1 PRENFLO: PSG and PDQ · As a technology-driven engineering company, Uhde can act as integrated...
Transcript of 1 PRENFLO: PSG and PDQ · As a technology-driven engineering company, Uhde can act as integrated...
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PRENFLO: PSG and PDQ
Latest Developments based on
10 years Operating Experienceat Elcogas IGCC, Puertollano, Spain
Karsten Radtke, Max Heinritz-Adrian; Uhde, Germany
Max Hooper, Bill Richards; Uhde Corporation of America
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Uhde‘s Gasification Highlights – SUMMARY:
Invention of Entrained-Flow Gasification:
Koppers-Totzek: dry-fed, membrane wall, multiple burners (1941)
Development, Design and Construction of
first Koppers-Totzek Coal Gasification Plant
first Texaco Coal Gasification Plant
first HTW Coal Gasification Plant
first Shell-Koppers Coal Gasification Plant
first PRENFLO Coal Gasification Plant
Over 100 Gasifiers designed, built and put into successful operation by Uhde
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Uhde‘s proprietary Koppers-Totzek Gasification ProcessFirst Entrained-Flow Gasification Technology
Koppers-Totzek gasification plant Modderfontein, South Africa
1,000 t/d of ammonia
Koppers-Totzek gasification plant Ramagundam, India900 t/d of ammonia
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PRENFLOwith Steam Generation
PSG
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Pressurised Entrained Flow Demonstration plants
Shell-Koppers plant inHamburg / Germany
PRENFLO plant inFürstenhausen / Germany
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World‘s largest IGCC: Elcogas, Puertollano, Spain (300 MWe)based on petcoke / coal feedstock
PRENFLO Gasifier
Gas Treatment
Coal PreparationASU
Combined
CycleNew CO2 capture
Pilot Plant under
implementation
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PRENFLO gasifier and waste heat boiler (PSG)
• dry coal/petcoke powder feed
• 4 horizontal co-annular burners
• membrane wall
• waste heat boiler (PSG)
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PRENFLO Membrane Wall protected by the slag layer
BFW, 40-70 bar
Water Tube
(membrane wall)
Gasification Reactor
> 1500 °C
molten slag
flows downwards
solidified slag
molten slag
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PRENFLO Gasifier Membrane Wall
View of gasifier membrane wall after operation (PRENFLO burner)
View of gasifier membrane wall before 1st operation (PRENFLO burner)
Perfect slag layer protecting membrane wall
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PRENFLO Gasifier - erection of internals (Puertollano)
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Lifting of PRENFLO Gasifier / HP-Boiler (Puertollano)
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Puertollano IGCC: Operating Experience
General
Gasification is flexible with broad range of solid fuels
high-ash hard coal and petroleum coke
addition of biomass successully demonstrated
Flexible load change behaviour
Nearly constant gas heating value irrespective of fuel
No formation of higher hydrocarbons, methane < 0.1 vol. %
Non-leachable slag production
Fly ash sold to cement industry
Elcogas statistics show that the vast majority of down-times was caused by non-gasifier related issues
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Puertollano IGCC: Lessons LearnedMajor Problems and Solutions
System Problem SolutionOverall plant 100% ASU integration restricts plant
operation
start-up compressor required
(future plants)
Gas turbine burner & combustor overheating various modifications
Coal preparation Frequent problems at mixing unit
(plugging, ...)
Utilize mill as mixing device (future
plants)
Gasifier Membrane wall water leakages
(restriction orifices blocked by
magnetite)
Improve water chemistry (pH>9.5),
Design change at distributor
Slag Slow slag transfer from accumulator
to sluice vessel
Install sluice support pump (forced
slag flow towards sluice vessel)
Slag Erosion at vessel outlets Install replaceable erosion protection,
preventive maintenance
Waste heat boiler Excessive fouling Design for higher velocities (value is
known)
Fly ash Element fouling, short useful lifetime Change operation strategy (less
cleaning pulses)
Utilize Pall/Schumacher design
Overall plant Low level of preventive maintenance Integrate trained operators and
maintenance services
Source: Elcogas, 2008
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Source: Elcogas, 2008. Costs are real total average 2007.
Puertollano IGCC: Lessons LearnedOperating Data: IGCC is least cost power generation
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PRENFLOwith Direct Quench
PDQ
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The PRENFLO process with Direct Quench (PDQ)
Targets
Integrate Lessons Learned from 10 years operation of Puertollano IGCC
Optimize PRENFLO technology for chemical and hydrogen applications
Identify areas of significant Capital Cost Reduction
Water Quench instead of Gas Quench and Waste Heat Boiler
Keep commercially proven elements of PRENFLO technology
Design of a robust system
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The PRENFLO process with Direct Quench (PDQ)
Process characteristics
Pressurized entrained-flow gasification
Dry coal dust feeding
Multiple co-annular burners (horizontal, tangential arrangement)
Membrane Wall, no refractory
Operation pressure flexible to requirements
approx. 25 - 40 bar
Raw gas temperature outlet of quench
approx. 200 - 250 °C
Slag lock-hopper system
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PRENFLO Gasification
Direct Quench Pilot Tests Germany
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Slag
Feed,oxygen
Waste heat boilers
Raw gas(incl. fly ash)
Raw gas
Slag
Feed, oxygen
PRENFLO gasifierwith Direct Quench (PDQ)
PRENFLO gasifierwith Steam Generation (PSG)
Direct Quench
Feed,oxygen
Raw gas
Samegasifier design
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PDQ – Design Aspects
� Slag Drip Edge is Required
(Proven Design)
� Install Slag Drip Edge at Dry/Hot Location
("No Water Contact!")
� All Downstream SurfacesPermanently Wetted (Protective
Water Film)
� Defined Minimum Residence
Time to Ensure Proper Cooling
Quench water: ���� perfect distribution
Temperature zones: ���� optimal dry/hot vs. wet separation
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PRENFLO with Direct Quench
1000 MWth, 40 bar
PRENFLOTM
with
Direct Quench
PDQ
© Uhde 2008
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Raw Gas
S/G=1.3
PSG
GasifierGas
QuenchWaste H.
Boiler
FA
Filter
Scrubber
CO-
Shift
Saturator H2 Gas
Steam
Raw gas
S/G=1.3
PDQ
GasifierDirect
Quench
Scrubber CO-
Shift
H2 Gas
Steam
PSG:
PDQ:
PRENFLO PSG vs. PRENFLO PDQImpact on Cost: Process Configuration (e.g. H2 plant)
substituted by Direct Quench
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PRENFLO PSG vs. PRENFLO PDQImpact on Cost: Plant Layout
PRENFLO (PDQ)
PRENFLO (PSG)
EPC cost savings:
~30 %
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-4,0%
-3,5%
-3,0%
-2,5%
-2,0%
-1,5%
-1,0%
-0,5%
0,0%
0% 20% 40% 60% 80% 100%
shifted gas fraction
∆∆ ∆∆ o
f ele
ctr
ic e
ffic
iency [%
-poin
ts]
• CTC
• CTL
• IGCC-CCS
PRENFLO PSG vs. PRENFLO PDQImpact on Efficiency
IGCC H2
� In the targeted applications, PDQ is -1.0 to -1.8 %-pointslower than PSG
� this low impact does notjustify the higher capital costof a waste heat boiler design
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Summary
Lessons Learned from 10 years operation of the Puertollano plant and decades of experience in coal gasification and all related down-streamprocesses are fully integrated in PRENFLO.
As a technology-driven engineering company, Uhde can act as integratedLicensor, E, EP or EPCM contractor – PRENFLO is a commercial product
PRENFLO is available with conventional steam generation (PSG)or direct quench mode (PDQ) with significant cost savings
PDQ Gasification was launched in February 2008. By October 2008, PDQ has been selected around the world for approx. 15,000 MWth new plant capacity
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Thank you for your attention.
PRENFLO IGCC, Puertollano, Spain
Summer 2008 www.prenflo.com