Post on 20-Oct-2021
according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumhexacyanoferrat(III) Lösungen
Revision date: 13.02.2020 Product code: 11146_collect Page 1 of 7
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Kaliumhexacyanoferrat(III) Lösungen
1.1. Product identifier
This MSDS covers the following products in all container sizes:
- REF: 11146.xxxxx – Kaliumhexacyanoferrat(III) 5% (Blutlaugensalz rot)
- REF: 15979.xxxxx – Kaliumhexacyanoferrat(III) 1% (Blutlaugensalz rot)
- REF: 16774.xxxxx – Kaliumhexacyanoferrat(III) 10% (Blutlaugensalz rot)
Further trade names
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Use as laboratory reagent.
Any non-intended use.
Uses advised against
1.3. Details of the supplier of the safety data sheet
MORPHISTO GmbHCompany name:
Street: Weismüllerstr. 45
Place: D-60314 Frankfurt am Main
Telephone: Telefax:+49 (0) 69 / 400 3019-60 +49 (0) 69 / 400 3019-64
info@morphisto.dee-mail:
http://www.morphisto.deInternet:
Poison Information Center Mainz, Germany, Tel: +49(0)6131/192401.4. Emergency telephone
number:
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) No. 1272/2008
This mixture is not classified as hazardous in accordance with Regulation (EC) No. 1272/2008.
2.2. Label elements
Hazard components for labelling@1501.B150213
No risks worthy of mention. Please observe the information on the safety data sheet at all times.
2.3. Other hazards
SECTION 3: Composition/information on ingredients
3.2. Mixtures
aqueous solutionChemical characterization
Further Information
Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article
59 (REACH)
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet
if possible).
General information
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumhexacyanoferrat(III) Lösungen
Revision date: 13.02.2020 Product code: 11146_collect Page 2 of 7
@1501.B015819 In case of allergic symptoms, especially in the breathing area, seek medical advice
immediately.
After inhalation
@0403.B004101 In case of skin irritation, seek medical treatment.
After contact with skin
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently consult an ophthalmologist.
After contact with eyes
Let water be drunken in little sips (dilution effect). In all cases of doubt, or when symptoms persist, seek medical
advice.
After ingestion
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Carbon dioxide (CO2). Dry extinguishing powder. alcohol resistant foam. Atomized water.
Suitable extinguishing media
High power water jet.
Unsuitable extinguishing media
5.2. Special hazards arising from the substance or mixture
Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Nitrogen oxides (NOx). Hydrocyanic
acid (hydrocyanic acid).
In case of fire: Wear self-contained breathing apparatus.
5.3. Advice for firefighters
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Additional information
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. (refer to chapter 8)
Do not allow to enter into surface water or drains.6.2. Environmental precautions
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal .
Clean contaminated objects and areas thoroughly observing environmental regulations.
6.3. Methods and material for containment and cleaning up
See protective measures under point 7 and 8.
6.4. Reference to other sections
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Wear personal protection equipment. (refer to chapter 8)
Advice on safe handling
Print date: 17.02.2020GB - ENRevision No: 1,0
according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumhexacyanoferrat(III) Lösungen
Revision date: 13.02.2020 Product code: 11146_collect Page 3 of 7
The product is not: Combustible.
No special fire protection measures are necessary.
Advice on protection against fire and explosion
Avoid contact with skin, eyes and clothes.
General protection and hygiene measures: refer to chapter 8
Further information on handling
7.2. Conditions for safe storage, including any incompatibilities
@1501.B015764
Protect against direct sunlight. Keep away from heat.
Requirements for storage rooms and vessels
Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Radioactive substances. Infectious
substances.
Hints on joint storage
Protect against: UV-radiation/sunlight. heat.
Further information on storage conditions
7.3. Specific end use(s)
@0102.B010347
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
To date, no national critical limit values exist.
Additional advice on limit values
8.2. Exposure controls
Use extractor hood (laboratory).
Appropriate engineering controls
Always close containers tightly after the removal of product. Do not eat, drink, smoke or sneeze at the
workplace. Wash hands before breaks and after work. Handle in accordance with good industrial hygiene and
safety practice.
Protective and hygiene measures
Tightly sealed safety glasses. DIN EN 166
Eye/face protection
In case of prolonged or frequently repeated skin contact:
Pull-over gloves of rubber. EN ISO 374
Suitable material:
NBR (Nitrile rubber). (0,11 mm, Breakthrough time >= 480 min):
Before using check leak tightness / impermeability. In the case of wanting to use the gloves again, clean them
before taking off and air them well.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves.
Hand protection
Protective clothing.
Minimum standard for preventive measures while handling with working materials are specified in the TRGS 500
Skin protection
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumhexacyanoferrat(III) Lösungen
Revision date: 13.02.2020 Product code: 11146_collect Page 4 of 7
(D).
With correct and proper use, and under normal conditions, breathing protection is not required.
Respiratory protection
No special measures are necessary.
Environmental exposure controls
yellow
liquidPhysical state:
Colour:
9.1. Information on basic physical and chemical properties
SECTION 9: Physical and chemical properties
not determinedOdour:
pH-Value: ~7
Changes in the physical state
~100 °CInitial boiling point and boiling range:
>60 °CFlash point:
none
Explosive properties
not determinedIgnition temperature:
none
Oxidizing properties
Vapour pressure: not determined
Density: not determined
Water solubility: highly soluble.
0% - @1501.B150227Solvent content:
9.2. Other information
No information available.
SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal storage and handling conditions.
10.2. Chemical stability
Stable under normal storage and handling conditions.
Hazardous decomposition products: Hydrocyanic acid (hydrocyanic acid).
10.3. Possibility of hazardous reactions
May release HCN at contact with strong acids when heated.
No information available.
10.4. Conditions to avoid
Oxidizing agents, strong. Reducing agents, strong. Nitrites. Strong acid. Ammonia. Halogen hydride.
10.5. Incompatible materials
Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Nitrogen oxides (NOx). Hydrocyanic
acid (hydrocyanic acid).
10.6. Hazardous decomposition products
SECTION 11: Toxicological information
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according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumhexacyanoferrat(III) Lösungen
Revision date: 13.02.2020 Product code: 11146_collect Page 5 of 7
11.1. Information on toxicological effects
Toxicocinetics, metabolism and distribution
No information available.
Acute toxicity
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Irritation and corrosivity
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Aspiration hazard
Based on available data, the classification criteria are not met.
No information available.
Specific effects in experiment on an animal
SECTION 12: Ecological information
12.1. Toxicity
@1718.B017281
12.2. Persistence and degradability
The methods for determining the biological degradability are not applicable to inorganic substances.
12.3. Bioaccumulative potential
No indication of bioaccumulation potential.
@1718.B017281
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
@1718.B017281
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal recommendations
Dispose of waste according to applicable legislation. Consult the local waste disposal expert about waste
disposal. Non-contaminated packages may be recycled.
List of Wastes Code - residues/unused products
160509 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16 05 08
List of Wastes Code - used product
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16 05 08
160509
List of Wastes Code - contaminated packaging
Print date: 17.02.2020GB - ENRevision No: 1,0
according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumhexacyanoferrat(III) Lösungen
Revision date: 13.02.2020 Product code: 11146_collect Page 6 of 7
WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; absorbents, filter materials, wiping cloths and protective
clothing; absorbents, filter materials, wiping cloths and protective clothing other than those mentioned
in 15 02 02
150203
Handle contaminated packages in the same way as the substance itself.
Contaminated packaging
SECTION 14: Transport information
Land transport (ADR/RID)
Not restricted
Other applicable information (land transport)
Inland waterways transport (ADN)
Not restricted
Other applicable information (inland waterways transport)
Marine transport (IMDG)
Not restricted
Other applicable information (marine transport)
Air transport (ICAO-TI/IATA-DGR)
Not restricted
Other applicable information (air transport)
14.5. Environmental hazards
noENVIRONMENTALLY HAZARDOUS:
14.6. Special precautions for user
No information available.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
No information available.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
0%, VOC Directive 2004/42/EC: 0 g/l2004/42/EC (VOC):
Additional information
The preparation is not dangerous in the sense of Directive 1999/45/EC.
This mixture is classified as not hazardous according to Regulation (EC) 1272/2008 [CLP].
National regulatory information
2 - clearly water contaminatingWater contaminating class (D):
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information
Changes
Rev. 1,00; 13.01.2015; Initial release
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route ( European Agreement
concerning the
Print date: 17.02.2020GB - ENRevision No: 1,0
according to Regulation (EC) No 1907/2006
Safety Data SheetMORPHISTO GmbH
Kaliumhexacyanoferrat(III) Lösungen
Revision date: 13.02.2020 Product code: 11146_collect Page 7 of 7
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations
Concerning the International Transport of Dangerous Goods by Rail )
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
OSHA: Occupational Safety and Health Administration
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
NOAEL: No observed adverse effect level
LOAEL: Lowest observed adverse effect level
NOAEC: No observed adverse effect level
LOAEC: Lowest observed adverse effect concentration
DNEL: Derived No Effect Level
PNEC: predicted no effect concentration
TSCA: Toxic Substances Control Act
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
NTP: National Toxicology Program
SARA: Superfund Amendments and Reauthorization Act
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
PBT: Persistent bioaccumulative toxic
SVHC: substance of very high concern
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of processing,
the information on this safety data sheet is not necessarily valid for the new made-up material.
Further Information
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)
Print date: 17.02.2020GB - ENRevision No: 1,0