Post on 22-Jan-2021
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
__________________________________________________________________________________________
Page: 1 of 10
Safety Data Sheet
© 2016, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilising 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written
agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention
of earning a profit thereon.
Document group: 16-2219-0 Version number: 3.00
Issue Date: 14/11/2016 Supersedes date: 06/10/2014
This Safety Data Sheet has been prepared in accordance with the New Zealand, Hazardous Substances and New Organisms
Act 1996 (HSNO Act) and Regulations, as amended.
SECTION 1: Identification
1.1. Product identifier
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
Product Identification Numbers
98-0212-2988-9 UU-0031-6527-9 WF-6009-0052-7
1.2. Recommended use and restrictions on use
Recommended use
Downhole Oil and Gas Applications, Industrial use.
1.3. Supplier’s details
Address: 3M New Zealand Ltd, 94 Apollo Drive, Rosedale 0632, Auckland
Telephone: (09) 477 4040
E Mail: innovation@nz.mmm.com
Website: 3m.co.nz
1.4. Emergency telephone number
24 hr Medical Emergency, National Poisons Centre, 0800 764 766 (0800 POISON)
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Classified as hazardous according to the New Zealand, Hazardous Substances (Minimum Degrees of Hazard) Regulations
2001 as amended. This product is considered to be an article which does not release or otherwise result in exposure to a
hazardous chemical under normal use conditions.
Not classified as a Dangerous Good according to; New Zealand, Land Transport Rule: Dangerous Goods 2005 (Rule
45001/1) as amended, NZS 5433:2012 Transport of Dangerous Goods on Land, UN Model Regulations on the Transport of
Dangerous Goods, International Maritime Dangerous Goods Code and IATA Dangerous Goods Regulations.
HSNO classification
6.1E Acute toxicity
2.2. Label elements
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
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Page: 2 of 10
SIGNAL WORD
WARNING!
HAZARD STATEMENTS:
H303 May be harmful if swallowed.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr % by Weight
Soda lime borosilicate glass 65997-17-3 97 - 100
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Material will not burn. Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
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6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container.
Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
Refer to Section 15: HSNO Controls for more information.
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
7.3. Approved handler test certificate
Not required
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient CAS Nbr Agency Limit type Additional comments
Glass filaments 65997-17-3 New Zealand
WES
TWA(as inhalable dust)(8
hours):5 mg/m3;TWA(as
respirable dust)(8 hours):1
f/mL;TWA(Respirable
fibers)(8 hours):1 f/mL
Soda lime borosilicate glass 65997-17-3 Manufacturer
determined
TWA(as dust):10 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
New Zealand WES : New Zealand Workplace Exposure Standards.
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
ppm: parts per million
mg/m³: milligrams per cubic metre
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Provide appropriate local exhaust ventilation at transfer points. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray.
If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
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Safety glasses with side shields.
Refer AS/NZS 1336 - Recommended practices for occupational eye protection and for performance specifications AS/NZS
1337, Parts 1 - 6 - Personal eye-protection.
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
Wear respiratory protection if ventilation is inadequate to prevent overexposure. An exposure assessment may be needed to
decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program.
Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates.
For questions about suitability for a specific application, consult with your respirator manufacturer.
Refer AS/NZS 1715 - Selection, use and maintenance of respiratory protective equipment and AS/NZS 1716 - Respiratory
protective devices.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state Solid.
Specific Physical Form: Fine Powder < 100 microns
Appearance/Odour White, Odourless
Odour threshold Not applicable.
Melting point/Freezing point No data available.
Boiling point/Initial boiling point/Boiling range Not applicable.
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas) Not classified
Flammable Limits(LEL) Not applicable.
Flammable Limits(UEL) Not applicable.
Vapour pressure Not applicable.
Vapour density Not applicable.
Density 0.1 - 0.6 g/cm3
Relative density 0.1 - 0.6 [Ref Std:WATER=1]
Water solubility Negligible
Solubility- non-water Not applicable.
Partition coefficient: n-octanol/water No data available.
Autoignition temperature Not applicable.
Decomposition temperature Not applicable.
Viscosity Not applicable.
Molecular weight No data available.
Volatile organic compounds (VOC) Not applicable.
Percent volatile < 0.5 % weight
Softening point >=600 ºC
VOC less H2O & exempt solvents Not applicable.
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
__________________________________________________________________________________________
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10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
Oxides of sulphur. If Breakage Occurs
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin contact
Mechanical skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye contact
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Ingestion
May be harmful if swallowed.
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute ToxicityName Route Species Value
Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg
Soda lime borosilicate glass Dermal LD50 estimated to be > 5,000 mg/kg
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
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Page: 6 of 10
Soda lime borosilicate glass Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/IrritationName Species Value
Soda lime borosilicate glass Professio
nal
judgemen
t
No significant irritation
Serious Eye Damage/IrritationName Species Value
Soda lime borosilicate glass Professio
nal
judgemen
t
No significant irritation
Skin Sensitisation
For the component/components, either no data are currently available or the data are not sufficient for classification.
Respiratory Sensitisation
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell MutagenicityName Route Value
Soda lime borosilicate glass In Vitro Some positive data exist, but the data are not
sufficient for classification
CarcinogenicityName Route Species Value
Soda lime borosilicate glass Inhalation Multiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
For the component/components, either no data are currently available or the data are not sufficient for classification.
Target Organ(s)
Specific Target Organ Toxicity - single exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity - repeated exposureName Route Target Organ(s) Value Species Test result Exposure
Duration
Soda lime borosilicate
glass
Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
__________________________________________________________________________________________
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SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. Additional information leading to material classification in
Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be
reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not
expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Number Organism Type Exposure Test endpoint Test result
Soda lime
borosilicate
glass
65997-17-3 Data not
available or
insufficient for
classification
12.2. Persistence and degradability
Material CAS Number Test type Duration Study Type Test result Protocol
Soda lime
borosilicate
glass
65997-17-3 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
12.3 : Bioaccumulative potential
Material CAS Number Test type Duration Study Type Test result Protocol
Soda lime
borosilicate
glass
65997-17-3 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
12.4. Mobility in soil
Please contact manufacturer for more details
12.5 Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1. Disposal methods
See Section 11.1 Information on toxicological effects
Contact your sales representative for information on reclaiming this product. Dispose of waste product in a permitted
industrial waste facility.
Packaging (that may or may not contain any residual substance) may be lawfully disposed of by householders or other
consumers through public or commercial waste collection services.
SECTION 14: Transport Information
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
__________________________________________________________________________________________
Page: 8 of 10
New Zealand Land Transport Rule: Dangerous Goods - Road/Rail Transport
UN No.: Not applicable.
Proper Shipping Name: Not applicable.
Class/Division: Not applicable.
Sub Risk: Not applicable.
Packing Group: Not applicable.
Hazchem Code:
IERG: Not applicable.
International Air Transport Association (IATA) - Air Transport
UN No.: Not applicable.
Proper Shipping Name: Not applicable.
Class/Division: Not applicable.
Sub Risk: Not applicable.
Packing Group: Not applicable.
International Maritime Dangerous Goods Code (IMDG) - Marine Transport
UN No.: Not applicable.
Proper Shipping Name: Not applicable.
Class/Division: Not applicable.
Sub Risk: Not applicable.
Packing Group: Not applicable.
Marine Pollutant: Not applicable.
SECTION 15: Regulatory information
HSNO Approval number HSR002503
Group standard name Additives, Intermediates, Process Chemicals and Raw Materials (Subsidiary Hazard) Group
Standard 2006
HSNO Hazard classification Refer to Section 2: Hazard identification
NZ Inventory of Chemicals (NZIoC) Status
This product is an article as defined by HSNO regulations, and is exempt from NZIoC listing requirements.
HSNO Controls
Approved handler test certificate Not required
Location and transit Depot certification test Not required
Hazardous atmosphere zone Not required
Fire extinguishers Not required
Emergency response plan 100 L or 100 kg (for a HSNO 9.1A substance); or 1,000 L or 1,000 kg (for a
HSNO 6.1D, 6.5A, 6.5B, 9.1B or 9.1C substance); or 10,000 L or 10,000 kg
(for a HSNO 6.6A, 6.8A, 6.9A, 8.3A, 9.1D substance)
Secondary containment 100 L or 100 kg (for a HSNO 9.1A substance); or 1,000 L or 1,000 kg (for a
HSNO 6.1D, 6.5A, 6.5B, 9.1B or 9.1C substance); or 10,000 L or 10,000 kg
(for a HSNO 6.6A, 6.8A, 6.9A, 8.3A, 9.1D substance)
Tracking Not required
Warning signage 100 L or 100 kg (for a HSNO 9.1A substance); or 1,000 L or 1,000 kg (for a
HSNO 8.3A, 9.1B or 9.1C substance); or 10,000 L or 10,000 kg (for a HSNO
6.1D or 9.1D substance)
SECTION 16: Other information
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
__________________________________________________________________________________________
Page: 9 of 10
Revision information:
Section 1: Product identification numbers information was modified.
Section 1: Product name information was modified.
Section 5: Fire - Extinguishing media information information was modified.
Section 8: Personal Protection - Skin/hand information information was modified.
Section 8: Skin protection - recommended gloves information information was deleted.
Section 8: Skin protection - recommended gloves text information was deleted.
Section 9: Property description for optional properties information was modified.
Section 10: Hazardous decomposition or by-products table information was modified.
Section 11: Aspiration Hazard text information was added.
Section 11: Health Effects - Ingestion information information was modified.
Section 11: Respiratory Sensitization text information was added.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Skin Sensitization text information was added.
Section 11: Specific Target Organ Toxicity - single exposure text information was added.
Prints No Data if Bioccumulative potential information is not present information was deleted.
Prints No Data if Persistence and Degradability information is not present information was deleted.
Section 14: Class/Div Group 2 information was added.
Section 14: IERG Group 1 information was added.
Section 14: IERG Group 2 information was added.
Section 14: Marine Pollutant Technical Name information was added.
Section 14: Packing Group Group 1 information was added.
Section 14: Packing Group Group 2 information was added.
Section 14: Special Instructions ADG Group 1 information was added.
Section 14: Special Instructions Group 2 information was added.
Section 14: Special Instructions IATA Group 1 information was added.
Section 14: Special Instructions IATA Group 2 information was added.
Section 14: Special Instructions IMDG Group 1 information was added.
Section 14: Special Instructions IMDG Group 2 information was added.
Section 14: Transport Class/Div Group 1 information was added.
Section 14: Transportation information information was deleted.
Section 14: Transportation Sub Risk Group 1 information was added.
Section 14: Transportation Sub Risk Group 2 information was added.
Section 14: UN Number IATA Group 1 information was added.
Section 14: UN Number IATA Group 2 information was added.
Section 14: UN Number information was added.
Section 14: UN Proper Shipping Name Group 1 information was added.
Section 14: UN Proper Shipping Name Group 2 information was added.
Section 14: UN Proper Shipping Name IATA Group 1 information was added.
Section 14: UN Proper Shipping Name IATA Group 2 information was added.
The information in this Safety Data Sheet (SDS) is believed to be correct as of the date of issue. TO THE EXTENT
PERMITTED BY LAW, 3M MAKES NO WARRANTY, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED
TO, ANY IMPLIED WARRANTY, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR
COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit
for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the
user evaluates the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or
application. 3M provides information in electronic form as a service to customers. Due to the remote possibility of electronic
transfer may have resulted in errors, omissions or alterations in this information; 3M makes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from 3M.
3M New Zealand SDS are available at 3M New Zealand Website: http://solutions.3mnz.co.nz
3M™ Glass Bubbles HGS750, HGS2000, HGS3000, HGS4000, HGS5000, HGS6000, HGS8000X, HGS10000, HGS18000,
HGS4K28, HGS19K46
__________________________________________________________________________________________
Page: 10 of 10
SAFETY DATA SHEET
ACPC11340A
1 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : ACPC11340A
Other means of identification : Not applicable.
Recommended use : PARAFFIN AND/OR ASPHALTENE CHEMICAL
Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.
Company : Ecolab New Zealand T/A Nalco New Zealand 2 Daniel Place Te Rapa, Hamilton New Zealand TEL: +64 7 958 2319 FAX: +64 7 958 2361
Emergency telephone number
: 0800 625 253, +64 7 958 2372 (International)
Issuing date : 23.09.2018
Section: 2. HAZARDS IDENTIFICATION
HSNO Hazard classification
Flammable Liquids : 3.1 D Acute toxicity (Oral) : 6.1 E Skin irritation : 6.3 A Eye irritation : 6.4 A GHS Label element
Hazard pictograms :
Signal Word : Danger
Hazard Statements : Combustible liquid
May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see supplemental first aid instructions on this label). Storage: Store in a well-ventilated place. Disposal:
SAFETY DATA SHEET
ACPC11340A
2 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018
Dispose of contents/ container to an approved waste disposal plant.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Concentration: (%)
Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, < 2% aromatics
64742-48-9 60 - 100
Phosphoric ester salt Proprietary 10 - 30 2-Butoxyethanol 111-76-2 5 - 10
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists.
If swallowed : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Aspiration hazard if swallowed - can enter lungs and cause damage. Get medical attention immediately.
If inhaled : Get medical attention if symptoms occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms and effects, both acute and delayed
: See Section 11 for more detailed information on health effects and symptoms.
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Foam
Carbon dioxide Dry powder Other extinguishing agent suitable for Class B fires For large fires, use water spray or fog, thoroughly drenching the burning material.
Unsuitable extinguishing media
: None known.
Specific hazards during firefighting
: Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance.
Hazardous combustion products
: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Oxides of phosphorus
Special protective equipment for firefighters
: Use personal protective equipment.
SAFETY DATA SHEET
ACPC11340A
3 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018
Specific extinguishing methods
: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
: Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up
: Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Avoid contact with skin and eyes. Take necessary action to avoid static
electricity discharge (which might cause ignition of organic vapours). Keep away from fire, sparks and heated surfaces. Wash hands thoroughly after handling.
Conditions for safe storage : Keep away from heat and sources of ignition. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.
Suitable material : Keep in properly labelled containers.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible concentration
Basis
2-Butoxyethanol 111-76-2 WES-TWA 25 ppm 121 mg/m3
NZ OEL
2-Butoxyethanol 111-76-2 TWA 20 ppm ACGIH
TWA 5 ppm 24 mg/m3
NIOSH REL
TWA 50 ppm 240 mg/m3
OSHA Z1
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards. Personal protective equipment Eye protection : Safety goggles
Face-shield
Hand protection : Wear the following personal protective equipment: Standard glove type. Nitrile gloves
SAFETY DATA SHEET
ACPC11340A
4 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018
Butyl gloves Breakthrough time: 1 – 4 hours Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Wear suitable protective clothing.
Respiratory protection : No personal respiratory protective equipment normally required.
Refer to AS/NZS 1715 and AS/NZS 1716 for selection, use and maintenance of respiratory protective equipment as applicable.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Colour : clear colourless
Odour : hydrocarbon-like
Flash point : > 62 °C, Method: Pensky-Martens closed cup
pH : 5 - 6, (20 °C)
Odour Threshold : no data available
Melting point/freezing point : pour point: < -30 °C
Initial boiling point and boiling range
: 179 - 214 °C, Solvent
Evaporation rate : 0.04, (BuAc = 1) Based on solvent
Flammability (solid, gas) : no data available
Upper explosion limit : 6 V%, Based on solvent
Lower explosion limit : 0.7 V%
Vapour pressure : 30 - 93 hPa, Based on solvent
Relative vapour density : not determined
Relative density : 0.805 - 0.835, (20 °C),
Density : 0.803 - 0.834 g/cm3
Water solubility : emulsifiable
Solubility in other solvents : no data available
Partition coefficient: n-octanol/water
: Not applicable.
Auto-ignition temperature : 235 - 315 °C
Thermal decomposition : no data available
Viscosity, dynamic : < 10 mPa.s (20 °C)
Viscosity, kinematic : no data available
Molecular weight : no data available
VOC : no data available
SAFETY DATA SHEET
ACPC11340A
5 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018
Section: 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions. Possibility of hazardous reactions
: No dangerous reaction known under conditions of normal use.
Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products
: Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Oxides of phosphorus
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
: Inhalation, Eye contact, Skin contact
Potential Health Effects Eyes : Causes serious eye irritation. Skin : Causes skin irritation. Ingestion : May be fatal if swallowed and enters airways. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Pain, Irritation Skin contact : Redness, Irritation Ingestion : Vomiting Inhalation : No symptoms known or expected. Toxicity Product
Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: > 40 mg/l Exposure time: 4 h Test atmosphere: vapour
Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg
Skin corrosion/irritation : no data available
Serious eye damage/eye irritation
: no data available
Respiratory or skin : no data available
SAFETY DATA SHEET
ACPC11340A
6 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018
sensitization
Carcinogenicity : No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive effects : No toxicity to reproduction
Germ cell mutagenicity : Contains no ingredient listed as a mutagen
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : May be fatal if swallowed and enters airways.
Human Hazard Characterization
Based on our hazard characterization, the potential human hazard is: High
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects.
Product
Toxicity to fish : no data available
Toxicity to daphnia and other aquatic invertebrates
: no data available
Toxicity to algae : no data available
Components
Toxicity to fish : 2-Butoxyethanol LC50 : 1,474 mg/l Exposure time: 96 h
Components
Toxicity to daphnia and other aquatic invertebrates
: 2-Butoxyethanol EC50 : 690 mg/l Exposure time: 48 h
Components
Toxicity to algae : 2-Butoxyethanol EC50 : 911 mg/l Exposure time: 72 h
Components
Toxicity to bacteria : 2-Butoxyethanol 463 mg/l
Components
Toxicity to fish (Chronic toxicity)
: 2-Butoxyethanol NOEC: > 100 mg/l Exposure time: 21 d
SAFETY DATA SHEET
ACPC11340A
7 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018
Components
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)
: 2-Butoxyethanol NOEC: > 100 mg/l Exposure time: 21 d
Persistence and degradability no data available Mobility no data available Bioaccumulative potential no data available Other information no data available ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be
taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport Proper shipping name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION Air transport (IATA) Proper shipping name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION Sea transport (IMDG/IMO) Proper shipping name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
Section: 15. REGULATORY INFORMATION
GROUP STANDARD NAME : Additives, Process Chemicals and Raw Materials
SAFETY DATA SHEET
ACPC11340A
8 / 8 First issue: 14.06.2018 Version Number: 1.1 Date issued: 23.09.2018
(Combustible) Group Standard 2017 HSNO APPROVAL NUMBER
: HSR002490
INTERNATIONAL CHEMICAL CONTROL LAWS : United States TSCA Inventory This product contains a substance not found on the TSCA 8(b) Inventory List and can only be used under the TSCA 5(h)(3) Research Exemption. Use must be supervised by a technically qualified individual. Canadian Domestic Substances List (DSL) This product contains one or several components that are not on the Canadian DSL nor NDSL. Australia. Industrial Chemical (Notification and Assessment) Act Not in compliance with the inventory New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals. China Inventory of Existing Chemical Substances Not in compliance with the inventory
Section: 16. OTHER INFORMATION
Revision Date : 23.09.2018 Version Number : 1.1 Prepared By : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
SAFETY DATA SHEET
AS-5 ANTI-SLUDGING AGENT
Revision Date: 01-Jun-2018 Revision Number: 33
1. Identification
Product Name Product Trade Name: AS-5 ANTI-SLUDGING AGENT
Other Names Synonyms None
Hazardous Material Number: HM000078
Recommended Use Recommended Use Anti-sludging Agent
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 3.1C Flammable Liquids - Medium hazard6.1D (Oral) Substances that are acutely toxic - Harmful6.3A Irritating to the skin8.3A Corrosive to ocular tissue9.1D Slightly harmful in the aquatic environment9.3C Harmful to terrestrial vertebrates
Hazard and Precautionary Statements
Hazard Pictograms
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_____________________________________________________________________________________________AS-5 ANTI-SLUDGING AGENT Revision Date: 01-Jun-2018
Signal Word Danger
Hazard Statements H226 - Flammable liquid and vaporH302 - Harmful if swallowedH315 - Causes skin irritationH318 - Causes serious eye damageH401 - Toxic to aquatic lifeH433 - Harmful to the terrestrial vertebrates.
Precautionary Statements
Prevention P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignitionsources. No smoking.P233 - Keep container tightly closedP240 - Ground and bond container and receiving equipment.P241 - Use explosion-proof electrical/ventilating/lighting/equipmentP242 - Use only non-sparking toolsP243 - Take action to prevent static discharges.P264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/eye protection/face protection
Response P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water [or shower].P370 + P378 - In case of fire: Use water spray for extinctionP301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP331 - Do NOT induce vomitingP302 + P352 - IF ON SKIN: Wash with plenty of water.P332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Storage P403 + P235 - Store in a well-ventilated place. Keep cool
Disposal P501 - Dispose of contents/container to an approved incineration plant
Contains
Substances CAS Number Substance HSNO Classification
C10-C16 Alkylbenzenesulfonic acid 68584-22-5 Not applicable
Benzene, C10-16 alkyl derivatives 68648-87-3 Not applicable
Isopropanol 67-63-0 3.1B6.1E (oral)6.3B6.4A
Sulfuric acid 7664-93-9 6.1D (Inhalation6.1E (Oral)6.7A8.2B6.9A
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8.1A8.2B8.3A9.1C (Crustacean)9.1D (Fish)
2.3. Other Hazards None known
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)C10-C16 Alkylbenzenesulfonic acid 68584-22-5 60 - 100%Benzene, C10-16 alkyl derivatives 68648-87-3 1 - 5%Isopropanol 67-63-0 10 - 30%Sulfuric acid 7664-93-9 1 - 5%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 30 minutes.Remove contact lenses after the first 5 minutes and continue washing. Seek immediatemedical attention/advice. Suitable emergency eye wash facility should be immediatelyavailable
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 30minutes and remove contaminated clothing, shoes and leather goods immediately. Getmedical attention immediately.
Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconsciousperson. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes severe skin irritation with tissue destruction. May causerespiratory irritation. May cause headache, dizziness, and other central nervous system effects. Harmful if swallowed.Carcinogen.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardFlammable Liquid
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsDo NOT spray pool fires directly with water. A solid stream of water directed into hot burning liquid can cause splattering.
HAZCHEM Code Hazchem Code: 2YE
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
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Special exposure hazards in a fire
_____________________________________________________________________________________________AS-5 ANTI-SLUDGING AGENT Revision Date: 01-Jun-2018
Decomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use appropriate protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Removesources of ignition. Take precautionary measures against static discharges All equipment used when handling the productmust be grounded Avoid contact with skin, eyes and clothing.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeledcontainers. Remove ignition sources and work with non-sparking tools.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsDo not breathe dust/fume/gas/mist/vapors/spray. Ensure adequate ventilation. Use appropriate protective equipment. Removesources of ignition. Ground and bond containers when transferring from one container to another. Avoid contact with eyes,skin, or clothing.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool well ventilated area. Keep from heat, sparks, and open flames.
Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 5 (oxidisers, organic peroxides)
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAC10-C16 Alkylbenzenesulfonicacid
68584-22-5 Not applicable Not applicable
Benzene, C10-16 alkylderivatives
68648-87-3 Not applicable Not applicable
Isopropanol 67-63-0 TWA: 400 ppmTWA: 983 mg/m3
STEL: 500 ppmSTEL: 1230 mg/m3
TWA: 200 ppmSTEL: 400 ppm
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_____________________________________________________________________________________________AS-5 ANTI-SLUDGING AGENT Revision Date: 01-Jun-2018
Sulfuric acid 7664-93-9 TWA: 1 mg/m3 TWA: 0.2 mg/m3
Engineering Controls Engineering Controls Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Nitrile gloves. (>= 0.4 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.
Skin Protection Rubber apron. Wear impervious protective clothing, including boots, gloves, lab coat,apron, rain jacket, pants or coverall, as appropriate, to prevent skin contact.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 0.98 - 1.98 (10% in 1:1 IPA:H2O)
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point 35 °C / 95 °F PMCC
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 0.998 - 1.023
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
Liquid Density 8.32 - 8.53 lbs/gal
Bulk Density 998 - 1023 kg/m3
10. Stability and Reactivity
10.2. Chemical stability Stable
Physical State: Liquid Color Clear Light Amber to Dark Amber
Odor: Alcohol Odor Threshold: No information available
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_____________________________________________________________________________________________AS-5 ANTI-SLUDGING AGENT Revision Date: 01-Jun-2018
10.4. Conditions to avoid Keep away from heat, sparks and flame.
10.5. Incompatible materials Strong oxidizers.
Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 5 (oxidisers, organic peroxides)
10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Product Information Under certain conditions of use, some of the product ingredients may cause thefollowing:
Inhalation May cause respiratory irritation. May cause central nervous system depression includingheadache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,giddiness and unconsciousness.
Eye Contact Causes serious eye damage.
Skin Contact Causes severe burns.
Ingestion Harmful if swallowed. Causes burns of the mouth, throat and stomach.
Chronic Effects/Carcinogenicity Contains known or suspected carcinogens.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
C10-C16Alkylbenzenesulfonicacid
68584-22-5 530 mg/kg (Rat)775 mg/kg (Rat)
1350 mg/kg (Rat)1470 mg/kg (Rat) (similar
substance)
530 mg/kg (Rat)2000 mg/kg (Rabbit)
No data available
Benzene, C10-16 alkylderivatives
68648-87-3 >5000 mg/kg-bw (rat) 10200 mg/kg-bw (rabbit) 71 mg/L (rat, 4h, aerosol)(similar substance)
Isopropanol 67-63-0 5840 mg/kg-bw (rat) 12870 mg/kg-bw (rabbit) 72.6 mg/L (Rat, 4h, vapor)
Sulfuric acid 7664-93-9 2140 mg/kg-bw (rat) No data available No data available
Substances CASNumber
Skin corrosion/irritation
C10-C16Alkylbenzenesulfonic acid
68584-22-5 Skin, rabbit: Causes burns
Benzene, C10-16 alkylderivatives
68648-87-3 Non-irritating to the skin (Rabbit) (similar substances)
Isopropanol 67-63-0 Non-irritating to the skin (Rabbit)
Sulfuric acid 7664-93-9 Causes severe burns
Substances CASNumber
Serious eye damage/irritation
C10-C16Alkylbenzenesulfonic acid
68584-22-5 Eye, rabbit: Causes eye burns
Benzene, C10-16 alkylderivatives
68648-87-3 Non-irritating to the eye (Rabbit) (similar substances)
Isopropanol 67-63-0 Causes moderate eye irritation (Rabbit)
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_____________________________________________________________________________________________AS-5 ANTI-SLUDGING AGENT Revision Date: 01-Jun-2018
Sulfuric acid 7664-93-9 Causes serious eye damage
Substances CASNumber
Skin Sensitization
C10-C16Alkylbenzenesulfonic acid
68584-22-5 Did not cause sensitization on laboratory animals (guinea pig)
Benzene, C10-16 alkylderivatives
68648-87-3 Did not cause sensitization on humans or laboratory animals. (guinea pig) (similar substances)
Isopropanol 67-63-0 Did not cause sensitization on laboratory animals (guinea pig)
Sulfuric acid 7664-93-9 Not regarded as a sensitizer.
Substances CASNumber
Respiratory Sensitization
C10-C16Alkylbenzenesulfonic acid
68584-22-5 No information available
Benzene, C10-16 alkylderivatives
68648-87-3 No information available
Isopropanol 67-63-0 No information available
Sulfuric acid 7664-93-9 Based on available data, the classification criteria are not met.
Substances CASNumber
Mutagenic Effects
C10-C16Alkylbenzenesulfonic acid
68584-22-5 In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects.
Benzene, C10-16 alkylderivatives
68648-87-3 In vivo tests did not show mutagenic effects. In vitro tests did not show mutagenic effects
Isopropanol 67-63-0 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
Sulfuric acid 7664-93-9 Based on available data, the classification criteria are not met.
Substances CASNumber
Carcinogenic Effects
C10-C16Alkylbenzenesulfonic acid
68584-22-5 No information available
Benzene, C10-16 alkylderivatives
68648-87-3 No information available
Isopropanol 67-63-0 Did not show carcinogenic effects in animal experiments
Sulfuric acid 7664-93-9 This substance is a potential carcinogen. (IARC 1).
Substances CASNumber
Reproductive toxicity
C10-C16Alkylbenzenesulfonic acid
68584-22-5 No data of sufficient quality are available.
Benzene, C10-16 alkylderivatives
68648-87-3 No information available
Isopropanol 67-63-0 Animal testing did not show any effects on fertility.
Sulfuric acid 7664-93-9 Did not show teratogenic effects in animal experiments.
Substances CASNumber
STOT - single exposure
C10-C16Alkylbenzenesulfonic acid
68584-22-5 May cause respiratory irritation.
Benzene, C10-16 alkylderivatives
68648-87-3 No information available
Isopropanol 67-63-0 May cause headache, dizziness, and other central nervous system effects.
Sulfuric acid 7664-93-9 May cause respiratory irritation.
Substances CASNumber
STOT - repeated exposure
C10-C16Alkylbenzenesulfonic acid
68584-22-5 No data of sufficient quality are available.
Benzene, C10-16 alkylderivatives
68648-87-3 No information available
Isopropanol 67-63-0 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Sulfuric acid 7664-93-9 Not applicable due to corrosivity of the substance.
Substances CASNumber
Aspiration hazard
C10-C16Alkylbenzenesulfonic acid
68584-22-5 Not applicable
Benzene, C10-16 alkylderivatives
68648-87-3 Not applicable
Isopropanol 67-63-0 Not applicable
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Sulfuric acid 7664-93-9 Based on available data, the classification criteria are not met.
12. Ecological Information
12.1. Toxicity Ecotoxicity effectsVery toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
C10-C16Alkylbenzenesulfonicacid
68584-22-5 EC50 (96h) 170 mg/L(Selenastrum
capricornutum)
LC50 (96h) 3 mg/L(Oncorhynchus mykiss)NOEC (90d) 0.25 mg/L(Tilapia mossambica)
(similar substance)
No information available EC50 (48h) 2.9 mg/L(Daphnia magna)
EC50 (24h) 5.9 mg/L(Daphnia magna)
Benzene, C10-16alkyl derivatives
68648-87-3 EC50 (96 h) >1000 mg/L(Pseudokirchneriella
subcapitata)
LC50 (96h) >1000 mg/L(Oncorhynchus mykiss)
No information available EC50 (48h) 0.01 mg/L(Daphnia magna)
MATC (21d) 0.075 mg/L(Daphnia magna)
Isopropanol 67-63-0 EC50 (72h) > 1000 mg/L(Desmodesmus
subspicatus)EC50 (7d) 1800 mg/L
(meanextinctionvalue)(Scenedesmus
quadricauda)
LC50 (96h) 9640 mg/L(Pimephales promelas)LC50 (7d) 7060 mg/L(Poecilia reticulata)
TT (16h) 1050 mg/L(Pseudomonas putida)
EC50 (48 h)=2285 mg/L(Daphnia sp.)
EC50 (24h) > 10,000mg/L (Daphnia magna)
Sulfuric acid 7664-93-9 No information available LC50 (96 h) 16 mg/L(Lepomis macrochirus)LC50 (96 h) 42 mg/L(Gambusia affinis)
No information available EC50 (24 h) 29 mg/L(Daphnia magna)
EC50 (48 h) 42.5 mg/L(Pandalus montagui)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
C10-C16 Alkylbenzenesulfonic acid 68584-22-5 (94% @ 28d)
Benzene, C10-16 alkyl derivatives 68648-87-3 Readily biodegradable (60% @ 28d)
Isopropanol 67-63-0 Readily biodegradable (53% @ 5d)
Sulfuric acid 7664-93-9 Readily biodegradable
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
C10-C16 Alkylbenzenesulfonic acid 68584-22-5 Log Pow = 4.15
Benzene, C10-16 alkyl derivatives 68648-87-3 7.94BCF = 35
Isopropanol 67-63-0 Not Bioaccumulative; LogPow < 4.5
Sulfuric acid 7664-93-9 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
C10-C16 Alkylbenzenesulfonic acid 68584-22-5 No information available
Benzene, C10-16 alkyl derivatives 68648-87-3 No information available
Isopropanol 67-63-0 No information available
Sulfuric acid 7664-93-9 No information available
Ecotoxicity Hazard Statements Toxic to aquatic lifeHarmful to terrestrial vertebrates.
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
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13. Disposal Considerations
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13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Contaminated packaging may be disposed of by: rendering packaging incapable ofcontaining any substance, or treating packaging to remove residual contents, or treatingpackaging to make sure the residual contents are no longer hazardous, or by disposingof packaging into commercial waste collection.
14. Transport Information
NZ 5433.1999 UN Number UN2924
UN proper shipping name: Flammable Liquid, Corrosive, N.O.S. (Contains Isopropanol, DodecylbenzenesulfonicAcid)
Transport Hazard Class(es): 3 (8)
Packing Group: III
Environmental Hazards: Marine Pollutant
IMDG/IMO UN Number UN2924
UN proper shipping name: Flammable Liquid, Corrosive, N.O.S. (Contains Isopropanol, DodecylbenzenesulfonicAcid)
Transport Hazard Class(es): 3 (8)
Packing Group: III
Environmental Hazards: Marine Pollutant
EMS: EmS F-E, S-C
IATA/ICAO UN Number UN2924
UN proper shipping name: Flammable Liquid, Corrosive, N.O.S. (Contains Isopropanol, DodecylbenzenesulfonicAcid)
Transport Hazard Class(es): 3 (8)Packing Group: III
Environmental Hazards: Marine Pollutant
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002495
Group Name Additives, Process Chemicals and Raw Materials (Flammable HSR002495)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers This product does NOT require an approved handler.
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%
_____________________________________________________________________________________________AS-5 ANTI-SLUDGING AGENT Revision Date: 01-Jun-2018
LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 01-Jun-2018
Revision NoteSDS sections updated:1
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
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SAFETY DATA SHEET
BARACARB® 50
1. Product and Company Identification
Product Name Product Trade Name: BARACARB® 50
Other Names Synonyms: None
Product Code: HM003488
Recommended Use Recommended Use Bridging Agent
Uses Advised Against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-Mail address: fdunexchem@halliburton.com
Emergency Telephone Number +64-6-7559274
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.4A Irritating to the eye6.7A Known or presumed human carcinogens6.9A Toxic to human target organs or systems
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Danger
Hazard Statements H319 - Causes serious eye irritationH350 - May cause cancer by inhalation
Precautionary Statements
Prevention P103 - Read label before useP104 - Read Safety Data Sheet before use.
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Revision Date: 22-Jun-2015 Revision Number: 23
_____________________________________________________________________________________________P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/protective clothing/eye protection/face protectionP281 - Use personal protective equipment as required
Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attentionP308 + P313 - IF exposed or concerned: Get medical advice/attention
Storage P405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
Contains
Substances CAS Number Substance HSNO Classification
Calcium carbonate 471-34-1 6.4A
Crystalline silica, quartz 14808-60-7 6.7A6.9A
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)
Calcium carbonate 471-34-1 60 - 100%
Crystalline silica, quartz 14808-60-7 0.1 - 1%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also beenassociated with scleroderma and kidney disease.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasons
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BARACARB® 50 Revision Date: 26-Jun-2015
_____________________________________________________________________________________________None known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special Exposure HazardsNot applicable.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. This product contains quartz, cristobalite, and/ortridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use onlywith adequate ventilation to keep exposure below recommended exposure limits. Wear a NIOSH certified, European StandardEn 149, or equivalent respirator when using this product. Material is slippery when wet.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers If more than 10 kg (Class 6) is present, then an approved handler must be present when the substance is being handled andwhen not in use, the substance must be locked away.
7.2. Conditions for safe storage, including any incompatibilities Store away from acids. Store in a cool, dry location. Use good housekeeping in storage and work areas to preventaccumulation of dust. Close container when not in use. Do not reuse empty container. Product has a shelf life of 60 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWA
Calcium carbonate 471-34-1 TWA: 10 mg/m3 10 mg/m3
Crystalline silica, quartz 14808-60-7 TWA: 0.2 mg/m3 TWA: 0.025 mg/m3
Engineering Controls Engineering Controls Use in a well ventilated area. Use approved industrial ventilation and local exhaust as
required to maintain exposures below applicable exposure limits.
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BARACARB® 50 Revision Date: 26-Jun-2015
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Personal Protective Equipment (PPE) Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, or
equivalent respirator when using this product.
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be launderedbefore reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 8-9
Freezing Point/Range No data available
Melting Point/Range No data available
Boiling Point/Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 2.7
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical Stability Stable
10.4. Conditions to Avoid None anticipated
10.5. Incompatible Materials Strong acids.
10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide. Amorphous silica may transform at elevated temperatures to tridymite (870 C) orcristobalite (1470 C).
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
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Odorless
Revision Date: 26-Jun-2015
Odor Threshold: No information availablePhysical State: Solid Powder Color: White
BARACARB® 50
Odor:
_____________________________________________________________________________________________
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources iscarcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanentlung damage may be occurring. Inhalation of dust may also have serious chronic healtheffects (See "Chronic Effects/Carcinogenicity" subsection below).
Eye Contact May cause mechanical irritation to eye.
Skin Contact May cause mechanical skin irritation.
Ingestion None known.
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis. Symptomsinclude cough, shortness of breath, wheezing, non-specific chest illness, and reducedpulmonary function. This disease is exacerbated by smoking. Individuals with silicosisare predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimental animals forthe carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer toIARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) inconjunction with the use of these minerals. The National Toxicology Program classifiesrespirable crystalline silica as "Known to be a human carcinogen". Refer to the 9thReport on Carcinogens (2000). The American Conference of Governmental IndustrialHygienists (ACGIH) classifies crystalline silica, quartz, as a suspected humancarcinogen (A2).
There is some evidence that breathing respirable crystalline silica or the disease silicosisis associated with an increased incidence of significant disease endpoints such asscleroderma (an immune system disorder manifested by scarring of the lungs, skin, andother internal organs) and kidney disease.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Calcium carbonate 471-34-1 6450 mg/kg (Rat)> 2000 mg/kg (Rat)
> 2000 mg/kg (Rat) > 3 mg/L (Rat) 4h
Crystalline silica, quartz 14808-60-7 >15,000 mg/kg (Human) No data available No data available
Substances CASNumber
Skin corrosion/irritation
Calcium carbonate 471-34-1 Non-irritating to the skin (Rabbit)
Crystalline silica, quartz 14808-60-7 Non-irritating to the skin
Substances CASNumber
Eye damage/irritation
Calcium carbonate 471-34-1 Non-irritating to the eye (Rabbit)
Crystalline silica, quartz 14808-60-7 Mechanical irritation of the eyes is possible.
Substances CASNumber
Skin Sensitization
Calcium carbonate 471-34-1 Did not cause sensitization on laboratory animals (mouse)
Crystalline silica, quartz 14808-60-7 No information available.
Substances CASNumber
Respiratory Sensitization
Calcium carbonate 471-34-1 No information available
Crystalline silica, quartz 14808-60-7 No information available
Substances CASNumber
Mutagenic Effects
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BARACARB® 50 Revision Date: 26-Jun-2015
_____________________________________________________________________________________________Calcium carbonate 471-34-1 In vitro tests did not show mutagenic effects
Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Substances CASNumber
Carcinogenic Effects
Calcium carbonate 471-34-1 No information available.
Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondaryto lung injury.
Substances CASNumber
Reproductive toxicity
Calcium carbonate 471-34-1 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.
Crystalline silica, quartz 14808-60-7 No information available
Substances CASNumber
STOT - single exposure
Calcium carbonate 471-34-1 No significant toxicity observed in animal studies at concentration requiring classification.
Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
STOT - repeated exposure
Calcium carbonate 471-34-1 No significant toxicity observed in animal studies at concentration requiring classification.
Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CASNumber
Aspiration hazard
Calcium carbonate 471-34-1 Not applicable
Crystalline silica, quartz 14808-60-7 Not applicable
12. Ecological Information
12.1. Toxicity Ecotoxicity Effects
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Calcium carbonate 471-34-1 EC50(72h): > 14 mg/L(growth rate)
(Desmodesmussubspicatus)
LC50(96h): > 100 mg/L(saturated solution)
(Oncorhynchus mykiss)
EC50(3h): > 1000 mg/L(Activated sludge)
EC50(48h): > 100 mg/L(saturated solution)(Daphnia magna)
Crystalline silica,quartz
14808-60-7 No information available LL0 (96h) 10,000 mg/L(Danio rerio) (similar
substance)
No information available LL50 (24h) > 10,000mg/L (Daphnia magna)
(similar substance)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Calcium carbonate 471-34-1 The methods for determiningbiodegradability are not applicable toinorganic substances.
Crystalline silica, quartz 14808-60-7 No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Calcium carbonate 471-34-1 No data available
Crystalline silica, quartz 14808-60-7 No data available
12.4. Mobility in soil
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BARACARB® 50 Revision Date: 26-Jun-2015
_____________________________________________________________________________________________Substances CAS Number Mobility
Calcium carbonate 471-34-1 No information available
Crystalline silica, quartz 14808-60-7 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
IMDG/IMO UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User: None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
HSNO Approval Number HSR002512
Group Name Additives, Process Chemicals and Raw Materials (Toxic 6.7 HSR002512)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers If more than 10 kg (Class 6) is present, then an approved handler must be present whenthe substance is being handled and when not in use, the substance must be lockedaway.
Poisons Schedule: None Allocated
16. Other information
The following sections have been revised since the last issue of this SDSNot applicable
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Revision Date: 26-Jun-2015BARACARB® 50
_____________________________________________________________________________________________
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 26-Jun-2015
Revision Note Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
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Revision Date: 26-Jun-2015BARACARB® 50
SAFETY DATA SHEET
BARACOR® 100
Revision Date: 14-Jul-2016 Revision Number: 53
1. Product and Company Identification
Product Name Product Trade Name: BARACOR® 100
Other Names Synonyms None
Hazardous Material Number: HM003391
Recommended Use Recommended Use Corrosion Inhibitor
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number: +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 3.1C Flammable Liquids - Medium hazard6.1D (Oral) Acutely Toxic Substances6.1D (Dermal) Acutely Toxic Substances8.2C Corrosive to dermal tissue if exposed for greater than 1 hour8.3A Corrosive to ocular tissue6.7B Suspected human carcinogens6.9A Toxic to human target organs or systems9.3C Harmful to terrestrial vertebrates
Hazard and Precautionary Statements
Hazard Pictograms
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_____________________________________________________________________________________________BARACOR® 100 Revision Date: 14-Jul-2016
Signal Word Danger
Hazard Statements H226 - Flammable liquid and vaporH302 - Harmful if swallowedH312 - Harmful in contact with skinH314 - Causes severe skin burns and eye damageH318 - Causes serious eye damageH351 - Suspected of causing cancerH361 - Suspected of damaging fertility or the unborn childH370 - Causes damage to organsH433 - Harmful to the terrestrial vertebrates.
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP210 - Keep away from heat/sparks/open flames/hot surfaces. - No smokingP233 - Keep container tightly closedP240 - Ground/Bond container and receiving equipmentP241 - Use explosion-proof electrical/ventilating/lighting/equipmentP242 - Use only non-sparking toolsP243 - Take precautionary measures against static dischargeP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/eye protection/face protectionP281 - Use personal protective equipment as required
Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP331 - Do NOT induce vomitingP303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water/showerP363 - Wash contaminated clothing before reuseP304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a positioncomfortable for breathingP310 - Immediately call a POISON CENTER or doctor/physicianP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing
Storage P403 + P235 - Store in a well-ventilated place. Keep coolP405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
Contains
Substances CAS Number Substance HSNO Classification
Ethanol, 2,2'-oxybis-, reaction products withammonia, morpholine derivatives residues
68909-77-3 6.1D (oral)8.2C 8.3A
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_____________________________________________________________________________________________BARACOR® 100 Revision Date: 14-Jul-2016
9.3C
Methanol 67-56-1 3.1B6.1C (Oral)6.1C (Dermal)6.1C (Inhalation)6.4A6.8B6.9A (Inhalation)9.3C
Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 6.1D (oral)6.1E (inhalation)6.7B8.2C8.3A; 9.3C
2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Ethanol, 2,2'-oxybis-, reaction products with ammonia,morpholine derivatives residues
68909-77-3 10 - 30%
Methanol 67-56-1 10 - 30%Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 1 - 5%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, move victim to fresh air and seek medical attention.
Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek promptmedical attention.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15minutes. Get medical attention. Remove contaminated clothing and launder beforereuse.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. Harmful ifswallowed. Potential carcinogen. Potential reproductive hazard. May cause birth defects. May cause damage to internalorgans.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardFlammable Liquid
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code
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_____________________________________________________________________________________________BARACOR® 100 Revision Date: 14-Jul-2016
Hazchem Code: 3WE
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireMay be ignited by heat, sparks or flames Use water spray to cool fire exposed surfaces. Closed containers may explode in fire.Decomposition in fire may produce harmful gases. Runoff to sewer may cause fire or explosion hazard.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Remove sources of ignition. Use appropriate protective equipment. Wear self-contained breathing apparatus in enclosedareas. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Evacuate all personsfrom the area.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. Consult local authorities.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Remove ignition sources and work with non-sparking tools. Contain spill with sand orother inert materials. Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsRemove sources of ignition. Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation.Wash hands after use. Launder contaminated clothing before reuse. Ground and bond containers when transferring from onecontainer to another. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container closed when not in use. Product has ashelf life of 24 months.
Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 6 (toxic)
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAEthanol, 2,2'-oxybis-, reaction 68909-77-3 Not applicable Not applicable
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_____________________________________________________________________________________________BARACOR® 100 Revision Date: 14-Jul-2016
products with ammonia,morpholine derivativesresidues
Methanol 67-56-1 TWA: 200 ppmTWA: 262 mg/m3
STEL: 250 ppmSTEL: 328 mg/m3
TWA: 200 ppmSTEL: 250 ppm
Nitrilotriacetic acid, trisodiumsalt monohydrate
5064-31-3 Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without
good cross ventilation.
Personal Protective Equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Positive pressure self-contained breathing apparatus if methanol is released.
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Neoprene gloves. Nitrile gloves. Butyl rubber gloves. (>= .? mmthickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.
Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 9-11
Freezing Point / Range -23 °C
Melting Point / Range No data available
Boiling Point / Range 100 °C / 212 °F
Flash Point 33 °C / 92 °F PMCC
Upper flammability limit 36%
Lower flammability limit 6%
Evaporation rate 1.6
Vapor Pressure No data available
Vapor Density > 1
Specific Gravity 1.01
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water -0.84
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information
Physical State: Liquid Color Brown
Odor: Alcohol Odor Threshold: No information available
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VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid Keep away from heat, sparks and flame.
10.5. Incompatible materials Strong oxidizers.
Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 6 (toxic)
10.6. Hazardous decomposition products Ammonia. Oxides of nitrogen. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause respiratory irritation. May cause central nervous system depression includingheadache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,giddiness and unconsciousness.
Eye Contact Causes severe eye irritation which may damage tissue.
Skin Contact Causes skin irritation. May cause an allergic skin reaction. May be absorbed through theskin.
Ingestion Harmful if swallowed.
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart, centralnervous system and spleen damage. Contains nitrilotriacetic acid or its salts, which isNTP Classification 2 (Reasonably Anticipated to be a Human Carcinogen) and IARCClassification 2B (a Possible Human Carcinogen)Prolonged or repeated exposure may cause embryo and fetus toxicity.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 3816 mg/kg-bw (rat) > 2000 mg/kg (Rat) No toxicity at saturation (rat, 8 h,vapour)
Methanol 67-56-1 300 mg/kg-bw (human)< 790 to 13,000 mg/kg (rat)
1000 mg/kg-bw (human)17,100 mg/kg (rabbit)
10 mg/L (human, vapor, 4h)
Nitrilotriacetic acid,trisodium saltmonohydrate
5064-31-3 1740 mg/kg (Rat) > 2000 mg/kg (Rabbit) > 5 mg/L (Rat, Aerosol, 4h)
Substances CASNumber
Skin corrosion/irritation
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 Causes moderate skin irritation. (Rabbit) Skin, rabbit:
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Methanol 67-56-1 Non-irritating to the skin (Rabbit)
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 Non-irritating to the skin (Rabbit) Not irritating to skin in rabbits. Skin, rabbit:
Substances CASNumber
Serious eye damage/irritation
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 Causes eye burns Causes severe eye irritation. Will damage tissue.
Methanol 67-56-1 Non-irritating to the eye (Rabbit)
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 Irritating to eyes (Rabbit) Eye, rabbit: Causes moderate eye irritation
Substances CASNumber
Skin Sensitization
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 May cause sensitization by skin contact (mouse)
Methanol 67-56-1 Did not cause sensitization on laboratory animals (guinea pig)
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 Did not cause sensitization on laboratory animals (guinea pig)
Substances CASNumber
Respiratory Sensitization
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 No information available
Methanol 67-56-1 No information available
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 No information available
Substances CASNumber
Mutagenic Effects
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
Methanol 67-56-1 The weight of evidence from available in vitro and in vivo studies indicates that this substance is notexpected to be mutagenic.
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 Not regarded as mutagenic. In vivo tests did not show mutagenic effects. In vitro tests did not showmutagenic effects
Substances CASNumber
Carcinogenic Effects
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 No information available
Methanol 67-56-1 No data of sufficient quality are available.
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 Contains nitrilotriacetic acid or its salts, which is listed as a suspect carcinogen of the urinary tractand kidneys by NTP, based on feeding studies with laboratory animals. According to the ACGIHguidelines, NTA would "not be considered an occupational carcinogen of any significance." IARCcancer review classification: 2B (Possibly Carcinogenic to Humans)Available data indicate that this substance is a suspected carcinogen.
Substances CASNumber
Reproductive toxicity
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.
Methanol 67-56-1 Experiments have shown reproductive toxicity effects on laboratory animals
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.
Substances CASNumber
STOT - single exposure
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 No significant toxicity observed in animal studies at concentration requiring classification.
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Methanol 67-56-1 May cause disorder and damage to the Central Nervous System (CNS)
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
STOT - repeated exposure
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 No significant toxicity observed in animal studies at concentration requiring classification.
Methanol 67-56-1 No data of sufficient quality are available.
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
Aspiration hazard
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 Not applicable
Methanol 67-56-1 Not applicable
Nitrilotriacetic acid,trisodium salt monohydrate
5064-31-3 Not applicable
12. Ecological Information
12.1. Toxicity Ecotoxicity effects
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Ethanol, 2,2'-oxybis-,reaction products withammonia, morpholinederivatives residues
68909-77-3 EC50 (72 h) =100 mg/L(Skeletonema costatum)EC50 (72 h) >120 mg/L
(Desmodesmussubspicatus)
NOEC (72 h) >120 mg/L(Desmodesmus
subspicatus)
LC50 (96 h) >100 mg/L(Scophthalmus
maximus)LC50 (96 h) =681.1 mg/L
(Leuciscus idus)
EC50 (3h) > 1000 mg/L(activated sludge)
LC50 (48 h) =287.2 mg/L(Acartia tonsa)
EC50 (48 h) >120 mg/L(Daphnia Magna)
Methanol 67-56-1 EC50 (96 h) =22000mg/L
(Pseudokirchnerellasubcapitata)
NOEC (8 d) =8000 mg/L(Scenedesmusquadricauda)
LC50 (96 h) =15400mg/L (Lepomismacrochirus)
EC50 (200 h) =14536mg/L (Oryzias latipes)
IC50 (3h) > 1000 mg/L(activated sludge)
EC50 (96 h) =18260mg/L (Dapnia magna)
NOEC (21 d) =208 mg/L(Dapnia magna)
Nitrilotriacetic acid,trisodium saltmonohydrate
5064-31-3 EC50 (72 h) >91.5 mg/L(Desmodesmus
subspicatus)
TL50 (96 h) =103 mg/L(Pimephales promelas)NOEC (229 d) >54 mg/L(Pimephales promelas)
NOEC (90d) >200 mg/L(activated sludge)
TL50 (96 h) range115mg/L (Gammaruspseudolimnaeus)
NOEC (147 d) =9.3 mg/L(Gammarus
pseudolimnaeus)
12.2. Persistence and degradability Not readily biodegradableSubstances CAS Number Persistence and Degradability
Ethanol, 2,2'-oxybis-, reaction products withammonia, morpholine derivatives residues
68909-77-3
Methanol 67-56-1 (95-97% @ 20d)
Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 Readily biodegradable (100% @ 14d)Marine water Persistent (6% @ 28d)
12.3. Bioaccumulative potential Does not bioaccumulate.
Substances CAS Number Log Pow
Ethanol, 2,2'-oxybis-, reaction products with 68909-77-3 Log Pow <1
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ammonia, morpholine derivatives residues
Methanol 67-56-1 -0.77BCF = 1.0 – 4.5 (Cyprinus carpio)
BCF < 10 (Leuciscus idus melanotus)
Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 -2.62 (calculated)
12.4. Mobility in soil
Substances CAS Number Mobility
Ethanol, 2,2'-oxybis-, reaction products with ammonia,morpholine derivatives residues
68909-77-3 No information available
Methanol 67-56-1 No information available
Nitrilotriacetic acid, trisodium salt monohydrate 5064-31-3 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
IMDG/IMO UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Methanol)
Transport Hazard Class(es): 3
Packing Group: III
Environmental Hazards: Not applicable
EMS: EmS F-E, S-E
NZ 5433.1999 UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Methanol)
Transport Hazard Class(es): 3
Packing Group: III
IATA/ICAO UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Methanol)
Transport Hazard Class(es): 3
Packing Group: III
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002497
Group Name Flammable, Corrosive, Toxic [6.7] (HSR002497)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
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Approved Handlers Not Applicable
Poisons Schedule: S6
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 14-Jul-2016
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
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SAFETY DATA SHEET
BARA-DEFOAM® HP
Revision Date: 11-Feb-2016 Revision Number: 17
1. Product and Company Identification
Product Name Product Trade Name: BARA-DEFOAM® HP
Other Names Synonyms: None
Product Code: HM003504
Recommended Use Recommended Use Defoamer
Uses Advised Against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-Mail address: fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1D (Oral) Acutely Toxic Substances6.4A (mild irritant) Irritating to the eye9.3C Harmful to terrestrial vertebrates
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Warning
Hazard Statements H302 - Harmful if swallowedH320 - Causes mild eye irritationH433 - Harmful to the terrestrial vertebrates.
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at hand
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P102 - Keep out of reach of childrenP103 - Read label before useP264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this product
Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attention
Storage None
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
Contains
Substances CAS Number Substance HSNO Classification
Oxylated polyether polyol Proprietary 6.4A
Polyether polyol Proprietary 6.1D (Oral)6.4A9.3C
2.3. Other Hazards None known
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Oxylated polyether polyol Proprietary 10 - 30%Polyether polyol Proprietary 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists. Removecontaminated clothing and launder before reuse.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media
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Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
_____________________________________________________________________________________________BARA-DEFOAM® HP Revision Date: 11-Feb-2016
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special Exposure HazardsAvoid spraying water directly into storage containers due to danger of boilover. Decomposition in fire may produce harmfulgases.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Keep floors clean of spills.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Keep container closed when not in use. Product has a shelf life of 36 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAOxylated polyether polyol Proprietary Not applicable Not applicable
Polyether polyol Proprietary Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of this
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product.
Respiratory Protection Not normally necessary.
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: No data available
Freezing Point/Range -15 °C
Melting Point/Range No data available
Boiling Point/Range No data available
Flash Point > 182 °C / > 357 °F PMCC
Evaporation rate No data available
Vapor Pressure < 0.01 mmHg
Vapor Density > 1
Specific Gravity 1
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical Stability Stable
10.4. Conditions to Avoid Keep away from heat, sparks and flame.
10.5. Incompatible Materials Strong oxidizers. Isocyanates. Strong acids.
10.6. Hazardous Decomposition Products Aldehydes. Ketones. Organic acid vapors. Hydrocarbons. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation Heated vapors may cause respiratory irritation.
Eye Contact May cause mild eye irritation.
Skin Contact Prolonged or repeated contact may cause skin irritation.
Ingestion None known.
Physical State: Liquid Color: Clear colorless to pale yellow
Odor: Mild sweet Odor Threshold: No information available
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Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Oxylated polyetherpolyol
Proprietary No data available No data available No data available
Polyether polyol Proprietary > 5000 mg/kg (Rat) (similarsubstances)
> 3000 mg/kg (Rabbit) > 2.34 mg/L (Rat) (similarsubstances)
12. Ecological Information
12.1. Toxicity Ecotoxicity Effects
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Oxylated polyetherpolyol
Proprietary No information available No information available No information available No information available
Polyether polyol Proprietary No information available LC50: > 100 mg/l(Poecilia reticulata)
No information available EC50: > 100 mg/l(Daphnia magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Oxylated polyether polyol Proprietary
Polyether polyol Proprietary Readily biodegradable
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Oxylated polyether polyol Proprietary No data available
Polyether polyol Proprietary 0.3 - 1.13
12.4. Mobility in soil
Substances CAS Number Mobility
Oxylated polyether polyol Proprietary No information available
Polyether polyol Proprietary No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
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13. Disposal Considerations
13.1. Waste treatment methods Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
IMDG/IMO UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User: None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002503
Group Name Additives, Process Chemicals and Raw Materials (Subsidiary hazard HSR002503)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
The following sections have been revised since the last issue of this SDSNot applicable
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronymsbw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% MARPOL – International Convention for the Prevention of Pollution fromShips mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – OccupationalExposure Limit ppm – parts per million TWA – Time-Weighted Average VOC – Volatile Organic Carbon C - Celsius IATA/ICAO- International Air Transport Association / International Civil Aviation Organization IMDG/IMO - International MaritimeDangerous Goods / International Maritime Organization mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimetermercury w/w - weight/weight d - day
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Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 11-Feb-2016
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
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SAFETY DATA SHEET
BARAKLEAN®-926
Revision Date: 15-Jun-2018 Revision Number: 3
1. Identification
Product Name Product Trade Name: BARAKLEAN®-926
Other Names Synonyms None
Hazardous Material Number: HM008654
Recommended Use Recommended Use Cleaner
Uses advised against Consumer use
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 3.1D Flammable Liquids - Low hazard6.1E (Oral) Acutely Toxic Substances6.1E (Aspiration Hazard) Acutely Toxic Substances6.3A Irritating to the skin6.9B Harmful to human target organs or systems8.3A Corrosive to ocular tissue
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Danger
Hazard Statements H227 - Combustible liquidH303 - May be harmful if swallowed
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H304 - May be fatal if swallowed and enters airwaysH315 - Causes skin irritationH318 - Causes serious eye damageH373 - May cause damage to organs through prolonged or repeated exposure
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignitionsources. No smoking.P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/protective clothing/eye protection/face protection
Response P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER ordoctor/physicianP331 - Do NOT induce vomitingP302 + P352 - IF ON SKIN: Wash with plenty of water.P332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP314 - Get medical attention/advice if you feel unwellP370 + P378 - In case of fire: Use CO2, dry chemical, or foam
Storage P403 + P235 - Store in a well-ventilated place. Keep coolP405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
Contains
Substances CAS Number Substance HSNO Classification
Hydrocarbons, C10-14 (even numbered),n-alkanes, isoalkanes, <2% aromatic
1174522-27-0 6.1E (asp)3.1D
Diethylene glycol monobutyl ether 112-34-5 3.1D6.1E (oral)6.1E (Dermal)6.3B6.4A6.9B (oral, Inhalation)
2-Ethyl hexanol 104-76-7 3.1D6.1D (Oral)6.1D (Dermal)6.1D (Inhalation)6.3A6.4A9.1D (Fish, Crustacean, Algae)9.3C
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 6.1E (oral)6.1E (dermal)6.3A8.3A9.1C
2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Hydrocarbons, C10-14 (even numbered), n-alkanes,isoalkanes, <2% aromatic
1174522-27-0 60 - 100%
Diethylene glycol monobutyl ether 112-34-5 10 - 30%2-Ethyl hexanol 104-76-7 5 - 10%Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 5 - 10%
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4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 30 minutes.Remove contact lenses after the first 5 minutes and continue washing. Seek immediatemedical attention/advice. Suitable emergency eye wash facility should be immediatelyavailable
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15minutes. Get medical attention.
Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconsciousperson. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. Aspiration into the lungs may cause chemicalpneumonitis including coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. May beharmful if swallowed May cause damage to organs through prolonged or repeated exposure
Medical Attention and Special Treatment Notes to PhysicianAspiration may cause severe lung damage. Evacuate stomach in a way which avoids aspiration.
5. Fire-fighting measures
Type of Hazard Flammability HazardCombustible liquid
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsDo NOT spray pool fires directly with water. A solid stream of water directed into hot burning liquid can cause splattering.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use appropriate protective equipment. Remove sources of ignition. Take precautionary measuresagainst static discharges All equipment used when handling the product must be grounded Avoid contact with skin, eyes andclothing.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeledcontainers. Remove ignition sources and work with non-sparking tools.
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6.4. Reference to other sections
_____________________________________________________________________________________________BARAKLEAN®-926 Revision Date: 15-Jun-2018
See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsEnsure adequate ventilation. Use appropriate protective equipment. Remove sources of ignition. Ground and bond containerswhen transferring from one container to another. Avoid contact with eyes, skin, or clothing.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool well ventilated area. Keep from heat, sparks, and open flames.
Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 5 (oxidisers, organic peroxides)
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAHydrocarbons, C10-14 (evennumbered), n-alkanes,isoalkanes, <2% aromatic
1174522-27-0 Not applicable Not applicable
Diethylene glycol monobutylether
112-34-5 Not applicable TWA: 10 ppm
2-Ethyl hexanol 104-76-7 Not applicable Not applicable
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 Not applicable Not applicable
Engineering Controls Engineering Controls Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.
Hand Protection Use gloves which are suitable for the chemicals present in this product as well as otherenvironmental factors in the workplace.
Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain jacket,pants or coverall, as appropriate, to prevent skin contact.
Eye Protection Safety glasses with side-shields. If splashes are likely to occur, wear: Goggles,
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_____________________________________________________________________________________________BARAKLEAN®-926 Revision Date: 15-Jun-2018
Face-shield.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 7.31
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point 82.2 °C / 179.9 °F
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 0.833 at 68F
Water Solubility Dispersible Emulsifies
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity 2.4 cSt
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid Keep away from heat, sparks and flame.
10.5. Incompatible materials Strong oxidizers. Strong acids. Strong alkalis.
Product is incompatible with: Class 1 (explosives)Class 2 (flammable gases, aerosols)Class 3.2 (liquid desensitised explosives)Class 4 (readily combustible, self-reactive, solid desensitised explosives, spontaneouslycombustible, dangerous when wet)Class 5 (oxidisers, organic peroxides)
10.6. Hazardous decomposition products Carbon oxides.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact Causes severe eye irritation which may damage tissue.
Skin Contact Causes skin irritation.
Physical State: Liquid Color Clear colorless to pale yellow
Odor: Pungent Odor Threshold:
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No information available
_____________________________________________________________________________________________BARAKLEAN®-926 Revision Date: 15-Jun-2018
Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing, difficultybreathing, wheezing, coughing up blood and pneumonia, which can be fatal.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes,<2% aromatic
1174522-27-0
>2000 mg/kg-bw (rat)(similarsubstance)
>2000 mg/kg-bw (rat)(similarsubstance)
>5.3 mg/L (rat, 4h, aerosol)(similar substance)
Diethylene glycolmonobutyl ether
112-34-5 6560 mg/kg (rat) 2764 mg/kg (Rabbit) >29 ppm (rat, 2h, aerosol)
2-Ethyl hexanol 104-76-7 > 2000 mg/kg 1980 mg/kg 1.45 mg/L (rat, mist, 4h)
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 >2000-5000 mg/kg-bw (rat) >2000-5000 mg/kg-bw (rabbit) >0.22 mg/L (rat, 4h, aerosol)(similar substances)
Substances CASNumber
Skin corrosion/irritation
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
Not irritating to skin in rabbits. (similar substances)
Diethylene glycolmonobutyl ether
112-34-5 Mild skin irritation (Rabbit)
2-Ethyl hexanol 104-76-7 Causes moderate skin irritation. (Rabbit)
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 Causes moderate skin irritation. (similar substances)
Substances CASNumber
Serious eye damage/irritation
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
(Rabbit) (similar substances) No eye irritation
Diethylene glycolmonobutyl ether
112-34-5 Causes moderate eye irritation (Rabbit)
2-Ethyl hexanol 104-76-7 Causes moderate eye irritation (Rabbit)
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 Causes severe eye irritation (similar substances)
Substances CASNumber
Skin Sensitization
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
(guinea pig) (similar substances) Did not cause sensitization on laboratory animals
Diethylene glycolmonobutyl ether
112-34-5 Did not cause sensitization on laboratory animals (guinea pig)
2-Ethyl hexanol 104-76-7 Did not cause sensitization on laboratory animals (guinea pig)
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 (similar substances) Did not cause sensitization on laboratory animals (guinea pig)
Substances CASNumber
Respiratory Sensitization
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
No information available
Diethylene glycolmonobutyl ether
112-34-5 No information available
2-Ethyl hexanol 104-76-7 Not regarded as a sensitizer.
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 No information available
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_____________________________________________________________________________________________BARAKLEAN®-926 Revision Date: 15-Jun-2018
Substances CASNumber
Mutagenic Effects
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
No data of sufficient quality are available.
Diethylene glycolmonobutyl ether
112-34-5 In vivo tests did not show mutagenic effects. In vitro tests did not show mutagenic effects
2-Ethyl hexanol 104-76-7 In vitro tests did not show mutagenic effects.
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 In vivo tests did not show mutagenic effects. (similar substances) In vitro tests did not showmutagenic effects
Substances CASNumber
Carcinogenic Effects
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
No data of sufficient quality are available.
Diethylene glycolmonobutyl ether
112-34-5 No information available
2-Ethyl hexanol 104-76-7 Did not show carcinogenic effects in animal experiments
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 Did not show carcinogenic effects in animal experiments (similar substances)
Substances CASNumber
Reproductive toxicity
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
(similar substances) Animal testing did not show any effects on fertility. Did not show teratogeniceffects in animal experiments.
Diethylene glycolmonobutyl ether
112-34-5 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.
2-Ethyl hexanol 104-76-7 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 (similar substances) Animal testing did not show any effects on fertility.
Substances CASNumber
STOT - single exposure
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
(similar substances) No significant toxicity observed in animal studies at concentration requiringclassification.
Diethylene glycolmonobutyl ether
112-34-5 No significant toxicity observed in animal studies at concentration requiring classification.
2-Ethyl hexanol 104-76-7 May cause respiratory irritation.
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Substances CASNumber
STOT - repeated exposure
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Diethylene glycolmonobutyl ether
112-34-5 No significant toxicity observed in animal studies at concentration requiring classification.
2-Ethyl hexanol 104-76-7 No significant toxicity observed in animal studies at concentration requiring classification.
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Substances CASNumber
Aspiration hazard
Hydrocarbons, C10-14(even numbered),n-alkanes, isoalkanes, <2%aromatic
1174522-27-0
May be fatal if swallowed and enters airways
Diethylene glycol 112-34-5 Not applicable
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_____________________________________________________________________________________________BARAKLEAN®-926 Revision Date: 15-Jun-2018
monobutyl ether
2-Ethyl hexanol 104-76-7 Not applicable
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 No adverse health effects are expected from swallowing.
12. Ecological Information
12.1. Toxicity Ecotoxicity effectsProduct is not classified as hazardous to the environment.
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Hydrocarbons,C10-14 (evennumbered),n-alkanes, isoalkanes,<2% aromatic
1174522-27-0
EL50 (72 h) >100 mg/L(Desmodesmus
subspicatus)
LC50 (96 h) 1000 mg/L(Salmo gairdneri)
EC50 (3 h) >1000 mg/L(activated sludge)
EC50 (48 h) 1000 mg/L(Daphnia magna)
NOAEC (21 days) >1mg/L (Daphnia magna)
Diethylene glycolmonobutyl ether
112-34-5 EC50 > 100 mg/L(Desmodesmus
subspicatus)
LC50 1300 mg/L(Lepomis macrochirus)
EC10 >1995 mg/L(Activated sludge,
industrial)
EC50 > 100 mg/L(Daphnia magna)
2-Ethyl hexanol 104-76-7 No information available LC50 (96h) 17.1 mg/L(Leuciscus idus
melanotus)
No information available No information available
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 EC50 (72 h) 475.51mg/L (Skeletonema
costatum)EC50 (72 h) >10 mg/L ()
NOEC (30 d) 0.28 mg/L(Pimephales promelas)
No information available LC50 (48 h) 13.76 mg/L(Acartia tonsa)
EC50 (48 h) >10 mg/L(Daphnia magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Hydrocarbons, C10-14 (even numbered), n-alkanes,isoalkanes, <2% aromatic
1174522-27-0
Diethylene glycol monobutyl ether 112-34-5 No information available
2-Ethyl hexanol 104-76-7 Readily biodegradable (100% @ 14d)
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Hydrocarbons, C10-14 (even numbered),n-alkanes, isoalkanes, <2% aromatic
1174522-27-0 No data available
Diethylene glycol monobutyl ether 112-34-5 No information available
2-Ethyl hexanol 104-76-7 Not Bioaccumulative; LogPow = 2.73
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Hydrocarbons, C10-14 (even numbered), n-alkanes,isoalkanes, <2% aromatic
1174522-27-0 No information available
Diethylene glycol monobutyl ether 112-34-5 No information available
2-Ethyl hexanol 104-76-7 KOC = 26
Poly(oxy-1,2-ethanediyl),.alpha.-(2-propylheptyl)-.omega.-hydroxy-
160875-66-1 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects
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Endocrine Disruptor Information
_____________________________________________________________________________________________BARAKLEAN®-926 Revision Date: 15-Jun-2018
This product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002525
Group Name Cleaning Products (Combustible, HSR002525)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%
_____________________________________________________________________________________________BARAKLEAN®-926 Revision Date: 15-Jun-2018
LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 15-Jun-2018
Revision NoteInitial Release
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
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SAFETY DATA SHEET
BaraSure™ W-988Revision Date: 22-Apr-2019 Revision Number: 3
1. Identification
Product Name Product Trade Name: BaraSure™ W-988
Other Names Synonyms None
Hazardous Material Number: HM009037
Recommended Use Recommended Use Shale stabilizer
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
136-140 Connett Road East, BlockNew PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1E (Oral) Acutely Toxic Substances6.3B (Mildly) irritating to the skin6.4A Irritating to the eye
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Warning
Hazard Statements H303 - May be harmful if swallowedH316 - Causes mild skin irritationH319 - Causes serious eye irritation
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_____________________________________________________________________________________________BaraSure™ W-988 Revision Date: 22-Apr-2019
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear eye protection/face protection
Response P332 + P313 - If skin irritation occurs: Get medical advice/attentionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attention
Storage None
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
Contains
Substances CAS Number Substance HSNO Classification
Organic salt Proprietary 6.1E (Oral)6.3B6.4A (mild irritant)
2.3. Other Hazards None known
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Organic salt Proprietary 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation Move person to fresh air.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Rinse mouth with water many times. Get medical attention, if symptoms occur
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected. Causes eye irritation Causes mild skin irritation May be harmful if swallowed
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaWater spray. Carbon dioxide (CO2). Foam. Dry powder
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
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_____________________________________________________________________________________________BaraSure™ W-988 Revision Date: 22-Apr-2019
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Do not breathedust/fume/gas/mist/vapors/spray.See Section 8 for additional information
6.2. Environmental precautions None known.
6.3. Methods and material for containment and cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeledcontainers.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Ensure adequate ventilation. Avoid creating or inhaling dust. Avoid extended skincontact.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a cool, well ventilated place
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAOrganic salt Proprietary Not applicable Not applicable
Engineering Controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures
below applicable exposure limits. Ensure adequate ventilation, especially in confinedareas
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard
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_____________________________________________________________________________________________BaraSure™ W-988 Revision Date: 22-Apr-2019
EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Safety glasses with side-shields. If splashes are likely to occur, wear: Goggles,Face-shield.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 6.5 - 8.0
Freezing Point / Range No data available
Melting Point / Range No data available
Pour Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity ~ 1.1
Water Solubility No data available
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers. Strong acids. Strong alkalis.
10.6. Hazardous decomposition products Oxides of nitrogen. Carbon oxides.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact May cause eye irritation.
Physical State: Viscous liquid Color Clear Colorless to Light yellow
Odor: Odorless Odor Threshold: No information available
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_____________________________________________________________________________________________BaraSure™ W-988 Revision Date: 22-Apr-2019
Skin Contact May cause mild skin irritation.
Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Organic salt Proprietary 3400 mg/kg (Rat)3900 mg/kg (mouse)
No data available No data available
Substances CASNumber
Skin corrosion/irritation
Organic salt Non-irritating to the skin (Rabbit)
Substances CASNumber
Serious eye damage/irritation
Organic salt Non-irritating to the eye (Rabbit)
Substances CASNumber
Skin Sensitization
Organic salt Did not cause sensitization on laboratory animals (guinea pig)
Substances CASNumber
Respiratory Sensitization
Organic salt Based on available data, the classification criteria are not met.
Substances CASNumber
Mutagenic Effects
Organic salt In vitro tests did not show mutagenic effects.
Substances CASNumber
Carcinogenic Effects
Organic salt Based on available data, the classification criteria are not met.
Substances CASNumber
Reproductive toxicity
Organic salt Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.
Substances CASNumber
STOT - single exposure
Organic salt No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
STOT - repeated exposure
Organic salt No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
Aspiration hazard
Organic salt Based on available data, the classification criteria are not met.
12. Ecological Information
12.1. Toxicity Ecotoxicity effectsProduct is not classified as hazardous to the environment.
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Organic salt Proprietary EC50(72h): > 500 mg/L LC50(96h): > 10000 EC50(17h): 132.8 mg/L EC50(24h): 250 mg/L
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BaraSure™ W-988 Revision Date: 22-Apr-2019
(Desmodesmussubspicatus)
mg/L (Leuciscus idus) (Pseudomonas putida) (Daphnia magna)EC50(48h): 500 mg/L
(Daphnia magna)NOEC(21d): 30.2 mg/L(reproduction) (Daphnia
magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Organic salt Proprietary Readily biodegradable (>75% @ 5d)
12.3. Bioaccumulative potential
Substances CAS Number Bioaccumulation
Organic salt Proprietary -3.77BCF: 3.16 L/kg
12.4. Mobility in soil
Substances CAS Number Mobility
Organic salt Proprietary No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Dispose in accordance with local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BaraSure™ W-988 Revision Date: 22-Apr-2019
HSNO Approval Number HSR006672
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 22-Apr-2019
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
BARAZAN® D PLUS
Revision Date: 15-Aug-2018 Revision Number: 30
1. Identification
Product Name Product Trade Name: BARAZAN® D PLUS
Other Names Synonyms None
Hazardous Material Number: HM003535
Recommended Use Recommended Use Viscosifier
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
136-140 Connett Road East,Bell Block, New PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances in NA Non-hazardous
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_____________________________________________________________________________________________BARAZAN® D PLUS Revision Date: 15-Aug-2018
concentrations above cut-off values according tothe competent authority
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA NF
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential.
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.
_____________________________________________________________________________________________
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See Section 8 for additional information
_____________________________________________________________________________________________BARAZAN® D PLUS Revision Date: 15-Aug-2018
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsSlippery when wet. Avoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation.Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties Physical State: Powder Color White to off white
Odor: Slight Odor Threshold: No information available
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_____________________________________________________________________________________________BARAZAN® D PLUS Revision Date: 15-Aug-2018
Property Values Remarks/ - Method
pH: 7 (1%)
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.6
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature 204 °C / 400 °F
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight 1000000
VOC Content (%) No data available
Bulk Density 52.4 lbs/ft3
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May impede respiration.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values according
NA No data available No data available No data available
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_____________________________________________________________________________________________BARAZAN® D PLUS Revision Date: 15-Aug-2018
to the competentauthority
12. Ecological Information
12.1. Toxicity Ecotoxicity effectsProduct is not classified as hazardous to the environment.
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BARAZAN® D PLUS Revision Date: 15-Aug-2018
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-Hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
Page 6 / 7
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - Celsius
_____________________________________________________________________________________________BARAZAN® D PLUS Revision Date: 15-Aug-2018
IATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDWHO/FAO
Revision Date: 15-Aug-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
BARAZAN® D
Revision Date: 16-Jun-2016 Revision Number: 23
1. Product and Company Identification
Product Name Product Trade Name: BARAZAN® D
Other Names Synonyms None
Hazardous Material Number: HM003534
Recommended Use Recommended Use Viscosifier
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number: +64 800 451719
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable
2.3. Other Hazards
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BARAZAN® D Revision Date: 16-Jun-2016
This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardCombustible dust when in finely divided and highly suspended state.
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
_____________________________________________________________________________________________
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6.3. Methods and material for containment and cleaning up
_____________________________________________________________________________________________BARAZAN® D Revision Date: 16-Jun-2016
Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsSlippery when wet. Avoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation.Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 7 (1%)
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Physical State: Powder Color White to off white
Odor: Slight Odor Threshold:
_____________________________________________________________________________________________
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No information available
_____________________________________________________________________________________________BARAZAN® D Revision Date: 16-Jun-2016
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.6
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature 204 °C / 400 °F
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight 1000000
VOC Content (%) No data available
Bulk Density 52.4 lbs/ft3
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May impede respiration.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BARAZAN® D Revision Date: 16-Jun-2016
12. Ecological Information
12.1. Toxicity Ecotoxicity effects
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
_____________________________________________________________________________________________
Page 5 / 7
_____________________________________________________________________________________________BARAZAN® D Revision Date: 16-Jun-2016
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
_____________________________________________________________________________________________
Page 6 / 7
Key literature references and sources for datawww.ChemADVISOR.com/
_____________________________________________________________________________________________BARAZAN® D Revision Date: 16-Jun-2016
NZ CCID
Revision Date: 16-Jun-2016
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
BARITE
Revision Date: 22-Jan-2018 Revision Number: 50
1. Product and Company Identification
Product Name Product Trade Name: BARITE
Other Names Synonyms None
Hazardous Material Number: HM000105
Recommended Use Recommended Use Weight Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.7A Known or presumed human carcinogens6.9B Harmful to human target organs or systems6.9A Toxic to human target organs or systems
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Danger
Hazard Statements H350i - May cause cancer by inhalationH373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Precautionary Statements
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BARITE Revision Date: 22-Jan-2018
Prevention P103 - Read label before useP104 - Read Safety Data Sheet before use.P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required
Response P308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell
Storage P405 - Store locked up
Disposal P501 - Dispose of contents/container to an approved landfill
Contains
Substances CAS Number Substance HSNO Classification
Crystalline silica, quartz 14808-60-7 6.7A6.9A
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Crystalline silica, quartz 14808-60-7 1 - 5%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also beenassociated with scleroderma and kidney disease.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters
_____________________________________________________________________________________________
Page 2 / 7
Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
_____________________________________________________________________________________________BARITE Revision Date: 22-Jan-2018
Special exposure hazards in a fireNone anticipated
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposurelimits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material isslippery when wet.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers If more than 10 kg (Class 6) is present, then an approved handler must be present when the substance is being handled andwhen not in use, the substance must be locked away.
7.2. Conditions for safe storage, including any incompatibilities Store in a well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Use goodhousekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuseempty container.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWACrystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
Engineering Controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures
below applicable exposure limits.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BARITE Revision Date: 22-Jan-2018
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be launderedbefore reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: No data available
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 4.23
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight 233.4
VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials None known.
10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanentlung damage may be occurring. Inhalation of dust may also have serious chronic healtheffects (See "Chronic Effects/Carcinogenicity" subsection below).
Physical State: Solid Color Pink to tan to gray
Odor: Odorless Odor Threshold:
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No information available
_____________________________________________________________________________________________BARITE Revision Date: 22-Jan-2018
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis. Symptomsinclude cough, shortness of breath, wheezing, non-specific chest illness, and reducedpulmonary function. This disease is exacerbated by smoking. Individuals with silicosisare predisposed to develop tuberculosis.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available
Substances CASNumber
Skin corrosion/irritation
Crystalline silica, quartz 14808-60-7 Non-irritating to the skin
Substances CASNumber
Serious eye damage/irritation
Crystalline silica, quartz 14808-60-7 Non-irritating to the eye
Substances CASNumber
Skin Sensitization
Crystalline silica, quartz 14808-60-7 No information available.
Substances CASNumber
Respiratory Sensitization
Crystalline silica, quartz 14808-60-7 No information available
Substances CASNumber
Mutagenic Effects
Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Substances CASNumber
Carcinogenic Effects
Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.
Substances CASNumber
Reproductive toxicity
Crystalline silica, quartz 14808-60-7 No information available
Substances CASNumber
STOT - single exposure
Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
STOT - repeated exposure
Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CASNumber
Aspiration hazard
Crystalline silica, quartz 14808-60-7 Not applicable
12. Ecological Information
12.1. Toxicity
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Product Ecotoxicity DataNo data available
_____________________________________________________________________________________________BARITE Revision Date: 22-Jan-2018
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Crystalline silica,quartz
14808-60-7 EC50 (72 h) =440 mg/L(Selenastrum
capricornutum)(similarsubstance)
LL0 (96 h) =10000 mg/L(Danio rerio)(similar
substance)
No information available LL50 (24 h) >10000mg/L (Daphniamagna)(similar
substance)
12.2. Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.Substances CAS Number Persistence and Degradability
Crystalline silica, quartz 14808-60-7 The methods for determiningbiodegradability are not applicable toinorganic substances.
12.3. Bioaccumulative potential Does not bioaccumulate.
Substances CAS Number Log Pow
Crystalline silica, quartz 14808-60-7 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Crystalline silica, quartz 14808-60-7 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Follow all applicable community, national or regional regulations regarding waste
management methods.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
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_____________________________________________________________________________________________BARITE Revision Date: 22-Jan-2018
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002512
Group Name Additives, Process Chemicals and Raw Materials (Toxic 6.7 HSR002512)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers If more than 10 kg (Class 6) is present, then an approved handler must be present whenthe substance is being handled and when not in use, the substance must be lockedaway.
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 22-Jan-2018
Revision NoteSDS sections updated:1
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
_____________________________________________________________________________________________
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End of Safety Data Sheet
SAFETY DATA SHEET
BAROFIBRE®
Revision Date: 05-Mar-2014 Revision Number: 16
Manufacturer/Supplier
Classification
Halliburton New Zealand1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
Product Code:
Non-hazardous
HM003539
Hazard and Precautionary Statements
1. Product and Company Identification
E-Mail address: fdunexchem@halliburton.com
Hazard Pictograms
Signal Word None
Emergency Telephone Number +64-6-7559274
Recommended Use
Hazard Statements Not Hazardous
Product Name
Precautionary Statements
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
Recommended Use
Prevention None
Loss Circulation Material
Other Names
Response None
Uses Advised Against No information available
Storage None
2. Hazard(s) Identification
Disposal None
Statement of Hazardous Nature
Contains
Synonyms: None
Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Company Name, Address and Contact Details
_____________________________________________________________________________________________
Product Trade Name:
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BAROFIBRE®
_____________________________________________________________________________________________BAROFIBRE® Revision Date: 05-Mar-2014
5. Fire-fighting measures
Under normal conditions, first aid procedures are not required.
Mixture
Type of Hazard
Not applicable
Eyes
Flammability HazardOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Substances CAS Number
Skin
5.1 Extinguishing media
Under normal conditions, first aid procedures are not required.
PERCENT (w/w)
Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Dust can form an explosive mixture in air
Ingestion
Extinguishing media which must not be used for safety reasonsNone known.
Under normal conditions, first aid procedures are not required.
Substance HSNO Classification
Contains no hazardous substances
HAZCHEM Code
Mixture
Hazchem Code: None Allocated
60 - 100%
Workplace Facilities Required
Substances
Special Protective Equipment and Precautions for Fire Fighters
None
Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special Exposure HazardsOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential.
Relation to Health Effect
6. Spillage, Accidental Release Measures
Most Important Symptoms/EffectsNo significant hazards expected.
4. First-Aid Measures
6.1 Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.
CAS Number
Contains no hazardous substances
See Section 8 for additional information
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
6.2 Environmental precautions
3. Composition and Information on Ingredients
2.3 Other Hazards
Requirements for First Aid or Medical Care
_____________________________________________________________________________________________
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Inhalation
_____________________________________________________________________________________________Revision Date: 05-Mar-2014BAROFIBRE®
Not applicable
Handling Practices
Engineering Controls
Engineering Controls Use in a well ventilated area.
7. Handling and Storage
Store Site Requirements
Personal Protective Equipment (PPE)
None known.
Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, or equivalent respirator when using this product. Selection of and instruction onusing all personal protective equipment, including respirators, should be performed by anIndustrial Hygienist or other qualified professional.
No special controls required
6.4 Reference to other sections
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Safety glasses.
Packaging
Other Precautions None known.
Scoop up and remove.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice
No special packaging required
Approved Handlers
7.1 Precautions for Safe Handling
9. Physical and Chemical Properties
This product does NOT require an approved handler.
See Section 8 and 13 for additional information.
6.3 Methods and material for containment and cleaning up
9.1 Information on basic physical and chemical properties
8. Exposure Controls and Personal Protection
Handling PrecautionsAvoid creating or inhaling dust.
Workplace Exposure Standards
7.2 Conditions for safe storage, including any incompatibilities
Exposure Limits
Store away from oxidizers. Store in a dry location. Product has a shelf life of 36 months.
Substances CAS Number New Zealand WES ACGIH TLV-TWA
Contains no hazardoussubstances
Mixture Not applicable
No information availableOdor: Odorless
Physical State:
_____________________________________________________________________________________________
Solid Powder Color:
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Tan
Odor Threshold:
_____________________________________________________________________________________________BAROFIBRE® Revision Date: 05-Mar-2014
None known.
No information available
No data available
Remarks/ - Method
Hazardous Reactions
Boiling Point/Range
Hazardous Polymerization: Will Not Occur
Specific Gravity
9.2 Other information
1.3
No data available
11. Toxicological Information
VOC Content (%) No data available
Property
Water Solubility
Health Effect from Likely Routes of Exposure
Insoluble in water
Acute Toxicity
Freezing Point/Range
10. Stability and Reactivity
Flash Point
Solubility in other solvents
Inhalation May cause mild respiratory irritation.
No data available
193 °C PMCC
Eye Contact May cause mild eye irritation.
10.2 Chemical Stability
190 °C
Skin Contact None known.
Partition coefficient: n-octanol/water
Stable
Ingestion None known
No data available
Values
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% arechronic health hazards.
Evaporation rate
Autoignition Temperature
10.4 Conditions to Avoid
No data available
Toxicity Data
No data available
None anticipated
pH:
Decomposition Temperature
Toxicology data for the components
No data available
Melting Point/Range
10.5 Incompatible Materials
Vapor Pressure
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Viscosity
Strong oxidizers.
Contains no hazardoussubstances
Mixture No data available No data available No data available
No data available
No data available
No data available
Explosive Properties No information available
_____________________________________________________________________________________________
4.9 (1%)
10.6 Hazardous Decomposition Products
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Vapor Density
Oxidizing Properties
_____________________________________________________________________________________________BAROFIBRE® Revision Date: 05-Mar-2014
No information available
No information available
No information available
IMDG/IMO
No information available
UN Number: Not restricted.
No information available
UN Proper Shipping Name: Not restricted
Ecotoxicity Hazard Statements
Transport Hazard Class(es): Not applicable
None known
NZ 5433.1999
UN Number: Not restricted.
Ecotoxicity Effects
UN Proper Shipping Name: Not restricted
12.2 Persistence and degradability
12.6 Other adverse effects
Transport Hazard Class(es): Not applicable
Substance Ecotoxicity Data
12. Ecological Information
Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
Biodegradable.
IATA/ICAO
Product Ecotoxicity DataNo data available
UN Number: Not restricted.
Substances
UN Proper Shipping Name: Not restricted
13. Disposal Considerations
Transport Hazard Class(es): Not applicable
CAS Number Toxicity to Algae
Special Precautions for User None
12.3 Bioaccumulative potential
13.1 Waste treatment methods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Toxicity to Fish Toxicity toMicroorganisms
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
15. Regulatory Information
Does not bioaccumulate
Toxicity toInvertebrates
Contaminated Packaging Follow all applicable national or local regulations.
New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
12.1 Toxicity
14. Transport Information
Contains nohazardoussubstances
_____________________________________________________________________________________________
12.4 Mobility in soil
Page 5 / 6
Mixture
_____________________________________________________________________________________________Revision Date: 05-Mar-2014BAROFIBRE®
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Group Name Not Applicable
Revision Date: 05-Mar-2014
16. Other information, including date of preparation or last revision
Revision Note
Not applicable
Approved Handlers Not Applicable
The following sections have been revised since the last issue of this SDSNot applicable
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Compliance at 1-580-251-4335.
HSNO Approval Number Non-hazardous
_____________________________________________________________________________________________
Poisons Schedule:
Page 6 / 6
None Allocated
SAFETY DATA SHEET
BENTONITE
Revision Date: 05-Feb-2018 Revision Number: 47
1. Identification
Product Name Product Trade Name: BENTONITE
Other Names Synonyms None
Hazardous Material Number: HM000126
Recommended Use Recommended Use Weight Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.7A Known or presumed human carcinogen6.9B Harmful to human target organs or systems
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Danger
Hazard Statements H350 - May cause cancer by inhalationH373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Precautionary Statements
Prevention P103 - Read label before use
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_____________________________________________________________________________________________BENTONITE Revision Date: 05-Feb-2018
P104 - Read Safety Data Sheet before use.P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required
Response P308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell
Storage P405 - Store locked up
Disposal P501 - Dispose of contents/container to an approved landfill
Contains
Substances CAS Number Substance HSNO Classification
Crystalline silica, quartz 14808-60-7 6.7A6.9A
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Crystalline silica, quartz 14808-60-7 1 - 5%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Rinse mouth with water many times. Get medical attention if symptoms occur
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also beenassociated with scleroderma and kidney disease.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
_____________________________________________________________________________________________
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Special exposure hazards in a fire
_____________________________________________________________________________________________BENTONITE Revision Date: 05-Feb-2018
None anticipated
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
6.2. Environmental precautions None known.
6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposurelimits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material isslippery when wet.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers If more than 10 kg (Class 6) is present, then an approved handler must be present when the substance is being handled andwhen not in use, the substance must be locked away.
7.2. Conditions for safe storage, including any incompatibilities Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do notreuse empty container.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWACrystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
Engineering Controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures
below applicable exposure limits.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BENTONITE Revision Date: 05-Feb-2018
of and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)
Hand Protection Use gloves which are suitable for the chemicals present in this product as well as otherenvironmental factors in the workplace.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be launderedbefore reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 9.9
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 2.65
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Hydrofluoric acid.
10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.
Physical State: Solid Color Various
Odor: Odorless Odor Threshold:
_____________________________________________________________________________________________
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No information available
_____________________________________________________________________________________________BENTONITE Revision Date: 05-Feb-2018
Breathing silica dust may not cause noticeable injury or illness even though permanentlung damage may be occurring. Inhalation of dust may also have serious chronic healtheffects (See "Chronic Effects/Carcinogenicity" subsection below).
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion May act as obstruction if swallowed.
Chronic Effects/Carcinogenicity This product contains a suspected carcinogen. May cause damage to organs throughprolonged or repeated exposure. Silicosis: Excessive inhalation of respirable crystallinesilica dust may cause a progressive, disabling, and sometimes-fatal lung disease calledsilicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chestillness, and reduced pulmonary function. This disease is exacerbated by smoking.Individuals with silicosis are predisposed to develop tuberculosis.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available
Substances CASNumber
Skin corrosion/irritation
Crystalline silica, quartz 14808-60-7 Non-irritating to the skin
Substances CASNumber
Serious eye damage/irritation
Crystalline silica, quartz 14808-60-7 Non-irritating to the eye
Substances CASNumber
Skin Sensitization
Crystalline silica, quartz 14808-60-7 No information available.
Substances CASNumber
Respiratory Sensitization
Crystalline silica, quartz 14808-60-7 No information available
Substances CASNumber
Mutagenic Effects
Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Substances CASNumber
Carcinogenic Effects
Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.
Substances CASNumber
Reproductive toxicity
Crystalline silica, quartz 14808-60-7 No information available
Substances CASNumber
STOT - single exposure
Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
STOT - repeated exposure
Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CASNumber
Aspiration hazard
Crystalline silica, quartz 14808-60-7 Not applicable
12. Ecological Information
_____________________________________________________________________________________________
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_____________________________________________________________________________________________BENTONITE Revision Date: 05-Feb-2018
12.1. Toxicity Ecotoxicity effectsProduct is not classified as hazardous to the environment.
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Crystalline silica,quartz
14808-60-7 EC50 (72 h) =440 mg/L(Selenastrum
capricornutum)(similarsubstance)
LL0 (96 h) =10000 mg/L(Danio rerio)(similar
substance)
No information available LL50 (24 h) >10000mg/L (Daphniamagna)(similar
substance)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Crystalline silica, quartz 14808-60-7 The methods for determiningbiodegradability are not applicable toinorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Crystalline silica, quartz 14808-60-7 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Crystalline silica, quartz 14808-60-7 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Follow all applicable community, national or regional regulations regarding waste
management methods.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
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_____________________________________________________________________________________________BENTONITE Revision Date: 05-Feb-2018
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002512
Group Name Additives, Process Chemicals and Raw Materials (Toxic 6.7 HSR002512)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers If more than 10 kg (Class 6) is present, then an approved handler must be present whenthe substance is being handled and when not in use, the substance must be lockedaway.
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 05-Feb-2018
Revision NoteSDS sections updated:2
_____________________________________________________________________________________________
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Disclaimer Statement
_____________________________________________________________________________________________BENTONITE Revision Date: 05-Feb-2018
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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BIOGUARD PLUSWilhelmsen Ships Service LtdCatalogue number: 778918 (25L)
Version No: 8.9
Safety Data Sheet according to HSNO Regulations
Issue Date: 13/02/2018
Print Date: 12/03/2019
S.GHS.NZL.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name BIOGUARD PLUS
Synonyms Not Available
Proper shipping name AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Dodecyl dipropylene triamine)
Other means ofidentification
778918 (25L), 778918
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Seawater Dispersant for Marine Systems
Details of the supplier of the safety data sheet
Registered companyname
Wilhelmsen ShipsService Ltd
Wilhelmsen Ships Service AS*Outback (M)SDS portal:http://jr.chemwatch.net/outb/account/autologin?login=wilhelmsen
Address6B Wagener PlaceAuckland 1025 NewZealand
Willem Barentszstraat 50 RotterdamNetherlands
--------Use our Outback portal to obtain our(M)SDSs in other languages and/orformat.--------- For questions relating to ourSDSs please use Email:WSS.GLOBAL.SDSINFO@wilhelmsen.com--------- Norway
Telephone (+64) 9 8494783 +31 10 4877 777 Not Available
Fax Not Available +31 10 4877888 Not Available
Website Not Available http://www.wilhelmsen.com Not Available
Email Not Available wss.rotterdam@wilhelmsen.com Not Available
Emergency telephone number
Association /Organisation
CHEMTREC Dutch nat. poison centreAmerican Chemistry Council 24hrs -Chemtrec
Emergency telephonenumbers
(+64) 9 8455758 + 31 30 274 88 88 +1 703 527 3887
Other emergencytelephone numbers
Not Available Not Available (800) 424 9300
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
Continued...
Classification [1] Acute Toxicity (Oral) Category 4, Skin Corrosion/Irritation Category 1B, Specific target organ toxicity - repeated exposureCategory 2, Chronic Aquatic Hazard Category 1
Legend:1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No1272/2008 - Annex VI
Determined byChemwatch using
GHS/HSNO criteria6.1D (oral), 8.2B, 6.9B, 9.1A
Label elements
Hazard pictogram(s)
SIGNAL WORD DANGER
Hazard statement(s)
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s) Prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P270 Do not eat, drink or smoke when using this product.
Precautionary statement(s) Response
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.
Precautionary statement(s) Storage
P405 Store locked up.
Precautionary statement(s) Disposal
P501 Dispose of contents/container in accordance with local regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
SubstancesSee section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
2372-82-9* 30-40
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids byoccasionally lifting the upper and lower lids.
N-(3-aminopropyl)-N-dodecyl-1,3-propanediamine
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Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
For amines:If liquid amines come in contact with the eyes, irrigate immediately and continuously with low pressure flowing water,preferably from an eye wash fountain, for 15 to 30 minutes.For more effective flushing of the eyes, use the fingers to spread apart and hold open the eyelids. The eyes shouldthen be “rolled” or moved in all directions.Seek immediate medical attention, preferably from an ophthalmologist.
Skin Contact
If skin or hair contact occurs:Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons InformationCentre. Transport to hospital, or doctor.
For amines:In case of major exposure to liquid amine, promptly remove any contaminated clothing, including rings, watches, andshoe, preferably under a safety shower.Wash skin for 15 to 30 minutes with plenty of water and soap. Call a physician immediately.Remove and dry-clean or launder clothing soaked or soiled with this material before reuse. Dry cleaning of contaminatedclothing may be more effective than normal laundering.Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing.Discard contaminated leather articles such as shoes, belts, and watchbands.Note to Physician: Treat any skin burns as thermal burns. After decontamination, consider the use of cold packs andtopical antibiotics.
Inhalation
If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, orpocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably insemi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative orbeclomethasone derivative may be considered.
This must definitely be left to a doctor or person authorised by him/her.(ICSC13719)For amines:
All employees working in areas where contact with amine catalysts is possible should be thoroughly trained in theadministration of appropriate first aid procedures.Experience has demonstrated that prompt administration of such aid can minimize the effects of accidental exposure.Promptly move the affected person away from the contaminated area to an area of fresh air. Keep the affected person calm and warm, but not hot.If breathing is difficult, oxygen may be administered by a qualified person.If breathing stops, give artificial respiration. Call a physician at once.
Ingestion
For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed.
If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airwayand prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.
For amines:If liquid amine are ingested, have the affected person drink several glasses of water or milk.Do not induce vomiting.Immediately transport to a medical facility and inform medical personnel about the nature of the exposure. The decisionof whether to induce vomiting should be made by an attending physician.
Indication of any immediate medical attention and special treatment neededFor acute or short-term repeated exposures to highly alkaline materials:
Respiratory stress is uncommon but present occasionally because of soft tissue edema. Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary. Oxygen is given as indicated. The presence of shock suggests perforation and mandates an intravenous line and fluid administration. Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and solubilisation of proteins allow deep
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penetration into the tissue. Alkalis continue to cause damage after exposure. INGESTION:
Milk and water are the preferred diluents No more than 2 glasses of water should be given to an adult.
Neutralising agents should never be given since exothermic heat reaction may compound injury. * Catharsis and emesis are absolutely contra-indicated.* Activated charcoal does not absorb alkali.* Gastric lavage should not be used. Supportive care involves the following:
Withhold oral feedings initially. If endoscopy confirms transmucosal injury start steroids only within the first 48 hours. Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention. Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia).
SKIN AND EYE:Injury should be irrigated for 20-30 minutes.
Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology]For amines:
Certain amines may cause injury to the respiratory tract and lungs if aspirated. Also, such products may cause tissue destruction leading to stricture. Iflavage is performed, endotracheal and/or esophagoscopic control is suggested.No specific antidote is known.Care should be supportive and treatment based on the judgment of the physician in response to the reaction of the patient.
Laboratory animal studies have shown that a few amines are suspected of causing depletion of certain white blood cells and their precursors in lymphoidtissue. These effects may be due to an immunosuppressive mechanism.Some persons with hyperreactive airways (e.g., asthmatic persons) may experience wheezing attacks (bronchospasm) when exposed to airway irritants.Lung injury may result following a single massive overexposure to high vapour concentrations or multiple exposures to lower concentrations of anypulmonary irritant material.Health effects of amines, such as skin irritation and transient corneal edema (“blue haze,” “halo effect,” “glaucopsia”), are best prevented by means offormal worker education, industrial hygiene monitoring, and exposure control methods. Persons who are highly sensitive to the triggering effect ofnon-specific irritants should not be assigned to jobs in which such agents are used, handled, or manufactured.
Medical surveillance programs should consist of a pre-placement evaluation to determine if workers or applicants have any impairments (e.g.,hyperreactive airways or bronchial asthma) that would limit their fitness for work in jobs with potential for exposure to amines. A clinical baseline can beestablished at the time of this evaluation.Periodic medical evaluations can have significant value in the early detection of disease and in providing an opportunity for health counseling.Medical personnel conducting medical surveillance of individuals potentially exposed to polyurethane amine catalysts should consider the following:
Health history, with emphasis on the respiratory system and history of infectionsPhysical examination, with emphasis on the respiratory system and the lymphoreticular organs (lymph nodes, spleen, etc.)Lung function tests, pre- and post-bronchodilator if indicatedTotal and differential white blood cell countSerum protein electrophoresis
Persons who are concurrently exposed to isocyanates also should be kept under medical surveillance.Pre-existing medical conditions generally aggravated by exposure include skin disorders and allergies, chronic respiratory disease (e.g. bronchitis,asthma, emphysema), liver disorders, kidney disease, and eye disease.Broadly speaking, exposure to amines, as characterised by amine catalysts, may cause effects similar to those caused by exposure to ammonia. Assuch, amines should be considered potentially injurious to any tissue that is directly contacted.Inhalation of aerosol mists or vapors, especially of heated product, can result in chemical pneumonitis, pulmonary edema, laryngeal edema, and delayedscarring of the airway or other affected organs. There is no specific treatment.Clinical management is based upon supportive treatment, similar to that for thermal burns.Persons with major skin contact should be maintained under medical observation for at least 24 hours due to the possibility of delayed reactions.
Polyurethene Amine Catalysts: Guidelines for Safe Handling and Disposal Technical Bulletin June 2000Alliance for Polyurethanes Industry
SECTION 5 FIREFIGHTING MEASURES
Extinguishing mediaFoam. Dry chemical powder. BCF (where regulations permit).
Special hazards arising from the substrate or mixture
Fire IncompatibilityAvoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignitionmay result
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course.
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For amines:For firefighting, cleaning up large spills, and other emergency operations, workers must wear a self-contained breathingapparatus with full face-piece, operated in a pressure-demand mode.Airline and air purifying respirators should not be worn for firefighting or other emergency or upset conditions.Respirators should be used in conjunction with a respiratory protection program, which would include suitable fit testingand medical evaluation of the user.
Fire/Explosion Hazardcarbon dioxide (CO2)other pyrolysis products typical of burning organic material.May emit corrosive fumes.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency proceduresSee section 8
Environmental precautionsSee section 12
Methods and material for containment and cleaning up
Minor Spills
Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before dischargeor disposal of material. Check regularly for spills and leaks. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.
for amines:If possible (i.e., without risk of contact or exposure), stop the leak.Contain the spilled material by diking, then neutralize.Next, absorb the neutralized product with clay, sawdust, vermiculite, or other inert absorbent and shovel into containers.
Major Spills
Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus.
For amines:First remove all ignition sources from the spill area.Have firefighting equipment nearby, and have firefighting personnel fully trained in the proper use of the equipment andin the procedures used in fighting a chemical fire.Spills and leaks of polyurethane amine catalysts should be contained by diking, if necessary, and cleaned up only byproperly trained and equipped personnel.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area.
DO NOT allow clothing wet with material to stay in contact with skin
Other information
Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area.
DO NOT store near acids, or oxidising agentsNo smoking, naked lights, heat or ignition sources.
Conditions for safe storage, including any incompatibilities
Suitable container
Lined metal can, lined metal pail/ can. Plastic pail. Polyliner drum.
For low viscosity materialsDrums and jerricans must be of the non-removable head type. Where a can is to be used as an inner package, the can must have a screwed enclosure.
For materials with a viscosity of at least 2680 cSt.
Storage incompatibilityAvoid reaction with oxidising agents Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.
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Ingredient Material name TEEL-1 TEEL-2 TEEL-3
Ingredient Original IDLH Revised IDLH
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
Not Available
EMERGENCY LIMITS
BIOGUARD PLUS Not Available Not Available Not Available Not Available
N-(3-aminopropyl)-N-dodecyl-1,3-propanediamine
Not Available Not Available
Exposure controls
Appropriate engineeringcontrols
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactionsto provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.
Personal protection
Eye and face protection
Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as inlaboratories; spectacles are not sufficient where complete eye protection is needed such as when handlingbulk-quantities, where there is a danger of splashing, or if the material may be under pressure.Chemical goggles.whenever there is a danger of the material coming in contact with the eyes; goggles must be properlyfitted.Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes;these afford face protection.
For amines:SPECIAL PRECAUTION:
Because amines are alkaline materials that can cause rapid and severe tissue damage, wearing of contact lenses whileworking with amines is strongly discouraged. Wearing such lenses can prolong contact of the eye tissue with the amine,thereby causing more severe damage. Appropriate eye protection should be worn whenever amines are handled or whenever there is any possibility of directcontact with liquid products, vapors, or aerosol mists.
Skin protection See Hand protection below
Hands/feet protection
Elbow length PVC gloves When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which varyfrom manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of theglove material can not be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.hasto be observed when making a final choice.For amines:
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommendedWhere there is a possibility of exposure to liquid amines skin protection should include: rubber gloves, (neoprene, nitrile,or butyl).
Body protection See Other protection below
Other protectionOveralls. PVC Apron. PVC protective suit may be required if exposure severe.
Respiratory protection
Type EK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the
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contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important.
Required minimum protectionfactor
Maximum gas/vapour concentration present in air p.p.m. (byvolume)
Half-faceRespirator
Full-FaceRespirator
up to 10 1000 EK-AUS / Class1 P2 -up to 50 1000 - EK-AUS / Class 1 P2up to 50 5000 Airline * -up to 100 5000 - EK-2 P2up to 100 10000 - EK-3 P2100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demandA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogencyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methylbromide, AX = Low boiling point organic compounds(below 65 degC)
· Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygencontent.
· The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odourmay indicate that the mask is not functioning properly, that the vapour concentration is too high, or that the mask is not properlyfitted. Because of these limitations, only restricted use of cartridge respirators is considered appropriate.
· Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determinedthat the humidity is less than 75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily,regardless of the length of time used
Where engineering controls are not feasible and work practices do not reduce airborne amine concentrations below recommended exposure limits,appropriate respiratory protection should be used. In such cases, air-purifying respirators equipped with cartridges designed to protect against amines arerecommended.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Liquid, light, yellow, miscible with water
Physical state LiquidRelative density (Water =
1)0.97
Odour Not AvailablePartition coefficient
n-octanol / waterNot Available
Odour threshold Not AvailableAuto-ignition temperature
(°C)Not Applicable
pH (as supplied) >7Decomposition
temperatureNot Available
Melting point / freezingpoint (°C)
Not Available Viscosity (cSt) Not Available
Initial boiling point andboiling range (°C)
Not Available Molecular weight (g/mol) Not Available
Flash point (°C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Upper Explosive Limit(%)
Not ApplicableSurface Tension (dyn/cm
or mN/m)Not Available
Lower Explosive Limit(%)
Not ApplicableVolatile Component
(%vol)Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Miscible pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.
Possibility of hazardousreactions
See section 7
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Conditions to avoid See section 7
Incompatible materials See section 7
Hazardousdecomposition products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lungdamage.Inhaling corrosive bases may irritate the respiratory tract. Symptoms include cough, choking, pain and damage to themucous membrane.Inhalation of amine vapours may cause irritation of the mucous membrane of the nose and throat, and lung irritation withrespiratory distress and cough. Swelling and inflammation of the respiratory tract is seen in serious cases; with headache,nausea, faintness and anxiety.
Ingestion
Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 grammay be fatal or may produce serious damage to the health of the individual.Ingestion of alkaline corrosives may produce burns around the mouth, ulcerations and swellings of the mucousmembranes, profuse saliva production, with an inability to speak or swallow. Both the oesophagus and stomach mayexperience burning pain; vomiting and diarrhoea may follow.Amines without benzene rings when swallowed are absorbed throughout the gut. Corrosive action may cause damagethroughout the gastrointestinal tract.
Skin Contact
The material can produce severe chemical burns following direct contact with the skin.Skin contact is not thought to produce harmful health effects (as classified under EC Directives using animal models).Systemic harm, however, has been identified following exposure of animals by at least one other route and the materialmay still produce health damage following entry through wounds, lesions or abrasions.Skin contact with alkaline corrosives may produce severe pain and burns; brownish stains may develop. The corrodedarea may be soft, gelatinous and necrotic; tissue destruction may be deep.Volatile amine vapours produce irritation and inflammation of the skin. Direct contact can cause burns.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmfuleffects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Eye
If applied to the eyes, this material causes severe eye damage.Direct eye contact with corrosive bases can cause pain and burns. There may be swelling, epithelium destruction, cloudingof the cornea and inflammation of the iris. Mild cases often resolve; severe cases can be prolonged with complicationssuch as persistent swelling, scarring, permanent cloudiness, bulging of the eye, cataracts, eyelids glued to the eyeballand blindness.Vapours of volatile amines irritate the eyes, causing excessive secretion of tears, inflammation of the conjunctiva andslight swelling of the cornea, resulting in 'halos' around lights. This effect is temporary, lasting only for a few hours.However this condition can reduce the efficiency of undertaking skilled tasks, such as driving a car.The material can produce severe chemical burns to the eye following direct contact. Vapours or mists may be extremelyirritating.
Chronic
Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes inthe mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumoniamay ensue.Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs orbiochemical systems.Long-term exposure to respiratory irritants may result in airways disease, involving difficulty breathing and relatedwhole-body problems.
BIOGUARD PLUSTOXICITY IRRITATION
Not Available Not Available
N-(3-aminopropyl)-N-dodecyl-
1,3-propanediamine
TOXICITY IRRITATION
dermal (rat) LD50: >600 mg/kg *[2] Skin (rabbit): Corrosive *
Oral (rat) LD50: 245 mg/kg *[2]
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
N-(3-aminopropyl)-N-dodecyl-
1,3-propanediamine
The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. Thepathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type.
Chemwatch: 9-221869
Catalogue number: 778918 (25L)
Version No: 8.9
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No significant acute toxicological data identified in literature search. FND ether amines and FND amines are very similar in structure (length of chain or degree of saturation), function andtoxicity. Acute exposure to FND ether amines by oral, dermal and inhalation may produce moderate to slight toxicity butrepeated skin contact can be highly irritating. However, exposure did not produce any organ-specific toxicity, genetic,reproductive or developmental defect same as in FND amines.The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure toirritants may produce conjunctivitis.The material may produce respiratory tract irritation, and result in damage to the lung including reduced lung function.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness,swelling, the production of vesicles, scaling and thickening of the skin.For alkyl polyamines:The alkyl polyamines cluster consists of two terminal primary and at least one secondary amine groups and arederivatives of low molecular weight ethylenediamine, propylenediamine or hexanediamine. Toxicity depends on route ofexposure. Cluster members have been shown to cause skin irritation or sensitisation, eye irritation and genetic defects,but have not been shown to cause cancer.The acute oral LD50 in the rat was estimated to be ~ 260 mg/kg. Dermal LD50 was determined to be greater than 600mg/kg pure substance. The substance (in 30% concentration) is severely irritating/ corrosive to the skin but was not asensitiser when tested in low concentrations. A 90-day oral toxicity study showed at higher doses (30 and 90 mg/kg/day),a dose related increase in some liver enzymes but, no treatment related effects at doses of 5 or 10 mg/kg/day. It was notfound to produce mutations in S. typhimurium, or the Chinese hamster V-79 cell line and there were no clastogenic effectsin the Chinese hamster V-79 cell line. NICNAS Public Report 1995
BIOGUARD PLUS &N-(3-aminopropyl)-N-
dodecyl-1,3-propanediamine
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to anon-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to highlevels of highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease ina non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documentedexposure to the irritant.Overexposure to most of these materials may cause adverse health effects.Many amine-based compounds can cause release of histamines, which, in turn, can trigger allergic and other physiologicaleffects, including constriction of the bronchi or asthma and inflammation of the cavity of the nose. Whole-bodysymptoms include headache, nausea, faintness, anxiety, a decrease in blood pressure, rapid heartbeat, itching, reddeningof the skin, urticaria (hives) and swelling of the face, which are usually transient.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious EyeDamage/Irritation
STOT - Single Exposure
Respiratory or Skinsensitisation
STOT - RepeatedExposure
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification – Data available to make classification
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
BIOGUARD PLUSENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
Not Available Not Available Not Available Not Available Not Available
N-(3-aminopropyl)-N-dodecyl-
1,3-propanediamine
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
LC50 96 Fish 0.431mg/L 2
EC50 48 Crustacea 0.073mg/L 2
EC50 96 Algae or other aquatic plants 0.054mg/L 2
NOEC 72 Algae or other aquatic plants 0.007mg/L 2
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - AquaticToxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic ToxicityData 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -Bioconcentration Data 8. Vendor Data
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water whencleaning equipment or disposing of equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.Prevent, by any means available, spillage from entering drains or water courses.
Chemwatch: 9-221869
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Ingredient Persistence: Water/Soil Persistence: Air
Ingredient Bioaccumulation
Ingredient Mobility
DO NOT discharge into sewer or waterways.
Persistence and degradability
No Data available for all ingredients No Data available for all ingredients
Bioaccumulative potential
No Data available for all ingredients
Mobility in soil
No Data available for all ingredients
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packagingdisposal
Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.
Otherwise:If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be usedto store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer tolaws operating in their area. In some areas, certain wastes must be tracked.
DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if nosuitable treatment or disposal facility can be identified. Treat and neutralise at an approved treatment plant.
Ensure that the hazardous substance is disposed in accordance with the Hazardous Substances (Disposal) Notice 2017
Disposal RequirementsPackages that have been in direct contact with the hazardous substance must be only disposed if the hazardous substance was appropriately removed and cleaned out from the package.The package must be disposed according to the manufacturer's directions taking into account the material it is made of.Packages which hazardous content have been appropriately treated and removed may be recycled.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant
HAZCHEM 2X
Land transport (UN)
UN number 2735
UN proper shippingname
AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Dodecyl dipropylene triamine)
Chemwatch: 9-221869
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Air transport (ICAO-IATA / DGR)
Sea transport (IMDG-Code / GGVSee)
Transport hazardclass(es)
Class 8
Subrisk Not Applicable
Packing group II
Environmental hazard Environmentally hazardous
Special precautions foruser
Special provisions 274
Limited quantity 1 L
UN number 2735
UN proper shippingname
Amines, liquid, corrosive, n.o.s. * (Dodecyl dipropylene triamine); Polyamines, liquid, corrosive, n.o.s. * (Dodecyldipropylene triamine)
Transport hazardclass(es)
ICAO/IATA Class 8
ICAO / IATA Subrisk Not Applicable
ERG Code 8L
Packing group II
Environmental hazard Environmentally hazardous
Special precautions foruser
Special provisions A3 A803
Cargo Only Packing Instructions 855
Cargo Only Maximum Qty / Pack 30 L
Passenger and Cargo Packing Instructions 851
Passenger and Cargo Maximum Qty / Pack 1 L
Passenger and Cargo Limited Quantity Packing Instructions Y840
Passenger and Cargo Limited Maximum Qty / Pack 0.5 L
UN number 2735
UN proper shippingname
AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Dodecyl dipropylene triamine)
Transport hazardclass(es)
IMDG Class 8
IMDG Subrisk Not Applicable
Packing group II
Environmental hazard Marine Pollutant
Special precautions foruser
EMS Number F-A , S-B
Special provisions 274
Limited Quantities 1 L
Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixtureThis substance is to be managed using the conditions specified in an applicable Group StandardHSR No 002684 - Water Treatment Chemicals (Subsidiary Hazard) Group Standard 2017.
N-(3-AMINOPROPYL)-N-DODECYL-1,3-PROPANEDIAMINE(2372-82-9*) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Chemwatch: 9-221869
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Version No: 8.9
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International Air Transport Association (IATA) Dangerous Goods Regulations
International Maritime Dangerous Goods Requirements (IMDG Code)
New Zealand Hazardous Substances and New Organisms (HSNO) Act -Classification of Chemicals
New Zealand Hazardous Substances and New Organisms (HSNO) Act -Classification of Chemicals - Classification Data
New Zealand Inventory of Chemicals (NZIoC)
United Nations Recommendations on the Transport of Dangerous GoodsModel Regulations (Chinese)
United Nations Recommendations on the Transport of Dangerous GoodsModel Regulations (English)
United Nations Recommendations on the Transport of Dangerous GoodsModel Regulations (Spanish)
Hazardous Substance LocationSubject to the Health and Safety at Work (Hazardous Substances) Regulations 2017.
Hazard ClassQuantity beyond which controls apply forclosed containers
Quantity beyond which controls apply when use occurring inopen containers
Not Applicable Not Applicable Not Applicable
Certified HandlerSubject to Part 4 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.
Class of substance Quantities
9.1A, 9.2A, 9.3A, and 9.4A Any quantity
Refer Group Standards for further information
Tracking RequirementsNot Applicable
National Inventory Status
National Inventory Status
Australia - AICS Yes
Canada - DSL Yes
Canada - NDSL No (N-(3-aminopropyl)-N-dodecyl-1,3-propanediamine)
China - IECSC Yes
Europe - EINEC / ELINCS /NLP
Yes
Japan - ENCS Yes
Korea - KECI No (N-(3-aminopropyl)-N-dodecyl-1,3-propanediamine)
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA Yes
Legend:Yes = All ingredients are on the inventoryNo = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specificingredients in brackets)
SECTION 16 OTHER INFORMATION
Revision Date 13/02/2018
Initial Date 13/02/2018
CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheetWilhelmsen Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: WSS.GLOBAL.SDSINFO@wilhelmsen.com - Telephone: Tel.:+31 10 4877775
Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards areRisks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Powered by AuthorITe, from Chemwatch.
Chemwatch: 9-221869
Catalogue number: 778918 (25L)
Version No: 8.9
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end of SDS
SAFETY DATA SHEET
CALCIUM CHLORIDE - FLAKE
Revision Date: 22-Jun-2016 Revision Number: 19
1. Product and Company Identification
Product Name Product Trade Name: CALCIUM CHLORIDE - FLAKE
Other Names Synonyms None
Hazardous Material Number: HM000142
Recommended Use Recommended Use Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number: +64 800 451719
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1D (Oral) Acutely Toxic Substances6.1E (Dermal) Acutely Toxic Substances6.3A Irritating to the skin6.4A Irritating to the eye9.3C Harmful to terrestrial vertebrates
Hazard and Precautionary Statements
Hazard pictograms
Signal Word Warning
Hazard Statements H302 - Harmful if swallowedH313 - May be harmful in contact with skinH315 - Causes skin irritationH319 - Causes serious eye irritationH433 - Harmful to the terrestrial vertebrates.
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_____________________________________________________________________________________________CALCIUM CHLORIDE - FLAKE Revision Date: 22-Jun-2016
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/eye protection/face protection
Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP331 - Do NOT induce vomitingP312 - Call a POISON CENTER or doctor/physician if you feel unwellP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attention
Storage None
Disposal P501 - Dispose of contents/container to an approved landfill
Contains
Substances CAS Number Substance HSNO Classification
Calcium chloride 10043-52-4 6.1D (Oral)6.1E (Dermal)6.3A6.4A9.3C
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Calcium chloride 10043-52-4 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water forat least 15 minutes and get medical attention immediately after flushing.
Skin Wash with soap and water. Get medical attention if irritation persists. Removecontaminated clothing and launder before reuse.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses eye irritation
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
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_____________________________________________________________________________________________CALCIUM CHLORIDE - FLAKE Revision Date: 22-Jun-2016
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireNone anticipated
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensureadequate ventilation. Wash hands after use. Launder contaminated clothing before reuse.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWACalcium chloride 10043-52-4 Not applicable Not applicable
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_____________________________________________________________________________________________CALCIUM CHLORIDE - FLAKE Revision Date: 22-Jun-2016
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 10
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure 1 mmHg
Vapor Density No data available
Specific Gravity 1.85
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight 111
VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials None known.
10.6. Hazardous decomposition products None known.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Physical State: Solid Color White
Odor: Odorless Odor Threshold: No information available
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_____________________________________________________________________________________________CALCIUM CHLORIDE - FLAKE Revision Date: 22-Jun-2016
Inhalation May cause mild respiratory irritation.
Eye Contact Causes eye irritation.
Skin Contact May cause mild skin irritation.
Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Calcium chloride 10043-52-4 > 1000 mg/kg (Rat)2301 mg/kg (Rat)
> 2000 mg/kg (Rat)2240 mg/kg (Rat)
5000 mg/kg (Rabbit) No data available
Substances CASNumber
Skin corrosion/irritation
Calcium chloride 10043-52-4 Causes mild skin irritation (Rabbit)
Substances CASNumber
Serious eye damage/irritation
Calcium chloride 10043-52-4 Causes moderate eye irritation (Rabbit)
Substances CASNumber
Skin Sensitization
Calcium chloride 10043-52-4 No information available
Substances CASNumber
Respiratory Sensitization
Calcium chloride 10043-52-4 No information available
Substances CASNumber
Mutagenic Effects
Calcium chloride 10043-52-4 Did not show mutagenic effects in animal experiments
Substances CASNumber
Carcinogenic Effects
Calcium chloride 10043-52-4 No information available
Substances CASNumber
Reproductive toxicity
Calcium chloride 10043-52-4 Animal testing did not show any effects on fertility.
Substances CASNumber
STOT - single exposure
Calcium chloride 10043-52-4 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
STOT - repeated exposure
Calcium chloride 10043-52-4 No information available.
Substances CASNumber
Aspiration hazard
Calcium chloride 10043-52-4 Not applicable
12. Ecological Information
12.1. Toxicity Ecotoxicity effects
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Product Ecotoxicity Data
_____________________________________________________________________________________________CALCIUM CHLORIDE - FLAKE Revision Date: 22-Jun-2016
No data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Calcium chloride 10043-52-4 ErC50 (72h) 2900 mg/L(Pseudokirchnerella
subcapitata)ErC50 (72h) 4000 mg/L
(Pseudokirchnerellasubcapitata)
LC50 (96h) 4630 mg/L(Pimephales promelas)LC50 (48h) >6560 mg/L(Pimephales promelas)LC50 (24h) >6660 mg/L(Pimephales promelas)
No information available EC50 (48h) 2400 mg/L(Daphnia magna)
EC50 (21d) 610 mg/L(reproduction) (Daphnia
magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Calcium chloride 10043-52-4 The methods for determiningbiodegradability are not applicable toinorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Calcium chloride 10043-52-4 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Calcium chloride 10043-52-4 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
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_____________________________________________________________________________________________CALCIUM CHLORIDE - FLAKE Revision Date: 22-Jun-2016
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR003389
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDOSHAECHA C&L
Revision Date: 22-Jun-2016
Revision NoteSDS sections updated:15
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
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SAFETY DATA SHEET
CAL-SEAL 60
Revision Date: 01-Jun-2018 Revision Number: 20
1. Identification
Product Name Product Trade Name: CAL-SEAL 60
Other Names Synonyms None
Hazardous Material Number: HM000146
Recommended Use Recommended Use Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Non-hazardous
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_____________________________________________________________________________________________CAL-SEAL 60 Revision Date: 01-Jun-2018
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireNot applicable
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
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6.3. Methods and material for containment and cleaning up
_____________________________________________________________________________________________CAL-SEAL 60 Revision Date: 01-Jun-2018
Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location. Product has a shelf life of 24 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust levels.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 10.4
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Physical State: Solid Color White
Odor: Odorless Odor Threshold:
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No information available
_____________________________________________________________________________________________CAL-SEAL 60 Revision Date: 01-Jun-2018
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 2.7
Water Solubility Partly soluble
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight 145
VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials None known.
10.6. Hazardous decomposition products None known.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation None known.
Eye Contact Non-irritating to rabbit's eye
Skin Contact Not irritating to skin in rabbits.
Ingestion May act as obstruction if swallowed.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
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_____________________________________________________________________________________________CAL-SEAL 60 Revision Date: 01-Jun-2018
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
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_____________________________________________________________________________________________CAL-SEAL 60 Revision Date: 01-Jun-2018
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-Hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
_____________________________________________________________________________________________
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Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
_____________________________________________________________________________________________CAL-SEAL 60 Revision Date: 01-Jun-2018
National Toxicology Program (NTP)
Revision Date: 01-Jun-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
CAUSTIC SODA
Revision Date: 14-Sep-2018 Revision Number: 38
1. Identification
Product Name Product Trade Name: CAUSTIC SODA
Other Names Synonyms None
Hazardous Material Number: HM003599
Recommended Use Recommended Use pH Control
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
136-140 Connett Road East,Bell Block, New PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1D (Oral) Substances that are acutely toxic - Harmful6.1D (Dermal) Substances that are acutely toxic - Harmful8.1A Corrosive to metals8.2B Corrosive to dermal tissue if exposed for greater than 3 mins.8.3A Corrosive to ocular tissue9.1D Slightly harmful in the aquatic environment9.3C Harmful to terrestrial vertebrates
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Danger
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_____________________________________________________________________________________________CAUSTIC SODA Revision Date: 14-Sep-2018
Hazard Statements H290 - May be corrosive to metalsH302 - Harmful if swallowedH312 - Harmful in contact with skinH314 - Causes severe skin burns and eye damageH315 - Causes skin irritationH402 - Harmful to aquatic lifeH433 - Harmful to the terrestrial vertebrates.
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P234 - Keep only in original packaging.P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/eye protection/face protection
Response P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomitingP303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water [or shower].P363 - Wash contaminated clothing before reuseP304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable forbreathing.P310 - Immediately call a POISON CENTER or doctor/physicianP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP390 - Absorb spillage to prevent material damage
Storage P405 - Store locked up
Disposal P501 - Dispose of contents/container to an approved landfill
Contains
Substances CAS Number Substance HSNO Classification
Sodium hydroxide 1310-73-2 6.1D (Oral)6.1D (Dermal)8.1A8.2B8.3A9.1D (Crustacean, Fish)9.3C
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Sodium hydroxide 1310-73-2 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, move victim to fresh air and seek medical attention.
Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek promptmedical attention.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 30minutes and remove contaminated clothing, shoes and leather goods immediately. Getmedical attention immediately.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
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_____________________________________________________________________________________________CAUSTIC SODA Revision Date: 14-Sep-2018
Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes severe skin irritation with tissue destruction. May causerespiratory irritation. Harmful if swallowed.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: 2W
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireMay form explosive mixtures with strong acids. Reaction with steel and certain other metals generates flammable hydrogengas.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid creating and breathing dust. Ensureadequate ventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. Consult local authorities.
6.3. Methods and material for containment and cleaning up Neutralize to pH of 6-8. Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensureadequate ventilation. Wash hands after use. Launder contaminated clothing before reuse.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from acids. Store in a cool, dry location. Store locked up.
Store Site Requirements
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_____________________________________________________________________________________________CAUSTIC SODA Revision Date: 14-Sep-2018
No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWASodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust levels.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Nitrile gloves. Butyl rubber gloves. (>= 0.7 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.
Skin Protection Full protective chemical resistant clothing. Rubber boots
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 14
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range 1390 °C / 2535 °F
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 2.13
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
Physical State: Solid Color White to off white
Odor: Odorless Odor Threshold:
_____________________________________________________________________________________________
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No information available
_____________________________________________________________________________________________CAUSTIC SODA Revision Date: 14-Sep-2018
9.2. Other information Molecular Weight 40
VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Contact with acids. Peroxides. Halogenated compounds. Prolonged contact with aluminum, lead, or zinc may liberateflammable hydrogen.
10.6. Hazardous decomposition products None known.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation Causes severe respiratory irritation.
Eye Contact Causes severe eye burns.
Skin Contact Causes severe burns.
Ingestion Causes burns of the mouth, throat and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Sodium hydroxide 1310-73-2 Not applicable due to corrosivityof the substance.
Not applicable due to corrosivityof the substance.
Not applicable due to corrosivityof the substance.
Substances CASNumber
Skin corrosion/irritation
Sodium hydroxide 1310-73-2 Causes severe burns
Substances CASNumber
Serious eye damage/irritation
Sodium hydroxide 1310-73-2 Causes severe eye burns (Rabbit)
Substances CASNumber
Skin Sensitization
Sodium hydroxide 1310-73-2 Did not cause sensitization on laboratory animals (guinea pig)
Substances CASNumber
Respiratory Sensitization
Sodium hydroxide 1310-73-2 No information available
Substances CASNumber
Mutagenic Effects
Sodium hydroxide 1310-73-2 Did not show mutagenic effects in animal experiments In vitro tests did not show mutagenic effects.
Substances CASNumber
Carcinogenic Effects
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_____________________________________________________________________________________________CAUSTIC SODA Revision Date: 14-Sep-2018
Sodium hydroxide 1310-73-2 No data of sufficient quality are available.
Substances CASNumber
Reproductive toxicity
Sodium hydroxide 1310-73-2 No information available
Substances CASNumber
STOT - single exposure
Sodium hydroxide 1310-73-2 May cause respiratory irritation.
Substances CASNumber
STOT - repeated exposure
Sodium hydroxide 1310-73-2 No significant toxicity observed in animal studies at concentration requiring classification. Notapplicable due to corrosivity of the substance.
Substances CASNumber
Aspiration hazard
Sodium hydroxide 1310-73-2 Not applicable
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Sodium hydroxide 1310-73-2 No information available LC50(48h) 189 mg/L(Leuciscus idus
melanotus)LLC50(48h) 189 mg/L(Leuciscus melanotus)LC50(24h) 145 mg/L(Poecilia reticulate)
LC50(96h) 125 mg/L(Gambusia affinis)
LOEL(150 d) = 25 mg/L(Lebistes reticulatus)
No information available EC50 (48h) 40.4 mg/L(Ceriodaphnia sp.)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Sodium hydroxide 1310-73-2 The methods for determiningbiodegradability are not applicable toinorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Bioaccumulation
Sodium hydroxide 1310-73-2 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Sodium hydroxide 1310-73-2 No information available
Ecotoxicity Hazard Statements Harmful to aquatic lifeHarmful to terrestrial vertebrates.
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
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13.1. Waste treatment methods
_____________________________________________________________________________________________CAUSTIC SODA Revision Date: 14-Sep-2018
Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection. Contaminated packaging may be disposed of by: rendering packagingincapable of containing any substance, or treating packaging to remove residualcontents, or treating packaging to make sure the residual contents are no longerhazardous, or by disposing of packaging into commercial waste collection.
14. Transport Information
NZ 5433.1999 UN Number UN1823
UN proper shipping name: Sodium Hydroxide, Solid
Transport Hazard Class(es): 8
Packing Group: II
Environmental Hazards: Not applicable
IMDG/IMO UN Number UN1823
UN proper shipping name: Sodium Hydroxide, Solid
Transport Hazard Class(es): 8
Packing Group: II
Environmental Hazards: Not applicable
EMS: EmS F-A, S-B
IATA/ICAO UN Number UN1823
UN proper shipping name: Sodium Hydroxide, Solid
Transport Hazard Class(es): 8
Packing Group: II
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR001547
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%
_____________________________________________________________________________________________CAUSTIC SODA Revision Date: 14-Sep-2018
LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 14-Sep-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
CFR-3L
Revision Date: 16-Sep-2016 Revision Number: 20
1. Product and Company Identification
Product Name Product Trade Name: CFR-3L
Other Names Synonyms None
Hazardous Material Number: HM000211
Recommended Use Recommended Use Friction Reducer
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number: +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable
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_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
2.3. Other Hazards None known
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up
_____________________________________________________________________________________________
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Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 7
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point > 98 °C / > 210 °F PMCC
Evaporation rate No data available
Physical State: Liquid Color Red
Odor: Musty Odor Threshold:
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No information available
_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.17
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
Liquid Density 9.75 lbs/gal
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation None known.
Eye Contact Non-irritating to rabbit's eye
Skin Contact Not irritating to skin in rabbits.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
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_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill or burn in an approved incinerator according to federal, state,
and local regulations. Substance should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999
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_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Not Hazrdous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers This product does NOT require an approved handler.
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 16-Sep-2016
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_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
Revision NoteSDS sections updated:9
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
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SAFETY DATA SHEET
CITRIC ACID
1. Product and Company Identification
Product Name Product Trade Name: CITRIC ACID
Other Names Synonyms: None
Product Code: HM004421
Recommended Use Recommended Use Scale Remover; pH Control
Uses Advised Against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-Mail address: fdunexchem@halliburton.com
Emergency Telephone Number +64-6-7559274
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1E (Inhalation) Acutely Toxic Substances6.3B Mildly irritating to the skin8.3A Corrosive to ocular tissue
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Danger
Hazard Statements H316 - Causes mild skin irritationH318 - Causes serious eye damageH333 - May be harmful if inhaled
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at hand
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Revision Date: 14-May-2015 Revision Number: 33
_____________________________________________________________________________________________P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P280 - Wear eye protection/face protection
Response P304 + P312 - IF INHALED: Call a POISON CENTER or doctor/physician if you feelunwellP331 - Do NOT induce vomitingP332 + P313 - If skin irritation occurs: Get medical advice/attentionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Storage None
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
Contains
Substances CAS Number Substance HSNO Classification
Citric acid 77-92-9 6.1E (Inhalation)6.3B8.3A
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)
Citric acid 77-92-9 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Getimmediate medical attention.
Skin For skin contact, wipe away excess material with dry towel. Then wash affected areaswith plenty of water, and soap if available, for several minutes. Get medical attention ifirritation occurs.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses eye irritation. Causes eye irritation
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardCombustible dust when in finely divided and highly suspended state.
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
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CITRIC ACID Revision Date: 14-May-2015
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Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special Exposure HazardsDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location. Product has a shelf life of 60 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWA
Citric acid 77-92-9 Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard
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CITRIC ACID Revision Date: 14-May-2015
_____________________________________________________________________________________________EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Nitrile gloves. (>= 0.35 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 1.8
Freezing Point/Range No data available
Melting Point/Range 153 °C / 307.4 °F
Boiling Point/Range Decomposes
Flash Point 345 °C / 653 °F
upper flammability limit 65
lower flammability limit %
Evaporation rate No data available
Vapor Pressure 0.00000221 Pa
Vapor Density No data available
Specific Gravity 1.66
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water -1.61 to -1.80
Autoignition Temperature 1010 °C / 1832 °F
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight 192.12
VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical Stability Stable
10.4. Conditions to Avoid None anticipated
10.5. Incompatible Materials Strong alkalis.
10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide.
Hazardous Reactions
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Physical State: Solid Color: White
CITRIC ACID
Odor: Odorless
Revision Date: 14-May-2015
Odor Threshold: No information available
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Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact Causes eye irritation.
Skin Contact May cause mild skin irritation.
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,nausea, and diarrhea.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Citric acid 77-92-9 5400 mg/kg (Rat)5790 mg/kg (Mouse)11,700 mg/kg (Rat)
> 2000 mg/kg No data available
Substances CASNumber
Skin corrosion/irritation
Citric acid 77-92-9 Not irritating to skin in rabbits.
Substances CASNumber
Eye damage/irritation
Citric acid 77-92-9 Causes severe eye irritation.
Substances CASNumber
Skin Sensitization
Citric acid 77-92-9 Patch test on human volunteers did not demonstrate sensitization properties
Substances CASNumber
Respiratory Sensitization
Citric acid 77-92-9 No information available
Substances CASNumber
Mutagenic Effects
Citric acid 77-92-9 Did not show mutagenic effects in animal experiments
Substances CASNumber
Carcinogenic Effects
Citric acid 77-92-9 Did not show carcinogenic effects in animal experiments
Substances CASNumber
Reproductive toxicity
Citric acid 77-92-9 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.
Substances CASNumber
STOT - single exposure
Citric acid 77-92-9 No data of sufficient quality are available.
Substances CASNumber
STOT - repeated exposure
Citric acid 77-92-9 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
Aspiration hazard
Citric acid 77-92-9 No adverse health effects are expected from swallowing.
12. Ecological Information
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Revision Date: 14-May-2015CITRIC ACID
_____________________________________________________________________________________________
12.1. Toxicity Ecotoxicity Effects
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Citric acid 77-92-9 NOEC (8d) 425 mg/L(cell density)
(Scenedesmusquadricauda)
LOEC (8d) >80 mg/L(Microcystis aeruginosa)
LC50 (96h) 1516 mg/L(Lepomis macrochirus)LC50 (48h) 440 mg/L
(Leuciscus idusmelanotus)
LC50 (96h) >100 mg/L(Pimephales promelas)
TT (72h) 485 mg/L(Entosiphon sulcatum)
TLM96 100-330 ppm(Crangon crangon)
EC50 (24h) 1535 mg/L(Daphnia magna)
LC50 (48h) 160 mg/L(Daphnia magna)
EC50 (48h) >50 mg/L(Daphnia magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Citric acid 77-92-9 Readily biodegradable (97% @ 28d)
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Citric acid 77-92-9 -1.61 to -1.80
12.4. Mobility in soil
Substances CAS Number Mobility
Citric acid 77-92-9 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
IMDG/IMO UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
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CITRIC ACID Revision Date: 14-May-2015
_____________________________________________________________________________________________
IATA/ICAO UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User: None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
Group Name Not Applicable
ERMA Register Approval Number HSR003138
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
The following sections have been revised since the last issue of this SDSNot applicable
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key literature references and sources for datawww.ChemADVISOR.com/OSHAECHA C&LNZ CCID
Revision Date: 14-May-2015
Revision Note Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
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CITRIC ACID Revision Date: 14-May-2015
SAFETY DATA SHEET
CEMENT - CLASS G
Revision Date: 30-Jul-2018 Revision Number: 37
1. Identification
Product Name Product Trade Name: CEMENT - CLASS G
Other Names Synonyms None
Hazardous Material Number: HM001839
Recommended Use Recommended Use Cement
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
136-140 Connett Road East,Bell Block, New PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1E (Inhalation) Acutely Toxic Substances8.2C Corrosive to dermal tissue if exposed for greater than 1 hour8.3A Corrosive to ocular tissue6.5B Contact sensitiser6.7A Known or presumed human carcinogen6.9A Toxic to human target organs or systems
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Danger
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_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 30-Jul-2018
Hazard Statements H314 - Causes severe skin burns and eye damageH318 - Causes serious eye damageH350i - May cause cancer by inhalationH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH333 - May be harmful if inhaledH317 - May cause an allergic skin reaction
Precautionary Statements
Prevention P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP272 - Contaminated work clothing should not be allowed out of the workplaceP280 - Wear protective gloves/eye protection/face protectionP281 - Use personal protective equipment as required
Response P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomitingP303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water [or shower].P353 - Rinse skin with water [or shower].P363 - Wash contaminated clothing before reuseP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP304 + P312 - IF INHALED: Call a POISON CENTER or doctor/physician if you feelunwellP308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell
Storage P405 - Store locked up
Disposal P501 - Dispose of contents/container to an approved landfill
Contains
Substances CAS Number Substance HSNO Classification
Portland cement 65997-15-1 6.1E (Inh)8.2C8.3A6.5B
Crystalline silica, quartz 14808-60-7 6.7A6.9A
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Portland cement 65997-15-1 60 - 100%Crystalline silica, quartz 14808-60-7 1 - 5%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek promptmedical attention.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15minutes. Get medical attention.
Ingestion Under normal conditions, first aid procedures are not required.
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_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 30-Jul-2018
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. May causerespiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silicahas also been associated with scleroderma and kidney disease.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaNone - does not burn.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireNot applicable
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation. Evacuate all persons from the area.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite, and/or tridymite which may becomeairborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation tokeep exposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalentrespirator when using this product. Material is slippery when wet. Wash hands after use. Launder contaminated clothingbefore reuse.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
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_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 30-Jul-2018
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Usegood housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Product hasa shelf life of 24 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAPortland cement 65997-15-1 TWA: 10 mg/m3 TWA: 1 mg/m3
Crystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
Engineering Controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures
below applicable exposure limits.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.
Hand Protection Impervious rubber gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be launderedbefore reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 12.4
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 3.14
Water Solubility No data available
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Physical State: Solid Color Gray
Odor: Odorless Odor Threshold:
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No information available
_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 30-Jul-2018
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid Keep away from any contact with water.
10.5. Incompatible materials Hydrofluoric acid.
10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation Causes moderate respiratory irritation. Inhaled crystalline silica in the form of quartz orcristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).There is sufficient evidence in experimental animals for the carcinogenicity of tridymite(IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanentlung damage may be occurring. Inhalation of dust may also have serious chronic healtheffects (See "Chronic Effects/Carcinogenicity" subsection below).
Eye Contact Causes severe eye irritation which may damage tissue.
Skin Contact Causes skin irritation. May cause alkali burns with confined contact. May cause anallergic skin reaction. Can dry skin.
Ingestion Causes burns of the mouth, throat and stomach.
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis. Symptomsinclude cough, shortness of breath, wheezing, non-specific chest illness, and reducedpulmonary function. This disease is exacerbated by smoking. Individuals with silicosisare predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimental animalsfor the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer toIARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) inconjunction with the use of these minerals. The National Toxicology Program classifiesrespirable crystalline silica as "Known to be a human carcinogen". Refer to the 9thReport on Carcinogens (2000). The American Conference of Governmental IndustrialHygienists (ACGIH) classifies crystalline silica, quartz, as a suspected humancarcinogen (A2). There is some evidence that breathing respirable crystalline silica orthe disease silicosis is associated with an increased incidence of significant diseaseendpoints such as scleroderma (an immune system disorder manifested by scarring ofthe lungs, skin, and other internal organs) and kidney disease.
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Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Portland cement 65997-15-1 > 2000 mg/kg (Rat) > 2000 mg/kg > 1 mg/L (Rat) 4h
Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available
Substances CASNumber
Skin corrosion/irritation
Portland cement 65997-15-1 Irritating to skin. (Rabbit)
Crystalline silica, quartz 14808-60-7 Non-irritating to the skin
Substances CASNumber
Serious eye damage/irritation
Portland cement 65997-15-1 Corrosive to eyes
Crystalline silica, quartz 14808-60-7 Non-irritating to the eye
Substances CASNumber
Skin Sensitization
Portland cement 65997-15-1 May cause sensitization by skin contact
Crystalline silica, quartz 14808-60-7 No information available.
Substances CASNumber
Respiratory Sensitization
Portland cement 65997-15-1 No information available
Crystalline silica, quartz 14808-60-7 No information available
Substances CASNumber
Mutagenic Effects
Portland cement 65997-15-1 No data of sufficient quality are available.
Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Substances CASNumber
Carcinogenic Effects
Portland cement 65997-15-1 No data of sufficient quality are available.
Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.
Substances CASNumber
Reproductive toxicity
Portland cement 65997-15-1 No data of sufficient quality are available.
Crystalline silica, quartz 14808-60-7 No information available
Substances CASNumber
STOT - single exposure
Portland cement 65997-15-1 May cause respiratory irritation.
Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
STOT - repeated exposure
Portland cement 65997-15-1 No data of sufficient quality are available.
Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CASNumber
Aspiration hazard
Portland cement 65997-15-1 Not applicable
Crystalline silica, quartz 14808-60-7 Not applicable
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
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_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 30-Jul-2018
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Portland cement 65997-15-1 No information available No information available No information available No information available
Crystalline silica,quartz
14808-60-7 EC50 (72 h) =440 mg/L(Selenastrum
capricornutum)(similarsubstance)
LL0 (96 h) =10000 mg/L(Danio rerio)(similar
substance)
No information available LL50 (24 h) >10000mg/L (Daphniamagna)(similar
substance)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Portland cement 65997-15-1 The methods for determiningbiodegradability are not applicable toinorganic substances.
Crystalline silica, quartz 14808-60-7 The methods for determiningbiodegradability are not applicable toinorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Portland cement 65997-15-1 No data available
Crystalline silica, quartz 14808-60-7 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Portland cement 65997-15-1 No information available
Crystalline silica, quartz 14808-60-7 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance
should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
_____________________________________________________________________________________________
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_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 30-Jul-2018
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002543
Group Name Construction Products (Corrosive and Toxic 6.7 HSR002543)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers This product does NOT require an approved handler.
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 30-Jul-2018
Revision NoteUpdate to Format
_____________________________________________________________________________________________
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Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination of
_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 30-Jul-2018
suitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
CLAY GRABBER®
Revision Date: 26-Jan-2018 Revision Number: 31
1. Identification
Product Name Product Trade Name: CLAY GRABBER®
Other Names Synonyms None
Hazardous Material Number: HM004931
Recommended Use Recommended Use Viscosifier
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Hydrotreated light petroleum distillate 64742-47-8 6.1E (Aspiration
Ethoxylated branched C13 alcohol 78330-21-9 6.1D (Oral)6.3A
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_____________________________________________________________________________________________CLAY GRABBER® Revision Date: 26-Jan-2018
8.3a9.1D
2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Hydrotreated light petroleum distillate 64742-47-8 10 - 30%Ethoxylated branched C13 alcohol 78330-21-9 1 - 5%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists. Wash offimmediately with soap and plenty of water for at least 15 minutes while removing allcontaminated clothing and shoes. Flush skin with large amounts of water. If irritationpersists, get medical attention.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNot a Flammable Hazard.
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
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Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.
_____________________________________________________________________________________________CLAY GRABBER® Revision Date: 26-Jan-2018
See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
Prevent product from entering drains
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequateventilation. Wash hands after use. Launder contaminated clothing before reuse.
HandlingAvoid contact with skin, eyes and clothing. Do not breathing vapors or spray mist. Wash thoroughly after handling Remove andwash contaminated clothing before re-use
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container closed when not in use. Keep fromfreezing. Product has a shelf life of 12 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAHydrotreated light petroleumdistillate
64742-47-8 Not applicable Not applicable
Ethoxylated branched C13alcohol
78330-21-9 Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Organic vapor respirator.
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeation
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_____________________________________________________________________________________________CLAY GRABBER® Revision Date: 26-Jan-2018
time as per EN 374): Nitrile gloves. (>= 0.35 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pHpH: 6.5 - 7.5
Freezing Point / Range -15 °C
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point > 392 °C / PMCC
Evaporation rate No data available
Vapor Pressure 0.002
Vapor Density No data available
Specific Gravity 1.04
Water Solubility Miscible with water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity 75 - 125 mm2/s @ 40 °C
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers. Contact with metals.
10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Physical State: Liquid Physical State Liquid
Color Off white Appearance Off-white
Odor: Mild hydrocarbon Odor Mild, Hydrocarbon-like
Odor Threshold: No information available
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_____________________________________________________________________________________________CLAY GRABBER® Revision Date: 26-Jan-2018
Inhalation May cause mild respiratory irritation.
Eye Contact In vitro tests indicate that the product is not an eye irritant.
Skin Contact May cause mild skin irritation.
Ingestion May cause mild gastric distress.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Hydrotreated lightpetroleum distillate
64742-47-8 >5000 mg/kg-bw (rat) (similarsubstance)
>2000 mg/kg-bw (rabbit) (similarsubstance)
>5.2 mg/L (rat, 4 h, vapor)(similar substance)
Ethoxylated branchedC13 alcohol
78330-21-9 1600 mg/kg-bw (rat) (similarsubstance)
>2000 mg/kg-bw (rabbit) (similarsubstance)
>0.22 mg/L (rat, 4h, aerosol,saturated) (similar substance)
Substances CASNumber
Skin corrosion/irritation
Hydrotreated lightpetroleum distillate
64742-47-8 Non-irritating to the skin (similar substances)
Ethoxylated branched C13alcohol
78330-21-9 Skin, rabbit: Causes moderate skin irritation. (similar substances)
Substances CASNumber
Serious eye damage/irritation
Hydrotreated lightpetroleum distillate
64742-47-8 Non-irritating to rabbit's eye (similar substances)
Ethoxylated branched C13alcohol
78330-21-9 Eye, rabbit: Causes severe eye irritation which may damage tissue. (similar substances)
Substances CASNumber
Skin Sensitization
Hydrotreated lightpetroleum distillate
64742-47-8 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)
Ethoxylated branched C13alcohol
78330-21-9 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)
Substances CASNumber
Respiratory Sensitization
Hydrotreated lightpetroleum distillate
64742-47-8 Based on available data, the classification criteria are not met.
Ethoxylated branched C13alcohol
78330-21-9 Based on available data, the classification criteria are not met.
Substances CASNumber
Mutagenic Effects
Hydrotreated lightpetroleum distillate
64742-47-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects. (similarsubstances)
Ethoxylated branched C13alcohol
78330-21-9 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects. (similarsubstances)
Substances CASNumber
Carcinogenic Effects
Hydrotreated lightpetroleum distillate
64742-47-8 Did not show carcinogenic effects in animal experiments (similar substances)
Ethoxylated branched C13alcohol
78330-21-9 Did not show carcinogenic effects in animal experiments (similar substances)
Substances CASNumber
Reproductive toxicity
Hydrotreated lightpetroleum distillate
64742-47-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments. (similar substances)
Ethoxylated branched C13alcohol
78330-21-9 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments. (similar substances)
Substances CASNumber
STOT - single exposure
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_____________________________________________________________________________________________CLAY GRABBER® Revision Date: 26-Jan-2018
Hydrotreated lightpetroleum distillate
64742-47-8 No significant toxicity observed in animal studies at concentration requiring classification.
Ethoxylated branched C13alcohol
78330-21-9 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Substances CASNumber
STOT - repeated exposure
Hydrotreated lightpetroleum distillate
64742-47-8 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Ethoxylated branched C13alcohol
78330-21-9 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Substances CASNumber
Aspiration hazard
Hydrotreated lightpetroleum distillate
64742-47-8 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,wheezing, coughing up blood and pneumonia, which can be fatal.
Ethoxylated branched C13alcohol
78330-21-9 Based on available data, the classification criteria are not met.
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Hydrotreated lightpetroleum distillate
64742-47-8 ErL50(72 h)>10000 mg/L(Skeletonema costatum)
LC50(96 h)>10000 mg/L(Scophthalmus
maximus)NOELC(28 d)>1000
mg/L (fish)
No information available LC50(48 h)>10000 mg/L(Acartia tonsa)
NOEC(21 d)=1000 mg/L(Daphnia magna)
Ethoxylated branchedC13 alcohol
78330-21-9 IC50(72 h)=1-10 mg/L(Desmodesmus
subspicatus)
LC50(96 h)=1-10 mg/L(Cyprinus carpio)
No information available EC50(48 h)=1-10 mg/L(Daphnia magna)
NOAEC (21d) 0.77 mg/L(Daphnia magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Hydrotreated light petroleum distillate 64742-47-8 Readily biodegradable (68.1% @ 28d)
Ethoxylated branched C13 alcohol 78330-21-9 Readily biodegradable (> 60% @ 28d)
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Hydrotreated light petroleum distillate 64742-47-8 No data available
Ethoxylated branched C13 alcohol 78330-21-9 Not Bioaccumulative; BCF = 12.7 - 237L/Kg
12.4. Mobility in soil
Substances CAS Number Mobility
Hydrotreated light petroleum distillate 64742-47-8 No information available
Ethoxylated branched C13 alcohol 78330-21-9 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________CLAY GRABBER® Revision Date: 26-Jan-2018
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
Page 7 / 8
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limit
_____________________________________________________________________________________________CLAY GRABBER® Revision Date: 26-Jan-2018
ppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 26-Jan-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
CLAY SYNC™ IIRevision Date: 05-Feb-2018 Revision Number: 21
1. Identification
Product Name Product Trade Name: CLAY SYNC™ II
Other Names Synonyms None
Hazardous Material Number: HM006277
Recommended Use Recommended Use Shale stabilizer
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable
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_____________________________________________________________________________________________CLAY SYNC™ II Revision Date: 05-Feb-2018
2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardCombustible dust when in finely divided and highly suspended state.
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
6.2. Environmental precautions
_____________________________________________________________________________________________
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Prevent from entering sewers, waterways, or low areas.
_____________________________________________________________________________________________CLAY SYNC™ II Revision Date: 05-Feb-2018
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use.Slippery when wet. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a dry location. Store between 40.5 F (4.7 C) and 120.5 F (49 C). Product has a shelf life of24 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls A well ventilated area to control dust levels.
Personal Protective Equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties Physical State: Granules Color Off white
Odor: Odorless Odor Threshold: No information available
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_____________________________________________________________________________________________CLAY SYNC™ II Revision Date: 05-Feb-2018
Property Values Remarks/ - Method
pH: 6.5-7.5 (1%)
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.04
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight 500,000-750,000 g/mole
VOC Content (%) No data available
Bulk Density 50 lbs/ft3 @ 20 C
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competent
NA No data available No data available No data available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________CLAY SYNC™ II Revision Date: 05-Feb-2018
authority
12. Ecological Information
12.1. Toxicity Ecotoxicity effectsContains no substances known to be hazardous to the environment.
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
_____________________________________________________________________________________________
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14. Transport Information
_____________________________________________________________________________________________CLAY SYNC™ II Revision Date: 05-Feb-2018
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic meter
_____________________________________________________________________________________________CLAY SYNC™ II Revision Date: 05-Feb-2018
mm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/
Revision Date: 05-Feb-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
DEXTRID® LTE
Revision Date: 10-Sep-2018 Revision Number: 31
1. Identification
Product Name Product Trade Name: DEXTRID® LTE
Other Names Synonyms None
Hazardous Material Number: HM003615
Recommended Use Recommended Use Fluid Loss Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
136-140 Connett Road East,Bell Block, New PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances in NA Non-hazardous
_____________________________________________________________________________________________
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_____________________________________________________________________________________________DEXTRID® LTE Revision Date: 10-Sep-2018
concentrations above cut-off values according tothe competent authority
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardCombustible dust when in finely divided and highly suspended state.
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential. Decomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid creating and breathing dust. Ensureadequate ventilation.See Section 8 for additional information
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_____________________________________________________________________________________________DEXTRID® LTE Revision Date: 10-Sep-2018
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Avoid dust accumulations. Ensure adequateventilation. Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 12 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.
Hand Protection Use gloves which are suitable for the chemicals present in this product as well as otherenvironmental factors in the workplace.
Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain jacket,pants or coverall, as appropriate, to prevent skin contact.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
_____________________________________________________________________________________________
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9. Physical and Chemical Properties
_____________________________________________________________________________________________DEXTRID® LTE Revision Date: 10-Sep-2018
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 10
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.5
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid Keep away from heat, sparks and flame.
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances in
NA No data available No data available No data available
Physical State: Powder Color White to off white
Odor: Musty Odor Threshold: No information available
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_____________________________________________________________________________________________DEXTRID® LTE Revision Date: 10-Sep-2018
concentrations abovecut-off values accordingto the competentauthority
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Bioaccumulation
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________DEXTRID® LTE Revision Date: 10-Sep-2018
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
Page 6 / 7
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - Celsius
_____________________________________________________________________________________________DEXTRID® LTE Revision Date: 10-Sep-2018
IATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/
Revision Date: 10-Sep-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
ECONOLITE LIQUID
Revision Date: 02-Aug-2016 Revision Number: 36
1. Product and Company Identification
Product Name Product Trade Name: ECONOLITE LIQUID
Other Names Synonyms None
Hazardous Material Number: HM000478
Recommended Use Recommended Use Light Weight Cement Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number: +64 800 451719
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1E (Oral) Acutely Toxic Substances6.3A Irritating to the skin8.3A Corrosive to ocular tissue
Hazard and Precautionary Statements
Hazard pictograms
Signal Word Danger
Hazard Statements H303 - May be harmful if swallowedH315 - Causes skin irritationH318 - Causes serious eye damage
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at hand
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 02-Aug-2016
P102 - Keep out of reach of childrenP103 - Read label before useP264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/eye protection/face protection
Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Storage None
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
Contains
Substances CAS Number Substance HSNO Classification
Sodium silicate 1344-09-8 6.1E (oral)6.3A8.3A
2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Sodium silicate 1344-09-8 30 - 60%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water forat least 15 minutes and get medical attention immediately after flushing.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15minutes. Get medical attention. Remove contaminated clothing and launder beforereuse.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code
_____________________________________________________________________________________________
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 02-Aug-2016
Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Neutralize to pH of 6-8. Scoop up andremove. Do NOT spread spilled product with water.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing before reuse. Avoid breathingvapors. Avoid breathing mist. Ensure adequate ventilation. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from acids. Store in a cool well ventilated area. Keep container closed when not in use.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWASodium silicate 1344-09-8 Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without
good cross ventilation.
Personal Protective Equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 02-Aug-2016
Dust/mist respirator. (N95, P2/P3)
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): (>= 0.4 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result ofthe many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.
Skin Protection Full protective chemical resistant clothing.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 11.2
Freezing Point / Range -1 °C
Melting Point / Range No data available
Boiling Point / Range 101 °C / 214 °F
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.4
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong acids. Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.
10.6. Hazardous decomposition products Hydrogen
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Physical State: Liquid Color Clear to hazy
Odor: Slightly soapy Odor Threshold: No information available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 02-Aug-2016
Inhalation May cause respiratory irritation.
Eye Contact Causes severe eye irritation which may damage tissue.
Skin Contact Causes skin irritation.
Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Sodium silicate 1344-09-8 3400 mg/kg (Rat) > 5000 mg/kg (Rat) (similarsubstance)
> 2.06 mg/L (Rat) 4h (similarsubstance – Potassium silicate)
Substances CASNumber
Skin corrosion/irritation
Sodium silicate 1344-09-8 Causes moderate skin irritation. (Rabbit)
Substances CASNumber
Serious eye damage/irritation
Sodium silicate 1344-09-8 Causes severe eye irritation which may damage tissue. (Rabbit)
Substances CASNumber
Skin Sensitization
Sodium silicate 1344-09-8 Did not cause sensitization on laboratory animals (mouse) (similar substances)
Substances CASNumber
Respiratory Sensitization
Sodium silicate 1344-09-8 No information available
Substances CASNumber
Mutagenic Effects
Sodium silicate 1344-09-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
Substances CASNumber
Carcinogenic Effects
Sodium silicate 1344-09-8 No information available
Substances CASNumber
Reproductive toxicity
Sodium silicate 1344-09-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments. (similar substances)
Substances CASNumber
STOT - single exposure
Sodium silicate 1344-09-8 No information available.
Substances CASNumber
STOT - repeated exposure
Sodium silicate 1344-09-8 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
Aspiration hazard
Sodium silicate 1344-09-8 Not applicable
12. Ecological Information
12.1. Toxicity Ecotoxicity effects
_____________________________________________________________________________________________
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Product Ecotoxicity DataNo data available
_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 02-Aug-2016
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Sodium silicate 1344-09-8 EC50 (72h) > 345 mg/L(growth rate)
(Scenedesmussubspicatus)
EC0 (72h) 35 mg/L(growth rate)
(Scenedesmussubspicatus)
LC50 (96h) 1108 mg/L(Danio rerio)
LC50 (96h) 260 – 310mg/L (Oncorhynchus
mykiss)
EC0 (0.5h) 3454 mg/L(Pseudomonas putida)
EC50 (48h) 1700 mg/L(Daphnia magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Sodium silicate 1344-09-8 The methods for determiningbiodegradability are not applicable toinorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Sodium silicate 1344-09-8 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Sodium silicate 1344-09-8 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
_____________________________________________________________________________________________
Page 6 / 7
_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 02-Aug-2016
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR003640
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: S5
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 02-Aug-2016
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
EMBR11720A
1 / 9 First issue: 24.05.2018 Version Number: 1.0 Date issued: 23.09.2018
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : EMBR11720A
Other means of identification : Not applicable.
Recommended use : DEMULSIFIER
Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.
Company : Ecolab New Zealand T/A Nalco New Zealand 2 Daniel Place Te Rapa, Hamilton New Zealand TEL: +64 7 958 2319 FAX: +64 7 958 2361
Emergency telephone number
: 0800 625 253, +64 7 958 2372 (International)
Issuing date : 23.09.2018
Section: 2. HAZARDS IDENTIFICATION
HSNO Hazard classification
Flammable Liquids : 3.1 C Acute toxicity (Oral) : 6.1 E Acute toxicity (Dermal) : 6.1 D Acute toxicity (Inhalation) : 6.1 E Skin irritation : 6.3 A Eye irritation : 6.4 A Carcinogenicity : 6.7 B Specific Target Organ Systemic Toxicity (Single Exposure or Repeated Exposure)
: 6.9 B
Aquatic toxicity (Acute or Chronic)
: 9.1 C
Ecotoxic to terrestrial vertebrates
: 9.3 C
GHS Label element
Hazard pictograms :
Signal Word : Danger
Hazard Statements : Flammable liquid and vapour.
May be fatal if swallowed and enters airways. May be harmful if swallowed. Harmful in contact with skin. May cause respiratory irritation. Causes skin irritation. Causes serious eye irritation.
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Suspected of causing cancer. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects. Harmful to terrestrial vertebrates.
Precautionary Statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/ physician. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. Storage: Store in a well-ventilated place. Disposal: Dispose of contents/ container to an approved waste disposal plant.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Pure substance/mixture : Mixture
Chemical Name CAS-No. Concentration: (%)
Xylene 1330-20-7 60 - 100 Formaldehyde, polymers with branched 4-nonylphenol, ethylene oxide and propylene oxide
153795-76-7 5 - 10
Heavy Aromatic Naphtha 64742-94-5 1 - 5 Naphthalene 91-20-3 0.1 - 1
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops and persists.
If swallowed : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Aspiration hazard if swallowed - can enter lungs and cause damage. Get medical attention immediately.
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.
Notes to physician : Treat symptomatically.
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Most important symptoms and effects, both acute and delayed
: See Section 11 for more detailed information on health effects and symptoms.
Section: 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Foam
Carbon dioxide Dry powder Other extinguishing agent suitable for Class B fires For large fires, use water spray or fog, thoroughly drenching the burning material.
Unsuitable extinguishing media
: None known.
Specific hazards during firefighting
: Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Hazardous combustion products
: Decomposition products may include the following materials: Carbon oxides
Special protective equipment for firefighters
: Use personal protective equipment.
Specific extinguishing methods
: Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Hazchem Code : •3Y
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
: Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up
: Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Avoid contact with skin and eyes. Open drum carefully as content may be under
pressure. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Do not ingest. Keep away from fire, sparks and heated surfaces. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Use only with adequate ventilation.
Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well-ventilated
SAFETY DATA SHEET
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place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.
Suitable material : Keep in properly labelled containers.
Unsuitable material : not determined
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible concentration
Basis
Xylene 1330-20-7 WES-TWA 50 ppm 217 mg/m3
NZ OEL
Xylene 1330-20-7 TWA 100 ppm 435 mg/m3
OSHA Z1
TWA 100 ppm ACGIH
STEL 150 ppm ACGIH
Heavy Aromatic Naphtha 64742-94-5 TWA 500 ppm 2,000 mg/m3
OSHA Z1
TWA 200 mg/m3 (as total hydrocarbon vapor)
ACGIH
Biological occupational exposure limits
Component CAS-No. Control parameters
Biological specimen
Sampling time Permissible concentration
Basis
Xylene 1330-20-7
Methylhippuric acid
Urine End of shift 1.5 g/l NZ BEI
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards. Personal protective equipment Eye protection : Safety goggles
Face-shield
Hand protection : Wear the following personal protective equipment: Standard glove type. NITRILE GLOVES VITON GLOVES Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin protection : Wear suitable protective clothing.
Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Refer to AS/NZS 1715 and AS/NZS 1716 for selection, use and maintenance of respiratory protective equipment as applicable.
SAFETY DATA SHEET
EMBR11720A
5 / 9 First issue: 24.05.2018 Version Number: 1.0 Date issued: 23.09.2018
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid
Colour : Yellow to Brown
Odour : no data available
Flash point : 27 °C, Method: Pensky-Martens closed cup
pH : 10.50 - 12.10
Odour Threshold : no data available
Melting point/freezing point : no data available
Initial boiling point and boiling range
: no data available
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 0.87 - 0.97, (25 °C),
Density : no data available
Water solubility : no data available
Solubility in other solvents : no data available
Partition coefficient: n-octanol/water
: no data available
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : < 20.5 mm2/s (40 °C)
Molecular weight : no data available
VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions. Possibility of hazardous reactions
: No dangerous reaction known under conditions of normal use.
Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition : In case of fire, hazardous decomposition products may be produced such as:
SAFETY DATA SHEET
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6 / 9 First issue: 24.05.2018 Version Number: 1.0 Date issued: 23.09.2018
products Carbon oxides
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
: Inhalation, Eye contact, Skin contact
Potential Health Effects Eyes : Causes serious eye irritation. Skin : Harmful in contact with skin. Causes skin irritation. Ingestion : May be fatal if swallowed and enters airways. May be harmful if swallowed. Inhalation : May cause respiratory tract irritation. May cause nose, throat, and lung irritation.
Inhalation may cause central nervous system effects. May cause drowsiness or dizziness. Chronic Exposure : Suspected of causing cancer. Experience with human exposure Eye contact : Redness, Pain, Irritation Skin contact : Redness, Irritation Ingestion : Vomiting Inhalation : Respiratory irritation, Cough, Dizziness, Drowsiness Toxicity Product
Acute oral toxicity : Acute toxicity estimate: 647.84 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: 32.39 mg/l Exposure time: 4 h Test atmosphere: vapour
Acute dermal toxicity : Acute toxicity estimate: 1,426 mg/kg
Skin corrosion/irritation : no data available
Serious eye damage/eye irritation
: no data available
Respiratory or skin sensitization
: no data available
Carcinogenicity : This product contains naphthalene. The International Agency for Research on Cancer (IARC) has evaluated naphthalene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in experimental animals and inadequate evidence in humans).
Reproductive effects : No toxicity to reproduction
Germ cell mutagenicity : Contains no ingredient listed as a mutagen
SAFETY DATA SHEET
EMBR11720A
7 / 9 First issue: 24.05.2018 Version Number: 1.0 Date issued: 23.09.2018
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : May be fatal if swallowed and enters airways.
Human Hazard Characterization
Based on our hazard characterization, the potential human hazard is: High
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity Environmental Effects : Harmful to aquatic life with long lasting effects.
Harmful to terrestrial vertebrates.
Product
Toxicity to fish : no data available
Toxicity to daphnia and other aquatic invertebrates
: no data available
Toxicity to algae : no data available
Components
Toxicity to fish : Heavy Aromatic Naphtha LC50 Oncorhynchus mykiss (rainbow trout): 3.5 mg/l Exposure time: 96 h
Persistence and degradability no data available Mobility no data available Bioaccumulative potential no data available Other information no data available ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : The product should not be allowed to enter drains, water
courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
SAFETY DATA SHEET
EMBR11720A
8 / 9 First issue: 24.05.2018 Version Number: 1.0 Date issued: 23.09.2018
Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport UN/ID No. : UN 1993 Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Xylene Transport hazard class(es) : 3 Packing group : III Hazchem Code : •3Y Air transport (IATA) UN/ID No. : UN 1993 Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Xylene Transport hazard class(es) : 3 Packing group : III Sea transport (IMDG/IMO) UN/ID No. : UN 1993 Proper shipping name : FLAMMABLE LIQUID, N.O.S. Technical name(s) : Xylene Transport hazard class(es) : 3 Packing group : III
Section: 15. REGULATORY INFORMATION
GROUP STANDARD NAME : Additives, Process Chemicals and Raw Materials (Flammable,
Toxic [6.7]) Group Standard 2017 HSNO APPROVAL NUMBER
: HSR002502
INTERNATIONAL CHEMICAL CONTROL LAWS : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.
Section: 16. OTHER INFORMATION
Revision Date : 23.09.2018 Version Number : 1.0 Prepared By : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.
SAFETY DATA SHEET
EMBR11720A
9 / 9 First issue: 24.05.2018 Version Number: 1.0 Date issued: 23.09.2018
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Wilhelmsen Ships Service Ltd
ENVIROCLEAN
Catalogue number: 765018Version No: 3.3Safety Data Sheet according to HSNO Regulations
Issue Date: 09/12/2016Print Date: 20/05/2019
L.GHS.NZL.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product IdentifierProduct name ENVIROCLEAN
Synonyms Product Part Number: 765018 (25 liter)
Other means ofidentification
765018, 765018
Relevant identified uses of the substance or mixture and uses advised againstRelevant identified uses Use according to manufacturer's directions.
Details of the supplier of the safety data sheet
Registered companyname
Wilhelmsen ShipsService Ltd Wilhelmsen Ships Service AS*
Outback (M)SDS portal:http://jr.chemwatch.net/outb/account/autologin?login=wilhelmsen
Address6B Wagener PlaceAuckland 1025 NewZealand
Willem Barentszstraat 50 RotterdamNetherlands
--------Use our Outback portal to obtain our(M)SDSs in other languages and/orformat.--------- For questions relating to ourSDSs please use Email:WSS.GLOBAL.SDSINFO@wilhelmsen.com--------- Norway
Telephone (+64) 9 8494783 +31 10 4877 777 Not Available
Fax Not Available +31 10 4877888 Not Available
Website Not Available http://www.wilhelmsen.com Not Available
Email Not Available wss.rotterdam@wilhelmsen.com Not Available
Emergency telephone numberAssociation /Organisation CHEMTREC Dutch nat. poison centre American Chemistry Council 24hrs
- Chemtrec
Emergency telephonenumbers (+64) 9 8455758 + 31 30 274 88 88 +1 703 527 3887
Other emergencytelephone numbers Not Available Not Available (800) 424 9300
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification [1] Serious Eye Damage Category 1
Continued...
Legend:1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from Regulation (EU) No1272/2008 - Annex VI
Determined byChemwatch using
GHS/HSNO criteria8.3A
Label elements
Hazard pictogram(s)
SIGNAL WORD DANGER
Hazard statement(s)H318 Causes serious eye damage.
Precautionary statement(s) GeneralP101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
Precautionary statement(s) PreventionP280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement(s) Response
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
Precautionary statement(s) StorageNot Applicable
Precautionary statement(s) DisposalNot Applicable
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
SubstancesSee section below for composition of Mixtures
MixturesCAS No %[weight] Name
160875-66-1* 10-30
161074-93-7* 1-5
112-34-5* 1-5
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact
If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids byoccasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
Fatty alcohol ethoxylate
Alkylglucosid
2-(2-butoxyethoxy)ethanol
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Continued...
Skin Contact
If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.
Inhalation
If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, orpocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.
IngestionImmediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Indication of any immediate medical attention and special treatment neededTreat symptomatically.
SECTION 5 FIREFIGHTING MEASURES
Extinguishing mediaThere is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area.
Special hazards arising from the substrate or mixtureFire Incompatibility None known.
Advice for firefighters
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire.
Fire/Explosion Hazard
Non combustible. Not considered a significant fire risk, however containers may burn.
May emit poisonous fumes.May emit corrosive fumes.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency proceduresSee section 8
Environmental precautionsSee section 12
Methods and material for containment and cleaning up
Minor Spills
Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable, labelled container for waste disposal.
Major Spills
Moderate hazard.Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage of concentrated product from entering drains or water course. Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Neutralise/decontaminate residue (see Section 13 for specific agent). Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains.
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ENVIROCLEAN
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Continued...
After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling
Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Avoid contact with moisture. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. DO NOT allow clothing wet with material to stay in contact with skin
Other information
Conditions for safe storage, including any incompatibilities
Suitable containerPolyethylene or polypropylene container. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
+ X + O + + +
X — Must not be stored together0 — May be stored together with specific preventions+ — May be stored together
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATANot Available
EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
2-(2-butoxyethoxy)ethanol Butoxyethoxy)ethanol, 2-(2-; (Diethylene glycol monobutyl ether) 30 ppm 33 ppm 200 ppm
Ingredient Original IDLH Revised IDLH
Fatty alcohol ethoxylate Not Available Not Available
Alkylglucosid Not Available Not Available
2-(2-butoxyethoxy)ethanol Not Available Not Available
MATERIAL DATASensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposurestandards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations requirethat nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors orsafety factors of 5 to 10 or more. On occasion animal no-observable-effect-levels (NOEL) are used to determine these limits where human results areunavailable. An additional approach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, hasbeen to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence fromirritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category systembased on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU)Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA.
Exposure controlsAppropriate engineering Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
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Continued...
controls
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactionsto provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker andventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an aircontaminant if designed properly. The design of a ventilation system must match the particular process and chemical orcontaminant in use.Employers may need to use multiple types of controls to prevent employee overexposure.
Personal protection
Eye and face protection
Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policydocument, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. Thisshould include a review of lens absorption and adsorption for the class of chemicals in use and an account of injuryexperience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readilyavailable. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon aspracticable.
Skin protection See Hand protection below
Hands/feet protection
Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which varyfrom manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of theglove material can not be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.hasto be observed when making a final choice.Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves,hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.
Body protection See Other protection below
Other protection
Overalls. P.V.C. apron.Barrier cream.Skin cleansing cream.Eye wash unit.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical propertiesAppearance Liquid, orange, soluble in water
Physical state Liquid Relative density (Water =1)
1.005 - 1.010
Odour Not Available Partition coefficientn-octanol / water
Not Available
Odour threshold Not Available Auto-ignition temperature(°C)
Not Available
pH (as supplied) 10-11 Decompositiontemperature
Not Available
Melting point / freezingpoint (°C)
Not Available Viscosity (cSt) Not Available
Initial boiling point andboiling range (°C)
>100-760 Molecular weight (g/mol) Not Available
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Upper Explosive Limit(%)
Not Available Surface Tension (dyn/cmor mN/m)
Not Available
Lower Explosive Limit(%)
Not Available Volatile Component(%vol)
Not Available
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Continued...
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Miscible pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7
Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.
Possibility of hazardousreactions
See section 7
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardousdecomposition products
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled
Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in asubstantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to achemical insult by first removing or neutralising the irritant and then repairing the damage. The repair process, whichinitially evolved to protect mammalian lungs from foreign matter and antigens, may however, produce further lungdamage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory tract irritation oftenresults in an inflammatory response involving the recruitment and activation of many cell types, mainly derived from thevascular system.The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This isbecause of the lack of corroborating animal or human evidence. In the absence of such evidence, care should be takennevertheless to ensure exposure is kept to a minimum and that suitable control measures be used, in an occupationalsetting to control vapours, fumes and aerosols.
Ingestion
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This isbecause of the lack of corroborating animal or human evidence. The material may still be damaging to the health of theindividual, following ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident. Presentdefinitions of harmful or toxic substances are generally based on doses producing mortality rather than those producingmorbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupationalsetting however, ingestion of insignificant quantities is not thought to be cause for concern.
Skin Contact
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in asubstantial number of individuals following direct contact, and/or produces significant inflammation when applied to thehealthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or more after theend of the exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may result in aform of contact dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling(oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. At the microscopic levelthere may be intercellular oedema of the spongy layer of the skin (spongiosis) and intracellular oedema of the epidermis.The material may accentuate any pre-existing dermatitis conditionSkin contact is not thought to have harmful health effects (as classified under EC Directives); the material may stillproduce health damage following entry through wounds, lesions or abrasions.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemicinjury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage issuitably protected.
EyeWhen applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours ormore after instillation.
Chronic
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and relatedsystemic problems.Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effectsinvolving organs or biochemical systems.
ENVIROCLEANTOXICITY IRRITATION
Not Available Not Available
Fatty alcohol ethoxylateTOXICITY IRRITATION
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Not Available Not Available
AlkylglucosidTOXICITY IRRITATION
Not Available Not Available
2-(2-butoxyethoxy)ethanol
TOXICITY IRRITATION
Dermal (rabbit) LD50: 4120 mg/kg[2] Eye (rabbit): 20 mg/24h moderate
Oral (rat) LD50: 5660 mg/kg[2] Eye (rabbit): 5 mg - SEVERE
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
ENVIROCLEAN
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be dueto a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposureto high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of precedingrespiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes tohours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderateto severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation,without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritatinginhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritatingsubstance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to highconcentrations of irritating substance (often particulate in nature) and is completely reversible after exposure ceases. Thedisorder is characterised by dyspnea, cough and mucus production.
Fatty alcohol ethoxylate
Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products suchas soaps, detergents, and other cleaning products . Exposure to these chemicals can occur through ingestion, inhalation,or contact with the skin or eyes. Studies of acute toxicity show that volumes well above a reasonable intake level wouldhave to occur to produce any toxic response. Moreover, no fatal case of poisoning with alcohol ethoxylates has everbeen reported. Multiple studies investigating the acute toxicity of alcohol ethoxylates have shown that the use of thesecompounds is of low concern in terms of oral and dermal toxicity .Clinical animal studies indicate these chemicals may produce gastrointestinal irritation such as ulcerations of the stomach,pilo-erection, diarrhea, and lethargy. Similarly, slight to severe irritation of the skin or eye was generated when undilutedalcohol ethoxylates were applied to the skin and eyes of rabbits and rats.Alcohol ethoxylates are according to CESIO (2000) classified as Irritant or Harmful depending on the number of EO-units:EO < 5 gives Irritant (Xi) with R38 (Irritating to skin) and R41 (Risk of serious damage to eyes)EO > 5-15 gives Harmful (Xn) with R22 (Harmful if swallowed) - R38/41EO > 15-20 gives Harmful (Xn) with R22-41>20 EO is not classified (CESIO 2000)Oxo-AE, C13 EO10 and C13 EO15, are Irritating (Xi) with R36/38 (Irritating to eyes and skin) .AE are not included in Annex 1 of the list of dangerous substances of the Council Directive 67/548/EEC
In general, alcohol ethoxylates (AE) are readily absorbed through the skin of guinea pigs and rats and through thegastrointestinal mucosa of rats. AE are quickly eliminated from the body through the urine, faeces, and expired air(CO2).Orally dosed AE was absorbed rapidly and extensively in rats, and more than 75% of the dose was absorbed.When applied to the skin of humans, the doses were absorbed slowly and incompletely (50% absorbed in 72 hours). Halfof the absorbed surfactant was excreted promptly in the urine and smaller amounts of AE appeared in the faeces andexpired air (CO2) ). The metabolism of C12 AE yields PEG, carboxylic acids, and CO2 as metabolites. The LD50 valuesafter oral administration to rats range from about 1-15 g/kg body weight indicating a low to moderate acute toxicity.
Alkylglucosid
Alkyl glycosides (syn: alkyl polyglucosides, alkyl polyglycosides, APGs) are considered non-irritating to skin, butirritating to eyes at very high concentrations. A general classification of a 65% C8 alkyl glycoside solution according tothe Substance Directive 67/548/EEC is Irritating (Xi) with the risk phrase R41 (Risk of serious damage to the eyes) or R36(Irritating to the eyes) (Akzo Nobel 1998).Acute toxicity:In single dose dermal studies with caprylyl/capryl glucoside and C10-16 alkyl glucoside (both 50% a.i., n:1.6) in rabbits,the LD50 was greater than the 2000 mg/kg dose administered. In oral studies with the same test substances, none of themice dosed with 2000 mg/kg caprylyl glucoside and none of the rats dosed with 5000 mg/kg C10-16 alkyl glucoside diedduring the study.Ocular:In system studies for ocular irritation, the ocular irritation potential of decyl, lauryl, C10-16 alkyl, and coco-glucosideswas non to slightly irritating and of caprylyl/ capryl glucoside was highly irritating. In a HET-CAM study with APG ofvarying proportions of alkyl chain length, the ocular irritation potential increased with the increased proportion ofshorter-chain APGs. In studies using rabbits, neutralized lauryl glucoside produced slight ocular reactions.
2-(2-butoxyethoxy)ethanol
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposureto irritants may produce conjunctivitis.For diethylene glycol monoalkyl ethers and their acetates:This category includes diethylene glycol ethyl ether (DGEE), diethylene glycol propyl ether (DGPE) diethylene glycolbutyl ether (DGBE) and diethylene glycol hexyl ether (DGHE) and their acetates.
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Legend: – Data either not available or does not fill the criteria for classification– Data available to make classification
Acute toxicity: There are adequate oral, inhalation and/or dermal toxicity studies on the category members. Oral LD50values in rats for all category members are all > 3000 mg/kg bw, with values generally decreasing with increasingmolecular weight. Four to eight hour acute inhalation toxicity studies were conducted for all category members exceptDGPE in rats at the highest vapour concentrations achievable. No lethality was observed for any of these materials underthese conditions. Dermal LD50 values in rabbits range from 2000 mg/kg bw (DGHE) to 15000 mg/kg bw (DGEEA). Signsof acute toxicity in rodents are consistent with non-specific CNS depression typical of organic solvents in general.
Fatty alcohol ethoxylate &Alkylglucosid
No significant acute toxicological data identified in literature search.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity
Serious EyeDamage/Irritation STOT - Single Exposure
Respiratory or Skinsensitisation
STOT - RepeatedExposure
Mutagenicity Aspiration Hazard
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
ENVIROCLEANENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
NotAvailable
Not Available Not AvailableNotAvailable
NotAvailable
Fatty alcohol ethoxylateENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
NotAvailable
Not Available Not AvailableNotAvailable
NotAvailable
AlkylglucosidENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
NotAvailable
Not Available Not AvailableNotAvailable
NotAvailable
2-(2-butoxyethoxy)ethanol
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE
LC50 96 Fish 1-300mg/L 2
EC50 48 Crustacea 4-950mg/L 2
EC50 72 Algae or other aquatic plants 1-101mg/L 2
NOEC 96 Algae or other aquatic plants >=100mg/L 1
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - AquaticToxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic ToxicityData 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -Bioconcentration Data 8. Vendor Data
DO NOTdischarge concentrated product into sewer or waterways.
Persistence and degradabilityIngredient Persistence: Water/Soil Persistence: Air
2-(2-butoxyethoxy)ethanol LOW LOW
Bioaccumulative potentialIngredient Bioaccumulation
2-(2-butoxyethoxy)ethanol LOW (BCF = 0.46)
Mobility in soilIngredient Mobility
2-(2-butoxyethoxy)ethanol LOW (KOC = 10)
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SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of Controls seems to be common - the user should investigate:
Reduction Reuse Recycling Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be appropriate.
It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a licensed apparatus (after admixture with suitable combustible material). Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
Ensure that the hazardous substance is disposed in accordance with the Hazardous Substances (Disposal) Notice 2017
Disposal Requirements Packages that have been in direct contact with the hazardous substance must be only disposed if the hazardous substance was appropriately removed and cleaned out from the package. The package must be disposed according to the manufacturer's directions taking into account the material it is made of. Packages which hazardous content have been appropriately treated and removed may be recycled.
The hazardous substance must only be disposed if it has been treated by a method that changed the characteristics or composition of the substance and it is no longer hazardous. Only dispose to the environment if a tolerable exposure limit has been set for the substance. Only deposit the hazardous substance into or onto a landfill or sewage facility or incinerator, where the hazardous substance can be handled and treated appropriately.
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant
NO
Not Applicable
HAZCHEM Not Applicable
Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture This substance is to be managed using the conditions specified in an applicable Group Standard
HSR Number Group Standard
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HSR002530 Cleaning Products (Subsidiary Hazard) Group Standard 2017
FATTY ALCOHOL ETHOXYLATE(160875-66-1*) IS FOUND ON THE FOLLOWING REGULATORY LISTS
New Zealand Inventory of Chemicals (NZIoC)
ALKYLGLUCOSID(161074-93-7*) IS FOUND ON THE FOLLOWING REGULATORY LISTS
International Air Transport Association (IATA) Dangerous Goods Regulations International Maritime Dangerous Goods Requirements (IMDG Code)
New Zealand Land Transport Rule: Dangerous Goods 2005 - Schedule 1 Quantity limits United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)
2-(2-BUTOXYETHOXY)ETHANOL(112-34-5*) IS FOUND ON THE FOLLOWING REGULATORY LISTS
GESAMP/EHS Composite List - GESAMP Hazard Profiles IMO IBC Code Chapter 17: Summary of minimum requirements IMO MARPOL (Annex II) - List of Noxious Liquid Substances Carried in Bulk IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
IMO Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals - Classification Data New Zealand Inventory of Chemicals (NZIoC)
Hazardous Substance Location Subject to the Health and Safety at Work (Hazardous Substances) Regulations 2017.
Hazard Class Quantity beyond which controls apply for closed containers
Quantity beyond which controls apply when use occurring in open containers
Not Applicable Not Applicable Not Applicable
Certified Handler
Subject to Part 4 of the Health and Safety at Work (Hazardous Substances) Regulations 2017.
Class of substance Quantities
Not Applicable Not Applicable
Refer Group Standards for further information
Tracking RequirementsNot Applicable
National Inventory StatusNational Inventory Status
Australia - AICS No (Alkylglucosid)
Canada - DSL No (Alkylglucosid; Fatty alcohol ethoxylate)
Canada - NDSL No (2-(2-butoxyethoxy)ethanol; Fatty alcohol ethoxylate)
China - IECSC Yes
Europe - EINEC / ELINCS /NLP
No (Fatty alcohol ethoxylate)
Japan - ENCS No (Fatty alcohol ethoxylate)
Korea - KECI No (Alkylglucosid)
New Zealand - NZIoC No (Alkylglucosid)
Philippines - PICCS No (Alkylglucosid; Fatty alcohol ethoxylate)
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (Alkylglucosid; Fatty alcohol ethoxylate)
Vietnam - NCI Yes
Russia - ARIPS No (Alkylglucosid; Fatty alcohol ethoxylate)
Thailand - TECI No (Alkylglucosid; Fatty alcohol ethoxylate)
Legend:Yes = All declared ingredients are on the inventoryNo = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specificingredients in brackets)
SECTION 16 OTHER INFORMATION
Revision Date 09/12/2016
Initial Date 09/12/2016
CONTACT POINT- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheetWilhelmsen Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: WSS.GLOBAL.SDSINFO@wilhelmsen.com - Telephone: Tel.: +31 104877775
Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards areRisks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current oravailable engineering controls must be considered.
Definitions and abbreviationsPC-TWA: Permissible Concentration-Time Weighted AveragePC-STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold Value
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BCF: BioConcentration FactorsBEI: Biological Exposure Index
Notes
“This composition meets the criteria for not being harmful to the marine environment according to MARPOL Annex V and may be
discharged into the sea when used to clean cargo holds and external surfaces on ships.”
Powered by AuthorITe, from Chemwatch.
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ENVIROCLEAN
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end of SDS
SAFETY DATA SHEETERIFON CLS 40 (NZ) Infosafe No.: LQ92D
ISSUED Date : 19/09/2018ISSUED by: MACDERMID OFFSHORE
SOLUTIONS
1. IDENTIFICATION
GHS Product IdentifierERIFON CLS 40 (NZ)
Company NameMACDERMID OFFSHORE SOLUTIONS (ABN 84 133 834 812)
Address29 Dennis Street Campbellfield,VIC 3061 Australia
Telephone/Fax NumberTel: +61 3 9303 5150
Emergency phone number+61 3 9303 5150 (9-5pm)
Recommended use of the chemical and restrictions on useClosed loop BOP fluid.
DisclaimerMacDermid Offshore Solutions is the trading name of MacDermid Canning Limited.
2. HAZARD IDENTIFICATION
GHS classification of the substance/mixtureClassified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.Not classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of DangerousGoods on Land.6.1D (Oral) - Substance that is acutely toxic6.3B Substance that is mildly irritating to the skin6.4A Substance that is irritating to the eyes6.9A (Single exposure) - Substance that is toxic to human target organs or systems6.9A (Repeated exposure) - Substance that is toxic to human target organs or systems9.3C Substance that is harmful to terrestrial vertebrates
Signal Word (s)DANGER
Hazard Statement (s)H302 Harmful if swallowed.H316 Causes mild skin irritation.H319 Causes serious eye irritation.H370 Causes damage to organs (kidney, nervous system) by ingestion.H372 Causes damage to organs (kidney) through prolonged or repeated exposure by ingestion.H433 Harmful to terrestrial vertebrates.
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Pictogram (s)Exclamation mark,Health hazard
Precautionary statement – PreventionP102 Keep out of reach of children.P103 Read label before use.P260 Do not breathe dust/fume/gas/mist/vapours/spray.P264 Wash contaminated skin thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P273 Avoid release to the environment.P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement – ResponseP101 If medical advice is needed, have product container or label at hand.P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.P314 Get medical advice/attention if you feel unwell.P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P330 Rinse mouth.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.P337+P313 If eye irritation persists: Get medical advice/attention.P332+P313 If skin irritation occurs: Get medical advice/attention.
Precautionary statement – StorageP405 Store locked up.
Precautionary statement – DisposalP501 In the case of a substance that is in compliance with a HSNO approval other than a Part 6A (Group Standards) approval, alabel must provide a description of one or more appropriate and achievable methods for the disposal of a substance in accordancewith the Hazardous Substances (Disposal) Regulations 2001. This may also include any method of disposal that must be avoided.See Section 13 for disposal details.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Name CAS Proportion
Ethylene glycol 107-21-1 35-<50 %
1-Propanol, 2-(dimethylamino)-2-methyl- 7005-47-2 1-<3 %
Ingredients determined not to be hazardous, includingwater.
Balance
4. FIRST-AID MEASURES
InhalationIf inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist seekmedical attention.
IngestionDo not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention.
SkinRemove all contaminated clothing immediately. Wash affected area thoroughly with soap and water. Wash contaminated clothingbefore reuse or discard. Seek medical attention.
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Eye contactIf in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing forseveral minutes until all contaminants are washed out completely. Seek medical attention.
First Aid FacilitiesEyewash, safety shower and normal washroom facilities.
Advice to DoctorTreat symptomatically.
Other InformationFor advice in an emergency, contact a Poisons Information Centre or a doctor at once. (0800 764 766)
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaUse appropriate fire extinguisher for surrounding environment.
Hazards from Combustion ProductsUnder fire conditions this product may emit toxic and/or irritating fumes, smoke and gases including carbon monoxide, carbondioxide and oxides of nitrogen.
Specific Hazards Arising From The ChemicalFollowing evaporation of the aqueous component under fire conditions, the non-aqueous component may decompose and/or burn.
Decomposition TemperatureNot available
Precautions in connection with FireFire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA) operated in positive pressure mode.Fight fire from safe location.
6. ACCIDENTAL RELEASE MEASURES
Emergency ProceduresWear appropriate personal protective equipment and clothing to prevent exposure. If possible contain the spill. Place inertabsorbent material onto spillage. Collect the material and place into a suitable labelled container. Do not dilute material butcontain. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterwaysoccurs inform the local water and waste management authorities in accordance with local regulations.
7. HANDLING AND STORAGE
Precautions for Safe HandlingAvoid inhalation of vapours and mists, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when notin use. Prevent the build up of mists or vapours in the work atmosphere. Maintain high standards of personal hygiene i.e. Washinghands prior to eating, drinking, smoking or using toilet facilities.
Conditions for safe storage, including any incompatibilitiesStore in a cool, dry, well-ventilated area, out of direct sunlight. Protect from freezing. Store in suitable, labelled containers. Keepcontainers tightly closed. Store away from incompatible materials. Ensure that storage conditions comply with applicable local andnational regulations.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational exposure limit valuesNo exposure value assigned for this material. However, the available exposure limits for ingredients are listed below:
Ethylene glycolTWA: 50 ppm, 127 mg/m³ (Vapour and mist)Notices: Ceiling.
TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight-
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hour working day, for a five-day week.Ceiling: A concentration that should not be exceeded during any part of the working day.
Source: Workplace Exposure Standards and Biological Exposure Indices.
Biological Limit ValuesNo biological limits allocated.
Appropriate Engineering ControlsThis substance is hazardous and should be used with a local exhaust ventilation system, drawing vapours away from workers'breathing zone. If the engineering controls are not sufficient to maintain concentrations of vapours/mists below the exposurestandards, suitable respiratory protection must be worn.
Respiratory ProtectionIf engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable vapor/mistfilter should be used. Refer to relevant regulations for further information concerning respiratory protective requirements.Reference should be made to Australian Standards AS/NZS 1715 (2009), Selection, Use and Maintenance of Respiratory ProtectiveDevices; and AS/NZS 1716 (2012), Respiratory Protective Devices, in order to make any necessary changes for individualcircumstances.
Eye ProtectionSafety glasses with side shields, chemical goggles or full-face shield as appropriate should be used. Final choice of appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform to relevant regulations.Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 2 & 6 (2012) - Eye Protectors for IndustrialApplications.
Hand ProtectionWear gloves of impervious material such as nitrile, latex rubber or neoprene (>8 hours breakthrough time). Final choice ofappropriate gloves will vary according to individual circumstances. i.e. methods of handling or according to risk assessmentsundertaken. Occupational protective gloves should conform to relevant regulations.Reference should be made to AS/NZS 2161.1 (2016): Occupational protective gloves - Selection, use and maintenance.
Body ProtectionSuitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron isrecommended where large quantities are handled.
9. PHYSICAL AND CHEMICAL PROPERTIES
Properties Description Properties Description
Form Liquid Appearance Liquid
Colour Straw Odour Amine-like
Decomposition Temperature Not available Melting Point Not available
Boiling Point 100 °C Solubility in Water Not available
pH 9.6 Vapour Pressure Not available
Vapour Density (Air=1) Not available Evaporation Rate Not available
Odour Threshold Not available Viscosity 4 cSt (20 °C)
Partition Coefficient: n-octanol/water
Not available Density 1.07 g/cm³ (15.6 °C)
Flash Point Not available Flammability Non flammable
Auto-Ignition Temperature Not applicable Flammable Limits - Lower Not available
Flammable Limits - Upper Not available
10. STABILITY AND REACTIVITY
Chemical StabilityStable under normal conditions of storage and handling.
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Reactivity and StabilityReacts with incompatible materials.
Conditions to AvoidExtremes of temperature and direct sunlight.
Incompatible materialsNot available
Hazardous Decomposition ProductsThermal decomposition may result in the release of toxic and/or irritating fumes, smoke and gases including: carbon monoxide,carbon dioxide and oxides of nitrogen.
Possibility of hazardous reactionsUnder normal conditions of storage and use, hazardous reactions will not occur.
11. TOXICOLOGICAL INFORMATION
Toxicology InformationThe available toxicity data for product and ingredients is given below.
Acute Toxicity - OralAcute toxicity estimates (ATE): 1214.5 mg/kg
Acute Toxicity - DermalEthylene glycolLD50(mouse - male, female): 3500 mg/kg
IngestionHarmful if swallowed. Ingestion of this product may cause irritation to the mouth, throat, oesophagus and stomach with symptomsof nausea, abdominal discomfort, vomiting and diarrhoea.
InhalationInhalation of product vapours may cause irritation of the nose, throat and respiratory system.
SkinCauses mild skin irritation. Skin contact will cause redness, itching and swelling. Repeated exposure may cause skin dryness andcracking and may lead to dermatitis.
EyeCauses serious eye irritation. On eye contact this product will cause tearing, stinging, blurred vision, and redness.
Respiratory sensitisationNot expected to be a respiratory sensitiser.
Skin SensitisationNot expected to be a skin sensitiser.
Germ cell mutagenicityNot considered to be a mutagenic hazard.
CarcinogenicityNot considered to be a carcinogenic hazard.
Reproductive ToxicityNot considered to be toxic to reproduction.
STOT-single exposureCauses damage to organs (kidney, nervous system) by ingestion.
STOT-repeated exposureCauses damage to organs (kidney) through prolonged or repeated exposure by ingestion.
Aspiration HazardNot expected to be an aspiration hazard.
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12. ECOLOGICAL INFORMATION
EcotoxicityHarmful to terrestrial vertebrates.
Persistence and degradability1-Propanol, 2-(dimethylamino)-2-methyl-Degradability: 31 % - Inherent - 28 days
MobilityNot available
Bioaccumulative PotentialEthylene glycolLogPow: -1.36, low bioaccumulative potential
Other Adverse EffectsNot available
Environmental ProtectionPrevent this material entering waterways, drains and sewers.
Acute Toxicity - FishEthylene glycolLC50(Pimephales promelas): 72,860 mg/l/96h (fresh water)LC50(Pimephales promelas): 8050 mg/l/96h (fresh water)
Acute Toxicity - DaphniaEthylene glycolEC50(Daphnia magna): >100 mg/l/48h (fresh water)LC50(Daphnia magna - Neonate): 41,000 mg/l/48h (fresh water)
Acute Toxicity - AlgaeEthylene glycolEC50(Pseudokirchneriella subcapitata): >6500 mg/l/96h (fresh water)
Acute Toxicity - Other OrganismsEthylene glycolLC50(Crangon crangon - Adult): 100 mg/l/48h (marine water)EC50(Micro-organism): >1995 mg/l/30min (fresh water)
13. DISPOSAL CONSIDERATIONS
Disposal considerationsProduct Disposal:Product wastes are controlled wastes and should be disposed of in accordance with all applicable local and national regulations.This product can be disposed through a licensed commercial waste collection service. In this specific case the product is water-based/water-soluble and therefore can be sent through a Waste Water Treatment Plant and after treatment can be dischargedinto environment through the sewerage or drainage systems as authorized.
Personal protective clothing and equipment as specified in Section 8 of this SDS must be worn during handling and disposal of thisproduct. The ventilation requirements as specified in the same section must also be followed, and the precautions given in Section7 of this SDS regarding handling must also be followed. Do not dispose into the sewerage system. Do not discharge into drains orwatercourses or dispose where ground or surface waters may be affected.
In New Zealand, the disposal agency or contractor must comply with the New Zealand Hazardous Substances (Disposal) Regulations2001. Further details regarding disposal can be obtained on the EPA New Zealand website under specific group standards.
Container Disposal:The container or packaging must be cleaned and rendered incapable of holding any substance. It can then be disposed of in amanner consistent with that of the substance it contained. In this instance the packaging can be disposed through a commercialwaste collection service.
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Alternatively, the container or packaging can be recycled if the hazardous residues have been thoroughly cleaned or rendered non-hazardous.
In New Zealand, the packaging (that may or may not hold any residual substance) that is lawfully disposed of by householders orother consumers through a public or commercial waste collection service is a means of compliance with regulations.
14. TRANSPORT INFORMATION
Transport InformationNot classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of DangerousGoods on Land.Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous GoodsRegulations for transport by air.Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transportby sea.
U.N. NumberNone Allocated
UN proper shipping nameNone Allocated
Transport hazard class(es)None Allocated
IMDG Marine pollutantNo
Transport in BulkNot available
Special Precautions for UserNot available
15. REGULATORY INFORMATION
Regulatory informationClassified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.All components of this product are listed on the New Zealand Inventory of Chemicals (NZIoC) or exempted.
Group Standard: Lubricants, Lubricant Additives, Coolants and Anti-freeze Agents (Subsidiary Hazard) Group Standard 2006
HSNO Approval NumberHSR002606
16. OTHER INFORMATION
Date of preparation or last revision of SDSSDS created: September 2018
ReferencesWorkplace Exposure Standards and Biological Exposure Indices.Transport of Dangerous goods on land NZS 5433.Preparation of Safety Data Sheets - Approved Code of Practice Under the HSNO Act 1996 (HSNO CoP 8-1 09-06).Assigning a hazardous substance to a group standard.Adopted biological exposure determinants, American Conference of Industrial Hygienists (ACGIH).
Contact Person/PointMr Anthony DalleoreGeneral Manager Ph +61 3 9303 5150
Mr Bruce GrayQES officer Ph +61 3 9303 5150
Page 7 / 8
The data included herein presented according to MacDermid Offshore Solutions practices current at the time of preparation hereof,is made available solely for the consideration, investigation and verification of the original recipients hereof and does not
constitute a representation or warranty for which MacDermid Offshore Solutions assumes legal responsibility. It is theresponsibility of a recipient for this data to remain currently informed on chemical hazard information, to design and update itsown safety program and to comply with all Federal, State and Local laws and regulations applicable to safety, occupational health,right to know and environmental protection.
END OF SDS© Copyright Chemical Safety International Pty Ltd
Copyright in the source code of the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe SDS displayed is the intellectual property of ChemicalSafety International Pty Ltd.Copyright in the layout, presentation and appearance of each Infosafe SDS displayed is the intellectual property of Chemical Safety International Pty Ltd.The compilation of SDS’s displayed is the intellectual property of Chemical Safety International Pty Ltd.Copying of any SDS displayed is permitted for personal use only and otherwise is not permitted. In particular the SDS’s displayed cannot be copied for the purpose of sale or licence or forinclusion as part of a collection of SDS without the express written consent of Chemical Safety International Pty Ltd.
Page 8 / 8
SAFETY DATA SHEETERIFON HD 603 HP NO DYE (NZ) Infosafe No.: LQ92A
ISSUED Date : 19/09/2018ISSUED by: MACDERMID OFFSHORE
SOLUTIONS
1. IDENTIFICATION
GHS Product IdentifierERIFON HD 603 HP NO DYE (NZ)
Company NameMACDERMID OFFSHORE SOLUTIONS (ABN 84 133 834 812)
Address29 Dennis Street Campbellfield,VIC 3061 Australia
Telephone/Fax NumberTel: +61 3 9303 5150
Emergency phone number+61 3 9303 5150 (9-5pm)
Recommended use of the chemical and restrictions on useOpen loop BOP fluid.
DisclaimerMacDermid Offshore Solutions is the trading name of MacDermid Canning Limited.
2. HAZARD IDENTIFICATION
GHS classification of the substance/mixtureClassified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.Not classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of DangerousGoods on Land.6.1D (Oral) - Substance that is acutely toxic6.3A Substance that is irritating to the skin6.9A (Single exposure) - Substance that is toxic to human target organs or systems6.9A (Repeated exposure) - Substance that is toxic to human target organs or systems8.3A Substance that is corrosive to ocular tissue9.1C Substance that is harmful in the aquatic environment9.3C Substance that is harmful to terrestrial vertebrates
Signal Word (s)DANGER
Hazard Statement (s)H302 Harmful if swallowed.H315 Causes skin irritation.H318 Causes serious eye damage.H370 Causes damage to organs (kidney, nervous system) by ingestion.H372 Causes damage to organs (kidney) through prolonged or repeated exposure by ingestion.H412 Harmful to aquatic life with long lasting effects.H433 Harmful to terrestrial vertebrates.
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Pictogram (s)Exclamation mark,Health hazard,Corrosion
Precautionary statement – PreventionP102 Keep out of reach of children.P103 Read label before use.P260 Do not breathe dust/fume/gas/mist/vapours/spray.P264 Wash contaminated skin thoroughly after handling.P270 Do not eat, drink or smoke when using this product.P273 Avoid release to the environment.P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement – ResponseP101 If medical advice is needed, have product container or label at hand.P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P330 Rinse mouth.P302+P352 IF ON SKIN: Wash with plenty of soap and water.P332+P313 If skin irritation occurs: Get medical advice/attention.P362 Take off contaminated clothing and wash before reuse.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.P310 Immediately call a POISON CENTER or doctor/physician.P314 Get medical advice/attention if you feel unwell.
Precautionary statement – DisposalP501 In the case of a substance that is in compliance with a HSNO approval other than a Part 6A (Group Standards) approval, alabel must provide a description of one or more appropriate and achievable methods for the disposal of a substance in accordancewith the Hazardous Substances (Disposal) Regulations 2001. This may also include any method of disposal that must be avoided.See Section 13 for disposal details.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Name CAS Proportion
Ethylene glycol 107-21-1 25-<35 %
Amides, tall-oil fatty, N,N-bis(hydroxyethyl) 68155-20-4 10-<20 %
Decanoic Acid 334-48-5 5-<10 %
Diethanolamine 111-42-2 5-<7 %
N,N'-methylene-bis [5-methyloxazolidine] 66204-44-2 1-<3 %
Ingredients determined not to be hazardous, includingwater.
Balance
4. FIRST-AID MEASURES
InhalationIf inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or persist seekmedical attention.
IngestionDo not induce vomiting. Wash out mouth thoroughly with water. Seek immediate medical attention.
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SkinRemove all contaminated clothing immediately. Wash affected area thoroughly with soap and water. Wash contaminated clothingbefore reuse or discard. Seek medical attention.
Eye contactIf in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing untiladvised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Seek immediate medical attention.
First Aid FacilitiesEyewash, safety shower and normal washroom facilities.
Advice to DoctorTreat symptomatically.
Other InformationFor advice in an emergency, contact a Poisons Information Centre or a doctor at once. (0800 764 766)
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing MediaUse appropriate fire extinguisher for surrounding environment.
Hazards from Combustion ProductsUnder fire conditions this product may emit toxic and/or irritating fumes, smoke and gases including carbon monoxide, carbondioxide and oxides of nitrogen.
Specific Hazards Arising From The ChemicalFollowing evaporation of the aqueous component under fire conditions, the non-aqueous component may decompose and/or burn.
Decomposition TemperatureNot available
Precautions in connection with FireFire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA) operated in positive pressure mode.Fight fire from safe location.
6. ACCIDENTAL RELEASE MEASURES
Emergency ProceduresWear appropriate personal protective equipment and clothing to prevent exposure. If possible contain the spill. Place inertabsorbent material onto spillage. Collect the material and place into a suitable labelled container. Do not dilute material butcontain. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterwaysoccurs inform the local water and waste management authorities in accordance with local regulations.
7. HANDLING AND STORAGE
Precautions for Safe HandlingAvoid inhalation of vapours and mists, and skin or eye contact. Use only in a well ventilated area. Keep containers sealed when notin use. Prevent the build up of mists or vapours in the work atmosphere. Maintain high standards of personal hygiene i.e. Washinghands prior to eating, drinking, smoking or using toilet facilities.
Conditions for safe storage, including any incompatibilitiesStore in a cool, dry, well-ventilated area, out of direct sunlight. Protect from freezing. Store in suitable, labelled containers. Keepcontainers tightly closed. Store away from incompatible materials. Ensure that storage conditions comply with applicable local andnational regulations.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational exposure limit valuesNo exposure value assigned for this material. However, the available exposure limits for ingredients are listed below:
Ethylene glycol
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TWA: 50 ppm, 127 mg/m³ (Vapour and mist)Notices: Ceiling.
DiethanolamineTWA: 3 ppm, 13 mg/m³
TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day week.Ceiling: A concentration that should not be exceeded during any part of the working day.
Source: Workplace Exposure Standards and Biological Exposure Indices.
Biological Limit ValuesNo biological limits allocated.
Appropriate Engineering ControlsThis substance is hazardous and should be used with a local exhaust ventilation system, drawing vapours away from workers'breathing zone. If the engineering controls are not sufficient to maintain concentrations of vapours/mists below the exposurestandards, suitable respiratory protection must be worn.
Respiratory ProtectionIf engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable vapor/mistfilter should be used. Refer to relevant regulations for further information concerning respiratory protective requirements.Reference should be made to Australian Standards AS/NZS 1715 (2009), Selection, Use and Maintenance of Respiratory ProtectiveDevices; and AS/NZS 1716 (2012), Respiratory Protective Devices, in order to make any necessary changes for individualcircumstances.
Eye ProtectionSafety glasses with full face shield should be used. Eye protection devices should conform to relevant regulations.Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 2 & 6 (2012) - Eye Protectors for IndustrialApplications.
Hand ProtectionWear gloves of impervious material such as nitrile, latex rubber or neoprene (>8 hours breakthrough time). Final choice ofappropriate gloves will vary according to individual circumstances. i.e. methods of handling or according to risk assessmentsundertaken. Occupational protective gloves should conform to relevant regulations.Reference should be made to AS/NZS 2161.1 (2016): Occupational protective gloves - Selection, use and maintenance.
Body ProtectionSuitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron isrecommended where large quantities are handled.
9. PHYSICAL AND CHEMICAL PROPERTIES
Properties Description Properties Description
Form Liquid Appearance Liquid
Colour Amber Odour Amine-like
Decomposition Temperature Not available Melting Point Not available
Boiling Point 100 °C Solubility in Water Not available
pH 10 Vapour Pressure Not available
Vapour Density (Air=1) Not available Evaporation Rate Not available
Odour Threshold Not available Viscosity 20 cSt (20 °C)
Partition Coefficient: n-octanol/water
Not available Density 1.06 g/cm³ (20 °C)
Flash Point Not available Flammability Non flammable
Auto-Ignition Temperature Not applicable Flammable Limits - Lower Not available
Flammable Limits - Upper Not available
Page 4 / 9
10. STABILITY AND REACTIVITY
Chemical StabilityStable under normal conditions of storage and handling.
Reactivity and StabilityReacts with incompatible materials.
Conditions to AvoidExtremes of temperature and direct sunlight.
Incompatible materialsNot available
Hazardous Decomposition ProductsThermal decomposition may result in the release of toxic and/or irritating fumes, smoke and gases including: carbon monoxide,carbon dioxide and oxides of nitrogen.
Possibility of hazardous reactionsUnder normal conditions of storage and use, hazardous reactions will not occur.
11. TOXICOLOGICAL INFORMATION
Toxicology InformationThe available toxicity data for product and ingredients is given below.
Acute Toxicity - OralAcute toxicity estimates (ATE): 1287.7 mg/kg
Acute Toxicity - InhalationAcute toxicity estimates (ATE value)Inhalation (vapours): 440 mg/lInhalation (dusts and mists): 44.44 mg/l
Acute Toxicity - DermalEthylene glycolLD50(mouse - male, female): 3500 mg/kg
IngestionHarmful if swallowed. Ingestion of this product may cause irritation to the mouth, throat, oesophagus and stomach with symptomsof nausea, abdominal discomfort, vomiting and diarrhoea.
InhalationInhalation of product vapours may cause irritation of the nose, throat and respiratory system.
SkinCauses skin irritation. Skin contact will cause redness, itching and swelling. Repeated exposure may cause skin dryness and crackingand may lead to dermatitis.
DiethanolamineSpecies: rabbitExposure: 500mg (24h)Result: Mild irritant
Decanoic AcidSpecies: rabbitExposure: 50mgResult: Mild irritant
EyeCauses eye damage. Eye contact will cause stinging, blurring, tearing, severe pain and possible burns, necrosis, permanent damageand blindness.
DiethanolamineSpecies: rabbit
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Exposure: 750 mg (24h)Result: Severe irritant
Exposure: 5500 mg (24h)Result: Severe irritant
Decanoic AcidSpecies: rabbitExposure: 72hScore: >2Result: Cornea opacity
Respiratory sensitisationNot expected to be a respiratory sensitiser.
Skin SensitisationNot expected to be a skin sensitiser.
Decanoic AcidSpecies: Guinea pigResult: Not sensitizing
Germ cell mutagenicityNot considered to be a mutagenic hazard.
CarcinogenicityNot considered to be a carcinogenic hazard.
Diethanolamine is listed as a Group 2B: Possibly carcinogenic to humans according to International Agency for Research on Cancer(IARC).
Reproductive ToxicityNot considered to be toxic to reproduction.
STOT-single exposureCauses damage to organs (kidney, nervous system) by ingestion.
STOT-repeated exposureCauses damage to organs (kidney) through prolonged or repeated exposure by ingestion.
Aspiration HazardNot expected to be an aspiration hazard.
12. ECOLOGICAL INFORMATION
EcotoxicityHarmful to aquatic life with long lasting effects. Harmful to terrestrial vertebrates.
Persistence and degradabilityDiethanolamineDegradability: 93 % - Readily - 28 days
Decanoic AcidDegradability: >60 % - Readily - 30 days (OECD 301D)
MobilityNot available
Bioaccumulative PotentialEthylene glycolLogPow: -1.36, low bioaccumulative potential
DiethanolamineLogPow: -1.43, low bioaccumulative potential
Other Adverse EffectsNot available
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Environmental ProtectionPrevent this material entering waterways, drains and sewers.
Acute Toxicity - FishEthylene glycolLC50(Pimephales promelas): 72,860 mg/l/96h (fresh water)LC50(Pimephales promelas): 8050 mg/l/96h (fresh water)
DiethanolamineLC50(Pimephales promelas - Juvenile): 100 mg/l/96h (fresh water)(fledgling, hatchling, weanling)
Decanoic AcidLC50(fish): 275 mg/l/96h
Acute Toxicity - DaphniaEthylene glycolEC50(Daphnia magna): >100 mg/l/48h (fresh water)LC50(Daphnia magna - Neonate): 41,000 mg/l/48h (fresh water)
DiethanolamineLC50(Daphnia magna): 55,000 mìcrog/l/48h (fresh water)
Decanoic AcidEC50(Daphnia): >20 mg/l/48h
Acute Toxicity - AlgaeEthylene glycolEC50(Pseudokirchneriella subcapitata): >6500 mg/l/96h (fresh water)
DiethanolamineEC50(Pseudokirchneriella subcapitata): 12 mg/l/96h (fresh water)
Acute Toxicity - Other OrganismsEthylene glycolLC50(Crangon crangon - Adult): 100 mg/l/48h (marine water)EC50(Micro-organism): >1995 mg/l/30min (fresh water)
DiethanolamineLC50(Ceriodaphnia dubia - Neonate): 28,800 mìcrog/l/48h (fresh water)
13. DISPOSAL CONSIDERATIONS
Disposal considerationsProduct Disposal:Product wastes are controlled wastes and should be disposed of in accordance with all applicable local and national regulations.This product can be disposed through a licensed commercial waste collection service. In this specific case the product is water-based/water-soluble and therefore can be sent through a Waste Water Treatment Plant and after treatment can be dischargedinto environment through the sewerage or drainage systems as authorized.
Personal protective clothing and equipment as specified in Section 8 of this SDS must be worn during handling and disposal of thisproduct. The ventilation requirements as specified in the same section must also be followed, and the precautions given in Section7 of this SDS regarding handling must also be followed. Do not dispose into the sewerage system. Do not discharge into drains orwatercourses or dispose where ground or surface waters may be affected.
In New Zealand, the disposal agency or contractor must comply with the New Zealand Hazardous Substances (Disposal) Regulations2001. Further details regarding disposal can be obtained on the EPA New Zealand website under specific group standards.
Container Disposal:The container or packaging must be cleaned and rendered incapable of holding any substance. It can then be disposed of in amanner consistent with that of the substance it contained. In this instance the packaging can be disposed through a commercialwaste collection service.
Page 7 / 9
Alternatively, the container or packaging can be recycled if the hazardous residues have been thoroughly cleaned or rendered non-hazardous.
In New Zealand, the packaging (that may or may not hold any residual substance) that is lawfully disposed of by householders orother consumers through a public or commercial waste collection service is a means of compliance with regulations.
14. TRANSPORT INFORMATION
Transport InformationNot classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport of DangerousGoods on Land.Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous GoodsRegulations for transport by air.Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transportby sea.
U.N. NumberNone Allocated
UN proper shipping nameNone Allocated
Transport hazard class(es)None Allocated
IMDG Marine pollutantNo
Transport in BulkNot available
Special Precautions for UserNot available
15. REGULATORY INFORMATION
Regulatory informationClassified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.All components of this product are listed on the New Zealand Inventory of Chemicals (NZIoC) or exempted.
Group Standard: Lubricants, Lubricant Additives, Coolants and Anti-freeze Agents (Subsidiary Hazard) Group Standard 2006
HSNO Approval NumberHSR002606
16. OTHER INFORMATION
Date of preparation or last revision of SDSSDS created: September 2018
ReferencesWorkplace Exposure Standards and Biological Exposure Indices.Transport of Dangerous goods on land NZS 5433.Preparation of Safety Data Sheets - Approved Code of Practice Under the HSNO Act 1996 (HSNO CoP 8-1 09-06).Assigning a hazardous substance to a group standard.Adopted biological exposure determinants, American Conference of Industrial Hygienists (ACGIH).
Contact Person/PointMr Anthony DalleoreGeneral Manager Ph +61 3 9303 5150
Mr Bruce GrayQES officer Ph +61 3 9303 5150
Page 8 / 9
The data included herein presented according to MacDermid Offshore Solutions practices current at the time of preparation hereof,is made available solely for the consideration, investigation and verification of the original recipients hereof and does not
constitute a representation or warranty for which MacDermid Offshore Solutions assumes legal responsibility. It is theresponsibility of a recipient for this data to remain currently informed on chemical hazard information, to design and update itsown safety program and to comply with all Federal, State and Local laws and regulations applicable to safety, occupational health,right to know and environmental protection.
END OF SDS© Copyright Chemical Safety International Pty Ltd
Copyright in the source code of the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe SDS displayed is the intellectual property of ChemicalSafety International Pty Ltd.Copyright in the layout, presentation and appearance of each Infosafe SDS displayed is the intellectual property of Chemical Safety International Pty Ltd.The compilation of SDS’s displayed is the intellectual property of Chemical Safety International Pty Ltd.Copying of any SDS displayed is permitted for personal use only and otherwise is not permitted. In particular the SDS’s displayed cannot be copied for the purpose of sale or licence or forinclusion as part of a collection of SDS without the express written consent of Chemical Safety International Pty Ltd.
Page 9 / 9
SAFETY DATA SHEET
EZ-MUD® DP
Revision Date: 03-Mar-2016 Revision Number: 20
1. Product and Company Identification
Product Name Product Trade Name: EZ-MUD® DP
Other Names Synonyms None
Product Code: HM003644
Recommended Use Recommended Use Shale Inhibitor
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according to
NA Not applicable
_____________________________________________________________________________________________
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_____________________________________________________________________________________________EZ-MUD® DP Revision Date: 03-Mar-2016
the competent authority
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardCombustible dust when in finely divided and highly suspended state.
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation. Slippery when wet.See Section 8 for additional information
6.2. Environmental precautions
_____________________________________________________________________________________________
Page 2 / 7
Prevent from entering sewers, waterways, or low areas.
_____________________________________________________________________________________________EZ-MUD® DP Revision Date: 03-Mar-2016
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment. Slippery when wet.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
Physical State: Solid Color White
Odor: Mild Odor Threshold:
_____________________________________________________________________________________________
Page 3 / 7
No information available
_____________________________________________________________________________________________EZ-MUD® DP Revision Date: 03-Mar-2016
pH: 6-8
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 0.8
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
Bulk Density 40 lbs/ft3
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Ammonia. Oxides of nitrogen. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation None known.
Eye Contact May cause mild eye irritation.
Skin Contact May cause mild skin irritation.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________EZ-MUD® DP Revision Date: 03-Mar-2016
12. Ecological Information
12.1. Toxicity Ecotoxicity effects
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
_____________________________________________________________________________________________
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_____________________________________________________________________________________________EZ-MUD® DP Revision Date: 03-Mar-2016
IMDG/IMO UN Number Not restricted
UN proper shipping name Not restricted
Transport Hazard Class(es) Not applicable
Packing Group: Not applicable
Environmental Hazards Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name Not restricted
Transport Hazard Class(es) Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name Not restricted
Transport Hazard Class(es) Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
The following sections have been revised since the last issue of this SDSNot applicable
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% MARPOL – International Convention for the Prevention of Pollution fromShips mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – OccupationalExposure Limit ppm – parts per million TWA – Time-Weighted Average VOC – Volatile Organic Carbon C - Celsius IATA/ICAO- International Air Transport Association / International Civil Aviation Organization IMDG/IMO - International MaritimeDangerous Goods / International Maritime Organization mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimetermercury w/w - weight/weight d - day
Key literature references and sources for datawww.ChemADVISOR.com/
Revision Date: 03-Mar-2016
Revision NoteSDS sections updated:1
_____________________________________________________________________________________________
Page 6 / 7
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is
_____________________________________________________________________________________________EZ-MUD® DP Revision Date: 03-Mar-2016
obtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
CS: 3.3.2
Page: 1
Safety Data Sheet
7of
Emergency Response Number: 1800 625 526
Infosafe No™ IMIDS March 2017 ISSUED by IMCDASTIssue Date :
Fluoresceine DyeProduct Name :
Classified as hazardous
1. Identification
Fluoresceine DyeGHS Product
Identifier5406263Product Code
IMCD Australia Limited (ABN 44 000 005 578)Company Name
1st Floor, 372 Wellington Road MulgraveVictoria 3170 Australia
Address
Tel: (03)8544 3100 (Business hours) Fax: (03)8544 3299
Telephone/Fax
Number1800 625 526Emergency phone
numberNEW ZEALANDEmergency Response: 0800 500 288IMCD New Zealand Limited459 Great South RoadPenrose, AucklandPh: (09) 582 0250Fax (09) 525 0030
Emergency Contact
Address
reg@imcd.com.auE-mail Address
Colouring product for various applicationsRecommended use of
the chemical and
restrictions on useName Product CodeOther Names
Fluoresceine Dye 5406326
It is the user's responsibility to determine the suitability of this product for their applications and their methods of use.
Additional
InformationTHIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS.OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Other Information
2. Hazard Identification
Acute Toxicity - Oral: Category 5Eye Damage/Irritation: Category 2ASensitization - Skin: Category 1Skin Corrosion/Irritation: Category 2Classified as Hazardous according to the Hazardous Substances (Minimum Degrees of Hazard) Regulations 2001, New Zealand.
GHS classification of
the
substance/mixture
WARNINGSignal Word (s)
H303 May be harmful if swallowed.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.
Hazard Statement (s)
Exclamation markPictogram (s)
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CS: 3.3.2
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Safety Data Sheet
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Emergency Response Number: 1800 625 526
Infosafe No™ IMIDS March 2017 ISSUED by IMCDASTIssue Date :
Fluoresceine DyeProduct Name :
Classified as hazardous
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.P264 Wash contaminated skin thoroughly after handling.P272 Contaminated work clothing should not be allowed out of the workplace.P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary
statement –
Prevention
P302+P352 IF ON SKIN: Wash with plenty of soap and water.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P312 Call a POISON CENTER or doctor/physician if you feel unwell.P332+P313 If skin irritation occurs: Get medical advice/attention.P333+P313 If skin irritation or rash occurs: Get medical advice/attention.P337+P313 If eye irritation persists: Get medical advice/attention.P362 Take off contaminated clothing and wash before reuse.P363 Wash contaminated clothing before reuse.
Precautionary
statement – Response
P501 Dispose of contents/container according to local regulations.Precautionary
statement – DisposalHSNO Approval Number: HSR002503Haz classes: 6.1E, 6.3A, 6.4A, 6.5BGroup Standard: Additives, Process Chemicals and Raw Materials (Subsidiary Hazard)
Other Information
3. Composition/information on ingredients
Name CAS ProportionIngredients
Sodium carbonate 497-19-8 <60 %
Fluorescein 2321-07-5 44-47 %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other Information
4. First-aid measures
You should call a doctor or Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. Have the Safety Data Sheet with you when you call.
First Aid Measures
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Inhalation
Do NOT induce vomiting if the product is swallowed or enters mouth; wash out mouth with water and provide water to drink. Never give anything by mouth to unconscious person. If large quantities of this material is swallowed, call a physician immediately. Loosen tight clothing such as collar, tie, belt or waistband.
Ingestion
Excess product may be washed off. Flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed, if irritation does occur.
Skin
Flush the exposed eye(s) with lukewarm gently flowing water immediately, while holding the eyelid(s) open until the product have been removed. Seek medical attention if the eye(s) continue to be irritated, or if product is trapped in surface of the eye(s). If exposed person is wearing contact lenses, special care must be taken.
Eye contact
Maintain eyewash fountain and safety shower in work area.First Aid Facilities
5. Fire-fighting measures
If involved in fire, Firefighters must wear selfcontained breathing apparatus and protective clothingin fighting large fires. If safe to do so, remove containers from path of
Fire Fighting
Measures
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CS: 3.3.2
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Safety Data Sheet
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Emergency Response Number: 1800 625 526
Infosafe No™ IMIDS March 2017 ISSUED by IMCDASTIssue Date :
Fluoresceine DyeProduct Name :
Classified as hazardous
fire.Use Dry Chemical Powder or water jet. Fight larger fires with water sprays, fog or foam.
Suitable
extinguishing mediaIf involved with a fire, the following can be released: Carbon Monoxide and Carbon Dioxide.
Hazards from
Combustion
ProductsIf a significant quantity of this product is involved in a fire, call the fire brigade. Do not scatter spilled material with high pressure water jets.
Specific Methods
Combustion is unlikely to occur. Inhalation of heated toxic and/or oxygen deficient fire gases is typically the major hazard in fires.
Specific hazards
arising from the
chemicalNo data available.Decomposition Temp.
6. Accidental release measures
Avoid accidents, clean up immediately. Clear area of unprotected personnel. Wear protective equipment to prevent eye contact. Collect and seal in properly labelled containers or drums for disposal. Wash area down with excess water.
Emergency
Procedures
If safe to do so, stop leak, and contain spill. Prevent from entering into soil, ditches, sewers, water ways, and/or ground water. Use absorbent (soil, sand or other inert) material. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. This material may be suitable for approved landfill. Ensure legality of disposal by consultingregulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Methods and
materials for
containment and
cleaning up
Prevent from entering into soil, ditches, sewers, water ways, and/or ground water. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.
Environmental
Precautions
7. Handling and storage
Keep container tightly sealed. Store in cool dry place away from heat and sources of ignition. Keep locked up. Ensure good ventilation/exhaustion at the workplace. Do not breathe dust. Avoid contact with skin and eyes.
Precautions for Safe
Handling
Make sure that containers of this product are kept tightly closed. Keep containers dry and away from water. Make sure that the product does not come into contact with substances listed under 'Incompatibilities' in Section 10. Check packaging - there may be further storage instructions on the label. Keep away from children.
Conditions for safe
storage, including
any incompatibilities
8. Exposure controls/personal protection
The following Australian and New Zealand Standards will provide general advice regarding safety clothing and equipment:Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
Exposure Controls,
Personal Protection
No exposure standards have been established for this product by Worksafe Australia, however, the TWA exposure standard for dusts not otherwise specified is 10 mg/m3.
Occupational
exposure limit values
Ensure ventilation is adequate and that air concentrations of components are controlled below quoted Workplace Exposure Standards. Keep containers closed when not in use. If in the handling and application of this material, safe exposure levels could be exceeded, the use of engineering controls such as local exhaust must be considered and results documented. If achieving safe exposure levels does not require engineering controls, then a detailed and documented risk
Appropriate
engineering controls
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CS: 3.3.2
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Safety Data Sheet
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Emergency Response Number: 1800 625 526
Infosafe No™ IMIDS March 2017 ISSUED by IMCDASTIssue Date :
Fluoresceine DyeProduct Name :
Classified as hazardous
assessment using the relevant Personal Protective Equipment (PPE) (refer to PPE section below) as a basis must be carried out to determine the minimum PPE requirements.If there is a significant chance that dusts are likely to build up in the area where this product is being used, we recommend that you use a suitable dust mask. Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.
Respiratory
Protection
Wear suitable protective glasses or goggles.Eye Protection
The information at hand indicates that this product is not harmful and that normally no special skin protection is necessary. However, we suggest that you routinely avoid contact with all chemical products and that you wear suitable gloves (preferably elbow-length) when the skin contact is likely.We suggest that protective clothing be made from the following materials: cotton, rubber, PVC.
Hand Protection
Protective clothing.We suggest that protective clothing be made from the following materials: cotton, rubber, PVC.
Body Protection
Ensure that eyewash stations and safety showers are close to the workstation location. General industrial hygiene practice.
Hygiene Measures
9. Physical and chemical properties
SolidForm
Solid crystalline powder.Appearance
Yellow (Yellowish–Red) to RedColour
No odour.Odour
No data available.Decomposition
Temperature315 °CMelting Point
No data available.Freezing Point
No data available.Boiling Point
Insoluble in cold waterSolubility in Water
Insoluble in diethyl ether, petroleum ether, benzene. Soluble in methanol, hot alcohol,, glacial acetic acid, alkali hydroxides and carbonates.
Solubility in Organic
Solvents
No data available.Specific Gravity
No data available.pH
Negligible at normal ambient temperatures.Vapour Pressure
No data available.Vapour Density
(Air=1)No data available.Evaporation Rate
No data available.Coefficient
Water/Oil Distr.No data available.Odour Threshold
Nil at normal ambient temperatures.Volatile Component
No data available.Flash Point
No data available.Flammability
Not applicable - does not burn.Auto-Ignition
TemperatureNo data available.Flammable Limits -
Lower
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CS: 3.3.2
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Emergency Response Number: 1800 625 526
Infosafe No™ IMIDS March 2017 ISSUED by IMCDASTIssue Date :
Fluoresceine DyeProduct Name :
Classified as hazardous
No data available.Flammable Limits -
UpperNo data available.Explosion Properties
No data available.Oxidising Properties
10. Stability and reactivity
This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
Reactivity
Moisture.Excess heat, excess dust generation incompatible materials.
Conditions to Avoid
Reactive with oxidizing agents.Incompatible
MaterialsNo significant quantities of decomposition products are expected at temperatures normally achieved in a fire
Hazardous
Decomposition
ProductsWill not occur.Hazardous
Polymerization
11. Toxicological Information
No data is available on the product itself.Components:Sodium carbonate: LD50, rat: 4090 mg/kg (NZ CCID)Fluorescein: LD50, mouse: 4738 mg/kg (NZ CCID)
Acute Toxicity - Oral
No data available.Acute Toxicity -
DermalNo data is available on the product itself.Components:Sodium carbonate: LC50, rat, dust/mist 2hr: 2.3mg (NZ CCID)
Acute Toxicity -
Inhalation
Swallowing may result in nausea, vomiting, abdominal pain to gastrointestinal tract.
Ingestion
Breathing in mist or aerosols may produce respiratory irritation.Inhalation
Contact to skin may cause mild irritation.Skin
Spray or mist can cause mild eye irritationEye
No data available.Respiratory
sensitisationMay cause an allergic skin reaction.Skin Sensitisation
No data available.Germ cell
mutagenicityNo data available.Carcinogenicity
No data available.Reproductive
ToxicityNo data available.STOT-single
exposureNo data available.STOT-repeated
exposureNo data available.Aspiration Hazard
Mutagenic effects: Mutagenic for bacteria and/or yeast.Chronic Effects
May cause eye irritation.Serious eye
damage/irritationRepeated prolonged contact may cause drying of the skin leading to flaking.Skin
corrosion/irritation
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CS: 3.3.2
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Safety Data Sheet
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Emergency Response Number: 1800 625 526
Infosafe No™ IMIDS March 2017 ISSUED by IMCDASTIssue Date :
Fluoresceine DyeProduct Name :
Classified as hazardous
12. Ecological information
This product is unlikely to adversely affect the environment. Salts, acids and bases are typically diluted and neutralised when released to the environment in small quantities. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Expected to not be an environmental hazard.
Ecological
Information
No data available.Ecotoxicity
No data available.Persistence and
degradabilityNo data available.Mobility
No data available.Bioaccumulative
PotentialNo data available.Other Adverse
Effects
13. Disposal considerations
Dispose of waste according to applicable local, state and federal regulations.Disposal
ConsiderationsThis product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these options is suitable, consider landfill. Refer to Waste Management Authority. Dispose of contents/container in accordance with local/regional/national/international regulations.
Waste Disposal
14. Transport information
Not classified as a Dangerous Good according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. Not regulated for transport of Dangerous Goods: ADG7, UN, IATA, IMDG.
Transport
Information
15. Regulatory information
All components of this material are listed on or exempt from the New Zealand Inventory of Chemicals (NZIoC).
Regulatory
InformationNot ScheduledPoisons Schedule
HSR002503HSNO Approval
NumberAll components of this material are listed on or exempt from the Australian Inventory of Chemical Substances (AICS).
AICS (Australia)
16. Other Information
An electronic version of this SDS is available at www.imcdgroup.comContact Person/Point
ADG Code: Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th EditionAICS: Australian Inventory of Chemical SubstancesASCC: Office of the Australian Safety and Compensation CouncilBCF: Bioconcentration FactorCAS number: Chemical Abstracts Service Registry NumberCMR: Carcinogenic, Mutagenic or toxic to ReproductionDMEL: Derived Minimum Effect LevelDNEL: Desired NO Effect LevelEPA: Environmental Protection AgencyGHS: Globally Harmonised System of Classification and Labelling of ChemicalsHazchem Code: Emergency action code of numbers and letters that provide information to emergency services especially fire fightersIARC: International Agency for Research on Cancer
Other Information
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CS: 3.3.2
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Emergency Response Number: 1800 625 526
Infosafe No™ IMIDS March 2017 ISSUED by IMCDASTIssue Date :
Fluoresceine DyeProduct Name :
Classified as hazardous
IOELV: Indicative Occupational Exposure Limit ValueLC50: Lethal Concentration, 50 percentLD50: Lethal Dose, 50 percentNICNAS: National Industrial Notification & Assessment SchemeNIOSH: National Institute for Occupational Safety & HealthNOAEL: No Observed Adverse Effect LevelNOEC: No Observed Effect ConcentrationNOS: Not otherwise specifiedNTP: National Toxicology Program (USA)OEL: Occupational Exposure LimitOSHA: Occupational Safety & Health AdministrationPBT: Persistent Bioaccumulative Toxic chemicalPMCC: Pensky Martens Closed CupPNEC: Predicted No Effect ConcentrationR-Phrase: Risk PhraseSTEL: Short Term Exposure LimitSTOT-SE: Specific Target Organ Toxicity (Single Exposure)STOT-RE: Specific Target Organ Toxicity (Repeated Exposure)SUSMP: Standard for the Uniform Scheduling of Medicines & PoisonsTWA: Time Weighted AverageUN Number: United Nations NumbervPvB: Very Persistent and Very BioaccumulativeWEEL: Workplace Environmental Exposure LevelWEL-TWA: Workplace Exposure Limit, Time Weighted Average...End Of MSDS...
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Print Date: 4/03/2019 CS: 3.3.2
SAFETY DATA SHEET
GASCON 469
Revision Date: 16-Aug-2018 Revision Number: 30
1. Identification
Product Name Product Trade Name: GASCON 469
Other Names Synonyms None
Hazardous Material Number: HM000753
Recommended Use Recommended Use Cement Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
136-140 Connett Road East,Bell Block, New PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.3B (Mildly) irritating to the skin
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Warning
Hazard Statements H316 - Causes mild skin irritation
Precautionary Statements
Prevention P103 - Read label before useP104 - Read Safety Data Sheet before use.
Response P332 + P313 - If skin irritation occurs: Get medical advice/attention
Storage None
Disposal P501 - Dispose of contents/container to an approved waste disposal plant
Contains
Substances CAS Number Substance HSNO Classification
_____________________________________________________________________________________________
Page 1 / 7
_____________________________________________________________________________________________GASCON 469 Revision Date: 16-Aug-2018
Sodium hydroxide 1310-73-2 6.1D (Oral)6.1D (Dermal)8.1A8.2B8.3A9.1D (Crustacean, Fish)9.3C
2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Sodium hydroxide 1310-73-2 0.1 - 1%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses mild skin irritation.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireNot applicable
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
_____________________________________________________________________________________________
Page 2 / 7
Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequate
_____________________________________________________________________________________________GASCON 469 Revision Date: 16-Aug-2018
ventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool well ventilated area. Keep from excessive heat. Keep from freezing. Keep container closed when not in use.Store in non-rusting containers. Product has a shelf life of 12 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWASodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)
Hand Protection None known.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
_____________________________________________________________________________________________
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_____________________________________________________________________________________________GASCON 469 Revision Date: 16-Aug-2018
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 10
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range 100 °C / 212 °F
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.1
Water Solubility Soluble in water (10g/100ml)
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) 80
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers. Strong acids.
10.6. Hazardous decomposition products None known.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation None known.
Eye Contact May cause mechanical irritation to eye.
Skin Contact Causes mild skin irritation.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Sodium hydroxide 1310-73-2 Not applicable due to corrosivityof the substance.
Not applicable due to corrosivityof the substance.
Not applicable due to corrosivityof the substance.
Substances CAS Skin corrosion/irritation
Physical State: Liquid Color Transparent
Odor: Odorless Odor Threshold:
_____________________________________________________________________________________________
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No information available
_____________________________________________________________________________________________GASCON 469 Revision Date: 16-Aug-2018
Number
Sodium hydroxide 1310-73-2 Causes severe burns
Substances CASNumber
Serious eye damage/irritation
Sodium hydroxide 1310-73-2 Causes severe eye burns (Rabbit)
Substances CASNumber
Skin Sensitization
Sodium hydroxide 1310-73-2 Did not cause sensitization on laboratory animals (guinea pig)
Substances CASNumber
Respiratory Sensitization
Sodium hydroxide 1310-73-2 No information available
Substances CASNumber
Mutagenic Effects
Sodium hydroxide 1310-73-2 Did not show mutagenic effects in animal experiments In vitro tests did not show mutagenic effects.
Substances CASNumber
Carcinogenic Effects
Sodium hydroxide 1310-73-2 No data of sufficient quality are available.
Substances CASNumber
Reproductive toxicity
Sodium hydroxide 1310-73-2 No information available
Substances CASNumber
STOT - single exposure
Sodium hydroxide 1310-73-2 May cause respiratory irritation.
Substances CASNumber
STOT - repeated exposure
Sodium hydroxide 1310-73-2 No significant toxicity observed in animal studies at concentration requiring classification. Notapplicable due to corrosivity of the substance.
Substances CASNumber
Aspiration hazard
Sodium hydroxide 1310-73-2 Not applicable
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Sodium hydroxide 1310-73-2 No information available LC50(48h) 189 mg/L(Leuciscus idus
melanotus)LLC50(48h) 189 mg/L(Leuciscus melanotus)LC50(24h) 145 mg/L(Poecilia reticulate)
LC50(96h) 125 mg/L(Gambusia affinis)
LOEL(150 d) = 25 mg/L(Lebistes reticulatus)
No information available EC50 (48h) 40.4 mg/L(Ceriodaphnia sp.)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Sodium hydroxide 1310-73-2 The methods for determiningbiodegradability are not applicable toinorganic substances.
12.3. Bioaccumulative potential
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_____________________________________________________________________________________________GASCON 469 Revision Date: 16-Aug-2018
Substances CAS Number Bioaccumulation
Sodium hydroxide 1310-73-2 No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Sodium hydroxide 1310-73-2 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Incineration recommended in approved incinerator according to federal, state, and localregulations. Substance should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002503
Group Name Additives, Process Chemicals and Raw Materials (Subsidiary hazard HSR002503)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
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_____________________________________________________________________________________________GASCON 469 Revision Date: 16-Aug-2018
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 16-Aug-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
GEM™ CPRevision Date: 15-Mar-2017 Revision Number: 21
1. Product and Company Identification
Product Name Product Trade Name: GEM™ CP
Other Names Synonyms None
Hazardous Material Number: HM003659
Recommended Use Recommended Use Shale stabilizer
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number: +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1D (Inhalation) Acutely Toxic Substances6.9B Harmful to human target organs or systems
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Warning
Hazard Statements H332 - Harmful if inhaledH373 - May cause damage to organs through prolonged or repeated exposure
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at hand
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_____________________________________________________________________________________________GEM™ CP Revision Date: 15-Mar-2017
P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP271 - Use only outdoors or in a well-ventilated area
Response P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a positioncomfortable for breathingP312 - Call a POISON CENTER or doctor/physician if you feel unwellP331 - Do NOT induce vomitingP314 - Get medical attention/advice if you feel unwell
Storage None
Disposal P501 - Dispose of contents/container to an approved incineration plant
Contains
Substances CAS Number Substance HSNO Classification
Methyloxirane polymer with oxirane, monbutylether
9038-95-3 Not applicable
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Methyloxirane polymer with oxirane, monbutyl ether 9038-95-3 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably
mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water forat least 15 minutes and get medical attention immediately after flushing.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsHarmful if inhaled.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
_____________________________________________________________________________________________
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Special Protective Equipment and Precautions for Fire Fighters
_____________________________________________________________________________________________GEM™ CP Revision Date: 15-Mar-2017
Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid breathing vapors. Avoid contact with skin, eyes and clothing. Ensure adequateventilation. Evacuate all persons from the area.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid breathing vapors. Avoid breathing mist. Ensure adequate ventilation. Avoid contact with eyes, skin, or clothing. Useappropriate protective equipment. Wash hands after use. Launder contaminated clothing before reuse.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store away from acids. Store away from alkalis. Keep container closed when not in use. Producthas a shelf life of 60 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAMethyloxirane polymer withoxirane, monbutyl ether
9038-95-3 Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without
good cross ventilation.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Organic vapor respirator with a dust/mist filter. (A2P2/P3)
Hand Protection Impervious rubber gloves. Polyvinylchloride gloves. Neoprene gloves.
Skin Protection Rubber apron.
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_____________________________________________________________________________________________GEM™ CP Revision Date: 15-Mar-2017
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 5-7.5 (10%)
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point > 93 °C / > 200 °F PMCC
Evaporation rate < 0.1
Vapor Pressure < 0.01 mmHg
Vapor Density > 1
Specific Gravity 1.02
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/waterAutoignition Temperature 370 °C / 698 °F
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight 405
VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers. Strong acids. Strong alkalis.
10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation Harmful if inhaled.
Eye Contact Non-irritating to rabbit's eye
Skin Contact Not irritating to skin in rabbits.
Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Physical State: Liquid Color Clear light yellow
Odor: Mild Odor Threshold:
_____________________________________________________________________________________________
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No information available
_____________________________________________________________________________________________GEM™ CP Revision Date: 15-Mar-2017
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Methyloxirane polymerwith oxirane, monbutylether
9038-95-3 >5000 mg/kg-bw (rat) >8000 mg/kg-bw (rabbit) >1 - <5 mg/L (rat, 4 h, aerosol)
Substances CASNumber
Skin corrosion/irritation
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 Not a dermal irritant Non-irritating to the skin
Substances CASNumber
Serious eye damage/irritation
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 Non-irritating to the eye
Substances CASNumber
Skin Sensitization
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 No sensitization responses were observed (similar substances)
Substances CASNumber
Respiratory Sensitization
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 No information available
Substances CASNumber
Mutagenic Effects
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 No information available
Substances CASNumber
Carcinogenic Effects
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 Did not show carcinogenic effects in animal experiments (similar substances)
Substances CASNumber
Reproductive toxicity
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 No information available
Substances CASNumber
STOT - single exposure
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 No data of sufficient quality are available.
Substances CASNumber
STOT - repeated exposure
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 No data of sufficient quality are available.
Substances CASNumber
Aspiration hazard
Methyloxirane polymer withoxirane, monbutyl ether
9038-95-3 Not applicable
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Methyloxirane 9038-95-3 EC50(72 h)=465 mg/L LC50(96 h)=3200 mg/L No information available EC50(48 h)=4400 mg/L
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_____________________________________________________________________________________________GEM™ CP Revision Date: 15-Mar-2017
polymer with oxirane,monbutyl ether
(Skeletonema costatum) (Pimephales promelas)LC50(96 h)>1800 mg/L
(Scophthalmusmaximus)
(Daphnia magna)LC50(48 h)=356 mg/L
(Acartia tonsa)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Methyloxirane polymer with oxirane, monbutyl ether 9038-95-3 (24% @ 20d)
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Methyloxirane polymer with oxirane, monbutylether
9038-95-3 Log Pow=0.353
12.4. Mobility in soil
Substances CAS Number Mobility
Methyloxirane polymer with oxirane, monbutyl ether 9038-95-3 No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR003207
Group Name Not Applicable
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_____________________________________________________________________________________________GEM™ CP Revision Date: 15-Mar-2017
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 15-Mar-2017
Revision NoteSDS sections updated:121114
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
GEM™ GP
1. Product and Company Identification
Product Name Product Trade Name: GEM™ GP
Other Names Synonyms: None
Product Code: HM003660
Recommended Use Recommended Use Shale stabilizer
Uses Advised Against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-Mail address: fdunexchem@halliburton.com
Emergency Telephone Number +64-6-7559274
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 6.1D (Oral) Acutely Toxic Substances
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Warning
Hazard Statements H302 - Harmful if swallowed
Precautionary Statements
Prevention P101 - If medical advice is needed, have product container or label at handP102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P264 - Wash face, hands and any exposed skin thoroughly after handling
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Revision Date: 14-May-2015 Revision Number: 41
_____________________________________________________________________________________________P270 - Do not eat, drink or smoke when using this product
Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP331 - Do NOT induce vomiting
Storage None
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
Contains
Substances CAS Number Substance HSNO Classification
Polyethylene glycol butyl ether 9004-77-7 6.1D (Oral)
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)
Polyethylene glycol butyl ether 9004-77-7 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, move victim to fresh air and seek medical attention.
Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek promptmedical attention.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardCombustible liquid
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special Exposure HazardsDecomposition in fire may produce harmful gases.
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GEM™ GP Revision Date: 14-May-2015
_____________________________________________________________________________________________
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothingbefore reuse. Ensure adequate ventilation. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store away from acids. Keep container closed when not in use.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWA
Polyethylene glycol butyl ether 9004-77-7 Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without
good cross ventilation.
Personal Protective Equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Organic vapor respirator.
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, directcontact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374): Nitrile gloves. (>= 0.35 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerablyshorter than the permeation time determined in accordance with EN 374 as a result of
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GEM™ GP Revision Date: 14-May-2015
_____________________________________________________________________________________________the many influencing factors (e.g. temperature). If signs of wear and tear are noticedthen the gloves should be replaced. Manufacturer's directions for use should beobserved because of great diversity of types.
Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 6.5 - 9
Freezing Point/Range -45 °C
Melting Point/Range No data available
Boiling Point/Range 126 °C / 260 °F
Flash Point 166 °C / 330 °F PMCC
upper flammability limit 3.8 %
lower flammability limit 0.8 %
Evaporation rate No data available
Vapor Pressure 0.002 mmHg
Vapor Density No data available
Specific Gravity 1.012
Water Solubility Miscible with water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature 203 °C / 397.4 °F
Decomposition Temperature No data available
Viscosity 10-11 cP @ 20°C
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical Stability Stable
10.4. Conditions to Avoid Keep away from heat, sparks and flame.
10.5. Incompatible Materials Strong oxidizers. Mineral acids.
10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact Causes severe eye irritation which may damage tissue.
Skin Contact May cause mild skin irritation.
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,
_____________________________________________________________________________________________
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Physical State: Liquid
GEM™ GP
Color: Yellow to brown
Revision Date: 14-May-2015
Odor: Mild Odor Threshold: No information available
_____________________________________________________________________________________________nausea, and diarrhea.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Polyethylene glycol butylether
9004-77-7 > 5000 mg/kg (Rat)> 2000 mg/kg (Rat)
6540 mg/kg (Rat)3540 mg/kg (Rabbit) (similar
substance)> 2000 mg/kg (Rat) (similar
substance)
> 2.6 mg/L (Rat) 4h (similarsubstance)
> 2000 mg/L (Rat) 1h (similarsubstance)
Substances CASNumber
Skin corrosion/irritation
Polyethylene glycol butylether
9004-77-7 Non-irritating to the skin (Rabbit)
Substances CASNumber
Eye damage/irritation
Polyethylene glycol butylether
9004-77-7 Eye, rabbit: Causes severe eye irritation which may damage tissue.
Substances CASNumber
Skin Sensitization
Polyethylene glycol butylether
9004-77-7 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)
Substances CASNumber
Mutagenic Effects
Polyethylene glycol butylether
9004-77-7 In vivo tests did not show mutagenic effects. In vitro tests did not show mutagenic effects (similarsubstances)
Substances CASNumber
Carcinogenic Effects
Polyethylene glycol butylether
9004-77-7 No information available.
Substances CASNumber
Reproductive toxicity
Polyethylene glycol butylether
9004-77-7 Not regarded as a reproductive and developmental toxicant. Did not show teratogenic effects inanimal experiments. (similar substances)
Substances CASNumber
STOT - single exposure
Polyethylene glycol butylether
9004-77-7 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Substances CASNumber
STOT - repeated exposure
Polyethylene glycol butylether
9004-77-7 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)
Substances CASNumber
Aspiration hazard
Polyethylene glycol butylether
9004-77-7 Not applicable
12. Ecological Information
12.1. Toxicity Ecotoxicity Effects
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Revision Date: 14-May-2015GEM™ GP
_____________________________________________________________________________________________
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Polyethylene glycolbutyl ether
9004-77-7 EC50(72h): 391 mg/L(growth rate)
(Skeletonema costatum)
EC50: 475 ppm (Abraalba)
LC50(96h): >1800 mg/L(Scophthalmus
maximus)
IC50(16h): > 5000 mg/L(Growth inhibition,
Activated sludge) (similarsubstance –
2-(2-(2-butoxyethoxy)ethoxy)ethanol)
EC10(30m): > 1995mg/L (respiration rate,
activated sludge) (similarsubstance –
2-(2-(2-butoxyethoxy)ethoxy)ethanol)
TLM48: 310 mg/l(Acartia tonsa)
EC50(48h): > 3200 mg/L(Daphnia magna)(similar substance –ethanol, 2-butoxy-,
manufacture of,by-products from)
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Polyethylene glycol butyl ether 9004-77-7 Readily biodegradable (68% @ 28d)
12.3. Bioaccumulative potential Does not bioaccumulate
Substances CAS Number Log Pow
Polyethylene glycol butyl ether 9004-77-7 0.436
12.4. Mobility in soil
Substances CAS Number Mobility
Polyethylene glycol butyl ether 9004-77-7 Log Kow < 4.5
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
IMDG/IMO UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number: Not restricted
_____________________________________________________________________________________________
Page 6 / 7
GEM™ GP Revision Date: 14-May-2015
_____________________________________________________________________________________________
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User: None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
Group Name Not Applicable
ERMA Register Approval Number HSR003673
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
The following sections have been revised since the last issue of this SDSNot applicable
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 14-May-2015
Revision Note Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
Revision Date: 14-May-2015GEM™ GP
SAFETY DATA SHEET
HALAD® 344 CEMENT ADDITIVE
Revision Date: 22-Jun-2016 Revision Number: 35
1. Product and Company Identification
Product Name Product Trade Name: HALAD® 344 CEMENT ADDITIVE
Other Names Synonyms None
Hazardous Material Number: HM000816
Recommended Use Recommended Use Fluid Loss Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number: +64 800 451719
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazard(s) Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable
2.3. Other Hazards
_____________________________________________________________________________________________
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_____________________________________________________________________________________________HALAD® 344 CEMENT ADDITIVE Revision Date: 22-Jun-2016
This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition and Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First-Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Getimmediate medical attention.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardCombustible dust when in finely divided and highly suspended state.
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
6. Spillage, Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
_____________________________________________________________________________________________
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6.3. Methods and material for containment and cleaning up
_____________________________________________________________________________________________HALAD® 344 CEMENT ADDITIVE Revision Date: 22-Jun-2016
Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location. Store away from oxidizers. Keep container closed when not in use. Product has a shelf life of 60months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls and Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational
exposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)
Hand Protection None known.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: No data available
Freezing Point / Range -8 °C
Physical State: Powder Color White to off white
Odor: Odorless Odor Threshold:
_____________________________________________________________________________________________
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No information available
_____________________________________________________________________________________________HALAD® 344 CEMENT ADDITIVE Revision Date: 22-Jun-2016
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.37
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information Molecular Weight > 600
VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials None known.
10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide. Oxides of sulfur.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation None known.
Eye Contact Non-irritating to rabbit's eye
Skin Contact Not irritating to skin in rabbits.
Ingestion No adverse health effects are expected from swallowing.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________HALAD® 344 CEMENT ADDITIVE Revision Date: 22-Jun-2016
12. Ecological Information
12.1. Toxicity Ecotoxicity effects
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability Not readily biodegradableSubstances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential Does not bioaccumulate.
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance
should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
_____________________________________________________________________________________________
Page 5 / 7
_____________________________________________________________________________________________HALAD® 344 CEMENT ADDITIVE Revision Date: 22-Jun-2016
14. Transport Information
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Special Precautions for User None
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
Page 6 / 7
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organization
_____________________________________________________________________________________________HALAD® 344 CEMENT ADDITIVE Revision Date: 22-Jun-2016
mg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 22-Jun-2016
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
HALAD® 413 CEMENT ADDITIVE
Revision Date: 01-Jun-2018 Revision Number: 30
1. Identification
Product Name Product Trade Name: HALAD® 413 CEMENT ADDITIVE
Other Names Synonyms None
Hazardous Material Number: HM000823
Recommended Use Recommended Use Fluid Loss Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Non-hazardous
_____________________________________________________________________________________________
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_____________________________________________________________________________________________HALAD® 413 CEMENT ADDITIVE Revision Date: 01-Jun-2018
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential.
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
_____________________________________________________________________________________________
Page 2 / 7
6.2. Environmental precautions
_____________________________________________________________________________________________HALAD® 413 CEMENT ADDITIVE Revision Date: 01-Jun-2018
Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
_____________________________________________________________________________________________
Page 3 / 7
9.1. Information on basic physical and chemical properties
_____________________________________________________________________________________________HALAD® 413 CEMENT ADDITIVE Revision Date: 01-Jun-2018
Property Values Remarks/ - Method
pH: 7.5
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.48
Water Solubility Miscible with water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation None known.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values according
NA No data available No data available No data available
Physical State: Solid Color Brown-black
Odor: Sweet Odor Threshold: No information available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________HALAD® 413 CEMENT ADDITIVE Revision Date: 01-Jun-2018
to the competentauthority
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
_____________________________________________________________________________________________
Page 5 / 7
_____________________________________________________________________________________________HALAD® 413 CEMENT ADDITIVE Revision Date: 01-Jun-2018
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-Hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
Page 6 / 7
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organization
_____________________________________________________________________________________________HALAD® 413 CEMENT ADDITIVE Revision Date: 01-Jun-2018
mg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 01-Jun-2018
Revision NoteSDS sections updated:1
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
HALAD® 413L CEMENT ADDITIVE
Revision Date: 30-Jul-2018 Revision Number: 27
1. Identification
Product Name Product Trade Name: HALAD® 413L CEMENT ADDITIVE
Other Names Synonyms None
Hazardous Material Number: HM000824
Recommended Use Recommended Use Fluid Loss Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
136-140 Connett Road East,Bell Block, New PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances in NA Non-hazardous
_____________________________________________________________________________________________
Page 1 / 7
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 30-Jul-2018
concentrations above cut-off values according tothe competent authority
2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors.See Section 8 for additional information
6.2. Environmental precautions
_____________________________________________________________________________________________
Page 2 / 7
Prevent from entering sewers, waterways, or low areas.
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 30-Jul-2018
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothingbefore reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Product has a shelf life of 24 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
_____________________________________________________________________________________________
Page 3 / 7
9.1. Information on basic physical and chemical properties
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 30-Jul-2018
Property Values Remarks/ - Method
pH: 7.5
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.1
Water Solubility Miscible with water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation None known.
Eye Contact None known.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values according
NA No data available No data available No data available
Physical State: Liquid Color Brown-black
Odor: Sweet Odor Threshold: No information available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 30-Jul-2018
to the competentauthority
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
_____________________________________________________________________________________________
Page 5 / 7
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 30-Jul-2018
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-Hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
Page 6 / 7
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organization
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 30-Jul-2018
mg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 30-Jul-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
HALAD® 567 CEMENT ADDITIVE
Revision Date: 01-Jun-2018 Revision Number: 19
1. Identification
Product Name Product Trade Name: HALAD® 567 CEMENT ADDITIVE
Other Names Synonyms None
Hazardous Material Number: HM003245
Recommended Use Recommended Use Fluid Loss Additive
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Non-hazardous
_____________________________________________________________________________________________
Page 1 / 7
_____________________________________________________________________________________________HALAD® 567 CEMENT ADDITIVE Revision Date: 01-Jun-2018
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Ensure adequate ventilation. Avoid contact with skin,eyes and clothing.See Section 8 for additional information
6.2. Environmental precautions
_____________________________________________________________________________________________
Page 2 / 7
Prevent from entering sewers, waterways, or low areas.
_____________________________________________________________________________________________HALAD® 567 CEMENT ADDITIVE Revision Date: 01-Jun-2018
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensureadequate ventilation. Wash hands after use. Launder contaminated clothing before reuse.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 48 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: No data available
Freezing Point / Range No data available
Physical State: Solid Color Brown
Odor: Characteristic Odor Threshold:
_____________________________________________________________________________________________
Page 3 / 7
No information available
_____________________________________________________________________________________________HALAD® 567 CEMENT ADDITIVE Revision Date: 01-Jun-2018
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.47
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Ammonia. Oxides of nitrogen. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation None known.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
_____________________________________________________________________________________________
Page 4 / 7
_____________________________________________________________________________________________HALAD® 567 CEMENT ADDITIVE Revision Date: 01-Jun-2018
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance
should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
NZ 5433.1999 UN Number Not restricted
_____________________________________________________________________________________________
Page 5 / 7
_____________________________________________________________________________________________HALAD® 567 CEMENT ADDITIVE Revision Date: 01-Jun-2018
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers This product does NOT require an approved handler.
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
Page 6 / 7
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimeter
_____________________________________________________________________________________________HALAD® 567 CEMENT ADDITIVE Revision Date: 01-Jun-2018
mmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 01-Jun-2018
Revision NoteSDS sections updated:1
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
HR-5
Revision Date: 01-Jun-2018 Revision Number: 33
1. Identification
Product Name Product Trade Name: HR-5
Other Names Synonyms None
Hazardous Material Number: HM000899
Recommended Use Recommended Use Cement Retarder
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Non-hazardous
_____________________________________________________________________________________________
Page 1 / 7
_____________________________________________________________________________________________HR-5 Revision Date: 01-Jun-2018
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
_____________________________________________________________________________________________
Page 2 / 7
_____________________________________________________________________________________________HR-5 Revision Date: 01-Jun-2018
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store in a cool, dry location.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 9.5-10.3
Physical State: Solid Color Black
Odor: Molasses Odor Threshold:
_____________________________________________________________________________________________
Page 3 / 7
No information available
_____________________________________________________________________________________________HR-5 Revision Date: 01-Jun-2018
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.41
Water Solubility Soluble in water (25g/100ml)
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Oxides of sulfur.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
_____________________________________________________________________________________________
Page 4 / 7
_____________________________________________________________________________________________HR-5 Revision Date: 01-Jun-2018
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance
should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
NZ 5433.1999
_____________________________________________________________________________________________
Page 5 / 7
_____________________________________________________________________________________________HR-5 Revision Date: 01-Jun-2018
UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers This product does NOT require an approved handler.
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
_____________________________________________________________________________________________
Page 6 / 7
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic meter
_____________________________________________________________________________________________HR-5 Revision Date: 01-Jun-2018
mm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 01-Jun-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 7 / 7
SAFETY DATA SHEET
HR-6L
Revision Date: 01-Jun-2018 Revision Number: 17
1. Identification
Product Name Product Trade Name: HR-6L
Other Names Synonyms None
Hazardous Material Number: HM000901
Recommended Use Recommended Use Cement Retarder
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Non-hazardous
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_____________________________________________________________________________________________HR-6L Revision Date: 01-Jun-2018
2.3. Other Hazards None known
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up
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Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
_____________________________________________________________________________________________HR-6L Revision Date: 01-Jun-2018
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Keep container closed when not in use.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Not normally necessary.
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 9.5
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point > 98 °C / > 210 °F PMCC
Physical State: Liquid Color Dark brown
Odor: Molasses Odor Threshold:
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No information available
_____________________________________________________________________________________________HR-6L Revision Date: 01-Jun-2018
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.21
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
Liquid Density 10.08 lbs/gal
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
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_____________________________________________________________________________________________HR-6L Revision Date: 01-Jun-2018
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods This product is not regarded as hazardous waste. Dispose in accordance with local
regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO
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_____________________________________________________________________________________________HR-6L Revision Date: 01-Jun-2018
UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-Hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
_____________________________________________________________________________________________
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Key literature references and sources for datawww.ChemADVISOR.com/
_____________________________________________________________________________________________HR-6L Revision Date: 01-Jun-2018
NZ CCID
Revision Date: 01-Jun-2018
Revision NoteSDS sections updated:1
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
HR-25L
Revision Date: 28-Nov-2018 Revision Number: 36
1. Identification
Product Name Product Trade Name: HR-25L
Other Names Synonyms None
Hazardous Material Number: HM000893
Recommended Use Recommended Use Cement Retarder
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
136-140 Connett Road East, BlockNew PlymouthNew ZealandTelephone: +64 6-755 2405Company Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation 2001;Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification 8.3A Corrosive to ocular tissue9.3C Harmful to terrestrial vertebrates
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word Danger
Hazard Statements H318 - Causes serious eye damageH433 - Harmful to the terrestrial vertebrates.
Precautionary Statements
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_____________________________________________________________________________________________HR-25L Revision Date: 28-Nov-2018
Prevention P102 - Keep out of reach of childrenP103 - Read label before useP104 - Read Safety Data Sheet before use.P280 - Wear eye protection/face protection
Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Storage None
Disposal P501 - Dispose of contents/container to an approved waste disposal plant
Contains
Substances CAS Number Substance HSNO Classification
Tartaric acid 87-69-4 8.3A9.3C
2.3. Other Hazards This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Tartaric acid 87-69-4 30 - 60%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek promptmedical attention.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical attention.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardNon-flammable
5.1. Extinguishing media Suitable Extinguishing MediaAll standard fire fighting media
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
_____________________________________________________________________________________________
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Special exposure hazards in a fire
_____________________________________________________________________________________________HR-25L Revision Date: 28-Nov-2018
Decomposition in fire may produce harmful gases.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.See Section 8 for additional information
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Neutralize to pH of 6-8. Scoop up andremove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not inuse. Product has a shelf life of 60 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWATartaric acid 87-69-4 Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European StandardEN 149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selectionof and instruction on using all personal protective equipment, including respirators,should be performed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)
Hand Protection Impervious rubber gloves.
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_____________________________________________________________________________________________HR-25L Revision Date: 28-Nov-2018
Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method
pH: 1.7
Freezing Point / Range No data available
Melting Point / Range No data available
Pour Point / Range No data available
Boiling Point / Range 103 °C / 219 °F
Flash Point No data available
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.2
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers. Strong alkalis.
10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact Causes severe eye irritation which may damage tissue.
Skin Contact Not irritating to skin in rabbits.
Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Physical State: Liquid Color Light yellow-green
Odor: Odorless Odor Threshold: No information available
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_____________________________________________________________________________________________HR-25L Revision Date: 28-Nov-2018
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Tartaric acid 87-69-4 2000 - 5000 mg/kg (Rat) > 2000 mg/kg (Rat) No data available
Substances CASNumber
Skin corrosion/irritation
Tartaric acid 87-69-4 Non-irritating to the skin (Rabbit) (in vitro)
Substances CASNumber
Serious eye damage/irritation
Tartaric acid 87-69-4 Causes severe eye irritation (Rabbit)
Substances CASNumber
Skin Sensitization
Tartaric acid 87-69-4 Did not cause sensitization on laboratory animals (mouse)
Substances CASNumber
Respiratory Sensitization
Tartaric acid 87-69-4 No information available
Substances CASNumber
Mutagenic Effects
Tartaric acid 87-69-4 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
Substances CASNumber
Carcinogenic Effects
Tartaric acid 87-69-4 Did not show carcinogenic effects in animal experiments (Rat) (similar substances)
Substances CASNumber
Reproductive toxicity
Tartaric acid 87-69-4 Did not show teratogenic effects in animal experiments.
Substances CASNumber
STOT - single exposure
Tartaric acid 87-69-4 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
STOT - repeated exposure
Tartaric acid 87-69-4 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CASNumber
Aspiration hazard
Tartaric acid 87-69-4 Not applicable
12. Ecological Information
12.1. Toxicity Ecotoxicity effectsHarmful to aquatic life.
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Tartaric acid 87-69-4 E(B)C50 2575.2 mg/L(Skeletonema costatum)
E(R)C50 1198 mg/L(Skeletonema costatum)
EC50 791.25 mg/L(Skeletonema costatum)
EC50 (72h) 51.4043mg/L
(Pseudokirchnerellasubcapitata)
LC50 250 mg/L(Scophthalmus
maximus)LC50 (96h) > 100 mg/L
(Danio rerio)
EC50 (3h) > 1000 mg/L(Activated sludge)
TLM96 330-1000 ppm(Crangon crangon)
EC50 46.04 - 165.37mg/L (Ceriodaphnia
dubia)LC50 3753.85 (Acartia
tonsa)EC50 (48h) 93.313 mg/L
(Daphnia magna)
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_____________________________________________________________________________________________HR-25L Revision Date: 28-Nov-2018
12.2. Persistence and degradability Readily biodegradableSubstances CAS Number Persistence and Degradability
Tartaric acid 87-69-4 Readily biodegradable (85% @ 28d)
12.3. Bioaccumulative potential Does not bioaccumulate.
Substances CAS Number Bioaccumulation
Tartaric acid 87-69-4 -1
12.4. Mobility in soil
Substances CAS Number Mobility
Tartaric acid 87-69-4 No information available
Ecotoxicity Hazard Statements Harmful to terrestrial vertebrates.
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Incineration recommended in approved incinerator according to federal, state, and localregulations. Substance should NOT be deposited into a sewage facility.
Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treatingpackaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial wastecollection.
14. Transport Information
NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number HSR002503
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_____________________________________________________________________________________________HR-25L Revision Date: 28-Nov-2018
Group Name Additives, Process Chemicals and Raw Materials (Subsidiary hazard HSR002503)
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organizationmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 28-Nov-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________
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SAFETY DATA SHEET
HR-601
Revision Date: 01-Jun-2018 Revision Number: 26
1. Identification
Product Name Product Trade Name: HR-601
Other Names Synonyms None
Hazardous Material Number: HM005093
Recommended Use Recommended Use Cement Retarder
Uses advised against No information available
Company Name, Address and Contact Details Manufacturer/Supplier Halliburton New Zealand
1 Paraite Rd,Bell Block, New PlymouthNew Zealand Registration No.: 824207
E-mail Address fdunexchem@halliburton.com
Emergency Telephone Number +64 800 451719Global Incident Response Access Code: 334305Contract Number: 14012
New Zealand National PoisonsCentre
0800 764 766 (24 hours)
2. Hazards Identification
Statement of Hazardous Nature Not Classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulation2001; Not Classified as dangerous good according to NZS 5433:2012, UN, IMDG or IATA
Classification Non-hazardous
Hazard and Precautionary Statements
Hazard Pictograms
Signal Word None
Hazard Statements Not Hazardous
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
Contains
Substances CAS Number Substance HSNO Classification
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Non-hazardous
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_____________________________________________________________________________________________HR-601 Revision Date: 01-Jun-2018
2.3. Other Hazards This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
3. Composition/Information on Ingredients
Substances CAS Number PERCENT (w/w)Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA 60 - 100%
4. First Aid Measures
Requirements for First Aid or Medical Care Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.
Skin Wash with soap and water. Get medical attention if irritation persists.
Ingestion Under normal conditions, first aid procedures are not required.
Workplace Facilities Required None
Relation to Health Effect Most Important Symptoms/EffectsNo significant hazards expected.
Medical Attention and Special Treatment Notes to PhysicianTreat symptomatically
5. Fire-fighting measures
Type of Hazard Flammability HazardOrganic dust in the presence of an ignition source can be explosive in high concentrations. Good housekeeping practices arerequired to minimize this potential.
5.1. Extinguishing media Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasonsNone known.
HAZCHEM Code Hazchem Code: None Allocated
Special Protective Equipment and Precautions for Fire Fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.See Section 8 for additional information
_____________________________________________________________________________________________
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6.2. Environmental precautions
_____________________________________________________________________________________________HR-601 Revision Date: 01-Jun-2018
Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
6.4. Reference to other sections See Section 8 and 13 for additional information.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.
Handling Practices Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Approved Handlers This product does NOT require an approved handler.
7.2. Conditions for safe storage, including any incompatibilities Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 24 months.
Store Site Requirements No special controls required
Packaging No special packaging required
8. Exposure Controls/Personal Protection
Workplace Exposure Standards Exposure Limits
Substances CAS Number New Zealand WES ACGIH TLV-TWAContains no hazardoussubstances in concentrationsabove cut-off values accordingto the competent authority
NA Not applicable Not applicable
Engineering Controls Engineering Controls Use in a well ventilated area.
Personal Protective Equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Not normally needed. But if significant exposures are possible then the followingrespirator is recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.
Skin Protection Normal work coveralls.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values
Physical State: Solid Color Brown
Odor: Woody Odor Threshold: No information available
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_____________________________________________________________________________________________HR-601 Revision Date: 01-Jun-2018
Remarks/ - Method
pH: 7.8
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point No data available
Upper flammability limit 3.5 oz/ft3
Lower flammability limit 0.2 oz/ft3
Evaporation rate No data available
Vapor Pressure No data available
Vapor Density No data available
Specific Gravity 1.089
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
Bulk Density 30.5 lbs/ft3 @ 20 C
10. Stability and Reactivity
10.2. Chemical stability Stable
10.4. Conditions to avoid None anticipated
10.5. Incompatible materials Strong oxidizers.
10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide.
Hazardous Reactions Hazardous Polymerization: Will Not Occur
11. Toxicological Information
Health Effect from Likely Routes of Exposure Acute Toxicity
Inhalation May cause mild respiratory irritation.
Eye Contact May cause mechanical irritation to eye.
Skin Contact None known.
Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% arechronic health hazards.
Toxicity Data
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competent
NA No data available No data available No data available
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authority
12. Ecological Information
12.1. Toxicity
Product Ecotoxicity DataNo data available
Substance Ecotoxicity Data
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms
Toxicity toInvertebrates
Contains nohazardoussubstances inconcentrations abovecut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and Degradability
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values accordingto the competent authority
NA No data available
12.4. Mobility in soil
Substances CAS Number Mobility
Contains no hazardous substances in concentrationsabove cut-off values according to the competentauthority
NA No information available
Ecotoxicity Hazard Statements None known
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
13.1. Waste treatment methods Disposal methods This product is not regarded as hazardous waste. Dispose in accordance with local
regulations. Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
14. Transport Information
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NZ 5433.1999 UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IMDG/IMO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
IATA/ICAO UN Number Not restricted
UN proper shipping name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None
15. Regulatory Information
New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
HSNO Approval Number Non-Hazardous
Group Name Not Applicable
HSNO Controls Refer to the NZ EPA website for more information: http://www.epa.govt.nz
Approved Handlers Not Applicable
Poisons Schedule: None Allocated
16. Other information
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
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Key or legend to abbreviations and acronyms used in the safety data sheetbw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%MARPOL – International Convention for the Prevention of Pollution from Shipsmg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure Limitppm – parts per millionTWA – Time-Weighted AverageVOC – Volatile Organic CarbonC - CelsiusIATA/ICAO - International Air Transport Association / International Civil Aviation OrganizationIMDG/IMO - International Maritime Dangerous Goods / International Maritime Organization
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mg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Revision Date: 01-Jun-2018
Revision NoteSDS sections updated:2
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information isobtained from various sources including the manufacturer and other third party sources. The information may not be validunder all conditions nor if this material is used in combination with other materials or in any process. Final determination ofsuitability of any material is the sole responsibility of the user.
End of Safety Data Sheet
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