1.2 Hazards Inherit to Oil and Gas

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    NEBOSH, International Certificate in Oil & Gas

    Operational SafetyModule 1.2 Hazards Inherit to Oil and Gas

    FLASH POINTThe flash point of a

    volatile liquid is the

    lowest temperature at

    which it can vaporize to

    form an ignitable

    mixture in air

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    VAPOUR DENSITY

    The ratio of the weight of a given volume of one gas

    to the weight of an equal volume of another gas,

    typically hydrogen, at the same temperature and

    pressure.

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    VAPOUR PRESSUREA measure of the

    tendency of a material to

    form a vapour. The

    higher the vapour

    pressure, the higher the

    potential vapour

    concentration.

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    FLAMMABLEEasily ignitable and

    capable of burning

    rapidly. Flash point of

    between 21 degrees C

    and 55 degrees C

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    HIGHLY FLAMMABLEA liquid that has a flash

    point of less than 21

    degrees C.

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    FLAMMABLE RANGE:The percentage of

    either flammable

    vapour or gasconcentration in the

    ambient air at which

    combustion will take

    place.

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    FLAMMABLE LIMITSThe Flammable Limits refer to the conditions under

    which a mixture of a flammable material and air

    may catch fire or explode. If the percentage offlammable material in the air is between the

    minimum and maximum limits, the presence of a

    flame or a source of ignition is likely to lead to rapid

    combustion or explosion

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    UFL & LFLUFL - The mixture of substance and air is too rich in

    fuel (deficient in oxygen) to burn. This is sometimes

    called the upper explosive limit (UEL).

    LFL - the mixture of substance and air lacks

    sufficient fuel (substance) to burn. This issometimes called the lower explosive limit (LEL).

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    TOXICITYToxicity is the degree to

    which a substance can

    damage an organism

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    SKIN IRRITANT A noninfective agent,

    physical or chemical,

    caplable of causing celldamage if applied to

    the skin for sufficient

    time

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    CarcinogensThese are substances which are believed to cause

    cancer. They fall into 2 groups:

    Geno-Toxic: May cause damage to DNA

    Non Geno-Toxic: Does not cause damage to DNA

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    PRODUCT PROPERTIES HAZARDS

    HYDROGEN Colourless, Odourless

    Gas, lighter than air

    Fire

    Explosion

    METHANE Colourless, Odourless

    Gas, lighter than air

    Fire

    Explosion

    Narcotic properties

    LPG, LNG Colourless, Odourless

    Gas, lighter than air

    Fire

    Explosion

    H2S Colourless, distinctivesmell of rotten eggs

    ExplosiveToxic

    Corrosive

    NITROGEN (GAS) Colourless odourless gas Asphyxiation by removal of

    air from O2

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    MERCAPTANSMercaptans are a group of sulfur-containing organic

    chemical substances. They smell like rotting

    cabbage. They are used as an odourizing agent innatural gas.

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    ADDITAVES:Anti-foaming agents are used to speed up the

    removal of gas bubbles in crude oil. Gas bubbles

    can effect production quality and efficiency

    Corrosion inhibitors: A corrosion inhibitor is a

    chemical compound that, when added to a liquid orgas, decreases the corrosion rate of a material,

    typically a metal

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    SLUDGESLow Specific Activity Sludges are naturally occurring

    radioactive material

    Other sludges may be produces as a result of the

    process. They are a mixture of liquid and suspended

    material

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    SLUDGES HAZARDS

    Chemical

    Skin irritant

    Radiation

    Carcinogenic

    Environmental

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    MICRO BIOCIDESUsed to disinfect inanimate objects such as steel

    pipes. This slows down and prevents corrosion.

    They are also used in A/C units to prevent legionella

    They are toxic by ingestion

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    MUD

    SEE HANDOUT