1. 2 Introducing carbohydrates Carbohydrates are a group of substances used as both energy sources...
-
Upload
horatio-blair -
Category
Documents
-
view
220 -
download
2
Transcript of 1. 2 Introducing carbohydrates Carbohydrates are a group of substances used as both energy sources...
1
2
Introducing carbohydratesCarbohydrates are a group of substances used as both energy sources and structural materials in organisms.
All carbohydrates contain carbon, hydrogen and oxygen, with the general formula: Cx(H2O)y.
There are three main groups of carbohydrates:
monosaccharides – these are simple sugars, with the general formula (CH20)n, where n can be 3–7
disaccharides – these are ‘double sugars’, formed from two monosaccharides
polysaccharides – these are large molecules formed from many monosaccharides.
Glucose
The structure of glucose can be represented in different ways:
Glucose is an abundant and very important monosaccharide. It contains six carbon atoms so it is a hexose sugar. Its general formula is C6H12O6.
Glucose is the major energy source for most cells. It is highly soluble and is the main form in which carbohydrates are transported around the body of animals.
straight chain ring ring (simplified)
Remembering how to draw α-glucose
Remember:
LOHexagonWings
Alpha and beta glucoseGlucose exists in different forms called structural isomers. Two common isomers are alpha glucose and beta glucose.
alphaglucose
betaglucose
The only difference between these two isomers is the position of the H and -OH group attached to carbon 1. In α-glucose, H is above the carbon and in β-glucose it is below the carbon.
1
23
4
5
6
1
23
4
5
6
This minor structural difference has a major effect on the biological roles of α and β glucose.
Two forms of glucose
Fructose and galactose
Galactose is not as soluble as glucose and has an important role in the production of glycolipids and glycoproteins.
Two other important hexose monosaccharides are fructose and galactose.
fructose galactose
Fructose is very soluble and is the main sugar in fruits and nectar. It is sweeter than glucose.
The formation of disaccharides
Maltose, sucrose and lactoseMaltose (malt sugar) is formed from two glucose molecules joined by an alpha 1–4 glycosidic bond.
Sucrose (table sugar) is formed from glucose and fructose joined by an alpha 1–4 glycosidic bond.
Lactose (milk sugar) is formed from galactose and glucose joined by a beta 1–4 glycosidic bond.
Condensation and hydrolysis
14 of 30 © Boardworks Ltd 2008
What are polysaccharides?
Polysaccharides are polymers containing many monosaccharides linked by glycosidic bonds. Like disaccharides, polysaccharides are formed by condensation reactions.
The major polysaccharides are starch and cellulose in plants, and glycogen in animals.
Polysaccharides are mainly used as an energy store and as structural components of cells.
Starch
Found in many parts of the plant as small grains.Large amounts in seeds and storage organsMajor energy source in most diets
Alpha glucose + alpha glucose + alpha glucose + alpha glucose + alpha glucose + alpha glucose + alpha glucose ............................. etc. = starch
1000s of glucose molecules bonded together by glycosidic bonds in condensation reactions makes starch
Starch: Amylose and Amylopectin
16
The glucose molecules are joined by 1,4 glycosidic bonds.
Amylose is alpha glucose, forming straight chains.
The chains fold naturally into a helical shape.
Starch: Amylose and Amylopectin
17
The branches are made with 1,6 glycosidic bonds.
Amylopectin is also alpha glucose, forming branched chains.
Starch: Amylose and Amylopectin
18
Starch is a mixture of amylose and amylopectin; it's insoluble and is used as a storage molecule for plants.
Starch: Amylopectin
19
Starch is a mixture of amylose and amylopectin; it's insoluble and is used as a storage molecule for plants.
The structure of starch
StarchMain role of starch is energy storage, something
it’s especially suited for because:
It is insolubleIt is compactWhen hydrolysed it forms α-glucoseStored as granules
What are the advantages of these properties?
Subunit structure of glycogen
VERY similar to amylopectin – but shorter and more highly branched
GlycogenStarch is never found in animal cells; instead you find glycogen
(energy storage)Similar to amylopectin in starch, except shorter chain and it’s
more highly branched• Stored as small granules mainly in the muscles and liver. • Consists of 1-4 glycosidic linked chains of alpha glucose
which are shorter and more branching• Not soluble in water• Readily hydrolysed
What are the advantages of these properties?
β-glucose polymers
β-glucose molecules bond together through condensation reaction to form long chain
Unlike α-glucose, forms long straight chains due to orientation of glycosidic bonds
Straight chains contain up to 10 000 β-glucose molecules
Cellulose chains found only in plants
Orientation of β-glucose and chain formation
Made of β-glucose rather than α-glucose like in starch and glycogen.
‘flip-flop’ arrangement of glucose
CelluloseForms straight unbranched chains rather than a
coiled chain like starch or a branched chain like glycogen.
Chains run parallel to each other allowing hydrogen bonds to form cross-links between adjacent chains (microfibrils)
Provides strength to cellulose cell walls Individual bonds are weak but large numbers
adds to considerable strength.
Cellulose chains, microfibrils and macrofibril (fibre)
Task
Construct a table to compare starch, glycogen and cellulose. Think about their structures, properties and functions.
41
42
43
44
46
47
48
49
Starch, glycogen and cellulose
Aims:How are α-glucose monomers arranged to form the polymers of starch and glycogen?How are β-glucose monomer arranged to form the polymer cellulose?How do the molecular structures of starch, glycogen and cellulose relate to their functions?
Plenary: Compare and contrast starch, glycogen and cellulose