1.Spherical Powders Technologyeng.luxonkorea.co.kr/down/Spherical Powder Technology ver... · 2020....

Copyright © 2020 by LUXON Co,. Ltd. ALL RIGHTS RESERVED.

1

Spherical Powders TechnologyVersion 1.1

For more information

Home Page : www.luxonkorea.co.kr

E-Mail: [email protected] (EN)

[email protected] (CN)

Office telephone : +82-31-943-7751

Cellular Phone : +82-10-9869-7751

http://www.luxonkorea.co.kr


INCI Name Product Name Particle Size(µ m)Oil Absorption

(ml/100g)

SILICA Non-coated

Silica

SILIA LX3 3

130~180SILIA LX7 7

SILIA LX13 13

SPHESTA SB606 6

50~80SPHESTA SB609 9

SPHESTA SB6013 13

SPHESTA MD7 7 90~130

SPHESTA HS10 10 230~270

SILICA coated

Silica

SILIA LX7 ASM 7 80~140

SPHESTA MD6 ASM 6 90~130

SPHESTA MD6 MSM 6 90~130

SPHESTA MD6 DSM 6 60 ~ 90

Spherical Porous Silica Powder



Spherical Porous Silica powder

High Purity

Sebum Control

Semi-transparent

Soft focus effect

Smooth feeling

EU REACH

Ecocert

Spherical Porous Silica Powder



User Guideline of SHPESTA



Analysis recipe

Must proceed to Pure Water.

Part Ingredients %

AD.I-Water 76.5

Carbopol 940 1% sol. 17.0

BD.I-Water 1.0

TEA 0.5

C Powder 5.0

1. Prepare 200ml beaker

2. Carbopol 940 1% solution prepared in advance

3. Manufactured A Phase and prepared for the

first time.

4. Manufacture B Phase and put it into A Phase.

5. Manufactured at maximum rpm of stirrer

6. Understand the flowability of the final Phase.

TEST Method

TEST Results

MD7 ‘S’ co ‘A’ co


Excellent Thickener Compatibility

Thickener compatibility TEST_Carbopol 940



Analysis recipe

Must proceed to Pure Water.

Part Ingredients %

AD.I-Water 94.0

RHEOSOL AVH 1.0

B Powder 5.0

1. Manufactured A Phase

2. Put B Phase into A Phase.

3. Manufactured at maximum rpm of stirrer

4. Understand the flowability of the final Phase.

TEST Method

TEST Results



Excellent Thickener Compatibility

Thickener compatibility TEST_RHEOSOL AVH


Our Proposal of Basic Foundation ( SPF40, PA+++ )

PHASE RAW MATERIALS INCI %

A

LX SUN MCX Ethylhexyl Methoxycinnamate 6.00

LX SUN EHS Ethylhexyl Salicylate 4.00

SF 5600Z Phenyl Trimethicone 10.00

BSF 0015Z Cyclopentasiloxane (and) Cyclohexasiloxane 5.00

Bentone 38 VCG Disteardimonium Hectorite 0.50

CMicrocare e 9016 Cetyl PEG/PPG-10/1 Dimethicone 3.50

Rheodol AO-15 Sorbitan Sesquioleate 1.00

D

LX Bianco 200HDTitanium Dioxide / Aluminum / Hydrogen Dimethicone

10.00

LX IOY ASM Iron oxide yellow / Triethoxycaprylylsilan 0.50

LX IOR ASM Iron oxide red / Triethoxycaprylylsilan 0.15

LX IOB ASM Iron oxide blue / Triethoxycaprylylsilan 0.10

ZINC STEARATE Zinc Stearate 1.00

SILIA LX7 Silica 3.70

LX SS150 Zinc Oxide / Silica / Triethoxycaprylylsilane 2.00

E

WATER Water To 100

EDTA-2Na Disodium EDTA 0.05

MgSO4 Magnesium Sulfate Heptahydrate 1.00

LX MOILUB 1000 Biosaccharide Gum-1 2.00

F PRESERVATIVESCaprylhydroxamic Acid/CaprylylGlycol/Glycerin

2.00

Key Ingredients our products

1. LX Bianco 200HD2. LX IOY ASM, LX IOR ASM,

LX IOB ASM 3. SILIA LX74. LX SS150

Commend

5. LX SUN MCX, EHS

6. LX MOILUB 1000

HTT0714FD01

Standard Operating Procedures

1. Heat phase A to 85℃, then homomix at 3500rpm for 10 minutes.

2. After homo dispersing phase B at 2000rpm , 85 ℃, for 10 minutes, add to phase A

3. Homo disperse phase C at 1500 rpm for 5 minutes, and then add to phase A

4. Add phase D into phase A

5. After homo dispersing phase E at 1500rpm at 85℃, add to phase A

6. Add phase F into phase A at 60℃



Our Proposal of Double Make-up Foundation (SPF 30 PA++)


A

TMS 803 50C Cyclopentasiloxane/ Trimethyl siloxysilicate 25.00

Microcare e9016 Cetyl PEG/PPG-10/1 Dimethicone 3.50

REODOL AO-15 Sorbitan Sesquioleate 1.50

BDC 245 Cyclopentasiloxane 5.00

BENTON 38V CG Disteardimonium Hectorite 1.50

C

LX MICA DSM Mica, Dimethicone 1.00

LX PMSQ P50 Polymethylsilsesquioxane 2.00

SPHESTA MD 7 Silica 2.00

D

DACHE EZH Ti70 Please refer to MSDS 18.00

DACHE EZH IOY50 Please refer to MSDS 2.60

DACHE EZH IOR55 Please refer to MSDS 0.70

DACHE EZH IOB60 Please refer to MSDS 0.15

E

Water Water To 100

Disodium EDTA Disodium EDTA 0.02

Sodium Chloride Sodium Chloride 1.50


Preservative Phenoxyethanol, Caprylyl Glycol, 1,2hexandiol 2.00

Allantoin Allantoin 0.02

D-Panthenol D-Panthenol 0.02

Key Ingredients of LUXON products

• DACHE EZH Ti70

• DACHE EZH IOY50

• DACHE EZH IOR55

• DACHE EZH IOB60

• LX MICA DSM

• LX PMSQ P50

• SPHESTA MD 7

• MD 7

Recommend use with

• LX MOILUB 1000


1. Heat phase A to 80℃.

2. Heat phase B to 80℃., then Homomix at 3000rpm for 5minutes. And add to phase A.

3. Add phase C to phase A+B

4. Add phase D into phase A+B+C

5. After homo dispersing phase E at 3000rpm for 5minutes at 85℃, add to phase A+B+C+D

6. Homomix at 3500rpm for 10 minutes.

7. Cooling & Defoaming.



Ingredient

Silica, Corn Starch modified, Dimethicone, Vinyl Dimethicone Crosspolymer, Caprylic/Capric Triglyceride, Mica, Methicone, Mineral Salts, Camellia Sinensis Leaf Extract,. Mentha Arvensis Leaf ExtractEthylhexylglycerin, Glyceryl caprylate, Ethylene/Acrylic Acid Copolymer, 1,2-Hexanediol, Fragrance

Key Ingredients

SPHESTA MD7

LX Mica DSM

LX PMSQ P50

Formulation for SEBUM control powder in use SPHESTA[SILIA] Series

Phase Trade Name INCI %

A SPHESTA MD7 Silica 56.75

HICOS GTC Caprylic/Capric Triglyceride 5.00

B Dry Flo PC Aluminum Starch Octenylsuccinate 25.00


LX Mica DSM Mica, Dimethicone 3.00

C SpectrastatCaprylhydroxamic Acid/CaprylylGlycol/Glycerin

0.15

Perfume 0.10

100.0

Our Proposal of Sebum control powder



Is a cross linked polymethylmetaacrylate powder

Touch modifying agent

Soft feel effect

Gloss control

Concealing effect to hide defects


(ml/100g)

PMMA

Poly methyl-metacrylate LX PMMA PR7 7 50 ~ 80

LX PMMA PR7

Poly MethylMethacylate Powder



LX PMMA PR7 is organic crosslinked microsphere developed by Luxon’s original suspension polymerization. When it was used to cosmetic, it provides a rolling effect, the prevention of aggregation, an elegant silky texture, oil absorption etc. Also LX PMMA PR7 overcame the limitation of application due to high specifics surface and the introduction of functional groups. These characteristics of LX PMMA PR7 allow for the use of other application such as LCD panel filler, toner for electronic photos, as well as the super plasticizer of paints and inks.

Characteristics of products

Spherical cross-linked organic particles Various sizes with low moisture content and neutral pH Excellent chemical and thermal stability Readily dispersed in numerous solvents Impart desirable physical properties Suitable for additive or perfume carrier due to its oil absorption Best spread ability, provides very soft feeling to skin Suitable for the payoff control of pressed-type product Water insoluble

LX PMMA PR7

Poly MethylMethacylate Powder



Our Proposal of Loose Powder formulation

Phase Trade Name INCI %A SILIA LX-7 Silica 59.493

LX PMMA PR-7 Polymethylmethacrylate 20.0

LX ELASTA SP101Vinyl Dimethicone/MethiconeSilsesquioxane Crosspolymer

2.0

LX Glight-1000Boron Nitride &

Triethoxycaprylylsilane4.0

BNeossanceHemisqualane

Hemisqualane 1.0

DC556 Phenyl Trimethicone 5.0

Demosoft GMCY Glyceryl caprylate 0.3

SC-50 EthylhexylGlycerin 0.2

W-RF16011781 Fragrance 0.007

100.0


1. SILIA LX-7

2. LX PMMA PR-7

3. LX ELASTA SP101

4. LX Glight-1000


1. Weigh A and Mix it2. Weigh B and Mix it 3. Input B into A Mixer 3,000rpm ; 15Sec, 3times4. Filter by 100 Mesh



Spherical PMSQ is widely used in

Color cosmetics

Daily skin care porducts

Recreational sunscreen products


(ml/100g)

PMSQ

Poly methyl-silsequioxane LX PMSQ P50 5 40 ~ 60

LX PMSQ P50

Poly Methylsilsequioxane Powder



LX PMSQ is a silicone resin sphere with 3-dimensional network structure.

INCI name is polymethylsilsequioxane.

Low reflective index 1.43

Does not dissolve or swell in all sorts of solvent

Excellent water repellency

More slip an lubricity / better skin feel

Excellent elasticity

Water Insoluble

LX PMSQ P50

Poly Methylsilsequioxane Powder




A

TMS 803 50C Cyclopentasiloxane/ Trimethyl siloxysilicate 20.00

Microcare e9016 Cetyl PEG/PPG-10/1 Dimethicone 3.50

REODOL AO-15 Sorbitan Sesquioleate 2.00

Parsol MCX Ethylhexyl Methoxycinnamate 5.00

BDowsil F2-3196 Caprylyl Methicone 5.00

BENTON 38V CG Disteardimonium Hectorite 0.50

C

LX MICA AM Mica, Lauroyl lysine 1.00


SPHESTA MD 7 Silica 2.00

D

DACHE EZH Ti70 Please refer to MSDS 25.00

DACHE EZH IOY50 Please refer to MSDS 5.60

DACHE EZH IOR55 Please refer to MSDS 1.60

DACHE EZH IOB60 Please refer to MSDS 0.2

E

Water Water To 100

Disodium EDTA Disodium EDTA 0.02

Sodium Chloride Sodium Chloride 1.50


Preservative Phenoxyethanol, Caprylyl Glycol, 1,2hexandiol 2.00

Allantoin Allantoin 0.02

D-Panthenol D-Panthenol 0.02

Our Proposal of Moisture fit Foundation (SPF 15 PA+)

Key Ingredients of LUXON products

• DACHE EZH Ti70

• DACHE EZH IOY50

• DACHE EZH IOR55

• DACHE EZH IOB60

• LX MICA DSM

• LX PMSQ P50

• SPHESTA MD 7

Recommend use with

• LX MOILUB 1000


1. Heat phase A to 80℃.

2. Heat phase B to 80℃., then Homomix at 3000rpm for 5minutes. And add to phase A.

3. Add phase C to phase A+B

4. Add phase D into phase A+B+C

5. After homo dispersing phase E at 3000rpm for 5minutes at 85℃, add to phase A+B+C+D

6. Homomix at 3500rpm for 10 minutes.

7. Cooling & Defoaming.


Microbeads Issue


EU proposes ban on 90% of microplastic pollutants



Problem

Micro Beads Problems



Plastic in cosmetics is a design error



Our Proposal

SPHESTA SB606 HSM

SPHESTA ECO 3(Natural)

SPHESTA ECO 7(Natural)

SPHESTA ECO H10(Natural)

SS-2000

Type Spherical powder Spherical Powder Spherical Powder Spherical Powder Spherical Powder

INCISilica & Hydrogen

Dimethicone

Silica & Lauryl Alcohol& Cetyl Alcohol



Zinc Oxide & Triethoxycarylylsil

ane

CAS. NO7631-86-9

& 68037-59-2

7631-86-9& 112-53-8

& 36653-82-4

7631-86-9& 112-53-8

& 36653-82-4

7631-86-9& 112-53-8

& 36653-82-4

1314-13-2 & 2943-75-1

Particle Size 4.5 ~ 7.5 um 1.5 ~ 4.5 um 7.0 ~ 11 um 10.0 ~ 15.0 um 1.0 ~ 3.0 um

OilAbsorption

55 50 ~ 90 50 ~ 90 170 ~ 210 50 ~ 70

Hydrophobicity[LXTM-007] 3.5 min 3.5 min 3.5 min 3.5 min 3.5 min

Patent Pending: KR 10-2020-0075958



Water Cyclopentasiloxane Liquid Paraffin Water Cyclopentasiloxane Liquid Paraffin

SPHESTA ECO H10SPHESTA ECO H10 SPHESTA ECO H10 PMMA Porous PMMA Porous PMMA Porous

SPHESTA ECO H10 PMMA Porous type

Water Cyclopentasiloxane Liquid Paraffin

SILICA STANDARD SILICA STANDARD SILICA STANDARD

SILICA Standard ( Non coating )

After input 3min After input 3min

After input 3min

Selective sebum control

Selective Sebum Control Test



1. Disperse A and B respectively

2. Mix A and B, disperse after adding C

3. Heating D at 60 °C and confirming

complete dissolution, then cooling to 25 °C

4. Put D in A~C to emulsify

( 7000rpm, 8 min )

5. Finish after cooling to 35 °C


1. LX NT95 HD (TIO2)

2. LX HPA30 HD (ZnO)

3. LX SS150 (ZnO)

4. SPHESTA ECO H10

5. SILIA LX7 ASM

Commend

6. LX MOILUB 1000

7. LX SUN MCX, EHS, HMS, TNS

Our Proposal of Sun Cream Sebum Care W/S ( SPF50+, PA++++ )

PHASE Ingredient INCI %

A

SF1202 Cyclopentasiloxane 16.00

BENTONE 38V CG Disteardimonium Hectorite 1.20

MICROCARE E9016 Cetyl PEG/PPG-10/1 Dimethicone 3.00

LX GEL A20Dimethicone / Phenyl Trimethicone / Cyclomethicone Crosspolymer

2.00

DC556 Phenyl Trimethicone 3.50

B

FINSOLV TN-O C12-15 Alkyl Benzoate 5.00

LX SUN MCX Ethylhexyl Methoxycinnamate 7.00

LX SUN EHS Ethylhexyl Salicylate 4.00

LX SUN HMS Homosalate 2.00

LX SUN TNSBis-Ethylhexyloxyphenol Methoxyphenyl Triazine

0.50

LX NT95 HDTitanium Dioxide / Aluminum Hydroxide / Stearic Acid / Dimethicone

7.00

LX HPA30 HD Zinc Oxide / Hydrogen Dimethicone 6.00

LX SS150Zinc Oxide / Silica / Triethoxycaprylylsilane

2.00

SPHESTA ECO H10 Silica / Cetyl Alcohol / Lauryl Alcohol 2.00

SILIA LX7 ASM Silica / Triethoxycaprylylsilane 2.00

C

D.I.WATER Water To 100

NACL Sodium Chloride 1.00

LX MOILUB 1000Biosaccharide Gum-1PEG/PPG17/6 Copolymer

3.50

D PreservativesPentylene Glycol,Ethylhexylglycerin,Phenoxyethanol

2.00

SB606 HSM & Nylon-12



SPHESTA SB606 HSM Nylon-12(T co,Ltd)

Type Spherical powder Spherical powder

INCI Silica & Hydrogen Dimethicone Nylon-12

CAS. NO7631-86-9

& 68037-59-225038-74-8

Particle Size 4.5 ~ 7.5 um 5.0 ~7.0um

Oil Absorption 50 ~ 90 50 ~ 90

Hydrophobicity[LXTM-007]

3.5 5.0

SB606 HSM & Nylon-12



① : SPHESTA SB606 HSM ② : Nylone-12

Manufacturer LUXON ‘S’ company

Loss on Drying 0.65% 0.76%

Hydrophobicity 5 5

Median Size (㎛) 6.90 7.88

PH 7.30 7.50

Oil Absorption 53 57

SEM

Heat Resistance(130℃ 30min)

Yellow Index 3.01 Yellow Index 6.12

SPHESTA SB606 HSM & ‘S’co Nylone-12

SPHESTA SB606HSM_comparison analysis



Analysis equipment : Malvern Instruments

① : SPHESTA SB606 HSM (LUXON)

Results

D50 6.90 ㎛

D90 11.00 ㎛

② : Nylone-12 (‘S’ company)

Results

D50 7.88 ㎛

D90 17.60 ㎛

Side Effect

# Side Effect : particle aggregation, rough feeling

Comparison Analysis



Philicsta MD7



No Sebum Toner

IOPEPore ResetMattifying Toner

Water, Ethanol, Propanediol, Glyserine, 1,2 hexanediol,

Green tea extract, Silica, Bis-peg 18 methylethyldimethylsilane,

PG-60 Hydrogenated Castor Oil, Butylene Glycol, SmallIndium

magnesium silicate, ethylhexyl glycerin, calcium chloride,

2Na EDTA, fragrance

All ingredients

No Sebum Toner with Silica

Silica function

Easy daily sebum care withpowder toner

Sensory additive Enhanced stability in O/W

Silica layer



No Sebum Toner

Pong DangDaily ClarifyingFacial Toner

All ingredients Silica

Silica layer

No Sebum Toner with Silica

Silica function

Easy daily sebum care withpowder toner

Sensory additive Enhanced stability in O/W



SPHESTA MD 7( Standard Silica )

PHILICSTA MD7( Special Silica )

Type Spherical Powder Spherical Powder

INCI Silica Silica

& Phytic Acid

CAS. NO 7631-86-97631-86-9 &

83-86-3

Particle Size 5.0 ~ 9.0 um 5.0 ~ 9.0 um

Oil Absorption 50 ~ 90 70 ~ 110

Hydrophobicity

[LXTM-007]1.0 max 1.0 max

Our Proposal

OP

HO

OHO

O

P OH

OH

OOP

OHHO

OOP

OH

HO

O

OP

HO

HO

O

OP

OH

OHO

Coating Agent

Phytic Acid



Dispersion Test Method

1. Water : 60g + 3g ; vial 100ml2. Mixer ( 500rpm; 3min )3. Precipitation for 24hr4. Shaking 10times5. Turn vial over6. Check the redispersibility

Sample A

Water 50g Powder 2g

Powder Input

Mixer ; 500rpm 3min

Sample B

Precipitation for 24hr Hand Shaking 10times

Sample B

Turn Vial Over

Sample A Sample B

Sample A

ExcellentRedispersibility

1 2 3

4 5 6

Redispersibility test of Water



Standard Silica HYDROPHILICSTASilica

Precipitation for 24hr After Shaking 10times, Turn over

Sample A Sample B

Sample B Sample A

ExcellentRedispersibility

Standard Silica HYDROPHILICSTASilica

Test Result of redispersibility Water


Korea Factory/R&D : 4th Fl, B, 512, Hoedong-gil, Paju-si, Gyeonggi-do, Korea Tel:+82-31-943-7751 Fax:+82-31-943-7752

China HuZhou Factory : No.328 Guangyuan Road,Wuxing District,Huzhou City, ZheJiang Province, China Tel:+86-572-2607665 Fax:+86-572-2607-675

Shanghai Branch : Rm 2116,Block A,East International Building,No.85 Loushanguan Rd,Changning District,Shanghai City,China Tel:+86-21-6278-2288~216 Fax:+86-21-6278-3723

Website : http://www.luxonkorea.co.kr

Thank you

1.Spherical Powders Technologyeng.luxonkorea.co.kr/down/Spherical Powder Technology ver... · 2020....

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