1_HempelPackage 8783

Hempel helps Mlheim provide a smooth flow

Its a long journey by pipeline from Russia to Western Europe, so anything to make the natural gas flow more smoothly is welcomed. HEMPELS HS GAS PIPE COATING 87830 specialises in doing just that. It is applied as a one-coat lining for natural gas transport pipes.

HEMPELS HS GAS PIPE COATING 87830 is designed to reduce drag resistance by making the inside pipe walls smoother, explains Gregor Schiffer, Hempel Germanys salesperson serving pipeline customers. We call it flow coat. When the gas flows faster, fewer pumping stations are needed to keep the gas flowing.

Hempel Germany has been supplying HEMPELS HS GAS PIPE COATING 87830 to Mlheim Pipecoatings GmbH, a supplier of pipes for, among other projects, the Nord Stream I offshore pipeline taking form along the bottom of the Baltic Sea from Vyborg, Russia to Greifswald, Germany. At 1,222 km, this will be the worlds longest subsea pipeline. It is to be completed during 2011.

Mlheim is providing 75% (860,000 tonnes) of the pipes for Nord Stream I. It also has signed a contract to provide coated pipes for Nord Stream II, a second pipeline to run parallel to the first. Construction of the second is to begin in spring 2011 and be completed in 2012.

PIPE COATING 87830 is a two-component epoxy polyamine cured coating formulated in accordance with the American Petroleum Institutes standard RP5L2 (Internal Coating of Line Pipe for Non-corrosive Gas Transmission Service). It features very low VOCs (130 g/l), high solids (81%), and fast drying.

Mlheim Pipecoatings application technology takes full advantage of PIPE COATING 87830s excellent qualities. The two-component product is applied by airless spray and mixed at the nozzle. The paint is warmed to 40 C, which reduces the viscosity to provide a more even paint flow and coverage.

The guys working close to the nozzle of the spray gun say it is easier to handle this product, Mr. Schiffer reports. Relative to competing products, Mlheim experience has shown 87830 to have less odour, less wear on the spray nozzles, and allows easier cleaning of the spray equipment. There is no contamination in the dry film and the paint film is very uniform and with a lower roughness profile.

Very importantly, Mr. Christian Balkenohl, Production Manager at Mlheim Pipecoatings, reports that its customer is satisfied with the performance of PIPE COATING 87830 and the finished pipes.

Hempels dedication has led to a very good project realization up to now, Mr. Balkenohl notes. We are sure it will continue in the same way through the coating phase for the Nord Stream Pipeline Project and that it will open a new horizon for future cooperation on gas pipeline projects requiring flow coat.

Based upon the experience with HEMPELS HS GAS PIPE COATING 87830, Hempel has made adjustments to the product to extend the shelf life, which is a challenge for high solids paints applied with low dry film thickness. This new product is named HEMPELS HS GAS PIPE COATING 87831. It has passed all relevant tests according to the standards DIN EN 10 201:2003, ISO 15741:2001 and TRANSCO CM2.

HEMPELS HS GAS PIPE COATING 87830

Case Stories

H EMP E L C A S E S T O R I E S 1

Hempel works with Bredero Shaw to lower VOCs and save costs

Engineers and transport companies designing and constructing natural gas pipelines aim to build pipelines through which gas can flow faster and at lower cost. Bredero Shaw is supplying its customer pipes to meet those demands for building the 940 km QSN3 gas pipeline from South Australias Moomba Gas Fields to South West Queensland. It has chosen HEMPELS HS GAS PIPE COATING 87830 for coating half of the project.

Texas-based Bredero Shaw bills itself as the global leader in pipe coating solutions, so its coating systems simply must be the best available. The companys cooperation with Hempel began about 5 years ago, explains Chris Francis, Manager Container & Pipelines at Hempel (Australia). The QSN3 is owned by Epic Energy, and it has contracted with Netherlands-based Nacap to do the construction.

We introduced HEMPELS HS GAS PIPE COATING 87830 to them a short time later, Mr. Francis explains, when the QSN3 project was in front-end engineering design. We offered the advantages of higher solids volume (81% compared to 48% offered by the competing supplier) that also better fit the clients production system, a smoother and glossier finish, cost-savings via a massive 40% lower paint consumption, as well as better work place safety and lower VOCs.

HEMPELS HS GAS PIPE COATING 87830 is a two-component epoxy polyamine cured coating formulated in accordance with the American Petroleum Institutes standard RP5L2 (Internal Coating of Line Pipe for Non-corrosive Gas Transmission Service). In addition to its very low VOCs (130 g/l) and high solids (81%), it is also fast drying and has good application properties.

At the end of the day, Mr. Francis explains, our success was due to the fact that, by using HEMPELS HS GAS PIPE COATING 87830, our customer was able to offer significant savings while providing a quality finish.

An internally lined gas pipe reduces friction, Mr. Francis adds, thus providing greater flow capacity, or allowing smaller gauge pipes to deliver equivalent gas flow. The pipes are easier to pig and clean while the coating also provides corrosion protection.

(A final note: Based upon the experience with HEMPELS HS GAS PIPE COATING 87830, Hempel has made adjustments to the product to extend the shelf life, which is a challenge for high solids paints applied with low dry film thickness. This new product is named HEMPELS HS GAS PIPE COATING 87831. It has passed all relevant tests according to the standards DIN EN 10 201:2003, ISO 15741:2001, TRANSCO CM2, and API RP5L2.)

HEMPEL (UK) LTD.Llantarnam Industrial ParkGwent NP44 3XF CwmbranTel.: +44 (01633) 874024Fax: +44 (01633) 489089E-mail: [email protected]


Case Stories

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H EMP E L C A S E S T O R I E S 2

4Typical useHEMPELS HS GAS PIPE COATING 87831 is used as a one-coat system for internal protection of gas pipes designed for carrying of dry, sweet gas. The coating is designed to reduce the drag resistance in the pipeline by making the pipe walls smoother.

Improve gas flow Reduced pumping costs - increased pipeline life Long term corrosion protection and chemical resistance Easier and faster inspection of pipeline More effective pigging/scraping Improved product purity Diverse pipeline use easier product switch Environment protection

4Product descriptionHEMPELS HS GAS PIPE COATING 87831 is a two-component epoxy polyamine cured coating. Formulated according to the requirements in AMERICAN PETROLEUM INSTITUTES STANDARD RP 5L2.


FEATURES BENEFITSGlossy and smooth appearance Easy to clean

Fast drying and good film forming properties High application productivity and absence of pores

Meet requirements of API, ISO, EN standards Well proven product performance all over the world

Service temperatures up to 140C Wide range of service temperatures

VOC compliant coating High volume solid paint without increased coating thickness or loss of performance

4Physical constantsHEMPELS HS GAS PIPE COATING 87831

Colour: Reddish brown/50890

Volume solids, %: 82 1

Theoretical spreading rate: 11,6 m2/litre 70 micron

464 sq.ft./US gallon - 2.8 milsFlash point: 28C/82F

Specific gravity: 1.4 kg/litre 11.4 lbs/US gallon

Dry to touch: 4 hours at 20C/68F

Fully cured: 7 days at 20C/68F

V.O.C.: 155 g/litre 1.4 lbs/US gallon

Recoating: Recoating will normally only apply in connection with touch-up of too low dry film thicknessRecoat interval, min: 5 hours (20C/68F)

Recoat interval, max: 8 days (20C/68F)

Product Information

1H EMP E L P RO D U C T I N F O RMAT I O N

Please consult Product Data Sheet for further details.

HEMPEL (UK) LTD. Llantarnam Industrial Park Gwent NP44 3XF Cwmbran Tel.: +44 (01633) 874024Fax: +44 (01633) 489089 E-mail: [email protected]

4Typical SpecificationThe flow coats are usually specified with thickness from 60-70 to 100 micron depending on speci-fication of the owners. A specification can be adjusted to suit local regulations, local working condi-tions or specific demands from designers or pipe coating manufacturers.

HEMPELS HS GAS PIPE COATING 87831One coat application1 x HEMPELS HS GAS PIPE COATING 87831 70 Micron

70 Micron

HEMPELS HS GAS PIPE COATING 87831One coat application1 x HEMPELS HS GAS PIPE COATING 87831 90 Micron

90 Micron

2H EMP E L P RO D U C T I N F O RMAT I O N

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Other custom-built specifications are possible - please contact your local Hempel office. This product should not be used without reference to relevant Product Data sheet and Material Safety Data sheet, copies of which are available from Hempel upon request.

4More information available upon request


4Test reports

API RP 5L2:2002 Recommended Practice for Internal Coating for Non-Corrosive Gas Transmission Service according to API RP 5L2:2002 issued by Institut fr Lackprfung

DIN EN 10 301:2004 Steel tubes and fittings for on and offshore pipelines Internal coatings for the reduction of friction for conveyance of non corrosive gas according to DIN EN 10 301:2004 issued by Institut fr Lackprfung

ISO 15 741:2001 Paints and varnishes Friction-reduction coatings for the interior of on- and offshore steel pipelines for non-corrosive gases according to ISO 15 741:2001 issued by Institut fr Lackprfung

TRANSCO CM2 Technical Specification for Internal Coating Materials for Steel Line Pipe and Fittings according to TRANSCO CM2, Edition March 2003 issued by Institut fr Lackprfung

Gazprom VNIIGAZ Internal flow coating meets STO Gazprom 2-2.2-180-2007 Internal flow pipe coating specifications standard requirements

PROJECT NAME DATE DESCRIPTION

DOLPHIN GAS PIPELINE U.A.E. 2008 Pipeline connection from Qatar to U.A.E.

NORTH-SOUTH PROJECT 2009The pipeline connection from north east to south Netherlands by N.V. Nederlandse Gasunie.

NORD-STREAM BALTIC-SEA PIPELINE / GAZPROM

20082011

Nord Stream is a gas pipeline that links Russia to Europe via the Baltic Sea, carrying a natural gas supply for both business and household use. The new pipeline is an im-portant factor of energy security in Europe. Nord Stream will transport up to 55 billion cubic metres of gas each year, enough to supply more than 26 million households.

NORD-STREAM LINE 2 20102011

Nord Stream Line 2 is 1,224 kilometres long and consists of two parallel lines. The second line is due to be completed in 2012, doubling annual capacity to around 55 billion cubic metres.

WINGAS - OPAL (OSTSEE-PIPELINE--ANBINDUNGS-LEITUNG BALTIC SEA PIPELINE LINK)

20082011

OPAL connects Germany and Europe to major natural gas reserves in Siberia via the Nord-Stream Pipeline. The OPAL will pick up natural gas in Lubmin near Greifswald from the Nord Stream pipeline and transport it 470 kilometres south to Olbernhau on the Czech border.

NEL (NORDDEUTSCHE ERDGASLEITUNG)

20102011

North European Gas Pipeline (NEL) is 440 km long, used to transport Russian natural gas from the Nord Stream Baltic Sea pipeline landing point in Lubmin near Gre-ifswald towards Rehden in Lower Saxony.

QSN3 GAS PIPELINE 20102011The QSN3 pipeline stretches 945 km from South Australias Moomba Gas Fields, through to S/W Queensland.

H EMP E L L I S T O F A P P L I C A T I O N S

List of applications HEMPELS HS GAS PIPE COATING 87830

HEMP E L L I S T O F A P P L I C A T I O N S

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HEMPEL (UK) LTD. Llantarnam Industrial Park Gwent NP44 3XF Cwmbran Tel.: +44 (01633) 874024Fax: +44 (01633) 489089 E-mail: [email protected]

*HEMPELS HS GAS PIPE COATING 87830 has been applied to all the projects mentioned above. Currently there is available HEMPELS HS GAS PIPE COATING 87831 which is an improved version of HEMPELS HS GAS PIPE COATING 87830 to have extended anti-settlement property. Extended anti-settlement properties, which is a huge challenge for high solids paints applied with low dry film thickness, enable our customers to have the application process easier.

Product DataProduct Data

Product Data Sheet

HEMPEL

Issued: December 2010 Page 1 of 2

HEMPELS HS GAS PIPE COATING 87831 BASE 87838 with CURING AGENT 95830

Description: HEMPELS HS GAS PIPE COATING 87831 is a two-component epoxy polyamine cured coating. Formulated according to the requirements in AMERICAN PETROLEUM INSTITUTES STANDARD RP 5L2.

Recommended use: As a one-coat system for internal coating of gas pipes designed for carrying of dry,

sweet gas. The coating is designed to reduce the drag resistance in the pipeline by making the pipe walls smoother.

Service temperatures: Maximum, dry exposure only: 140C/284F. Availability: Not included in Group Assortment. Availability subject to special agreement. PHYSICAL CONSTANTS: Colours/Shade nos: Reddish brown/50890 Finish: Semi-gloss Volume solids, %: 82 1 Theoretical spreading rate: 11.6 m/litre - 70 micron 464 sq.ft./US gallon - 2.8 mils Flash point: 28C/82F Specific gravity: 1.4 kg/litre - 11.4 lbs/US gallon Dry to touch: 4 hours at 20C/68F Fully cured: 7 days at 20C/68F V.O.C.: 155 g/litre 1.4 lbs/US gallon The physical constants stated are nominal data according to the HEMPEL Group's approved formulas. They are

subject to normal manufacturing tolerances and where stated, being standard deviation according to ISO 3534-1.

APPLICATION DETAILS: Mixing ratio for 87831: Base 87838 : Curing agent 95830 4 : 1 by volume (see REMARKS overleaf) Application method: Dual feed hot airless Airless spray Brush (see REMARKS overleaf) Thinner (max.vol.): No thinning recommended Pot life: 60 minutes (20C/68F) (API standard method) 10 minutes (60C/140F) Nozzle orifice: .018"-.021" Nozzle pressure: 150 bar/2200 psi (Airless spray data are indicative and subject to adjustment) Cleaning of tools: HEMPELS TOOL CLEANER 99610 Indicated film thickness, dry: 70 micron/2.8 mils Indicated film thickness, wet: 100 micron/4 mils Recoat interval, min: 5 hours (20C/68F) (see REMARKS overleaf) Recoat interval, max: 8 days (20C/68F) Safety: Handle with care. Before and during use, observe all safety labels on packaging and

paint containers, consult HEMPEL Material Safety Data Sheets and follow all local or national safety regulations. Avoid inhalation, avoid contact with skin and eyes, and do not swallow. Take precautions against possible risks of fire or explosions as well as protection of the environment. Apply only in well ventilated areas.

Product Data Sheet

Issued: December 2010 Page 2 of 2


SURFACE Remove oil and grease thoroughly with suitable detergent. Remove salt and other contaminants PREPARATION: by high pressure fresh water cleaning. Abrasive blasting to Sa 2 with a surface profile corresponding to Rugotest No. 3, BN9a, Keane-

Tator Comparator, 2.0 G/S, 2S, or ISO Comparator, FINE (G). APPLICATION Use only where application and curing can proceed at temperatures above 20C/68F at all times CONDITIONS: until curing is completed. Apply only on a clean and dry surface with a temperature above the dew

point to avoid condensation. Maximum steel temperature approximately 45C/113F. Relative humidity max. 85%. In confined spaces provide adequate ventilation..

SUBSEQUENT None or according to specification. COAT: REMARKS: Application Application by duel feed hot airless spray equipment is recommended. Each component must be equipment: preheated in heating caps to 60C/140F prior to mixing. If ordinary airless spray is used the

mixture should be made at 20C/68F and heated after the pump to 50C/122F. Hoses must be kept at 50C/122F during the entire application. Note the short pot life at 60C/140F, approximately 10 minutes.

Curing conditions: Initial curing must take place at temperatures above 25C/77F. Mixing ratio: Base 87838 : Curing agent 95830 6 : 1 by weight Mixing tolerance 5% Recoating: Recoating will normally only apply in connection with touch-up of too low dry film thickness. Note: HEMPELS HS GAS PIPE COATING 87831 is for professional use only. ISSUED BY: HEMPEL A/S - 8783150890CR001

This Product Data Sheet supersedes those previously issued. For explanations, definitions and scope, see Explanatory Notes in the HEMPEL Book. Data, specifications, directions and recommendations given in this data sheet represent only test results or experience obtained under controlled or specially defined circumstances. Their accuracy, completeness or appropriateness under the actual conditions of any intended use of the Products herein must be determined exclusively by the Buyer and/or User. The Products are supplied and all technical assistance is given subject to HEMPEL's GENERAL CONDITIONS OF SALES, DELIVERY AND SERVICE, unless otherwise expressly agreed in writing. The Manufacturer and Seller disclaim, and Buyer and/or User waive all claims involving, any liability, including but not limited to negligence, except as expressed in said GENERAL CONDITIONS for all results, injury or direct or consequential losses or damages arising from the use of the Products as recommended above, on the overleaf or otherwise.

This Product Data Sheet supersedes those previously issued. For explanations, definitions and scope, see Explanatory Notes in the HEMPEL Book. Data, specifications, directions and recommendations given in this data sheet represent only test results or experience obtained under controlled or specially defined circumstances. Their accuracy, completeness or appropriateness under the actual conditions of any intended use of the Products herein must be determined exclusively by the Buyer and/or User. The Products are supplied and all technical assistance is given subject to HEMPEL's GENERAL CONDITIONS OF SALES, DELIVERY AND SERVICE, unless otherwise expressly agreed in writing. The Manufacturer and Seller disclaim, and Buyer and/or User waive all claims involving, any liability, including but not limited to negligence, except as expressed in said GENERAL CONDITIONS for all results, injury or direct or consequential losses or damages arising from the use of the Products as recommended above, on the overleaf or otherwise. Product data are subject to change without notice and become void five years from the date of issue.

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Safety Data SheetSafety Data SheetHEMPEL'S HS GAS PIPE COATING 87838

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II. - Europe

Product identity : 8783850890

Ready-for-use mixture : 87838 4 Li / 95830 1 Li

Product type : epoxy paint (base for 2-component product)

Field of application : metal industry

Identified uses : Industrial applications, Used by spraying.

Emergency telephone number (with hours of operation)Company details :

+45 45 93 38 00 (08.00 - 17.00)See section 4 First aid measures.

HEMPEL A/SLundtoftevej 150DK-2800 Kgs. LyngbyDenmarkTel.: + 45 45 93 38 [email protected]

Date of issue : 11 February 2011

16 December 2010.Date of previous issue :

HEMPEL'S HS GAS PIPE COATING 87838Product name :

Classification : R10Xi; R36/38R43N; R51/53

Physical/chemical hazards : Flammable.

Human health hazards : Irritating to eyes and skin. May cause sensitization by skin contact.

Environmental hazards : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixtureProduct definition : Mixture

Classification according to Directive 1999/45/EC [DPD]The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

2.2 Label elements

Supplemental label elements :

Containers to be fitted with child-resistant fastenings :

Not applicable.

Tactile warning of danger : Not applicable.

Contains epoxy constituents. See information supplied by the manufacturer.

Special packaging requirements

Hazard symbol or symbols :

Safety phrases : S23- Do not breathe vapor or spray.S24- Avoid contact with skin.S37- Wear suitable gloves.S51- Use only in well-ventilated areas.

R10- Flammable.R36/38- Irritating to eyes and skin.R43- May cause sensitization by skin contact.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Risk phrases :

Hazardous ingredients :

Irritant, Dangerous for the environment

bisphenol A-(epichlorhydrin) epoxy resin MW =< 700

Indication of danger :

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Safety Data SheetDate of issue: February 2011

8783850890

bisphenol A-(epichlorhydrin)epoxy resin MW =< 700

EC: 500-033-5CAS: 25068-38-6Index: 603-074-00-8

35-50 Xi; R36/38R43N; R51/53

SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2SKIN SENSITIZATION - Category 1AQUATIC TOXICITY (CHRONIC) - Category 2

[1]

xylene EC: 215-535-7CAS: 1330-20-7Index: 601-022-00-9

5-10 R10Xn; R20/21Xi; R38

FLAMMABLE LIQUIDS - Category 3ACUTE TOXICITY: SKIN - Category 4ACUTE TOXICITY: INHALATION - Category 4SKIN CORROSION/IRRITATION - Category 2

[1] [2]

n-butanol EC: 200-751-6CAS: 71-36-3Index: 603-004-00-6

1-3 R10Xn; R22Xi; R41, R37/38R67

FLAMMABLE LIQUIDS - Category 3ACUTE TOXICITY: ORAL - Category 4SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SPECIFIC TARGET ORGAN TOXICITY (SINGLEEXPOSURE) [Respiratory tract irritation and Narcoticeffects] - Category 3

[1] [2]

ethylbenzene EC: 202-849-4CAS: 100-41-4Index: 601-023-00-4

1-3 F; R11Xn; R20

FLAMMABLE LIQUIDS - Category 2ACUTE TOXICITY: INHALATION - Category 4

[1] [2]

alpha'-(1,3-xylenediyl)bis(12-hydroxyoctadecanamide)

- 0.1-1 Xn; R20R43R53

ACUTE TOXICITY: INHALATION - Category 4SKIN SENSITIZATION - Category 1AQUATIC TOXICITY (CHRONIC) - Category 4

[1]

See Section 16 for the fulltext of the R-phrasesdeclared above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, areclassified as hazardous to health or the environment and hence require reporting in this section.

SECTION 3: Composition/information on ingredients

TypeRegulation (EC) No. 1272/2008 [CLP]

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit, see section 8.[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Type

Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive 67/548/EEC orassigned an occupational exposure limit or PBT or vPvB.

Product/ingredient name Identifiers % 67/548/EEC

Classification

Skin contact :

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or userecognized skin cleanser. Do NOT use solvents or thinners.

4.1 Description of first aid measures

Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and seekmedical advice.

Ingestion :

Inhalation :

Eye contact :

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous tothe person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughlywith water before removing it, or wear gloves.

SECTION 4: First aid measures

4.2 Most important symptoms and effects, both acute and delayedPotential acute health effects

No known significant effects or critical hazards.

Irritating to mouth, throat and stomach.

Irritating to skin. May cause sensitization by skin contact.

Irritating to eyes.

Over-exposure signs/symptomsAdverse symptoms may include the following:irritationwateringredness

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouthto an unconscious person.

If swallowed, seek medical advice immediately and show this container or label. Keep person warm andat rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so thatvomit will not re-enter the mouth and throat.

Eye contact :

Inhalation :

Skin contact :

Ingestion :

Eye contact :

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Notes to physician : Not applicable.

Specific treatments :

No specific data.

No specific data.

Adverse symptoms may include the following:irritationredness

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.

Inhalation :

Skin contact :

Ingestion :

Hazardous combustion products :

Hazards from the substance ormixture :

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, withthe risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

5.1 Extinguishing mediaExtinguishing media :

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Recommended: alcohol resistant foam, CO2, powders, water spray.Not to be used: waterjet.

Decomposition products may include the following materials: carbon oxides halogenated compoundsmetal oxide/oxides

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving anypersonal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a healthhazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters shouldwear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide abasic level of protection for chemical incidents.

6.2 Environmental precautions

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to localregulations (see section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the samehazard as the spilled product.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if theproduct has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment ifreleased in large quantities.

6.3 Methods and materials for containment and cleaning up

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.4 Reference to other sectionsSee Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer to protectivemeasures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training. If the productcontaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

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SECTION 7: Handling and storage

7.1 Precautions for safe handling

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable orexplosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, theproduct should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipmentshould be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receivingcontainer with bonding strap. No sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy andamine containing products, they may cause allergic reactions.Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in areawhere this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containersmade from the same material as the original one.

Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from incompatible materials andignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Preventunauthorized access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

Product/ingredient name Exposure limit values

Recommended monitoring procedures

xylene EU OEL (Europe, 12/2009). Absorbed through skin.STEL: 442 mg/m 15 minute(s).STEL: 100 ppm 15 minute(s).TWA: 221 mg/m 8 hour(s).TWA: 50 ppm 8 hour(s).

n-butanol ACGIH TLV (United States, 2/2010).TWA: 20 ppm 8 hour(s).

ethylbenzene EU OEL (Europe, 12/2009). Absorbed through skin.STEL: 884 mg/m 15 minute(s).STEL: 200 ppm 15 minute(s).TWA: 442 mg/m 8 hour(s).TWA: 100 ppm 8 hour(s).

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required todetermine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardous substances.

Safety eyewear complying with an approved standard should be used when a risk assessment indicatesthis is necessary to avoid exposure to liquid splashes, mists or dusts.

Eye/face protection :

Appropriate engineering controls8.2 Exposure controls

Hygiene measures :

No DELs available.

Predicted effect concentrationsNo PECs available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Derived effect levels

Individual protection measures

Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dustlowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,using lavatory, and at the end of day.

General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must beworn when soiling is so great that regular work clothes do not adequately protect skin against contactwith the product. Safety eyewear should be used when there is a likelihood of exposure.

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Hand protection :

Respiratory protection :

Environmental exposure controlsEmissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmentalprotection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary toreduce emissions to acceptable levels.

Body protection : Personal protective equipment for the body should be selected based on the task being performed andthe risks involved handling this product.Wear suitable protective clothing. Always wear protective clothing when spraying.If working areas have insufficient ventilation: When the product is applied by means that will notgenerate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filterof type A, when grinding use particle filter of type P. When the product is applied by spraying and forcontinuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh orcompressed air or a full face, powered air purifying filter. Be sure to use an approved/certified respiratoror equivalent.

Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Thequality of the chemical-resistant protective gloves must be chosen as a function of the specificworkplace concentrations and quantity of hazardous substances.Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find theappropriate type.

Physical state :

Melting point/freezing point :

Boiling point/boiling range :

Vapor pressure :

Relative density :

Vapor density :

Solubility(ies) :

Solvent-likeOdor :

pH :

Evaporation rate :

Auto-ignition temperature :

Flash point :

Highly explosive in the presence of the following materials or conditions: open flames, sparks and staticdischarge and heat.

Viscosity :

Partition coefficient (LogKow) :

Upper/lower flammability orexplosive limits :

Explosive properties :

Oxidizing properties :

9.1 Information on basic physical and chemical properties

9.2 Other information

Decomposition temperature :

SECTION 9: Physical and chemical properties

Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks andstatic discharge and heat.

Liquid.

Testing not relevant or not possible due to nature of the product.


1.498 g/cm3Testing not relevant or not possible due to nature of the product.



Partially soluble in the following materials: cold water and hot water.

Closed cup: 28C (82.4F)

0.8 - 11.2 vol %


Weighted average: 17 %Solvent(s) % by weight :

Water % by weight : Weighted average: 0 %

Solvent Gas : Weighted average: 0.052 m3/l

TOC Content : Weighted average: 166 g/l






VOC content : 255.3 g/l

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8783850890

10.6 Hazardous decomposition products

10.4 Conditions to avoid

The product is stable.10.2 Chemical stability

10.5 Incompatible materials

10.3 Possibility of hazardous reactionsUnder normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity

10.1 ReactivityNo specific test data related to reactivity available for this product or its ingredients.

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:

Decomposition products may include the following materials: carbon oxides halogenated compounds metal oxide/oxides

Highly reactive or incompatible with the following materials: oxidizing materials and acids.Reactive or incompatible with the following materials: reducing materials.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat orsources of ignition.

Acute toxicity

bisphenol A-(epichlorhydrin) epoxyresin MW =< 700

LD50 Dermal Rabbit >2000 mg/kg -

LD50 Oral Rat >2000 mg/kg -xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours

LD50 Dermal Rabbit >1700 mg/kg -LD50 Oral Rat 4300 mg/kg -

n-butanol LC50 Inhalation Gas. Rat >8000 ppm 4 hoursLC50 Inhalation Vapor Rat 24000 mg/m3 4 hoursLD50 Dermal Rabbit 3400 mg/kg -LD50 Oral Rat 790 mg/kg -

ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -LD50 Oral Rat 3500 mg/kg -

alpha'-(1,3-xylenediyl)bis(12-hydroxyoctadecanamide)

LC50 Inhalation Gas. Rat 3.6 mg/L 4 hours

LD50 Dermal Rat >2000 mg/kg -LD50 Oral Rat >2000 mg/kg -

Product/ingredient name Result Species Dose Exposure

Irritation/Corrosion

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity estimates

Oral 31549.2 mg/kgDermal 21992.2 mg/kgInhalation (gases) 52922.3 ppmInhalation (vapors) 589.3 mg/l

Route ATE value

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratorysystem irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects byabsorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extremecases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resultingin non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversibledamage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs viavomiting.Epoxy and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after only a short exposureperiod.

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8783850890


Potential chronic health effects


Eyes - Moderate irritant Rabbit - - -

Skin - Moderate irritant Rabbit - - -xylene Eyes - Severe irritant Rabbit - - -

Skin - Mild irritant Rat - - -Skin - Moderate irritant Rabbit - - -

n-butanol Eyes - Severe irritant Rabbit - - -Skin - Moderate irritant Rabbit - - -

ethylbenzene Eyes - Severe irritant Rabbit - - -Skin - Mild irritant Rabbit - - -

Product/ingredient name Result Score Exposure ObservationSpecies

Other information :

Sensitization : Contains bisphenol A-(epichlorhydrin) epoxy resin MW =< 700, alpha'-(1,3-xylenediyl)bis(12-hydroxyoctadecanamide). May produce an allergic reaction.No additional known significant effects or critical hazards.

Mobility :

LogPow BCF Potential

12.3 Bioaccumulative potential

12.6 Other adverse effectsNo known significant effects or critical hazards.

Product/ingredient name

xylene - 6 - 23.4 lown-butanol 0.88 - lowethylbenzene 3.15 - high

No known data avaliable in our database.

12.1 Toxicity


Acute EC50 1.4 - 1.7 mg/l Daphnia - Daphnia magna 48 hours

Acute LC50 3.1 mg/l Fish - fathead minnow (Pimephalespromelas)

96 hours

xylene Acute LC50 8500 ug/L Marine water Crustaceans - Palaemonetes pugio 48 hoursAcute LC50 8200 - 10032 ug/L Fresh water Fish - Oncorhynchus mykiss - 0.6 g 96 hours

n-butanol Acute EC50 1983000 - 2072000 ug/L Freshwater

Daphnia - Daphnia magna - 6 - 24 hours 48 hours

Acute LC50 1730000 - 1840000 ug/L Fresh water Fish - Pimephales promelas - 33 days -20.6 mm - 0.119 g

96 hours

ethylbenzene Acute EC50 2930 - 4400 ug/L Fresh water Daphnia - Daphnia magna - Neonate -5200 ug/L Marine water Crustaceans - Americamysis bahia -

8783850890

SECTION 13: Disposal considerations

13.1 Waste treatment methods

PackagingThe generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfillshould only be considered when recycling is not feasible.

The generation of waste should be avoided or minimized wherever possible.Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable regulations.Spillage, remains, discarded clothes and similar should be discarded in a fireproof container.European waste catalogue no. (EWC) is given below.

European waste catalogue (EWC) : 08 01 11*

SECTION 14: Transport information

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable.

UN1263

UN1263

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport bysea, IATA for transport by air.Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting theproduct know what to do in the event of an accident or spillage.

14.1UN no.

14.2Proper shipping name

14.4PG*

14.3Transport hazard class(es) Additional information

III3PAINTADR/RIDClass

IMDGClass

PAINT. (bisphenol A-(epichlorhydrin)epoxy resin MW =< 700)

3 III

IATAClass

UN1263 PAINT 3 III -

PG* : Packing groupEnv.* : Environmental hazards

14.5Env*

14.6 Special precautions for user

Yes.

Not available.

Yes.

Special provisions640 (E)

Tunnel code(D/E)

Emergency schedules(EmS)F-E, S-E

Yes.

Other EU regulationsNot applicable.

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureEU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern

15.2 Chemical Safety AssessmentThis product contains substances for which Chemical Safety Assessments are still required.

None of the components are listed.

Seveso category : 9.ii

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8783850890

Indicates information that has changed from previously issued version.

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It providesguidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guaranteeof the technical preformance or suitability for particular applications.It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Notice to reader

Hazard pictograms :

Warning

Flammable liquid and vapor.Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction.Toxic to aquatic life with long lasting effects.

Hazard statements :

Signal word :

R11- Highly flammable.R10- Flammable.R20- Harmful by inhalation.R22- Harmful if swallowed.R20/21- Harmful by inhalation and in contact with skin.R41- Risk of serious damage to eyes.R38- Irritating to skin.R36/38- Irritating to eyes and skin.R37/38- Irritating to respiratory system and skin.R43- May cause sensitization by skin contact.R67- Vapors may cause drowsiness and dizziness.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R53- May cause long-term adverse effects in the aquatic environment.

Full text of abbreviated R phrases :

F - Highly flammableXn - HarmfulXi - IrritantN - Dangerous for the environment

Full text of classifications [DSD/DPD] :

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification

FLAMMABLE LIQUIDS - Category 3 On basis of test dataSKIN CORROSION/IRRITATION - Category 2 Calculation methodSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 Calculation methodSKIN SENSITIZATION - Category 1 Calculation methodAQUATIC TOXICITY (CHRONIC) - Category 2 Calculation method

Page: 9/9-


1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Safety Data SheetSafety Data SheetHEMPEL'S CURING AGENT 95830

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II. - Europe

Product identity : 9583000000

Ready-for-use mixture : 87839 16 LI / 95830 4 LI

Product type : polyamine curing agent.

Field of application : used only as part of two- or multi component products.

Identified uses : Industrial applications, Used by spraying.

Emergency telephone number (with hours of operation)Company details :

+45 45 93 38 00 (08.00 - 17.00)See section 4 First aid measures.

HEMPEL A/SLundtoftevej 150DK-2800 Kgs. LyngbyDenmarkTel.: + 45 45 93 38 [email protected]

Date of issue : 3 December 2010

No previous validation.Date of previous issue :

HEMPEL'S CURING AGENT 95830Product name :

Classification : Xn; R22C; R35R43R52/53

Human health hazards : Harmful if swallowed. Causes severe burns. May cause sensitization by skin contact.

Environmental hazards : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.


2.1 Classification of the substance or mixtureProduct definition : Mixture

Classification according to Directive 1999/45/EC [DPD]The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

2.2 Label elements

Special packaging requirements

Hazard symbol or symbols :

Safety phrases : S23- Do not breathe vapor or spray.S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label wherepossible).S51- Use only in well-ventilated areas.

R22- Harmful if swallowed.R35- Causes severe burns.R43- May cause sensitization by skin contact.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.

Risk phrases :

Hazardous ingredients :

Corrosive

m-Xylylene-diamine2,2,4- and 2,4,4- trimethylhexamethylene diaminetetraethylenepentamine

Indication of danger :

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Safety Data SheetDate of issue: December 2010

9583000000


Containers to be fitted with child-resistant fastenings :

Not applicable.

Tactile warning of danger : Not applicable.

m-Xylylene-diamine EC: 216-032-5CAS: 1477-55-0

10-20 Xn; R20/22C; R35R43R52/53

ACUTE TOXICITY: ORAL - Category 4ACUTE TOXICITY: INHALATION - Category 3SKIN CORROSION/IRRITATION - Category 1BSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SKIN SENSITIZATION - Category 1AQUATIC TOXICITY (CHRONIC) - Category 3

[1] [2]

p-tert-butylphenol EC: 202-679-0CAS: 98-54-4

10-20 Xi; R36/37/38N; R51/53

SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLEEXPOSURE): INHALATION [Respiratory tract irritation] -Category 3AQUATIC TOXICITY (ACUTE) - Category 1AQUATIC TOXICITY (CHRONIC) - Category 1

[1]

benzyl alcohol EC: 202-859-9CAS: 100-51-6Index: 603-057-00-5

7-25 Xn; R20/22 ACUTE TOXICITY: ORAL - Category 4ACUTE TOXICITY: INHALATION - Category 4

[1]

2,2,4- and 2,4,4-trimethylhexamethylenediamine

EC: 247-134-8CAS: 25620-58-0

7-10 Xn; R22C; R34R43N; R51/53

ACUTE TOXICITY: ORAL - Category 4SKIN CORROSION/IRRITATION - Category 1BSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SKIN SENSITIZATION - Category 1AQUATIC TOXICITY (CHRONIC) - Category 2

[1]

2,4,6-tris(dimethylaminomethyl)phenol

EC: 202-013-9CAS: 90-72-2Index: 603-069-00-0

3-5 Xn; R22Xi; R36/38

ACUTE TOXICITY: ORAL - Category 4SKIN CORROSION/IRRITATION - Category 2SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2

[1]

tetraethylenepentamine EC: 203-986-2CAS: 112-57-2Index: 612-060-00-0

2.5-3 Xn; R21/22C; R34R43N; R51/53

ACUTE TOXICITY: ORAL - Category 4ACUTE TOXICITY: SKIN - Category 4SKIN CORROSION/IRRITATION - Category 1BSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SKIN SENSITIZATION - Category 1AQUATIC TOXICITY (CHRONIC) - Category 2

[1]

See Section 16 for the fulltext of the R-phrasesdeclared above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, areclassified as hazardous to health or the environment and hence require reporting in this section.

SECTION 3: Composition/information on ingredients

TypeRegulation (EC) No. 1272/2008 [CLP]

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit, see section 8.[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Type

Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive 67/548/EEC orassigned an occupational exposure limit or PBT or vPvB.

Product/ingredient name Identifiers % 67/548/EEC

Classification

Skin contact :

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or userecognized skin cleanser. Do NOT use solvents or thinners. In case of burns flush with water until thepain ceases. While flushing remove clothing from the affected area unless it is burnt into the skin. Ifhospital treatment is necessary flushing must continue during transfer and until the hospital staff takesover the treatment.

4.1 Description of first aid measures

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing bymouth. If unconscious, place in recovery position and get medical attention immediately.

Ingestion :

Inhalation :

Eye contact :


General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouthto an unconscious person.

If swallowed, seek medical advice immediately and show this container or label. Keep person warm andat rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so thatvomit will not re-enter the mouth and throat.

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9583000000


Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed.

Specific treatments :

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected thatfumes are still present, the rescuer should wear an appropriate mask or self-contained breathingapparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayedPotential acute health effects

May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure todecomposition products may cause a health hazard. Serious effects may be delayed followingexposure.

Harmful if swallowed. May cause burns to mouth, throat and stomach.

Severely corrosive to the skin. Causes severe burns. May cause sensitization by skin contact.

Severely corrosive to the eyes. Causes severe burns.

Over-exposure signs/symptoms

No specific data.

Adverse symptoms may include the following:stomach pains

Adverse symptoms may include the following:pain or irritationrednessblistering may occur

Adverse symptoms may include the following:painwateringredness

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.

Eye contact :

Inhalation :

Skin contact :

Ingestion :

Eye contact :

Inhalation :

Skin contact :

Ingestion :

Hazardous combustion products :

Hazards from the substance ormixture :

In a fire or if heated, a pressure increase will occur and the container may burst.

5.1 Extinguishing mediaExtinguishing media :

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Recommended: alcohol resistant foam, CO2, powders, water spray.Not to be used: waterjet.

Decomposition products may include the following materials: carbon oxides nitrogen oxides

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving anypersonal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a healthhazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters shouldwear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide abasic level of protection for chemical incidents.

6.2 Environmental precautions


6.1 Personal precautions, protective equipment and emergency proceduresAvoid all direct contact with the spilled material. Refer to protective measures listed in sections 7 and 8. No action shall be taken involvingany personal risk or without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities inaccordance with local regulations.

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9583000000


Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to localregulations (see section 13). Contaminated absorbent material may pose the same hazard as the spilled product.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if theproduct has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment ifreleased in large quantities.

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sectionsSee Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in areawhere this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containersmade from the same material as the original one.

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources. Keepout of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized access.Containers that are opened must be carefully resealed and kept upright to prevent leakage.

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

Product/ingredient name Exposure limit values

Recommended monitoring procedures

m-Xylylene-diamine ACGIH TLV (United States, 2/2010). Absorbed through skin.C: 0.1 mg/m

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required todetermine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardous substances.

Appropriate engineering controls8.2 Exposure controls

Hygiene measures :

No DELs available.

Predicted effect concentrationsNo PECs available.


8.1 Control parameters

Derived effect levels

Individual protection measures

Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dustlowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,using lavatory, and at the end of day.

General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must beworn when soiling is so great that regular work clothes do not adequately protect skin against contactwith the product. Safety eyewear should be used when there is a likelihood of exposure.

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9583000000


Hand protection :

Safety eyewear complying with an approved standard should be used when a risk assessment indicatesthis is necessary to avoid exposure to liquid splashes, mists or dusts.

Eye/face protection :

Respiratory protection :

Environmental exposure controlsEmissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmentalprotection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary toreduce emissions to acceptable levels.

Body protection : Personal protective equipment for the body should be selected based on the task being performed andthe risks involved handling this product.Wear suitable protective clothing. Always wear protective clothing when spraying.Chemical-resistant apron.If working areas have insufficient ventilation: When the product is applied by means that will notgenerate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filterof type A, when grinding use particle filter of type P. When the product is applied by spraying and forcontinuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh orcompressed air or a full face, powered air purifying filter. Be sure to use an approved/certified respiratoror equivalent.

Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Thequality of the chemical-resistant protective gloves must be chosen as a function of the specificworkplace concentrations and quantity of hazardous substances.

Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find theappropriate type.

Physical state :

Melting point/freezing point :

Boiling point/boiling range :

Vapor pressure :

Relative density :

Vapor density :

Solubility(ies) :

Non-characteristic.Odor :

pH :

Evaporation rate :

Auto-ignition temperature :

Flash point :

Slightly explosive in the presence of the following materials or conditions: open flames, sparks andstatic discharge and heat.

Viscosity :

Partition coefficient (LogKow) :

Upper/lower flammability orexplosive limits :

Explosive properties :

Oxidizing properties :

9.1 Information on basic physical and chemical properties

9.2 Other information

Decomposition temperature :

SECTION 9: Physical and chemical properties

Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks andstatic discharge.Flammable in the presence of the following materials or conditions: heat.

Liquid.



0.992 g/cm3Testing not relevant or not possible due to nature of the product.



Partially soluble in the following materials: cold water and hot water.

Closed cup: 93C (199.4F)

1.7 - 15 vol %


Weighted average: 8 %Solvent(s) % by weight :

Water % by weight : Weighted average: 0 %

Solvent Gas : Weighted average: 0.018 m3/l

TOC Content : Weighted average: 15 g/l






VOC content : 16 g/l

Page: 5/9-


9583000000

10.6 Hazardous decomposition products

10.4 Conditions to avoid

The product is stable.10.2 Chemical stability

10.5 Incompatible materials

10.3 Possibility of hazardous reactionsUnder normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity

10.1 ReactivityNo specific test data related to reactivity available for this product or its ingredients.

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:

Decomposition products may include the following materials: carbon oxides nitrogen oxides

Reactive or incompatible with the following materials: oxidizing materials.Slightly reactive or incompatible with the following materials: reducing materials.

No specific data.

Acute toxicity

m-Xylylene-diamine LC50 Inhalation Gas. Rat 700 ppm 1 hoursLD50 Dermal Rabbit 2 g/kg -LD50 Oral Rat 930 mg/kg -

p-tert-butylphenol LD50 Dermal Rabbit 2520 uL/kg -benzyl alcohol LD50 Oral Rat 1230 mg/kg -2,2,4- and 2,4,4-trimethylhexamethylene diamine

LD50 Oral Rat 910 mg/kg -


LD50 Dermal Rat 1280 mg/kg -

LD50 Oral Rat 1200 mg/kg -tetraethylenepentamine LD50 Dermal Rabbit 660 uL/kg -

LD50 Oral Rat 3990 mg/kg -

Product/ingredient name Result Species Dose Exposure

Irritation/Corrosion

Product/ingredient name Result Score Exposure ObservationSpecies


11.1 Information on toxicological effects

Acute toxicity estimates

Oral 2429.4 mg/kgDermal 37950.1 mg/kgInhalation (gases) 4387.9 ppmInhalation (vapors) 137.7 mg/l

Route ATE value

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratorysystem irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects byabsorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extremecases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resultingin non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversibledamage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs viavomiting.Inhalation of a corrosive substance may result in health effects such as stinging, coughing and in extreme cases, dyspnoea or loss ofconsciousness with a risk of lung damage, possibly lung oedema. Cauterization of skin and mucous membrane. If splashed in the eyes, theliquid may cause ireversible damage. Accidental swallowing may cause stinging and cauterization to mouth, oesophagus and stomach.Symptoms and signs include bloody vomiting, chock and loss of consciousness.

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Potential chronic health effects

m-Xylylene-diamine Eyes - Severe irritant Rabbit - - -Skin - Severe irritant Rabbit - - -

p-tert-butylphenol Eyes - Severe irritant Rabbit - - -Skin - Mild irritant Rabbit - - -

benzyl alcohol Skin - Mild irritant Man - - -Skin - Moderate irritant Rabbit - - -


Eyes - Severe irritant Rabbit - - -

Skin - Mild irritant Rat - - -Skin - Severe irritant Rat - - -Skin - Severe irritant Rabbit - - -

tetraethylenepentamine Eyes - Moderate irritant Rabbit - - -Skin - Severe irritant Rabbit - - -

Other information :

Sensitization : Contains m-Xylylene-diamine, 2,2,4- and 2,4,4- trimethylhexamethylene diamine,tetraethylenepentamine. May produce an allergic reaction.No additional known significant effects or critical hazards.

Mobility :

12.3 Bioaccumulative potential

12.6 Other adverse effectsNo known significant effects or critical hazards.



12.1 Toxicity

p-tert-butylphenol Acute EC50 3900 - 4500 ug/L Fresh water Daphnia - Daphnia magna - 6 - 24 hours 48 hoursAcute LC50 5140 - 5620 ug/L Fresh water Fish - Pimephales promelas - 31 - 35

days - 97 mg96 hours

benzyl alcohol Acute LC50 10000 ug/L Fresh water Fish - Lepomis macrochirus - 33 - 75mm

96 hours

Product/ingredient name SpeciesResult Exposure

12.2 Persistence and degradability

PBT : Not applicable.

vPvB : Not applicable.

SECTION 12: Ecological information

12.4 Mobility in soilSoil/water partition coefficient(KOC) :

12.5 Results of PBT and vPvB assessment

Do not allow to enter drains or watercourses. Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.



SECTION 13: Disposal considerations

13.1 Waste treatment methods

PackagingThe generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfillshould only be considered when recycling is not feasible.

The generation of waste should be avoided or minimized wherever possible.Residues of the product is listed as hazardous waste. Dispose of according to all state and local applicable regulations.European waste catalogue no. (EWC) and national waste group, catalouge, code or number is given below.

European waste catalogue (EWC) : 08 01 11*

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9583000000

SECTION 14: Transport information

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable.

UN3066

UN3066

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport bysea, IATA for transport by air.Transport within users premises: always transport in closed containers that are upright and secure. Ensure that persons transporting theproduct know what to do in the event of an accident or spillage.

14.1UN no.

14.2Proper shipping name

14.4PG*

14.3Transport hazard class(es) Additional information

II8PAlNTADR/RIDClass

IMDGClass

PAlNT. (p-tert-butylphenol) 8 II

IATAClass

UN3066 PAlNT 8 II -

PG* : Packing groupEnv.* : Environmental hazards

14.5Env*

14.6 Special precautions for user

Yes.

Not available.

Yes.

Tunnel code(E)

Emergency schedules(EmS)F-A, S-B

Yes.

Other EU regulationsNot applicable.

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureEU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern

15.2 Chemical Safety AssessmentThis product contains substances for which Chemical Safety Assessments are still required.

None of the components are listed.

Seveso category : -

Indicates information that has changed from previously issued version.


Abbreviations and acronyms : ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration NumberR22- Harmful if swallowed.R20/22- Harmful by inhalation and if swallowed.R21/22- Harmful in contact with skin and if swallowed.R34- Causes burns.R35- Causes severe burns.R36/38- Irritating to eyes and skin.R36/37/38- Irritating to eyes, respiratory system and skin.R43- May cause sensitization by skin contact.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Full text of abbreviated R phrases :

C - CorrosiveXn - HarmfulXi - IrritantN - Dangerous for the environment

Full text of classifications [DSD/DPD] :

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9583000000


Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Modified data or content compared with the previous version are maked with a triangular marker in the upper-left corner within the SafetyData Sheet.The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It providesguidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guaranteeof the technical preformance or suitability for particular applications.It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Notice to reader

Hazard pictograms :

Danger

Harmful if inhaled.Causes severe skin burns and eye damage.May cause an allergic skin reaction.Toxic to aquatic life with long lasting effects.

Hazard statements :

Signal word :

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification

ACUTE TOXICITY: INHALATION - Category 4 Calculation methodSKIN CORROSION/IRRITATION - Category 1B Calculation methodSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation methodSKIN SENSITIZATION - Category 1 Calculation methodAQUATIC TOXICITY (CHRONIC) - Category 2 Calculation method

Page: 9/9-


Institut fr Lackprfung Andreas Keiner GmbH

nicht akkreditiertes Verfahren Die Ergebnisse beziehen sich ausschlielich auf die vom Antragsteller eingereichten und untersuchten Proben. Falls nicht anders schriftlich vereinbart, wird das eingereichte

Probenmaterial 4 Wochen nach Erstellung des Prfungs-Berichtes entsorgt.

manager: Andreas Keiner, Amtsgericht Gieen HRB-Nr. 3614 office and laboratory: Felsweg 10, 35435 Wettenberg phone: (+49) 06 41/8 61 88 Postfach 10 04 39, 35334 Gieen fax: (+49) 06 41/8 63 87 banking accounts: Volksbank Mittelhessen (BLZ: 513 900 00) Kto.: 819603 internet: www.institut-lackpruefung.de Sparkasse Gieen (BLZ: 513 500 25) Kto.: 225001756 e-mail: [email protected] Sparkasse Wetzlar (BLZ: 515 500 35) Kto.: 2014488 USt-IdNr. DE 213687861

Test-Report

Application No.: 6-12-10/1

Applicant: HEMPEL A/S Lundtoftevej 150 DK-2800 Kgs. Lyngby

Application for

inspection on the: 2010-06-15 Order No. or sign: Mr. Barreiro

Applied for: Recommended Practice for Internal Coating for Non-Corrosive Gas Transmission Service according to API RP 5L2:2002

Recieve of samples: 2010-07-02

Testing-Material: - 80 test panels 150 75 0,8 mm coated with: Hempels HS Gas Pipe Coating 87831 Color: redbrown

- 2,0 kg Hempels HS Gas Pipe Coating 87838 Part A MR by volume: 4 : 1 with

Hempels Curing Agent 95830 Part B Color: redbrown

- 1,0 kg Hempels Curing Agent 95830 Part B

- 2,0 l Hempels Thinner 08080

INSTITUT FR LACKPRFUNG ANDREAS KEINER GMBH

- Test-Report 6-12-10/1 Page 2 -

Recommended Practice for Internal Coating for Non-Corrosive Gas Transmission Service according to API RP 5L2:2002

This Recommended Practice provides for the internal coating of line pipe used for non-corrosive natural gas service.

2. COATING MATERIAL SPECIFICATION

2.1 Purpose

This section describes laboratory methods of identifying and qualifying coating materials suitable for use under the intent of this Recommended Practice.

2.2 Description

2.2.1 Coating Materials

2.2.1.1 The material normally consists of the following:

a. Pigmented or clear base b. Pigmented or clear converter c. Pigment that includes sufficient rust inhibitor to pass salt spray test. (See Par. 3.5.1) d. Application solvent for adjusting to suitable spray viscosity

Result: meets description

2.2.1.2 The coating material shall contain no substances which could be released from the coating in service and prove detrimental to the operation of the pipeline and/or quality of the Gas.

2.2.1.3 The coating material, including repair materials, shall neither degrade nor produce hazardous vapors when later subjected to external coating thermal cycles up to 575 F (300 C)



2.2.2 Mixing

The coating materials shall be mixed before use by agitating together portions of base and converter as recommended by the supplier.

Result: 4 parts by volume base, 1 part by volume converter

2.2.3 Thinning

The coating material may be thinned by mixing with the solvent supplied and/or specified by the supplier.

2.3 Physical Properties

2.3.1 Individual Components

Property Value Method Base Gal. Wt. 12,61 ASTM D 1475 Converter Gal. Wt. 8,32 ASTM D 1475 Solvent Boiling Range designated ASTM D 1078 Base Boiling Range value ASTM D 1078 Converter Boiling Range specified ASTM D 1078 Application Boiling Range by supplier ASTM D 1078

Base Settling 10 ASTM D 1309 (testing) ASTM D 869 (reporting) Converter Settling 10 ASTM D 1309 (testing) ASTM D 869 (reporting)

2.3.2 Mixed Components

Property Value Method Volume Solids 83,20 % Appendix #1 Grind 6 ASTM D 1210

Coarse Particles none ASTM D 185 (except use ETHYLENE GLYCOL MONOBUTYL ETHER as washliquid)



2.3.3 Thinned (In ratio according to Supplier`s instructions)

Property Value Method

Flow Uniform appearance when applied on vertical surface of given temperatures

Spray application on steel at 50 F [10 C], 100 F [37 C], 150 F [66 C] to result in 3.0 mil [76 micron] minimum dry film.

Pot Life cured ASTM D 1200 Viscosity 95 sec. # 4 Ford Cup at 77 F [25 C]

3. LABORATORY COATING TESTING

3.1 Purpose

This section describes laboratory tests required to qualify coating materials and laboratory methods. Qualification of coating by laboratory methods is required prior to production. Once qualification is made, no further qualification tests are required unless the coating materials or laboratory application methods change. For each qualified material, the supplier shall provide a qualitative analysis. An acceptable method is an infra-red spectrum. The supplier shall certify to the applicator and/or purchaser the results of tests performed under section 3 for each qualified coating material.

3.2 Steel Panels for Performance Testing

Test panels shall be mild carbon steel 3 6 0,032 in. (75 150 0,8 mm). The surface to be coated shall be sand blasted to any of the following standards:

(1) NACE No. 1 white metal finish in accordance with NACE Visual Standard TM-01-75 (2) Steel Structures Painting Council SSPC-Vis-1-82T SP5. (3) Swedish Pictorial Standard SIS 05-59-00 SA3. (4) DIN 55 928 Part 4

3.3 Laboratory Application of Coating Materials

3.3.1 Mixing

Coating material shall be mixed or thinned to normal spray viscosity in accordance with supplier`s recommendation.



3.3.2 Application

Application shall be made by spray on the prepared side of a test panel. The atmospheric environment, during spraying, shall be controlled to (77 5) F (25 3 C), and a maximum relative humidity of 80 %. The back and edges of the panel shall be protected.

3.3.3 Dry Film Thickness

Test thickness of film on completed panel (conditioned per Par. 3.4) shall be 2.0 0.2 mils (51 5) microns measured by a film thickness gauge calibrated with a National Bureau of Standards Coating Thickness Calibration Standard of a thickness within 20 % of specified nominal thickness.

Result: meets requirements dry film thickness 61 - 135 m / 2,4 - 5,3 mils

3.4 Conditioning of coated Panels

3.4.1 For qualification tests, the following schedule of conditioning shall apply:

Air dry for 10 days at 77 5 F (25 3 C), followed by a 24 hour bake in a circulating air oven at 120 5 F (49 3 C). Relative humidity during the air drying shall not exceed 80 %.

3.4.2 After completing the schedule of conditioning outlined above, panels may be stored at room temperature until needed for testing, but not longer than 90 days.

3.5 Performance of Laboratory coated Steel Panels

3.5.1 Testing

The tests in table 3.5 shall be performed on the test panels which have been prepared, coated and conditioned in accordance with the above procedures. Tests shall be performed on duplicate panels. A test result is acceptable when results of both test panels comply with the criteria listed below. In case of failure of either panel, the test shall be repeated on duplicate panels. One such retest shall be permit-ted.



Table 3.5 Test Acceptance Criterion

Test Method Results

Salt Spray Appendix #2 ASTM B 117, 500 hr. (see Appendix #2) meets requirements

Water Immersion No blistering over 0.25 in. (6.3 mm) from edges. (1)

Saturated CaCO3 solution in distilled water 100 % immersion, room temperature, 21 days.

meets requirements

Mixture, equal parts by volume, methanol & water

No blistering over 0.25 in. (6.3 mm) from edges. (1)

100 % immersion, room temperature, 21 days.

meets requirements

Stripping Appendix #8 Appendix #8 meets requirements

Bend

At 0.5 in. (13 mm) diameter and larger, the panel shall show no flaking, loss of adhesion or cracking of the coating as determined by unaided visual inspection.

ASTM D 522 meets requirements

Adhesion No lifting of any material other than cuttings.

Appendix #4 meets requirements

Hardness Min. 94 Buchholz at 77 2 F (25 1 C) DIN 53 153 meets requirements

(125) Gas Blistering No blistering Appendix #5 meets requirements

Abrasion Minimum 23 Coef. of Abrasion ASTM D 968, Method A meets requirements

Hydraulic Blistering No blistering Appendix #6 meets requirements

3.5.2 Additional Tests

At the option of the purchaser or applicator, additional performance tests may be specified to meet individual requirements.



3.6 Performance Testing Glass Panels

3.6.1 Panel Preparation

3.6.1.1 Panel Size

The test panel shall be standard 1 3 in. (25 75 mm) glass slides, frosted one side.

3.6.1.2 Cleaning

Panels shall be solvent cleaned by rinsing first in xylol, than in acetone, immidiately prior to coating application.

3.6.2 Application of Coating Material

Follow Par. 3.3.1 and 3.3.2, making the coating application on the frosted side of the panel only. The wet film thickness shall result in a 2.0 0.2 mil (51 5 micron) dry film.

3.6.3 Performance of Laboratory coated Glass Panels

Test Appeptance Critierion Test Method Result

Pinhole (Wet Film) meets requirements no pinholes

Pinhole (Dry Film) no pinholes Appendix G

meets requirements no pinholes

5. PRODUCTION INSPECTION AND ACCEPTANCE

5.1 Purpose

This section defines the limits of acceptance of internally coated pipe and methods of final testing to assure compliance therewith.

5.2 General



5.2.1 Working Area

A safe working area that is suitable for the performance of their duties shall be provided by the applicator for the purchasers inspectors and representatives.

5.2.2 Applied Coating Film

The applied coating film should be uniform in gloss, thickness and colour and should be free of irregularities. Blushing, regardless of the degree of colour change, shall not considered detrimental provided the affected area meets the requirements of Par. 5.3.4.4 Bond (Adhesion) Test and Par. 5.3.4.2 Film Thickness Test.

Result: meets requirements

5.2.3 Special Requirement

Any pipe which requires closer inspection shall be set aside upon curing of the coating. Purchaser may require that the applicator set aside such pipe as their representative may request for testing, providing that the amount of such pipe shall not exceed two joints for each eight-hour production period on a current basis, or one joint from each four-hour period.

5.3 Production Tests

The following production tests are recommended for proper quality control of the coated pipe and should be conducted at a frequency that will assure control. The pinhole test (Par. 5.3.4.1) and the film thickness test (Par. 5.3.4.2) shall be conducted hourly and whenever production is interrupted, or production parameters change. All other production tests shall be conducted once per shift.

5.3.1 Test for pH on Bare Surface of pickled or Wet Cleaned Pipe

Water having an initial pH value of 6.0 to 8.5 as determined with a pH meter, is poured into a pipe at one end and gathered in a cup at the other end. Limits of pH: within 0.5 of initial pH value, and between 6.0 to 8.5, immediately prior to coating application.

This test for pH is not applicable to the bare surface of mechanically cleaned pipe.

Result: no laboratory test

5.3.2 Panel and Slide Preparation

Metal panels shall be prepared in accordance with 3.2 or in a manner simulating pipe surface condition before coating.



5.3.3 Coating and Curing of Panel or Slide

A panel or slide is attached to the inside of a clean pipe. The panel is coated. The panel or slide is to remain in the pipe for a minimum of five minutes. After the panel or slide is removed, the test area on the pipe is spot repaired. After 15 to 30 minutes of air drying, the test panel or slide is dried for 10 mi

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