13/10/2011 MMPH-IHMK-Laboratori i Analitikes Mjedisore, Agron Shala.

13/10/2011 MMPH-IHMK-Laboratori i Analitikes Mjedisore, Agron Shala

Legal basis Law on hydro meteorological activity no. 2005 article 3

and 5/IV,XI,XII,XI,XVAdministrative Instruction for limited values of

effluents that discharges into water body and public sewage network 2008.

Water law 2004/24Directives of European Parliament and Council

2000/60/EC Directive on Environmental Impact Assessment

(85/337/EEC) Directive on Wastewater (86/278/EEC)Directive on Urban Wastewater Treatment (91/271/EEC)Directive on Nitrate (91/676/EEC); Prevention Directive and Integrated Pollution control

(96/61/EEC)


Network of water monitoring

Surface water - rivers - lakes - blunder - recreational

Underground waterUrban discharged water. industrial and fish farm



Draft Kod

Nr Id Z X Y Description TypeWAO

1 0 924 7431066.3151 4728976.8341 Drelaj Lumbardhi i Pejës 141

2 0 590 7443202.9577 4733372.1584 Radovc Burimi Radavci 121

3 0 496 7444604.3801 4723685.2432 Pejë-Dalje Lumbardhi i Pejës 142

4 0 678 7439247.7732 4712306.8347 Deçan-Hyrje Lumbardhi i Deçanit, 151

5 0 792 7437486.2457 4707033.2556 Jasiq Ereniku Jasiq 161

6 0 511 7457576.2722 4738971.8291 Burim i Istogut Burimi i Istogut, 111

7 0 403 7461510.4482 4726076.9641 Zllakuqan Lumi i Istgut 112

8 0 375 7464816.4405 4719461.9755 Klinë Lumi Klina, 132

9 0 383 7463205.9644 4716591.1183 Grabanicë Lumbardhi i Pejës 143

10 0 390 7465051.5176 4717241.3111 Klinë Drini i Badhë 121

11 0 346 7464230.2654 4709217.9065 Voljakë Mirusha Klinë 171

12 0 0 7560972.6300 4720469.1600 Cerpule Lumi Klina 131

13 0 442 7470926.2756 4698057.5590 Zhdrellë Lumi Rimnik 181

14 0 322 7466345.9015 4688390.6558 Xërxë Lumi Rimnik 182

15 0 332 7459543.8592 4691170.4941 Ura e Terzive Lumi Erenik 162

16 0 290 7471076.3207 4679498.9873 Gjonaj Drini i Bardhë 123

17 0 337 7473145.9395 4683221.1067 Piranë Lumi Toplluha 192

18 0 309 7471254.3772 4672695.9505 Vlashnje Lumbardhi i Prizrenit 202

19 0 289 7463356.0096 4670235.2130 Vermicë Drini i Badhë 124

20 0 0 7489818.9431 4692339.8470 Buqallë Lumi Toplluha 191

21 0 576 7499578.8738 4696432.0721 Shtime/Petrovë Lumi i Topillës 271

22 0 611 7493691.1082 4708602.7171 Baicë/Kroimir Lumi Drenica 261

23 0 668 7504356.3085 4691532.5991 Jezercë Lumi Nerodime 321

24 0 1544 7497767.3285 4669437.9760 Prevallë Lumbardhi i Prizrenit 201

25 0 1597 7496121.8384 4669135.8768 Prevallë Lepenc 311

26 0 359 7524576.3697 4666915.2124 Hani i Elezit Lepenc 313

27 0 470 7521173.3525 4676257.0143 Kaçanik Lepenc 312

PIKAT MONITORUESE PËR KUALITETIN E UJËRAVE SIPËRFAQËSOR

Datumi: Kosova Ref01


Draft Kod

Nr Id Z X Y Description TypeWAO

28 0 560 7516831.0497 4685787.8745 Gërlicë Lumi Nerodime 322

29 0 588 7510979.2962 4692473.8800 Bifurkacioni Lumi Nerodime

30 0 561 7511796.5397 4700558.3105 Bablak Sitnica 221

31 0 565 7507746.3263 4701137.4864 Muzeqinë Lumi Shtime 272

32 0 533 7529697.9077 4682670.9436 Shushtë/KorbuliqMorava e Binçës 411

33 0 502 7530444.1332 4691278.5246 Kllokot Morava e Binçës 412

34 0 494 7543149.9428 4698610.7224 Uglar Morava e Binçës 413

35 0 546 7509397.8213 4708132.5817 Lipjan Sitnica 222

36 0 543 7505052.5161 4718801.7818 Vragoli Sitnica 223

37 0 540 7504865.4607 4719374.9571 Vragoli Drenica 262

38 0 543 7505549.6670 4719030.8539 Vragoli Graçanka 251

39 0 545 7506985.0972 4720480.2838 Bresje Prishtevka 241

40 0 525 7503148.9443 4729692.0532 Plemetin Sitnica 224

41 0 552 7499216.7644 4739703.0497 Nedakovc Sitnica 226

42 0 553 7484464.3406 4747629.4349 Kushtovë Ibri 231

43 0 505 7489517.8547 4750731.3644 Mitrovicë Ibri 232

44 0 507 7490392.1188 4750843.3952 Mitrovicë Sitnica 225

45 0 506 7489492.8458 4751446.5734 Kelmend Ibri 233

46 0 536 7506368.9148 4731866.7031 Milloshevë Llapi 213

47 0 453 7551990.5984 4708051.5539 Domarovc Kriva reka 422

48 0 447 7552723.8162 4707424.3733 Domarovc Morava e Binçës 414

49 0 557 7533593.7500 4712884.6800 Zebince Kriva reka 412

50 0 480 7521217.3655 4676272.0258 Kaçanik Nerodime 323

51 749 7504005.1400 4771239.4800 Murgulle Llapi 211

52 599 7515879.6600 4750422.8000 Podujev Llapi 212

53 339 7462285.2100 4708849.9900 Kralan Lumbardhi i Deçanit, 152

54 550 7481762.4500 4702760.3800 Burimi-Baje e Malisheves Lumi Mirusha 172

PIKAT MONITORUESE PËR KUALITETIN E UJËRAVE SIPËRFAQËSOR

Datumi: Kosova Ref01

Dynamic

Rivers Resources 2 times for a year, April and August

(18)The others 11 times a year (36)

The othersAccording to requirements


Team and training

Team

1 specialist on water quality4 technic for three components, water, air and soil.

Training

Italy – FIRENZE-2003EU Project “Institutional Support for MESP”-2008/09Twining Project supported by EU-2010/11


Water pollution Industry;Mining;Urban water

discharge;Road traffic;Petroleum derivates;Agriculture lands;Waste deposited; Contamination

through wells;Septic tanks;LivestockCareless people;Natural pollution est.


Sampling

ISO 5667-6Working tools for taking samples Preparing measuring equipments for the

fieldPreparing of vesselsConservations TransportProtocolSaving



FORMULAR PËR MOSTRIMIT E UJËRAVE SIPËRFAQËSORE Marrja e mostrave dhe analiza fiziko- kimike e ujrave siperfaqesor nëe lumenjë, burime, liqej, ujerrjedha në teritorin e Republikës së Kosovës

Nr. I radhes : Emri I urdherdhënësi:

Mostruesi

Drejtimi I Marshutes mostruese

Data e mostrimit: Vendi (Lokacioni) Marrja e Mostres Matjet ne vendmostrim Vezhgimi i dukurive ne vendmostrim

N° Nacional I stacionit

Emri I stacionit Ora e

mostrimit Laboratori referent

Lloji I enes

mostruese

Temp. e ajrit

pH Temp. e ujit

O2 I tretur

Met

eoro

logj

ia

Duk

shm

eria

Ngj

yra

Aro

ma

Lym

i

Shk

uma

Gje

thet

Par

qitja

e

ngjra

ve t

e Y

lber

it

Niv

eli n

e m

Verejtje gjate mostrimit:

Ora e dorezimit Emri dhe nenshkri

Dorezuesi I mostrave Pergje. per mostrim Transportuesi

Veretje gjate analizave ne laborator Pranuesi I mostrave

ne laborator Pergj. I transportit

Pergj I pranimit te mostrave ne laborator


Vendemostrimi Volljak Kralan UraTerzive

Lumi Mirusha L.B.Deqanit Ereniku

nr Data 02.12.2011 simb. njësia 320 321 322

Param.Fizik

1 Ora h 0:0 12:05 12:20 13:30

2 Moti Mot Vroj vranët vranët vranët

3 Temp.ajrit TA C0

4 Temp.ujit Tu C0 10.1 10.3 9.6

5 Aroma Aro nuhat

6 Ngjyra Ngjy Co/Pt

7 Turbullira TUR NTU 8.00 29.3 40.2

8 Perq.Elektrike χ μScm 661 392 327

9 Mat.e tr.në ujë TDS mg/l 330 195 163

10 Përq.i jonit H pH 1-14 7.96 8.26 8.16

Par.Kimik

11 Oksigje. i tr. O2 mg/l 12.97 11.29 10.80

12 Ngop.me O2 O2 % 115.08 100.71 94.73

13 Mat. e susp. TSS mg/l 6.4 21.6 39.2

14 Shp.kim.i oks. SHKO mg/l 34.0 37.5 58.5

15 Shp.biok.i oks. SHBO5 mg/l 5.00 2.34 1.54

16 KarboniT.O TOC mg/l 5.1 7.4 9.3

17 Nitratet NO3- mg/l 5.9 0.9 3.8

18 Detergjentet SUR mg/l 0.0 0.0 0.0

19 Jonet nitrite NO2- mg/l 0.065 0.10 0.12

20 Joni i amonjak. NH4+ mg/l 0.09 0.41 0.14

21 Joni fosfat PO43- mg/l 0.025 0.041 0.057

22 Posfori total PT mg/l 0.020 0.028 0.012

23 Joni sulfat SO42- mg/l 39.64 16.84 17.94

Field measuring equipments


Measuring techniques

• Entitlement • Gravimeter• Electrochemical• Photometric• Spektrophotmetric VIS, UV, AA• GC with detector ECD and FID• IC


Measuring equipments


Perdoren metoda standarde sipas ISO US-standard methods EN DIN est.


Standard methods of work

Parameters on fieldSampling timeWeather pH valueWater Temp.Air Temp. BlurP. electricalTotal dissolved substancesThe amount of oxygen on water dissolvedWater with oxygen


Parameters that are determinate on laboratoryAnyoneCationTotal nitrogen Total phosphors Total alkalinePhenolFat and oilWater hardness, calcium, and magnezHeavy metals


AnyoneSulfates EPA 375.4 and US Stand. Meth 4500- SO42- E

Nitrate ISO 7890/1 dhe DIN 38405 D9

Nitrite EPA 354.1, US Method standard 4500-NO2-B, and method of DIN 26 777 D10

Klorure EPA 325.1 dhe US-Standard Method 45000-Cl-E.

Phosphates EPA 365.2+3, Metodat standarde të US 4500-P E and ISO 6878

Carbonates, Bicarbonates, and Hydroksider US Stan. Meth. 403


Kations

Ammoniac-EPA 350-1, US-Standard Methods 4500-NH3 D, ISO 7150/1 and DIN 38406 E5.

Calcium- ISS BEC 041 Magnesium- ISS.BEC.031.REV00


Hazardous materials –Heavy metals

Lead -Pb, ISS DAA 012

Chrome-Cr, ISS DAA 008

Cadmium -Cd, ISS DAA 007

Nickel-Ni, ISS DAA 014

Magana -Mn, ISS DAA 025

Copper-Cu, ISS DAA 009

Zinc-Zn, ISS DAA 049

Iron -Fe, ISS DAA 024


Drini i bardhë river basin


Lepenci river basin


Ibri river basin


Morava e Binqes river basin


Nutrient

NH4-N - EPA 350-1, US Stand. Meth.4500-NH3 D, ISO 7150/1 and DIN38406 E5

NOx –N - ISO 7890/1 dhe DIN 38405 D9 and EPA 354.1, US standard Methods 4500-NO2-B, DIN 26 777 D10

AT - EN ISO 11905-1

OF - EPA 365.2+3, US Stand. Meth 4500-P E and ISO 6878

FT - EPA 365.2+3, US Stand. Meth 4500-P E and ISO 6878


13/10/2011MMPH-IHMK-Laboratori i Analitikes Mjedisore, Agron Shala

Nutrient on Drini i Bardhë river basin -2009


Nutrient on Morava e Binces river basin and Lepenci river basin- 2009


Nutrient on Lepenci river basin - 2009

Analytical quality control

ISO 17025Control tablesCalibration curvesCertified solutions Metrology Software programs est.Laboratory tests


Control tables


Calibration curves


Lakorja e kalibrimit

y = 0.1983x + 0.0107

0

0.05

0.1

0.15

0.2

0.25

0.3

0.35

0.4

0.45

0 0.5 1 1.5 2 2.5

Perqendrimi

Abs

orba

nca

absorbanca Linear (absorbanca)

Certified solutions


Laboratory testsNational International


Underground waterPilot projekti I vitit 2009, BE-GFAFrom data in 81-82TUN221 local wells 2 primary resources of riversFrom chemical analysis has result that 60% of

wells have been contaminated by different parameters.


Thank you for y

our atta

ntion


13/10/2011 MMPH-IHMK-Laboratori i Analitikes Mjedisore, Agron Shala.

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Transcript of 13/10/2011 MMPH-IHMK-Laboratori i Analitikes Mjedisore, Agron Shala.