1.1 Introduction & Historical Development€¦ · 1.1 Introduction & Historical ... Brain Material...
Transcript of 1.1 Introduction & Historical Development€¦ · 1.1 Introduction & Historical ... Brain Material...
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Chap. 1. Basic Principles1.1 Introduction & Historical Development
Stone age Bronze age Iron age
Steel age [Industrial Revolution]
Silicon age and silica age [telecom revolution])
Polymer age
Human NatureMachine Computer Brain Material Semiconductor MacromoleculesMethod Electricity SpiritRegeneration Waste, Regeneration Reproduction
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Polymer Science and Engineering
SCIENCE of LARGE MOLECULES
SYNTHESIS: linking of atoms
CHARACTERIZATION: physical property
POLYMER PHYSICS AND PHYSICAL CHEMISTRY:law of nature (thermodynamics)
ENGINEERING: form of material
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What are Polymers and Why Polymers are Important?
Long Chain Molecules
Extraordinary Range of Physical Properties
Many (Not All) are Cheap
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What is a Polymer ?
—M— M— M— M— M— M— or — (M)n —Many repeating units
A large molecule made upof small building blocks (monomers)
POLYMER
MONOMERS Building blocks
HOMOPOLYMER What you get if the buildingblocks are all the same
A polymer made up ofdifferent monomers
COPOLYMER
BLEND A mixture of different polymers
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Classification by Origin
• Synthetic organic polymers
• Biopolymers
(proteins, polypeptides, polynucleotides,
polysaccharides, natural rubber) ,
• Semi-synthetic polymers
(chemically modified biopolymers)
• Inorganic polymers
(siloxanes, silanes, phosphazenes)
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How Big are Polymers ?
Ethylene
CH2=CH2
Polyethylene
-(CH2-CH2)n-
Then because there are only 200 ethylene units in this chain (ie it is a 200-mer), its molecular weight is only 5,600 (=28 x 200).
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1.2 Definitions of Common Polymer TermsA) Molecular Size/Weight
Polymer Monomer polymerization
(covalent bonding)
mono + mer poly + merGreek many part single part
Monomer ⇒ Oligomer⇒ Polymer
oligos + merfew part
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B) Polymer Structure
1) Repeating Unita) Conventional Repeating unit depends on
monomer used in synthesis, e.g.
i) Polyethylene from Ethylene
C C
H
H
H
H
C C
H
H
H
H
nn
ii) Polymethylene from Diazomethane
CH2N+
-Nn C
H
H
n+ N2n
b) The Base Unit is independent to synthetic route and is smallest possible Repeating Unit
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2) End groups: structural units that terminate polymer chains
CH3CH2 CH2 CH2CH2 CHn
End group End groupRepeating unit= monomer unit
3) Living Polymers
a) Telechelic Polymers (reactive end groups)
tele + chele = far + claw
b) Reactive Oligomers
Oligomers containing reactive end groups capable of undergoing polymerization, usually by heating, to form network polymers
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C) Average Degree of Polymerization = DP
1) DP = # of repeating units in chain + # of end groups
2) DP = Average Degree of Polymerization
3) MW = DP x (MW of Repeating Unit)
4) CH3-(CH2)2000-CH3 has a DP = 2002
n CH
OCOCH3
CH2 CH
OCOCH3
CH2 n
poly(vinyl acetate) (MW = 2000 x 86 = 172,000)
vinyl acetate (MW = 86)
DP = 2000 n = 2000
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D) Types of Atoms in Polymer Backbone
1) Homochain polymerpolymer chain (or backbone) consists of a single atom type
C C C C C C C
e.g., vinyl polymers, polyacetylene, polysulfur, poly(dimethyl silane)
2) Heterochain polymercontain more than one atom type in the backbone
C C O C C O C
e.g., polyesters, polyethers, polyamides
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E) Order of repeating units in backbone1) Homopolymer (cf. Homochain Polymer)
made from a single monomer (or pair of monomers in cases like polyesters, etc.)
2) Copolymera) Synthesis
i) made from more than one type of monomerii) occasionally from more than one type of polymer
b) Types of Copolymersi) Random Copolymer
ii) Block Copolymer
iii) Alternating Copolymer
iv) Graft Copolymer
Figure next page
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E) Order of repeating units in backbone
1) Homopolymer and Copolymer
Figure 1.1 p8
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F) Conventional Polymer Structure Types
1) LinearNo branching other than the pendant groups associated with the monomer
2) Branchedmay have only a few side chains or may be every few repeating units
3) Network (Crosslinked)
a) Crosslink density related to “hardness”
b) an average of more than two crosslinks per chain⇒ infinite network
Figure next page
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F) Conventional Polymer Structure Types
Fig. 1.2 p8
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Network Formation
How would you make chains that branch and then perhaps interconnect to form networks?
A. Use a mixture of bifunctional and monofunctional units
B. Get a tube of Molecular Super Glue and stick a bunch
of chains together
C. Use multifunctional (f>2) monomers
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G) Unconventional Polymer Structures1) Branched
a) Stari) has a central core from which 3 or more arms branchii) uses: viscosity modifiers in high performance engine oils
b) Dendrimer (also known as Starburst or Cascade Polymers)i) generation numbers up to 5-7ii) near spherical shapes
iii) steric crowding gradientiv) uses: microencapsulation and drug deliveryc) Comb
i) from Macromonomers such as 1-C20H40
ii) very high number of side chains, all of similar length
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2) Networka) Ladder cf. DNA (see next page)
b) Semiladder (Stepladder)
3) Supramolecular
a) molecular superstructures held together by non-covalent bondsb) examples
i) Polyrotaxane
washers on a wire
ii) Polycatenane
chain links
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Star polymer Comb polymer Ladder polymer
Semiladder polymer(or Stepladder polymer)
Polyrotaxane Polycatenane
Dendrimer
Figure 1.3 (p9)
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H) Crosslinking
1) Degree of Crosslinking directly correlated with:
a) hardness, elasticity, solvent induced swelling, etc.
b) degree of swelling indicates degree of solvent-polymer compatibility and the degree of crosslinking
2) First “designed” crosslinking process is Vulcanization of rubber (Polyisoprene)
3) Can be via covalent bonds, ionic interactions, or Van der Waals interactions
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I) Thermoset Polymers
Example: Phenol-Formaldehyde resin (see next page)
a) Crosslinked network
b) One gigantic molecule
c) Insoluble
d) Non-melting
e) Only swell in a solvent
Thermoplastic Polymer (e.g., PE)
a) Linear, branched
b) Melt or flow
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OH
+H C H
O
OHH2C
OHH2C
OH
H2C
OH
OH
CH2
OH
- H2O
HC
HO
H+
CH2 OH+
CH2 OH+
Phenol-formaldehyde resin
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Bakelite
The first true synthetic plastic
The hydrogens in the ortho and para positions to the OH group, which by convention are not usually shown but here are indicatedby a , can react with fomaldehyde to form (initially) oligomers.
Network Formation
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Condensation Reaction!!
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Network Formation
Continued reaction builds up a densely cross-linked network.This is Bakelite, athermosettingpolymer. Once the reaction is complete, the material cannot be reheated and reformed. So, what do you think the definition of athermoplastic is?
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J) Classification by Use
1) Plastics
2) Fibers
3) Rubbers (Elastomers)
4) Coatings
5) Adhesives
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Information Technology Applications
• Photoresists for semiconductor fabrication for microprocessor fabrication
• Interlayer dielectrics for semiconductor fabrication fabrication
• Alignment layers for liquid crystal displays Alignment layers for liquid crystal displays
• Lubricants for computer hard disks Lubricants for computer hard disks
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1.3. Polymerization ProcessesClassification of Polymer Reactions
1) Reaction Stoichiometric Classification a) Condensation vs. Addition Polymerizationb) Determined by loss of weight (or not) on polymerization
2) Mechanistic Classificationa) Step-Growth (Step-Reaction) vs. Chain-Growth (Chain-Reaction)b) Determined by reactive species
Condensation: Formation of byproduct, weight lossAddition: No byproduct, No loss of weight
Step-Growth: All species grow step by stepChain-Growth: Successive linking of monomers to
the end of a growing chain
HO OH HOOC COOH+ HO O C COOHO
+ H2O
R + CH
G
CH2CH
G
CH2R* *
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Making a PolymerThe molecules are monofunctional;
To make linear chains we need bifunctional molecules;
Except the reaction doesn’t happen all in one go, like this, but in a step-growth fashion.
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Making a Polyester
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Making a Polyester
Note, reacting a diacid and a dialcoholwill give you a polyester!
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Invention of Nylon
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Nylon 6,6
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Types of Reactions
Condensation
Addition
Ring opening
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Condensation
Is a molecule of water always split out?
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Nylon Rope Trick
Cl-CO-(CH2)4-CO-ClIn CHCl3
H2N-(CH2)6-NH2In H2O
-[NH-(CH2)6-NH-CO-(CH2)4-CO]-
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Step-Growth Polymerization ; Summary
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1.4 Step-Reaction Polymerization1) Most commonly found with condensation reactions
but there are exceptionsa) Bonds formed one at a timeb) Most monomer used up quickly but get high MW only near endc) Wide MW distributions typical
2) Work out the DP & DP for the following
a) DP ≈ Number of repeating units in chain
MW = DP x (Repeating Unit MW)
b) DP = Average Number of repeating units in chain (plus the number of end groups)
MW = DP x (Repeating Unit MW)
DP = MW / Repeating Unit MW = Average Number of Repeating Units in Chain
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c) p = reaction conversion = extent of reaction
i)
p = fraction of the original functional groups consumed
No = number of molecules initially
N = number of molecules finally
whereo
o
NNNp −
= or N = No(1 - p)
p11
NNDP o
−==ii)
p = 0 at start when no polymerization
p ≈ 1 when polymerization complete (the numerical value of p gets closer to 1 at higher final MW)
for 98% reaction conversion (i.e., p = 0.98) DP = 50
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iii) To get high MW you need
- excellent reaction conversions(i.e., clean reactions that go to completion)
- very pure reagents (no monofunctional species)
- very precise reaction stoichiometries
Figure 1.4i) Step Reaction Polymerization of monomer A-B
ii) Show how polymerization effects array of A-B monomers
iii) Shows how even as p approaches 1, the average chain length stays low
iv) Only at very end when almost no low MW species present long chains form
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Figure 1.4 Step-reaction polymerization
Unreacted monomerA
B
A
B
AB
A
B
A
B
A
B
A
B
A
BA
B
A
B
A
B
A
B
AB
A
B
AB
A
B
A
B
A
B
A
B
A
BA
B
A
B
A
B
A
B
Conversion : monomer to polymer
33.125.01
19
12DP =−
==%50126conversion == %25
12912p =
−=
AB
A
B
AB
A
B
A
B
A
B
A
B
A
BA
B
A
B
A
B
A
B
71.142.01
17
12DP =−
==%75129conversion == %42
12712p =
−=
AB
A
B
AB
A
B
A
B
A
B
A
B
A
BA
B
A
B
A
B
A
B
%1001212conversion == %67
12412p =
−= 3
67.011
412DP =
−==
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Conversion and Molecular Weightin Step-Growth Polymerizations
Note; you only get high molecular weight polymerat high degrees of conversion.
= DP = degree of polymerization= number of repeating unit
nx
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What Are Polyolefins?The term polyolefin embraces all polymers that are derived from simple unsaturated aliphatic hydrocarbons that contain one double bond per monomer. Examples include:
The most important polyolefins in terms of production volume are polyethylene (PE), polypropylene (PP) and the ethylene/propylene copolymers (EP). Other significant polyolefins include, polybut-1-ene, poly-4-methylpent-1-ene and polyisobutene (PIB).
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1.5 Chain-reaction Polymerization1) Most commonly found with addition reactions but there are
exceptions (e.g., the Chain/Condensation polymerization of diazomethane)
2) Generic Mechanisms a) Chain Initiation Step(s)
Generation of highly reactive species, e.g.
- Free radical intermediate - Carbocation or carbanion- Transition metal species
b) Chain Propagation Step(s)Increase MW by adding monomers to end of growing chain
c) Chain Termination Step(s)Consume the active species by recombination, etc.
d) Chain Transfer Step(s)May be present and typically modify final polymer structure and MW
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3) Commonly found when have highly reactive intermediates
Free Radicals, Carbocations, Carbanions, etc.
4) Examples
a) FR Polymerization of Ethylene
C C
H
H
H
HR C C
H
H
H
H
nn
R +
b) Nucleophilic Polymerization of Ethylene Oxide (Ring Opening)
RO- + CH2 CH2
O
RO CH2CH2O-
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5) Figure 1.5
a) Chain-Reaction Polymerization of monomer C = C
b) Show how polymerization effects array of C = C monomers
c) Even at low values of p (reaction conversion), some high MW chains are present
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Figure 1.5 Chain-reaction polymerization
CC
CC
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CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
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CC
CC
CC
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CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
Unreacted monomer
%50126conversion == %42
12712p =
−= 71.1
42.011
712DP =
−==
%75129conversion == %67
12412p =
−= 3
67.011
412DP =
−==
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
CC
%1001212conversion == %92
12112p =
−= 12
92.011
112DP =
−==
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Chain Polymerizations
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Chain Polymerizations
- a simplistic view
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Characteristics of Chain Polymerizations
Need to consider;
1. Initiation
2. Propagation
3. Termination
4. Chain Transfer
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Chain Polymerizations– Types(nature of the active site)
Free Radical
Anionic
Cationic
Coordination (Catalyst)
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Free Radical Polymerization
- Initiation
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Free Radical Polymerization
- Propagation
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Free Radical Polymerization
- Termination
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Short Chain Branching in Polyethylene
Formation of short chain branches in polyethylene
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Chain Polymerizations
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1.6 Step-Reaction Addition & Chain-Reaction Condensation1) Step-Reaction Addition
a) diisocyanates (OCN~R~NCO) + diols (HO~R’~OH)→ polyurethane -(CONH~R~NHCOO~R’~O)-
b) diisocyanates (OCN~R~NCO) + diamines (H2N~R’~NH2)→ polyurea -(CONH~R~NHCONH~R’~NH)-
c) Diels-Alder reaction of 1,6-bis(cyclopentadienyl)hexanes with benzoquinone
CH2 6+
O
O
6
O
O
CH2
2) Chain-Reaction Condensation
Polymerization of CH2N2 initiated by BF3
CH2 +CH2N2 N2
BF3
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Polyurethanes
A reaction that does not involve the splitting out of a small molecule;
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International Union of Pure and Applied Chemistry (IUPAC)
1) Polycondensation: condensation + step-reactionFormation of low-mol-wt byproductStep-reaction polymerization
2) Polyaddition: addition + step-reaction
No byproductsStep-reaction polymerization
3) Chain polymerization: addition + chain polymerizationNo byproductsChain-reaction polymerization
4) Condensative chain polymerization: condensation + chain-reaction
Formation of low-mol-wt byproductChain-reaction polymerization
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1.7 NomenclatureIUPAC name
1) The smallest constitutional repeating unit (CRU) is identified
2) Substituent groups are assigned the lowest possible numbers
3) The name is placed in parenthesis, and prefixed with poly1.7.1 Vinyl polymers
poly + monomer name
CH2CH2
Source name= common name
IUPAC name
polyethylene poly(methylene)
CF2CF2
CH2 CH
polytetrafluoroethylene
polystyrene
poly(difluoromethylene)
poly(1-phenylethylene)
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poly + (monomer name) more than one word or letter or number
Source name= common name
IUPAC name
poly(1-carboxylatoethylene)CH2CHCOOH
poly(acrylic acid)
CH2CCH3
poly(1-methyl-1-phenylethylene)poly(α-methylstyrene)
poly[1-(1-propyl)ethylene] CH2CHCH2CH2CH3
poly(1-pentene)
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Source name= common name
IUPAC name
H2C CH CH CH2
CH2 CH2
CH CH2
1,2-addition
CH2CH CHCH2
1,4--addtion
1,3-butadiene
1,2-poly(1,3-butadiene)
1,4-poly(1,3-butadiene)
Poly(1-vinylethylene)
Poly(1-butene-1,4-diyl)
TABLE 1.2 Nomenclature of Vinyl Polymers (p19)
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1.7.2. Vinyl CopolymersIUPAC recommends source-based nomenclature for copolymers.
Concise Systematic
Poly[styrene-co-(methyl methacrylate)] Copoly(styrene/methyl methacrylate)
Poly[styrene-alt-(methyl methacrylate)] Alt-copoly(styrene/methyl methacrylate)
Polystyrene-block-poly(methyl methacrylate) Block-copoly(styrene/methyl methacrylate)
Polystyrene-graft-poly(methyl methacrylate) Graft-copoly(styrene/methyl methacrylate)
Poly(styrene-co-ethylene-co-propylene) Copoly(styrene/ethylene/propylene)
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1.7.3. Nonvinyl PolymersPolyethers, polyesters, polyamides
Heteroatoms Seniority: O, S, N, P
1) Polyethers
IUPAC nameSource name
H2C CH2
OCH2CH2O
CH2O
CH3CHO CHO
CH3
CH2O
Poly(ethylene oxide)
Polyformaldehyde
Polyacetaldehyde
Poly(oxyethylene)
Poly(oxymethylene)
Poly(oxyethylidene)
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2) Polyesters
O C
O
CH2CH2
O
O
OCH2CH2C
O
HO CH2 9
O
OH
O
HO2C CO2H
+
O
CO
oxyethylene
oxy terephthaloyl
O(CH2)9C
HOCH2CH2OH
OCH2CH2OC
oxy 1-oxopropane-1,3-diylpoly(β-propiolactone)= poly(3-propionate)poly[oxy(1-oxopropane-1,3-diyl)]
poly(10-decanoate)
poly[oxy(1-oxodecane-1,10-diyl)]
poly(ethylene terephthalate)poly(oxyethyleneoxyterephthaloyl)
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3) Polycarbonate
OC
O
O C
CH3
CH3
Bisphenol A polycarbonate
poly(oxycarbonyloxy-1,4-phenyleneisopropylene-1,4-phenylene)
Heteroatoms Seniority: O, S, N, P
4) Polyamide
NHO
C NH(CH2)5
OPolycaprolactam= nylon 6
Poly[imino(1-oxohexane-1,6-diyl)]
NH(CH2)10 CO
H2N(CH2)10COOHPoly(undecanoamide)= nylon 11
Poly[imino(1-oxoundecane-1,11-diyl)]
caprolactam
11-aminoundecanoic acid
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H2N(CH2)6NH2
+HOOC(CH2)8COOH
NH(CH2)6NH CO
(CH2)8 CO
Hexamethylenediamine
Sebacic acid
Poly(hexamethylenesebacamide) or nylon 610
Poly(iminohexane-1,6-diyliminosebacoyl)
CO
CClO
Cl
+H2N NH2
CO
CO
HN NH
Terephthaloyl chloride
m-Phenylenediamine
Poly(m-phenyleneterephthalate)
Poly(imino-1,3-phenyleneiminoterephthaloyl)
H2N(CH2)4NH2
+ NH(CH2)4NH
ClO2S SO2Cl
O2S SO2
Tetramethylenediamine
m-Benzenedisulfonyl chloride
Poly(tetramethylene-m-benzenesulfonamide)
Poly(sulfonyl-1,3-phenylenesulfonylimino-butane-1,4-diylimino)
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1.7.4 Nonvinyl copolymersIUPAC source-based nomenclature for nonvinyl copolymers
2:1:1 –molar ratio of the monomers ethylene glycol, terephthalic acid, and isophthalic acid
poly(ethylene terephthalate-co-ethylene isophthalate)
6-aminohexanoic acid + 11-aminoundecanoic acid poly[(6-aminohexanoic acid)-co-(11-aminoundecanoic acid)]poly[(6-hexanoamide)-co-(11-undecanoamide)]
COOHHOOC HOOC COOHHO(CH2)2OH ++
O(CH2)2O CO
CO
O(CH2)2O CO
CO
H2N(CH2)10COOHH2N(CH2)5COOH +
(CH2)10COHN(CH2)5CO NH
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1.7.5 End Groups
H OCH2CH2 OHn
α-Hydro-ω-hydroxypoly(oxyethylene)
1.7.6 Abbreviations
Appendix A (p515)
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1.8 Industrial Polymers
Plastics weigh less and are more corrosion resistant than metals
Lower energy process
Five major classifications of the polymer industry
PlasticsFibersRubber (elastomers) AdhesivesCoatings
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1.8.1 Plastics
1) Commodity plastics
a) High volume and low cost
b) Materials properties limited by relatively low intermolecularforces (primarily Van der Waals, dipole - induced dipole, anddipole-dipole ∴ need relatively high MW to get desired strengths, etc.
2) Engineering plastics
a) Lower volume and higher cost
b) Superior mechanical properties and greater durability
c) Mostly Heterochain polymers
Hydrogen-Bonds hold even relatively short chains together very strongly
Most building blocks are quite highly aromatic in character
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p26TABLE 1.4 Five Major Commodity Plastics
Type AbbrLow-density polyethylene
eviation Major Use
LDPE Packaging film, wire and cable insulation, toys, flexible bottle, housewares, coatings
High-density polyethylene
Bottles, drums, pipe, conduit, sheet, film,wire and cable insulationHDPE
Automobile and appliance parts, furniture,cordage, webbing, carpeting, film packagingPolypropylene PP
Construction, rigid pipe, flooring, wire and cable insulation, film and sheetPoly(vinyl chloride) PVC
Packaging (foam and film), foam insulation,appliances, housewares, toys
PSPolystyrene
Low-density: < 0.94 g/cm3, branchedHigh-density: > 0.94 g/cm3, linear
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Linear and Branched Polyethylenes
Linear
Branched
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Low Density Polyethylene
A modern cable coating
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Low Density Polyethylene
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2) Engineering Plastics
TABLE 1.5 Principal Engineering Plastics (p27)
a) Polyamide: nylon 6, nylon 66
b) Polyester: poly(ethylene terephthalate (PET), poly(butylene terephthalate (PBT)
c) Polycarbonate (PC)
d) Acetal: Polyoxymethylene (POM) = polyformaldehyde
e) Poly(phenylene oxide) (PPO)
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Poly(methyl methacrylate) (PMMA)
An beautifully clear glassy material
‘Plexiglas’ or ‘Perspex’
Cockpit canopies for military aircraft
A Hawker “Hurricane” withPerspex canopy
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TABLE 1.6 Thermosetting Plastics p28
Major UseType Abbreviation
Phenol-formaldehyde PF Electrical and electronic equipment,automobile parts, utensil handles,plywood adhesives, particle board binder
Urea-formaldehyde UF Similar to PF polymers, treatment of textiles (crease-resistant), coatings
Melamine-formaldehyde MF Similar to UF polymers, decorative panels,counter and table tops, dinnerware
Unsaturated polyester UP Construction, automobile parts, boat hulls,marine accessories, corrosion-resistant ducting, pipe, tank, etc.,Business equipment
Epoxy Protective coatings, adhesives,electrical and electronics applications,industrial flooring, highway paving materials,composites
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1.8.2 FibersHigh strength and modulus, good elongation (stretchability), good thermal stability (enough to withstand ironing), spinnability (the ability to be converted to filaments)
CellulosicTABLE 1.7 Principal Synthetic Fibers
Acetate rayon Cellulose acetate
HO
OH
H
HO
H
HOHH
O
OH
O
HH
HH
OH
O
OH
HO
Cellulose
Polyester ; PETNylon ; nylon 66, nylon 6, aromatic polyamideOlefin ; PPAcrylic ; polyacrylonitrile
Viscose rayon Regenerated cellulose
Noncellulosic
Cell-OH + (CH3CO)2O → Cell-OCOCH3 + CH3COOH
Cell-OH + CS2 + NaOH→ Cell-O-C-S- Na+ + H2O
=
Cell-O-C-S- Na+→ Cell-OH + CS2 + Na+
=S
S
H+
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1.8.3 Rubber (Elastomers)TABLE 1.8 Principal Types of Synthetic Rubber
Type Description
Styrene-butadiene rubber (SBR)cis-1,4 polymerEPDM for ethylene-propylene-diene monomerTrans-1,4 polymer, known as neoprene rubberCis-1,4 polymer, “synthetic natural rubber”Copolymer of acrylonitrile and butadieneCopolymer of isobutylene and isoprenePolysiloxaneLinking polyethers through urethane groups
Styrene-butadienePolybutadieneEthylene-propylenePolychloroprenePolyisopreneNitrileButylSiliconeUrethane
Cl Cl
CH3 CH3
Si O
CH3
CH3HO OH + OCN Ar NCO
C Ar NCOO O NH
OCAr NH
OCO O NH
OCO
NHArOCN
excess
OCN Ar NCO (unreacted)
H2N R NH2
CAr NH
OCO O NH
O
CO
NHArHN R NH C NH
O
"Hard" segment "Soft" segment
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Natural Rubber
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Buna S Rubber
Styrene-butadiene rubber (SBR)
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1.8.4 Coatings and Adhesives
Polyester (alkyd):Styrene-butadiene copolymer:Poly(vinyl acetate) and
poly(acrylate esters):
varnishes, paintsinterior latex wall paints
exterior latex paints
Coatings
AdhesivesPhenol-formaldehyde and
urea-formaldehyde:EpoxidesCyanoacrylate
wood industries (plywood, particle board)
Efforts to reduce VOC (volatile organic carbon)
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1.9 Polymer Recycling
TABLE 1.9 Plastics Recycling Code2
HDPE
Number Letters Plastic
1234567
PETEHDPEV or PVCLDPEPPPSOther
Poly(ethylene terephthalate)High-density polyethylenePoly(vinyl chloride)Low-density polyethylenePolypropylenePolystyreneOthers or mixed plastics
• Solutions of polymer waste- Degradable polymer: landfill- Combustible polymer: energy recovery- Recycling- Innovative uses: Automobile tires; ground and blended into
molded rubber products or asphalt paving materials, construct barrier reefs