X-ray Diffractometer

XRD-6000

Application Field of X-ray Diffractometer

Achievement of shimadzu XRD

NaCl Diamond

Unit Cell of NaCl

PDF2 Data of NaCl

Data list of Carbon in PDF2

DiamondC60Graphite

Crystal Structures of different Carbons

Diamond

C60

Graphite

History of Shimadzu X-ray DifractometerProducts Outline

1945 World first XRD

1996 XRD-6000 Windows95 operated XRD

1962 GX-31958 GX-21955 GX-1

Stand-alone XRD

Shimadzu first XRD｝1970 VD-21965 VD-1 ｝Automated recording XRD with

GRS matching start function

1978 XD-3A,5A1974 XD-3,5 ｝Fully automated XRD with

small & safety case

1986 XD-610 Computer controlled XRD

1992 XD-D1 Fully computerized XRD

XRD-6000

Big Features of XRD-6000

1. Compact & Safety Case Design

2.High Precision & Very StableVertical Goniometer

XRD-6000

3.User Friendly Operation(Windows95/98)

1.Compact & Safety Case Design

・ Size of Main BodyW900×D700×H1600

・ Door is Locked whenthe X-ray Power is ON

・ No Switch for Cancellation of Interlock system

900 700

1600

XRD-6000

2.High Precision & Very StableVertical Goniometer

・ Angle Reproducibility±0.001 ゜ (2θ)

・ Scanning Angle Range-6 ～＋ 163 ゜（ 2θ ）-180 ～＋ 180 ゜（ θ ）

・ θ-Axis oscillationEquipped as Standard

XRD-6000

3.User Friendly Operation (Windows95/98 or NT)

・ Multitasking

・ Mouse Operation

・ Easy to Upgrade(H/W,S/W)

・ Ready for Network

・ Easy to Transfer the Datato the General-purposeS/W such as MS-Wordor Excel

XRD-6000

MeasurementSection

Basic Data Processing

SearchMatch

Quant.Calc Advanced Data Process

Standard Configuration Optional Software

XRD-6000 Main Window

XRD-6000

XRD-6000 STATUS DISPLAY WINDOW

X-RAY POWER CONTROL WINDOW

XRD-6000

GONIOMETER OPTICAL ADJUSTMENT

XRD-6000

MEASUREMENT CONDITION EDITING

XRD-6000

MEASUREMENT WINDOW

XRD-6000

XRD-6000

BASIC DATA PROCESSING

BASIC DATA PROCESSING

XRD-6000

BASIC DATA PROCESSING

XRD-6000

SEARCH/MATCH

XRD-6000

SEARCH/MATCH

XRD-6000

Search/Match result of some Minerals

Anorthite

Albite

Augite

Search/Match result of some Minerals

ＱＡＮＴＩＴＡＴＩＶＥ ＡＮＡＬＹＳＩＳ

XRD-6000

CALIBRATION CURVE

XRD-6000

CALIBRATION CURVE

XRD-6000

QUANTITATIVE ANALYSIS

Thin Film Attachment

Specification・ Sample StageRotation 360°Fixation Vacuum SackingSize(max) φ102x10mm・ Adjustment for Sample Surfaceby Micrometer Head・ Rotation Speed 72rpm・ β-axis MeasurementContinuous/step scan・ Monochrometer Graphite

XRD-6000

Crystalinity Measurement

Calculation of Crystallite Size and Lattice Strain

β ＝ β ｓ＋ βoβｓ： FWHM for Crystallite Size(D)

βo :FWHM for Lattice Strain(η)

β ＝ β ｓ＋ βo ＝

β ｓ＝ λ D ･ Cosθ

βo ＝ 2η ･ Sinθλ

Sinθλ

λ D ･ Cosθ

＋

β ･ Cosθλ

＋ 2η ･ Sinθλ

１D＝

Hall’s equation

Crystallite size & Lattice Strain

Counter Monochromator for XRD-6000

Rotational Sample Stage for XRD-6000

Environmental Measurement Stage for XRD-6000

Sample Heating Attachment for XRD-6000

Sample Heating Attachment for XRD-6000Low Temperature Stage TTK-450

Main Specification

Temperature Range -193 through 450degSize of ApparatusOuter Diameter 105mmThickness 60mmWindow for X-ray 12mm/200degMaterial of X-ray Window25 micron KAPTON Thin FilmDetector for TemperaturePlatinum(PT100)Consumption Rate of Liquid Nitrogen1.5 litter/hour(at -193degree)

TTK-450 Low Temperature Stage

TTK-450 Low Temperature Stage

Application Data by TTK-450

Main Specification

Sample Heating Attachment for XRD-6000High Temperature Stage HTK-1200

Temperature Range RT through 1200degSize of ApparatusOuter Diameter 150mmThickness 60mmWindow for X-ray 10mm/200degMaterial of X-ray Window25 micron KAPTON Thin FilmDetector for TemperatureThermocouple(Pt-PtRh)AtmosphereAir,Inert Gas, Vacuum, Corrosive Gas

HTK-1200 High Temperature Stage

HTK-1200 High Temperature Stage

Pole Figure Attachment for XRD-6000

Advanced Crystal Structure Analysis

• Precise Lattice Constant Calculation • Crystal System Determination• Rietveld Analysis (with NARiet

process)Refine Crystal ParametersQuantitative Analysis of Multi ComponentCrystal Solid Model Display

TiO2 Rutile structure

Ｔｉ

Ｏ

Fulleren C60 structure

Summary

1. Shimadzu XRD has long history

2. Shimadzu XRD-6000 is most compact & safety

3. Shimadzu XRD-6000 has most stable hardware

4. Shimadzu XRD-6000 has user friendly S/W

5. Shimadzu XRD-6000 has more capability