009 jgc2016 energy transmission & storage_Schmitz
-
Upload
senicsummerschool -
Category
Education
-
view
144 -
download
0
Transcript of 009 jgc2016 energy transmission & storage_Schmitz
12016 JGCSE Shanghai 1
2016 International Joint Graduate Course on
Energy Transmission amp StorageJuly 18th ndash July 28th 2016
Shanghai Jiao Tong University China (Host)Norwegian University of Science and Technology (Co-host) University of Maryland College Park USAKorea University South KoreaTsinghua UniversityHamburg University of Technology Germany
22016 JGCSE Shanghai
Energy systems
32016 JGCSE Shanghai
Kind of Energy Definition Example
Non‐renewable primary energy
Energies set free by irreversible change of limited matter on earth
coal oil gas uranium
Renewableenergies
Time integrated energy flows from the inner earth and from celestial bodies
Direct renewable energies Solar Tidal energy (kinetic energy of the moon) Geothermal energyIndirect renewable energies Wind Biomass
Sekunary energy Energy or energy carrier turned from primary energy to secondary energy to transport energy over long distances or to store energy
Electricity Hydrogen Synthetic Methan
End Energy Energy or energy carrier for local energy use to be turned into useful energy
District heat gas Oil Coal Electricity
Useful Energy Energy used to cover anthropoid demands Heat Work
42016 JGCSE Shanghai 4
Energy Conversion Ways
UraniumCoalOilGas
Non RenewableEnergies
Renewable Energies like Wind Solar Geothermal etc
LH
CO
LHHH
LH
HH
CO
LH
CO
LH
LH
CO
KIPO
KIPO
KI KineticEnergy
PO PotentialEnergy
LH LowTemp Heat
CO Cooling
HH High Temp Heat
ThermalStorage
CHP
ElectrStorage Electr
Motor
ResistantHeating
Heattransfo
Power
HeatpumpRefriger
AbsorbChill
Power
Heatpump
Refrigera
Boiler
Heatpump
AbsorbChill
Motor
Combust
PowerPlant
Primary Energy Useful EnergyTransport Conversion
Conversion
Gas Oil
Heat
Electricity
Endenergy
52016 JGCSE Shanghai 5
DC Electricity Lines (planned)
VDE
Wilster
Lehrte
Fulda
Grafenrheinfeld
Kassel
Hannover
Hamburg
62016 JGCSE Shanghai 6
European Gas Grid
72016 JGCSE Shanghai 7
P Q
250 423
P Q
321 814
P Q
2 350
P Q
20 100
299 943
KW Moorburg
P Q
1654 ‐
Hamburg Far District Heating Grid (Vattenfall)
82016 JGCSE Shanghai
Energy supply should be
economical
ecological
Reliable
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
22016 JGCSE Shanghai
Energy systems
32016 JGCSE Shanghai
Kind of Energy Definition Example
Non‐renewable primary energy
Energies set free by irreversible change of limited matter on earth
coal oil gas uranium
Renewableenergies
Time integrated energy flows from the inner earth and from celestial bodies
Direct renewable energies Solar Tidal energy (kinetic energy of the moon) Geothermal energyIndirect renewable energies Wind Biomass
Sekunary energy Energy or energy carrier turned from primary energy to secondary energy to transport energy over long distances or to store energy
Electricity Hydrogen Synthetic Methan
End Energy Energy or energy carrier for local energy use to be turned into useful energy
District heat gas Oil Coal Electricity
Useful Energy Energy used to cover anthropoid demands Heat Work
42016 JGCSE Shanghai 4
Energy Conversion Ways
UraniumCoalOilGas
Non RenewableEnergies
Renewable Energies like Wind Solar Geothermal etc
LH
CO
LHHH
LH
HH
CO
LH
CO
LH
LH
CO
KIPO
KIPO
KI KineticEnergy
PO PotentialEnergy
LH LowTemp Heat
CO Cooling
HH High Temp Heat
ThermalStorage
CHP
ElectrStorage Electr
Motor
ResistantHeating
Heattransfo
Power
HeatpumpRefriger
AbsorbChill
Power
Heatpump
Refrigera
Boiler
Heatpump
AbsorbChill
Motor
Combust
PowerPlant
Primary Energy Useful EnergyTransport Conversion
Conversion
Gas Oil
Heat
Electricity
Endenergy
52016 JGCSE Shanghai 5
DC Electricity Lines (planned)
VDE
Wilster
Lehrte
Fulda
Grafenrheinfeld
Kassel
Hannover
Hamburg
62016 JGCSE Shanghai 6
European Gas Grid
72016 JGCSE Shanghai 7
P Q
250 423
P Q
321 814
P Q
2 350
P Q
20 100
299 943
KW Moorburg
P Q
1654 ‐
Hamburg Far District Heating Grid (Vattenfall)
82016 JGCSE Shanghai
Energy supply should be
economical
ecological
Reliable
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
32016 JGCSE Shanghai
Kind of Energy Definition Example
Non‐renewable primary energy
Energies set free by irreversible change of limited matter on earth
coal oil gas uranium
Renewableenergies
Time integrated energy flows from the inner earth and from celestial bodies
Direct renewable energies Solar Tidal energy (kinetic energy of the moon) Geothermal energyIndirect renewable energies Wind Biomass
Sekunary energy Energy or energy carrier turned from primary energy to secondary energy to transport energy over long distances or to store energy
Electricity Hydrogen Synthetic Methan
End Energy Energy or energy carrier for local energy use to be turned into useful energy
District heat gas Oil Coal Electricity
Useful Energy Energy used to cover anthropoid demands Heat Work
42016 JGCSE Shanghai 4
Energy Conversion Ways
UraniumCoalOilGas
Non RenewableEnergies
Renewable Energies like Wind Solar Geothermal etc
LH
CO
LHHH
LH
HH
CO
LH
CO
LH
LH
CO
KIPO
KIPO
KI KineticEnergy
PO PotentialEnergy
LH LowTemp Heat
CO Cooling
HH High Temp Heat
ThermalStorage
CHP
ElectrStorage Electr
Motor
ResistantHeating
Heattransfo
Power
HeatpumpRefriger
AbsorbChill
Power
Heatpump
Refrigera
Boiler
Heatpump
AbsorbChill
Motor
Combust
PowerPlant
Primary Energy Useful EnergyTransport Conversion
Conversion
Gas Oil
Heat
Electricity
Endenergy
52016 JGCSE Shanghai 5
DC Electricity Lines (planned)
VDE
Wilster
Lehrte
Fulda
Grafenrheinfeld
Kassel
Hannover
Hamburg
62016 JGCSE Shanghai 6
European Gas Grid
72016 JGCSE Shanghai 7
P Q
250 423
P Q
321 814
P Q
2 350
P Q
20 100
299 943
KW Moorburg
P Q
1654 ‐
Hamburg Far District Heating Grid (Vattenfall)
82016 JGCSE Shanghai
Energy supply should be
economical
ecological
Reliable
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
42016 JGCSE Shanghai 4
Energy Conversion Ways
UraniumCoalOilGas
Non RenewableEnergies
Renewable Energies like Wind Solar Geothermal etc
LH
CO
LHHH
LH
HH
CO
LH
CO
LH
LH
CO
KIPO
KIPO
KI KineticEnergy
PO PotentialEnergy
LH LowTemp Heat
CO Cooling
HH High Temp Heat
ThermalStorage
CHP
ElectrStorage Electr
Motor
ResistantHeating
Heattransfo
Power
HeatpumpRefriger
AbsorbChill
Power
Heatpump
Refrigera
Boiler
Heatpump
AbsorbChill
Motor
Combust
PowerPlant
Primary Energy Useful EnergyTransport Conversion
Conversion
Gas Oil
Heat
Electricity
Endenergy
52016 JGCSE Shanghai 5
DC Electricity Lines (planned)
VDE
Wilster
Lehrte
Fulda
Grafenrheinfeld
Kassel
Hannover
Hamburg
62016 JGCSE Shanghai 6
European Gas Grid
72016 JGCSE Shanghai 7
P Q
250 423
P Q
321 814
P Q
2 350
P Q
20 100
299 943
KW Moorburg
P Q
1654 ‐
Hamburg Far District Heating Grid (Vattenfall)
82016 JGCSE Shanghai
Energy supply should be
economical
ecological
Reliable
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
52016 JGCSE Shanghai 5
DC Electricity Lines (planned)
VDE
Wilster
Lehrte
Fulda
Grafenrheinfeld
Kassel
Hannover
Hamburg
62016 JGCSE Shanghai 6
European Gas Grid
72016 JGCSE Shanghai 7
P Q
250 423
P Q
321 814
P Q
2 350
P Q
20 100
299 943
KW Moorburg
P Q
1654 ‐
Hamburg Far District Heating Grid (Vattenfall)
82016 JGCSE Shanghai
Energy supply should be
economical
ecological
Reliable
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
62016 JGCSE Shanghai 6
European Gas Grid
72016 JGCSE Shanghai 7
P Q
250 423
P Q
321 814
P Q
2 350
P Q
20 100
299 943
KW Moorburg
P Q
1654 ‐
Hamburg Far District Heating Grid (Vattenfall)
82016 JGCSE Shanghai
Energy supply should be
economical
ecological
Reliable
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
72016 JGCSE Shanghai 7
P Q
250 423
P Q
321 814
P Q
2 350
P Q
20 100
299 943
KW Moorburg
P Q
1654 ‐
Hamburg Far District Heating Grid (Vattenfall)
82016 JGCSE Shanghai
Energy supply should be
economical
ecological
Reliable
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
82016 JGCSE Shanghai
Energy supply should be
economical
ecological
Reliable
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
92016 JGCSE Shanghai
Energiewende
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
102016 JGCSE Shanghai
Estimated and real wind power high voltage grid Vattenfall Germany 2008
Fluctuating Power
Source Speicher fuumlr Stromnetze mit hohem Anteil erneuerbarer Energie etz (2)2ndash3 2009
Power demand Real wind power
Estimated wind power
Hydro power storages in Germany 7000 MW 40000 MWh
Pow
er
date
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
112016 JGCSE Shanghai 11
Elec
trici
ty P
rodu
ctio
nsin
rega
rdto
m
axim
al p
ower
per
day
in G
erm
any
Wind EnergySolar Energy
month month
1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
Fluctuation of Solar and Wind Energy in Germany
Diplomarbeit Joumlrg Luumltge
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
122016 JGCSE Shanghai
0
20
40
60
80
100
120
930 940 950 1000 1010 1020 1030 1040 1050 1100 1110 1120 1130
Pri
maumlrl
eis
tung in
MW
Gesa
mte
nerg
ieve
rbra
uch
in M
Wh
Primaumlrleistung amp Energiebedarf Schmelzbetrieb 1-Korb amp 3-Korb Charge
Ofenleistung Energie EnergyZeit
Power
0
50
100 PPmax
Power Demand of an Electric Steel Melting FurnaceSource ArcelorMittal Hamburg GmbH
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
132016 JGCSE Shanghai
supply resources
demand
Time in h
Loadin GW
Energy Management Today
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
142016 JGCSE Shanghai
Time in h
Loadin GW
demand
supply resources
Energy Management Tomorrow
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
152016 JGCSE Shanghai
Correspond to an optimized demand supply sufficientenergy with the needed energy quality at the right time tothe right place ndash with as low as possible quantitative andqualitative energy losses
supply AND demand side management (integration)
Requirements Energiewende
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
162016 JGCSE Shanghai
More fluctuating energies means
less predictability of energy sourcesless reliability of electricity systems
and needs
more intelligent energy managementmore back up systemsmore short term and long term storages
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
172016 JGCSE Shanghai 17
Energy storages
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
182016 JGCSE Shanghai 18
dtdE
dtdE
dtdUWQ potkin
t 1212
Energy storages
Energy could be storage only as
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
192016 JGCSE Shanghai 19
Energy storages
Energy could be storage only as
Potential Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
202016 JGCSE Shanghai 20
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy
dtdE
dtdE
dtdUWQ potkin
t 1212
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
212016 JGCSE Shanghai 21
Energy storages
Energy could be storage only as
Potential EnergyKinetic Energy or asInner Energy
There are no ldquoHeat Storagesrdquo or ldquoElectrical Storagesrdquo
dtdE
dtdE
dtdUWQ potkin
t 1212
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
222016 JGCSE Shanghai
Inner Energy Storages Potential Energy Storages
Warm Water
Gas
Fly WheelsSource BeaconPower
Energy storages
District heating
hydropowerSourceVattenfall
Compressed airSource RWE
Hydro-gen
H H
Source httpdeacademicru
Electricity line
Batteries
Kinetic Energy Storages
Heat Pump Thermal Storage
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
232016 JGCSE Shanghai
Storages for electrical work
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
242016 JGCSE Shanghai
Principle of an Electrical Energy Storage System
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
252016 JGCSE Shanghai
Quelle RWE
Quelle Beacon Power
Energy storages for Electrical Work
QuelleVattenfall
H H
Quelle httpdeacademicru
VRFB Vanadium‐Red‐Ox‐Flow‐BatteryNaS Natrium‐Sulfur‐BatteryLA Lead‐Acid‐Battery (Blei‐Saumlure‐Batterie)FESS Fly Wheel Energy System
HP High PerformanceHTS Magnetic bearings Vacuum
HSS‐SOFC Hydrogen Storage System ndash Solid Oxid Fuel CellHSS‐PEMFC H2 ‐ PEM ndash Fuel CellHSS‐GT H2 ‐ GasturbineHSS‐CCGT H2 ndash Combined Cycle Gas Turbine
ACES Adiabatic Compressed Air Energy StorageDCAS Diabatic Compressed Air Energy StoragePHES Pumped Hydro ‐ Storages Energy Systems
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
262016 JGCSE Shanghai 26
Criteria for assessment of storages
Discharging timeScalingExergy densityDynamicsSelf discharge durabilityLifetimeEnvironment
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
272016 JGCSE Shanghai
Efficiency of Energy Storages
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
282016 JGCSE Shanghai
bdquoDurabilityldquo of Energy in Storages
h
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
292016 JGCSE Shanghai
Exergy density of Storages
h
kWhmsup3
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
302016 JGCSE Shanghai
Efficiency Scaling Dynamics Self‐discharge
Lifetime Environ‐ment
PHES + ‐ 0 + + + + ‐
DCAES 0 0 ‐ + + + + ‐
ACAES 0 0 ‐ 0 + + +
HSS ndash CCGT ‐ + 0 + + + 0
HSS ndash PEMFC ‐ ‐ + + + + 0 0
VRFB + 0 + + + + 0 ‐
NaS 0 0 + + ‐ ‐ ‐
LA + 0 + + + ‐ ‐ ‐
FESS ndash HP ++ ‐ ‐ + ‐ ‐ + + +
FESS ndash HTS ++ 0 ++ ‐ + ++
ThermExStor 0 0 ‐ 0 ++ + +
Strengths and Weaknesses of ESS
Assessment of Energy Storages
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
312016 JGCSE Shanghai 31
Batteries
Batteries
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
322016 JGCSE Shanghai
Fly wheels
bull CFKbull 100 kW25 kWh (41) 16000 1min 85 4 hbull Frequency control 4 projectsbull 1150 eurokW 4615 eurokWh
bull Beacon Power
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
332016 JGCSE Shanghai
0001020304050607080910
0 2 4 6 8 10 12 14 16
η cycle d
ay
average capacity utilisation for 24 h in MWh
FES
NaS
Efficiency of FES amp NaS
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
342016 JGCSE Shanghai
bull High perfomance steelbull 10hellip500 kW50 kWh (101) 6000 1min 85 1 hbull Frequency control integration of renewable energy 2 projectsbull 770 eurokW 3077 eurokWh
bull Temporal Power
Alternative suppliers (1)
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
352016 JGCSE Shanghai
bull Composite steel CFKbull 2 MW1 MWh (21) 6000 1min 90 25 hbull Frequency control integration of renewable energy
2 projectsbull 450 eurokW 900 eurokWh
bull Rotokinetik
Alternative suppliers (2)
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
362016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
372016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Peek demand supply
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
382016 JGCSE Shanghai
0
200
400
600
800
1000
1200
1400
1600
0
200
400
600
800
1000
1200
1400
1600
0 2 4 6 8 10 12 14 16 18 20 22
Energy in kW
h
power kW
daytime (h)
power‐orig power ‐ comb useful energy FES ‐ comb
Gradient smoothing amp peek demand supply
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
392016 JGCSE Shanghai
Future Energy System
Windpower Flywheelstorage
Biogas-CHP
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
402016 JGCSE Shanghai 40
ADELE ndash High Pressure Air Storage
Source RWE
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
412016 JGCSE Shanghai 41
lower basin pumpturbine
higherbasin
water
Hydro Power Storage
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
422016 JGCSE Shanghai 42
Coal mine
Water storage
Daylight mine Refuse dump
Turbine PumpReservoirSource bdquoDie Zeitldquo
Reuse of Old Coal Mines
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
432016 JGCSE Shanghai 43
Thermal Potential Storages
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
442016 JGCSE Shanghai
Gas storages
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
452016 JGCSE Shanghai
Gas is a storage
Gas infrastructure with high storage capacity availableGas means not only natural gas but also hydrogen biogas synthetic methanSynergies between sectors through coupling of electricity and gas grids more RE in heat as well as industry and mobility sectors can be achieved
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
462016 JGCSE Shanghai
M E exI
E exII
H2
H2O
EexVI
EexS
EexV
Eexchem= H2O
EexVII
O2
e -e -
H2
OxygenWater
Hydrogen Hydrogen
Hydrogenstorage
OxygenAirWater
Salt cavern
Hydrogen Elextrolysis
W elI W el
II
Gasturbine orFuel Cell
Hydrogen
O2
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
472016 JGCSE Shanghai 47
Use of Hydrogen
Conversion (back) into electricity by gas turbinesConversion into electricity by fuel cellsAdditive to natural gas Synthetic Natural Gas (SNG)Use for mobile applications like cars and airplanesUse as a chemical raw product
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
482016 JGCSE Shanghai 48
Efficiency of Fuel Cells and Gas Turbines
H2O2-fuel celltheoretical efficiency
Carnot efficiency
Source ASUETemperature [K]
Effic
ienc
y
Gas turbinetheoretical efficiency
but pure hydrogen combustion not yetpossible
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
492016 JGCSE Shanghai 49
Network of Hydrogen Fueling Stations in GermanyCompany Town Place pressure
OMV Stuttgart Flughafenstr 70 700bar350bar
EnBW Stuttgart Talstr117 700bar
AGIP Frankfurt Industriepark Houmlchst 700bar350bar
Total Berlin Heerstr324 700bar350bar
Total Berlin Holzmarktr36-42 700bar350bar
Shell Berlin Sachsendamm 90-92 700bar350bar
Total Berlin Heidestr19 700barHamburger Hochbahn Hamburg-Hummelsbuumlttel Lademannbogen 2 350bar
Total Hamburg Cuxhavenerstr 380 700barVattenfall Hamburg Hafencity 700bar
350barShell Hamburg Bramfelder Chausee 370 700barEnBW Karlsruhe Durlacher Allee 87 700barLinde Unterschleiszligheim Carl-von-Linde Str 350bar
Fraunhofer Institut Freiburg Heidenhofstr2 350bar
700barAir Liquide Duumlsseldorf Houmlherweg 350bar
700bar
B-Klasse F-CELL Daimler
Source wwwdaimlercom
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
502016 JGCSE Shanghai 50
Hydrogen injection into a natural gas grid
Questions
How much hydrogen can be fed into the gridHow much excess renewable energy can be usedHow big is the influence on CO2‐emissions
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
512016 JGCSE Shanghai 51
Properties of HydrogenH2 CH4 C3H8
Ignition temperature degC 585 540 487Min ignition energy mJ 002 029 026Stoichiometric air requirement msup3msup3 061 96 012Density Kgmsup3 009 072 201Ignition limits in air Vol‐ 4‐75 53‐15 21‐95Rate of combustion cms 265 40 47Flame temperature degC 2045 1875 2112Wobbe Index kWhmsup3 1343 1485 2255
Adjustment of air ratio necessary CO - emissions criticalProblems with modern flame control methods (SCOT)Gas motors change of Methan number engine knocking Higher ignition ratio safety issuesHigher flame temperatures without -adaption higher NOx-emissionsLower thermal output Wobbe-Index control locallyHigher water content in flue gases
For gas appliances this means in the case of Hydrogen feeding in a gas grid
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
522016 JGCSE Shanghai
12
c1p1A1
c2p2A2
Gas nozzle
OBB HVQ
Gas
tenvironmennozzlebefore ppc
)(2
2
Gas
tenvironmennozzlebeforeB
ppAcAV
)(2222
OGas
tenvironmennozzlebeforeB H
ppAQ
)(22
Luft
Gasd
dHpp
AQ O
Luft
tenvironmennozzlebeforeB
)(22
dHW O
O
Heat flux
Wobbe Index
Relative density
Gas velocity
Volume flow
Wobbe Index
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
532016 JGCSE Shanghai
Upp
erhe
atin
gva
lue
Ho
kWh
msup3
Upp
erhe
atin
gva
lue
Ho
MJ
msup3
Relative density dn
DVGW G260
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
542016 JGCSE Shanghai
Hydrogen Injection
H2
consumer
0001
0002
00030005
0006
0007
0008
0004
0005
0006 0007
0008
00090010
0011
0012
0013
00140015
00160017
0018
0017
up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260up to 10 Vol- Hydrogen feeding into a local gas gridseems to be possible according DVGW G260
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
552016 JGCSE Shanghai 55
3 H2 + CO CH4 + H2O HR0 = -2064 KJmol
4 H2 + CO2 CH4 + 2 H2O HR0 = -2649 KJmol
Shift-Reaktion
H2O + CO H2 + CO2 HR0 = - 415 KJmol
Synthetic (or Substitute) Natural Gas (CH4) with CO2 fromBiogas plants or Carbon Capture Power Plants
But G (Gibbs Energy) = H ndash T S
Synthetic Methan
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
562016 JGCSE Shanghai 56
Elektrolysis Cavern Fuel cell
Exergy Analysis of Hydrogen Conversion Pathes
Elektrolysis Cavern
Electricity output
Low temperatureheat
Chemical product
Chemical plant
AnergyExergy
Path electricity ndash Hydrogen - electricity
Path electricity - Hydrogen - chemical product
examplesbull Ammonia synthesisbull Plastic productionbull Dissolverbull Hydrocrackingbull Steel production
Ex 70 90 Ex 60
Electricityinput
Electricityinput
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
572016 JGCSE Shanghai
Hydrogen as a chemical product in Hamburg
(catalytic gas reformer)
35000 ta
385 ta
25000 ta
153 ta
External from Dow
90 ta297 ta
Demand 2013 60925 ta
Potential wind - H2 2023 16205 ta
(catalytic gas reformer)
External from DowExternal from Dow
External from Dow
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
582016 JGCSE Shanghai 58
Biogas
1 Biogas usage for electricityand heat production directlyat the biogas production
2Biogas conditioning and feed into the natural gas grid
3Biogas transport by specialbiogas pipelines to centerwith high heat demand
CHP CHPConditioning
- drying- desulfurization- compression- cleaning- CO2-removal
Feed into natural gas grid
CHP
Electr HeatElectr Heat
Heat Fuel
Electr Heat
Biogas optionsFermenter
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
592016 JGCSE Shanghai 59
Liquid Organic Hydrogen Carrier (LOHC)
9 H2
HydrationChemical connection of H2 to a liquid carriercatalytic reaction 50 barExotherm 10 kWhthkg H2 150degCcontinuisly process
DehydrationRelease of H2 by catalytic reactionEndotherm 10 kWhthkg H2 300degCGas cleaning necessarycontinuisly process
Data630 Nmsup3 H2 per msup3 LOHCDibenzyltoluolWorking space -39degC ndash 390degCNon toxid non explosiveNo evaporation of H2Easy transport
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
602016 JGCSE Shanghai
Heat storages
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
612016 JGCSE Shanghai 61
Thermal storage
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
622016 JGCSE Shanghai
Thermal Storage
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
632016 JGCSE Shanghai 63
Combined heat and power
Quelle Lichtblick
CFCL high temperature fuel cell15 kWel 05 kWtherm
Volkswagen co-gen motor190 kWel 360 kWtherm
Vaillant-Ecopower47 kWel 125 kWtherm
But Demand for electricity and heat has to be at the same time Difficult (summer)Buffer water storage necessary
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
642016 JGCSE Shanghai 64
gt32 kW Heat~19 kW Electr
Virtual power plant
on off load
Run
ning
time
sche
dul
e
Time schedule 3 4 5 6 7 8 9 10
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
652016 JGCSE Shanghai
CHP Plant operation optimisationEl Production Min required power price
pow
erpo
wer
prof
itpr
ofit
sche
duel
sche
duel
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
662016 JGCSE Shanghai 66
bull Limestone (chalk CaOCa(OH)2)bull Paraffinebull Salts
Chemical heat storages
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
672016 JGCSE Shanghai 67
Without heat conducting structure
Phase Change Materials (PCM-) storage
Source PhD TUHH Ekkehard Lohse
With heat conducting structure
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
682016 JGCSE Shanghai 68
Phase Change Materials (PCM-) storage
Prototype
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
692016 JGCSE Shanghai
Modelling of energy systems
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
702016 JGCSE Shanghai
Comparisonheat flow demandheat flow supplyfor different modellingapproaches
Steady state- - - demand
supply- - - demand
supply
- - - demandsupply
- - - demandsupply
time timetime
timetime
Steady state ndash quasi steady state ndash non steady state
Quasi steady state
Non ndash steady state (dynamic)
- - - demandsupply
- - - demandsupply
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
712016 JGCSE Shanghai
Future energy system
Hamburg
Each System locally balanced
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
722016 JGCSE Shanghai 72
Research Project TransiEntEE
Transientes Verhalten gekoppelter Energienetze mit hohem Anteil Erneuerbarer EnergienTransient Assessment of Coupled Energy Grids with High Amount of Renewable Energies
wwwmodelicaorghttpsopenmodelicaorgdownloaddownload-windows
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
732016 JGCSE Shanghai
Dynamic modelling
Air
Wall
CO2Pipeclass DynamicWallCF
bdquoCylindriccapacitive wall cross-flow parameter Integer n(min=1) = 1parameter SIunitsTemperature T_wall0=273 ThermoFluidInterfacesHeatTransferHeatFlowD qa(n=n)ThermoFluidInterfacesHeatTransferHeatFlowD qb(n=n)
equation for i in 1n loop
qaq[i] = (qaT[i] - T_wall[i])(geoRwn2)qbq[n + 1 - i] = (qbT[n + 1 - i] - T_wall[i])(geoRwn2)end for
end DynamicWallCF
geoCpgeomnder(T_wall[i]) = qaq[i] + qbq[n + 1 - i]
2
2
xT
0 =
tTcp
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
742016 JGCSE Shanghai
High Volt Power Line Middle Volt Power Line Low Volt Power Line
Gas pipelines high middle low pressure
District Heating HH 13660degC
+ -
+ -
+ -
+ -
Coal PowerPlant with CO2 ndashCapture
BiomassPowerPlant
Windenergy(Nothsea)
Hydropowerstorage
FlywheelStorage
(Big)Batterystorage
PipeGasStorage
Gas storage
Gas-turbine
H2
H2 CH4
CO2 CO2
CH4
H2
Heattrans-former
Photo-voltaicplant
Solarthermalplant
Boiler
ElHeatPump
Thermal storage
CHP
Battery
(Big) Battery
FlyWheelStorage
Compressor Turbine
High pressureAir storage
PCM-Storager
TransiEntEE
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
752016 JGCSE Shanghai
TransiEntEE ndash Library
Electricity heat
Power plants CHP boilers
Grid
Batteries thermal storages
For developer
For users
Economical data
Weather data
Mediahellip
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
762016 JGCSE Shanghai
High pressure gas grid of Hamburg
Data of gridbull Operator Hamburg Netz
bull Market area GASPOOL
bull Feeder grid operator GASUNIE
GASCADE
bull H-Gas with 113kWhm
076kgm
bull Pressure 15MPa
bull Length 528 km
bull Output points 350
bull Annual output (2014)
194 9kWh 172 9m
bull Simultaneous peak load (2014)
5807MW 143m hfraslSource wwwnetz-hhcom 2013
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
772016 JGCSE Shanghai
Power-to-Gas-plant
77El grid
Compressor
Elektrolysis
P_el_PtG
m_flow_H2_max
max m_flow_H2
Mixing
Sensor m_flow_H2
m_flow_H2
m_flow_NGXi_NG
Determination ofElektrolysis- andAuxiliary power demand
P_el_VP_el_E
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
782016 JGCSE Shanghai
Scenario overviewYear 2050Overload ability 300 for maximal 8 hours3 electrolyzers at the gas transfer stations (GTS) to HamburgControlled by electrical residual load hydrogen is only produced when there is excess renewable powerRestrictions feed‐in limit maximum power of ELY overload abilityScenario variationsFeed‐in limits 2 5 10 vol‐Hydrogen storage without (wo) and with (w)
4MPa 15MPa3 150000 rarr ∆ 3 3467356m
System modeled and simulated with ModelicaDymola
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
792016 JGCSE Shanghai
Residual load and maximal allowed H2 mass flow rates
Much excess power and little gas demand
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
802016 JGCSE Shanghai
Summary (2)
Non renewable energies will be necessary the next 50 yearsTo evaluate define an energy system well it is crucial to define the right system boundary and the right time periodicThe storability of energies has to be taken into considerationEnergy should be as much as possible converted locallyEach energy systems has to be adopted to the local conditionsSmart energy management tools are neededTo model big systems is the challenge of the futureChanging of energy systems will produce setbacks nevertheless not way back
812016 JGCSE Shanghai
schmitztuhhde
812016 JGCSE Shanghai
schmitztuhhde