جامعة الأزهر (فرع...
Transcript of جامعة الأزهر (فرع...
)فرع البنات( جامعة األزهر
كلية العلوم
قسم الكيمياء
Al-Azhar University (Girls branch)
Faculty of Science
Department of Chemistry
Course Specification
Course title: Physical chemistry Code: chem. 468
Program(s) on which the course is given: zoology/ chemistry
Major or minor element of program: Single Double
Department offering the program: zoology
Department offering the course: chemistry
Academic: year 4th Level 2nd
Date of specification approval: 1/2016
A- Basic information
Academic year : 4th Course Title: physical chemistry Code : Chem. 468
Lecture : 4 Practical : 3 Tutorial : 1 Total : 8
√
B- Professional Information
1- Develop wide background in knowledge
related to the different branches of chemistry, to
serve as preparation for graduate work in
chemistry.
2- Utilize chemistry facts and theories to
analyze and interpret practical data.
3- Provide students with a knowledge and
skills base from which they can proceed (if so
desired) to further studies in specialized areas of
chemistry or multidisciplinary areas involving
chemistry and participate effectively in research
activities.
4- Deal with scientific data in English.
5- Develop knowledge and experience of
practical skills and advanced laboratory
techniques. So that they can understand and assess
risks and work safely in the laboratory.
14- Demonstrate a broad education in
fundamental aspects in different branches of
chemistry, to serve as preparation for graduate
work in chemistry.
1- Overall aims of course
2- Intended learning outcomes of course (ILOs)
a1. Identify integrated knowledge and comprehension of the theories,
facts, concepts, fundamentals and techniques related to the fields of
physical chemistry.
a2. Characterize the chemical nature and properties of the functional
groups in different types of molecules with special focus on
insecticides.
a. Knowledge and
Understanding
a3. Demonstrate the chemistry of biological molecules to determine
their biological functions.
b1. Connect between qualitative and quantitative scientific data
relevant to the various subjects of chemistry and entomology.
B2. Postulate and deduce mechanisms and procedures to deal
with scientific problems relevant to contemporary approaches
in entomology and chemistry.
b3. Analyze quantitative data from graphs, figures, tables,
equations and other sources of information.
b. Intellectual
Skills
c1. Perform investigations using appropriate techniques in
accordance with the standard scientific guide lines.
c2. Handle chemical materials safely, particularly insecticides, and
conduct risk assessments taking into account their physical and
chemical properties to avoid the hazards, to users and
environment, associated with their use.
c3. use standard laboratory procedures and techniques.
c4. Search and evaluate the validity and relevance of literature in a
critical thinking approach.
c. Professional and
Practical Skills
d1. Use information and communication technology effectively.
d2. Identify roles and responsibilities, delegate tasks, and set clear
guidelines and performance indicators.
d3. Think independently, and solve problems on scientific basis.
d4. Work in a team effectively; manage time, collaborate and
communicate with others positively.
d5. Address the community linked problems with considerable
attention to the community ethics and traditions.
d. General and
Transferable Skills
3. Contents
No. of hours/week
Topic Total Tutori
al
Practic
al
Lecture
8
1 3 4
Unit 1.
Surface tension
Surface tension and free surface energy
Surfaces between two liquids
Work of adhesion and work of cohesion
Work of adhesion between solids and liquids
Spreading of one liquid on another
Measurements of surface tension of liquids
Surface tension and temperature
Parachor and its application
Adsorption
Types of adsorption
Adsorption at solution surfaces
Application of adsorption
Chromatography
Water softening
Water proofing
Surfactants
definition
composition and structure
classification of surfactants in pharmacy
bio surfactants
application
Unit 2.
Reversible and irreversible electrode process
- Types of over potential and experimental precautions
– Derivation of the Tafel equation
– mechanism of Hydrogen evolution
– Heat of Activation of the cathodic Hydrogen
evolution.
–Oxygen evolution
– concentration polarization
– Cathodic deposition of metals
– Anodic processes
– passivity
– Dissolution and corrosion of metals
– Cells used as a source of E.M.F.
– Primary – Secondary and Fuel Cells. Applications.
Unit 3.
Chemical kinetic of catalytic reactions Heterogeneous catalysis
Properties of catalysts Mechanism of chemisorption
Langmuir adsorption isotherm The products may be adsorbed on the surface of the catalyst
Steps of heterogeneous catalytic processes Kinetically and diffusion controlled heterogeneous catalytic processes Features of heterogeneous catalyst it processes
Activation in heterogeneous catalytic reaction
Homogeneous catalysis
Homogeneous catalysis in the gas phase Homogeneous catalysis in the solution
Theory of homogeneous catalysis
Verification of Shipitalaky’ theory of homogeneous catalysis Acid- base catalysis : Bronsted theory
Acid- base catalytic constants
Specific acid- base catalysis General acid- base catalysis
The secondary salt effect or Duslislic theory of catalysis
Enzyme catalysis
Enzyme Enzyme structure
Enzyme kinetics Composition of active site : Chymotrypsin
Activation in heterogeneous catalytic reaction
Unit 4.
Solutions
Conductance of electrolytic solution, Equivalent and molar conductance, Conductance and solution resistance measurement.
Effect of purity of solvent on the conductivity, temperature and concentration dependence of conductivity.
Determination of equivalent conductance at infinite
dilution, Deby- Huckel Onsager theory for electrolytic conductance.
Deviation from the Onsager equation, Frequency- dependence of conductance.
Effect of high potential- gradient, Independent migration of ions (Kohlraush’s law).
Application of (Kohlraush’s law).
Effect of dielectric on conductance of electrolyte, Absolute velocities and mobility of ions.
Abnormal mobility or ionic conductance of hydrogen and hydroxyl ions, Ionic conductance and viscosity.
Application of the conductance measurement.
Complex formation reaction, determining the rate of reaction.
Determining of degree of hydrolysis, Some typical industrial application of conductance measurements.
Transference numbers and equivalent conductance, temperature dependence of transference numbers, abnormal transference numbers, transference numbers in mixed electrolytic solutions.
Some experimental in conductance, determining the activity, surface
tension and adsorption.
4. Teaching and learning methods
lecture,
discussion,
tutorials, practical,
videos and power point
6- Student assessment
To assess: Knowledge and
Understanding
5.1.1. Written exam
5.1. Methods -To assess: Knowledge and
Understanding
- Intellectual Skills
5.1.2. Oral exam
To assess: Professional and
Practical Skills
5.1.3. Practical exam
To assess: General and
Transferable Skills
5.1.4. Taken the presence of
students.
Week: at the end of the term Assessment 1:
5.2. Assessment
schedule
Week: at the end of the term Assessment 2:
Week: at the end of the term Assessment 3:
14% Semester Work %
5.3. Weighting of
assessments
6% Oral Examination %
20% Practical Examination %
60% Final Examination%
---- Other Type of assessments%
100% Total %
6- List of references
Course Note 6.1. Course Note (if available)
6.2. Text Book
6.3. Additional References
6.4. Periodical journals,….. etc.
7- Facilities required for teaching and learning:
Board and data show
8- Matrix between course specification ILOs and ILOs of program
Knowledge &
understanding
Intellectual skills Professional
practical skills
General &
transferable skills
ILOs of
Course
ILOs of
Program
ILOs of
Course
ILOs of
Program
ILOs of
Course
ILOs of
Program
ILOs of
Course
ILOs of
Program
a1 A1 b1 B2 c1 C1 d1 D1
a2 A1 b2 B5 c2 C5 d2 D2
a3 A3 b3 B9 c3 C2 d3 D3
c4 C7 d4 D4
d5 D5
9- Matrix between contents and ILOs of course:
Course content
Week (s)
No.
A knowledge and
Understanding
Skills
Intellectual
Skills
Professional
skills
General
skills
Surface tension
Surface tension and free surface energy
Surfaces between two liquids
Work of adhesion and work of cohesion
Work of adhesion between solids and liquids
Spreading of one liquid on another
1-3 a1
Measurements of surface tension of liquids
Surface tension and temperature
Parachor and its application
Adsorption
Types of adsorption
4-6 a2 b5 c1,c3 d1,d2,
d3
Adsorption at solution surfaces
Application of adsorption
Chromatography
Water softening
Water proofing
7-9 a3 b6 c4 d4,d5,
Surfactants
definition
composition and structure
classification of surfactants in pharmacy
bio surfactants
application
10-12 c5
Unit 2.
Week (s)
No.
A knowledge and
Understanding
Skills
Intellectual
Skills
Professional
skills
General
skills
Reversible and irreversible electrode process
- Types of over potential and experimental precautions
– Derivation of the Tafel equation
1-3 a1
– mechanism of Hydrogen evolution
– Heat of Activation of the
cathodic Hydrogen evolution.
–Oxygen evolution
4-6 a1,a2 b2, b5 c1,c3 d1,d2,
d3
– concentration polarization
– Cathodic deposition of
metals
– Anodic processes
7-9 a3 b6 c4 d4,d5,
– passivity 10-12 a2 c5
– Dissolution and corrosion of
metals
– Cells used as a source of
E.M.F.
– Primary – Secondary and
Fuel Cells. Applications.
Course content
Week (s)
No.
A knowledge and
Understanding
Skills
Intellectual
Skills
Professional
skills
General
skills
Unit 3. Heterogeneous catalysis
Properties of catalysts Mechanism of chemisorption
Langmuir adsorption isotherm The products may be adsorbed on the
surface of the catalyst
Steps of heterogeneous catalytic
processes
1-3 a2 b2 c1
Kinetically and diffusion controlled
heterogeneous catalytic processes Features of heterogeneous catalyst it
processes
Activation in heterogeneous catalytic
reaction
Homogeneous catalysis
Homogeneous catalysis in the gas
phase Homogeneous catalysis in the solution
4-6 a1,a2 b5 c4 d1,d2,
d3
Theory of homogeneous catalysis
Verification of Shipitalaky’ theory of
homogeneous catalysis Acid- base catalysis : Bronsted theory
Acid- base catalytic constants
Specific acid- base catalysis General acid- base catalysis
The secondary salt effect or Duslislic
theory of catalysis
7-9 a3 b2, b6 c5 d4,d5,
Enzyme catalysis
Enzyme
10-12 a3 b5 c3
Enzyme structure
Enzyme kinetics Composition of active site : Chymotrypsin
Activation in heterogeneous catalytic
reaction
Course content
Week (s)
No.
A knowledge and
Understanding
Skills
Intellectual
Skills
Professional
skills
General
skills
Unit 4.
Conductance of electrolytic solution, Equivalent and molar conductance, Conductance and solution resistance measurement.
Effect of purity of solvent on the conductivity, temperature and concentration dependence of conductivity.
Determination of equivalent conductance at infinite dilution, Deby- Huckel Onsager theory for electrolytic conductance.
1-3 a1 b2 c3
Deviation from the Onsager equation, Frequency- dependence of conductance.
Effect of high potential- gradient, Independent migration of ions (Kohlraush’s law).
Application of (Kohlraush’s law).
4-6 a3 b5 c5 d1,d2,
d3
Effect of dielectric on conductance of electrolyte, Absolute velocities and mobility of ions.
Abnormal mobility or ionic conductance of hydrogen and hydroxyl ions, Ionic conductance and viscosity.
Application of the conductance measurement.
7-9 a2 b6 c1 d4,d5, d
Complex formation reaction, 10-12 b6 c4
determining the rate of reaction.
Determining of degree of hydrolysis, Some typical industrial application of conductance measurements.
Transference numbers and equivalent conductance, temperature dependence of transference numbers, abnormal transference numbers, transference numbers in mixed electrolytic solutions.
Course coordinator:
Head of Department of