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Transcript of 00022379
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SERVICE LIFE LIMITATIONS OF
FLOODED L EAD ACID BATTERIESI N UPS SERVICE
W T . Rut ledge
PACIFIC BELL
BBSTR CT
Thi s paper d e sc r ib e s d i f f i c u l t i e st h a t h av e e v ol ve d i n t h e a p p l i c a t i o n off l oo d ed l e a d a c i d b a t t e r i e s t o Un in te r -ru pt ib le Power Systems (UPS) se rv ic e .I n d u s t r y p r e s s u r e s f o r g r e a t e r p owerd e n s i t i e s appear t o ha ve r e s u l t e d i ndevelopments t h a t may have been coun-t e rp r od u ct iv e t o t h e s e r v i ce l i f e oft h e UPS c e l l s . The h i g h c u r r e n t , s h o r tterm d i sc h a rg e c h a r a c t e r i s t i c s t h a t a red e s i r a b l e f o r UPS a p p l i c a t i o n s r e s u l ti n b a t t e r y d e s i g ns t un e d t o l e ss t h a noptimum l i f e . Uni n t e r rup t i b l e P owerSystems a r e g e n e r a l l y a pp l i e d t o l a r g ecompu te r da t a cen t e r s . The da t a cen t e rmanagers, who adm inis ter th es e a p p l i c a -t i o n s , t e nd t o b e l e ss in formed on thel i f e / c o n s tr u c t io n c h a r a c t e r i s t i c s o f
b a t t e r i e s t h a t ca n r e s u l t i n u nf or es ee na nd s e v e r e e co no mi c l o s s e s f o r t h e i rmanage ment . T h i s p a p e r d e s c r i b e se f f o r t s by t h e I EEE t o p r ov i de a p p l i -ca t i ons docum en t a t ion des i gned t o re-d u ce t h i s i n f o rm a t io n g a p , b r i n g t h ematter ou t i n t o t h e open , and r educet h e s e c o m p e t i t i v e p r e s s u r e s on t h e b a t -te ry and UPS in du s t r i es .
HISTORY
Hi s t o r i ca l l y , t h e m a jo r comm erc i alb a t t e r y a p p l i c a t i o n s h av e b ee n i n t h era i l road , t e l ecom m un i ca t i ons and elec-t r i c u t i l i t y m a r ke t s. E ac h o f t h e s emarket segments is populated by enoughre l a t i ve l y l a r ge compan ies who can a f -f o r d t h e t e c h n i c a l e x p e r t i se t o e f f e c tc o n t r o l of p r o d uc t q u a l i t y t h r o u ght h e i r p u r c ha s in g p o l i c i e s .
UPS
The emerging UPS ba t t er y marke t ,u n l i k e t h e p r e v io u s m a r k et s , is cons i -d e r a b l y less s o p h i s ti c a t e d i n i t s b a s i cknowledge of b at te ry t echnology. N e w
o r r e pl ac e me n t b a t t e r i e s are of t en p ro -cured by Data C en t e r m anagers o r bu i l d -in g maintenance pe rson s. The demandso f t h i s m ar ke t h av e d r i v e n t h e b a t t e r ym a n u f a c t u r i n g i n d u s t r y i n t o a competi-t i v e race t o p r o v id e t h e h i g h e s t p os -
s i b l e power den s i t y . TheUPS
u s e r sh av e n o t r e c o g ni z e d t h e b a t t e r y d e s i g nt r a d e- o f f s t h a t c an r e s u l t i n r ed uc edb a t t e r y l i f e .
UPS u s e r grou ps a re now forming t odi sc us s and compare common problems .U n f u l f i l l e d b a t t e r y l i f e h as s u r f a c e d ast h e i r f o re mo st d i f f i c u l t y . I n i t i a l i n -v e s t i g a t i o n s b y West co as t UPS use rs andse ve ra l UPS main tenance co nt r ac tor s havedef i ned t he p rob l em as fo l l ows :
H I G H POWER DENSITYBATTERIES
A f t e r i n i t i a l UPS i n s t a l l a t i o n s wereequipped wi t h g ene ra l purpose te lecom-m u n ic a t io n s t y p e c e l l s , t h e b a t t e r y man-u f a c tu r e rs , i n an e f f o r t t o meet cus-tomer demand f o r more Watts per u n i tvolume responded wi t h se ve ra l des ignc ha ng es . F i r s t , e l e c t r o l y t e s p e c i f i c
g r a v i t i e s were i n c r e a s e d t o p r o v i d e b e t -t e r s h o r t term d i s c h a r g e r a t e p e r f o r -mance. Second, p l a t e g r i d d e s i g ns wereimproved to b e t t e r c o l l e c t e n e r g y f r o ma r e a s more d i s t a n t f ro m t h e b a t t e r yp o s t s . A h e a v i er o v e r a l l c u r r e n t c o l -l e c t i o n s ys te m was b u i l t i n t o t h e c e l l s
i n c l u di n g c o pp er i n s e r t s i n t h e p o s t s t oaccommodate th e very h ig h sh o r t termd i s c h a r g e r a t e s . T h i r d , p l a t e s weret h i n ne d down t o a l l o w t h e g r e a t e r s u r -f a c e d i s c h a r g e a c t i o n t h a t a cc om pa ni esh i g h d i s c h a r g e r a t e s . Also , i n somec a s e s t h e d e n s i t y o f t h e a c t i v e m a t e r i a lp a s te d i n t o t h e pla tes was d e c r e a s e d t oa l lo w b e t t e r c o n d uc t i vi t y t o t h e i n ne rs u r f a c e a r e a s of t h e a c t i v e m a t e ri a l .F i n a l l y , t h e h e a v i e r , f i b e r g l a s s , p os -i t i v e p l a t e r e t a i n i n g mats t h a t h ol d t h ed e l i c a t e l e a d d i o xi d e c h ar g e c r y s t a l sa g a i n s t t h e s u r f a c e s o f t h e p o s i t i v ep la te s were e i t h e r t hi n ne d t o t h e t h i c k -n e s s o f t i s s u e paper or com pl e t e l yremoved.
Each of t h e d e s i g n c ha ng es t h a t s oenhanced th e h ig h r a t e UPS performancea l s o t en de d t o d e c r e a se t h e c e l l l i f eand l i m i t i t s a b i l i t y t o h an dl e t h ed e ep e r d i s c h ar g e s t h a t a l s o t e n d t oaccompany high r a t e usage.
The u s e r s f o r t h e most par t , however ,were no t made aware of the consequenceso f t h e i r h i g h p ower d e n s i t y s e l e c t i o n so n t h e e xp e c t e d b a t t e r y s e r v i c e l i f e .
Oft en , i n new UPS i n s t a l l a t i o ns , t he
b a t t e r yis
purch ased thro ugh t h e UPSsu pp l i er who may be unaware of t he h ig hpower d e n s i t y r i s k s o r he is under pres -s u r e o f price com pet i t io n and may ten dt o c u t c o r n er s w i t h t h e b a t t e r y .
379 CH2653 4/88/0000 0379 01 00 C 1988 IEEE
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WARRANTIES
A l l o f t h e s e f a c t o r s h av e f o r c e dt h e b a t t e r y m a n u fa c tu r er s i n t o a h i g h l yc o m p et i t iv e e f f o r t t o o f f e r h i gh erp ow er d e n s i t i e s a t l o w er c o s t s . Onem ig ht e x p e c t t h a t a d r o p i n w a r r a n t y
i n t e r v a l s w ould f o l l o w a l o n g w i t h t h i se f f o r t . Tha t , howe ve r, d id no t oc c u r .The use r saw t h e same twe n ty year war-r a n t y . Some manufacturers addedc l au s e s t o l i m i t l i a b i l i t y . Fo r i n s-t a n c e , w i t h h i g h er s p e c i f i c g r a v i t y ,t h e u s e r m ig ht b e c o n s t r a i n e d , u n de rwa r r a n ty , t o ke ep th e t e m pe r a tu r e downt o 5 80F t o e x p e c t f u l l t we nt y yearb a t t er y l i f e .
EAR LY POSITIVEFAILURES
PLATE
A s t h e UPS use r s ba nde d toge t he r t ocompare maintenance no te s , t soon be-
came e v i de n t t h a t t h e in d u s t r y was ex-p e r i e n c i n g a v e r y h i g h i n c i d e n c e o fe a r l y b a tt e r y f a i l u r e s . A t t h i s p o i ntthe t e l e phone c om pa ny UPS u s e r s c a l l e dupon t h e i r more e xpe r i e nc e d ba t t e r yp eo pl e t o f u r t h e r d e f i n e t h e r o o tproblem.
I n i t i a l i n s p e c ti o n o f s e v e r a ls t r i n g s of t h e f a i l i n g c e l l s showed ex-c e s s i v e a mo un ts o f p o s i t i v e p la t e ma-t e r i a l s l o u gh e d o f f i n t o t h e s e d i me n tba s i ns . The m a nuf a c tu r er s f e l t t h a tt h e p l a t e f a i l u r e s were t h e r e s u l t o fe x c e s s i v e d e e p d i s c h a r g e c y c l i n g . C al -cium c e l l s t e n d t o b e h e a v i l y d e p e nd e n to n f i b e r g l a s s p o s i t i v e p l a t e w r ap t os u p p o r t d e e p d i s c h a r g e c y c l i n g c h a r a c-t e r i s t i c s . C e r t a i n l y , w i t h t h e h i g h
r a t e UPS d i s c h a r g e c h a r a c t e r i s t i c s , t
is easy t o l og many he avy d i sc ha r g e sd u r i n g t h e UPS i n s t a l l a t i o n / t e s t i n t e r -v a l b e f o r e t h e u s e r e v en p l a c e s t h esys tem i n s e r v i c e . A ls o, a wellmeaning us e r who wishes t o be ce r t a i nt h a t h i s c o n n e ct i o ns a re p r o p e r l yt o r q u e d a nd c a p a b l e o f c a r r y i n g t h eh i g h r a t e l o a d s , may u s e t h e l oa d t omake voltage drop measurements of t h ei n t e r c e l l c o n n e c ti o n s . Th e p u z z l i n gq u e s t i o n w i t h t h i s s c e na r i o is t h a t t h eus ers group had members wi t h mu l t ip lea ged id e n t i c a l UPS m odu les , a l l i de n -t i c a l l y t r e a t e d , whose b a t t e r y f a i l u r emodes d i f f e r e d g r e a t l y . W r e c o r de do ne l o c a t i o n w i t h 4 year old te lecom-m unic a t ions c e l l s t h a t were s t i l l per -f o r m ing ve r y well. A few f e e t away, i nt h e same ba t t e r y r oom , we obse r ve d anewer des ign UPS b a t t e r y t h a t h adTOT LLY f a i l e d a f t e r o n l y s e ve n y e a rso f a p p a r e n t l y i d e n t i c a l t r e a t m e n t ?
Tests of t h e f a i l i n g c e l l s r e v e a l e dAC r i p p l e c u r r e n t s o f as much a s 400
times t h e e x pe ct ed f l o a t c u r r e n t s f o rt h e f l o a t v o l t ag e s a t w hich t h e c e l l swere b e i n g o p e r a t e d . The o l d e r , t e l e -communications c e l l s a l s o r e c o r de d w ha twe c o n s i d e r e d v e ry h i g h r i p p l e c u r -
re nt s . They were , however , magni tudeslower than the newer UPS d e s i g n s .Measurements a t s e v e r a l o t h e r u s e r l o -c a t i o n s r e v e a l e d s i m i l a r h i g h r i p p l ecu r r en ts i n th e new UPS c e l l d e s i g n s .
We, a t f i r s t , s u s p e c t e d p o or m ain -t e n an c e o f t h e UPS r e c t i f i e r s t a g e f i l -t e r c a p a c i t o r s . F u r t h e r t e s t s showed,h ow ev er , t h a t t h e f i l t e r b an ks werep u l l i n g t h e i r p ro p er s h a r e o f t h e r i p p l ec u r r e n t s . F u r t h e r c o n s i d e r a t i o n o f t h eb a t t e r y i n d u s t r i e s a t t e m p t s t o p r o vi d et h e h i g h e s t p o s s i b l e s h o r t term c u r r e n tr a t e s , l e d us t o b e li e v e t h a t t h ene c e ssa r y lower b a t t e r y impedance ha dpr ov ide d a b e t t e r s h o r t c i r c u i t p a t h f o rt h e r i p p l e c u r r e n t s t h a n t h e i n t en d e dr e c t i f i e r f i l t e r c a p a ci t o r s. A ls o, t
would seem l o g i c a l t h a t t h e s e r i p p l ec u r r en t s c ou ld s t r i p t h e d e l i c a t e l ea dd i o x i d e ( c h a r g e ) c r y s t a l s f ro m t h e nowu n p ro t ec t ed s u r f a c e s o f t h e p o s i t i v ep l a t e s . T h i s p o s s i b i l i t y g e n e r at e d , asyou might expec t , g rea t i n t e r e s t f ro mt h e b a t t e r y a nd UPS s u p p l i e r s .
UPS, A DIFFERENT LOAD
The UPS i n v e r t e r p r e s e n t s a f a rd i f f e r e n t l o a d t o a b a t t e r y t h a n a ny o fo u r p r e vi o u s i n d u s t r y a p p l i c a t i o n s . Re
c o g ni z e t h a t p r e v i o u s b a t t e r y l o a d s wereg e n e r a l l y ran do m i n n a t u r e ( t e n s o fthousa nds o f t e l e pho ne r e l a y s ) and
t en d ed t o p r e s e n t a r e l a t i v e l y s m o o t hl o ad t o t h e b at t e r y . A ls o, t h er e c t i f i e r s were well a b l e t o k e ep u pw i t h t h e s l o w e r r a t e o f c u r r e n tchanges . The In ve r t e r s tage of t h e UPS,however, draws massive amounts of energya t t h e 60/360 Hz r a t e . I n t h e case of a
s o f t AC power l i ne , t h i s e ne r gy m ustcome f ro m e i t h e r t h e f i l t e r c a p a c i t o r si n t h e r e c t i f i e r s t a g e o r f ro m t h ebatteru The new lowe r impedance ba t-t e r i e s who can s o r e a d i l y r es po nd t o t h en ee d o f t h e i n v e r t e r a p p ea r t o p r o vi d et h e s e s h o r t term e ne r gy r e qu i r e m e n t s .
One UPS m a n u fa c t ur e r f e l t t h a t r i p p l ec u r r e n t s were of to t a l l y no conseque nc e
s t a t i n g t h a t b a t t e r i e s were e ve nknown t o be f l o a t ed on ha l f wave rec-t i f i e d power w i t h o u t a ny a d v e r s e a f f e c t .
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UPS, A DIFFERENT LOAD
(Cont.
T h i s s of c our se ve r y t r ue . Wi th nol o ad o n t h e b a t t e r y , l i k e a c a p a c i t o r ,t c h ar ge s t o a p e ak v a l u e w i t h l i t t l e
d i sc ha r ge f r om i t s i n t e r n a l l o s s e s.Eve n though the r i p p l e VOLTAGE s ex-
cee din gl y HIGH, t h e r i p p l e CURRENTS areve r y LOW. The case f o r i n v e rt e r s is
j u s t t h e o p p o s i t e . The r e c t i f i e r s pre-s e n t a n e x t r e m e l y l ow r i p p l e v o l t a g ef ro m t h e i r s i x p ha se b r i d g e well f i l -t e r e d systems. However, even th e small
va l l e y s i n t h e wavef or m c a n be dep -l e t e d by t h e h ea v y, c y c l i c a l e n e r g y re-qu i r e m e n t s of t h e i n v e r t e r g e n e r a ti n ge v e n h i g h e r r i p p l e CURRENTS t h a n mi gh tbe measured i n an unloaded , ha l f wavec h a r g e d b a t t e r y s y s t e m .
DO RIPPLE CURRENTS DAMAGE?
One m ig ht c e r t a i n l y e x p e c t t h i s t o
b e t h e case s i n c e t h e b a t t e r y manu-f a c t u r e r s h av e f o r so l ong p l a c e ds t r i n g e n t r i p p l e v o l t a g e c o n s t r a i n t s o nt h e a p p l i c a t i o n o f t h e i r p r o d uc t s . I tis p o s s i b l e , t h ou g h, t h a t t h e s e c on -s t r a i n t s were d i c t a t e d by o ne of t h e i rm a jo r m a r ke t s , t h e t e l e c om m unica t ionsin du st ry , who s i m p l y w is he d t o l i m i t
t h e hum i n t h e s u b s c r i b e r s e ar s. We,t h e u s e r s , a re a w a i t i n g w i t h grea ti n t e r e s t , t h e p u b l i c a ti o n o f d e t a i l e d ,d e f i n i t i v e , t e s t r e s u l t s on t h e ef fec t sof r i p p l e a l o n e a nd r i p p l e / c y c l e com-b ine d e xpe r im e n t s on t he UPS l i n e ofce l l s w i t h o u t f i b e r g l a s s r e t a i n e r s a ndw i t h a l l o f t h e o t h e r c h an g es e mb od ie di n t h e c u r r e n t UPS l i n e o f c e l l s .P r e v ious r i p p l e / l i f e papers ha ve no twell d e f in e d t h e e f f e c t s o f r e t a i n i n g
m a t s , p o s i t i v e p l a t e e n c a p s u l a t i o n , o rg r i d a l l o y s t h a t makes l i f t t r u c k c e l l ss o r e s i s t a n t t o c yc l in g .
UPS us er s cont inu ed t o be confused byf a i l u r e s of b a t t e r y s t r i n g s ( Some i no n l y 3 years) wit h no known his to ry of
c y c l i n g . User g r ou p i n q u i r i e s d i s c l o s e ds i m i l a r e a r l y f a i l u r e s i n s e v e r a l manu-f a c t u r e r s UPS p r oduc t l i n e s a nd wereve r i f i e d by se ve r a l UPS ba t t e r y m a inte -n a n c e c o n t r a c t o r s .
I EEE INVOLVEMENT
A t t h i s p o i n t , UPS d e s i g n c o ns u l -t a n t s , u nd er f i r e from t h e i r c l i e n t s ,a s k e d t h e I EEE t o c on v en e a g r ou p t os tudy the p r ob le m . A m aj or d i f f i c u l t y ,t was d i s c e r n e d , stems from th e new and
smaller b a t t e r y u s e r s who t e n d t o b eu n f am i l i ar w i t h t h e e f f e c t s of t h e UPSb a t t e r y d e s i g n c h a n ge s t h a t t h e y h av ep r e s s e d i n t o e x i s t e n c e . An I EEE t a s kf o r c e h as b ee n f or me d u n de r t h e S t a t i o nB a t t e r y Working Subgroup. Th is grou p is
i n t h e p r o c e s s o f p r e p a r in g a u s e r l e v e li n f o r m a t i v e d oc um en t t h a t w i l l preparet h e new UPS market t o se l e c t t h e b e s te n e r g y s t o r a g e system t o meet t h e i r
ne e ds .
W T . R u t l e d g e , P a c i f i c B e l l
R e f e r e nc e : I n f lue nc e O f SuperimposedAl t e r n a t i ng C u r r e n t On Capaci ty andC yc le L i f e For Lead Acid Ba t te r ies ,S. Oka z a k i , S Higuc h i , 0. Nakamura,S Ta ka ha sh i ,J o u r n a l of A p p l i e d E l e c t r o c h e m i s t r y-16 1986) 894-898)
Spec ia l Thanks To D r D 0. F e d e r f o rh i s e f f o r t s in e d i t i n g t h i s d oc um en t.
381