1. Resin R3X5_material Safety Data Sheet_Part A

Date : 3 June 2013 Product : R3X5BL, R3X5GY MSDS No. : 21306001 (Part A)

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MATERIAL SAFETY DATA SHEET in accordance with REACH (1907/2006/EC, as amended by 453/2010/EC)

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier: R3X5BL, R3X5GY (part A), Date : 3 June 2013 MSDS No. : 21306001 1.2. Relevant identified uses of the substance or mixture and uses advised against R3X5BL, R3X5GY Polymer Composite. Repair damage caused by impact, abrasion, erosion or corrosion, rebuild worn areas, fill holes and cracks, provide abrasion resistant surfaces.

1.3. Details of the supplier of the safety data sheet Company: 3X ENGINEERING 9 Av. Albert II 98000 Monaco Tel. : +377 92 05 79 81 Fax : +377 92 05 72 71 (mon. fri. 8 a.m. 5 p.m.) E-mail (questions) : [email protected]

Supplier:

1.4. Emergency telephone number 24 hours per day, 7 days per week Call Infotrac: 1-800-535-5053 Outside N. America: +1 352-323-3500 (collect) Use : 3X Polymer Composite. Repair damage caused by impact, abrasion, erosion or corrosion; rebuild worn areas; fill holes and cracks; provide abrasion resistant surfaces. 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture 2.1.1. Classification according to Directive 1999/45/EC Irritant; Xi; R36/38 R43 Dangerous for the environment; N; R51/53

2.1.2. Canadian WHMIS classification D2A: Very toxic materials causing other effects; D2B: Toxic materials causing other effects

2.1.3. Australian classification Hazardous according to criteria of Safe Work Australia. 2.1.4. Additional information For full text of R-phrases: see SECTIONS 2.2 and 16.

2.2. Label elements Labeling according to Directive 1999/45/EC Danger symbols: Xi - Irritant; N - Dangerous for the environment

R-phrases: R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrases: S37/39 Wear suitable gloves and eye/face protection. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28A After contact with skin, wash immediately with plenty of soap and water. S61 Avoid release to the environment. Refer to special instructions/safety data sheets.


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Other information: Contains epoxy constituents. See information supplied by the manufacturer. 2.3. Other hazards The safety and health hazards are detailed separately for Part A and Part B. The final cured material is considered nonhazardous. Upon machining, refer to the precautions in the safety data sheets for Part A and Part B. 3. COMPOSITION / INFORMATION ON INGREDIENTS 3.2. Mixtures Hazardous Ingredients % Wt. CAS No.1 REACH Classification Classification EC No. Reg. No. (acc. to 1272120081EC) (6715481EEC)

Epoxy resin (number average 10-30 25068-38-6 01- Eye Irrit. 2, H319 Xi; 836/38-43- molecular weight


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4. FIRST AID MEASURES 4.1. Description of first aid measures Inhalation : Not applicable.

Skin Contact: Remove contaminated clothing. Wash skin with soap and water. Consult physician if irritation develops.

Eye Contact: Flush eyes for at least 15 minutes with large amounts of water. Consult physician if irritation develops.

Ingestion : Do not induce vomiting. Contact physician immediately.

Advice to Physician: : Advice to Physician: Treat symptoms.

4.2. Most important symptoms and effects, both acute and delayed Moderate eye and skin irritant. May cause skin sensitization as evidenced by rashes or hives. Repeated inhalation of respirable free silica may cause scarring of the lungs with cough and shortness of breath. Silicosis, a delayed lung injury that is a disabling, progressive and sometimes fatal pulmonary fibrosis, may result. The International Agency for Research on Cancer (IARC) and the National Toxicology Program (NTP) have classified inhaled silica as a human carcinogen. Prolonged, excessive inhalation of Graphite dust has caused emphysema and pneumoconiosis. The silica and graphite in this product do not separate from the mixture or in of themselves become airborne, therefore, do not present a hazard in normal use. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptoms. 5. FIRE-FIGHTING MEASURES 5.1. Extinguishing media: Carbon Dioxide, dry chemical, foam or water fog 5.2. Special hazards arising from the substance or mixture none

5.3. Advice for firefighters: Cool exposed containers with water. Recommend Firefighters wear self-contained breathing apparatus. Flammability classification: - HAZCHEM Emergency Action Code: 2 Z 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin contact. Utilize exposure controls and personal protection as specified in Section 8. 6.2. Environmental Precautions Keep out of sewers, streams and waterways. 6.3. Methods and material for containment and cleaning up Contain spill to a small area. Pick up with absorbent material (sand, sawdust, clay, etc.) and place in a suitable container for disposal. 6.4. Reference to other sections Refer to section 13 for disposal advice. 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Remove contaminated clothing immediately. Wash clothing before reuse. Contaminated leather including shoes cannot be decontaminated and should be discarded. Utilize exposure controls and personal protection as specified in Section 8. Avoid creating and breathing dust during removal, drilling, grinding, sawing or sanding. 7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry area. 7.3. Specific end use(s) No special precautions.


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8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1. Control parameters Hazardous Ingredients OSHA PEL ACGIH TLV UK WEL AUSTRALIA ES ppm mg1m3 ppm mg1m3 ppm mg1m3 ppm mg1m3 Epoxy resin (number average

molecular weight


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Under normal Use: exposure. Acute Effects: Moderate eye and skin irritant. May cause skin sensitization as evidenced by rashes or hives.

Substance Test Result Epoxy resin LD50 oral, rat 5000 mg/kg Epoxy resin LC50 dermal, rabbit > 3000 mg/kg

Chronic Effects: Repeated inhalation of respirable free silica may cause scarring of the lungs with cough and shortness of breath. Silicosis, a delayed lung injury that is a disabling, progressive and sometimes fatal pulmonary fibrosis, may result. The International Agency for Research on Cancer (IARC) and the National Toxicology Program (NTP) have classified inhaled silica as a human carcinogen. Prolonged, excessive inhalation of Graphite in this product do not separate from the mixture or in of themselves become airborne, therefore, do not present a hazard in normal use.

Carcinogenicity: Based on recent 2-year mice skin painting studies and other available information, the International Agency for Research on Cancer (IARC) concluded that they did not have enough information to classify Epoxy resin (number average molecular weight


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14. TRANSPORT INFORMATION 14.1. UN number ADRIRIDIADNIIMDGIICAO: UN3082 TDG: UN3082 US DOT: UN3082 14.2. UN proper shipping name ADRIRIDIADNIIMDGIICAO: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN) TDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN) US DOT: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN) 14.3. Transport hazard class(es) ADRIRIDIADNIIMDGIICAO: 9 TDG: 9 US DOT: 9 14.4. Packing group ADRIRIDIADNIIMDGIICAO: III TDG: III US DOT: III 14.5. Environmental hazards MARINE POLLUTANT 14.6. Special precautions for user NO SPECIAL PRECAUTIONS FOR USER 14.7. Transport in bulk according to Annex II of MARPOL73178 and the IBC Code NOT APPLICABLE 14.8. Other information US DOT: ERG NO.171, May be shipped as Limited Quantities in packaging having a rated capacity gross weight of 66 lb. or less and in inner packages not over 5 Liters (49 CFR 173.155 (b,2) IMDG: EmS. F-A, S-F ADR: Classification code M6 Tunnel restriction code (E) 15. REGULATORY INFORMATION 15.1. Safety, health and environmental regulations legislation specific for the substance or mixture 15.1.1. EU regulations Authorizations under Title VII: Not applicable Restrictions under Title VIII: None Other EU regulations: Directive 94/33/EC on the protection of young people at work. Directive 92/85/EEC on the safety and health at work of pregnant workers and workers who have recently given birth or are breastfeeding. 15.1.2. National regulations

US EPA SARA TITLE III Hazardous Materials Identification System (HMIS) 312 Hazards : 313 Chemicals : Immediate none Delayed

4 = Severe Hazard 3 = Serious Hazard 2 = Moderate Hazard 1 = Slight Hazard 0 = Minimal Hazard * = See Section 8

HEALTH 1 FLAMMABILITY 1 REACTIVITY 1 Personal Protection *

JAPAN PRTR Class I Chemicals : Class II Chemicals :


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Bisphenol A type epoxy resin (liquid) none

Other national regulations: National implementations of the EC Directives referred to in section 15.1.1. 15.2. Chemical safety assessment No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier. 16. OTHER INFORMATION Abbreviations ACGIH: American Conference of Governmental Industrial Hygienists and acronyms: ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road CLP: Classification Labeling Packaging Regulation (1272/2008/EC) ES: Exposure Standard GHS: Globally Harmonized System ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods LC50: Lethal Concentration to 50 % of a test population LD50: Lethal Dose to 50% of a test population LOEL: Lowest Observed Effect Level N/A: Not Applicable NA: Not Available NOEL: No Observed Effect Level OSHA: Occupational Health & Safety Administration PBT: Persistent, Bio accumulative and Toxic substance PEL: Permissible Exposure Limit REACH: Registration, Evaluation, Authorization and Restriction of Chemicals Regulation (1907/2006/EC) RID: Regulations concerning the International Carriage of Dangerous Goods by Rail SDS: Safety Data Sheet STEL: Short Term Exposure Limit STOT: Specific Target Organ Toxicity TDG: Transportation of Dangerous Goods (Canada) TLV: Threshold Limit Value US DOT: United States Department of Transportation vPvB: very Persistent and very Bio accumulative substance WEL: Workplace Exposure Limit WHMIS: Workplace Hazardous Materials Information System Key literature references Commission de la sant et de la scurit du travail (CSST) and sources for data: European chemical Substances Information System (ESIS) European Chemicals Agency (ECHA) - Information on Chemicals Hazardous Substances Data Bank (HSDB) Hazardous Substances Information System (HSIS) Swedish Chemicals Agency (KEMI) Relevant H-statements: H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H411: Toxic to aquatic life with long lasting effects. Relevant R-phrases: R36/38: Irritating to eyes and skin. R43: May cause sensitization by skin contact. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Changes to the SDS in this revision: Sections 1-16, updated to new format. Further information: None This information is based solely on data provided by suppliers of the materials used, not on the mixture itself. No warranty is expressed or implied

Regarding the suitability of the product for the users particular purpose. The user must make their own determination as to suitability

1. Resin R3X5_material Safety Data Sheet_Part A

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