1.1 Product identifier 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1...

EU/EECAccording to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)

Safety Data Sheet

Section 1: Identification of the Substance/Mixture and of the Company/Undertaking

1.1 Product identifierProduct Name • #150 Natural Flavor nondiacetyl1.2 Relevant identified uses of the substance or mixture and uses advised againstRelevant identified use(s) • Flavor

1.3 Details of the supplier of the safety data sheetManufacturer • DairyChem

9120 Technology Drive Fishers, IN 46038 United States www.dairychem.com

Telephone (General) • 3178498400

1.4 Emergency telephone numberManufacturer • 8004249300 CHEMTREC

Section 2: Hazards Identification

2.1 Classification of the substance or mixtureCLP • Skin Sensitization 1 H317DSD/DPD • Irritant (Xi)

R432.2 Label ElementsCLP

WARNING

Hazard statements • H317 May cause an allergic skin reaction

Precautionary statementsPrevention • P261 Avoid breathing mists, vapours, and/or spray.

P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves .

Response • P302+P352 IF ON SKIN: Wash with plenty of soap and water. P363 Wash contaminated clothing before reuse. P321 Specific treatment, see supplemental first aid information. P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

#150 Natural Flavor non-diacetyl#150 Natural Flavor non-diacetyl#150 Natural Flavor non-diacetyl#150 Natural Flavor non-diacetyl

Preparation Date: 26/August/2015Preparation Date: 26/August/2015Preparation Date: 26/August/2015Preparation Date: 26/August/2015Revision Date: 26/August/2015Revision Date: 26/August/2015Revision Date: 26/August/2015Revision Date: 26/August/2015

Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)EU CLP, EU DSD/DPD, OSHA HCS 2012EU CLP, EU DSD/DPD, OSHA HCS 2012EU CLP, EU DSD/DPD, OSHA HCS 2012EU CLP, EU DSD/DPD, OSHA HCS 2012

of 20Page 1 of 20Page 1 of 20Page 1 of 20

United States (US) According to: OSHA 29 CFR 1910.1200 HCS

Storage/Disposal • P501 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

DSD/DPD

Risk phrases • R43 May cause sensitisation by skin contact. Safety phrases • S24 Avoid contact with skin.

S37 Wear suitable gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

2.3 Other HazardsCLP • According to Regulation (EC) No. 1272/2008 (CLP) this material is considered

hazardous. DSD/DPD • According to European Directive 1999/45/EC this material is considered dangerous.

2.1 Classification of the substance or mixtureOSHA HCS 2012 • Skin Irritation 2

Skin Sensitization 1 Serious Eye Damage 1

2.2 Label elementsOSHA HCS 2012

DANGER

Hazard statements • Causes skin irritation May cause an allergic skin reaction Causes serious eye damage

Precautionary statementsPrevention • Avoid breathing mists, vapours, and/or spray.

Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection.

Response • If on skin: Wash with plenty of water . Take off contaminated clothing and wash before reuse. Specific treatment, see supplemental first aid information. If skin irritation or rash occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Storage/Disposal • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.

2.3 Other hazardsOSHA HCS 2012 • Under United States Regulations (29 CFR 1910.1200 Hazard Communication

Standard), this product is considered hazardous.





See Section 16 for full text of Hstatements and Rphrases.

Section 3 Composition/Information on Ingredients

3.1 Substances

• Material does not meet the criteria of a substance.

3.2 Mixtures

CompositionChemical Name Identifiers % LD50/LC50 Classifications According to

Regulation/Directive Comments

Natural flavor Proprietary 0.998% TO 3%

Ingestion/OralRat LD50 • 3310 mg/kgSkinRabbit LD50 • 1060 mg/kgInhalationRat LC50 • 11000 mg/m³ 4 Hour(s)

EU DSD/DPD: Annex VI, Table 3.2: R10; C, R35 EU CLP: Annex VI, Table 3.1: Flam. Liq. 3, H226; Skin Corr. 1A, H314 OSHA HCS 2012: Flam. Liq. 3; Acute Tox. 4 (Skn); Acute Tox. 4 (Inhl); Skin Corr. 1B; Eye Dam. 1

NDA

2,3Pentanedione

CAS:600146 EINECS:2099848

0.98% TO 1%

Ingestion/OralRat LD50 • 3 g/kgSkinRabbit LD50 • >2500 mg/kg

EU DSD/DPD: Xi; R36/37/38; R43 EU CLP: Eye Irrit. 2, H319; Skin Irrit. 2, H315; STOT SE 3: Resp. Irrit., H335; Skin Sens. 1, H317 OSHA HCS 2012: Eye Irrit. 2A; Skin Irrit. 2; STOT SE 3: Resp. Irrit.; Skin Sens. 1

NDA

Natural flavor Proprietary < 1%

Ingestion/OralRat LD50 • 2600 mg/kgSkinRabbit LD50 • 500 µL/kgInhalationRat LC50 • >4900 mg/m³ 4 Hour(s)

EU DSD/DPD: Annex VI, Table 3.2: C, R34 EU CLP: Annex VI, Table 3.1: Skin Corr. 1B, H314 OSHA HCS 2012: Flam. Liq. 3; Skin Corr. 1B; Eye Dam. 1; Acute Tox. 3 (skn)

NDA


Ingestion/OralRat LD50 • 1850 mg/kgSkinRabbit LD50 • >20 mL/kgInhalationRat LC50 • 28950 mg/m³

EU DSD/DPD: Annex VI, Table 3.2: F, R11; Xn, R20/22; Xi, R36/37 EU CLP: Annex VI, Table 3.1: Flam. Liq. 2, H225; Acute Tox. 4, H332; Acute Tox. 4, H302; Eye Irrit. 2, H315; STOT SE 3: Resp. Irrit., H335 OSHA HCS 2012: Flam. Liq. 2; Acute Tox. 4 (orl); STOT SE 3: Narc.; Eye Irrit. 2A; STOT SE 3: Resp. Irrit.

NDA


Ingestion/OralRat LD50 • >5 g/kgSkinRabbit LD50 • >5 g/kg

EU DSD/DPD: Xi; R36/38 EU CLP: Eye Irrit. 2, H319; Skin Irrit. 2, H315 OSHA HCS 2012: Eye Irrit. 2A; Skin Irrit. 2

NDA

Natural flavor Proprietary < 1% NDA

EU DSD/DPD: R10, Xi, R36/38 EU CLP: Flam. Liq. 3, H226; Skin Irrit. 2, H315; Eye Irrit. 2, H319 OSHA HCS 2012: Flam. Liq. 3; Skin Irrit. 2; Eye Irrit. 2

NDA


Ingestion/OralRat LD50 • 5620 mg/kgSkinRabbit LD50 • >20 mL/kgInhalationRat LC50 • 1600 ppm 8 Hour(s)

EU DSD/DPD: Annex VI, Table 3.2: F, R11; Xi, R36; R66; R67 EU CLP: Annex VI, Table 3.1: Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3: Narc., H336 OSHA HCS 2012: Flam. Liq. 2; Eye Irrit. 2

NDA





Section 4 First Aid Measures

4.1 Description of first aid measuresInhalation • IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing.

Skin • In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Take off contaminated clothing and wash before reuse. If irritation develops and persists, get medical attention.

Eye • In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. If eye irritation persists: Get medical advice/attention.

Ingestion • Do not use mouthtomouth method if victim ingested the substance.

4.2 Most important symptoms and effects, both acute and delayed• Refer to Section 11 Toxicological Information.

4.3 Indication of any immediate medical attention and special treatment neededNotes to Physician • All treatments should be based on observed signs and symptoms of distress in the

patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred.

Section 5 Firefighting Measures

5.1 Extinguishing mediaSuitable Extinguishing Media • LARGE FIRE: Water spray, fog or regular foam.

SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media

• No data available.

5.2 Special hazards arising from the substance or mixtureUnusual Fire and Explosion Hazards

• Containers may explode when heated. Some of these materials may burn, but none ignite readily.

Hazardous Combustion Products

• No data available.

5.3 Advice for firefighters• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Wear positive pressure selfcontained breathing apparatus (SCBA).

Section 6 Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency proceduresPersonal Precautions • Ventilate enclosed areas. Do not walk through spilled material. Wear appropriate

personal protective equipment, avoid direct contact. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Emergency Procedures • As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Stay upwind. Keep out of low areas. Keep unauthorized personnel away.

6.2 Environmental precautions• Avoid release to the environment.

6.3 Methods and material for containment and cleaning up





Containment/Cleanup Measures

• Stop leak if you can do it without risk. SMALL SPILLS: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. LARGE SPILLS: Dike far ahead of spill for later disposal.

6.4 Reference to other sections• Refer to Section 8 Exposure Controls/Personal Protection and Section 13 Disposal Considerations.

Section 7 Handling and Storage

7.1 Precautions for safe handlingHandling • Use only with adequate ventilation. Wear appropriate personal protective equipment,

avoid direct contact. Avoid breathing mist, vapors, spray. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco.

7.2 Conditions for safe storage, including any incompatibilitiesStorage • Store in a wellventilated place. Keep container tightly closed.

7.3 Specific end use(s)• Refer to Section 1.2 Relevant identified uses.

Section 8 Exposure Controls/Personal Protection

8.1 Control parametersExposure Limits/Guidelines

Result ACGIH Canada Ontario Canada Quebec China Denmark

Natural flavor (Proprietary)

STELs 15 ppm STEL 15 ppm STEL 15 ppm STEV; 37 mg/m3 STEV 20 mg/m3 STEL Not established

TWAs 10 ppm TWA 10 ppm TWA 10 ppm TWAEV; 25 mg/m3 TWAEV 10 mg/m3 TWA 10 ppm TWA; 25

mg/m3 TWA


STELs Not established Not established Not established 60 mg/m3 STEL Not established


mg/m3 TWA


STELs Not established Not established Not established 300 mg/m3 STEL Not established


mg/m3 TWA


TWAs Not established 100 ppm TWA 100 ppm TWAEV; 303 mg/m3 TWAEV Not established 100 ppm TWA; 300

mg/m3 TWA

STELs 100 ppm STEL Not established Not established Not established Not established

Exposure Limits/Guidelines (Con't.)Result Germany DFG Germany TRGS NIOSH OSHA

TWAs Not established

10 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2); 25 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be

10 ppm TWA; 25 mg/m3 TWA







excluded when AGW and BGW values are observed, exposure factor 2)

STELs Not established Not established 15 ppm STEL; 37 mg/m3 STEL Not established

Ceilings 20 ppm Peak; 50 mg/m3 Peak Not established Not established Not established

MAKs 10 ppm TWA MAK; 25 mg/m3 TWA MAK Not established Not established Not established


STELs Not established Not established 15 ppm STEL; 45 mg/m3 STEL Not established


10 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2); 31 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2)

10 ppm TWA; 30 mg/m3 TWA Not established





400 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2); 1500 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2)





100 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed,






TWAs Not established exposure factor 1); 310 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 1)





Exposure Control Notations

ACGIH •Natural flavor (Proprietary): Carcinogens: (A4 Not Classifiable as a Human Carcinogen) Germany TRGS •Natural flavor (Proprietary): Skin: (skin notation) Germany DFG •Natural flavor (Proprietary): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) •Natural flavor (Proprietary): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) •Natural flavor (Proprietary): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) •Natural flavor (Proprietary): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) | Skin: (skin notation)

Exposure Limits Supplemental

ACGIH •Natural flavor (Proprietary): TLV Basis Critical Effects: (eye and upper respiratory tract irritation; pulmonary function) •Natural flavor (Proprietary): TLV Basis Critical Effects: (eye and upper respiratory tract irritation) •Natural flavor (Proprietary): TLV Basis Critical Effects: (eye, skin and upper respiratory tract irritation) •Natural flavor (Proprietary): TLV Basis Critical Effects: (upper respiratory tract irritation)

8.2 Exposure controlsEngineering Measures/Controls

• Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Personal Protective EquipmentRespiratory • If occupational limits are exceeded, use a NIOSH/MSHA approved

chemical/mechanical respirator designed to remove a combination of particulate and organic vapor. Observe OSHA regulations (29 CFR 1910.134) for respirator use. Prolonged exposure to vapors may cause lung disease.

Eye/Face • Wear chemical splash safety goggles.Skin/Body • Wear appropriate gloves.

Environmental Exposure Controls

• Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Follow best practice for site management and disposal of waste.

Key to abbreviations

ACGIH =American Conference of Governmental Industrial Hygiene STEL = Short Term Exposure Limits are based on 15minute exposures

MAK =Maximale Arbeitsplatz Konzentration is the maximum permissible concentration STEV = Short Term Exposure Value

NIOSH = National Institute of Occupational Safety and Health TLV =Threshold Limit Value determined by the American Conference of Governmental Industrial Hygienists (ACGIH)

OSHA = Occupational Safety and Health Administration TWA = TimeWeighted Averages are based on 8h/day, 40h/week exposures





Section 9 Physical and Chemical Properties

9.1 Information on Physical and Chemical PropertiesMaterial Description Physical Form Liquid Appearance/Description Light yellow to dark yellow liquid.Color Light yellow to dark yellow. Odor Data lackingOdor Threshold Data lacking General Properties Boiling Point > 70 C(> 158 F) Melting Point/Freezing Point Data lackingDecomposition Temperature Data lacking pH 2.75 to 3.25Specific Gravity/Relative Density Data lacking Density 0.98 to 1.02 g/mLWater Solubility Appreciable 10 to 99 % Viscosity Data lackingExplosive Properties Data lacking Oxidizing Properties: Data lackingVolatility Vapor Pressure Data lacking Vapor Density Data lackingEvaporation Rate Data lacking Flammability Flash Point > 100 C(> 212 F) UEL Data lackingLEL Data lacking Autoignition Data lackingFlammability (solid, gas) Data lacking Environmental Octanol/Water Partition coefficient Data lacking

9.2 Other Information• No additional physical and chemical parameters noted.

Section 10: Stability and Reactivity

10.1 Reactivity• No dangerous reaction known under conditions of normal use.

10.2 Chemical stability• Stable under normal temperatures and pressures.

10.3 Possibility of hazardous reactions• Hazardous polymerization will not occur.

10.4 Conditions to avoid• No data available.

10.5 Incompatible materials• No data available.

10.6 Hazardous decomposition products• No data available.

Section 11 Toxicological Information

11.1 Information on toxicological effects





Components

Natural flavor (0.998% TO 3%)

Proprietary

Acute Toxicity: Ingestion/OralRat LD50 • 3310 mg/kg; Ingestion/OralHuman TDLo • 1470 µg/kg; Gastrointestinal:Change in structure or function of esophagus; Gastrointestinal:Ulceration or bleeding from small intestine; Gastrointestinal:Ulceration or bleeding from large intestine; InhalationRat LC50 • 11000 mg/m³ 4 Hour(s); InhalationMouse TCLo • 12 ppm 6 Minute(s); Lungs, Thorax, or Respiration:Respiratory depression; SkinRabbit LD50 • 1060 mg/kg; SkinRat TDLo • 0.25 mg/kg; Gastrointestinal:Ulceration or bleeding from dlodenum; Irritation: EyeRabbit • 5 mg 30 Second(s)Rinse • Mild irritation; SkinHuman • 50 mg 24 Hour(s) • Mild irritation; SkinRabbit • 525 mgOpen • Severe irritation; Multidose Toxicity: InhalationRat TCLo • 5070 µg/m³ 24 Hour(s) 95 Day(s)Continuous; Kidney, Ureter, and Bladder:Other changes in urine composition; Blood:Changes in leucocyte (WBC) count; Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels:True cholinesterase; Mutagen: Unscheduled DNA synthesis • SkinMouse • 79279 µg/kg; Other mutation test systems • SkinMouse • 1201 mg/kg; Tumorigen / Carcinogen: Ingestion/OralRat TDLo • 5760 mg/kg 32 Week(s)Intermittent; Tumorigenic:Equivocal tumorigenic agent by RTECS criteria; Gastrointestinal:Tumors; Tumorigenic:Facilitates action of known carcinogen

2,3Pentanedione (0.98% TO 1%)

600146 Acute Toxicity: SkinRabbit LD50 • >2500 mg/kg; Irritation: SkinRabbit • 500 mg 24 Hour(s) • Moderate irritation

Natural flavor (< 1%) Proprietary

Acute Toxicity: Ingestion/OralRat LD50 • 5620 mg/kg; InhalationRat LC50 • 200 g/m³; Behavioral:Somnolence (general depressed activity); Lungs, Thorax, or Respiration:Acute pulmonary edema; Gastrointestinal:Changes in structure or function of salivary glands; SkinRabbit LD50 • >20 mL/kg; Irritation: EyeHuman • 400 ppm; Multidose Toxicity: InhalationRat TCLo • 1500 ppm 90 Day(s)Intermittent; Sense Organs and Special Senses:Olfaction:Change in sensation of smell; Sense Organs and Special Senses:Olfaction:Other changes


Acute Toxicity: Ingestion/OralRat LD50 • 2600 mg/kg; InhalationRat LC50 • >4900 mg/m³ 4 Hour(s); SkinRabbit LD50 • 500 µL/kg; Irritation: EyeRabbit • 990 µg • Severe irritation; SkinRabbit • 495 mgOpen • Severe irritation; Multidose Toxicity: InhalationRat TCLo • 23 mg/m³ 24 Hour(s) 30 Day(s)Continuous; Brain and Coverings:Recordings from specific areas of CNS; Blood:Changes in erythrocyte (RBC) count; Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels:True cholinesterase


Acute Toxicity: Ingestion/OralRat LD50 • >5 g/kg; SkinRabbit LD50 • >5 g/kg; Irritation: SkinRabbit • 500 mg 24 Hour(s) • Moderate irritation; Multidose Toxicity: Ingestion/OralRat TDLo • 66 g/kg 13 Week(s)Continuous; Liver:Changes in liver weight; Blood:Normocytic anemia; Nutritional and Gross Metabolic:Gross Metabolite Changes:Weight loss or decreased weight gain; Reproductive: Ingestion/OralRat TDLo • 12600 mg/kg (42D male); Reproductive Effects:Paternal Effects:Testes, epididymis, sperm duct


Acute Toxicity: Ingestion/OralRat LD50 • 1850 mg/kg; Behavioral:Somnolence (general depressed activity); Lungs, Thorax, or Respiration:Dyspnea; InhalationRat LC50 • 28950 mg/m³; SkinRabbit LD50 • >20 mL/kg; Irritation: SkinRabbit • 460 mgOpen • Mild irritation; Multidose Toxicity: Ingestion/OralRabbit TDLo • 619 mg/kg 13 Week(s)Intermittent; Kidney, Ureter, and Bladder:Interstitial nephritis; Kidney, Ureter, and Bladder:Proteinuria; Blood:Other changes; Tumorigen / Carcinogen: SkinMouse TDLo • 110 g/kg 9 Week(s)Intermittent; Tumorigenic:Equivocal tumorigenic agent by RTECS criteria; Skin and Appendages:Other:Tumors

Natural flavor (< 1%) Proprietary Irritation: SkinRabbit • 500 mg 24 Hour(s) • Moderate irritation

GHS Properties Classification

Respiratory sensitizationEU/CLP • Data lacking OSHA HCS 2012 • Data lacking





Serious eye damage/IrritationEU/CLP • Data lacking OSHA HCS 2012 • Serious Eye Damage 1

Acute toxicityEU/CLP • Data lacking OSHA HCS 2012 • Data lacking

Aspiration HazardEU/CLP • Data lacking OSHA HCS 2012 • Data lacking

CarcinogenicityEU/CLP • Data lacking OSHA HCS 2012 • Data lacking

Skin corrosion/IrritationEU/CLP • Data lacking OSHA HCS 2012 • Skin Irritation 2

Skin sensitizationEU/CLP • Skin Sensitizer 1 OSHA HCS 2012 • Skin Sensitizer 1

STOTREEU/CLP • Data lacking OSHA HCS 2012 • Data lacking

STOTSEEU/CLP • Data lacking OSHA HCS 2012 • Data lacking

Toxicity for ReproductionEU/CLP • Data lacking OSHA HCS 2012 • Data lacking

Germ Cell MutagenicityEU/CLP • Data lacking OSHA HCS 2012 • Data lacking

Potential Health EffectsInhalationAcute (Immediate) • Product is irritating and possibly detrimental to the respiratory system. Inhalation

symptoms may include sore throat, coughing, dullness, and unconsciousness.Chronic (Delayed) • Prolonged exposure to high concentrations may cause lung damage or disease.

SkinAcute (Immediate) • Product is irritating to the skin. May cause skin sensitization. Symptoms include

redness, and skin rash.Chronic (Delayed) • No data available.

EyeAcute (Immediate) • Product is irritating to the eyes.Chronic (Delayed) • No data available.

IngestionAcute (Immediate) • Product is harmful if swallowed. Symptoms of ingestion may include sore throat and

abdominal pain.Chronic (Delayed) • No data available.

Key to abbreviationsLC = Lethal ConcentrationLD = Lethal DoseTC= Toxic ConcentrationTD= Toxic Dose

Section 12 Ecological Information

12.1 Toxicity





• Material data lacking.

12.2 Persistence and degradability• Material data lacking.

12.3 Bioaccumulative potential• Material data lacking.

12.4 Mobility in Soil• Material data lacking.

12.5 Results of PBT and vPvB assessment• No PBT and vPvB assessment has been conducted.

12.6 Other adverse effects• No studies have been found.

Section 13 Disposal Considerations

13.1 Waste treatment methodsProduct waste • Dispose of content and/or container in accordance with local, regional, national, and/or

international regulations.Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or

international regulations.

Section 14 Transport Information

14.1 UN number

14.2 UN proper shipping name

14.3 Transport hazard class(es)

14.4 Packing group

14.5 Environmental hazards

DOT NDA Not Regulated NDA NDA NDA

IMO/IMDG NDA Not Regulated NDA NDA NDA

IATA/ICAO NDA Not Regulated NDA NDA NDA

14.6 Special precautions for user

• None specified.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

• Data lacking.

Section 15 Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureSARA Hazard Classifications • Acute

State Right To KnowComponent CAS MA NJ PA

2,3Pentanedione 600146 No No No

Natural flavor Proprietary No Yes No

Natural flavor Proprietary Yes Yes Yes







Natural flavor Proprietary Yes No Yes


Water 7732185 No No No

InventoryComponent CAS Canada DSL Canada NDSL China EU EINECS EU ELNICS

2,3Pentanedione 600146 Yes No Yes Yes No

Natural flavor Proprietary Yes No Yes Yes No






Water 7732185 Yes No Yes Yes No

Inventory (Con't.)Component CAS Japan ENCS Korea KECL TSCA

2,3Pentanedione 600146 Yes Yes Yes







Water 7732185 No Yes Yes

AustraliaLabor

Australia Work Health and Safety Regulations Hazardous Substances Requiring Health Monitoring

• Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Water 7732185 Not Listed

Australia High Volume Industrial Chemicals List

• Natural flavor Proprietary • Natural flavor Proprietary Not Listed • Natural flavor Proprietary • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Water 7732185





Australia List of Designated Hazardous Substances Classification

• Natural flavor Proprietary C R10, R35 • Natural flavor Proprietary C R34 • Natural flavor Proprietary F, Xi R11, R36, R66, R67 • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary F, Xn, Xi R11, R20/22, R36/37 • Water 7732185 Not Listed

Environment Australia National Pollutant Inventory (NPI) Substance List

• Natural flavor Proprietary 10 tonne/yr Threshold category 1

• Natural flavor Proprietary Not Listed

• Natural flavor Proprietary 10 tonne/yr Threshold category 1

• 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Water 7732185 Not Listed

Australia Ozone Protection Act Scheduled Substances


Australia Priority Existing Chemical Program


CanadaLabor

Canada WHMIS Classifications of Substances

• Natural flavor Proprietary

B3, E (including 1080% [Available data does not allow a precise evaluation of the threshold concentration from which solutions meet the B3 criterion], >80%); D2B (310%)





• Natural flavor Proprietary B3, D1B, E • Natural flavor Proprietary B2 • 2,3Pentanedione 600146 B2, D2B

• Natural flavor Proprietary Uncontrolled product according to WHMIS classification criteria

• Natural flavor Proprietary Not Listed • Natural flavor Proprietary B2, D2B

• Water 7732185 Uncontrolled product according to WHMIS classification criteria

Canada WHMIS Ingredient Disclosure List

• Natural flavor Proprietary 1 % • Natural flavor Proprietary 1 % • Natural flavor Proprietary 1 % • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary 1 % • Natural flavor Proprietary 1 % • Natural flavor Proprietary 1 % • Water 7732185 Not Listed

Environment Canada CEPA Priority Substances List


EuropeOther

EU CLP (1272/2008) Annex VI Table 3.2 Classification

• Natural flavor Proprietary R10 C; R35 • Natural flavor Proprietary C; R34 • Natural flavor Proprietary F; R11 Xi; R36 R66 R67 • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary F; R11 Xn; R20/22 Xi; R36/37 • Water 7732185 Not Listed

EU CLP (1272/2008) Annex VI Table 3.2 Concentration Limits

• Natural flavor Proprietary 10%<=C<25%: Xi; R:36/38 90%<=C: C; R:35 25%<=C<90%: C; R:34

• Natural flavor Proprietary 10%<=C<25%: Xi; R:36/37/38 25%<=C: C; R:34

• Natural flavor Proprietary Not Listed • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed





• Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Water 7732185 Not Listed

EU CLP (1272/2008) Annex VI Table 3.2 Labelling

• Natural flavor Proprietary C R:1035 S:(1/2)232645 • Natural flavor Proprietary C R:34 S:(1/2)233645

• Natural flavor Proprietary F Xi R:11366667 S:(2)162633

• 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed

• Natural flavor Proprietary F Xn R:1120/2236/37 S:(2)916242633

• Water 7732185 Not Listed

EU CLP (1272/2008) Annex VI Table 3.2 Notes Substances and Preparations

• Natural flavor Proprietary B • Natural flavor Proprietary B • Natural flavor Proprietary Not Listed • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Water 7732185 Not Listed

EU CLP (1272/2008) Annex VI Table 3.2 Safety Phrases

• Natural flavor Proprietary S:(1/2)232645 • Natural flavor Proprietary S:(1/2)233645 • Natural flavor Proprietary S:(2)162633 • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary S:(2)916242633 • Water 7732185 Not Listed

United StatesLabor

U.S. OSHA Process Safety Management Highly Hazardous Chemicals


U.S. OSHA Specifically Regulated Chemicals• Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed






Environment U.S. CAA (Clean Air Act) 1990 Hazardous Air Pollutants


U.S. CERCLA/SARA Hazardous Substances and their Reportable Quantities

• Natural flavor Proprietary 5000 lb final RQ; 2270 kg final RQ




U.S. CERCLA/SARA Radionuclides and Their Reportable Quantities


U.S. CERCLA/SARA Section 302 Extremely Hazardous Substances EPCRA RQs


U.S. CERCLA/SARA Section 302 Extremely Hazardous Substances TPQs• Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed






U.S. CERCLA/SARA Section 313 Emission Reporting


U.S. CERCLA/SARA Section 313 PBT Chemical Listing


U.S. RCRA (Resource Conservation & Recovery Act) Basis for Listing Appendix VII

• Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed

• Natural flavor Proprietary Included in waste stream: F039


U.S. RCRA (Resource Conservation & Recovery Act) Phase 4 LDR Rule Universal Treatment Standards

• Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed

• Natural flavor Proprietary 0.34 mg/L (wastewater); 33 mg/kg (nonwastewater)


U.S. RCRA (Resource Conservation & Recovery Act) U Series Wastes Acutely Toxic Wastes & Other Hazardous Characteristics• Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed

• Natural flavor Proprietary waste number U112 (Ignitable waste)

• 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed





• Natural flavor Proprietary Not Listed • Water 7732185 Not Listed

United States CaliforniaEnvironment

U.S. California Proposition 65 Carcinogens List


U.S. California Proposition 65 Developmental Toxicity


U.S. California Proposition 65 Maximum Allowable Dose Levels (MADL)


U.S. California Proposition 65 No Significant Risk Levels (NSRL)


U.S. California Proposition 65 Reproductive Toxicity Female• Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed





• Water 7732185 Not Listed

U.S. California Proposition 65 Reproductive Toxicity Male


United States PennsylvaniaLabor

U.S. Pennsylvania RTK (Right to Know) Environmental Hazard List

• Natural flavor Proprietary • Natural flavor Proprietary • Natural flavor Proprietary • 2,3Pentanedione 600146 Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Natural flavor Proprietary Not Listed • Water 7732185 Not Listed

U.S. Pennsylvania RTK (Right to Know) Special Hazardous Substances


15.2 Chemical Safety Assessment• No Chemical Safety Assessment has been carried out.

Section 16 Other Information

Relevant Phrases (code & full text)• H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H302 Harmful if swallowed H314 Causes severe skin burns and eye damage. H315 Causes skin irritation H319 Causes serious eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H336 May cause drowsiness or dizziness R10 Flammable. R11 Highly flammable. R20/22 Harmful by inhalation and if swallowed. R34 Causes burns. R35 Causes severe burns.





R36 Irritating to eyes. R36/37 Irritating to eyes and respiratory system. R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.

Revision Date • 26/August/2015Preparation Date • 26/August/2015Disclaimer/Statement of Liability

• The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein.

Key to abbreviationsNDA = No Data Available





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