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Hookston Station Final Report
Pleasant Hill, California
GEOSIERRA ENVIRONMENTAL, INC. 1 Final Construction Report - Sept 2009
TABLE OF CONTENTS
EXECUTIVE SUMMARY .............................................................................................. 3
1.0 INTRODUCTION ................................................................................................ 4 2.0 SITE DESCRIPTION........................................................................................... 6
2.1 Site Location and Access ..................................................................................... 6 2.2 Subsurface Site Characterization ......................................................................... 6
3.0 REVIEW OF SELECTED REMEDY ................................................................ 7 3.1 Iron Permeable Reactive Barriers ............................................................................. 7
3.1.1 Background .................................................................................................... 7
3.1.2 Zero Valent Iron ............................................................................................. 7 3.1.3 Emplacement Methods................................................................................... 8
3.2 PRB Design Requirements and Criteria ................................................................... 8
4.0 PRB INSTALLATION METHOD...................................................................... 9 4.1 Full-Scale ZVI PRB Geometry ................................................................................ 9
4.2 PRB Emplacement Methods .................................................................................... 9 4.3 Selected Emplacement Method ................................................................................ 9
4.3.1. Azimuth-Controlled Vertical Hydrofracturing ............................................. 9
4.3.2. Hydraulic Fracture Cross-Linked Gel ......................................................... 10 4.4 Summary of the HydroFrac Installation Methods .................................................. 10
4.4.1 Overview of the Installation Method ........................................................... 10
5.0 IRON REACTIVE PRB SYSTEM CONSTRUCTION ........................................ 13 5.1 Iron PRB System .................................................................................................... 13 5.2 Construction Sequence ........................................................................................... 13
5.2.1 Site Preparation ............................................................................................ 13 5.2.2 Resistivity String and Frac Casing Installation ........................................... 14 5.2.3 PRB Installation with Active Resistivity Monitoring ................................. 14
5.3 Construction Quality Assurance Monitoring ................................................. 17 5.3.1 Active Resistivity Monitoring ................................................................. 17
5.3.2 Post-Installation Inclined Profile Borings ............................................... 18 5.3.3. Post-PRB Installation Hydraulic Interference Pulse Testing .................. 21
5.4 Construction Quantities .................................................................................. 23
SUMMARY ..................................................................................................................... 24 REFERENCES ................................................................................................................ 25
TABLES
1. Fracture Gel Composition Summary
2. Fracture Well Installation Details
3. Resistivity String Installation Details
4. Deep PRB Iron Injection Summary
5. Shallow PRB Iron Injection Summary
6. Summary of Cross-Linked Gel QA/QC
7. Summary of Hydraulic Pulse Interference Results
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Pleasant Hill, California
GEOSIERRA ENVIRONMENTAL, INC. 2 Final Construction Report - Sept 2009
FIGURES
1. Hookston Station Site Location Map
2. Permeable Reactive Barrier Location Plan
3. Hydrofracture Well Casing Resistivity String and QA/QC Boring Installation
Details
4. Typical Monitoring System Layout
APPENDICES
A. Resistivity Receiver CPT Report
B. Selected Active Resistivity Images
C. Typical Injection Well Pressure Outputs
D. Post-Installation Inclined Profile Magnetometer Outputs
E. Hydraulic Pulse Interference Data Sheets
F. Photo Journal
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Pleasant Hill, California
GEOSIERRA ENVIRONMENTAL, INC. 3 Final Construction Report - Sept 2009
EXECUTIVE SUMMARY This document outlines the construction activities and quality assurance/quality control
measures as part of the installation of an iron permeable reactive barrier (PRB) recently
installed at an off-site location near the Hookston Station Site (site) in Pleasant Hill,
California. The iron PRB was installed in the subsurface in a northwest-to-southeast
orientation across Len Hester Park, proceeding parallel to and then across Hookston
Road. The objective of the PRB is to degrade chlorinated volatile organic compounds in
site ground water to non-toxic end products and thus limit downgradient migration of
such chemicals in ground water.
The PRB was constructed using azimuth-controlled vertical hydrofracturing technology.
It is approximately 480 feet in total length, oriented mostly perpendicular to ground water
flow, with 180 linear feet of 3-inch average effective-iron-thickness and 300 linear feet of
4.5-inch average effective-iron-thickness, extending from 51 feet above mean sea level
(MSL) (approximately 11 to 15 feet below ground surface (bgs) adjusting for topographic
changes along the proposed alignment) to 19 feet MSL (approximately 44 to 48 feet bgs).
This Final Installation Report has been prepared to detail the construction activities
associated with the PRB, describe the quality assurance/quality control measures that
were implemented to assure that the PRB was constructed according to the 100% Design
Specifications developed in November 2008, and to document minor deviations from the
aforementioned specifications.
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Pleasant Hill, California
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1.0 INTRODUCTION
GeoSierra Environmental, Inc. (GeoSierra) was retained by ERM-West, Inc. (ERM) to
design and install an in situ zero-valent iron permeable reactive barrier (PRB) at the
Hookston Station Site (site) in Pleasant Hill, California.
The subsurface PRB consists of one continuous reactive zone of zero valent iron (ZVI)
approximately 480 feet in length. The PRB was installed from approximately 51 feet
above mean sea level (MSL) down to approximately 19 feet MSL to intersect ground
water flow through silts and higher-permeability sand lenses within the A-Zone aquifer.
The PRB was installed in a northwest-to-southeast orientation across the southern portion
of Len Hester Park, and extends parallel to and then across Hookston Road. A series of
boreholes were drilled along the PRB alignment and two fracture casings (frac casings)
were installed in each borehole to facilitate construction of individual 15- to 16-foot high
panels. The PRB was constructed by injecting iron filings into the subsurface to create a
continuous zone of iron filings approximately 32 feet in vertical height.
With construction of the PRB completed, ground water will flow through the iron filings
unimpeded and the chlorinated solvent impacts present in ground water will be destroyed
by the iron particles to non-toxic end products with a goal of clean ground water
emerging downgradient from the PRB. The iron PRB is a passive treatment system and
does not require any operation or maintenance.
The objective of the final ground water remedy for the site was to develop and install a
PRB treatment system that will reduce the levels of chlorinated volatile organic
compounds (CVOCs) encountered in the ground water to below cleanup goals
established by the California Regional Water Quality Control Board, San Francisco Bay
Region (RWQCB), in Order No. R2-2007-0009. The technology chosen to remediate the
site ground water was zero valent iron (ZVI), patent numbers 5,266,213 and 6,287,472B1
by EnviroMetal Technologies Inc.
For ease of review, this report is divided into the following sections:
Section 1 provides an introduction to the report, objectives, and background
information.
Section 2 provides a brief description of the site.
Section 3 summarizes the selected remedy, including an overview of the iron PRB
system technology, reactivity of ZVI, iron emplacement methods, and the design
requirements and criteria for the system;
Section 4 presents the PRB installation methods including the azimuth-controlled
vertical hydrofracturing technology, gel, installation methods, and previous
design issues.
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Pleasant Hill, California
GEOSIERRA ENVIRONMENTAL, INC. 5 Final Construction Report - Sept 2009
Section 5 describes results of verification testing conducted during and following
installation of the PRB; and
Section 6 presents a summary of the final PRB system installation.
These sections are supported by tables, figures and appendices, which summarize field
collected quality assurance/quality control (QA/QC) results, resistivity imaging outputs,
and the final post-PRB hydraulic pulse interference testing results.
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2.0 SITE DESCRIPTION 2.1 Site Location and Access The Hookston Station Site is in Pleasant Hill, California, as shown on Figure 1. A site plan is included as Figure 2 with the PRB orientation and location. The PRB was installed as one continuous reactive zone of ZVI extending approximately 480 feet on a northwest-to-southeast alignment with access to the site from both Hookston Road and Hampton Drive. As shown on Figure 2, approximately 250 linear feet (lf) of the PRB was installed within Len Hester Park, while approximately 230 lf is beneath Hookston Road. 2.2 Subsurface Site Characterization The area of interest for the installation of a PRB treatment system is within the A-Zone aquifer extending from approximately 51 feet MSL down to approximately 19 feet MSL. The primary constituents in the ground water are CVOCs, specifically trichloroethene (TCE), cis-1,2-dichloroethene (cis-1,2-DCE), vinyl chloride (VC), and 1,1-dichloroethene (1,1-DCE). The site is underlain by approximately 80 feet of unconsolidated materials forming the A-Zone and B-Zone. In the vicinity of the PRB, the A-Zone extends from grade to 19 feet MSL and consists of clay, silty clay, clayey silt, and silt. The B-Zone generally extends from 19 feet MSL to -18 feet MSL and consists of silty sand, sand, sandy gravel, or gravelly sand. The PRB was installed in the A-Zone, which initially had a hydraulic conductivity ranging from 0.62 feet per day (ft/day) or 2.17x10-4 centimeters per second to as high as 65 ft/day or 2.3x10-2 centimeters per second, based on pre-PRB installation slug and pulse testing activities conducted by GeoSierra. The hydraulic gradient of the A-Zone is estimated to range from 0.001 to 0.004 feet per foot. The ground water flow direction of the A-Zone is to the northeast. Based on historical sampling of ground water monitoring wells both upgradient and within the location of the PRB, concentrations of TCE in A-Zone ground water range from non-detect (ND) (generally less than 0.5 micrograms per liter [g/L] to 9,500 g/L); cis-1,2-DCE ranges from ND to 5,800 g/L; 1,1-DCE ranges from ND to 1,100 g/L; and VC ranges from ND to 1,400 g/L.
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3.0 REVIEW OF SELECTED REMEDY
This section summarizes the selected A-Zone ground water remedy, a process description
of the ZVI technology, and the previously approved design requirements and criteria for
the system.
3.1 Iron Permeable Reactive Barriers
3.1.1 Background
In situ passive iron PRBs have been placed at a number of sites, dating back to the first
constructed at CFB Borden in 1991, by the University of Waterloo. The early iron
reactive barriers were designed on the funnel and gate concept (Starr and Cherry, 1994).
Recently, continuous permeable barriers have been installed by back hoe, continuous
trenchers, and azimuth-controlled vertical hydrofracturing. The continuous permeable
barriers do not modify the natural ground water flow, whereas funnel and gate systems do
impact the flow.
Iron PRBs have significant advantages over conventional technologies for remediation of
chlorinated-solvent-impacted ground water; the prime advantage is that the system is
passive. It is a simple process that has been proven in both the laboratory and the field.
Site characterization and laboratory bench-scale studies are sufficient to design and
construct an iron reactive barrier. The first iron PRB was constructed in 1991 as a field
trial, followed by two more in early 1995. During the past 15 years, a significant number
of full-scale systems have been installed. The rapid increase in the number of reactive
barriers installed reflects the increasing maturity and acceptance of ZVI as a proven and
effective remedial technology.
3.1.2 Zero Valent Iron
Zero valent metals have been known to abiotically degrade certain compounds, such as
pesticides as described by Sweeny and Fisher (1972), and halogenated compounds such
as tetrachloroethene (PCE), TCE, VC, and isomers of DCE as detailed in Gillham and
O’Hannesin (1994). In the case of ZVI, a first-order reduction process can approximate
the abiotic degradation of halogenated aliphatics. The compounds are progressively
degraded and eventually broken down into ethenes and ethanes, as described by Orth and
Gillham (1996). In the presence of ZVI, the chlorinated compound TCE is
predominantly degraded through the dichloroacetylene pathway with only a minor
generation of daughter product cis-1,2-DCE. Therefore, the reductive process in the
presence of ZVI generates significantly fewer daughter products than those generated due
to natural degradation. In column experiments conducted during design activities, the
molar fraction of TCE degraded into chlorinated daughter products such as cis-1,2-DCE
and VC was 4% and 10%, respectively for the Hookston site, similar to the published
mole fractions of 5 to 10% in scientific literature (Gillham and O’Hannesin, 1994). Five-
and 10-year performance data of the Borden ZVI barrier indicated no decline in
degradation performance over time (Gillham and O’Hannesin, 1998; Reynolds et al.,
2002). Current expectations are that ZVI PRBs will function for at least 30 years with
the possibility of a greater lifetime depending on site conditions.
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3.1.3 Emplacement Methods
The placement of iron filings in the subsurface for passive in situ treatment of impacted
ground water was first discussed by Gillham (1993). Iron filings have traditionally been
placed by conventional technologies such as shoring and excavation, and trenching, and
more recently by azimuth-controlled vertical hydrofracturing.
3.2 PRB Design Requirements and Criteria
The ZVI PRB was designed to reduce the levels of CVOCs in ground water to below
cleanup goals specified in RWQCB Order R2-2007-0009. The design methodology
considered all site-specific data, defined functional design requirements and design
criteria for the system, and determined the most appropriate system design by use of a
probabilistic forecast model of barrier performance. The Hookston Station ZVI PRB was
designed to meet the following functional design requirements and criteria:
Included consideration of geotechnical, hydrogeologic, and ground water
chemistry data collected during previous investigations of the site;
Considered the use of commercially available ZVI filings and the selected
emplacement technique;
Accommodated the variability of the site data, iron reactivity column test data,
and installed PRB thickness;
Will be designed for target CVOC parent and daughter products to have effluent
concentrations below their associated site cleanup goals; and
Was designed so that applicable QA/QC procedures can be implemented during
construction.
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Pleasant Hill, California
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4.0 PRB INSTALLATION METHOD
4.1 Full-Scale ZVI PRB Geometry
The PRB extends 480 feet in length from approximately 51 to 19 feet MSL, resulting in a
cross-sectional area of approximately 15,360 square feet (ft2). Most of the PRB (the
portions within Len Hester Park and a small portion that crosses Hookston Road) is
oriented approximately perpendicular to the direction of ground water flow. The final
alignment of the PRB was selected based on pre-design investigations that were
performed by the Hookston Station Parties. These investigations included detailed
sampling and analysis of geologic materials and chemical distribution in this vicinity.
Although the portion of the PRB that is oriented east-west along the northern side of
Hookston Road is not directly perpendicular to ground water flow, it is positioned there
to reduce the travel time of treated water migrating beneath residential structures, and
therefore provide the residential neighborhood the most immediate benefit from this
treatment technology.
4.2 PRB Emplacement Methods The placement of iron filings in the subsurface for passive in situ treatment of impacted
ground water was first discussed by Gillham (1993). Iron filings have traditionally been
placed by conventional technologies such as shoring and excavation, trenching, and more
recently by azimuth-controlled vertical hydraulic fracturing. Several other experimental
methods have been investigated, namely (a) jet grouting, (b) driver/vibrated beam, and
(c) deep solid mixing; however, these methods are still considered experimental and have
not been used to install full-scale PRB systems.
A continuous PRB was selected as an optimum system since it would have minimal
impact on the natural ground water flow pattern. Of all the PRB emplacement methods,
azimuth-controlled vertical hydraulic fracturing technology was the only viable method
of constructing an iron PRB at this site, since excavation would not be feasible based on
the proximity to adjacent residences, the extension of the PRB into Hookston Road
requiring substantial utility disconnects and rerouting, the depth constraints that would
result in substantial cost impacts, and the necessity for a low impact installation method
with little waste generation.
4.3 Selected Emplacement Method
4.3.1. Azimuth-Controlled Vertical Hydrofracturing
Azimuth-controlled vertical hydraulic fracturing was utilized to install the PRB at the
Hookston Station Site, since it involves no soil excavation and causes minimal site
disturbance, thus eliminating excavated waste issues, impact on utilities, and neighboring
property owner concerns. Using the hydrofracturing technology, the PRB was
constructed from a series of conventionally drilled boreholes along the PRB alignments,
with a specialized frac casing grouted into the boreholes as shown on Figure 3. The PRB
was constructed by injection of the iron filings into these frac casings with real-time QA
monitoring of the injections to quantify the PRB geometry and iron-loading densities.
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4.3.2. Hydraulic Fracture Cross-Linked Gel
The gel used to suspend and transport the iron filings into the subsurface must be of
sufficiently high quality and purity to have no impact on the iron reactivity and
permeability. Guar gum-based gels are potentially suitable; however, particular care
needs to be taken in designing such gel mixtures. Of special importance is the “clean
breaking” property of the gel in the presence of the iron and at ground water
temperatures. The “breaking” of the gel refers to the breakdown of the gel starches into
sugars. An enzyme is typically used to break these gels; however, at elevated pH, low
temperatures, and in the presence of iron, most enzyme activity is extremely low.
The placement of iron PRBs by azimuth-controlled vertical hydrofracturing requires a
fracturing fluid gel that is both compatible with the iron and the hydraulic fracturing
process. The fracturing fluid must (1) be compatible with the formation and formation
fluids, (2) be capable of controlling viscosity to carry the iron filings, (3) be an efficient
fluid, (4) have minimal residue after breaking, and (5) have a low friction coefficient. A
water-based fracturing cross-linked gel was used, hydroxypropylguar (HPG), a natural
polymer used in the food industry as a thickener. The HPG gel is water soluble in the
uncross-linked state and water insoluble in the cross-linked state. Cross-linked, the gel
can be extremely viscous, ensuring the iron filings remain suspended in the gel at all
times during installation.
The gel was mixed with the iron filings, cross-linked, and pumped into the formation by
the injection equipment through the downhole initiation tooling. The gel is viscous and
carries the iron filings to the extremes of the fracture propagation. Enzyme and other
additives typically break down the HPG after about 1 to 2 hours. Upon breaking of the
gel, the iron mixture in the ground becomes highly permeable with minimal residue. The
composition of the fracturing gel is detailed in Table 1.
4.4 Summary of the HydroFrac Installation Methods
4.4.1 Overview of the Installation Method
The azimuth-controlled vertical hydraulic fracturing placed iron PRB was constructed
from conventionally drilled wells installed along the barrier alignment as shown on
Figure 2. Controlled vertical fractures were initiated at the required azimuth orientation
and depth in each well inside of a specialized frac casing utilizing downhole frac
initiation tools. The iron filings were blended and injected in the form of the highly
viscous, degradable food-grade quality gel, HPG. Multiple casing well heads were
injected with the iron-gel mixture to form a continuous PRB. The gel biodegrades into
water and sugars by the use of a suitable enzyme and leaves an in situ permeable iron
reactive treatment zone. The goal for hydraulic fracturing at the Hookston Station Site
was 3 to 4.5 inches, depending on location.
Azimuth-controlled vertical hydrofracturing technology (Hocking, 1996; Hocking and
Wells, 1997; and Hocking et al., 1998a and b) consists of an injection delivery system
comprising three primary components: (1) the fracture initiation device, (2) the controlled
pumping equipment, and (3) the real-time monitoring and inverse algorithms for
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GEOSIERRA ENVIRONMENTAL, INC. 11 Final Construction Report - Sept 2009
determining fracture geometry. The fracture initiation device is used to control the
fracture orientation and comprises a suite of tools and fracture well casings. The
selection of the initiation device is dependent on the geological formation, depth, and the
fracturing fluid required for the particular application. The hydraulic fracturing injection
system consists of a mixing/blending and pumping system, which is specially designed to
achieve a precise control of fracture fluid pressures and flow rates. The real-time
monitoring system provides feedback response to ensure the fractures are propagating
and constructed as planned.
The iron filings were transported to the site in 3,000-pound (lb), sealed, numbered bags.
Prior to shipment, the iron reactivity and physical properties were analyzed by ERM.
Discussions regarding these parameters are not included within the scope of this
document. Once onsite, the 3,000 lb supersacks of iron filings were pre-loaded into
5,500-lb-capacity hoppers for discharge into the mixing and blending equipment.
The HPG was pre-mixed in a 3,000-gallon mixing tanks utilizing a Venturi blender and
fed along with the iron filings into a 100-gallon mixing/blending tank. The iron and HPG
were mechanically agitated to ensure the iron filings remain suspended and the mixture
was then fed to the hydrofracturing pump and cross-linked in line on the pressure side of
the pump.
The PRB installation was monitored in real time to ensure mixture consistency, and
determine volume and weights of iron injected and the geometrical extent of the barrier,
thus ensuring it was constructed as designed. A general layout of the monitoring system
used during construction of a PRB is shown on Figure 4. During injection, the iron gel
mixture was electrically energized with a low-voltage 100-hertz (Hz) signal. Downhole
resistivity receivers were installed and monitored to record the in-phase induced voltage
by the propagating fracture. By monitoring the fracture fluid-induced voltages and
utilizing an incremental inverse integral model, the fracture fluid geometry was
quantified and displayed during the installation process. As discussed below, resistivity
strings were installed on 24-foot, lateral spacing to provide satisfactory PRB image
resolution.
Post-PRB installation hydraulic pulse interference tests are used to demonstrate the
minimal impact of the PRB on site hydrogeology. Hydraulic pulse interference tests
(Johnson et al., 1966; Kamal, 1983) involve a cyclic injection of fluid into the source well
and, by high precision measurement of the pressure pulse in a neighboring well, detailed
hydraulic characterization between wells can be made. The pulse interference test is
highly sensitive to hydrogeological properties between the wells, and relatively
insensitive to conditions outside the wells. The hydraulic pulse interference test are
relatively short duration tests of approximately 2 minutes maximum and involved the
injection typically of less than 10 gallons of potable water. The test is a truly hydraulic
transient test and can determine site hydrogeological properties, such as transmissivity
and storativity, from generated “type curves.” Post-PRB pulse interference tests were
conducted following installation of the PRB and a comparison of before and after pulse
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interference data is used to confirm the minimal impact the PRB has on the site
hydrogeology and thus the minimal impact on ground water flow patterns. The results of
the post-installation pulse interference testing are discussed in Section 5.
Strict QC procedures were required during construction of the PRB to provide the
necessary assurance that the reactive barrier system’s design performance requirements
were achieved. Construction QC procedures and acceptance criteria concentrated on the
following:
In-line and batch consistency tests of the iron reactive mixture;
Thickness and injected quantities of reactive iron;
Geometry of the iron PRB monitored (active resistivity) during injection;
Angled borings that were drilled into the PRB to verify emplaced thickness; and
Quantification of hydraulic impact of the PRB from hydraulic pulse tests.
Testing of these parameters in addition to other QA/QC measures undertaken during
construction of the PRB are further described below.
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5.0 IRON REACTIVE PRB SYSTEM CONSTRUCTION
5.1 Iron PRB System
The iron PRB system consists of installing a reactive barrier perpendicular to the natural
ground water flow direction. The ZVI barrier was installed using azimuth-controlled
vertical hydrofracturing installation. The ZVI barrier is approximately 480 feet in total
length, consisting of 3- and 4.5-inch-thick segments. The PRB was constructed within
the confined silty-clay unit and range in depth from approximately 11 to 15 feet below
ground surface (bgs) down to a total depth of 43 to 47 feet.
The PRB is approximately 15,360 ft2 and was constructed from 40 hydraulic fracturing
casing locations (denoted as F1 through F40), with each frac casing location containing
an upper and lower casing installed along the PRB alignment as shown on Figure 2, with
installation details provided on Figure 3. The iron PRB is 480 feet in total length and
approximately 3 to 4.5 inches in average iron-effective-thickness with a total of 465 tons
of iron filings injected into the subsurface. In addition to the frac wells, a total of 20
subsurface active resistivity receiver strings (denoted as RR1 through RR20) were
installed offset upgradient from the PRB alignment, as shown on Figure 2, to monitor the
geometry of the PRB during construction.
5.2 Construction Sequence
The construction of the iron PRB for the site required a specific construction sequence as
follows:
1. Completed site preparation;
2. Installed active resistivity strings and hydraulic fracturing casings,
simultaneously;
3. Install permeable reactive barrier while conducting real-time PRB installation
monitoring;
4. Install angled borings to verify emplaced PRB thickness;
5. Conduct pulse tests after PRB installation; and
6. Clean site and demobilize.
5.2.1 Site Preparation
Prior to mobilization of frac equipment to the site, typical site setup activities included a
temporary 6-foot, chain-link fence completely around the site; installation of silt fence;
and site support facilities (fabrication areas, portable toilets, waste handling and storage
areas, etc.). Each area was set up to accommodate different activities that would occur
over the duration of project construction both within the park and along Hookston Road.
Once the areas were prepared and the various support areas were constructed, the frac
casing and resistivity string installation equipment were mobilized to the site.
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5.2.2 Resistivity String and Frac Casing Installation
Following mobilization to the site, frac casing and resistivity string installation activities
commenced within Len Hester Park. As detailed on Tables 2 and 3, the base elevation of
the frac casings was targeted for approximately 21 ft MSL to allow the PRB installation
and monitoring from 51 ft to 19 ft MSL, and the resistivity strings were targeted for a
bottom receiver elevation at 19 ft MSL.
The installation of frac casings 1 to 40 were installed utilizing two separate methods.
Although the design called for installation via mud-rotary techniques at all locations,
overhead utilities present in the area of F37 to F40 necessitated use of a limited access,
hollow-stem-auger rig. Because of this deviation, an alternative method of construction
was implemented wherein the augers were advanced to the final depth of the frac casings
(approximately 49 feet MSL to the base of the stinger), the augers were filled with a
heavy drilling mud and then removed, while topping off the mud as the augers were
withdrawn. Once the augers were withdrawn, the frac casings were set into the boreholes
at the design elevation and the ground was allowed to set. The details regarding
installation of F1 to F40 are included within Table 2.
To install the resistivity strings, a track-mounted Cone Penetrometer Rig (CPT) was
mobilized to the site and utilized to install the resistivity strings. The results of the CPT
logging were evaluated for unknown or concerning lithologic changes along the cross
section that could inhibit construction of the wall to the Design Specifications. During
the installation program, although some sand seams were noted towards the southeastern
half of the PRB along Hookston Road, there were no significant deviations from the
100% Design. The final elevations of receivers are detailed on Table 3 and the
installation CPT report is included as Appendix A.
5.2.3 PRB Installation with Active Resistivity Monitoring
Following installation of the frac casings and resistivity strings, the hydrofracture and
monitoring equipment was mobilized to the site to begin installation activities. Some of
the equipment mobilized included:
(2) 3,000-gallon, stainless-steel mixing tanks;
Glove box pump skid;
350-horsepower hydraulic power unit;
Scale/auger unit;
Blending skid;
Pumping unit;
Frac Trak trailer with electronic monitoring systems;
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4,000 lb capacity concrete hoppers;
10,000 lb Lull and Moffet forktrucks; and
Other miscellaneous support equipment.
PRB Construction F1 – F11 (Segment 1)
Following completion of mobilization and site-setup activities, PRB construction
commenced at frac wells F1 to F11 in the lower panel following installation of the
mechanical packers and riser pipe. As shown on Tables 4 and 5, a total of 118,350 lb of
ZVI was injected to build the lower panel. This is approximately 22,000 lb higher than
the Design Specification required, due to vertical migration of the iron into the shallow
panel. During monitoring, the active resistivity system showed that leakoff was vertically
higher than expected, potentially causing the deep wall to be thinner than designed. As
such, an additional 2,000 lb of iron was injected into each of the lower frac casings to
ensure that the proper thickness was constructed.
Once construction of the lower panel was complete, the packers and internal injection
piping was removed from each well, each of the lower casings was filled with iron to
approximately 2 to 3 feet above of top of the bottom frac casing and construction of the
upper panel commenced. A total of 88,650 lb of iron was injected into the upper panel in
Segment 1. One deviation from the design was noted during the upper panel construction
and was related to the quantity of iron injected into frac well F1. Because of its
proximity to a high-pressure, large-diameter gas main and the propagation of the fracture
into the right-of-way at the surface near the gas main, the total design mass of iron was
not injected into F1. A total of 5,856 lb of iron was injected compared to the 8,640 lb
Design Specification. Because F1 is the first frac well in the PRB and is in the lower
concentrated boundary area of the plume, there should be no effect on the performance of
the PRB in this area due to the reduced mass of iron injected. Some surfacing and
surface fracturing was noted during Segment 1 construction; however, increased viscosity
in the gel (discussed further below) and lower individual injection volumes minimized
surfacing. Primary pathways of surfacing were primarily previously abandoned
investigation points that were not complete filled with bentonite or concrete. Selected
resistivity images are included within Appendix B.
Upon completion of Segment 1, the equipment was relocated to install the PRB in
Segment 2 from F12 to F25. Additionally, inclined profile borings were completed in the
upper and lower panels of Segment 1 concurrent with Segment 2 construction. The
results of the inclined profile borings are discussed further below.
PRB Construction F12 – F25 (Segment 2)
Following completion of Segment 1, GeoSierra commenced installation of the PRB in the
lower panels from frac wells F12 through F25. Similar to Segment 1, the mechanical
packers and riser pipe were installed to isolate the lower panel and allow lower panel
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construction. There were no deviations from the design for the Segment 2 lower panel.
A total of 183,175 lb of iron was injected into the lower panel of Segment 2.
Once the packers were removed and the lower casings were filled with iron, construction
of the upper panel commenced. The only deviation from Segment 2 was related to F20,
where the mechanical packer became wedged inside the riser pipe and could not be
removed. With the packer and riser pipe still in the well, the upper casing could not be
injected. As such, frac wells F19 and F21 were over-injected with iron planned for F20.
Instead of F19 and F21 receiving 13,000 lb of iron per the design, each received
approximately 19,500 lb. Based upon the limited surfacing adjacent to wells F19, F20
and F21, fractures extended approximately 15 feet along the azimuth of the PRB,
resulting in complete coalescence around frac well F20 from F19 and F21. This was also
noted on resistivity imaging. A total of 183,447 lb of iron was injected into the upper
panel of Segment 2.
Upon completion of Segment 2, the hydrofracture equipment was trailer-mounted to
allow installation of the PRB into Segment 3 from F26 to F40. Additionally, inclined
profile borings were completed in the upper and lower panels of Segment 2 concurrent
with Segment 3 construction. The results of the inclined profile borings are discussed
further below.
PRB Construction F26 – F40 (Segment 3)
The final segment for construction was Segment 3 from frac wells F26 to F40. Because
these wells were all located within Hookston Road, all of the hydrofracture equipment
had to be trailer-mounted to allow reopening of Hookston Road at the end of each day.
Identical to the other two segments built on site, the lower panel of Segment 3 was
completed first with no deviations from the design. In accordance with the design, a total
of 180,450 lb of iron was injected into the lower panel.
Once the lower panel of Segment 3 was completed, the mechanical packers were
removed and the completion of the upper panel within Segment 3 was completed. Similar
to F20 in Segment 2, one deviation from the design occurred when the mechanical packer
in F40 was sanded into the casing and it was not possible to remove it from the frac well.
Based on this, GeoSierra injected as much of the iron as possible, per Design
Specifications, and utilized a “chase” of clean gel in attempt to keep the casing clear to
permit additional injections. A total of 3,857 lb of iron was injected in F40 before
sanding of the casing prevented further injections. As discussed on site, the remaining
4,783 lb was injected in F38 and F39. Similar to F1, because F40 is located at the end of
the PRB, there should not be detrimental effects on the PRB from the reduced quantity of
iron injected into F40.
Following completion and verification of Segments 1 to 3, all frac wells and resistivity
receivers were abandoned in accordance with the requirements of the State of California
by a licensed drilling company and under the supervision of the Contra Costa County
Environmental Health Department.
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5.3 Construction Quality Assurance Monitoring
As outlined in the design, construction QA procedures were followed to ensure that the
PRB was installed in accordance with the Construction Drawings and Technical
Specifications. QA procedures focused on the following criteria:
ZVI/gel mix design including mix density, resistivity, and viscosity (gel only);
Hydrofracturing injection pressures;
Approximate ZVI filings placement rate per square foot of PRB by determining
the PRB geometry by active resistivity mapping and the weight of iron injected in
each hydrofracturing casing;
Post-installation angled borings into the PRB to verify thickness; and
Pre- and post-PRB hydraulic pulse interference tests to quantify the PRB
hydraulic effectiveness.
Each QA processes described above was implemented during the construction of the
PRB. Additionally, a sampling on hydrofracturing injection pressures is included within
Appendix C. Deviations from the Design Specifications and/or results of the QA
Monitoring Program are discussed briefly below.
Forty-six batches of gel (approximately 134,000 gallons of gel) were mixed to complete
injections and cleanout of equipment and hoses at the site. Due to vertical migration of
the fractures throughout the project, the viscosity of the gel was increased from the
Design Specifications in attempt to reduce the quantity of gel and iron from migrating
vertically to the surface. Similarly, due to vertical migration of the gel/iron mixture into
the unsaturated zone above the resistivity strings, the actual placement per square foot
could not be calculated. Rather the estimated quantity required for each panel based on
well spacing and the design height was calculated and used as a guide for injections. The
results of these calculations are included on Tables 4 and 5. Aside from viscosity, there
were no other significant deviations from the Design Specifications for the gel and iron
mixture. The results of gel QA/QC monitoring are included as Table 6.
Hydrofracture injection pressures were monitored throughout the duration of injections
and in general, low injection pressures were noted in all fracture wells. Fracture
pressures typically ranged from approximately 10 to 80 pounds per square inch
depending on depth and thickness of the segment under construction.
5.3.1 Active Resistivity Monitoring
During construction of the PRB, active resistivity mapping was utilized to track the
propagation of the iron/gel mixture through the subsurface. As discussed above and
shown on Figure 2, active resistivity strings were installed on 24-foot centers
approximately 20 feet offset from the wall azimuth. Each resistivity string contained
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seven stainless-steel collars in direct contact with surrounding soil and ground water.
The receivers were connected to individual 12-gauge copper wires that terminated at
ground surface. Each individual receiver was then hardwired through a junction box and
reel to the patch panel within Frac Trak trailer. Following installation, each connection
was tested for continuity with the aquifer through a test box via excitement of each
receiver and testing for signal in adjacent receivers.
Once the receivers were tested for continuity, up to nine strings each containing five
active receivers was monitored during injections. During early injections of Segment 1,
the entire array of seven receivers per string was monitored from 51 to 19 feet MSL;
however, during construction of the shallow panels following completion of the deep
panels, preferential current flow to the continuous deep panel resulted in washing out of
the shallow well receiver signal. As such, subsequent injections in Segments 1 through 3
utilized only five receivers in the lower panel (approximately 19 to 44 feet MSL) and five
receivers in the upper panel during monitoring (26 to 51feet MSL) to negate the washout
effect.
During injection activities, a 100 hz square wave signal was generated within the Frac
Trak trailer and sent to the active frac injection well to excite the gel/iron being
monitored by the active resistivity system. Depending on location and local
conductivity/resistivity properties adjacent to the frac well under injection, the signal
current was increased or decreased to provide a crisp image compared to surrounding soil
properties.
The resistivity outputs were used as a guide to ensure that gaps in the wall did not exist
and that panels of iron overlapped during construction. Additionally in the deeper zone,
initial outputs were used to estimate the panel thickness based upon tonnage injected at
each location. The shallow zone thicknesses could not be calculated due to fracture
migration vertically outside the active resistivity monitoring capabilities (e.g., above the
water table). Because of the extensive lateral fracture propagation, individual fractures
were calculated at approximately 0.75-inch to 1-inch thick; therefore, each well typically
received a minimum of 4 to 8 fractures to meet the specified design criteria thickness of 3
to 4.5 inches, depending on the segment location and iron quantity injected. Included
within Appendix B are outputs from the resistivity system for each frac well at various
well injection timepoints. These images have been provided to show the lateral extent of
influence from each frac well that was noted during injections. Generally, each well had
as much as a 15- to 20-foot lateral fracture in each direction during construction and with
a 12-foot, center-to-center spacing of the frac wells. This influence provided for
significant overlap of iron panels. This was verified during inclined profile testing where
iron thicknesses were verified at the center point between frac wells in both the shallow
and deep PRB zones, as discussed below.
5.3.2 Post-Installation Inclined Profile Borings
As shown on Figure 2, a total of four post-installation inclined profile borings (ICPs)
were completed within Segments 1 and 2 to confirm installed PRB thickness within both
the shallow and deep panel segments. Borings were completed utilizing a variety or
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methods for the highest resolution results and minimal disturbance within the wall
sections.
The first two borings, ICP-1 and ICP-2, were completed in Segment 1 between F-7 and
F-8. Prior to testing the PRB thickness utilizing a downhole tiltmeter/magnetometer
(AOSI EZ-Compass 3), a 2-inch, Schedule 40 polyvinyl chloride (PVC) casing was
installed through the wall at approximately 46 degrees from vertical. GeoProbe rods
(3.5-inch) were driven through the wall utilizing direct-push methods, in attempt to
minimally disrupt the iron filings within the wall. Offsets were measured approximately
20 and 34 feet from the azimuth of the PRB and the borings were installed at the target
angle. Once the borings were completed, the PVC casings were installed and the
GeoProbe rods were removed. At the 46-degree angle and the offset distances from the
PRB, the location and thickness of the PRB were measured between the frac wells at a
targeted depth of approximately 20 and 35 feet bgs, or the center point of the upper and
lower casings between the target frac wells. Once the casings were completed, the
downhole magnetometer was inserted into the casing and measurements of localized
magnetic field commenced at approximately 2 to 3 feet before and 2 to 3 feet after the
anticipated location of the PRB. Magnetic field measurements were collected every 1
inch in the 4- to 6-foot measured interval to determine entrance and exit locations of the
magnetometer within the PRB.
Segment 1 – ICP-1 and ICP-2
As shown on Figure 2, inclined profile ICP-1 was installed between Frac Wells F-7 and
F-8 or at the approximate center location of Segment 1. ICP-1 was collected within the
deep panel segment with an offset of 34 feet from the PRB azimuth. Following
installation of the 2-inch casing at a 46-degree angle, the azimuth of the PRB should have
been located at approximately 48.9 feet within the casing. Appendix D contains the
output from the magnetometer following data reduction. The “h” value represents the
combination of the “X” and “Y” (horizontal vectors combined to represent the field
perpendicular to the PRB on a horizontal plane) magnetic field measurements, while the
“z” value represents the vertical horizontal field measurement with no data reduction
necessary. Based upon the data reduction and evaluation at this location, the PRB was
encountered at approximately 48.16 feet within the casing and the magnetometer
emerged from the PRB at approximately 48.58 feet, or within 6 inches of the anticipated
PRB azimuth. When correcting for the declination angle of the casing compared to the
vertical PRB, these measurements represent approximately 3.62 inches of iron.
The 3.62-inch-thick iron PRB is consistent with the quantity of iron injected within
Segment 1, as one additional ton of iron was injected into the lower panel in frac wells F1
to F-11 to account for vertical migration of iron into the shallow segment. Finally, the
3.62-inch iron thickness exceeds the Design Specification for Segment 1, which was
specified as 3 inches.
ICP-2 was installed utilizing the same technique as ICP-1 except with a 20-foot offset
from the PRB azimuth. The 2-inch casing was installed at a 46.3-degree angle from
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vertical, which should have encountered the PRB at approximately 28.9 feet within the
casing. As shown in Appendix D, the PRB was encountered at approximately 29.33 feet
and the magnetometer emerged from the PRB at approximately 29.66 feet. Once
corrected for the declination angle of the PVC casing, this represents a primary fracture
thickness of 2.85 inches, or within 5% of 3 inches. In addition to the primary fracture
measured, there were also secondary fractures measured on both sides of the primary
fracture. As discussed earlier, additional iron was injected into the deep well within
Segment 1 to account for vertical iron migration during the lower PRB construction. The
secondary fractures described on outputs in Appendix D represent secondary fractures
created during vertical migration from the deep zone. Once the secondary fracture
thicknesses (approximately one-half-inch) are accounted for, the actual iron thickness in
the shallow zone is above the 3-inch Design Specification (approximately 3.85 inches).
Segment 2 – ICP-3 and ICP-4
In an attempt to physically sample the thickness of the PRB, which has historically been
extremely difficult to accomplish depending largely on site lithology, the casing
installation method was changed to sonic methods for ICP-3 and ICP-4. The two borings
were installed at approximately 25 feet and 35 feet offset from the PRB, targeting the
bottom of the upper casing and center point of the lower casings. The sonic cores were
collected from approximately 5 feet before the PRB and 5 feet after.
ICP-3 was installed approximately 25 feet from the anticipated azimuth of the PRB
between F-13 and F-14. Cores were collected and analyzed at the surface to evaluate iron
thickness and fracture locations. The sample core for this boring was successful in
collecting samples of the iron and, similar to the magnetometer results from Segment 1,
the primary fracture was surrounded on either side by secondary fractures from below,
confirming the results and interpretation of ICP-2 in Segment 1.
Following installation of the 2-inch casing, the magnetometer study was performed on
ICP-3 utilizing the same means and methods of data collection and reduction as previous
borings. With the 25-foot offset and installation of the casing at a 47-degree angle, the
azimuth of the PRB is calculated to be approximately 36.6 feet into the 2-inch casing. As
shown in Appendix D, the primary PRB fracture was encountered at approximately 36 to
36.5 feet within the casing. The primary fracture thickness once corrected for the casing
declination angle is approximately 5.17 inches, or in excess of the required 4.5-inch
thickness in Segment 2. Additionally, secondary fractures were noted at approximately
31 and 33 feet inside the casing, which correspond to smaller secondary fractures
identified in the recovered soil core.
ICP-4 was installed approximately 35 feet from the anticipated azimuth of the PRB
between F13 and F14. Collection of soil cores was also attempted at this location;
however, the cores collected were not viable based upon liquefaction of the soils
immediately adjacent to the PRB from the sonic drill rig. This occurred when the sonic
rods encountered stiff resistance that required significant time and effort to push through.
That location was estimated to be within 2 to 3 feet of the azimuth of the PRB. This is
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also evident from the Segment 2, ICP-4 data reduction and output from the
magnetometer. Three peaks of magnetism were encountered over approximately 3 feet
of measurement. This measured data was confirmed during a second test within the same
borehole to ensure data accuracy. The data in Appendix D show that three magnetic
peaks with an effective iron thickness of over 9 inches were measured. Based on the
mass of iron injected and the approximate fracture geometry at this location from active
resistivity imaging, this thickness is not feasible; therefore, although iron was measured
in this location, its exact thickness could not be confirmed with a degree of precision.
5.3.3. Post-PRB Installation Hydraulic Interference Pulse Testing
Hydraulic pulse interference tests (HPIT) were conducted prior to and following the
installation of the PRB to verify that the PRB will not impact the natural ground water
flow. The HPIT is highly sensitive and defines the degrees of hydraulic continuity
between the source and receiver wells. The HPIT is a transient test and hydraulic
properties, such as transmissivity and storativity, of the formation can be quantified.
The point-source HPIT can be modeled from the solution of a continuous point source in
an infinite isotropic homogeneous medium (Carslaw and Jaeger, 1986) as given by
equation (1). This fundamental solution can be modified to incorporate finite aquifer
systems, confined and unconfined conditions, and anisotropic and heterogeneous
conditions in a similar manner, as the line source solution has been modified in the
petroleum literature. This line-source solution for continuous injection is the exponential
integral, whereas the point-source solution is the complementary error function. The
pressure response in a receiver well is given by the following equation:
d
d
dwt
rerfc
rrK
qtp
*4****4)( (1)
where Δp(t) is the pressure response at a given time, K is the formation hydraulic
conductivity, Ss is the formation specific storage, rw is the well bore radius of a source
well, td is dimensionless time defined in equation (2), and rD is the dimensionless distance
defined by the following equation:
w
Dr
rr
where r is the distance from the receiver well to the source well. The dimensionless time
is defined as:
sw
DSr
tKt
*
*2
(2)
where t is the elapsed time since the start of the injection.
A total of eight monitoring wells were tested in the vicinity of the PRB including MW-
30A, MW-30A2, MW-31A, MW-31A2, MW-32A, MW-32A2, MW-33A, and MW-
33A2. All wells were 2 inches in diameter with the “A” wells screened in the shallow A-
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Zone horizon, while the “A2“ wells were screened in the deep A-Zone horizon. HPIT
was conducted across all monitoring wells to provide detailed hydrogeological
characterization of the site by cross hole paths, perpendicular to the PRB alignment.
Field Procedures
The source well injection system consists of an inflatable packer to isolate the injection
horizon and a pressure transducer that is placed in the source well to monitor injection
pressures. The receiver well system also consists of an inflatable packer isolating the
high-precision pressure transducer from well bore storage effects. The injection flow rate
is controlled by a constant flow rate direct drive pump with solenoid adjustable time
interval switching values to modulate the periodic timed injection and shut-in of the
source well.
During the HPIT, the source well’s flow rate and pressure are monitored along with all of
the receiver pressure transducers. The pressure transducers must be of high precision and
the flow rate and pressures must be continuously monitored and recorded at high data
acquisition rates. To ensure the tests are repeatable, the pulse switching mechanism
needs to be automatically controlled and recorded on the data acquisition system. To
optimize the resolution of the test, the injection/shut-in time interval and/or injection flow
rate was varied depending on site conditions and the distances between source and
receiver wells.
Results
The interpretation of the point-source HPIT follows similar procedures to line source
interpretation procedures using type curves as detailed in Hocking (2001). The HPIT
arrangement, typical data, and type-curve matching are shown on outputs in Appendix E.
The hydraulic pulse interference tests were conducted across the monitoring well pairs as
follows:
Source Well Receiver Well
MW-31A MW-30A
MW-31A MW-30A2
MW-31A2 MW-30A
MW-31A2 MW-30A2
MW-33A MW-32A
MW-33A MW-32A2
MW-33A2 MW-32A
MW-33A2 MW-32A2
The locations of the monitoring wells respective to the PRB are shown on Figure 2.
Type-curve matching for all of the source-receiver well pairs detailed above is contained
in Appendix E. The type-curve match assumed a confined aquifer from a depth of 5 feet
down to a total depth of 45 feet.
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The hydraulic conductivity and storativity values computed for each well pair are detailed
in Table 7. The hydraulic conductivity calculated from the test data range from a low of
1.09 ft/day to a high of 64.2 ft/day. The calculated storativity values from the test data
range from low 1.43E-05 to a high of 2.23E-04. The field data and best-fit type curves
are contained in Appendix E for all hydraulic pulse interference test data. Based on these
field data, good hydraulic connection exists between all well pairs, with higher
conductivities encountered in the deeper well pairs compared to the shallow well pairs.
To compare the results from the pre- and post-PRB installation hydraulic pulse
interference testing, the results from both test events are detailed on Table 7 in addition to
the percent change between the events. In general, there is good agreement between both
events with some variation in the shallow results, whereas the deep well pair results are
well within the precision of the test. The combination of the construction of the shallow
monitoring wells across the water table, the amount of open screen and the low water
table all likely account for the less precise results in the shallow well pairs. Because the
receiver wells are receiving the pulse across the aquifer, if monitoring wells are not
screened fully within the saturated zone, attenuation of the pulse can occur faster than
what is representative by the actual formation characteristics. This is evident by the
higher conductivity and storativity value within the shallow well pairs from pre- to post-
PRB testing, compared to a very small change in the deep well pairs with fully saturated
screens.
Although the results varied slightly, the mean changes to the shallow and deep well pairs
were approximately 2 and 0.45 ft/day, respectively. Based on these results, there are no
apparent impacts of the PRB on the natural aquifer characteristics and ultimately natural
ground water flow of the aquifer.
5.4 Construction Quantities
The PRB construction ultimately utilized the following materials to complete
construction of the 480 lf PRB that is approximately 32 feet in height.
Forty frac well injection locations were installed with two casings per location,
utilizing a combination of mud-rotary and hollow-stem-auger techniques;
Twenty resistivity strings were installed with seven receivers each, or a total of
140 receivers with all locations except RR-20 logged with a CPT rig;
A total of 473 tons of granular iron was delivered and injected;
A total of approximately 134,000 gallons of gel was utilized for pre-construction
formation “slicking,” for injection equipment cleanout, out of spec gel batches
and injection of the iron; and
Four inclined profile borings were completed in Segments 1 and 2 and
successfully verified in situ PRB thickness.
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GEOSIERRA ENVIRONMENTAL, INC. 24 Final Construction Report - Sept 2009
SUMMARY ERM retained GeoSierra to design and install a ZVI PRB within the A-Zone aquifer
within a residential neighborhood downgradient of the Hookston Station Site in Pleasant
Hill, California. This report details the final installation activities, QA/QC monitoring,
and results of the PRB installation. A brief photo journal is included as Appendix F. The
ZVI PRB was installed in the subsurface extending from Len Hester Park to the south
side of Hookston Road from the northwest to southeast. The objective of the PRB is to
degrade chlorinated volatile organic compounds in site ground water to below approved
cleanup goals.
Based on column testing and results of installation activities, a ZVI PRB should
effectively reduce ground water impacts present at the site. The geology, ground water
conditions, and depth of the PRB were all very amenable to construction by the azimuth-
controlled vertical hydrofracture installation method.
The PRB was designed and installed to specification to achieve effluent CVOC
concentrations below their respective cleanup goals. The PRB was built approximately
480 feet in total length and ranged from 3.85 to 5.15 inches in thickness, and is
perpendicular to the local ground water flow direction. The PRB was constructed from
approximately 51 feet MSL (approximately 11 to 15 feet bgs, adjusting for topographic
changes along the proposed alignment) to 19 feet MSL (approximately 44 to 48 feet bgs).
The PRB was constructed as one continuous, single wall.
The construction of the PRB commenced with drilling in March 2009 and was completed
in June 2009, a total of 4 months. Due to surfacing issues within the shallow zone, an
additional 4 weeks was needed to ensure construction of the PRB was within
specification.
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GEOSIERRA ENVIRONMENTAL, INC. 25 Final Construction Report - Sept 2009
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GEOSIERRA ENVIRONMENTAL, INC. 26 Final Construction Report - Sept 2009
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GEOSIERRA ENVIRONMENTAL, INC. 27 Final Construction Report - Sept 2009
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Jeen, S.W., K.U. Mayer, R.W. Gillham, and D.W. Blowes (2007). Reactive Transport
Modeling of Trichloroethene Treatment with Declining Reactivity of Iron. Environmental
Science and Technology, Vol. 41, No. 4, pp 1432–1438, ACS.
Johnson, C.R., R.A. Greehorn, and E.G. Woods (1966). Pulse testing: A New Method
for Describing Reservoir Flow Properties between Wells. JPT, Vol. 237, pp 1599-1604,
Trans., AIME.
Kamal, M.M. (1983). Interference and Pulse Testing- A Review. JPT, pp 2257-2270.
Mayer, K.U., D.W. Blowes, and E.O. Frind (2001). Reactive Transport Modeling of an
In-Situ Reactive Barrier for the Treatment of Hexavalent Chromium and Trichloroethene
in Groundwater. Water Resour. Res. Vol 37, 3091-3103
Orth, S., and R.W. Gillham (1996). Dehalogenation of Trichloroethene in the Presence
of Zero Valent Iron, Environ.Sci. Technol., Vol 30, pp 66-71.
Peck, R.B., W.E. Hanson, and T.H. Thornburn (1974). Foundation Engineering, 2nd
Ed.,
John Wiley & Sons, New York.
Reynolds, T., R.W. Gillham, and S. F. O’Hannesin (2002). In-Situ Monitoring of the
Ten Year Old PRB at Borden, Ontario. RTDF Permeable Reactive Barrier Action Team
Meeting, Washington, DC, November 6-7.
Roberts, A.L., L.A. Totten, W.A. Arnold, D.R. Burris, and T.J. Campbell (1996).
Reductive Elimination of Chlorinated Ethylenes by Zero Valent Iron, Env. Sci. &
Technol., Vol 30, No 8, pp 2654-2659.
Sivavec, T.M., and D P. Horney (1995). “Reactive Dechlorination of Chlorinated Ethenes
by Iron Metal,” Proc. 209th
. American Chemical Society National Meeting, Vol 35, No 1,
pp 695-698.
Sivavec, T. M., P.D. Mackenzie, D.P. Horney, and S.S. Bagel (1997). “Redox-Active
Media Selection for Permeable Reactive Barriers,” Int. Containment Conf., St.
Petersburg, FL, February 10-12.
Hookston Station Final Report
Pleasant Hill, California
GEOSIERRA ENVIRONMENTAL, INC. 28 Final Construction Report - Sept 2009
Starr, R.C., and J.A. Cherry (1994). In Situ Remediation of Contaminated Groundwater:
The Funnel-and-Gate System. Ground Water, Vol 32, No. 4, pp 465-476.
Su, C., and R.W. Puls (1998). Temperature Effect on Reductive Dechlorination of
Trichloroethene by Zero Valent Metals, 1st Int. Conf. on Remediation of Chlorinated and
Recalcitrant Compounds, Monterey, CA, May 18-21.
Sweeny, K.H., and J.R. Fisher (1972). Reductive Degradation of Halogenated Pesticides.
U.S. Patent No. 2,640,821.
Hookston Station Final Report
Pleasant Hill, California
GEOSIERRA ENVIRONMENTAL, INC. 29 Final Construction Report - Sept 2009
TABLES
Table 1. Fracture Gel Composition Summary. Hookston Station ZVI PRB. Pleasant Hill, California. G205001
Material Description MSDS Product NameProduct per
gallonof water
Zero Valent Iron PL-14D-WWCA 10
Gel (Hydroxypropyl Guar) GS-B-1 0.0533
Acetic Acid GS-BA-1 0.58 - .75 mls
Gel Cross Linker GS-BC-1 0.02 gals
Gel Enzyme Breaker GS-BE-4 0.002 lbs
Sodium Chloride Sodium Chloride 0.02 lbs
GEOSIERRA ENVIRONMENTAL, INC. 1 Table 1 - Gel Composition Table
Table 2. Fracture Well Installation Details. Hookston Station ZVI PRB. Pleasant Hill, CaliforniaG205001
Frac Casing Number
Surface Elevation (ft
MSL)
Bottom Casing Target
Elevation (ft MSL)
Top Casing Target Zone Elevation (ft.
MSL)
Total Depth of Boring (bgs)
Bottom Elevation of Frac Casing
(Ft MSL)
Top Elevation of Frac Casing
(Ft MSL)
F1 64.29 21 46 45 21.79 46.79F2 65.07 21 46 46 21.57 46.57F3 65.74 21 46 47 21.24 46.24F4 66.14 21 46 47 21.64 46.64F5 66.37 21 46 47 21.87 46.87F6 66.43 21 46 47.5 21.43 46.43F7 66.54 21 46 47 22.04 47.04F8 66.67 21 46 47.5 21.67 46.67F9 66.67 21 46 47.5 21.67 46.67F10 66.69 21 46 47.5 21.69 46.69F11 66.36 21 46 47.5 21.36 46.36F12 66.56 21 46 47.5 21.56 46.56F13 66.82 21 46 48 21.32 46.32F14 67.12 21 46 48 21.62 46.62F15 67.19 21 46 48 21.69 46.69F16 66.97 21 46 48 21.47 46.47F17 66.62 21 46 47.5 21.62 46.62F18 66.25 21 46 47 21.75 46.75F19 65.72 21 46 47 21.22 46.22F20 64.84 21 46 46 21.34 46.34F21 64.07 21 46 45.5 21.07 46.07F22 63.34 21 46 45 20.84 45.84F23 63.16 21 46 45 20.66 45.66F24 63.61 21 46 44 22.11 47.11F25 63.86 21 46 45 21.36 46.36F26 64.13 21 46 45 21.63 46.63F27 64.40 21 46 45 21.90 46.90F28 64.62 21 46 46 21.12 46.12F29 64.86 21 46 46 21.36 46.36F30 65.01 21 46 46 21.51 46.51F31 65.15 21 46 46 21.65 46.65F32 65.20 21 46 46 21.70 46.70F33 65.24 21 46 46 21.74 46.74F34 64.24 21 46 46 20.74 45.74F35 65.20 21 46 46 21.70 46.70F36 65.14 21 46 46 21.64 46.64F37 65.07 21 46 46 21.57 46.57F38 65.25 21 46 46 21.75 46.75F39 65.27 21 46 46 21.77 46.77F40 64.91 21 46 46 21.41 46.41
GEOSIERRA ENVIRONMENTAL, INC. Tables 2 and 3 - Frac and RR Installation Details
Table 3. Resistivity String Installation Details. Hookston Station ZVI PRB. Pleasant Hill, CaliforniaG205001
RR String
Number
Date Installed
Ground Surface
Elevation (ft MSL)
End of Tip (bgs)
Elevation of Black Receiver (ft MSL)
Elevation of White Receiver (ft MSL)
Elevation of Red
Receiver (ft MSL)
Elevation of Green Receiver (ft MSL)
Elevation of Orange Receiver (ft MSL)
Elevation of Yellow Receiver (ft MSL)
Elevation of Blue
Receiver (ft MSL)
Location Along
Alignment (ft)
RR1 3/6/2009 65.00 47.1 18.9 23.9 28.9 33.9 38.9 43.9 48.9 19RR2 3/5/2009 65.01 47.1 18.9 23.9 28.9 33.9 38.9 43.9 48.9 33RR3 3/5/2009 66.05 47.1 20.0 25.0 30.0 35.0 40.0 45.0 50.0 57RR4 3/5/2009 66.19 47.2 20.0 25.0 30.0 35.0 40.0 45.0 50.0 81RR5 3/5/2009 65.64 46.6 20.0 25.0 30.0 35.0 40.0 45.0 50.0 105RR6 3/5/2009 64.85 45.9 20.0 25.0 30.0 35.0 40.0 45.0 50.0 129RR7 3/4/2009 65.06 46.1 20.0 25.0 30.0 35.0 40.0 45.0 50.0 154RR8 3/6/2009 66.16 47.2 20.0 25.0 30.0 35.0 40.0 45.0 50.0 179RR9 3/6/2009 66.23 47.2 20.0 25.0 30.0 35.0 40.0 45.0 50.0 203.5RR10 3/4/2009 64.64 45.6 20.0 25.0 30.0 35.0 40.0 45.0 50.0 226.75RR11 3/7/2009 63.34 44.3 20.0 25.0 30.0 35.0 40.0 45.0 50.0 256RR12 3/7/2009 63.62 44.5 20.1 25.1 30.1 35.1 40.1 45.1 50.1 276RR13 3/9/2009 64.01 45.5 19.5 24.5 29.5 34.5 39.5 44.5 49.5 298RR14 3/9/2009 64.45 46.0 19.5 24.5 29.5 34.5 39.5 44.5 49.5 322RR15 3/9/2009 64.90 46.0 19.9 24.9 29.9 34.9 39.9 44.9 49.9 342RR16 3/9/2009 65.26 46.5 19.8 24.8 29.8 34.8 39.8 44.8 49.8 376.75RR17 3/7/2009 65.55 45.5 21.1 26.1 31.1 36.1 41.1 46.1 51.1 396.25RR18 3/7/2009 65.67 45.0 21.7 26.7 31.7 36.7 41.7 46.7 51.7 420.25RR19 3/7/2009 65.57 47.5 19.1 24.1 29.1 34.1 39.1 44.1 49.1 444.9RR20 3/11/2009 65.33 45.0 21.3 26.3 31.3 36.3 41.3 46.3 51.3 474.9
GEOSIERRA ENVIRONMENTAL INC. Tables 2 and 3 - Frac and RR Installation Details
Table 4. Deep PRB Iron Injection Summary Hookston Station ZVI PRB. Pleasant Hill, California G205001
4 5 6 7 8 13 14 21 27 28 29 30 1 2 3 26 27 28 29 30 31 1 2 3
F1 3156 2534 935 1980 2110 10,715 10,640 45 15 47 13.54 433.3 6 9748.8F2 4036 1994 2932 2172 11,134 10,640 45 15 47 10.58 338.6 15.08 7617.6F3 998 2110 1984 2046 3720 10,858 10,640 45 15 47 12 384.0 27.16 8640F4 2986 2018 2578 2108 1000 10,690 10,640 45 15 47 11.21 358.7 39.08 8071.2F5 1886 1896 2079 2973 2028 10,862 10,640 45 15 47 12.04 385.3 49.58 8668.8F6 4004 2072 2446 2026 10,548 10,640 45 15 47 12.96 414.7 63.16 9331.2F7 2124 2460 1964 2168 1998 10,714 10,640 45 15 47 11.42 365.4 75.5 8222.4F8 3004 1970 2437 3045 10,456 10,640 45 15 47 10.79 345.3 86 7768.8F9 1870 2032 1990 3020 1974 10,886 10,640 45 15 47 11.875 380.0 97.08 8550F10 1020 3022 1948 4766 10,756 10,640 45 15 47 12.96 414.7 109.75 9331.2F11 2012 2000 2006 1793 1934 986 10,731 10,640 45 15 47 12.875 412.0 123 9270F12 1054 2052 1991 3918 1991 2098 13,104 13,000 67.5 15 47 12.165 389.3 135.5 13138.2F13 2098 962 4068 2288 3714 13,130 13,000 67.5 15 47 11.875 380.0 147.33 12825F14 946 1948 2000 3796 2068 2002 12,760 13,000 67.5 15 47 12 384.0 159.25 12960F15 1904 1979 3982 2012 3232 13,109 13,000 67.5 15 47 12.04 385.3 171.33 13003.2F16 1006 1995 2048 4058 1980 2038 13,125 13,000 67.5 15 47 12 384.0 183.33 12960F17 1992 4002 2122 3800 1156 13,072 13,000 67.5 15 47 12 384.0 195.33 12960F18 1026 2034 1952 3987 1998 2044 13,041 13,000 67.5 15 47 11.55 369.6 206.88 12474F19 1978 3977 1884 3900 1310 13,049 13,000 67.5 15 47 12.22 391.0 219.1 13197.6F20 972 1988 200 3976 2098 1858 2059 13,151 13,000 67.5 15 47 12.78 409.0 231.88 13802.4F21 2026 4046 2076 4037 976 13,161 13,000 67.5 15 47 12.78 409.0 244.66 13802.4F22 1076 983 1818 3162 1452 1558 3105 13,154 13,000 67.5 15 47 10 320.0 254.66 10800F23 2003 2998 1487 3464 1530 1647 13,129 13,000 67.5 15 47 13.5 432.0 268.16 14580F24 958 2016 2018 2753 1484 1088 2587 12,904 13,000 67.5 15 47 12 384.0 280.16 12960F25 2051 3047 1544 3504 1990 1150 13,286 13,000 67.5 15 47 11 352.0 291.16 11880F26 1434 1538 4117 1905 2047 2152 13,193 13,000 67.5 15 47 12.75 408.0 303.91 13770F27 1552 2044 2076 2093 2962 2547 13,274 13,000 67.5 15 47 12.25 392.0 316.16 13230F28 1500 1480 3968 1942 1940 2307 13,137 13,000 67.5 15 47 12 384.0 328.16 12960F29 1020 1539 1480 2012 1966 1949 1997 1160 13,123 13,000 67.5 15 47 11.85 379.2 340.01 12798F30 1750 1559 3839 2106 2094 1701 13,049 13,000 67.5 15 47 12.1 387.2 352.11 13068F31 962 1530 1539 1972 1888 2002 2051 1308 13,252 13,000 67.5 15 47 12.3 393.6 364.41 13284F32 1576 1449 4128 1884 1980 2208 13,225 13,000 67.5 15 47 11.9 380.8 376.31 12852F33 1475 1467 2077 2094 2161 2032 1964 13,270 13,000 67.5 15 47 12.1 387.2 388.41 13068F34 1490 1546 4019 2020 1937 2182 13,194 13,000 67.5 15 47 11.75 376.0 400.16 12690F35 2499 1633 2016 1940 1889 1967 1129 13,073 13,000 67.5 15 47 12 384.0 412.16 12960F36 1509 1475 3931 2066 1986 2212 13,179 13,000 67.5 15 47 12 384.0 424.16 12960F37 1393 1999 2000 1996 1430 8,818 8,640 45 15 47 10.6 339.2 434.76 7632F38 1988 1918 4929 8,835 8,640 45 15 47 10.6 339.2 445.36 7632F39 2145 2098 1590 1971 1045 8,849 8,640 45 15 47 13.13 420.2 458.49 9453.6F40 1978 2260 4741 8,979 8,640 45 15 47 12.33 394.6 470.82 8877.6
Subtotals 26,076 22,106 0 10,958 27,395 25,063 6,752 11,040 26,007 38,147 39,063 38,722 18,560 9,049 2,587 1,982 16,302 18,111 36,122 14,109 30,077 27,931 25,101 10,715 481,975 476,600 479.82
Location along wall (ft)
Target (pounds)
Iron Loading (pounds/
sq.ft.)
Top of PRB (ft) Cross-Sectional Area (ft2)
Lbs Req'd for Wall
Geometry (lbs)
LOWER PANEL
Bottom of PRB (ft)
Length of PRB (ft)Frac Casing No.
Apr-09 Quantity of Iron Injected (tons)
May-09 Jun-09
GEOSIERRA ENVIRONMENTAL, INC. Tables 4 and 5 - PRB Injected Quantities
Table 5. Shallow PRB Iron Injection Summary. Hookston Station ZVI PRB. Pleasant Hill, California G205001
14 15 16 17 18 19 2 3 4 5 6 11 12 14 15 16 17 18 2 3 4 10 11 12 13 14 15 16 17 24 25 26 27
F1 798 1032 954 2,784 8,640 45 15 47 13.54 433.3 6 9748.8F2 3076 1017 1978 616 502 1162 513 8,864 8,640 45 15 47 10.58 338.6 15.08 7617.6F3 1472 1002 1976 1932 1260 682 858 9,182 8,640 45 15 47 12 384.0 27.16 8640F4 2496 2028 1996 1386 1020 8,926 8,640 45 15 47 11.21 358.7 39.08 8071.2F5 1509 2572 2024 1968 744 8,817 8,640 45 15 47 12.04 385.3 49.58 8668.8F6 2402 2020 2016 1359 1002 8,799 8,640 45 15 47 12.96 414.7 63.16 9331.2F7 1697 2444 1993 1916 627 8,677 8,640 45 15 47 11.42 365.4 75.5 8222.4F8 2348 1990 2011 1011 1552 8,912 8,640 45 15 47 10.79 345.3 86 7768.8F9 1642 2520 1982 2020 365 8,529 8,640 45 15 47 11.875 380.0 97.08 8550
F10 2528 2046 2080 659 1314 8,627 8,640 45 15 47 12.96 414.7 109.75 9331.2F11 1522 2548 1948 2028 1020 9,066 8,640 45 15 47 12.875 412.0 123 9270F12 2630 1038 2280 1944 1890 2096 904 12,782 13,000 67.5 15 47 12.165 389.3 135.5 13138.2F13 1001 939 2346 1082 1838 1977 2086 1870 13,139 13,000 67.5 15 47 11.875 380.0 147.33 12825F14 2008 938 1636 1943 2078 1886 2850 13,339 13,000 67.5 15 47 12 384.0 159.25 12960F15 974 1038 2202 1002 2266 2084 1950 1695 13,211 13,000 67.5 15 47 12.04 385.3 171.33 13003.2F16 1938 1088 1988 2104 1975 2034 2072 13,199 13,000 67.5 15 47 12 384.0 183.33 12960F17 1098 1020 2026 936 2028 2006 2034 2114 13,262 13,000 67.5 15 47 11.775 376.8 195.33 12717F18 2090 974 2166 1971 1978 2038 1944 13,161 13,000 67.5 15 47 11.885 380.3 206.88 12835.8F19 966 950 1820 1056 1626 1930 2110 1968 3444 1044 1021 1138 19,073 19,500 67.5 15 47 12.5 400.0 219.1 13500F20 0 0 67.5 15 47 12.78 409.0 231.88 13802.4F21 1080 1110 2204 1068 1982 2108 1898 2036 1023 1039 990 1220 17,758 19,500 67.5 15 47 11.39 364.5 244.66 12301.2F22 1052 956 968 1080 1157 1101 1331 1080 507 1005 953 1052 540 12,782 13,000 67.5 15 47 11.75 376.0 254.66 12690F23 1038 1012 1557 444 1112 1056 1095 1121 1745 1041 1198 752 13,171 13,000 67.5 15 47 12.75 408.0 268.16 13770F24 1974 548 1006 950 989 989 1367 1053 469 965 1004 1072 608 12,994 13,000 67.5 15 47 11.5 368.0 280.16 12420F25 897 396 1581 448 1014 1018 987 1087 1461 940 1088 1056 644 426 13,043 13,000 67.5 15 47 11.875 380.0 291.16 12825F26 1036 1724 917 1250 1190 1194 874 1164 704 1067 1192 582 12,894 13,000 67.5 15 47 12.5 400.0 303.91 13500F27 1056 1008 1651 749 1072 1117 1554 912 901 1485 1226 12,731 13,000 67.5 15 47 12.25 392.0 316.16 13230F28 1020 1512 1040 1016 1090 1158 1059 1179 678 1474 1119 627 12,972 13,000 67.5 15 47 12 384.0 328.16 12960F29 1002 942 1620 1129 1146 1490 1023 1385 1337 1486 439 12,999 13,000 67.5 15 47 11.85 379.2 340.01 12798F30 976 1531 1015 1002 1151 1094 938 1049 739 1385 1330 409 12,619 13,000 67.5 15 47 12.1 387.2 352.11 13068F31 962 1056 1579 1129 1186 1510 1009 1224 1380 1348 611 12,994 13,000 67.5 15 47 12 384.0 364.11 12960F32 1029 1461 963 974 1244 1139 1053 998 673 1179 1386 796 12,895 13,000 67.5 15 47 12.2 390.4 376.31 13176F33 1022 1036 1443 978 1012 1502 977 1440 1292 1418 730 12,850 13,000 67.5 15 47 12.1 387.2 388.41 13068F34 1021 1558 1033 1039 1028 1067 977 819 707 1360 1490 682 12,781 13,000 67.5 15 47 11.75 376.0 400.16 12690F35 1066 900 1451 1055 1109 1569 1028 1533 1314 1494 520 13,039 13,000 67.5 15 47 12 384.0 412.16 12960F36 949 1627 1029 989 1179 1044 1023 1026 691 1511 1382 539 12,989 13,000 67.5 15 47 12 384.0 424.16 12960F37 914 1048 1552 487 976 940 1491 1036 8,444 8,640 45 15 47 10.6 339.2 434.76 7632F38 1042 1275 922 515 1251 1215 997 1064 850 1396 624 11,151 11,031 45 15 47 10.6 339.2 445.36 7632F39 953 1040 1600 1222 1318 1689 1123 1579 773 11,297 11,030 45 15 47 13.13 420.2 458.49 9453.6F40 1089 1749 1019 3,857 3,857 45 15 47 12.33 394.6 470.82 8877.6
Subtotals 8,640 24,968 19,978 19,945 9,047 6,072 3,021 513 6,053 18,157 19,278 16,080 21,858 22,246 22,304 22,359 9,806 976 6,034 2,978 11,424 10,251 23,643 18,834 8,021 15,694 15,739 17,726 14,407 13,748 17,379 15,495 5,935 448,609 454,598 479.95
Iron Loading (pounds/
sq.ft.)
Location along wall (ft)Cross-Sectional Area (ft2)
Top of PRB (ft)
Bottom of PRB (ft)
Length of PRB (ft)
Lbs Req'd for Wall
Geometry (lbs)
UPPER PANEL
Quantity of Iron Injected (tons)
Apr-09 Target (pounds)Frac Casing No.
May-09 Jun-09
GEOSIERRA ENVIRONMENTAL, INC. Tables 4 and 5 - PRB Injected Quantities
Table 6. Summary of Gel QA/QC Testing. Hookston Station ZVI PRB. Pleasant Hill, California Page 1 of 4
Gel Viscocity (cP) Shear Rate (sec-1)
1 10 100
5.89 280 last of old gel
7 12.9
305
4/27/2009 13 18.0 1200 580 159
4/17/2009 9 15.0
4/16/2009 8 15.2
1400 610 158 5.52
540/550 146/149 7.6 /5.22
176 5.80
1250
5.83
6.24 280
290
4/13/2009 5 15.9 1200/1300
4/14/2009
4/15/2009
6 14.1 1700
300
270
Ph too high, 500 ml added ..retest
7.06
300
4/8/2009 4 15.1 1600 370 150
2804/3/2009 207
4/6/2009 3 21.8 1800 650 165 6.90
Batch Size/RemarksGel
Resistivity (ohms-cm)
Date Gel pH
1
Gel Batch No.
Temperature (oC)
16.5
4/5/2009 2 19.6 2601100/2700 940/850 189/200 7.05 viscosity not zeroed
5.67
1300 300
2300 916 water PH 7.90
590 162
132500
690
600 152 5.29 270
270 1/2 batch 1500 gallons
5.44
4/21/2009 12 26.9 1500
4/19/2009 10 18.5/19.1 900/1000 270/470 170 5.68
2604/20/2009 11 20.6 1150 500 132
GEOSIERRA ENVIRONMENTAL, INC. Table 6 Summary of Gel QA-QC Testing
Table 6. Summary of Gel QA/QC Testing. Hookston Station ZVI PRB. Pleasant Hill, California Page 2 of 4
Gel Viscocity (cP) Shear Rate (sec-1)
1 10 100 Batch Size/Remarks
Gel Resistivity (ohms-cm)
Date Gel pHGel
Batch No.
Temperature (oC)
5/15/2009 25 20.7 2000 850 224 6.16 300
5/1/2009 19 18.3 2000 900 250 6.01 300
4/29/2009 16 15.8 2200 980 242 6.25 270 very wet crosslink
4/30/2009 17 15.9 2200 1000 246 6.15 270
4/30/2009 18 21.0 1500 800 210 6.26 270
5/2/2009 20 17.8 1700 600 171 6.51 290
5/14/2009 24 19.3 2100 890 235 6.11
23 23.6 1400 700 192 6.05
5/11/2009 22 20.5 2000 890 221 6.08
new gel..acid lowered to 1750 ml6.2 2904/28/2009 14 16.4 2000
900 241
950 247
4/28/2009 15 18.6 2000 6.41 270 gel crosslink on wetside
5/5/2009 21 19.8 1000 450 lot of overnight rain
5/16/2009 26 25.3 1900 880
305 gel sat in tank for 1 day while the power unit was down
5/11/2009
240
140 6.32 250
270
270
236 6.23
GEOSIERRA ENVIRONMENTAL, INC. Table 6 Summary of Gel QA-QC Testing
Table 6. Summary of Gel QA/QC Testing. Hookston Station ZVI PRB. Pleasant Hill, California Page 3 of 4
Gel Viscocity (cP) Shear Rate (sec-1)
1 10 100 Batch Size/Remarks
Gel Resistivity (ohms-cm)
Date Gel pHGel
Batch No.
Temperature (oC)
39 19.6 2100 970 219 5.94
6.47 260
243 6.57 3006/11/2009 38 20.5 2500 1000
6.1 260
5/30/2009 31 23.2 2300 800 230
5/29/2009 30 20.9 2200 1100 250
5/28/2009 29 23.4 2100 870 232 5.92 250
very hot740 210 5.92 240
820 221 6.1 250
5/17/2009 27 34.1 1600
950 227 5.92 300
5/27/2009 28 23.7 2000 machine stalled a few times while mixing
1900
6/1/2009 33 19.4 2200
900 212 6.05 280
6/10/2009 37 19.7 2200 960 236
6/12/2009
6.27
250900 210
210
6.23
6/2/2009 35
5/30/2009 32 23.9
1020 230
6/1/2009 34 24.1 2200
19.6 2500
6/3/2009 36 24.6 2000 870 250
320
6.4 260
290
6.12
GEOSIERRA ENVIRONMENTAL, INC. Table 6 Summary of Gel QA-QC Testing
Table 6. Summary of Gel QA/QC Testing. Hookston Station ZVI PRB. Pleasant Hill, California Page 4 of 4
Gel Viscocity (cP) Shear Rate (sec-1)
1 10 100 Batch Size/Remarks
Gel Resistivity (ohms-cm)
Date Gel pHGel
Batch No.
Temperature (oC)
213 6.35 310
6/14/2009 41 22.2 1900
6/12/2009 40 24.8 1900
870 208 5.87 280
870
6/15/2009 42 21.3 2700 1300 221 5.85 330
21 2500 5.6 3501000 227 2000 gal batch-30 pds of salt 1200 ml of acid
6/24/2009 44 23.1 2400 940 212 5.85
6/17/2009 43
225 6.23 /6/24/2009 45 21.4 2800
/ 1000 gal no salt
620 only 30 lbs of salt
no salt!
5.86
1000
6/25/2009 46 24.2 3000 1400 250
GEOSIERRA ENVIRONMENTAL, INC. Table 6 Summary of Gel QA-QC Testing
Table 7. Summary of Hydraulic Pulse Interference Test Results. Hookston Station ZVI PRB. Pleasant Hill, California. G205001
Test Location
Hydraulic Conductivity
(ft/day)
Hydraulic Conductivity
(cm/sec)Storativity
(1/ft)
Hydraulic Conductivity
(ft/day)
Hydraulic Conductivity
(cm/sec)Storativity
(1/ft)
Percent Change Pre -
Post
Pulse Test Data SummaryShallow Well PairsSource Well MW31A; Receiver Well MW30A 11.5 4.06E-03 1.17E-04 15.3 5.40E-03 1.17E-04 33%Source Well MW33A; Receiver Well MW32A 0.615 2.17E-04 1.43E-05 1.09 3.85E-04 1.43E-05 77%Shallow Wells Average Conductivity 6.06 2.14E-03 6.57E-05 8.20 2.89E-03 6.57E-05 35%Shallow Wells Geometric Mean Conductivity 2.66 9.38E-04 4.09E-05 4.08 1.44E-03 4.09E-05 54%Shallow Wells Standard Deviation from Mean 7.70 2.72E-03 7.26E-05 10.05 3.54E-03 7.26E-05 31%
Deep Well PairsSource Well MW31A2; Receiver Well MW30A2 10.5 3.70E-03 2.17E-04 10.9 3.85E-03 2.17E-04 4%Source Well MW33A2; Receiver Well MW32A2 65.3 2.30E-02 2.04E-04 64.2 2.26E-02 2.04E-04 -2%Deep Wells Average Conductivity 37.90 1.34E-02 2.11E-04 37.55 1.32E-02 2.11E-04 -1%Deep Wells Geometric Mean Conductivity 26.18 9.24E-03 2.10E-04 26.45 9.33E-03 2.10E-04 1%Deep Wells Standard Deviation from Mean 38.75 1.37E-02 9.19E-06 37.69 1.33E-02 9.19E-06 -3%
Combined Well PairsSource Well MW31A; Receiver Well MW30A2 32.9 1.16E-02 7.08E-05 50.3 1.77E-02 7.08E-05 53%Source Well MW31A2; Receiver Well MW30A 22.9 8.08E-03 2.23E-04 19.0 6.70E-03 2.23E-04 -17%Source Well MW33A; Receiver Well MW32A2 16.5 5.82E-03 3.17E-05 24.8 8.75E-03 3.17E-05 50%Source Well MW33A2; Receiver Well MW32A 54.8 1.93E-02 3.26E-05 52.3 1.85E-02 3.26E-05 -5%Combined Wells Average Conductivity 31.78 1.12E-02 8.95E-05 36.60 1.29E-02 8.95E-05 15%Combined Wells Geometric Mean Conductivity 28.73 1.01E-02 6.36E-05 33.37 1.18E-02 6.36E-05 16%Combined Wells Standard Deviation from Mean 16.77 5.92E-03 9.08E-05 17.16 6.05E-03 9.08E-05 2%
Pre-PRB Installation Hydraulic Pulse Intereference Testing
Post-PRB Installation Hydraulic Pulse Intereference Testing
GEOSIERRA ENVIRONMENTAL, INC. Table 7 - Pre - Post HPIT Results Summary
Hookston Station Final Report
Pleasant Hill, California
GEOSIERRA ENVIRONMENTAL, INC. 30 Final Construction Report - Sept 2009
FIGURES
CLIENT/PROJECT
TITLE
DRAWN
CHECKED
REVIEWED
DATE
SCALE
FILE NO.
JOB NO.
DWG. NO.
SUBTITLE
REV. NO.
FIGURE NO.
HOOKSTON STATION SITE LOCATION MAP
MAT 8/23/08 G1533
1Figure 1
Pleasant Hill
Medford, NJAtlanta, GA
HOOKSTON STATIONPLEASANT HILL, CALIFORNIA
JGO
Site
N
Ground Surface
Low VoltageExcitation
High ResistiveSoil Medium
ConductiveFrac Fluid
Record In PhaseInduced Voltage
Down HoleReceivers
Surface Pins
-20
0
Z
X
Y
.25
.50
.375
60
20
40
20
0
-20
-40
-60
Multiple Vertical Fractures
Down Hole Induced Voltagesdue to Energized Fractures
TITLE
CLIENT/PROJECT DRAWN DATE
SCALE
FILE NO.
JOB NO.
DWG NO.
SUBTITLE FIGURE NO.
REV. NO.CHECKED
REVIEWED
MAT
NTS
4
TYPICAL MONITORING SYSTEM LAYOUT
HOOKSTON STATIONPLEASANT HILL, CALIFORNIA
Figure 3.cdr
8/23/09 G205001
JGO
Medford, NJ
Atlanta, GA