Membrane technology for sustainable wastewater...

Post on 10-Jul-2020

1 views 0 download

Transcript of Membrane technology for sustainable wastewater...

13-06-2018

A journey in the future

Membrane technologyfor sustainable wastewater treatment

Content

BLUE-tec

Development of municipal wastewater treatment

The road paht towards a sustainalbe wastewater treatment plant

Ammonia membrane stripping

CoRe Water – the next step

BLUE-tec

• Company Started in October 2014 Founder & CEO: Lex van Dijk International team of 8 persons

• Technologies Pressure driven membrane processes Forward Osmosis Ammonia Membrane Stripping

• What we do: Produce membrane modules Realization of membrane systems Realization of plants Pilot testing & studies

4

Lab-scale & bench scale testing

Flexible pilot plants using industrial modules

Assembly of complete systems

Facilities

Renkum [NL]

WWTP: 150 Years of evolution

VISION

Break with the lineair development in the design of WWTP’s

Transition towards a new generation WWTP’s

First sewersystem in London

Inventionactivated sludge

First referenceoxidation ditch

Laws on wastewaterdischarge

RemovalN&P

Removal micro pollutants

Energy andrecourcerecovery

Main trends in wastewater treament

DEVELOPMENTS Excellent effluent quality including removal of micropollutants Reduction of greenhouse gas emissions (N2O) Recovery of valuable materials Modular and flexible

Wastewater is full with raw materials

The road path towards a sustainable WWTP

Now

Time

Optimizing exisiting WWTP’s 90% of compounds are oxidized Recovery of valuables from sludge Recovery of ammonium from

digested sludge supernatant

Directe separation of domesticwastewater Very clean water for (re)use Concentrate for recovery of

valuables

Decentral sanitation Effective Long road to

implementation

AMS™ CoRe Water - FO VUNA

2020 future

Ammonia recycling at WWTP

8

Agriculture

Humans/Consumers

WWTP

food

wastewater

Fertilizer

Haber BoschN2

NH4

N2O

9

Ammonia Membrane Stripping (AMS™)

Ammonia removal & recovery

Selective membrane for ammonia removal

Applicable NH4 > 500 mg/l

Removal 70 -85%

Product 35 w% Ammonium Sulphate

Quote Christoph EgliGeneral manager wastewater treatment plant Altenrhein (CH):“By introducing the novel Ammonia Membrane Stripping technology in our wastewater treatment plant we can significantly reduce on greenhouse gas emissions.”

10

Ammonia Membrane Stripping

Characteristics

Production of fertilizer

Minimum greenhouse gas emissions

Very small foot print

Modular & flexible

Robust process

Pilot development

11

BLUE-tec AMS™-pilot unit

Capacity: 24 – 48 m3/d

Pre-sieve CO2 stripper Caustic dosing and Membrane Fertilizer production sedimentation stripper

Membrane and module improvement

13

Better membrane coefficient

Less particle pre-treatment

Higher temperatures

Improvement in capacity

High product concentration

Lower chemical consumption

Module development

14

Testing

15

Membrane/Module comparison

16

Cappilary Spiral wound Hollow fibre Spiral wound

Commercial production

+++ +Single, handmade

+Single, handmade

+++Semi automated

standardization +++ + + +++

Membraneperformance

+ ++++ ++ +++++

Particle un- sensivity - ++++ +++ +++

experience +++ ++ + ++

Max. temperature 60 60 80 (atm 60) 45 - 60

Max. product concentration

++ ++++ ++ ++++

AMS™ vs Biological N removal

Ammonia membrane stripping vs Biological N-removal

High investment GHG emission: 4,0 kg CO2 per kg N Conversion into N2

Big installations Sensitive (pH/T/start up)

Low investment GHG emission: 1,1 kg CO2per kg N Production fertilizer Modular and scalable Robust

Projects and applications of AMS™

Ammonia Membrane Stripping Supernatant from sewage sludge dewatering

Manure/digestate

Landfill leachate

Industrial wastewater

Sour water in oil & gas industry

Successful pilots and economic attractive projects

The road path towards a sustainable WWTP

Now

Time

Optimizing exisiting WWTP’s 90% of compounds are oxidized Recovery of valuables from sludge Recovery of ammonium from

digested sludge supernatant

Directe separation of domesticwastewater Very clean water for (re)use Concentrate for recovery of

valuables

Decentral sanitation Effective Long road to

implementation

AMS™ CoRe Water - FO VUNA

2020 future

DIRECT SEPARATION OF RAW WASTEWATER

o Very clean effluent

o Concentrate

INNOVATIVE TECHNOLOGY

o Pressureless process

o Little membrane fouling

o High concentration factors

o Excellent permeate quality

o Modulair

Forward Osmose as key technology

Pilot test on WWTP Simpelveld [NL]

Biogas

Liquid fertilizer

md

Raw wastewater

Clean water

Succesful pilot in 2017

PRELIMINARY RESULTS

o Pilot plant 200 l/u

o Concentration factor > 20

o Little fouling and cleaning

o Clean water for discharge

o Concentrate for biogas and nutrients recovery

Preliminary results

STRATEGY

o Development of a sustainable water factory

o The core of the concept is ‘Concentrate’, ‘Recover’ en ‘Reuse (CoRe)’

PLAN

o Direct concentration of raw wastewater

o Co-creation with several innovation partners

o Phase 1 (2018 – 2020): scale up pilot (2 m3/h)

water (re)use

concentrate treatment

o Phase 2 (2020 – 2022): demonstration plant 20 – 50 m3/h

CoRe Water will make the transition possible

Programm CoRe Water

CoRe Water Limburg

CoRe Water Water in Cities

CoRe WaterResource Recovery

o 1999 : Direct RO at WUR

o 2005 -2014 : Sewer mining project at KWR

o 2016 - 2017 : Eurostars FO-pilot test at WWTP Simpelveld

o End 2017 : Iniative CoRe Water

o March 2018 : MOU on Core Water

o 2018 - 2021 : CoRe Water phase 1

o 2021 : Evaluation and validation value case

o 2021 - 2023 : CoRe Water Limburg phase 2

Development CoRe Water

TRL 4 - 5:Small pilot (0,2 m³/h)Technology development

TRL 5 - 6:Big pilot/prototype (2 m³/h)System development

TRL 7 - 8:Demo system (20-50 m³/h)1e ‘full scale’ application

TRL 2- 3:Lab scale testsProof of concept

The road path towards a sustainable WWTP

Now

Time

Optimizing exisiting WWTP’s 90% of compounds are oxidized Recovery of valuables from sludge Recovery of ammonium from

digested sludge supernatant

Directe separation of domesticwastewater Very clean water for (re)use Concentrate for recovery of

valuables

Decentral sanitation Effective Long road to

implementation

AMS™ CoRe Water - FO VUNA

2020 future

Thank you for your attention!