14S1-MSE002-Crystal Structure 1.pdf

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    CRYSTAL STRUCTURE -1

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    EXCELLENCE ACADEMY

    Name: Arun J

    Class Name: MSE002 Batch: 14 S1

    http://www.amiestudy.com/http://www.amiestudy.com/
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    Content

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    Type of atomic bonding

    Type of crystal lattices

    Crystal structures in metallic materials

    Methods to specify the directions and planes in

    crystalline material

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    Atomic bonding3

    Materials are composed of atoms.

    Each atoms are closely packed in some manner and

    exerts forces on each other- attractive or repulsive.

    When these forces are equal there exist a state of

    equilibrium.

    After that the energy required to separate two

    atom is called bonding energy. The bonding are ofdifferent types mainly

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    Primary bonding4

    Ionic bond- Composed of metallic and

    nonmetallic elements e.g. Li, Na, K and F, Cl ,

    Br. Atoms of metallic element give up their

    valence electrons to non metallic atoms andform stable.

    This is non directional i.e. magnitude is equal in

    all direction (+ve attracts all neighboring ve)

    Bad conductor of electricity and temperature

    because ions are held tightly.

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    Continued5

    Covalent bond- The central group of elements in

    periodic table are not ready to give their valence

    electrons because it is too large. Hence ionic bond is

    not possible and so sharing of electrons in outermostshell take place and is called covalent bond.

    It is directional because the centers of +ve and ve

    charges are dispersed

    Bad conductors of electricity and temperature

    because outermost electrons are shared.

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    Continued6

    Metallic bond- Forms due to electrostatic force of

    attraction between +ve ions and ve electron cloud of

    same or different material.

    It is non directional because +ve ion and electron cloud

    take part in formation of bond.

    These are good conductors of electricity and

    temperature because of free electrons.

    Secondary bond- Exist between virtually all atoms ormolecules along with primary bond . Usually seen in

    elements or compounds where no electron transfer takes

    place.

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    Crystallography7

    Atoms of some materials arrange themselves in

    regular systematic pattern in three dimensions

    called crystalline materials.

    Space lattice- Crystalline material is formed whenatoms arrange in three dimensional pattern, in

    which rows can be identified in various directions

    along which atoms are regularly placed and the

    centers of the atom are connected by straight lines.Then a network of lines are formed called space

    lattice or crystal lattice.

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    Continued

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    Unit cell- In a crystal lattice the repetition of cells whichproduce the crystal can be identified called unit cell i.e.it is the building block of a crystal.

    Unit cells for most crystal structures are parallelopipeds

    or prism whose inter atomic spaces along three axis is a,b, c and inter axial angles are .

    In a unit cell there are definite locations where atomsare positioned and these are called lattice points.

    Depending upon the relation between latticeparameters they are classified into seven groups and isagain classified into 14 typed based on atomicarrangement.

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    Continued9

    Various arrangement includes

    Lattice point at cell corners- simple

    Lattice point at centre of two opposite faces in addition

    to cell corners- base centered

    Lattice point at centre of all the faces in addition to

    corner.

    Lattice point at body centre in addition to corner.

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    Crystal system

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    Continued..

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    C i d

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    Continued..

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    hank you

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    References14

    IP Singh, Material Science & Engineering ,Jain

    Brothers New Delhi

    Navneet Gupta, Material Science & Engineering,

    Dhanpat Rai & Co New Delhi

    Dr.S Jose, Metallurgy and material science ,

    Pentagon Education Services , Kerala

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