0 Intro 190409 · 2019-04-03 · kT≈ 0.6kcal /mol (~ 20 meV) ! Z* (100m ) 1cm 1mm 1mm 7 ! {z(h9d...
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5O?0M $'Xcb'a=`]W^0L[e 1 $' Part 1 $ Part 2 'aRM Part 3 (Ea'8M Part 4 I'V!7V &dZYda'V UEa' Part 5 < <B Bo op pm mg gk k Tetra-PEGi is sf f9 9W W\ \ D D i is s? ? -5$<$?<B*K / https://www.shibayamalab.issp.u-tokyo.ac.jp/ References: 1) +>:V$%VC4 2) Brückel et al., Eds., Neutron Scattering, Forschungszentrum Jülich, 3) ;QV'aRMV3, 4) G"FVT58NzV1PJ.V 5) Higgins & Benoit, Polymers and Neutron Scattering, Oxford, 1994 6)J. Alfken, =58(Vxwqgosuntls_HV yw62S(_A)@ 7) Experimental Neutron Scattering, B.T.M. Wills, and C.J. Carlile, Oxford, 2009. 8) 'a=_#9V/V2014 v. 1.0 (2019/03/03) khjrvs
Transcript of 0 Intro 190409 · 2019-04-03 · kT≈ 0.6kcal /mol (~ 20 meV) ! Z* (100m ) 1cm 1mm 1mm 7 ! {z(h9d...
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Part 1Part 2Part 3Part 4
Part 5Tetra-PEG
https://www.shibayamalab.issp.u-tokyo.ac.jp/
References:1) 2) Brückel et al., Eds., Neutron Scattering, Forschungszentrum Jülich,3) 4) 5) Higgins & Benoit, Polymers and Neutron Scattering,Oxford, 19946)J. Alfken,
7) Experimental Neutron Scattering, B.T.M. Wills,and C.J. Carlile, Oxford, 2009.
8) 2014
v. 1.0 (2019/03/03)
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Introduction:VII 2018.4.9
https://www.shibayamalab.issp.u-tokyo.ac.jp/
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Infrared UV Cold Neutronsoft x-ray x-rayNeutron
Microwave
Electron Microscopy (destructive)STM (surface)In-situ analysis : Neutron & X-rayWe need
1 nanometer1cm 1mm 1µm
10-2m 10-3m 10-4m 10-5m 10-6m 10-7m 10-8m 10-9m 10-10m
Natural
Protein
Manmade
Nanotube electronics 3Choi, AONSA Neutron School, KAIST, 2008
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(
(
SEM AFM
SAXS (Lab.)SAXS (SPring-8)
SANS (J-PARC/JRR-3)
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( 100m
(10cm) (5cm)(11mm) (1mm)
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2dsinΘ=nλ
300 = 25.8 meV = 1.8 ÅkT ≈ 0.6kcal /mol (~ 20 meV)
(100m )1cm
1mm 1mm
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2dsinΘ=nλ
300 K = 25.8 meV = 1.8 ÅkT ≈ 0.6kcal /mol (~ 20 meV)
Part 1
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中性子の優れた能力
水・水素 検出能力 物質透過能力非破壊可視化能力
松林（原子力機構）・持木（武蔵工大）・東芝
Ｘ線 中性子
噴水の玩具
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Chadwick
Fermi
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#12
(2.5 )
( ∝ ) ( ; 1MW ~ 15MW)
(~ )
(60 )
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Bird’s eye photo
J-PARC
TransmutationFacility(Phase II
Hadron Experiment Facility
KAMIOKANDENeutrino Exp. Facility(294km to Super)
Materials & Life Science Facility (MLF)
3GeV Synchrotron(25Hz,1MW)
Linac(400MeV(180MeV))
JRR-3M800m to
MLF
30GeV Synchrotron(0.75MW)
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J-PARC/MLF (Materials and Life Science Experimental Facility)
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Li
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H/D
Li
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本郷
東大
柏
東大物性研
SANS-U, 東大物性研
東海
JRR-3日本原子力研究開発機構(20MW 原子炉)
100km
http://neutrons.issp.u-tokyo.ac.jp/20
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SANS-U
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小小角角散散乱乱装装置置
1nm – 100 nmナナノノ構構造造
0.1 ~ 10 mm
1.0 ~ 2.5 cm (beam diameter)
(SANS-U, JRR-3, Japan)
J. Appl. Crystallogr., 2011, 44, 558.
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高高分分子子にに関関すするるSANS研研究究のの歴歴史史1970s ココンンフフォォメメーーシショョンン
ババルルクク (Wignall, Kirste-Schelten), 溶溶液液, 結結晶晶 (Sadler)
“random conformation” of polymer chains1980s ポポリリママーーブブレレンンドド (Stein, Han),
ブブロロッックク共共重重合合体体 (Bates)miscibility, critical phenomena
1990s 変変形形 (Boué), 流流動動場場, 臨臨界界現現象象,不不均均一一性性 (Shibayama)deformation mechanism, inhomogeneities
2000s ココンンポポジジッットト, 外外場場 (flow, P)高高強強力力ゲゲルル, etc.
2010s 精精密密ゲゲルルのの構構造造、、ゲゲルル化化、、架架橋橋制制御御
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