1980 to 1989

THE Conference on Industrial Water

OFFICIAL PROCEEDINGS

THE INTERNATIONALWATER CONFERENCE

41st ANNUAL MEETING

October 20., 21, & 22, 1980William Penn Hotel

Pittsburgh, Pennsylvania, U.S.A.

Andrew F. McClureGeneral Chairman

Yale SolomonProgram Chairman

Mary Jean EdgarSecretary

Sponsored By The

Engineers' Society of Western Pennsylvania

INCORPORATED 1980

Rights to reprint articles in this publication are automatically granted provided credit is given the author(s) and author(s) companyincluding the statement in a conspicuous place, preferably the first page:

"Reprinted from the Proceedings of the 41st International Water Conference, Pittsburgh, Pa. (USA), October 20, 21 & 22, 1980.(Please advise IWC of the extent of reprint)

© 1980 ENGINEERS' SOCIETY OF WESTERN PENNSYLVANIA

1

Papers presented, Monday, October 20, 1980MORNING SESSION "A"

Ion Exchange & Condensate PolishingStephen Vajda, Session Chairman, Jones & Laughlin Steel Corporation, Pittsburgh, Pennsylvania

Irving M. Abrams, Session Discussion Leader, Diamond Shamrock Chemical Company, Redwood City, CaliforniaSTATUS OF DEEP BED CONDENSATE POLISHING - 1980

Louis F. Wirth, Dow Chemical Company, Midland, Michigan, (IWC-80-52) 1THREE YEARS OPERATING EXPERIENCE WITH PRECOAT MATERIALS CONTAINING FIBERAND POWDERED ION EXCHANGE RESINS

C.J. Halfifoster and Chester Parks, Ecodyne/ Graver Water Division, Union, New Jersey (IWC-80-1) ... 16

PLANT OPERATING EXPERIENCE WITH THE FIRST-TRI-BED CONDENSATE POLISHINGINSTALLATION IN THE U.S.A.

Ralph H. Eherts, Baltimore Gas & Electric, Lusby, Maryland, (IWC-80-2) 25

MORNING SESSION "B"Water and Wastewater Treatment

Edward F. Maziarz, Session Chairman, Aluminum Company of America, Pittsburgh, PennsylvaniaStiles B. Twitchel, Session Discussion Leader, Mogul Corporation, Chagrin Falls, Ohio

PROGRAMMABLE LOGIC CONTROLLERS - EXPERIENCE WITH A LARGE MAKEUPDEMINERALIZER INCLUDING PRETREATMENT

Linda Brown, Exxon, Baytown, Texas and Jack Samkoff, Ecodyne/ Graver Water Division,Union, New Jersey (IWC-80-4) 33

DESIGN AND OPERATION OF A COOLING TOWER SIDESTREAM TREATMENT SYSTEMR.J. Weis, Peabody-Welles, Roscoe, Illinois, and Lee Stierwalt, City of Colorado Springs, ColoradoSprings, Colorado (IWC-80-5) 39

ECONOMIC CONSIDERATIONS IN OILY WASTEWATERR.J. Churchill, Petrolite Corporation, Tretolite Division, St. Louis, Missouri (IWC-80-6) 47

AFTERNOON SESSION "A"Boiler Treatment

Ray N. Baum, Session Chairman, Craft Products Company, Inc., Pittsburgh, PennsylvaniaSamuel B. Dilcer, Session Discussion Leader, Hercules, Incorporated, Wilmington, Delaware

TESTING OF A HIGH GRADIENT MAGNETIC FILTER AT THE BRUNSWICK STEAMELECTRIC PLANT

D.N. Rodgers, W.J. Marble, General Electric Company, San Jose, California and R. Nichols, G. Warriner,Sala Magnetics, Cambridge, Massachusetts and M. McDowell, Carolina Power & Light, Raleigh,North Carolina (IWC-80-7) 57

AN IN-DEPTH FIELD EVALUATION OF IRON TRANSPORT IN 1400 PSI BOILERS WITHVARIOUS WATER TREATMENTS

H.A. Chagnard, T.J. Tvedt, Dow Chemical Company, Plaquemine, Louisiana and B.L. Shearer, BetzLaboratories, Inc., Baton Rouge, Louisiana (IWC-80-8) 67

SAVING ENERGY BY CATALYTIC REDUCTION OF OXYGEN IN FEEDWATERF.B. Martinola, P. Thomas, Bayer A.G., Leverkusen, West Germany (IWC-80-9) 77

THE INVESTIGATION OF SCALING AND CORROSION MECHANISMS USINGPROCESS SIMULATION

P.T. Colombo, J.A. Kelly, Nalco Chemical Company, Oak Brook, Illinois (IWC-80-10) 85

AFTERNOON SESSION "B"Membrane Technology

Walter Zabban, Session Chairman, The Chester Engineers, Coraopolis, PennsylvaniaGeorge J. Crits, Session Discussion Leader, Cochrane Environmental Systems, King of Prussia, Pennsylvania

REVERSE OSMOSIS SYSTEM DESALTS CITY SEWAGE EFFLUENT TO PROVIDE WATERFOR OIL REFINERY

Robert Quinn, The Permutit Company, Paramus, New Jersey (IWC-80-1 1) 95ELECTRODIALYSIS IN INDUSTRIAL WATER TREATMENT

William H. Highfield, Consultant Phoenix, Arizona (IWC-80-12) 99THE ROLE OF ULTRAFILTRATION IN THE PRODUCTION OF ULTRA HIGH PURITY WATER

Michael Kaszyski, Western Electric Company, Allentown, Pennsylvania and Steven R. Gagnon andGary D. Jones, Illinois Water Treatment Company, Rockford, Illinois (IWC-80-13) 105

ii

THE PRODUCTION OF HIGH PURITY WATER WITH COMBINED REVERSE OSMOSIS ANDION EXCHANGE POLISHING

Frank X. McGarvey, Michael Gottlieb, S.M. Ziarkowski, Ionac Chemical Company, Birmingham,New Jersey (IWC-80-14)

117

Papers presented, Tuesday, October 21, 1980MORNING SESSION "A"

Steam Purity and Turbine Corrosionsponsored by ASME

Arthur W. Fynsk, Session Chairman, E.I. du Pont de Nemours & Company, Wilmington, DelawarePhilip A. Barker, Session Discussion Leader, Nalco Chemical Company, Oak Brook, Illinois

DEPOSITION OF SALTS FROM STEAMW.E. Allmon, N.J. Mravich, The Babcock & Wilcox Company, Alliance, Ohio and R.J. Saia, GeneralElectric Company, Schenectady, New York and Thomas O. Passell, Electric Power Research Institute,Palo Alto, California (IWC-80-15) 127

CHARACTERIZATION OF IMPURITIES IN THE FEEDWATER, STEAM AND CONDENSATECYCLE OF A ONCE-THROUGH STEAM GENERATION PLANT

James K. Rice, Consultant, Olney, Maryland (I.WC-80-16) 141

CONDENSATE FEEDWATER, STEAM SAMPLING AND ANALYSIS IN ONTARIO HYDROTHERMAL GENERATING STATIONS

J. Brown and R.E. Massey, Ontario Hydro Research, Toronto, Ontario, Canada (IWC-80-17) 151

STEAM/CONDENSATE CHEMICAL MAINTENANCE AND CONTROL INPOWER PLANT OPERATIONS

W.M. Hickam, J.C. Bellows, S.H. Peterson, D.F. Pensenstadler, Westinghouse Electric Corporation,Pittsburgh, Pennsylvania and E.K. Evans, C. Green, E.G. Mallari, City of Austin, Austin, Texas(IWC-80-18) 159

MORNING SESSION "B"Cooling Water

Paul Puckorius, Session Chairman, Puckorius & Associates, Evergreen, ColoradoGerald Schweitzer, Session Discussion Leader, Calgon Corporation, Pittsburgh, Pennsylvania

TOWARD A BETTER UNDERSTANDING OF COMMERCIAL PHOSPHONATESR.E. Campbell, Philip A. Hunt Chemical Company, Lincoln, Rhode Island (IWC-80-19) 167

CORROSION CONTROL IN LARGE COOLING SYSTEMS WITH MOLYBDATESW.J. Ward, D.A. Jenson, Olin Water Services, Overland Park, Kansas (IWC-80-20)

177

THE EFFECT OF POLYMERIC DISPERSANTS ON CORROSION INHIBITION OF MILD STEELGerald D. Hansen, Victoria D. Powell, ARCO Performance Chemicals, Glenolden,Pennsylvania (IWC-80-21) 185

EVALUATION OF MINERAL SCALE FORMATION AND ITS INHIBITIONJ.S. Gill, Calgon Corporation, Pittsburgh, Pennsylvania (IWC-80-22) 193

Papers presented, Tuesday, October 21, 1980AFTERNOON SESSION "B"

Chemical CleaningPaul Goldstein, Session Chairman, NUS Corporation, Pittsburgh, Pennsylvania

John R. Gatewood, Session Discussion Leader, Halliburton Services, Duncan, OklahomaFLUORIDE CLEANING OF A COOLING WATER SYSTEM

Edward A. Yorkgitis, U.S. Steel Corporation, Pittsburgh, Pennsylvania (IWC-80-27) 198

PREOPERATIONAL CLEANING OF A STEAM GENERATION SYSTEM AT A NEWCHEMICAL PLANT

A.W. Fynsk, R.T. Harris, E.I. du Pont de Nemours & Company, Wilmington, Delaware (IWC-80-28) ...205

THE CHEMICAL CLEANING OF A FIBER CARTRIDGE FROM A REVERSE OSMOSIS PERMEATORH.D. Johnson, M.B. Lawson, Halliburton Services, Duncan, Oklahoma (IWC-80-29) 213

A STUDY OF CORROSION OF BOILER METALS IN INHIBITED CHEMICAL CLEANING SOLVENTSW.W. Frenier, K.J. Loescher, Dowell Division, Dow Chemical Company, Tulsa, Oklahoma(IWC-80-30) 217

iii

Papers presented, Wednesday, October 22, 1980MORNING SESSION "B"

Ion Exchange - Progress ReportsLouis F. Wirth, Session Chairman, Dow Chemical Company, Midland, Michigan

Richard Hetherington, Session Discussion Leader, Epicor Incorporated, Fort Washington, PennsylvaniaOPTIMIZATION OF SULPHURIC ACID CONDITIONS IN COUNTERCURRENT REGENERATEDION EXCHANGE UNITS

P. Vulliez-Sermet, Rohm & Haas European Laboratories, Valbonne, France (IWC-80-50) 225

STANDARDIZATION OF METHODOLOGY FOR ESTIMATING THE ORGANIC FOULING OFION EXCHANGE RESINS

Sallie Fisher, Gerard Otten, Puricons, Inc., Berwyn, Pennsylvania (IWC-80-35) 23.1

CONTINUOUS ION EXCHANGE FOR METAL RECOVERY AND WATER TREATMENTAlex Himsley, Himsley Engineering Ltd., Toronto, Ontario, Canada (IWC-80-36) 236

PILOT SCALE EVALUATION OF STRONG BASE ANION RESINS WITH SYNCRUDE CANADA LTD.L. Ciplijauskas, B.J. Fuhr, J.K. Liu, Syncrude Canada, Ltd., Edmonton, Alberta, Canada(IWC-80-37) 241

A SIGNIFICANT REDUCTION OF POLLUTION FROM ION EXCHANGE SOFTENERS BY USEOF A NOVEL SINGLE TANK RECLAIMING AND REGENERATION SYSTEM

George J. Crits, D.R. Zimmerman, J.P. Pratt, Cochrane Environmental Systems, King of Prussia,Pennsylvania (IWC-80-38) 247

PROCEDURE FOR MEASUREMENT OF RESIN LEAKAGE: PRELIMINARY RESULTS FROMTHE DAVIS BESSE NUCLEAR STATION

S.J. Elmiger, J.M. Kibler, E.D. Yochheim, Babcock & Wilcox, Alliance, Ohio and W. Mills, ToledoEdison, Toledo, Ohio (IWC-80-39) 250

AFTERNOON SESSION "B"Miscellaneous - Progress Reports

Charles A. Bishop, Session Chairman, U.S. Steel Corporation, Pittsburgh, PennsylvaniaSallie Fisher, Session Discussion Leader, Puricons, Inc., Berwyn, Pennsylvania

DEWATERING ALTERNATIVES FOR FGD SLUDGESF. Jankowski, W.A. Pabst, IU Conversion Systems, Horsham, Pennsylvania (IWC-80-44) 256

THE USE OF POLYSULFONATED STYRENE COPOLYMERS AS BOILER WATER SLUDGECONDITIONING AGENTS

P.E. Greenlimb, D.A. Carter, Dearborn Chemical Company, Lake Zurich, Illinois (IWC-80-45) 261

NITRIFICATION BLOCK FOR CLOSED SYSTEMSS.R. Tressider, Perolin-Bird Archer, Ltd., Cobourg, Ontario, Canada (IWC-80-51) 266

A NEW OXYGEN SCAVENGER FOR BOILER APPLICATIONSD. Bloom, L.R. Gess, Nalco Chemical Company, Oak Brook, Illinois (IWC-80-47) 269

THE USE OF A NEWLY DESIGNED BIOTOWER AND MUTANT CULTURES TO EFFECTIVELYAND ECONOMICALLY TREAT PROCESS WASTEWATER

George Goyak, William O'Donnell, Philip W. Spraker, Michael J. Telepchak, Sybron Corporation,Leopold Division, Zelienople, Pennsylvania (IWC-80-48) 275

THE USE OF AUTOMATED, MULTI-ELEMENT ANALYSIS TECHNIQUE TOMONITOR DISCHARGES

C.J. Cardarelli, A.T. Kashuba, G.J. Kralik, Betz Laboratories, Inc., Trevose, Pennsylvania(IWC-80-49) 279

Papers presented, Tuesday, October 21, 1980AFTERNOON SESSION "A"

Symposium Session I - Chemical Data Base and Data EstimationRobert E. Mesmer, Session Chairman, Oak Ridge National Laboratories, Oak Ridge, Tennessee

ESTIMATION OF CONCENTRATION QUOTIENTS FOR IONIC EQUILIBRIA IN HIGHTEMPERATURE WATER: THE MODEL SUBSTANCE APPROACH

W.T. Lindsay, Jr., Westinghouse Electric Corporation, Pittsburgh, Pennsylvania (IWC-80-24) 284

CHEMICAL EQUILIBRIA IN AQUEOUS SYSTEMS AT HIGH TEMPERATURESJames W. Cobble, San Diego State University, San Diego, California (IWC-80-25) 295

iv

ESTIMATES OF THERMODYNAMIC PROPERTIES OF AQUEOUS ELECTROLYTE SOLUTIONSAT HIGH TEMPERATURES

Cecil M. Criss, University of Miami, Coral Gables, Florida (IWC-80-26) 311

Papers presented, Wednesday, October 22, 1980MORNING SESSION "A"

Symposium Session II - Calculations at High Temperatures - Steam Generating SystemsYale Solomon Session Chairman, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania

CALCULATIONSF STEAM GENERATOR CHEMISTRYR.J. Bawden, R. Garnsey, Central Electricity Research Laboratories, Leatherhead, Surrey, England,and L.J. Martel, Electric Power Research Institute, Palo Alto, California (IWC-80-31) 318

COMPUTATION OF CHEMICAL EQUILIBRIA IN STEAM GENERATOR WATERP.V. Balakrishnan, Atomic Energy of Canada, Ltd., Chalk River, Ontario, Canada (IWC-80-32) 323

MODELING THE. EFFECTS OF CONDENSER INLEAKAGE ON PWR CHEMISTRYJ. Leibovitz, S.G. Sawochka, NWT Corporation, San Jose, California (IWC-80-33) 335

CALCULATIONS OF STEAM GENERATOR CHEMISTRY (BOILER-TOTAL SYSTEM ACCOUNTING)J.L Walker, W.L. Trace, Calgon Corporation, Pittsburgh, Pennsylvania (1WC-80-34) 343

Papers presented, Wednesday, October 22, 1980AFTERNOON SESSION "A"

Symposium Session III - Calculations at Intermediate Temperatures - Cooling Water SystemsJames K. Rice, Session Chairman, Consultant, Olney, Maryland

CALCULATIONS OF COOLING WATER SYSTEMSJ.T. Aronson, Stearns Roger Engineering Corporation, Denver, Colorado and Wayne C. Micheletti,Radian Company, Austin, Texas and Winston Chow, Electric Power Research Institute, Palo Alto,Calfornia(IWC-80-41) 350

COMPUTERIZED WATER MODELING IN THE DESIGN AND OPERATION OF INDUSTRIALWATER SYSTEMS

Donald A. Johnson, Kenneth E. Fulks, Nalco Chemical Company, Oak Brook, Illinois (IWC-80-42) . .. .357

THE USE OF COMPUTER MODELLING IN CALGUARD TO MATHEMATICALLY SIMULATECOOLING WATER SYSTEMS AND RETRIEVE DATA

Charles J. Schell, Calgon Corporation, Pittsburgh, Pennsylvania (IWC-80-43) 364

SPECIAL PAGESDedication in memory of William K. (Bill) Porter...

. viIWC Executive Committee And Advisory Committee Representatives 203Index of Advertisers for IWC 41st Proceedings 204

v




42nd ANNUAL MEETING

October 25, 26, & 27, 1981William Penn Hotel


Edward F. Maziarz

Mary Jean EdgarGeneral Chairman

Executive Director

Robert D. Scherer

Florence K. TroyProgram Chairman

Program Coordinator

Sponsored By The


INCORPORATED 1880


"Reprinted from the Proceedings of the 42nd International Water Conference, Pittsburgh, Pa. (USA), October 25, 26, & 27, 1981.(Please advise IWC of the extent of reprint)



Cooling WaterRay Baum, Session Chairman, Craft Product Company Inc., Pittsburgh, Pennsylvania

Richard Every, Session Discussion Leader, ARCO Performance Chemicals, Philadelphia, PennsylvaniaWHAT A USER EXPECTS FROM A COOLING WATER TREATMENT VENDOR

Robert J. Franco, Exxon Research & Engineering Company, Florham Park, New Jersey, (IWC-81-1) ...

1COOLING WATER USE IN ENERGY INDUSTRIES

W. K. Jing and S. H. Chiang, University of Pittsburgh, Pittsburgh, Pennsylvania, (IWC-81-2) 11

MORNING SESSION "B"Membrane Technology

C. B. Mitchell, Session Chairman, E. I. du Pont de Nemours & Company, Wilmington, DelawareEdward Geishecker, Session Discussion Leader, Ionics Incorporated, Watertown, Massachusetts

OPERATING EXPERIENCE WITH SIX LARGE REVERSE OSMOSIS PLANTSMichael O'Brien and Terrence LaTerra, Ecodyne/Graver Water Division, Union, New Jersey,(IWC-81-3) 21

OPERATING EXPERIENCES ON A REVERSE OSMOSIS PLANT CONVERTING SEA WATER INTOBOILER FEEDWATER

Ivan Vera, CADAFE, National Electric Company of Venezuela, Carabobo, Venezuela, (IWC-81-4) 35

AFTERNOON SESSION "A"Boiler Water Treatment

Paul Goldstein, Session Chairman, NUS Corporation, Pittsburgh, PennsylvaniaSamuel B. Dilcer, Session Discussion Leader, Hercules Incorporated, Wilmington, Delaware

DEPOSIT GROWTH IN A 600 PSI BOILER USING CHELATE BASED WATER TREATMENTF. H. Seels, D. L. Gibbon, and G. C. Simon, Calgon Corporation, Pittsburgh, Pennsylvania, (IWC-81-5). 47

BOILER SCALE INHIBITORSLawrence A. Gaylor and Sherman J. Sprague, The Mogul Corporation, Chagrin Falls, Ohio, (IWC-81-6) . 59

THE THERMAL/HYDROLYTIC STABILITY OF 1-HYDROXYETHYLIDENE 1, 1-DIPHOSPHONICACID (HEDP)

R. Brian Good and Joseph B. Arots, Hercules Incorporated, Wilmington, Delaware, (IWC-81-7) 65

HEATING BOILER TREATMENT: CHROMATE VS A NONHAZARDOUS TREATMENTR. Kent Stultz, Lee G. Harrow, C. K. Huang, D. C. Hutchens, G. H. Hoekfer, Omaha Public Power District,Omaha, Nebraska, and James M. Chambers, Drew Chemical Company, Omaha, Nebraska, (IWC-81-8).. 83

AFTERNOON SESSION "B"Industrial Solid Wastes - Case Histories

(Sponsored by ASTM)Walter Zabban, Session Chairman, The Chester Engineers, Coraopolis, Pennsylvania

E. Dennis Escher, Session Discussion Leader, Penn Environmental Consultants, Pittsburgh, PennsylvaniaCASE HISTORY OF A CHEMICAL WASTE LANDFILL

E. L. Patton, Union Carbide Corporation, Charleston, West Virginia, (IWC-81-9) 91

DISPOSAL PROPERTIES OF DRY SCRUBBER RESIDUESWilliam Webseter, Webster & Associates, Norristown, Pennsylvania, and John C. Buschman,Niro Atomizer, Inc., Columbia, Maryland, and James R. Donnelly, A/S Niro Atomizer, Soeborg,Denmark, (IWC-81-10) : 105

ROTARY KILN INCINERATION - CRITICAL DESIGN FEATURES OF A SUCCESSFULINCINERATION PROJECT

Thomas Rinker, Environmental Elements Corporation, Baltimore, Maryland, (IWC-81-11) 113

DEVELOPMENT OF GROUNDWATER MONITORING PLANS UNDER RCRAMark Dowiak, Donald Messinger, and Daniel Threlfall, Penn Environmental Consultants, Pittsburgh,Pennsylvania, (IWC-81-12) 117

Papers presented Tuesday, October 27, 1981MORNING SESSION "A"Steam Generating Systems

(Sponsored by ASME)Walter Riedel, Session Chairman, Consultant, Baltimore, Maryland

Robert D. Scherer, Session Discussion Leader, Duquesne Light Company, Pittsburgh, Pennsylvania

i

TRANSPORT OF IONIC IMPURITIES IN FOSSIL AND PWR CYCLES - NEW OBSERVATIONSOtakar Jonas, Westinghouse Electric Corporation, Wilmington, Delaware, (IWC-81-40) 125

ELECTROMAGNETIC FILTER EFFICIENCY FOR TYPICAL POWER PLANT PARTICULATESJames Brown, B. Bzovey, D. J. Dodd, J. Harnoy, and P. Leinonen, Ontario Hydro Research Division,Toronto, Ontario, Canada, (IWC-81-14) 141

SOME RESEARCH WORK ON WATER TREATMENT IN CHINESE UTILITY PLANTSQin Jin Zao and He Hui Chen, Thermal Power Engineering Research Institute, Peking,Peoples Republic of China, (IWC-81-15) 149

GUIDELINES FOR LAY-UP OF BOILERS AND THEIR AUXILIARIESJesse Beecker, Drew Chemical Corporation, Boonton, New Jersey, and Russell W. Lane, Consultant,Champaign, Illinois, (IWC-81-16) 155

MORNING SESSION "B"Industrial Solid Wastes - Panel Discussion

(Sponsored by ASTM)B. Charles Malloy, Session Chairman, Engineering Science Inc., Berwyn, Pennsylvania

INTRODUCTION OF ASTM WORKWilliam Webster, Webster & Associates, Norristown, Pennsylvania 159

PANEL DISCUSSION ON RISK ASSESSMENTJames E. Kerrigan, AMAX Environmental Services, Inc., Golden, Colorado,Dr. Steven Taub, Stablex Corp., Radnor, Pennsylvania,Jacqueline Rams, ASTM, WMO, Washington, D.C.Joseph Mayhew, Chemical Manufacturers Association, Washington, D.C., (IWC-81-17) 159

AFTERNOON SESSION "A"Condensate Polishing

Paul Cohen, Session Chairman, Consultant, Pittsburgh, PennsylvaniaGeorge J. Crits, Session Discussion Leader, Cochrane Environmental Systems, King of Prussia, Pennsylvania150 MILLION MEGAWATT HOURS OF CONDENSATE POLISHING

Mike Wadlington, Texas Utilities Generating Company, Dallas, Texas, Paul Gross, Datum Company,Houston, Texas, and John Longo, Ecodyne/Graver Water Division, Union, New Jersey, (IWC-81-18) . . .171

STATE-OF-THE-ART EVALUATION OF CONDENSATE POLISHER PERFORMANCEStephen J. Elmiger and M. J. Bell, Babcock & Wilcox Company, Alliance, Ohio, and C. S. Welty,Electric Power Research Institute, Palo Alto, California, (IWC-81-19) 185

OPERATING EXPERIENCE WITH A `TRIPOL' AMMONIA CYCLE CONDENSATE POLISHERPhilip W. Renouf, the Permutit Company of Australia Pty., Ltd. Sydney, N.S.W, Australia, andJ. H. Smith, Portals Water Treatment, Isleworth, Middlesex, United Kingdom, (IWC-81-20) 195

A DIFFERENT APPROACH TO CONDENSATE POLISHINGRalph E. Mickel, Allegheny Power Service Corporation, Greensburg, Pennsylvania, and Glenn R. Holmesand Patrick C. Canary, Monongahela Power Company, Maidsville, West Virginia, (IWC-81-21) 209

AFTERNOON SESSION "B"Instrumentation/Monitoring

E. Stuart Savage, Session Chairman, Dravo Corporation, Pittsburgh, PennsylvaniaGerald F. Connell, Session Discussion Leader, Capital Controls Company, Colmar, Pennsylvania

EXPERIENCES WITH CALCIUM ION ELECTRODE TECHNOLOGY IN CONTINUOUS SOFTENERSYSTEM MONITORING

Paul F. Pelosi, Drew Chemical Corporation, Boonton, New Jersey, and Philip D. Hill,American Cyanamid Company, Bound Brook, New Jersey, (IWC-81-22) 219

ENERGY LOSSES IN WATER CONDUITS: MONITORING AND DIAGNOSISW. G. Characklis, Nicholas Zelver, Frank L. Roe, and Mukesh H. Turakhia, Montana State University,Bozeman, Montana, (IWC-81-23) 229

DIGICHEM TM 3000 CHEMICAL ANALYZER: A NEW ON-LINE CHEMICAL ANALYZER FOR BOILERFEEDWATER ANALYSISRonald A. Perreault, Ionics Incorporated, Watertown, Massachusetts, (IWC-81-24) 236

A RAPID METHOD FOR ANALYSIS OF PHOSPHONATE COMPOUNDSPaul G. Blystone and Paul E. Larson, Hach Company, Loveland, Colorado, (IWC-81-26) 245

ii

Papers presented, Wednesday, October 28, 1981MORNING SESSION "A"Cooling Water Treatment

Paul Puckorius, Session Chairman, Puckorius & Associates, Evergreen, ColoradoGerald Schweitzer, Session Discussion Leader, Calgon Corporation, Pittsburgh, Pennsylvania

PRACTICAL APPLICATION OF CONDENSER SYSTEM PERFORMANCE MONITORING TO WATERTREATMENT DECISION MAKING

Robert J. Ferguson and M. J. Smas, Apollo Technologies, Whippany, New Jersey, (IWC-81-25) 251

THE EFFECT OF CARBON DIOXIDE TRANSFER ON COOLING WATER pH AND CALCIUMCARBONATE DEPOSITION

Ralph D. Boroughs, Jean E. McKee, and Robert D. Moss, Tennessee Valley Authority,Chattanooga, Tennessee, (IWC-81-27) 269

EVALUATION OF SULFONATED POLYMERS AS DEPOSIT CONTROL ADDITIVESIngrid E. Woerner and Robert A. Holzer, National Starch & Chemical Corporation, Bridgewater,New Jersey, (IWC-81-28) 281

MORNING SESSION "B"Ion Exchange Progress Reports

(No Prepared Discussion - All Floor Discussion)Richard Hetherington, Session Chairman, Epicor Incorporated, Fort Washington, Pennsylvania

Sallie Fisher, Session Discussion Leader, Puricons, Inc., Berwyn, PennsylvaniaTECHNIQUES FOR THE MEASUREMENTS AND REDUCTION OF RESIN CARRY-OVER FROMCONDENSATE POLISHERS

R. J. Gartmann, Transamerica Delaval, Florence, New Jersey, (IWC-81-30) 289

EFFECTS OF CAUSTIC QUALITY ON THE PERFORMANCE OF STRONG BASE ANIONEXCHANGERS

F. X. McGarvey, S. M. Ziarkowski, E. W. Hauser, and M. C. Gottlieb, Sybron/Chemical Division,Birmingham, New Jersey, (IWC-81-31) 297

KINETIC PERFORMANCES OF ANION EXCHANGE RESINSN. J. Ray, M. Ball, and A. Coates, Central Electricity Generating Board, Nottingham, England,(IWC-81-32) 307

INORGANIC ION EXCHANGERS AND THEIR APPLICATION IN INDUSTRYJasbir S. Gill, Calgon Corporation, Pittsburgh, Pennsylvania, (IWC-81-33) 315

SLOUGHAGE OF ORGANIC MATERIAL FROM FIELD DECROSSLINKED SULFONIC ACIDCATION EXCHANGE RESINS

Sallie Fisher and Gerard Otten, Puricons, Inc., Berwyn, Pennsylvania, (IWC-81-34) 319

LIFTBED- AND RINSEBED-PROCESS, A NOVEL TECHNIQUE FOR ION EXCHANGEFriedrich B. Martinola and Guenter Siegers, Bayer AG, Leverkusen, West Germany, (IWC-81-35) 325

EVALUATION OF ANION EXCHANGE CAPACITY FOR STRONG BASE ION EXCHANGE RESINSE. D. Nace, Rohm & Haas Company, Spring House, Pennsylvania, (IWC-81-47) 333

AFTERNOON SESSION "A"Steam Purity and Turbine Corrosion

James K. Rice, Session Chairman, Consultant, Olney, MarylandYale Solomon, Session Discussion Leader, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania

CORROSION PRODUCT RELEASE FROM ALLOYS 706 and 715 IN CONDENSER APPLICATIONSW. L. Pearl, S. G. Sawochka, and P. S. Wall, NWT Corporation, San Jose, California, (IWC-81-39) 339

CONTINUOUS AND GRAB SAMPLING AND ANALYSIS OF HIGH PURITY STEAMT. C. Roginski, Betz*Converse*Murdoch, Inc., Plymouth Meeting, Pennsylvania, (IWC-81-13) 351

STEAM TURBINE ENVIRONMENT MONITORING WITH METALLURGICAL SPECIMENSJ. Anello and J. C. Bellows, Westinghouse Electric Corporation, Philadelphia, Pennsylvania,(IWC-81-38) 359

iii

AFTERNOON SESSION "B"Miscellaneous Progress Reports

(No Prepared Discussion - All Floor Discussion)Andrew F. McClure, Session Chairman, Dravo Corporation, Pittsburgh, Pennsylvania

Donald E. West, Session Discussion Leader, Garratt-Callahan Company, Millbrae, CaliforniaTHE ELF/ANVAR COALESCENCE PROCESS FOR THE TREATMENT OF OILY STEAMCONDENSATE

Robert O'Connell, Graver Water Conditioning Company, Union, New Jersey, (IWC-81-41) 369

ACHIEVING HIGH RECOVERY RATE FROM BRACKISH WATER WITH A SEEDED REVERSEOSMOSIS SYSTEM

Terry M. O'Neail, Otto Kirchner, and William J. Day, Resources Conservation Company,Seattle, Washington, (IWC-81-42) 375

PERFORMANCE OF A HIGH TEMPERATURE MAGNETIC FILTER IN A BOILER WATERREACTOR PUMPED FORWARD HEATER DRAINS

Douglas N. Rodgers and Henry H. Elliott, General Electric Company, San Jose,California, (IWC-81-43) 383

EVALUATION OF CALCIUM HYDROXIDE CHEMISTRY TO CONTROL DENTING IN NUCLEARRECIRCULATING STEAM GENERATORS

Thomas A. Beineke, John F. Hall, David J. Morgan, Kathy E. Marugg, and D. B. Scott,Combustion Engineering Inc., Windsor, Connecticut, (IWC-81-44) 393

THE INVESTIGATION OF SCALING AND CORROSION MECHANISMS USING PROCESSSIMULATION - PART II

John A. Kelly, Nalco Chemical Company, Naperville, Illinois, (IWC-81-45) 399

NEUTRALIZING RETURN LINE CORROSION INHIBITOR WITH A VOLATILE OXYGENSCAVENGER

D.G. Cuisia, J. W. Rudolph, C. M. Hwa, and E. A. Tehle, Jr., Dearborn Chemical (U.S.),Lake Zurich, Illinois, (IWC-81-46) 407

iv

Printed and Bound by Publishers Choice Book Mfg. Co.Mars, Pennsylvania 16046




43rd ANNUAL MEETING

October 25, 26 & 27, 1982William Penn Hotel

Pittsburgh, Pennsylvania, U.S.A.Yale SolomonGeneral Chairman

Robert D. Scherer

Mary Jean EdgarVice Chairman

Executive Director

James R. Guseman

Florence K. TroyProgram Chairman

Program Director

Sponsored By The


INCORPORATED 1880


"Reprinted from the Proceedings of the 43rd International Water Conference, Pittsburgh, Pa. (USA), October 25, 26, & 27, 1982.(Please advise IWC of the extent of reprint)



Condensate PolishingRichard Hetherington, Session Chairman, Epicor, Incorporated, Fort Washington, Pennsylvania

James D. Shivers, Session Discussion Leader, L*A/Water Treatment Division, City of Industry, CaliforniaTWO YEAR STUDY ON CONDENSATE POLISHER PERFORMANCE AT SOUTHERN CALIFORNIAEDISON

David Auerswald and Frances M. Cutler, Southern California Edison, Paramount,California, (IWC-82-1) 1

NEW APPROACH OF RESIN SEPARATION IN CONDENSATE POLISHER APPLICATIONJames Chen, Belco Pollution Control, Parsippany, New Jersey, and James Nichols, Kansas City Power &Light Company, Lacygne, Kansas, (IWC-82-2) 21

MORNING SESSION "B"Water Reuse

E. Stuart Savage, Session Chairman, Dravo Corporation, Pittsburgh, PennsylvaniaM. L. Mitchell, Session Discussion Leader, Betz Laboratories, Trevose, Pennsylvania

A CASE HISTORY OF ZERO DISCHARGE AT NORTHWEST ALLOYS, INC.Ned P. Swanson, Northwest Alloys, Addy, Washington, and Douglas Austin, Resources ConservationCompany, Seattle, Washington, and F. Mark Sittig, Aluminum Company of America, Pittsburgh,Pennsylvania, (IWC-82-3) 34

ZERO COOLING TOWER DISCHARGE RECENTLY ACHIEVED BY SIDE-STREAM SOFTENINGAT A PETROLEUM REFINERY

Paul R. Puckorius, Teague Harris, Puckorius & Dannenbaum, Evergreen, Colorado, (IWC-82-4) 53

AFTERNOON SESSION "A"Membranes

Joseph M. Loftis, Session Chairman, Ionics, Incorporated, Bridgeville, PennsylvaniaPhilip VanWormer, Session Discussion Leader, E. I. du Pont de Nemours & Company, Wilmington, Delaware

SPIRAL ULTRAFILTRATION: EFFECTIVE AND ECONOMICAL PRETREATMENT OFSEAWATER FOR REVERSE OSMOSIS DESALINATION

Mark F. Hayward and William T. Choate, Abcor, Inc., Wilmington, Massachusetts, (IWC-82-5) 64EXPERIENCES WITH REVERSE OSMOSIS IN BWR RADWASTE TREATMENT

Alex O. Hobbs, and Kenneth Fennell, Carolina Power and Light, Raleigh, North Carolina,(IWC-82-6) 75

OPERATION AND PERFORMANCE OF A REVERSE OSMOSIS SYSTEM TO TREAT STEELPHOSPHATIZING WASTEWATER

A. W. Simon, M. E. Terril, B. A. Burke, U.S. Steel Corporation, Pittsburgh, Pennsylvania,(IWC-82-7) 85

AFTERNOON SESSION "B"Cooling Water

Kenneth Fulks, Session Chairman, Nalco Chemical Company, Oak Brook, IllinoisJames Dromgoole, Session Discussion Leader, Maintenance Engineering, Houston, Texas

THE USE OF SUB-TOXIC LEVELS OF CHLORINE DIOXIDE TO PREVENT SURFACE CONDENSERFOULING IN ONCE-THROUGH SEAWATER COOLING EXCHANGERS

Paul J. Kemp, Midland Research, Laboratory, Inc., Lenexa, Kansas, and Norman Okimoto,Hawaiian Electric Company, Pearl City, Hawaii, (IWC-82-8) 96

POLYMERIC CHELATING AGENTS AS CORROSION INHIBITORS FOR OPEN RECIRCULATINGCOOLING WATER SYSTEMS

Allen E. Feltzin, Hercules, Incorporated, Wilmington, Delaware, (IWC-82-9) 106

A RATIONAL APPROACH TO PROBLEMS OF FOULING DEPOSITIONWilliam G. Characklis, Montana State University, Bozeman, Montana, (IWC-82-10) 119

Papers presented Tuesday, October 26, 1982MORNING SESSION "A"

Corrective Action And Results: PWR Secondary Water Chemistry Systems(Sponsored by ASME)

Wesley L. Pearl, Session Chairman, NWT Corporation, San Jose, CaliforniaWilliam Greenaway, Session Discussion Leader, NUS Corporation, Pittsburgh, Pennsylvania

PWR SECONDARY WATER CHEMISTRY GUIDELINES - AN OVERVIEWJohn A. Mundis, Electric Power Research Institute, Palo Alto, California, (IWC-82-14) 158

PWR STEAM GENERATOR REPLACEMENT AT SURRY 2: PRE- AND POST-OPERATIONAL CHEMISTRYWilliam Thornton, Virginia Electric and Power Company, Richmond, Virginia, (IWC-82-11) 132

FLORIDA POWER AND LIGHT COMPANY'S STEAM GENERATOR PROTECTION PLANAND ITS EFFECT ON WATER CHEMISTRY

Alan J. Gould, Florida Power and Light Company, Miami, Florida, (IWC-82-12) 145ARRESTING OF STEAM GENERATOR TUBE DENTING, SALEM UNIT ONE

Lynn Miller, Salem Nuclear Generating Station, Public Service Electric and Gas,Hancock Bridge, New Jersey, (IWC-82-13) 150

MORNING SESSION "B"Process Control Technology

Joseph L. Beals, Session Chairman, Wallace & Tiernan Div. Pennwalt Corporation, Oak Brook, IllinoisGerald F. Connell, Session Discussion Leader, Capital Controls Company, Colmar, Pennsylvania

OPTIMIZING THE COAGULATION PROCESSRichard F. Jaccarino, Neptune Microfloc Company, Corvallis, Oregon, (IWC-82-15) 169

AN ALTERNATIVE APPROACH TO THE ESTIMATION OF CALCIUM CARBONATE SCALINGTENDENCY IN BLAST-FURNACE RECYCLE WATER

D. A. Lange-Kennedy, and E. L. Mihelic, U.S. Steel Corporation, Pittsburgh, Pennsylvania, and R. G.Luthy, Carnegie-Mellon University, Pittsburgh, Pennsylvania, (IWC-82-16) 178

CONTROLLING CLARIFICATION USING A STREAMING CURRENT DETECTOR (SCD)Jack Adams, Weyerhaeuser, Co., Everett, Washington, and Richard Cardile, and Steve Clark, NalcoChemical Company, Oak Brook, Illinois, (IWC-82-17) 192

IMPACT OF THE PROGRAMMABLE CONTROLLER ON THE INSTRUMENTATION AND CONTROLSFOR WATER TREATMENT

Anthony M. Arnone, The Permutit Company, Paramus, New Jersey, (IWC-82-18) 197

AFTERNOON SESSION "A"Water and Wastewater Treatment

Edward F. Maziarz, Session Chairman, Aluminum Company of America, Pittsburgh, PennsylvaniaLeonard Limon, Session Dicussion Leader, Ecodyne/Graver Water Division, Union, New Jersey

COMBINED ALKALINE/BREAKPOINT CHLORINATION TREATMENT PROCESSLynn A. Kleinvehn, and Harris E. Dicker, Aquatechnics, Inc., Naperville, Illinois, (IWC-82-19) 203

A MODIFIED TEST PROCEDURE FOR PREDICTING POLYMER PERFORMANCE INBELT PRESS SLUDGE DEWATERING

William Lindenberger, and Delmar Prah, Nalco Chemical Company, Naperville, Illinois, (IWC-82-20) 213WASTEWATER AS A PLANT RESOURCE

Terrence J. McManus, Betz * Converse * Murdoch * Inc., Plymouth Meeting, Pennsylvania,(IWC-82-21) 221

REMOVAL OF HIGH LEVELS OF CHLORINATED HYDROCARBONS FROM CONTAMINATEDGROUND WATERS

V. A. Iadavaia, and E. J. Connelley, Havens and Emerson, Inc., Saddle Brook, New Jersey,(IWC-82-22) 232

AFTERNOON SESSION "B"Miscellaneous Progress Reports

David R. Sexsmith, Session Chairman, Drew Chemical Company, Boonton, New JerseyRichard Becklund, Session Discussion Leader, Culligan, U.S.A., Boxford, Massachusetts

THE RELEASE OF CORROSION FROM SURFACES IN THE PRIMARY COOLANT SYSTEMSOF LIGHT-WATER-COOLED REACTORS

W. H. Hocking, Atomic Energy of Canada Limited, Pinawa, Manitoba, Canada and Derek Lister,and E. McAlpine, Atomic Energy of Canada, Ltd., Chalk River, Ontario, Canada, (IWC-82-23) 242

SIMULATION OF PWR PRIMARY CIRCUIT IN HIGH TEMPERATURE LOOPS TO STUDY THEMIGRATION AND DEPOSITION OF CORROSION PRODUCTS

M. Noe, P. Beslu, G. Frejaville, Commissariat a L'Energie Atomique, St. Paul lez Durance, France,(IWC-82-24) 256

PILOT PLANT TESTING OF MAGNETIC FILTERS FOR THE N-REACTOR CIRCUITBlair B. Emory, UNC Nuclear Industries, Inc., Richland, Washington, (IWC-82-25) 307

PRE-OPERATIONAL SUPERHEAT AND REHEAT CHEMICAL CLEANING USING AMONO-AMMONIUM CITRATE SOLVENT

John A. Tassin, Central Louisiana Electric Company, Pineville, Louisiana, and W. E. Stevens,Halliburton Services, Baton Rouge, Louisiana, Robert Baird, Halliburton Services, New Orleans,Louisiana, and Kenneth L. Atwood, Halliburton Services, Gaithersburg, Maryland, (IWC-82-26) 313

COLLOIDAL SILICA REMOVAL TO THE PPB RANGE: A REALITY WITH MIXED MEDIAFILTRATION

Daniel L. Comstock, Neptune Microfloc, Corvallis, Oregon, Robert Guptill, Corvallis, Oregon,and Sallie A. Fisher, Puricons, Inc., Berwyn, Pennsylvania, (IWC-82-27) 328

DEVELOPMENT OF A STEAM QUALITY MONITORING PROGRAM FOR STEAM TURBINESThomas C. Roginski, Betz* Converse *Murdoch* Inc., Plymouth Meeting, Pennsylvania, and Harry B.Gayley, Transamerica Delaval, Trenton, New Jersey, (IWC-82-28) 344

MEASUREMENT OF TRACES OF DISSOLVED OXYGEN IN RADIOACTIVE WATERJohn Hale, Orbisphere Laboratories, Geneva, Switzerland, (IWC-82-29) : 358

Papers presented Wednesday, October 27, 1982MORNING SESSION "A"

Ion ExchangeIrving M. Abrams, Session Chairman, Consultant, Los Altos, California

Henry P. Stoebenau, Session Discussion Leader, Rohm and Haas Company, Philadelphia, PennsylvaniaCO-COUNTER-CURRENT REGENERATION IN ION EXCHANGE SYSTEMS

George J. Crits, W. Y. McIntire, R. D. Zimmerman, Cochrane Environmental Systems,King of Prussia, Pennsylvania, (IWC-82-30) 361

THREE YEARS OF FIELD EXPERIENCE WITH AN ACRYLIC GEL STRONG BASE ANIONEXCHANGE RESIN

Kenneth J. Kozelski, E. I. du Pont de Nemours and Company, Inc., Camden, South Carolina,(IWC-82-31) 373

DEVELOPMENT OF "TWIN STRATA" ION EXCHANGE SYSTEMS BASED ON FIELD EXPERIENCEY. Haraguchi, A. Miyahara, Japan Organo Company Ltd., Tokyo, Japan, (IWC-82-32) 387

SPECIFICATIONS FOR BUYING ION EXCHANGE RESINS, A NECESSITY OR A NUISANCE?Sallie A. Fisher, and Gerard Otten, Puricons, Inc., Berwyn, Pennsylvania, (IWC-82-33) 393

MORNING SESSION "B"What Should aUser of Cooling Water Chemicals Expect from a Chemical Supplier in the Way of Services, Etc.

Panel DiscussionRobert J. Franco, Moderator, Exxon Research & Engineering, Florham Park, New Jersey

Paul Puckorius, Discussion Leader, Puckorius & Associates, Evergreen, ColoradoPanel Members

USER REPRESENTATIVES:James Axsom, Sun Tech, Marcus Hook, Pennsylvania, and Thomas Breske, E. I. du Pont de Nemours & Co ,Wilmington, Delaware, and David Auerswald, Southern California Edison, Paramount, California 404

SUPPLIER REPRESENTATIVES:Gerald Schweitzer, Calgon Corporation, Pittsburgh, Pennsylvania, and David Sexsmith, Drew ChemicalCorporation, Boonton, New Jersey, and Sidney Sussman, Olin Water Services, Stamford, Connecticut 406

AFTERNOON SESSION "A"Boiler Water

Robert D. Scherer, Session Chairman, Duquesne Light Company, Pittsburgh, PennsylvaniaDick Colman, Session Discussion Leader, Bechtel Power Corporation, Norwalk, California

THE USE OF DISPERSANTS FOR REMOVAL OF SLUDGE FROM A NUCLEAR STEAM GENERATORWilliam Lechnick, NUS Corporation, Pittsburgh, Pennsylvania, T. H. Penny, P. T. Thomas, andJ. M. McDowell, Carolina Power and Light, New Hill, North Carolina, (IWC-82-35) 414

CONTROL OF SECONDARY COOLANT CHEMISTRY IN JAPANESE PWR PLANTSTakahisa Hattori, and Hisashi Fujii, Mitsubishi Heavy Industries, Takasago, Japan, and S. H. Peterson,D. F. Pensenstadler, W. M. Hickam, Westinghouse R & D Center, Pittsburgh, Pennsylvania,(IWC-82-36) 422

CHARACTERIZATION AND THERMAL STABILITY OF POLYMERS FOR BOILER TREATMENTWilliam F. Masler, B. F. Goodrich, Avon Lake, Ohio, (IWC-82-37) 434

ORGANIC LEAKAGE AND ITS SOLUTIONKurt Hochmuller, BASF AG, Ludwigshafen/Rhein, Federal Republic of Germany, (IWC-82-38) 447

AFTERNOON SESSION "B"Progress Reports

Carl Hazen, Session Chairman, Chemical Separations Corporation, Oak Ridge, TennesseeCharles H. Eshrich, Session Discussion Leader, Ebasco Services, New York, New York

TRACE METAL ANALYSIS BY ION CHROMATOGRAPHYArthur W. Fitchett, John Riviello, E. L. Johnson, Dionex Corporation, Sunnyvale, California,(IWC-82-39) 458

BARIUM FOULED SULPHONIC-ACID RESINSRicardo Allen, Potomac Electric Power Company, Washington, D.C., (IWC-82-41) 468

REPLACING MULTI-STAGE FLASH WITH REVERSE OSMOSIS DESALINATION PLANTFOR HIGH PRESSURE BOILER FEEDWATER

Earl W. Johansen, Neptune Microfloc, Corvallis, Oregon, and Samuel Paredes Zarate, Federal de Electricadad,Mexicali, Mexico, (IWC-82-42) 480

TREATMENT OF A BLEND OF MAKEUP AND RECIRCULATING COOLING WATER IN ACONVENTIONAL CLARIFIER-SOFTENER SYSTEM - RESULTS OF A PILOT PLANT TEST

J. T. Aronson, Stearns-Roger Engineering Corporation, Denver, Colorado, G. Miller, Public ServiceCompany of Colorado, Denver, Colorado, Winston Chow, Electric Power Research Institute, Palo Alto,California, W. C. Micheletti, Radian Corporation, Austin, Texas, R. V. Long, Stone and WebsterEngineering Corporation, Boston, Massachusetts, (IWC-82-44) 493

RECENT DEVELOPMENTS. AND FIELD EXPERIENCES WITH SOLIDS CONTACT CLARIFIERSUSING HYDRAULIC SLUDGE RECIRCULATION

David Siskind, Ecodyne Corporation, Union, New Jersey, (IWC-82-45) 504

MONDAY THROUGH WEDNESDAYPoster Session

ANION RESIN KINETIC TESTING FOR CONDENSATE POLISHINGJames T. McNulty, and Claude A. Bevan, Rohm and Haas Company, Springhouse, Pennsylvania,(IWC-82-46) 511

TRI-AMMONEX: A NEW METHOD IN THE USE OF INERT RESIN IN CONDENSATE POLISHINGGeorge J. Crits, Cochrane Environmental Systems, King of Prussia, Pennsylvania, (IWC-82-47) 519

IMPROVED BIOLOGICAL DEGRADATION CHLORINATED HYDROCARBONS USINGMUTANT BACTERIA

John A. Christiansen, and J. Paige Straley, Anne L. Kopecky, Sybron/Biochemical, Birmingham,New Jersey, (IWC-82-48) 523

CLEANING AND PASSIVATING COOLING WATER SYSTEMSJesse Beecher, Peter A. Thomas, John Stinger, Drew Chemical Corporation, Boonton, New Jersey,(IWC-82-49) 533

PROBLEMS OBSERVED WITH ION EXCHANGE RESINS IN FIELD OPERATIONBrian J. Hoffman, Rohm and Haas Company, Springhouse, Pennsylvania, (IWC-82-50) 545

ORGANIC COOLING WATER CORROSION CONTROLSharon W. Akin, Zimmite Corporation, Cleveland, Ohio, (IWC-82-51) 554

COMPARISON OF ANION KINETIC LEAKAGE IN MIXED BED OPERATIONAND IN SINGLE COLUMN OPERATION

J. H. Smith, Portals Water Treatment, Permutit-Boby Limited, Isleworth, Middlesex, United Kingdom,(IWC-82-52) 569

THE Conference on

-VPNNW'

Industrial Water



44th ANNUAL MEETING .

October 24, 25 & 26, 1983William Penn Hotel


Robert D. SchererGeneral Chairman

James R. Guseman


Executive Director

Joseph M. Loftis

Mary K. NortonProgram Chairman

Program Coordinator

Sponsored By The

Engineers' Society of Western Pennsylvaniao..w,.,,

INCORPORATED 1880

Rights to reprint articles in this publication are automatically granted provided credit is given the author(s) andauthor(s) company including the statement in a conspicuous place, preferably the first page:

"Reprinted from the Proceedings of the 44th International Water Conference, Pittsburgh, Pa. (USA), October 24,25,26, 1983 (Please advise IWC of the extent of reprint)

0 1983 ENGINEERS' SOCIETY OF WESTERN PENNSYLVANIA

PRINTED BY: ASSOCIATES LITHO, INC.PITTSBURGH. PA 15201

Papers presented Monday, October 24, 1983MORNING SESSION "A"

ORGANICSGerald D. Hansen, Session Chairman, Chemlink, Incorporated, Philadelphia, Pennsylvania

E. Dennis Escher, Session Discussion Leader, NUS Corporation, PEC Division, Pittsburgh, PennsylvaniaDEMINERALIZATION OF A RIVER WATER WITH A HIGH ORGANIC CONTENT

David H. Cameron, London Monenco Consultants Ltd., St. Catherines, Ontario, Canada; Hugh Borland, Derrick L. Brooks,D. Beaudette, Ontario Hydro, Thunder Bay, Ontario, Canada, (IWC-83-1) 1

REMOVAL OF CHLORINATED ORGANICS UTILIZING ROTATING BIOLOGICAL CONTACTORSCharles D. Blumenschein, Robert Helwick, The Chester Engineers, Pittsburgh, Pennsylvania,(IWC-83-2) 10

MORNING SESSION "B"

WASTEWATERE. Stuart Savage, Session Chairman, Dravo Corporation, Pittsburgh, Pennsylvania

James R. Guseman, Session Discussion Leader, U.S. Steel Corporation, Pittsburgh, PennsylvaniaWATER MANAGEMENT AND ADVANCED WASTEWATER TREATMENT FOR WATER-SCARCE SITES

Dale M. Sopocy, Al F. Aschoff, Robert J. Chiesa, Sargent & Lundy Engineers, Chicago, Illinois,(IWC-83-8) 63

CHARACTERIZATION AND TREATMENT OF TRACE METALS IN COAL PILE DRAINAGEKen L. Ogle, Ken Chen, Tennessee Valley Authority, Chattanooga, Tennessee; Roger A. Minear, University of Tennessee,Knoxville, Tennessee, (IWC-83-9) 83

AFTERNOON SESSION "A"

MEMBRANESPhilip Van Wormer, Session Chairman, E.I. Du Pont de Nemours & Company, Houston, Texas

Edward Geishecker, Session Discussion Leader, Ionics, Incorporated, Watertown, MassachusettsHYDROPERM T" CROSS FLOW MICROFILTRATION: A NEW PROCESS FOR THE LIQUID PROCESS INDUSTRY

Daniel Comstock, Joseph A. Millen, Andrew K. Hsiung, Neptune Microfloc, Corvallis, Oregon, (IWC-83-5) 35ULTRAFILTRATION AIDS IN PRODUCTION OF HIGH QUALITY WATER FOR ELECTRONICS MANUFACTURE,A CASE HISTORY

Ray N. Haralson, Western Electric Company, Indianapolis, Indiana; Kenneth E. Johndahl, Osmonics, Incorporated,Minnetonka, Minnesota, (IWC-83-6) 44

STATE-OF-THE-ART OF THE ELECTRODIALYSIS REVERSAL (EDR) PROCESS IN 1983William E. Katz, Ionics, Incorporated, Watertown, Massachusetts, (IWC-83-7) 51

AFTERNOON SESSION "B"

WATER CHEMISTRYPaul Puckorius, Session Chairman, Puckorius & Associates, Evergreen, Colorado

David Simon, Session Discussion Leader, NUS Corporation, Pittsburgh, PennsylvaniaTHE USE OF CORROSION INHIBITOR MECHANISMS IN THE DEVELOPMENT OF PRODUCTS ANDAPPLICATION PROGRAMS

Leonard Freedman, Hercules, Incorporated, Wilmington, Delaware, (IWC-83-3) 17MECHANISM OF SCALE INHIBITION BY PHOSPHONATES

Jasbir S. Gill, Cheryl D. Anderson, Richard G. Varsanik, Calgon Corporation, Pittsburgh, Pennsylvania,(IWC-83-4) 26

OZONE IN HIGH PURITY WATER SYSTEMSCarl Nebel, PCI Ozone Corporation, West Caldwell, New Jersey, (IWC-83-10) 95

Papers presented Tuesday, October 25, 1983MORNING SESSION "A"

COOLING WATERRay Baum, Session Chairman, Craft Products Company, Incorporated, Pittsburgh, PennsylvaniaGerald D. Schweitzer, Session Discussion Leader, Calgon Corporation, Pittsburgh, Pennsylvania

THE USE OF TRIAZINE AS AN ALGAECIDE FOR CIRCULATING COOLING WATERGary R. Tangen, Cooperative Power Association, Underwood, North Dakota; James Chambers, Drew Chemical Corporation,Omaha, Nebraska, (IWC-83-11) 98

APPLICATION OF A NEW ENVIRONMENTALLY ACCEPTABLE COOLING WATER TREATMENTThomas W. Isaac, Alex J. Korvin, Robert S. Klonowski, Wright Chemical Corporation, Schiller Park,Illinois, (IWC-83-12) 105

THEORETICAL AND PRACTICAL CONSIDERATIONS OF PHOSPHONATE OXIDATIONCharles Ebersole, Philip A. Jarvio, Philip A. Hunt Chemical Corporation, Lincoln, Rhode Island,(IWC-83-13) 112

A NEW COMMERCIAL MONOMER FOR USE IN WATER TREATMENT APPLICATIONSWilliam E. Hagstrand, The Lubrizol Corporation, Wickliffe, Ohio, (IWC-83-14) 118

MORNING SESSION "B"

ION EXCHANGE/CONDENSATE POLISHINGLeonard Limon, Session Chairman, Graver Water Conditioning, Union, New Jersey

Paul Cohen, Session Discussion Leader, Consultant, Pittsburgh, PennsylvaniaCONDENSATE POLISHER RESIN LEAKAGE AND RESIN TRANSPORT STUDIES

C.C. Stauffer, S.J. Elmiger, Babcock & Wilcox Company, Alliance, Ohio; P.L. Doss, Babcock & Wilcox Company,Lynchburg, Birginia; C.S. Welty, Jr., Electric Power Research Institute, Palo Alto, California, (IWC-83-15) 125

CONDENSATE POLISHER PERFORMANCE AT THE SURRY NUCLEAR POWER STATIONDavid P. Siegwarth, D.A. McNea, NWT Corporation, San Jose, California; William A. Thornton, Virginia ElectricPower Company, Richmond, Virginia, (IWC-83-16) 141

A UNIQUE ADVANCE IN CONDENSATE POLISHING AT CENTRAL ILLINOIS PUBLIC SERVICE COMPANYCarl Scheerer, Central Illinois Public Service Company, Springfield, Illinois; Eli Salem, Graver Water Divisionof the Graver Company, Union, New Jersey, (IWC-83-17) 151

SAN MIGUEL: A CASE FOR A DRUM BOILER CONDENSATE POLISHING RETROFITEmery Lange, Jr., San Miguel Electric Cooperative, Incorporated, Jourdanton, Texas; Paul Gross, Datum Company,Houston, Texas; Douglas Johnstone, The Graver Company, Union, New Jersey, (IWC-83-18) 166


BOILER WATERSponsored by ASME

Walter Riedel, Session Chairman, Consultant, Baltimore, MarylandArthur W. Fynsk, Session Discussion Leader, E.I. du Pont de Nemours & Co., Wilmington, Delaware

DYNAMIC DEPOSITION AND SOLUBILITY OF SODIUM CHLORIDE IN SUPERHEATED STEAMM. Roidt, S. Manocha, Westinghouse R&D Center, Pittsburgh, Pennsylvania; Otakar Jonas, Jonas, Incorporated,Wilmington, Delaware, (IWC-83-19) 174

IMPROVED CONTROL OF BOILER SCALING AND CORROSION WITH AN ALL-POLYMER INTERNALTREATMENT PROGRAM

J.A. Kelly, M.L. Lin, G.W. Flasch, Nalco Chemical Company, Oak Brook, Illinois, (IWC)-83-20) 194THE BEHAVIOR OF SODIUM, CHLORIDE, AND SULFATE IN PWR SECONDARY CYCLES

Stephen G. Sawochka, Wesley L. Pearl, NWT Corporation, San Jose, California, (IWC-83-21) 249DIETHYLHYDROXYLAMINE FOR CORROSION PROTECTION IN INDUSTRIAL AND UTILITY BOILERS

Dionisio G. Cuisia, Dearborn Chemical Company, Lake Zurich, Illinois, (IWC-83-22) 262


GENERALKenneth Fulks, Session Chairman, Nalco Chemical Company, Oak Brook, Illinois

Samuel B. Dilcer, Session Discussion Leader, Hercules, Incorporated, Wilmington, DelawareGENERIC REACTOR COOLANT HIGH TEMPERATURE ELECTROMAGNETIC FILTRATION SYSTEM FOR PWR PLANTS

Michael Troy, Sam Kang, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania;Michael D. Naughton, Electric Power Research Institute, Palo Alto, California, (IWC-83-23) 272

REVIEWING THE USAGE OF APPLIED-FIELDS IN INDUSTRIAL WATER TREATMENT-WHAT WORKS?WHAT DOES NOT WORK?

Robert S. Reimers, Ann C. Anderson, LuAnn White, Tulane University, New Orleans, Louisiana,(IWC-83-24) 280

A NEW POTABLE WATER RADIUM/RADON REMOVAL SYSTEMRichard E. Rozelle, Dow Chemical Company, Midland, Michigan, (IWC-83-25) 292

COMPUTERIZATION OF GENERATING STATION WATER CHEMISTRY DATA IN THE GPU SYSTEMAlvin N. Hewing, Ray H. Warmkesser, General Public Utilities Service Corporation, Reading,Pennsylvania, (IWC-83-26) 301

Papers presented Wednesday, October 26, 1983MORNING SESSION "A"

ION EXCHANGE TECHNOLOGYH.P. Stoebenau, Session Chairman, Rohm & Haas Company, Philadelphia, Pennsylvania

Irving M. Abrams, Session Discussion Leader, Consultant, Los Altos, CaliforniaPREVENTION OF IRON, ORGANIC, AND MICROBIOLOGICAL RESIN FOULING VIA A NEW CONCEPT INION EXCHANGE MAINTENANCE

A.W. Oberhofer, L.M. May, Nalco Chemical Company, Naperville, Illinois; L.R. Gass, Nalco Chemical Company,Oak Brook, Illinois, (IWC-83-27) 306

SYNCRUDE CANADA LTD'S. FIVE YEARS OPERATING EXPERIENCE WITH CANADA'S LARGEST DEMINERALIZERElizabeth Wilkins, Boyce Tucker, Syncrude Canada, Ltd., Fort McMurray, Alberta, Canada;David Hickling, Ecodyne, Ltd., Oakville, Ontario, Canada, (IWC-83-28) 319

DEVELOPMENT OF ACRYLOBED T", A NEW ANION EXCHANGE RESIN SYSTEM FOR WATER DEMINERALIZATIONA.D. Prunac, E. Zaganiaris, Rohm & Haas European Laboratories, Valbonne, France, (IWC-83-29) 334

PERFORMANCE OF AIR BLOCK COUNTERCURRENT REGENERATION FOR DEMINERALIZATION OFHIGH TDS SURFACE WATER

Sid Wilson, Champlin Petroleum Company, Corpus Christi, Texas; Joseph Zuback, Infilco Degremont,Incorporated, Richmond, Virginia, (IWC-83-30) 343

MORNING SESSION "B"

MONITORING, CONTAINMENT AND TREATMENT OF GROUNDWATER(PANEL)

Walter Zabban, Session Chairman, The Chester Engineers, Pittsburgh, PennsylvaniaGROUNDWATER MONITORING AND RESPONSE PROGRAM

C.J. Touhill, A.P. Pajak and A.J. Shuckrow, Baker/TSA Division, Michael Baker, Jr., Inc.,Beaver, Pennsylvania, (IWC-83-31) 355

SUBSURFACE CUT-OFF WALLS: DESIGN CONSIDERATIONS IN THEIR APPLICATION TOGROUNDWATER RECOVERY PROGRAMS

Robert D. Mutch, Jr., Wehran Engineering, Middleton, New York, (IWC-83-32) 361SYNTHETIC LININGS FOR POLLUTION CONTROL

Charles E. Staff, Staff Industries, Incorporated, Upper Montclair, New Jersey, (IWC-83-33) 369AIR STRIPPING OF ORGANICS

R.P. Helwick and C.D. Blumenschein, The Chester Engineers, Coraopolis, Pennsylvania, (IWC-83-34) 372MONITORING, CONTAINMENT, AND TREATMENT OF GROUNDWATER: INTRODUCTION AND CONCLUSION

Walter Zabban, The Chester Engineers, Pittsburgh, Pennsylvania, (IWC-83-35) 378


PROGRESS REPORTS/ION EXCHANGERalph Mickel, Session Chairman, Allegheny Power Service Corporation, Greensburg, Pennsylvania

FACTORS AFFECTING THE PERFORMANCE OF CONDENSATE POLISHING PLANTSJ.R. Emmett, A. Hebbs, NEI Thompson Ltd., Kennicott Water Treatment, West Midlands,England, (IWC-83-36) 380

COLLOIDAL SILICA REMOVAL WITH ION EXCHANGE RESIN AT MILLIKEN STATIONFrank P. Roma, New York Electric & Gas Company, Binghamton, New York; Frank X. McGarvey,Sybron Corporation/lonac Division, Birmingham, New Jersey; William S. Miller, Ecolochem, Incorporated,Norfolk, Virginia; Thomas M. Isert, Gilbert Associates, Reading, Pennsylvania, (IWC-83-37) 388

DEEP BED COUNTERCURRENT CATIONSJohn Farrar, Joseph H. Smith, Portals Water Treatment, Ltd., Isleworth, Middlesex,United Kingdom, (IWC-83-38) 395

REMOVAL OF ORGANICS FROM UTILITY AND INDUSTRIAL WATERSJoseph F. Giannelli, Graver Water and Graver Chemical Divisions of the Graver Company,Union, New Jersey, (IWC-83-39) 400

THE EFFECT OF BEAD SIZE AND HYDRATED BEAD DENSITY ON THE SEPARABILITY OF MIXED BEDSSallie Fisher, Gerard Otten, Puricons, Incorporated, Berwyn, Pennsylvania, (IWC-83-40) 409

POTENTIAL OF WEAK-ACID CATION RESINS IN AMMONIATED CONDENSATE SYSTEMSHoward L. Simpson, Water Treatment Consultant, Cupertino, California; Charles A. Sauer,Duolite International, Inc., Redwood City, California; Robert A. Anderson, Ion Exchanger Consultant,Sunnyvale, California, (IWC-83-41) 417

ION EXCHANGE OF MIXED RADWASTEGregory R. Allan, Consultant, Bellevue, Washington, (IWC-83-42) 424


PROGRESS REPORTS/ANALYTICALJudith Rawa, Session Chairman, Calgon Corporation, Pittsburgh, Pennsylvania

APPLICATION OF TOC ANALYZER TO THE PPB-LEVEL MEASUREMENT OF CO2 TRAPPED INAMMONIATED STEAM CONDENSATE

Robert J. Joyce, Yoshihiro Takahashi, Dohrmann Division of Xertex Corporation, Santa Clara,California; Louis F. Wirth, Consultant, Midland, Michigan, (IWC-83-43) 430

ORGANIC ACIDS IN STEAM CONDENSATE BY ION EXCLUSION CHROMATOGRAPHYW. Arthur Byers, W.M. Hickam, S.L. Anderson, Westinghouse Research & Development Center,Pittsburgh, Pennsylvania, (IWC-83-44) 436

A RAPID METHOD FOR MONITORING MICROBIAL FOULING IN INDUSTRIAL COOLING WATER SYSTEMSLinda Young-Bandala, Dearborn Chemical Company, Lake Zurich, Illinois; Ralph J. Kajdasz,Dearborn Chemical Company, Nashville, Tennessee, (IWC-83-45) 442

FIELD EXPERIENCE WITH A SIMPLE COOLING WATER BIOFILM MONITORING DEVICEKenneth J. Kozelski, E.I. du Pont de Nemours & Co., Inc., Camden, South Carolina, (IWC-83-46) 447

ANALYSIS OF CALCIUM AND MAGNESIUM IN EFFLUENTS CONTAINING HIGH SALT LEVELSBY EMISSION SPECTROSCOPY

Gerhard A. Meyer, Robert R. Frable, Dow Chemical, U.S.A., Midland, Michigan, (IWC-83-47) 455A NEW DISSOLVED HYDROGEN DETECTOR

John Hale, Orbisphere Laboratories, Geneva, Switzerland, (IWC-83-48) 460A NEW AMINIC VOLATILE DEOXIDIZING CONDITIONING PRODUCT ALTERNATIVE TO HYDRAZINE

Marcello Bartoletti, R. Dona, S.P.A., Milan, Italy, (IWC-83-49) 466

THE Conference

'ga'r.

on

^

,

Industrial Water



45th ANNUAL MEETING

October 22, 23, & 24, 1984

Pittsburgh,William

Pennsylvania,Penn Hotel

U.S.A.

James R. GusemanGeneral Chairman

Joseph M. Loftis


Executive Director

Michael C. Skriba

Mary NortonProgram Chairman

Program Coordinator

Sponsored By The

Engineers' Society of Western Pennsylvaniapr w lsr..

^

i

y5. .•'fs .arc

INCORPORATED 1880

Rights to reprint articles in this publication are automatically granted provided credit is given the author(s) andauthor(s) company including the statement in a conspicuous place, preferably the first page:

"Reprinted from the Proceedings of the 45th International Water Conference, Pittsburgh, Pa. (USA), October 22, 23,24, 1984. " (Please advise IWC of the extent of reprint.)

©1984 ENGINEERS' SOCIETY OF WESTERN PENNSYLVANIA

PRINTED BY: ASSOCIATES LITHO, INC.PITTSBURGH, PA 15201

Papers presented on Monday, October 22, 1984MORNING SESSION "A"

COMPUTER APPLICATIONS TO WATER CHEMISTRY CONTROLPaul Goldstein, Session Chairman, NUS Corporation, Pittsburgh, Pennsylvania

COMPUTER-AIDED POWER PLANT CHEMISTRY EVALUATIONLeyon 0. Brestel, Duane K. Nelson, Colorado-Ute Electric Association, Montrose, Colorado, (IWC-84-6) 1

AN ARTIFICIAL INTELLIGENCE CHEMISTRY DIAGNOSTIC SYSTEMJames C. Bellows, Westinghouse Steam Turbine-Generator Division, Orlando, Florida, (IWC-84-80) 15

MORNING SESSION "B"

GROUNDWATERAndrew F. McClure, Session Chairman, PEC Division, NUS Corporation, Pittsburgh, PennsylvaniaClarence D. Colley, Session Discussion Leader, Hewlett-Packard Company, Palo Alto, California

EXAMPLES OF GROUNDWATER CONTAINMENT STRATEGIES NEW AND REMEDIAL WORKChristopher R. Ryan, Geo-Con, Incorporated, Pittsburgh, Pennsylvania, (IWC-84-112) 26

DESIGN AND OPERATION OF A 3,500-GPM AIR STRIPPING SYSTEM FOR VOC REMOVALBob Rosain, Chet Morton, CH2M Hill, Bellevue, Washington, (IWC-84-44) 35


MEMBRANE TECHNOLOGYWilliam E. Katz, Session Chairman, Ionics, Incorporated, Watertown, Massachusetts

Frederick H. Flor, Jr., Session Discussion Leader, Rohm & Haas Company, Philadelphia, PennsylvaniaHYDROPERM LIME SOFTENING-A CASE HISTORY

Lorne Gramms, Urban Systems, Ltd., Calgary, Alberta; Daniel Comstock, Doug Hagen, NeptuneMicrofloc, Inc., Corvallis, Oregon, (IWC-84-26) 41

ELECTRODIALYSIS REVERSAL UNIT USED AS PRE-DEMINERALIZER IN BOILER FEEDWATER TREATMENTMike Mansouri, Amoco Chemicals Corporation, Alvin, Texas, (IWC-84-53) 54

PERFORMANCE STUDY OF A SEMICONDUCTOR HIGH PURITY WATER SYSTEM USINGADVANCED FILTRATION TECHNOLOGIES

Chris Mistry, Jerry Gililland, Andy Koutalides, Hewlett Packard, CID, Cupertino, California;Rosalie Mandaro, Mandaro Associates, Wallingford, Connecticut, (IWC-84-91) 65


INSTRUMENTATION/ANALYTICAL TECHNIQUESJudith Ann Rawa, Session Chairman, Calgon Corporation, Pittsburgh, Pennsylvania

James N. Tanis, Session Discussion Leader, Aquatec Comercial, Ltda., Sao Paulo, BrazilSULFITE DEGRADATION AND APPARENT TURBINE ROTOR CORROSION

Mark Brayden, Reuben Barber, Hayes Barnett, Harold Chagnard, Dow Chemical, U.S.A.,Plaquemine, Louisiana, (IWC-84-21) 78

BIOCIDAL EFFICACY WITH' RESPECT TO SESSILE AND PLANKTONIC ORGANISMSRalph J. Kajdasz, R.V. Einstman, Dearborn Chemical Company, Nashville, Tennessee;Linda Young-Bandala, Dearborn Chemical Company, Lake Zurich, Illinois, (IWC-84-60) 85

THE WESTINGHOUSE OXYGEN PROBE-A NEW MONITOR FOR STEAMWilliam M. Hickam, P.K. Lee, W.E. Snyder, Westinghouse R&D Center, Pittsburgh, Pennsylvania, (IWC-84-81) 94

Papers presented on Tuesday, October 23, 1984MORNING SESSION "A"

ION EXCHANGELouis F. Wirth, Session Chairman, Louis F. Wirth, Inc., Midland, Michigan

Peter L. Tremont, Session Discussion Leader, Monsanto Corporation, St. Louis, Missouri50 YEARS IN SEPARATE BEDS

J.H. Smith, Portals Water Treatment Ltd., Isleworth, United Kingdom;P.W. Renouf, The Permutit Company of Australia, Ltd., Brookville, Australia;M. Crossen, L*A Water Treatment, City of Industry, California, (IWC-84-86) 105

PROCESS AND CONTROL MODIFICATIONS OF A MAKE-UP DEMINERALIZER SYSTEMCheryl O. Malhiet, Cajun Electric Power Cooperative, Baton Rouge, Louisiana;Henry Bydalek, Ebasco Services, Inc., Norcross, Georgia, (IWC-84-15) 115

DESIGN AND OPERATION OF CONTINUOUS ION EXCHANGE PROCESS FORTREATING URANIUM MINE WATER

C. Palmer, Cotter Corporation, Lakewood, Colorado; A. Himsley, J.A. Bennett,Himsley Engineering Ltd., Toronto, Canada, (IWC-84-23) 125

MAKEUP DEMINERALIZATION WITH AN ORGANIC SCAVENGER/MONOBED SYSTEMHugh H. Harper, Jr., David L. Drummonds, Southern Company Services, Inc.,Birmingham, Alabama, (IWC-84-105) 131

MORNING SESSION "B"

COOLING WATERJames C. Dromgoole, Session Chairman, Maintenance Engineering Corporation, Houston, Texas

Sam Dilcer, Session Discussion Leader, Hercules, Incorporated, Wilmington, DelawareA PROGRAM FOR REVIEW AND SELECTION OF WATER TREATMENT SUPPLIERS

Timothy E. Keister, Brockway, Inc., Brockway, Pennsylvania, (IWC-84-35) 142BIOCONTROL-KEY TO HEAT EXCHANGER EFFICIENCY IN GRAIN ALCOHOL PLANT

Jack Freund, Midwest Solvents Company, Inc., Atchison, Kansas; James M. Booker, William J. Ward,Midland Research Laboratories, Lenexa, Kansas, (IWC-84-49) 149

SUGGESTED GUIDELINES FOR LAYING UP IDLE EQUIPMENT IN COOLING SYSTEMSTom Gale, Ashland Petroleum Company, Ashland, Kentucky; Jesse Beecher, Drew Chemical Corporation,Boonton, New Jersey, (IWC-84-2) 156

AN AUTOMATIC INSTRUMENT FOR MEASURING SCALE GROWTH IN COOLING WATER SYSTEMSDouglas K. Bender, C.M. Finley, Rohrback Cosasco Systems, Santa Fe Springs, California, (IWC-84-108) 166


ION EXCHANGEDavid A. Jayes, Session Chairman, Rohm & Haas Company, Philadelphia, Pennsylvania

Irving M. Abrams, Session Discussion Leader, IMA Consultants, Los Altos, CaliforniaEVALUATION OF UNIFORM MESH ION EXCHANGE RESINS FOR CONDENSATE POLISHING

Michael D. Mayne, Dow Chemical Company, Freeport, Texas; Jack B. Prentiss, Central Power and Light CompanyCorpus Christi, Texas, (IWC-84-43) 179

THE HYDRAULIC PROPERTIES OF ION EXCHANGE RESINSFrank X. McGarvey, E.W. Hauser, B. Kiefer, Sybron Chemicals, Inc., Birmingham, New Jersey, (IWC-84-103) 194

CATIONIC POLYELECTROLYTE FOULING OF CATION EXCHANGE RESINSDavid I. Devore, Betz Laboratories, Inc., Trevose, Pennsylvania, (IWC-84-73) 253


PROGRESS REPORTS (GENERAL)Gerald F. Connell, Session Chairman, Capital Controls Company, Colmar, Pennsylvania

QUALIFICATION OF ANALYTICAL METHODS FOR MONITORINGSTEAM ELECTRIC POWER PLANT AQUEOUS DISCHARGES

James K. Rice, Consulting Engineer, Olney, Maryland; Ray F. Maddalone, Energy Technology Division,TRW, Inc., Redondo Beach, California; Winston Chow, Electric Power Research Institute,Palo Alto, California, (IWC-84-9) : 263

MAGNETIC WATER TREATMENT DEVICES-THE RESULTS OF A UNIVERSITY STUDYKenneth W. Busch, Ralph E. Darling, Marianna Busch, James L. McAtee, Deborah Parker,Baylor University, Waco, Texas, (IWC-84-10) : 270

TRACE ELEMENT REMOVAL BY ADSORPTION/COPRECIPITATION ON AMORPHOUS IRON OXYHYDROXIDEDouglas T. Merrill, Brown and Caldwell, Walnut Creek, California; Winston Chow, Electric Power Research Institute,Palo Alto, California; James 0. Leckie, Stanford University, Stanford, California, (IWC-84-54) 279

PILOT PLANT STUDY TO TREAT PRIORITY POLLUTANTS IN COAL PILE DRAINAGEKen Chen, Robert D. Moss, Ken L. Ogle, Tennessee Valley Authority, Chattanooga, Tennessee, (IWC-84-56) 284

EFFICACY AND DECOMPOSITION OF DBNPA IN TWO COOLING SYSTEMSAmanda K. Meitz, Mogul Corporation, Chagrin Falls, Ohio, (IWC-84-50) 293

COLORIMETRIC DETERMINATION OF TRACE BENZOTRIAZOLE OR TOLYLTRIAZOLEDanial L. Harp, Hach Company, Loveland, Colorado, (IWC-84-13) 299

Papers presented on Wednesday, October 24, 1984MORNING SESSION "A"

ASME SESSIONWATER CHEMISTRY GUIDELINES FOR LARGE STEAM GENERATING POWER PLANTS

Wesley L. Pearl, Session Chairman, NWT Corporation, San Jose, CaliforniaPaul Cohen, Session Discussion Leader, Consultant, Pittsburgh, Pennsylvania

WATER CHEMISTRY GUIDELINES FOR BWRSWarren J. Bilanin, Robin L. Jones, Charles S. Welty, Jr., Electric Power Research Institute,Palo Alto, California, (IWC-84-114) : 302

BOILER AND FEEDWATER STANDARDS IN FOSSIL AND NUCLEAR PLANT OPERATED BY THE C.E.G.B.K. Tittle, Central Electricity Generating Board, Manchester, England, (IWC-84-115) 311

VGB GUIDELINES ON BOILER FEEDWATER, BOILER WATER AND STEAM OF WATER-TUBE BOILERSDr. Albert Bursik, Grosskraftwerk Mannheim AG, Mannheim, Federal Republic of Germany, (IWC-84-116) 319

PWR SECONDARY WATER CHEMISTRY GUIDELINES: REVISION IC.S. Welty, Jr. and S.J. Green, Electric Power Research Institute, Palo Alto, California, (IWC-84-113) 325

MORNING SESSION "B"

WASTEWATER TREATMENTRussell C. Vandenberg, Session Chairman, Resources Conservation Company, Seattle, WashingtonTheodore J. Caridis, Session Discussion Leader, PCF Sales Corporation, Pittsburgh, Pennsylvania

LESSONS LEARNED FROM THE USE OF ION EXCHANGE FOR WASTEWATER TREATMENTWilliam E. Moore, Monsanto Chocolate Bayou, Alvin, Texas; Peter L. Tremont, Monsanto Central Engineering,St. Louis, Missouri, (IWC-84-96) 332

APPLICATION OF INNOVATIVE TECHNOLOGIES TORECLAIM HIGH QUALITY SEMI-CONDUCTOR RINSE WATERS

Peter S. Cartwright, C3 International, Inc., Roseville, Minnesota, (IWC-84-76) 344SEWER PLANT EFFLUENT-A USABLE SOURCE OF COOLING TOWER MAKEUPFOR POWER PLANT OPERATIONS

Norman D. Fahrer, ChemTreat, Inc., Ashland, Virginia; Shuler W. Massey, Vero Beach Utilities,Vero Beach, Florida, (IWC-84-18) 349


BOILER WATER CONDITIONINGGerald D. Hansen, Session Chairman, ChemLink, Incorporated, Philadelphia, PennsylvaniaDonald E. West, Session Discussion Leader, Garratt-Callahan Company, Millbrae, California

FIELD EXPERIENCES WITH SULPHONATED STYRENE COPOLYMERS FORON-LINE BOILER DESCALING IN SOUTH AFRICA

I.R. Gibson, Industrial Water Management, Pty., Johannesburg, South Africa;C.M. Hwa, Dearborn Chemical Company, Lake Zurich, Illinois, (IWC-84-39) 361

REDUCTION OF OXYGEN WITH HYDROGEN AT AMBIENT TEMPERATURE USINGLEWATIT OC-1045 CATALYST-A POTENTIAL OXYGEN CONTROL METHOD FOR WATER SYSTEMS

S. Gregory de Silva, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania;Alexander J. Siber, Mobay Chemical Corporation, Pittsburgh, Pennsylvania, (IWC-84-93) 375

STUDIES OF TWO-PHASE EROSION-CORROSION USINGTHE C.E.G.B. NORTHWEST REGION BOILER RIG

M.J. Fountain, G.S. Harrison, D. Penfold, J.C. Greene, M.A. Walker, Central Electricity Generating Board,Manchester, England, (IWC-84-109) 393


PROGRESS REPORTS (ION EXCHANGE/COMPUTER)Michael C. Skriba, Session Chairman, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania

"EXTRACTABLES" IN NEW RESINS: A CRITICAL LOOK ATTHE HOW, WHAT AND WHY OF THEIR MEASUREMENT

Sallie A. Fisher, Gerard Otten, Puricons, Inc., Berwyn, Pennsylvania, (IWC-84-70) 402PROGRESS IN THE DETECTION AND ELIMINATION OF POWDERED RESIN LEAKAGEFROM CONDENSATE POLISHING SYSTEMS

John Longo, Graver Chemical Division of the Graver Company, Union, New Jersey, (IWC-84-42) 407REDUCTION OF CONDENSATE CLEANUP TIME FOR SUPERCRITICAL UNITS

Benjamin Nonaka, Dale Liao, Department of Water and Power, City of Los Angeles,Long Beach, California, (IWC-84-71) 414

FOUR YEARS OPERATING EXPERIENCE WITH A 3,000 GPM COUNTERFLOW MAKEUPDEMINERALIZATION SYSTEM TREATING MISSISSIPPI RIVER WATER

M.B. Yeligar, Permutit Company, Inc., Paramus, New Jersey; Jim Smith, Shell Oil Company, Norco, Louisiana;Dan Setaro, Betz Laboratories, Metairie, Louisiana, (IWC-84-33) 419

COMPUTER MODELING OF COOLING WATER CHEMISTRYRory R. Musil, Hugo J. Nielsen, Sargent & Lundy Engineers, Chicago, Illinois, (IWC-84-104) 428

EFFECTIVE CONDENSATE SYSTEM ANALYSIS THROUGH COMPUTER MODELINGM. Linda"Lin, Brian V. Jenkins, Nalco Chemical Company, Oak Brook, Illinois, (IWC-84-20) 438

PRINTED BY: ARTCRAFTS UNLIMITED, INC.PITTSBURGH, PA 15206




46th ANNUAL MEETING

November 4, 5, 6 & 7, 1985Hilton Hotel


Joseph M. LoftisGeneral Chairman

E. Peter Benzing


Executive Director

Michael C. Skriba

Mary NortonProgram Chairman

Program Coordinator

Sponsored By The

Engineers'. Society of Western Pennsylvania

INCORPORATED 1880


"Reprinted from the Proceedings of the 46th International Water Conference, Pittsburgh, Pa. (USA), November 4,5,6,7, 1985."'(Please advise 1WC of the extent of reprint.)

© ENGINEERS' SOCIETY OF WESTERN PENNSYLVANIA

Papers presented on Monday, November 4, 1985

MORNING SESSION "A"

ORGANICS IN ION EXCHANGEOtakar Jonas, Session Chairman, Jonas, Inc., Wilmington, Delaware

Frank McGarvey, Session Discussion Leader, Sybron Chemicals,lnc., Birmingham, New JerseyREMOVAL OF ORGANICS FROM SECONDARY MAKEUP WATER

S. L. Wiser, Virginia Electric and Power Company, Richmond, Virginia; Y.H. Lee, C.R. Stroh, Sargent & Lundy,Chicago Illinois; M. O'Brien, The Graver Company, Union, New Jersey, (IWC-85-1) 1

WHAT REALLY HAPPENS TO ORGANICS IN THE WATER TREATMENT SYSTEM PART II: THE FATE OFORGANICS IN THE ANION EXCHANGE CYCLE

Sallie Fisher, Gerard Otten, Puricons, Inc., Berwyn, Pennsylvania (IWC-85-2) 18

MORNING SESSION "B"

GROUNDWATER

Clarence D. Colley, Session Chairman, Hewlett-Packard Company, Palo Alto, CaliforniaStanley D. Heden, Session Discussion Leader, Eimco Process Equipment, Salt Lake City, Utah

WHEN HAZARDOUS WASTE THREATENS THE GROUNDWATERChristopher R. Ryan, Geo-Con, Inc., Pittsburgh, Pennsylvania, (IWC-85-3) 30

APPLICATIONS OF ADVANCED MEMBRANE FILTRATION TO INDUSTRIAL WASTEWATER TREATMENT ANDGROUNDWATER CLEAN-UP

Erich W. Tiepel, Resource Technologies Group, Inc., Denver, Colorado; Jacob Shorr,Memtek Corporation, Woburn, Massachusetts, (IWC-85-4) 35


ION EXCHANGE I

Henry P. Stoebenau, Session Chairman, Rohm & Haas Company, Philadelphia, PennsylvaniaRonald G. Byers, Session Discussion Leader, Dow Chemical Company, Midland, Michigan

EXPERIENCES WITH A CO-COUNTER-CURRENT REGENERATION SYSTEM AT THE AVON LAKE STATIONGeorge P. Baker, Cleveland Electric Illuminating Co., Cleveland, Ohio; George J.Crits, Cochrane Environmental Systems, King of Prussia, Pennsylvania, MC-85 .6) 53

THE MULTISTEP SYSTEM, A FLEXIBLE ARRANGEMENT FOR WATER TREATMENT WITH ION EXCHANGE RESINSFriedrich B. Martinola, Gerfried Wutte,Bayer AG, Leverkusen, West Germany, (IWC-85-7) 66

GEL VS. MACROPOROUS RESINS FOR HIGH RATE DEMINERALIZATION ON A HIGH ORGANIC WATERT.K. Copolo, Carolina Power & Light Co., Roxboro, North Carolina; H.A. Schlesinger,Gibbs & Hill, Inc., New York, New York (IWC-85-8) 76


IN PLANT INSTRUMENTATION/ANALYTICALGerald Connell, Session Chairman, Capital Controls Company, Colmar, Pennsylvania

William J. Herbert, Session Discussion Leader, JM Chemical Feed & Control Systems, Ivyland, PennsylvaniaEVALUATION OF A REACTOR COOLANT DISSOLVED HYDROGEN MONITOR FOR PRESSURIZED WATER REACTORS

G.L. Ward, Duke Power Company, Charlotte, North Carolina, (IWC-85-10) 82OPERATING EXPERIENCE WITH THE DETECTION OF UTILITY BOILER WATER QUALITY PROBLEMS UTILIZINGBOILING WATER CATION CONDUCTIVITY

Michael G. Cashin, Central Illinois Public Service Co., Springfield, Illinios (IWC-85-11)

91

Papers presented on Tuesday, November 5, 1985

MORNING SESSION "A"

ION EXCHANGE IIGeorge Crits, Session Chairman, Cochrane Environmental Systems, King of Prussia, Pennsylvania

Irving M. Abrams, Session Discussion Leader, IMA Consultants, Los Altos, CaliforniaTHE TRIPOL CONDENSATE PURIFICATION PROCESS

Malcolm Ball, Robert J. Burrows, Central Electricity Generating Board, Nottingham, England (IWC-85-12) 112CONDENSATE POLISHER EXPERIENCES RECENTLY ENCOUNTERED IN CONVERSION TO AVT ENVIRONMENTAND THE USE OF INERT RESIN AT CAROLINA POWER & LIGHT

John'E. Kristensen, Harry G. Hartjen, Ebasco Services, Incorporated, Lyndhurst, New Jersey, (IWC-85-13) 122

EVALUATION OF WEAK ELECTROLYTE RESINS FOR APPLICATIONS IN A MIXED RESIN SYSTEMJames A. Mathews, Duke Power Company, Charlotte, North Carolina (IWC-85-5) 44

A NEW GKM APPROACH TO MAKEUP WATER TREATMENT AND CONDENSATE POLISHINGAlbert Bursik, Grosskraftwerk Mannheim AG, Mannheim, West Germany, (IWC-85-15) 136

MORNING SESSION "B"

ASME ' SESSION - FOSSIL PLANT WATER TREATMENTWilliam Greenaway, Session Chairman, NUS Corporation, Pittsburgh, Pennsylvania

James K. Rice, Session Discussion Leader, James K. Rice Company, Olney, MarylandVANADIUM REMOVAL FROM OIL-FIRED POWER PLANT WASTEWATERS

Hans W. Schick, Central Hudson Gas & Electric Corporation, Poughkeepsie, New York;Robert M. Rosain, Ch2M Hill, Bellevue, Washington, (IWC-85-16) 145

EPRI'S INTERIM CONSENSUS GUIDELINES ON FOSSIL PLANT CYCLE CHEMISTRYDale M. Sopocy, A.F. Aschoff, Sargent & Lundy Engineers, Chicago, Illinios; R. B. Dooley,Electric Power Research Institute, Palo Alto, California; Otakar Jonas, Jonas, Inc.,Wilmington, Delaware, (IWC-85-17) 153

WATER-RELATED INTERNAL PROBLEMS IN ASH TRANSPORT SYSTEMSPhilip A. Barker, Nalco Chemical Company Oak Brook, Illinois; Thomas Fitzsimmons,Basin Electric Power Cooperative, Bismarck, North Dakota; Wayne C. Michaletti, Electric Power ResearchInstitute, Palo Alto, California, (IWC-85-18) 187

EVOLUTION OF A WASTEWATER TREATMENT SYSTEM FOR PROCESSING SCRUBBER BLOWDOWNAND CHEMICAL PLANT DISCHARGES AT A COAL-FIRED GENERATION STATION

G.L. Wilson, J.C. Nowak, T.M. O'Neail, Resources Conservation Co., Bellevue, Washington, (IWC-85-19) 196


ION EXCHANGE - PROGRESS REPORTSJames D. Shivers, Session Chairman, L*A Water Treatment, Industry, California

A PROGRESS REPORT ON THE APPLICATION OF WEAKLY ACIDIC CATION EXCHANGE RESINS INCONDENSATE POLISHING

Michael O'Brien, Robert Kunin, George C. Flynn, Graver Water Division, Union, New Jersey, (IWC-85-20) 207PROGRESS IN THE REMOVAL OF ORGANICS PRESENT IN UTILITY WATER SYSTEMS

Ligaya S. Hartjen, Graver Water Division, Union, New Jersey; William M. Cain,Carolina Power & Light Company, Southport, North Carolina, (IWC-85-22) 217

RADWASTE ION-EXCHANGE OPTIMIZATIONN.P. Jacob, E. Morgan, J.M. Storton, J.F. Kramer, Babcock & Wilcox, Lynchburg, Virginia;J.P. Kangley, Millstone Nuclear Station, Waterford, Connecticut; M.D. Naughton, Electric Power ResearchInstitute, Palo Alto, California, (IWC-85-23) 227

EFFECTS OF COAGULANT OVERDOSE IN CLARIFIERS ON DOWNSTREAM ION EXCHANGE PROCESSESL.M. May, W.M. Carlson, Nalco Chemical Company, Naperville, Illinois, (IWC-85-24) 235

THE USE OF AN INORGANIC GLASSY CATION EXCHANGER FOR THE PURIFICATION OF NUCLEAR WASTE STREAMSAa. Barkaat, K. A. Michael, W. Sousanpour, Al. Barkatt, L.M. Penafiel, B.P. MacedoThe Catholic University of America, Washington, D.C.; H.G. Sutter, Duratek Corporation,Greenbelt, Maryland, (IWC-85-25) 240


INSTRUMENTATION/ANALYTICAL PROGRESS REPORTSRussell W. Lane, Session Chairman, Consultant, Champagne, Illinois

ANALYSIS OF ETHYLENEDIAMIN gTETRAACETIC ACID IN BOILER WATER BY HIGH PRESSURE LIQUIDCHROMATOGRAPHY

Kathleen A.S. Hardy, John C. Cooper, Naval Research Laboratory, Washington, D.C.'Thomas K. Ayres, Walter E. Rudzinski, Southwest Texas State University, San Marcos,Texas, (IWC-85-26) 245

EVALUATION AND APPLICATIONS OF A NEW DISSOLVED HYDROGEN MONITOROtakar Jonas, Jonas, Inc., Wilmington, Delaware; S.C. Smith, ChemLink, Inc., Cherry Hill,New Jersey; R.W. Bradshaw, Combustion Engineering, Windsor, Connecticut; J.P. Gibeault,Manleh Engineering, Rouses Point, New York, (IWC-85-27) 250

WATER CHEMISTRY STUDIES AT THE SEQUOYAH NUCLEAR PLANT USING AN ONLINE IONCHROMATOGRAPHIC ANALYZER

Curt Blair, Tennessee Valley Authority, Chattanooga, Tennessee; Jim Mullenix, Johnny Barker,Tennessee Valley Authority, Soddy Daisy, Tennessee; Lani Angers, Dionex Corporation,Sunnyvale, California (IWC-85-28) 305

ASTM POWER PLANT WATER ANALYSIS MANUALW.E. Allmon, S.J. Potterton, The Babcock & Wilcox Company, Alliance, Ohio;S.I. Lerman, Consolidated Edison of New York, Astoria, New York, (IWC-85-29) 311

Papers presented on Wednesday, November 6, 1985

MORNING SESSION "A"

MEMBRANESFred Flor, Session Chairman, Rohm & Haas Company, Philadelphia, Pennsylvania

Abdalla M. Ahmed, Session Discussion Leader, E.I. du Pont de Nemours & Company, Kennett Square, PennsylvaniaCOMMERCIAL PRODUCTION OF ULTRAPURE WATER BY FULLY-AUTOMATIC TRIPLE-MEMBRANE(UF/EDR/RO) DEMINERALIZERS

William E. Katz, Frederick G. Clay, Ionics, Incorporated, Watertown, Massachusetts,(IWC-85-30) 315

ED: POLARITY REVERSAL OR NOT?Paul A. Foster, Michael J. Rowe, John B. Farrar, Portals Water Treatment, Isleworth,United Kingdom, (IWC-85-31) 330

PARAMETRIC STUDY OF THIN-FILM COMPOSITE POLYAMIDE-TYPE REVERSE OSMOSIS MEMBRANESYaw C. Yang, J.M. Dickson, McMaster University, Ontario, Canada, (IWC-85-32) 342

MORNING SESSION "B"

COOLING WATERJesse Beecher, Session Chairman, Consultant, Drew Chemical Division Ashland, Boonton, New Jersey

Richard W. Lutey, Session Discussion Leader, Buckman Laboratories, Memphis, TennesseeZERO SLOWDOWN BY SIDESTREAM SOFTENING ON COOLING SYSTEMS OF BASE LOAD UNITS

Bob L. Proctor, Chester M. Malewski, Sierra Pacific Power Company, Reno, Nevada, (IWC-85-33) 350ON STREAM IRON REMOVAL IN COOLING SYSTEMSGary G. Engstrom, Vincent Kuhn, Dearborn Chemical Company, Lake Zurich, Illinois, (IWC-85-34) 360

COOLING WATER PRODUCT EVALUATION AND SELECTION: A CASE STUDYBrian R. Ohler, Public Service Company of New Mexico, Farmington, New Mexico; WilliamR. Hollingshad, Calgon Corporation, Pittsburgh, Pennsylvania,.(IWC-85-35) 367

THE INVESTIGATION AND APPLICATION OF OZONE FOR COOLING WATER TREATMENTLeroy V. Baldwin, Ellen S. Feeney, EG&G Florida, Inc., Kennedy Space Center, Florida;Rick Blackwelder, NASA, Kennedy Space Center, Florida, (IWC-85-36) 375


PROGRESS REPORTS - GENERALGerald D. Hansen, Session Chairman, ChemLink, Inc., Newton Square, Pennsylvania

SILICA REMOVAL IN LIME-SODA SOFTENERSTimothy W. Trofe, Milton L. Owen, Radian Corporation, Austin, Texas; Wayne C. Micheletti,Electric Power Research Institute, Palo Alto, California, (IWC-85-37) 385

CONDENSER AIR INLEAKAGE AND DISSOLVED OXYGEN CONTROL TESTING AT CALLAWAY NUCLEAR PLANTScott Bond, Union Electric, Callaway Nuclear Plant, Fulton, Missouri; Alexander D. MacArthur,Westinghouse Electric Corporation, Pittsburgh, Pennsylvania, (IWC-85-38) 392

PWR SECONDARY SYSTEM WATER CHEMISTRY GUIDELINES AND THEIR APPLICATIONP.J. Battaglia, M.W. Rootham, M.J. Wootten, Westinghouse Electric Corporation,Pittsburgh, Pennsylvania, (IWC-85-39) 396

FLUID COMPOSITION IN THE TUBE SHEET. CREVICES OF A NUCLEAR STEAM GENERATOROleh Weres, Leon Tsao, Lawrence Berkeley Laboratory, University of California,Berkeley, California, (IWC-85-40) 402

INITIAL OPERATING EXPERIENCE WITH A LIQUID WASTE TREATMENT SYSTEM FOR NYSEG'S SOMERSET UNIT #1Robert S. Bernstein, Ebasco Services, Inc., New York, New York; Steven F. DeMarco,New York State Electric & Gas, Binghamton, New York, (IWC-85-41) 410


COOLING WATERPaul Puckorius, Session Chairman, Puckorius & Associates, Evergreen, Colorado

David Sexsmith, Session Discussion Leader, Drew Chemical Division/Ashland, Boonton, New JerseyEVALUATION OF ALTERNATIVE CHEMICALS FOR POWER PLANT CONDENSER BIOFOULING CONTROL

Robert Chiesa, Sargent & Lundy, Chicago, Illinois; Dennis Geary, Wisconsin Power& Light Company, Madison, Wisconsin, (IWC-85-42) 414

COOLING WATER TREATMENT USING A LIQUIFIED GAS FEEDER AND BROMINE CHLORIDEBlair Jones, Capital Controls Company, Inc., Colmar, Pennsylvania; Gerald Slifer,Public Service Electric and Gas Company, Newark, New Jersey, (IWC-85-43) 427

COMPATIBILITY OF DBNPA WITH CHLORINE AS WATER TREATMENT BIOCIDESRichard W. Walter, Jr., Jack F. Mills, Attila G. Relenyi, The Dow Chemical CompanyMidland, Michigan, (IWC-85-45) 434.

Papers presented on Thursday, November 7, 1985

MORNING SESSION "A"

PROGRESS REPORTS - MEMBRANES FILTRATIONE.A. Savinelli, Session Chairman, Consultant, Wilton, Connecticut

UNIQUE DOUBLE PASS REVERSE OSMOSIS SYSTEM ELIMINATES ION EXCHANGEFOR MANY DEIONIZATION APPLICATIONS

Gregory A. Pittner, Arrowhead Industrial Water, Los Angeles, California; Richard R.LeVander, Arrowhead Industrial Water, San Diego, California; John F. Bossier,Arrowhead Industrial Water, Fallsington, Pennsylvania, (IWC-85-46) : 444

A PROGRESS REPORT ON AN EDR INSTALLATIONTheodore Pickering, Betty J. White, Florida Power & Light Company, Fort Myers, Florida,(IWC-85-47) 450

ACID FREE SCALE CONTROL FOR RO SYSTEMSD.P. Logan, H.E. Nehus, A.L. Smith, Calgon Corporation, Pittsburgh, Pennsylvania,(IWC-85-48) 456

APPLICATION OF HIGH TEMPERATURE ELECTROMAGNETIC FILTRATION FORSECONDARY CYCLE CORROSION PRODUCT TRANSPORT CONTROL IN PRESSURIZED WATER REACTORS

William R. Kassen, NWT Corporation, San Jose, California; J.M. Burger, Empire State ElectricEnergy Research Corporation, New York, New York; J. Higgins, P. Silliman (retired),Consolidated Edison, New York, New York, (IWC-85-49) 467

MORNING SESSION "B"

BOILER WATERPeter L. Tremont, Session Chairman, Monsanto Corporation, St. Louis, Missouri

C.M. Hwa, Session Discussion Leader, Dearborn Chemical Division, Lake Zurich, IllinoisRETROFITTING THE WATER CHEMISTRY PROGRAMS AT SYNCRUDE CANADA LTD..

Michael E. Rogers, Syncrude Canada, Ltd., Alberta, Canada, (IWC-85-50) 587WATER CONDITIONING IN HIGH VOLTAGE ELECTRODE BOILERS

Edgard Eihachi Watanabe, Messias Candido Amaral, Aquatec Quimica S.A.,Sao Paulo, Brazil, (IWC-85-51) : 498

FOAMED SOLVENTS FOR CLEANING SURFACE CONDENSERSGary W. Bradley, Gary D. Arnold, Halliburton Services, Duncan, Oklahoma, (IWC-85-52) 512


GROUNDWATERE. Dennis Escher, Session Chairman, NUS Corporation, Pittsburgh, Pennsylvania

Leonard Limon, Session Discussion Leader, Graver Water, Union, New JerseyIN-GROUND REMOVAL OF IRON AND MANGANESE FROM WELL WATER

David F. Edson, Ground Water Associates, Inc., Arlington, Massachusetts, (IWC-85-53) 518PARTIAL DEMINERALIZATION OF GROUNDWATER BY THE CARIX ION EXCHANGE PROCESS

Wolfgang H. Hoell, Karlsruhe Nuclear Research Center, Federal Republic of Germany, (IWC-85-54) 525HYDROGEOLOGICAL INVESTIGATION FOR DESIGN AND CONSTRUCTION OF A GROUND

WATER SUPPLY FOR COOLING WATER MAKE-UPHenry C. Hunt, Bennett & Williams, Inc., Columbus, Ohio, (IWC-85-55) 533


BOILER WATERJames C. Dromgoole, Session Chairman, Maintenance Engineering Corporation, Houston, Texas

John Meakim, Session Discussion Leader, Petrolite Corporation, St. Louis, MissouriWATER TREATMENT FACILITIES FOR COGENERATION PLANTS

Jerry Printz, Stearns Catalytic Corporation, Denver, Colordao, (IWC-85-56) 538EXPERIENCE WITH A NOVEL, VOLATILE BOILER WATER OXYGEN SCAVENGER .

Carl J. Cappabianca, Paul F. Pelosi, James H. Nulty, Drew Industrial Division, AshlandChemical Company, Boonton, New Jersey, (IWC-85-58) 558

TREATMENT AND TEMPERATURE EFFECTS ON TURBIDITY AND MORPHOLOGY IN BOILERSPaul E. Foster, Hercules Incorporated, Wilmington, Delaware, (IWC-85-57) 550

Pi

"W,

A.




47th ANNUAL MEETING

October

Pittsburgh,

Michael

27,Hilton

General

28

C.Chairman

&Hotel

Skriba

Pennsylvania

29, 1986

Gerald W. Schweitzer


Executive Director

E. Peter Benzing

Mary Norton.Program Chairman

Program Coordinator

Sponsored By The

Engineers' Society of Western Pennsylvania.......

%INCORPORATED 1880

Rights to reprint articles in this publication may be granted, provided that: written permission from the author and a statement of the prospectivepublisher's intent are received by the IWC and that the IWC grants written permission to the prospective publisher.

© ENGINEERS' SOCIETY OF WESTERN PENNSYLVANIA

ASSOCIATES LITHO, INC.PITTSBURGH, PA 15201

Papers presented on Monday, October 27, 1986

MORNING SESSION "A"

CLEANINGJohn R. Gatewood, Session Chairman, Halliburton Services, Duncan, Oklahoma

E. A. Savinelli, Session Discussion Leader, Savinelli Associates, Wilton, ConnecticutENHANCED FOAM CLEANING OF COPPER-ALLOY SURFACE CONDENSERS

Edgar F. Hoy, Dowell Schlumberger, Tulsa, Oklahoma, (IWC-86-1) 1VIDEO INSPECTION AND SAMPLING OF THE CRYSTAL RIVER UNIT-3 ONCE-THROUGH STEAMGENERATORS

Rocky H. Thompson, Florida Power Corporation, Crystal River, Florida; Larry S. Lamanna, Babcock and Wilcox,Lynchburg, Virginia, MC-86-3) : 9

MORNING SESSION "B"

WASTEWATERRussell C. Vandenberg, Session Chairman, Resources Conservation Company, Bellevue, Washington

Thomas A. McAllister, Session Discussion Leader, Burmah Technical Services, Pontiac, MichiganRENOVATION OF DILUTE PROCESS WASTEWATERS: MINI-PILOT PLANT EVALUATION OF ANINTEGRATED PROCESS SYSTEM TO MEET THE CLEAN WATER ACT'S HEAVY-METAL AND ORGANICTREATMENT REQUIREMENTS AT OAK RIDGE NATIONAL LABORATORY

John M. Begovich, Clifton H. Brown, John F. Villiers-Fisher, Oak Ridge National Laboratory, Oak Ridge, Tennessee;Warren T. Thompson, Martin Marietta Energy Systems, Oak Ridge, Tennessee; George C. Patrick, H. Snider,Engineering-Science, Inc., Atlanta, Georgia (IWC-86-4) 17

THE APPLICATION OF ELECTRODIALYSIS TO INDUSTRIAL WATER REUSEJames D. Lynch, HPD Incorporated, Naperville, Illinois; Takuo Kawahara, Asahi Glass Company, Ltd., Tokyo, Japan,(IWC-86-5) 31,

WATER QUALITY PROTECTION WITH FISH MONITORSRoy Wilkes, pHox Systems, Ltd., Shefford, Beds., England, (IWC-86-6) 39

AFTERNOON SESSION "A'

ION EXCHANGEJames D. Shivers, Session Chairman, Consultant, Glendora, California

Irving M. Abrams, Session Discussion Leader, I.M.A. Consultants, Los Altos, CaliforniaWATER DEIONIZATION BY RECOFLO SHORT BED ION EXCHANGE

Craig J. Brown, Catherine J. Fletcher, Eco-Tec Limited, Pickering, Ontario, Canada, (IWC-86-7) 51ION EXCHANGE RESIN PERFORMANCE IN CANDU MODERATOR SYSTEMS

Babu R. Nott, Duane R. Chartier, Duncan H. Barber, Ontario Hydro, Research Division, Toronto, Canada, (IWC-86-8) 60DESIGN AND IMPLEMENTATION OF A SOFTENING PROCESS FOR HIGH TDS OIL FIELD PRODUCEDWATER

Robert A. Hart, Sally A. Thomas, Conoco, Inc., Ponca City, Oklahoma, (IWC-86-9) 72TOC REMOVAL FROM MAKE-UP WATER AT MILLSTONE NUCLEAR GENERATING STATION

William S. Miller, Ecolochem, Inc., Norfolk, Virginia; Vernon W. Jones, Robert H. Langer, Northeast Utilities ServiceCompany, Waterford, Connecticut, (IWC-86-10) 81


INSTRUMENTATION/ANALYTICALGerald F. Connell, Session Chairman, Capital Controls Company, Colmar, Pennsylvania

Walter Zabban, Session Discussion Leader, The Chester Engineers, Pittsburgh, PennsylvaniaINDUSTRY-WIDE SURVEY OF ORGANICS IN PWR's

W. A. Byers, J. E. Richards, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania; S. A. Hobart, Electric PowerResearch Institute, Palo Alto, California, (IWC-86-11) 90

ON-LINE ANALYSIS OF FLUORIDE, ACETATE, FORMATE, CHLORIDE, CARBONATE, AND SULFATE IN A SINGLERUN USING GRADIENT ION CHROMATOGRAPHY

Gary D. Burns, Richard C. Nolan, John E. Crutchfield, NUS Operating Services Corporation, Pittsburgh,Pennsylvania;Thomas 0. Passell, Electric Power Research Institute, Palo Alto, California, (IWC-86-12) 105

CHARACTERIZATION VS. IDENTIFICATION OF ORGANICS IN BOILER FEED WATER TREATMENTJoseph F. Selann, David Bromley Engineering, Ltd., Edmonton, Canada; Michael E. Rogers, Emerson C. Sanford,Syncrude Canada, Ltd., Edmonton, Canada, (IWC-86-13) 122

SIDE-BY-SIDE COMPARISON OF ANALYTICAL TECHNIQUES: ORGANIC ACIDS, TOTAL ORGANIC CARBON, ANDANIONS IN PWR SECONDARY CYCLES

Sue A Hobart, Electric Power Research Institute, Palo Alto, California; W. Art Byers, James Richards, Hector Silva,Westinghouse Electric Corporation, Pittsburgh, Pennsylvania; Gerard F. Palino, Michael R. Miller, Paul S. Wall, NWTCorporation, San Jose, California, (IWC-86-14) 130

Papers presented on Tuesday, October 28, 1986

MORNING SESSION "A"

ION EXCHANGE PROGRESS REPORTSGeorge Crits, Session Chairman, Cochrane Environmental, King of Prussia, Pennsylvania

THE REGENERATION OF WEAK AND STRONG CATION EXCHANGE RESINS WITH AN AQUEOUS SOLUTION OFSO2

R. Raiter, Ayalon Water Conditioning Company, Ltd., Haifa, Israel, (IWC-86-15) 144DEMINERALIZATION RETROFIT AND UPGRADE AT JERSEY CENTRAL POWER AND LIGHT COMPANY,SAYREVILLE PLANT

M. K. Burris, Jr., D. P. Fetterman, K. H. Frederick, GPU Nuclear Corporation, Reading, Pennsylvania; Nicholas T.Esposito, Jersey Central Power & Light Company, Morristown, New Jersey; Kenneth J. Kallfisch, Ebasco Services, Inc.,New York, New York; Alan A. Davis, Hungerford & Terry, Inc., Clayton, New Jersey, (IWC-86-16) 148

FIELD EXPERIENCE WITH REPLACING DEMINERALIZED WATER WITH DECATIONIZED WATER FOR ACIDREGENERANT DILUTION AND ANION BLOCK

David J. Hayek, Leonard W. Tarpley, Corpus Christi Petrochemical Company, Corpus Christi, Texas,(IWC-86-17) 152ION EXCHANGE RESINS-THEIR APPLICATION IN FLUE GAS SCRUBBING AT INCINERATION PLANTS

Friedrich B. Martinola, Heiko D. Hoffmann, Bayer AG, Leverkusen, West Germany, (IWC-86-18) 158POWDERED WEAKLY ACIDIC ION EXCHANGE RESINS IN CONDENSATE POLISHING

Bruce L. Libutti, Robert D. Forman, Robert Kunin, Graver Chemical Company, Union, New Jersey, (IWC-86-19) 164"EXTRACTABLES" IN RESINS: A FURTHER LOOK AT WHAT THEY ARE AND WHAT BECOMES OF THEM

Sallie Fisher, Gerard Otten, Puricons, Inc., Berwyn, Pennsylvania (IWC-86-20) 169

MORNING SESSION "B'

ASME SESSION: FEATURES OF CYCLIC OPERATION-FOSSIL FUELED UTILITY BOILERS

David E. Simon, Session Chariman, NUS Corporation, Pittsburgh, PennsylvaniaFrank Gabrielli, Session Discussion . Leader, Combustion Engineering, Windsor, Connecticut

ALTERNATIVE CHEMICAL TREATMENTS FOR CYCLICALLY OPERATED UNITSLinda L. Schneider, Donovan C. Hutchens, Omaha Public Power District, Omaha, Nebraska, (IWC-86-21) 177

EPRI RP2712-3 MONITORING CYCLE CHEMISTRY AT SIX FOSSIL PLANTSA. F. Aschoff, D. M. Sopocy, Sargent & Lundy, Chicago, Illinois; C. C. Stauffer, Babcock & Wilcox, Alliance,Ohio;R. B. Dooley, Electric Power Research Institute, Palo Alto, California, (IWC-86-22) 183

RETROFITTING OF CONDENSER STEAM SPARGERSBob Palmer, Mike Bennett, Detroit Edison, Detroit, Michigan, (IWC-86-23) 198

CORROSION PRODUCT TRANSPORT AT A CYCLING FOSSIL PLANTT. A. Hook, W. L. Pearl, S. G. Sawochka, NWT Corporation, San Jose, California; J. Scheibel, Electric Power ResearchInstitute, Palo Alto, California; J. Pugsley, Florida Power & Light Company, Miami, Florida (IWC-86-24) 206


BOILER WATERJames O. Robinson, Session Chairman, Betz Laboratories, Trevose, Pennsylvania

John McAllister, Session Discussion Leader, Petrolite Corporation, St. Louis, MissouriSTANDBY BOILER VIA NOVEL VAPOR PHASE INHIBITOR

Edgar Eihachi Watanabe, Nelson Gastaldo, Aquatec Quimica S. A., Sao Paulo, Brasil; James Tanis, Aquatec QuimicaS. A., Ridgefield, Connecticut, (IWC-86-25) 217

EIGHT YEARS OF MODIFIED AVT WITH ELEVATED OXYGEN LEVEL FOR ONCE-THROUGH STEAM GENERATORSAlbert Bursik, Grosskraftwerk Mannheim AG, Mannheim, Federal Republic of Germany, (IWC-86-26) 227

REVIEW OF BOILER WATER ALKALINITY CONTROLJ. Stodola, Ontario Hydro, Toronto, Canada, (IWC-86-27) 235

MONITORING OF MORPHOLINE AND ITS DECOMPOSITION PRODUCTS AT BEAVER VALLEY POWER STATIONJohn M. Riddle, NUS Operating Services Corporation, Pittsburgh, Pennsylvania; Thomas O. Passell, Electric PowerResearch Institute, Palo Alto, California; V. J. Linnenbom, Jr., Duquesne Light Company, Shippingport, Pennsylvania,(IWC-86-28) 245.


MEMBRANES/WATER PREPARATIONEdward P. Geishecker, Session Chairman, Ionics, Inc., Watertown, Massachusetts

Clarence Colley, Session Discussion Leader, Hewlett-Packard Company, Palo Alto, CaliforniaEDR RETROFIT AT MCKAY BAY REFUSE TO ENERGY PLANT

Prabhat Kumar Sinha, Bechtel Civil, Inc., Gaithersburg, Maryland; Kishore T. Gokhale, Bechtel Eastern PowerCorporation, Gaithersburg, Maryland; Edward P. Geishecker, Ionics, Inc., Waterford, Massachusetts; William D. Engel,Waste Management, Inc., Tampa, Florida, (IWC-86-29) 257

THE DECISION TO RETROFIT REVERSE OSMOSIS FOR BOILER WATER MAKE-UP AT A MIDWEST UTILITYMark C. Adams, Kansas City Power & Light Company, Kansas City, Missouri; Austin F. McCormack, McCormackCorporation, Dallas, Texas, (IWC-86-30) 274

COLLOIDAL SILICA REMOVAL BY ULTRAFILTRATIONJames A. McCaw, Jr., New York State Electric & Gas Corporation, Binghamton, New York, (IWC-86-31) 283

HOLLOW FIBER FILTRATION-A SUMMARY ECONOMIC AND FILTRATION REPORTRobert L. Harkins, HPD Incorporated, Naperville, Illinois; James F. Small, Union Electric Company, Fulton, Missouri,(IWC-86-32) 290

Papers presented on Wednesday, October 29, 1986

MORNING SESSION "A"

ION EXCHANGE RESIN STABILITYSallie Fisher, Session Chairman, Puricons, Inc., Berwyn, Pennsylvania

THE PHYSICAL STRENGTH OF ION EXCHANGE RESINSMalcolm Ball, Richard R. Harries, Walter W. Pickering, Central Electricity Generating Board, Nottingham, England,(IWC-86-33) 299

EXPERIENCES WITH A SHOCK TEST FOR THE DETERMINATION OF THE RESISTANCE OF ION EXCHANGERESINS TO OSMOTIC AND HYDROMECHANICAL STRESSES

Kurt HochmOller, BASF AG, Ludwigshafen/Rhein, Federal Republic of Germany (IWC-86-56) 306THE THERMAL DEGRADATION OF HYDROXYL FORM STRONG BASE TYPE I ANION EXCHANGE MATERIAL

George Simon, UNC Nuclear Industries, Richland, Washington, (IWC-86-53) 312FIELD EXPERIENCES WITH THE STABILITY OF STRONG BASE RESINS AT CORPUS -CHRISTI PETROCHEMICALCOMPANY

M. Moldofsky, F. X. McGarvey, Sybron Chemicals, Inc., Brimingham, New Jersey; David Hayek, Leonard Tarpley, CorpusChristi Petrochemical Company, Corpus Christi, Texas, (IWC-86-55) 327

ANION EXCHANGE RESIN KINETIC TESTING-AN INDISPENSABLE DIAGNOSTIC TOOL FOR CONDENSATEPOLISHER TROUBLESHOOTING

J. T. McNulty, M. Eumann, C. A. Bevan, V.C.T. Tan, Rohm and Haas Company, Spring House, Pennsylvania,(IWC-86-54) 335!

MORNING SESSION "B"

COOLING WATERRichard W. Lutey, Session Chairman, Buckman Laboratories, Inc., Memphis, Tennessee

James N. Tanis, Session Discussion Leader, Aquatec Quimica S.A., Ridgefield, ConnecticutFIELD EXPERIENCES AND RESULTS OF TWO TARGETED TREATMENT SYSTEMS

Robert D. Moss, Tennessee Valley Authority, Chattanooga, Tennessee; Patrick A. March, Tennessee Valley Authority,Norris, Tennessee; Stephen P. Gautney, Tennessee Valley Authority, Muscle Shoals, Alabama, (IWC-86-34) 343

CONTROLLING CORROSION IN ADMIRALTY SURFACE CONDENSERS-A NEW APPROACHChris A. Bissett, West Texas Utilities Company, Abilene, Texas; James F. Harrison, Calgon Corporation, Pittsburgh,Pennsylvania, MC-86-35) 353

AN IMPROVED METHOD FOR THE ON-LINE DETERMINATION OF OPERATING EFFICIENCY OF A COOLINGWATER SYSTEM

George F. Hays, Jenny Thom, Drew Industrial Division, Boonton, New Jersey, (IWC-86-36) 358CORROSION INHIBITION TECHNIQUES IN RECIRCULATING COOLING WATER

Paul D. Schumacher, Wisconsin Electric Power Company, Milwaukee, Wisconsin; Roy A. Johnson, John A. Romberger,Nalco Chemical Company, Naperville, Illinois, (IWC-86-37) 364

MORNING SESSION "C'

GENERAL PROGRESS REPORTSThomas M. Laronge, Session Chairman, Thomas M. Laronge, Inc., Vancouver, Washington

RAPID BIOCIDE SELECTIONRichard A. Clark, Buckman Laboratories, Memphis, Tennessee, (IWC-86-38) 379

KINETIC ANALYSIS OF A NEW BIOCIDE DELIVERY SYSTEM FOR COOLING TOWERSWilliam F. McCoy, James E. Ridge, Edward S. Lashen, Rohm and Haas Company, Spring House, Pennsylvania,(IWC-86-39) 384

RAPID EVALUATION OF CORROSION INHIBITORSMichael F. Coughlin, Gary Caplan, Bird Archer, Inc., Cobourg, Canada, (IWC-86-40) 390

TEMPERATURE EFFECTS ON COAGULATION PROCESSES USING SALTS OF ALUMINUMBrian A. Dempsey, The Pennsylvania State University, University Park, Pennsylvania; Lindle Willnow, University Collegeof Dublin, Dublin, Ireland; Penelope Pagoni, University of Missouri-Rolla, Rolla, Missouri, (IWC-86-41) 397

MEASUREMENT OF SODIUM IN BOILER FEED WATER: CALIBRATION WITHOUT CALIBRATION SOLUTIONHans Zehnder, Polymetron AG, Switzerland (IWC-86-57) (Final paper not available.)


COMPUTERJames K. Rice, Session Chairman, James K. Rice Company, Olney, MarylandOtakar Jonas, Session Discussion Leader, Jonas, Inc., Wilmington, Delaware

MICROCOMPUTER CODE FOR POWER PLANT WATER MANAGEMENTD. M. Sopocy, N. M. Kass, R. J. Chiesa, Sargent & Lundy, Chicago, Illinois; W. C. Micheletti, Electric Power ResearchInstitute, Palo Alto, California, (IWC-86-42) 403

ADVANCED REAL-TIME DATA ACQUISITION/DATA MANAGEMENT TECHNIQUES FOR CHEMICAL ON-LINEMONITORS

S. M. Wozniak, J. R. Balavage, P. J. Battaglia, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania(IWC-86-43) 418

UTILIZING SPC TECHNIQUES TO MONITOR SURFACE CONDENSER PERFORMANCEW. T. Chisholm, D. Burella, Dofasco, Inc., Hamilton, CAnada, (IWC-86-45) 426


WATER TREATMENTJesse S. Beecher, Session Chairman, Consultant, Drew Industrial Division, Pittsburgh, Pennsylvania

James C. Dromgoole, Session Discussion Leader, Maintenance Engineering, Houston, TexasIDENTIFICATION AND CONTROL OF SCALING IN RECIRCULATING ASH-DISPOSAL SYSTEMS

Marvin D. Silbert, Marvin Silbert & Associates, Willowdale, Ontario, Canada; Gabriel M. Nicolaides, Tony A. Tonelli,Zenon Environmental, Inc., Burlington, Ontario, Canada, (IWC-86-47) 436

INNOVATIVE DESIGN FOR CHLORAMINE REMOVAL FOR PHARMACEUTICAL COMPANY WATER SUPPLYJohn C. Detweiler, Brown and Caldwell Consulting Engineers, Eugene, Oregon; David R. Jones, Brown and CaldwellConsulting Engineers, Pasadena, California; David E. Severy, Hyland Therapeutics Division, Travenol Laboratories, LosAngeles, California, (IWC-86-48) 445

SIGNIFICANT SILICA REDUCTION IN COLD LIME PROCESSP.C.D. George Samuel, Madras Refineries Limited, Madras, Tamil Nadu, India, (IWC-86-49) : 456

AFTERNOON SESSION "C"

GENERAL PROGRESS REPORTSMaury Rapp, Session Chairman, Dowell/Schlumberger, Charlotte, North Carolina

COMPARITIVE INVESTIGATION INTO CORROSION INHIBITORS FOR COPPERDan Vanderpool, Mobay Corporation, Pittsburgh, Pennsylvania; H. J. Rother, Bayer AG, Krefeld, West Germany;D. Kuron, S. Strop, Bayer AG, Leverkusen, West Germany, (IWC-86-50) 464

OPERATING EXPERIENCE IN CORRECTING SEVERE SECONDARY CHEMISTRY UPSETS BY CONTROLLINGMAKEUP WATER ORGANICS (TOC)

Walter G. Flint, Kewaunee Nuclear Station, Kewaunee, Wisconsin; Robert J. McIntosh, Anatel Instrument Corporation,Boulder, Colorado, MC-86-51) 470

NEW CONDENSATE MONITORiNG TECHNIQUESW. E. Bornak, Betz Laboratories, Inc., Trevose, Pennsylvania, (IWC-86-52) 476

%W



THEWATER

INTERNATIONALCONFERENCE

48th ANNUAL MEETING

November 2-4, 1987

Jesse S. Beecher

Pittsburgh,

E. Peter

Hilton

General

Pennsylvania

BenzingChairman

Hotel

Gerald W. SchweitzerVice Chairman

Program Chairman

Sponsored By The

Engineers' Society of Western Pennsylvaniaf•wfS

INCORPORATED 1880

Rights to reprint articles in this publication may be granted, provided that: written permission from the author and a statement of theprospective publisher's intent are received by the IWC and that the IWC grants written permission to the prospective publisher.

The opinions and findings expressed in this publication are not necessarily those of theInternational Water Conference Board, Advisory Committee or the Engineers' Society of Western Pennsylvania

©ENGINEERS' SOCIETY OF WESTERN PENNSYLVANIA


Papers presented on Monday, November 2, 1987

MORNING SESSION "A"

COMPUTERMichael C. Skriba, Session Chairman, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania

Michael Gottlieb, Discussion Leader, ResinTech, Cherry Hill, New Jersey

EXPERT SYSTEMS APPLICATIONS IN WATER TREATMENTD.M. Sopocy, A.R. Glazer, J.A. Montanus, Sargent & Lundy, Chicago, Illinois (IWC-87-1) 1

WATER QUALITY DATA ACQUISITION SYSTEMDavid J. Sonntag, Leonard J. Trudeau, Detroit Edison, Detroit, Michigan (IWC-87-2) : 11

A PC BASED CONDENSATE/FEEDWATER CHEMISTRY MONITORING AND CONTROL SYSTEMFOR HIGH PRESSURE AND SUPERCRITICAL BOILERS

Barry W. Vial, Duke Power Company, Charlotte, North Carolina (IWC-87-3) 19

MORNING SESSION "B"

INSTRUMENTATION/ANALYTICAL PROGRESS REPORTSGerald Connell, Session Chairman, Capital Controls Company, Colmar, Pennsylvania

EXPERIENCES WITH A BOILER WATER MONITORING SYSTEM FORTHREE REMOTE STANDBY GENERATING UNITS

Roger A. Lewis, Southern Company Services, Birmingham, Alabama;Jud Richardson, Alabama Power Company, Gorgas, Alabama (IWC-87-4) 29

MICROCHEMISTRY OF CORROSION: FAILURE ANALYSIS USING MODERN ELECTRON-BEAM TECHNIQUESDonald L. Gibbon, Richard G. Varsanik, George C. Simon, Calgon Corporation,Pittsburgh, Pennsylvania (IWC-87-5) 35

A SELF-CLEANING DISSOLVED OXYGEN SENSOR FOR CONTINUOUS DISSOLVEDOXYGEN MONITORING IN HIGHLY EUTROPHIC AQUEOUS ENVIRONMENTS

Jim Dartez, Royce Instrument Corporation, New Orleans, Louisiana (IWC-87-6) 52ION CHROMATOGRAPHIC ANALYSIS OF ORGANOPHOSPHONATES IN COOLING WATER

David Berg, Dan Vanderpool, Mobay Corporation, Pittsburgh, Pennsylvania;Dick Rubin, Dionex Corporation, Sunnyvale, California (IWC-87-7) 56


ION EXCHANGEFrank X. McGarvey, Session Chairman, Sybron Chemicals, Birmingham, New Jersey

William Miller, Discussion Leader, Ecolochem, Inc., Norfolk, Virginia

PREDICTION AND IDENTIFICATION OF LEACHABLES FROM CATION EXCHANGE RESINSJ.R. Stahlbush, R.M. Strom, R.G. Byers, J.B. Henry, N.E. Skelly, The Dow Chemical Company,Midland, Michigan (IWC-87-10) 67

ADVANCED ION EXCHANGE HYDRAULIC ANALYSIS AND APPLICATIONSGregory R. Allan, Nuclear Fluids, Inc., Redmond, Washington (IWC-87-8) 78

THERMAL DEGRADATION OF STRONGLY BASIC ANION EXCHANGE RESINS IN CAUSTIC REGENERANTSF.X. McGarvey, E.W. Hauser, B. Bachs, J. Stellitano, Sybron Chemicals Inc.,Birmingham, New Jersey (IWC-87-9) 93

STUDY ON ATTRITION OSMOTIC STABILITY AND EXTRACTABLES OF VARIOUS ION EXCHANGE RESINSHideo Kawazu, Masahiro Hagiwara, Takeshi Izumi, Ebara Corporation, Tokyo, Japan;Kanroku Chonan, Kazuyuki Koyama; Ebara-Infilco Co., Ltd., Tokyo, Japan (IWC-87-11) 103


COOLING WATER PROGRESS REPORTSPaul Puckorius, Session Chairman, Puckorius & Associates, Evergreen, Colorado

MOLYBDATE-BASED COOLING WATER TREATMENT:NEW DEVELOPMENTS WHICH EXPAND THEIR APPLICATION AREAS

Kenneth F. Soeder, Joseph S. Roti, Drew Industrial Division, Boonton, New Jersey (IWC-87-12) 115FIELD TESTING OF A NEW BROMINE RELEASE BIOCIDE

Samuel E. Shull, Francis J. Himpler, Lonza, Inc., Williamsport, Pennsylvania;Paul R. Puckorius, Puckorius Associates, Inc., Evergreen, Colorado (IWC-87-13) 129

ON-SITE PILOT PLANT STUDY FOR VERIFICATION ANDOPTIMIZATION OF COOLING WATER CONDITIONING

R. C. Schwarz, Betz Industrial, Trevose, Pennsylvania (IWC-87-14) 134GALVANIZED COOLING TOWERS-WHITE RUST

H. Raymond Tool, Branchemco, Inc., Jacksonville, Florida (IWC-87-15) 139TARGETED CHLORINATION FIXED-NOZZLES DESIGN ATBRAYTON POINT STATION UNIT 2 CONDENSER

W. Chow, Electric Power Research Institute, Palo Alto, California;Y.G. Mussalli, Stone & Webster Engineering Corporation, Boston, Massachusetts;W. Freddo, New England Power Company, Somerset, Massachusetts (IWC-87-16) 149

Papers presented on Tuesday, November 3, 1987

MORNING SESSION "A"

ASME SESSION: WATER CHEMISTRY CONTROL IN FOSSIL UTILITY BOILERSDavid E. Simon, II, Session Chairman, NUS Corporation, Pittsburgh, Pennsylvania

Anton Banweg, Discussion Leader, Babcock & Wilcox, Barberton, Ohio

CHEMICAL TRANSPORT AND TURBINE CORROSION IN PHOSPHATE TREATED DRUM BOILER UNITSOtakar Jonas, Jonas, Inc. Consultants, Wilmington, Delaware;Barry C. Syrett, Electric Power Research Institute, Palo Alto, California (IWC-87-17) 158

DEOXYGENATION IN A CYCLING FOSSIL PLANTT.A. Hook, W.L. Pearl, NWT Corporation, San Jose, California; J. Scheibe!, Electric Power Research Institute,Palo Alto, California; C. Henry, TU Electric Company, Dallas, Texas (IWC-87-18) : 167

EPRI INTERIM CONSENSUS GUIDELINES ON FOSSIL PLANT CYCLE CHEMISTRYAND EUROPEAN PRACTICE-A CRITICAL ASSESSMENT

Albert Bursik, Grosskraftwerk Mannheim, Mannheim, Federal Republic of Germany (IWC-87-19) 176COMPARISON OF NEW ZEALAND AND UNITED STATES PRACTICESFOR FOSSIL PLANT CYCLE CHEMISTRY

David J. Nicholson, Electricity Corporation of New Zealand, Ltd., Wellington, New Zealand;Nathaniel E. Pritchard, Electricity Corporation of New Zealand, Ltd., Huntly, New Zealand;Robert Chiesa, RMT, Inc., Madison, Wisconsin (IWC-87-20) :..r 183

MORNING SESSION "B"

LAY-UP CLEANINGJohn Siegmund, Session Chairman, Sheppard T. Powell Associates, Baltimore, Maryland

John Knox, Discussion Leader, Halliburton Services, Duncan, Oklahoma

COOLING WATER TREATMENT APPLICATIONS FOLLOWING ANUNSCHEDULED TWO MONTH WINTER SHUTDOWN

Al Thieme, Clark Oil and Refining Corporation, Blue Island, Illinois;Harold Moffat, John Chiappetta, Drew Industrial Division, Ashland Chemical, Countryside, Illinois (IWC-87-21) 192

CORROSION PREVENTION OF TURBINES DURING EXTENDED OUTAGES (CASE HISTORIES)Thomas H. Pike, Western Farmers Electric Cooperative, Hugo, Oklahoma (IWC-87-22) ' 200

CHEMICAL CLEANING OF THE BOILER, SUPERHEATER, REHEATER ANDMAIN STEAM LINES AT ST. JOHNS RIVER POWER PARK UNIT #1

Joseph M. Parent, Florida Power & Light Co., Indiantown, Florida;Jose P. Lozada, Julius Isaac, Ebasco Services Incorporated, New York, New York;Frank H. Thomas, Jacksonville Electric Authority, Jacksonville, Florida (IWC-87-23) 209

THE STATE OF THE ART IN MECHANICAL CONDENSER CLEANINGM.D. Rosen, A.F. Aschoff, Sargent & Lundy, Chicago, Illinois;J.A. Bartz, Electric Power Research Institute, Palo Alto, California (IWC-87-24) 218


BOILERJim Robinson, Session Chairman, Betz Laboratories, Trevose, Pennsylvania

Jim Dromgoole, Discussion Leader, Maintenance Engineering, Houston, Texas

CONTAMINATED BOILER SYSTEMS-TREATMENT RESULTS OF PHOSPHATE VS. ORGANIC TECHNOLOGIESEdgar E. Watanabe, Aquatec Quimica, S.A., Sao Paulo, Brasil;James N. Tanis, Aquatec Quimica, S.A., Ridgefield, Connecticut (IWC-87-25) 230

DEAERATOR CRACKING, AN INDUSTRY UPDATEJ.A. Kelly, Dearborn Division, W.R. Grace & Company, Lake Zurich, Illinois;C.E. Guzi, The Proctor & Gamble Company, Cincinnati, Ohio;T.M. Laronge, Thomas M. Laronge, Inc., Vancouver, Washington (IWC-87-26) 241

STUDY OF THE CHEMICAL AND PHYSICAL CHARACTERISTICS OF CRYSTAL RIVERUNIT STEAM GENERATOR DEPOSITS

Rocky H. Thompson, Florida Power Corporation, Crystal River, Florida;Larry S. Lamanna, The Babcock & Wilcox Company, Lynchburg, Virginia (IWC-87-27) 255

FIELD STUDY: ELECTROMAGNETIC DEVICE USED TO TREAT A WATERTUBE BOILERGary Caplan, Fred Stegmayer, Bird Archer, Inc., Cobourg, Ontario, Canada (IW.C-87-28) 267


WASTEWATERStan Haden, Session Chairman, Eimco Process Equipment, Salt Lake City, Utah

Walter Zabban, Discussion Leader, The Chester Engineers, Pittsburgh, Pennsylvania

WASTEWATER MANAGEMENT AND REUSE AT A MUNICIPAL WASTE-TO-ENERGY FACILITYPrabhat Kumar Sinha, Nancy D. Zeigler, Lawrence J. Gasper, Bechtel Civil, Inc., Gaithersburg, Maryland (IWC-87-29) 283

AN INNOVATIVE SOLUTION FOR STEAM STRIPPING OF VOLATILE ORGANIC COMPOUNDS AND HIGH BOILINGPOINT POLLUTANTS FROM GROUNDWATERS WITH THE AQUADETOX STRIPPING SYSTEM

Robert L. Solomon, Daniel J. Peterson,,Resources Conservation Co., Bellevue, Washington (IWC-87-30) 296

START-UP OF A COAL FIRED POWER PLANT'S WASTEWATER TREATMENT PLANTH.A. (Hank) Mann, Stanley Consultants, Inc., Muscatine, Iowa;Jim Volk, Niagara Mohawk Power Corporation, Albany, New York;Jorge Villali, Niagara Mohawk Power Corporation, Syracuse, New York (IWC-87-31) 307

OZONE TREATMENT OF WATER-A NEW PROCESSA Rony Joel, Shaun S. Pierson, Capital Controls Company, Colmar, Pennsylvania (IWC-87-32) 310

Papers presented on Wednesday, November 4, 1987

MORNING SESSION "A"

ION EXCHANGE PROGRESS REPORTSLen Limon, Session Chairman, Graver Water, Union, New Jersey

ON-SITE GENERATION OF ACID AND BASE WITH BIPOLAR MEMBRANES:A NEW ALTERNATIVE TO PURCHASING AND STORING REGENERANTS

Thomas A. Davis, Terrance LaTerra, Graver Water Division of The Graver Company, Union, New Jersey (IWC-87-33) 316WEAK ACID RESIN FOR CONDENSATE POLISHING

Michael O'Brien, Eli Salem, Graver Water Division, The Graver Company, Union, New Jersey;Bruce L. Libutti, Graver Chemical Division, The Graver Company, Union, New Jersey;Robert Kunin, Consultant, The Graver Company, Union, New Jersey (IWC-87-34) 324

A THREE BED DEMINERALIZER CASE HISTORY ON ORGANIC BEARING SURFACE WATERA.S. Bruntlett, V.P. Murphy, International Paper, Mansfield, Louisianna;V.K. Puri, Calgon Corporation, Pittsburgh, Pennsylvania;B.E. Barton, Calgon Corporation, Shreveport, Louisiana (IWC-87-35) : 332

NEW TECHNOLOGY IN THE SOFTENING OF "PRODUCED WATER" IN ENHANCED OIL RECOVERY SYSTEMSPeter Michael Lange, Friedrich B. Martinola, Hans Karl Soest, Bayer AG, Leverkusen, Germany (IWC-87-36) 346

PARTICLE SIZE MEASUREMENT OF ION-EXCHANGE RESINS AND POLYMERS BY HIACL.S. Golden, Purolite International Ltd., Pontyclun, S. Wales, United Kingdom (IWC-87-37) 350

AN EVALUATION OF THE FIRST INSTALLATION OF "ACRYLOBED" IN THE UNITED STATESThomas M. Bachey, Cincinnati Gas & Electric, New Richmond, Ohio;Ellen Adamski, Illinois Water Treatment, Rockford, Illinois (IWC-87-38) 357

MORNING SESSION "B"

COOLING WATERRichard W. Lutey, Session Chairman, Buckman Laboratories, Memphis, TennesseeThomas Puthoff, Discussion Leader, Ciba-Geigy Corporation, Oak Brook, Illinois

PRACTICAL AIR WASHER TREATMENT IN SYNTHETIC FIBER MANUFACTURING PLANTSJohn C. Peterson, Wright Chemical Corporation, Greensboro, North Carolina (IWC-87-39) 366

ROLE OF POLYMERS IN THE MECHANISMS AND PERFORMANCE OFPHOSPHATE-BASED COOLING WATER PROGRAMS

G.A. Crucil, J.R. Macdonald; E.B. Smyk, Nalco Chemical Company, Naperville, Illinois (IWC-87-40) ....: 373WATER TREATMENT IN WET FIN-FAN COOLING TOWERS

Ken W. Roland, Christopher H. Norton, Southern California Gas Company, Los Angeles, California (IWC-87-41) 381BROMINE CHEMISTRY AN ALTERNATIVE TO DECHLORINATION INCOOLING WATER AND WASTEWATER DISINFECTION

Jeffery C. Conley, Edward H. Puzig, Great Lakes Chemical Corporation, West Lafayette, Indiana;James E. Alleman, Purdue University, West Lafayette, Indiana (IWC-87-42) 389

MORNING SESSION "C"

GENERAL PROGRESS REPORTSJames N. Tanis, Session Chairman, Aquatec Quimica, S.A., Ridgefield, Connecticut

A SAFE-LOW TEMPERATURE-FERRIC OXIDE SOLVENT SYSTEMEdgar F. Hoy, Dowell Schlumberger, Tulsa, Oklahoma (IWC-87-43) (Not published in this proceedings.)

OXYGEN SCAVENGING WITH CARBONACEOUS PRECOATS UNDER STARTUP AND STEADY STATE CONDITIONSBruce L. Libutti, Robert Kunin (Consultant), Graver Chemical Division of the Graver Company, Union, New Jersey;Billy D. Fellers, Texas Utilities Generating Company, Glen Rose, Texas;Charles R. Mosser, Graver Chemical Division of the Graver Company, Arlington, Texas (IWC-87-44) 397

AN UNUSUAL CASE STUDY OF COPPER PICKUP IN ALL STEEL UTILITY STEAM GENERATION CYCLEDouglas B. Dewitt-Dick, Drew Industrial Div., Boonton, New Jersey (IWC-87-45) 404

SIMPLE AND RAPID METHODS FOR THE DETERMINATION OF TRACE (PPB) LEVELSOF IRON AND COPPER IN BOILER FEEDWATERS AND CONDENSATES

Earl L. Henn, Calgon Corporation, Pittsburgh, Pennsylvania (IWC-87-46) 412DETERIORATION OF CONDENSATE POLISHING KINETIC AS A RESULT OF ORGANIC FOULING

Karol Daucik, I/S Skaerbaekvaeket, Fredericia, Denmark;Kate Wieck-Hansen, I/S Nordkraft, Aalborg, Denmark (IWC-87-47) 425

DESIGN AND OPERATION OF A 2600 PSIG MODEL STEAM GENERATORA.C. McDonald, G.J. Patek, Betz Laboratories, Inc., The Woodlands, Texas (IWC-87-48) 431


MEMBRANES/WATER PREPARATIONClarence Colley, Session Chairman, Hewlett-Packard Company, Palo Alto, California

George Crits, Discussion Leader, Cochrane Environmental, King of Prussia, Pennsylvania

SEAWATER REVERSE OSMOSIS: UTILITY PLANT OPERATING EXPERIENCEEdward L. Dubost, Constantine T. Polidoroff, Pacific Gas and Electric Company, San Francisco, California;Michael J. Peterson, Pacific Gas and Electric Company, Avila Beach, California;Michael Humphreys, K. Scott Jackson, Hydranautics, Santa Barbara, California;Kan Lin, Bechtel Power Corporation, San Francisco, California (IWC-87-49) : 438

CONTAINERIZED TREATMENT SYSTEM OVERCOMES PROBLEMS,DELIVERS HIGH PURITY WATER TO NUCLEAR POWER PLANT

Luther B. Jones, Virginia Electric Power Company, Richmond, Virginia;John F. Bossier, Arrowhead Industrial Water, Fallsington, Pennsylvania (IWC-87-50) : 448

USE OF RO MEMBRANES IN THE YUMA DESALTING PLANTCharles M. Cummings, UOP Fluid Systems, San Diego, California;Alan B. Riedinger, Consultant, San Diego, California (IWC-87-51) 456


NUCLEARAiroy Aschoff, Session Chairman, Sargent & Lundy, Chicago, Illinois

Robert D. Scherer, Discussion Leader, Duquesne Light Company, Pittsburgh, Pennsylvania

KLM'S OPTIMIZED BARS FOR SILICA AND WASTE REMOVALDonald A. Schuelke, Northern States Power Company, Welch, Minnesota;B. George Kniazewycz, Mark A. Brossart, KLM Technologies, Inc., Walnut Creek, California;Joseph Markind, KLM Technologies, Inc., Boxborough, Massachusetts (IWC-87-52) 468

AN OVERVIEW OF THE OPERATIONAL SECONDARY SIDE WATER CHEMISTRYOF A SEAWATER COOLED CANDU 600

George Plume, Cyril MacNeil, New Brunswick Electric Power Commission, Lepreau, New Brunswick, Canada;Peter Watts, Ecodyne Limited, Oakville, Ontario, Canada (IWC-87-53) 474

CONDENSATE POLISHERS-THEIR EFFECT ON STEAM GENERATOR CHEMISTRYRobert H. Langer, Northeast Utilities Service Company, Berlin, Connecticut;Thomas H. Burns, Northeast Nuclear Energy Company, Waterford, Connecticut (IWC-87-54) 491

AFTERNOON SESSION "C"

GENERAL PROGRESS REPORTSAndrew F. McClure, Session Chairman, NUS Corporation, Aiken, South Carolina

WASTEWATER TREATMENT SYSTEM FOR HAZARDOUS WASTE LANDFILL LEACHATERandolph W. Rakoczynski, Waste Resource Associates, Inc., Niagara Falls, New York (IWC-87-57) 502

ELECTRODEIONIZATION-AN ECONOMIC ANALYSISJonathan Wood, Yair Egozy, Gary C. Ganzi, Millipore Corporation, Bedford, Massachusetts (IWC-87-55) 507

DESTRUCTION OF TOC USING-ULTRAVIOLET LIGHTPeter S. Meyers, L*A Water Treatment Corporation, City of Industry, California (IWC-87-56) 519

DIOXINE: TREATMENT WITH OZONEDieter Von der Mark, Schmidding-Werke, Cologne, West Germany;Hans H. Rump, Institut Fresenius;Shaun S. Pierson, Capital Controls Company, Inc., Colmar, Pennsylvania (IWC-87-58) : 526



THE INTERNATIONALWATER CONFERENCE ®

49th ANNUAL MEETING

October 24-26, 1988Hilton Hotel

Pittsburgh, Pennsylvania

Gerald W. SchweitzerGeneral Chairman

Ray Baum

Jesse S. BeecherVice Chairman

Program Chairman

Sponsored by the


INCORPORATED 1880Rights to reprint articles in this publication may be granted, provided that: written permission from the author and a statement of the

prospective publisher's intent are received by the IWC and that the IWC grants written permission to the prospective publisher.

The opinions and findings expressed in this publication are not necessarily those of theInternational Water Conference Committee, Advisory Council or the Engineers' Society of Western Pennsylvania

©ENGINEERS' SOCIETY OF WESTERN PENNSYLVANIA


TABLE of CONTENTSPapers presented on Monday, October 24, 1988

MONDAY MORNING SESSION "A"

COOLING/BIOSession Chairman: Paul Puckorius, Puckorius & Associates, Evergreen, Colorado

Discussion Leader: Bill Hollingshad, Calgon Corporation, Pittsburgh, Pennsylvania

A CASE HISTORY OF BIOFOULING CONTROL AT VIRGINIA POWER'S YORKTOWN GENERATING STATION

1J.W. Thornton, D.S. Morelen, Virginia Power, Yorktown, Virginia (IWC-88-1)

Prepared Discussion

11Billy D. Fellers, Texas Utilities, Glen Rose, Texas

QUANTITATION OF LEGIONELLA PNEUMOPHILA IN ONE THOUSAND COMMERCIALAND INDUSTRIAL COOLING TOWERS

: 13Richard W. Gilpin, Adele M. Kaplan, Edwin F. Goldstein, Arc Water Treatment Company,Philadelphia, Pennsylvania (IWC-88-2)

Prepared Discussion

18James C. Feeley, Pathogen Control Associates, Tucker, Georgia

A NOVEL SYNERGISTIC CHLORINE AND COPPER TECHNIQUE TO CONTROLBIOFOULING WITH LOW ENVIRONMENTAL IMPACT

: 20E.E. Williams, B. Knox-Holmes, M.F. DiProse, Biofouling and Corrosion Control, Ltd., Sheffield, England;Y.G. Mussalli, Stone & Webster Engineering Corporation, Boston, Massachusetts (IWC-88-3)

Prepared Discussion

28Alan L. Smith, Calgon Corporation, Pittsburgh, Pennsylvania

MONDAY MORNING SESSION "B"

MEMBRANESSession Chairman: Clarence D. Colley, Hewlett Packard Company, Palo Alto, California

Discussion Leader: William S. Miller, Ecolochem, Inc., Norfolk, Virginia

TOC REMOVAL FROM SURFACE WATERS BY COMMERCIALLY OPERATINGTRIPLE MEMBRANE DEMINERALIZERS

32William E. Katz, Frederick G. Clay, Ionics, Incorporated, Watertown, Massachusetts (IWC-88-4)

Prepared Discussion

: 42Thomas A. Davis, Graver Water Division of the Graver Company, Union, New Jersey

REDUCING CHLORIDES AND SULFATES BY ULTRAFILTRATION 46Robert Dvorin, SAIC, Paramus, New Jersey; John Kristensen, New York Power Authority, Buchanan, New York;John Zahn, New York Power Authority, White Plains, New York (IWC-88-5)

Prepared Discussion

49Robert H. Langer, Vernon W. Jones, Northeast Utilities, Hartford, Connecticut

GROUNDWATER RESTORATION BY REVERSE OSMOSIS

52Glenn J. Catchpole, Uranerz U.S.A., Inc., Casper, Wyoming; Mark Moxley, Wyoming Department of Environmental Quality;Rick Kaiser, Polymetrics, Inc., San Jose, California (IWC-88-6)

Prepared Discussion

: 57Hari B. Gupta, Culligan International, Northbrook, Illinois

MONDAY AFTERNOON SESSION "A"

ION EXCHANGESession Chairman: Leonard Limon, Graver Water, Union, New JerseyDiscussion Leader: Robert Kunin, Consultant, Yardley, Pennsylvania

EVALUATION OF A UNIFORM PARTICLE SIZE TYPE II ANION RESIN

61Gordon P. Usitalo, Thomas J.P. Wysocki, Detroit Edison, Detroit, Michigan;Daniel B. Rice, The Dow Chemical Company, Midland, Michigan (IWC-88-7)

Prepared Discussion

66Frances M. Cutler, Southern California Edison, Paramount, California

LEACHABLES VS. IONIC LEAKAGE IN POWDERED RESIN SYSTEMS

68Sallie A. Fisher, Gerard Otten, Puricons, Inc., Malvern, Pennsylvania (IWC-88-8)

Prepared Discussion

75J.R. Stahlbush, R.M. Strom, The Dow Chemical Company, Midland, Michigan

TREATMENT OF DRINKING WATER BY THE CARIX ION EXCHANGE PROCESS-EXPERIENCES FROM TWO YEARS OF OPERATION OF THE FIRST FULL SCALE CARIX PLANT ' 80

Wolfgang H. Holl, Karlsruhe Nuclear Research Center, Karlsruhe, Federal Republic of Germany (IWC-88-9)Prepared Discussion 86

Frank X. McGarvey, Sybron Chemicals, Inc., Birmingham, New JerseyTHE SIGNIFICANCE AND LIMITATIONS OF LABORATORY RESIN ANALYSES IN EVALUATINGION EXCHANGE OPERATING PERFORMANCE

89G.J. Crits, D.H. Valentine, Cochrane Environmental Systems, King of Prussia, Pennsylvania (IWC-88-10)

Prepared Discussion

97Michael J. O'Brien, The Graver Company, Union, New Jersey

MONDAY AFTERNOON SESSION "B"

COMPUTERSession Chairman: Michael C. Skriba, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania

Discussion Leader: Robert Hamilton, Consultant, Denver, Colorado

-

USING MICROCOMPUTERS TO IMPROVE POWER PLANT WATER MANAGEMENT

99D.M. Sopocy, J.A. Montanus, M.D. Rosen, Sargent & Lundy, Chicago, Illinois;W.C. Micheletti, Electric Power Research Institute, Palo Alto, California;K. Swazas, Salt River Project, Phoenix, Arizona (IWC-88-11)

Prepared DiscussionNancy K. Henning, West Texas Utilities, Abelene, Texas (Not published in this Proceedings.)

USING OPERATIONAL SOLUBILITY PRODUCT CONSTANTS TO IMPROVEWATER SOFTENING CALCULATIONS

113Douglas T. Merrill, Bruce D. Douglas, Brown & Caldwell, Pleasant Hill, California;Wayne C. Micheletti, Electric Power Research Institute, Palo Alto, California (IWC-88-12)

Prepared Discussion

120A.W. (Gus) Cummings, III, Public Service Company of Colorado, Brush, Colorado

ON-LINE, REAL-TIME EXPERT SYSTEM FOR COOLING WATER

123David Roberts, Calgon Corporation, Pittsburgh, Pennsylvania;Richard Herrod, Leon Tietz, Texas Instruments, Inc., Dallas, Texas (IWC-88-13)

Prepared Discussion

135Paul Puckorius, Puckorius & Associates, Evergreen, Colorado


TUESDAY MORNING SESSION "A"

STEAM PURITY FOR INDUSTRIAL TURBINES (ASME SESSION)Session Chairman: Dave Simon, Cyrus Rice Consulting Group, Pittsburgh, Pennsylvania

Discussion Leader: Art Fynsk, E.I. DuPont de Nemours, Newark, Delaware

DETERMINATION OF STEAM PURITY LIMITS FOR INDUSTRIAL TURBINES

137Otakar Jonas, Jonas, Inc., Wilmington, Delaware (IWC-88-15)

Prepared Discussion

145James O. Robinson, Betz Laboratories, Trevose, Pennsylvania

STEAM PURITY PROBLEMS ENCOUNTERED IN INDUSTRIAL TURBINES

148Douglas Dewitt-Dick, Drew Industrial Division, Ashland Chemical Company, Boonton, New Jersey;Jesse S. Beecher, Frank Seels, Drew Industrial Division, Ashland Chemical Company,Pittsburgh, Pennsylvania (IWC-88-16)

Prepared Discussion

158Samuel B. Dilcer, Jr., Calgon Corporation, Pittsburgh, Pennsylvania

STEAM PURITY FOR INDUSTRIAL TURBINES

160Alan Whitehead, Richard T. Bievenue, General Electric Company, Schenectady, New York (IWC-88-17)

Prepared Discussion

171Joseph A. Cameron, Consultant, Greensburg, Pennsylvania

STEAM PURITY FOR INDUSTRIAL STEAM GENERATORS

173G. Navitsky, Combustion Engineering, Inc., Windsor, Connecticut;H.A. Grabowski, H.A. Grabowski, Inc., Chicago, Illinois (IWC-88-18)

TUESDAY MORNING SESSION "B"

INSTRUMENTATION/ANALYTICALSession Chairman: John Siegmund, Sheppard T. Powell, Baltimore, Maryland

Discussion Leader: Steven I. Lerman, SIL Consulting, Plainview, New York

DEFINING ANALYTICAL METHODS PERFORMANCE FOR POWER PLANT AQUEOUS DISCHARGE COMPLIANCE

181James K. Rice, Consulting Engineer, Olney, Maryland; Raymond F. Maddalone, TRW, Inc., Redondo Beach, California;Winston Chow, Electric Power Research Institute, Palo Alto, California (IWC-88-19)

Prepared Discussion

: : 194James L. Greco, Pennsylvania Electric Company, Johnstown, Pennsylvania

GUIDELINES ON INSTRUMENTATION AND CONTROL FOR FOSSIL PLANT CYCLE CHEMISTRY

197Kevin J. Shields, Strati Yorgiadis, Sheppard T. Powell Associates, Baltimore, Maryland;R. Barry Dooley, Electric Power Research Institute, Palo Alto, California (IWC-88-20)

Prepared Discussion

214Robert M. Ricker, Sentry Equipment Corporation, Oconomowoc, Wisconsin

ANALYTICAL TECHNIQUES FOR DETERMINING OILY WATER IN CONDENSATESUSED IN COGENERATION STEAM PLANTS 217

Mike E. Rogers, Howard Hamilton, Ade Oseni, Syncrude Canada, Ltd., Fort McMurray, Alberta, Canada (IWC-88-21)Prepared Discussion

Myra Burgess, Commonwealth Edison Company, Maywood, Illinois (Not published in this Proceedings.)

TUESDAY MORNING SESSION "C"

ION EXCHANGE PROGRESS REPORTSSession Chairman: Frank X. McGarvey, Sybron Chemicals, Inc., Birmingham, New Jersey

TREATMENT OF REFINERY CONDENSATE BY A UNIQUE COALESCING PROCESS

229Robert O'Connell, The Graver Company, Union, New Jersey (IWC-88-24)

COST SAVINGS IN TREATMENT OF COOLING WATER THROUGH USE OF ION-EXCHANGE PROCESSESWITH CHEMICALS SUPPLIED FROM WASTE BRINE

234John W. Kaakinen, Chemetek, Astoria, Oregon (IWC-88-25)

REPORT ON THE EFFECTS OF FILTER AID BODY FEED TO CONDENSATE PRECOAT FILTER/DEMINERALIZERSAT GEORGIA POWER COMPANY'S PLANT I.E. HATCH

240Randy R. Jones, Georgia Power Company, Bayley, Georgia;George C. Flynn, Graver Water, Union, New Jersey (IWC-88-26)

RETROFITTING LOW EFFICIENCY DEMINERALIZERS WITH NEW INTERNALS PAYS BIG DIVIDENDS

245Philip K. Hazen, Texas Municipal Power Company, Carlos, Texas;Glenda Ard, McCormack Corporation, Dallas, Texas (IWC-88-27)

ULTRAPURE WATER TREATMENT PLANT FOR I .C. MANUFACTURING

250Jose Luis del Arco, Graver Espanola, SA, Bilbao, Spain; Jose Fernandez Benlloch, Foster Wheeler Iberia, Madrid, Spain;Peter Zogas, ATT, Allentown, Pennsylvania (IWC-88-53)

TUESDAY AFTERNOON SESSION "A"

COOLING WATERSession Chairman: Richard W. Lutey, Buckman Laboratories, Inc., Memphis, Tennessee

Discussion Leader: Tom Sclofani, Drew Industrial Division, Ashland Chemical, Boonton, New Jersey

DEVELOPMENT AND APPLICATION OF A NEW CORROSION INHIBITOR FOR COPPER-BEARING ALLOYS

254Orin Hollander, Betz Laboratories, Inc., Trevose, Pennsylvania; Jack Lambert, Betz Industrial, Huntsville, Alabama;David Willeison, Georgia Power, Taylorsville, Georgia (IWC-88-28)

Prepared Discussion

265Gerald D. Hansen,. Consultant, Holicond, Pennsylvania

CORROSION INHIBITOR PERFORMANCE IN A SCALE MODEL COOLING WATER SYSTEM SIMULATOR

267Allen E. Feltzin, Airco Industrial Gases, Murray Hill, New Jersey;Robert Di Stefano, Syntec Corporation, Water Management Group, Newark, Delaware (IWC-88-44)

Prepared Discussion

275Mike A. Winters, Amoco Corporation, Naperville, Illinois

DEVELOPMENT OF A COOLING WATER TREATMENT PROGRAM TO PROTECT ACB FILL IN AHIGH TDS RECIRCULATING COOLING WATER SYSTEM

277Timothy W. Trofe, Radian Corporation, Austin, Texas; Richard J. Sugam, Public Service Electric & Gas Company,Newark, New Jersey; Ashok Pasricha, Public Service Electric & Gas Company, Hancocks Bridge, New Jersey;Wayne C. Micheletti, Electric Power Research Institute, Palo Alto, California (IWC-88-30)

Prepared Discussion

283Peter L. Tremont, Peter L. Tremont & Associates, Houston, Texas

COMBINATION COOLING WATER/FGD WET SCRUBBER CHEMICAL TREATMENT AT MONTANA POWER COMPANY 288Carl R. Camper, Jr , Mark R. Stevens, Montana Power Company, Colstrip, Montana; Edward W. Ekis, Jr., M. Linda Lin,Michael T. Meyerkord, Richard J. Mouche, Robert W. Shiely, Nalco Chemical Company, Naperville, Illinois (IWC-88-31)

Prepared Discussion

297Wayne C. Micheletti, Electric Power Research Institute, Palo Alto, California

TUESDAY AFTERNOON SESSION "B"

NUCLEARSession Chairman: Alroy F. Aschoff, Sargent & Lundy Engineers, Chicago, Illinois

Discussion Leader: Robert D. Scherer, Duquesne Light Company, Pittsburgh, Pennsylvania

USE OF ADVANCED ANALYTICAL TECHNIQUES TO EVALUATE PWR SECONDARY CYCLE WATER CHEMISTRY

301Sue A. Hobart, Adams & Hobart Consulting Engineers, San Jose, California; Clarine Anderson, Balazs AnalyticalLaboratory, Mountain View, California; Meredith J. Angwin, Crescent Project Management, Palo Alto, California;Jan Svenson, Vattenfall (Swedish State Power Board), Varobacka, Sweden (IWC-88-32)

Prepared Discussion

309Maryann Klick, GPU Nuclear Corporation, Reading, Pennsylvania

THE CONTINUING MAINTENANCE OF SUPERIOR CHEMISTRY AT A PWR NUCLEAR STATION:PSE&G COMPANY, SALEM STATION

313Norman Sevrin, Robert J. Dolan, Public Service Electric & Gas, Hancocks Bridge, New Jersey;Eli Salem, The Graver Company, Union, New Jersey (IWC-88-33)

Prepared Discussion 327......................................David C. Auerswald, Southern California Edison, Paramount, California

A NEW LOOK AT PHOSPHATE VS AVT FOR NUCLEAR STEAM GENERATORS

332Cyril K. MacNeil, New Brunswick Electric Power Commission, Point Lepreau, New Brunswick, Canada;Marvin D. Silbert, Marvin Silbert and Associates, Willowdale, Ontario, Canada (IWC-88-34)

Prepared Discussion

339K. Anthony Selby, Water Technology Consultants, Chicago, Illinois

EVALUATION OF HIDEOUT RETRUN DATA: COMPARISON OF MULTEQ ANALYSES OF SLOWDOWNAND FEEDWATER WITH OTHER EVALUATIVE TECHNIQUES

342Gary E. Brobst, GEBCO Engineering, Edgewater, Maryland; Sue A. Hobart, Adams & Hobart Consulting Engineers,San Jose, California; Francis J. Keneshea, Consultant, Portola Valley, California; Thomas O. Passell, Charles S. Welty,Electric Power Research Institute, Palo Alto, California (IWC-88-35)

Prepared Discussion

355S.G. Sawochka, NWT Corporation, San Jose, California

TUESDAY AFTERNOON SESSION "C"

WASTEWATERSession Chairman: James K. Rice, James K. Rice Company, Olney, Maryland

Discussion Leader: Eugene Goldman, Bechtel Environmental, San Francisco, California

REMOVAL OF TRACE ELEMENTS FROM POWER PLANT WASTE STREAMS BYIRON ADSORPTION/COPRECIPITATION

361Mark A. Manzione, Douglas T. Merrill, Brown and Caldwell, Pleasant Hill, California;Mary E. McLearn, Winston Chow, Electric Power Research Institute, Palo Alto, California;James F. Stine, Pennsylvania Power and Light Company, Allentown, Pennsylvania;Shigeru Kobayashi, Pennsylvania Power and Light Company, Washingtonville, Pennsylvania;Wayne J. Martin, Battelle Pacific Northwest Laboratories, Richland, Washington (IWC-88-36)

Prepared Discussion

369David E. Simon, II, Cyrus Rice Consulting Group, Pittsburgh Pennsylvania

FRG WASTEWATER TREATMENT-STATE OF THE ART IN THE FEDERAL REPUBLIC OF GERMANY

373Albert Bursik, Grosskraftwerk Mannheim AG, Mannheim, Federal Republic of Germany;Erich Deterle, Philipp Mueller, Nachfolger Eugen Bucher GmBH & Co., Stuttgart, Federal Republic of Germany (IWC-88-38)

Prepared Discussion 378Walter Zabban, The Chester Engineers, Pittsburgh, Pennsylvania

AN ON-SITE CHEMICAL TREATMENT FOR REMOVING IRON AND COPPERFROM CHELANT CLEANING WASTES

380M.L. Samuelson, S.B. McConnell, E.F. Hoy, Dowell Schiumberger, Tulsa, Oklahoma (IWC-88-39) - _

Prepared Discussion

386John W. Schumann, City of Los Angeles Department of Water and Power, Los Angeles, California

NEW LOWER COST METHOD FOR TREATING ACID MINE DRAINAGE-A CASE HISTORY: MARTINKA MINE #1

389Ronald L. Kolbash, American Electric Power, Lancaster, Ohio;Donald Budeit, Turbojett International, Canonsburg, Pennsylvania (IWC-88-37)

Prepared Discussion

393Donald H. Newman, Schneider Engineers, Bridgeville, Pennsylvania


WEDNESDAY MORNING SESSION "A"

STEAM GENERATING SYSTEMSSession Chairman: James O. Robinson, Betz Laboratories, Inc., Trevose, PennsylvaniaDiscussion Leader:James C. Dromgoole, Maintenance Engineering, Houston, Texas

FREE VS. CAPTIVE ALKALINITY... FACTORS AFFECTING THE CHOICE OF A HIGH PRESSUREINDUSTRIAL BOILER INTERNAL TREATMENT PROGRAM

395S.T. Costa, J.M. Pace, R.D. Trumbetta, Calgon Corporation, Pittsburgh, Pennsylvania (IWC-88-40)

Prepared Discussion

401T.J. Tvedt, Jr., The Dow Chemical Company, Freeport, Texas

PHOSPHATE HIDEOUT IN HIGH-PRESSURE SOLUTIONS

: 404A.C. McDonald, B.L. Tracy, Betz Laboratories, Inc., The Woodlands, Texas (IWC-88-41)

Prepared Discussion

411A. Banweg, Babcock & Wilcox Company, Alliance, Ohio

ON-LINE CHEMISTRY DIAGNOSTICS

414James C. Bellows, Karen L. Weaver, Westinghouse Electric Corporation, Orlando, Florida;James Gallatin, Orlando Utilities Commission, Orlando, Florida (IWC-88-42)

Prepared Discussion

: : 420Dale M. Sopocy, Sargent & Lundy Engineers, Chicago, Illinois

COMPARISON OF OXYGEN CONTROL AND AMINE STRATEGIES TO MINIMIZE CRUD LOADINGIN HIGH-PRESSURE BOILER FEEDWATER SYSTEMS

424P.D. Schumacher, R.D. Muehlenkamp, K.A. Koehler, Wisconsin Electric Power Company, Milwaukee, Wisconsin;R.A. Johnson, Nalco Chemical Company, Naperville, Illinois (IWC-88-43)

Prepared Discussion

433Peter Turner, San Diego State University, San Diego, California

WEDNESDAY MORNING SESSION "B"

COOLING WATER PROGRESS REPORTSSession Chairman: Gerald F. Connell, Capital Controls Company, Colmar, Pennsylvania

PERFORMANCE AND MECHANISM OF COOLING WATER PROGRAMS BASED ON HYDROXYPHOSPHONOCARBOXYLIC ACID (HPA)

435Patrick Sullivan, Alan Yeoman, Ciba-Geigy Corporation, Ardsley, New York (IWC-88-45)

PREDICT FOULING, PRESERVE THERMAL EFFICIENCY: REAL-LIFE, REAL TIME PROGRAM EVALUATIONS

441J. Fred Wilkes, Aquatec Quimica S.A., Titusville, Florida;Flavio Bianchi, Messias C. Amaral, Aquetec Quimica S.A., Titusville, Florida (IWC-88-47)

BIOFOULING CONTROL USING A SYNERGISTIC HYDROGEN PEROXIDE AND FERROUS ION TECHNIQUE

449Sunao Ikuta, Mitsubishi Gas Chemical Company, Inc., Tokyo Japan;Kunio Nishimura, Toru Yasunaga, Seiichi Ichikawa, Yoshiharu Wakao, Katayama Chemical, Inc., Osaka, Japan (IWC-88-48)

technical Merit/Presentation of the Session

4'NW

AgMI' i;,,



THEWATER

INTERNATIONALCONFERENCE ®

50th ANNIVERSARY

October 23-25, 1989

Pittsburgh,Hilton Hotel

Pennsylvania

Jesse S. BeecherGeneral Chairman

Connie Glover

David E. Simon 11Vice Chairman

Program Chairman

Sponsored by the

Engineers' Society of Western Pennsylvania^!!!!!:,,4

Rights to reprint articles in this publication may

INCORPORATED 1880

from the author and a statement of thebe granted, provided that: written permissionprospective publisher's intent are received by the IWC and that the IWC grants written permission to the prospective publisher.

The opinions and findings expressed in this publication are not necessarily those of theInternational Water Conference Committee, Advisory Council or the Engineers ' Society of Western Pennsylvania

@ENGINEERS' SOCIETY OF WESTERN PENNSYLVANIA

ASSOCIATES LITHO, INC.

TABLE of CONTENTSPapers presented on Monday, October 23, 1989

KEYNOTE ADDRESS

THE HISTORY OF THE INTERNATIONAL WATER CONFERENCEJ. Fred Wilkes, Consultant, Titusville, Florida

MONDAY MORNING SESSION "A"

MEMBRANESSession Chairman/Discussion Leader: William S. Miller, Ecolochem, Inc., Norfolk, Virginia

PAST, PRESENT AND FUTURE OF MEMBRANE TECHNOLOGY

1Peter S. Cartwright, Cartwright Consulting Co., Minneapolis, Minnesota (IWC-89-1)

EVALUATION OF LOW PRESSURE REVERSE OSMOSIS MEMBRANES

8Robert M. Quinn, R Q Associates, Inc., Teaneck, New Jersey;Connie Morton, City of Sarasota Water Plant, Sarasota, Florida (IWC-89-2)

Prepared DiscussionRoy Hango, IBM Corporation, Essex Junction, Vermont (Not published in this Proceedings.)

MONDAY MORNING SESSION "B"

CLEANINGSession Chairman: Maury Rapp, Dowell/Schlumberger, Charlotte, North Carolina

Discussion Leader: David E. Simon II, Cyrus Rice Consulting Group, Pittsburgh, Pennsylvania

SERVICE WATER IRON DEPOSIT REMOVAL AT GRAND GULF NUCLEAR

15J.E. Antoine, G.O. Smith, System Energy Resources, Inc., Port Gibson, Mississippi;E.W. Ekis, Nalco Chemical Company, Naperville, Illinois;W.M. Kemp, G.J. Peterson, Nalco Chemical Company, Atlanta, Georgia (IWC-89-3)

Prepared Discussion

: 20Peter L. Tremont, Peter L. Tremont & Associates, Houston, Texas

REMOVAL OF COPPER FROM UTILITY BOILERS UTILIZING AN ENVIRONMENTALLY ACCEPTABLE OXIDENT

25S.T. Arrington, G.W. Bradley, Halliburton Services, Duncan, Oklahoma (IWC-89-4)

Prepared Discussion

32Kenneth F. Layton, Utah Power and Light Company, Salt Lake City, Utah

MONDAY AFTERNOON SESSION "A"

COOLING WATER ISession Chairman: Tom Sclofani, Drew Industrial Division, Blue Bell, Pennsylvania

Discussion Leader: James C. Dromgoole, Maintenance Engineering Corp., Houston, Texas

FIFTY YEARS OF COOLING WATER TREATMENT-A REVIEW AND COMMENTARY

36

E.A. Savinelli, Savinelli Associates, Wilton, Connecticut;A.J. Freedman, T.M. Laronge, Thomas M. Laronge, Inc., Vancouver, Washington (IWC-89-5)

COOLING WATER TECHNOLOGY OF THE 1990 's

43

Jack V. Matson, University of Houston, Houston, Texas (IWC-89-6)Prepared Discussion

: 46

M.A. Winters, Amoco Corporation, Naperville, IllinoisMANGANESE/AMINOPHOSPHONIC ACID CHEMISTRY: A NEW PERSPECTIVE ON COOLING WATER TREATMENT

49

T.J. Tvedt, Jr., C.A. Jones, J.G. Grierson, The Dow Chemical Company, Freeport, Texas;L. Jones, The Dow Chemical Company, Midland, Michigan (IWC-89-7)

Prepared Discussion

59

Joseph S. Roti, Drew Industrial Division, Boonton, New JerseyHOW TO INSPECT INDUSTRIAL WATER COOLING TOWERS

James L. Willa, Willa, Inc., St. Louis, Missouri (IWC-89-8) (Not published in this Proceedings)Prepared Discussion

62

Allen E. Feltzin, Airco Industrial Gases, Murray Hill, New Jersey

MONDAY AFTERNOON SESSION "B"

WASTE TREATMENTSession Chairman: Alroy F. Aschoff, Sargent & Lundy Engineers, Chicago, Illinois

Discussion Leader: Louis J. Koenig. Jr., Zinkan Enterprises, Inc., Chagrin Falls, Ohio

THE IMPACT OF WATER QUALITY AND TOXICS-BASED NPDES PERMITTING

64

Robert M. Rosain, CH2M Hill, Bellevue, Washington (IWC-89-9)Prepared Discussion

70

Winston Chow, Electric Power Research Institute, Palo Alto, CaliforniaOPERATION OF SEMASS ZERO DISCHARGE WATER MANAGEMENT SYSTEM

72

Prabhat Kumar Sinha, Lawrence J. Gasper, Bechtel Corporation, Gaithersburg, Maryland;Gregory C. Wilson, Bechtel (SEMASS Operations), Rochester, Massachusetts (IWC-89-10)

Prepared Discussion

83

Mark Manzione, Brown & Caldwell Consulting Engineers, Walnut Creek, California

BOILER CHEMICAL CLEANING WASTE TREATMENT AND DISPOSAL OPTIONS

85Thomas A. Lott, Wayne C. Micheletti, Electric Power Research Institute, Palo Alto, California;Larry Holcombe, Radian Corporation, Austin, Texas (IWC-89-11)

Prepared Discussion

95Stanley B. McConnell, Dowell Schlumberger Incorporated, Tulsa, Oklahoma

THE WASTE WATER CONCENTRATING COOLING TOWER,A NEW TECHNIQUE FOR WASTE WATER VOLUME REDUCTION

William G. Sanderson, Richard L. Lancaster, Zurn/Nepco, Woodinville, Washington (IWC-89-12)(Not published in this Proceedings.)

Prepared Discussion

98Paul R. Puckorius, Puckorius & Associates, Inc., Evergreen, Colorado


TUESDAY MORNING SESSION "A"CORROSION IN STEAM GENERATING SYSTEMS

Session Chairman: Otakar Jonas, Jonas, Inc., Wilmington, DelawareDiscussion Leader: A. Banweg, Babcock & Wilcox, Barberton, Ohio

CYCLE CHEMISTRY RELATED BOILER TUBE FAILURES AND REDUCTION 100Barry Dooley, Electric Power Research Institute, Palo Alto, California (IWC-89-13)

-Prepared Discussion

107David N. French, David N. French, Inc., Metallurgists, Northborough, Massachusetts

STATUS OF CORROSION FATIGUE FAILURE INVESTIGATION IN DRUM TYPE UTILITY BOILERS

109R.W. Patterson, Jan Stodola, D. Sidey, D. McNabb, Ontario Hydro, Toronto, Ontario, Canada;A. Banweg, L. Paul, Babcock & Wilcox, Alliance, Ohio (IWC-89-14)

Prepared Discussion

: 122R.B. Pond, Jr., Baltimore Gas & Electric Company, Baltimore, Maryland

FIELD OPERATING EXPERIENCES WITH A VOLATILE OXYGEN SCAVENGER/METAL PASSIVATORIN A HIGH PRESSURE UTILITY CIRCUIT

124Kaj D. Rondum, Everett J. Fuller, Douglas B. Dewitt-Dick, Drew Industrial Division, Ashland Chemical Company,Sub. Ashland Oil, Inc., Boonton, New Jersey;Alan M. Bargender, Wisconsin Public Service Corporation, Rothschild, Wisconsin (IWC-89-15)

Prepared DiscussionManfred Noack, Olin Corporation, Cheshire, Connecticut (Not published in this Proceedings.)

EROSION CORROSION IN POWER PLANTS-SINGLE-AND TWO-PHASE FLOW EXPERIENCE, PREDICTION,NDE DATA MANAGMENT AND REMEDIAL MEASURES

139Norbert Henze!, Dennis Egan, Bechtel-KWU Alliance, Gaithersburg, Maryland (IWC-89-16)

Prepared Discussion

147Frank J. Witt, U.S. Nuclear Regulatory Commission, Washington, D.C.

TUESDAY MORNING SESSION "B"

INSTRUMENTATION/ANALYTICAL ISession Chairman: John Siegmund, Sheppard T. Powell Associates, Baltimore, Maryland

Discussion Leader: Steven Lerman, SIL Consulting, Plainview, New York

INDUSTRIAL WATER QUALITY MEASUREMENT: A RETROSPECTIVE/PROSPECTIVE VIEW

150James K. Rice, Consulting Engineer, Olney, Maryland (IWC-89-17)

THE DIRECT MEASUREMENT OF AMMONIA ALKALINITY IN "ALL VOLATILE" TREATED POWER PLANT SYSTEMS

171Jeffrey Scot Hovis, Orion Research Incorporated, Boston, Massachusetts (IWC-89-18))

Prepared Discussion

183W.E. Allmon, C.C. Stauffer, The Babcock & Wilcox Company, Alliance, Ohio

MONITORING AND CONTROL OF A NON-HYDRAZINE REDUCING AGENT

184William L. Trace, Calgon Corporation, Pittsburgh, Pennsylvania;Keith H. Kehrer, Delmarva Power, Millsboro, Delaware (IWC-89-19)

Prepared Discussion

:... 190Robert Muehlenkamp, Paul Schumacher, Wisconsin Electric Power Company, Milwaukee, Wisconsin

SEPARATION AND DETECTION OF TRACE LEVEL CATIONS AND ORGANIC AMINES IN POWER PLANT WATERSUSING ION CHROMATOGRAPHY 192

Daniel L. Campbell, Robert Joyce, John Stillian, Steve Carson, Dionex Corporation, Sunnyvale, California (IWC-89-20)Prepared Discussion 204

Frances M. Cutler, Southern California Edison Company, Paramount, California

TUESDAY MORNING SESSION "C"

GROUNDWATER/ORGANIC REMOVALSession Chairman: Lester C. Webb, Black & Veatch, Kansas City, Missouri

Discussion Leader: Arthur J. Freedman, Thomas M. Laronge, Inc., Califon, New Jersey

REMOVAL AND TREATMENT OF DISSOLVED AND FLOATING ORGANIC COMPOUNDSIN A CONTAMINATED GROUNDWATER

209Thomas F. Klumpp, The Dow Chemical Company, Midland, Michigan;Samuel S. Tawney, D. Eric Strang, EDI Engineering & Science, Grand Rapids, Michigan (IWC-89-21)

Prepared Discussion

223G. Kent Peterson, Illinois Water Treatment Company, Rockford, Illinois

COMPUTER SIMULATION OF GROUNDWATER CONTAMINATION CAUSED BYPETROLEUM HYDROCARBONS SPILLAGE

: 226Jing-Yea Yang, Shi-Tao Yeh, Roy F. Weston, Inc., West Chester, Pennsylvania (IWC-89-22)

Prepared Discussion

231Gianni O. Chieruzzi, The Chester Engineers, Pittsburgh, Pennsylvania

CASE HISTORY OF A REVERSE OSMOSIS SYSTEM ON HIGH ORGANIC CONTENT WELL WATER

232A. Arseneaux, L. Stoner, Air Products and Chemicals, Inc., New Orleans, Louisiana;S. Whipple, Dow Chemical Company, Midland, Michigan (IWC-89-23)

Prepared DiscussionPeter Cartwright, Cartwright Consulting, Minneapolis, Minnesota (Not published in this Proceedings.)

REMOVAL OF ORGANICS BY REVERSE OSMOSIS

241Abu Nurmohamed, Partec Lavalin,Inc., Calgary, Alberta, Canada;Roger Cowles, Syncrude Canada Ltd., Edmonton, Alberta, Canada;Michael E. Rogers, Syncrude Canada Ltd., Ft. McMurray, Alberta, Canada (IWC-89-24)

Prepared Discussion

248Michael J. O'Brien, The Graver Company, Union, New Jersey

TUESDAY AFTERNOON SESSION "A"

ION EXCHANGE ISession Chairman: James O. Robinson, Betz Laboratories, Trevose, Pennsylvania

Discussion Leader: Peter S. Meyers, L*A Water Treatment Div., City of Industry, California

ION EXCHANGE, PAST, PRESENT AND FUTURE

250Dr. Robert Kunin, Consultant, Yardley, Pennsylvania (IWC-89-25)

ARE ALL TYPE I STRONG BASE ANION RESINS CHEMICALLY EQUALIN THEIR ABILITY TO POLISH CONDENSATE?

:.: 254Sallie Fisher, Gerard Otten, Puricons, Inc., Malvern, Pennsylvania (IWC-89-26)

Prepared Discussion

261Stephen C. Foor, Illinois Water Treatment Company, Rockford, Illinois

IS TOTAL CAPACITY MEASUREMENT AN INDICATOR OF COLUMN PERFORMANCE OFANION EXCHANGE RESINS?

265F.X. McGarvey, M.E. Childs, R. Gonzalez, Sybron Chemicals, Inc., Birmingham, New Jersey (IWC-89-27)

.............. ...............................Prepared Discussion

283James T. McNulty, Rohm and Haas Company, Spring House, Pennsylvania

AN ECONOMIC OPTIMIZATION MODEL FOR OPERATION OF APULSED-RESIN-BED ION EXCHANGE LOOP

287David F. McLaughlin, Westinghouse Electric Corporation, Pittsburgh, Pennsylvania (IWC-89-28)

Prepared Discussion

: 295Michael C. Gottlieb, ResinTech, Cherry Hill, New Jersey

TUESDAY AFTERNOON SESSION "B"

INSTRUMENTATION/ANALYTICAL IISession Chairman: Gerald F. Connell, Capital Controls Co., Colmar, Pennsylvania

Discussion Leader: Judy Rawa, Calgon Corporation, Pittsburgh, Pennsylvania

DEVELOPMENT AND APPLICATION OF AN EMPIRICAL DIAGNOSTIC TOOL TO OPTIMIZECONDENSATE TREATMENT VIA AMINE TRACKING

299Gary M. Reggiani, Betz Industrial, The Water Management Division, Betz Laboratories, Inc., Trevose, Pennsylvania;Richard Prentice, Ken Jones, Betz Industrial, Houston, Texas;Glen Rider, Amoco, Texas City, Texas (IWC-89-29)

Prepared Discussion

: 309T.J. Tvedt, Jr., The Dow Chemical Company, Freeport, Texas

ON-SITE CONDENSATE MONITORING-A TOOL FOR DETERMINING THE EFFECTIVENESS OFCONDENSATE TREATMENT PROGRAMS

312D.G. Gingrich, Alchem, Inc., Burlington, Ontario, Canada;D.M. Bloom, Nalco Chemical Company, Naperville, Illinois (IWC-89-30)

Prepared Discussion

318Douglas B. DeWitt-Dick, Drew Industrial Division, Boonton, New Jersey

MONITORING CONDENSATE POLISHER OPERATION USING CONDUCTIVITY (SPECIFIC, CATION ANDDEGASSED CATION) AND SODIUM ANALYSIS

: 321Carl C. Scheerer, Central Illinois Public Service Company, Springfield, Illinois;John Cluzel, Rosemount Analytical, Inc., Cedar Grove, New Jersey;Russell W. Lane, Water Treatment Consultant, Champaign, Illinois (IWC-89-31)

Prepared Discussion

330William E. Allmon, Babcock & Wilcox Company, Alliance, Ohio

UNDERSTANDING STREAMING CURRENT: PRACTICAL COAGULANT CONTROL

335James B. Carling, Milton Roy Company, Ivyland, Pennsylvania (IWC-89-32)

Prepared Discussion

:338Dr. E.R. Baumann, Iowa State University, Ames, Iowa

TUESDAY AFTERNOON SESSION "C"

COOLING WATER IISession Chairman: Paul Puckorius, Puckorius & Associates, Evergreen, Colorado

Discussion Leader: Bill Hollingshad, Calgon Corporation, Pittsburgh, Pennsylvania

MECHANISMS OF ACTION OF DIMETHYLAMIDES AS A PENETRANT/DISPERSANT IN COOLING WATER SYSTEMS 340Richard W. Lutey, Vanja M. King, Maryann Cleghorn, Buckman Laboratories, Memphis, Tennessee (IWC-89-33)

Prepared Discussion 345William F. McCoy, Great Lakes Chemical Corporation, West Lafayette, Indiana

SEARCH FOR A BETTER COOLING WATER MONITOR

347Patricia Zuniga, Amoco Chemical Company, Alvin, Texas;Kenneth Miller, Amoco Oil Company, Texas City, Texas;Mike Winters, Amoco Research Center, Naperville, Illinois (IWC-89-34)

Prepared Discussion

353Thomas C. Breske, E.I. du Pont de Nemours & Co., Inc., Newark, Delaware

FIELD DEMONSTRATION OF A MOVING MANIFOLD TARGETED CHLORINATION SYSTEMAT JOHN SEVIER FOSSIL PLANT

356Bruce W. Vigon, Norman G. Reichenbach, Battelle Columbus Division, Columbus, Ohio;Robert D. Moss, Tennessee Valley Authority, Chattanooga, Tennessee;Winston Chow, Electric Power Research Institute, Palo Alto, California (IWC-89-35)

Prepared Discussion

370Alan L. Smith, Calgon Corporation, Pittsburgh, Pennsylvania

WATER TECHNOLOGY EXPERIENCES IN THERMAL STORAGE SYSTEMS

373Richard M. Ahigren, Ahlgren Associates, Waukesha, Wisconsin (IWC-89-36)

Prepared Discussion

383K. Anthony Selby, Puckorius & Associates, Inc., Evergreen, Colorado


WEDNESDAY MORNING SESSION "A"

ION EXCHANGE IISession Chairman: Leonard Limon, Graver Water, Union, New Jersey

Discussion Leader: Richard Hetherington, Epicor, Inc., Fort Washington, Pennsylvania

PARTS PER TRILLION WITHOUT MIXED BEDS

385David C. Auerswald, Frances M. Cutler, Shawn S. Simmons, Southern California Edison Company,Paramount, California (IWC-89-37)

Prepared Discussion

411Dr. Robert Kunin, Consultant, Yardley, Pennsylvania

COMPARATIVE EVALUATION OF CONDENSATE POLISHER DESIGN AND PERFORMANCE

419Albert Bursik, Grosskraftwerk Mannheim AG, Mannheim, West Germany;Francois de Dardel, Rohm and Haas France S.A., Paris, France (IWC-89-38)

Prepared Discussion

425F.X. McGarvey, Sybron Chemicals, Inc., Birmingham, New Jersey

REGENERATION OF CONDENSATE POLISHING MIXED BED RESINS: A REVIEW OF 10 YEARS EXPERIENCEWITH THE CONESEP SEPARATION/REGENERATION SYSTEM

428M.A. Sadler, H.R. Bolton, NEI Thompson Ltd., Kennicott, Wolverhampton, England (IWC-89-39)

Prepared Discussion

: 437Carl C. Scheerer, Central Illinois Public Service Co., Springfield, Illinois

OPERATING EXPERIENCE AT A NUCLEAR POWER PLANT USING441DEEP BED CATION FILTERS AND MIXED BED POLISHERS : :.

William Jocher, Kim Reynolds, Milton Rejcek, Houston Light & Power, Wadsworth, Texas;Michael J. O'Brien, Graver Water, Union, New Jersey (IWC-89-40)

Prepared Discussion

446Billy Fellers, Texas Utilities Electric, Glen Rose, Texas

WEDNESDAY MORNING SESSION "B"

COMPUTERSession Chairman: Jim Bellows, Westinghouse, Orlando, Florida

Discussion Leader: Wayne Bernahl, Nalco Chemical Company, Naperville, Illinois

COMPUTERIZED CHEMISTRY DATA ACQUISITION AND MANAGEMENT (CCDAMS)

448Leroy D. Hughes, Toledo Edison Company, Oak Harbor, Ohio;Bradley D. Barlocker, Babcock & Wilcox, Lynchburg, Virginia (IWC-89-41)

Prepared DiscussionJim Gassen, Nalco Chemical Company, Chicago, Illinois (Not published in this Proceedings.)

A TOTALLY INTEGRATED CHEMISTRY DATA MANAGEMENT SYSTEM

457R.E. Allen, Louisiana Power & Light Company, Killona, Louisiana;R.D. McCullough, Radian Corporation, Austin, Texas (IWC-89-42)

Prepared DiscussionDale Sopocy, Sargent & Lundy, Chicago, Illinois (Not published in this Proceedings.)

COMPUTER CONTROL OF REVERSE OSMOSIS

465Larry Ashcraft, Pete Weaver, Eastman Kodak Company, Rochester, New York;Fred Wale, Rust International Corp., Portland, Oregon;Tom LaHue, Ebara Corp., Glendale, California;Susan Mashima, Shin Taniguchi, Ebara Corp., Tokyo, Japan (IWC-89-55)

Prepared Discussion

472Hermann W. Pohland, E.I. du Pont de Nemours & Co., Inc., Wilmington, Delaware

PLC-BASED DISTRIBUTED CONTROLS: AN ECONOMICAL AND FLEXIBLE SOLUTION FORINDUSTRIAL WASTEWATER TREATMENT SYSTEMS

475James L. Dunn, Resources Conservation Company, Bellevue, Washington (IWC-89-56)

Prepared DiscussionMichael C. Skriba, Westinghouse Electric, Pittsburgh, Pennsylvania (Not published in this Proceedings.)

WEDNESDAY MORNING SESSION "C"UTILITY BOILERS

Session Chairman: Frank Gabrielli, Combustion Engineering, Windsor, ConnecticutDiscussion Leader: William R. Greenaway, Bechtel/KWU, Gaithersburg, Maryland

A REVIEW OF THE HISTORY OF IWC UTILITY POWER CYCLE CHEMISTRY

482F.J. Pocock, Consultant, Casselberry, Florida;N.J. Mravich, Babcock & Wilcox Company, Alliance, Ohio;A. Banweg, Babcock & Wilcox Company, Barberton, Ohio (IWC-89-45)

LOW PHOSPHATE-LOW SODIUM HYDROXIDE TREATMENT IN 2600 PSIG BOILERS ATSALT RIVER PROJECT'S CORONADO STATION

493Donald D. Goldstrohm, Thomas W. Robertson, Salt River Project, St. Johns, Arizona (IWC-89-46)

Prepared Discussion

: 500Douglas E. Noll, Consulting Engineer, Gibsonia, Pennsylvania

ON-LINE WATER CHEMISTRY MONITORING AT TWO FOSSIL FIRED ENEL POWER PLANTS,-OPERATED ACCORDING TO EPRI WATER CHEMISTRY GUIDELINES

504

Fabio Sigon, ENEL-DSR-CRTN, Milano, Italy;Giovanni Quadri, ENEL DCO/ULP, Piacenza, Italy;Giovanni Scalari, ENEL DPT/SAS, Pisa, Italy (IWC-89-47)

Prepared Discussion

: 525C.C. Stauffer, Babcock & Wilcox Company, Alliance, Ohio

HIDEOUT IN PWR STEAM GENERATORS DURING NORMAL OPERATION

529S.G. Sawochka, NWT Corporation, San Jose, California (IWC-89-48)

Prepared Discussion

535Gary E. Brobst, GEBCO Engineering, Inc., Los Altos, California;Gary Burns, NUS Corporation, Pittsburgh, Pennsylvania

WEDNESDAY AFTERNOON SESSION "A"ION EXCHANGE PROGRESS REPORTS

Session Chairman: Charles Dickert, Rohm and Haas Company, Philadelphia, Pennsylvania

A NEW RESIN SEPARATION SYSTEM FOR IMPROVED CONDENSATE POLISHER PERFORMANCEAT VIRGINIA POWER COMPANY'S SURRY NUCLEAR POWER STATION

541

Al Stengel, Virginia Power Company, Surry, Virginia;Jerome Earls, Radiological & Chemical Technology, Inc., San Jose, California;Stephen C. Foor, Illinois Water Treatment Company, Rockford, Illinois (IWC-89-49)

PERFORMANCE PROJECTIONS FOR ANION RESINS IN TWO BED DEMINERALIZERS

: 546

Michael C. Gottlieb, ResinTech, Inc., Cherry Hill, New Jersey MC-89-50)MECHANISM OF CRUD REMOVAL BY DEEP BED RESINS

552

Ichiro Inami, Hiroyuki Nagao, Toshiba Corporation, Kawasaki, Japan;Masahiro Nakamura, Toshiba Corporation, Yokohama, Japan;Hideo Kawazu, Ebara Corporation, Tokyo, Japan;Susumu Yoshikawa, Tokyo Electric Power Co., Inc., Tokyo, Japan (IWC-89-51)

CRUD REMOVAL CHARACTERISTICS OF NEWLY DEVELOPED ION EXCHANGE RESINS

558

Takeshi Izumi, Ebara Corporation, Kanagawa, Japan;Hideo Kawazu, Ebara Corporation, Tokyo, Japan;Yukio Hemmi, NAIG Nuclear Research Lab., Kanagawa, Japan;Masahiro Nakamura, Yoshitake Morikawa, Toshiba Corporation,Kanagawa, Japan;Susumu Yoshikawa, Tokyo Electric Power Company, Tokyo, Japan (IWC-89-52)

WEDNESDAY AFTERNOON SESSION "B"INSTRUMENTATION/ANALYTICAL III

Session Chairman: Connie Conboy, Mobay Corporation, Pittsburgh, PennsylvaniaDiscussion Leader: Wayne C. Micheletti, Electric Power Research Institute, Palo Alto, California

ICP PERFORMANCE FOR THE MEASUREMENT OF FOURTEEN TRACE METALS IN POWER PLANT WASTE STREAMS.... 566Raymond F. Maddalone, TRW, Redondo Beach, California;James K. Rice, Consultant, Olney, Maryland;Winston Chow, Electric Power Research Institute, Palo Alto, California (IWC-89-61)

Prepared Discussion

588

Dr. Robert J. Faust, Calgon Corporation, Pittsburgh, Pennsylvania

ADVANCES IN HIGH RANGE CONDUCTIVITY MEASUREMENT FOR WATER TREATMENT

590David M. Gray, E.W. Shaffer, Leeds & Northrup, North Wales, Pennsylvania (IWC-89-57)

Prepared Discussion

594Robert M. Ricker, Sentry Equipment Corp., Oconomowoc, Wisconsin

WEDNESDAY AFTERNOON SESSION "C"

MISCELLANEOUSSession Chairman: Jerry Printz, Stearns Roger, Denver, Colorado

Discussion Leader: D.R. Colman, Bechtel Power Corporation, El Segundo, California

NEW HIGH RATE FILTER

597Takeshi Iwatsuka, Japan Organo Company, Ltd., Tokyo, Japan (IWC-89-58)

Prepared Discussion

: 607J.D. Darji, Infilco Degremont Inc., Richmond, Virginia

INNOVATIVE PROCESSES PROVIDE COGENERATION POWER PLANT WITH THE ABILITY TO UTILIZE OIL FIELD WATERLarry W. VandeVenter, Infilco Degremont Inc., Richmond, Virginia;Michael W. Vera, Mt. Poso Cogeneration Plant, Bakersfield, California (IWC-89-59) (Not published in this Proceedings.)

Prepared Discussion 609R. Gregory Balmer, Exxon Research & Engineering Company, Florham Park, New Jersey

FLUSHING AND CHEMICALLY CLEANING NEW PIPING SYSTEMS 610Anthony D'Ippolito, Arizona Public Service Company, Phoenix, Arizona (IWC-89-60)

- -Prepared Discussion

: 620John Gatewood, Halliburton Industrial Services Division, Duncan, Oklahoma

1980 to 1989

Documents

Transcript of 1980 to 1989