14S1-MSE002-Crystal Structure 1.pdf
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7/25/2019 14S1-MSE002-Crystal Structure 1.pdf
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CRYSTAL STRUCTURE -1
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www.amiestudy.com
EXCELLENCE ACADEMY
Name: Arun J
Class Name: MSE002 Batch: 14 S1
http://www.amiestudy.com/http://www.amiestudy.com/ -
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Content
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Type of atomic bonding
Type of crystal lattices
Crystal structures in metallic materials
Methods to specify the directions and planes in
crystalline material
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Atomic bonding3
Materials are composed of atoms.
Each atoms are closely packed in some manner and
exerts forces on each other- attractive or repulsive.
When these forces are equal there exist a state of
equilibrium.
After that the energy required to separate two
atom is called bonding energy. The bonding are ofdifferent types mainly
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Primary bonding4
Ionic bond- Composed of metallic and
nonmetallic elements e.g. Li, Na, K and F, Cl ,
Br. Atoms of metallic element give up their
valence electrons to non metallic atoms andform stable.
This is non directional i.e. magnitude is equal in
all direction (+ve attracts all neighboring ve)
Bad conductor of electricity and temperature
because ions are held tightly.
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Continued5
Covalent bond- The central group of elements in
periodic table are not ready to give their valence
electrons because it is too large. Hence ionic bond is
not possible and so sharing of electrons in outermostshell take place and is called covalent bond.
It is directional because the centers of +ve and ve
charges are dispersed
Bad conductors of electricity and temperature
because outermost electrons are shared.
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Continued6
Metallic bond- Forms due to electrostatic force of
attraction between +ve ions and ve electron cloud of
same or different material.
It is non directional because +ve ion and electron cloud
take part in formation of bond.
These are good conductors of electricity and
temperature because of free electrons.
Secondary bond- Exist between virtually all atoms ormolecules along with primary bond . Usually seen in
elements or compounds where no electron transfer takes
place.
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Crystallography7
Atoms of some materials arrange themselves in
regular systematic pattern in three dimensions
called crystalline materials.
Space lattice- Crystalline material is formed whenatoms arrange in three dimensional pattern, in
which rows can be identified in various directions
along which atoms are regularly placed and the
centers of the atom are connected by straight lines.Then a network of lines are formed called space
lattice or crystal lattice.
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Continued
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Unit cell- In a crystal lattice the repetition of cells whichproduce the crystal can be identified called unit cell i.e.it is the building block of a crystal.
Unit cells for most crystal structures are parallelopipeds
or prism whose inter atomic spaces along three axis is a,b, c and inter axial angles are .
In a unit cell there are definite locations where atomsare positioned and these are called lattice points.
Depending upon the relation between latticeparameters they are classified into seven groups and isagain classified into 14 typed based on atomicarrangement.
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Continued9
Various arrangement includes
Lattice point at cell corners- simple
Lattice point at centre of two opposite faces in addition
to cell corners- base centered
Lattice point at centre of all the faces in addition to
corner.
Lattice point at body centre in addition to corner.
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Crystal system
ONLINE AMIE COACHING MATERIAL SCIENCE AND ENGINEERING
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Continued..
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C i d
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Continued..
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hank you
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References14
IP Singh, Material Science & Engineering ,Jain
Brothers New Delhi
Navneet Gupta, Material Science & Engineering,
Dhanpat Rai & Co New Delhi
Dr.S Jose, Metallurgy and material science ,
Pentagon Education Services , Kerala
EXCELLENCE ACADEMY MATERIAL SCIENCE AND ENGINEERING