1074_PDF_C02

2. VAPOR-LIQUID EQUILIBRIUM (VLE) DATA

OF BINARY COPOLYMER SOLUTIONS

2.1. Partial solvent vapor pressures or solvent activities for copolymer

solutions

_____________________________________________________________________________

Copolymers from acrylonitrile and butadiene

_____________________________________________________________________________

Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________

Copolymer (B) Acronym Ref.

_____________________________________________________________________________

Acrylonitrile/butadiene copolymer

21.0 wt% acrylonitrile AN-B/21w 95GUP



_____________________________________________________________________________

Characterization:

_____________________________________________________________________________

Copolymer (B) Mn/ Mw/ M/ Further information

g/mol g/mol g/mol

_____________________________________________________________________________

AN-B/21w Sci. Polym. Products, catalog #523



_____________________________________________________________________________

Experimental VLE data:

_____________________________________________________________________________

copolymer (B): AN-B/21w 95GUP

solvent (A): acetonitrile C2H3N 75-05-8

T/K = 333.15

wB 0.989 0.974 0.935 0.915 0.888 0.813

PA/kPa 6.8 13.7 26.1 30.1 34.1 39.3


solvent (A): cyclohexane C6H12 110-82-7

T/K = 333.15

wB 0.823 0.824 0.790 0.784 0.717

PA/kPa 35.6 35.7 38.1 39.7 43.1


solvent (A): n-hexane C6H14 110-54-3

T/K = 333.15

wB 0.975 0.956 0.918 0.896 0.866 0.830 0.764 0.749

PA/kPa 12.9 25.6 38.8 44.5 50.8 57.5 63.7 64.9


solvent (A): n-octane C8H18 111-65-9

T/K = 333.15

wB 0.964 0.948 0.936 0.921 0.889 0.842

PA/kPa 2.90 4.19 5.08 5.91 6.91 8.41


solvent (A): n-pentane C5H12 109-66-0

T/K = 333.15

wB 0.984 0.979 0.967 0.954 0.945 0.930 0.922 0.911

PA/kPa 36.0 46.8 65.5 84.0 97.3 113.3 124.8 137.6



T/K = 333.15

wB 0.977 0.957 0.935 0.909 0.852 0.794

PA/kPa 6.7 13.3 18.3 23.2 32.5 37.9



T/K = 333.15

wB 0.998 0.983 0.974 0.963

PA/kPa 12.4 25.1 36.0 43.3



T/K = 333.15

wB 0.986 0.975 0.973 0.968 0.964 0.956 0.950 0.945

PA/kPa 26.9 53.5 64.7 77.5 89.7 101.7 115.7 130.1


solvent (A): trichloromethane CHCl3 67-66-3

T/K = 333.15

wB 0.920 0.830 0.828 0.738 0.628 0.576 0.515 0.437

PA/kPa 13.6 26.8 26.9 39.6 52.8 59.9 66.3 73.3



T/K = 333.15

wB 0.979 0.953 0.889 0.856 0.818 0.707

PA/kPa 6.8 13.7 26.1 30.1 34.1 39.3



T/K = 333.15

wB 0.993 0.989 0.985 0.976 0.968 0.953 0.940 0.909

PA/kPa 13.7 19.1 19.6 26.4 32.0 35.6 39.7 43.1



T/K = 333.15

wB 0.982 0.980 0.971 0.967 0.959 0.956 0.938 0.938

PA/kPa 12.9 25.6 38.8 44.5 50.8 57.5 63.7 64.9



T/K = 333.15

wB 0.993 0.990 0.987 0.985 0.979 0.974

PA/kPa 2.85 4.19 5.08 5.91 6.91 8.41



T/K = 333.15

wB 0.991 0.987 0.981 0.978 0.978 0.974 0.973 0.966

PA/kPa 36.0 46.8 65.5 84.0 97.3 113.3 124.8 137.6

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Copolymers from acrylonitrile and styrene

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Acrylonitrile/styrene copolymer

25.0 wt% acrylonitrile S-AN/25w 98SCH

28.0 wt% acrylonitrile S-AN/28w 96WO2

28.0 wt% acrylonitrile S-AN/28w 97WO1

30.0 wt% acrylonitrile S-AN/30w 95GUP

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-AN/25w 90000 147000 Bayer AG Leverkusen, Ger.

S-AN/28w 46000 100000 synthesized in the laboratory

S-AN/30w 185000 Sci. Polym. Products, catalog #495

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-AN/25w 98SCH

solvent (A): toluene C7H8 108-88-3

T/K = 313.15

wB 0.399 0.447 0.497 0.522 0.601 0.638 0.699 0.747 0.799

PA/PAs

0.999 0.991 0.954 0.952 0.902 0.869 0.796 0.745 0.644

wB 0.848 0.894 0.952

PA/PAs

0.544 0.476 0.331



T/K = 323.15

wB 0.352 0.448 0.499 0.524 0.603 0.643 0.702 0.750 0.802

PA/PAs

0.996 0.986 0.934 0.918 0.877 0.848 0.779 0.717 0.628

wB 0.852 0.897 0.955

PA/PAs

0.529 0.454 0.337



T/K = 333.15

wB 0.353 0.449 0.500 0.525 0.604 0.644 0.704 0.751 0.803

PA/PAs

0.989 0.979 0.924 0.909 0.872 0.843 0.776 0.711 0.625

wB 0.853 0.899 0.956

PA/PAs

0.523 0.446 0.332

copolymer (B): S-AN/28w 96WO2, 97WO1

solvent (A): benzene C6H6 71-43-2

T/K = 343.15

wB 0.8339 0.8053 0.7876 0.7501 0.7207 0.6967 0.6587 0.6384 0.6198

PA/PAs

0.6433 0.7080 0.7415 0.8036 0.8454 0.8752 0.9097 0.9251 0.9369

wB 0.5892 0.5564

PA/PAs

0.9598 0.9724


solvent (A): propylbenzene C9H12 103-65-1

T/K = 398.15

wB 0.8270 0.8132 0.8018 0.7781 0.7649 0.7346 0.7179 0.6834

PA/PAs

0.7559 0.7834 0.8033 0.8423 0.8618 0.8991 0.9127 0.9372



T/K = 343.15

wB 0.7962 0.7433 0.7192 0.6960 0.6607 0.6482 0.6199 0.5856

PA/PAs

0.7257 0.8126 0.8458 0.8735 0.9090 0.9172 0.9377 0.5856



T/K = 373.15

wB 0.8003 0.7632 0.7375 0.7157 0.7093 0.6831 0.6686 0.6388 0.6056

PA/PAs

0.7071 0.7752 0.8147 0.8410 0.8523 0.8817 0.8951 0.9208 0.9427

wB 0.5883 0.5654

PA/PAs

0.9567 0.9690


solvent (A): o-xylene C8H10 95-47-6

T/K = 398.15

wB 0.7606 0.7371 0.7107 0.6838 0.6593 0.6276 0.5960 0.5586

PA/PAs

0.8048 0.8389 0.8722 0.9008 0.9228 0.9459 0.9642 0.9800


solvent (A): m-xylene C8H10 108-38-3

T/K = 398.15

wB 0.7977 0.7611 0.7428 0.7167 0.6884 0.6460 0.6198 0.5894

PA/PAs

0.7462 0.8162 0.8387 0.8690 0.9010 0.9405 0.9510 0.9701


solvent (A): p-xylene C8H10 106-42-3

T/K = 373.15

wB 0.7632 0.7416 0.7204 0.6997 0.6566 0.6223 0.5917

PA/PAs

0.8081 0.8378 0.8736 0.8883 0.9347 0.9547 0.9714



T/K = 398.15

wB 0.8082 0.7896 0.7534 0.7263 0.7006 0.6731 0.6519 0.6292 0.6028

PA/PAs

0.7188 0.7537 0.8142 0.8528 0.8828 0.9101 0.9286 0.9439 0.9609



T/K = 423.15

wB 0.7738 0.7547 0.7259 0.6931 0.6674 0.6492 0.6211

PA/PAs

0.7769 0.8077 0.8483 0.8846 0.9106 0.9253 0.9444

copolymer (B): S-AN/30w 95GUP

solvent (A): 1,2-dichloroethane C2H4Cl2 107-06-2

T/K = 343.15

wB 0.861 0.804 0.757 0.719 0.704 0.661

PA/kPa 30.8 36.5 40.7 43.9 46.0 49.1

copolymer (B): S-AN/30w 95GUP

solvent (A): 1,2-dichloroethane C2H4Cl2 107-06-2

T/K = 353.15

wB 0.749 0.721 0.652 0.624 0.611

PA/kPa 45.7 50.1 57.6 59.5 60.7

_____________________________________________________________________________

Copolymers from p-bromostyrene and p-methylstyrene

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

p-Bromostyrene/p-methylstyrene copolymer

16.7 mol% p-bromostyrene pBS-pMS/17x 63COR





_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

pBS-pMS/17x 5000-10000 synthesized in the laboratory





_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): pBS-pMS/17x 63COR


T/K = 293.20

B 0.1643 0.2633 0.3444 0.4641 0.5449 0.6416aA 0.9952 0.9865 0.9650 0.9259 0.8696 0.7859



T/K = 293.20

B 0.1970 0.2792 0.3648 0.4799 0.5932 0.6473aA 0.9952 0.9860 0.9649 0.9255 0.8708 0.7858



T/K = 293.20

B 0.1857 0.2672 0.3696 0.4870 0.5755 0.6629aA 0.9952 0.9865 0.9652 0.9250 0.8690 0.7855



T/K = 293.20

B 0.1803 0.3066 0.3931 0.5074 0.5844 0.6742aA 0.9952 0.9865 0.9650 0.9250 0.8680 0.7852



T/K = 293.20

B 0.2088 0.3489 0.4095 0.5417 0.6147 0.7028aA 0.9952 0.9868 0.9658 0.9256 0.8698 0.7859

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Copolymers from butadiene and styrene

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Butadiene/styrene copolymer

5.0 wt% styrene S-BR/05w 95GUP

23.0 wt% styrene S-BR/23w 95GUP

41.0 wt% styrene S-BR/41w 96WO1

41.0 wt% styrene S-BR/41w 97WO1

45.0 wt% styrene S-BR/45w(1) 90IWA

45.0 wt% styrene S-BR/45w(1) 91IWA

45.0 wt% styrene S-BR/45w(2) 95GUP

Butadiene/styrene copolymer

(block copolymer without specification)

30.0 wt% styrene S-?-B/30w 90IWA




Polystyrene-b-polybutadiene-b-polystyrene

triblock copolymer

31.0 wt% styrene S-B-S/31w 99FRE

Polystyrene-b-polybutadiene(hydrogenated)-

b-polystyrene triblock copolymer

13.0 wt% styrene S-B(h)-S/13w 99FRE

31.0 wt% styrene S-B(h)-S/31w 99FRE

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-BR/05w Sci. Polym. Products, catalog #199

S-BR/23w Sci. Polym. Products, catalog #200

S-BR/41w 86300 181200 synthesized in the laboratory

S-BR/45w(1) 130430 600000 Sci. Polym. Products

_____________________________________________________________________________

continue

continue

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-BR/45w(2) Sci. Polym. Products, catalog #201

S-?-B/30w 108000 140000 Sci. Polym. Products

S-?-B/77w 117650 200000 Denki Kagaku Industry

S-B-S/31w 111000

S-B(h)-S/13w 90000 synthesized in the laboratory

S-B(h)-S/31w 48000 synthesized in the laboratory

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-BR/05w 95GUP


T/K = 333.15

wB 0.848 0.811 0.767 0.724 0.677

PA/kPa 24.8 29.5 33.7 37.6 40.7


solvent (A): 2-propanone C3H6O 67-64-1

T/K = 323.15

wB 0.944 0.933 0.928 0.933 0.934 0.922 0.921 0.920 0.909

PA/kPa 41.5 45.3 46.5 47.2 47.3 51.1 52.3 53.3 55.2

wB 0.885 0.890 0.880

PA/kPa 59.6 59.7 61.3



T/K = 308.15

wB 0.957 0.901 0.816 0.681 0.584 0.487

PA/kPa 0.93 2.08 3.04 4.36 4.83 5.45



T/K = 323.15

wB 0.960 0.894 0.796 0.728 0.659 0.543 0.511 0.463 0.420

PA/kPa 8.5 16.3 25.5 31.6 38.3 45.5 47.6 50.0 53.7

wB 0.362

PA/kPa 56.4



T/K = 296.65

wB 0.803 0.724 0.672

PA/kPa 7.64 9.03 10.03



T/K = 333.15

wB 0.864 0.832 0.792 0.756 0.713

PA/kPa 24.8 29.5 33.7 37.6 40.7



T/K = 343.15

wB 0.890 0.838 0.738

PA/kPa 48.8 61.5 75.2



T/K = 333.15

wB 0.954 0.945 0.930 0.922 0.911

PA/kPa 84.0 97.3 113.3 124.8 137.6



T/K = 333.15

wB 0.979 0.963 0.938 0.908 0.872 0.853 0.817 0.769

PA/kPa 26.4 40.7 54.8 68.5 81.3 84.8 91.5 97.9



T/K = 323.15

wB 0.951 0.939 0.929 0.925 0.915 0.912 0.909 0.900 0.875

PA/kPa 36.3 41.5 45.3 46.5 51.1 52.3 53.3 55.2 59.6

wB 0.880 0.870

PA/kPa 59.7 61.3



T/K = 308.15

wB 0.971 0.969 0.968 0.963 0.963 0.962

PA/kPa 0.93 2.08 3.04 4.36 4.83 5.45



T/K = 323.15

wB 0.954 0.889 0.794 0.730 0.662 0.551 0.518 0.486 0.434

PA/kPa 8.5 16.3 25.5 31.6 38.3 45.5 47.6 50.0 53.7

wB 0.379

PA/kPa 56.4

copolymer (B): S-BR/41w 96WO1, 97WO1


T/K = 343.15

wB 0.7998 0.7553 0.7207 0.6864 0.6485 0.6039 0.5517 0.4916 0.4326

PA/PAs

0.5091 0.5897 0.6418 0.6910 0.7388 0.7876 0.8357 0.8798 0.9143



T/K = 343.15

wB 0.7831 0.7564 0.7197 0.6712 0.6394 0.6008 0.5586 0.5234

PA/PAs

0.6522 0.6966 0.7491 0.8083 0.8385 0.8693 0.8985 0.9176


solvent (A): ethylbenzene C8H10 100-41-4

T/K = 373.15

wB 0.7917 0.7604 0.7285 0.6799 0.6412 0.5996 0.5616 0.5173 0.4845

PA/PAs

0.5829 0.6358 0.6841 0.7471 0.7897 0.8271 0.8562 0.8854 0.9037



T/K = 398.15

wB 0.6887 0.6528 0.6293 0.5818 0.5495 0.5106 0.4698

PA/PAs

0.7292 0.7736 0.7973 0.8390 0.8629 0.8876 0.9108


solvent (A): mesitylene C9H12 108-67-8

T/K = 398.15

wB 0.7694 0.7389 0.6908 0.6576 0.6232 0.5856 0.5407 0.5009

PA/PAs

0.6520 0.6982 0.7617 0.7987 0.8311 0.8610 0.8911 0.9107



T/K = 343.15

wB 0.7619 0.7198 0.6721 0.6276 0.5800 0.5317 0.4961 0.4533

PA/PAs

0.5825 0.6476 0.7125 0.7634 0.8103 0.8497 0.8753 0.9011



T/K = 373.15

wB 0.8168 0.7701 0.7387 0.6970 0.6319 0.5726 0.5063 0.4308

PA/PAs

0.4844 0.5704 0.6214 0.6833 0.7612 0.8178 0.8691 0.9143



T/K = 398.15

wB 0.8071 0.7593 0.7162 0.6784 0.6499 0.6075 0.5698 0.5201 0.4899

PA/PAs

0.5536 0.6388 0.7027 0.7503 0.7803 0.8216 0.8520 0.8884 0.9050

copolymer (B): S-BR/45w(2) 95GUP


T/K = 296.65

wB 0.824 0.747 0.699

PA/kPa 7.64 9.03 10.03



T/K = 333.15

wB 0.870 0.837 0.800 0.760 0.718

PA/kPa 24.8 29.5 33.7 37.6 40.7

copolymer (B): S-BR/45w(1) 90IWA


T/K = 373.15

wB 0.9717 0.9589 0.9452 0.9448 0.9248 0.9112 0.9022 0.8830 0.8390

PA/kPa 4.00 5.42 6.92 6.89 9.10 10.00 11.10 12.60 16.10

wB 0.8380 0.0000

PA/kPa 16.10 34.25



T/K = 403.15

wB 0.9791 0.9738 0.9723 0.9639 0.9587 0.9559 0.9539 0.9494 0.9407

PA/kPa 7.14 8.79 9.45 11.40 12.60 13.80 14.30 15.70 18.10

wB 0.9333 0.9332 0.9308 0.9241 0.9229 0.9110 0.9081 0.9036 0.8920

PA/kPa 19.70 20.50 20.40 22.00 22.20 25.60 26.50 27.10 29.60

wB 0.8850 0.8790 0.8450 0.0000

PA/kPa 31.30 32.00 38.70 85.55



T/K = 343.15

wB 0.897 0.845 0.751

PA/kPa 48.8 61.5 75.2


solvent (A): n-nonane C9H20 111-84-2

T/K = 373.15

wB 0.9832 0.9516 0.9428 0.9308 0.9093 0.9082 0.8820 0.8700 0.8460

PA/kPa 2.87 6.45 7.36 8.51 10.20 10.20 12.00 12.70 14.00

wB 0.8270 0.8260 0.0000

PA/kPa 14.90 14.90 20.72



T/K = 403.15

wB 0.9819 0.9647 0.9589 0.9468 0.9286 0.9171 0.9098 0.8960 0.8820

PA/kPa 6.86 12.10 13.80 17.40 21.40 24.10 25.40 28.00 30.50

wB 0.8520 0.8290 0.0000

PA/kPa 35.00 37.40 55.85



T/K = 333.15

wB 0.978 0.978 0.974 0.973 0.966

PA/kPa 84.0 97.3 113.3 124.8 137.6



T/K = 323.15

wB 0.954 0.939 0.926 0.922 0.926 0.929 0.912 0.908 0.905

PA/kPa 36.3 41.5 45.3 46.5 47.2 47.3 51.1 52.3 53.3

wB 0.895 0.863 0.870 0.859

PA/kPa 55.2 59.6 59.7 61.3



T/K = 333.15

wB 0.956 0.931 0.899 0.860 0.837 0.803 0.742

PA/kPa 40.7 54.8 68.5 81.3 84.8 91.5 97.9



T/K = 323.15

wB 0.957 0.893 0.795 0.728 0.657 0.537 0.500 0.466 0.408

PA/kPa 8.5 16.3 25.5 31.6 38.3 45.5 47.6 50.0 53.7

wB 0.350

PA/kPa 56.4

copolymer (B): S-?-B/30w 90IWA


T/K = 373.15

wB 0.9704 0.9528 0.9240 0.9098 0.9022 0.8760 0.8550 0.8360 0.8130

PA/kPa 3.87 5.83 8.79 10.00 10.70 13.00 14.80 16.10 17.80

wB 0.0000

PA/kPa 34.25



T/K = 403.15

wB 0.9752 0.9692 0.9643 0.9582 0.9533 0.9509 0.9409 0.9368 0.9270

PA/kPa 7.93 9.73 11.10 12.30 13.80 14.70 17.10 18.20 20.40

wB 0.9196 0.9145 0.9055 0.9042 0.8950 0.8860 0.8700 0.8600 0.8510

PA/kPa 22.20 23.50 25.60 25.70 27.90 29.60 33.00 34.80 37.10

wB 0.8340 0.0000

PA/kPa 39.70 85.55



T/K = 373.15

wB 0.9801 0.9673 0.9506 0.9489 0.9291 0.9229 0.9076 0.8970 0.8830

PA/kPa 2.81 4.28 5.95 6.17 7.85 8.44 9.57 10.20 11.30

wB 0.8690 0.8470 0.8360 0.0000

PA/kPa 12.00 13.20 13.60 20.72



T/K = 403.15

wB 0.9867 0.9750 0.9584 0.9459 0.9294 0.9248 0.9224 0.9032 0.8950

PA/kPa 4.62 8.12 12.70 15.90 20.20 20.80 21.40 25.30 26.80

wB 0.8720 0.8700 0.8600 0.8400 0.0000

PA/kPa 30.60 30.70 32.40 34.90 55.85



T/K = 373.15

wB 0.9780 0.9693 0.9614 0.9520 0.9319 0.9266 0.9140 0.8980 0.8810

PA/kPa 3.85 4.85 5.81 7.17 9.10 9.69 11.10 12.60 14.70

wB 0.8690 0.8460 0.8400 0.0000

PA/kPa 15.20 17.10 17.60 34.25



T/K = 403.15

wB 0.9744 0.9685 0.9572 0.9461 0.9402 0.9358 0.9354 0.9232 0.9213

PA/kPa 10.00 11.80 14.70 18.20 20.00 21.00 21.60 24.30 25.00

wB 0.9026 0.9004 0.8940 0.8780 0.8560 0.0000

PA/kPa 29.60 30.40 32.10 35.00 40.80 85.55



T/K = 373.15

wB 0.9847 0.9581 0.9514 0.9344 0.9275 0.9195 0.9037 0.8820 0.8490

PA/kPa 3.41 7.32 7.88 10.20 10.90 11.30 12.80 14.40 16.40

wB 0.8480 0.0000

PA/kPa 16.40 20.72



T/K = 403.15

wB 0.9842 0.9765 0.9579 0.9578 0.9442 0.9429 0.9330 0.9120 0.9082

PA/kPa 7.10 10.90 17.40 17.90 22.00 22.70 25.40 30.60 31.50

continue

continue

wB 0.8780 0.8620 0.8300 0.0000

PA/kPa 36.90 39.90 44.20 55.85

copolymer (B): S-B-S/31w 99FRE


T/K = 323.85

wB 0.9877 0.9866 0.9674 0.9627 0.9618 0.9614 0.9607 0.9539 0.9485

aA 0.0533 0.0543 0.1324 0.1488 0.1536 0.1529 0.1568 0.1766 0.1988

wB 0.9393 0.9373 0.9296 0.9131 0.9097 0.8989 0.8955 0.8857 0.8753

aA 0.2288 0.2358 0.2612 0.3128 0.3314 0.3539 0.3563 0.3886 0.4153

wB 0.8655 0.8625 0.8581 0.8508 0.8459 0.8414 0.8381 0.8352 0.8242

aA 0.4398 0.4606 0.4569 0.4745 0.4854 0.4948 0.5035 0.5092 0.5327

wB 0.8198 0.8198 0.8196

aA 0.5424 0.5424 0.5430



T/K = 348.15

wB 0.9820 0.9678 0.9530 0.9542 0.9246 0.9256 0.9260 0.8773 0.8810

aA 0.0790 0.1282 0.1861 0.1832 0.2880 0.2805 0.2805 0.4209 0.4129

wB 0.8815 0.7972

aA 0.4112 0.5942



T/K = 373.15

wB 0.9779 0.9481 0.9197 0.9167 0.8804

aA 0.0915 0.1993 0.2907 0.2899 0.4042



T/K = 393.15

wB 0.9845 0.9851 0.9850 0.9767 0.9765 0.9768 0.9628 0.9643 0.9489

aA 0.0513 0.0513 0.0512 0.0778 0.0778 0.0780 0.1198 0.1192 0.1666

wB 0.9492 0.9487 0.9486 0.9488 0.9255 0.9266 0.9264 0.8973 0.8972

aA 0.1661 0.1657 0.1660 0.1664 0.2324 0.2327 0.2326 0.3173 0.3166

wB 0.8920 0.8952 0.8954 0.8973

aA 0.3046 0.3186 0.3159 0.3166

copolymer (B): S-B(h)-S/13w 99FRE


T/K = 324.35

wB 0.9963 0.9943 0.9929 0.9910 0.9888 0.9869 0.9868 0.9855 0.9839

aA 0.0127 0.0204 0.0247 0.0312 0.0388 0.0474 0.0455 0.0484 0.0543

wB 0.9807 0.9800 0.9710 0.9662 0.9555 0.9462 0.9460 0.9460 0.9452

aA 0.0639 0.0666 0.0951 0.1102 0.1433 0.1732 0.1733 0.1712 0.1710

wB 0.9404 0.9332 0.9129 0.9123 0.9118 0.9086 0.9078 0.9076 0.8396

aA 0.1901 0.2098 0.2735 0.2841 0.2761 0.2833 0.2849 0.2874 0.5550

wB 0.8381

aA 0.5602

copolymer (B): S-B(h)-S/31w 99FRE


T/K = 393.15

wB 0.9935 0.9934 0.9906 0.9893 0.9891 0.9875 0.9867 0.9846 0.9810

aA 0.0241 0.0247 0.0347 0.0400 0.0390 0.0441 0.0472 0.0556 0.0716

wB 0.9771 0.9702 0.9670 0.9666 0.9635 0.9521 0.9499 0.9479 0.9472

aA 0.0854 0.1088 0.1139 0.1156 0.1307 0.1748 0.1748 0.1782 0.1774

wB 0.9409 0.9406 0.9294 0.9289 0.9139 0.9135 0.9084 0.9052 0.8832

aA 0.1938 0.1966 0.2323 0.2339 0.2772 0.2785 0.2885 0.2967 0.3551

wB 0.8830 0.8818 0.8808 0.8429 0.7884 0.7880 0.7410 0.7373 0.7368

aA 0.3557 0.3570 0.3600 0.4446 0.5502 0.5491 0.6734 0.6751 0.6738

_____________________________________________________________________________

Copolymers from dimethylsiloxane and methylphenylsiloxane

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Dimethylsiloxane/methylphenylsiloxane copolymer

15 wt% methylphenylsiloxane DMS-MPS/15w 98SCH

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

DMS-MPS/15w 9100 41200 Dow Corning Corp., Midland, USA

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): DMS-MPS/15w 98SCH

solvent (A): anisole C7H8O 100-66-3

T/K = 313.15

wB 0.309 0.408 0.451 0.506 0.562 0.606 0.640 0.633 0.754

PA/PAs

0.997 0.987 0.988 0.987 0.963 0.934 0.920 0.886 0.807

wB 0.798 0.850 0.896 0.949

PA/PAs

0.734 0.631 0.505 0.301



T/K = 323.15

wB 0.406 0.449 0.503 0.558 0.604 0.638 0.631 0.753 0.798

PA/PAs

0.992 0.997 0.987 0.968 0.950 0.918 0.926 0.813 0.733

wB 0.850 0.896 0.949

PA/PAs

0.625 0.499 0.298



T/K = 333.15

wB 0.306 0.404 0.447 0.501 0.556 0.602 0.636 0.629 0.752

PA/PAs

0.991 0.980 0.981 0.976 0.957 0.944 0.918 0.919 0.804

wB 0.797 0.849 0.896 0.948

PA/PAs

0.724 0.610 0.486 0.289



T/K = 343.15

wB 0.306 0.404 0.447 0.501 0.556 0.602 0.636 0.629 0.752

PA/PAs

0.988 0.977 0.971 0.966 0.942 0.925 0.896 0.903 0.793

wB 0.797 0.849 0.896 0.948

PA/PAs

0.714 0.606 0.479 0.284



T/K = 305.15

wB 0.400 0.452 0.499 0.549 0.595 0.649 0.699 0.752 0.799

PA/PAs

0.971 0.966 0.956 0.948 0.935 0.920 0.915 0.891 0.858

wB 0.849 0.899 0.948

PA/PAs

0.785 0.683 0.489



T/K = 309.15

wB 0.401 0.453 0.500 0.551 0.596 0.651 0.701 0.753 0.801

PA/PAs

0.980 0.973 0.976 0.961 0.947 0.932 0.880 0.846 0.823

wB 0.850 0.900 0.949

PA/PAs

0.731 0.622 0.436



T/K = 314.15

wB 0.402 0.454 0.501 0.552 0.597 0.652 0.702 0.754 0.802

PA/PAs

0.976 0.970 0.968 0.949 0.927 0.916 0.884 0.844 0.797

wB 0.851 0.901 0.950

PA/PAs

0.718 0.599 0.411



T/K = 318.15

wB 0.404 0.456 0.502 0.553 0.599 0.653 0.703 0.756 0.804

PA/PAs

0.975 0.975 0.963 0.947 0.923 0.886 0.862 0.823 0.776

continue

continue

wB 0.853 0.902 0.951

PA/PAs

0.693 0.575 0.374



T/K = 322.15

wB 0.407 0.458 0.504 0.555 0.601 0.655 0.705 0.758 0.805

PA/PAs

0.958 0.960 0.957 0.947 0.915 0.887 0.859 0.807 0.765

wB 0.854 0.903 0.952

PA/PAs

0.687 0.565 0.372

_____________________________________________________________________________

Copolymers from ethylene and vinyl acetate

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Ethylene/vinyl acetate copolymer

9.0 wt% vinyl acetate E-VA/09w 95GUP

15.6 wt% vinyl acetate E-VA/16w(1) 73BEL





39.4 wt% vinyl acetate E-VA/39w 75BOB


41.4 wt% vinyl acetate E-VA/41w 76KIE


42.6 wt% vinyl acetate E-VA/43w 76KIE



_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

E-VA/09w Sci. Polym. Products, catalog #506

E-VA/16w(1) 2774 fractionated in the laboratory




E-VA/25w 20000 88000 Sci. Polym. Products, catalog #245

E-VA/39w 3650 fractionated in the laboratory







_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): E-VA/16w(1) 73BEL


T/K = 373.15

B 0.0000 0.0982 0.1729 0.1895 0.2573 0.2839 0.3228 0.3641PA/Torr 1335.0 1327.9 1315.8 1313.0 1294.9 1287.9 1273.6 1254.1



T/K = 373.15

B 0.0000 0.0675 0.1307 0.1907 0.2503 0.3082 0.3310 0.3791 0.4668PA/Torr 1335.0 1331.6 1324.9 1315.1 1300.7 1284.4 1276.5 1255.0 1206.0



T/K = 373.15

B 0.0000 0.0775 0.1465 0.1884 0.2624 0.3308 0.3817PA/Torr 1335.0 1331.0 1323.3 1316.8 1300.3 1278.4 1257.8



T/K = 373.15

B 0.0000 0.0976 0.1647 0.2072 0.2609 0.3142 0.3670 0.3971PA/Torr 1335.0 1330.8 1323.6 1317.0 1307.9 1295.0 1286.7 1260.0

copolymer (B): E-VA/39w 75BOB


T/K = 303.15

wB 0.000 0.244 0.292 0.333 0.498 0.516 0.536 0.590 0.622

PA/Torr 118.5 118.3 118.2 116.4 110.1 106.5 105.0 101.6 95.5

wB 0.739 0.760 0.835 0.872

PA/Torr 82.0 79.2 69.7 59.7



T/K = 323.15

wB 0.000 0.157 0.224 0.259 0.279 0.306 0.336 0.392 0.485

PA/Torr 269.20 268.90 267.20 265.90 266.25 261.95 259.45 254.00 233.80

wB 0.489 0.646 0.719 0.848 0.870

PA/Torr 215.40 210.10 189.80 167.70 155.15



T/K = 303.15

wB 0.000 0.247 0.299 0.318 0.349 0.396 0.415 0.478 0.497

PA/Torr 118.50 118.20 117.40 117.70 116.90 115.95 114.10 110.75 109.55

wB 0.518 0.622 0.672 0.712 0.779

PA/Torr 107.50 96.20 89.00 85.65 77.15



T/K = 323.15

wB 0.000 0.149 0.224 0.336 0.427 0.513 0.559 0.618 0.665

PA/Torr 269.20 269.15 261.90 257.05 242.15 220.85 207.05 193.25 181.80

wB 0.758 0.801 0.802 0.888 0.907

PA/Torr 150.90 121.35 124.35 106.00 70.20



T/K = 323.15

wB 0.000 0.307 0.325 0.348 0.435 0.495 0.527 0.557 0.621

PA/Torr 269.20 265.80 258.25 256.10 243.20 234.60 227.00 217.90 203.35

wB 0.692 0.730 0.749

PA/Torr 176.40 161.40 151.70



T/K = 343.15

wB 0.000 0.360 0.457 0.506 0.516 0.563 0.584 0.593 0.615

PA/Torr 548.16 519.90 494.40 476.90 496.90 445.50 433.50 423.60 414.40

wB 0.647 0.674 0.679

PA/Torr 388.10 372.10 366.60

copolymer (B): E-VA/09w 95GUP

solvent (A): 1-butanol C4H10O 71-36-3

T/K = 353.15

wB 0.994 0.988 0.983 0.973 0.969 0.966 0.964

PA/kPa 2.7 5.2 8.0 10.8 12.3 13.9 15.2

copolymer (B): E-VA/41w 76KIE

solvent (A): butyl acetate C6H12O2 123-86-4

T/K = 323.15

wB 0.1771 0.2141 0.2897 0.3163 0.3655 0.4005 0.4623 0.5462

PA/Torr 41.80 40.30 38.00 36.80 34.80 33.80 31.30 28.00



T/K = 343.15

wB 0.1802 0.2374 0.2580 0.3315 0.3655 0.4387 0.4892 0.5773

PA/Torr 101.40 98.10 96.40 89.70 87.40 79.90 75.40 64.90



T/K = 363.15

wB 0.1866 0.2591 0.3132 0.3767 0.4165 0.4571 0.5355 0.6488

PA/Torr 219.80 209.60 201.10 190.00 181.50 175.20 158.30 134.80



T/K = 353.15

wB 0.860 0.772 0.762 0.723 0.700 0.631

PA/kPa 39.7 54.9 55.5 60.7 64.1 70.4



T/K = 353.15

wB 0.896 0.841 0.830 0.795 0.775 0.713

PA/kPa 39.7 54.9 55.5 60.7 64.1 70.4



T/K = 353.15

wB 0.974 0.919 0.877 0.867 0.844 0.809 0.758

PA/kPa 14.4 39.7 54.9 55.5 60.7 64.1 70.4


solvent (A): ethyl acetate C4H8O2 141-78-6

T/K = 303.15

wB 0.2430 0.2805 0.3496 0.3565 0.3804 0.4400 0.5301

PA/Torr 118.70 118.30 117.85 115.60 114.10 111.75 100.90



T/K = 323.15

wB 0.2554 0.2959 0.3241 0.3707 0.3817 0.4400 0.5704

PA/Torr 281.20 279.10 274.90 272.80 263.10 257.20 230.20



T/K = 343.15

wB 0.2302 0.2885 0.3372 0.3651 0.4539 0.5754 0.7667

PA/Torr 588.20 584.00 570.40 566.70 547.55 489.10 386.30



T/K = 303.15

wB 0.2143 0.2476 0.3038 0.3490 0.3654 0.4005 0.4487 0.4851

PA/Torr 118.00 117.20 116.20 115.20 111.50 109.90 108.00 104.20



T/K = 323.15

wB 0.2208 0.2558 0.3170 0.3655 0.3849 0.4224 0.4764 0.5195

PA/Torr 277.20 276.40 270.50 269.70 259.00 252.00 244.00 235.70



T/K = 343.15

wB 0.2475 0.2894 0.3003 0.3750 0.4399 0.5250 0.6110 0.6960

PA/Torr 575.80 569.50 568.10 547.00 529.30 488.50 499.30 392.10


solvent (A): methyl acetate C3H6O2 79-20-9

T/K = 303.15

wB 0.2654 0.3257 0.3549 0.3651 0.4123 0.5102 0.5610 0.6130

PA/Torr 265.75 261.75 260.05 258.75 255.25 240.75 232.15 215.75



T/K = 323.15

wB 0.2561 0.3030 0.3762 0.3879 0.4387 0.4829 0.6341 0.7189

PA/Torr 586.15 584.15 565.15 561.65 550.65 535.15 473.15 424.65



T/K = 303.15

wB 0.1951 0.2632 0.3190 0.3725 0.3951 0.4839 0.5363 0.5744

PA/Torr 265.75 263.95 262.75 258.25 257.05 244.75 234.15 220.75



T/K = 323.15

wB 0.2154 0.2744 0.3706 0.4313 0.4775 0.5564 0.6653 0.7667

PA/Torr 586.15 579.15 565.05 542.15 526.35 490.15 439.45 378.15


solvent (A): propyl acetate C5H10O2 109-60-4

T/K = 303.15

wB 0.1978 0.2330 0.2662 0.2815 0.3335 0.3865 0.4445 0.5075

PA/Torr 42.70 42.10 41.50 40.70 39.50 38.20 36.20 34.00



T/K = 323.15

wB 0.2048 0.2428 0.2671 0.2959 0.3249 0.3701 0.4180 0.4815

PA/Torr 111.70 108.60 106.80 104.50 101.90 96.20 91.20 84.50



T/K = 343.15

wB 0.2200 0.2644 0.2931 0.3387 0.3658 0.4052 0.4434 0.5749

PA/Torr 250.60 243.00 237.50 227.90 220.90 211.00 202.70 168.00



T/K = 363.15

wB 0.2523 0.3126 0.3569 0.4066 0.4427 0.5364 0.6073 0.8102

PA/Torr 501.60 481.40 463.30 443.40 427.30 381.80 344.80 245.80



T/K = 373.15

B 0.0000 0.1459 0.2589 0.3228 0.3869 0.4668 0.4760 0.5356PA/Torr 558.60 542.50 533.10 518.50 499.90 472.60 470.80 444.60



T/K = 373.15

B 0.0000 0.0496 0.1272 0.2658 0.3599 0.3843 0.4432 0.5039PA/Torr 558.60 557.20 552.10 543.60 515.60 510.50 491.60 475.70



T/K = 373.15

B 0.0000 0.1209 0.2005 0.2113 0.3186 0.3711 0.4590 0.5357PA/Torr 558.60 553.00 545.60 544.40 527.90 513.60 493.60 473.80



T/K = 373.15

B 0.0000 0.1116 0.2037 0.2245 0.3482 0.3725 0.4318 0.4803 0.5302PA/Torr 558.60 555.60 547.20 544.40 528.20 522.90 509.00 497.10 485.10



T/K = 303.15

wB 0.000 0.364 0.413 0.463 0.469 0.488 0.524 0.588 0.666

PA/Torr 41.65 41.00 41.10 40.00 39.05 40.20 38.50 36.65 28.15

wB 0.687

PA/Torr 30.05



T/K = 323.15

wB 0.000 0.389 0.437 0.501 0.520 0.571 0.642 0.661 0.668

PA/Torr 97.25 96.30 93.25 90.35 89.30 87.35 81.50 78.00 74.20

continue

continue

wB 0.718 0.730

PA/Torr 62.25 63.75



T/K = 303.15

wB 0.000 0.201 0.276 0.339 0.414 0.436 0.465 0.523 0.546

PA/Torr 41.65 40.20 40.00 38.85 39.50 38.20 37.50 36.90 36.00

wB 0.555 0.578 0.598 0.621

PA/Torr 37.40 35.50 33.90 32.30



T/K = 323.15

wB 0.000 0.237 0.311 0.328 0.438 0.495 0.515 0.568 0.604

PA/Torr 97.25 96.15 95.00 95.95 94.60 94.00 91.00 89.35 80.60

wB 0.630 0.673 0.694

PA/Torr 81.35 72.90 65.35



T/K = 323.15

wB 0.000 0.403 0.473 0.519 0.537 0.567 0.571 0.600 0.673

PA/Torr 92.00 85.38 80.78 77.83 77.30 74.50 72.13 71.00 62.00

wB 0.736 0.749 0.785

PA/Torr 52.60 51.50 44.90



T/K = 343.15

wB 0.000 0.375 0.448 0.504 0.543 0.619 0.649 0.652 0.672

PA/Torr 204.05 191.80 182.60 176.70 169.80 154.30 149.80 147.30 139.20

wB 0.694 0.728 0.765 0.795

PA/Torr 132.80 124.10 109.40 101.20



T/K = 363.15

wB 0.000 0.431 0.506 0.524 0.549 0.570 0.600 0.680 0.715

PA/Torr 407.00 370.70 348.70 346.00 339.00 323.80 315.30 277.40 251.00

wB 0.771

PA/Torr 220.00



T/K = 333.15

wB 0.969 0.933 0.896 0.853 0.832 0.804 0.784 0.747

PA/kPa 14.0 28.1 40.1 53.2 58.4 66.1 72.3 87.1



T/K = 333.15

wB 0.938 0.860 0.772 0.680 0.642 0.599 0.559 0.519

PA/kPa 13.9 26.7 39.9 53.2 59.9 66.5 73.1 79.3



T/K = 333.15

wB 0.902 0.798 0.697 0.602 0.561 0.523 0.488 0.448

PA/kPa 13.9 26.7 39.9 53.2 59.9 66.5 73.1 79.3



T/K = 333.15

wB 0.941 0.839 0.713 0.597 0.550 0.511 0.474 0.427

PA/kPa 13.9 26.7 39.9 53.2 59.9 66.5 73.1 79.3



T/K = 323.15

wB 0.000 0.157 0.298 0.363 0.376 0.381 0.457 0.503 0.628

PA/Torr 25.76 25.30 25.25 25.10 25.30 25.30 24.20 23.20 17.80

continue

continue

wB 0.630 0.643 0.730 0.817 0.852 0.867

PA/Torr 17.50 18.35 14.80 11.90 10.40 8.45



T/K = 343.15

wB 0.000 0.307 0.336 0.386 0.437 0.442 0.504 0.577 0.588

PA/Torr 60.82 60.60 59.60 58.10 56.30 55.50 51.00 48.20 46.50

wB 0.616 0.640 0.676 0.716 0.780

PA/Torr 45.25 43.30 42.00 39.80 35.55



T/K = 363.15

wB 0.000 0.380 0.479 0.487 0.581 0.676 0.724 0.790 0.800

PA/Torr 139.00 129.10 120.90 120.65 108.85 93.10 85.10 71.15 63.10



T/K = 373.15

B 0.0000 0.1593 0.3009 0.3797 0.4441 0.4629 0.5091 0.5602PA/Torr 242.1 237.5 226.9 218.4 209.0 206.1 196.6 186.1



T/K = 373.15

B 0.0000 0.1767 0.2788 0.3282 0.3886 0.4585 0.5094 0.5728PA/Torr 242.1 237.0 229.4 225.0 217.7 206.9 199.0 181.3



T/K = 373.15

B 0.0000 0.1256 0.1878 0.2892 0.3569 0.4169 0.4525 0.5668PA/Torr 242.1 239.4 236.5 228.9 223.7 214.9 201.6 189.2



T/K = 373.15

B 0.0000 0.1573 0.2319 0.3007 0.3691 0.4466 0.5104 0.5857PA/Torr 242.1 238.0 234.3 229.5 222.3 212.1 201.3 189.0



T/K = 323.15

wB 0.000 0.157 0.180 0.325 0.416 0.441 0.530 0.545 0.576

PA/Torr 32.25 31.95 32.20 32.00 31.00 29.85 27.05 26.76 25.00

wB 0.578 0.632

PA/Torr 25.80 23.20



T/K = 343.15

wB 0.000 0.241 0.297 0.317 0.420 0.464 0.542 0.578 0.640

PA/Torr 75.70 75.50 73.50 72.90 70.05 67.05 61.40 59.35 56.60

wB 0.660 0.745 0.762

PA/Torr 51.90 46.65 43.60



T/K = 343.15

wB 0.000 0.440 0.524 0.599 0.605 0.615 0.643 0.748 0.802

PA/Torr 75.70 67.85 62.40 57.60 56.70 55.50 54.30 42.70 36.20



T/K = 363.15

wB 0.000 0.450 0.489 0.549 0.577 0.630 0.690 0.737 0.760

PA/Torr 167.80 149.70 145.20 136.90 131.90 121.80 110.70 103.35 91.95

wB 0.812

PA/Torr 77.20



T/K = 323.15

wB 0.000 0.451 0.512 0.597 0.634 0.649 0.732 0.737 0.800

PA/Torr 32.25 28.60 26.85 24.45 23.05 22.75 19.30 18.30 14.95



T/K = 343.15

wB 0.000 0.390 0.477 0.575 0.597 0.637 0.655 0.764 0.814

PA/Torr 75.70 69.15 65.15 59.20 56.80 53.50 52.10 40.75 37.80



T/K = 363.15

wB 0.000 0.450 0.509 0.558 0.600 0.641 0.681 0.717 0.732

PA/Torr 167.80 149.70 142.95 135.90 127.50 120.80 114.80 104.00 109.70

wB 0.773 0.827

PA/Torr 89.40 70.00

_____________________________________________________________________________

Copolymers from ethylene oxide and tert-butyl methacrylate

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Poly(ethylene oxide)-b-poly(tert-butyl methacrylate)

diblock copolymer

49 mol% ethylene oxide EO-b-tBMA/49x 94WOH

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________

Copolymer (B) Mn/ Further information

g/mol

_____________________________________________________________________________

EO-b-tBMA/49x 8200 (= 4000 + 4200) synthesized in the laboratory

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): EO-b-tBMA/49x 94WOH


T/K = 323.15

B 0.0000 0.4505 0.4669 0.4983 0.5444 0.5827 0.6132 0.6352 0.6469PA/Torr 92.12 86.46 85.81 83.88 81.36 78.58 76.25 74.12 72.88

B 0.6715 0.7086 0.7461 0.7622 0.7877PA/Torr 69.51 65.20 60.40 57.28 53.11

Comments: segment fraction is based on Bondi's volumina with rB = 80

copolymer (B): EO-b-tBMA/49x 94WOH


T/K = 343.75

B 0.0000 0.5091 0.5128 0.5663 0.5976 0.6185 0.6439 0.6590 0.6879PA/Torr 208.40 184.38 182.95 175.99 170.90 167.55 162.12 158.66 151.55

B 0.6879 0.7232 0.7501 0.7501PA/Torr 152.29 143.51 134.77 135.21


_____________________________________________________________________________

Copolymers from ethylene oxide and methyl methacrylate

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Poly(ethylene oxide)-b-poly(methyl methacrylate)

diblock copolymer

51.7 mol% ethylene oxide EO-b-MMA/52x 86KRC

Poly(ethylene oxide)-b-poly(methyl methacrylate)-

b-poly(ethylene oxide) triblock copolymer

61.0 mol% ethylene oxide EO-MMA-EO/61x 86KRC

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________

Copolymer (B) Mn/ Further information

g/mol

_____________________________________________________________________________

EO-b-MMA/52x 8900 (= 4600 + 4300) synthesized in the laboratory

EO-MMA-EO/61x 7860 (= 2400 + 3060 + 2400) synthesized in the laboratory

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): EO-b-MMA/52x 86KRC


T/K = 323.41

B 0.536 0.562 0.648 0.747 0.766PA/kPa 10.626 10.226 9.613 7.933 7.773




continue

continue

T/K = 343.27

B 0.522 0.562 0.567 0.615 0.641 0.644PA/kPa 23.878 22.638 22.691 21.878 21.252 20.132




T/K = 373.27

B 0.432 0.499 0.559 0.609 0.668 0.744 0.789 0.829 0.839PA/kPa 69.671 67.697 64.822 62.333 59.430 54.473 50.826 47.979 46.333

B 0.867PA/kPa 44.703


copolymer (B): EO-MMA-EO/61x 86KRC


T/K = 323.08

B 0.461 0.547 0.599 0.667 0.736 0.762PA/kPa 11.457 10.626 10.226 9.613 8.706 8.399

Comments: segment fraction is based on Bondi's volumina with rB = 73.2



T/K = 343.17

B 0.535 0.573 0.583 0.629 0.654 0.697PA/kPa 23.878 22.638 22.691 21.878 21.252 19.772




T/K = 373.26

B 0.554 0.612 0.628 0.665 0.685 0.729 0.785 0.876PA/kPa 69.010 66.786 65.349 63.299 61.341 57.274 56.992 54.174


_____________________________________________________________________________

Copolymers from ethylene oxide and propylene oxide

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Poly(ethylene oxide)-b-poly(propylene oxide)

diblock copolymer

40.0 mol% propylene oxide EO-b-PO/40x 94WOH

58.0 wt% propylene oxide EO-b-PO/58w 89MOE

Poly(ethylene oxide)-b-poly(propylene oxide)-

b-poly(ethylene oxide) triblock copolymer

50.0 mol% propylene oxide EO-PO-EO/50x 94WOH

67.0 wt% propylene oxide EO-PO-EO/67w 89MOE



Poly(propylene oxide)-b-poly(ethylene oxide)-

b-poly(propylene oxide) triblock copolymer

50.0 mol% propylene oxide PO-EO-PO/50x 94WOH

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

EO-b-PO/40x 4240 4700 synthesized in the laboratory

EO-b-PO/58w 1700

EO-PO-EO/50x 10800 synthesized in the laboratory

EO-PO-EO/67w 1900

EO-PO-EO/87w 950

EO-PO-EO/93w 1800

PO-EO-PO/50x 10800 synthesized in the laboratory

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): EO-b-PO/40x 94WOH


T/K = 343.75

wB 0.1075 0.1277 0.1496 0.1859 0.2135 0.2315 0.2626 0.3182 0.5333

PA/PAs

0.9961 0.9959 0.9922 0.9892 0.9851 0.9839 0.9795 0.9637 0.9057

wB 0.6201 0.6639 0.6987 0.7048 0.7339 0.7655 0.7805 0.8040 0.8290

PA/PAs

0.8528 0.8135 0.7823 0.7750 0.7431 0.7072 0.6805 0.6532 0.6036

copolymer (B): EO-b-PO/58w 89MOE

solvent (A): tetrachloromethane CCl4 56-23-5

T/K = 303.15

wB 0.1004 0.2011 0.3019 0.4026 0.5038 0.6038 0.7032 0.8031 0.8971

aA 0.9830 0.9466 0.8884 0.8088 0.7088 0.5925 0.4620 0.3163 0.1704

copolymer (B): EO-PO-EO/50x 94WOH


T/K = 323.35

B 0.0000 0.4191 0.4480 0.4565 0.4877 0.5584 0.5834 0.6325 0.6906PA/Torr 92.90 84.97 83.29 82.84 80.76 75.51 73.03 68.18 60.69

B 0.7184 0.7604 0.7856 0.8077PA/Torr 57.08 50.74 46.62 42.56


copolymer (B): EO-PO-EO/50x 94WOH


T/K = 343.75

B 0.0000 0.4471 0.4635 0.4811 0.5474 0.5629 0.5818 0.6436 0.6717PA/Torr 208.40 178.31 176.28 173.77 163.06 160.68 157.33 144.30 138.30

B 0.6986 0.7356 0.7556PA/Torr 130.92 121.29 114.87


copolymer (B): EO-PO-EO/67w 89MOE


T/K = 303.15

wB 0.0995 0.1993 0.2994 0.3992 0.5004 0.6004 0.7021 0.8014 0.9032

aA 0.9919 0.9620 0.9114 0.8383 0.7416 0.6264 0.4910 0.3423 0.1755



T/K = 303.15

wB 0.0991 0.1987 0.2988 0.3986 0.4991 0.5998 0.7004 0.8007 0.9025

aA 0.9810 0.9453 0.8912 0.8162 0.7204 0.6054 0.4746 0.3281 0.1677



T/K = 303.15

wB 0.0991 0.1988 0.2986 0.3994 0.4998 0.6002 0.7009 0.8017 0.8981

aA 0.9861 0.9518 0.8964 0.8173 0.7179 0.6010 0.4674 0.3219 0.1712

copolymer (B): PO-EO-PO/50x 94WOH


T/K = 323.05

B 0.0000 0.3885 0.4300 0.4341 0.4682 0.5138 0.5604 0.5761 0.6269PA/Torr 91.72 84.97 83.29 82.84 80.76 77.99 74.37 73.03 68.18

B 0.7369 0.7580 0.7838PA/Torr 54.35 50.74 46.62


copolymer (B): PO-EO-PO/50x 94WOH


T/K = 342.65

B 0.0000 0.3794 0.4077 0.4516 0.5346 0.5629 0.6045 0.6148 0.6320PA/Torr 200.10 181.02 178.31 173.77 163.06 158.86 152.05 150.12 147.40

B 0.6646 0.7063 0.7262 0.7695 0.7898PA/Torr 140.64 130.92 125.98 114.87 108.41


_____________________________________________________________________________

Copolymers from ethylene oxide and styrene

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Polystyrene-b-poly(ethylene oxide) diblockcopolymer

blocks are not further specified S-b-EO/? 94WOH

Poly(ethylene oxide)-b-polystyrene-b-poly(ethylene oxide)

triblock copolymer

blocks are not further specified EO-S-EO/? 94WOH

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-b-EO/? 45000 synthesized in the laboratory

EO-S-EO/? 45000 synthesized in the laboratory

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-b-EO/? 94WOH


T/K = 322.95

wB 0.0000 0.5773 0.6233 0.6728 0.6772 0.6981 0.7255 0.7387 0.7551

PA/Torr 91.33 82.40 79.77 76.10 75.51 73.38 70.90 69.71 67.48

wB 0.7842 0.7903 0.8222

PA/Torr 65.05 62.82 58.71

copolymer (B): S-b-EO/? 94WOH


T/K = 342.65

wB 0.0000 0.5628 0.5805 0.6064 0.6212 0.6532 0.6839 0.7077 0.7280

PA/Torr 200.10 182.80 179.74 178.06 175.64 170.71 165.13 160.98 156.29

wB 0.7385 0.7439 0.7467 0.7841 0.8155

PA/Torr 154.61 152.14 153.18 144.15 135.01

copolymer (B): EO-S-EO/? 94WOH


T/K = 323.35

wB 0.0000 0.5825 0.6191 0.6634 0.6865 0.7081 0.7210 0.7379 0.7592

PA/Torr 92.90 82.40 79.77 75.51 73.38 70.90 69.71 67.48 65.05

wB 0.7666 0.7704 0.8017 0.8269

PA/Torr 64.11 62.82 58.71 54.00

copolymer (B): EO-S-EO/? 94WOH


T/K = 343.75

wB 0.0000 0.5576 0.5759 0.5978 0.6141 0.6165 0.6390 0.6717 0.6863

PA/Torr 208.40 182.80 179.74 178.06 175.64 174.51 170.71 165.13 160.98

wB 0.7144 0.7144 0.7209 0.7343 0.7591 0.7856 0.8057

PA/Torr 154.61 156.29 153.18 152.14 144.15 135.01 127.11

_____________________________________________________________________________

Copolymers from 3-hydroxybutanoic acid and 3-hydroxypentanoic acid

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

3-Hydroxybutanoic acid/3-hydroxypentanoic acid copolymer

14 wt% 3-hydroxypentanoic acid HBA-HPA/14w 99WOH

22 wt% 3-hydroxypentanoic acid HBA-HPA/22w 99WOH

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

HBA-HPA/14w 153000 454000 Aldrich Chem.Co., catalog #34739-6

HBA-HPA/22w 188000 529000 Aldrich Chem.Co., catalog #34741-8

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): HBA-HPA/14w 99WOH

solvent (A): chlorobenzene C6H5Cl 108-90-7

T/K = 373.15

wB 0.7854 0.7495 0.7028 0.6566 0.6205 0.5746 0.5311 0.0000

PA/Pa 23780.0 26315.0 28811.7 30649.7 32403.5 33602.1 34540.3 38293.0



T/K = 388.15

wB 0.7312 0.6970 0.6627 0.6245 0.5989 0.5581 0.5128 0.4885 0.0000

PA/Pa 43492.0 46497.2 49109.0 51272.2 52716.4 54775.2 56514.4 57104.4 61455.4



T/K = 403.15

wB 0.8103 0.7537 0.7093 0.6687 0.6329 0.5908 0.5617 0.5113 0.0000

PA/Pa 53051.4 62960.1 68848.4 74082.4 77856.2 81961.9 83886.7 86475.3 94819.4

copolymer (B): HBA-HPA/w 99WOH


T/K = 373.15

wB 0.7663 0.7015 0.6779 0.6482 0.6289 0.5963 0.5340 0.4813 0.4220

PA/Pa 23538.7 27283.8 28260.2 29592.8 30354.9 31698.9 33418.3 34578.6 35777.2



T/K = 388.15

wB 0.0000 0.4112 0.5127 0.5600 0.6122 0.6354 0.6708 0.7046 0.7352

PA/Pa 61455.4 57983.2 54984.1 52833.2 50178.3 48605.1 45882.6 43246.2 40658.9

wB 0.7740 0.7970

PA/Pa 37039.2 34556.4



T/K = 403.15

wB 0.0000 0.5091 0.5586 0.5997 0.6354 0.6731 0.7182 0.7501 0.7877

PA/Pa 94819.4 85015.1 81582.6 78690.6 74376.3 71199.9 64941.8 60722.3 54435.8

_____________________________________________________________________________

Copolymers from styrene and butyl methacrylate

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Styrene/butyl methacrylate copolymer

50.0 wt% styrene S-BMA/50w 95GUP

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-BMA/50w 105300 200000 Sci. Polym. Products, catalog #595

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-BMA/50w 95GUP


T/K = 333.15

wB 0.978 0.956 0.947 0.929 0.910 0.867 0.856 0.836 0.799

PA/kPa 23.5 43.3 51.6 60.3 67.6 81.7 85.3 90.4 95.9

wB 0.776 0.746

PA/kPa 98.7 100.4

copolymer (B): S-BMA/50w 95GUP


T/K = 343.15

wB 0.922 0.852 0.778 0.708 0.631 0.545 0.488

PA/kPa 13.3 26.4 40.1 53.6 65.5 78.8 86.0

_____________________________________________________________________________

Copolymers from styrene and docosyl maleate

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Styrene/docosyl maleate copolymer

50.0 mol% styrene S-DCM/50x 97MIO

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-DCM/50x 244500 293400 synthesized in the laboratory

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-DCM/50x 97MIO


T/K = 333.15

wB 0.976 0.967 0.943 0.929 0.906 0.881 0.846 0.809 0.765

PA/Torr 50.5 76.5 106.0 131.5 157.5 188.5 218.0 251.5 279.0

wB 0.710 0.630 0.000

PA/Torr 300.5 362.5 390.0


solvent (A): methanol CH4O 67-56-1

T/K = 333.15

wB 0.982 0.975 0.965 0.954 0.940 0.920 0.895 0.879 0.000

PA/Torr 128.0 190.0 247.5 296.0 354.5 400.5 457.5 489.5 635.0



T/K = 323.15

wB 0.974 0.965 0.957 0.945 0.927 0.904 0.874 0.846 0.799

PA/Torr 106.0 156.0 196.0 243.0 295.5 346.5 406.0 448.0 492.0

wB 0.769 0.000

PA/Torr 513.0 612.0



T/K = 343.15

wB 0.976 0.964 0.950 0.937 0.915 0.890 0.858 0.827 0.806

PA/Torr 230.0 317.5 408.5 494.5 587.0 679.5 786.0 857.5 896.0

wB 0.000

PA/Torr 1196.0

_____________________________________________________________________________

Copolymers from styrene and dodecyl maleate

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Styrene/dodecyl maleate copolymer

50.0 mol% styrene S-DDM/50x 97MIO

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-DDM/50x 177500 213000 synthesized in the laboratory

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-DDM/50x 97MIO


T/K = 333.15

wB 0.990 0.978 0.963 0.941 0.935 0.914 0.887 0.856 0.821

PA/Torr 50.5 76.5 106.0 131.5 157.5 188.5 218.0 251.5 279.0

wB 0.769 0.692 0.000

PA/Torr 300.5 362.5 390.0



T/K = 333.15

wB 0.976 0.966 0.950 0.931 0.907 0.835 0.808 0.000

PA/Torr 128.0 190.0 247.5 296.0 354.5 457.5 489.5 635.0



T/K = 323.15

wB 0.965 0.950 0.941 0.921 0.893 0.861 0.826 0.786 0.712

PA/Torr 106.0 156.0 196.0 243.0 295.5 346.5 406.0 448.0 492.0

wB 0.665 0.000

PA/Torr 513.0 612.0



T/K = 343.15

wB 0.978 0.961 0.947 0.927 0.898 0.863 0.817 0.778 0.746

PA/Torr 230.0 317.5 408.5 494.5 587.0 679.5 786.0 857.5 896.0

wB 0.000

PA/Torr 1196.0

_____________________________________________________________________________

Copolymers from styrene and isoprene

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Polystyrene-b-polyisoprene-b-polystyrene triblock copolymer

15.0 wt% styrene S-I-S/15w 99FRE



_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-I-S/15w 159000 synthesized in the laboratory



_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-I-S/15w 99FRE


T/K = 323.45

wB 0.9941 0.9922 0.9921 0.9883 0.9833 0.9826 0.9791 0.9709 0.9649

aA 0.0242 0.0298 0.0291 0.0449 0.0646 0.0661 0.0798 0.1097 0.1306

wB 0.9531 0.9209 0.8960 0.8959 0.8680 0.8679 0.8447 0.8376 0.8364

aA 0.1712 0.2792 0.3526 0.3529 0.4409 0.4412 0.5140 0.5505 0.5546

wB 0.8359 0.8195 0.8183

aA 0.5547 0.6841 0.6941



T/K = 323.55

wB 0.9916 0.9839 0.9806 0.9724 0.9581 0.9579 0.9445 0.9421 0.8907

aA 0.0325 0.0602 0.0700 0.1007 0.1496 0.1503 0.1948 0.2032 0.3552

wB 0.8894 0.8570 0.8158

aA 0.3606 0.4376 0.5434



T/K = 323.95

wB 0.9922 0.9921 0.9892 0.9891 0.9814 0.9785 0.9768 0.9723 0.9670

aA 0.0327 0.0321 0.0440 0.0439 0.0737 0.0854 0.0912 0.1086 0.1294

wB 0.9574 0.9492 0.9305 0.9231 0.9226 0.8606 0.7565

aA 0.1644 0.1925 0.2565 0.2791 0.2817 0.4405 0.6721

_____________________________________________________________________________

Copolymers from styrene and maleic anhydride

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Styrene/maleic anhydride copolymer

50.0 mol% styrene S-MAH/50x 97MIO

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-MAH/50x 96700 116000

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-MAH/50x 97MIO


T/K = 333.15

wB 0.932 0.906 0.878 0.830 0.794 0.761 0.737 0.700 0.657

PA/Torr 127.5 175.5 229.5 286.5 339.0 393.0 434.5 484.5 505.0

wB 0.000

PA/Torr 635.0

copolymer (B): S-MAH/50x 97MIO


T/K = 323.15

wB 0.902 0.856 0.819 0.783 0.771 0.714 0.621 0.000

PA/Torr 215.5 278.0 336.5 389.0 400.0 454.0 489.0 612.0

_____________________________________________________________________________

Copolymers from styrene and methyl methacrylate

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Styrene/methyl methacrylate copolymer

44.0 wt% styrene S-MMA/44w 97WO2

50.0 wt% styrene S-MMA/50w 97TAN

Polystyrene-b-poly(methyl methacrylate) diblock copolymer

47.8 wt% polystyrene S-b-MMA/48w 98WOH

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________

Copolymer (B) Mn/ Mw/ Further information

g/mol g/mol

_____________________________________________________________________________

S-MMA/44w 50600 85000 synthesized in the laboratory

S-MMA/50w 91000 100000 Polysciences Inc.

S-b-MMA/48w 18000 20500 ( = 9800-b-10700) Polysciences Inc.

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-MMA/44w 97WO2


T/K = 343.15

wB 0.0000 0.4664 0.5157 0.5797 0.6218 0.6566 0.7079 0.7615 0.8101

PA/Pa 73128.3 67029.4 65054.9 61786.1 59190.0 56652.5 52147.8 46421.8 40015.8



continue

continue

T/K = 373.15

wB 0.0000 0.5735 0.5905 0.6201 0.6489 0.6717 0.7056 0.7339 0.7653

PA/Pa 34300.5 31378.1 31172.3 30668.1 29937.5 29296.1 28253.3 27196.9 25704.8

wB 0.8097

PA/Pa 23190.6



T/K = 398.15

wB 0.0000 0.5496 0.6039 0.6328 0.6600 0.7014 0.7221 0.7575 0.7930

PA/Pa 74321.2 68866.0 67022.9 65618.2 64243.2 61493.4 59895.5 56603.0 52693.7

wB 0.8143

PA/Pa 49661.4



T/K = 398.15

wB 0.0000 0.6365 0.6783 0.7010 0.7321 0.7598 0.7834 0.8066 0.8293

PA/Pa 32215.7 29635.2 28936.1 28614.0 27708.7 26822.8 25982.0 24703.0 23085.8



T/K = 343.15

wB 0.0000 0.4775 0.5203 0.5674 0.6186 0.6607 0.7091 0.7520 0.7997

PA/Pa 27250.3 24991.3 24459.9 23707.8 22857.6 21868.4 20484.1 19042.5 17017.8



T/K = 373.15

wB 0.0000 0.5029 0.5586 0.6111 0.6508 0.6930 0.7366 0.7823

PA/Pa 74464.2 67256.1 65118.9 62594.6 59765.0 57464.0 53673.8 48736.8



T/K = 398.15

wB 0.0000 0.6109 0.6393 0.6708 0.6954 0.7112 0.7467 0.7799 0.8083

PA/Pa 69803.4 64896.2 63967.8 63179.1 61985.4 60987.2 58209.1 54893.4 51598.7

wB 0.8363

PA/Pa 47368.6

copolymer (B): S-MMA/50w 97TAN


T/K = 323.15

wB 0.919 0.879 0.826 0.754 0.679 0.000

PA/kPa 43.10 52.81 61.39 68.83 74.73 78.69



T/K = 323.15

wB 0.926 0.874 0.769 0.555 0.000

PA/kPa 51.98 64.30 76.06 81.66 81.67



T/K = 323.15

wB 0.884 0.749 0.626 0.492 0.376 0.000

PA/kPa 14.36 27.96 40.43 51.86 60.79 70.17

copolymer (B): S-b-MMA/48w 98WOH


T/K = 343.15

wB 0.0000 0.4524 0.5067 0.5491 0.5889 0.6291 0.6674 0.7127 0.7567

PA/Pa 73128.3 67614.5 65530.0 63512.0 61303.5 58751.0 55877.5 51840.5 46977.5



continue

continue

T/K = 373.15

wB 0.0000 0.5801 0.6199 0.6512 0.6990 0.7293 0.7617 0.8014

PA/Pa 34300.5 31591.0 30891.0 30243.0 28843.5 27807.5 26384.0 24151.0



T/K = 398.15

wB 0.0000 0.5794 0.6262 0.6508 0.6833 0.7158 0.7485 0.7771 0.8144

PA/Pa74321.2 68279.0 66465.5 65410.0 63500.0 61137.0 58201.0 54886.0 50211.5



T/K = 398.15

wB 0.0000 0.6714 0.6997 0.7223 0.7591 0.7982 0.8245

PA/Pa 32215.7 29603.0 28965.0 28430.5 26984.0 25295.5 23646.5



T/K = 343.15

wB 0.0000 0.5017 0.5340 0.5611 0.5960 0.6326 0.6723 0.7138 0.7469

PA/Pa 27250.3 24751.5 24362.0 23947.5 23372.5 22699.5 21511.5 20585.0 19418.5

wB 0.7782

PA/Pa 18277.0



T/K = 373.15

wB 0.0000 0.4832 0.5364 0.5796 0.6298 0.6663 0.6997 0.7462 0.7897

PA/Pa 74464.2 68224.0 66668.0 64694.5 61939.0 59750.0 57404.5 53197.0 48424.0



T/K = 398.15

wB 0.0000 0.5998 0.6476 0.6895 0.7192 0.7465 0.7839 0.8124

PA/Pa 69803.4 64910.0 63870.0 62292.5 60268.0 58328.0 54314.0 51424.0

_____________________________________________________________________________

Copolymers from styrene and pentyl maleate

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Styrene/pentyl maleate copolymer

50.0 mol% styrene S-PM/50x 97MIO

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________


g/mol g/mol g/mol

_____________________________________________________________________________

S-PM/50x 130000 156000 synthesized in the laboratory

_____________________________________________________________________________


_____________________________________________________________________________

copolymer (B): S-PM/50x 97MIO


T/K = 333.15

wB 0.996 0.994 0.982 0.981 0.975 0.953 0.946 0.934 0.892

PA/Torr 76.5 106.0 131.5 157.5 188.5 218.0 251.5 279.0 300.5

wB 0.874 0.000

PA/Torr 362.5 390.0



T/K = 333.15

wB 0.970 0.956 0.940 0.915 0.882 0.847 0.783 0.734 0.000

PA/Torr 128.0 190.0 247.5 296.0 354.5 400.5 457.5 489.5 635.0



T/K = 323.15

wB 0.967 0.942 0.932 0.914 0.888 0.848 0.806 0.759 0.675

PA/Torr 106.0 156.0 196.0 243.0 295.5 346.5 406.0 448.0 492.0

wB 0.631 0.000

PA/Torr 513.0 612.0



T/K = 343.15

wB 0.985 0.968 0.950 0.924 0.891 0.849 0.794 0.745 0.706

PA/Torr 230.0 317.5 408.5 494.5 587.0 679.5 786.0 857.5 896.0

wB 0.000

PA/Torr 1196.0

_____________________________________________________________________________

Copolymers from vinyl acetate and vinyl chloride

_____________________________________________________________________________


_____________________________________________________________________________


_____________________________________________________________________________

Vinyl acetate/vinyl chloride copolymer

10.0 wt% vinyl acetate VA-VC/10w 95GUP

12.0 wt% vinyl acetate VA-VC/12w(1) 98KIM

12.0 wt% vinyl acetate VA-VC/12w(2) 95GUP

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Characterization:

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g/mol g/mol g/mol

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VA-VC/10w 115000 Sci. Polym. Products, catalog #068

VA-VC/12w(1) 7800 22000 Sci. Polym. Products

VA-VC/12w(2) 14300 30000 Sci. Polym. Products, catalog #063

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copolymer (B): VA-VC/12w(1) 98KIM


T/K = 398.15

wB 0.9747 0.9689 0.9610 0.9503 0.9421 0.9309 0.9190

aA 0.1084 0.1384 0.1648 0.1991 0.2099 0.2593 0.2911



T/K = 418.15

wB 0.9690 0.9630 0.9561 0.9482 0.9400 0.9318 0.9289

aA 0.1120 0.1371 0.1614 0.1846 0.2166 0.2774 0.2869

copolymer (B): VA-VC/12w(2) 95GUP

solvent (A): 1-butanol C4H10O 71-36-3

T/K = 353.15

wB 0.993 0.984 0.978 0.967 0.960 0.956 0.954

PA/kPa 2.7 5.2 8.0 10.8 12.3 13.9 15.2



T/K = 398.15

wB 0.9880 0.9841 0.9794 0.9738 0.9674 0.9600 0.9516

aA 0.0828 0.0927 0.1159 0.1517 0.1990 0.2268 0.2642



T/K = 398.15

wB 0.9703 0.9611 0.9510 0.9384 0.9225 0.9010 0.8716

aA 0.2431 0.3024 0.3670 0.4353 0.5054 0.5755 0.6955



T/K = 418.15

wB 0.9794 0.9748 0.9691 0.9622 0.9547 0.9460 0.9364

aA 0.1793 0.2100 0.2508 0.2973 0.3446 0.3957 0.4476



T/K = 428.15

wB 0.9814 0.9773 0.9727 0.9676 0.9613 0.9538 0.9446

aA 0.1406 0.1709 0.2030 0.2360 0.2690 0.3260 0.3890

copolymer (B): VA-VC/12w(2) 95GUP


T/K = 353.15

wB 0.971 0.970 0.968 0.963 0.963 0.962

PA/kPa 13.6 28.4 39.9 52.5 65.7 79.1



T/K = 398.15

wB 0.9846 0.9828 0.9809 0.9789 0.9766 0.9742 0.9718

aA 0.1859 0.2023 0.2188 0.2355 0.2521 0.2686 0.2849



T/K = 418.15

wB 0.9823 0.9804 0.9786 0.9766 0.9744 0.9722 0.9701

aA 0.2006 0.2268 0.2496 0.2606 0.2738 0.3038 0.3296



T/K = 398.15

wB 0.9884 0.9843 0.9791 0.9729 0.9649 0.9549 0.9432

aA 0.0927 0.1472 0.1970 0.2368 0.2890 0.3436 0.4189



T/K = 418.15

wB 0.9864 0.9815 0.9752 0.9675 0.9583 0.9476 0.9355

aA 0.1262 0.1677 0.2148 0.2765 0.3420 0.4001 0.4566

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Copolymers from vinyl acetate and vinyl alcohol

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Vinyl acetate/vinyl alcohol copolymer

8.0 mol% vinyl acetate VA-VAL/08x 2000NAG

17.5 mol% vinyl acetate VA-VAL/18x 2000NAG

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Characterization:

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g/mol g/mol g/mol

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VA-VAL/08x 70000 B (298 K) = 1.241 g/cm3VA-VAL/18x 85000 B (298 K) = 1.234 g/cm3_____________________________________________________________________________


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copolymer (B): VA-VAL/08x 2000NAG

solvent (A): water H2O 7732-18-5

T/K = 298.15

B 0.0039 0.0075 0.0083 0.0113 0.0125 0.0151 0.0164 0.0206aA 0.999968 0.999963 0.999959 0.999945 0.999917 0.999896 0.999867 0.999839

B 0.0302 0.0330 0.0360 0.0409 0.0505 0.0575 0.0635 0.0727aA 0.999998 0.999996 0.999995 0.999992 0.999991 0.999990 0.999987 0.999980

B 0.0747 0.0883 0.0910 0.1065aA 0.999819 0.999

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