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    Relationship to Thermodynamics

    Chapter One

    Section 1.3

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    Alternative Formulations

    Alternative Formulations

    Time Basis:

    At an instant

    or

    Over a time interval

    Type of System:

    Control volume

    Control surface

    An important tool in heat transfer analysis, often

    providing thebasis for determiningthe temperature

    of a system.

    CONSERVATION OF ENERGY

    (FIRST LAW OF THERMODYNAMICS)

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    At an Instant of Time:

    Note representation of system by a

    control surface (dashed line)at the boundaries.

    Surface Phenomena

    ,

    in out

    : rate

    energy transfer across the controlof thermal and/or mechanical

    due to heat transfer, fluid flow and/or work interactions.surface

    E E

    Volumetric Phenomena

    : rate of due to conversion from another energy form

    (e.g., electrical, nuclear, or chemical); energy conversion proc

    thermal ener

    ess occurs w

    gy generatio

    ithin the sy e

    n

    m.

    st

    gE

    stenergy: storate of rage inchang the se o ysf m.teE

    Conserv

    ation of Energy

    in out stst

    gdE

    dtE E E E (1.12c)

    Each term has units of J/s or W.

    APPLICATION TO A CONTROL VOLUME

    Over a Time Interval

    Each term has units of J.

    in out stgE E E E (1.12b)

    CV at an Instant and over a Time Interval

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    At an instant

    tdUq Wdt

    Special Cases (Linkages to Thermodynamics)

    (i) TransientProcess for a Closed Systemof Mass (M) Assuming Heat Transfer

    to the System (Inflow) and Work Done by the System (Outflow).

    Over a time intervaltot

    stQ EW (1.12a)

    Closed System

    For negligible changes in potential or kinetic energy

    tQ W U

    Internalthermal energy

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    Example 1.4: Application to thermal response of a conductor with Ohmic

    heating (generation):

    Involves change in thermal energyand for an incompressible substance.

    tdU dT

    Mcdt dt

    Heat transfer is from the conductor (negative )q

    Generation may be viewed as electrical workdone on the system (negative )W

    Example 1.4

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    Example 1.6: Application to isothermal solid-liquid phase change in a container:

    Latent Heat

    of Fusion

    latt sfU U Mh

    Example 1.6

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    (ii) Steady Statefor Flow through an Open Systemwithout Phase Change or

    Generation:

    flow ow rkpv enthalp ytu pv i

    in out in out

    ideal gas constant specific heFor an w :atith

    pi i c T T

    in out in out

    in out

    For an :incompressible liqu

    0

    id

    u u c T T

    pv pv

    2 2

    in

    in

    out0

    2 2

    0out

    For systems with significant heat transfer:

    V V

    gz gz

    At an Instant of Time:2

    out

    02t

    m u pv V gz W

    2

    in2t

    m u pv V gz q

    (1.12d)

    Open System

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    Surface Energy Balance

    A special case for which no volume or mass is encompassed by the control surface.

    Conservation of Energy(Instant in Time):

    outin 0E E (1.13)

    Applies for steady-state and transient conditions.

    Consider surface of wall with heat transfer by conduction, convection and radiation.

    cond conv rad 0q q q

    4 41 2 2 2 2 sur 0T T

    k h T T T T L

    With no mass and volume, energy storage and generation are not pertinent to the energy

    balance, even if they occur in the medium bounded by the surface.

    THE SURFACE ENERGY BALANCE

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    Methodology

    On a schematicof the system, represent the control surfaceby

    dashed line(s).

    Choose the appropriate time basis.

    Identify relevant energytransport, generation and/or storage terms

    by labeled arrowson the schematic.

    Write the governing form of the Conservation of Energyrequirement.

    Substitute appropriate expressions for terms of the energy equation.

    Solve for the unknown quantity.

    METHODOLOGY OF FIRST LAW ANALYSIS

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    Problem 1.57: Thermal processing of silicon wafers in a two-zone furnace.

    Determine (a) the initial rate of change of the wafer

    temperature and (b) the steady-state temperature.

    Problem: Silicon Wafer

    KNOWN: Silicon wafer positioned in furnace with top and bottom surfaces exposed to hotand cool zones, respectively.

    FIND: (a) Initial rate of change of the wafer temperature from a value of 300K,w,iT and (b)

    steady-state temperature. Is convection significant? Sketch the variation of wafer temperature

    with vertical distance.

    SCHEMATIC:

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    Problem: Silicon Wafer (cont.)

    ASSUMPTIONS: (1) Wafer temperature is uniform, (2) Hot and cool zones have uniformtemperatures, (3) Radiation exchange is between small surface (wafer) and large enclosure

    (chamber, hot or cold zone), and (4) Negligible heat losses from wafer to pin holder.

    ANALYSIS: The energy balance on the wafer includes convection to the upper (u) and lower

    (l) surfaces from the ambient gas, radiation exchange with the hot- and cool-zones and an energystorage term for the transient condition. Hence, from Eq. (1.12c),

    in out stE E E

    or, per unit surface area

    rad, rad, cv, cv,w

    h c u l d T

    q q q q cd

    dt

    4 4 4 4sur,sur, ww c w u w l whd T

    T T T T h T T h T T cd dt

    (a) For the initial condition, the time rate of change of the wafer temperature is determined

    using the foregoing energy balance with , 300K,w w iT T

    8 2 4 4 4 8 2 4 4 4 440.65 5.67 10 W / m K 1500 300 K 0.65 5.67 10 W / m K 330 300 K

    2 28W / m K 300 700 K 4W / m K 300 700 K

    32700 kg / m 875J / kg K 0.00078 /w im dT dt

    104 K/sw idT / dt