1. IDENTIFICATION OF PRODUCT AND COMPANY

1.1 Product Identification

Product Name: Acetic Silicone Poliplás 1.2 Details of supplier

Company Identification: Poliplás Selantes e Adesivos Limitada. Rua Vitório Gasparo, 120 Mini Distrito Ind. Adail Vetorazzo São José do Rio Preto – SP CEP: 15046-768 Fone: +55 17 3354 5000 SAC: 0800 723 7237 1.3 Emergencies phones:

Phone:+55 17 3354 5000 SAC: 0800 723 7237

2. HAZARDS IDENTIFICATION 2.1 CLASSIFICATION SYSTEM UTILIZED

In conformity with ABNT NBR 14725-2 norm – Informations of safety, health and environment

2.2 HAZARD CLASSIFICATION

GHS Classifications Acute aquatic toxicity: Category 3

2.3 ELEMENTS OF LABELLING ACCORDING TO GHS

Hazard Pictogram: Signal Word: Warning Hazard Statements: H402 Harmful to aquatic life Precautionary Statements : Prevention:

P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment

Other hazards which do not result in classification None known.

3. INGREDIENTS COMPOSITION AND INFORMATION “This product is a mixture.” 3.1 Chemistry nature Substance / Mixture : Mixture

Chemical nature : Silicone elastomer: 3.2 Dangerous components Composed % CAS number

Distillates (petroleum), hydrotreated middle

>= 20 - < 30

64742-46-7

Titanium dioxide >= 0,1 - < 1 13463-67-7

4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One

< 0,1 64359-81-5

4. FIRST AID MEASURES If inhaled : If inhaled, remove to fresh

air. Get medical attention if symptoms occur.

In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur.

In case of eye contact : Flush eyes with water as a

precaution. Get medical attention if irritation develops and persists.

If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.

Most important symptoms and effects, both acute and delayed

: None known.

Protection of first-aiders : No special precautions are necessary for first aid responders.

Notes to physician : Treat symptomatically and supportively.

5. FIRE FIGHTING MEASURES Suitable extinguishing media : Water spray

Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical

Unsuitable extinguishing media

: None known.

Specific hazards during fire fighting

: Exposure to combustion products may be a hazard to health.

Hazardous combustion products : Carbon oxides

Silicon oxides Formaldehye

Specific extinguishing meth-ods : Use extinguishing measures that

are appropriate to local cir-cumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.

Special protective equipment for fire-fighters

: Wear self-contained breathing apparatus for firefighting if nec-essary.

Use personal protective equipment.

6. METHODS SPILLAGE OR LEAKAGE CONTROL Personal precautions, protec-tive equipment and emer-gency procedures

: Follow safe handling advice and personal protective equipment recommendations.

Environmental precautions : Discharge into the environment

must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up

: Soak up with inert absorbent material. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable.

Note: See Section 8 for Personal Protective Equipment (PPE) for spillage.

7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation : Use only with adequate

ventilation.

Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment.

Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-nº Value type (Form of

exposure) Control parameters/ Permissible concentration

Basis

Titanium dioxide 13463-67-7 TWA 10 mg/m² (Titanium dioxide)

ACGIH

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Paste

Color Clear, White, Grey, Black

Odor Acetic Acid

Odor Threshold No data available

PH Not aplicable

Melting point/freezing point No data available

Initial Boiling point Not Aplicable

Flash point >100ºC Method: closed up

Evaporation rate Not applicable

Flammability (solid, gas) Not classified as a flammability hazard

Upper explosion limit No data available

Lower explosion limit No data available

Vapor pressure Not applicable

Relative vapor density No data available

Relative density 0,98 g/l

Water solubility No data available

Partition coefficient: noctanol/water No data available

Autoignition temperature No data available

Decomposition temperature No data available

Viscosity, dynamic Not applicable

Explosive properties Not explosive

Oxidizing properties The substance or mixture is not classified as oxidizing.

Molecular weight No data available

10. STABILITY AND REACTIVITY Reactivity: Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions: Use at elevated temperatures may form highly hazardous

compounds. Can react with strong oxidizing agents. Hazardous decomposition products will be formed upon contact with water or humid air. Hazardous decomposition products will be formed at elevated temperatures.

Conditions to avoid: None known Incompatible materials: Oxidizing agents

Water Hazardous decomposition products Thermal decomposition: Formaldehyde

11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Skin contact

Ingestion Eye contact

11.1 Acute Toxicicity Unknown applicable information. Ingredients Distillates (petroleum), hydrotreated middle: Acute oral toxicity : LD50 (Rat): > 5.000 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 5.266 mg/m³

Exposure time: 4 h Test atmosphere: dust/mist

Acute dermal toxicity : LD50 (Rabbit): > 3.160 mg/kg Assessment: The substance or mixture has no acute dermal toxicity

Titanium dioxide: Acute oral toxicity : LD50 (Rat): > 5.000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 6,82 mg/l

Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity

4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Acute oral toxicity : LD50 (Rat): 1.636 mg/kg

Acute inhalation toxicity : LC50 (Rat): 0,26 mg/l

Exposure time: 4 h Test atmosphere: dust/mist

Acute dermal toxicity : Acute toxicity estimate: 1.100

mg/kg Method: Expert judgment

Skin corrosion/irritation Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated middle: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation

Titanium dioxide: Species: Rabbit Result: No skin irritation 4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Result: Corrosive after 1 to 4 hours of exposure

Serious eye damage/eye irritation

Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated middle: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405

Titanium dioxide: Species: Rabbit Result: No eye irritation 4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Result: Irreversible effects on the eye Remarks: Based on skin corrosivity. Respiratory or skin sensitization Skin sensitization Not classified based on available information. Respiratory sensitization Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated middle: Test Type: Maximization Test Routes of exposure: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials

Titanium dioxide: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative 4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Test Type: Maximization Test Routes of exposure: Skin contact Species: Guinea pig Result: positive Assessment: Probability or evidence of high skin sensitization rate in humans

Germ cell mutagenicity

Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated middle: Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Result: negative

Genotoxicity in vivo : Test Type: Mutagenicity (in vivo

mammalian bone-marrow cytogenetic test, chromosomal analysis)

Species: Rat Application Route: Intraperitoneal injection Result: negative

Titanium dioxide: Genotoxicity in vitro : Test Type: Bacterial reverse

mutation assay (AMES) Result: negative

Genotoxicity in vivo : Test Type: In vivo micronucleus

test Species: Mouse Result: negative

Carcinogenicity

Not classified based on available information. Ingredients: Titanium dioxide: Species: Rat Application Route: inhalation (dust/mist/fume) Exposure time: 24 Months Method: OECD Test Guideline 453 Result: positive Remarks: The mechanism or mode of action may not be relevant in humans. The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard. Carcinogenicity - Assess-ment : Limited evidence of

carcinogenicity in inhalation studies with animals.

Reproductive toxicity

Not classified based on available information Ingredients:

Distillates (petroleum), hydrotreated middle: Effects on fertility : Test Type: Combined repeated

dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Remarks: Based on data from similar materials

Effects on fetal development : Test Type: Embryo-fetal

development

Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative

4,5-Dichloro-2-N-Octyl-4 Isothiazolin-3-One: Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative

Effects on fetal development : Test Type: Embryo-fetal

development Species: Rat Application Route: Ingestion Result: negative

STOT-single exposure

Not classified based on available information. Ingredients: 4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Assessment: May cause respiratory irritation.

STOT-repeated exposure

Not classified based on available information. Ingredients: 4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Routes of exposure: Ingestion Assessment: No significant health effects observed in animals at concentrations of 100 mg/kg bw or less.

Repeated dose toxicity Ingredients: Distillates (petroleum), hydrotreated middle: Species: Rat NOAEL: >= 5.000 mg/kg Application Route: Ingestion Exposure time: 13 Weeks Remarks: Based on data from similar materials

Titanium dioxide: Species: Rat NOAEL: 24.000 mg/kg Application Route: Ingestion Exposure time: 28 Days Species: Rat NOAEL: 10 mg/m³

Application Route: inhalation (dust/mist/fume) Exposure time: 2 y Remarks: The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard. 4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Species: Rat NOAEL: 20 mg/kg LOAEL: 100 mg/kg Application Route: Ingestion Exposure time: 28 Days Aspiration toxicity Not classified based on available information. Ingredients: Distillates (petroleum), hydrotreated middle: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re-garded as if it causes a human aspiration toxicity hazard.

12. ECOLOGICAL INFORMATION 12.1 Ecotoxicity Ingredients: Distillates (petroleum), hydrotreated middle: Toxicity to fish : LL50 (Scophthalmus

maximus (turbot)): > 1.028 mg/l Exposure time: 96 h

Test substance: Water Accommodated Fraction

Toxicity to daphnia and other aquatic invertebrates

: LL50 (Acartia tonsa): > 3.193 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction

Toxicity to algae : EL50 (Skeletonema

costatum (marine diatom)): > 10.000 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction

Toxicity to daphnia and other aquatic invertebrates (Chron-ic toxicity)

: NOELR (Ceriodaphnia dubia (water flea)): > 100 mg/l Exposure time: 8 d Test substance: Water Accommodated Fraction

Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 3 h Method: OECD Test Guideline 209

Titanium dioxide: Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h

Toxicity to algae : EC50 (Skeletonema

costatum (marine diatom)): > 10.000 mg/l Exposure time: 72 h

4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Toxicity to fish : LC50 (Oncorhynchus

mykiss (rainbow trout)): 0,0027 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 0,0052 mg/l Exposure time: 48 h

Toxicity to algae : ErC50 (Pseudokirchneriella

subcapitata (green algae)): 0,077 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

Toxicity to fish (Chronic tox-icity)

: NOEC (Oncorhynchus mykiss (rainbow trout)): 0,00056 mg/l Exposure time: 97 d

Toxicity to bacteria : EC50: > 1.000 mg/l Exposure time: 3 h Method: OECD Test Guideline 209

M-Factor (Acute aquatic tox-icity)

: 100

Toxicity to daphnia and other: NOEC (Daphnia magna (Water flea)): 0,00063 mg/l Aquatic invertebrates (Chronic Tocicity) Exposure Time: 21 d M-Factor (Chronic aquatic toxicity)

: 10

Toxicity to bacteria : EC50: > 5,7 mg/l

Exposure time: 3 h

Persistence and degradability Ingredients:

Distillates (petroleum), hydrotreated middle: Biodegradability : Result: Readily biodegradable.

Biodegradation:74% Exposure time: 28 d Method: OECD Test Guideline 306

4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Biodegradability : Result: rapidly degradable

Bioaccumulative potential Ingredients: 4,5-Dichloro-2-N-Octyl-4-Isothiazolin-3-One: Bioaccumulation : Species: Lepomis macrochirus

(Bluegill sunfish) Bioconcentration factor (BCF): 750

Partition coefficient: n-octanol/water

: log Pow: 2,8

Mobility in soil No data available Other adverse effects

No data available

13. TREATMENT AND DISPOSAL CONSIDERATIONS Product: Co processing, thermal or industrial landfill decomposition, according to local regulations. Product residues: should be disposed of as local regulations, following the criterion of the same product. Used packaging: Do not reuse packages and dispose of according to current local regulations.

14. TRANSPORT INFORMATION 14.1 Brazilian roads (according to the rules of IMDG) The product is not considered as hazardous for transport. International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation ANTT 420 Not regulated as a dangerous good

15. REGULATION User attention this product may contain local regulations. Safety, health and environmental regulations/legislation specific for the substance or mixture National List of Carcinogenic Agents for Humans - (LINACH): Not applicable Brazil. Ordinance No. 1274 on the control and monitoring of chemicals.: n-Hexane Methano

The ingredients of this product are reported in the following inventories: TSCA : All chemical substances in this material are included on or

exempted from listing on the TSCA Inventory of Chemical Substances.

AICS: All ingredients listed or exempt. DSL: All chemical substances in this product comply with the CEPA

1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).

16. FINAL INFORMATION Note: This information is offered in good faith and not as a product specification. No express or implied warranties are hereby made. Security procedures and hygiene are recommended in general character, however, each user should review these recommendations for each specific case and determine whether they are appropriate. Please consult MSDS updates before use.

Filled By: Poliplás Selantes e Adesivos Limitada. www.poIipIas.com.br