

    Sulphate-Resisting Cements

    SRPC is normally a low alkali cement which benefitsconcrete in resisting the alkali silica reaction (ASR).However, it is not the only sulphate-resisting cementavailable. Various factory-made composite cements arealso sulphate-resisting including the generally availableCEM II/B-V type of Portland-fly ash cement containing atleast 25% of fly ash. Such CEM II/B-V cements arepermitted for use in the same wide-range of sulphate

    exposure conditions as is SRPC and are also low inreactive alkalis. Moreover, SRPC is a type of CEM Icement with a high clinker content, it is no longermanufactured in the UK and is becoming more difficult tosource. Consequently, greener sulphate-resistingcomposite cements will continue to grow in importance.

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    Application of Different Types

    of Cement

    SRPC is used where precaution against moderate

    sulphate attack is important, as in drainage structures

    where sulphate concentrations in groundwater are

    higher than normal but not unusually severe (Table).

    Relative Degreeof Sulfate Attack

    Percentage Water-SolubleSulfate (as SO4) in Soil

    Samples

    Sulfate (as SO4) inWater Samples,

    ppm

    CementType

    Negligible 0.00 to 0.10 0 to 150 CEM IPositive 0.10 to 0.20 150 to 1500 SRPC

    Severe 0.20 to 2.00 1500 to 10,000 CEM II/B-V

    Very Severe 2.00 or more 10,000 or more CEM II/B-V

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    Application of Different Types

    of Cement

    Rapid Hardening Portland Cements

    Rapid hardening versions of CEM I cements are

    available. The average particle size is smaller in these

    cements and they gain strength more quickly than doordinary CEM I types. They generate more heat in the

    early stages and can be useful in cold weather

    concreting. However, their principal use is in

    manufacturing precast concrete units where the highearly strength of the concrete permits quick re-use of

    moulds and formwork.

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    Application of Different Types

    of Cement

    White Cement

    White cement is a Portland cement CEM I made

    from specially selected raw materials, usuallypure chalk and white clay (kaolin) containing

    very small quantities of iron oxides and

    manganese oxides. White cement is frequently

    chosen by architects for use in white, off-whiteor coloured concretes that will be exposed,

    inside or outside buildings, to the public's gaze.

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    Application of Different Types

    of Cement

    White Cement

    White cement is a Portland cement CEM I made

    from specially selected raw materials, usuallypure chalk and white clay (kaolin) containing

    very small quantities of iron oxides and

    manganese oxides. White cement is frequently

    chosen by architects for use in white, off-whiteor coloured concretes that will be exposed,

    inside or outside buildings, to the public's gaze.

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    Summary

    Port land cement, the chief ingredient in cement paste,

    is the most w idely used bui ld ing mater ial in the wo r ld.

    In the presence of water , the chemical compounds

    with in Port land cement hydrate causing hardening and

    strength gain.

    Port land cement can be speci f ied based on i ts chem ical

    compos i t ion and other var ious physical character ist ics

    that affect i ts behavior.

    Tests to character ize Port land cement, such as

    f ineness, soundness, sett ing t ime and strength are

    useful in quali ty contro l and speci f ications but should

    no t be subs t i tuted for tests on PCC.

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    Thank You