Post on 23-Feb-2022
Genesis of the Rosebery massive sulphide deposit, western Tasmania, Australia.
(Volume 2 - Appendices)
by
Neil K. Martin (BSc. Hons.)
Submitted in fulfilment of the requirements for the degree of Doctor of Philosophy
UNIVERSITY OF TASMANIA
September, 2004
Declaration
This thesis contains no material that has been accepted for a degree or diploma by the
University or any other institution, except by way of background information and duly
acknowledged in the thesis, and to the best of the candidate’s knowledge and belief, contains
no material previously published or written by another person, except where due
acknowledgement is made in the text of the thesis.
Neil K. Martin
Date:
Confidentiality
This thesis is not to be made available for loan or copying for two years following the date this
statement was signed. Following that time, the thesis may be made available for loan and
limited copying in accordance with the Copyright Act 1969.
Neil K. Martin
Date:
Contents
Appendix 1. Sample Catalogue 1 Appendix 2. Whole Rock Analyses 8 Appendix 3. Microprobe Analyses - Silicates 14 Appendix 4. Microprobe Analyses - Sulphides 18 Appendix 5. LA-ICP-MS Analyses - Sulphides 51 Appendix 6. Sulphur Isotope Analyses 87 Appendix 7. Geological Logs 92 Appendix 8. Specific New Data Collected & Presented 125
Appendix 1: Sample Catalogue
2
1535
53
B
V-0
020
R64
12
6
3.5
cor
e
ore
sem
i-mas
s. s
p-ga
ore
R
,1TS
15
3554
BV
-007
8
R
6460
69
c
ore
o
re
m
ass.
sp-
ga o
re
R,1
TS
1535
55
B
V-0
127
R65
29
9
1.2
cor
e
ore
dk ta
n sp
-py
R
,1TS
15
3556
BV
-016
6
R
7042
16.
7
c
ore
f
w
f
inel
y ba
nded
and
dis
s. p
y an
d sp
R
1535
57
B
V-0
167
R70
42
1
7.6
cor
e
ore
sem
i-mas
s. o
re, c
oars
e, b
lebb
y py
in c
l-sch
ist,
min
or g
a-cp
y
R
15
3558
BV
-016
8
R
7042
18.
3
c
ore
o
re
m
ass.
hon
ey-b
row
n sp
-ga
ore
R
1535
59
B
V-0
169
R70
42
1
9.1
cor
e
ba
mas
s. b
a w
ith s
p-ga
-py
R
15
3560
BV
-017
1
R
7042
19.
5
c
ore
t
sv
fg
sem
i-mas
s. p
y an
d al
tere
d se
dim
ent
R
15
3561
BV
-017
3
R
7042
20.
2
c
ore
o
re
m
ass.
sp-
ga w
ith b
a cl
ast
R
1535
62
B
V-0
175
R70
42
2
0.8
cor
e
sill
alte
red
sedi
men
t with
som
e ba
nds
sp, p
ossi
ble
porp
hyry
sill
R
15
3563
BV
-018
4
R
7044
21.
1
c
ore
o
re
m
ass.
hon
ey-b
row
n to
ora
nge
sp a
nd b
a
R
,1TS
15
3564
BV
-021
0
R
7046
25.
5
c
ore
o
re
m
ass.
fine
-gra
ined
lam
inat
ed p
y w
ith m
inor
sp
R,1
TS
1535
65
B
V-0
219
R69
53
1
3.5
cor
e
ore
mas
s. s
p-ga
-py
R
,1TS
15
3566
BV
-022
0
R
6953
14.
5
c
ore
o
re
m
ass.
sp-
ga
R,1
TS
1535
67
B
V-0
223
R69
53
1
8.3
cor
e
ore
mas
s. p
y-sp
R
1535
68
B
V-0
226
R69
53
2
2
cor
e
ore
mas
s. b
ande
d sp
-py
R
,1TS
15
3569
BV
-022
7
R
6953
24
c
ore
o
re
m
ass.
py,
min
or s
p
1535
70
C
00-0
079
1
23R
14
55.8
c
ore
o
re
m
ass.
hon
ey-b
row
n sp
-py-
cpy-
ga o
re w
ith "c
last
ic" t
extu
re
R
,PB
15
3571
C00
-008
2
123
R
1469
.5
cor
e
fw
si-s
e-cb
aug
en s
chis
t, di
ss. p
y
R
,PB
15
3572
C00
-008
7
123
R
1500
.9
cor
e
fw
se-
qz a
ugen
sch
ist w
ith c
l pse
udof
iam
me
R,1
TS
1535
73
C
00-0
091
1
32R
-D2
11
07
c
ore
h
w
dk
gre
y cl
alte
red,
fp c
ryst
al-r
ich
sand
ston
e
R,P
D,C
R,1
TS,X
RF
glas
s 15
3574
C00
-009
2
132
R-D
2
1131
.5
cor
e
hw
dk g
rey
cl a
ltere
d, fp
cry
stal
-ric
h sa
ndst
one,
late
cl v
einl
ets
R
,PD
,CR
,XR
F gl
ass
1535
75
C
00-0
098
1
32R
-D2
12
52.5
c
ore
s
ill
dk
gre
y se
-si a
ltere
d, q
z-fp
por
phyr
y si
ll, m
inor
cla
stic
xen
olith
s, m
inor
py
R,1
TS
1535
76
C
00-0
124
1
32R
-D2
13
89.4
c
ore
f
w
m
ass.
rhod
ochr
osite
+ c
l sch
ist w
ith re
lict f
p
R
1535
77
C
00-0
134
8
4R
82
8.4
c
ore
t
sv
fg
si-a
ltere
d sa
ndst
one/
schi
st +
ba-
min
or p
y
R,1
TS
1535
78
C
00-0
139
8
7R
61
9.8
c
ore
h
w
po
lym
ict b
recc
ia, m
ass
flow
uni
t, am
ygda
loid
al m
afic
cla
st
R
,1TS
15
3579
C00
-014
3
87R
770.
1
cor
e
tsv
pum
iceo
us fp
san
dsto
ne +
sha
le in
tracl
asts
, qua
rtz d
eriv
ed fr
om p
orph
yry
sill
R,P
D,C
R,X
RF
glas
s 15
3580
C00
-014
4
87R
772.
2
cor
e
tsv
pum
iceo
us fp
san
dsto
ne, q
uartz
der
ived
from
por
phyr
y si
ll
R,P
D,X
RF
glas
s 15
3581
C00
-015
6
R55
81-D
2 69
8.4
c
ore
t
sv
si
-se
alte
red,
fg fe
ldsp
athi
c sa
ndst
one,
min
or d
iss.
py
R,1
TS
1535
82
C
00-0
184
R
6760
135
.7
co
re
ts
v
st
ratif
ied
si-s
e al
tere
d se
dim
ent,
fp c
ryst
als
to 3
mm
R
,1TS
15
3583
C00
-020
8
127
R
1523
.2
cor
e
tsv
fg s
e-cl
-cb-
si s
chis
t, m
inor
dis
s. p
y-sp
R,P
D,C
R,X
RF
glas
s 15
3584
C00
-021
1
127
R
1505
.9
cor
e
tsv
mas
s. b
lack
cl-m
agne
tite-
cb +
sp-
py-g
a (D
ev. m
etas
.)
R
,1TS
,PB
1535
85
C
00-0
220
1
27R
14
55
c
ore
t
sv
se
-si a
ltere
d, fg
fp-c
ryst
al s
ands
tone
, nor
mal
ly g
rade
d
R
,1TS
15
3586
C00
-022
3
127
R
1394
.8
cor
e
tsv
si-s
e al
tere
d, d
iffus
ely
stra
tifie
d fg
feld
spat
hic
sand
ston
e
R
,1TS
15
3587
C00
-024
7
121
R
1327
.6
cor
e
fw
cl-s
e sc
hist
, pos
sibl
y fg
top
dact
itic
debr
is fl
ow u
nit
R
,1TS
15
3588
C00
-026
1
121
R-D
1
1282
.2
cor
e
tsv
fine
py re
plac
emen
t? o
f sed
imen
t bel
ow s
ill
R,1
TS,P
B 15
3589
C00
-027
8
R64
11
9
1.8
cor
e
tsv
grey
si-s
e sc
hist
, py
+ m
inor
sp
lens
es p
aral
lel t
o fo
liatio
n
R
,PD
,1TS
,PB
,XR
F gl
ass
Uni
v. T
as.
fie
ld id
.
hole
id.
de
pth
sa
mpl
e un
it
sam
ple
desc
riptio
n
c
atal
ogue
d m
ater
ials
ca
talo
gue
(m)
type
Appendix 1: Sample Catalogue
3
1535
90
C
00-0
280
R
6411
96.
3
c
ore
t
sv
si
-se
schi
st, f
g di
ss. p
y, m
inor
dk
tan
sp a
long
folia
tion
R
,PD
,1TS
,PB
,XR
F gl
ass
1535
91
C
00-0
283
R
6411
104
.2
co
re
or
e
dk
tan
sp-g
a-py
with
cg
text
ure,
min
or b
a cl
asts
R
15
3592
C00
-028
4
R64
11
1
06.4
core
ore
d
k re
d-br
own
sp-p
y, c
ore
very
bro
ken
R,P
D,P
B,X
RF
glas
s 15
3593
C00
-028
5
R65
29
8
7.6
cor
e
tsv
cl-s
e sc
hist
,cb
bleb
s, ta
n sp
as
wis
py le
nses
par
alle
l fol
iatio
n
R
,PD
,1TS
,PB
,XR
F gl
ass
1535
94
C
00-0
287
R
6529
90.
8
c
ore
o
re
dk
tan
sp-p
y-ga
, ser
iciti
c cl
asts
R,P
D,1
TS,P
B,X
RF
glas
s 15
3595
C00
-029
0
R65
29
9
9.5
cor
e
ore
mas
s. fg
pal
e ta
n sp
-ga
(+ b
a) +
late
r pat
chy
cpy-
py
R,P
D,1
TS,P
B,X
RF
glas
s 15
3596
C00
-029
2
R65
87
2
6
cor
e
fw
si-s
e sc
hist
, dk
red-
brow
n sp
in la
te s
yn- t
o po
st-d
efor
mat
ion
qz-c
b ve
in
R,P
D,1
TS,P
B,X
RF
glas
s 15
3597
C00
-029
7
R65
87
7
1.1
cor
e
ore
qz-s
e sc
hist
- pa
tchy
/blo
tchy
dis
s. to
mas
s. ta
n sp
-ga-
py, m
inor
cpy
R
,PD
,1TS
,PB
,XR
F gl
ass
1535
98
C
00-0
299
R
6587
77.
2
c
ore
o
re
m
ass.
fg p
ale
tan
sp-g
a +
ba v
einl
ets
R,P
D,1
TS,P
B,X
RF
glas
s 15
3599
C00
-030
1
R65
87
8
2.8
cor
e
ore
sem
i-mas
s. s
ulph
ide,
si-s
e sc
hist
, pat
chy/
blot
chy
tan
and
crea
m s
p-ga
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
00
C
00-0
306
R
6592
78.
6
c
ore
o
re
se
mi-m
ass.
/dis
s. s
ulph
ide,
si-s
e sc
hist
, pat
chy/
blot
chy
pale
to ta
n sp
-ga
R,P
D,1
TS,P
B,X
RF
glas
s 15
3601
C00
-030
7
R65
92
8
2.7
cor
e
ore
sem
i-mas
s./d
iss.
sul
phid
e, s
i-se
schi
st, p
atch
y/bl
otch
y ta
n sp
-ga
R,P
D,1
TS,P
B,X
RF
glas
s 15
3602
C00
-031
7
R65
93
5
9.6
cor
e
ore
mas
s. s
ulph
ide,
si-s
e sc
hist
, tan
sp-
ga w
ith p
y ed
ges
R,P
D,1
TS,P
B,X
RF
glas
s 15
3603
C00
-032
0
R64
26
7
7.4
cor
e
fw
se-
si s
chis
t, di
ss. p
y
R,P
D,1
TS,P
B,X
RF
glas
s 15
3604
C00
-032
3
R64
26
9
3
cor
e
fw
si-s
e sc
hist
, tan
sp-
ga a
s w
ispy
dis
sem
inat
ions
par
alle
l fol
iatio
n
R,P
D,1
TS,P
B,X
RF
glas
s 15
3605
C00
-032
6
R64
26
1
05.9
core
ore
m
ass.
dk
tan
sp-g
a-py
R,P
D,1
TS,P
B,X
RF
glas
s 15
3606
C00
-032
9
R64
26
1
13.3
core
ore
m
ass.
fine
ly la
min
ated
sul
phid
e, s
i bre
ccia
with
mas
s. s
ulph
ide
mat
rix, d
k ta
n sp
-ga
R,P
D,2
TS,P
B,X
RF
glas
s 15
3607
C00
-033
2
R64
26
1
25
core
ore
m
ass.
ban
ded
red-
brow
n sp
-ga-
py +
ban
d m
ass.
py,
cla
sts
si-s
e-cl
sch
ist/b
recc
ia
R
15
3608
C00
-033
3
R64
64
8
9.8
cor
e
tsv
fg c
l-se-
si s
chis
t, di
ss. t
an s
p-ga
as
wis
py d
isse
min
atio
ns p
aral
lel f
olia
tion
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
09
C
00-0
337
R
6464
104
.1
co
re
or
e
mas
s. s
ulph
ide,
tan
sp-g
a
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
10
C
00-0
338
R
6464
109
co
re
or
e
mas
s. s
p-py
-ga
with
se-
si a
ltere
d se
dim
ent m
ass.
py
R,1
TS
1536
11
C
00-0
341
R
6464
111
.8
co
re
or
e
mas
s. s
ulph
ide,
fg ta
n sp
-ga-
py, w
ith la
te p
y ve
in/b
and
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
12
C
00-0
343
R
6926
118
.7
co
re
or
e
cl-s
e-si
sch
ist,
diss
. to
sem
i-mas
s.dk
red-
brow
n sp
-py-
ga
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
13
C
00-0
345
R
6926
123
.6
co
re
or
e
mas
s. s
ulph
ide,
late
qz
vein
, tan
sp-
ga-p
y
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
14
C
00-0
346
R
6926
128
.2
co
re
ts
v
py
ritic
she
ar in
qz-
fp p
orph
yry
R,P
D,C
R,X
RF
glas
s 15
3615
C00
-035
0
R69
21
1
32
core
ore
b
ande
d se
mi-m
ass.
ligh
t tan
sp-
ga-p
y, fg
cl-s
e-si
sch
ist
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
16
C
00-0
351
R
6921
135
.4
co
re
ba
mas
s. b
ande
d fg
ba,
min
or s
ulph
ides
R
15
3617
C00
-035
3
R70
13
1
64.6
core
ore
d
iss.
to s
emi-m
ass.
py,
min
or s
p-ga
, si-s
e sc
hist
, cb
bleb
s
R,P
D,1
TS,P
B,X
RF
glas
s 15
3618
C00
-035
5
R64
76
9
0.4
cor
e
fw
si-s
e au
gen
schi
st, 2
% d
iss.
py
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
19
C
00-0
357
R
6476
98.
4
c
ore
f
w
s
i-se
auge
n sc
hist
, min
or ta
n sp
vei
nlet
s, c
l-qz-
cb+p
y-cp
y-ga
-sp
vein
lets
, min
or d
iss.
py
R,P
D,1
TS,P
B,XR
F gl
ass
1536
20
C
00-0
359
R
6476
107
co
re
or
e
mas
s. p
ale
hone
y sp
-ga
with
min
or s
ilice
ous
patc
hes
(qz
vein
or c
last
)
R,P
D,1
TS,P
B,X
RF
glas
s 15
3621
C00
-036
2
R64
76
1
15.3
core
ore
m
ass.
sul
phid
es c
ut b
y qz
-cb
vein
s, a
ll or
ange
sp-
ga-p
y
R,P
D,1
TS,P
B,X
RF
glas
s 15
3622
C00
-036
3
R64
76
1
18
core
ore
m
ass.
sp-
ga, p
y ba
nd re
plac
ing
sp-g
a or
e (c
onta
ins
sp-g
a in
clus
ion)
R
,2TS
15
3623
C00
-036
4
R64
76
1
20.8
core
ore
m
ass.
fg ta
n sp
-py-
ga, t
r cpy
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
24
C
00-0
365
R
6476
123
.2
co
re
or
e
mas
s. "c
ooke
d" re
d br
own
sp-g
a an
d py
, min
or c
last
s si
-alte
red
sedi
men
t
R,P
D,1
TS,P
B,X
RF
glas
s 15
3625
C00
-036
6
R64
76
1
24.8
core
sill
blac
k si
licifi
ed p
orph
yry
sill,
late
dk
red-
brow
n sp
-py-
ga a
nd q
z-cb
vei
nlet
s,
R
1536
26
C
00-0
369
R
6476
135
.9
co
re
si
ll
si
-se
qz-fp
-por
phyr
y si
ll cu
t by
qz-c
b+(s
p-ga
-py
) vei
ns +
tan
sp-g
a-py
vei
ns
R,P
D,1
TS,P
B,X
RF
glas
s
Uni
v. T
as.
fie
ld id
.
hole
id.
de
pth
sa
mpl
e un
it
sam
ple
desc
riptio
n
c
atal
ogue
d m
ater
ials
ca
talo
gue
(m)
type
Appendix 1: Sample Catalogue
4
1536
27
C
00-0
371
R
5802
90
c
ore
f
w
s
e-si
aug
en s
chis
t
R
,1TS
,PB
1536
28
C
00-0
372
R
5802
108
.5
co
re
ts
v
cl
-se
alte
red
sand
ston
e/sh
ale
(with
in p
eper
itic
porp
hyry
?), f
g di
ss. p
y
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
29
C
00-0
374
R
5802
175
.6
co
re
ts
v
ba
nded
bar
itic
sand
ston
e/m
ass.
ba,
fp c
ompo
nent
, ove
rlies
sill,
min
or p
y
R
,1TS
15
3630
C00
-037
5
R58
02
1
76.2
core
tsv
band
ed b
a cu
t by
red/
met
allic
pyr
agyr
ite v
ein
R,1
TS
1536
31
C
00-0
378
1
31R
12
59.1
c
ore
t
sv
fg
si-s
e sc
hist
, min
or d
iss.
tan
sp-g
a-py
R,P
D,1
TS,P
B,X
RF
glas
s 15
3632
C00
-037
9
R68
47
1
cor
e
tsv
dk g
reen
cl-s
e sc
hist
, ban
d of
red-
brow
n sp
-py,
10%
dis
s. p
y in
sch
ist
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
33
C
00-0
381
R
6847
6.7
c
ore
t
sv
br
ecci
ated
se-
si s
chis
t, m
atrix
mas
s. ta
n/re
d br
own
sp-g
a-py
, ear
ly?
cg g
a-sp
-py-
cpy R
,PD
,1TS
,PB
,XR
F gl
ass
1536
34
C
00-0
383
R
6847
12.
3
c
ore
o
re
fg
ban
ded
mas
s. ta
n sp
-py-
ga
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
35
C
00-0
385
R
6847
17.
6
c
ore
o
re
fg
diff
usel
y ba
nded
- m
ass.
tan
sp-g
a-py
R
,PD
,1TS
,PB
,XR
F gl
ass
1536
36
C
01-0
397
R
5192
-D1
631.
7
cor
e
ore
mas
s. b
ande
d ta
n sp
-min
or g
a-py
-cpy
, cla
stic
fp c
ompo
nent
R
,1TS
15
3637
C01
-040
0
R51
92-D
1 64
9
c
ore
b
a
m
ass.
ban
ded
ba, m
inor
py-
se
R
,1TS
15
3638
C01
-041
2
R59
75
2
01.9
core
tsv
ba v
ein/
band
with
sp-
ga s
elva
ges
in s
ilici
fied
shal
e/ch
ert
R,1
TS
1536
39
C
01-0
422
R
6298
74.
9
c
ore
o
re
m
ass.
fg p
y in
si-s
e sc
hist
R,1
TS
1536
40
C
01-0
423
R
6298
78.
8
c
ore
o
re
m
ass.
fg p
y w
ith w
hite
cb
fleck
s, re
lict p
orph
yriti
c te
xtur
e?
R
,1TS
15
3641
C01
-042
8
R62
97
7
3.3
cor
e
fw
fg
pale
blu
e-gr
een
se-c
l-si s
chis
t, m
g/cg
san
dsto
ne
R,P
D,C
R,1
TS,X
RF
glas
s 15
3642
C01
-044
3
R60
11
3
62
core
ore
d
k ta
n sp
-ga-
py w
ith s
i-se
and
ba c
last
s, lo
oks
high
ly fo
liate
d
R
,1TS
15
3643
C01
-046
5
R72
51
3
6
cor
e
ore
collo
form
py
vei
n in
of s
i-alte
red
sedi
men
ts w
ith o
rang
e sp
-py
ore
R
,1TS
15
3644
C01
-047
7
R62
17
1
13.2
core
tsv
se-s
i sch
ist,
mg/
cg c
last
ic s
ands
tone
with
qz,
inte
rest
ing
py te
xtur
es
R,1
TS
1536
45
C
01-0
495
R
5192
379
.3
co
re
fw
fg
se-s
i sch
ist w
ith c
b bl
ebs,
trac
e di
ss. p
y-ga
R,2
TS
1536
46
C
01-0
506
R
6335
247
.9
co
re
fw
blu
e-gr
ey, f
g se
-si s
chis
t
R,P
D,C
R,X
RF
glas
s 15
3647
C01
-050
8
R63
35
2
72.2
core
fw
s
e-si
sch
ist,
py v
ein
and
trace
sp
R
,PD
,XR
F gl
ass
1536
48
C
01-0
509
R
6335
303
.3
co
re
fw
se-
si s
chis
t/fp
xsta
l san
dsto
ne
R
,PD
,CR
,XR
F gl
ass
1536
49
C
01-0
532
R
6203
-D1
402
cor
e
fw
blu
e-gr
een
se-s
i-cl s
chis
t, m
inor
cpy
-py
in q
z-cl
vei
nlet
s
R,P
D,C
R,X
RF
glas
s 15
3650
C01
-054
7
R53
84
1
91.4
core
ore
m
ass.
ban
ded
py-s
p w
ith re
lict c
last
ic fp
R
,1TS
15
3651
C01
-054
8
R53
84
2
06.6
core
TSV
m
ass.
ba
vein
, int
ense
cb-
se-s
i alte
red
base
of t
urbi
dite
uni
t
R
,1TS
15
3652
C01
-054
9
R53
84
2
45.5
core
ba
m
ass.
ban
ded
ba, m
inor
pal
e sp
-ga,
R
15
3653
C01
-055
0
R53
84
2
54.6
core
ba
b
ande
d su
gary
ba,
min
or g
a-sp
R
1536
54
C
01-0
556
R
5827
227
.5
co
re
ba
mas
s. m
ottle
d ba
+ p
ale
sp-g
a w
ith s
e sc
hist
frag
men
ts (b
recc
ia)
R,2
TS
1536
55
C
01-0
557
R
5827
241
.7
co
re
ba
ban
ded
ba, m
inor
sp-
ga
R,1
TS
1536
56
C
01-0
558
R
5827
289
co
re
ba
mot
tled
ba o
re a
nd s
e sc
hist
(bre
ccia
), pa
le s
p-ga
R
1536
57
C
01-0
561
R
5827
657
.4
co
re
or
e
cl s
chis
t with
sul
phid
e st
ockw
ork,
cpy
-py-
po (D
ev. m
etas
.)
R
,1TS
15
3658
C01
-057
0
R68
03
5
0.5
cor
e
ore
mas
s. p
y-sp
-ga,
min
or b
a cl
asts
, lam
inat
ed +
fp g
rain
s
R
1536
59
C
01-0
574
R
6804
81.
3
c
ore
t
sv
lt
grey
si s
chis
t/che
rt, p
re-d
efor
mat
ion?
dk
grey
qz
vein
s
R
,PD
,1TS
,XR
F gl
ass
1536
60
C
01-0
575
R
6804
75.
5
c
ore
o
re
se
-si c
last
s? in
mas
s. p
ale
sp-g
a-py
+ fp
gra
ins
R
,1TS
15
3661
C01
-057
8
R68
04
6
7.7
cor
e
ore
fg la
min
ated
se
schi
st, p
ale
sp-g
a-py
with
si-s
e cl
asts
?
R
1536
62
C
01-0
579
R
6804
57.
7
c
ore
t
sv
se
-si s
chis
t afte
r mg
feld
spat
hic
sand
ston
e, tr
ace
fg d
iss.
py
R,P
D,C
R,X
RF
glas
s 15
3663
C01
-058
0
R68
04
4
7.5
cor
e
ore
mas
s. p
ale
sp-g
a-py
, min
or s
e-si
cla
sts,
gre
y fp
gra
ins
R
Uni
v. T
as.
fie
ld id
.
hole
id.
de
pth
sa
mpl
e un
it
sam
ple
desc
riptio
n
c
atal
ogue
d m
ater
ials
ca
talo
gue
(m)
type
Appendix 1: Sample Catalogue
5
1536
64
C
01-0
581
R
6804
40.
4
c
ore
t
sv
gr
ey s
e-si
-(cl
) sch
ist,
diss
. pal
e sp
-ga-
py
R,P
D,C
R,X
RF
glas
s 15
3665
C01
-058
2
R68
05
6
9.5
cor
e
ore
sem
i-mas
s. p
y-sp
-ga
in s
i-se
schi
st &
qz-
cb v
eins
R
1536
66
C
01-0
586
R
6805
31.
2
c
ore
o
re
se
mi-m
ass.
/dis
s. p
y-ta
n sp
-ga
in c
l-se
schi
st
R
1536
67
C
01-0
587
R
6805
5.4
c
ore
f
w
s
e-si
-(cl)
auge
n sc
hist
, lar
ge a
spy
crys
tal
R,P
D,C
R,X
RF
glas
s 15
3668
C01
-058
8
R68
04
2
6.9
cor
e
tsv
grey
si s
chis
t, dk
gre
y pr
e-de
form
atio
n? q
z ve
ins,
dis
s. p
y
R
,PD
,CR
,XR
F gl
ass
1536
69
C
01-0
589
R
6804
20.
2
c
ore
t
sv
lt
grey
si-s
e sc
hist
with
vei
ns/b
ands
ba
and
tan
sp-g
a-py
R
,PD
,CR
,XR
F gl
ass
1536
70
C
01-0
592
R
6806
56.
9
c
ore
o
re
m
ass.
tan
sp-g
a-py
ore
, diff
use
lam
inat
ions
R
15
3671
C01
-059
4
R68
06
4
3.8
cor
e
ore
mas
s. ta
n sp
-py-
ga w
ith fp
gra
ins
R,1
TS
1536
72
C
01-0
596
R
6806
34.
6
c
ore
o
re
m
ass.
tan
sp-p
y-ga
, diff
use
lam
inat
ions
R
15
3673
C01
-059
7
R68
06
2
9
cor
e
ore
sem
i-mas
s.-m
ass.
py
(+ta
n sp
-ga)
in c
l-se
schi
st
R
1536
74
C
01-0
600
R
6889
19.
4
c
ore
t
sv
si
-se
schi
st, d
iss.
sp-
ga-p
y
R
,PD
,XR
F gl
ass
1536
75
C
01-0
645
R
6902
104
co
re
ts
v
fg
ligh
t gre
en q
z-ph
yric
san
dsto
ne s
e-cl
alte
red
R
,PD
,CR
,XR
F gl
ass
1536
76
C
01-0
651
R
6901
64.
3
c
ore
f
w
d
k gr
ey-b
lack
cl-s
e-si
sch
ist &
~10
% p
y
R,1
TS
1536
77
C
01-0
656
R
6901
83.
7
c
ore
o
re
m
ass.
tan
sp-g
a-py
R
1536
78
C
01-0
658
R
6901
89.
2
c
ore
t
sv
m
ass.
fg p
y ve
in in
mas
s. c
b
R,1
TS
1536
79
C
01-0
662
R
6901
115
.1
co
re
ba
mas
s. b
ande
d ba
R
15
3680
C01
-066
3
R69
01
1
20.7
core
ore
m
ass.
py
vein
, min
or w
hite
ba
R
1536
81
C
01-0
665
R
6901
131
.6
co
re
ts
v
pa
le g
reen
fg q
z ph
yric
sed
imen
t
R
,PD
,CR
,1TS
,XR
F gl
ass
1536
82
C
01-0
698
R
5387
15.
9
c
ore
f
w
s
e-si
aug
en s
chis
t with
cl p
seud
ofia
mm
e
R
,PD
,CR
,XR
F gl
ass
1536
83
C
01-0
699
R
5387
77.
3
c
ore
f
w
b
lue-
grey
se-
si s
chis
t with
Fe-
Mn
cb fl
ecks
afte
r fp
R
,PD
,CR
,XR
F gl
ass
1536
84
C
01-0
700
R
5387
106
co
re
fw
fg
blue
-gre
y se
-si-(
cl) s
chis
t with
stro
ng fo
liatio
n
R,P
D,C
R,X
RF
glas
s 15
3685
C01
-070
2
R53
87
1
30.9
core
fw
d
k gr
ey s
e-cl
-si s
chis
t
R
,PD
,CR
,XR
F gl
ass
1536
86
C
01-0
705
R
5387
155
.7
co
re
fw
mot
tled
grey
se-
si s
chis
t with
bar
itic
vein
lets
/sto
ckw
ork
R
,1TS
15
3687
C01
-070
7
R53
87
1
57.9
core
ba
m
ass.
ban
ded
py-b
a
R
1536
88
C
01-0
713
R
5824
255
.9
co
re
fw
fg
grey
se-
si s
chis
t with
cb/
se fl
ecks
afte
r fp,
trac
e fg
dis
s. p
y
R
,PD
,CR
,XR
F gl
ass
1536
89
C
01-0
717
R
5824
317
.1
co
re
fw
mas
s. p
y, m
inor
sp-
ga w
ith d
k gr
ey fp
in s
i-alte
red
schi
st
R,1
TS
1536
90
C
01-0
718
R
5824
318
.3
co
re
fw
mas
s. p
y ve
ins
in s
i sch
ist (
collo
form
?)
R
,1TS
15
3691
C01
-072
0
R58
24
3
24.7
core
ore
m
ass.
py,
min
or s
p-ga
R
1536
92
C
01-0
724
R
5824
340
.7
co
re
ba
mas
s. b
ande
d ba
min
or s
p-ga
-py
+ la
ter p
y ve
in
R
1536
93
C
01-0
740
R
5824
494
.6
co
re
ts
v
fg
se-
si s
chis
t with
pre
-def
orm
atio
n qz
-py
vein
R,1
TS
1536
94
C
01-0
743
R
5824
523
.8
co
re
ts
v
fg
se-
si s
chis
t with
pre
-def
orm
atio
n qz
-py
vein
R,1
TS
1536
95
C
01-0
758
R
6052
272
.1
co
re
or
e
mas
s. ta
n sp
-ga-
py +
ba,
fp g
rain
s
R
15
3696
C01
-075
9
R60
52
2
77.9
core
ba
s
emi-m
ass.
ba
in s
e-si
sch
ist
R
1536
97
C
01-0
776
R
6055
319
.3
co
re
ts
v
dk
gre
en c
l-sch
ist +
cpy
-py
vein
lets
(Dev
. met
as.)
R,1
TS
1536
98
C
01-0
794
R
7467
35
c
ore
o
re
m
ass.
sp-
py-g
a-cp
y
R,P
B
1536
99
C
01-0
795
R
7467
41.
2
c
ore
o
re
m
ass.
py-
sp-g
a-cp
y
R,P
B
1537
00
C
01-0
797
R
7467
46.
4
c
ore
o
re
m
ass.
sp-
ga-p
y
R,P
B
Uni
v. T
as.
fie
ld id
.
hole
id.
de
pth
sa
mpl
e un
it
sam
ple
desc
riptio
n
c
atal
ogue
d m
ater
ials
ca
talo
gue
(m)
type
Appendix 1: Sample Catalogue
6
1537
01
C
01-0
799
R
7467
51.
4
c
ore
o
re
m
ass.
rem
obili
sed
sp-g
a-py
R
,PB
15
3702
C01
-080
1
R74
89
2
7.2
cor
e
fw
dis
s. p
y in
si-s
e-cl
sch
ist
R
,PB
15
3703
C01
-080
2
R74
89
2
9.5
cor
e
fw
dis
s. s
p-py
in s
i-se-
cl s
chis
t
R,P
B
1537
04
C
01-0
803
R
7489
34.
7
c
ore
o
re
m
ass.
ban
ded
py-s
p-ga
R,P
B
1537
05
C
01-0
804
R
7489
36.
7
c
ore
t
sv
m
ass.
py-
sp in
mas
s. c
b
R,P
B
1537
06
C
01-0
807
R
7489
41.
8
c
ore
o
re
m
ass.
sp-
ga-p
y
R,P
B
1537
07
C
01-0
808
R
7407
13.
4
c
ore
f
w
q
z-cb
-cl-s
ulph
ide
vein
(Dev
onia
n) in
si-s
e au
gen
schi
st
R,1
TS,P
B 15
3708
C01
-080
9
R74
07
4
6.2
cor
e
ore
mas
s. ta
n sp
-ga-
py
R
,PB
15
3709
C01
-081
0
R74
07
4
9
cor
e
ore
sem
i-mas
s. p
y-sp
-ga
in s
e-cl
sch
ist
R
,PB
15
3710
C01
-081
1
R74
07
5
3.5
cor
e
ore
mas
s. p
y-sp
-ga
R
,PB
15
3711
C01
-081
2
R74
07
5
5.8
cor
e
ore
mas
s. ta
n sp
-ga-
py in
si-c
l sch
ist
R,P
B
1537
12
C
01-0
813
R
7407
57.
7
c
ore
o
re
m
ass.
tan
sp-g
a-py
R,P
B
1537
13
C
01-0
814
R
7394
55.
8
c
ore
f
w
d
iss.
py
in s
e-si
sch
ist
R,P
B
1537
14
C
01-0
815
R
7394
60.
1
c
ore
o
re
m
ass.
red-
bn s
p-py
R,P
B
1537
15
C
01-0
817
R
7394
70.
8
c
ore
t
sv
di
ss. p
y-sp
in s
i-se
schi
st
R,P
B
1537
16
C
01-0
818
R
7394
74.
9
c
ore
o
re
m
ass.
red-
bn s
p-ga
-py
R,P
B
1537
17
C
01-0
820
R
7394
83.
1
c
ore
o
re
m
ass.
tan
sp-g
a-py
R,P
B
1537
18
C
01-0
822
R
7394
91.
1
c
ore
o
re
m
ass.
red-
bn s
p-ga
-py
R,P
B
1537
19
C
01-0
823
R
7455
51.
8
c
ore
f
w
g
rey
si-s
e sc
hist
+ d
iss.
py
R,P
B
1537
20
C
01-0
824
R
7455
70.
5
c
ore
t
sv
bl
ack
cl-s
e sc
hist
+ p
y-cp
y
R
,PB
15
3721
C01
-082
5
R74
55
8
3.7
cor
e
ore
mas
s. re
d-bn
sp-
ga-p
y
R
,PB
15
3722
C01
-082
6
R74
55
9
0.2
cor
e
ore
mas
s.dk
tan
sp-g
a-py
+ c
b bl
ebs
R,P
B
1537
23
C
01-0
828
R
7455
101
.1
co
re
or
e
m
ass.
dk ta
n sp
-py
band
ed o
re
R
,PB
15
3724
C01
-083
0
R74
55
1
11.5
core
ore
m
ass.
tan
sp-g
a-py
R,P
B
1537
25
C
01-0
832
R
7455
121
.9
co
re
or
e
mas
s. h
oney
-bn
sp-g
a-py
R
,PB
15
3726
C01
-083
3
R69
32
1
02.5
core
fw
v
eins
/dis
s. c
py-p
y-sp
in s
i-se
schi
st
R
,PB
15
3727
C01
-083
4
R69
32
1
11.4
core
ore
m
ass.
tan
sp-g
a-py
/si-s
e sc
hist
R,P
B
1537
28
C
01-0
835
R
6932
115
co
re
or
e
mas
s. ta
n sp
-ga-
py/s
i-se
schi
st -
mot
tled
R,P
B
1537
29
C
01-0
836
R
6932
120
.1
co
re
or
e
mas
s. ta
n sp
-ga-
py
R
,PB
15
3730
C01
-083
8
R69
32
1
27.3
core
ore
m
ass.
sp-
ga-p
y
R,P
B
1537
31
C
01-0
840
1
23R
14
52
c
ore
o
re
m
ass.
tan
sp-g
a-py
R,P
B
1537
32
C
01-0
841
R
6978
96.
7
c
ore
o
re
m
ass.
tan
sp-g
a-py
R,P
B
1537
33
C
01-0
842
R
6978
99.
5
c
ore
o
re
m
ass.
ba-
py (p
y ov
erpr
ints
?)
R,P
B
1537
34
C
01-0
844
R
6978
103
.3
co
re
or
e
mas
s. b
ande
d ta
n sp
-ga-
py
R
,PB
15
3735
C01
-084
6
R53
14
3
5.8
cor
e
ore
mas
s. p
y-sp
-ga-
po n
ear q
z-to
vei
n in
J-L
ens
(Dev
. met
as.)
R
,PB
15
3736
C01
-084
8
R53
14
4
1.8
cor
e
ore
mas
s. p
o-sp
-ga-
cpy-
py in
J-L
ens
(Dev
. met
as.)
R
,PB
15
3737
C01
-084
9
CP
-281
172
cor
e
-
to-s
ulph
ide
alte
red
rock
(Cha
mbe
rlain
pro
spec
t)
R,P
B
Uni
v. T
as.
fie
ld id
.
hole
id.
de
pth
sa
mpl
e un
it
sam
ple
desc
riptio
n
c
atal
ogue
d m
ater
ials
ca
talo
gue
(m)
type
Appendix 1: Sample Catalogue
7
1537
50
R
00-0
01
33K
x-c
ut -
north
face
1470
730
24
57
roc
k
or
e
ban
ded
mas
s. s
p-py
-ga,
late
py-
sp v
ein,
cl-s
e sc
hist
R
,1TS
,PB
1537
51
R
00-0
03
33K
x-c
ut -
north
face
1470
730
24
57
roc
k
or
e
ban
ded
mas
s. s
p-py
-ga,
late
py-
sp v
ein,
cl-s
e sc
hist
R
,1TS
,PB
1537
52
R
00-0
20
33K
- or
e dr
ive
14
90
7
33
2457
r
ock
ore
m
ass.
fg s
p-ga
ore
R
1537
53
R
01-0
49
31P
x-c
ut
9
72
780
25
10
roc
k
fa
ult
qz-
cb-c
py-p
y ve
ins
(faul
t) in
se-
si s
chis
t (P
6)
R
,PB
15
3754
R01
-064
39
P-P
10 o
re d
rive
1
080
1020
233
0
rock
sill
qz-p
hyric
por
phyr
y, s
hear
ed &
se-
si a
ltere
d
R,P
D,C
R,X
RF
glas
s 15
3755
R01
-065
38
P-P
10-o
re d
rive
north
109
0
10
20
2
345
ro
ck
o
re
m
ass.
py
with
fp g
rain
s &
mas
s. ta
n sp
-ga
R
,2TS
15
3756
R01
-070
M
urch
ison
Min
e
5
3765
40 3
8567
0
-
rock
ore
mas
sive
sp-
cb w
ith m
inor
cpy
(Dev
onia
n)
R
,PB
15
3757
R01
-075
S
alis
bury
pro
spec
t
5371
750
3777
40
-
rock
ore
goss
anou
s py
-si-t
o al
tere
d ro
ck
R,P
B
1537
58
R
01-0
78
Sou
th C
omet
min
e
5361
530
3710
60
-
rock
ore
mas
s. b
ande
d sp
-py
ore,
(Dev
onia
n) fi
ssur
e ho
sted
R
,PB
15
3759
R02
-081
37
P -
1020
N x
cut,
N fa
ce
10
25
1
025
2380
r
ock
ore
m
assi
ve b
ande
d sp
-ga-
py o
re P
13
R
15
3760
R02
-082
no
rther
n ex
plor
atio
n de
clin
e 1
860
900
23
60
roc
k
si
ll
qz-
fp p
orph
yry
dyke
/sill
- in
trusi
ve x
-cut
s fo
otw
all
R,P
D,C
R,X
RF
glas
s
Uni
v. T
as.
fiel
d id
. lo
catio
n
n
orth
east
R
L
sa
mpl
e u
nit
de
scrip
tion
cat
alog
ued
mat
eria
ls
cata
logu
e
typ
e
1537
38
C
02-0
852
1
12R
-D3
10
91
c
ore
f
w
s
e-si
-py
alte
red,
rhyo
litic
aph
yric
/fp-p
hyric
pep
eriti
c in
trusi
ve -
sth
end
of m
ine
R
,PD
,CR
,XR
F gl
ass
1537
39
C
02-0
854
R
7683
14
c
ore
f
w
q
z-fp
por
phyr
y un
it - x
-cut
s fo
otw
all a
nd jo
ins
K-le
ns p
orph
yry?
R
,PD
,CR
,XR
F gl
ass
1537
40
C
02-0
858
R
7128
4
c
ore
f
w
s
e-al
tere
d si
ltsto
ne -
diss
. sul
phid
e
R
1537
41
C
02-0
859
R
7128
7
c
ore
o
re
qz
-alte
red
sedi
men
t - s
emi-m
assi
ve s
ulph
ide
R
1537
42
C
02-0
860
R
7128
12
c
ore
o
re
m
ass.
pal
e sp
-ga
R
1537
43
C
02-0
861
R
7128
18
c
ore
o
re
se
-alte
red
sedi
men
t + d
iss.
sp-
ga-p
y
R
15
3744
C02
-086
2
R71
28
3
0
cor
e
tsv
qz-c
b al
tere
d qz
-fp p
orph
yry
R
15
3745
C02
-086
3
R71
28
3
5
cor
e
ore
mas
sive
ora
nge
brow
n sp
-ga
R
1537
46
C
02-0
864
R
7128
36.
5
c
ore
o
re
ba
ritic
qz-
se a
ltere
d se
dim
ent
R
1537
47
C
02-0
866
R
7128
60
c
ore
t
sv
cb
alte
red
sedi
men
t, di
ssem
inat
ed s
ulph
ide
R
15
3748
C02
-086
7
R71
28
6
7
cor
e
ore
mas
sive
pin
k cb
- sp
-ga-
py
R
15
3749
C02
-086
8
R71
28
6
8
cor
e
ore
sem
i-mas
sive
ora
nge-
brow
n sp
-ga
R
Uni
v. T
as.
fie
ld id
.
hole
id.
de
pth
sa
mpl
e un
it
sam
ple
desc
riptio
n
c
atal
ogue
d m
ater
ials
ca
talo
gue
(m)
type
Not
e: fi
eld
num
bers
util
ised
in th
e m
ain
text
hav
e be
en a
bbre
viat
ed (e
.g. C
00-2
93 =
C29
3 et
c.)
R =
rock
, PD
=pol
ishe
d re
sin
mou
nt, T
S=t
hin
sect
ion,
CR
=cru
shed
resi
due,
XR
F gl
ass=
XR
F gl
ass
disk
9
Appendix 2: Whole Rock Analyses
XR
F Si
O2
TiO
2 A
l2O
3 Fe
2O3
MnO
M
gO
CaO
N
a2O
K
2O
P2O
5 S
Ag
As
Ba
Bi
Cd
w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
) C
00-2
78
64.6
5 0.
33
15.0
0 6.
09
1.45
1.
52
0.13
<0
.1
4.79
0.
04
2.17
2
18
1205
4
8 C
00-2
80
84.9
5 0.
10
5.02
3.
84
0.03
0.
29
<0.0
2 <0
.1
1.77
<0
.01
3.37
3
42
516
9 21
C
00-2
84
15.5
1 0.
02
0.60
20
.21
0.18
0.
15
0.04
0.
2 0.
16
0.02
32
.83
56
131
50
74
703
C00
-285
50
.28
0.30
14
.21
8.19
4.
93
4.35
0.
39
<0.1
3.
54
0.06
2.
46
1 4
833
4 76
C
00-2
87
12.6
0 0.
16
3.56
17
.83
0.76
0.
24
0.26
<0
.1
1.24
0.
14
27.0
2 22
1 24
6 44
0 <4
54
1 C
00-2
90
5.86
0.
08
1.79
10
.39
0.16
0.
08
0.21
0.
2 0.
54
0.03
28
.86
265
1149
65
62
66
975
C00
-297
42
.54
0.44
12
.36
9.86
1.
14
0.86
0.
16
<0.1
4.
18
0.10
12
.58
17
430
2468
35
27
3 C
00-2
99
4.11
0.
04
0.09
5.
41
0.11
<0
.1
0.02
0.
5 0.
06
0.02
27
.07
473
562
2628
58
11
43
C00
-301
63
.54
0.48
14
.92
2.96
0.
06
0.96
0.
08
<0.1
5.
10
0.06
3.
98
65
43
4740
<3
93
C
00-3
06
63.4
8 0.
46
13.6
4 2.
90
0.06
0.
90
0.04
<0
.1
4.58
0.
04
4.58
10
5 13
9 59
12
<3
102
C00
-307
59
.64
0.28
6.
68
5.72
0.
08
0.50
0.
04
<0.1
2.
26
<0.0
1 10
.75
20
139
1583
<3
11
9 C
00-3
17
32.9
6 0.
44
10.3
8 7.
06
0.72
1.
10
1.14
0.
2 3.
66
0.08
14
.63
304
218
5336
<4
36
6 C
00-3
20
58.7
0 0.
18
8.18
17
.48
0.04
0.
42
0.06
<0
.1
2.88
0.
02
14.6
9 6
77
1680
22
1
C00
-323
65
.20
0.18
9.
06
6.72
0.
16
0.38
0.
06
<0.1
3.
06
<0.0
1 8.
22
22
15
984
67
155
C00
-326
7.
76
0.22
5.
14
15.1
0 2.
58
1.02
0.
28
0.2
1.50
0.
08
23.5
4 31
0 99
5 64
2 <4
65
6 C
00-3
29
43.6
0 0.
14
3.82
6.
84
0.10
0.
14
<0.0
2 <0
.1
1.32
<0
.01
14.6
9 52
7 59
8 44
0 <4
36
6 C
00-3
33
30.5
4 0.
46
21.7
2 14
.46
1.24
2.
92
0.14
<0
.1
5.82
0.
06
9.19
2
6 16
32
9 19
1 C
00-3
37
17.8
5 0.
04
0.68
12
.17
0.17
<0
.1
<0.0
2 0.
3 0.
25
0.02
27
.64
419
316
543
60
803
C00
-341
14
.89
0.04
0.
14
6.26
0.
22
<0.1
0.
84
0.3
0.04
0.
02
24.4
2 53
7 10
77
38
12
871
C00
-343
19
.76
0.52
14
.32
25.3
4 6.
06
0.60
0.
54
<0.1
4.
66
0.12
18
.85
21
220
2640
38
11
6 C
00-3
45
22.1
0 0.
10
2.56
16
.96
1.18
0.
64
0.10
0.
1 0.
90
<0.0
1 19
.72
952
2860
27
71
12
588
C00
-350
19
.26
0.50
13
.54
25.7
0 2.
52
1.06
0.
42
<0.1
4.
48
0.12
24
.42
71
168
5019
14
7 19
1 C
00-3
53
13.7
1 0.
26
5.87
31
.29
2.62
1.
62
4.01
0.
7 1.
58
0.02
29
.93
766
598
3965
42
15
3 C
00-3
55
76.3
1 0.
19
8.62
6.
22
0.05
0.
44
0.02
<0
.1
2.99
0.
01
4.82
4
21
1040
6
3 C
00-3
57
77.1
8 0.
11
5.95
6.
50
0.14
0.
41
0.08
<0
.1
2.11
<0
.01
5.57
29
59
12
27
60
29
C00
-359
9.
70
0.08
0.
65
11.5
2 0.
32
0.47
0.
79
0.4
0.22
0.
02
31.7
9 63
29
4 18
35
46
1183
C
00-3
62
49.3
4 0.
04
0.50
5.
80
0.22
0.
10
2.34
<0
.1
0.10
<0
.01
15.1
6 33
9 29
7 10
6 <4
23
9 C
00-3
64
1.22
0.
02
0.10
18
.81
0.22
0.
40
1.97
0.
1 0.
02
0.02
33
.44
257
1533
<4
12
9 10
18
C00
-365
24
.23
0.02
0.
21
34.4
1 0.
03
0.11
0.
16
<0.1
0.
05
0.01
32
.61
101
554
22
31
269
C00
-369
65
.52
0.28
9.
60
7.56
0.
04
0.36
0.
54
<0.1
5.
28
0.06
6.
85
37
113
2636
<3
70
C
00-3
72
42.2
4 0.
69
20.8
3 16
.11
0.07
1.
49
0.14
0.
04
7.63
0.
12
12.1
6 3
3500
29
58
<2
1 C
00-3
78
68.4
7 0.
44
14.2
3 3.
80
0.25
1.
21
0.09
<0
.1
4.60
0.
08
2.32
9
27
1811
<3
31
C
00-3
79
22.2
2 0.
50
14.7
8 26
.84
2.40
1.
60
0.28
<0
.1
4.62
0.
12
21.8
3 17
14
5 31
84
37
126
C00
-381
20
.12
0.26
8.
24
16.1
0 0.
10
0.52
<0
.02
<0.1
2.
84
0.02
23
.74
101
336
3754
<4
44
2 C
00-3
83
5.19
0.
04
0.72
8.
32
0.18
0.
13
0.24
0.
4 0.
25
0.03
28
.68
319
732
1212
23
95
9 C
00-3
85
8.67
0.
06
0.62
6.
36
0.31
0.
30
1.52
0.
2 0.
32
0.04
25
.45
703
778
1692
6 57
96
8
10
Appendix 2: Whole Rock Analyses
XR
F C
o C
u M
o N
b N
i Pb
R
b Sb
Se
Sn
Sr
Th
Tl
Y
Zn
Zr
(p
pm)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
) C
00-2
78
21
521
2 15
5
66
232
3 <2
<2
12
22
9
48
4200
26
5 C
00-2
80
92
691
2 4
1 87
2 83
2
<2
<2
4 7
8 12
95
00
79
C00
-284
61
20
00
10
<2
11
1190
0 12
32
i/P
b n.
a.
<2
<3
i/Pb
<3
3485
00
8 C
00-2
85
25
40
<1
11
1 59
17
3 5
<2
2 9
22
6 40
34
600
242
C00
-287
27
18
00
24
<2
<3
1443
00
i/Pb
291
i/Pb
n.a.
5
i/Pb
i/Pb
i/Pb
2484
00
76
C00
-290
19
24
00
72
<2
17
1575
00
i/Pb
645
i/Pb
n.a.
52
i/P
b i/P
b i/P
b 38
0000
25
C
00-2
97
29
1600
11
4
<3
2200
0 20
5 27
i/P
b n.
a.
10
14
i/Pb
i/Pb
1252
00
196
C00
-299
18
27
00
27
<2
4 21
3200
i/P
b 22
10
i/Pb
n.a.
17
i/P
b i/P
b i/P
b 42
1700
C00
-301
33
50
8 3
6 3
2140
0 20
5 83
i/P
b <2
13
17
i/P
b i/P
b 41
200
240
C00
-306
37
66
0 6
5 <3
25
700
201
353
i/Pb
<2
10
20
i/Pb
i/Pb
4760
0 21
3 C
00-3
07
59
273
8 1
6 24
800
104
33
i/Pb
n.a.
4
10
i/Pb
i/Pb
1208
00
51
C00
-317
33
40
0 22
<2
58
10
7700
i/P
b 40
5 i/P
b n.
a.
46
i/Pb
i/Pb
i/Pb
1596
00
158
C00
-320
10
2 74
00
9 7
1 36
9 15
0 5
<2
3 6
12
5 12
20
3 14
8 C
00-3
23
56
2600
12
5
4 20
00
147
8 <2
n.
a.
6 11
12
23
67
000
154
C00
-326
16
44
00
18
<2
<3
1618
00
i/Pb
401
i/Pb
n.a.
8
i/Pb
i/Pb
i/Pb
2576
00
103
C00
-329
76
92
00
10
<2
<3
1269
00
i/Pb
863
i/Pb
n.a.
<2
i/P
b i/P
b i/P
b 15
8200
71
C
00-3
33
12
2400
12
11
<3
29
9 28
8 10
<2
n.
a.
14
34
14
43
9580
0 36
5 C
00-3
37
51
1000
11
<2
13
10
9800
i/P
b 77
5 i/P
b n.
a.
<2
i/Pb
i/Pb
i/Pb
3356
00
14
C00
-341
25
36
00
50
<2
15
1737
00
i/Pb
2004
i/P
b n.
a.
19
i/Pb
i/Pb
i/Pb
3626
00
4 C
00-3
43
34
6600
14
8
<3
1800
20
5 6
<2
n.a.
16
17
12
42
53
200
231
C00
-345
50
72
00
32
1 15
41
000
40
3230
i/P
b n.
a.
4 i/P
b i/P
b i/P
b 25
9400
47
C
00-3
50
27
4600
19
6
<3
9100
20
3 16
<2
n.
a.
12
i/Pb
i/Pb
i/Pb
8780
0 21
9 C
00-3
53
40
2400
39
5
<3
2270
0 80
22
51
i/Pb
n.a.
14
0 5
i/Pb
i/Pb
7320
0 15
5 C
00-3
55
79
1310
10
8
<3
527
137
3 <2
<2
6
12
7 17
97
0 14
7 C
00-3
57
76
204
8 5
<3
6300
10
6 4
3 <2
5
<3
i/Pb
15
8700
91
C
00-3
59
54
1400
24
<2
37
69
00
15
58
<2
n.a.
37
<3
i/P
b 6
4600
00
32
C00
-362
39
60
0 5
<2
<3
8870
0 i/P
b 62
9 i/P
b n.
a.
45
4 i/P
b i/P
b 18
1600
11
C
00-3
64
32
2000
29
<2
<3
10
3700
i/P
b 42
4 i/P
b n.
a.
14
i/Pb
i/Pb
i/Pb
3615
00
6 C
00-3
65
60
3800
8
<2
4 50
600
9 12
7 i/P
b n.
a.
3 i/P
b i/P
b i/P
b 10
5600
24
C
00-3
69
73
1200
56
5
5 42
00
122
59
<2
n.a.
57
13
10
24
29
400
125
C00
-372
18
16
36
16
5
178
308
34
<2
6 18
29
60
45
20
4 31
8 C
00-3
78
31
198
2 10
4
6300
18
9 15
<2
2
16
18
i/Pb
29
1520
0 20
9 C
00-3
79
28
5600
11
8
<3
1600
24
9 10
<2
n.
a.
12
17
33
37
5740
0 23
2 C
00-3
81
26
5800
8
<2
<3
1188
00
i/Pb
126
i/Pb
n.a.
9
i/Pb
i/Pb
i/Pb
1924
00
128
C00
-383
22
16
00
55
<2
13
1849
00
i/Pb
516
i/Pb
n.a.
7
i/Pb
i/Pb
i/Pb
3982
00
8 C
00-3
85
13
3600
30
<2
<3
17
4900
i/P
b 18
65
i/Pb
n.a.
13
3 i/P
b i/P
b i/P
b 36
9600
9
11
Appendix 2: Whole Rock Analyses
XRF
SiO
2 Ti
O2
Al2O
3 Fe
2O3
MnO
M
gO
CaO
N
a2O
K
2O
P2O
5 B
aO
S LO
I B
a C
u Pb
Sr
Zn
Zr
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) (p
pm)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
) C
00-1
43
58.5
0.
62
20.1
5 3.
86
0.15
2.
45
1.81
1.
33
4.93
0.
15
0.23
1.
23
5.35
21
00
<100
<2
00
147
200
258
C00
-144
54
.17
0.8
23.9
2 3.
55
0.21
1.
81
0.93
4.
05
4.83
0.
19
0.25
1.
86
4.66
22
00
<100
60
0 38
2 12
00
347
C00
-208
63
.98
0.47
13
.31
3.93
2.
6 1.
95
2.94
0.
21
3.35
0.
11
0.18
0.
15
6.67
16
00
<100
<2
00
63
300
215
C00
-346
66
.52
0.48
16
.79
1.42
0.
1 0.
65
2.06
3.
61
4.65
0.
12
0.29
0.
44
3.5
2600
<1
00
<200
13
4 40
0 21
2 C
01-4
28
67.0
3 0.
31
13.7
3 2.
47
0.6
5.21
2.
06
0.54
2.
82
0.05
0.
27
0.11
5.
5 24
00
<100
<2
00
73
200
245
C01
-506
71
.62
0.28
13
.05
1.83
0.
5 3.
15
1.1
0.08
3.
89
0.04
0.
1 0.
26
4.24
90
0 <1
00
<200
25
10
0 22
1 C
01-5
08
75.0
4 0.
21
6.62
0.
88
1.55
0.
67
5.38
0.
05
2.27
0.
06
0.13
0.
58
6.68
12
00
200
2200
10
9 52
00
96
C01
-509
63
.52
0.65
18
.11
2.99
0.
4 1.
25
0.55
0.
91
5.51
0.
15
1.07
2.
18
4.65
96
00
<100
<2
00
72
400
299
C01
-532
70
.64
0.29
13
.4
2.42
0.
13
3.66
1.
26
2.61
1.
82
0.04
0.
08
0.01
3.
59
700
<100
40
0 10
0 10
0 23
3 C
01-5
74
82.2
1 0.
32
8.16
1.
63
0.38
0.
71
0.45
0.
08
2.59
0.
04
0.58
1.
18
2.78
52
00
<100
1<
200
13
800
109
C01
-579
61
.73
0.69
18
.7
3.89
0.
54
1.27
0.
36
1.22
5.
56
0.15
0.
71
2.31
4.
6 64
00
<100
<2
00
28
300
302
C01
-581
72
.64
0.36
10
.22
4.12
0.
3 0.
56
0.35
0.
06
3.22
0.
1 0.
68
3.4
3.63
61
00
1400
13
00
9 26
600
119
C01
-587
73
.02
0.28
11
.85
1.55
0.
76
2.02
1.
7 0.
14
4.15
0.
04
0.22
0.
06
4.05
20
00
<100
20
0 56
20
0 21
4 C
01-5
88
35.4
9 0.
2 5.
6 2.
93
2.55
0.
66
9.01
0.
025
1.82
0.
03
17.7
9 6.
78
8.01
2E
+05
2700
48
00
3297
19
100
58
C01
-589
80
.21
0.21
9.
74
2.64
0.
04
0.52
0.
08
0.06
3.
22
0.03
0.
33
1.51
2.
53
3000
10
0 38
00
11
400
146
C01
-600
76
.26
0.21
11
.39
2.43
0.
04
0.62
0.
03
0.08
3.
85
0.03
0.
41
1.93
2.
83
3700
40
0 30
0 8
1590
0 12
7 C
01-6
98
71.9
6 0.
28
12.4
3 6.
7 0.
22
1.08
0.
1 0.
05
3.73
0.
05
0.21
0.
32
2.69
19
00
<100
<2
00
8 10
0 20
5 C
01-6
99
71.9
0.
3 12
.91
2.14
0.
36
2.23
1.
76
0.41
3.
75
0.05
0.
18
0.21
4.
05
1600
<1
00
<200
71
10
0 23
5 C
01-7
00
62.2
4 0.
38
16.2
2.
08
0.1
3.31
4.
65
1.43
3.
12
0.06
0.
21
0.01
6.
45
1900
<1
00
<200
23
6 <1
00
306
C01
-702
66
.77
0.36
16
.63
2.67
0.
15
4.83
0.
82
1.44
1.
79
0.05
0.
33
0.13
4.
32
3000
<1
00
<200
42
8 10
0 28
7 C
01-7
13
72.6
5 0.
28
12.4
1 1.
53
0.24
1.
89
2.51
0.
73
3.31
0.
04
0.17
0.
03
4.19
15
00
<100
<2
00
90
100
220
R01
-064
41
.68
0.5
18.0
3 7.
08
4.51
3.
09
4.43
1.
71
4.22
0.
11
1.89
2.
85
12.4
6 16
900
<100
10
0 10
0 30
0 24
8
12
Appendix 2: Whole Rock Analyses
XRF
SiO
2 Ti
O2
Al2
O3
Fe2O
3 M
nO
MgO
C
aO
Na2
O
K2O
P2
O5
BaO
LO
I to
tal
S B
a N
b Sc
V
Y Zr
w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) w
t(%)
wt(%
) (p
pm)
(ppm
) (p
pm)
(ppm
) (p
pm)
(ppm
)
RO
2-08
2 68
.25
0.38
12
.9
2.85
0.
35
0.92
2.
81
1.37
5.
71
0.11
0.
21
3.92
99
.77
0.02
18
79
10.1
11
51
29
.1
170
CO
S-85
4 70
.37
0.43
14
.73
2 0.
09
0.49
1.
88
2.57
4.
41
0.12
0.
15
2.8
100.
03
0.07
13
47
11
10
58
22.3
19
6
CO
S-85
2 65
.03
0.4
16.4
4 3.
36
2.48
1.
49
0.42
0.
19
6.48
0.
06
0.33
3.
18
99.8
7 0.
36
3000
16
.8
9 18
46
.9
289
CO
O-0
91
74.6
1 0.
3 13
.71
2.01
0.
06
0.53
0.
45
4.3
2.28
0.
03
0.16
1.
09
99.5
3 <0
.01
1398
11
.6
6 13
27
.5
227
CO
O-0
92
70.8
5 0.
36
16.3
2.
26
0.08
0.
7 0.
54
4.09
3.
02
0.04
0.
2 1.
71
100.
13
0.01
17
62
14.9
6
14
29.6
27
6
CO
I-665
54
.37
0.98
26
.33
1.34
0.
04
1.49
0.
17
0.52
6.
69
0.13
4.
06
3.93
10
0.05
0.
52
3640
0 38
.3
15
123
33.8
45
4
CO
I-645
67
.91
0.58
15
.69
1.65
0.
19
2.43
1.
52
1.51
3.
34
0.07
1.
62
3.7
100.
2 0.
26
1450
0 19
.7
11
89
32.2
26
4
4 1
2 1.
5 1
1 de
tect
ion
limit(
ppm
)
Who
le ro
ck X
RF
anal
ysis
und
erta
ken
at D
epar
tmen
t of E
arth
Sci
ence
s - U
nive
rsity
of T
asm
ania
n.
a. -
not a
naly
sed
i/Pb
- int
erfe
renc
e fro
m h
igh
Pb c
onte
nt
13
Appendix 2: Whole Rock Analyses
ELEMENTS As Be Ga Ge In Rb Se Se Sn Te Tl U UNITS ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm DETECTION LIMIT 1 0.1 0.1 0.1 0.01 0.05 2 0.5 0.1 0.1 0.02 0.01 METHOD A/MS A/MS A/MS A/MS A/MS A/MS A/MS A/EMS A/MS A/MS A/MS A/MS C00-285 8 1.8 20.7 1.0 2.16 178.81 <2 0.8 3.3 0.1 5.92 4.09 C00-287 158 0.2 7.6 0.6 0.15 65.26 4 5.1 0.9 0.1 7.22 4.36 C00-290 728 0.1 15.9 2.2 0.74 24.02 6 7.1 0.8 0.1 24.19 5.29 C00-320 92 0.8 11.6 0.7 3.12 153.46 <2 1.0 1.9 0.1 4.51 3.25 C00-323 22 0.8 12.1 0.5 5.69 153.76 <2 1.6 4.2 0.1 10.61 3.34 C00-326 833 0.4 12.7 0.3 0.49 77.09 4 5.2 1.7 0.1 26.57 2.97 C00-329 430 0.3 8.7 13.7 0.16 47.42 2 3.7 4.6 0.1 11.07 5.48 C00-355 26 0.8 10.1 0.8 1.00 150.95 <2 <0.5 1.4 0.1 6.73 3.50 C00-357 69 0.7 8.3 1.0 2.93 112.55 <2 0.6 1.4 0.1 10.44 2.69 C00-359 311 0.4 20.6 3.5 158.53 13.87 8 10.9 18.7 0.1 11.90 11.36 C00-362 256 <0.1 2.5 18.4 0.10 3.75 4 4.5 0.8 0.1 7.67 0.86 C00-364 1224 <0.1 15.2 8.6 51.45 0.46 6 8.3 4.9 0.1 55.34 3.11 C00-365 473 <0.1 2.2 1.1 8.61 3.13 <2 2.5 1.0 0.1 15.64 1.32 C00-369 142 1.0 12.7 1.1 0.97 132.65 <2 0.6 1.8 0.1 10.19 4.00 C00-379 164 1.2 19.2 0.7 5.85 234.27 <2 1.6 2.6 0.1 31.96 5.53 C00-381 287 0.7 14.2 1.0 0.06 146.89 4 3.8 2.3 0.1 41.38 3.57 C00-383 500 <0.1 16.3 2.6 0.02 13.49 7 7.9 0.3 0.1 15.14 2.90 C00-385 555 <0.1 9.8 9.4 0.63 10.52 6 7.7 0.3 0.1 10.55 2.25 Laboratory : Genalysis Pty. Ltd. Job Code : 6.3/0306028 Client : Neil Martin Date : 17/10/2003
ELEMENTS Au Au-Rp1 Au-Rp2 UNITS ppm ppm ppm DETECTION LIMIT 0.01 0.01 0.01 METHOD FA/AAS FA/AAS FA/AAS C00-278 0.05 C00-280 0.13 C00-284 6.37 6.23 C00-285 0.06 C00-287 2.25 2.62 C00-290 2.57 C00-297 0.40 C00-299 3.42 C00-301 0.29 C00-306 0.77 C00-307 0.51 C00-317 0.67 C00-320 0.27 C00-323 0.17 C00-326 0.72 C00-329 2.50 C00-333 0.22 C00-337 4.31 3.53 C00-341 10.20 5.78 16.56 C00-343 0.29 C00-345 10.27 8.49 C00-350 0.56 C00-353 2.50 C00-355 0.10 C00-357 0.47 C00-359 2.16 1.93 C00-362 1.12 C00-364 5.94 0.87 4.10 C00-365 1.68 1.46 C00-369 1.93 2.38 C00-372 0.06 C00-378 0.04 C00-379 0.31 Laboratory : Genalysis Pty. Ltd. C00-381 0.90 Job Code : 6.3/0004693 C00-383 2.51 Client : Neil Martin C00-385 3.77 Date : 7/09/2000
Appendix 3: Microprobe Analysis—Silicates
15 15
C08
7
chl1
cl
cl p
seud
ofia
mm
e - C
amb.
mat
rix 6
.17
0.01
4.
49
6.69
0
.48
1.
59
1.59
0.
04
0.09
0
.01
0.
00
0.0
0
0.05
2
8.00
19.
58 0
.81
C08
7
chl3
cl
cl p
seud
ofia
mm
e - C
amb.
mat
rix 5
.33
0.02
5.
46
6.40
0
.42
2.
23
2.23
0.
02
0.05
0
.00
0.
00
0.0
0
0.06
2
8.00
19.
92 0
.74
C08
7
chl4
cl
cl p
seud
ofia
mm
e - C
amb.
mat
rix 5
.31
0.02
5.
46
6.24
0
.44
2.
04
2.04
0.
02
0.39
0
.01
0.
00
0.0
0
0.07
2
8.00
19.
95 0
.75
C21
1
chl1
cl
mas
sive
cl-m
ag-s
p - D
ev. m
etas
.
m
etas
. 5.7
6 0.
02
4.52
8.
01
0.3
8
1.19
1.
19
0.00
0.
07
0.0
0
0.00
0
.00
0.
11
28.
00 1
9.96
0.8
7 C
211
ch
l2
cl
m
assi
ve c
l-mag
-sp
- Dev
. met
as.
met
as. 5
.81
0.00
4.
33
8.22
0
.32
1.
29
1.29
0.
01
0.01
0
.00
0.
00
0.0
0
0.02
2
8.00
20.
02 0
.86
C21
1
chl3
cl
mas
sive
cl-m
ag-s
p - D
ev. m
etas
.
m
etas
. 5.7
2 0.
03
4.57
7.
87
0.3
7
1.26
1.
26
0.00
0.
09
0.0
0
0.00
0
.01
0.
08
28.
00 1
9.95
0.8
6 C
211
ch
l4
cl
m
assi
ve c
l-mag
-sp
- Dev
. met
as.
met
as. 6
.05
0.04
3.
95
7.57
0
.21
1.
56
1.56
0.
01
0.49
0
.01
0.
00
0.0
1
0.3
2
8.00
19.
93 0
.83
C21
1
chl5
cl
mas
sive
cl-m
ag-s
p - D
ev. m
etas
.
m
etas
. 5.6
0 0.
01
4.80
7.
83
0.4
3
1.27
1.
27
0.00
0.
03
0.0
1
0.00
0
.00
0.
14
28.
00 1
9.99
0.8
6 C
247
cl
1
cl
c
l sch
ist -
in g
roun
dmas
s
m
atrix
5.7
2 0.
01
5.38
3.
58
0.2
5
4.61
4.
61
0.02
0.
00
0.0
0
0.01
0
.00
0.
28
28.
00 1
9.59
0.4
4 C
333
ch
l1
cl
cl
-se-
si s
chis
t in
grou
ndm
ass
mat
rix 5
.19
0.01
5.
60
5.60
0
.39
3.
18
3.18
0.
00
0.01
0
.01
0.
00
0.0
0
0.15
2
8.00
20.
00 0
.64
C33
3
chl3
cl
cl-s
e-si
sch
ist i
n gr
ound
mas
s
m
atrix
5.2
8 0.
02
5.47
5.
51
0.3
9
3.27
3.
27
0.00
0.
01
0.0
0
0.00
0
.00
0.
18
28.
00 1
9.96
0.6
3 C
333
ch
l4
cl
cl
-se-
si s
chis
t in
grou
ndm
ass
mat
rix 5
.19
0.01
5.
57
5.66
0
.38
3.
21
3.21
0.
01
0.00
0
.00
0.
00
0.0
0
0.17
2
8.00
20.
02 0
.64
C56
1
chl1
cl
cl-s
chis
t cpy
-py-
po -
C o
r D?
m
atrix
5.2
8 0.
01
5.34
4.
67
0.4
0
4.32
4.
32
0.00
0.
00
0.0
0
0.01
0
.00
0.
21
28.
00 2
0.04
0.5
2 C
561
ch
l2
cl
cl
-sch
ist c
py-p
y-po
- C
or D
?
mat
rix 5
.44
0.01
5.
02
4.39
0
.42
4.
72
4.72
0.
00
0.01
0
.01
0.
02
0.0
1
0.29
2
8.00
20.
04 0
.48
C56
1
chl3
cl
cl-s
chis
t cpy
-py-
po -
C o
r D?
m
atrix
5.3
0 0.
01
5.30
4.
54
0.4
1
4.45
4.
45
0.00
0.
00
0.0
0
0.00
0
.01
0.
18
28.
00 2
0.03
0.5
0 C
651
ch
l1
cl
cl
-sch
ist -
py -
Cam
b. -
belo
w P
-lens
m
atrix
5.2
8 0.
00
5.46
4.
59
0.3
5
4.27
4.
27
0.00
0.
00
0.0
1
0.01
0
.00
0.
21
28.
00 1
9.98
0.5
2 C
651
ch
l2
cl
cl
-sch
ist -
py -
Cam
b. -
belo
w P
-lens
m
atrix
5.2
9 0.
02
5.52
4.
55
0.3
5
4.18
4.
18
0.00
0.
01
0.0
0
0.00
0
.00
0.
23
28.
00 1
9.93
0.5
2 C
651
ch
l3
cl
cl
-sch
ist -
py -
Cam
b. -
belo
w P
-lens
m
atrix
5.2
8 0.
01
5.54
4.
67
0.4
1
4.01
4.
01
0.00
0.
00
0.0
1
0.00
0
.00
0.
19
28.
00 1
9.94
0.5
4 C
651
ch
l4
cl
cl
-sch
ist -
py -
Cam
b. -
belo
w P
-lens
m
atrix
5.3
5 0.
00
5.49
4.
55
0.3
4
4.17
4.
17
0.01
0.
00
0.0
0
0.00
0
.00
0.
16
28.
00 1
9.91
0.5
2 C
651
ch
l5
cl
cl
-sch
ist -
py -
Cam
b. -
belo
w P
-lens
m
atrix
5.3
2 0.
00
5.52
4.
56
0.3
3
4.16
4.
16
0.01
0.
00
0.0
0
0.00
0
.00
0.
19
28.
00 1
9.91
0.5
2 C
651
ch
l6
cl
cl
-sch
ist -
py -
Cam
b. -
belo
w P
-lens
m
atrix
5.3
3 0.
01
5.46
4.
42
0.3
6
4.32
4.
32
0.00
0.
01
0.0
0
0.00
0
.01
0.
27
28.
00 1
9.93
0.5
1 C
776
ch
l1
cl
cl
sch
ist -
cpy
,py
- pos
sibl
e D
ev. c
l?
mat
rix 5
.26
0.02
5.
45
5.66
0
.42
3.
15
3.15
0.
00
0.00
0
.00
0.
01
0.0
1
0.23
2
8.00
19.
99 0
.64
C77
6
chl2
cl
cl s
chis
t - c
py,p
y - p
ossi
ble
Dev
. cl?
m
atrix
5.2
5 0.
00
5.36
5.
72
0.4
5
3.29
3.
29
0.00
0.
00
0.0
0
0.00
0
.00
0.
24
28.
00 2
0.07
0.6
4 C
776
ch
l3
cl
cl
sch
ist -
cpy
,py
- pos
sibl
e D
ev. c
l?
mat
rix 5
.18
0.01
5.
51
5.60
0
.47
3.
27
3.27
0.
00
0.00
0
.00
0.
00
0.0
1
0.07
2
8.00
20.
05 0
.63
C77
6
chl4
cl
cl s
chis
t - c
py,p
y - p
ossi
ble
Dev
. cl?
m
atrix
5.1
5 0.
02
5.54
5.
59
0.4
6
3.28
3.
28
0.00
0.
01
0.0
0
0.00
0
.00
0.
16
28.
00 2
0.06
0.6
3 C
776
ch
l5
cl
cl
sch
ist -
cpy
,py
- pos
sibl
e D
ev. c
l?
mat
rix 5
.22
0.02
5.
46
5.70
0
.43
3.
16
3.16
0.
01
0.01
0
.01
0.
00
0.0
1
0.13
2
8.00
20.
03 0
.64
C80
8
chl1
cl
qz-c
b-cl
-sul
phid
e ve
in -
Dev
.
m
etas
. 5.3
6 0.
00
5.36
4.
98
0.3
2
3.89
3.
89
0.00
0.
00
0.0
0
0.00
0
.01
0.
19
28.
00 1
9.95
0.5
6 C
808
ch
l2
cl
qz
-cb-
cl-s
ulph
ide
vein
- D
ev.
met
as. 5
.35
0.00
5.
33
4.94
0
.35
3.
99
3.99
0.
00
0.00
0
.00
0.
00
0.0
0
0.2
2
8.00
19.
98 0
.55
C80
8
chl3
cl
qz-c
b-cl
-sul
phid
e ve
in -
Dev
.
m
etas
. 5.3
6 0.
01
5.36
5.
11
0.3
3
3.78
3.
78
0.00
0.
01
0.0
0
0.00
0
.00
0.
18
28.
00 1
9.95
0.5
7 C
808
ch
l4
cl
qz
-cb-
cl-s
ulph
ide
vein
- D
ev.
met
as. 5
.32
0.00
5.
39
4.95
0
.32
3.
97
3.97
0.
00
0.00
0
.01
0.
01
0.0
0
0.25
2
8.00
19.
98 0
.55
C80
8
chl5
cl
qz-c
b-cl
-sul
phid
e ve
in -
Dev
.
m
etas
. 5.3
9 0.
01
5.30
4.
89
0.3
3
4.01
4.
01
0.00
0.
00
0.0
0
0.00
0
.00
0.
17
28.
00 1
9.94
0.5
5 C
824
ch
l1
cl
bl
ack
cl-s
e sc
hist
+py-
cpy
- Cam
b. P
-lens
mat
rix 5
.29
0.01
5.
42
5.12
0
.26
3.
86
3.86
0.
00
0.00
0
.01
0.
01
0.0
1
0.28
2
8.00
19.
99 0
.57
C82
4
chl2
cl
blac
k cl
-se
schi
st+p
y-cp
y - C
amb.
P-le
ns m
atrix
5.3
0 0.
02
5.35
5.
10
0.2
7
3.93
3.
93
0.00
0.
01
0.0
1
0.02
0
.00
0.
21
28.
00 2
0.00
0.5
6 C
824
ch
l3
cl
bl
ack
cl-s
e sc
hist
+py-
cpy
- Cam
b. P
-lens
mat
rix 5
.34
0.02
5.
34
5.08
0
.28
3.
89
3.89
0.
00
0.00
0
.01
0.
00
0.0
1
0.19
2
8.00
19.
97 0
.57
C82
4
chl4
cl
blac
k cl
-se
schi
st+p
y-cp
y - C
amb.
P-le
ns m
atrix
5.3
3 0.
01
5.32
5.
11
0.2
3
3.96
3.
96
0.00
0.
00
0.0
1
0.00
0
.01
0.
29
28.
00 1
9.99
0.5
6 sa
mpl
e po
int
type
des
crip
tion
all
valu
es w
t% S
i
Ti
A
l
Fe
Mn
M
g
Ca
N
a
K
Sr
B
a
C
r
F
t_O
t
_cat
. Fe#
Appendix 3: Microprobe Analysis—Silicates
16
R01
-065
Tra
vA1_
1
feld
spar
/ab
48.9
676
8.3
761
0.
001
1
0.58
52 3
2.10
36 0
.000
2
0.02
6
0.0
778
0.
0315
0
.027
7
0.02
33
0.0
049
10
0.22
R
01-0
65 T
ravA
1_2
fe
ldsp
ar/a
b 49
.101
4 8
.460
9
0.00
02
10.
5811
32.
2268
0.0
002
0.
0317
0
.022
8
0.01
13
0.0
238
0.
0078
0
.000
1
100.
47
R01
-065
Tra
vA1_
3
feld
spar
/ab
48.9
738
8.3
449
0.
0002
1
0.67
1
32.0
639
0.0
002
0.
0226
0
.085
0.00
9
0.0
079
0.
0201
0
.005
8
100.
2 R
01-0
65 T
ravA
1_4
fe
ldsp
ar/a
b 48
.803
9 8
.396
6
0.00
02
10.
4715
32.
0581
0.0
013
0.
0215
0
.071
3
0.00
23
0.0
001
0.
0447
0
.015
99.8
9 R
01-0
65 T
ravA
1_5
fe
ldsp
ar/a
b 48
.969
1 8
.325
6
0.01
31
10.
569
32
.154
5 0
.000
6
0.02
65
0.0
414
0.
0045
0
.000
1
0.02
26
0.0
149
10
0.14
R
01-0
65 T
ravA
1_6
fe
ldsp
ar/a
b 48
.822
9 8
.449
4
0.00
22
10.
5853
31.
9244
0.0
007
0.
0209
0
.14
0.0
36
0.
0158
0
.088
1
0.00
84
100
.09
R01
-065
Tra
vA1_
7
feld
spar
/ab
48.9
517
8.3
217
0.
0002
1
0.50
27 3
2.18
76 0
.002
6
0.02
26
0.0
607
0.
0113
0
.000
1
0.03
17
0.0
211
10
0.11
R
01-0
65 T
ravA
1_8
fe
ldsp
ar/a
b 48
.669
6 8
.327
9
0.01
09
10.
5015
31.
9106
0.0
008
0.
0158
0
.112
7
0.02
25
0.0
001
0.
0648
0
.011
7
99.6
5 R
01-0
65 T
ravA
1_9
fe
ldsp
ar/a
b 47
.782
3 7
.002
5
0.22
65
11.
6989
30.
1059
0.0
002
1.
3746
0
.088
7
0.00
01
0.1
537
0.
0534
0
.853
8
99.3
4 R
01-0
65 T
ravA
1_10
fel
dspa
r/ab
48.8
315
8.2
884
0.
0002
1
0.57
13 3
2.01
67 0
.000
2
0.04
63
0.1
052
0.
0248
0
.000
1
0.05
44
0.0
001
99
.94
R01
-065
Tra
vA1_
11 f
elds
par/a
b 47
.664
1 7
.730
2
0.09
19
10.
8056
30.
8067
0.0
025
0.
4924
0
.062
2
0.00
68
0.0
811
0.
0175
0
.314
2
98.0
8 R
01-0
65 T
ravA
1_12
fel
dspa
r/ab
48.8
576
8.3
0
.004
2
10.5
636
32.
0592
0.0
002
0.
0192
0
.078
4
0.00
01
0.0
001
0.
0486
0
.019
9
99.9
5 R
01-0
65 T
ravA
1_13
fel
dspa
r/ab
48.9
39
8.3
59
0.
0022
1
0.57
13 3
2.08
43 0
.000
2
0.02
26
0.1
0
.024
8
0.01
58
0.0
524
0.
0428
1
00.2
1 R
01-0
65 T
ravA
1_14
fel
dspa
r/ab
48.5
78
8.0
598
0.
075
1
0.88
28 3
1.46
34 0
.000
2
0.40
18
0.1
267
0.
0607
0
.017
8
0.04
87
0.2
717
99
.99
R01
-065
Tra
vA1_
15 f
elds
par/a
b 47
.471
9 8
.073
5
0.03
9
9.8
468
30
.555
6 0
.000
2
0.01
4
1.4
267
1.
5313
0
.080
9
0.07
37
0.0
063
99
.12
R01
-065
Tra
vB1_
1
feld
spar
/ab
45.5
445
7.5
897
0.
0002
9
.761
8
29.9
43
0.0
002
0.
0107
0
.143
1
0.02
25
0.0
653
0.
044
0
.044
9
93.1
7 R
01-0
65 T
ravB
1_2
fe
ldsp
ar/a
b 48
.626
7 8
.345
3
0.00
02
10.
4872
31.
904
0.
0008
0
.028
2
0.08
34
0.0
023
0.
0001
0
.033
7
0.00
35
99.
52
R01
-065
Tra
vB1_
3
feld
spar
/ab
48.2
816
8.1
596
0.
0132
1
0.34
33 3
1.48
06 0
.000
2
0.02
2
0.5
553
0.
4005
0
.039
5
0.04
79
0.0
001
99
.34
R01
-065
Tra
vB1_
4
feld
spar
/ab
49.0
469
8.3
539
0.
0002
1
0.62
73 3
2.13
65 0
.000
2
0.02
82
0.0
738
0.
0811
0
.021
8
0.02
27
0.0
21
10
0.41
R
01-0
65 T
ravB
1_5
fe
ldsp
ar/a
b 49
.023
5 8
.448
1
0.00
39
10.
5338
32.
1377
0.0
002
0.
0226
0
.115
3
0.05
63
0.0
317
0.
0732
0
.034
6
100.
48
R01
-065
Tra
vB1_
6
feld
spar
/ab
48.9
783
8.3
945
0.
0016
1
0.57
05 3
2.10
91 0
.000
9
0.03
56
0.0
617
0.
0406
0
.047
5
0.04
28
0.0
002
10
0.28
R
01-0
65 T
ravB
1_7
fe
ldsp
ar/a
b 48
.919
8
.309
6
0.00
02
10.
4925
32.
1197
0.0
002
0.
022
0
.127
9
0.09
46
0.0
257
0.
033
0
.010
5
100.
15
R01
-065
Tra
vB1_
8
feld
spar
/ab
48.9
567
8.3
46
0.
0002
1
0.61
85 3
2.07
3
0.00
14
0.0
068
0.
133
0
.011
3
0.00
01
0.0
343
0.
0182
1
00.2
R
01-0
65 T
ravB
1_9
fe
ldsp
ar/a
b 48
.936
8 8
.304
2
0.00
02
10.
6275
32.
0578
0.0
021
0.
0232
0
.137
6
0.00
01
0.0
001
0.
0395
0
.018
100.
15
R01
-065
Tra
vB1_
10 f
elds
par/a
b 48
.866
8
.317
4
0.00
02
10.
5821
32.
0109
0.0
002
0.
0333
0
.167
0.02
03
0.0
001
0.
0467
0
.017
5
100.
06
R01
-065
Tra
vB1_
11 f
elds
par/a
b 48
.966
9 8
.325
9
0.01
54
10.
5797
32.
0966
0.0
002
0.
0169
0
.166
4
0.00
23
0.0
001
0.
0434
0
.033
4
100.
25
R01
-065
Tra
vB1_
12 f
elds
par/a
b 48
.849
3 8
.299
6
0.00
06
10.
5573
31.
9891
0.0
021
0.
022
0
.219
5
0.05
63
0.0
079
0.
0596
0
.007
5
100.
07
R01
-065
Tra
vB1_
13 f
elds
par/a
b 48
.860
4 8
.305
3
0.00
02
10.
4987
32.
0571
0.0
052
0.
0249
0
.158
8
0.10
81
0.0
04
0.
011
0
.000
1
100.
03
R01
-065
Tra
vB1_
14 f
elds
par/a
b 48
.84
8
.221
0.00
02
10.
6218
31.
957
0.
0069
0
.014
1
0.18
46
0.0
586
0.
0198
0
.059
0.01
78
100
R
01-0
65 T
ravB
1_15
fel
dspa
r/ab
45.8
877
5.9
625
0.
0002
7
.207
1
20.9
297
6.6
083
0.
0522
1
2.47
09 0
.083
1
0.00
59
0.0
485
0.
0002
9
9.26
R
01-0
65 T
ravB
1_16
fel
dspa
r/ab
48.8
651
8.3
15
0.
0061
1
0.50
37 3
2.10
55 0
.000
2
0.03
56
0.0
84
0.
009
0
.000
1
0.02
53
0.0
001
99
.95
R01
-065
Tra
vB1_
17 f
elds
par/a
b 49
.125
6 8
.36
0.0
128
10
.612
7 3
2.23
2
0.00
02
0.0
209
0.
0617
0
.011
3
0.00
79
0.0
641
0.
0001
1
00.5
1 R
01-0
65 T
ravB
2_1
fe
ldsp
ar/a
b 48
.784
3 8
.295
3
0.00
93
10.
5597
31.
9553
0.0
002
0.
0001
0
.116
8
0.06
08
0.0
455
0.
0389
0
.018
2
99.8
8 R
01-0
65 T
ravB
2_2
fe
ldsp
ar/a
b 41
.661
9 6
.880
9
0.30
17
8.2
885
24
.973
2 0
.000
1
0.03
52
4.6
705
4.
5049
0
.129
1
0.03
43
0.0
001
91
.48
R01
-065
Tra
vB2_
3
feld
spar
/ab
48.8
135
8.3
621
0.
0002
1
0.46
67 3
2.05
65 0
.000
8
0.03
33
0.0
455
0.
0676
0
.041
6
0.04
41
0.0
115
99
.94
R01
-065
Tra
vB2_
4
feld
spar
/ab
48.7
983
8.3
081
0.
0032
1
0.49
77 3
2.03
08 0
.007
1
0.01
53
0.0
926
0.
0315
0
.009
9
0.06
67
0.0
11
99
.87
R01
-065
Tra
vB2_
5
feld
spar
/ab
48.0
219
8.1
778
0.
0561
1
0.33
43 3
1.13
97 0
.000
2
0.00
84
0.7
175
0.
6143
0
.000
1
0.01
36
0.0
089
99
.09
R01
-065
Tra
vB2_
6
feld
spar
/ab
48.8
241
8.3
175
0.
0002
1
0.58
35 3
2.00
49 0
.000
2
0.01
98
0.0
794
0.
0316
0
.007
9
0.02
92
0.0
007
99
.9
sam
ple
tra
v/po
int
typ
e
W%
(O )
W%
(Na)
W%
(Mg)
W%
(Al)
W%
(Si)
W%
(P )
W%
(K )
W%
(Ca)
W%
(Mn)
W%
(Fe)
W%
(Sr)
W%
(Ba)
wt%
tota
l
Appendix 3: Microprobe Analysis—Silicates
17
R01
-065
Tra
vB2_
7
feld
spar
/ab
49.0
433
8.4
256
0.
0002
1
0.68
71 3
2.06
8
0.00
02
0.0
074
0.
1285
0
.040
6
0.00
01
0.0
292
0.
0105
1
00.4
4 R
01-0
65 T
ravB
2_8
fe
ldsp
ar/a
b 48
.935
3 8
.499
0.00
23
10.
4674
32.
1469
0.0
002
0.
017
0
.032
9
0.06
31
0.0
001
0.
0369
0
.000
1
100.
2 R
01-0
65 T
ravB
2_9
fe
ldsp
ar/a
b 49
.191
1 8
.382
2
0.00
48
10.
5684
32.
2663
0.0
002
0.
0356
0
.154
7
0.13
07
0.0
001
0.
0104
0
.015
2
100.
76
R01
-065
Tra
vC1_
1
feld
spar
/ab
49.2
078
8.3
642
0.
0002
1
0.63
15 3
2.26
51 0
.002
5
0.03
05
0.1
199
0.
0698
0
.000
1
0.02
46
0.0
001
10
0.72
R
01-0
65 T
ravC
1_2
fe
ldsp
ar/a
b 49
.049
5 8
.323
7
0.00
26
10.
6908
32.
0822
0.0
002
0.
0384
0
.157
3
0.00
01
0.0
297
0.
0396
0
.009
6
100.
42
R01
-065
Tra
vC1_
3
feld
spar
/ab
47.3
896
7.9
748
0.
0466
1
0.11
11 3
0.61
7
0.00
02
0.0
186
0.
958
1
.059
6
0.00
4
0.0
454
0.
0383
9
8.26
R
01-0
65 T
ravC
1_4
fe
ldsp
ar/a
b 48
.870
5 8
.361
4
0.00
02
10.
5828
32.
0392
0.0
002
0.
0345
0
.055
2
0.00
01
0.0
238
0.
035
0
.005
6
100.
01
R01
-065
Tra
vC1_
5
feld
spar
/ab
49.0
1
8.4
084
0.
0067
1
0.53
61 3
2.18
76 0
.000
2
0.02
09
0.0
278
0.
036
0
.000
1
0.05
05
0.0
208
10
0.31
R
01-0
65 T
ravC
1_6
fe
ldsp
ar/a
b 48
.935
6 8
.431
2
0.00
02
10.
5785
32.
0974
0.0
002
0.
0368
0
.013
7
0.02
25
0.0
001
0.
0208
0
.011
2
100.
15
R01
-065
Tra
vC1_
7
feld
spar
/ab
48.6
777
8.3
072
0.
0013
1
0.53
7
31.8
92
0.0
002
0.
0356
0
.121
0.03
61
0.0
001
0.
0636
0
.020
4
99.6
9 R
01-0
65 T
ravC
1_8
fe
ldsp
ar/a
b 48
.782
6 8
.310
5
0.00
1
10.
5181
32.
0221
0.0
002
0.
0481
0
.064
8
0.00
45
0.0
198
0.
0344
0
.007
3
99.8
1 R
01-0
65 T
ravC
1_9
fe
ldsp
ar/a
b 48
.940
4 8
.316
4
0.00
8
10.
6054
32.
0554
0.0
031
0.
0452
0
.093
1
0.00
01
0.0
455
0.
0843
0
.025
5
100.
22
R01
-065
Tra
vC1_
10 fe
ldsp
ar/a
b 48
.720
1 7
.955
5
0.06
44
10.
9288
31.
6279
0.0
002
0.
3675
0
.070
8
0.00
9
0.0
435
0.
0188
0
.236
8
100.
04
R01
-065
Tra
vC1_
11 fe
ldsp
ar/a
b 48
.781
8 8
.1
0.0
561
10
.780
6 3
1.76
62 0
.000
2
0.31
13
0.1
012
0.
0001
0
.035
6
0.04
41
0.1
663
10
0.14
R
01-0
65 T
ravC
1_12
feld
spar
/ab
48.7
891
8.2
275
0.
0002
1
0.57
78 3
2.01
67 0
.000
2
0.04
58
0.0
643
0.
0001
0
.000
1
0.03
5
0.0
001
99
.76
R01
-065
Tra
vC1_
13 fe
ldsp
ar/a
b 49
.053
8 8
.309
4
0.00
02
10.
6697
32.
1374
0.0
002
0.
0385
0
.081
5
0.00
01
0.0
178
0.
0538
0
.005
1
100.
37
R01
-065
Tra
vC1_
14 fe
ldsp
ar/a
b 47
.954
7
.259
7
0.18
24
11.
3147
30.
6117
0.0
002
0.
9836
0
.102
1
0.00
22
0.1
206
0.
0319
0
.586
7
99.1
5 R
01-0
65 T
ravC
1_15
feld
spar
/ab
48.8
43
8.2
772
0.
0141
1
0.60
41 3
1.99
08 0
.000
2
0.10
75
0.0
83
0.
0293
0
.000
1
0.03
31
0.0
499
10
0.03
R
01-0
65 T
ravC
1_16
feld
spar
/ab
48.8
07
8.3
411
0.
0039
1
0.51
72 3
2.04
21 0
.000
2
0.03
28
0.0
658
0.
0001
0
.007
9
0.02
79
0.0
091
99
.86
R01
-065
Tra
vC1_
17 fe
ldsp
ar/a
b 48
.899
8
.412
5
0.00
61
10.
5296
32.
101
0.
0087
0
.032
8
0.00
71
0.0
09
0.
0119
0
.009
1
0.00
01
100
.03
R01
-065
Tra
vC1_
18 fe
ldsp
ar/a
b 48
.813
3 8
.273
5
0.00
74
10.
531
32
.066
2 0
.000
2
0.03
51
0.0
177
0.
0248
0
.013
9
0.01
56
0.0
001
99
.8
R01
-065
Tra
vC1_
19 fe
ldsp
ar/a
b 48
.616
8
.311
0.00
64
10.
4889
31.
9097
0.0
002
0.
0322
0
.059
7
0.00
01
0.0
079
0.
0019
0
.018
99.4
5 R
01-0
65 T
ravC
1_20
feld
spar
/ab
48.5
968
8.2
914
0.
0002
1
0.53
88 3
1.85
91 0
.000
2
0.01
98
0.0
557
0.
0001
0
.011
9
0.04
28
0.0
173
99
.43
R01
-065
Tra
vC1_
21 fe
ldsp
ar/a
b 47
.704
6 6
.902
5
0.27
83
11.
6228
30.
1017
0.0
002
1.
2937
0
.079
3
0.00
9
0.1
599
0.
0346
0
.973
3
99.1
6
sam
ple
tra
v/po
int
typ
e
W%
(O )
W%
(Na)
W%
(Mg)
W%
(Al)
W%
(Si)
W%
(P )
W%
(K )
W%
(Ca)
W%
(Mn)
W%
(Fe)
W%
(Sr)
W%
(Ba)
wt%
tota
l
sam
ple
poin
t ty
pe
de
scrip
tion
a
ll va
lues
wt%
Si
Ti
A
l
Fe
Mn
M
g
Ca
N
a
K
S
r
Ba
Cr
F
C
l
O
C00
-087
se2
se
ricite
au
gen
schi
st -
FW, p
roxi
mal
18.2
8 0
.05
14
.79
9.3
4 0
.71
1.5
9
0.07
0
.12
5.6
8 0
.02
0.
10
0.0
0
0.37
0
.01
39.
19
C00
-171
se1
se
ricite
se
-si-c
l sch
ist -
FW
, pro
xim
al
23
.15
0.2
6
15.0
4 2
.17
0.0
8 1
.99
0.
00
0.0
5 7
.88
0.0
0
0.30
0
.00
0.
59
0.0
0 4
3.54
C
00-1
71 s
e2
seric
ite
se-s
i-cl s
chis
t - F
W, p
roxi
mal
23.3
9 0
.26
15
.36
2.7
9 0
.13
2.2
2
0.03
0
.06
7.5
1 0
.00
0.
21
0.0
0
0.49
0
.00
44.
37
C00
-333
se2
se
ricite
se
-si s
chis
t - F
W, p
roxi
mal
23
.73
0.0
6
16.9
2 1
.60
0.0
7 0
.99
0.
01
0.1
5 8
.29
0.0
3
0.11
0
.00
0.
72
0.0
0 4
5.02
C
01-5
04 s
e1
seric
ite
auge
n sc
hist
- or
e
22.6
0 0
.18
16
.13
3.4
2 0
.08
1.5
9
0.03
0
.08
7.6
6 0
.00
0.
41
0.0
0
0.40
0
.01
43.
92
C01
-650
se1
se
ricite
py
in c
l-se
schi
st -
FW, p
roxi
mal
23.2
8 0
.06
17
.55
1.1
7 0
.05
0.9
9
0.00
0
.12
8.5
6 0
.00
0.
30
0.0
2
0.46
0
.00
45.
01
C02
-824
se5
se
ricite
B
lack
cl-s
e sc
hist
- FW
, pro
xim
al
22
.71
0.1
8
16.8
5 2
.19
0.0
6 0
.91
0.
00
0.1
8 8
.23
0.0
4
0.15
0
.00
0.
52
0.0
1 4
4.00
Appendix 4: Microprobe Analysis—Sulphides
19
S py/apy 151 S tet 131 high Cu/As Mn py/apy 102 Fe tet 128 high Sb/Ag Fe py/apy 187 Fe tet 142 Co py/apy 117 Cu tet 201 high Cu/As Ni py/apy 130 Zn tet 163 high Sb/Ag Cu py/apy 146 Zn tet 175 high Cu/As As py/apy 92 As tet 207 high Sb/Ag Se py/apy 61 As tet 184 high Cu/As Ag py/apy 84 Se tet 185 high Sb/Ag Au py/apy 323 Se tet 203 Bi py/apy 268 Ag tet 223 Cd tet 189 high Cu/As S ga 385 Sb tet 170 high Sb/Ag Zn ga 185 Sb tet 199 high Cu/As As ga 134 Te tet 125 high Sb/Ag Se ga 87 Te tet 137 high Cu/As Ag ga 199 Hg tet 175 high Sb/Ag Cd ga 198 Hg tet 199 high Cu/As Sb ga 202 Pb tet 365 high Sb/Ag Pb ga 799 Pb tet 381 high Cu/As Bi tet 230 high Sb/Ag S cpy 130 Bi tet 240 Mn cpy 109 Fe cpy 191 S py (with Tl) 225 Co cpy 128 Fe py (with Tl) 207 Ni cpy 143 Cu py (with Tl) 161 Cu cpy 181 Zn py (with Tl) 143 As cpy 89 As py (with Tl) 72 Se cpy 59 Se py (with Tl) 47 Ag cpy 90 Ag py (with Tl) 120 Au cpy 348 Cd py (with Tl) 132 Bi cpy 244 Sb py (with Tl) 95 Te py (with Tl) 97 S sp 135 Au py (with Tl) 611 Mn sp 91 Hg py (with Tl) 218 Fe sp 103 Tl py (with Tl) 238 Co sp 96 Pb py (with Tl) 288 Ni sp 121 Bi py (with Tl) 286 Cu sp 137 Zn sp 353 As sp 85 Beam set at 20kV and 60nA. Se sp 58 Ag sp 101 Cd sp 107
Calculated detection limits for microprobe analyses: element mineral d.l. comments element mineral d.l. comments (ppm) (ppm)
Appendix 4: Microprobe Analysis—Sulphides
20
C26
1
A_p
y_1
p
y
54.
7539
0.
0272
45.7
117
0
0.00
82
0.
0001
0.27
59
0
.007
1
0.
0112
0.0
067
0.00
01
10
0.80
C
261
A
_py_
2
py
5
4.51
59
0.03
13
45
.947
7
0
.003
2
0.
0086
0.01
45
0.
2501
0.0
156
0.01
07
0
.000
1
0.
0001
100.
80
C26
1
A_p
y_3
p
y
54.
3251
0.
0319
45.2
24
0
0.01
47
0.
0094
0.67
92
0
.023
1
0.
0069
0.0
001
0.00
01
10
0.31
C
261
B
_py_
7
py
5
4.68
59
0.01
91
46
.118
9
0
0.
002
0.0
001
0.21
48
0
.015
8
0.
0001
0.0
028
0.00
01
10
1.06
C
261
B
_py_
8
py
5
4.93
25
0.00
4
4
5.99
83
0
0.01
16
0.
0013
0.16
78
0
.017
1
0.
0001
0.0
001
0.00
01
10
1.13
C
261
B
_py_
9
py
5
4.55
5
0.00
63
45
.959
6
0
0.
0001
0.00
01
0.
1764
0.0
235
0.00
01
0
.000
1
0.
0001
100.
72
C27
8
A_p
y_1
p
y
52.
7368
0.
0011
46.2
506
0
0.00
01
0.
0024
0.07
14
0
.009
1
0.
0001
0.0
001
0.00
01
99
.07
C27
8
A_p
y_2
p
y
52.
7321
0.
0226
45.9
252
0
0.00
43
0.
0034
0.12
32
0
.019
2
0.
0058
0.0
001
0.00
01
98
.84
C27
8
A_p
y_3
p
y
52.
7502
0.
0094
45.9
748
0
0.00
01
0.
0016
0.06
88
0
.023
6
0.
0044
0.0
001
0.00
01
98
.83
C27
8
C_p
y_7
p
y
52.
7817
0.
0006
46.1
526
0
0.00
01
0.
0001
0.06
28
0
.013
3
0.
0065
0.0
001
0.00
01
99
.02
C27
8
C_p
y_8
p
y
52.
8407
0.
0001
45.9
292
0.0
189
0.00
01
0.
0085
0.13
04
0
.012
4
0.
0172
0.0
001
0.00
01
98
.96
C27
8
C_p
y_9
p
y
52.
9247
0.
0001
46.1
302
0
0.00
01
0.
0001
0.10
43
0
.013
6
0.
0141
0.0
001
0.00
01
99
.19
C28
0
A_p
y_1
p
y
53.
1281
0.
0001
46.1
506
0.0
004
0.00
01
0.
0001
0.06
8
0
.023
6
0.
0039
0.0
001
0.00
01
99
.38
C28
0
A_p
y_2
p
y
52.
9244
0.
0001
45.8
071
0.0
005
0.00
01
0.
0001
0.05
82
0
.022
0.
0001
0.0
001
0.00
01
98
.81
C28
0
A_p
y_3
p
y
52.
9082
0.
0001
46.0
846
0
0.00
01
0.
0001
0.06
92
0
.016
7
0.
0001
0.0
001
0.00
01
99
.08
C28
0
C_p
y_10
py
53.0
132
0.0
001
46.1
871
0.0
011
0.00
01
0.
0065
0.06
77
0
.014
1
0.
0009
0.0
001
0.00
01
99
.29
C28
0
C_p
y_11
py
52.6
556
0.0
001
46.1
68
0
0.00
79
0.
0001
0.07
48
0
.014
4
0.
0104
0.0
001
0.00
01
98
.93
C28
0
C_p
y_12
py
52.8
243
0.0
123
45.9
696
0
0.00
26
0.
0001
0.31
67
0
.016
4
0.
0213
0.0
001
0.00
01
99
.16
C28
4
A_p
y_1
p
y
52.
5448
0.
0098
44.7
633
0.0
077
0.02
46
0.
0089
0.09
04
0
.014
2
0.
0118
0.0
001
0.00
01
97
.48
C28
4
A_p
y_2
p
y
52.
9277
0.
004
44.
2976
0.
0304
0.0
144
0.00
01
0.
1931
0.0
136
0.00
68
0
.000
1
0.
0001
97.4
9 C
284
A
_py_
3
py
5
2.93
85
0.00
46
45
.578
6
0
.010
4
0.
0001
0.00
01
0.
1125
0.0
172
0.01
52
0
.000
1
0.
0001
98.6
8 C
284
C
_py_
13
py
52
.890
7
0
.000
1
45
.412
3
0
0.
0001
0.00
01
0.
1188
0.0
108
0.00
01
0
.015
2
0.
0001
98.4
5 C
284
C
_py_
14
py
52
.891
6
0
.000
1
45
.365
9
0
.020
2
0.
0107
0.00
42
0.
092
0.0
15
0.00
01
0
.000
1
0.
0001
98.4
0 C
284
C
_py_
15
py
53
.040
9
0
.006
7
45
.295
6
0
.014
1
0.
0001
0.00
13
0.
0907
0.0
14
0.00
01
0
.000
1
0.
0001
98.4
6 C
285
A
_py_
1
py
5
4.86
01
0.00
14
44
.773
0
0.
0001
0.00
59
0.
0724
0.0
095
0.00
67
0
.000
1
0.
0001
99.7
3 C
285
A
_py_
2
py
5
4.73
32
0.00
83
45
.067
9
0
.000
9
0.
0099
0.00
01
0.
0695
0.0
279
0.00
37
0
.000
1
0.
0001
99.9
2 C
285
A
_py_
3
py
5
4.88
06
0.00
01
45
.093
8
0
.153
5
0.
0001
0.01
29
0.
1401
0.0
116
0.00
04
0
.000
1
0.
0001
100.
29
C28
5
C_p
y_10
py
54.6
504
0.0
001
45.4
838
0.0
08
0.00
4
0
.009
3
0.
1967
0.0
167
0.00
7
0.00
01
0
.000
1
10
0.38
C
285
C
_py_
11
py
54
.888
3
0
.000
1
45
.383
7
0
.004
2
0.
0001
0.00
24
0.
1347
0.0
068
0.00
61
0
.029
3
0.
0001
100.
46
C28
5
C_p
y_12
py
54.8
679
0.0
001
45.5
957
0.1
071
0.01
27
0.
0017
0.13
62
0
.034
8
0.
0046
0.0
001
0.00
01
10
0.76
C
287
A
_py_
1
py
5
2.86
13
0.00
13
45
.318
6
0
0.
0001
0.00
24
0.
0682
0.0
076
0.00
89
0
.000
1
0.
0001
98.2
7 C
287
A
_py_
2
py
5
2.60
16
0.01
55
44
.477
1
0
0.
0001
0.01
31
0.
2093
0.0
141
0.01
33
0
.000
1
0.
0001
97.3
4 C
287
A
_py_
3
py
5
3.13
05
0.00
01
45
.483
0
.015
6
0.
0018
0.01
29
0.
0786
0.0
077
0.00
96
0
.000
1
0.
0001
98.7
4 C
290
A
_py_
1
py
5
2.69
78
0.00
01
46
.116
4
0
.01
0
.013
2
0.
0001
0.07
85
0
.016
9
0.
0001
0.0
001
0.00
01
98
.93
C29
0
A_p
y_2
p
y
52.
7928
0.
0001
45.9
229
0.0
062
0.00
02
0.
0042
0.08
06
0
.018
9
0.
0141
0.0
015
0.00
01
98
.84
C29
0
A_p
y_3
p
y
52.
7691
0.
0017
46.1
937
0.0
067
0.00
87
0.
0087
0.08
52
0
.010
2
0.
008
0.
0001
0.0
001
99.0
9 C
290
C
_py_
19
py
52
.547
4
0
.000
1
45
.549
4
0
0.
0001
0.01
51
0.
1975
0.0
165
0.01
34
0
.000
1
0.
0001
98.3
4 C
290
C
_py_
20
py
52
.915
1
0
.000
1
45
.926
0
.000
8
0.
0031
0.02
42
0.
1078
0.0
205
0.00
01
0
.000
1
0.
0001
99.0
0
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
21
C29
0
C_p
y_21
py
52.5
121
0.0
009
45.6
626
0
0.00
01
0.
0189
0.27
2
0
.011
4
0.
0105
0.0
001
0.00
01
98
.49
C29
2
A_p
y_4
p
y
52.
6689
0.
0001
46.5
969
0.0
042
0.00
01
0.
0001
0.08
0
.021
5
0.
0081
0.0
001
0.00
01
99
.38
C29
2
A_p
y_5
p
y
52.
7459
0.
0001
46.2
578
0
0.00
26
0.
0098
0.15
92
0
.017
9
0.
0027
0.0
001
0.00
01
99
.20
C29
2
A_p
y_6
p
y
52.
7231
0.
0004
46.1
774
0.0
014
0.00
08
0.
0001
0.07
62
0
.021
4
0.
0109
0.0
25
0.00
01
99
.04
C29
2
B_p
y_10
py
52.6
733
0.0
064
46.0
492
0
0.00
01
0.
0029
0.06
4
0
.013
8
0.
0113
0.0
157
0.00
01
98
.84
C29
2
B_p
y_11
py
52.8
625
0.0
001
46.0
903
0
0.00
01
0.
0001
0.06
05
0
.023
6
0.
0125
0.0
001
0.00
01
99
.05
C29
2
B_p
y_12
py
52.7
375
0.0
001
46.0
219
0.0
093
0.00
33
0.
0001
0.07
01
0
.014
8
0.
0092
0.0
001
0.00
01
98
.87
C29
2
B_p
y_7
p
y
52.
8056
0.
0001
46.1
454
0.0
011
0.00
56
0.
0009
0.06
61
0
.007
4
0.
0139
0.0
001
0.00
01
99
.05
C29
2
B_p
y_8
p
y
52.
8276
0.
0001
46.2
138
0
0.00
01
0.
0001
0.06
16
0
.023
4
0.
0001
0.0
001
0.00
01
99
.13
C29
2
B_p
y_9
p
y
52.
6641
0.
0001
46.1
172
0
0.00
01
0.
0113
0.14
9
0
.014
9
0.
0001
0.0
001
0.00
01
98
.96
C29
7
A_p
y_1
p
y
53.
0541
0.
0027
45.1
399
0.0
181
0.00
01
0.
0001
0.08
88
0
.010
9
0.
0141
0.0
105
0.00
01
98
.34
C29
7
A_p
y_2
p
y
53.
0324
0.
0061
45.3
837
0.0
1
0.0
001
0.00
01
0.
0977
0.0
143
0.00
01
0
.033
5
0.
0001
98.5
8 C
297
A
_py_
3
py
5
2.80
41
0.00
01
45
.396
7
0
0.
0001
0.00
01
0.
2803
0.0
215
0.00
01
0
.000
1
0.
0001
98.5
0 C
297
B
_py_
4
py
5
3.04
47
0.00
01
45
.078
8
0
0.
0072
0.00
01
0.
0746
0.0
192
0.00
75
0
.000
1
0.
0001
98.2
3 C
297
B
_py_
5
py
5
3.14
05
0.00
81
45
.325
1
0
.014
8
0.
0065
0.00
01
0.
0743
0.0
17
0.00
57
0
.000
1
0.
0001
98.5
9 C
297
B
_py_
6
py
5
2.84
41
0.00
01
44
.903
4
0
.006
7
0.
0001
0.01
7
0
.137
6
0.
0148
0.00
01
0
.000
1
0.
0001
97.9
2 C
297
D
_py_
16
py
52
.687
1
0
.000
6
45
.057
2
0
0.
0001
0.00
2
0
.281
9
0.
0208
0.00
01
0
.000
1
0.
0001
98.0
5 C
297
D
_py_
17
py
53
.147
7
0
.001
2
44
.837
2
0
0.
0168
0.00
01
0.
0631
0.0
14
0.00
01
0
.000
1
0.
0001
98.0
8 C
297
D
_py_
18
py
52
.921
4
0
.005
8
44
.913
4
0
.01
0
.014
7
0.
0001
0.07
02
0
.016
7
0.
0018
0.0
001
0.00
01
97
.95
C29
9
C_p
y_16
py
55.2
439
0.0
159
45.6
962
0.0
097
0.00
01
0.
0019
0.07
76
0
.012
5
0.
0086
0.0
001
0.00
01
10
1.07
C
299
C
_py_
17
py
55
.063
0
.004
3
45
.916
9
0
0.
0101
0.01
13
0.
0715
0.0
193
0.00
63
0
.000
1
0.
0001
101.
10
C29
9
C_p
y_18
py
55.1
001
0.0
001
45.1
442
0
0.00
01
0.
0058
0.07
08
0
.016
2
0.
0001
0.0
001
0.00
01
10
0.34
C
299
D
_py_
19
py
55
.180
5
0
.000
1
45
.400
9
0
.014
4
0.
0096
0.00
01
0.
0821
0.0
052
0.00
48
0
.000
1
0.
0001
100.
70
C29
9
D_p
y_20
py
54.9
828
0.0
001
45.7
139
0
0.00
67
0.
0001
0.05
64
0
.011
1
0.
0075
0.0
001
0.00
01
10
0.78
C
299
D
_py_
21
py
55
.123
5
0
.014
7
45
.418
7
0
0.
0001
0.00
97
0.
0598
0.0
095
0.00
01
0
.030
5
0.
0001
100.
67
C30
1
A_p
y_7
p
y
54.
5435
0.
0065
45.4
705
0.0
006
0.00
01
0.
0001
0.11
91
0
.020
1
0.
0003
0.0
001
0.00
01
10
0.16
C
301
A
_py_
8
py
5
4.73
54
0.00
05
45
.635
3
0
0.
004
0.0
001
0.10
8
0
.016
9
0.
0099
0.0
167
0.00
01
10
0.53
C
301
A
_py_
9
py
5
4.37
11
0.00
26
45
.695
5
0
.016
5
0.
0203
0.00
35
0.
2278
0.0
089
0.00
03
0
.035
3
0.
0006
100.
38
C30
1
B_p
y_10
py
54.7
786
0.0
051
45.9
85
0.0
023
0.00
01
0.
0339
0.07
16
0
.018
3
0.
0001
0.0
141
0.00
01
10
0.91
C
301
B
_py_
11
py
54
.474
0
.000
1
45
.294
6
0
0.
0108
0.00
01
0.
08
0.0
161
0.00
8
0.00
01
0
.020
8
99
.90
C30
1
B_p
y_12
py
53.7
734
0.0
001
45.0
45
0
0.00
39
0.
0001
1.73
63
0
.020
1
0.
0001
0.0
001
0.00
01
10
0.58
C
306
A
_py_
1
py
5
4.95
49
0.00
01
45
.508
3
0
.032
0.
0054
0.00
05
0.
074
0.0
132
0.00
01
0
.024
0.
0001
100.
61
C30
6
A_p
y_2
p
y
54.
885
0.
0001
45.1
077
0
0.00
56
0.
0001
0.16
31
0
.007
9
0.
0016
0.0
222
0.00
01
10
0.19
C
306
A
_py_
3
py
5
4.82
68
0.00
21
44
.419
3
0
.028
6
0.
0008
0.00
01
0.
393
0.0
147
0.00
01
0
.021
4
0.
0001
99.7
1 C
306
C
_py_
10
py
55
.290
9
0
.000
1
45
.067
0
0.
0001
0.00
63
0.
0707
0.0
113
0.00
01
0
.000
1
0.
0001
100.
45
C30
6
C_p
y_11
py
54.8
545
0.0
037
45.3
388
0.0
314
0.00
01
0.
01
0.0
882
0.00
79
0.
021
0.
0001
0.0
001
100.
36
C30
6
C_p
y_12
py
55.2
804
0.0
001
45.5
532
0
0.00
13
0.
0001
0.14
99
0
.013
7
0.
0121
0.0
001
0.00
01
10
1.01
C
307
A
_py_
1
py
5
2.80
48
0.00
01
46
.467
4
0
0.
0001
0.00
91
0.
1124
0.0
105
0.00
01
0
.000
1
0.
0001
99.4
0
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
22
C30
7
A_p
y_2
p
y
53.
0182
0.
0001
45.8
681
0
0.00
01
0.
006
0.0
828
0.00
98
0.
0085
0.0
001
0.00
01
98
.99
C30
7
A_p
y_3
p
y
52.
6584
0.
0001
46.2
356
0
0.00
01
0.
0001
0.11
52
0
.018
8
0.
0108
0.0
001
0.00
01
99
.04
C30
7
B_p
y_10
py
52.2
405
0.0
042
45.8
995
0
0.00
84
0.
0002
0.32
8
0
.009
0.
0001
0.0
001
0.00
01
98
.49
C30
7
B_p
y_11
py
52.6
334
0.0
001
45.9
824
0
0.00
01
0.
0001
0.27
25
0
.009
5
0.
0065
0.0
001
0.00
01
98
.90
C30
7
B_p
y_12
py
52.8
948
0.0
119
46.2
375
0
0.00
01
0.
0001
0.15
68
0
.011
0.
0004
0.0
001
0.00
01
99
.31
C30
7
B_p
y_7
p
y
52.
3158
0.
0001
45.9
248
0
0.00
01
0.
0001
0.37
27
0
.025
0.
0021
0.0
001
0.00
01
98
.64
C30
7
B_p
y_8
p
y
52.
5348
0.
0001
46.1
065
0
0.01
77
0.
0073
0.37
72
0
.021
3
0.
0001
0.0
001
0.00
01
99
.07
C30
7
B_p
y_9
p
y
52.
4007
0.
007
46.
1081
0
0.
0001
0.01
05
0.
388
0.0
223
0.00
77
0
.000
1
0.
0001
98.9
4 C
317
B
_py_
7
py
5
3.07
65
0.01
15
45
.755
6
0
.007
7
0.
0473
0.01
35
0.
103
0.0
187
0.00
23
0
.000
1
0.
0001
99.0
4 C
317
B
_py_
8
py
5
3.09
66
0.00
71
45
.766
1
0
0.
0457
0.00
01
0.
0984
0.0
213
0.00
01
0
.000
1
0.
0001
99.0
4 C
317
B
_py_
9
py
5
3.02
28
0.01
71
45
.446
9
0
.011
0.
0086
0.01
88
0.
148
0.0
145
0.01
1
0.00
01
0
.000
1
98
.70
C31
7
C_p
y_10
py
52.9
55
0.0
012
45.9
209
0.0
04
0.00
3
0
.000
1
0.
0635
0.0
11
0.00
51
0
.000
1
0.
0001
98.9
6 C
317
C
_py_
11
py
52
.831
9
0
.006
7
45
.685
0
.000
1
0.
0001
0.00
33
0.
0683
0.0
006
0.00
01
0
.000
1
0.
0001
98.6
0 C
317
C
_py_
12
py
52
.954
8
0
.019
4
45
.357
8
0
0.
0001
0.01
55
0.
0885
0.0
153
0.00
01
0
.000
1
0.
0001
98.4
5 C
320
A
_py_
1
py
5
2.82
28
0.00
78
45
.824
2
0
0.
0001
0.00
01
0.
0712
0.0
268
0.01
37
0
.004
0.
0001
98.7
7 C
320
A
_py_
2
py
5
2.88
95
0.00
08
45
.549
4
0
0.
0001
0.00
71
0.
0638
0.0
096
0.00
01
0
.000
1
0.
0001
98.5
2 C
320
A
_py_
3
py
5
2.96
9
0.00
01
45
.767
5
0
0.
0001
0.00
04
0.
0698
0.0
244
0.01
34
0
.000
1
0.
0001
98.8
4 C
320
A
_py_
4
py
5
2.79
74
0.00
01
45
.601
5
0
0.
0001
0.00
13
0.
078
0.0
155
0.00
87
0
.018
4
0.
0001
98.5
2 C
320
A
_py_
5
py
5
2.81
91
0.00
06
45
.801
5
0
0.
0001
0.00
01
0.
0882
0.0
134
0.00
01
0
.000
1
0.
0001
98.7
2 C
320
A
_py_
6
py
5
2.83
62
0.01
13
45
.656
1
0
0.
0034
0.00
01
0.
0961
0.0
169
0.00
01
0
.000
1
0.
0001
98.6
2 C
320
B
_py_
10
py
52
.682
7
0
.000
1
45
.915
7
0
0.
0003
0.00
41
0.
0698
0.0
212
0.01
23
0
.000
1
0.
0001
98.7
1 C
320
B
_py_
11
py
53
.002
9
0
.005
7
45
.653
6
0
0.
008
0.0
001
0.07
11
0
.015
7
0.
0071
0.0
001
0.00
01
98
.76
C32
0
B_p
y_12
py
53.0
167
0.0
074
45.8
078
0.0
125
0.00
01
0.
0161
0.06
73
0
.015
2
0.
0001
0.0
001
0.00
01
98
.94
C32
0
B_p
y_7
p
y
52.
8921
0.
0001
45.9
692
0.0
153
0.00
07
0.
0064
0.05
76
0
.018
9
0.
0001
0.0
001
0.00
01
98
.96
C32
0
B_p
y_8
p
y
52.
7957
0.
0001
45.7
805
0.0
397
0.00
14
0.
0001
0.06
7
0
.007
4
0.
0001
0.0
001
0.00
18
98
.69
C32
0
B_p
y_9
p
y
52.
9542
0.
0014
45.6
755
0.0
064
0.00
01
0.
0023
0.06
86
0
.018
6
0.
0034
0.0
115
0.00
01
98
.74
C32
3
B_p
y_7
p
y
53.
0448
0.
0001
45.7
66
0
0.00
01
0.
0059
0.05
93
0
.020
4
0.
0027
0.0
001
0.00
01
98
.90
C32
3
B_p
y_8
p
y
52.
7253
0.
0054
45.2
538
0.0
199
0.00
01
0.
0131
0.07
25
0
.016
9
0.
0017
0.0
001
0.00
01
98
.11
C32
3
B_p
y_9
p
y
52.
8438
0.
005
45.
378
0
0.
0001
0.02
49
0.
0645
0.0
166
0.00
01
0
.000
1
0.
0001
98.3
3 C
323
C
_py_
10
py
52
.880
9
0
.000
1
45
.517
4
0
0.
007
0.0
001
0.05
34
0
.021
7
0.
0001
0.0
001
0.00
01
98
.48
C32
3
C_p
y_11
py
52.9
591
0.0
001
45.6
058
0
0.00
03
0.
003
0.0
732
0.00
78
0.
0001
0.0
001
0.00
01
98
.65
C32
3
C_p
y_12
py
53.0
717
0.0
038
45.4
544
0
0.00
01
0.
0001
0.08
43
0
.010
5
0.
0001
0.0
001
0.00
01
98
.63
C32
6
A_p
y_1
p
y
51.
804
0.
0001
46.2
232
0
0.00
3
0
.000
1
0.
2532
0.0
187
0.00
27
0
.000
1
0.
0013
98.3
1 C
326
A
_py_
2
py
5
2.31
26
0.00
01
46
.472
1
0
0.
0128
0.00
01
0.
0754
0.0
121
0.01
38
0
.000
1
0.
0001
98.9
0 C
326
A
_py_
3
py
5
2.12
77
0.00
36
46
.239
7
0
0.
0022
0.00
89
0.
0828
0.0
157
0.00
46
0
.000
1
0.
0001
98.4
9 C
326
B
_py_
10
py
52
.347
4
0
.000
1
46
.435
6
0
.002
6
0.
0001
0.00
01
0.
0687
0.0
201
0.00
01
0
.000
1
0.
0001
98.8
8 C
326
B
_py_
11
py
52
.389
0
.000
1
46
.223
0
0.
0059
0.00
01
0.
11
0.0
182
0.00
07
0
.000
1
0.
0001
98.7
5 C
326
B
_py_
12
py
52
.362
8
0
.000
1
46
.282
5
0
0.
0022
0.00
01
0.
0681
0.0
209
0.00
11
0
.000
1
0.
0001
98.7
4
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
23
C32
6
B_p
y_T1
-01
py
52.1
944
0.0
171
46.2
105
0
0.00
99
0.
01
0.1
268
0.00
7
0
.009
0.
0001
0.0
001
98.5
8 C
326
B
_py_
T1-0
2
py
51
.494
9
0
.000
1
45
.946
2
0
0.
0001
0.01
86
1.
0822
0.0
167
0.00
88
0
.000
1
0.
0001
98.5
7 C
326
B
_py_
T1-0
3
py
51
.608
5
0
.000
1
45
.811
9
0
0.
0001
0.73
74
0.
1217
0.0
113
0.00
01
0
.000
1
0.
0001
98.2
9 C
326
B
_py_
T1-0
4
py
52
.16
0
.000
1
46
.058
3
0
0.
0201
0.04
21
0.
166
0.0
166
0.00
63
0
.000
1
0.
013
98.
48
C32
6
B_p
y_T1
-05
py
51.3
96
0.0
01
45.7
919
0.0
055
0.00
69
0.
9593
0.07
86
0
.015
5
0.
0057
0.0
001
0.00
01
98
.26
C32
6
B_p
y_T1
-06
py
52.3
296
0.0
001
46.2
341
0
0.00
01
0.
0043
0.06
1
0
.013
6
0.
0001
0.0
001
0.00
27
98
.65
C32
6
B_p
y_T1
-07
py
52.4
103
0.0
104
46.3
202
0.0
069
0.01
06
0.
0068
0.06
39
0
.023
7
0.
0058
0.0
001
0.00
01
98
.86
C32
6
B_p
y_T1
-08
py
52.3
854
0.0
033
46.4
218
0
0.00
01
0.
0028
0.06
7
0
.025
2
0.
0027
0.0
001
0.00
01
98
.91
C32
6
B_p
y_T1
-09
py
52.1
155
0.0
001
46.4
241
0
0.00
01
0.
0001
0.07
65
0
.023
8
0.
0088
0.0
001
0.00
01
98
.65
C32
6
B_p
y_T1
-10
py
52.3
414
0.0
001
46.5
704
0
0.00
01
0.
0001
0.06
57
0
.014
5
0.
0001
0.0
001
0.00
01
98
.99
C32
6
B_p
y_T1
-11
py
52.4
0.0
075
46.3
164
0
0.00
01
0.
0001
0.14
13
0
.022
0.
0109
0.0
001
0.00
01
98
.90
C32
6
B_p
y_T1
-12
py
52.0
716
0.0
063
46.2
08
0
0.00
6
0
.015
5
0.
097
0.0
139
0.00
54
0
.000
1
0.
0001
98.4
2 C
326
B
_py_
T1-1
3
py
52
.121
9
0
.012
7
45
.784
0
0.
0077
0.00
01
0.
0891
0.0
167
0.00
71
0
.000
1
0.
0001
98.0
4 C
326
C
_py_
T2-0
1
py
52
.238
1
0
.042
4
46
.196
9
0
.008
1
0.
0089
0.00
01
0.
0883
0.0
187
0.01
02
0
.015
7
0.
0001
98.6
3 C
326
C
_py_
T2-0
2
py
52
.329
6
0
.008
6
46
.364
4
0
.000
2
0.
0001
0.01
16
0.
105
0.0
139
0.00
88
0
.000
1
0.
0001
98.8
4 C
326
C
_py_
T2-0
3
py
52
.065
8
0
.000
1
46
.276
1
0
0.
025
0.0
001
0.08
96
0
.010
2
0.
0106
0.0
001
0.00
01
98
.48
C32
6
C_p
y_T2
-04
py
52.3
504
0.0
001
46.5
542
0
0.00
79
0.
0015
0.05
54
0
.005
9
0.
0001
0.0
045
0.00
01
98
.98
C32
6
C_p
y_T2
-05
py
51.9
487
0.0
294
46.0
259
0
0.00
01
0.
0129
0.05
2
0
.026
0.
0019
0.0
228
0.00
01
98
.12
C32
6
C_p
y_T2
-06
py
52.2
157
0.0
001
46.3
05
0
0.00
01
0.
0102
0.08
98
0
.015
8
0.
0031
0.0
001
0.00
01
98
.64
C32
6
C_p
y_T2
-07
py
51.7
961
0.0
001
46.1
42
0.0
091
0.00
01
0.
0104
0.08
91
0
.017
4
0.
0449
0.0
121
0.01
1
9
8.13
C
326
C
_py_
T2-0
8
py
52
.386
0
.000
1
46
.511
0
.003
7
0.
0001
0.00
01
0.
1031
0.0
154
0.00
01
0
.000
1
0.
0001
99.0
2 C
326
C
_py_
T2-0
9
py
52
.121
7
0
.004
46
.245
7
0
.000
3
0.
0001
0.00
22
0.
0659
0.0
216
0.00
01
0
.028
9
0.
0001
98.4
9 C
326
C
_py_
T2-1
0
py
52
.387
6
0
.013
1
46
.344
0
0.
0007
0.01
37
0.
0617
0.0
139
0.01
7
0.00
01
0
.000
1
98
.85
C32
6
C_p
y_T2
-11
py
52.4
937
0.0
001
46.3
559
0
0.00
91
0.
0048
0.08
09
0
.021
0.
0103
0.0
001
0.00
72
98
.98
C32
6
C_p
y_T2
-12
py
52.2
138
0.0
001
46.2
812
0.0
071
0.00
01
0.
0164
0.21
13
0
.017
5
0.
0229
0.0
001
0.00
01
98
.77
C32
6
C_p
y_T2
-13
py
52.0
631
0.0
127
46.1
996
0
0.01
24
0.
0137
0.25
04
0
.014
6
0.
0079
0.0
001
0.00
01
98
.57
C32
6
C_p
y_T2
-14
py
52.1
505
0.0
1
46.3
876
0
0.00
4
0
.000
1
0.
1554
0.0
137
0.00
01
0
.000
1
0.
0001
98.7
2 C
326
C
_py_
T2-1
5
py
52
.338
5
0
.000
1
46
.076
4
0
0.
0001
0.01
68
0.
1691
0.0
169
0.00
81
0
.002
9
0.
0049
98.6
3 C
326
C
_py_
T2-1
6
py
52
.470
4
0
.000
2
46
.450
1
0
0.
0001
0.00
01
0.
0871
0.0
149
0.00
92
0
.000
1
0.
0001
99.0
3 C
326
C
_py_
T2-1
7
py
52
.358
5
0
.000
1
46
.074
2
0
0.
0001
0.00
01
0.
0951
0.0
158
0.00
01
0
.019
7
0.
0001
98.5
6 C
329
aA
_py_
4
py
52
.154
2
0
.000
1
45
.390
6
0
.002
3
0.
0138
0.07
13
0.
6967
0.0
082
0.00
91
0
.000
1
0.
0001
98.3
5 C
329
aA
_py_
5
py
52
.895
7
0
.005
1
45
.477
4
0
0.
0036
0.02
53
0.
1416
0.0
11
0.00
67
0
.000
1
0.
0001
98.5
7 C
329
aA
_py_
6
py
52
.575
3
0
.003
9
45
.674
6
0
.000
1
0.
007
0.1
102
0.11
89
0
.015
2
0.
0044
0.0
001
0.00
01
98
.51
C32
9
aB_p
y_16
py
5
2.66
25
0.00
6
4
5.66
26
0.01
35
0
.000
1
0.
0001
0.10
69
0
.016
5
0.
0093
0.0
001
0.00
01
98
.48
C32
9
aB_p
y_17
py
5
2.86
6
0.00
01
45
.603
9
0
0.
0152
0.00
45
0.
0791
0.0
212
0.00
01
0
.000
1
0.
0001
98.5
9 C
329
aB
_py_
18
p
y
52.
863
0.
0037
45.7
18
0
0.00
55
0.
0017
0.09
54
0
.013
4
0.
0001
0.0
001
0.00
01
98
.70
C32
9
bA_p
y_1
py
55.0
144
0.0
067
46.0
495
0
0.03
47
0.
0011
0.27
29
0
.017
6
0.
021
0.
0001
0.0
001
101.
42
C32
9
bA_p
y_2
py
54.7
081
0.0
054
46.1
876
0
0.03
3
0
.000
1
0.
2216
0.0
232
0.01
25
0
.000
1
0.
0001
101.
19
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
24
C32
9
bA_p
y_3
py
54.8
774
0.0
125
46.0
683
0
0.00
2
0
.014
8
0.
094
0.0
177
0.01
45
0
.022
0.
0001
101.
12
C32
9
bC_p
y_16
py
5
4.58
41
0.01
63
46
.394
6
0
0.
0045
0.01
79
0.
0706
0.0
171
0.01
14
0
.000
1
0.
0001
101.
12
C32
9
bC_p
y_17
py
5
5.08
71
0.00
04
46
.202
8
0
0.
0059
0.00
44
0.
0984
0.0
123
0.00
01
0
.000
1
0.
0001
101.
41
C32
9
bC_p
y_18
py
5
5.07
23
0.00
25
46
.282
8
0
0.
0084
0.00
91
0.
12
0.0
204
0.00
01
0
.000
1
0.
0018
101.
52
C33
3
A_p
y_1
p
y
52.
7923
0.
0117
46.3
707
0
0.00
7
0
.005
5
0.
0763
0.0
169
0.02
5
0.00
01
0
.000
1
99
.31
C33
3
A_p
y_2
p
y
52.
9631
0.
0042
46.1
316
0.0
005
0.00
01
0.
008
0.0
728
0.00
71
0.
0001
0.0
001
0.00
01
99
.19
C33
3
A_p
y_3
p
y
52.
8413
0.
0001
46.2
668
0.0
001
0.00
01
0.
0001
0.07
37
0
.027
7
0.
0028
0.0
001
0.00
2
9
9.21
C
333
A
_py_
4
py
5
2.67
54
0.00
01
46
.174
8
0
.008
7
0.
0001
0.01
78
0.
063
0.0
104
0.00
01
0
.000
1
0.
0001
98.9
5 C
333
A
_py_
5
py
5
2.56
05
0.00
32
46
.105
3
0
.008
8
0.
0001
0.01
04
0.
0766
0.0
239
0.01
97
0
.031
3
0.
0001
98.8
4 C
333
A
_py_
6
py
5
2.64
11
0.00
66
45
.961
1
0
.007
4
0.
0055
0.00
01
0.
0871
0.0
242
0.00
08
0
.022
5
0.
0001
98.7
6 C
333
B
_py_
10
py
52
.883
4
0
.002
8
46
.102
1
0
.010
5
0.
0001
0.00
36
0.
0772
0.0
128
0.00
26
0
.000
1
0.
0001
99.1
0 C
333
B
_py_
11
py
52
.800
6
0
.000
1
46
.062
2
0
.002
7
0.
0017
0.00
01
0.
0845
0.0
152
0.01
06
0
.006
7
0.
0001
98.9
8 C
333
B
_py_
12
py
52
.895
0
.000
6
46
.210
5
0
.011
5
0.
0001
0.00
76
0.
0965
0.0
104
0.00
01
0
.000
1
0.
0001
99.2
3 C
333
B
_py_
13
py
52
.859
8
0
.005
1
46
.183
3
0
.003
8
0.
0146
0.00
01
0.
0755
0.0
107
0.00
02
0
.000
1
0.
0042
99.1
6 C
333
B
_py_
14
py
52
.887
6
0
.000
1
45
.817
4
0
.007
5
0.
0055
0.00
01
0.
0737
0.0
173
0.01
23
0
.000
1
0.
0001
98.8
2 C
333
B
_py_
15
py
52
.777
4
0
.000
1
46
.037
8
0
0.
0001
0.01
18
0.
0728
0.0
15
0.01
51
0
.000
1
0.
0001
98.9
3 C
337
A
_py_
1
py
5
1.69
52
0.00
01
46
.438
9
0
0.
0001
0.00
01
0.
1046
0.0
155
0.00
83
0
.000
1
0.
0001
98.2
6 C
337
A
_py_
2
py
5
1.92
13
0.00
01
45
.999
0
.005
1
0.
005
0.0
001
0.08
28
0
.007
0.
0237
0.0
001
0.00
01
98
.04
C33
7
A_p
y_3
p
y
51.
9155
0.
0056
46.2
592
0.0
172
0.00
44
0.
0001
0.13
19
0
.011
8
0.
0058
0.0
001
0.00
01
98
.35
C33
7
B_p
y_10
py
52.1
084
0.0
001
46.5
085
0
0.00
96
0.
0177
0.07
52
0
.014
2
0.
0001
0.0
001
0.00
01
98
.73
C33
7
B_p
y_11
py
52.3
115
0.0
084
46.3
478
0
0.00
86
0.
0042
0.06
89
0
.019
4
0.
007
0.
0013
0.0
001
98.7
8 C
337
B
_py_
12
py
52
.045
4
0
.000
1
46
.325
2
0
0.
0049
0.00
01
0.
0687
0.0
142
0.02
53
0
.000
1
0.
0001
98.4
8 C
341
A
_py_
1
py
5
5.17
57
0.00
21
46
.115
1
0
.003
6
0.
0034
0.00
01
0.
0622
0.0
178
0.01
51
0
.068
8
0.
0095
101.
47
C34
1
A_p
y_2
p
y
55.
1763
0.
0001
46.2
115
0.0
005
0.00
46
0.
0001
0.07
47
0
.016
4
0.
0011
0.0
001
0.00
01
10
1.49
C
341
A
_py_
3
py
5
5.20
45
0.00
19
46
.178
8
0
.001
7
0.
0052
0.01
97
0.
0816
0.0
094
0.00
93
0
.000
1
0.
0001
101.
51
C34
1
D_p
y_19
py
54.2
001
0.0
255
45.7
184
0
0.00
74
0.
0183
0.94
09
0
.024
9
0.
0001
0.0
001
0.00
01
10
0.94
C
341
D
_py_
20
py
54
.938
9
0
.024
9
45
.628
8
0
0.
0093
0.03
25
0.
3861
0.0
181
0.00
01
0
.000
1
0.
0001
101.
04
C34
1
D_p
y_21
py
55.0
363
0.0
388
45.9
927
0
0.00
51
0.
0001
0.49
54
0
.015
9
0.
0001
0.0
001
0.00
01
10
1.58
C
343
A
_py_
1
py
5
3.01
74
0.01
58
45
.631
3
0
.001
0.
0001
0.01
82
0.
074
0.0
112
0.00
05
0
.000
1
0.
0001
98.7
7 C
343
A
_py_
2
py
5
3.08
61
0.00
23
45
.756
9
0
0.
0001
0.00
01
0.
0606
0.0
068
0.00
8
0.00
01
0
.000
1
98
.92
C34
3
A_p
y_3
p
y
53.
072
0.
0001
46.0
441
0
0.00
01
0.
015
0.0
698
0.00
68
0.
0088
0.0
001
0.00
01
99
.22
C34
3
B_p
y_7
p
y
52.
8642
0.
0001
45.5
696
0
0.00
19
0.
0191
0.12
29
0
.011
4
0.
0001
0.0
001
0.00
01
98
.59
C34
3
B_p
y_8
p
y
52.
9527
0.
0047
45.4
387
0.0
116
0.00
39
0.
0001
0.07
69
0
.011
2
0.
0093
0.0
001
0.00
01
98
.51
C34
3
B_p
y_9
p
y
52.
8414
0.
0001
45.9
487
0
0.00
03
0.
0113
0.11
58
0
.016
9
0.
0043
0.0
152
0.00
01
98
.95
C34
5
A_p
y_1
p
y
55.
0126
0.
0164
45.7
245
0.0
145
0.00
01
0.
0237
0.07
33
0
.015
4
0.
0111
0.0
001
0.00
01
10
0.89
C
345
A
_py_
2
py
5
5.03
68
0.00
01
45
.988
0
0.
0001
0.00
01
0.
0727
0.0
233
0.00
93
0
.000
1
0.
0001
101.
13
C34
5
A_p
y_3
p
y
55.
025
0.
0066
46.0
33
0
0.01
33
0.
0126
0.07
46
0
.017
4
0.
0001
0.0
001
0.00
01
10
1.18
C
345
B
_py_
7
py
5
4.95
8
0.00
01
46
.124
0
0.
0081
0.00
59
0.
0775
0.0
198
0.00
12
0
.000
1
0.
0001
101.
19
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
25
C34
5
B_p
y_8
p
y
55.
0166
0.
0001
46.1
426
0
0.00
01
0.
0202
0.07
88
0
.016
6
0.
005
0.
0001
0.0
001
101.
28
C34
5
B_p
y_9
p
y
54.
9628
0.
0001
46.1
567
0
0.00
15
0.
0001
0.10
07
0
.023
0.
0039
0.0
461
0.00
01
10
1.30
C
350
A
_py_
1
py
5
2.90
41
0.00
08
46
.421
9
0
.002
4
0.
0001
0.00
47
0.
0717
0.0
115
0.00
45
0
.017
8
0.
0001
99.4
4 C
350
A
_py_
2
py
5
2.22
7
0.00
01
45
.874
0
0.
0001
0.00
01
0.
6888
0.0
115
0.01
49
0
.000
1
0.
0001
98.8
2 C
350
A
_py_
3
py
5
2.72
16
0.00
13
46
.059
1
0
.006
9
0.
0001
0.03
43
0.
2267
0.0
257
0.00
16
0
.000
1
0.
0001
99.0
8 C
350
B
_py_
4
py
5
2.69
51
0.00
19
46
.080
2
0
0.
0001
0.00
6
0
.080
7
0.
0172
0.00
93
0
.000
1
0.
0001
98.8
9 C
350
B
_py_
5
py
5
2.96
89
0.01
66
46
.220
7
0
0.
0188
0.01
6
0
.090
8
0.
0168
0.00
24
0
.000
1
0.
0001
99.3
5 C
350
B
_py_
6
py
5
2.85
45
0.00
81
46
.175
6
0
0.
0099
0.00
01
0.
0718
0.0
144
0.00
01
0
.000
1
0.
0001
99.1
3 C
350
C
_py_
10
py
52
.587
5
0
.003
46
.292
8
0
0.
0001
0.00
01
0.
0787
0.0
176
0.00
91
0
.000
1
0.
0001
98.9
9 C
350
C
_py_
11
py
52
.692
3
0
.000
1
46
.159
0
.003
5
0.
0001
0.00
01
0.
0904
0.0
205
0.00
4
0.00
01
0
.000
1
98
.97
C35
0
C_p
y_12
py
52.8
348
0.0
081
45.8
735
0.0
012
0.00
73
0.
0027
0.09
65
0
.009
6
0.
0024
0.0
001
0.00
01
98
.84
C35
3
A_p
y_1
p
y
52.
9587
0.
0001
45.8
401
0
0.00
01
0.
0075
0.05
73
0
.011
9
0.
0001
0.0
123
0.00
01
98
.89
C35
3
A_p
y_2
p
y
53.
0093
0.
0113
45.5
061
0
0.00
01
0.
0001
0.08
01
0
.014
9
0.
0023
0.0
001
0.00
01
98
.62
C35
3
A_p
y_3
p
y
53.
0879
0.
0129
45.7
141
0
0.00
01
0.
0144
0.06
49
0
.013
9
0.
0001
0.0
001
0.00
01
98
.91
C35
3
C_p
y_10
py
53.1
325
0.0
055
45.9
373
0
0.00
01
0.
0001
0.06
22
0
.018
4
0.
0001
0.0
001
0.00
01
99
.16
C35
3
C_p
y_11
py
52.9
778
0.0
333
45.7
997
0
0.00
01
0.
0001
0.07
41
0
.028
2
0.
0001
0.0
001
0.00
01
98
.91
C35
3
C_p
y_12
py
53.0
018
0.0
17
45.6
353
0
0.00
48
0.
0101
0.12
08
0
.009
5
0.
0043
0.0
001
0.00
01
98
.80
C35
5
A_p
y_T1
-01
py
52.7
313
0.0
063
46.2
436
0
0.00
29
0.
0305
0.13
53
0
.017
5
0.
0093
0.0
001
0.00
01
99
.18
C35
5
A_p
y_T1
-02
py
52.5
991
0.0
18
46.0
669
0
0.00
01
0.
0276
0.07
95
0
.022
3
0.
0074
0.0
374
0.00
01
98
.86
C35
5
A_p
y_T1
-03
py
52.4
094
0.0
048
46.2
659
0
0.00
01
0.
0001
0.06
97
0
.012
4
0.
0001
0.0
1
0.0
001
98.7
7 C
355
A
_py_
T1-0
4
py
52
.406
1
0
.002
7
46
.220
1
0
0.
006
0.0
17
0.12
99
0
.010
8
0.
0044
0.0
001
0.00
01
98
.80
C35
5
A_p
y_T1
-05
py
51.8
709
0.0
295
45.6
367
0
0.00
03
0.
8619
0.10
82
0
.012
6
0.
0235
0.0
001
0.00
01
98
.54
C35
5
A_p
y_T1
-06
py
52.1
289
0.0
149
46.0
573
0
0.00
87
0.
0173
0.53
17
0
.018
9
0.
0005
0.0
001
0.00
01
98
.78
C35
5
A_p
y_T1
-07
py
52.3
837
0.0
001
46.4
62
0
0.00
72
0.
0081
0.06
45
0
.018
3
0.
0005
0.0
218
0.00
01
98
.97
C35
5
A_p
y_T1
-08
py
52.2
036
0.0
001
46.4
409
0
0.00
01
0.
0001
0.06
41
0
.016
4
0.
0014
0.0
031
0.00
01
98
.73
C35
5
A_p
y_T1
-09
py
52.0
774
0.0
056
46.4
381
0
0.00
01
0.
015
0.1
169
0.01
45
0.
0028
0.0
001
0.00
01
98
.67
C35
5
A_p
y_T1
-10
py
52.4
275
0.0
001
46.4
179
0
0.00
45
0.
0001
0.06
49
0
.012
4
0.
0018
0.0
001
0.00
01
98
.93
C35
5
A_p
y_T2
-01
py
52.1
37
0.0
046
46.0
955
0.0
028
0.00
01
0.
0249
0.07
67
0
.025
1
0.
0236
0.0
001
0.00
01
98
.39
C35
5
A_p
y_T2
-02
py
52.3
2
0.0
001
46.3
278
0.0
039
0.00
01
0.
0001
0.08
35
0
.015
6
0.
0001
0.0
186
0.00
01
98
.77
C35
5
A_p
y_T2
-03
py
52.3
338
0.0
109
46.4
644
0.0
05
0.00
01
0.
0001
0.07
12
0
.019
7
0.
0084
0.0
001
0.00
01
98
.91
C35
5
A_p
y_T2
-04
py
52.4
974
0.0
001
46.4
5
0.
0266
0.0
024
0.00
01
0.
0684
0.0
136
0.01
39
0
.000
1
0.
0001
99.0
7 C
355
A
_py_
T2-0
5
py
52
.331
8
0
.012
1
46
.209
1
0
0.
0001
0.00
07
0.
153
0.0
175
0.00
01
0
.000
1
0.
0001
98.7
2 C
355
A
_py_
T2-0
7
py
52
.247
0
.000
1
46
.244
5
0
.003
6
0.
0001
0.00
01
0.
0664
0.0
206
0.00
01
0
.000
1
0.
0001
98.5
8 C
355
A
_py_
T2-0
8
py
52
.486
2
0
.004
8
46
.398
6
0
.002
0.
0001
0.00
52
0.
0893
0.0
139
0.00
01
0
.000
1
0.
0001
99.0
0 C
355
A
_py_
T2-0
9
py
52
.154
7
0
.000
1
46
.313
3
0
0.
0054
0.00
01
0.
075
0.0
105
0.01
72
0
.000
1
0.
0078
98.5
8 C
355
A
_py_
T3-0
1
py
52
.079
7
0
.000
1
46
.097
3
0
0.
0077
0.02
01
0.
0731
0.0
196
0.01
24
0
.000
1
0.
0001
98.3
1 C
355
A
_py_
T3-0
2
py
52
.065
3
0
.007
1
46
.138
5
0
0.
0116
0.00
94
0.
0789
0.0
108
0.00
01
0
.000
1
0.
0001
98.3
2 C
355
A
_py_
T3-0
3
py
52
.236
4
0
.000
1
46
.250
6
0
.034
5
0.
0001
0.00
01
0.
0672
0.0
132
0.00
62
0
.000
1
0.
0001
98.6
1
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
26
C35
5
A_p
y_T3
-04
py
52.4
6
0.
0036
46.
2622
0
0.
0001
0.03
49
0
.088
0.
0201
0.00
92
0
.000
1
0.
0001
98.
88
C35
5
A_p
y_T3
-05
py
52.0
502
0.0
001
46.3
596
0
0.0
001
0.00
01
0
.065
2
0.
0125
0.00
01
0
.017
0.
0001
98.
51
C35
5
A_p
y_T3
-06
py
52.1
008
0.0
013
46.3
331
0
0.0
087
0.00
37
0
.066
5
0.
0273
0.00
01
0
.016
5
0.
0001
98.
56
C35
5
A_p
y_T3
-07
py
52.0
723
0.0
001
46.4
896
0.0
024
0.00
77
0.
0037
0.0
876
0.01
17
0.
0005
0.0
001
0.00
01
9
8.68
C
355
A
_py_
T3-0
8
py
52
.163
7
0
.002
7
46
.511
2
0
.000
7
0.
0003
0.00
15
0
.079
5
0.
0164
0.00
28
0
.000
1
0.
0001
98.
78
C35
5
A_p
y_T3
-09
py
52.0
819
0.0
001
46.6
248
0
0.0
04
0.00
01
0
.077
5
0.
0147
0.00
44
0
.000
1
0.
0001
98.
81
C35
7
B_p
y_4
p
y
53
.076
8
0
.000
1
45
.204
6
0
0
.012
9
0.
0102
0.0
748
0.02
35
0.
0146
0.0
001
0.00
01
9
8.42
C
357
B
_py_
5
py
52.7
06
0.0
001
45.4
586
0.0
018
0.00
01
0.
0001
0.0
591
0.01
55
0.
0044
0.0
001
0.00
01
9
8.25
C
357
B
_py_
6
py
53.0
114
0.0
038
45.2
799
0
0.0
001
0.01
13
0
.077
0.
0236
0.01
81
0
.000
1
0.
0001
98.
43
C35
7
C_p
y_7
p
y
52
.821
4
0
.000
1
45
.179
1
0
0
.003
2
0.
0197
0.2
838
0.01
23
0.
0053
0.0
001
0.00
01
9
8.33
C
357
C
_py_
8
py
52.8
323
0.0
001
45.5
889
0
0.0
037
0.00
01
0
.139
4
0.
0226
0.00
33
0
.020
7
0.
0001
98.
61
C35
7
C_p
y_9
p
y
52
.981
6
0
.015
45
.810
3
0
0
.003
7
0.
0022
0.0
916
0.02
49
0.
0001
0.0
001
0.00
01
9
8.93
C
357
D
_py_
10
py
53
.027
0
.000
1
45
.676
3
0
.086
0.
0001
0.00
01
0
.073
6
0.
0143
0.01
27
0
.005
0.
0001
98.
90
C35
7
D_p
y_11
py
53.0
694
0.0
035
45.6
75
0
0.0
05
0.00
5
0.09
32
0
.007
4
0.
0044
0.0
001
0.00
01
9
8.86
C
357
D
_py_
12
py
52
.906
6
0
.002
7
45
.514
5
0
0
.008
4
0.
0126
0.0
73
0.01
11
0.
0074
0.0
001
0.00
14
9
8.54
C
359
A
_py_
1
py
52.9
171
0.0
121
45.6
074
0.0
081
0.00
43
0.
0137
0.0
677
0.00
74
0.
0065
0.0
083
0.00
07
9
8.65
C
359
A
_py_
2
py
52.8
529
0.0
001
45.5
705
0
0.0
056
0.01
11
0
.063
5
0.
0059
0.00
01
0
.000
1
0.
0001
98.
51
C35
9
A_p
y_3
p
y
52
.986
3
0
.003
1
45
.207
2
0
0
.001
0.
0024
0.0
563
0.01
96
0.
0001
0.0
001
0.00
01
9
8.28
C
359
B_
py_1
0
py
53
.070
4
0
.004
9
45
.668
5
0
0
.000
1
0.
0143
0.0
702
0.01
88
0.
0122
0.0
001
0.00
01
9
8.86
C
359
B_
py_1
1
py
53
.021
7
0
.025
45
.906
1
0
.001
7
0.
0001
0.00
01
0
.071
1
0.
0146
0.02
59
0
.000
1
0.
0001
99.
07
C35
9
B_py
_12
py
53.0
166
0.0
025
45.3
974
0.0
091
0.01
53
0.
0173
0.0
697
0.00
6
0
.000
1
0.
0192
0.00
01
9
8.55
C
362
B
_py_
7
py
52.5
715
0.0
021
45.9
71
0.0
004
0.00
01
0.
0001
0.1
316
0.02
71
0.
0001
0.0
001
0.00
01
9
8.70
C
362
B
_py_
8
py
52.5
217
0.0
025
45.7
217
0
0.0
001
0.01
13
0
.086
0.
0175
0.00
52
0
.000
1
0.
0001
98.
37
C36
2
B_p
y_9
p
y
52
.699
7
0
.000
1
45
.777
3
0
0
.000
1
0.
0001
0.1
095
0.01
65
0.
0079
0.0
001
0.01
27
9
8.62
C
362
C
_py_
16
py
52
.696
0
.002
3
46
.167
5
0
0
.005
6
0.
1059
0.0
818
0.01
72
0.
0175
0.0
001
0.00
91
9
9.10
C
362
C
_py_
17
py
52
.676
6
0
.000
1
45
.947
6
0
0
.007
3
0.
0363
0.0
987
0.01
3
0
.000
1
0.
0001
0.00
01
9
8.78
C
362
C
_py_
18
py
52
.556
6
0
.000
1
46
.251
3
0
0
.000
1
0.
0487
0.0
817
0.00
62
0.
0064
0.0
363
0.00
01
9
8.99
C
362
C
_py_
19
py
52
.631
4
0
.003
2
45
.451
0
0
.02
0.
0001
0.1
051
0.01
14
0.
0141
0.0
001
0.00
01
9
8.24
C
362
C
_py_
20
py
52
.541
2
0
.011
7
46
.016
3
0
0
.000
1
0.
0001
0.2
368
0.01
31
0.
0001
0.0
001
0.00
01
9
8.82
C
362
C
_py_
21
py
52
.580
4
0
.005
7
45
.773
9
0
.001
9
0.
001
0.0
001
0.09
81
0
.022
1
0.
0033
0.0
001
0.00
01
9
8.49
C
364
A
_py_
1
py
53.0
415
0.0
001
46.1
902
0
0.0
101
0.00
01
0
.083
2
0.
0176
0.01
25
0
.000
1
0.
0001
99.
36
C36
4
A_p
y_2
p
y
53
.130
2
0
.013
2
45
.787
4
0
0
.000
1
0.
0001
0.0
84
0.01
77
0.
0145
0.0
001
0.00
01
9
9.05
C
364
A
_py_
3
py
52.8
586
0.0
236
45.8
152
0
0.0
001
0.00
05
0
.088
6
0.
0196
0.00
61
0
.017
5
0.
0001
98.
83
C36
4
B_py
_19
py
53.0
223
0.0
162
45.8
59
0
0.0
001
0.01
53
0
.060
5
0.
0054
0.00
72
0
.000
1
0.
0091
99.
00
C36
4
B_py
_20
py
53.0
111
0.0
001
45.9
91
0
0.0
001
0.00
62
0
.071
4
0.
0093
0.02
51
0
.000
1
0.
0001
99.
11
C36
4
B_py
_21
py
52.7
583
0.0
001
46.0
419
0.0
014
0.00
01
0.
0053
0.0
771
0.01
18
0.
0031
0.0
001
0.00
01
9
8.90
C
365
A
_py_
1
py
53.1
189
0.0
001
45.3
418
0.0
067
0.00
01
0.
0041
0.0
702
0.01
54
0.
008
0.0
1
0.00
01
9
8.58
C
365
A
_py_
2
py
53.0
778
0.0
001
45.2
76
0
0.0
04
0.00
7
0.06
54
0
.007
2
0.
0001
0.0
001
0.00
01
9
8.44
sam
ple
poi
nt
typ
e W
%(S
)
W
%(M
n)
W%
(Fe)
W%
(Co)
W
%(N
i)
W%
(Cu)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Au)
W
%(B
i)
W%
(sum
)
Appendix 4: Microprobe Analysis—Sulphides
27
C36
5
A_p
y_3
p
y
52.
9496
0.
0001
45.7
021
0
0.00
91
0.
0092
0.08
53
0
.016
6
0.
0001
0.0
001
0.00
01
98
.77
C36
5
B_p
y_10
py
53.0
034
0.0
019
45.1
847
0
0.00
01
0.
0001
0.06
26
0
.011
0.
0076
0.0
001
0.00
01
98
.27
C36
5
B_p
y_11
py
52.8
757
0.0
088
45.5
28
0.0
04
0.01
06
0.
0144
0.06
96
0
.022
7
0.
0001
0.0
001
0.00
79
98
.54
C36
5
B_p
y_12
py
52.8
738
0.0
001
45.0
825
0.0
136
0.00
01
0.
0001
0.07
36
0
.021
4
0.
0172
0.0
001
0.00
01
98
.08
C36
5
B_p
y_7
p
y
51.
4385
0.
0001
44.9
181
0
0.00
35
0.
0007
2.52
15
0
.032
0.
015
0.
0003
0.0
001
98.9
3 C
365
B
_py_
8
py
5
2.62
4
0.00
29
45
.469
4
0
0.
0096
0.18
0
.090
8
0.
0161
0.00
78
0
.000
1
0.
0001
98.4
0 C
365
B
_py_
9
py
5
3.14
25
0.00
29
45
.678
0
0.
0001
0.01
55
0.
0738
0.0
123
0.00
36
0
.000
1
0.
0001
98.9
3 C
365
C
_py_
16
py
53
.191
0
.010
7
45
.825
4
0
.005
3
0.
0001
0.00
01
0.
0685
0.0
142
0.01
03
0
.000
1
0.
0001
99.1
3 C
365
C
_py_
17
py
52
.853
0
.000
1
45
.537
9
0
0.
0001
0.00
01
0.
0707
0.0
134
0.00
08
0
.000
1
0.
0001
98.4
8 C
365
C
_py_
18
py
53
.355
4
0
.000
1
45
.331
1
0
.009
1
0.
0067
0.00
06
0.
0754
0.0
154
0.00
78
0
.000
1
0.
0001
98.8
0 C
369
A
_py_
1
py
5
5.14
32
0.00
01
46
.162
2
0
0.
0047
0.01
02
0.
0675
0.0
112
0.00
48
0
.000
1
0.
0001
101.
40
C36
9
A_p
y_2
p
y
55.
0099
0.
0039
46.2
563
0
0.00
69
0.
0001
0.08
81
0
.010
2
0.
0048
0.0
001
0.00
01
10
1.38
C
369
A
_py_
3
py
5
5.12
81
0.00
48
45
.951
3
0
.064
6
0.
0143
0.00
2
0
.123
4
0.
0149
0.00
17
0
.000
1
0.
0001
101.
31
C36
9
B_p
y_7
p
y
54.
8624
0.
0067
46.0
292
0.0
049
0.00
35
0.
0113
0.13
5
0
.018
9
0.
0001
0.0
001
0.00
01
10
1.07
C
369
B
_py_
8
py
5
4.86
0.00
12
46
.249
7
0
.001
5
0.
0001
0.00
81
0.
0833
0.0
094
0.00
01
0
.000
1
0.
0001
101.
21
C36
9
B_p
y_9
p
y
55.
0788
0.
004
46.
2116
0.
0178
0.0
001
0.00
19
0.
0816
0.0
059
0.01
45
0
.000
1
0.
0001
101.
42
C37
2
A_p
y_4
p
y
54.
8668
0.
0001
45.5
332
0.0
105
0.00
01
0.
0001
0.13
75
0
.016
9
0.
0107
0.0
001
0.00
01
10
0.58
C
372
A
_py_
5
py
5
4.49
79
0.00
94
45
.639
1
0
0.
0001
0.00
01
0.
2132
0.0
226
0.01
61
0
.000
1
0.
0001
100.
40
C37
2
A_p
y_6
p
y
54.
5679
0.
0009
45.7
272
0
0.00
01
0.
0101
0.25
72
0
.016
6
0.
0022
0.0
229
0.00
01
10
0.61
C
372
B
_py_
10
py
54
.664
1
0
.000
1
44
.536
3
0
.015
2
0.
0001
0.00
88
0.
486
0.0
192
0.00
57
0
.000
1
0.
0001
99.7
4 C
372
B
_py_
11
py
54
.691
7
0
.000
1
45
.069
2
0
0.
0001
0.00
01
0.
2817
0.0
189
0.01
56
0
.000
1
0.
0001
100.
08
C37
2
B_p
y_12
py
54.9
591
0.0
001
45.8
252
0
0.00
27
0.
0001
0.15
26
0
.023
1
0.
0049
0.0
001
0.00
01
10
0.97
C
378
A
_py_
1
py
5
2.67
9
0.00
91
46
.029
7
0
0.
0147
0.01
18
0.
083
0.0
17
0.00
47
0
.000
1
0.
0001
98.8
5 C
378
A
_py_
2
py
5
2.61
79
0.00
01
45
.882
1
0
0.
0071
0.00
01
0.
1173
0.0
157
0.01
62
0
.027
3
0.
0001
98.6
8 C
378
A
_py_
3
py
5
3.01
59
0.00
01
45
.952
7
0
0.
0001
0.00
01
0.
064
0.0
151
0.00
29
0
.000
1
0.
0001
99.0
5 C
378
B
_py_
4
py
5
2.59
24
0.00
23
45
.873
8
0
0.
0038
0.00
01
0.
1945
0.0
243
0.00
01
0
.000
1
0.
0001
98.6
9 C
378
B
_py_
5
py
5
2.73
92
0.00
92
45
.948
0
0.
0001
0.00
01
0.
1583
0.0
061
0.00
21
0
.000
1
0.
0001
98.8
6 C
378
B
_py_
6
py
5
2.75
83
0.00
01
46
.168
0
0.
0111
0.00
42
0.
2149
0.0
237
0.00
62
0
.000
1
0.
0001
99.1
9 C
379
A
_py_
1
py
5
4.82
55
0.00
01
45
.376
6
0
.007
2
0.
005
0.0
001
0.06
28
0
.009
3
0.
0108
0.0
001
0.00
01
10
0.30
C
379
A
_py_
1
py
5
2.88
25
0.01
04
45
.567
9
0
0.
0001
0.00
01
0.
072
0.0
112
0.01
07
0
.000
1
0.
0001
98.5
6 C
379
A
_py_
2
py
5
3.10
06
0.00
79
45
.109
4
0
0.
0055
0.00
01
0.
0698
0.0
131
0.00
13
0
.000
1
0.
0001
98.3
1 C
379
A
_py_
2
py
5
5.12
42
0.00
01
45
.662
4
0
.006
3
0.
0001
0.00
82
0.
0588
0.0
211
0.00
41
0
.000
1
0.
0001
100.
89
C37
9
A_p
y_3
p
y
53.
2897
0.
0036
45.1
862
0.0
126
0.00
44
0.
0102
0.07
05
0
.018
6
0.
0008
0.0
001
0.00
01
98
.60
C37
9
A_p
y_3
p
y
55.
1155
0.
0001
45.5
96
0
0.00
83
0.
0001
0.06
33
0
.019
5
0.
0067
0.0
001
0.00
01
10
0.81
C
379
B
_py_
7
py
5
2.84
41
0.00
4
4
5.46
68
0
0.00
03
0.
0001
0.06
47
0
.009
8
0.
0001
0.0
001
0.00
01
98
.39
C37
9
B_p
y_7
p
y
55.
2126
0.
0087
46.2
27
0.0
015
0.00
01
0.
0217
0.06
7
0
.019
7
0.
0001
0.0
001
0.00
01
10
1.56
C
379
B
_py_
8
py
5
2.86
05
0.00
01
45
.403
1
0
.000
7
0.
0001
0.00
01
0.
0626
0.0
189
0.02
5
0.00
01
0
.000
1
98
.37
C37
9
B_p
y_8
p
y
55.
0461
0.
0106
46.0
566
0
0.00
53
0.
0001
0.07
07
0
.020
9
0.
012
0.
0001
0.0
001
101.
22
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
28
C37
9
B_p
y_9
p
y
53.
0066
0.
0094
45.3
579
0
0.01
06
0.
0001
0.05
87
0
.020
1
0.
0064
0.0
001
0.00
01
98
.47
C37
9
B_p
y_9
p
y
55.
2355
0.
0001
45.9
342
0
0.00
01
0.
0062
0.07
26
0
.011
4
0.
0001
0.0
001
0.00
01
10
1.26
C
379
C
_py_
16
py
55
.018
5
0
.011
9
45
.223
8
0
0.
0001
0.00
6
0
.087
7
0.
0104
0.00
57
0
.037
2
0.
0001
100.
40
C37
9
C_p
y_16
py
53.0
427
0.0
008
45.2
451
0
0.00
01
0.
0001
0.07
43
0
.019
7
0.
0019
0.0
001
0.00
01
98
.38
C37
9
C_p
y_17
py
53.0
054
0.0
001
44.8
529
0
0.00
02
0.
0044
0.06
67
0
.024
7
0.
0121
0.0
001
0.00
01
97
.97
C37
9
C_p
y_17
py
55.0
28
0.0
001
44.9
944
0
0.01
23
0.
0049
0.06
28
0
.018
8
0.
0046
0.0
001
0.00
01
10
0.13
C
379
C
_py_
18
py
54
.819
1
0
.000
1
45
.438
8
0
0.
0022
0.00
01
0.
0734
0.0
117
0.00
14
0
.000
1
0.
0001
100.
35
C37
9
C_p
y_18
py
52.9
741
0.0
001
45.5
259
0
0.00
01
0.
0001
0.06
24
0
.014
4
0.
0043
0.0
089
0.00
01
98
.59
C38
1
B_p
y_10
py
52.5
958
0.0
834
45.6
269
0
0.01
35
0.
0001
0.59
16
0
.017
8
0.
0131
0.0
001
0.00
01
98
.94
C38
1
B_p
y_11
py
52.8
488
0.0
694
45.7
286
0
0.00
01
0.
0152
0.24
67
0
.024
6
0.
0046
0.0
001
0.00
01
98
.94
C38
1
B_p
y_12
py
52.5
356
0.0
489
45.7
238
0
0.00
39
0.
0001
0.62
47
0
.018
4
0.
0001
0.0
001
0.00
01
98
.96
C38
3
A_p
y_1
p
y
52.
9155
0.
0001
45.8
983
0
0.00
61
0.
0047
0.06
65
0
.014
7
0.
0001
0.0
001
0.00
01
98
.91
C38
3
A_p
y_2
p
y
52.
9632
0.
0223
46.0
083
0
0.00
01
0.
0001
0.06
45
0
.013
6
0.
0098
0.0
001
0.00
01
99
.08
C38
3
A_p
y_3
p
y
52.
8728
0.
0001
45.8
524
0
0.02
94
0.
0001
0.06
01
0
.017
1
0.
0064
0.0
001
0.00
01
98
.84
C38
3
B_p
y_10
py
52.6
514
0.0
025
46.5
23
0
0.00
01
0.
0001
0.06
59
0
.022
3
0.
0078
0.0
292
0.00
13
99
.30
C38
3
B_p
y_11
py
52.5
514
0.0
04
46.2
192
0
0.00
07
0.
0053
0.07
05
0
.019
9
0.
0017
0.0
001
0.00
01
98
.87
C38
3
B_p
y_12
py
52.9
942
0.0
001
46.3
006
0.0
003
0.00
01
0.
0001
0.07
74
0
.020
2
0.
003
0.
0001
0.0
001
99.4
0 C
385
A
_py_
4
py
5
5.01
52
0.00
39
44
.676
2
0
.008
3
0.
0001
0.00
51
0.
0996
0.0
044
0.00
01
0
.000
1
0.
0001
99.8
1 C
385
A
_py_
5
py
5
5.14
17
0.00
01
44
.584
3
0
.021
8
0.
0107
0.00
48
0.
0879
0.0
123
0.00
57
0
.000
1
0.
0001
99.8
7 C
385
A
_py_
6
py
5
5.03
56
0.00
01
44
.458
1
0
0.
0001
0.00
54
0.
0717
0.0
207
0.00
01
0
.000
1
0.
0001
99.5
9 C
385
C
_py_
16
py
54
.916
5
0
.001
2
44
.524
1
0
0.
0001
0.00
01
0.
0737
0.0
087
0.00
83
0
.000
1
0.
0001
99.5
3 C
385
C
_py_
17
py
54
.914
2
0
.000
1
45
.458
9
0
0.
0071
0.00
01
0.
061
0.0
153
0.00
08
0
.000
1
0.
0001
100.
46
C38
5
C_p
y_18
py
55.0
651
0.0
001
44.5
534
0
0.01
19
0.
0001
0.06
38
0
.007
9
0.
0114
0.0
001
0.00
01
99
.71
C79
4
A_p
y_1
p
y
54.
0338
0.
0001
46.7
442
0
0.00
01
0.
0001
0.07
24
0
.022
2
0.
0001
0.0
001
0.00
01
10
0.87
C
794
A
_py_
2
py
5
4.12
76
0.01
27
46
.898
4
0
0.
0001
0.01
15
0.
0765
0.0
15
0.01
26
0
.018
5
0.
0001
101.
17
C79
4
A_p
y_3
p
y
53.
8586
0.
004
46.
5009
0.
0005
0.0
129
0.00
01
0.
0706
0.0
252
0.00
01
0
.000
1
0.
0001
100.
47
C79
5
A_p
y_1
p
y
53.
1931
0.
0117
47.6
583
0
0.00
01
0.
0001
0.27
08
0
.012
0.
0135
0.0
001
0.00
01
10
1.16
C
795
A
_py_
2
py
5
3.25
66
0.00
01
47
.467
8
0
0.
0055
0.01
43
0.
0973
0.0
239
0.01
3
0.00
81
0
.000
1
10
0.89
C
795
A
_py_
3
py
5
3.28
74
0.00
01
47
.696
4
0
.001
1
0.
0001
0.00
39
0.
059
0.0
08
0.00
39
0
.000
1
0.
0001
101.
06
C79
7
A_p
y_1
p
y
53.
326
0.
0094
47.7
66
0
0.02
11
0.
0001
0.07
28
0
.028
0.
0047
0.0
001
0.00
01
10
1.23
C
797
A
_py_
2
py
5
3.56
45
0.00
75
47
.808
5
0
.005
5
0.
0066
0.00
01
0.
0598
0.0
077
0.00
3
0.00
01
0
.000
1
10
1.46
C
797
A
_py_
3
py
5
3.30
63
0.00
66
47
.882
9
0
0.
0084
0.00
01
0.
0985
0.0
207
0.00
01
0
.000
1
0.
0001
101.
32
C80
1
A_p
y_1
p
y
53.
0281
0.
0081
47.4
517
0
0.00
01
0.
0001
0.06
44
0
.012
3
0.
0002
0.0
001
0.00
01
10
0.57
C
801
A
_py_
2
py
5
3.01
06
0.00
01
47
.415
3
0
0.
0001
0.00
01
0.
0667
0.0
167
0.00
36
0
.000
1
0.
0001
100.
51
C80
1
A_p
y_3
p
y
53.
4149
0.
0089
47.4
662
0
0.00
01
0.
0001
0.07
85
0
.015
8
0.
0001
0.0
001
0.00
13
10
0.99
C
802
B
_py_
4
py
5
3.62
26
0.00
23
47
.416
6
0
.025
9
0.
0001
0.02
33
0.
1281
0.0
153
0.01
93
0
.000
1
0.
0004
101.
25
C80
2
B_p
y_5
p
y
53.
803
0.
003
47.
2164
0.
0288
0.0
001
0.00
01
0.
1157
0.0
116
0.00
01
0
.000
1
0.
0001
101.
18
C80
2
B_p
y_6
p
y
53.
179
0.
0001
47.0
592
0.0
294
0.00
15
0.
003
0.2
003
0.01
49
0.
0041
0.0
13
0.00
01
10
0.50
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
29
C80
3
A_p
y_1
p
y
53.
7238
0.
0057
46.4
979
0.0
03
0.00
47
0.
0001
0.09
12
0
.009
6
0.
0163
0.0
001
0.00
01
10
0.35
C
803
A
_py_
2
py
5
3.83
12
0.00
32
46
.940
8
0
0.
0089
0.00
96
0.
1018
0.0
195
0.01
31
0
.000
1
0.
0002
100.
93
C80
3
A_p
y_3
p
y
53.
6781
0.
0001
46.5
968
0
0.00
01
0.
0441
0.22
36
0
.021
9
0.
0001
0.0
001
0.00
09
10
0.57
C
804
B
_py_
4
py
5
3.75
46
0.14
77
46
.753
3
0
0.
0023
0.00
26
0.
0876
0.0
118
0.00
01
0
.044
2
0.
0308
100.
84
C80
4
B_p
y_5
p
y
52.
2461
0.
013
45.
2033
0
0.
0062
0.21
51
2.
9675
0.0
417
0.01
4
0.00
01
0
.000
1
10
0.71
C
804
B
_py_
6
py
5
3.93
41
0.00
59
46
.622
5
0
0.
0001
0.03
39
0.
282
0.0
206
0.00
01
0
.002
1
0.
0001
100.
90
C81
2
A_p
y_1
p
y
53.
0321
0.
0038
47.1
349
0
0.09
39
0.
0001
0.37
08
0
.019
7
0.
0061
0.0
073
0.00
01
10
0.67
C
812
A
_py_
2
py
5
3.12
27
0.00
77
47
.190
1
0
0.
0428
0.00
01
0.
1938
0.0
113
0.00
91
0
.000
1
0.
0001
100.
58
C81
2
A_p
y_3
p
y
53.
2209
0.
0017
47.2
698
0
0.04
01
0.
0115
0.18
35
0
.015
2
0.
0098
0.0
057
0.00
01
10
0.76
C
813
B
_py_
4
py
5
3.20
5
0.00
04
47
.842
3
0
.003
8
0.
0055
0.00
01
0.
078
0.0
095
0.00
81
0
.013
8
0.
0001
101.
17
C81
3
B_p
y_5
p
y
53.
1588
0.
0062
47.6
706
0.0
075
0.00
34
0.
0001
0.08
12
0
.009
5
0.
0164
0.0
001
0.00
01
10
0.95
C
813
B
_py_
6
py
5
3.58
95
0.01
44
47
.567
7
0
0.
0084
0.00
01
0.
0767
0.0
165
0.00
01
0
.000
1
0.
0001
101.
27
C81
5
A_p
y_1
p
y
53.
3421
0.
0074
47.9
216
0
0.03
6
0
.015
6
0.
0839
0.0
184
0.00
82
0
.000
1
0.
0001
101.
43
C81
5
A_p
y_2
p
y
53.
1156
0.
0001
47.9
754
0
0.01
53
0.
0001
0.09
55
0
.014
0.
0095
0.0
001
0.00
01
10
1.23
C
815
A
_py_
3
py
5
3.19
39
0.00
01
47
.733
5
0
0.
0037
0.01
61
0.
1012
0.0
13
0.00
49
0
.000
1
0.
0001
101.
07
C81
7
B_p
y_4
p
y
54.
0448
0.
0034
46.5
017
0.0
086
0.00
74
0.
0001
0.12
36
0
.017
9
0.
0053
0.0
001
0.00
01
10
0.71
C
817
B
_py_
5
py
5
4.25
05
0.00
01
46
.919
0
0.
0001
0.00
01
0.
1184
0.0
214
0.00
17
0
.005
7
0.
0001
101.
32
C81
7
B_p
y_6
p
y
54.
2582
0.
0001
46.7
372
0
0.00
65
0.
0089
0.10
31
0
.016
5
0.
0162
0.0
001
0.00
01
10
1.15
C
820
A
_py_
1
py
5
2.93
17
0.01
39
47
.778
4
0
0.
0001
0.00
01
0.
1495
0.0
245
0.01
08
0
.000
1
0.
0001
100.
91
C82
0
A_p
y_2
p
y
52.
5005
0.
0028
47.7
357
0
0.00
01
0.
0001
0.50
76
0
.009
3
0.
0129
0.0
568
0.00
01
10
0.83
C
820
A
_py_
3
py
5
2.96
86
0.04
29
47
.689
3
0
0.
0008
0.00
59
0.
2202
0.0
188
0.01
11
0
.000
1
0.
0001
100.
96
C82
3
A_p
y_1
p
y
52.
7651
0.
0013
47.7
787
0
0.01
85
0.
0154
0.06
43
0
.021
9
0.
0001
0.0
001
0.00
01
10
0.67
C
823
A
_py_
2
py
5
3.32
02
0.00
17
48
.026
3
0
0.
0001
0.00
78
0.
0605
0.0
259
0.00
57
0
.038
7
0.
0001
101.
49
C82
3
A_p
y_3
p
y
53.
0077
0.
0036
48.0
401
0
0.01
01
0.
0001
0.07
86
0
.009
9
0.
0062
0.0
057
0.00
01
10
1.16
C
824
B
_py_
4
py
5
2.98
73
0.00
01
47
.472
7
0
0.
0042
0.01
57
0.
1721
0.0
136
0.01
41
0
.000
1
0.
0001
100.
68
C82
4
B_p
y_5
p
y
53.
1274
0.
0045
47.5
9
0
0.
0017
0.00
01
0.
1089
0.0
119
0.00
36
0
.000
1
0.
0001
100.
85
C82
4
B_p
y_6
p
y
53.
1649
0.
007
47.
4779
0
0.
0001
0.00
3
0
.184
9
0.
0176
0.00
3
0.02
56
0
.000
1
10
0.88
C
825
A
_py_
1
py
5
3.36
97
0.01
08
47
.716
5
0
.027
2
0.
0195
0.00
57
0.
0869
0.0
156
0.00
22
0
.001
8
0.
0001
101.
26
C82
5
A_p
y_2
p
y
53.
0177
0.
0001
47.3
181
0.0
304
0.00
01
0.
0094
0.09
13
0
.019
7
0.
0036
0.0
029
0.00
01
10
0.49
C
825
A
_py_
3
py
5
3.03
56
0.00
01
47
.268
5
0
0.
0313
0.00
01
0.
0902
0.0
049
0.00
01
0
.000
1
0.
0001
100.
43
C82
8
A_p
y_1
p
y
52.
9792
0.
0001
47.5
161
0
0.00
01
0.
0265
0.08
05
0
.015
6
0.
0001
0.0
001
0.00
01
10
0.62
C
828
A
_py_
2
py
5
2.78
24
0.00
17
47
.472
3
0
0.
0055
0.00
83
0.
1072
0.0
093
0.01
19
0
.000
1
0.
0001
100.
40
C82
8
A_p
y_3
p
y
53.
3193
0.
0023
47.6
55
0
0.00
25
0.
0239
0.14
36
0
.015
6
0.
0029
0.0
001
0.00
01
10
1.17
C
832
A
_py_
1
py
5
3.86
33
0.00
01
46
.924
2
0
0.
0001
0.00
94
0.
0645
0.0
139
0.00
07
0
.000
1
0.
0001
100.
88
C83
2
A_p
y_2
p
y
53.
9892
0.
0115
46.4
19
0
0.00
01
0.
0001
0.06
45
0
.026
1
0.
0054
0.0
001
0.00
01
10
0.52
C
832
A
_py_
3
py
5
3.81
15
0.00
77
46
.843
5
0
0.
0032
0.00
22
0.
0692
0.0
189
0.00
01
0
.000
1
0.
01
100
.77
C83
4
A_p
y_1
p
y
52.
8983
0.
0141
47.3
896
0
0.00
01
0.
0813
0.07
58
0
.009
0.
0001
0.0
001
0.00
01
10
0.47
C
834
A
_py_
2
py
5
2.59
02
0.00
85
47
.336
4
0
0.
0001
0.00
01
1.
0681
0.0
247
0.00
01
0
.000
1
0.
0001
101.
03
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
30
C83
4
A_p
y_3
p
y
53.
3778
0.
0001
47.5
303
0
0.00
05
0.
0087
0.15
41
0
.02
0.
0002
0.0
001
0.00
01
10
1.09
C
835
A
_py_
1
py
5
3.11
9
0.00
01
47
.424
4
0
0.
0234
0.00
82
0.
0674
0.0
089
0.00
01
0
.000
1
0.
0001
100.
65
C83
5
A_p
y_2
p
y
53.
3086
0.
0001
47.3
213
0
0.00
01
0.
0135
0.07
45
0
.020
8
0.
0001
0.0
001
0.00
01
10
0.74
C
835
A
_py_
3
py
5
3.15
93
0.00
01
47
.225
7
0
0.
015
0.0
082
0.07
84
0
.008
0.
0163
0.0
001
0.00
01
10
0.51
C
836
A
_py_
1
py
5
3.15
34
0.00
28
47
.500
4
0
0.
0001
0.00
65
0.
1193
0.0
19
0.00
45
0
.024
6
0.
0001
100.
83
C83
6
A_p
y_2
p
y
52.
9614
0.
0049
47.3
74
0.0
013
0.01
29
0.
0001
0.11
42
0
.020
6
0.
0001
0.0
001
0.00
01
10
0.49
C
836
A
_py_
3
py
5
3.39
99
0.00
01
47
.647
7
0
0.
0001
0.00
01
0.
0926
0.0
177
0.00
18
0
.000
1
0.
0001
101.
16
C84
0
A_p
y_1
p
y
52.
8277
0.
0247
46.0
981
0.0
054
0.01
2
0
.000
1
1.
2553
0.0
149
0.00
65
0
.000
1
0.
0001
100.
24
C84
0
A_p
y_2
p
y
54.
2932
0.
0134
46.7
439
0
0.00
55
0.
0148
0.08
75
0
.014
7
0.
0144
0.0
001
0.00
01
10
1.19
C
840
A
_py_
3
py
5
4.12
68
0.00
64
46
.606
5
0
0.
0001
0.00
01
0.
0669
0.0
127
0.00
01
0
.000
1
0.
0001
100.
82
C84
8
A_p
y_1
p
y
52.
7985
0.
0001
47.6
733
0
0.01
09
0.
0117
0.08
8
0
.017
3
0.
0069
0.0
239
0.00
01
10
0.63
C
848
A
_py_
2
py
5
2.81
78
0.00
45
47
.806
7
0
.000
4
0.
0002
0.00
11
0.
0702
0.0
159
0.00
42
0
.000
1
0.
0001
100.
72
C84
8
A_p
y_3
p
y
52.
8729
0.
0113
47.7
857
0
0.01
28
0.
0001
0.06
64
0
.013
6
0.
0107
0.0
001
0.00
01
10
0.77
C
849
A
_py_
7-7-
1
py
5
2.70
55
0.00
78
46
.212
7
0
.002
9
0.
1267
0.00
01
0.
0853
0.0
257
0.00
03
0
.000
1
0.
0001
99.1
7 C
849
A
_py_
8-8-
1
py
5
2.49
86
0.00
01
46
.723
2
0
0.
1054
0.01
28
0.
0669
0.0
199
0.00
01
0
.000
1
0.
0001
99.4
3 C
849
A
_py_
9-9-
1
py
5
2.58
62
0.00
01
46
.286
2
0
0.
2118
0.00
01
0.
0902
0.0
265
0.00
16
0
.004
5
0.
0001
99.2
1 R
001
A
_py_
1
py
5
1.95
97
0.00
42
46
.212
6
0
0.
0001
0.00
01
0.
0728
0.0
127
0.00
01
0
.000
1
0.
0001
98.2
6 R
001
A
_py_
2
py
5
2.47
2
0.00
01
46
.078
8
0
.101
0.
0001
0.01
33
0.
0918
0.0
191
0.00
35
0
.000
1
0.
0001
98.7
8 R
001
A
_py_
3
py
5
2.47
15
0.00
52
46
.187
0
0.
0001
0.00
01
0.
1038
0.0
046
0.01
55
0
.000
1
0.
0001
98.7
9 R
001
B
_py_
7
py
5
2.44
74
0.00
55
46
.235
0
0.
0059
0.02
26
0.
1024
0.0
118
0.00
68
0
.000
1
0.
0001
98.8
4 R
001
B
_py_
8
py
5
2.81
34
0.00
36
46
.141
3
0
.036
5
0.
0001
0.00
01
0.
0879
0.0
124
0.00
01
0
.034
3
0.
0001
99.1
3 R
001
B
_py_
9
py
5
2.51
54
0.01
24
46
.145
1
0
.036
1
0.
0039
0.00
29
0.
0898
0.0
229
0.00
38
0
.000
1
0.
0001
98.8
3 R
003
A
_py_
1
py
5
3.06
09
0.00
8
4
6.05
45
0
0.00
01
0.
016
0.0
66
0.01
29
0.
0001
0.0
001
0.00
01
99
.22
R00
3
A_p
y_2
p
y
52.
9818
0.
0001
46.2
21
0
0.01
31
0.
0105
0.06
19
0
.016
5
0.
0112
0.0
001
0.00
28
99
.32
R00
3
A_p
y_3
p
y
52.
8696
0.
0001
45.8
796
0
0.00
27
0.
0203
0.06
22
0
.018
6
0.
0016
0.0
001
0.00
01
98
.85
R00
3
B_p
y_7
p
y
53.
0521
0.
0148
46.0
533
0.0
009
0.00
48
0.
0001
0.06
98
0
.023
3
0.
011
0.
0001
0.0
001
99.2
3 R
003
B
_py_
8
py
5
3.13
21
0.00
78
46
.231
6
0
0.
0026
0.00
92
0.
0554
0.0
211
0.01
65
0
.000
1
0.
0001
99.4
8 R
003
B
_py_
9
py
5
3.09
85
0.00
72
45
.941
1
0
0.
0001
0.00
53
0.
0838
0.0
153
0.00
3
0.00
43
0
.000
1
99
.16
R07
5
A_p
y_4-
4-1
p
y
53.
0087
0.
0093
46.4
499
0
0.00
01
0.
0084
0.07
37
0
.018
4
0.
0001
0.0
001
0.00
01
99
.57
R07
5
A_p
y_5-
5-1
p
y
53.
3661
0.
0001
46.4
544
0
0.00
01
0.
0074
0.08
28
0
.007
9
0.
0004
0.0
001
0.00
01
99
.92
R07
5
A_p
y_6-
6-1
p
y
52.
6817
0.
0001
46.3
684
0.0
079
0.00
01
0.
0001
0.06
89
0
.019
0.
0085
0.0
001
0.00
13
99
.16
R07
8
A_p
y_10
-10-
1 py
52.6
033
0.0
153
46.0
955
0
0.01
08
0.
0001
0.12
19
0
.019
4
0.
0001
0.0
001
0.00
01
98
.87
R07
8
A_p
y_11
-11-
1 py
52.8
584
0.0
035
46.2
648
0
0.00
15
0.
0001
0.17
1
0
.018
5
0.
0001
0.0
045
0.00
01
99
.32
R07
8
A_p
y_12
-12-
1 py
52.8
658
0.0
073
45.6
917
0
0.00
01
0.
0047
0.07
34
0
.012
0.
0001
0.0
453
0.00
01
98
.70
R07
8
A_p
y_7-
7-1
p
y
52.
6807
0.
0031
46.4
874
0
0.00
36
0.
0011
0.11
87
0
.010
6
0.
0014
0.0
001
0.00
01
99
.31
R07
8
A_p
y_8-
8-1
p
y
53.
1797
0.
0046
46.4
411
0
0.00
21
0.
0001
0.08
56
0
.013
9
0.
0117
0.0
001
0.00
01
99
.74
R07
8
A_p
y_9-
9-1
p
y
53.
0229
0.
0138
46.3
237
0
0.00
01
0.
0075
0.07
14
0
.02
0.
0001
0.0
001
0.00
01
99
.46
sam
ple
poi
nt
typ
e W
%(S
)
W%
(Mn)
W
%(F
e)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
31
C07
9
_sp_
7
s
p
32.5
845
0.
0445
1.81
95
0
.005
0
0.
0001
0.0
100
67.3
113
0.
0185
0.0
236
0.00
80
0
.177
6
10
2.00
C
079
_s
p_8
sp
32
.619
8
0.04
12
1.
8939
0.0
000
0.00
01
0
.018
3
67
.496
9
0.02
99
0
.028
8
0.
0067
0.1
783
102.
31
C07
9
_sp_
9
s
p
32.6
287
0.
0287
1.85
05
0
.005
6
0.
0016
0.0
246
67.2
151
0.
0259
0.0
067
0.00
01
0
.203
0
10
1.99
C
082
_s
p_7
sp
32
.926
7
0.08
46
6.
8858
0.0
000
0.00
01
2
.446
6
58
.459
5
0.03
48
0
.026
8
0.
0226
0.1
574
101.
04
C08
2
_sp_
8
s
p
33.0
848
0.
0578
7.36
48
0
.002
1
0.
0032
3.1
292
57.1
413
0.
0427
0.0
233
0.00
01
0
.177
9
10
1.03
C
082
_s
p_9
sp
32
.913
0
0.05
31
7.
3504
0.0
000
0.01
00
2
.839
3
57
.939
1
0.03
39
0
.020
9
0.
0268
0.1
820
101.
37
C21
1
A_s
p_1
s
p
34.3
962
0.
6604
10.8
046
0
.000
0
0.
0042
0.0
807
54.2
529
0.
0452
0.0
164
0.00
01
0
.206
5
10
0.47
C
211
A
_sp_
2
sp
34
.136
9
0.64
49
10
.865
5
0.0
000
0.00
01
0
.104
2
53
.940
4
0.04
83
0
.022
5
0.
0001
0.2
213
99.9
8 C
211
A
_sp_
3
sp
34
.322
9
0.68
11
11
.004
3
0.0
000
0.00
77
0
.100
0
53
.600
1
0.03
89
0
.031
1
0.
0140
0.1
908
99.9
9 C
211
A
_sp_
4
sp
34
.353
0
0.67
67
10
.925
5
0.0
000
0.00
01
0
.132
3
54
.134
1
0.03
80
0
.025
9
0.
0001
0.2
003
100.
49
C21
1
A_s
p_5
s
p
34.2
805
0.
6459
10.8
008
0
.000
0
0.
0001
0.1
219
53.9
071
0.
0434
0.0
021
0.00
01
0
.196
6
10
0.00
C
211
A
_sp_
6
sp
34
.399
1
0.66
44
10
.847
7
0.0
000
0.00
01
0
.117
2
54
.202
0
0.04
57
0
.019
7
0.
0001
0.1
935
100.
49
C21
1
A_s
p_7
s
p
34.8
296
0.
6233
10.5
371
0
.000
0
0.
0001
0.1
047
54.3
628
0.
0483
0.0
091
0.00
20
0
.204
3
10
0.72
C
211
A
_sp_
8
sp
34
.622
3
0.62
82
10
.516
6
0.0
000
0.00
93
0
.090
3
54
.322
4
0.03
85
0
.026
3
0.
0001
0.2
146
100.
47
C21
1
A_s
p_9
s
p
34.8
620
0.
6704
10.6
076
0
.000
0
0.
0001
0.1
195
54.1
467
0.
0480
0.0
164
0.00
01
0
.229
5
10
0.70
C
211
B_
sp_1
0
sp
34.7
286
0.
6202
10.5
786
0
.000
0
0.
0001
0.1
648
54.3
616
0.
0378
0.0
156
0.00
01
0
.189
0
10
0.70
C
211
B_
sp_1
1
sp
34.6
891
0.
6525
10.5
900
0
.000
0
0.
0076
0.1
811
54.1
922
0.
0406
0.0
239
0.00
01
0
.182
3
10
0.56
C
211
B_
sp_1
2
sp
34.7
797
0.
6061
10.4
284
0
.000
0
0.
0132
0.1
315
54.4
772
0.
0331
0.0
106
0.01
30
0
.207
2
10
0.70
C
278
B
_sp_
4
sp
33
.090
6
0.29
07
6.
6635
0.0
000
0.00
06
0
.027
6
59
.807
2
0.01
80
0
.021
2
0.
0015
0.1
811
100.
10
C27
8
B_s
p_5
s
p
33.0
321
0.
3122
6.44
65
0
.001
1
0.
0029
0.0
281
59.7
456
0.
0400
0.0
250
0.00
49
0
.150
1
99
.79
C27
8
B_s
p_6
s
p
32.9
148
0.
2978
6.34
46
0
.000
0
0.
0001
0.0
198
60.0
288
0.
0383
0.0
142
0.00
01
0
.153
1
99
.81
C28
0
B_s
p_4
s
p
33.3
455
0.
2782
5.65
74
0
.000
0
0.
0001
0.0
106
60.7
033
0.
0390
0.0
154
0.00
24
0
.194
3
10
0.25
C
280
B
_sp_
5
sp
33
.085
0
0.27
55
5.
3569
0.0
000
0.00
01
0
.020
5
60
.958
3
0.04
31
0
.019
2
0.
0001
0.1
847
99.9
4 C
280
B
_sp_
6
sp
32
.786
0
0.27
52
5.
4471
0.0
000
0.00
01
0
.018
4
61
.042
4
0.03
30
0
.017
2
0.
0001
0.1
760
99.8
0 C
284
A
_sp_
4
sp
33
.435
4
0.13
74
5.
0201
0.0
037
0.00
67
0
.000
1
60
.222
4
0.03
53
0
.013
8
0.
0193
0.1
865
99.0
8 C
284
A
_sp_
5
sp
33
.211
5
0.12
72
4.
9859
0.0
000
0.00
81
0
.018
5
58
.763
8
0.02
91
0
.016
2
0.
0001
0.1
646
97.3
3 C
284
A
_sp_
6
sp
33
.235
0
0.12
83
4.
8344
0.0
147
0.00
45
0
.002
6
59
.437
0
0.04
70
0
.024
1
0.
0001
0.1
624
97.8
9 C
284
C
_sp_
16
sp
33.1
272
0.
1753
5.00
44
0
.000
3
0.
0063
0.0
058
59.8
557
0.
0295
0.0
101
0.00
01
0
.190
2
98
.40
C28
4
C_s
p_17
sp
33
.086
3
0.15
31
4.
9742
0.0
000
0.01
06
0
.013
3
60
.488
5
0.02
71
0
.007
2
0.
0001
0.1
592
98.9
2 C
284
C
_sp_
18
sp
32.9
728
0.
1258
5.39
97
0
.005
5
0.
0036
0.0
027
58.7
929
0.
0349
0.0
298
0.00
81
0
.158
4
97
.53
C28
5
B_s
p_4
s
p
33.1
934
0.
2356
5.17
25
0
.000
0
0.
0023
0.0
462
59.2
138
0.
0367
0.0
284
0.00
08
0
.176
2
98
.11
C28
5
B_s
p_5
s
p
33.2
546
0.
2584
5.22
43
0
.000
0
0.
0052
0.0
074
59.0
678
0.
0186
0.0
319
0.00
01
0
.165
0
98
.03
C28
5
B_s
p_6
s
p
33.2
595
0.
2419
5.25
75
0
.000
0
0.
0019
0.0
001
61.0
893
0.
0311
0.0
094
0.00
01
0
.152
1
10
0.04
C
285
B
_sp_
7
sp
33
.143
9
0.27
00
5.
1554
0.0
080
0.00
07
0
.000
4
58
.589
0
0.02
38
0
.015
9
0.
0022
0.1
722
97.3
8 C
285
B
_sp_
8
sp
33
.129
4
0.28
52
5.
2310
0.0
044
0.00
08
0
.000
1
60
.200
5
0.03
89
0
.011
0
0.
0001
0.1
912
99.0
9 C
285
B
_sp_
9
sp
33
.118
5
0.29
94
5.
1746
0.0
086
0.00
50
0
.004
5
59
.612
2
0.03
31
0
.014
7
0.
0001
0.1
677
98.4
4 C
287
B
_sp_
4
sp
32
.986
5
0.19
87
4.
1884
0.0
004
0.01
62
0
.008
2
60
.687
1
0.03
74
0
.024
0
0.
0085
0.1
663
98.3
2 C
287
B
_sp_
5
sp
33
.001
5
0.20
45
4.
1071
0.0
000
0.00
79
0
.007
8
60
.347
7
0.02
51
0
.011
0
0.
0001
0.1
867
97.9
0
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
32
C28
7
B_s
p_6
s
p
32.8
573
0.
2030
4.05
03
0
.000
6
0.
0001
0.0
001
60.2
757
0.
0364
0.0
197
0.00
01
0
.179
7
97
.62
C28
7
C_s
p_10
sp
33
.082
9
0.20
36
4.
0367
0.0
000
0.01
36
0
.004
1
59
.841
7
0.02
61
0
.012
8
0.
0030
0.1
506
97.3
8 C
287
C
_sp_
11
sp
33.0
323
0.
2102
4.14
89
0
.000
0
0.
0001
0.0
001
60.2
861
0.
0456
0.0
111
0.00
01
0
.165
3
97
.90
C28
7
C_s
p_12
sp
33
.237
1
0.20
12
4.
0819
0.0
000
0.00
20
0
.007
9
60
.174
4
0.03
25
0
.007
1
0.
0001
0.1
571
97.9
0 C
290
A
_sp_
4
sp
32
.621
1
0.15
58
1.
7731
0.0
009
0.00
59
0
.003
1
64
.940
5
0.01
87
0
.017
2
0.
0001
0.1
881
99.7
2 C
290
A
_sp_
5
sp
32
.575
1
0.15
11
1.
6617
0.0
058
0.00
01
0
.000
1
64
.789
4
0.02
87
0
.027
6
0.
0001
0.1
963
99.4
4 C
290
A
_sp_
6
sp
32
.484
9
0.15
64
1.
7806
0.0
054
0.00
82
0
.001
5
64
.783
9
0.03
27
0
.028
2
0.
0001
0.2
075
99.4
9 C
290
A
_sp_
7
sp
32
.648
4
0.11
43
1.
5443
0.0
055
0.00
67
0
.014
3
64
.388
0
0.02
25
0
.017
4
0.
0069
0.2
093
98.9
8 C
290
A
_sp_
8
sp
32
.763
6
0.11
06
1.
5055
0.0
000
0.00
17
0
.007
4
64
.276
1
0.01
60
0
.023
4
0.
0069
0.2
055
98.9
2 C
290
A
_sp_
9
sp
32
.542
8
0.11
81
1.
4521
0.0
041
0.00
29
0
.007
3
64
.284
2
0.02
29
0
.015
3
0.
0039
0.1
874
98.6
4 C
290
B
_sp_
13
sp
32
.485
7
0.11
97
3.
4301
0.0
000
0.00
01
0
.022
0
62
.754
3
0.03
26
0
.017
5
0.
0001
0.2
193
99.0
8 C
290
B
_sp_
14
sp
32
.452
8
0.12
99
3.
5902
0.0
000
0.00
18
0
.004
4
62
.927
4
0.02
03
0
.023
0
0.
0001
0.2
111
99.3
6 C
290
B
_sp_
15
sp
32
.649
8
0.12
23
3.
6295
0.0
077
0.00
01
0
.014
4
62
.503
4
0.03
25
0
.008
8
0.
0080
0.1
967
99.1
7 C
297
_s
p_1-
1-1
sp
32
.376
7
0.22
83
5.
0708
0.0
010
0.00
71
0
.000
1
61
.257
1
0.05
03
0
.019
0
0.
0001
0.1
810
99.1
9 C
297
_s
p_2-
2-1
sp
32
.416
9
0.18
54
5.
0235
0.0
010
0.00
01
0
.013
2
61
.870
5
0.04
63
0
.023
6
0.
0001
0.1
414
99.7
2 C
297
_s
p_3-
3-1
sp
32
.508
0
0.24
18
5.
1272
0.0
000
0.00
77
0
.009
2
60
.986
3
0.02
07
0
.016
4
0.
0001
0.1
658
99.0
8 C
299
A
_sp_
4
sp
34
.196
9
0.09
92
1.
9414
0.0
124
0.00
22
0
.004
6
63
.194
7
0.03
31
0
.016
9
0.
0123
0.1
765
99.6
9 C
299
A
_sp_
4
sp
33
.163
1
0.10
74
1.
9290
0.0
049
0.00
57
0
.014
5
63
.530
7
0.02
28
0
.021
2
0.
0085
0.1
837
98.9
9 C
299
A
_sp_
5
sp
34
.124
5
0.10
58
1.
9792
0.0
038
0.00
33
0
.000
1
63
.262
3
0.03
02
0
.019
6
0.
0001
0.1
818
99.7
1 C
299
A
_sp_
5
sp
32
.983
1
0.09
80
1.
9477
0.0
003
0.00
01
0
.000
1
62
.665
5
0.01
50
0
.024
5
0.
0001
0.1
877
97.9
2 C
299
A
_sp_
6
sp
34
.189
1
0.10
00
1.
9301
0.0
041
0.00
83
0
.000
1
63
.218
3
0.02
36
0
.033
1
0.
0001
0.1
808
99.6
9 C
299
A
_sp_
6
sp
32
.982
2
0.09
66
1.
9114
0.0
007
0.00
01
0
.002
5
62
.974
3
0.01
57
0
.005
4
0.
0001
0.1
497
98.1
4 C
299
B
_sp_
10
sp
34
.353
7
0.10
21
1.
9946
0.0
043
0.00
38
0
.000
1
62
.948
9
0.02
34
0
.013
4
0.
0001
0.1
982
99.6
4 C
299
B
_sp_
10
sp
33
.221
5
0.11
40
1.
9527
0.0
065
0.00
24
0
.012
7
63
.569
1
0.02
76
0
.016
1
0.
0001
0.1
966
99.1
2 C
299
B
_sp_
11
sp
33
.187
0
0.09
26
1.
9494
0.0
000
0.00
01
0
.000
1
64
.383
1
0.03
37
0
.011
6
0.
0073
0.1
674
99.8
3 C
299
B
_sp_
12
sp
33
.248
2
0.09
43
1.
9375
0.0
069
0.00
67
0
.011
5
64
.121
2
0.03
62
0
.014
4
0.
0001
0.1
784
99.6
6 C
301
A
_sp_
1
sp
32
.963
2
0.24
56
3.
4947
0.0
000
0.00
95
0
.015
7
61
.257
0
0.02
13
0
.021
9
0.
0062
0.1
993
98.2
3 C
301
A
_sp_
2
sp
33
.012
9
0.24
89
3.
4301
0.0
082
0.00
02
0
.004
6
60
.968
1
0.03
86
0
.015
6
0.
0001
0.1
879
97.9
2 C
301
A
_sp_
3
sp
33
.031
8
0.20
86
3.
3612
0.0
000
0.00
01
0
.013
5
60
.836
6
0.02
79
0
.017
4
0.
0003
0.1
846
97.6
8 C
306
A
_sp_
4
sp
34
.163
1
0.15
81
2.
5560
0.0
062
0.00
08
0
.003
2
63
.003
3
0.02
21
0
.013
7
0.
0001
0.1
893
100.
12
C30
6
A_s
p_5
s
p
34.1
254
0.
1340
2.47
78
0
.005
7
0.
0130
0.0
001
63.1
670
0.
0178
0.0
040
0.00
01
0
.198
4
10
0.14
C
306
A
_sp_
6
sp
34
.173
8
0.13
54
2.
4771
0.0
000
0.00
01
0
.000
1
62
.941
4
0.03
35
0
.019
0
0.
0001
0.1
752
99.9
6 C
306
B
_sp_
7
sp
34
.053
9
0.20
74
2.
5361
0.0
062
0.00
01
0
.000
1
62
.855
1
0.02
65
0
.015
7
0.
0010
0.1
679
99.8
7 C
306
B
_sp_
8
sp
33
.902
2
0.18
33
2.
5222
0.0
040
0.00
10
0
.000
1
62
.873
1
0.03
12
0
.029
8
0.
0001
0.1
592
99.7
1 C
306
B
_sp_
9
sp
34
.058
1
0.17
35
2.
5366
0.0
000
0.00
01
0
.020
2
63
.083
0
0.02
18
0
.006
1
0.
0001
0.1
919
100.
09
C30
7
A_s
p_4
s
p
32.9
679
0.
0374
4.46
93
0
.000
0
0.
0089
0.1
928
60.9
106
0.
0324
0.0
129
0.00
35
0
.197
3
98
.83
C30
7
A_s
p_5
s
p
32.9
920
0.
0507
4.97
90
0
.004
1
0.
0001
0.3
578
60.7
622
0.
0193
0.0
301
0.01
89
0
.251
2
99
.47
C30
7
A_s
p_6
s
p
32.4
775
0.
0477
4.47
40
0
.000
0
0.
0117
0.0
730
60.9
843
0.
0360
0.0
130
0.00
01
0
.209
5
98
.33
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
33
C30
7
C_s
p_16
sp
32
.969
7
0.05
02
4.
3183
0.0
000
0.00
17
0
.011
5
60
.094
8
0.01
26
0
.020
3
0.
0001
0.2
299
97.7
1 C
307
C
_sp_
17
sp
33.0
737
0.
0970
5.16
57
0
.000
0
0.
0001
0.0
028
59.2
544
0.
0359
0.0
162
0.00
01
0
.248
0
97
.89
C30
7
C_s
p_18
sp
32
.932
1
0.05
41
4.
6558
0.0
000
0.00
04
0
.000
1
59
.907
8
0.04
72
0
.027
7
0.
0001
0.2
297
97.8
6 C
317
A
_sp_
4
sp
32
.769
6
0.09
86
2.
2850
0.0
000
0.00
01
0
.083
8
64
.600
5
0.01
85
0
.012
8
0.
0001
0.1
829
100.
05
C31
7
A_s
p_5
s
p
32.8
703
0.
1118
2.39
22
0
.001
5
0.
0001
0.0
661
64.5
439
0.
0215
0.0
233
0.00
01
0
.170
7
10
0.20
C
317
A
_sp_
6
sp
32
.741
9
0.11
81
3.
0833
0.0
000
0.00
01
0
.966
6
63
.311
2
0.03
22
0
.015
4
0.
0144
0.1
826
100.
47
C31
7
D_s
p_16
sp
32
.726
6
0.13
43
3.
0457
0.0
033
0.00
01
0
.000
1
63
.512
8
0.03
59
0
.017
5
0.
0059
0.1
928
99.6
8 C
317
D
_sp_
17
sp
32.8
555
0.
1257
3.01
52
0
.000
0
0.
0001
0.0
001
63.8
205
0.
0279
0.0
277
0.00
01
0
.186
0
10
0.06
C
317
D
_sp_
18
sp
32.7
486
0.
1242
2.98
70
0
.005
1
0.
0001
0.0
064
63.5
984
0.
0003
0.0
246
0.00
01
0
.186
9
99
.68
C32
3
A_s
p_4
s
p
32.8
335
0.
0983
5.87
74
0
.000
0
0.
0090
0.2
111
60.8
286
0.
0344
0.0
133
0.00
01
0
.202
3
10
0.11
C
323
A
_sp_
5
sp
32
.988
7
0.10
54
6.
0264
0.0
025
0.00
01
0
.079
0
60
.402
8
0.04
07
0
.009
4
0.
0084
0.1
709
99.8
3 C
323
A
_sp_
6
sp
33
.070
1
0.08
88
5.
7682
0.0
000
0.00
16
0
.278
2
60
.880
4
0.04
37
0
.026
8
0.
0001
0.2
125
100.
37
C32
3
D_s
p_13
sp
33
.221
3
0.14
62
6.
2425
0.0
000
0.00
72
0
.000
1
60
.347
9
0.05
28
0
.014
5
0.
0001
0.1
711
100.
20
C32
3
D_s
p_14
sp
33
.278
1
0.14
62
6.
2799
0.0
000
0.00
25
0
.007
4
60
.468
2
0.02
63
0
.005
8
0.
0001
0.1
829
100.
40
C32
3
D_s
p_15
sp
33
.146
4
0.14
72
6.
2833
0.0
000
0.00
71
0
.005
0
60
.507
9
0.04
88
0
.011
3
0.
0001
0.1
862
100.
34
C32
6
A_s
p_4
s
p
32.2
846
0.
1916
5.30
90
0
.000
0
0.
0001
0.0
035
61.0
852
0.
0152
0.0
265
0.00
01
0
.168
7
99
.08
C32
6
A_s
p_5
s
p
32.5
641
0.
1902
5.29
55
0
.000
0
0.
0001
0.0
001
61.0
175
0.
0314
0.0
170
0.00
01
0
.161
6
99
.28
C32
6
A_s
p_6
s
p
32.7
190
0.
1751
5.25
97
0
.000
0
0.
0006
0.0
001
61.3
432
0.
0210
0.0
331
0.00
01
0
.174
5
99
.73
C32
6
B_s
p_13
s
p
32.6
341
0.
1805
5.43
39
0
.000
0
0.
0008
0.0
001
61.4
951
0.
0415
0.0
153
0.00
01
0
.160
5
99
.96
C32
6
B_s
p_14
s
p
32.6
482
0.
1683
5.39
77
0
.000
0
0.
0001
0.0
085
61.4
320
0.
0498
0.0
185
0.01
37
0
.166
3
99
.90
C32
6
B_s
p_15
s
p
32.2
961
0.
1720
5.47
02
0
.000
0
0.
0094
0.0
001
61.0
339
0.
0291
0.0
236
0.00
01
0
.175
9
99
.21
C32
9
aA_s
p_7
sp
32
.959
7
0.22
08
4.
1325
0.0
000
0.00
71
0
.034
6
60
.705
6
0.04
17
0
.018
4
0.
0095
0.1
860
98.3
2 C
329
aA
_sp_
8
sp
33.1
913
0.
1338
3.96
09
0
.002
7
0.
0010
0.0
419
60.4
450
0.
0190
0.0
286
0.00
01
0
.165
6
97
.99
C32
9
aA_s
p_9
sp
33
.295
6
0.18
63
4.
0660
0.0
000
0.00
01
0
.016
3
61
.202
9
0.02
30
0
.015
1
0.
0001
0.1
705
98.9
8 C
329
aB
_sp_
19 s
p
32.8
689
0.
2144
4.09
68
0
.002
4
0.
0014
0.0
251
60.9
063
0.
0350
0.0
134
0.00
42
0
.172
1
98
.34
C32
9
aB_s
p_20
sp
33
.114
3
0.22
27
4.
1033
0.0
122
0.01
05
0
.027
3
61
.302
0
0.02
98
0
.017
9
0.
0001
0.1
956
99.0
4 C
329
aB
_sp_
21 s
p
33.3
941
0.
2360
4.01
47
0
.003
0
0.
0128
0.0
004
60.6
230
0.
0394
0.0
238
0.00
01
0
.189
9
98
.54
C32
9
bA_s
p_7
sp
33
.880
0
0.21
24
3.
8868
0.0
103
0.00
01
0
.074
4
62
.034
4
0.03
31
0
.031
9
0.
0001
0.1
681
100.
33
C32
9
bA_s
p_8
sp
33
.965
3
0.23
84
3.
9327
0.0
000
0.00
61
0
.021
6
61
.844
4
0.04
13
0
.005
0
0.
0069
0.1
585
100.
22
C32
9
bA_s
p_9
sp
33
.852
3
0.25
48
3.
9647
0.0
004
0.00
66
0
.027
2
62
.403
0
0.03
61
0
.018
6
0.
0001
0.1
636
100.
73
C33
3
A_s
p_7
s
p
32.9
491
0.
2069
6.40
51
0
.000
0
0.
0134
0.0
078
58.3
861
0.
0491
0.0
194
0.00
01
0
.179
5
98
.22
C33
3
A_s
p_8
s
p
33.3
791
0.
2055
6.48
77
0
.000
0
0.
0001
0.0
083
58.9
383
0.
0271
0.0
166
0.00
01
0
.152
4
99
.22
C33
3
A_s
p_9
s
p
33.0
923
0.
2079
6.52
94
0
.000
0
0.
0085
0.0
005
58.2
256
0.
0537
0.0
144
0.00
01
0
.165
3
98
.30
C33
3
B_s
p_16
s
p
33.2
658
0.
2011
6.28
03
0
.000
0
0.
0009
0.0
184
57.8
648
0.
0293
0.0
212
0.00
01
0
.163
6
97
.85
C33
3
B_s
p_17
s
p
33.1
314
0.
1793
6.34
04
0
.000
0
0.
0001
0.0
143
58.6
210
0.
0381
0.0
168
0.00
01
0
.159
1
98
.50
C33
3
B_s
p_18
s
p
33.1
885
0.
1834
6.31
49
0
.000
0
0.
0157
0.0
001
58.5
412
0.
0380
0.0
216
0.00
34
0
.166
1
98
.47
C33
7
A_s
p_4
s
p
32.3
813
0.
2505
2.90
79
0
.009
2
0.
0119
0.0
063
63.9
279
0.
0319
0.0
211
0.00
01
0
.175
7
99
.72
C33
7
A_s
p_5
s
p
32.4
390
0.
2213
2.91
30
0
.014
1
0.
0043
0.0
001
63.9
817
0.
0312
0.0
237
0.00
07
0
.157
3
99
.79
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
34
C33
7
A_s
p_6
s
p
32.4
258
0.
2105
2.93
27
0
.000
0
0.
0001
0.0
120
64.0
477
0.
0358
0.0
193
0.00
01
0
.154
2
99
.84
C33
7
B_s
p_13
s
p
32.0
588
0.
2233
2.93
72
0
.007
8
0.
0001
0.0
021
63.4
104
0.
0255
0.0
211
0.00
63
0
.165
0
98
.86
C33
7
B_s
p_14
s
p
32.6
784
0.
2197
2.87
52
0
.003
8
0.
0001
0.0
173
64.1
261
0.
0367
0.0
135
0.00
01
0
.182
9
10
0.15
C
337
B
_sp_
15
sp
32
.318
8
0.22
21
2.
9329
0.0
061
0.00
01
0
.002
2
64
.068
5
0.02
45
0
.033
2
0.
0071
0.1
955
99.8
1 C
341
A
_sp_
4
sp
33
.980
8
0.15
20
2.
4353
0.0
089
0.01
14
0
.000
1
63
.326
4
0.03
98
0
.041
0
0.
0001
0.1
846
100.
18
C34
1
A_s
p_5
s
p
34.0
180
0.
1444
2.42
47
0
.005
7
0.
0001
0.0
001
63.1
055
0.
0298
0.0
156
0.00
01
0
.187
6
99
.93
C34
1
A_s
p_6
s
p
33.9
931
0.
1518
2.45
46
0
.002
6
0.
0158
0.0
001
63.2
009
0.
0107
0.0
196
0.00
01
0
.199
0
10
0.05
C
341
B
_sp_
13
sp
34
.151
3
0.17
02
2.
0298
0.0
033
0.00
01
0
.006
3
63
.444
6
0.03
52
0
.003
9
0.
0001
0.1
992
100.
04
C34
1
B_s
p_14
s
p
34.2
650
0.
1601
2.02
53
0
.000
0
0.
0001
0.0
001
63.4
293
0.
0289
0.0
091
0.00
01
0
.192
0
10
0.11
C
341
B
_sp_
15
sp
34
.266
7
0.14
44
2.
0681
0.0
000
0.00
69
0
.100
7
63
.740
7
0.03
19
0
.010
0
0.
0001
0.1
987
100.
57
C34
3
A_s
p_4
s
p
33.4
697
0.
1328
5.99
54
0
.000
0
0.
0010
0.0
217
60.6
686
0.
0314
0.0
163
0.00
01
0
.172
0
10
0.51
C
343
A
_sp_
5
sp
33
.355
2
0.20
56
5.
7949
0.0
021
0.00
13
0
.042
0
59
.906
4
0.01
52
0
.012
3
0.
0001
0.1
818
99.5
2 C
343
A
_sp_
6
sp
33
.721
2
0.14
71
7.
4316
0.0
000
0.00
01
2
.221
5
54
.984
1
0.03
20
0
.010
2
0.
0187
0.1
797
98.7
5 C
343
B
_sp_
10
sp
33
.203
2
0.08
50
5.
9756
0.0
000
0.00
01
0
.612
7
58
.775
9
0.03
93
0
.008
4
0.
0110
0.1
603
98.8
7 C
343
B
_sp_
11
sp
33
.187
2
0.06
20
5.
9985
0.0
012
0.00
01
0
.742
9
59
.652
2
0.02
78
0
.012
4
0.
0001
0.1
700
99.8
5 C
343
B
_sp_
12
sp
33
.135
5
0.07
37
5.
7245
0.0
000
0.00
01
0
.186
0
58
.801
6
0.03
21
0
.020
3
0.
0024
0.1
866
98.1
6 C
345
A
_sp_
4
sp
34
.198
2
0.05
51
2.
4407
0.0
057
0.00
03
0
.000
1
63
.364
8
0.01
66
0
.004
1
0.
0067
0.1
712
100.
26
C34
5
A_s
p_5
s
p
34.2
759
0.
0571
2.49
12
0
.012
8
0.
0037
0.0
001
63.0
558
0.
0356
0.0
253
0.00
01
0
.182
6
10
0.14
C
345
A
_sp_
6
sp
34
.199
8
0.04
78
2.
5037
0.0
047
0.01
33
0
.035
6
63
.574
1
0.04
08
0
.009
4
0.
0082
0.1
852
100.
62
C35
3
A_s
p_4
s
p
33.2
232
0.
1835
3.65
72
0
.000
0
0.
0092
0.0
120
61.7
896
0.
0418
0.0
294
0.00
90
0
.154
7
99
.11
C35
3
A_s
p_5
s
p
33.2
190
0.
1798
3.92
32
0
.000
0
0.
0001
0.0
015
61.4
975
0.
0510
0.0
112
0.00
01
0
.154
8
99
.04
C35
3
A_s
p_6
s
p
33.1
389
0.
1561
3.40
46
0
.000
0
0.
0001
0.0
041
62.0
520
0.
0195
0.0
189
0.00
14
0
.147
9
98
.94
C35
3
C_s
p_13
sp
33
.130
6
0.12
47
2.
6780
0.0
000
0.00
70
0
.004
7
62
.822
3
0.02
55
0
.023
9
0.
0001
0.1
572
98.9
7 C
353
C
_sp_
14
sp
33.1
042
0.
1190
2.99
69
0
.000
0
0.
0044
0.0
195
62.8
197
0.
0189
0.0
152
0.00
01
0
.182
7
99
.28
C35
3
C_s
p_15
sp
32
.960
0
0.08
47
2.
9062
0.0
000
0.00
01
0
.020
4
62
.412
4
0.01
17
0
.015
8
0.
0126
0.1
575
98.5
8 C
355
_s
p_1-
1-1
sp
32
.755
0
0.19
81
8.
3577
0.0
000
0.00
61
0
.024
1
57
.433
2
0.04
42
0
.017
4
0.
0001
0.1
577
98.9
9 C
355
_s
p_2-
2-1
sp
32
.777
7
0.17
29
8.
2118
0.0
000
0.00
01
0
.021
2
58
.087
9
0.04
91
0
.005
7
0.
0001
0.1
669
99.4
9 C
355
_s
p_3-
3-1
sp
32
.891
3
0.21
10
8.
0343
0.0
000
0.00
02
0
.018
7
58
.354
4
0.05
09
0
.022
4
0.
0157
0.1
630
99.7
6 C
357
A
_sp_
1
sp
32
.839
9
0.04
05
3.
6592
0.0
078
0.00
77
0
.023
8
63
.262
6
0.02
19
0
.024
4
0.
0141
0.2
142
100.
12
C35
7
A_s
p_2
s
p
33.0
792
0.
0343
3.44
02
0
.000
0
0.
0124
0.0
171
63.5
270
0.
0338
0.0
167
0.00
91
0
.205
8
10
0.38
C
357
A
_sp_
3
sp
33
.212
1
0.03
76
3.
4389
0.0
000
0.00
01
0
.023
5
63
.466
7
0.03
98
0
.028
8
0.
0007
0.2
053
100.
45
C35
9
A_s
p_4
s
p
33.2
274
0.
0285
1.00
99
0
.003
6
0.
0031
0.0
127
64.4
081
0.
0273
0.0
159
0.00
01
0
.232
0
98
.97
C35
9
A_s
p_5
s
p
32.9
121
0.
0251
1.02
08
0
.000
0
0.
0001
0.0
153
63.5
305
0.
0312
0.0
093
0.00
77
0
.225
5
97
.78
C35
9
A_s
p_6
s
p
32.9
009
0.
0277
1.03
56
0
.003
0
0.
0040
0.0
290
63.7
711
0.
0149
0.0
144
0.00
64
0
.218
5
98
.03
C35
9
B_s
p_16
s
p
33.0
222
0.
0359
1.07
31
0
.002
0
0.
0001
0.1
234
63.7
751
0.
0321
0.0
168
0.01
16
0
.199
4
98
.29
C35
9
B_s
p_17
s
p
33.0
758
0.
0219
1.31
01
0
.002
5
0.
0048
0.2
957
64.8
582
0.
0198
0.0
153
0.00
42
0
.208
1
99
.82
C35
9
B_s
p_18
s
p
32.7
467
0.
0374
1.16
67
0
.006
6
0.
0001
0.1
701
63.5
026
0.
0227
0.0
170
0.00
01
0
.231
1
97
.90
C36
2
A_s
p_1
s
p
32.7
842
0.
0682
2.20
28
0
.006
4
0.
0019
0.0
010
64.5
765
0.
0345
0.0
161
0.00
51
0
.100
2
99
.80
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
35
C36
2
A_s
p_2
s
p
32.6
115
0.
0517
2.13
58
0
.000
0
0.
0001
0.0
001
64.5
595
0.
0265
0.0
189
0.00
74
0
.108
2
99
.52
C36
2
A_s
p_3
s
p
32.5
453
0.
0715
2.17
36
0
.000
0
0.
0001
0.0
002
64.6
273
0.
0261
0.0
156
0.00
01
0
.127
7
99
.59
C36
2
B_s
p_10
s
p
32.5
686
0.
0730
2.18
88
0
.000
0
0.
0001
0.0
001
64.4
746
0.
0415
0.0
138
0.00
72
0
.102
2
99
.47
C36
2
B_s
p_11
s
p
32.5
455
0.
0586
2.11
06
0
.000
0
0.
0001
0.0
001
64.1
407
0.
0259
0.0
215
0.00
01
0
.113
5
99
.02
C36
2
B_s
p_12
s
p
32.5
100
0.
0715
2.17
80
0
.006
1
0.
0001
0.0
023
64.3
079
0.
0221
0.0
174
0.01
23
0
.115
6
99
.24
C36
4
A_s
p_4
s
p
32.7
729
0.
0446
2.53
43
0
.003
1
0.
0001
0.0
365
63.9
857
0.
0238
0.0
032
0.00
01
0
.250
4
99
.65
C36
4
A_s
p_5
s
p
32.5
332
0.
0402
2.47
48
0
.000
0
0.
0108
0.0
399
63.9
013
0.
0289
0.0
037
0.01
30
0
.221
0
99
.27
C36
4
A_s
p_6
s
p
32.5
910
0.
0389
2.50
48
0
.000
0
0.
0001
0.0
194
64.0
320
0.
0383
0.0
257
0.01
77
0
.229
2
99
.50
C36
4
B_s
p_22
s
p
32.5
202
0.
0495
2.27
88
0
.007
8
0.
0044
0.0
263
64.1
582
0.
0355
0.0
137
0.02
01
0
.229
5
99
.34
C36
4
B_s
p_23
s
p
32.5
870
0.
0485
2.24
53
0
.006
3
0.
0001
0.0
342
64.1
080
0.
0380
0.0
119
0.01
30
0
.248
1
99
.34
C36
4
B_s
p_24
s
p
32.5
691
0.
0482
2.31
35
0
.000
0
0.
0001
0.0
157
64.1
311
0.
0313
0.0
148
0.00
35
0
.220
5
99
.35
C36
5
A_s
p_4
s
p
32.8
507
0.
0481
4.73
19
0
.000
0
0.
0001
0.0
001
61.9
883
0.
0281
0.0
116
0.00
01
0
.187
5
99
.85
C36
5
A_s
p_5
s
p
32.8
215
0.
0509
4.79
75
0
.000
5
0.
0001
0.0
001
61.9
959
0.
0261
0.0
000
0.00
45
0
.202
5
99
.90
C36
5
A_s
p_6
s
p
32.9
072
0.
0503
4.77
53
0
.001
0
0.
0001
0.0
192
62.1
639
0.
0264
0.0
307
0.00
01
0
.207
1
10
0.18
C
365
B
_sp_
13
sp
33
.081
3
0.02
65
4.
7103
0.0
000
0.00
46
0
.017
2
62
.088
0
0.00
51
0
.031
0
0.
0001
0.2
159
100.
18
C36
5
B_s
p_14
s
p
32.9
583
0.
0432
4.73
94
0
.000
0
0.
0001
0.0
102
61.9
243
0.
0224
0.0
342
0.01
10
0
.200
9
99
.94
C36
5
B_s
p_15
s
p
33.3
693
0.
0222
4.49
61
0
.000
0
0.
0001
0.0
001
62.0
696
0.
0286
0.0
194
0.00
30
0
.214
5
10
0.22
C
369
A
_sp_
4
sp
34
.495
9
0.04
13
4.
7031
0.0
000
0.00
14
0
.000
1
62
.226
6
0.03
12
0
.017
9
0.
0001
0.1
912
101.
71
C36
9
A_s
p_5
s
p
34.1
205
0.
0281
4.65
61
0
.002
9
0.
0001
0.0
050
61.3
988
0.
0394
0.0
182
0.02
33
0
.162
5
10
0.45
C
369
A
_sp_
6
sp
34
.186
6
0.02
51
4.
6906
0.0
000
0.00
01
0
.000
1
61
.459
1
0.03
03
0
.009
5
0.
0071
0.1
825
100.
59
C36
9
B_s
p_10
s
p
34.0
403
0.
0267
4.69
35
0
.000
0
0.
0001
0.0
030
61.2
902
0.
0397
0.0
123
0.01
48
0
.180
2
10
0.30
C
369
B
_sp_
11
sp
34
.481
4
0.02
33
4.
6123
0.0
000
0.00
01
0
.000
1
61
.572
2
0.04
47
0
.020
9
0.
0001
0.1
833
100.
94
C36
9
B_s
p_12
s
p
34.1
726
0.
0264
4.62
23
0
.002
1
0.
0001
0.0
001
61.6
214
0.
0311
0.0
255
0.00
01
0
.176
4
10
0.68
C
378
B
_sp_
16
sp
32
.863
0
0.03
05
2.
5686
0.0
000
0.00
01
0
.546
3
63
.346
5
0.03
20
0
.013
4
0.
0001
0.1
943
99.5
9 C
378
B
_sp_
17
sp
32
.832
2
0.03
64
2.
8813
0.0
000
0.00
01
0
.961
3
61
.860
2
0.02
93
0
.017
7
0.
0001
0.1
881
98.8
1 C
378
B
_sp_
18
sp
32
.822
1
0.06
39
2.
3514
0.0
039
0.00
40
0
.122
3
63
.546
2
0.03
27
0
.022
2
0.
0001
0.1
528
99.1
2 C
379
A
_sp_
4
sp
34
.353
8
0.15
09
5.
0490
0.0
062
0.00
18
0
.004
5
60
.702
6
0.04
23
0
.028
2
0.
0001
0.1
616
100.
50
C37
9
A_s
p_4
s
p
33.1
811
0.
1531
5.04
67
0
.000
0
0.
0046
0.0
098
60.6
713
0.
0366
0.0
323
0.00
01
0
.185
9
99
.32
C37
9
A_s
p_5
s
p
34.2
673
0.
1594
5.07
46
0
.000
0
0.
0054
0.0
176
60.8
552
0.
0252
0.0
284
0.00
01
0
.177
0
10
0.61
C
379
A
_sp_
5
sp
33
.149
8
0.15
32
5.
1421
0.0
000
0.00
83
0
.000
1
59
.125
3
0.03
29
0
.018
0
0.
0142
0.1
857
97.8
3 C
379
A
_sp_
6
sp
34
.518
3
0.16
94
5.
1287
0.0
000
0.00
31
0
.003
8
60
.392
3
0.04
33
0
.013
3
0.
0001
0.1
779
100.
45
C37
9
A_s
p_6
s
p
33.1
467
0.
1871
5.19
02
0
.000
0
0.
0001
0.0
001
59.3
730
0.
0321
0.0
179
0.00
15
0
.198
5
98
.15
C37
9
B_s
p_10
s
p
34.2
657
0.
1731
5.17
01
0
.000
0
0.
0001
0.0
237
60.8
852
0.
0347
0.0
271
0.00
01
0
.182
0
10
0.76
C
379
B
_sp_
10
sp
33
.300
1
0.17
04
5.
1681
0.0
084
0.00
01
0
.014
4
59
.059
1
0.02
26
0
.026
8
0.
0001
0.1
835
97.9
5 C
379
B
_sp_
11
sp
34
.346
5
0.15
78
5.
0252
0.0
000
0.00
01
0
.000
1
60
.629
8
0.03
20
0
.028
3
0.
0001
0.1
920
100.
41
C37
9
B_s
p_11
s
p
33.4
074
0.
1445
5.11
21
0
.000
0
0.
0066
0.0
122
60.0
717
0.
0185
0.0
218
0.00
01
0
.176
4
98
.97
C37
9
B_s
p_12
s
p
34.1
878
0.
1599
5.00
32
0
.000
0
0.
0001
0.0
047
60.4
428
0.
0227
0.0
241
0.00
72
0
.172
2
10
0.02
C
379
B
_sp_
12
sp
33
.473
8
0.15
36
5.
1712
0.0
022
0.00
01
0
.000
4
60
.007
5
0.03
78
0
.021
6
0.
0001
0.1
776
99.0
5
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
36
C38
1
A_s
p_7
s
p
33.3
565
0.
1403
4.46
61
0
.000
0
0.
0053
0.0
001
60.6
406
0.
0283
0.0
279
0.00
01
0
.180
9
98
.85
C38
1
A_s
p_8
s
p
33.1
584
0.
1588
4.47
75
0
.000
0
0.
0001
0.0
174
59.9
562
0.
0381
0.0
211
0.00
01
0
.175
2
98
.00
C38
1
A_s
p_9
s
p
33.1
397
0.
1435
4.46
39
0
.007
0
0.
0044
0.0
030
60.6
813
0.
0330
0.0
157
0.01
34
0
.163
9
98
.67
C38
1
B_s
p_13
s
p
33.1
939
0.
1099
4.30
17
0
.003
7
0.
0026
0.0
082
61.0
250
0.
0370
0.0
107
0.00
07
0
.202
7
98
.90
C38
1
B_s
p_14
s
p
33.0
697
0.
0864
4.23
96
0
.008
1
0.
0001
0.0
001
60.9
703
0.
0312
0.0
291
0.00
01
0
.174
9
98
.61
C38
1
B_s
p_15
s
p
32.9
767
0.
1508
4.32
66
0
.000
0
0.
0001
0.0
001
60.7
027
0.
0373
0.0
195
0.00
01
0
.154
5
98
.37
C38
3
A_s
p_4
s
p
32.8
961
0.
1232
1.39
55
0
.002
9
0.
0028
0.0
001
65.1
458
0.
0123
0.0
303
0.00
01
0
.179
9
99
.79
C38
3
A_s
p_5
s
p
32.4
989
0.
1166
1.36
67
0
.005
7
0.
0001
0.0
073
65.4
347
0.
0282
0.0
184
0.00
01
0
.151
9
99
.63
C38
3
A_s
p_6
s
p
32.7
119
0.
1176
1.24
33
0
.012
1
0.
0083
0.0
001
65.4
653
0.
0170
0.0
163
0.00
01
0
.178
2
99
.77
C38
3
B_s
p_13
s
p
33.0
112
0.
1078
1.44
82
0
.009
1
0.
0001
0.0
001
64.9
547
0.
0397
0.0
335
0.00
18
0
.179
6
99
.79
C38
3
B_s
p_14
s
p
32.7
227
0.
1088
1.46
48
0
.000
0
0.
0020
0.0
001
64.2
759
0.
0231
0.0
158
0.00
01
0
.152
9
98
.77
C38
3
B_s
p_15
s
p
33.2
505
0.
1095
1.45
63
0
.007
9
0.
0010
0.0
001
64.8
749
0.
0273
0.0
276
0.00
01
0
.172
7
99
.93
C38
5
B_s
p_10
s
p
32.9
567
0.
0639
2.45
77
0
.000
0
0.
0001
0.0
098
63.1
579
0.
0391
0.0
217
0.00
32
0
.207
2
98
.92
C38
5
B_s
p_11
s
p
32.9
737
0.
0730
2.42
64
0
.001
0
0.
0001
0.0
008
62.7
541
0.
0252
0.0
175
0.00
21
0
.183
8
98
.46
C38
5
B_s
p_12
s
p
33.1
992
0.
0586
2.46
08
0
.000
0
0.
0001
0.0
434
62.6
529
0.
0210
0.0
038
0.00
80
0
.202
6
98
.65
C38
5
C_s
p_19
sp
32
.983
4
0.05
53
2.
3483
0.0
000
0.00
28
0
.000
1
61
.996
5
0.01
92
0
.018
7
0.
0109
0.1
855
97.6
2 C
385
C
_sp_
20
sp
33.0
951
0.
0710
2.33
67
0
.005
0
0.
0001
0.0
135
62.5
711
0.
0328
0.0
256
0.00
01
0
.194
8
98
.35
C38
5
C_s
p_21
sp
33
.103
8
0.06
74
2.
3580
0.0
000
0.00
01
0
.004
9
62
.347
0
0.03
69
0
.024
6
0.
0001
0.1
919
98.1
3 C
794
_s
p_4
sp
32
.907
9
0.05
70
7.
1888
0.0
000
0.00
64
1
.702
3
58
.558
9
0.04
69
0
.017
5
0.
0013
0.1
437
100.
63
C79
4
_sp_
4
s
p
32.9
214
0.
0576
7.21
15
0
.000
0
0.
0050
1.7
013
59.3
365
0.
0382
0.0
296
0.01
20
0
.133
2
10
1.45
C
795
_s
p_4
sp
32
.726
6
0.16
36
0.
9529
0.0
019
0.00
77
0
.026
4
67
.377
6
0.02
55
0
.010
5
0.
0001
0.0
819
101.
37
C79
5
_sp_
5
s
p
32.7
627
0.
1159
1.18
48
0
.000
0
0.
0006
0.1
139
67.4
031
0.
0264
0.0
175
0.01
67
0
.058
7
10
1.70
C
795
_s
p_6
sp
32
.798
3
0.14
65
1.
0055
0.0
090
0.00
15
0
.022
2
67
.724
2
0.04
69
0
.021
5
0.
0072
0.0
567
101.
84
C79
7
_sp_
4
s
p
32.8
298
0.
1742
2.54
78
0
.000
0
0.
0001
0.0
010
65.9
356
0.
0191
0.0
230
0.00
01
0
.170
3
10
1.70
C
797
_s
p_5
sp
32
.859
5
0.17
95
2.
5611
0.0
071
0.00
01
0
.000
1
65
.653
9
0.02
26
0
.016
3
0.
0088
0.1
798
101.
49
C79
7
_sp_
6
s
p
32.7
275
0.
1794
2.53
97
0
.000
0
0.
0069
0.0
059
65.8
374
0.
0280
0.0
103
0.00
91
0
.177
5
10
1.52
C
799
_s
p_4
sp
33
.022
6
0.04
44
3.
5255
0.0
000
0.00
01
0
.016
1
65
.304
3
0.01
50
0
.004
6
0.
0102
0.3
077
102.
25
C79
9
_sp_
5
s
p
32.9
469
0.
0571
3.56
93
0
.000
0
0.
0020
0.0
107
65.2
709
0.
0162
0.0
114
0.00
01
0
.336
8
10
2.22
C
799
_s
p_6
sp
33
.161
0
0.04
88
3.
5220
0.0
000
0.00
21
0
.000
1
64
.957
6
0.03
14
0
.016
3
0.
0076
0.3
553
102.
10
C80
1
_sp_
4
s
p
32.5
142
0.
0578
1.46
56
0
.003
0
0.
0061
0.0
151
66.2
732
0.
0229
0.0
220
0.00
01
0
.173
8
10
0.55
C
801
_s
p_5
sp
30
.422
6
0.08
04
1.
3660
0.0
078
0.00
01
0
.165
7
65
.462
0
0.02
45
0
.020
5
0.
0599
0.1
736
97.7
8 C
801
_s
p_6
sp
32
.591
8
0.05
73
1.
4273
0.0
092
0.00
23
0
.004
4
66
.802
9
0.03
09
0
.026
1
0.
0007
0.1
903
101.
14
C80
2
_sp_
1
s
p
32.7
727
0.
1450
3.84
05
0
.008
9
0.
0001
0.0
055
63.9
124
0.
0373
0.0
189
0.00
01
0
.152
4
10
0.89
C
802
_s
p_2
sp
32
.873
7
0.14
21
3.
7675
0.0
000
0.00
60
0
.000
1
63
.997
3
0.04
49
0
.025
6
0.
0004
0.1
504
101.
01
C80
2
_sp_
3
s
p
32.8
939
0.
1409
3.78
84
0
.000
0
0.
0001
0.0
015
64.0
251
0.
0318
0.0
166
0.00
31
0
.158
3
10
1.06
C
803
_s
p_4
sp
32
.753
7
0.11
82
3.
2253
0.0
069
0.00
55
0
.006
0
65
.351
4
0.03
04
0
.021
4
0.
0034
0.1
689
101.
69
C80
3
_sp_
5
s
p
32.7
063
0.
0979
3.39
47
0
.000
0
0.
0035
0.1
615
64.9
324
0.
0333
0.0
155
0.00
31
0
.180
9
10
1.53
C
803
_s
p_6
sp
32
.793
2
0.09
22
3.
0353
0.0
053
0.00
01
0
.022
7
65
.629
6
0.01
87
0
.022
6
0.
0001
0.1
501
101.
77
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
37
C80
4
_sp_
1
s
p
32.5
496
0.
0423
2.00
77
0
.000
0
0.
0001
0.1
253
66.1
043
0.
0062
0.0
146
0.00
11
0
.185
4
10
1.04
C
804
_s
p_2
sp
32
.753
5
0.04
86
2.
4032
0.0
068
0.00
01
0
.124
4
66
.302
2
0.01
74
0
.023
1
0.
0001
0.1
856
101.
87
C80
4
_sp_
3
s
p
32.7
398
0.
0593
2.29
67
0
.006
0
0.
0046
0.3
632
66.2
525
0.
0344
0.0
232
0.00
01
0
.164
8
10
1.94
C
807
_s
p_7
sp
32
.967
0
0.14
64
4.
5482
0.0
000
0.00
14
0
.008
0
63
.293
2
0.03
32
0
.030
3
0.
0167
0.1
396
101.
18
C80
7
_sp_
8
s
p
33.2
220
0.
1625
4.54
90
0
.000
0
0.
0001
0.0
056
63.7
151
0.
0273
0.0
156
0.00
01
0
.134
1
10
1.83
C
807
_s
p_9
sp
33
.210
3
0.15
99
4.
5127
0.0
068
0.00
21
0
.005
2
63
.396
9
0.03
81
0
.005
3
0.
0039
0.1
506
101.
49
C80
8
_sp_
1
s
p
32.5
813
0.
1343
4.98
08
0
.000
0
0.
0032
0.0
001
63.2
817
0.
0352
0.0
284
0.00
01
0
.165
4
10
1.21
C
808
_s
p_2
sp
32
.718
4
0.09
02
4.
3398
0.0
068
0.00
84
0
.002
9
64
.153
4
0.04
67
0
.031
2
0.
0001
0.1
873
101.
59
C80
8
_sp_
3
s
p
32.7
027
0.
1238
4.83
06
0
.011
0
0.
0001
0.0
001
63.7
426
0.
0244
0.0
073
0.00
01
0
.190
3
10
1.63
C
809
_s
p_7
sp
33
.118
1
0.11
95
4.
7377
0.0
156
0.00
01
0
.014
3
63
.608
4
0.03
47
0
.010
4
0.
0040
0.1
597
101.
82
C80
9
_sp_
8
s
p
33.0
060
0.
1618
4.81
13
0
.000
0
0.
0029
0.0
094
62.9
830
0.
0273
0.0
217
0.00
01
0
.168
1
10
1.19
C
809
_s
p_9
sp
32
.229
2
0.08
27
4.
9945
0.0
000
0.00
01
0
.514
3
60
.826
4
0.02
17
0
.013
0
0.
0001
0.1
538
98.8
4 C
810
_s
p_4
sp
32
.412
7
0.34
01
3.
6786
0.0
000
0.00
49
0
.000
1
64
.056
6
0.02
76
0
.021
4
0.
0001
0.1
447
100.
69
C81
0
_sp_
5
s
p
32.5
335
0.
3336
3.65
26
0
.000
0
0.
0001
0.0
041
64.3
053
0.
0306
0.0
117
0.00
07
0
.147
6
10
1.02
C
810
_s
p_6
sp
32
.408
3
0.30
79
3.
4367
0.0
000
0.00
01
0
.008
0
64
.658
0
0.01
37
0
.018
2
0.
0001
0.1
427
100.
99
C81
1
_sp_
4
s
p
32.7
496
0.
2650
3.42
06
0
.001
2
0.
0017
0.0
282
65.1
638
0.
0271
0.0
204
0.00
01
0
.153
0
10
1.83
C
811
_s
p_5
sp
32
.769
8
0.27
18
3.
5823
0.0
003
0.00
92
0
.032
6
64
.507
1
0.02
33
0
.015
6
0.
0001
0.1
715
101.
38
C81
1
_sp_
6
s
p
32.4
603
0.
2789
4.55
85
0
.010
3
0.
0006
1.6
631
62.8
535
0.
0405
0.0
299
0.00
01
0
.152
0
10
2.05
C
812
_s
p_4
sp
33
.113
3
0.13
15
4.
1323
0.0
023
0.00
28
0
.000
1
64
.015
9
0.02
71
0
.021
8
0.
0105
0.1
783
101.
64
C81
2
_sp_
5
s
p
33.0
266
0.
1437
4.32
11
0
.000
0
0.
0016
0.0
120
63.8
527
0.
0191
0.0
188
0.00
89
0
.182
0
10
1.59
C
812
_s
p_6
sp
33
.191
8
0.14
48
4.
2782
0.0
000
0.00
01
0
.015
4
63
.997
6
0.03
64
0
.021
6
0.
0142
0.1
526
101.
85
C81
3
_sp_
1
s
p
33.2
000
0.
1193
3.29
91
0
.004
5
0.
0001
0.0
134
65.2
276
0.
0196
0.0
167
0.00
31
0
.204
2
10
2.11
C
813
_s
p_2
sp
32
.915
9
0.11
53
3.
2347
0.0
020
0.00
80
0
.009
4
65
.479
2
0.03
32
0
.009
2
0.
0080
0.1
708
101.
99
C81
3
_sp_
3
s
p
33.0
870
0.
1095
3.28
68
0
.005
9
0.
0041
0.0
001
65.3
046
0.
0210
0.0
138
0.01
03
0
.203
6
10
2.05
C
815
_s
p_4
sp
32
.881
5
0.17
69
5.
2995
0.0
000
0.00
77
0
.013
6
62
.836
4
0.03
35
0
.027
8
0.
0158
0.1
439
101.
44
C81
5
_sp_
5
s
p
32.8
237
0.
1905
5.24
98
0
.000
6
0.
0001
0.0
008
62.7
427
0.
0230
0.0
140
0.00
01
0
.164
4
10
1.21
C
815
_s
p_6
sp
33
.229
2
0.17
78
5.
3611
0.0
000
0.00
01
0
.004
7
62
.827
0
0.04
52
0
.023
7
0.
0001
0.1
411
101.
81
C81
7
_sp_
7
s
p
33.2
139
0.
0866
3.46
45
0
.001
1
0.
0087
0.0
609
64.9
800
0.
0222
0.0
309
0.00
44
0
.183
0
10
2.06
C
817
_s
p_8
sp
33
.141
0
0.12
35
4.
0342
0.0
013
0.00
01
0
.255
8
64
.213
2
0.03
78
0
.021
7
0.
0044
0.1
725
102.
01
C81
7
_sp_
9
s
p
33.1
922
0.
0924
4.43
07
0
.000
0
0.
0078
1.5
681
62.0
604
0.
0385
0.0
130
0.00
63
0
.165
3
10
1.57
C
818
_s
p_1
sp
33
.334
9
0.19
21
5.
8967
0.0
000
0.00
54
0
.003
6
61
.807
5
0.03
63
0
.025
2
0.
0001
0.1
823
101.
48
C81
8
_sp_
2
s
p
32.9
531
0.
1795
5.88
86
0
.000
0
0.
0114
0.0
121
62.2
118
0.
0412
0.0
178
0.00
09
0
.185
4
10
1.50
C
818
_s
p_3
sp
33
.068
9
0.17
94
5.
8792
0.0
000
0.00
01
0
.000
1
61
.848
4
0.02
70
0
.013
2
0.
0013
0.1
929
101.
21
C82
0
_sp_
4
s
p
32.3
720
0.
0970
3.46
09
0
.000
0
0.
0001
0.0
001
64.4
768
0.
0380
0.0
263
0.01
61
0
.132
8
10
0.62
C
820
_s
p_5
sp
32
.675
0
0.07
49
3.
4041
0.0
000
0.00
01
0
.006
0
65
.026
8
0.02
78
0
.035
3
0.
0027
0.1
470
101.
40
C82
0
_sp_
6
s
p
32.3
836
0.
0993
3.46
08
0
.001
6
0.
0001
0.0
041
64.6
534
0.
0340
0.0
126
0.00
01
0
.129
1
10
0.78
C
822
_s
p_1
sp
33
.040
7
0.21
01
4.
3986
0.0
123
0.00
73
0
.006
0
63
.734
2
0.02
26
0
.017
9
0.
0001
0.1
993
101.
65
C82
2
_sp_
2
s
p
32.8
751
0.
1924
4.39
26
0
.006
6
0.
0023
0.0
001
63.4
508
0.
0228
0.0
186
0.00
01
0
.194
4
10
1.16
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
38
C82
2
_sp_
3
s
p
33.0
318
0.
2005
4.41
28
0
.000
0
0.
0001
0.0
021
63.5
638
0.
0374
0.0
122
0.00
01
0
.190
2
10
1.45
C
825
_s
p_4
sp
32
.985
3
0.17
22
4.
7018
0.0
042
0.00
50
0
.006
5
62
.758
1
0.05
55
0
.015
9
0.
0035
0.1
833
100.
89
C82
5
_sp_
5
s
p
32.9
821
0.
1688
4.80
18
0
.000
0
0.
0042
0.0
204
63.0
913
0.
0306
0.0
185
0.00
01
0
.162
1
10
1.28
C
825
_s
p_6
sp
33
.115
8
0.15
44
4.
7048
0.0
043
0.00
08
0
.000
1
63
.222
5
0.01
58
0
.021
6
0.
0097
0.1
813
101.
43
C82
6
_sp_
7
s
p
32.9
638
0.
0358
2.18
25
0
.000
3
0.
0001
0.0
001
66.8
359
0.
0262
0.0
000
0.00
53
0
.216
3
10
2.27
C
826
_s
p_8
sp
33
.108
0
0.02
99
2.
3686
0.0
082
0.00
60
0
.054
7
66
.391
4
0.02
42
0
.011
3
0.
0097
0.2
101
102.
22
C82
6
_sp_
9
s
p
32.9
619
0.
0292
2.21
73
0
.000
4
0.
0040
0.0
209
66.8
578
0.
0071
0.0
249
0.00
01
0
.225
4
10
2.35
C
828
_s
p_4
sp
32
.735
2
0.11
58
2.
2390
0.0
076
0.00
80
0
.010
0
65
.563
6
0.01
94
0
.030
4
0.
0001
0.2
034
100.
93
C82
8
_sp_
5
s
p
33.0
581
0.
1094
3.00
11
0
.000
0
0.
0041
0.9
956
64.0
200
0.
0270
0.0
097
0.02
46
0
.201
7
10
1.45
C
828
_s
p_6
sp
33
.015
3
0.12
80
2.
3316
0.0
021
0.00
43
0
.012
1
65
.717
9
0.02
56
0
.004
4
0.
0001
0.2
179
101.
46
C83
0
_sp_
4
s
p
32.8
815
0.
0866
2.19
45
0
.000
0
0.
0001
0.0
244
66.4
336
0.
0214
0.0
319
0.01
85
0
.205
0
10
1.90
C
830
_s
p_5
sp
32
.643
3
0.10
22
2.
1797
0.0
000
0.00
34
0
.000
1
65
.888
8
0.03
01
0
.006
4
0.
0093
0.1
917
101.
06
C83
0
_sp_
6
s
p
32.6
745
0.
0817
2.32
15
0
.005
5
0.
0001
0.0
001
65.9
393
0.
0171
0.0
290
0.00
01
0
.172
4
10
1.24
C
832
_s
p_4
sp
32
.829
4
0.07
97
1.
5824
0.0
129
0.00
01
0
.000
1
67
.890
9
0.01
67
0
.023
1
0.
0001
0.2
057
102.
64
C83
2
_sp_
5
s
p
32.9
502
0.
0677
1.55
53
0
.000
0
0.
0002
0.0
053
67.5
590
0.
0237
0.0
160
0.00
01
0
.183
4
10
2.36
C
832
_s
p_6
sp
32
.809
3
0.08
58
1.
5989
0.0
043
0.00
01
0
.000
1
67
.566
2
0.04
11
0
.006
0
0.
0001
0.1
899
102.
30
C83
3
_sp_
7
s
p
33.1
636
0.
0597
4.05
69
0
.000
0
0.
0001
1.0
693
63.7
787
0.
0473
0.0
131
0.00
36
0
.173
5
10
2.37
C
833
_s
p_8
sp
33
.173
8
0.06
39
4.
5800
0.0
000
0.00
01
1
.890
2
61
.826
5
0.03
37
0
.024
0
0.
0058
0.1
541
101.
75
C83
3
_sp_
9
s
p
33.0
964
0.
0714
4.33
27
0
.000
0
0.
0060
1.4
492
62.5
710
0.
0250
0.0
178
0.00
01
0
.134
3
10
1.70
C
834
_s
p_4
sp
32
.950
1
0.12
10
3.
6443
0.0
206
0.00
80
0
.016
8
64
.728
6
0.03
46
0
.016
0
0.
0001
0.1
776
101.
72
C83
4
_sp_
5
s
p
33.0
050
0.
1806
3.74
90
0
.000
0
0.
0035
0.0
072
64.5
842
0.
0306
0.0
301
0.00
59
0
.145
6
10
1.74
C
834
_s
p_6
sp
32
.880
7
0.12
89
3.
6523
0.0
000
0.00
12
0
.013
7
64
.290
0
0.03
35
0
.021
4
0.
0001
0.1
759
101.
20
C83
5
_sp_
4
s
p
32.6
831
0.
1670
2.61
62
0
.003
9
0.
0001
0.0
165
65.3
671
0.
0284
0.0
181
0.01
36
0
.176
4
10
1.09
C
835
_s
p_5
sp
32
.546
9
0.16
30
2.
6051
0.0
037
0.00
02
0
.000
1
65
.128
3
0.02
12
0
.023
3
0.
0113
0.1
693
100.
67
C83
5
_sp_
6
s
p
32.8
794
0.
1597
2.68
47
0
.009
6
0.
0023
0.0
123
65.7
481
0.
0346
0.0
231
0.00
01
0
.161
7
10
1.72
C
836
_s
p_4
sp
32
.979
9
0.05
61
3.
6208
0.0
000
0.00
38
0
.013
2
64
.026
5
0.02
97
0
.036
6
0.
0001
0.1
395
100.
91
C83
6
_sp_
5
s
p
32.7
974
0.
0647
3.64
18
0
.000
0
0.
0001
0.0
001
64.3
710
0.
0327
0.0
218
0.00
01
0
.164
2
10
1.09
C
836
_s
p_6
sp
32
.981
2
0.06
31
3.
6616
0.0
000
0.00
01
0
.003
4
63
.924
3
0.02
10
0
.015
3
0.
0001
0.1
722
100.
84
C83
8
_sp_
4
s
p
32.6
730
0.
1026
3.26
07
0
.000
0
0.
0035
0.0
001
65.2
218
0.
0291
0.0
015
0.00
01
0
.129
1
10
1.42
C
838
_s
p_5
sp
32
.780
6
0.10
43
3.
2474
0.0
000
0.00
11
0
.009
4
64
.830
2
0.04
91
0
.012
1
0.
0120
0.1
083
101.
15
C83
8
_sp_
6
s
p
32.4
375
0.
1016
2.97
65
0
.005
0
0.
0001
0.0
001
64.8
194
0.
0215
0.0
200
0.00
44
0
.134
1
10
0.52
C
840
_s
p_7
sp
33
.010
5
0.13
41
3.
6755
0.0
101
0.00
53
0
.000
1
64
.959
7
0.03
45
0
.028
2
0.
0023
0.1
628
102.
02
C84
0
_sp_
8
s
p
33.0
391
0.
1353
3.79
24
0
.000
0
0.
0001
0.0
072
64.9
472
0.
0335
0.0
285
0.01
42
0
.170
2
10
2.17
C
840
_s
p_9
sp
33
.128
1
0.11
61
3.
8214
0.0
000
0.00
34
0
.002
4
64
.812
0
0.04
32
0
.019
5
0.
0001
0.1
730
102.
12
C84
1
_sp_
7
s
p
32.8
808
0.
2048
3.31
40
0
.000
0
0.
0040
0.0
144
65.0
387
0.
0335
0.0
019
0.00
38
0
.174
4
10
1.67
C
841
_s
p_8
sp
32
.715
4
0.21
65
3.
3602
0.0
047
0.00
39
0
.070
3
64
.985
5
0.03
27
0
.022
3
0.
0050
0.1
772
101.
59
C84
1
_sp_
9
s
p
32.8
519
0.
2054
3.46
03
0
.006
3
0.
0035
0.0
299
64.8
973
0.
0165
0.0
206
0.00
19
0
.150
4
10
1.64
C
842
_s
p_1
sp
33
.115
9
0.27
20
1.
1329
0.0
047
0.00
01
0
.017
4
67
.939
3
0.04
45
0
.008
5
0.
0001
0.1
697
102.
71
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
39
C84
2
_sp_
2
s
p
33.2
273
0.
2751
1.12
62
0
.001
8
0.
0035
0.0
001
67.5
577
0.
0189
0.0
290
0.00
01
0
.144
8
10
2.38
C
842
_s
p_3
sp
32
.896
8
0.30
79
1.
0672
0.0
043
0.00
96
0
.000
1
67
.510
3
0.01
44
0
.024
6
0.
0001
0.1
707
102.
01
C84
4
_sp_
1
s
p
32.8
538
0.
1088
2.05
70
0
.000
0
0.
0101
0.0
001
66.6
548
0.
0318
0.0
199
0.00
01
0
.180
9
10
1.92
C
844
_s
p_2
sp
32
.669
1
0.11
65
2.
1113
0.0
049
0.00
01
0
.010
2
66
.696
3
0.02
69
0
.010
6
0.
0077
0.1
917
101.
85
C84
4
_sp_
3
s
p
32.8
040
0.
1155
2.00
53
0
.003
3
0.
0087
0.0
075
66.4
779
0.
0377
0.0
122
0.00
49
0
.188
1
10
1.67
C
849
_s
p_3-
3-1
sp
32
.612
9
0.30
47
4.
0725
0.0
000
0.01
37
1
.100
9
62
.380
3
0.02
59
0
.025
5
0.
0001
0.2
008
100.
74
C84
9
_sp_
4-4-
1 s
p
32.5
681
0.
2303
3.60
25
0
.004
0
0.
0001
0.9
112
62.4
593
0.
0350
0.0
285
0.00
96
0
.205
3
10
0.05
R
001
A
_sp_
4
sp
32
.322
0
0.18
56
5.
4002
0.0
002
0.00
57
0
.027
2
61
.186
1
0.04
57
0
.015
7
0.
0075
0.1
738
99.3
7 R
001
A
_sp_
5
sp
32
.429
9
0.16
57
5.
3854
0.0
000
0.00
84
0
.029
2
61
.543
3
0.02
95
0
.014
6
0.
0025
0.1
696
99.7
8 R
001
A
_sp_
6
sp
32
.330
8
0.18
77
5.
5418
0.0
000
0.00
01
0
.032
8
61
.206
0
0.02
85
0
.009
6
0.
0001
0.1
519
99.4
9 R
001
B
_sp_
10
sp
32
.675
0
0.21
70
5.
5328
0.0
010
0.00
08
0
.040
4
61
.334
1
0.02
95
0
.015
6
0.
0001
0.1
798
100.
03
R00
1
B_s
p_11
s
p
32.6
396
0.
1845
5.51
57
0
.000
0
0.
0073
0.0
276
61.2
662
0.
0204
0.0
220
0.00
68
0
.164
8
99
.85
R00
1
B_s
p_12
s
p
32.8
374
0.
1905
5.53
64
0
.000
0
0.
0030
0.0
351
61.1
518
0.
0455
0.0
200
0.00
01
0
.175
9
10
0.00
R
003
A
_sp_
4
sp
33
.330
0
0.10
16
4.
9095
0.0
000
0.00
16
0
.007
8
60
.871
6
0.02
37
0
.022
0
0.
0143
0.1
804
99.4
6 R
003
A
_sp_
5
sp
33
.232
1
0.10
81
4.
7708
0.0
000
0.00
01
0
.002
0
61
.795
1
0.03
10
0
.026
0
0.
0184
0.1
815
100.
17
R00
3
A_s
p_6
s
p
33.3
748
0.
0988
4.61
71
0
.000
0
0.
0001
0.0
053
60.6
380
0.
0360
0.0
257
0.00
01
0
.191
4
98
.99
R00
3
B_s
p_10
s
p
33.1
801
0.
3516
5.44
63
0
.007
3
0.
0001
0.0
030
59.3
865
0.
0272
0.0
146
0.00
61
0
.192
4
98
.62
R00
3
B_s
p_11
s
p
33.0
274
0.
2624
5.44
83
0
.000
0
0.
0001
0.0
001
60.2
806
0.
0272
0.0
133
0.00
01
0
.186
9
99
.25
R00
3
B_s
p_12
s
p
33.1
175
0.
3664
5.46
64
0
.000
6
0.
0061
0.0
180
59.4
811
0.
0325
0.0
271
0.00
01
0
.185
4
98
.70
R04
9
_sp_
1
s
p
32.7
049
0.
0683
1.28
86
0
.000
0
0.
0055
0.0
055
66.9
792
0.
0201
0.0
000
0.01
06
0
.202
4
10
1.29
R
049
_s
p_2
sp
32
.741
2
0.04
87
1.
2944
0.0
049
0.01
27
0
.004
8
67
.685
9
0.03
16
0
.034
7
0.
0001
0.1
952
102.
05
R04
9
_sp_
3
s
p
32.8
487
0.
0582
1.89
83
0
.000
0
0.
0019
0.7
113
66.6
712
0.
0310
0.0
202
0.00
01
0
.152
6
10
2.39
R
070
_s
p_10
sp
32.8
360
0.
0539
7.82
38
0
.000
0
0.
0001
1.8
517
58.3
264
0.
0241
0.0
249
0.01
27
0
.448
6
10
1.40
R
070
_s
p_11
sp
32.7
876
0.
0562
7.71
88
0
.000
0
0.
0001
1.0
595
59.2
637
0.
0301
0.0
393
0.00
01
0
.483
1
10
1.44
R
070
_s
p_12
sp
32.7
117
0.
0387
6.31
70
0
.000
0
0.
0001
3.0
996
58.8
126
0.
0300
0.0
226
0.00
01
0
.452
1
10
1.48
R
078
_s
p_1-
1-1
sp
32
.830
8
0.02
80
6.
4012
0.0
000
0.00
01
0
.000
1
60
.461
9
0.04
99
0
.021
8
0.
0079
0.2
467
100.
05
R07
8
_sp_
2-2-
1 s
p
32.7
824
0.
0260
6.50
03
0
.000
0
0.
0001
0.0
001
59.6
627
0.
0347
0.0
182
0.00
95
0
.201
0
99
.24
R07
8
_sp_
3-3-
1 s
p
32.7
464
0.
0210
6.26
50
0
.000
0
0.
0013
0.0
011
59.8
620
0.
0539
0.0
198
0.00
98
0
.268
1
99
.25
R07
8
_sp_
4-4-
1 s
p
32.7
736
0.
0371
6.72
98
0
.000
0
0.
0001
0.0
131
59.6
766
0.
0406
0.0
195
0.00
01
0
.512
6
99
.80
R07
8
_sp_
5-5-
1 s
p
32.6
326
0.
0257
6.75
79
0
.000
0
0.
0001
0.0
001
59.5
371
0.
0425
0.0
066
0.01
02
0
.475
1
99
.49
R07
8
_sp_
6-6-
1 s
p
32.3
886
0.
0246
7.06
80
0
.000
0
0.
0033
0.0
091
59.2
507
0.
0507
0.0
270
0.00
81
0
.500
1
99
.33
sam
ple
po
int
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
40
C28
7
B_g
a7
g
a
1
2.88
74
0.
0254
0.
0178
0
0
.132
6
0.00
56
0.13
85
86.7
349
99.9
4 C
287
B
_ga8
ga
12.
7192
0.00
01
0.00
49
0.00
85
0.08
66
0
0.
095
8
6.50
46
9
9.42
C
287
B
_ga9
ga
12.
6889
0.00
01
0.02
48
0.01
98
0.11
3
0
0.
1112
86
.268
9
99
.23
C29
0
B_g
a10
g
a
1
2.76
58
0.
0001
0.
0097
0
0
.106
6
0.02
76
0.03
42
86.3
366
99.2
8 C
290
B
_ga1
1
ga
12.
6371
0.00
29
0.01
2
0.0
044
0.0
916
0
0.02
31
86.5
788
99.3
5 C
290
B
_ga1
2
ga
12.
5896
0.01
2
0.0
075
0.0
113
0.1
063
0
0.06
07
85.9
987
98.7
9 C
301
A
_ga4
ga
13.
2545
0.00
01
0.01
46
0.01
83
0.07
59
0.02
8
0.1
441
86.
4605
100
.00
C30
1
A_g
a5
g
a
1
3.16
33
0.
0361
0.
0133
0.
0024
0.
0931
0.
031
0
.096
4
8
6.55
4
9
9.99
C
301
A
_ga6
ga
13.
1385
0.01
55
0.01
09
0.00
01
0.11
97
0.02
81
0.16
86.
4049
99.
88
C31
7
C_g
a13
g
a
1
2.66
76
0.
006
0
.020
3
0
.021
2
0
.069
8
0
0.
0891
87
.287
7
10
0.16
C
317
C
_ga1
4
ga
12.
756
0.00
61
0.01
44
0.01
82
0.07
96
0
0.
0951
86
.992
3
99
.96
C31
7
C_g
a15
g
a
1
2.77
23
0.
0001
0.
013
0
.023
9
0
.110
2
0
0.
1581
87
.285
6
10
0.36
C
317
D
_ga1
9
ga
12.
6602
0.05
87
0.01
86
0.00
78
0.14
22
0
0.
1726
86
.428
3
99
.49
C31
7
D_g
a20
g
a
1
2.78
13
0.
049
0
.015
0
.016
6
0
.164
7
0.01
24
0.11
8
86.
7583
99.
92
C31
7
D_g
a21
g
a
1
2.63
08
0.
3445
0.
0233
0.
0108
0.
1705
0
0.17
14
85.4
396
98.7
9 C
326
A
_ga7
ga
12.
3666
0.03
27
0.01
05
0.00
74
0.12
42
0
0.
1371
84
.679
3
97
.36
C32
6
A_g
a8
g
a
1
2.15
09
0.
0555
0.
0183
0.
0025
0.
1317
0
0.09
66
85.4
298
97.8
9 C
326
A
_ga9
ga
12.
405
0.43
12
0
0.0
207
0.1
289
0.
0122
0.
1222
85
.193
6
98
.31
C32
9
aA
_ga1
0
ga
1
3.09
74
0.
0142
0.
0106
0.
0001
0.
0696
0.
0316
0.
1062
87
.568
5
10
0.90
C
329
a
A_g
a11
ga
13.
0304
0.00
01
0.00
92
0.00
61
0.11
14
0.00
91
0.08
28
86.6
664
99.9
2 C
329
a
A_g
a12
ga
12.
8047
0.00
01
0.01
89
0.01
09
0.08
45
0
0.
109
8
6.65
31
9
9.68
C
329
a
B_g
a22
ga
12.
6622
0.00
3
0.0
025
0.0
041
0.0
682
0
0.11
65
87.4
211
100.
28
C32
9
aB
_ga2
3
ga
1
2.75
78
0.
0135
0.
005
0
.012
1
0
.077
3
0.00
72
0.06
35
86.8
134
99.7
5 C
329
a
B_g
a24
ga
12.
7151
0.00
01
0.02
88
0.01
48
0.07
85
0.00
8
0.0
676
86.
6941
99.
61
C34
1
B_g
a10
g
a
1
3.23
26
0.
0096
0.
0239
0.
0076
0.
0632
0.
0373
0.
0669
86
.007
4
99
.45
C34
1
B_g
a11
g
a
1
3.14
22
0.
03
0
.022
7
0
.025
6
0
.077
4
0.02
76
0.02
72
86.9
121
100.
26
C34
1
B_g
a12
g
a
1
3.12
76
0.
0213
0.
0182
0.
0053
0.
1049
0
0.06
89
86.6
657
100.
01
C34
1
D_g
a22
g
a
1
3.20
04
0.
0001
0
0
.012
4
0
.075
4
0
0.
1167
86
.185
8
99
.59
C34
1
D_g
a23
g
a
1
3.13
34
0.
0233
0.
0093
0
0
.053
4
0
0.
0696
86
.517
1
99
.81
C34
1
D_g
a24
g
a
1
3.20
52
0.
0259
0.
014
0
.010
6
0
.099
1
0.02
21
0.04
89
86.8
464
100.
27
C35
9
B_g
a13
g
a
1
2.85
78
0.
0411
0.
0008
0.
013
0.
2387
0.
0426
0.
0255
87
.076
10
0.30
C
359
B
_ga1
4
ga
12.
9805
0.02
62
0.01
74
0.02
12
0.20
55
0.01
88
0.00
01
87.1
207
100.
39
C35
9
B_g
a15
g
a
1
2.93
53
0.
0218
0.
0168
0.
007
0.
2233
0.
0124
0.
0001
86
.507
1
99
.72
C36
2
A_g
a4
g
a
1
2.56
34
0.
021
0
.018
6
0
.008
0
.128
7
0.03
48
0.12
93
86.0
127
98.9
2 C
362
A
_ga5
ga
12.
6081
0.02
67
0.01
15
0.00
91
0.04
69
0
0.
0567
86
.323
99
.08
C36
2
A_g
a6
g
a
1
2.47
79
0.
0385
0.
0092
0.
0202
0.
0806
0
0.09
26
86.3
103
99.0
3 C
362
C
_ga2
2
ga
12.
7457
0.01
78
0.01
75
0.01
08
0.05
9
0
0.
0994
85
.812
8
98
.76
C36
2
C_g
a23
g
a
1
2.62
55
0.
0371
0.
0061
0.
0135
0.
1306
0
0.11
64
86.3
635
99.2
9
sam
ple
poin
t
t
ype
W
%(S
)
W
%(Z
n)
W
%(A
s)
W
%(S
e)
W
%(A
g)
W
%(C
d)
W
%(S
b)
W
%(P
b)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
41
C36
2
C_g
a24
g
a
1
2.61
94
0.
004
0
.015
8
0
.001
1
0
.086
6
0.00
45
0.09
01
86.3
349
99.1
6 C
364
A
_ga7
ga
12.
8603
0.05
58
0.00
21
0.00
34
1.03
22
0
0.
0001
83
.501
3
97
.46
C36
4
A_g
a8
g
a
1
2.74
45
0.
0437
0
0
.007
9
1
.064
4
0.00
61
0.00
01
83.9
966
97.8
6 C
364
A
_ga9
ga
12.
8497
0.19
29
0.00
05
0.01
35
0.98
66
0
0.
0123
84
.251
8
98
.31
C36
5
C_g
a19
g
a
1
2.67
57
0.
015
0
.006
6
0
0.11
89
0
0.
1091
86
.276
4
99
.20
C36
5
C_g
a20
g
a
1
2.73
32
0.
0115
0.
0172
0.
0137
0.
1403
0.
0237
0.
122
8
6.25
38
9
9.32
C
365
C
_ga2
1
ga
12.
7325
0.00
27
0.01
38
0.00
02
0.12
73
0
0.
1168
87
.101
7
10
0.10
C
284
B
_ga1
0
ga
12.
8376
0.04
34
0.00
62
0.01
18
0.28
19
0.01
1
0.0
26
86.
8855
100
.10
C28
4
B_g
a11
g
a
1
2.71
55
0.
0391
0.
0021
0.
009
0.
3095
0.
0254
0.
04
8
6.71
27
9
9.85
C
284
B
_ga1
2
ga
12.
8879
0.36
68
0.00
15
0.01
91
0.30
01
0
0.
0001
86
.094
2
99
.67
C29
7
C_g
a13
g
a
1
2.80
13
0.
0001
0.
013
0
.002
7
0
.046
5
0.00
02
0.07
4
87.
3864
100
.32
C29
7
C_g
a14
g
a
1
2.64
91
0.
0001
0.
0194
0.
0117
0.
0636
0.
0121
0.
025
8
7.39
46
1
00.1
8 C
297
C
_ga1
5
ga
12.
7479
0.01
94
0.00
44
0.01
04
0.11
19
0
0.
0329
86
.992
2
99
.92
C29
9
B_g
a7
g
a
1
3.40
99
0.
2686
0.
0179
0.
0089
0.
1032
0
0.01
61
86.2
867
100.
11
C29
9
B_g
a8
g
a
1
3.33
33
0.
5612
0.
0111
0.
0118
0.
088
0
.022
7
0.02
09
86.5
593
100.
61
C29
9
B_g
a9
g
a
1
3.35
92
1.
1785
0.
0218
0.
015
0.
1115
0.
0272
0.
0001
86
.341
5
10
1.05
C
337
A
_ga7
ga
12.
0694
0.15
37
0.01
28
0.01
43
0.12
64
0
0.
0978
85
.081
9
97
.56
C33
7
A_g
a8
g
a
1
2.33
65
0.
2057
0.
0212
0.
0217
0.
0489
0.
0337
0.
0695
84
.380
8
97
.12
C33
7
A_g
a9
g
a
1
2.31
4
0.
0655
0.
0128
0.
0024
0.
1095
0
0.11
13
85.0
413
97.6
6 C
337
B
_ga1
6
ga
12.
4865
0.36
25
0.01
58
0
0.0
543
0.
003
0
.067
1
8
5.49
92
9
8.49
C
337
B
_ga1
7
ga
12.
4602
1.32
16
0.01
83
0.02
36
0.11
92
0
0.
0757
84
.943
2
98
.96
C33
7
B_g
a18
g
a
1
2.36
2
0.
2995
0.
0021
0.
0151
0.
0692
0
0.09
03
85.3
027
98.1
4 C
345
B
_ga1
0
ga
13.
3238
0.01
56
0.01
76
0.01
88
0.04
63
0
0.
0968
86
.635
4
10
0.15
C
345
B
_ga1
1
ga
13.
2677
0.03
4
0.0
181
0.0
149
0.1
091
0
0.11
81
86.5
895
100.
15
C34
5
B_g
a12
g
a
1
3.24
45
0.
0273
0.
0233
0.
022
0.
0494
0
0.05
36
86.4
64
99.8
8 C
345
C
_ga1
6
ga
13.
1737
0.01
63
0.01
56
0.01
75
0.08
9
0
0.
1353
86
.200
5
99
.65
C34
5
C_g
a17
g
a
1
3.26
67
0.
0186
0.
0188
0.
0022
0.
0928
0
0.09
56
86.5
833
100.
08
C34
5
C_g
a18
g
a
1
3.08
94
0.
0387
0.
0128
0.
0227
0.
1061
0
0.11
14
85.6
06
98.9
9 C
353
C
_ga1
6
ga
13.
0515
0.31
12
0.01
3
0.0
099
0.1
02
0
0.03
85
87.4
668
100.
99
C35
3
C_g
a17
g
a
1
2.92
94
0.
0492
0.
0145
0.
0062
0.
0761
0.
0001
0.
0459
87
.076
6
10
0.20
C
353
C
_ga1
8
ga
12.
8594
0.13
2
0.0
251
0.0
225
0.1
397
0.
0161
0.
0124
86
.761
2
99
.97
C37
9
C_g
a13
g
a
1
3.20
05
0.
0019
0.
0044
0.
0172
0.
7334
0
0.00
01
83.9
594
97.9
2 C
379
C
_ga1
3
ga
12.
7233
0.00
1
0.0
002
0.0
202
0.7
678
0.
0177
0.
0001
84
.769
3
98
.30
C37
9
C_g
a14
g
a
1
3.35
52
0.
0187
0.
0021
0.
0146
0.
7485
0.
0155
0.
0237
84
.840
6
99
.02
C37
9
C_g
a14
g
a
1
2.78
95
0.
0001
0.
0029
0.
0079
0.
8121
0
0.00
23
84.5
23
98.1
4 C
379
C
_ga1
5
ga
13.
2699
0.01
35
0.00
2
0.0
106
0.8
065
0
0.00
36
83.8
33
97.9
4 C
379
C
_ga1
5
ga
12.
7988
0.03
54
0.00
94
0.01
93
0.81
69
0
0.
0001
84
.894
8
98
.57
C38
5
B_g
a13
g
a
1
3.34
95
0.
1797
0.
0053
0.
0198
0.
076
0
.016
7
0.05
34
87.3
425
101.
04
sam
ple
poin
t
t
ype
W
%(S
)
W
%(Z
n)
W
%(A
s)
W
%(S
e)
W
%(A
g)
W
%(C
d)
W
%(S
b)
W
%(P
b)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
42
C38
5
B_g
a14
ga
13.
2023
0.12
88
0.01
68
0.01
55
0.08
05
0.02
42
0.04
77
87.0
878
100.
60
C38
5
B_g
a15
ga
13.
2461
0.36
01
0.02
61
0.02
22
0.05
47
0
0.
0835
85
.652
9
99
.45
C38
5
C_g
a22
ga
13.
2357
0.03
41
0.00
36
0.00
85
0.07
3
0.0
023
0.
0561
85
.793
4
99
.21
C38
5
C_g
a23
ga
13.
3775
0.07
31
0.01
71
0.00
28
0.05
39
0
0.
0749
87
.666
6
10
1.27
C
385
C
_ga2
4
ga
1
3.16
85
0.
1016
0.
0158
0.
0195
0.
0824
0.
0011
0.
0922
85
.923
4
99
.40
C37
8
B_g
a10
ga
12.
587
0.00
01
0.01
79
0.01
66
0.06
18
0
0.
0813
86
.121
3
98
.89
C37
8
B_g
a11
ga
12.
7076
0.00
1
0.0
05
0
0.
0441
0.
0079
0.
0913
87
.132
2
99
.99
C37
8
B_g
a12
ga
12.
6313
0.00
62
0.02
05
0.01
81
0.08
78
0
0.
0659
86
.550
4
99
.38
C37
8
B_g
a7
g
a
12
.633
9
0.0
194
0.0
017
0.0
065
0.0
886
0.
0065
0.
0969
87
.080
6
99
.93
C37
8
B_g
a8
g
a
12
.656
0.0
125
0.0
008
0.0
099
0.1
017
0
0.1
86.
2547
99.
14
C37
8
B_g
a9
g
a
13
.996
2
0.0
415
0.0
219
0.0
041
0.0
997
0
0.05
35
83.3
915
97.6
1 sa
mpl
e po
int
typ
e
W%
(S )
W%
(Zn)
W%
(As)
W%
(Se)
W%
(Ag)
W%
(Cd)
W%
(Sb)
W%
(Pb)
W%
(sum
)
C07
9
_C
py_1
0
cp
y
34
.573
5
0.00
57
29
.787
7
0
0.00
01
33.8
967
0
.074
2
0.
0197
0.00
78
0
.000
1
0.
0001
98
.37
C07
9
_C
py_1
1
cp
y
34
.927
1
0.00
01
30
.089
0
0.00
32
33.9
158
0
.066
0.
0148
0.00
01
0
.018
4
0.
0001
99
.03
C07
9
_C
py_1
2
cp
y
34
.649
5
0.00
01
30
.034
0
0.00
45
33.9
894
0
.072
5
0.
017
0.0
028
0.00
01
0.
0001
98
.77
C08
2
_C
py_4
cp
y
34
.159
6
0.00
96
30
.318
3
0
0.00
01
33.8
851
0
.053
5
0.
0284
0.01
04
0
.046
2
0.
0001
98
.51
C08
2
_C
py_5
cp
y
34
.292
5
0.01
23
30
.412
0
0.00
01
34.0
305
0
.083
3
0.
0219
0.00
45
0
.000
1
0.
0093
98
.87
C08
2
_C
py_6
cp
y
33
.997
6
0.00
72
30
.201
5
0
0.00
52
33.8
913
0
.057
0.
0104
0.01
26
0
.000
1
0.
0001
98
.18
C28
0
B_C
py_7
cpy
34.4
282
0.
0032
29.3
276
0
0.
0009
32
.615
2
0.0
577
0.01
42
0.
0083
0.0
001
0.00
01
96.4
6 C
280
B
_Cpy
_8
c
py
34
.490
3
0.00
01
29
.562
5
0
0.00
01
32.9
57
0
.068
2
0.
0118
0.00
35
0
.018
4
0.
0001
97
.11
C28
0
B_C
py_9
cpy
34.2
462
0.
0073
29.2
814
0
0.
0001
32
.625
1
0.0
718
0.01
97
0.
0155
0.0
001
0.00
01
96.2
7 C
284
B
_Cpy
_7
c
py
34
.748
1
0.00
01
29
.643
7
0
0.00
01
31.7
972
0
.067
8
0.
0142
0.00
59
0
.000
1
0.
001
9
6.28
C
284
B
_Cpy
_8
c
py
34
.957
4
0.00
74
29
.606
6
0
0.00
06
32.2
721
0
.064
7
0.
0242
0.00
86
0
.006
4
0.
0095
96
.96
C28
4
B_C
py_9
cpy
34.5
931
0.
002
29.
5471
0
0.
0008
32
.346
5
0.0
651
0.02
08
0.
0209
0.0
001
0.00
01
96.6
0 C
290
C
_Cpy
_16
c
py
34
.386
9
0.00
53
29
.785
8
0
0.00
01
33.0
072
0
.060
9
0.
0151
0.01
18
0
.000
1
0.
0001
97
.27
C29
0
C_C
py_1
7
cpy
34.3
392
0.
0062
29.8
398
0
0.
0001
32
.904
1
0.0
634
0.01
4
0
.011
1
0.
0123
0.00
01
97.1
9 C
290
C
_Cpy
_18
c
py
34
.224
5
0.00
23
29
.741
5
0
0.00
6
33.
1172
0.04
79
0
.014
1
0.
0142
0.0
001
0.00
01
97.1
7 C
292
A
_Cpy
_1
c
py
34
.685
0.00
32
29
.867
8
0
0.00
79
32.5
974
0
.059
4
0.
0283
0.01
71
0
.003
0.
0001
97
.27
C29
2
A_C
py_2
cpy
34.6
582
0.
0072
30.0
583
0
0.
0001
33
.035
4
0.0
682
0.02
27
0.
0004
0.0
375
0.00
01
97.8
9 C
292
A
_Cpy
_3
c
py
34
.528
8
0.00
01
29
.640
4
0
0.00
01
32.4
534
0
.072
5
0.
0224
0.00
6
0
.034
5
0.
0001
96
.76
C29
7
C_C
py_1
0
cpy
34.8
089
0.
0011
29.4
72
0
0.
0001
31
.366
5
0.0
717
0.03
32
0.
0144
0.0
084
0.00
01
95.7
8 C
297
C
_Cpy
_11
c
py
34
.881
5
0.00
01
29
.769
9
0
0.00
01
31.8
953
0
.065
1
0.
0114
0.00
65
0
.024
0.
0001
96
.65
C29
7
C_C
py_1
2
cpy
34.9
128
0.
0061
29.5
942
0
0.
0124
31
.443
8
0.0
621
0.02
11
0.
017
0.0
018
0.00
01
96.0
7
sam
ple
poin
t
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W%
(Cu)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Au)
W
%(B
i) W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
43
C31
7
A_C
py_1
cp
y
34.
8137
0
.000
1
29
.772
9
0
0.00
01
32.6
096
0
.048
7
0.
0164
0.0
06
0.00
01
0.
0001
97
.27
C31
7
A_C
py_2
cp
y
34.
772
0.00
01
2
9.50
45
0
0.00
01
32.5
853
0
.078
7
0.
0339
0.0
026
0.00
01
0.
0001
96
.98
C31
7
A_C
py_3
cp
y
34.
7319
0
.000
4
29
.609
1
0
0.00
01
32.3
709
0
.063
6
0.
0186
0.0
001
0.00
01
0.
0001
96
.79
C32
3
A_C
py_1
cp
y
34.
6009
0
.004
5
29
.469
3
0
0.00
01
31.5
106
0
.074
3
0.
0125
0.0
279
0.00
01
0.
0001
95
.70
C32
3
A_C
py_2
cp
y
34.
628
0.00
01
2
9.73
3
0
0.
0036
32
.065
3
0.0
723
0.00
58
0
.048
1
0.
0307
0.00
01
96.5
9 C
323
A
_Cpy
_3
cpy
3
4.64
64
0.0
07
29.5
517
0
0.
0001
31
.729
1
0.0
802
0.02
11
0
.044
9
0.
0001
0.00
01
96.0
8 C
329
a
A_C
py_1
cpy
3
4.59
83
0.0
075
29.8
782
0
0.
0001
32
.463
2
0.0
673
0.00
87
0
.025
2
0.
0001
0.00
01
97.0
5 C
329
a
A_C
py_2
cpy
3
4.58
02
0.0
049
29.7
585
0
0.
0001
32
.443
0.0
571
0.01
06
0
.023
1
0.
0213
0.00
01
96.9
0 C
329
a
A_C
py_3
cpy
3
4.67
67
0.0
001
29.9
271
0
0.
0182
32
.413
7
0.0
698
0.01
99
0
.029
2
0.
0001
0.00
01
97.1
5 C
329
a
B_C
py_1
3
cpy
3
4.49
01
0.0
029
29.6
813
0
0.
0001
31
.898
1
0.0
695
0.01
97
0
.02
0.
0057
0.00
01
96.1
9 C
329
a
B_C
py_1
4
cpy
3
4.81
19
0.0
015
29.7
983
0
0.
0088
32
.264
0.0
746
0.00
84
0
.025
5
0.
0036
0.00
01
97.0
0 C
329
a
B_C
py_1
5
cpy
3
4.74
5
0.
0001
29.
6755
0
0.
0002
32
.319
0.0
719
0.02
35
0
.033
6
0.
0001
0.00
01
96.8
7 C
329
b
A_C
py_4
cpy
3
5.93
27
0.0
119
30.0
628
0
0.
0053
33
.072
6
0.0
573
0.02
02
0
.000
3
0.
0001
0.00
01
99.1
6 C
329
b
A_C
py_5
cpy
3
6.17
6
0.
007
30.
0851
0
0.
0115
32
.946
1
0.0
632
0.02
5
0
.000
1
0.
0001
0.00
19
99.3
2 C
329
b
A_C
py_6
cpy
3
5.90
24
0.0
001
30.2
312
0
0.
0001
32
.963
9
0.0
637
0.02
46
0
.000
1
0.
0215
0.00
01
99.2
1 C
329
b
B_C
py_1
3
cpy
3
5.88
08
0.0
034
29.7
702
0
0.
0011
33
.259
0.0
695
0.01
03
0
.000
3
0.
0001
0.00
01
98.9
9 C
329
b
B_C
py_1
4
cpy
3
6.06
21
0.0
001
29.5
645
0
0.
0071
33
.085
9
0.0
639
0.00
64
0
.000
1
0.
0001
0.00
01
98.7
9 C
329
b
B_C
py_1
5
cpy
3
5.85
58
0.0
001
29.8
539
0
0.
005
3
2.84
72
0.0
704
0.01
06
0
.003
1
0.
0001
0.00
01
98.6
5 C
343
C
_Cpy
_13
c
py
34
.955
2
0.00
24
2
9.41
29
0
0.01
15
31.8
774
0
.069
9
0.
0156
0.0
658
0.00
62
0.
0001
96
.42
C34
3
C_C
py_1
4
cpy
34.7
455
0.
0001
29.
7748
0
0.
0001
32
.076
6
0.0
662
0.01
85
0
.057
4
0.
0001
0.00
01
96.7
4 C
343
C
_Cpy
_15
c
py
34
.795
7
0.00
01
2
9.67
22
0
0.00
27
32.1
64
0
.058
2
0.
0187
0.0
585
0.06
6
0
.000
1
96.8
4 C
350
B
_Cpy
_7
cpy
3
4.51
96
0.0
141
29.8
461
0
0.
0182
32
.689
2
0.0
705
0.01
73
0
.021
0.
0001
0.01
22
97.2
1 C
350
B
_Cpy
_8
cpy
3
4.65
45
0.0
009
30.0
412
0
0.
004
3
2.61
91
0.0
846
0.01
39
0
.005
8
0.
0001
0.00
01
97.4
2 C
350
B
_Cpy
_9
cpy
3
4.50
74
0.0
018
29.9
898
0
0.
0001
32
.637
0.0
725
0.02
46
0
.004
3
0.
0001
0.00
01
97.2
4 C
359
B
_Cpy
_7
cpy
3
4.85
01
0.0
001
29.7
146
0
0.
0077
32
.489
5
0.0
661
0.02
33
0
.015
3
0.
0421
0.00
01
97.2
1 C
359
B
_Cpy
_8
cpy
3
4.94
88
0.0
015
29.6
27
0
0.
0001
32
.794
9
0.0
787
0.02
92
0
.039
8
0.
0001
0.00
01
97.5
2 C
359
B
_Cpy
_9
cpy
3
4.88
13
0.0
042
29.5
716
0
0.
0001
32
.506
0.0
704
0.01
0
.022
3
0.
0416
0.00
01
97.1
1 C
364
C
_Cpy
_31
c
py
34
.352
9
0.00
48
2
9.98
33
0
0.00
01
33.0
346
0
.064
6
0.
0223
0.0
061
0.01
74
0.
0036
97
.49
C36
4
C_C
py_3
2
cpy
34.5
076
0.
0001
29.
7768
0
0.
009
3
2.99
64
0.0
691
0.01
51
0
.026
5
0.
0001
0.00
01
97.4
0 C
364
C
_Cpy
_33
c
py
34
.327
0.00
01
2
9.69
45
0
0.00
11
32.3
585
0
.055
2
0.
015
0.0
479
0.00
4
0
.005
8
96.5
1 C
369
C
_Cpy
_13
c
py
36
.063
0.00
01
2
9.99
63
0
0.00
01
33.3
975
0
.072
8
0.
0184
0.0
123
0.00
01
0.
0001
99
.56
C36
9
C_C
py_1
4
cpy
36.3
896
0.
0001
29.
6639
0
0.
0001
33
.237
3
0.0
633
0.02
61
0
.022
3
0.
0583
0.00
01
99.4
6 C
369
C
_Cpy
_15
c
py
35
.712
8
0.00
01
2
9.62
35
0
0.00
14
33.1
607
0
.064
9
0.
0184
0.0
226
0.04
19
0.
0001
98
.65
C37
8
B_C
py_1
3
cp
y
34.
526
0.00
01
2
9.75
4
0
0.
0008
32
.798
5
0.0
694
0.02
09
0
.011
7
0.
004
0.0
001
97
.19
C37
8
B_C
py_1
4
cp
y
34.
5979
0
.000
1
29
.212
1
0
0.00
01
32.4
533
0
.055
5
0.
0172
0.0
044
0.00
01
0.
0001
96
.34
C37
8
B_C
py_1
5
cp
y
34.
4275
0
.001
9
29
.346
8
0
0.00
19
32.3
053
0
.066
7
0.
0096
0.0
001
0.00
01
0.
0201
96
.18
C38
1
A_C
py_1
cp
y
34.
5971
0
.000
1
29
.870
7
0
0.00
61
32.3
532
0
.076
8
0.
0168
0.0
434
0.00
7
0
.000
1
96.9
7 C
381
A
_Cpy
_2
cpy
3
4.64
14
0.0
108
29.7
498
0
0.
0169
32
.689
4
0.0
778
0.02
02
0
.036
3
0.
0138
0.00
01
97.2
6
sam
ple
poin
t
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W%
(Cu)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Au)
W
%(B
i) W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
44
C38
1
A_C
py_3
cp
y
34.
9643
0
.000
1
29
.9
0
0.00
01
32.4
031
0
.063
8
0.
0245
0.0
413
0.00
01
0.
0001
97
.40
C38
5
D_C
py_2
5
cpy
36.0
024
0.
0045
29.
3764
0
0.
0001
31
.310
8
0.0
765
0.02
61
0
.003
9
0.
0001
0.00
01
96.8
0 C
385
D
_Cpy
_26
c
py
36
.105
1
0.00
56
2
9.31
96
0
0.01
7
31.
6476
0
.064
9
0.
0164
0.0
001
0.00
01
0.
0001
97
.18
C38
5
D_C
py_2
7
cpy
35.7
797
0.
0007
29.
1304
0
0.
0001
31
.037
9
0.0
666
0.01
72
0
.004
0.
0127
0.00
01
96.0
5 C
794
_
Cpy
_7
cpy
35.1
764
0.
0004
30.
0681
0
0.
0003
32
.688
1
0.0
689
0.01
93
0
.000
1
0.
0001
0.00
41
98.0
3 C
794
_
Cpy
_8
cpy
35.0
633
0.
0007
30.
2681
0
0.
0039
32
.285
7
0.0
527
0.00
83
0
.013
7
0.
0001
0.00
01
97.7
0 C
794
_
Cpy
_9
cpy
35.0
185
0.
0001
30.
0075
0
0.
0071
32
.421
3
0.0
59
0.01
35
0
.004
7
0.
0001
0.00
41
97.5
4 C
801
_
Cpy
_11
cpy
33.6
62
0.
0001
30.
5901
0
0.
0001
31
.345
1
0.6
064
0.02
45
0
.015
7
0.
0001
0.00
77
96.2
5 C
803
_
Cpy
_7
cpy
34.7
955
0.
0001
30.
1988
0
0.
0014
32
.605
7
0.0
647
0.02
35
0
.015
3
0.
0001
0.00
01
97.7
1 C
803
_
Cpy
_8
cpy
35.0
575
0.
0016
30.
0195
0
0.
0001
32
.800
6
0.0
621
0.01
58
0
.029
7
0.
0178
0.00
01
98.0
0 C
803
_
Cpy
_9
cpy
34.8
997
0.
0001
30.
0836
0
0.
0001
32
.787
3
0.0
566
0.01
97
0
.002
4
0.
0061
0.00
68
97.8
6 C
809
_
Cpy
_4
cpy
35.2
576
0.
0001
30.
0658
0
0.
0001
33
.345
1
0.0
699
0.01
86
0
.000
1
0.
0001
0.02
74
98.7
8 C
809
_
Cpy
_5
cpy
35.1
102
0.
0066
30.
1312
0
0.
0076
33
.387
7
0.0
659
0.02
39
0
.010
8
0.
0024
0.00
01
98.7
5 C
809
_
Cpy
_6
cpy
35.2
419
0.
0085
30.
2487
0
0.
0001
33
.703
2
0.0
699
0.01
35
0
.006
4
0.
0001
0.00
72
99.3
0 C
814
_
Cpy
_1
cpy
34.2
9
0
.000
1
30
.100
5
0
0.00
01
33.9
254
0
.064
9
0.
0189
0.0
444
0.02
52
0.
0001
98
.47
C81
4
_C
py_2
c
py
34
.399
0.00
19
3
0.00
89
0
0.00
01
34.1
57
0
.078
9
0.
0065
0.0
185
0.00
01
0.
0001
98
.67
C81
4
_C
py_3
c
py
34
.540
3
0.00
01
3
0.02
1
0
0.
0001
34
.006
5
0.0
589
0.02
34
0
.022
4
0.
0001
0.00
01
98.6
7 C
822
_
Cpy
_4
cpy
34.4
232
0.
0055
30.
9275
0
0.
0001
32
.618
6
0.0
62
0.00
86
0
.043
9
0.
0001
0.00
01
98.0
9 C
822
_
Cpy
_5
cpy
34.6
667
0.
0001
30.
833
0
0.00
01
32.8
575
0
.052
8
0.
0098
0.0
333
0.00
01
0.
0001
98
.45
C82
2
_C
py_6
c
py
34
.662
5
0.00
46
3
0.89
05
0
0.01
05
32.9
633
0
.069
0.
0165
0.0
301
0.03
65
0.
0001
98
.68
C82
4
_C
py_1
c
py
34
.390
4
0.20
98
3
0.70
66
0
0.00
01
33.1
532
0
.058
6
0.
0045
0.0
205
0.00
01
0.
0001
98
.54
C82
4
_C
py_2
c
py
34
.499
5
0.01
55
3
0.87
08
0
0.00
01
33.3
494
0
.077
9
0.
0176
0.0
409
0.04
21
0.
0001
98
.91
C82
4
_C
py_3
c
py
34
.293
6
0.01
46
3
0.80
5
0
0.
0001
33
.492
2
0.0
745
0.01
62
0
.022
6
0.
0432
0.00
01
98.7
6 C
825
_
Cpy
_7
cpy
34.3
396
0.
0051
30.
7701
0
0.
0009
32
.304
4
0.0
782
0.02
9
0
.038
5
0.
0001
0.00
01
97.5
7 C
825
_
Cpy
_8
cpy
34.2
754
0.
0049
30.
4228
0
0.
0001
32
.678
7
0.0
748
0.01
33
0
.055
2
0.
0025
0.00
01
97.5
3 C
825
_
Cpy
_9
cpy
34.3
38
0.
0023
30.
6143
0
0.
0001
33
.000
7
0.0
698
0.02
22
0
.042
9
0.
0001
0.00
01
98.0
9 C
826
_
Cpy
_1
cpy
34.6
791
0.
0006
29.
8762
0
0.
0001
33
.993
2
0.0
781
0.01
43
0
.010
3
0.
0001
0.00
01
98.6
5 C
826
_
Cpy
_2
cpy
34.6
636
0.
0001
29.
9686
0
0.
0001
33
.640
1
0.0
558
0.01
74
0
.023
2
0.
0095
0.00
01
98.3
8 C
826
_
Cpy
_3
cpy
34.6
549
0.
0043
30.
019
0
0.00
01
33.8
09
0
.070
9
0.
0148
0.0
088
0.00
01
0.
0001
98
.58
C82
8
_C
py_7
c
py
34
.524
7
0.00
16
3
0.75
22
0
0.00
01
33.2
876
0
.054
5
0.
0196
0.0
122
0.00
01
0.
0001
98
.65
C82
8
_C
py_8
c
py
34
.297
4
0.01
15
3
0.69
55
0
0.00
05
33.1
405
0
.061
4
0.
0271
0.0
005
0.01
34
0.
0001
98
.25
C82
8
_C
py_9
c
py
34
.446
6
0.00
99
3
0.64
42
0
0.00
01
32.9
123
0
.062
8
0.
0145
0.0
013
0.00
01
0.
0001
98
.09
C83
3
_C
py_4
c
py
34
.891
4
0.02
57
2
9.93
39
0
0.00
01
33.7
704
0
.081
1
0.
0137
0.0
058
0.00
01
0.
0001
98
.72
C83
3
_C
py_5
c
py
34
.752
8
0.01
11
2
9.89
24
0
0.00
2
33.
5366
0
.072
8
0.
0187
0.0
108
0.01
19
0.
0001
98
.31
C83
3
_C
py_6
c
py
34
.982
7
0.00
04
2
9.72
43
0
0.01
24
33.6
196
0
.069
0.
0146
0.0
153
0.00
01
0.
0001
98
.44
C83
5
_C
py_7
c
py
34
.388
4
0.00
01
3
0.56
97
0
0.01
46
32.8
07
0
.075
8
0.
0269
0.0
001
0.00
01
0.
0001
97
.88
C83
5
_C
py_8
c
py
34
.311
3
0.00
01
3
0.88
83
0
0.00
01
32.6
705
0
.077
4
0.
0217
0.0
291
0.03
77
0.
0001
98
.04
C83
5
_C
py_9
c
py
34
.639
7
0.00
01
3
0.50
74
0
0.00
01
32.8
075
0
.063
9
0.
0103
0.0
087
0.00
01
0.
0001
98
.04
sam
ple
poin
t
ty
pe
W%
(S )
W
%(M
n)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W%
(Cu)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Au)
W
%(B
i) W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
45
C84
0
_C
py_4
c
py
35
.454
1
0.00
5
3
0.63
88
0
0.00
01
32.9
504
0
.059
0.
0253
0.0
545
0.02
03
0.
0001
99
.21
C84
0
_C
py_5
c
py
35
.445
2
0.00
01
3
0.83
09
0
0.00
14
33.1
199
0
.074
1
0.
0136
0.0
467
0.00
01
0.
0001
99
.53
C84
1
_C
py_4
c
py
34
.664
1
0.00
01
2
9.85
62
0
0.00
44
34.2
495
0
.056
3
0.
0063
0.0
228
0.00
01
0.
0001
98
.86
C84
1
_C
py_5
c
py
34
.640
2
0.00
23
3
0.28
72
0
0.01
21
34.0
111
0
.069
9
0.
0087
0.0
369
0.01
0
.003
6
99.0
8 C
841
_
Cpy
_6
cpy
34.9
441
0.
0001
30.
1559
0
0.
0001
34
.061
4
0.0
775
0.00
1
0.02
66
0
.039
7
0.
0001
99
.31
C84
8
_C
py_1
3
cp
y
34.
4948
0
.021
3
31
.636
8
0
0.00
01
33.6
053
0
.051
9
0.
0341
0.0
234
0.00
41
0.
0001
99
.87
C84
8
_C
py_1
4
cp
y
34.
1082
0
.064
8
31
.703
8
0
0.01
04
33.0
579
0
.048
0.
013
0.
0193
0.0
18
0.00
01
99.0
4 C
848
_
Cpy
_15
cpy
3
4.29
55
0.0
573
31.2
964
0
0.
0011
33
.599
1
0.0
7
0.01
34
0
.028
3
0.
0001
0.00
19
99.3
6 R
049
_
Cpy
_4
cpy
34.5
265
0.
0001
30.
1975
0
0.
0065
34
.360
4
0.0
749
0.01
23
0
.031
7
0.
0176
0.01
32
99.2
4 R
049
_
Cpy
_5
cpy
34.3
152
0.
0001
30.
2553
0
0.
0091
34
.251
6
0.0
625
0.01
49
0
.036
3
0.
0472
0.00
01
98.9
9 R
049
_
Cpy
_6
cpy
34.3
924
0.
0001
30.
4128
0
0.
0001
34
.265
7
0.0
517
0.01
39
0
.006
4
0.
0372
0.00
01
99.1
8 R
070
_
Cpy
_7
cpy
34.1
842
0.
0057
30.
2157
0
0.
0001
34
.313
1
0.0
752
0.02
53
0
.008
2
0.
0001
0.00
01
98.8
3 R
070
_
Cpy
_8
cpy
34.3
271
0.
0042
29.
9601
0
0.
0005
34
.242
1
0.0
672
0.02
58
0
.003
5
0.
0076
0.01
56
98.6
5 R
070
_
Cpy
_9
cpy
34.0
974
0.
0036
29.
9138
0
0.
0001
33
.924
3
0.0
847
0.01
79
0
.067
0.
0326
0.00
01
98.1
4 R
075
_
Cpy
_7-7
-1
cpy
34.5
951
0.
0001
29.
6783
0
0.
0001
33
.650
1
0.0
75
0.02
23
0
.013
2
0.
0259
0.01
49
98.0
8 R
075
_
Cpy
_8-8
-1
cpy
34.5
006
0.
0082
29.
9978
0
0.
0001
33
.804
4
0.0
774
0.01
36
0
.005
5
0.
0001
0.00
98
98.4
2 R
075
_
Cpy
_9-9
-1
cpy
34.3
736
0.
0001
29.
7824
0
0.
0039
33
.724
9
0.0
856
0.01
88
0
.000
1
0.
0001
0.00
01
97.9
9 sa
mpl
e po
int
type
W
%(S
)
W%
(Mn)
W
%(F
e)
W%
(Co)
W
%(N
i) W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W%
(sum
)
sam
ple
p
oint
t
ype
W
%(S
)
W%
(Mn)
W%
(Fe)
W
%(C
o)
W%
(Ni)
W
%(C
u)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(A
u)
W%
(Bi)
W
%(s
um)
C84
6
po_4
po
3
8.42
49
0.0
086
59
.900
5
0
0.
0001
0.0
001
0.08
69
0
.028
5
0.
0081
0.00
01
0
.000
1
98
.46
C84
6
po_5
po
3
8.73
85
0.0
001
59
.432
9
0
0.
0122
0.0
008
0.09
3
0.02
31
0.
0001
0.00
69
0
.004
9
98
.31
C84
6
po_6
po
3
8.51
65
0.0
001
59
.947
4
0
.009
4
0.
0001
0.0
012
0.10
43
0
.035
5
0.
0054
0.00
01
0
.000
1
98
.62
C84
8
po_4
po
3
8.19
61
0.0
196
60
.741
5
0
0.
0097
0.0
001
0.08
57
0
.039
3
0.
0071
0.01
87
0
.008
6
99
.13
C84
8
po_5
po
3
9.31
9
0.
0001
6
0.00
2
0.00
06
0.
0065
0.0
248
0.08
82
0
.022
2
0.
0016
0.00
01
0
.000
1
99
.47
C84
8
po_6
po
3
8.25
28
0.0
062
60
.983
4
0
0.
0043
0.0
134
0.10
55
0
.018
5
0.
0016
0.00
01
0
.000
1
99
.39
C84
8
po_7
po
3
8.28
01
0.0
115
61
.218
3
0
0.
0018
0.0
061
0.11
07
0
.022
1
0.
0001
0.00
01
0
.000
1
99
.65
C84
8
po_8
po
3
8.23
61
0.0
117
60
.835
6
0
0.
0001
0.0
097
0.09
74
0
.019
7
0.
0001
0.00
01
0
.001
1
99
.21
C84
8
po_9
po
3
8.22
2
0.
0001
6
0.89
5
0
0.01
1
0
.013
2
0.
0938
0.0
241
0.01
91
0.
0001
0.0
001
99.2
8
Appendix 4: Microprobe Analysis—Sulphides
46
C26
1
AA
spy_
4
as
py
22
.453
4
0.0
087
34.7
639
0
0.0
171
0.00
01
42
.066
1
0.1
656
0.00
01
0
.000
1
0.
0001
99.4
8 C
261
A
Asp
y_5
aspy
22.6
592
0
.004
34
.965
8
0
0
.000
1
0.
0078
42.1
275
0
.154
3
0.
0001
0.0
001
0.00
01
99
.92
C26
1
AA
spy_
6
as
py
23
.162
2
0.0
07
35.1
146
0
0.0
113
0.01
05
41
.533
8
0.1
532
0.00
01
0
.000
9
0.
0001
99.9
9 C
297
B
Asp
y_7
aspy
21.5
618
0
.000
1
34
.088
3
0
0
.000
1
0.
0001
42.2
475
0
.175
6
0.
0001
0.0
001
0.00
01
98
.07
C29
7
BA
spy_
8
as
py
20
.956
9
0.0
001
33.9
207
0
0.0
001
0.02
55
43
.124
9
0.1
639
0.00
01
0
.000
1
0.
0001
98.1
9 C
297
B
Asp
y_9
aspy
21.0
79
0
.002
3
33
.968
9
0
0
.007
3
0.
0074
42.8
918
0
.158
0.
0001
0.0
001
0.00
01
98
.12
C36
4
AA
spy_
10
asp
y
21
.591
1
0.0
085
34.4
832
0
0.0
001
0.00
01
42
.601
1
0.1
626
0.00
01
0
.000
1
0.
0069
98.8
5 C
364
A
Asp
y_11
a
spy
21.2
729
0
.017
7
34
.434
8
0
0
.000
1
0.
012
42.
8155
0
.162
1
0.
0113
0.0
001
0.00
4
9
8.73
C
364
A
Asp
y_12
a
spy
21.0
784
0
.003
6
34
.273
3
0
0
.003
6
0.
0001
43.1
498
0
.175
6
0.
0006
0.0
001
0.00
01
98
.69
C36
4
BA
spy_
16
asp
y
21
.662
8
0.0
085
34.9
084
0
0.0
001
0.02
16
42
.126
4
0.1
653
0.00
01
0
.000
1
0.
0001
98.8
9 C
364
B
Asp
y_17
a
spy
21.6
587
0
.005
2
34
.789
8
0
0
.005
9
0.
0411
42.1
384
0
.159
5
0.
0086
0.0
001
0.00
85
98
.82
C36
4
BA
spy_
18
asp
y
21
.283
7
0.0
001
35.0
426
0
0.0
001
0.00
01
42
.666
0.1
735
0.00
01
0
.000
1
0.
0001
99.1
7 C
364
B
Asp
y_28
a
spy
21.4
578
0
.000
1
34
.694
9
0
0
.000
1
0.
0168
42.7
424
0
.157
5
0.
0001
0.0
163
0.01
47
99
.10
C36
4
BA
spy_
29
asp
y
21
.391
7
0.0
001
34.5
565
0
0.0
069
0.00
89
42
.712
3
0.1
717
0.00
1
0.00
01
0.
0001
98.8
5 C
364
B
Asp
y_30
a
spy
21.1
603
0
.003
5
34
.616
2
0
0
.000
1
0.
0001
42.8
035
0
.149
3
0.
0024
0.0
001
0.00
01
98
.74
C37
2
AA
spy_
1
as
py
22
.873
2
0.0
001
34.8
281
0
0.0
001
0.00
08
41
.476
4
0.1
664
0.00
8
0.00
01
0.
0001
99.3
5 C
372
A
Asp
y_2
aspy
22.8
789
0
.000
1
34
.350
2
0
0
.000
1
0.
0001
41.6
712
0
.173
0.
0027
0.0
001
0.00
01
99
.08
C37
2
AA
spy_
3
as
py
22
.058
6
0.0
01
34.7
369
0
0.0
001
0.00
84
42
.752
0.1
477
0.00
4
0.00
01
0.
0001
99.7
1 C
372
B
Asp
y_7
aspy
23.0
547
0
.008
7
34
.538
5
0
0
.000
1
0.
0101
41.2
572
0
.155
2
0.
0023
0.0
001
0.00
01
99
.03
C37
2
BA
spy_
8
as
py
22
.382
5
0.0
001
34.1
437
0
0.0
001
0.00
01
42
.182
1
0.1
661
0.00
01
0
.018
6
0.
0003
98.8
9 C
372
B
Asp
y_9
aspy
22.4
663
0
.000
1
34
.975
1
0
0
.013
2
0.
002
42.
4215
0
.168
7
0.
01
0.
0001
0.00
01
10
0.06
C
801
A
spy_
10
a
spy
27.0
975
0
.000
1
35
.481
9
0
0
.005
3
0.
917
38.
6501
0
.156
1
0.
0201
0.0
001
0.00
01
10
2.33
C
817
A
spy_
1
a
spy
21.6
546
0
.000
1
34
.863
8
0
0
.009
8
0.
0019
42.3
685
0
.161
6
0.
0103
0.0
001
0.01
93
99
.09
C81
7
Asp
y_2
asp
y
21
.654
8
0.0
001
35.2
573
0
0.0
001
0.00
01
42
.637
4
0.1
585
0.00
01
0
.000
1
0.
0005
99.7
1 C
817
A
spy_
3
a
spy
21.6
771
0
.000
1
34
.812
7
0
0
.002
1
0.
0001
42.3
355
0
.184
8
0.
0056
0.0
1
0.00
01
99
.03
sam
ple
poi
nt
ty
pe
W
%(S
)
W%
(Mn)
W
%(F
e)
W%
(Co)
W
%(N
i)
W%
(Cu)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Au)
W
%(B
i)
W%
(sum
)
sam
ple
poin
t
typ
e
W%
(S )
W%
(Fe)
W%
(Cu)
W%
(Zn)
W%
(As)
W%
(Se)
W%
(Ag)
W%
(Cd)
W%
(Sb)
W
%(T
e) W
%(H
g)
W%
(Pb)
W
%(B
i) W
%(s
um)
C84
9
bo_
1-1-
1 bo
urno
nite
18.
8053
0.4
032
12
.545
9 0
.009
4
0.01
98
0.0
299
0
0.02
45
23.
7037
0
.060
9
0.00
01
42
.232
4
0.0
001
97.
84
C84
9
bo_
2-2-
1 bo
urno
nite
18.
7809
0.4
553
12
.621
9 0
.000
1
0.05
02
0.0
316
0.
0114
0
23.
5692
0
.085
8
0.00
01
41
.935
8
0.0
001
97.
54
C84
9
bo_
5-5-
1 bo
urno
nite
18.
8871
0.1
278
12
.649
5 0
.013
8
0
0.
0282
0
0
24
.019
3
0.06
59
0.00
01
42
.408
0.0
001
98.
20
C84
9
bo_
6-6-
1 bo
urno
nite
18.
8372
0.6
074
12
.407
5 0
.011
7
0.40
21
0.0
321
0
0
23
.568
0.05
12
0.00
01
41
.205
6
0.0
001
97.
12
Appendix 4: Microprobe Analysis—Sulphides
47
C29
9
A
_tet
1
tet
2
6.53
28
3.68
4
3
6.17
71
3.6
093
4
.717
6
0.
0493
2.68
73
0.
0605
22.0
653
0.
0361
0.00
01
0.
0001
0.01
08
99.
63
C29
9
A
_tet
2
tet
2
6.41
84
3.74
77
35
.758
8
3.61
68
4.
814
0.0
68
2
.642
0
21.8
975
0.
0092
0.00
01
0.
0001
0.00
81
98.
98
C29
9
A
_tet
3
tet
2
6.56
79
3.72
71
35
.597
5
3.63
74
4.
7969
0.05
22
2.
5605
0.00
77
21
.994
1
0.02
47
0.
0001
0.00
01
0.
0193
9
8.99
C
299
C_t
et13
te
t
26.
4011
3.
5623
36.0
566
3.
9086
4.71
97
0.
0547
2.81
02
0.
0096
22.2
357
0.
0181
0.00
01
0.
0001
0.01
77
99.
79
C29
9
C
_tet
14
tet
2
6.62
82
3.57
66
35
.577
5
3.96
22
4.
6907
0.05
66
2.
9331
0.02
31
21
.858
6
0.01
54
0.
0001
0.00
01
0.
0001
9
9.32
C
299
C_t
et15
te
t
26.
4449
3.
5843
35.4
82
4.
315
4.71
52
0.
0376
2.90
93
0.
043
22.
2114
0.
0276
0.00
01
0.
0001
0.00
01
99.
77
C31
7
D
_tet
22
tet
2
1.81
31
4.92
95
22
.377
2
1.85
29
0
0.0
175
1
9.45
95
0
26.8
948
0.
0342
0.00
01
0.
079
0.0
001
9
7.46
C
317
D_t
et23
te
t
22.
6164
5.
3675
22.6
37
2.
6772
0
0
.023
4
19.
1316
0
.004
5
27.
0666
0.
0424
0.00
01
0.
0791
0.00
74
99.
65
C31
7
D
_tet
24
tet
2
2.44
4.90
87
22
.216
9
1.40
79
0
0.0
184
1
9.99
96
0.0
193
2
7.72
46
0.05
93
0.
0001
0.00
79
0.
018
98.8
2 C
317
D_t
et25
te
t
23.
0155
4.
8036
22.3
322
1.
44
0
0
.017
19.
0529
0
27
.628
8
0.03
17
0.
0001
0.00
01
0.
0001
9
8.32
C
329
_B_t
et10
tet
2
6.05
52
5.68
25
33
.072
2
1.31
31
6.
7171
0.06
76
8.
5619
0.01
81
18
.679
1
0.01
73
0.
0001
0.00
01
0.
0001
1
00.1
8 C
329
_B_t
et11
tet
2
6.43
53
5.66
89
33
.377
5
1.27
62
6.
582
0.0
647
8
.505
6
0.0
199
1
8.77
51
0.04
72
0.
0001
0.00
01
0.
0001
1
00.7
5 C
329
_B_t
et12
tet
2
6.16
75
5.62
53
32
.987
1.25
92
6.
6
0.0
543
8
.830
4
0.0
283
1
8.87
88
0.04
7
0.
0001
0.00
42
0.
0001
1
00.4
8 C
337
C_t
et19
te
t
22.
6613
5.
5305
26.4
893
2.
3188
0
0
.028
7
14.
7701
0
.012
6
26.
624
0
.025
1
0.
0001
0.00
01
0.
0129
9
8.47
C
337
C_t
et20
te
t
22.
8677
5.
0387
25.4
038
3.
3587
0
0
.020
5
15.
1215
0
.034
5
27.
0367
0.
0491
0.00
01
0.
0001
0.00
01
98.
93
C33
7
C
_tet
21
tet
2
2.98
35
4.91
58
27
.292
3.33
78
0
0.0
179
1
3.90
78
0.0
196
2
6.71
37
0.02
6
0.
0001
0.00
01
0.
0001
9
9.21
C
341
B_t
et7
te
t
27.
5341
5.
0392
38.1
143
2.
3117
10.6
524
0.
0827
3.12
7
0
.018
9
13.
122
0
.016
0.
0001
0.00
43
0.
0001
1
00.0
2 C
341
B_t
et8
te
t
27.
2288
4.
8775
37.5
973
2.
6946
9.29
34
0.
0759
3.31
11
0.
0188
15.3
39
0.
0273
0.00
01
0.
0001
0.00
84
100
.47
C34
1
B
_tet
9
tet
2
7.31
88
5.04
88
38
.028
3
2.35
54
10
.39
0.0
784
3
.192
0.0
66
1
3.90
14
0.00
86
0.
0001
0.00
01
0.
0019
1
00.3
9 C
341
C_t
et16
te
t
27.
3145
4.
8456
37.5
007
2.
4665
9.52
28
0.
0814
3.61
32
0.
0503
14.8
059
0.
0181
0.00
01
0.
0001
0.00
01
100
.22
C34
1
C
_tet
17
tet
2
7.22
68
4.91
41
37
.319
2
2.57
43
9.
6425
0.08
15
3.
6988
0.01
07
14
.797
5
0.02
65
0.
0001
0.00
01
0.
0001
1
00.2
9 C
341
C_t
et18
te
t
27.
2963
4.
9436
37.4
829
2.
4544
9.58
25
0.
0617
3.70
12
0.
0017
14.8
575
0.
0257
0.00
01
0.
0001
0.01
78
100
.43
C34
5
C
_tet
13
tet
2
7.61
26
5.07
63
37
.109
2.26
82
11
.118
0.08
82
4.
6222
0.01
51
12
.379
0.04
89
0.
0001
0.00
01
0.
0001
1
00.3
4 C
345
C_t
et14
te
t
27.
5187
5.
0326
37.0
7
2
.324
4
11.
0833
0
.088
7
4.6
181
0
.023
8
12.
4344
0.
0391
0.00
01
0.
0001
0.00
01
100
.23
C34
5
C
_tet
15
tet
2
7.33
87
5.06
65
37
.101
3
2.26
65
11
.102
6
0.08
9
4
.800
3
0.0
281
1
2.25
69
0.03
92
0.
0001
0.00
01
0.
0001
1
00.0
9 C
353
B_t
et7
te
t
24.
2975
4.
6308
30.2
172
2.
3032
2.65
14
0.
0203
10.6
921
0
24.
2362
0.
0295
0.00
01
0.
0001
0.01
4
99
.09
C35
3
B
_tet
8
tet
2
3.66
89
4.56
43
28
.277
9
2.41
46
1.
1905
0.03
76
12
.742
1
0
2
5.93
05
0.01
7
0.
0001
0.00
01
0.
0001
9
8.84
C
353
B_t
et9
te
t
23.
8958
4.
6796
27.6
419
2.
4657
1.13
87
0.
0309
13.1
889
0.
0151
26.1
047
0.
0503
0.00
01
0.
0001
0.00
01
99.
21
C36
2
B
_tet
13
tet
2
3.25
65
4.40
6
2
6.13
76
2.6
43
0
0.
0198
15.4
469
0.
0103
26.9
756
0.
0444
0.00
01
0.
0001
0.01
15
98.
95
C36
2
B
_tet
14
tet
2
3.16
87
4.42
34
25
.692
8
3.03
88
0
0.0
262
1
5.70
49
0
27.1
126
0.
0174
0.00
01
0.
0001
0.00
01
99.
19
C36
2
B
_tet
15
tet
2
3.28
53
4.45
2
2
5.67
7
4.5
495
0
0.
027
15.
6583
0
.019
26.
6396
0.
0243
0.00
01
0.
0001
0.00
27
100
.33
C36
2
D
_tet
25
tet
2
3.22
93
4.64
12
25
.392
7
2.18
83
0
0.0
28
1
6.05
57
0.0
369
2
6.95
21
0.04
31
0.
0001
0.00
01
0.
0244
9
8.59
C
362
D_t
et26
te
t
22.
8746
4.
7306
26.0
451
2.
0661
0
0
.018
2
15.
8699
0
.011
27.
3461
0.
0541
0.00
01
0.
0001
0.00
26
99.
02
C36
2
D
_tet
27
tet
2
3.42
05
4.61
06
26
.687
3
2.07
06
1.
1457
0.02
49
15
.035
6
0
2
5.40
44
0.04
39
0.
0001
0.00
01
0.
0448
9
8.49
C
364
A_t
et13
te
t
23.
0439
4.
349
24.
2582
2
.194
2
0
0.01
34
18
.288
6
0.03
56
26
.791
1
0.04
2
0.
0001
0.00
01
0.
1854
9
9.20
C
364
A_t
et14
te
t
22.
8182
4.
347
24.
4129
2
.266
7
0.1
432
0.02
17
18
.272
2
0.00
78
26
.49
0.03
05
0.
0001
0.00
01
0.
1504
9
8.96
C
364
A_t
et15
te
t
22.
9079
4.
3716
24.3
638
2.
241
0.05
83
0.
0153
18.1
738
0.
016
26.
6474
0.
0242
0.00
01
0.
0001
0.17
95
99.
00
C36
4
B
_tet
25
tet
2
3.04
7
4.87
64
24
.540
6
2.34
85
0.
1831
0.01
92
17
.549
6
0.03
55
26
.208
4
0.04
53
0.
0001
0.00
01
0.
5527
9
9.41
sam
ple
poin
t
typ
e W
%(S
)
W%
(Fe)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(S
b)
W%
(Te)
W
%(H
g)
W%
(Pb)
W
%(B
i)
W%
(sum
)
Appendix 4: Microprobe Analysis—Sulphides
48
C36
4
B
_tet
26
tet
2
2.96
45
4.64
67
24
.038
8
1.95
27
0.
616
0.0
16
1
7.88
46
0.0
426
2
5.22
18
0.01
73
0.
0001
0.00
01
0.
3814
9
7.78
C
364
B_t
et27
te
t
22.
9433
4.
9255
24.2
42
1.
7239
0
0
.019
1
18.
0379
0
.017
2
26.
7426
0.
0184
0.00
01
0.
0001
0.23
22
98.
90
C36
5
D
_tet
22
tet
2
2.81
47
5.20
94
22
.481
1
1.24
51
0
0.0
242
1
9.68
88
0.0
109
2
7.85
63
0.04
11
0.
0001
0.00
01
0.
0001
9
9.37
C
365
D_t
et23
te
t
22.
8006
5.
2389
22.3
614
1.
1744
0
0
.021
8
19.
4505
0
27
.605
8
0.04
39
0.
0001
0.00
01
0.
0001
9
8.70
C
365
D_t
et24
te
t
22.
3709
5.
3488
20.9
337
1.
0768
0
0
.029
2
21.
7647
0
27
.177
2
0.05
33
0.
0001
0.00
01
0.
0038
9
8.76
C
383
C_t
et19
te
t
27.
3359
5.
7265
38.0
966
2.
984
15.9
209
0.
0922
3.83
81
0.
0313
5.44
69
0.
0319
0.00
01
0.
0001
0.00
01
99.
50
C38
3
C
_tet
20
tet
2
4.38
64
4.56
85
29
.513
2
3.49
81
5.
0215
0.05
15
11
.336
4
0.02
42
20
.371
9
0.03
7
0.
0001
0.01
87
0.
0001
9
8.83
C
383
C_t
et21
te
t
23.
4959
4.
2103
26.4
11
4.
2199
2.01
31
0.
0362
14.1
159
0.
0312
23.8
216
0.
046
0.00
01
0.
0001
0.00
01
98.
40
C38
5
A
_tet
1
tet
2
6.30
84
4.93
11
33
.872
7
2.08
01
6.
2102
0.06
63
5.
762
0.0
294
1
9.18
45
0.04
74
0.
0001
0.00
01
0.
0001
9
8.49
C
385
A_t
et2
te
t
26.
1976
4.
9967
33.7
842
2.
0237
6.12
87
0.
0519
5.99
61
0
19.
3919
0.
02
0.00
01
0.
0001
0.00
24
98.
59
C38
5
A
_tet
3
tet
2
6.39
82
5.04
34
33
.964
7
2.15
92
6.
384
0.0
518
5
.801
8
0
19.3
913
0.
0253
0.00
01
0.
0001
0.00
01
99.
22
C38
5
B
_tet
7
tet
2
6.57
34
4.85
47
34
.198
7
2.44
45
6.
2028
0.05
86
5.
9508
0.04
67
19
.683
0.04
45
0.
0001
0.00
01
0.
0001
1
00.0
6 C
385
B_t
et8
te
t
26.
3906
4.
7179
33.5
046
2.
2628
6.31
04
0.
0616
5.89
56
0.
0393
19.3
555
0.
055
0.00
01
0.
0001
0.00
01
98.
59
C38
5
B
_tet
9
tet
2
6.45
23
4.84
88
33
.972
2.41
62
6.
24
0.0
783
5
.896
4
0.0
67
1
9.53
53
0.03
6
0.
0001
0.00
01
0.
0001
9
9.54
C
844
tet_
4
te
t
25.
7895
4.
6235
37.4
198
2.
9463
6.68
33
0.
0677
3.12
7
0
.015
5
18.
2763
0.
0219
0.00
01
0.
0001
0.00
01
98.
97
C84
4
te
t_5
tet
2
5.67
15
4.55
01
37
.605
8
3.12
75
6.
7766
0.06
35
3.
0677
0.01
39
18
.332
5
0.00
27
0.
0001
0.00
01
0.
0001
9
9.21
C
844
tet_
6
te
t
25.
7355
4.
6745
37.4
614
2.
9316
6.64
49
0.
0593
3.15
1
0
.016
7
18.
4516
0.
0381
0.00
01
0.
0001
0.00
01
99.
16
C81
3
te
t_7
tet
2
2.77
89
5.46
8
2
2.06
23
7.0
105
0
0.
0277
19.0
983
0.
0238
24.8
741
0.
05
0.00
01
0.
0079
0.00
01
101
.40
C81
3
te
t_8
tet
2
3.32
8
7.05
07
22
.667
1
2.21
64
0
0.0
326
1
9.76
8
0
25.7
865
0.
0614
0.00
01
0.
0001
0.00
53
100
.92
C81
2
te
t_7
tet
2
3.53
29
7.65
19
22
.328
1
1.53
59
0
0.0
205
1
9.95
87
0
25.5
415
0.
0359
0.00
01
0.
0001
0.00
01
100
.61
C81
2
te
t_8
tet
2
2.73
27
5.27
59
22
.967
5
2.86
08
0
0.0
25
2
0.95
98
0
26.1
261
0.
0674
0.00
01
0.
0001
0.00
01
101
.02
C81
2
te
t_9
tet
2
2.27
48
6.45
58
21
.308
1
3.08
39
0
0.0
272
2
0.23
65
0
25.0
099
0.
0547
0.00
01
0.
0001
0.00
01
98.
45
C83
6
te
t7
tet
2
5.23
06
5.53
71
35
.301
9
1.87
55
5.
488
0.0
614
5
.725
2
0.0
213
2
0.05
63
0.02
62
0.
0001
0.00
01
0.
0001
9
9.32
C
836
tet8
te
t
23.
7982
4.
6743
30.0
068
2.
6727
0
0
.025
4
10.
7675
0
.047
1
27.
5384
0.
0497
0.00
01
0.
0001
0.00
01
99.
58
C83
6
te
t9
tet
2
5.32
29
5.36
84
34
.346
9
3.20
09
4.
9362
0.06
48
6.
1286
0.00
31
20
.449
6
0.03
54
0.
0001
0.00
01
0.
0001
9
9.86
C
836
tet1
0
te
t
25.
1804
5.
1862
33.9
521
2.
2794
5.18
31
0.
0511
6.17
97
0.
0072
20.6
524
0.
0467
0.00
01
0.
0001
0.02
31
98.
74
C83
6
te
t11
tet
2
5.72
8
5.45
34
35
.234
6
2.28
33
6.
5509
0.05
49
5.
2464
0.02
36
18
.595
7
0.00
91
0.
0001
0.00
01
0.
0025
9
9.18
C
836
tet1
2
te
t
24.
492
6.
6626
29.9
366
2.
4471
5.86
81
0.
0511
6.31
85
0.
0457
19.7
146
0.
037
0.00
01
4.
8489
0.00
01
100
.42
C80
1
te
t7
tet
2
7.56
9
5.32
72
39
.800
7
2.61
08
15
.955
5
0.11
64
2.
748
0.0
17
5
.277
7
0.0
302
0.00
01
0.
0228
0.00
01
99.
48
C80
1
te
t8
tet
2
5.55
7
4.32
68
35
.222
9
4.60
46
7.
5466
0.07
77
5.
7276
0.05
42
16
.484
8
0.04
0.
0001
0.02
27
0.
0138
9
9.68
C
801
tet9
te
t
27.
3347
5.
3171
39.6
489
2.
6288
16.0
448
0.
1151
2.66
38
0.
027
5.2
316
0
.025
6
0.
0001
0.00
01
0.
0001
9
9.04
C
832
tet7
te
t
24.
7692
3.
1666
32.0
273
4.
3855
3.98
75
0.
0531
9.42
06
0.
0775
21.6
016
0.
0164
0.00
01
0.
0096
0.02
94
99.
54
C83
2
te
t8
tet
2
4.80
97
3.12
88
32
.651
2
4.68
31
4.
0281
0.05
58
8.
9817
0.05
67
21
.522
0.05
4
0.
0001
0.03
69
0.
0001
1
00.0
1 C
832
tet9
te
t
24.
6138
3.
1518
31.9
653
4.
237
4.00
72
0.
042
9.3
506
0
.053
9
21.
8251
0.
0251
0.00
01
0.
0201
0.00
01
99.
29
C07
9
te
t_2
tet
2
4.63
89
5.35
23
33
.470
2
2.56
02
3.
5725
0.04
65
8.
2519
0.03
23
22
.501
3
0.03
44
0.
0001
0.00
01
0.
0001
1
00.4
6 C
842
tet7
te
t
27.
7801
3.
859
41.
7134
4
.289
17.
0899
0
.124
1.6
047
0
.044
8
4.0
944
0
.025
7
0.
0001
0.00
01
0.
0001
1
00.6
3 C
842
tet_
8
te
t
27.
7937
3.
824
41.
8737
4
.272
7
17.
118
0.11
85
1.
579
0.0
295
4
.247
5
0.0
496
0.00
01
0.
0001
0.00
01
100
.91
C84
2
te
t_9
tet
2
7.68
14
4.02
72
41
.645
3
4.03
07
17
.101
0.12
11
1.
673
0
4.21
75
0.
0187
0.00
01
0.
0001
0.00
01
100
.52
sam
ple
poin
t
typ
e W
%(S
)
W%
(Fe)
W
%(C
u)
W%
(Zn)
W
%(A
s)
W%
(Se)
W
%(A
g)
W%
(Cd)
W
%(S
b)
W%
(Te)
W
%(H
g)
W%
(Pb)
W
%(B
i)
W%
(sum
)
Appendix 4: Microprobe Analysis—Sulphides
49
C29
0
te
t_1-
1-1
tet
2
1.65
71
4.00
29
25
.285
2
2.67
09
0.
8746
0.00
76
11
.935
8
0.03
58
22
.505
1
0.05
82
0.
0001
10.3
096
0.
0001
9
9.34
C
290
tet_
3-3-
1 ?
27.
6906
4.
9198
40.8
834
3.
0811
17.2
919
0.
1037
1.92
46
0.
0189
3.68
29
0.
0297
0.00
01
0.
0001
0.00
01
99.
63
C29
0
te
t_4-
4-1
?
2
5.99
38
3.80
97
37
.845
5
3.94
73
10
.393
8
0.07
8
3
.782
7
0.0
218
1
2.86
42
0.02
67
0.
0001
0.00
01
0.
0001
9
8.76
sa
mpl
e po
int
t
ype
W%
(S )
W
%(F
e)
W%
(Cu)
W
%(Z
n)
W%
(As)
W
%(S
e)
W%
(Ag)
W
%(C
d)
W%
(Sb)
W
%(T
e)
W%
(Hg)
W
%(P
b)
W%
(Bi)
W
%(s
um)
Appendix 4: Microprobe Analysis—Sulphides
50
C01
-828
py1
a
djac
ent t
o ab
latio
n pi
t 1
em
baye
d su
bhed
ral p
yrite
- "c
lean
"
52.
4826
45.
5437
0.0
2
0.
0001
0
.516
7
0.02
25
0.04
2
0.0
341
C01
-828
py1
a
djac
ent t
o ab
latio
n pi
t 2
em
baye
d su
bhed
ral p
yrite
- "c
lean
"
53.
1482
45.
7576
0.0
337
0.
0064
0
.176
7
0.02
04
0.01
07
0 C
01-8
28 p
y1
dis
tal t
o ab
latio
n pi
t
3
em
baye
d su
bhed
ral p
yrite
- "c
lean
"
53.
3335
46.
029
0.0
081
0.
0237
0
.115
8
0.01
93
0.00
97
0.00
05
C01
-828
py2
a
djac
ent t
o ab
latio
n pi
t 4
anh
edra
l fg
crys
talli
ne m
ass
- rel
ict s
pong
iform
53.
0915
44.
9848
0.0
466
0.
0035
0
.407
8
0.02
32
0.02
04
0 C
01-8
28 p
y2
adj
acen
t to
abla
tion
pit 5
a
nhed
ral f
g cr
ysta
lline
mas
s - r
elic
t spo
ngifo
rm 5
2.86
69 4
5.03
15 0
.051
2
0.01
89
0.3
441
0.
0224
0.
017
0
C
01-8
28 p
y2
dis
tal t
o ab
latio
n pi
t
6
anh
edra
l fg
crys
talli
ne m
ass
- rel
ict s
pong
iform
53.
0902
44.
783
0.1
354
0.
0001
0
.369
3
0.01
87
0.00
91
0.00
34
C01
-828
py3
a
djac
ent t
o ab
latio
n pi
t 7
anh
edra
l fg
crys
talli
ne m
ass
- rel
ict s
pong
iform
52.
963
44.
8151
0.0
032
0.
0001
0
.343
2
0.02
66
0.00
78
0 C
01-8
28 p
y3
adj
acen
t to
abla
tion
pit 8
a
nhed
ral f
g cr
ysta
lline
mas
s - r
elic
t spo
ngifo
rm 5
3.21
69 4
4.78
6 0
.101
1
0.00
01
0.3
866
0.
019
0
.024
3
0 C
01-8
28 p
y3
adj
acen
t to
abla
tion
pit 9
a
nhed
ral f
g cr
ysta
lline
mas
s - r
elic
t spo
ngifo
rm 5
3.12
68 4
4.44
61 0
.063
4
0.00
96
0.4
377
0.
0163
0.
0298
0.
0247
C
01-8
28 p
y4
adj
acen
t to
abla
tion
pit 1
0 a
nhed
ral f
g cr
ysta
lline
mas
s - r
elic
t spo
ngifo
rm 5
3.02
31 4
4.62
54 0
.212
4
0.00
87
0.2
972
0.
019
0
.015
7
0.00
95
C01
-828
py4
a
djac
ent t
o ab
latio
n pi
t 11
anh
edra
l fg
crys
talli
ne m
ass
- rel
ict s
pong
iform
53.
1736
45.
2945
0.0
189
0.
0351
0
.269
6
0.01
71
0
0.
0297
C
01-8
28 p
y4
adj
acen
t to
abla
tion
pit 1
2 a
nhed
ral f
g cr
ysta
lline
mas
s - r
elic
t spo
ngifo
rm 5
3.00
04 4
4.56
48 0
.096
1
0.03
78
0.5
73
0.
0239
0.
0335
0.
0183
C
01-8
28 p
y5
not
lase
r sam
pled
13
anh
edra
l fg
crys
talli
ne m
ass
- rel
ict s
pong
iform
53.
0294
45.
939
0.0
104
0.
0433
0
.102
5
0.00
95
0.02
43
0.02
2 C
01-8
28 p
y6
not
lase
r sam
pled
14
anh
edra
l fg
crys
talli
ne m
ass
- rel
ict s
pong
iform
53.
2224
45.
637
0.0
111
0.
0741
0
.108
8
0.01
1
0.0
086
0.
0181
C
01-8
28 p
y7
not
lase
r sam
pled
15
em
baye
d su
bhed
ral p
yrite
- "c
lean
"
53.
0991
45.
693
0.0
146
0.
0729
0
.101
7
0.01
0.0
154
0.
0189
Sam
ple
grai
n co
mm
ent
No
pyrit
e m
orph
olog
y
W
%(S
) W
%(F
e) W
%(C
u) W
%(Z
n) W
%(A
s) W
%(S
e) W
%(A
g) W
%(C
d)
C01
-828
py1
a
djac
ent t
o ab
latio
n pi
t 1
0.0
341
0.
0117
0.
0001
0
0.00
01
0.0
002
0.0
001
0.
0297
98
.7
C01
-828
py1
a
djac
ent t
o ab
latio
n pi
t 2
0
0
.000
1
0.00
01
0
0.
0134
0
.004
2 0
.000
1
0.00
01
99.1
7 C
01-8
28 p
y1
dis
tal t
o ab
latio
n pi
t
3
0.0
005
0.
0001
0.
0001
0
0.01
06
0.0
172
0.0
001
0.
0001
99
.57
C01
-828
py2
a
djac
ent t
o ab
latio
n pi
t 4
0
0
.000
1
0.00
01
0
0.
0032
0
.089
1 0
.000
1
0.00
01
98.6
7 C
01-8
28 p
y2
adj
acen
t to
abla
tion
pit 5
0
0.0
256
0.
0001
0
0.02
89
0.1
555
0.0
001
0.
0001
98
.56
C01
-828
py2
d
ista
l to
abla
tion
pit
6
0
.003
4
0.03
81
0.00
01
0.01
59
0.0
305
0.
1626
0.0
001
0.
0001
98
.66
C01
-828
py3
a
djac
ent t
o ab
latio
n pi
t 7
0
0
.033
2
0.00
01
0
0.
0001
0
.170
3 0
.000
1
0.00
01
98.3
6 C
01-8
28 p
y3
adj
acen
t to
abla
tion
pit 8
0
0.0
636
0.
0001
0.
0168
0
.045
9
0.18
84 0
.000
1
0.00
01
98.8
5 C
01-8
28 p
y3
adj
acen
t to
abla
tion
pit 9
0
.024
7
0.07
98
0.00
01
0
0.
0065
0
.242
1 0
.000
1
0.01
1
98.
49
C01
-828
py4
a
djac
ent t
o ab
latio
n pi
t 10
0.0
095
0.
0673
0.
0001
0.
0876
0
.035
7
0.20
27 0
.000
1
0.00
01
98.6
C
01-8
28 p
y4
adj
acen
t to
abla
tion
pit 1
1 0
.029
7
0.00
48
0.00
01
0
0.
0199
0
.031
9 0
.000
1
0.00
01
98.9
C
01-8
28 p
y4
adj
acen
t to
abla
tion
pit 1
2 0
.018
3
0.05
59
0.00
01
0
0.
0001
0
.260
7 0
.000
1
0.00
97
98.6
7 C
01-8
28 p
y5
not
lase
r sam
pled
13
0.0
22
0.
0001
0.
0001
0.
1156
0
.002
0.01
7
0.00
01
0.00
01
99.3
2 C
01-8
28 p
y6
not
lase
r sam
pled
14
0.0
181
0.
0001
0.
0001
0
0.00
01
0.0
006
0.0
001
0.
0001
99
.09
C01
-828
py7
n
ot la
ser s
ampl
ed
15 0
.018
9
0.00
01
0.00
01
0
0.
0175
0
.000
2 0
.000
1
0.00
01
99.0
4 Sa
mpl
e g
rain
com
men
t
N
o W
%(C
d) W
%(S
b) W
%(T
e) W
%(A
u) W
%(H
g) W
%(T
l) W
%(P
b) W
%(B
i) w
t% to
tal
52
Appendix 5: LA-ICP-MS Analysis—Sulphides
C07
9
ap19
a03
py
435
.729
2.9
17
7.8
20
4655
00
27.
238
9
.260
23.4
69
150
40.7
59
377
.461
C
079
ap
19a0
4
p
y
2
.145
<0.0
38
2.54
8
4
6550
0
24.2
66
13
.652
26
3.26
6
2
427.
855
241.
016
C07
9
ap19
a05
py
2.0
45
0.
211
12
3.12
1
4655
00
6.3
53
3
.078
33.0
72
14.
602
24
16.1
15
C07
9
ap19
a08
py
27.
580
0.
234
6.
052
465
500
79
.329
16.8
61
26.5
26
368
6.84
7
66
2.04
1 C
079
jl0
4a55
py
<0.8
41
<0.
087
<0.
674
4655
00
59.
387
7
.211
<4.1
07
<2.
117
16
.774
C
079
jl0
4a58
py
1546
.678
6.57
6
2.49
9
4
6550
0
32.4
45
10
.056
<3
.946
4
801.
433
94.6
21
C07
9
jl04a
59
py
2.
056
<
0.12
3
1
.591
46
5500
1
9.40
9
14.
544
59
7.57
7
2
437.
480
201.
733
C07
9
ap19
a06
sp
98.
530
0.
476
43
5.45
7
1850
0
<0
.019
<0.1
45
582.
477
n.a
.
1
.164
C
079
ap
19a0
7
s
p
1
.034
<0.0
52
420.
893
18
500
<0.0
30
<0
.232
98
.583
n
.a.
<1.
039
C
079
jl0
4a60
sp
<2.2
39
<0.
275
389
.468
1
5700
<0.6
41
<1
.800
73
.814
n
.a.
<7.
168
C
079
jl0
4a61
sp
1.60
6
<0.
098
360
.182
1
5700
<0.2
40
<0
.713
72
9.80
6
n
.a.
2.7
09
C08
2
ap18
a28
cpy
2.68
6
<0.
073
2.2
85
3043
00
0.2
74
<
0.44
0
n.a.
7
99.3
48
7.11
9 C
082
ap
18a2
9
p
y
2
.800
<0.0
60
<1.2
58
46
5500
0
.994
0.2
02
45
.025
4
.229
297.
522
C08
2
ap18
a30
py
3.5
53
<0
.076
<1
.320
4655
00
6.2
33
0
.363
351.
228
30.
958
43
.895
C
082
jl1
1a41
py
1091
.486
<0.1
71
664.
493
46
5500
1
8.05
6
6.5
49
14
.011
1
0.57
1
55.6
95
C08
2
jl11a
42
py
38
.358
<
0.17
7
3
.107
46
5500
4
.324
1.7
96
16
.665
<
2.01
0
98.4
20
C08
2
jl11a
43
py
<0
.805
<
0.06
2
0
.991
46
5500
3
1.09
5
<0.
557
5.
383
1.90
3
70
.123
C
082
jl1
1a44
py
<0.8
17
<0.
081
<0.
575
4655
00
25.
642
0
.716
<3.0
25
<1.
193
66
.759
C
211
ap
03c0
3
s
p
<
0.86
5
<0.1
85
5552
.669
10
7100
2
4.19
7
<0.
568
87
6.12
0
n
.a.
<0.
883
C
211
ap
03c0
4
s
p
<
1.28
5
<0.3
02
5635
.285
10
7100
3
1.84
8
<0.
548
13
44.0
87
n
.a.
<0.
987
C
211
ap
03c0
5
s
p
<
2.27
1
<0.3
26
6685
.981
10
7100
2
9.73
8
<0.
755
11
72.0
87
n
.a.
<1.
176
C
211
ap
03c0
6
s
p
<
2.28
2
<0.3
30
6479
.861
10
7100
3
0.90
7
<0.
584
20
29.0
20
n
.a.
<1.
471
C
261
ap
10d0
5
a
py
14
6.30
4
1
.083
1
64.3
10
343
000
1.
826
80.
006
15
.483
<
14.3
48
n.a.
C
261
ap
10d0
4
p
y
<
1.91
1
0.78
3
671.
946
46
5500
4
.066
99.
964
11
6.78
4
9
85.9
22
3828
.785
C
261
ap
10d0
6
p
y
2
8.71
6
1.94
3
70.1
32
46
5500
1
.326
33.
396
31
.989
5
.713
748.
481
C26
1
ap10
d07
py
24.
784
1.
288
60
.295
4655
00
2.0
09
4
5.82
8
320.
270
56.
080
80
2.00
6 C
261
ap
10d0
8
p
y
2
.685
<0.3
19
74.2
23
46
5500
1
.040
58.
358
29
.295
<
3.52
6
690.
675
C26
1
jl11a
18
py
1.
314
0
.259
6
4.69
5
46
5500
0
.385
27.
074
32
.685
4
60.4
07
813.
196
C26
1
jl11a
19
py
18
6.19
7
1
.534
6
7.05
0
46
5500
3
.352
43.
220
29
.930
3
.385
849.
587
C26
1
jl11a
20
py
2.
061
0
.126
5
0.04
6
46
5500
3
.167
53.
401
78
0.90
5
4
208.
344
748.
002
C27
8
ap03
e11
py
<4.
600
<0
.657
18
.746
4655
00
14.
214
2
.663
814.
386
9.4
11
35
67.4
50
C27
8
ap03
e13
py
<1.
904
<0
.289
<3
.030
4655
00
140
.835
1
2.72
7
2.18
8
32
.611
6
07.9
15
C27
8
ap03
e15
py
<4.
141
<0
.608
97
.027
4655
00
62.
079
1
1.11
4
7.78
5
67
.058
6
46.8
96
C27
8
ap03
e16
py
<4.
335
<0
.709
76
.853
4655
00
35.
633
6
.544
39.2
91
<5.
803
72
9.59
3 C
278
ap
03e1
2
s
p
<
5.47
1
<0.8
06
2927
.640
64
800
<0.5
90
<2
.396
20
3.61
2
n
.a.
<2.
833
C
278
ap
03e1
4
s
p
<
7.40
3
<1.0
11
1858
.470
64
800
<0.7
20
<2
.709
10
633.
232
n
.a.
<5.
129
C
278
ap
03e1
8
s
p
<
7.56
5
<0.9
41
1766
.946
64
800
<0.8
10
<2
.652
12
125.
403
n
.a.
<3.
790
C
280
ap
03e0
3
p
y
<
3.74
6
<0.7
51
<7.7
53
46
5500
<
0.35
0
<1.
533
<2
.497
<
5.76
1
4.73
5
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
53
Appendix 5: LA-ICP-MS Analysis—Sulphides
C28
0
ap03
e05
py
<4.
707
<0
.774
<6
.739
4655
00
<0.
519
<
1.36
4
<2.9
79
<9.
888
4.
185
C28
0
ap03
e06
py
29.
283
<0
.739
18
7.98
3
4655
00
4.7
78
<
1.92
0
844.
163
14.
376
26
49.6
33
C28
0
ap03
e07
py
10.
339
<0
.620
<6
.605
4655
00
0.8
21
<
1.56
4
8.07
7
<6
.418
5
25.7
80
C28
0
ap03
e10
py
556
.229
<0.
848
13.
563
4655
00
23.
344
<
2.23
8
45.1
58
15.
674
37
91.2
10
C28
0
ap03
e04
sp
<10
.306
<1.
334
282
2.65
0
5
4900
<0.8
62
<3
.286
66
.735
n
.a.
<5.
813
C
280
ap
03e0
8
s
p
<
7.78
6
<1.1
30
2602
.595
54
900
<0.6
95
<2
.250
81
0.23
0
n
.a.
<7.
651
C
280
ap
03e0
9
s
p
<
5.65
8
<0.8
10
2252
.563
54
900
<0.5
91
<2
.062
54
0.02
3
n
.a.
<3.
322
C
284
ap
06b0
5
c
py
<2
.016
<
0.44
4
<
5.42
2
30
4300
<
0.28
5
<0.
903
n.
a.
308
.835
7.
245
C28
4
ap06
b03
py
<4.
368
<0
.527
<5
.344
4655
00
262
.810
3
2.41
3
<3.0
61
37.
138
44
1.30
9 C
284
ap
06b0
6
p
y
<
0.95
9
<0.1
22
105.
722
46
5500
8
6.65
5
19.
258
8.
708
3283
.378
488.
034
C28
4
ap06
b08
py
<4.
564
<0
.431
34
.573
4655
00
177
.274
1
5.78
7
11.0
60
141
65.3
35
797
.100
C
284
ap
06b0
9
p
y
<
3.40
2
<0.4
35
<6.4
04
46
5500
3
26.3
57
48.
899
<4
.029
<
6.27
8
728.
139
C28
4
ap06
b10
py
9.7
38
1.
673
<8
.125
4655
00
143
.171
2
6.16
9
<2.9
72
10.
945
48
7.65
2 C
284
ap
06b0
4
s
p
<
4.86
5
<0.5
38
1358
.946
50
400
<0.5
41
<1
.298
99
.744
n
.a.
<3.
977
C
284
ap
06b0
7
s
p
<
5.83
6
<0.5
02
1731
.985
50
400
<0.3
59
<0
.921
55
.251
n
.a.
<3.
294
C
284
ap
06b1
1
s
p
<
4.43
4
<0.6
48
806.
341
50
400
<0.4
49
<1
.720
25
89.5
39
n
.a.
<3.
391
C
285
ap
03c0
7
p
y
5
.111
<0.1
91
86.1
33
46
5500
1
81.1
79
2.6
66
70
.587
3
.120
1516
.457
C
285
ap
03c1
0
p
y
<
4.46
5
<0.6
88
<5.4
66
46
5500
1
57.8
71
4.4
73
10
.738
<
7.97
0
448.
741
C28
5
ap03
c13
py
<1.
496
<0
.302
54
1.26
2
4655
00
69.
343
2
.272
124.
759
9.4
48
16
5.94
9 C
285
ap
03c1
4
p
y
<
1.31
5
<0.1
98
2.71
7
4
6550
0
74.1
66
0.
494
2
22.9
88
57.9
02
61.
433
C28
5
ap03
c17
py
<4.
872
<0
.710
<6
.622
4655
00
710
.298
<
1.62
1
<3.0
73
<4.
409
62
2.84
2 C
285
ap
03c1
8
p
y
1
.264
<0.2
34
34.8
55
46
5500
3
68.7
72
2.4
27
1.
426
2.05
6
58
9.88
4 C
285
ap
03c0
8
s
p
<
5.30
6
<0.7
87
2461
.151
52
000
2.24
6
<
1.87
7
32.3
76
n.a
.
<
3.90
1
C28
5
ap03
c09
sp
<7.
257
<0
.899
28
25.0
50
5200
0
1.
629
<2.
419
11
1.42
5
n
.a.
<3.
501
C
285
ap
03c1
1
s
p
<
5.85
9
<0.9
34
2994
.400
52
000
<0.8
25
<2
.245
24
.693
n
.a.
<6.
146
C
285
ap
03c1
2
s
p
<
5.65
2
<0.8
00
2922
.897
52
000
1.99
8
<
2.03
0
24.9
27
n.a
.
<
3.84
3
C28
5
ap03
c15
sp
<5.
446
<0
.745
21
26.3
08
5200
0
2.
866
<2.
117
60
6.56
6
n
.a.
<2.
655
C
285
ap
03c1
6
s
p
<
5.34
5
<0.8
69
2636
.939
52
000
3.15
9
<
2.47
9
26.4
11
n.a
.
<
3.82
4
C28
7
ap17
b03
py
<1.
268
<0
.160
34
.169
4655
00
<0.
111
<
0.51
9
3555
.151
5.4
28
11
3.93
9 C
287
ap
17b0
5
p
y
<
1.26
8
<0.1
50
7.42
8
4
6550
0
0.31
0
<
0.31
1
16.5
90
<2.
060
27
.052
C
287
ap
17b0
7
p
y
<
3.50
5
<0.3
49
6.38
2
4
6550
0
0.45
4
<
1.09
9
49.0
21
<6.
152
14
3.44
0 C
287
ap
17b0
9
p
y
6
.250
<0.3
85
11.7
52
46
5500
0
.386
<0.
763
62
.364
<
6.72
0
1691
6.32
3 C
287
ap
17b0
4
s
p
<
3.90
0
<0.4
48
1925
.691
41
000
<0.4
17
<0
.873
11
.304
n
.a.
<2.
431
C
287
ap
17b0
8
s
p
<
5.10
7
<0.8
34
1846
.858
41
000
<0.5
21
<1
.717
43
.607
n
.a.
<4.
221
C
290
ap
10f0
8
cpy
<4.8
04
<0.
532
9.0
56
3043
00
<0.
379
<
1.02
7
n.a.
2
20.4
45
81.0
13
C29
0
ap10
f03
py
<4
.169
<
0.59
6
<
7.18
0
46
5500
0
.567
46.
115
<2
.753
<
6.41
6
201.
171
C29
0
ap10
f07
py
<4
.380
<
0.46
0
<
4.19
4
46
5500
<
0.34
3
4.7
88
<2
.622
<
4.72
2
74.6
68
C29
0
ap10
f09
py
<2
.096
<
0.28
3
7
1.86
2
46
5500
<
0.21
1
1.7
12
10
19.7
01
1
2.85
2
1709
.241
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
54
Appendix 5: LA-ICP-MS Analysis—Sulphides
C29
0
ap10
f11
py
58
.933
<
0.42
2
<
7.00
5
46
5500
<
0.35
5
<1.
152
21
.293
3
7.29
7
51.5
22
C29
0
ap10
f12
py
<5
.418
<
0.47
4
9
.826
46
5500
0
.835
3.5
31
41
0.17
0
<
6.58
3
1170
.727
C
290
ap
10f1
3
py
<5.8
92
<0.
416
<5.
065
4655
00
<0.
338
6
.893
<2.9
06
<6.
404
11
9.79
9 C
290
ap
10f0
4
sp
<5.8
84
<0.
821
189
6.97
1
2
2600
<0.5
52
<1
.769
54
.204
n
.a.
<6.
420
C
290
ap
10f0
5
sp
<6.8
19
<1.
002
181
8.42
2
2
2600
<0.7
54
<1
.952
16
1.17
2
n
.a.
<8.
335
C
290
ap
10f1
0
tet
<7.9
30
<0.
679
110
.752
4
2400
<0.6
14
<2
.422
n.
a.
n.a
.
n
.a.
C29
2
ap06
g03
cpy
<3.4
03
<0.
474
<6.
654
3043
00
<0.
453
<
1.15
4
n.a.
3
33.3
06
6.16
3 C
292
ap
06g0
4
p
y
<
1.46
9
<0.1
73
<3.1
15
46
5500
2
5.26
4
3.4
38
3.
654
<1.6
83
112
.358
C
292
ap
06g0
5
p
y
<
0.88
3
<0.1
29
<2.4
30
46
5500
1
7.28
4
2.9
73
<1
.239
<
1.65
5
4.57
4 C
292
ap
06g0
6
p
y
1
8.28
5
<0.1
12
12.0
72
46
5500
3
3.60
8
4.5
82
<1
.287
<
1.72
4
14.6
84
C29
2
ap06
g07
py
6.6
29
<0
.161
4.
358
465
500
21
.821
2.17
8
5.6
54
<
1.44
1
46.8
20
C29
2
ap06
g08
py
37.
786
<0
.176
35
.658
4655
00
78.
160
1
0.81
7
<1.2
07
<1.
574
21
57.2
20
C29
2
ap06
g10
py
<1.
438
<0
.151
<2
.414
4655
00
19.
763
3
.369
23.3
41
<2.
122
5.
834
C29
7
ap10
a05
apy
<7.3
81
<0.
894
<8.
527
3430
00
6.3
07
6
.945
<5.6
13
785
.237
n.
a.
C29
7
ap10
a06
cpy
<2.7
83
<0.
366
<6.
943
3043
00
<0.
369
<
1.02
8
n.a.
9
03.1
37
260.
428
C29
7
ap10
a17
cpy
<3.4
52
<0.
477
<4.
280
3043
00
<0.
297
<
0.92
3
n.a.
6
20.2
14
88.7
88
C29
7
ap10
a03
py
<0.
838
<0
.105
20
.434
4655
00
9.5
32
3
.696
1194
.954
9.1
38
15
99.3
45
C29
7
ap10
a04
py
<0.
958
<0
.120
1.
681
465
500
5.
074
2.7
22
35
.706
<
1.95
1
1888
.526
C
297
ap
10a0
7
p
y
5
.859
<0.3
27
98.7
19
46
5500
2
7.31
5
4.9
54
63
1.96
8
2
3.87
1
885.
106
C29
7
ap10
a09
py
<2.
117
<0
.316
<3
.548
4655
00
0.2
56
1
.349
286.
310
<3.
632
10
30.1
94
C29
7
ap10
a11
py
<1.
260
<0
.118
<1
.817
4655
00
5.9
08
0
.812
39.7
85
2.6
81
64
6.65
3 C
297
ap
10a1
3
p
y
3
.552
<0.1
79
9.14
3
4
6550
0
5.28
5
0
.343
35.2
34
<2.
985
12
51.5
25
C29
7
ap10
a15
py
13.
874
<0
.198
10
.052
4655
00
13.
686
1
.214
678.
025
437
2.18
2
36
2.71
0 C
297
ap
10a1
6
p
y
2
9.29
0
<0.1
62
6.62
6
4
6550
0
8.45
3
2
.688
29.5
07
<2.
601
14
88.0
35
C29
7
ap10
a10
sp
<4.
992
<0
.453
23
47.7
28
5070
0
<0
.420
<1.8
11
44.0
37
n.a
.
6
.507
C
297
ap
10a1
2
s
p
<
3.53
9
<0.4
90
1953
.580
50
700
<0.3
54
<1
.193
58
6.00
7
n
.a.
7.1
80
C29
7
ap10
a14
sp
<5.
144
<0
.727
22
65.5
07
5070
0
<0
.361
<1.7
10
23.8
02
n.a
.
6
.001
C
299
ap
17c0
8
p
y
5
.488
<0.3
68
<5.8
07
46
5500
4
0.98
5
36.
776
<2
.483
<
6.70
4
67.2
34
C29
9
ap17
c10
py
<3.
042
0.
444
9.
763
465
500
19
.381
9.65
1
294
.358
39
0.25
2
4
65.7
25
C29
9
ap17
c11
py
<3.
595
<0
.436
63
.357
4655
00
28.
626
1
3.21
9
47.4
74
<7.
396
33
3.79
0 C
299
ap
17c0
4
s
p
<
3.85
3
<0.6
14
1036
.364
19
500
<0.3
67
<1
.108
16
.156
n
.a.
<3.
276
C
299
ap
17c0
6
s
p
<
5.65
4
<0.6
07
957.
739
19
500
<0.4
02
<1
.401
44
.407
n
.a.
<4.
470
C
299
ap
17c0
3
t
et
<1.4
01
<0.
230
160
.813
3
6500
<0.1
03
<0
.435
n.
a.
n.a
.
n
.a.
C29
9
ap17
c05
tet
<1
.297
<
0.19
9
1
81.8
89
365
00
<0
.122
<0.5
78
n.a.
n
.a.
n.a
. C
299
ap
17c0
7
t
et
<6.3
09
<0.
863
178
.011
3
6500
<0.5
55
<1
.524
n.
a.
n.a
.
n
.a.
C30
1
ap03
d14
py
<1.
390
<0
.182
<1
.705
4655
00
0.2
35
1
.571
238.
746
14.
350
74
67.5
67
C30
1
ap03
d15
py
<0.
990
<0
.168
15
.546
4655
00
90.
994
4
.396
257.
341
83.
296
66
54.5
67
C30
1
ap03
d17
py
<6.
294
<0
.896
<9
.866
4655
00
1.0
82
1
.776
17.5
83
<7.
048
38
58.6
70
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
55
Appendix 5: LA-ICP-MS Analysis—Sulphides
C30
1
ap03
d18
py
<1.
337
<0
.180
12
.345
4655
00
176
.004
1
3.41
2
104.
044
335
0.77
5
33
56.3
15
C30
1
ap03
d10
sp
<1.
482
<0
.187
22
03.8
23
3430
0
2.
243
<0.
475
30
17.2
23
n
.a.
<0.
944
C
301
ap
03d1
6
s
p
<
7.91
2
<1.0
13
785.
133
34
300
2.37
5
<
2.76
6
4946
.053
n.a
.
6
.916
C
306
ap
06e1
1
p
y
1
38.7
95
<
0.49
7
4
84.9
81
465
500
14
7.77
4
7.47
8
5.5
90
2
5521
.637
6
56.8
61
C30
6
ap06
e16
py
8.3
38
<0
.521
20
.923
4655
00
82.
733
1
7.58
3
4.93
7
76
38.3
69
14
9.94
0 C
306
ap
06e1
2
s
p
<
5.74
1
<0.4
93
1569
.277
25
200
1.15
3
<
1.40
4
6.70
9
n.
a.
<2.5
84
C30
6
ap06
e13
sp
<4.
283
<0
.606
15
76.7
97
2520
0
1.
183
<1.
021
5.
906
n.a.
<3
.083
C
306
ap
06e1
5
s
p
<
4.17
5
<0.4
37
1845
.562
25
200
0.98
2
<
1.32
0
6.19
3
n.
a.
<4.5
31
C30
6
ap06
e18
sp
<4.
858
<0
.448
95
2.64
9
2520
0
0.
819
<1.
328
7.
601
n.a.
<3
.149
C
307
ap
02a0
4
p
y
1
.898
0.21
7
7.04
0
4
6550
0
<0.1
06
<0
.366
35
2.63
7
1
943.
229
1640
.139
C
307
ap
02a0
5
p
y
4
47.3
75
0
.512
3
2.59
4
46
5500
1
7.07
9
2.0
92
5.
774
2655
2.72
1
309.
523
C30
7
ap02
a06
py
<3.
151
<0
.519
3.
525
465
500
0.
373
<1.
325
<3
.700
<
4.43
1
3929
.102
C
307
ap
02a0
7
p
y
1
0.01
2
<0.1
57
7.44
2
4
6550
0
<0.0
87
<0
.350
<1
.032
2
.448
4023
.697
C
307
ap
02a0
8
p
y
<
0.99
9
<0.1
77
3.07
4
4
6550
0
<0.0
95
<0
.418
<0
.888
2
.402
3429
.646
C
307
ap
02a0
9
p
y
3
7.82
5
<0.2
48
39.5
51
46
5500
<
0.11
7
<0.
524
2.
046
2.53
1
75
52.2
24
C30
7
ap02
a14
py
<3.
341
<0
.527
<4
.424
4655
00
0.5
97
4
.966
<2.7
91
<8.
572
45
41.2
80
C30
7
ap02
a15
py
<2.
812
<0
.559
7.
308
465
500
1.
322
2.0
18
<3
.662
<
5.07
1
2682
.112
C
307
ap
02a1
8
p
y
<
3.13
9
<0.6
39
<4.9
06
46
5500
<
0.36
9
1.1
74
<3
.161
<
5.15
1
3202
.549
C
307
ap
02a1
0
s
p
<
4.66
6
<0.7
92
423.
535
46
800
<0.4
62
<1
.235
18
97.5
63
n
.a.
<3.
024
C
307
ap
02a1
1
s
p
1
910.
034
2
.013
5
42.8
57
468
00
<0
.127
<0.4
83
2996
.426
n.a
.
1
.193
C
307
ap
02a1
3
s
p
6
.478
<0.1
43
664.
293
46
800
0.36
7
<
0.34
2
7488
.443
n.a
.
<
0.45
9
C31
7
ap17
f03
cp
y
<2
.784
<
0.62
3
<
7.19
6
30
4300
<
0.26
1
<1.
061
n.
a.
385
.918
9.
369
C31
7
ap17
f11
cp
y
<1
0.01
8
<
0.85
6
<
13.7
57
304
300
<0
.618
<2.6
70
n.a.
2
50.3
19
7.63
9 C
317
ap
17f1
6
cpy
<2.1
06
<0.
257
601
.570
3
0430
0
<0.2
00
<0
.615
n.
a.
274
.714
6.
265
C31
7
ap17
f05
py
<0
.966
<
0.15
1
4
1.33
7
46
5500
1
6.15
7
176
.508
0.9
19
<
1.58
2
105.
997
C31
7
ap17
f06
py
<1
.036
<
0.16
6
<
1.61
2
46
5500
2
.173
25.
946
1.
303
19.5
50
98.
072
C31
7
ap17
f09
py
18
8.30
0
0
.431
1
4.46
3
46
5500
1
.329
70.
719
3.
688
2327
.583
48.8
89
C31
7
ap17
f10
py
<0
.849
<
0.13
7
<
1.57
6
46
5500
0
.913
520
.963
0.7
76
<
2.13
5
475.
704
C31
7
ap17
f13
py
31
1.86
6
2
.095
2
39.7
42
465
500
68
.346
1108
.998
4.31
5
<6
.883
1
524.
555
C31
7
ap17
f14
py
<2
.494
<
0.44
8
3
80.2
46
465
500
13
.333
175.
004
<1.7
45
<5.
398
28
6.32
3 C
317
ap
17f1
5
py
<4.4
78
<0.
390
<6.
534
4655
00
<0.
399
2
30.4
55
<
2.04
5
42.
033
43
2.39
7 C
317
ap
17f0
4
sp
<4.4
12
<0.
724
113
0.85
7
2
8000
<0.4
15
<0
.766
57
32.4
63
n
.a.
<3.
839
C
317
ap
17f0
7
sp
<3.8
60
<0.
518
168
4.55
0
2
8000
<0.3
91
<0
.890
15
.899
n
.a.
<3.
319
C
320
ap
17a0
3
p
y
6
6.47
8
<0.1
69
67.9
01
46
5500
1
69.4
93
<0.
335
22
7.78
4
1
5.49
1
20.4
43
C32
0
ap17
a05
py
1.5
67
<0
.169
<2
.006
4655
00
22.
086
0
.611
1.51
7
<2
.585
4
14.4
40
C32
0
ap17
a06
py
3.9
47
<0
.222
<3
.138
4655
00
48.
892
0
.805
35.9
22
<4.
396
31
8.56
0 C
320
ap
17a0
7
p
y
<
1.89
7
<0.1
65
<2.0
20
46
5500
1
54.1
81
<0.
427
16
.106
1
56.8
29
3.66
9 C
320
ap
17a0
8
p
y
<
1.77
9
<0.1
55
<2.2
13
46
5500
1
0.25
4
<0.
414
4.
855
<2.2
77
155
.240
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
56
Appendix 5: LA-ICP-MS Analysis—Sulphides
C32
0
ap17
a09
py
6.5
99
<0
.483
14
.210
4655
00
34.
804
8
.902
16.9
52
<8.
001
60
9.00
8 C
320
ap
17a1
0
p
y
2
9.39
0
<0.3
75
5.34
3
4
6550
0
19.2
06
<0
.938
1.
911
<6.9
39
216
.770
C
320
ap
17a1
1
p
y
7
8.07
9
<0.3
08
43.0
32
46
5500
1
65.8
16
0.7
25
19
.182
<
5.57
8
194.
428
C32
3
ap17
d03
cpy
<2.8
31
<0.
344
<3.
335
3043
00
<0.
144
<
0.79
0
n.a.
5
63.0
51
8.56
5 C
323
ap
17d0
5
p
y
1
89.1
04
<
0.13
3
1
14.4
53
465
500
12
.718
0.90
5
104
.502
<1
.658
1
8.08
5 C
323
ap
17d0
6
p
y
1
5.21
3
<0.1
25
14.5
89
46
5500
2
7.67
9
0.2
96
9.
255
<1.7
90
161
.768
C
323
ap
17d0
8
p
y
3
1.72
7
<0.1
04
41.7
12
46
5500
8
.861
1.0
05
14
5.57
0
<
1.62
2
28.4
46
C32
3
ap17
d09
py
38.
735
<0
.091
35
.248
4655
00
20.
097
0
.466
6.25
4
2.
619
122.
309
C32
3
ap17
d10
py
6.5
34
<0
.218
13
.877
4655
00
11.
677
1
.348
6.61
6
<2
.460
1
60.1
85
C32
3
ap17
d04
sp
<4.
014
<0
.422
12
53.8
61
6080
0
<0
.339
<1.2
65
419.
851
n.a
.
<
3.00
5
C32
3
ap17
d07
sp
<3.
655
<0
.370
13
89.0
11
6080
0
<0
.268
<0.9
40
336.
667
n.a
.
<
2.30
4
C32
6
ap17
e03
py
2.4
81
<0
.125
10
0.74
3
4655
00
<0.
089
<
0.18
2
95.8
52
5.4
16
92
76.7
61
C32
6
ap17
e06
py
<0.
949
<0
.224
<2
.375
4655
00
0.3
96
<
0.39
0
806.
254
401
.712
31
4.71
4 C
326
ap
17e0
8
p
y
<
1.10
8
<0.1
30
19.8
87
46
5500
<
0.08
2
<0.
273
11
46.2
67
2
.211
608.
400
C32
6
ap17
e10
py
<3.
416
<0
.322
<4
.155
4655
00
1.6
81
<
0.68
4
226.
432
387
.941
71
46.3
97
C32
6
ap17
e11
py
<3.
111
<0
.245
28
.088
4655
00
8.4
62
<
0.90
3
4.31
9
61
57.7
55
40
4.24
9 C
326
ap
17e0
5
s
p
<
4.85
8
<0.6
44
2204
.902
53
600
<0.3
69
<1
.031
16
.782
n
.a.
<3.
202
C
326
ap
17e0
7
s
p
<
4.32
3
<0.3
88
1694
.573
53
600
<0.4
42
<0
.985
59
.050
n
.a.
<4.
812
C
329a
ap1
0e03
cp
y
<5
.107
<
0.55
1
<
4.92
9
30
4300
<
0.36
7
<0.
865
n.
a.
557
.856
99
.430
C
329a
ap1
0e05
cp
y
<5
.286
<
0.75
4
<
7.64
2
30
4300
<
0.53
1
<1.
276
n.
a.
325
.189
82
.522
C
329a
fb1
3a13
cp
y
<3
.608
<
0.55
3
<
8.97
7
30
4300
<
0.29
5
<1.
720
n.
a.
489
.547
<2
.321
C
329a
fb1
3a14
cp
y
<1
3.60
1
<
2.79
1
<
42.5
00
304
300
<1
.208
<5.9
67
n.a.
4
32.3
06
<9.0
13
C32
9a
a
p10e
06
py
<1.7
56
<0.
153
18.
665
4655
00
123
.525
4
9.52
7
2.73
2
50
07.4
05
54
3.48
2 C
329a
ap1
0e08
py
<1
.618
<
0.20
0
<
1.99
9
46
5500
<
0.14
4
0.5
16
55
0.16
9
1
11.6
25
1060
.199
C
329a
ap1
0e09
py
<4
.697
<
0.51
3
4
6.28
7
46
5500
2
4.52
4
98.
231
33
.093
1
1473
.148
1
022.
865
C32
9a
a
p10e
12
py
<3.9
78
<0.
568
25.
170
4655
00
1.3
56
7
.793
1950
.489
946
.108
43
74.2
39
C32
9a
f
b13a
12
py
<4.4
71
<0.
692
<7.
249
4655
00
22.
708
1
39.1
29
<
1.82
7
<5.
424
20
42.4
11
C32
9a
a
p10e
04
sp
<5.3
94
<0.
749
174
8.08
9
4
0600
<0.4
88
<1
.482
28
7.89
8
n
.a.
<5.
812
C
329a
ap1
0e07
sp
<5
.826
<
0.52
9
2
249.
195
406
00
<0
.448
<1.6
94
14.2
08
n.a
.
<
5.63
9
C32
9b
a
p06c
15
py
<3.3
48
<0.
298
<6.
135
4655
00
0.3
56
1
.155
144.
701
<5.
268
71
59.7
48
C32
9b
a
p06c
17
py
<3.6
32
<0.
352
<5.
823
4655
00
12.
895
6
1.26
4
<3.9
88
10.
356
68
9.83
9 C
329b
fb1
3a10
py
<3
.162
<
0.59
3
<
9.73
2
46
5500
3
.251
22.
648
36
.943
<
6.23
1
2077
.194
C
329b
fb1
3a11
py
<4
.451
<
0.48
5
2
5.02
6
46
5500
<
0.29
4
1.8
75
19
1.02
5
<
4.46
4
5920
.760
C
329b
ap0
6c13
sp
<5
.484
<
0.43
8
2
490.
770
393
00
<0
.516
<1.1
12
100.
842
n.a
.
<
3.66
3
C32
9b
a
p06c
18
sp
<7.0
44
<0.
775
253
7.85
2
3
9300
<0.7
27
2.
331
1
31.6
21
n.a.
<5
.738
C
329b
ap0
6c14
te
t
<7
.102
<
0.67
6
6
6.42
3
56
600
<0.6
79
<2
.060
n.
a.
n.a
.
n
.a.
C33
3
ap10
b11
py
0.8
28
<0
.115
13
87.7
63
4655
00
51.
347
0
.764
2.52
9
2.
247
158.
951
C33
3
ap10
b12
py
<1.
188
<0
.141
<1
.900
4655
00
15.
653
1
.007
1.50
0
<2
.146
2
49.9
82
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
57
Appendix 5: LA-ICP-MS Analysis—Sulphides
C33
3
ap10
b14
py
<1.
799
<0
.217
<2
.701
4655
00
104
.363
1
.411
<1.2
40
546
.606
47
2.03
1 C
333
ap
10b1
5
p
y
<
2.92
2
<0.3
37
<3.2
42
46
5500
2
.380
<0.
837
6.
104
<4.8
94
28.
626
C33
3
ap10
b17
py
<3.
070
<0
.417
93
.922
4655
00
34.
716
3
.206
196.
351
<9.
400
33
.180
C
333
ap
10b1
8
p
y
1
.653
<0.1
72
<2.0
91
46
5500
1
0.62
3
1.4
15
<1
.113
2
.517
458.
372
C33
3
ap10
b13
sp
<4.
851
<0
.530
22
18.5
79
6390
0
<0
.432
<1.8
02
68.3
35
n.a
.
<
3.59
2
C33
3
ap10
b16
sp
<3.
784
<0
.596
20
35.0
64
6390
0
<0
.542
<1.6
56
62.3
46
n.a
.
<
4.38
6
C33
7
ap17
b11
py
<3.
007
<0
.425
<5
.909
4655
00
168
.814
1
8.86
6
<1.4
71
73.
226
20
7.33
8 C
337
ap
17b1
3
p
y
8
.842
<0.1
16
<1.6
73
46
5500
1
.890
23.
040
0.
544
<2.0
47
328
.102
C
337
ap
17b1
5
p
y
<
1.45
6
<0.1
79
48.9
35
46
5500
<
0.13
6
<0.
339
35
.223
1
600.
414
323.
533
C33
7
ap17
b17
py
<4.
067
<0
.452
<5
.979
4655
00
33.
117
7
.079
<2.4
51
<7.
321
31
5.64
7 C
337
ap
17b1
8
p
y
<
4.20
2
<0.4
36
<6.8
43
46
5500
9
7.93
7
17.
053
<2
.393
<
6.81
2
220.
775
C33
7
ap17
b12
sp
<3.
841
<0
.563
24
80.7
74
2920
0
<0
.374
<0.8
14
54.3
38
n.a
.
<
2.45
8
C33
7
ap17
b14
sp
<4.
344
<0
.557
20
63.2
76
2920
0
<0
.421
<1.0
93
77.7
24
n.a
.
<
2.74
6
C34
1
ap10
f15
py
<1
.143
<
0.14
7
3
61.1
77
465
500
<0
.121
0.37
8
74.
835
1
4.10
7
8441
.251
C
341
ap
10f1
6
py
<1.6
56
<0.
171
150
.764
4
6550
0
<0.1
48
<0
.335
28
7.44
4
3
.734
1749
5.94
4 C
341
ap
10f1
7
py
<4.0
33
<0.
398
<4.
776
4655
00
<0.
369
1
.073
2758
.571
251
.814
35
45.6
06
C34
1
fb13
a06
py
<2
.232
<
0.28
0
1
65.6
58
465
500
1.
333
12.
254
60
8.08
2
3
.206
216.
008
C34
1
fb13
a07
py
<4
.321
<
0.63
5
4
60.4
87
465
500
<0
.308
<1.3
09
95.7
01
13.
547
98
44.7
78
C34
1
ap10
e13
sp
<5.
130
<0
.534
14
81.2
27
2240
0
<0
.510
<1.3
04
30.7
98
n.a
.
<
3.88
8
C34
1
ap10
e16
sp
<3.
871
<0
.676
17
25.8
40
2240
0
<0
.607
<2.1
44
455.
570
n.a
.
2
4.25
1 C
341
ap
10e1
8
s
p
<
5.63
2
<0.4
83
1391
.008
22
400
<0.4
99
<1
.665
27
.221
n
.a.
12.
857
C34
1
ap10
e14
tet
<5
.933
<
0.94
9
9
6.79
0
49
400
<0.8
54
<2
.207
n.
a.
n.a
.
n
.a.
C34
1
ap10
e15
tet
<6
.973
<
0.86
3
1
30.2
23
494
00
<0
.714
<1.9
52
n.a.
n
.a.
n.a
. C
341
ap
10e1
7
t
et
<8.2
45
<0.
825
141
.771
4
9400
<0.6
89
<2
.322
n.
a.
n.a
.
n
.a.
C34
3
ap06
c03
py
8.9
33
<0
.139
72
.201
4655
00
1.5
83
<
0.27
6
47.8
34
3.2
33
69
4.98
1 C
343
ap
06c0
5
p
y
<
4.70
0
<0.5
34
<4.8
32
46
5500
1
1.61
2
<1.
172
41
.672
1
1.58
1
1451
.123
C
343
ap
06c0
9
p
y
3
2.83
1
0.20
5
223.
000
46
5500
2
.797
<0.
342
19
.949
6
.751
95.0
94
C34
3
ap06
c10
py
157
.357
<0.
151
92.
723
4655
00
427
.754
2
.686
10.0
07
29.
160
17
2.22
8 C
343
ap
06c1
1
p
y
9
.404
<0.1
49
18.1
51
46
5500
8
.447
<0.
317
10
.089
1
45.4
10
61.7
06
C34
3
ap06
c04
sp
18.
984
<0
.550
95
5.70
6
6150
0
<0
.513
<1.2
10
3064
.107
n.a
.
<
3.17
6
C34
3
ap06
c06
sp
<4.
575
<0
.706
10
74.0
09
6150
0
<0
.535
<1.4
89
5893
.862
n.a
.
<
2.93
2
C34
3
ap06
c12
sp
<8.
475
<0
.672
85
5.16
8
6150
0
<0
.558
<1.8
57
9054
.526
n.a
.
<
3.16
0
C34
5
ap06
d14
py
<1.
908
<0
.217
<3
.055
4655
00
<0.
166
2
0.04
8
<1.6
56
<2.
625
18
5.80
5 C
345
ap
06d1
5
p
y
5
3.04
6
1.23
5
<7.9
42
46
5500
1
.521
21.
383
18
.959
6
057.
007
89.7
18
C34
5
ap06
d16
py
68.
540
0.
749
<5
.713
4655
00
5.0
20
1
07.2
30
7
.069
<4.
279
35
5.06
4 C
345
ap
06d1
8
p
y
3
.897
<0.3
26
<6.4
20
46
5500
4
.107
25.
316
11
.873
<
6.52
8
116.
920
C34
5
ap06
f15
py
<4
.356
<
0.43
1
<
6.08
0
46
5500
1
.888
38.
601
25
.557
<
5.59
1
68.1
82
C34
5
fb13
a08
py
19
.206
<
0.40
1
<
7.24
0
46
5500
6
.985
53.
246
3.
899
23.4
30
211
.009
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
58
Appendix 5: LA-ICP-MS Analysis—Sulphides
C34
5
fb13
a09
py
12
.641
<
0.37
4
<
4.78
4
46
5500
0
.290
1.0
66
1.
762
<2.7
24
52.
480
C34
5
ap06
f14
sp
<4
.365
<
0.43
6
5
82.5
71
248
00
<0
.510
<1.1
45
22.5
05
n.a
.
<
3.54
6
C34
5
ap06
f16
sp
<5
.109
<
0.35
6
7
49.8
09
248
00
<0
.393
<1.2
47
27.2
57
n.a
.
<
2.82
7
C34
5
ap06
f17
sp
<4
.635
<
0.49
3
7
22.9
19
248
00
<0
.330
<0.7
64
179.
047
n.a
.
<
3.08
1
C34
5
ap06
f18
te
t
<9
.785
<
1.21
9
5
2.64
7
50
600
<1.2
57
<2
.773
n.
a.
n.a
.
n
.a.
C35
0
ap03
d03
py
<1.
797
<0
.253
<2
.337
4655
00
3.5
47
<
0.40
2
748.
037
62.
439
10
45.8
06
C35
0
ap03
d04
py
<1.
394
<0
.190
<2
.478
4655
00
6.4
97
1
.617
<1.1
68
2.7
15
25
4.80
5 C
350
ap
03d0
6
p
y
4
.372
0.50
2
41.7
77
46
5500
6
.090
0.9
66
26
.730
4
.402
1459
.275
C
350
ap
03d0
7
p
y
8
.420
<0.5
01
17.0
90
46
5500
<
0.54
2
<1.
327
56
0.73
7
2
73.8
32
1648
.891
C
350
ap
03d0
8
p
y
<
1.14
1
<0.2
39
<2.1
56
46
5500
1
.689
<0.
566
54
5.66
1
1
70.5
65
3242
.635
C
350
ap
03d0
9
p
y
<
1.13
8
0.20
4
42.4
63
46
5500
2
.658
<0.
649
25
.986
3
25.3
91
978.
351
C35
3
ap06
f03
py
10
4.88
1
0
.771
1
2.05
9
46
5500
0
.677
1.9
56
3.
550
2.83
0
85
.857
C
353
ap
06f0
5
py
33.6
05
<0.
443
62.
995
4655
00
1.1
72
1
.702
<4.7
07
8.6
65
15
4.35
2 C
353
ap
06f0
7
py
8.87
1
<0.
852
<9.
345
4655
00
<0.
560
<
1.25
6
<6.4
42
611
.013
15
6.55
1 C
353
ap
06f0
8
py
<5.7
27
<0.
649
<7.
907
4655
00
1.5
56
1
.957
<6.0
66
60.
253
12
0.91
0 C
353
ap
06f1
0
py
33.4
17
<0.
526
20.
095
4655
00
0.9
32
3
.423
95.4
66
10.
786
40
7.37
6 C
353
ap
06f1
2
py
76.3
84
<0.
736
<10
.098
4
6550
0
0.72
9
<
1.62
9
18.8
95
43.
745
16
5.65
2 C
353
ap
06f1
3
py
8.52
2
<0.
565
<8.
026
4655
00
0.9
30
1
.927
5.40
1
<6
.041
9
6.22
2 C
353
ap
06f0
4
sp
<4.6
11
<0.
552
156
0.83
1
3
2600
<0.3
94
<1
.291
23
2.77
6
n
.a.
<2.
469
C
353
ap
06f0
6
sp
19.0
89
<0.
773
123
5.05
0
3
2600
<0.8
02
<1
.415
70
0.89
6
n
.a.
<4.
174
C
353
ap
06f1
1
sp
7.40
9
<0.
530
200
5.01
3
3
2600
<0.4
52
<0
.994
98
.966
n
.a.
<2.
846
C
355
ap
17a1
7
c
py
<1
2.36
0
<
1.30
8
<
15.4
63
304
300
<0
.871
<1.8
17
n.a.
3
74.4
63
<8.2
89
C35
5
ap17
d12
cpy
<9.6
93
<1.
093
<13
.871
3
0430
0
<0.8
54
<2
.527
n.
a.
105
2.16
7
9.
380
C35
5
ap17
a12
py
136
.619
0.2
02
134
.488
4
6550
0
14.1
32
1.
206
3
147.
858
121.
515
193
1.30
1 C
355
ap
17a1
5
p
y
4
3.41
1
<0.1
01
8.66
9
4
6550
0
20.9
56
0.
432
4
.629
2.7
74
15
1.44
4 C
355
ap
17a1
6
p
y
<
4.47
5
<0.4
29
<4.4
04
46
5500
6
6.70
0
<0.
802
1.
846
<6.1
56
65.
795
C35
5
ap17
d11
py
3.1
70
<0
.406
<4
.131
4655
00
25.
532
<
0.87
5
12.7
03
<3.
766
15
0.70
0 C
355
ap
17d1
3
p
y
<
2.73
7
<0.3
93
<6.9
92
46
5500
<
0.31
1
<1.
172
30
.926
<
7.58
5
19.3
91
C35
5
ap17
d15
py
218
.725
0.5
57
91.
331
4655
00
19.
211
0
.920
41.9
63
<3.
925
37
6.75
3 C
355
ap
17a1
8
s
p
<
5.19
8
<0.5
22
2164
.762
82
000
<0.3
73
<1
.191
11
9.55
2
n
.a.
<3.
503
C
355
ap
17d1
4
s
p
<
4.50
2
<0.4
47
1935
.759
82
000
<0.3
91
<1
.337
94
07.2
81
n
.a.
<3.
489
C
357
ap
06e0
4
p
y
2
.073
<0.1
44
<1.9
88
46
5500
2
1.45
8
<0.
308
4.
480
<1.3
44
21.
802
C35
7
ap06
e06
py
<2.
861
<0
.415
<5
.393
4655
00
1.5
86
<
0.80
0
<3.5
21
<4.
628
93
6.08
1 C
357
ap
06e0
7
p
y
4
.141
<0.5
13
<6.5
15
46
5500
4
7.80
3
<1.
193
<3
.919
<
6.68
3
5.78
4 C
357
ap
06e0
8
p
y
7
7.02
3
<0.3
68
13.1
09
46
5500
1
7.48
2
3.3
08
20
.351
<
3.98
4
373.
790
C35
7
ap06
e10
py
16.
383
<0
.494
10
.078
4655
00
29.
780
<
0.89
8
<3.5
03
<4.
784
66
.738
C
357
ap
06e0
3
s
p
<
6.10
9
<0.9
46
490.
402
35
100
<0.5
39
<1
.330
70
3.16
1
n
.a.
<4.
354
C
357
ap
06e0
9
s
p
<
4.79
9
<0.5
65
532.
572
35
100
<0.4
33
<1
.218
40
7.97
8
n
.a.
<5.
126
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
59
Appendix 5: LA-ICP-MS Analysis—Sulphides
C35
9
ap10
d12
cpy
<4.4
36
<0.
498
<6.
545
3043
00
<0.
400
<
1.19
1
n.a.
1
74.4
78
140.
966
C35
9
ap10
d10
py
<3.
163
<0
.371
12
.174
4655
00
34.
853
2
1.23
5
<2.9
79
<6.
268
54
.486
C
359
ap
10d1
3
p
y
<
4.59
2
<0.5
53
<6.5
80
46
5500
3
2.69
3
37.
429
<4
.041
<
6.23
5
189.
394
C35
9
ap10
d16
py
14.
548
<0
.464
<5
.634
4655
00
55.
583
4
9.33
0
<3.7
35
<6.
953
48
.629
C
359
ap
10d1
7
p
y
<
3.74
1
<0.4
29
<5.7
90
46
5500
2
2.33
4
27.
117
<3
.659
<
5.81
6
111.
006
C35
9
ap10
d18
py
<2.
256
<0
.220
<3
.292
4655
00
1.5
42
2
2.79
0
6.84
5
<3
.574
4
7.71
4 C
359
ap
10d1
1
s
p
<
4.04
1
<0.3
81
375.
047
11
000
<0.3
86
<1
.265
77
4.41
8
n
.a.
4.7
21
C35
9
ap10
d14
sp
23.
179
<0
.594
28
8.85
9
1100
0
<0
.758
<2.8
89
860.
547
n.a
.
<
6.35
8
C35
9
ap10
d15
sp
<4.
002
<0
.627
61
2.22
7
1100
0
<0
.553
<1.2
75
225.
815
n.a
.
5
.394
C
362
ap
06a0
4
p
y
<
3.17
7
<0.4
20
<5.0
32
46
5500
2
.359
10.
021
<3
.638
3
9.82
8
480.
495
C36
2
ap06
a06
py
<3.
717
<0
.432
7.
852
465
500
<0
.295
<0.8
29
276.
216
974
.812
69
5.77
1 C
362
ap
06a0
9
p
y
<
3.37
7
<0.3
83
<5.7
17
46
5500
1
.097
34.
930
<2
.755
<
5.50
6
366.
535
C36
2
ap06
a10
py
<4.
209
<0
.415
<5
.152
4655
00
2.0
62
7
.222
<4.0
36
<7.
013
38
6.46
4 C
362
ap
06a1
4
p
y
6
.635
<0.3
49
<5.3
56
46
5500
0
.736
7.5
67
12
9.60
7
1
00.2
79
794.
070
C36
2
ap06
a15
py
<4.
348
<0
.538
<7
.689
4655
00
2.6
28
6
.951
<3.9
89
<7.
238
17
3.38
0 C
362
ap
06a1
7
p
y
4
4.72
4
<0.4
11
63.8
37
46
5500
1
.217
7.9
40
<2
.716
<
5.65
3
468.
069
C36
2
ap06
a03
sp
<4.
720
<0
.525
60
0.62
6
2160
0
<0
.418
<1.2
92
4.78
6
n.
a.
<3.0
85
C36
2
ap06
a05
sp
<4.
665
<0
.467
71
8.98
9
2160
0
<0
.383
<1.1
63
10.2
99
n.a
.
<
2.11
0
C36
2
ap06
a11
sp
<5.
154
<0
.532
65
4.55
9
2160
0
<0
.399
<0.9
13
11.6
72
n.a
.
<
3.03
2
C36
2
ap06
a12
sp
<5.
213
<0
.500
79
0.92
6
2160
0
<0
.387
<1.1
30
9.73
3
n.
a.
<3.1
65
C36
2
ap06
a13
sp
<5.
208
<0
.504
73
0.56
3
2160
0
<0
.308
<1.3
66
25.8
23
n.a
.
<
3.06
3
C36
2
ap06
a16
sp
<4.
521
<0
.392
76
2.39
4
2160
0
<0
.409
<2.5
02
24.9
44
n.a
.
<
3.24
1
C36
4
ap10
c06
apy
<7.5
11
<1.
064
<15
.548
3
4300
0
<0.9
25
10
.610
<5
.925
<
12.4
69
n.a.
C
364
ap
10c1
1
c
py
<3
.333
<
0.56
2
<
6.59
7
30
4300
<
0.41
0
<1.
269
n.
a.
428
.409
25
0.81
7 C
364
ap
10c1
3
c
py
<3
.219
<
0.50
5
<
7.34
6
30
4300
<
0.52
7
<0.
905
n.
a.
131
0.26
5
20
6.48
3 C
364
ap
10c0
3
p
y
<
3.61
8
<0.4
73
<5.2
50
46
5500
4
5.80
3
5.1
87
<3
.063
<
4.60
7
259.
828
C36
4
ap10
c05
py
<4.
955
<0
.598
<6
.644
4655
00
29.
080
1
8.26
3
<3.5
90
138
4.56
1
87
0.82
1 C
364
ap
10c0
8
p
y
<
3.28
0
<0.5
87
<6.2
66
46
5500
1
.742
<1.
489
<3
.480
<
6.12
0
165.
301
C36
4
ap10
c12
py
<3.
218
<0
.408
<6
.428
4655
00
46.
147
2
.576
7.20
0
10
7.08
3
2
03.4
68
C36
4
ap10
c14
py
<3.
637
<0
.346
7.
599
465
500
49
.035
7.67
8
24.
082
7
613.
732
839.
536
C36
4
ap10
c15
py
<2.
495
<0
.347
<6
.400
4655
00
19.
641
3
.205
7.34
2
<6
.765
1
080.
210
C36
4
ap10
c17
py
<4.
551
<0
.438
51
5.68
2
4655
00
41.
397
8
.808
77.5
53
291
3.29
6
58
54.0
35
C36
4
ap10
c18
py
4.3
15
<0
.200
<2
.355
4655
00
66.
545
2
1.58
9
2.10
1
2.
726
715.
539
C36
4
ap10
c04
sp
<3.
130
<0
.470
36
5.47
8
2390
0
<0
.344
<1.1
89
366.
682
n.a
.
<
3.43
1
C36
4
ap10
c09
sp
<4.
056
<0
.507
37
0.12
3
2390
0
<0
.485
<1.1
14
234.
003
n.a
.
2
1.75
4 C
364
ap
10c1
0
s
p
<
4.42
0
<0.5
69
524.
969
23
900
<0.5
22
<1
.574
26
1.24
0
n
.a.
24.
238
C36
5
ap03
b03
py
<1.
141
<0
.197
47
.405
4655
00
0.8
33
1
.371
2682
.877
937
9.29
0
48
4.66
6 C
365
ap
03b0
9
p
y
3
3.94
4
<0.8
11
22.1
63
46
5500
1
3.37
5
6.2
32
<3
.970
1
2.85
4
289.
026
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
60
Appendix 5: LA-ICP-MS Analysis—Sulphides
C36
5
ap03
b11
py
9.5
55
<0
.559
30
.538
4655
00
0.9
59
4
.132
534.
409
177
.207
11
36.4
79
C36
5
ap03
b12
py
<3.
887
<0
.670
<7
.681
4655
00
<0.
312
<
1.60
3
3.76
4
<4
.027
5
8.28
0 C
365
ap
03b1
3
p
y
1
1.31
2
<0.9
47
<8.0
96
46
5500
6
6.52
2
11.
731
<3
.732
<
5.44
7
474.
534
C36
5
ap03
b16
py
<3.
989
<0
.658
12
.463
4655
00
<0.
466
<
1.75
4
4.88
8
<7
.294
5
74.8
17
C36
5
ap03
b17
py
<4.
526
<0
.592
45
.419
4655
00
<0.
427
<
1.21
5
12.6
51
12.
795
42
2.83
5 C
365
ap
03b0
4
s
p
<
5.32
0
<1.0
13
537.
726
47
100
<0.6
21
<2
.001
39
.795
n
.a.
<2.
974
C
365
ap
03b0
7
s
p
<
4.39
7
<0.9
00
495.
561
47
100
<0.5
08
<1
.484
39
.094
n
.a.
<3.
227
C
365
ap
03b1
0
s
p
<
5.42
0
<0.9
40
531.
936
47
100
<0.7
20
<2
.274
33
.328
n
.a.
<4.
739
C
365
ap
03b1
4
s
p
<
5.77
0
<1.1
36
559.
402
47
100
<0.6
59
<1
.853
35
.220
n
.a.
<3.
994
C
365
ap
03b1
5
s
p
<
5.74
1
<0.9
19
524.
972
47
100
<0.8
36
<2
.286
39
.674
n
.a.
<4.
452
C
369
fb
13a0
5
cpy
<12.
641
<1.
762
<34
.321
3
0430
0
<1.0
94
<5
.722
n.
a.
207
.701
<1
0.80
2
C36
9
ap06
b14
py
<3.
290
<0
.322
<4
.586
4655
00
27.
047
2
0.00
9
9613
.619
151
3.55
4
88
.295
C
369
ap
06b1
5
p
y
<
3.37
3
<0.3
69
6.77
7
4
6550
0
488.
121
45
.922
<3
.076
<
4.87
0
623.
778
C36
9
ap06
b16
py
<2.
589
<0
.300
<3
.229
4655
00
195
.682
1
41.5
83
2
.472
<3.
042
77
8.82
6 C
369
ap
06b1
7
p
y
<
4.94
1
<0.3
48
<7.0
01
46
5500
3
85.8
68
67.
239
5.
389
26.3
24
995
.939
C
369
fb
13a0
3
py
<1.8
35
<0.
270
<3.
731
4655
00
366
.015
6
1.50
7
<0.8
61
171
.549
47
9.65
4 C
369
fb
13a0
4
py
<6.8
32
<1.
004
<11
.654
4
6550
0
168.
438
66
.821
<2
.479
8
7.16
1
627.
434
C36
9
ap06
b12
sp
<4.
592
<0
.312
27
8.81
4
4660
0
<0
.305
<0.8
81
11.5
90
n.a
.
<
2.23
5
C36
9
ap06
b13
sp
<4.
516
<0
.447
23
7.32
5
4660
0
<0
.493
<2.1
80
2703
.421
n.a
.
<
2.18
8
C37
2
ap02
b03
apy
65.8
97
3.3
97
52.
824
3430
00
13.
312
1
1.56
6
5.99
5
66
.044
n
.a.
C37
2
ap02
b05
apy
<5.9
70
<1.
150
<9.
814
3430
00
1.0
69
3
.804
<7.1
92
<6.
948
n.
a.
C37
2
ap02
b12
apy
109.
611
<1.
211
63.
049
3430
00
14.
912
1
6.28
6
7.88
7
31
49.7
30
n.
a.
C37
2
ap02
b04
py
1.9
10
<0
.141
3.
292
465
500
18
.599
10.8
87
3.42
3
95
.920
3
791.
434
C37
2
ap02
b06
py
26.
169
<0
.200
6.
186
465
500
0.
914
0.8
78
2.
111
2.74
4
18
67.4
73
C37
2
ap02
b07
py
16.
610
1.
844
39
1.20
8
4655
00
38.
601
2
3.85
8
172.
707
46.
285
69
33.7
99
C37
2
ap02
b08
py
<1.
139
<0
.237
15
2.02
0
4655
00
50.
366
2
2.64
2
123.
630
9.4
02
39
36.7
75
C37
2
ap02
b09
py
<1.
809
<0
.338
<2
.228
4655
00
15.
374
1
1.69
7
5.02
5
6.
427
4396
.648
C
372
ap
02b1
0
p
y
2
2.80
5
1.28
9
10.3
19
46
5500
4
0.70
0
24.
269
6.
358
3.18
9
34
82.4
28
C37
2
ap02
b11
py
50.
270
0.
820
31
.745
4655
00
55.
926
2
4.58
8
10.6
87
5.3
57
17
575.
666
C37
2
ap02
b13
py
818
.164
1.1
10
5.2
01
4655
00
38.
973
1
8.98
7
3.77
7
3.
884
2220
.570
C
372
ap
02b1
4
p
y
3
1.94
6
0.76
9
14.2
45
46
5500
2
7.32
3
12.
783
2.
661
176.
890
143
67.1
19
C37
2
ap02
b15
py
<3.
967
2.
467
68
8.19
4
4655
00
69.
856
2
4.37
9
61.4
20
32.
012
25
77.8
36
C37
2
ap02
b16
py
67.
930
<0
.666
<5
.128
4655
00
1.9
32
8
.575
<2.9
07
<3.
576
33
74.2
48
C37
2
ap02
b17
py
<5.
351
<0
.698
<7
.505
4655
00
36.
482
1
3.68
2
4.27
6
<4
.202
1
917.
763
C37
2
ap02
b18
py
620
.840
0.7
90
3.1
16
4655
00
1.6
15
0
.967
9.70
9
3.
053
1218
.298
C
378
ap
10b0
6
c
py
<1
2.00
3
<
2.10
6
<
13.8
37
304
300
<1
.215
<2.5
65
n.a.
2
15.9
64
74.8
62
C37
8
ap10
b03
py
<3.
064
<0
.422
<5
.290
4655
00
33.
972
2
1.48
4
<2.4
54
<6.
143
12
5.80
7 C
378
ap
10b0
5
p
y
<
3.06
4
<0.5
41
<5.4
27
46
5500
1
.036
21.
583
<2
.952
<
5.19
1
2247
.529
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
61
Appendix 5: LA-ICP-MS Analysis—Sulphides
C37
8
ap10
b08
py
16.
055
<0
.241
10
8.09
9
4655
00
169
.819
5
5.77
0
<1.3
96
3.4
90
58
4.78
5 C
378
ap
10b0
9
p
y
<
2.94
8
<0.5
26
<5.0
33
46
5500
1
7.21
8
138
.098
<3.
060
<
5.95
3
1489
.875
C
378
ap
10b1
0
p
y
<
3.26
3
<0.4
08
<6.8
47
46
5500
6
0.27
0
50.
997
<3
.071
<
6.65
4
841.
925
C37
8
ap10
b07
sp
<3.
777
<0
.461
23
5.42
5
2600
0
<0
.411
<1.0
68
1335
0.17
8
n.a
.
<
3.92
6
C37
9
ap03
a03
py
19.
132
<0
.134
2.
268
465
500
16
.907
<0.3
74
4.35
9
2.
820
487.
829
C37
9
ap03
a06
py
<1.
084
<0
.173
1.
735
465
500
1.
041
<0.
393
<0
.714
<
1.38
8
7.70
8 C
379
ap
03a0
7
p
y
2
6.19
5
0.17
8
385.
075
46
5500
<
0.09
7
<0.
316
11
2.59
6
1
0.28
6
356.
788
C37
9
ap03
a08
py
7.9
30
<0
.156
1.
492
465
500
3.
740
<0.
384
2.
909
2.74
4
15
.034
C
379
ap
03a0
9
p
y
8
1.04
3
<0.1
68
1.34
1
4
6550
0
4.48
8
<
0.42
4
1.01
7
3.
219
21.6
88
C37
9
ap03
a11
py
1.9
33
<0
.218
<1
.761
4655
00
7.6
66
<
0.50
1
1.84
7
<2
9.04
4
4
41.3
56
C37
9
ap03
a12
py
<1.
636
<0
.166
36
.519
4655
00
0.4
35
<
0.35
9
225.
454
14.
228
33
9.64
7 C
379
ap
03a1
7
p
y
<
1.31
0
<0.1
49
3.45
6
4
6550
0
1.74
1
<
0.50
4
1.92
1
2.
895
25.2
18
C37
9
ap03
a18
py
96.
124
<0
.180
2.
107
465
500
11
.810
2.08
4
3.3
70
3
.526
47.5
40
C37
9
ap03
a04
sp
<2.
597
<0
.466
16
46.9
39
5110
0
<0
.265
<0.7
46
52.7
73
n.a
.
<
1.87
1
C37
9
ap03
a05
sp
59.
781
4.
087
69
5.61
5
5110
0
<0
.476
<1.9
40
365.
737
n.a
.
<
3.18
9
C37
9
ap03
a10
sp
<7.
824
<1
.074
14
95.5
52
5110
0
<0
.735
<2.2
52
815.
412
n.a
.
<
4.87
3
C37
9
ap03
a13
sp
<9.
278
<1
.351
16
18.4
95
5110
0
<0
.949
<3.1
78
21.7
50
n.a
.
<
6.28
8
C37
9
ap03
a14
sp
<7.
385
<1
.188
17
91.9
09
5110
0
<0
.784
<3.1
60
19.5
15
n.a
.
<
5.07
8
C37
9
ap03
a15
sp
16.
742
<1
.175
63
0.80
9
5110
0
<1
.027
<3.1
02
2233
.537
n.a
.
<
7.40
6
C37
9
ap03
a16
sp
<4.
707
<0
.806
20
01.6
44
5110
0
<0
.407
<1.2
38
17.7
48
n.a
.
<
2.95
1
C38
1
ap03
f16
ap
y
<9
.794
<
1.45
4
<
13.6
18
343
000
<0
.981
<3.1
58
89.7
93
<10
.611
n.
a.
C38
1
ap03
f03
cp
y
<4
.731
<
0.65
4
<
6.51
1
30
4300
<
0.63
9
<1.
339
n.
a.
555
.690
7.
602
C38
1
ap03
f08
cp
y
<1
5.20
2
<
2.34
3
<
21.2
15
304
300
<1
.883
<5.6
63
n.a.
4
58.9
60
8.95
6 C
381
ap
03f0
5
py
<3.1
31
<0.
615
921
.452
4
6550
0
1.22
7
<
1.29
1
61.5
88
32.
469
48
88.2
85
C38
1
ap03
f07
py
6.
940
<
0.25
6
6
81.5
75
465
500
<0
.134
1.39
5
206
.491
23
.070
3
330.
861
C38
1
ap03
f09
py
<1
.599
<
0.20
0
5
4.18
7
46
5500
3
3.16
3
6.5
04
18
0.64
2
3
.560
704.
879
C38
1
ap03
f11
py
<0
.837
<
0.12
7
8
80.0
56
465
500
<0
.120
<0.3
56
50.2
84
31.
051
52
48.2
47
C38
1
ap03
f12
py
<1
.169
<
0.16
0
5
86.6
95
465
500
<0
.088
0.47
6
102
.638
28
.736
5
362.
848
C38
1
ap03
f13
py
3.
630
<
0.20
2
<
2.24
2
46
5500
3
.433
0.5
43
1.
706
2.31
9
83
.729
C
381
ap
03f1
4
py
<1.3
01
<0.
165
124
0.21
0
4
6550
0
2.99
2
0
.581
76.3
97
25.
850
30
16.0
23
C38
1
ap03
f18
py
<3
.720
<
0.58
7
8
06.4
51
465
500
<0
.462
<1.8
29
3.51
3
22
.703
3
996.
168
C38
1
ap03
f04
sp
<1
.520
<
0.24
4
1
461.
854
438
00
<0
.171
<0.6
29
16.5
09
n.a
.
<
0.82
1
C38
1
ap03
f06
sp
<4
.884
<
0.82
5
1
067.
524
438
00
<0
.809
<3.2
69
15.9
31
n.a
.
<
6.61
3
C38
1
ap03
f10
sp
<4
.561
<
0.59
9
1
132.
260
438
00
<0
.457
<2.0
98
325.
984
n.a
.
<
3.09
8
C38
1
ap03
f15
sp
<5
.887
<
0.71
6
1
406.
284
438
00
<0
.507
<1.9
96
163.
342
n.a
.
<
4.10
6
C38
1
ap03
f17
sp
<6
.945
<
1.23
5
1
399.
280
438
00
<0
.755
<2.3
10
139.
202
n.a
.
1
2.20
6 C
383
ap
17e1
2
p
y
<
4.12
8
<0.5
17
<6.3
77
46
5500
5
.846
25.
908
<2
.451
<
6.26
9
19.8
82
C38
3
ap17
e14
py
23.
293
<0
.139
<1
.467
4655
00
7.5
12
2
7.00
9
0.73
8
4.
910
48.1
89
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
62
Appendix 5: LA-ICP-MS Analysis—Sulphides
C38
3
ap17
e16
py
118
.271
<0.
367
<5.
637
4655
00
8.7
47
5
1.42
6
<1.9
53
<6.
687
25
.860
C
383
ap
17e1
7
p
y
3
0.00
4
<0.4
36
<6.6
30
46
5500
5
.697
31.
996
11
0.92
9
6
.355
123.
088
C38
3
ap17
e18
py
<3.
821
<0
.326
<5
.238
4655
00
1.9
20
6
.014
1726
.882
267
.570
10
15.1
20
C38
3
ap17
e13
sp
110
.095
0.6
57
126
1.05
4
1
4000
<0.3
18
<1
.242
57
2.78
3
n
.a.
<2.
965
C
383
ap
17e1
5
s
p
<
3.71
9
<0.5
81
1017
.779
14
000
<0.4
16
<1
.199
22
5.77
6
n
.a.
<3.
088
C
385
ap
06d0
5
c
py
<1
2.05
2
<
1.18
8
<
22.3
23
304
300
<1
.151
<2.6
16
n.a.
2
886.
444
<8.5
15
C38
5
ap06
d04
py
<3.
705
<0
.530
<7
.053
4655
00
73.
337
6
.851
25.1
04
<5.
394
42
5.32
8 C
385
ap
06d0
6
p
y
<
3.50
9
<0.3
45
<5.8
57
46
5500
4
2.50
0
6.8
63
18
.280
<
4.41
3
13.1
26
C38
5
ap06
d09
py
4.2
90
<0
.148
<2
.432
4655
00
62.
749
1
2.90
7
1482
.360
93.
760
13
.520
C
385
ap
06d1
0
p
y
1
0.48
7
<0.4
96
60.3
19
46
5500
2
6.89
5
7.2
59
<4
.400
1
810.
139
65.5
27
C38
5
ap06
d11
py
<4.
970
<0
.499
16
.728
4655
00
31.
281
9
.505
13.8
98
155
.028
37
.327
C
385
ap
06d0
7
s
p
1
1.36
2
<0.4
61
647.
640
24
000
<0.4
42
<1
.102
26
.204
n
.a.
<3.
418
C
385
ap
06d0
8
s
p
<
5.02
3
<0.5
06
696.
640
24
000
<0.5
68
<1
.071
22
.718
n
.a.
<3.
005
C
385
ap
06d1
2
s
p
<
4.29
5
<0.3
67
612.
947
24
000
<0.4
59
<0
.946
31
.031
n
.a.
<3.
385
C
794
ap
18a3
4
c
py
6.
595
<
0.12
5
1
3.54
0
30
4300
<
0.06
4
<0.
413
n.
a.
897
.161
9.
521
C79
4
ap18
a33
py
11.
691
0.
591
34
2.85
5
4655
00
0.3
33
1
.245
1547
.262
693
.907
23
1.14
0 C
794
ap
18a3
6
p
y
2
.588
<0.0
82
14.1
70
46
5500
6
.055
8.2
47
1.
634
<2.7
76
72.
323
C79
4
ap18
a39
py
2.9
25
0.
492
10
.582
4655
00
0.6
19
<
5.62
1
1.03
0
<1
.754
2
21.8
22
C79
4
jl11a
74
py
<1
.092
<
0.12
5
6
.948
46
5500
2
.523
<0.
858
19
.873
<
2.22
0
271.
866
C79
4
jl11a
75
py
1.
937
<
0.09
4
1
.039
46
5500
0
.767
<0.
711
<4
.292
<
1.95
9
289.
796
C79
4
ap18
a37
sp
15.
896
1.
143
11
75.0
71
7200
0
0.
088
<0.
193
79
48.1
66
n
.a.
<1.
121
C
794
ap
18a3
8
s
p
1
.289
<0.0
83
1139
.687
72
000
0.05
5
0
.812
1175
6.05
9
n.a
.
1
.482
C
795
ap
19a4
9
p
y
4
4.66
5
1.48
5
245.
104
46
5500
0
.591
0.4
84
27
8.40
7
3
22.7
93
3293
.642
C
795
ap
19a5
0
p
y
2
.484
<0.0
50
3.01
9
4
6550
0
<0.0
36
<0
.130
12
.430
1
.196
173.
872
C79
5
ap19
a51
py
13.
020
0.
178
62
8.55
7
4655
00
0.1
32
0
.233
135.
511
968
5.90
4
27
67.7
23
C79
5
jl11a
59
py
0.
987
<
0.06
6
2
.620
46
5500
<
0.14
9
<0.
465
14
.167
2
50.3
43
88.7
56
C79
5
jl11a
60
py
<0
.748
<
0.07
5
1
3.08
6
46
5500
<
0.14
3
<0.
571
9.
849
2.91
7
92
.309
C
797
ap
19a9
1
p
y
2
.404
0.21
5
124.
934
46
5500
0
.663
0.2
86
57
9.48
1
4
.015
259.
954
C79
7
ap19
a92
py
15.
492
0.
165
17
3.37
0
4655
00
0.4
78
<
0.23
8
24.7
44
3.2
19
15
7.48
6 C
797
ap
19a9
5
p
y
2
.782
0.28
3
485.
321
46
5500
1
.964
1.6
81
10
9.80
4
6
.049
79.9
79
C79
7
jl11z
09
py
88
.791
<
0.09
1
1
0.20
7
46
5500
5
.977
<0.
780
15
7.59
2
1
.633
3907
.693
C
797
jl1
1z10
py
18.0
22
<0.
172
88.
908
4655
00
0.9
59
<
1.38
2
117.
829
<3.
142
48
6.40
4 C
797
ap
19a9
3
s
p
1
.206
<0.0
41
1731
.043
25
500
<0.0
38
<0
.126
13
.710
n
.a.
2.1
90
C79
7
ap19
a94
sp
0.8
20
<0
.041
14
96.8
33
2550
0
<0
.018
0.01
4
329
.189
n.
a.
1.42
2 C
799
ap
19a7
6
p
y
2
8.83
7
0.19
0
59.8
70
46
5500
0
.180
7.0
65
77
.591
1
97.0
78
1618
4.95
8 C
799
jl1
1a35
py
15.5
49
0.8
70
716
.605
4
6550
0
1.00
6
<
0.80
2
275.
265
246
.052
93
3.89
4 C
799
jl1
1a36
py
3.17
7
<0.
070
14.
550
4655
00
1.2
45
3
1.82
4
25.6
71
11.
931
15
32.2
93
C79
9
jl11a
37
py
4.
311
<
0.33
2
8
.173
46
5500
2
.226
10.
061
47
.202
1
509.
867
3369
.760
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
63
Appendix 5: LA-ICP-MS Analysis—Sulphides
C79
9
jl11a
38
py
4.
647
<
0.11
6
6
4.10
0
46
5500
1
.351
6.5
82
53
.063
1
7507
.728
1
733.
422
C79
9
ap19
a80
sp
1.0
28
<0
.063
47
4.88
1
3540
0
<0
.025
0.04
7
18.
472
n
.a.
1.8
89
C79
9
ap19
a81
sp
1.0
08
<0
.059
56
8.25
4
3540
0
<0
.026
<0.1
08
17.7
48
n.a
.
2
.169
C
801
ap
10a1
7
p
y
5
9.07
3
0.26
7
1.68
1
4
6550
0
44.6
43
31
.764
2.
370
234.
494
67.
177
C80
1
ap10
a18
py
5.1
72
<0
.114
7.
507
465
500
39
.634
18.0
98
6.44
0
10
425.
330
10
4.08
3 C
801
ap
10a2
2
p
y
2
.836
0.35
8
1.25
1
4
6550
0
6.24
9
1
9.64
9
2.24
0
12
.752
4
4.59
8 C
801
jl1
1z06
py
<0.7
87
<0.
056
<0.
429
4655
00
5.7
73
2
1.61
8
<2.4
83
16.
372
28
.088
C
801
jl1
1z07
py
<0.8
44
<0.
087
<0.
561
4655
00
2.0
82
3
6.66
9
<2.8
84
<1.
698
49
.250
C
801
jl1
1z08
py
0.69
7
<0.
063
<0.
476
4655
00
20.
260
2
1.79
8
<2.0
29
2.6
45
30
.537
C
801
ap
10a2
3
s
p
1
.426
<0.1
08
683.
727
14
200
<0.0
48
<0
.231
35
.438
n
.a.
<3.
956
C
803
ap
18a6
4
c
py
1.
545
<
0.13
8
<
2.75
4
30
4300
<
0.06
3
<0.
261
n.
a.
853
.591
7.
258
C80
3
ap18
a65
py
7.3
81
0.
476
55
3.98
7
4655
00
0.6
49
<
0.14
5
0.71
9
1.
750
517.
632
C80
3
jl11a
45
py
<0
.769
<
0.07
8
0
.682
46
5500
0
.733
<0.
598
20
0.89
7
1
62.7
84
472.
394
C80
3
jl11a
46
py
39
.799
<
0.07
8
4
.211
46
5500
0
.337
<0.
530
23
44.1
79
1
57.9
81
938.
739
C80
3
jl11a
47
py
1.
064
<
0.07
1
6
8.83
2
46
5500
1
.128
<0.
566
16
8.94
8
5
.244
3623
.942
C
803
jl1
1a48
py
<0.7
73
<0.
079
774
.388
4
6550
0
0.40
3
<
0.61
5
598.
458
126
2.65
8
32
8.17
3 C
803
ap
18a6
2
s
p
0
.387
0.02
1
102.
269
32
200
0.08
1
0
.094
142.
627
n.a
.
1
19.1
51
C80
3
ap18
a63
sp
0.9
87
<0
.050
19
15.5
86
3220
0
<0
.022
<0.1
66
1574
.307
n.a
.
<
1.10
9
C80
4
ap18
a17
py
22.
950
0.
052
73
2.28
8
4655
00
0.7
84
0
.362
178.
700
9.1
91
70
35.2
03
C80
4
ap18
a18
py
4.0
55
0.
408
<1
.093
4655
00
0.9
01
1
.301
<0.5
94
<4.
505
10
98.9
19
C80
4
jl11a
31
py
3.
885
0
.315
5
95.5
23
465
500
1.
197
<0.
497
21
6.35
0
2
1.57
7
2989
.498
C
804
jl1
1a32
py
28.7
62
1.3
76
155
4.68
0
4
6550
0
0.95
7
<
0.54
1
113.
891
6.1
65
29
69.4
73
C80
4
jl11a
34
py
92
.740
5
.109
4
11.3
55
465
500
0.
842
<0.
772
12
6.01
4
1
7.74
0
2077
.946
C
807
jl0
4a21
py
<1.0
60
<0.
090
14.
299
4655
00
0.3
75
<
0.53
9
<3.7
10
604
0.84
4
33
0.53
0 C
807
jl0
4a22
py
1.17
0
<0.
091
1.1
05
4655
00
0.4
29
<
0.56
9
<3.2
80
11.
710
21
4.89
1 C
807
jl0
4a23
py
1.39
0
<0.
076
28.
149
4655
00
<0.
169
<
0.48
7
42.5
71
510
4.03
3
29
7.28
6 C
807
jl0
4a24
py
1.96
7
<0.
098
3.9
47
4655
00
0.6
80
<
0.66
9
<2.8
23
310
.628
17
6.36
7 C
807
jl0
4a25
py
2.11
3
<0.
093
21.
585
4655
00
0.6
40
<
0.54
7
6.80
5
13
727.
871
16
8.13
1 C
807
jl0
4a26
sp
1.74
1
<0.
136
196
1.81
5
4
5400
<0.3
91
<1
.138
16
.306
n
.a.
<4.
924
C
807
jl0
4a27
sp
<1.3
58
<0.
191
243
2.76
1
4
5400
<0.4
14
<1
.355
10
.369
n
.a.
<4.
788
C
808
ap
18a4
6
s
p
0
.933
<0.0
60
1175
.882
47
200
4.51
8
<
0.15
1
20.4
71
n.a
.
<
1.17
6
C80
8
ap18
a47
sp
1.0
99
<0
.050
12
43.0
33
4720
0
5.
391
<0.
255
10
.813
n
.a.
0.8
87
C80
9
jl04a
64
py
15
.113
<
0.10
4
1
4.86
3
46
5500
3
.398
1.9
26
38
.392
1
76.9
59
44.5
61
C80
9
jl04a
65
py
3.
600
0
.092
3
.945
46
5500
1
11.0
23
3.2
54
<3
.669
1
591.
384
245.
610
C80
9
jl04a
66
py
14
.681
<
0.08
4
<
0.59
6
46
5500
1
8.65
5
6.2
47
3.
235
<2.8
27
19.
852
C80
9
jl04a
67
py
22
.825
<
0.09
2
1
.049
46
5500
2
77.7
77
4.4
90
<4
.061
2
8.44
5
290.
275
C80
9
jl04a
68
sp
4.
321
<
0.21
0
2
388.
413
485
00
<0
.636
<2.1
40
21.4
85
n.a
.
<
5.40
4
C80
9
jl04a
69
sp
4.
847
<
0.12
8
2
297.
708
485
00
0.
669
<0.
788
26
.941
n
.a.
<2.
728
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
64
Appendix 5: LA-ICP-MS Analysis—Sulphides
C81
0
ap19
a71
py
3.2
43
1.
522
50
97.8
64
4655
00
0.1
75
<
0.33
6
307.
746
36.
382
35
03.6
63
C81
0
ap19
a72
py
2.4
83
0.
255
16
36.7
40
4655
00
0.4
69
0
.124
43.3
32
3.6
76
50
7.54
8 C
810
ap
19a7
3
p
y
2
.371
<0.0
35
62.4
10
46
5500
1
.071
<0.
143
0.
522
<0.7
12
26.
894
C81
0
ap19
a74
py
2.7
06
0.
066
41
.075
4655
00
<0.
027
0
.017
8.56
7
0.
715
566.
101
C81
0
ap19
a67
sp
3.4
26
<0
.033
29
59.1
96
3590
0
<0
.044
<0.1
47
397.
238
n.a
.
<
2.28
3
C81
0
ap19
a68
sp
2.2
61
0.
087
31
17.9
40
3590
0
<0
.029
0.03
8
871
.412
n.
a.
<2.1
27
C81
1
jl04a
05
py
61
.253
2
.148
9
86.6
99
465
500
7.
839
<1.
079
22
6.64
4
1
266.
850
2266
.383
C
811
jl0
4a08
py
2.09
1
<0.
128
91.
604
4655
00
<0.
361
<
0.79
6
579.
229
5.9
09
16
57.2
43
C81
2
ap19
a85
cpy
1.55
5
<0.
071
<1.
900
3043
00
<0.
049
0
.719
n.a.
6
06.9
07
25.2
41
C81
2
ap19
a82
py
13.
945
2.
587
10
.770
4655
00
17.
108
1
81.7
14
7
.975
171
.833
12
37.2
28
C81
2
ap19
a84
py
114
.837
9.3
45
547
.074
4
6550
0
9.58
5
1
11.6
99
5
4.19
4
78.
742
18
66.3
12
C81
2
jl11a
55
py
<0
.914
<
0.06
4
<
0.42
5
46
5500
1
8.20
5
307
.856
<2.
816
<
1.24
6
1165
.023
C
812
jl1
1a57
py
181.
862
2.9
04
7.9
20
4655
00
17.
568
1
14.5
40
1
7.58
4
951
.524
17
85.7
52
C81
2
ap19
a86
sp
0.8
99
<0
.063
15
41.7
55
4240
0
<0
.051
<0.2
38
1223
.968
n.a
.
<
2.33
1
C81
2
ap19
a87
sp
1.1
79
<0
.064
12
86.5
19
4240
0
<0
.035
0.02
3
330
7.18
8
n.
a.
<2.9
35
C81
3
jl04a
37
py
2.
348
1
.946
2
3.68
9
46
5500
7
8.79
7
27.
778
<3
.423
7
133.
516
234.
531
C81
3
jl04a
38
py
67
6.77
6
0
.664
1
.544
46
5500
1
8.47
8
24.
375
3.
166
556.
082
175
.746
C
813
jl0
4a39
py
23.4
87
<0.
256
15.
561
4655
00
39.
157
2
0.61
3
<9.5
75
332
.300
70
.085
C
813
jl0
4a41
py
1.74
1
<0.
169
<1.
183
4655
00
28.
648
1
3.36
7
<5.9
35
<3.
136
87
.168
C
813
jl0
4a42
sp
3.26
1
<0.
140
130
6.82
3
3
2700
<0.4
35
<2
.178
52
.243
n
.a.
<3.
765
C
813
jl0
4a43
sp
1.33
5
<0.
103
129
3.47
6
3
2700
0.26
7
<
0.77
5
85.7
61
n.a
.
3
.487
C
814
ap
19a4
5
p
y
2
.520
<0.0
57
2.76
2
4
6550
0
11.1
97
0.
276
1
0.35
9
0.8
13
34
48.3
71
C81
4
ap19
a46
py
3.0
53
<0
.048
3.
862
465
500
5.
856
0.1
42
57
.415
<
1.10
1
3906
.099
C
814
ap
19a4
7
p
y
4
.968
<0.0
53
5.51
2
4
6550
0
23.0
69
0.
432
8
6.98
5
0.7
26
33
10.9
10
C81
4
ap19
a48
py
5.6
05
<0
.037
4.
706
465
500
3.
142
<0.
124
45
.810
0
.979
6429
.667
C
815
ap
18a9
3
p
y
1
.530
<0.0
47
31.1
56
46
5500
3
4.56
8
1.0
59
21
16.5
69
2
011.
846
2369
.593
C
815
ap
18a9
4
p
y
1
.884
<0.0
74
22.6
97
46
5500
1
2.78
8
4.6
39
15
85.0
55
3
773.
764
183.
730
C81
5
ap18
a95
py
12.
656
<0
.066
1.
364
465
500
4.
119
0.3
97
2.
341
0.77
4
49
.173
C
815
ap
18a9
6
p
y
5
.144
<0.0
36
2.07
8
4
6550
0
4.71
0
4
.023
24.2
07
22.
475
40
5.78
7 C
815
ap
18a9
7
s
p
9
.169
0.09
5
1941
.302
53
000
0.13
9
<
0.12
5
24.3
44
n.a
.
<
1.47
1
C81
5
ap18
a98
sp
1.1
68
<0
.048
14
98.3
68
5300
0
0.
134
<0.
215
64
4.36
7
n
.a.
<0.
868
C
817
ap
10a0
5
a
py
1.
125
<
0.18
9
<
3.44
2
34
3000
<
0.16
4
<0.
316
<0
.690
<
3.85
0
n.a.
C
817
ap
10a0
3
p
y
0
.669
0.41
0
1331
.325
46
5500
1
9.01
8
3.6
13
58
1.33
8
1
45.4
17
2339
.354
C
817
ap
10a0
4
p
y
1
.594
<0.1
36
85.4
47
46
5500
1
7.94
1
2.0
05
82
.627
3
362.
818
1249
.453
C
817
jl1
1a70
py
<0.6
55
<0.
077
0.9
64
4655
00
9.7
54
2
.413
184.
951
76.
128
27
56.2
57
C81
7
jl11a
71
py
25
1.94
7
0
.342
4
6.12
9
46
5500
4
.957
1.7
02
<2
.722
6
6.27
0
1453
.329
C
817
jl1
1a72
py
<3.8
34
1.3
54
212
5.14
2
4
6550
0
3.59
1
<
3.13
0
704.
540
41.
091
28
31.6
93
C81
7
jl11a
73
py
<1
.461
2
.034
1
790.
951
465
500
18
.124
6.68
0
638
.500
12
8.93
3
3
015.
601
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
65
Appendix 5: LA-ICP-MS Analysis—Sulphides
C81
8
jl04a
12
py
77
.309
0
.195
9
53.9
98
465
500
0.
275
<0.
588
23
0.10
0
6
0.05
6
1153
.657
C
818
jl0
4a13
py
3.63
1
0.1
60
283
3.06
6
4
6550
0
0.61
0
<
0.50
7
83.6
64
3.1
73
38
2.85
1 C
818
jl0
4a14
py
<1.2
54
<0.
118
841
.135
4
6550
0
0.38
2
<
1.02
0
35.0
17
4.4
30
16
4.86
1 C
818
jl0
4a15
py
18.6
04
<0.
165
654
.614
4
6550
0
<0.4
38
<1
.176
35
.713
<
6.30
9
118.
045
C81
8
jl04a
16
py
1.
358
<
0.08
0
0
.831
46
5500
1
.667
<0.
526
<3
.530
4
.193
209.
490
C81
8
jl04a
17
sp
1.
666
<
0.11
1
1
808.
043
589
00
<0
.309
<0.8
46
788.
141
n.a
.
<
2.96
2
C81
8
jl04a
18
sp
1.
450
<
0.18
8
1
797.
460
589
00
<0
.510
<1.2
48
440.
417
n.a
.
<
4.62
8
C82
0
jl04a
46
py
21
.405
1
.539
5
.544
46
5500
0
.557
4.8
39
<4
.145
4
.733
219.
192
C82
0
jl04a
47
py
2.
003
<
0.07
2
2
5.69
9
46
5500
0
.581
10.
346
<3
.603
2
228.
965
453.
479
C82
0
jl04a
50
py
16
.264
0
.168
2
8.11
6
46
5500
0
.462
4.3
11
6.
855
1602
2.12
7
974.
210
C82
0
jl11z
14
py
39
.033
0
.219
2
5.22
6
46
5500
2
.220
8.3
84
4.
033
1152
3.87
4
508.
379
C82
0
jl11z
15
py
<0
.960
<
0.06
6
<
0.48
0
46
5500
1
.235
8.9
03
<2
.785
1
.338
307.
691
C82
0
jl11z
16
py
4.
945
0
.268
2
5.88
7
46
5500
1
.063
9.5
98
3.
376
6409
.657
475.
292
C82
0
jl04a
51
sp
1.
546
<
0.12
1
1
150.
470
344
00
<0
.276
<0.7
12
7.64
0
n.
a.
<2.8
01
C82
0
jl04a
52
sp
1.
434
<
0.12
5
1
089.
896
344
00
<0
.294
<1.0
03
10.9
54
n.a
.
<
3.15
4
C82
2
jl04a
31
cp
y
<2
.922
<
0.32
9
<
2.46
3
30
4300
<
0.91
1
2.6
61
n.
a.
457
.497
11
.858
C
822
jl0
4a32
cpy
<1.9
32
<0.
261
10.
561
3043
00
<0.
549
3
.782
n.a.
5
07.6
41
9.00
2 C
822
ap
10a1
6
s
p
0
.735
<0.1
01
2347
.646
44
000
0.40
7
0
.590
26.2
28
n.a
.
9
.861
C
822
jl0
4a34
sp
2.61
5
<0.
259
217
8.26
2
4
4000
<0.5
72
<1
.647
22
.579
n
.a.
<7.
964
C
823
ap
18a4
3
p
y
2
.910
<0.0
96
2.60
2
4
6550
0
101.
807
3.
628
5
62.2
36
264.
973
57.
388
C82
3
ap18
a44
py
4.3
00
<0
.088
9.
870
465
500
14
1.04
8
6.42
0
9.8
88
<
1.27
0
143.
484
C82
3
ap18
a45
py
32.
831
0.
285
55
.334
4655
00
116
.248
2
.589
43.8
70
5.5
49
17
2.68
4 C
823
jl1
1a82
py
20.6
72
<0.
062
33.
043
4655
00
162
.168
3
.879
99.7
66
1.4
49
75
.734
C
823
jl1
1a83
py
202.
832
<0.
085
246
.753
4
6550
0
183.
175
3.
884
3
7.55
6
<1.
157
87
.831
C
823
jl1
1a84
py
47.6
86
0.1
30
40.
160
4655
00
146
.603
8
.094
24.3
43
2.0
11
43
0.96
1 C
824
ap
18a0
3
p
y
1
.427
<0.0
38
6.27
6
4
6550
0
68.1
19
3.
547
7
814.
700
71.3
09
205
.822
C
824
ap
18a0
5
p
y
3
.082
0.25
3
3.37
6
4
6550
0
52.7
71
2.
472
7
.900
1.1
94
49
0.47
7 C
824
ap
18a0
6
p
y
4
.165
<0.0
42
1.27
5
4
6550
0
16.7
32
1.
136
0
.952
1.3
37
84
4.52
6 C
824
jl1
1a49
py
2.27
7
<0.
152
3.5
85
4655
00
67.
461
3
.020
<5.2
34
<2.
521
50
7.86
9 C
824
jl1
1a50
py
46.9
91
1.3
51
884
.714
4
6550
0
43.8
00
<1
.882
<8
.076
5
7.21
2
150.
705
C82
4
jl11a
51
py
22
7.55
1
<
0.14
9
9
4.79
0
46
5500
3
3.03
0
<1.
183
<6
.694
5
.431
522.
172
C82
4
jl11a
52
py
<0
.901
<
0.11
1
0
.720
46
5500
1
8.06
7
<0.
907
<4
.056
<
1.74
4
1356
.502
C
825
ap
18a5
3
c
py
2.
162
<
0.11
9
<
2.02
1
30
4300
6
.394
13.
082
n.
a.
697
.678
59
.730
C
825
ap
18a5
0
s
p
1
.082
<0.0
70
1375
.325
47
400
0.11
6
<
0.50
6
1344
.803
n.a
.
1
.065
C
825
ap
18a5
6
s
p
4
.049
0.46
2
1756
.196
47
400
<0.0
53
<0
.463
23
2.39
1
n
.a.
<2.
934
C
826
ap
18a7
0
c
py
2.
294
<
0.10
6
2
9.19
2
30
4300
4
.410
9.9
80
n.
a.
239
.226
54
6.34
6 C
826
ap
18a6
9
p
y
3
.938
0.21
4
21.1
78
46
5500
0
.046
<0.
244
82
0.11
5
4
.794
349.
317
C82
6
ap18
a71
py
9.8
20
<0
.097
1.
978
465
500
14
.732
28.7
11
<5.9
08
434
.688
10
61.3
81
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
66
Appendix 5: LA-ICP-MS Analysis—Sulphides
C82
6
ap18
a73
py
2.2
16
<0
.080
2.
860
465
500
1.
603
6.5
45
11
75.9
06
3
879.
238
795.
918
C82
6
jl11a
67
py
<0
.944
0
.392
3
.904
46
5500
4
.359
1.7
72
50
.138
1
.767
161.
941
C82
6
jl11a
68
py
59
.456
0
.433
1
5.38
7
46
5500
3
4.49
9
22.
122
7.
414
1445
7.97
2
296.
512
C82
6
jl11a
69
py
<0
.744
<
0.05
5
2
.283
46
5500
2
.011
7.4
64
19
24.0
57
3
194.
253
880.
840
C82
6
ap18
a68
sp
0.7
13
0.
196
32
4.91
1
2260
0
<0
.034
<0.1
41
750.
389
n.a
.
1
.205
C
826
ap
18a7
4
s
p
0
.932
<0.0
58
367.
459
22
600
0.20
4
<
0.15
4
1411
.266
n.a
.
<
1.35
6
C82
8
ap18
a77
py
3.8
90
1.
893
53
86.8
61
4655
00
7.5
02
1
4.88
2
2995
.928
146
.908
34
08.4
94
C82
8
ap18
a78
py
18.
310
0.
855
60
17.9
77
4655
00
4.6
41
1
2.69
3
624.
170
55.
035
38
53.4
43
C82
8
ap18
a79
py
3.0
56
0.
542
46
.268
4655
00
16.
738
4
.924
1061
.230
56.
990
82
7.07
4 C
828
ap
18a8
2
p
y
1
.942
0.15
1
7045
.173
46
5500
2
.398
12.
467
85
9.42
2
5
5.61
6
3888
.053
C
828
ap
18a8
0
s
p
0
.804
0.16
5
1152
.409
25
200
0.37
0
0
.294
6356
.134
n.a
.
9
.489
C
828
ap
18a8
1
s
p
1
.091
<0.0
49
1396
.642
25
200
<0.0
33
<0
.185
25
38.6
18
n
.a.
1.2
20
C83
0
jl04a
80
py
<7
.105
<
0.76
0
<
4.18
8
46
5500
2
0.13
1
<4.
704
<3
2.70
4
<
19.0
83
46.9
46
C83
0
jl04a
81
py
1.
023
<
0.07
5
<
0.44
2
46
5500
3
.342
<0.
510
7.
300
<1.7
38
62.
488
C83
0
jl04a
82
py
1.
122
<
0.07
2
0
.507
46
5500
0
.812
0.5
86
6.
191
12.6
13
47.
797
C83
0
jl04a
83
py
0.
898
<
0.09
1
<
0.54
7
46
5500
5
3.64
3
7.8
53
<3
.428
<
1.95
0
204.
282
C83
0
jl04a
84
sp
1.
021
<
0.10
6
9
98.6
92
223
00
<0
.249
<0.7
99
15.1
13
n.a
.
2
.994
C
830
jl0
4a85
sp
<1.5
63
<0.
174
102
3.02
5
2
2300
<0.4
38
<1
.158
29
.903
n
.a.
<4.
576
C
832
ap
18a8
5
p
y
1
.824
<0.0
58
<0.9
46
46
5500
<
0.05
4
0.2
52
6.
529
<1.4
23
2.7
15
C83
2
ap18
a86
py
2.2
56
<0
.069
<1
.239
4655
00
0.0
15
<
0.29
7
246.
664
<1.
184
4.
024
C83
2
ap18
a89
py
2.0
42
<0
.069
2.
747
465
500
0.
056
2.3
46
19
.233
2
203.
603
75.3
04
C83
2
jl11z
03
py
<1
.058
<
0.08
2
<
0.45
1
46
5500
0
.269
<0.
561
<2
.538
<
1.17
5
5.52
3 C
832
jl1
1z04
py
<0.9
70
<0.
080
2.6
04
4655
00
0.7
55
9
.433
481.
059
541
1.88
4
10
1.80
8 C
832
jl1
1z05
py
<1.1
32
<0.
098
<0.
595
4655
00
<0.
206
<
0.82
1
10.2
99
<1.
699
20
.346
C
832
ap
18a8
7
s
p
0
.914
<0.0
69
750.
095
15
800
<0.0
52
<0
.313
33
.678
n
.a.
<1.
609
C
832
ap
18a8
8
s
p
1
.182
0.20
1
731.
908
15
800
<0.0
38
0.
039
1
28.9
81
n.a.
2.
094
C83
3
ap18
a14
cpy
3.94
0
<0.
128
<2.
921
4655
00
0.3
77
<
0.54
0
n.a.
1
681.
896
33.0
61
C83
3
ap18
a10
py
4.7
41
<0
.043
1.
689
465
500
1.
831
<0.
256
7.
096
2.01
2
37
5.81
6 C
833
ap
18a1
3
p
y
3
.833
<0.0
67
13.2
72
46
5500
<
0.05
3
<0.
171
55
34.7
91
4
0.31
6
82.9
70
C83
4
ap10
a26
py
3.1
84
<0
.232
8.
217
465
500
0.
444
<0.
411
11
02.7
27
1
3.13
6
1291
.445
C
835
jl0
4a90
py
14.0
93
1.0
96
44.
077
4655
00
9.8
95
0
.906
31.4
80
172
41.3
76
182
.287
C
835
jl0
4a92
py
111.
868
<0.
386
8.4
78
4655
00
19.
351
<
3.24
8
155.
793
23.
036
36
54.7
55
C83
5
jl04a
93
py
28
.793
<
0.08
2
2
1.76
1
46
5500
1
1.26
0
<0.
682
<3
.995
1
3098
.701
1
06.6
36
C83
5
jl04a
94
sp
1.
030
<
0.11
9
1
757.
029
264
00
<0
.278
<0.9
51
14.5
05
n.a
.
<
2.94
3
C83
5
jl04a
95
sp
<1
.625
<
0.20
7
1
781.
256
264
00
<0
.450
<1.4
00
9.50
4
n.
a.
<5.1
11
C83
6
ap19
a12
py
40.
532
0.
180
5.
705
465
500
10
3.16
9
30.4
23
2.76
2
74
22.1
47
62
4.92
0 C
836
ap
19a1
3
p
y
2
5.87
9
0.16
1
6.52
6
4
6550
0
106.
007
20
.653
2.
182
8154
.345
479.
276
C83
6
ap19
a14
py
16.
105
0.
041
16
.910
4655
00
78.
442
1
0.41
0
4.50
9
25
601.
063
30
7.88
3
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
67
Appendix 5: LA-ICP-MS Analysis—Sulphides
C83
6
ap19
a15
py
3.7
92
0.
058
1.
597
465
500
60
.511
17.2
59
0.81
5
13
66.4
35
42
5.66
1 C
836
jl1
1z17
py
1.59
1
<0.
075
2.3
93
4655
00
74.
405
1
4.36
8
3.42
8
36
29.3
18
30
5.65
4 C
836
jl1
1z18
py
<0.8
26
<0.
079
55.
406
4655
00
53.
814
1
5.08
5
139.
889
540
9.45
8
87
7.57
9 C
836
jl1
1z19
py
365.
243
57.
744
27.
457
4655
00
5.8
79
2
0.99
3
<3.8
37
209
0.11
8
57
4.89
6 C
836
ap
19a1
6
s
p
1
.877
<0.0
79
518.
402
36
400
0.06
7
<
0.38
5
126.
014
n.a
.
<
1.38
5
C83
6
ap19
a17
sp
1.0
52
<0
.060
62
2.67
6
3640
0
0.
135
<0.
083
34
.908
n
.a.
<1.
056
C
838
ap
19a5
5
p
y
2
.054
0.53
7
2136
.325
46
5500
<
0.02
2
1.4
19
21
07.9
63
8
7.26
1
712.
092
C83
8
ap19
a56
py
2.1
54
0.
483
57
.188
4655
00
<0.
019
1
.054
1553
.640
24.
155
40
1.99
7 C
838
ap
19a5
7
p
y
2
.164
1.07
2
11.5
47
46
5500
<
0.03
4
1.0
04
71
4.64
3
9
.218
344.
600
C83
8
jl11a
85
py
15
.998
2
.148
9
4.07
3
46
5500
0
.833
6.0
24
20
11.4
61
5
330.
268
1883
.412
C
838
jl1
1a86
py
3.76
3
2.1
14
285
.556
4
6550
0
0.19
2
5
.399
203.
682
321
.996
95
5.52
2 C
838
jl1
1a87
py
0.75
5
<0.
056
<0.
508
4655
00
<0.
141
2
.783
<3.0
40
101
.517
44
9.03
6 C
838
ap
19a5
8
s
p
1
.548
<0.0
63
848.
856
31
600
0.20
4
1
.442
15.5
16
n.a
.
3
82.4
91
C83
8
ap19
a59
sp
1.3
18
<0
.067
95
5.08
2
3160
0
<0
.027
<0.1
11
15.2
86
n.a
.
<
2.62
5
C84
0
ap19
a20
cpy
2.30
0
<0.
118
<2.
245
3043
00
<0.
154
0
.551
n.a.
5
48.6
93
5.93
7 C
840
ap
19a2
1
c
py
3.
079
<
0.11
9
1
.706
30
4300
<
0.10
1
<0.
272
n.
a.
622
.883
5.
980
C84
0
ap19
a22
cpy
2.51
1
<0.
088
<1.
669
3043
00
0.0
68
<
0.30
9
n.a.
5
69.2
61
5.00
9 C
840
ap
19a2
3
s
p
1
.713
<0.0
99
1353
.287
37
600
4.01
3
<
0.25
6
99.1
44
n.a
.
<
1.38
5
C84
0
ap19
a24
sp
1.6
34
<0
.064
12
87.1
30
3760
0
3.
973
0.2
30
10
2.39
3
n
.a.
7.5
65
C84
1
ap19
a102
cpy
1.71
2
<0.
124
<2.
132
3043
00
<0.
094
<
0.54
2
n.a.
6
11.7
70
22.4
76
C84
1
ap19
a103
cpy
2.76
0
<0.
125
6.4
90
3043
00
<0.
096
<
0.25
4
n.a.
6
26.3
54
27.5
71
C84
1
ap19
a100
py
3.05
7
0.0
88
4.3
31
4655
00
0.4
33
0
.128
196.
702
<0.
757
40
67.8
38
C84
1
ap19
a101
py
30.7
48
0.1
01
2.0
49
4655
00
18.
137
2
.410
12.4
26
31.
270
81
0.04
5 C
841
ap
19a9
8
p
y
2
.553
<0.0
83
940.
757
46
5500
4
0.94
4
0.4
86
19
9.58
3
5
830.
985
195.
318
C84
1
ap19
a99
py
20.
692
0.
065
46
.022
4655
00
129
.526
7
.989
8.60
2
16
543.
696
58
6.77
2 C
841
ap
19a1
06
sp
1.
068
<
0.06
4
2
497.
895
338
00
<0
.048
<0.1
58
64.0
46
n.a
.
<
1.96
7
C84
1
ap19
a107
sp
1.40
9
<0.
074
229
3.26
6
3
3800
<0.0
35
<0
.198
63
.546
n
.a.
<1.
876
C
841
ap
19a1
12
sp
0.
844
<
0.05
0
2
452.
907
338
00
<0
.041
<0.2
06
89.1
87
n.a
.
<
1.71
6
C84
1
ap19
a113
sp
1.03
0
<0.
040
239
4.21
3
3
3800
<0.0
60
<0
.148
97
.024
n
.a.
<2.
365
C
842
ap
19a6
2
p
y
4
.752
0.07
1
14.7
09
46
5500
0
.883
0.2
73
50
4.62
3
1
215.
315
1696
0.72
4 C
842
ap
19a6
3
p
y
2
.137
<0.0
75
26.9
62
46
5500
<
0.03
1
<0.
204
16
7.66
8
1
92.2
99
108.
843
C84
2
ap19
a64
py
13.
775
0.
080
6.
607
465
500
0.
456
0.1
32
95
.909
6
.277
4400
.903
C
842
jl1
1a79
py
33.3
27
0.0
88
0.6
34
4655
00
2.7
08
0
.802
29.3
89
<1.
146
41
7.56
0 C
842
jl1
1a80
py
211.
718
0.6
74
35.
619
4655
00
3.1
60
<
0.57
1
89.2
31
805
.392
12
39.4
22
C84
2
jl11a
81
py
<0
.723
<
0.05
9
4
.359
46
5500
<
0.13
1
<0.
499
29
4.03
1
6
.645
2518
.152
C
842
ap
19a6
5
s
p
1
.290
<0.0
73
2003
.851
11
100
<0.0
27
<0
.151
32
0.50
8
n
.a.
8.0
52
C84
2
ap19
a66
sp
2.7
14
<0
.064
17
39.4
72
1110
0
<0
.078
<0.3
30
1118
.502
n.a
.
6
.307
C
844
ap
10a0
9
s
p
1
.075
<0.1
81
1127
.125
20
600
<0.0
69
<0
.469
69
.225
n
.a.
26.
276
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
68
Appendix 5: LA-ICP-MS Analysis—Sulphides
C84
4
ap10
a10
sp
0.7
94
<0
.073
10
86.8
34
2060
0
<0
.043
<0.4
49
272.
781
n.a
.
1
3.54
3 C
844
ap
10a1
1
s
p
<
1.74
8
<0.5
29
1004
.346
20
600
<0.1
54
0.
562
5
1.63
7
n.a
.
2
3.96
8 C
846
ap
19a4
0
p
o
2
.468
<0.1
30
<2.9
05
62
3300
<
0.12
0
14.
238
<1
.456
<
2.35
7
94.9
77
C84
6
ap19
a41
po
2.7
17
<0
.176
61
2.98
4
6233
00
<0.
083
1
1.61
2
<1.1
23
<2.
653
95
.555
C
846
ap
19a4
2
p
o
2
.364
<0.1
73
26.1
75
62
3300
<
0.07
2
12.
121
<1
.600
<
2.18
1
83.4
46
C84
6
ap19
a37
py
2.5
10
<0
.057
3.
529
465
500
19
09.8
38
2
.106
369.
112
0.7
80
54
.462
C
846
ap
19a3
8
p
y
3
.620
<0.0
63
5.24
6
4
6550
0
552.
599
65
.479
43
3.86
3
7
76.8
36
295.
989
C84
6
ap19
a39
py
3.1
65
<0
.042
1.
153
465
500
21
17.4
62
1
2.27
5
0.68
6
0.
581
816.
860
C84
6
jl11a
62
py
<0
.780
<
0.05
4
8
.833
46
5500
5
16.1
22
16.
510
3.
451
1.19
7
11
8.06
5 C
846
jl1
1a63
py
64.7
23
0.3
91
122
8.59
0
4
6550
0
446.
265
10
3.25
4
7.
495
17.7
42
343
.677
C
846
jl1
1a64
py
1.50
5
<0.
069
28.
877
4655
00
194
9.30
3
2
6.63
2
170.
756
303
2.28
8
59
5.78
9 C
848
jl1
1a10
po
<4.0
26
<0.
472
<3.
340
6233
00
<0.
915
<
3.88
2
<15.
513
<5.
405
<7
.210
C
848
jl1
1a11
po
<2.9
78
<0.
388
<2.
266
6233
00
<0.
704
<
2.85
1
<13.
981
<5.
584
<6
.372
C
848
jl1
1a03
py
<3.1
58
<0.
223
55.
135
4655
00
78.
712
4
4.91
8
<7.7
80
17.
566
72
.903
C
848
jl1
1a04
py
<0.9
41
<0.
111
118
.656
4
6550
0
13.2
33
24
.758
<3
.140
<
1.30
1
202.
367
C84
8
jl11a
05
py
<1
.090
0
.108
9
74.4
73
465
500
31
.324
23.1
72
264.
731
216
.323
11
341.
879
C84
8
jl11a
06
py
<1
.030
<
0.13
9
1
40.7
07
465
500
59
.403
61.5
52
<3.3
49
4.5
19
18
0.45
5 C
848
jl1
1a07
py
<1.2
39
<0.
091
91.
189
4655
00
55.
223
4
5.00
3
<4.0
76
23.
001
14
3.61
7 C
849
jl1
1a14
py
92.6
21
0.7
52
2.2
54
4655
00
18.
988
6
3.37
9
<8.5
42
<3.
035
23
27.7
20
C84
9
jl11a
15
py
<3
.623
<
0.36
0
<
1.85
7
46
5500
1
746.
074
64.
480
<1
2.64
3
<
4.70
6
2562
.713
C
849
jl1
1a16
py
<1.5
81
<0.
151
5.4
08
4655
00
559
4.16
9
4
42.5
56
4
6.98
1
10.
451
11
05.2
86
C84
9
jl11a
17
py
29
.664
1
.919
3
.162
46
5500
5
9.76
9
96.
235
8.
326
2.94
0
20
84.9
98
R00
1
ap17
c13
py
<3.
364
<0
.331
30
.941
4655
00
2.2
71
<
0.76
0
240.
749
124
.259
24
7.51
9 R
001
ap
17c1
5
p
y
<
1.33
9
<0.1
12
48.0
87
46
5500
1
.721
<0.
250
15
3.51
5
1
1.25
0
275.
767
R00
1
ap17
c16
py
<1.
746
<0
.143
31
.747
4655
00
52.
207
<
0.41
0
10.2
96
<3.
402
27
42.6
96
R00
1
ap17
d16
py
<2.
446
<0
.219
5.
301
465
500
7.
897
<0.
485
11
3.02
7
1
2.17
1
931.
368
R00
1
ap17
d17
py
<0.
869
<0
.098
16
.563
4655
00
69.
193
0
.375
23.0
66
1.9
06
22
.574
R
001
ap
17c1
7
s
p
<
4.79
9
<0.6
51
1970
.782
54
900
<0.5
01
<1
.088
30
3.71
3
n
.a.
<2.
835
R
001
ap
17c1
8
s
p
<
3.63
4
<0.4
65
1890
.417
54
900
<0.3
77
<1
.190
29
3.24
3
n
.a.
<3.
115
R
003
ap
06g1
1
p
y
<
2.39
1
<0.2
01
15.9
67
46
5500
1
.708
<0.
464
2.
141
<2.4
66
4.1
07
R00
3
ap06
g13
py
<1.
129
<0
.142
17
18.2
96
4655
00
6.2
35
<
0.33
3
84.6
48
208
7.70
5
16
1.09
8 R
003
ap
06g1
6
p
y
<
2.38
9
<0.3
38
<5.4
48
46
5500
0
.862
<0.
655
<3
.157
<
4.69
1
13.9
36
R00
3
ap06
g17
py
<2.
613
<0
.257
19
.953
4655
00
1.5
61
0
.898
4.88
3
<4
.177
3
1.91
9 R
003
ap
06g1
8
p
y
1
5.52
5
<0.2
44
46.5
65
46
5500
1
.569
<0.
634
3.
411
<3.2
76
21.
806
R00
3
ap06
g12
sp
<6.
150
<0
.508
12
08.4
23
5110
0
<0
.581
<1.1
85
129.
668
n.a
.
<
4.91
8
R00
3
ap06
g14
sp
<4.
195
<0
.574
19
28.6
05
5110
0
<0
.642
<1.6
66
39.6
41
n.a
.
<
3.82
3
R00
3
ap06
g15
sp
<5.
570
<0
.528
20
39.1
27
5110
0
<0
.547
<1.7
10
45.7
16
n.a
.
<
4.33
5
R04
9
ap18
a20
cpy
2.04
0
<0.
120
<1.
807
3043
00
<0.
044
<
0.60
2
n.a.
7
00.5
09
8.14
2
sam
ple
ru
n/po
int
t
ype
Ti
(ppm
)
V (p
pm)
Mn
(ppm
)
Fe
(ppm
)
Co
(ppm
)
Ni (
ppm
)
C
u (p
pm)
Z
n (p
pm)
A
s (p
pm)
69
Appendix 5: LA-ICP-MS Analysis—Sulphides
R04
9
ap18
a25
cpy
2.18
4
<0.
149
2.3
17
3043
00
<0.
089
1
.284
n.a.
6
08.8
50
9.87
6 R
049
ap
18a1
9
p
y
3
2.57
0
1.98
4
385.
279
46
5500
1
.342
0.3
26
43
9.49
0
1
60.2
33
7110
.803
R
049
ap
18a2
6
p
y
3
.003
<0.0
42
3.37
2
4
6550
0
75.7
19
30
.344
8.
226
5979
.751
234.
728
R04
9
ap18
a27
sp
3.9
05
<0
.081
52
9.33
1
1490
0
3.
936
<0.
168
25
22.4
49
n
.a.
3.0
42
R07
0
ap19
a30
apy
1.93
0
<0.
077
8.6
23
3430
00
109
.008
5
.194
4.34
9
11
.194
n
.a.
R07
0
jl11z
20
ap
y
<0
.632
<
0.06
6
<
0.38
2
34
3000
<
0.10
7
<0.
464
7.
141
1.31
2
n.
a.
R07
0
ap19
a29
cpy
2.24
0
<0.
127
1.8
96
3043
00
<0.
083
<
0.36
1
n.a.
1
4183
.285
6
.685
R
070
ap
19a3
4
c
py
2.
402
<
0.11
0
7
.953
30
4300
<
0.04
5
0.2
30
n.
a.
851
8.31
6
15
2.10
2 R
070
ap
19a3
1
p
y
3
.069
<0.0
64
13.4
20
46
5500
4
.422
0.4
17
49
8.13
0
1
0228
.437
1
242.
678
R07
0
ap19
a32
py
3.4
76
0.
075
47
.034
4655
00
0.1
30
3
.946
2408
.632
769
3.18
4
35
6.37
6 R
070
ap
19a3
3
p
y
2
.871
<0.0
31
1.91
0
4
6550
0
7.63
4
1
32.9
73
1
973.
489
5151
.527
206.
722
R07
0
jl11z
21
py
0.
675
<
0.07
7
8
.593
46
5500
2
.689
3.8
76
15
41.8
73
7
058.
126
736.
801
R07
0
jl11z
22
py
<0
.764
<
0.08
4
1
.952
46
5500
0
.928
12.
890
71
9.68
1
3
286.
965
457.
258
R07
0
ap19
a25
sp
1.0
78
<0
.041
57
2.47
5
7290
0
0.
128
0.0
48
28
52.3
57
n
.a.
<0.
936
R
070
ap
19a2
6
s
p
1
.061
<0.0
39
626.
111
72
900
0.69
0
<
0.13
8
8390
.341
n.a
.
<
0.89
9
R07
5
jl11a
25
cp
y
<1
.963
<
0.17
0
3
.087
30
4300
<
0.34
0
<1.
271
n.
a.
785
.590
8.
444
R07
5
jl11a
23
py
1.
156
0
.155
0
.553
46
5500
1
23.9
69
<0.
526
12
57.9
23
4
67.8
56
2371
3.64
6 R
075
jl1
1a24
py
<1.3
43
<0.
115
<0.
666
4655
00
17.
542
1
1.41
6
41.5
86
6.7
43
11
41.3
06
R07
5
jl11a
26
py
<0
.904
<
0.09
6
<
0.65
8
46
5500
7
4.53
4
61.
058
73
4.39
8
3
06.4
09
211.
585
R07
5
jl11a
27
py
<0
.981
<
0.08
8
0
.970
46
5500
<
0.22
8
<0.
749
48
1.40
3
2
32.9
84
331.
662
R07
5
jl11a
28
py
<0
.896
<
0.09
6
0
.594
46
5500
8
.231
<0.
670
15
2.64
9
1
296.
579
685.
780
R07
8
jl04a
72
py
17
.450
0
.246
1
0.65
7
46
5500
6
9.05
2
629
.810
46.
830
3
6.24
5
2448
.075
R
078
jl0
4a73
py
2.28
8
<0.
079
11.
949
4655
00
48.
461
4
29.9
41
8
3.52
1
24.
164
31
83.3
18
R07
8
jl04a
76
sp
<3
.942
<
0.44
5
3
52.8
70
576
00
<1
.226
<2.4
70
61.3
02
n.a
.
<
9.55
1
R07
8
jl04a
77
sp
2.
541
<
0.13
1
2
67.3
77
576
00
0.
921
<0.
950
91
1.50
2
n
.a.
123
.549
sa
mpl
e
run/
poin
t
typ
e
Ti (p
pm)
V
(ppm
)
M
n (p
pm)
F
e (p
pm)
C
o (p
pm)
N
i (pp
m)
Cu
(ppm
)
Zn
(ppm
)
As
(ppm
)
70
Appendix 5: LA-ICP-MS Analysis—Sulphides
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
C07
9
ap19
a03
py
3.7
76
0.70
4
n.
a.
1.4
44
1
.907
0.26
9
3.
468
1
2.34
8
0.3
73
38
.2
C07
9
ap19
a04
py
3.8
52
0.86
6
n.
a.
0.3
05
6
.983
0.15
7
0.
157
3
2.01
7
0.1
97
33
.0
C07
9
ap19
a05
py
3.2
47
4.56
3
n.
a.
<0.
140
7
8.97
3
1.49
2
54
6.66
1
14
5.27
2
0.22
6
19.
1 C
079
ap
19a0
8
p
y
3
0.41
0
1.
938
n.a.
0
.246
16.
473
0.
697
0.59
6
157
.598
0.
768
2
6.0
C07
9
jl04a
55
py
<2
.208
<0.2
29
<14
.985
0.
609
<0.3
26
<0.
156
<
0.17
6
<0.5
03
<0
.051
21
.1
C07
9
jl04a
58
py
28
.217
0.25
3
17
.133
1
.081
0.8
82
<0
.126
6
.729
11.3
69
0.
115
4
3.2
C07
9
jl04a
59
py
5.
693
0.3
54
<
17.1
93
0.95
0
2.
357
<0.2
16
<0.
194
4.
365
<0.0
79
55.9
C
079
ap
19a0
6
s
p
4
5.53
3
15
.990
n
.a.
2.2
35
1
6.29
8
0.08
9
0.
264
3
04.6
72
0.08
5
50.
3 C
079
ap
19a0
7
s
p
1
3.72
3
8.
798
n.a.
1
.029
1.7
30
<0
.070
<
0.05
7
2.73
9
<0
.014
50
.3
C07
9
jl04a
60
sp
<7
.296
9.67
1
19
73.5
84
1
.971
2.4
58
<0
.504
<
0.36
9
7.43
3
<0
.137
69
.6
C07
9
jl04a
61
sp
12
3.11
5
15.5
23
201
0.46
5
2.
887
14.7
63
<0.
174
0
.304
23.2
82
<0
.052
67
.4
C08
2
ap18
a28
cpy
<0.4
72
26
.846
n
.a.
12.
540
2
1.29
4
<0.1
59
1.1
38
15
3.59
4
3.44
6
22.
5 C
082
ap
18a2
9
p
y
<
0.21
2
0.
156
n.a.
<
0.21
4
<0.
296
<0
.090
<
0.14
7
4.26
2
1.
447
4
8.6
C08
2
ap18
a30
py
<0.
256
0.14
0
n.
a.
<0.
392
0
.879
<0.1
65
<0.
234
6.
024
113.
506
34.
7 C
082
jl1
1a41
py
54.9
76
<0
.492
<
22.7
72
1.13
9
4.
366
<0.3
19
<0.
303
13
.177
18.5
80
67.
4 C
082
jl1
1a42
py
<5.8
59
<0
.462
<
19.3
75
1.16
3
<0
.517
<
0.18
9
<0.
234
37
.123
2.50
0
62.
6 C
082
jl1
1a43
py
<2.4
80
<0
.232
<
8.88
2
1.1
47
<
0.24
9
<0.1
74
<0.
107
2.
731
7.03
0
64.
3 C
082
jl1
1a44
py
<3.5
72
<0
.268
<
10.2
74
1.38
3
<0
.281
<
0.13
4
<0.
110
0.
872
2.04
8
63.
9 C
211
ap
03c0
3
s
p
<
1.49
5
20
.375
n
.a.
1.4
85
<
0.14
7
<0.1
11
<0.
067
<0
.101
<0.0
32
33.6
C
211
ap
03c0
4
s
p
<
1.34
8
30
.692
n
.a.
3.0
87
<
0.28
6
<0.1
74
<0.
087
<0
.167
<0.0
38
36.6
C
211
ap
03c0
5
s
p
<
2.17
7
21
.434
n
.a.
3.1
64
<
0.33
3
<0.2
13
<0.
152
<0
.185
<0.0
60
31.6
C
211
ap
03c0
6
s
p
<
1.50
7
41
.408
n
.a.
2.6
56
0
.361
<0.2
10
<0.
079
2.
654
0.67
1
41.
5 C
261
ap
10d0
5
a
py
68
.710
18.3
28
n.a
.
<
1.09
6
109
2.48
1
25
.619
88.8
43
2977
.807
<0.
184
38
.6
C26
1
ap10
d04
py
216
.109
1
00.9
23
n.a
.
0
.305
124
4.10
5
3.
222
1087
.664
1687
4.19
6
0.3
28
42
.5
C26
1
ap10
d06
py
68.
133
21.0
68
n.a
.
0
.311
85.
338
1.
178
45.1
31
4237
.070
0.0
68
39
.5
C26
1
ap10
d07
py
27.
763
201.
472
n.a
.
0
.336
523
.050
1.
005
38.1
17
9428
.101
0.1
02
37
.6
C26
1
ap10
d08
py
73.
255
25.6
93
n.a
.
<
0.30
1
98.
041
0.
966
37.8
72
9133
.873
0.0
88
36
.6
C26
1
jl11a
18
py
74
.150
20.8
84
<12
.234
1.
293
107.
202
1.0
67
5
1.81
1
7249
.488
<0.
095
48
.9
C26
1
jl11a
19
py
13
0.16
1
23.9
44
<19
.488
1.
246
99.9
02
0.7
68
3
2.52
3
1268
8.92
7
0.1
17
49
.3
C26
1
jl11a
20
py
38
.468
413.
781
15.
118
1
.373
137
5.28
5
0.
523
14.2
90
1075
5.66
9
0.1
11
51
.1
C27
8
ap03
e11
py
<2.
496
14.5
09
n.a
.
<
0.59
7
23.
715
10
.301
0.53
9
118
4.70
8
12
4.85
5
4
1.5
C27
8
ap03
e13
py
<1.
578
0.22
0
n.
a.
<0.
436
0
.367
<0.1
27
<0.
115
9.
166
2.02
3
25.
7 C
278
ap
03e1
5
p
y
<
3.91
8
<0
.517
n
.a.
<0.
764
0
.544
<0.4
83
<0.
280
9.
964
4.70
3
42.
5 C
278
ap
03e1
6
p
y
<
4.63
9
1.
222
n.a.
<
0.74
8
2.7
68
<0
.352
<
0.29
3
26.1
28
15
.589
4
4.5
C27
8
ap03
e12
sp
<4.
940
4.74
8
n.
a.
1.9
10
<
0.63
1
<0.4
28
<0.
390
1.
047
0.31
9
23.
7 C
278
ap
03e1
4
s
p
<
5.59
7
19
.269
n
.a.
2.0
28
1
5.36
2
<0.5
13
<0.
544
13
.225
7.58
6
38.
6 C
278
ap
03e1
8
s
p
<
6.81
6
15
.341
n
.a.
1.9
02
8
.276
<0.3
99
<0.
441
22
.417
12.8
88
42.
5
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
71
Appendix 5: LA-ICP-MS Analysis—Sulphides
C28
0
ap03
e03
py
<3.
579
<0.3
35
n.a
.
<
0.71
8
<0.
590
<0
.281
<
0.32
3
<0.3
82
<0
.086
33
.6
C28
0
ap03
e05
py
<4.
895
<0.4
78
n.a
.
<
0.81
6
<0.
517
<0
.328
<
0.28
7
0.51
9
0.
192
4
2.5
C28
0
ap03
e06
py
<3.
992
24.6
52
n.a
.
<
0.58
4
108
.306
6.
705
0.50
3
173
4.63
9
71
.477
3
9.5
C28
0
ap03
e07
py
<4.
448
2.73
3
n.
a.
<1.
707
3
.615
<0.3
17
<0.
262
19
2.82
3
18.3
12
32.
6 C
280
ap
03e1
0
p
y
7
.461
9.
383
n.a.
<
0.88
3
36.
006
27
.253
0.78
0
910
.048
21
.605
3
9.5
C28
0
ap03
e04
sp
<6.
558
1.20
4
n.
a.
<1.
521
<
0.98
3
<0.8
97
<0.
503
<0
.670
<0.1
81
35.6
C
280
ap
03e0
8
s
p
<
8.64
1
1.
316
n.a.
2
.071
<1.
157
<0
.616
<
0.63
9
1.83
3
<0
.160
35
.6
C28
0
ap03
e09
sp
<6.
417
1.97
9
n.
a.
1.1
08
<
0.91
6
<0.5
07
<0.
423
4.
502
0.44
5
30.
6 C
284
ap
06b0
5
c
py
<3
.764
111.
605
n.a
.
1
4.87
2
17.
648
<0
.267
0
.246
8.75
2
0.
618
3
3.6
C28
4
ap06
b03
py
<3.
834
<0.4
60
n.a
.
<
0.59
7
<0.
811
<0
.326
<
0.24
0
<0.3
12
<0
.057
45
.5
C28
4
ap06
b06
py
2.3
53
2.13
8
n.
a.
0.2
82
3
.239
0.15
1
<0
.064
10
9.33
5
3.33
1
43.
5 C
284
ap
06b0
8
p
y
<
4.38
2
1.
691
n.a.
<
0.57
6
4.1
28
0.
372
<0.2
00
46.8
30
2.
115
4
0.5
C28
4
ap06
b09
py
<4.
096
1.70
7
n.
a.
<0.
724
5
.617
<0.3
33
<0.
260
7.
862
0.58
8
24.
7 C
284
ap
06b1
0
p
y
5
.431
<0
.675
n
.a.
<0.
834
1
.300
<0.3
63
1.4
84
2.
321
0.38
7
20.
8 C
284
ap
06b0
4
s
p
<
5.16
6
21
.690
n
.a.
1.9
99
1
0.69
4
<0.4
01
<0.
484
13
.250
0.43
0
34.
6 C
284
ap
06b0
7
s
p
<
5.96
6
16
.384
n
.a.
1.2
60
4
.758
<0.3
05
<0.
340
8.
100
0.22
2
41.
5 C
284
ap
06b1
1
s
p
<
6.73
0
36
.236
n
.a.
1.8
14
2
4.05
5
<0.3
28
<0.
383
70
0.32
4
4.87
1
43.
5 C
285
ap
03c0
7
p
y
<
1.39
4
0.
254
n.a.
0
.251
13.
845
1.
498
<0.0
62
62.2
55
1.
200
4
3.5
C28
5
ap03
c10
py
<4.
958
<0.4
76
n.a
.
<
0.86
4
3.3
46
<0
.428
<
0.29
4
28.0
53
4.
221
4
4.5
C28
5
ap03
c13
py
<1.
634
0.35
2
n.
a.
0.4
11
3
.055
<0.1
31
<0.
084
10
5.75
2
31.1
12
42.
5 C
285
ap
03c1
4
p
y
<
1.38
7
0.
563
n.a.
0
.266
1.3
37
<0
.108
<
0.07
7
10.4
67
0.
068
2
4.7
C28
5
ap03
c17
py
<4.
070
<0.4
80
n.a
.
<
1.89
2
<0.
507
<0
.419
<
0.31
2
<0.2
85
0.
190
3
1.6
C28
5
ap03
c18
py
<1.
150
<0.1
11
n.a
.
<
0.29
5
<0.
255
<0
.096
<
0.10
7
4.39
7
0.
919
3
9.5
C28
5
ap03
c08
sp
<5.
194
3.53
9
n.
a.
1.1
82
2
.893
<0.4
94
<0.
329
3.
978
2.72
9
41.
5 C
285
ap
03c0
9
s
p
<
5.30
1
3.
013
n.a.
<
1.95
1
4.0
37
<0
.388
<
0.41
1
4.15
4
3.
999
4
2.5
C28
5
ap03
c11
sp
<6.
368
5.54
5
n.
a.
1.4
86
6
.429
<0.5
36
<0.
327
23
.399
13.2
17
38.
6 C
285
ap
03c1
2
s
p
<
5.40
9
2.
309
n.a.
1
.465
0.8
87
<0
.527
<
0.31
4
11.1
47
1.
938
3
9.5
C28
5
ap03
c15
sp
<5.
032
3.13
7
n.
a.
1.3
66
2
.407
<0.5
13
<0.
268
5.
927
4.12
0
45.
5 C
285
ap
03c1
6
s
p
<
4.92
6
1.
509
n.a.
1
.247
<1.
081
<0
.502
<
0.37
8
1.50
3
0.
170
4
3.5
C28
7
ap17
b03
py
31.
202
25.9
52
n.a
.
<
0.32
3
100
.962
1.
340
0.82
6
150
6.87
6
0.
120
1
0.9
C28
7
ap17
b05
py
<3.
755
0.19
4
n.
a.
<0.
297
0
.727
<0.0
91
<0.
054
91
.553
<0.0
28
33.6
C
287
ap
17b0
7
p
y
<
6.41
9
0.
878
n.a.
<
0.61
7
5.1
71
0.
446
<0.1
23
187.
253
<0
.042
42
.5
C28
7
ap17
b09
py
<7.
681
47.5
65
n.a
.
<
1.23
2
777
.345
1.
117
1.14
9
79.
193
<
0.07
2
12.9
C
287
ap
17b0
4
s
p
<
11.1
13
4.5
23
n
.a.
0.9
48
1
.521
<0.2
79
<0.
154
4.
261
<0.0
84
34.6
C
287
ap
17b0
8
s
p
<
17.4
81
26.
992
n
.a.
1.1
67
3
0.19
3
<0.4
66
0.1
83
19
.682
<0.1
21
12.9
C
290
ap
10f0
8
cpy
<4.6
88
31
.798
n
.a.
24.
574
1
1.13
7
<0.2
76
0.2
58
6.
426
<0.0
74
45.5
C
290
ap
10f0
3
py
<5.1
62
<0
.471
n
.a.
<0.
461
<
0.64
7
<0.3
12
<0.
156
0.
742
<0.0
95
33.6
C
290
ap
10f0
7
py
<4.9
86
<0
.400
n
.a.
<0.
394
<
0.82
5
<0.2
73
<0.
139
3.
060
<0.0
75
35.6
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
72
Appendix 5: LA-ICP-MS Analysis—Sulphides
C29
0
ap10
f09
py
<2
.012
27.7
21
n.a
.
0
.391
21.
446
5.
249
328.
884
2032
.855
2.3
96
31
.6
C29
0
ap10
f11
py
<2
.990
0.62
6
n.
a.
<0.
461
0
.996
0.37
9
<0
.159
26
.322
2.43
1
23.
7 C
290
ap
10f1
2
py
<3.6
60
11
.129
n
.a.
<0.
570
1
7.22
7
3.35
2
0.
372
8
87.0
56
0.95
1
22.
7 C
290
ap
10f1
3
py
<3.5
09
<0
.459
n
.a.
<0.
579
<
0.60
2
<0.2
96
<0.
135
<0
.363
<0.1
00
42.5
C
290
ap
10f0
4
sp
<5.8
73
3.
965
n.a.
1
.322
<0.
889
<0
.551
<
0.31
7
0.98
7
<0
.090
40
.5
C29
0
ap10
f05
sp
<9
.133
7.11
6
n.
a.
1.4
25
<
1.22
8
<0.5
58
<0.
267
27
.709
<0.1
20
38.6
C
290
ap
10f1
0
tet
<7.7
43
n.
a.
n.a
.
0
.968
n.a
.
<
0.48
6
<0.
321
0.
859
38.8
95
21.
7 C
292
ap
06g0
3
c
py
<4
.578
19.3
34
n.a
.
9
.432
4.5
53
<0
.254
<
0.21
0
1.98
1
1.
867
4
4.5
C29
2
ap06
g04
py
<2.
467
<0.2
53
n.a
.
<
0.29
9
<0.
260
<0
.161
<
0.07
9
1.92
7
1.
144
4
3.5
C29
2
ap06
g05
py
<1.
445
<0.2
38
n.a
.
0
.351
<0.
191
<0
.089
<
0.07
1
0.13
2
0.
048
4
5.5
C29
2
ap06
g06
py
<1.
773
<0.2
07
n.a
.
0
.282
<0.
328
<0
.095
<
0.07
3
2.53
7
2.
895
4
4.5
C29
2
ap06
g07
py
<1.
325
0.21
6
n.
a.
0.3
34
0
.505
<0.0
71
<0.
086
6.
162
4.33
7
42.
5 C
292
ap
06g0
8
p
y
<
1.34
6
<0
.230
n
.a.
<0.
223
0
.380
<0.1
02
<0.
080
1.
036
0.66
8
36.
6 C
292
ap
06g1
0
p
y
<
1.83
7
<0
.209
n
.a.
0.3
37
<
0.29
7
<0.1
33
<0.
054
10
.648
2.07
5
29.
7 C
297
ap
10a0
5
a
py
32
.698
<0.8
77
n.a
.
1
.363
630
.896
<0
.540
<
0.29
7
38.9
71
0.
228
4
3.5
C29
7
ap10
a06
cpy
<6.6
65
14
0.05
4
n
.a.
7.8
54
4
.918
<0.1
85
<0.
155
2.
424
<0.0
76
38.6
C
297
ap
10a1
7
c
py
<7
.700
168.
080
n.a
.
8
.700
3.9
01
<0
.283
<
0.16
9
1.98
7
<0
.048
39
.5
C29
7
ap10
a03
py
<1.
604
58.1
64
n.a
.
0
.175
56.
536
48
.111
0.13
6
404
.673
0.
151
4
4.5
C29
7
ap10
a04
py
<1.
909
2.29
2
n.
a.
<0.
167
9
9.34
5
2.11
6
<0
.044
71
6.44
4
<0.0
25
40.5
C
297
ap
10a0
7
p
y
<
3.77
3
1.
468
n.a.
<
0.31
9
34.
407
1.
768
0.48
7
561
.959
2.
016
3
5.6
C29
7
ap10
a09
py
<4.
226
2.18
7
n.
a.
0.3
15
2
2.57
6
1.90
6
<0
.110
28
0.68
0
<0.0
44
39.5
C
297
ap
10a1
1
p
y
<
2.12
1
1.
250
n.a.
<
0.24
7
45.
006
0.
230
<0.0
81
375.
715
0.
138
4
1.5
C29
7
ap10
a13
py
<2.
723
2.42
4
n.
a.
0.1
81
1
00.5
11
1.32
4
<0
.069
73
1.01
2
0.04
0
37.
6 C
297
ap
10a1
5
p
y
<
2.99
5
2.
580
n.a.
0
.259
26.
059
0.
860
0.08
8
819
.988
1.
238
3
9.5
C29
7
ap10
a16
py
<2.
631
3.79
6
n.
a.
0.2
49
8
8.17
1
2.45
0
<0
.049
11
94.5
53
0
.254
40.5
C
297
ap
10a1
0
s
p
<
9.15
0
2.
113
n.a.
0
.905
1.7
13
<0
.329
<
0.21
4
1.96
7
<0
.074
36
.6
C29
7
ap10
a12
sp
<9.
061
9.28
8
n.
a.
0.9
03
1
2.97
6
<0.4
83
<0.
217
6.
949
<0.0
94
39.5
C
297
ap
10a1
4
s
p
<
10.1
64
2.0
44
n
.a.
1.0
23
<
0.85
0
<0.4
11
<0.
226
1.
314
<0.0
95
33.6
C
299
ap
17c0
8
p
y
<
7.56
2
<0
.520
n
.a.
<0.
785
<
0.73
1
<0.1
69
<0.
157
1.
166
<0.0
62
44.5
C
299
ap
17c1
0
p
y
<
9.52
8
2.
574
n.a.
5
.278
17.
462
2.
353
1.62
3
132
.493
9.
088
4
4.5
C29
9
ap17
c11
py
27.
472
4.01
9
n.
a.
<0.
810
2
0.15
5
1.61
5
<0
.133
26
7.41
8
18.6
56
26.
7 C
299
ap
17c0
4
s
p
<
8.41
8
3.
455
n.a.
1
.443
3.9
18
<0
.276
<
0.12
8
3.54
3
<0
.075
41
.5
C29
9
ap17
c06
sp
<10
.286
9
.434
n.a
.
1
.971
45.
085
<0
.305
<
0.16
5
11.8
92
0.
123
2
2.7
C29
9
ap17
c03
tet
<2
.958
n.a.
n
.a.
0.6
16
n
.a.
<0.
085
<
0.06
1
0.20
6
11
3.31
8
4
2.5
C29
9
ap17
c05
tet
<3
.388
n.a.
n
.a.
0.6
34
n
.a.
<0.
077
<
0.06
3
0.24
8
11
4.22
1
4
0.5
C29
9
ap17
c07
tet
<1
3.56
5
n.a.
n
.a.
<1.
406
n
.a.
<0.
365
<
0.19
0
3.40
3
91
.238
1
9.8
C30
1
ap03
d14
py
<0.
994
6.85
8
n.
a.
<0.
249
3
8.23
8
31.9
68
<0
.072
44
5.39
3
0.02
4
30.
6 C
301
ap
03d1
5
p
y
1
.985
33
.111
n
.a.
0.6
97
1
01.0
82
5.70
4
<0
.079
25
46.2
80
0
.379
39.5
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
73
Appendix 5: LA-ICP-MS Analysis—Sulphides
C30
1
ap03
d17
py
<5.
151
1.35
0
n.
a.
<0.
942
11
.263
25.9
40
<0
.325
78
.467
<0.0
72
35.
6 C
301
ap
03d1
8
p
y
<
1.06
3
17
.161
n.a.
0
.312
92.6
09
17
.157
0.08
5
175
7.84
6
0.
031
39.5
C
301
ap
03d1
0
s
p
<
1.29
3
65
.163
n.a.
0
.680
3.37
7
43
.983
<0.0
71
2.96
2
<0
.024
4
0.5
C30
1
ap03
d16
sp
<7.
453
19.3
87
n.
a.
1.5
56
6.
294
<0.7
41
<0
.637
13
.493
<0.1
92
39.
5 C
306
ap
06e1
1
p
y
<
4.31
9
3.
610
n.a.
<
0.52
2
8.05
6
<0
.235
<0.1
46
80.9
34
<0
.052
1
8.8
C30
6
ap06
e16
py
<6.
128
0.68
5
n.
a.
<0.
665
5.
293
<0.2
16
<0
.226
12
.287
<0.0
55
28.
7 C
306
ap
06e1
2
s
p
<
6.75
4
13
.214
n.a.
1
.597
7.80
2
<0
.296
<0.2
65
99.9
28
<0
.098
4
5.5
C30
6
ap06
e13
sp
<8.
552
10.2
62
n.
a.
1.5
17
5.
494
<0.3
94
<0
.224
7.
672
<0.0
57
27.
7 C
306
ap
06e1
5
s
p
<
9.22
6
10
.917
n.a.
1
.642
4.67
8
<0
.339
<0.2
82
9.85
9
<0
.081
1
6.8
C30
6
ap06
e18
sp
<5.
308
21.3
95
n.
a.
1.3
49
18
.024
<0.3
62
0.
243
2
290.
869
<0.0
64
41.
5 C
307
ap
02a0
4
p
y
<
1.15
9
58
1.39
1
n.a.
0
.355
1165
.976
0.2
39
0
.207
1947
.808
3.4
73
21
.7
C30
7
ap02
a05
py
<1.
595
9.39
7
n.
a.
0.4
99
19
.515
0.10
5
0.
402
5
87.4
65
0.35
0
21
.7
C30
7
ap02
a06
py
<4.
515
1.09
3
n.
a.
<0.
729
4.
398
<0.2
30
<0
.232
12
5.57
1
0.49
2
15
.8
C30
7
ap02
a07
py
<1.
265
<0.1
35
n.
a.
0.2
66
0.
221
<0.1
00
<0
.053
0.
468
<0.0
25
41.
5 C
307
ap
02a0
8
p
y
<
1.36
1
<0
.110
n.a.
0
.218
<0.1
55
<0.
111
<
0.04
9
<0.1
18
<0
.019
4
1.5
C30
7
ap02
a09
py
4.4
03
6.43
2
n.
a.
0.3
02
19
.466
1.05
9
0.
218
1
493.
951
3.20
9
41
.5
C30
7
ap02
a14
py
<3.
758
<0.4
13
n.
a.
<0.
670
<0
.435
0
.328
<0.
234
<0
.640
<0.0
85
44.
5 C
307
ap
02a1
5
p
y
<
4.05
5
1.
189
n.a.
<
0.73
0
1.36
9
<0
.276
<0.1
87
133.
842
1.
375
24.7
C
307
ap
02a1
8
p
y
<
4.06
9
<0
.396
n.a.
<
0.68
2
<0.5
50
<0.
234
<
0.31
7
<0.5
51
<0
.066
1
8.8
C30
7
ap02
a10
sp
<4.
528
53.4
05
n.
a.
1.5
13
37
.995
<0.3
61
0.
977
8
55.0
26
0.85
7
44
.5
C30
7
ap02
a11
sp
19.
010
65.3
23
n.
a.
3.1
06
59
.912
<0.1
17
1.
104
4
054.
317
6.58
9
42
.5
C30
7
ap02
a13
sp
<0.
864
40.0
22
n.
a.
1.0
91
33
.600
0.09
1
0.
250
4
32.3
07
<0.0
18
41.
5 C
317
ap
17f0
3
c
py
<6
.282
33.5
00
n.
a.
2.8
32
10
.510
<0.2
91
0.
728
5
.259
<0.
060
42
.5
C31
7
ap17
f11
cpy
<15.
397
16
.679
n.a.
2
.703
2.96
4
<0
.643
<0.3
97
2.77
8
<0
.211
4
4.5
C31
7
ap17
f16
cpy
<3.1
08
15
.291
n.a.
2
.729
6.53
3
<0
.115
<0.1
06
1.66
8
<0
.041
4
3.5
C31
7
ap17
f05
py
<1.
529
<0.1
65
n.
a.
0.2
25
0.
292
<0.0
86
<0
.047
0.
608
<0.0
15
44.
5 C
317
ap
17f0
6
p
y
<
1.51
9
1.
856
n.a.
<
0.29
8
2.88
9
<0
.054
<0.0
47
360.
755
<0
.015
1
9.8
C31
7
ap17
f09
py
14.
362
0.64
9
n.
a.
<0.
307
3.
823
<0.1
46
<0
.058
40
.445
<0.0
26
10.
9 C
317
ap
17f1
0
p
y
<
1.72
6
<0
.168
n.a.
0
.251
<0.2
17
<0.
058
<
0.03
4
<0.5
37
<0
.018
2
2.7
C31
7
ap17
f13
py
10.
279
0.74
2
n.
a.
<0.
760
11
.923
<0.2
37
0.
254
5
9.14
0
0.1
79
11
.9
C31
7
ap17
f14
py
<4.
834
<0.4
72
n.
a.
<0.
657
<1
.009
<
0.33
7
<0.
093
1.
885
<0.0
47
43.
5 C
317
ap
17f1
5
p
y
<
3.93
9
<0
.719
n.a.
<
0.73
3
<1.1
06
<0.
442
<
0.14
6
<0.3
82
<0
.069
1
9.8
C31
7
ap17
f04
sp
<7.
747
9.29
0
n.
a.
1.3
88
2.
027
<0.2
85
<0
.147
4.
230
<0.0
40
38.
6 C
317
ap
17f0
7
s
p
8
.103
11
.726
n.a.
1
.427
12.9
70
0.
329
<0.1
50
6.39
6
<0
.079
4
0.5
C32
0
ap17
a03
py
<3.
092
39.6
69
n.
a.
0.2
14
<0
.314
<
0.08
7
<0.
056
12
20.0
00
8
49.6
85
44.5
C
320
ap
17a0
5
p
y
<
3.35
2
2.
620
n.a.
<
0.27
1
<0.3
84
<0.
095
<
0.04
5
196.
021
12
.302
3
7.6
C32
0
ap17
a06
py
<4.
600
4.07
9
n.
a.
<0.
445
7.
710
0.68
6
<0
.074
13
5.69
7
32.9
77
11.
9 C
320
ap
17a0
7
p
y
<
3.16
7
<0
.247
n.a.
<
0.36
0
<0.3
93
<0.
073
<
0.05
1
6.93
7
4.
264
29.7
sam
ple
r
un/p
oint
type
M
o (p
pm)
Ag
(ppm
)
Cd
(ppm
)
Sn
(ppm
)
Sb
(ppm
)
Au
(ppm
)
Tl (
ppm
)
Pb
(ppm
)
B
i (pp
m)
P
eak
(s)
74
Appendix 5: LA-ICP-MS Analysis—Sulphides
C32
0
ap17
a08
py
5.0
30
0.34
9
n.
a.
<0.
278
1
.043
0.08
0
<0
.056
39
.801
8.48
8
41.
5 C
320
ap
17a0
9
p
y
<
9.06
9
0.
733
n.a.
<
0.55
5
4.5
06
0.
836
<0.0
95
34.4
74
12
.721
4
3.5
C32
0
ap17
a10
py
32.
338
<0.5
61
n.a
.
<
0.63
2
<0.
854
<0
.197
<
0.10
8
18.6
73
5.
513
4
3.5
C32
0
ap17
a11
py
<6.
086
<0.4
62
n.a
.
<
0.47
1
1.8
46
0.
257
<0.0
93
15.8
15
4.
734
4
4.5
C32
3
ap17
d03
cpy
<4.0
61
37
2.63
4
n
.a.
21.
028
3
.256
<0.1
35
<0.
078
2.
308
2.40
8
44.
5 C
323
ap
17d0
5
p
y
<
1.63
8
0.
275
n.a.
0
.233
0.4
90
<0
.076
<
0.03
5
20.2
57
10
.418
4
2.5
C32
3
ap17
d06
py
1.8
01
0.69
4
n.
a.
<0.
200
1
.082
0.07
9
<0
.035
56
.728
11.9
46
44.
5 C
323
ap
17d0
8
p
y
<
1.45
1
0.
266
n.a.
0
.197
1.8
17
<0
.069
<
0.04
1
29.9
69
3.
612
4
4.5
C32
3
ap17
d09
py
<1.
627
0.22
5
n.
a.
<0.
171
<
0.26
2
<0.0
61
<0.
041
41
.750
7.38
7
43.
5 C
323
ap
17d1
0
p
y
<
2.40
3
<0
.228
n
.a.
<0.
292
<
0.30
1
<0.1
07
<0.
063
19
.224
3.23
6
11.
9 C
323
ap
17d0
4
s
p
<
6.82
4
2.
113
n.a.
1
.391
<1.
215
<0
.258
<
0.15
2
1.79
5
0.
575
4
0.5
C32
3
ap17
d07
sp
<6.
571
9.50
6
n.
a.
0.9
57
4
.167
<0.2
69
<0.
141
96
.370
9.61
9
44.
5 C
326
ap
17e0
3
p
y
<
1.37
2
26
.642
n
.a.
0.2
10
3
81.0
86
6.25
5
1.
228
4
74.9
58
<0.0
14
42.5
C
326
ap
17e0
6
p
y
<
2.63
1
6.
672
n.a.
0
.451
50.
229
0.
747
1.26
3
95.
731
<
0.02
4
32.6
C
326
ap
17e0
8
p
y
<
2.09
3
10
32.3
47
n
.a.
0.2
37
1
4.74
6
<0.0
61
0.0
46
17
9.97
6
<0.0
23
46.5
C
326
ap
17e1
0
p
y
1
8.65
1
48
.017
n
.a.
<0.
666
3
2.98
3
1.47
0
0.
170
1
347.
748
<0.0
48
40.5
C
326
ap
17e1
1
p
y
<
5.33
0
0.
615
n.a.
<
0.68
5
2.4
67
0.
341
0.37
7
15.
820
<
0.04
8
37.6
C
326
ap
17e0
5
s
p
5
5.90
4
18
.686
n
.a.
1.2
24
1
9.03
7
0.37
0
<0
.146
15
.771
<0.0
55
41.5
C
326
ap
17e0
7
s
p
<
7.00
9
11
.049
n
.a.
1.2
32
1
1.23
5
<0.2
90
<0.
191
6.
443
<0.0
84
41.5
C
329a
ap1
0e03
cp
y
<5
.731
288.
945
n.a
.
8
3.26
3
16.
230
<0
.322
<
0.17
4
4.31
5
<0
.084
44
.5
C32
9a
a
p10e
05
cpy
<7.5
70
16
9.45
9
n
.a.
63.
669
3
.091
<0.3
69
<0.
202
6.
945
<0.0
86
10.9
C
329a
fb1
3a13
cp
y
<5
.032
31.9
66
<6.
788
1
49.6
37
14.3
11
n.a
.
<
0.33
3
62.2
66
<0
.113
38
.9
C32
9a
f
b13a
14
cpy
<17.
375
23
.531
<
25.6
17
50.5
91
43.
369
n.
a.
<1.
430
11
35.7
50
<
0.28
0
10.6
C
329a
ap1
0e06
py
<2
.289
0.79
1
n.
a.
0.3
15
5
.385
0.17
9
<0
.060
15
9.41
1
<0.0
20
39.5
C
329a
ap1
0e08
py
<2
.001
3.98
2
n.
a.
0.6
37
3
5.70
9
0.76
3
<0
.051
18
8.42
8
<0.0
28
40.5
C
329a
ap1
0e09
py
<6
.979
3.31
1
n.
a.
<0.
551
8
.461
0.61
2
0.
500
7
32.1
69
<0.0
82
42.5
C
329a
ap1
0e12
py
<6
.498
59.7
54
n.a
.
3
.686
135
.547
17
.943
<0.1
74
1564
.159
<0.
070
21
.7
C32
9a
f
b13a
12
py
<4.5
75
<0
.663
<
6.51
8
<0.
446
<
1.29
4
n.a.
<
0.34
3
1.01
1
<0
.080
38
.9
C32
9a
a
p10e
04
sp
<6.7
34
12
.088
n
.a.
2.2
31
1
6.30
6
<0.2
91
<0.
209
62
.020
<0.0
84
33.6
C
329a
ap1
0e07
sp
<5
.976
4.88
5
n.
a.
1.7
96
4
.471
<0.3
08
<0.
181
4.
658
<0.1
02
31.6
C
329b
ap0
6c15
py
<3
.942
7.45
2
n.
a.
<0.
587
1
33.9
95
24.9
85
<0
.238
79
0.27
9
<0.0
59
18.8
C
329b
ap0
6c17
py
<5
.076
<0.5
21
n.a
.
<
0.75
1
<0.
763
<0
.329
<
0.22
3
<0.4
64
<0
.056
26
.7
C32
9b
f
b13a
10
py
<4.4
00
4.
426
<7.8
64
<0.
493
2
2.04
1
n.a.
<
0.35
6
199.
442
<0
.085
28
.3
C32
9b
f
b13a
11
py
<5.0
27
8.
465
<7.9
20
<0.
586
5
5.37
4
n.a.
<
0.42
7
515.
427
<0
.073
29
.2
C32
9b
a
p06c
13
sp
<5.3
11
3.
686
n.a.
1
.805
1.6
86
<0
.413
<
0.28
7
2.33
6
<0
.084
34
.6
C32
9b
a
p06c
18
sp
<10.
063
7.
302
n.a.
1
.767
9.2
61
<0
.736
<
0.30
7
17.6
26
<0
.097
12
.9
C32
9b
a
p06c
14
tet
<8.7
75
n.
a.
n.a
.
2
.133
n.a
.
<
0.42
1
<0.
377
14
.220
0.86
5
19.
8 C
333
ap
10b1
1
p
y
<
1.49
5
<0
.148
n
.a.
<0.
171
0
.563
<0.0
62
<0.
057
4.
947
0.86
4
43.
5
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
75
Appendix 5: LA-ICP-MS Analysis—Sulphides
C33
3
ap10
b12
py
<1.
514
5.43
3
n.
a.
0.2
60
0
.511
<0.1
07
0.0
65
48
4.63
2
11.7
68
35.
6 C
333
ap
10b1
4
p
y
<
2.08
6
<0
.270
n
.a.
0.4
98
<
0.31
9
<0.1
34
<0.
058
5.
653
0.35
2
42.
5 C
333
ap
10b1
5
p
y
<
3.49
0
<0
.385
n
.a.
<0.
458
<
0.63
2
<0.2
23
<0.
158
8.
645
11.6
34
10.
9 C
333
ap
10b1
7
p
y
<
3.56
6
0.
487
n.a.
<
0.55
2
6.8
14
<0
.370
<
0.15
7
139.
210
0.
264
3
8.6
C33
3
ap10
b18
py
<1.
551
<0.2
29
n.a
.
0
.201
0.6
39
<0
.094
0
.118
2.64
0
1.
506
2
1.7
C33
3
ap10
b13
sp
<6.
001
2.31
4
n.
a.
0.8
27
<
0.83
0
<0.3
86
<0.
151
0.
689
0.30
6
41.
5 C
333
ap
10b1
6
s
p
<
4.98
9
7.
863
n.a.
1
.154
4.4
96
<0
.421
<
0.20
2
14.2
90
4.
030
3
8.6
C33
7
ap17
b11
py
<8.
123
<0.4
22
n.a
.
<
0.48
0
<0.
677
<0
.191
<
0.11
2
<0.5
64
<0
.035
42
.5
C33
7
ap17
b13
py
64.
033
<0.1
84
n.a
.
<
0.28
1
<0.
174
<0
.078
<
0.03
4
0.45
4
<0
.012
43
.5
C33
7
ap17
b15
py
<4.
815
308.
137
n.a
.
4
3.99
8
2.5
29
0.
400
<0.0
64
23.1
66
<0
.017
39
.5
C33
7
ap17
b17
py
<12
.371
<
0.56
9
n.a
.
<
0.84
0
<1.
404
<0
.265
<
0.13
1
0.95
3
<0
.071
21
.7
C33
7
ap17
b18
py
35.
395
<0.7
28
n.a
.
<
0.71
2
<1.
141
<0
.198
<
0.13
4
<0.5
46
<0
.070
18
.8
C33
7
ap17
b12
sp
<10
.567
1
2.20
1
n.a
.
1
.799
12.
233
<0
.183
<
0.08
6
7.14
5
<0
.053
33
.6
C33
7
ap17
b14
sp
<11
.441
4
0.11
3
n.a
.
4
.005
87.
323
<0
.341
0
.596
1002
.152
0.3
61
25
.7
C34
1
ap10
f15
py
<1
.426
24.0
54
n.a
.
0
.176
165
.932
24
1.54
4
3.33
6
316
.451
0.
060
4
0.5
C34
1
ap10
f16
py
<2
.066
13.9
27
n.a
.
0
.262
73.
914
30
1.02
0
4.87
1
335
9.13
9
1.
076
3
6.6
C34
1
ap10
f17
py
<3
.668
27.2
31
n.a
.
0
.508
143
.762
45
.425
0.32
5
129
2.66
7
0.
441
4
0.5
C34
1
fb13
a06
py
26
4.63
2
102.
250
<2.
822
<
0.27
6
26.
706
n.
a.
7.8
71
72
4.50
0
0.14
9
39.
8 C
341
fb
13a0
7
py
<3.7
97
23
.723
<
6.84
7
<0.
429
1
24.9
30
n.a.
0
.784
107.
113
<0
.082
40
.7
C34
1
ap10
e13
sp
9.5
94
6.62
2
n.
a.
1.5
10
1
.864
<0.2
79
<0.
161
9.
664
<0.0
85
35.6
C
341
ap
10e1
6
s
p
1
1.20
1
17
.406
n
.a.
1.9
18
1
5.92
3
<0.6
41
<0.
254
68
.600
<0.0
97
14.8
C
341
ap
10e1
8
s
p
<
7.39
8
5.
681
n.a.
1
.378
2.8
71
<0
.312
<
0.22
1
6.47
7
<0
.132
38
.6
C34
1
ap10
e14
tet
<1
1.34
7
n.a.
n
.a.
1.4
28
n
.a.
<0.
495
<
0.31
3
1.20
8
17
.470
2
3.7
C34
1
ap10
e15
tet
<1
0.49
9
n.a.
n
.a.
1.4
10
n
.a.
<0.
305
<
0.37
1
1.07
5
17
.706
3
8.6
C34
1
ap10
e17
tet
<1
0.02
9
n.a.
n
.a.
1.6
57
n
.a.
<0.
359
<
0.21
9
1.25
5
22
.697
3
4.6
C34
3
ap06
c03
py
23.
613
1.04
6
n.
a.
0.2
12
2
.148
0.20
8
0.
176
9
6.24
0
53.
516
45
.5
C34
3
ap06
c05
py
<4.
611
2.17
4
n.
a.
<0.
784
2
8.29
4
3.90
0
<0
.202
22
8.79
1
1.35
6
21.
7 C
343
ap
06c0
9
p
y
<
1.39
7
1.
615
n.a.
0
.237
0.8
18
<0
.088
<
0.08
5
249.
785
80
.486
3
9.5
C34
3
ap06
c10
py
<1.
382
6.65
8
n.
a.
0.2
40
2
.786
0.15
6
<0
.073
12
30.2
01
6
3.71
7
35.6
C
343
ap
06c1
1
p
y
<
1.62
4
0.
160
n.a.
0
.295
0.3
19
<0
.097
<
0.07
7
87.7
39
17
.965
3
5.6
C34
3
ap06
c04
sp
<6.
099
13.6
72
n.a
.
1
.722
1.7
11
2.
698
<0.2
62
5.52
8
1.
231
4
2.5
C34
3
ap06
c06
sp
<6.
432
26.5
25
n.a
.
1
.162
5.3
34
2.
309
<0.3
38
14.5
95
8.
669
1
6.8
C34
3
ap06
c12
sp
<7.
930
30.7
88
n.a
.
1
.427
10.
497
<0
.440
<
0.38
6
40.1
34
12
.885
1
3.8
C34
5
ap06
d14
py
<2.
586
<0.2
14
n.a
.
<
0.36
0
<0.
346
<0
.162
<
0.09
5
0.96
4
<0
.031
12
.9
C34
5
ap06
d15
py
8.2
28
1.50
5
n.
a.
1.0
15
4
5.09
2
<0.4
46
1.1
34
5.
264
<0.0
86
22.7
C
345
ap
06d1
6
p
y
<
5.10
0
1.
450
n.a.
<
0.56
4
3.3
88
<0
.312
0
.301
62.4
98
<0
.064
38
.6
C34
5
ap06
d18
py
<5.
140
4.11
8
n.
a.
<0.
646
3
2.43
4
0.74
0
1.
754
2
8.20
4
<0.
058
34
.6
C34
5
ap06
f15
py
<7
.641
1.23
6
n.
a.
<0.
680
5
.494
<0.3
16
<0.
192
58
7.13
0
<0.0
87
46.5
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
76
Appendix 5: LA-ICP-MS Analysis—Sulphides
C34
5
fb13
a08
py
56
.128
<0.5
55
<3.
161
<
0.36
7
<1.
057
n.
a.
<0.
266
35
.289
<0.0
53
36.3
C
345
fb
13a0
9
py
<2.0
70
<0
.394
<
2.90
5
0.2
78
2
.620
n.a.
<
0.23
8
4.19
3
<0
.041
39
.8
C34
5
ap06
f14
sp
<6
.877
23.3
22
n.a
.
3
.025
53.
537
<0
.379
0
.682
1358
4.18
6
0.1
11
42
.5
C34
5
ap06
f16
sp
<6
.546
19.3
00
n.a
.
3
.339
37.
430
<0
.298
0
.214
161.
454
<0
.080
35
.6
C34
5
ap06
f17
sp
<7
.068
25.3
09
n.a
.
3
.481
53.
766
0.
309
<0.2
97
131.
551
<0
.046
34
.6
C34
5
ap06
f18
te
t
<2
2.13
8
n.a.
n
.a.
213
.676
n.
a.
14.5
03
6.
318
4
05.2
59
<0.2
76
11.9
C
350
ap
03d0
3
p
y
<
1.25
7
2.
391
n.a.
2
.477
2.6
32
0.
178
<0.1
00
28.5
24
31
.979
4
4.5
C35
0
ap03
d04
py
<1.
190
0.25
7
n.
a.
<0.
269
<
0.20
7
<0.1
76
<0.
095
11
.167
1.17
3
41.
5 C
350
ap
03d0
6
p
y
<
1.80
6
33
.966
n
.a.
0.4
31
1
0.57
6
0.17
7
0.
613
1
830.
742
68.1
09
44.
5 C
350
ap
03d0
7
p
y
<
3.86
8
15
.637
n
.a.
1.4
62
9
.100
0.98
1
<0
.211
12
04.6
02
1
80.0
56
37.6
C
350
ap
03d0
8
p
y
<
1.32
4
29
.014
n
.a.
0.9
21
9
.960
1.07
5
<0
.084
23
29.3
43
2
20.7
61
46.5
C
350
ap
03d0
9
p
y
<
1.14
3
0.
465
n.a.
<
0.36
0
0.3
30
<0
.117
<
0.09
3
25.9
82
59
.548
4
4.5
C35
3
ap06
f03
py
28
.638
4.92
0
n.
a.
0.5
77
1
0.01
3
0.17
4
0.
082
1
140.
293
8.59
9
28.
7 C
353
ap
06f0
5
py
<5.5
40
0.
678
n.a.
<
0.71
0
5.2
31
<0
.288
<
0.19
6
159.
093
0.
274
4
4.5
C35
3
ap06
f07
py
<7
.861
1.90
9
n.
a.
<0.
941
6
.439
<0.4
44
<0.
285
39
1.93
6
2.33
0
10.
9 C
353
ap
06f0
8
py
<8.0
60
<0
.685
n
.a.
<0.
849
<
0.88
1
<0.3
52
<0.
264
50
.052
<0.1
06
10.9
C
353
ap
06f1
0
py
25.4
40
24
.593
n
.a.
<0.
944
1
22.7
50
1.93
6
20
.707
17
63.0
85
5
.548
32.6
C
353
ap
06f1
2
py
<9.0
53
3.
061
n.a.
<
0.84
8
8.4
43
<0
.353
<
0.20
2
863.
954
1.
271
1
2.9
C35
3
ap06
f13
py
<9
.277
2.79
8
n.
a.
<0.
723
1
3.12
2
0.65
2
<0
.247
67
.714
0.87
5
19.
8 C
353
ap
06f0
4
sp
<4.9
01
7.
012
n.a.
1
.831
4.3
73
<0
.267
<
0.24
8
2.08
5
<0
.054
22
.7
C35
3
ap06
f06
sp
<8
.681
17.9
93
n.a
.
1
.894
27.
440
<0
.376
<
0.26
3
819.
322
1.
264
4
2.5
C35
3
ap06
f11
sp
<6
.213
6.67
7
n.
a.
1.3
66
1
.473
<0.2
37
<0.
198
2.
609
<0.0
58
43.5
C
355
ap
17a1
7
c
py
<2
1.18
5
237.
632
n.a
.
1
4.62
5
3.4
16
<1
.064
<
0.29
3
2.67
6
0.
365
4
5.5
C35
5
ap17
d12
cpy
<15.
706
31
9.92
9
n
.a.
16.
468
1
5.07
7
<0.8
60
0.6
32
7.
942
0.73
5
41.
5 C
355
ap
17a1
2
p
y
1
0.62
4
38
.600
n
.a.
3.5
88
5
1.80
5
3.91
7
0.
749
7
70.1
35
8.61
7
20.
8 C
355
ap
17a1
5
p
y
<
2.26
4
0.
615
n.a.
<
0.23
9
0.9
41
<0
.074
0
.102
34.1
78
5.
890
3
7.6
C35
5
ap17
a16
py
<10
.285
<
0.48
8
n.a
.
<
0.53
1
<0.
801
<0
.190
<
0.11
0
0.57
1
0.
300
4
2.5
C35
5
ap17
d11
py
9.7
62
0.57
6
n.
a.
<0.
447
2
.340
<0.2
14
<0.
088
37
.559
12.0
34
38.
6 C
355
ap
17d1
3
p
y
<
9.09
2
25
.837
n
.a.
<0.
500
1
8.16
8
0.31
5
0.
625
3
969.
216
69.6
89
12.
9 C
355
ap
17d1
5
p
y
1
1.78
6
0.
998
n.a.
0
.391
8.6
16
0.
257
0.12
5
95.
790
6
.958
38.6
C
355
ap
17a1
8
s
p
<
8.18
4
2.
052
n.a.
1
.102
<0.
961
<0
.476
<
0.16
4
0.93
8
0.
064
4
1.5
C35
5
ap17
d14
sp
<7.
173
14.0
99
n.a
.
1
.582
6.0
82
<0
.321
<
0.23
0
54.6
85
1.
096
3
9.5
C35
7
ap06
e04
py
<1.
438
0.29
9
n.
a.
0.2
23
<
0.28
8
<0.0
92
<0.
066
13
.062
8.88
8
40.
5 C
357
ap
06e0
6
p
y
<
4.48
4
<0
.499
n
.a.
<0.
507
<
0.46
7
<0.3
38
<0.
159
0.
336
0.12
4
43.
5 C
357
ap
06e0
7
p
y
<
7.33
3
<0
.460
n
.a.
<0.
635
<
0.85
2
<0.2
36
<0.
227
7.
959
12.8
62
13.
8 C
357
ap
06e0
8
p
y
2
2.85
8
1.
461
n.a.
<
0.43
6
5.7
38
0.
663
1.01
3
67.
793
6
.870
41.5
C
357
ap
06e1
0
p
y
<
6.07
5
<0
.508
n
.a.
<0.
545
0
.708
<0.3
36
<0.
168
10
.422
7.44
8
37.
6 C
357
ap
06e0
3
s
p
<
7.89
6
11
.995
n
.a.
1.6
13
6
.386
<0.3
55
<0.
366
12
3.10
0
4.02
3
22.
7
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
77
Appendix 5: LA-ICP-MS Analysis—Sulphides
C35
7
ap06
e09
sp
<7.
562
8.79
5
n.
a.
1.7
24
5
.322
<0.3
13
0.7
73
36
7.12
9
5.60
2
32.
6 C
359
ap
10d1
2
c
py
<4
.745
199.
430
n.a
.
8
8.24
3
22.
845
<0
.160
0
.280
20.6
88
0.
972
2
8.7
C35
9
ap10
d10
py
<5.
048
0.90
1
n.
a.
<0.
610
2
.505
0.36
0
0.
242
3
.872
0.1
50
34
.6
C35
9
ap10
d13
py
<5.
084
<0.5
84
n.a
.
<
0.64
0
<1.
079
<0
.411
<
0.20
8
0.87
8
<0
.096
14
.8
C35
9
ap10
d16
py
<5.
877
<0.6
62
n.a
.
0
.599
<0.
849
<0
.253
<
0.17
1
0.53
6
<0
.083
35
.6
C35
9
ap10
d17
py
<4.
874
<0.5
80
n.a
.
<
0.78
4
1.9
97
<0
.254
0
.296
5.14
8
0.
155
1
8.8
C35
9
ap10
d18
py
<2.
442
8.16
6
n.
a.
0.4
61
1
4.11
3
0.19
9
0.
911
3
119.
791
19.0
73
18.
8 C
359
ap
10d1
1
s
p
<
5.36
9
60
.079
n
.a.
2.5
27
2
5.14
7
<0.3
11
0.6
17
56
.657
0.33
6
40.
5 C
359
ap
10d1
4
s
p
<
6.02
2
52
.207
n
.a.
5.2
76
2
7.35
4
<0.4
62
0.9
53
39
89.5
60
1
8.65
4
36.6
C
359
ap
10d1
5
s
p
<
7.19
7
35
.203
n
.a.
2.5
45
1
3.52
1
<0.4
35
0.2
58
32
.312
0.16
2
29.
7 C
362
ap
06a0
4
p
y
<
6.56
5
<0
.602
n
.a.
<0.
672
<
0.92
6
<0.3
71
<0.
314
<0
.213
<0.0
65
40.5
C
362
ap
06a0
6
p
y
<
5.52
0
54
.268
n
.a.
<0.
899
5
2.25
5
1.21
2
3.
960
4
45.4
69
<0.1
06
12.9
C
362
ap
06a0
9
p
y
<
5.24
1
<0
.621
n
.a.
<0.
694
<
0.85
0
<0.3
56
<0.
251
<0
.287
<0.0
72
43.5
C
362
ap
06a1
0
p
y
<
4.66
2
<0
.549
n
.a.
<0.
740
<
0.96
6
<0.3
34
<0.
323
<0
.269
<0.0
70
40.5
C
362
ap
06a1
4
p
y
<
4.65
9
22
.063
n
.a.
<0.
563
1
5.37
5
0.92
4
0.
511
2
16.6
83
<0.0
64
37.6
C
362
ap
06a1
5
p
y
<
6.39
6
<0
.585
n
.a.
<0.
715
<
0.91
9
<0.4
19
<0.
353
13
.523
<0.1
06
45.5
C
362
ap
06a1
7
p
y
<
5.38
2
<0
.515
n
.a.
<0.
679
1
.284
<0.3
31
<0.
265
7.
611
<0.0
73
44.5
C
362
ap
06a0
3
s
p
<
4.47
4
1.
610
n.a.
1
.400
<0.
908
<0
.366
<
0.34
8
1.22
4
<0
.094
37
.6
C36
2
ap06
a05
sp
<5.
296
4.89
8
n.
a.
1.3
36
5
.673
<0.3
90
<0.
363
3.
415
<0.0
98
37.6
C
362
ap
06a1
1
s
p
<
6.74
2
6.
686
n.a.
1
.564
5.2
38
<0
.219
<
0.35
8
4.28
5
<0
.108
38
.6
C36
2
ap06
a12
sp
<6.
008
4.84
7
n.
a.
1.2
46
1
.574
<0.3
91
<0.
312
3.
788
<0.0
94
41.5
C
362
ap
06a1
3
s
p
<
6.42
4
5.
968
n.a.
1
.140
16.
455
<0
.487
<
0.42
4
52.0
74
<0
.065
21
.7
C36
2
ap06
a16
sp
<6.
356
10.8
20
n.a
.
1
.421
11.
401
<0
.438
<
0.38
7
9.09
8
<0
.137
41
.5
C36
4
ap10
c06
apy
<8.8
66
4.
225
n.a.
<
1.74
6
32.
605
1.
659
2.05
6
59.
490
2
8.33
1
44.5
C
364
ap
10c1
1
c
py
<4
.332
248.
282
n.a
.
1
039.
945
21.8
73
<0.
351
1
.316
9.78
3
3.
879
4
0.5
C36
4
ap10
c13
cpy
<4.2
11
30
7.69
7
n
.a.
117
4.56
8
39
.997
<
0.22
3
19.
949
51
51.1
81
1
49.9
08
40.5
C
364
ap
10c0
3
p
y
5
.854
<0
.531
n
.a.
<0.
560
<
0.65
1
<0.3
07
<0.
167
1.
717
0.08
6
30.
6 C
364
ap
10c0
5
p
y
8
4.65
7
<0
.779
n
.a.
<0.
886
1
.154
<0.4
26
0.3
99
13
.403
0.60
3
10.
9 C
364
ap
10c0
8
p
y
<
4.86
9
10
.672
n
.a.
<0.
649
1
0.97
9
<0.5
16
3.8
16
83
6.12
6
28.6
88
17.
8 C
364
ap
10c1
2
p
y
<
4.05
0
<0
.668
n
.a.
<0.
632
<
0.95
4
0.44
7
0.
450
3
2.35
2
0.9
96
42
.5
C36
4
ap10
c14
py
<4.
421
3.27
7
n.
a.
<0.
754
5
.877
5.10
8
0.
906
3
22.1
33
12.9
87
38.
6 C
364
ap
10c1
5
p
y
<
3.35
8
2.
514
n.a.
<
0.41
2
4.1
72
0.
870
2.21
9
21.
945
1
.980
26.7
C
364
ap
10c1
7
p
y
<
5.66
4
16
.466
n
.a.
<0.
641
5
1.42
7
18.1
95
27
.037
44
7.95
5
19.9
61
16.
8 C
364
ap
10c1
8
p
y
2
.951
<0
.247
n
.a.
0.3
09
<
0.29
3
<0.1
71
<0.
088
0.
955
0.04
9
39.
5 C
364
ap
10c0
4
s
p
<
4.01
4
14
.443
n
.a.
1.6
51
<
0.75
6
<0.3
26
<0.
149
2.
957
0.36
5
43.
5 C
364
ap
10c0
9
s
p
<
4.13
1
16
.748
n
.a.
2.2
43
1
.204
<0.3
63
<0.
169
4.
116
0.69
1
42.
5 C
364
ap
10c1
0
s
p
<
4.91
0
22
.172
n
.a.
2.4
87
1
.763
<0.3
42
0.4
03
15
.109
1.68
7
44.
5 C
365
ap
03b0
3
p
y
<
1.10
9
19
.639
n
.a.
5.8
83
2
88.9
56
1.71
5
0.
290
2
763.
382
0.76
5
41.
5
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
78
Appendix 5: LA-ICP-MS Analysis—Sulphides
C36
5
ap03
b09
py
8.7
84
<0.4
48
n.a
.
<
0.91
3
2.6
88
<0
.478
<
0.37
2
3.31
7
<0
.092
12
.9
C36
5
ap03
b11
py
13.
949
10.1
83
n.a
.
<
0.65
5
56.
911
2.
385
105.
544
995.
290
0.
232
3
5.6
C36
5
ap03
b12
py
<4.
553
<0.4
31
n.a
.
<
0.77
5
2.5
34
0.
334
<0.3
00
16.5
56
<0
.099
42
.5
C36
5
ap03
b13
py
7.2
49
0.84
6
n.
a.
<1.
062
1
.740
<0.5
01
<0.
291
25
7.97
9
<0.1
08
30.6
C
365
ap
03b1
6
p
y
<
4.91
3
0.
872
n.a.
<
0.80
5
28.
878
0.
775
43.1
64
46.8
80
<0
.096
28
.7
C36
5
ap03
b17
py
<4.
116
<0.5
97
n.a
.
<
1.03
2
29.
466
0.
350
50.8
74
167.
084
<0
.094
37
.6
C36
5
ap03
b04
sp
<4.
264
13.6
46
n.a
.
1
.342
7.4
67
<0
.305
<
0.35
2
6.71
4
<0
.084
41
.5
C36
5
ap03
b07
sp
<5.
583
4.55
7
n.
a.
<0.
984
1
.920
<0.3
49
<0.
255
2.
465
<0.1
04
37.6
C
365
ap
03b1
0
s
p
<
6.25
8
5.
741
n.a.
1
.400
<0.
968
<0
.357
<
0.33
5
0.83
9
<0
.110
33
.6
C36
5
ap03
b14
sp
<5.
863
11.2
87
n.a
.
1
.326
13.
038
<0
.454
<
0.39
6
5.65
7
<0
.153
39
.5
C36
5
ap03
b15
sp
<5.
410
20.3
33
n.a
.
<
1.19
4
22.
012
<0
.587
<
0.34
7
7.71
4
<0
.096
36
.6
C36
9
fb13
a05
cp
y
<1
8.54
9
176.
022
<21
.021
2.
854
<5.8
54
n.a
.
<
1.31
7
2.44
5
<0
.256
35
.4
C36
9
ap06
b14
py
<3.
939
32.8
01
n.a
.
<
0.61
2
29.
652
2.
074
0.32
5
60.
516
<
0.05
0
44.5
C
369
ap
06b1
5
p
y
3
5.22
9
<0
.474
n
.a.
<0.
800
2
.250
<0.3
20
<0.
217
10
.992
<0.0
44
34.6
C
369
ap
06b1
6
p
y
3
.240
<0
.393
n
.a.
<0.
406
0
.905
<0.1
68
<0.
209
5.
157
<0.0
56
12.9
C
369
ap
06b1
7
p
y
1
5.64
3
3.
988
n.a.
<
0.72
0
17.
417
<0
.532
<
0.33
1
1307
.505
0.2
46
12
.9
C36
9
fb13
a03
py
2.
994
<0.
389
3
.120
0.2
15
<
1.00
7
n.a.
<
0.16
0
0.88
4
<0
.033
33
.6
C36
9
fb13
a04
py
<7
.224
<1.2
82
<10
.723
<0
.832
<
3.32
4
n.a.
<
0.53
2
<0.5
81
<0
.151
37
.1
C36
9
ap06
b12
sp
<4.
843
3.47
1
n.
a.
1.1
68
0
.971
<0.3
76
<0.
317
1.
276
<0.0
81
43.5
C
369
ap
06b1
3
s
p
<
6.51
3
9.
622
n.a.
1
.320
9.5
03
<0
.334
<
0.30
7
4.37
6
<0
.086
43
.5
C37
2
ap02
b03
apy
11.8
16
8.
172
n.a.
2
.098
811
.276
1.
106
12.6
58
1161
.450
1.0
22
19
.8
C37
2
ap02
b05
apy
<8.9
40
1.
684
n.a.
<
1.36
9
337
6.43
5
<0
.733
0
.517
145.
837
0.
278
4
5.5
C37
2
ap02
b12
apy
180.
715
11
.421
n
.a.
<1.
244
1
981.
297
1.73
3
1.
747
4
77.2
59
0.80
8
47.
4 C
372
ap
02b0
4
p
y
<
1.06
1
0.
482
n.a.
0
.232
3.9
21
<0
.073
0
.343
17.1
22
0.
046
4
2.5
C37
2
ap02
b06
py
<1.
516
0.62
1
n.
a.
0.2
58
7
.041
<0.1
19
0.1
03
31
.084
0.06
6
45.
5 C
372
ap
02b0
7
p
y
5
48.1
85
23.
861
n
.a.
0.9
94
5
89.1
45
0.97
8
10
24.3
60
64
0.24
7
1.19
9
43.
5 C
372
ap
02b0
8
p
y
3
0.10
2
14
.184
n
.a.
0.4
78
3
49.1
96
0.36
7
83
1.34
4
39
2.23
5
0.50
4
43.
5 C
372
ap
02b0
9
p
y
<
1.53
4
4.
326
n.a.
0
.283
17.
875
<0
.103
0
.266
738.
664
0.
512
4
2.5
C37
2
ap02
b10
py
<1.
803
4.06
3
n.
a.
0.4
76
2
6.85
6
0.11
9
1.
510
1
33.7
14
0.17
7
25.
7 C
372
ap
02b1
1
p
y
5
2.68
3
5.
387
n.a.
0
.434
113
.610
0.
151
97.7
09
62.1
22
0.
157
4
2.5
C37
2
ap02
b13
py
27.
675
2.89
0
n.
a.
0.4
14
2
1.00
5
<0.0
83
0.4
66
19
5.52
6
0.43
8
39.
5 C
372
ap
02b1
4
p
y
6
8.38
6
1.
540
n.a.
0
.628
91.
175
<0
.087
0
.566
50.9
11
0.
073
4
3.5
C37
2
ap02
b15
py
895
.092
2
3.74
7
n.a
.
0
.760
615
.068
0.
649
310.
871
1905
.187
2.2
46
47
.4
C37
2
ap02
b16
py
5.3
55
<0.4
41
n.a
.
<
0.60
8
2.0
92
<0
.264
<
0.21
9
2.28
6
<0
.076
44
.5
C37
2
ap02
b17
py
<4.
878
5.97
6
n.
a.
<0.
734
1
9.45
9
<0.2
60
<0.
350
25
08.1
72
1
.193
27.7
C
372
ap
02b1
8
p
y
1
2.39
1
0.
642
n.a.
0
.363
10.
696
<0
.083
0
.185
24.3
01
0.
025
4
0.5
C37
8
ap10
b06
cpy
<13.
628
68
.337
n
.a.
6.0
91
8
.832
<0.8
69
<0.
514
42
59.0
21
<
0.23
7
46.5
C
378
ap
10b0
3
p
y
<
3.50
9
<0
.355
n
.a.
<0.
520
<
0.69
2
<0.3
15
<0.
124
5.
937
<0.0
62
44.5
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
79
Appendix 5: LA-ICP-MS Analysis—Sulphides
C37
8
ap10
b05
py
<3.
792
<0.4
16
n.a
.
<
0.47
9
<0.
581
<0
.312
<
0.20
0
0.68
3
<0
.072
41
.5
C37
8
ap10
b08
py
<2.
188
<0.2
47
n.a
.
<
0.31
4
<0.
425
<0
.157
<
0.09
1
1.99
5
<0
.036
13
.8
C37
8
ap10
b09
py
<3.
605
<0.4
28
n.a
.
<
0.56
9
<0.
778
<0
.210
<
0.14
0
<0.3
27
<0
.055
37
.6
C37
8
ap10
b10
py
<5.
226
<0.7
01
n.a
.
<
0.52
5
<0.
734
<0
.362
<
0.21
1
1.48
5
<0
.067
25
.7
C37
8
ap10
b07
sp
<4.
959
52.1
15
n.a
.
0
.853
20.
828
1.
789
<0.1
96
10.8
29
<0
.077
26
.7
C37
9
ap03
a03
py
<1.
096
0.14
2
n.
a.
<0.
283
0
.657
0.12
8
<0
.082
9.
290
1.95
0
16.
8 C
379
ap
03a0
6
p
y
<
1.05
3
<0
.093
n
.a.
2.5
80
<
0.11
4
<0.0
82
<0.
068
<0
.120
<0.0
22
43.5
C
379
ap
03a0
7
p
y
<
1.45
7
7.
456
n.a.
<
0.19
0
46.
216
0.
612
0.32
8
504
.605
11
.185
4
1.5
C37
9
ap03
a08
py
<1.
223
<0.1
12
n.a
.
<
0.24
4
0.3
75
<0
.093
<
0.08
8
8.79
4
0.
249
4
2.5
C37
9
ap03
a09
py
<0.
873
<0.1
10
n.a
.
0
.240
<0.
134
<0
.069
<
0.09
1
3.89
5
0.
038
4
2.5
C37
9
ap03
a11
py
<1.
290
<0.1
81
n.a
.
<
0.20
7
<0.
113
0.
167
<0.0
90
0.81
2
0.
171
4
4.5
C37
9
ap03
a12
py
<1.
485
3.88
7
n.
a.
<0.
286
6
.345
0.24
3
<0
.072
16
1.56
0
3.12
8
46.
5 C
379
ap
03a1
7
p
y
<
1.21
9
5.
384
n.a.
<
0.24
6
0.4
76
<0
.132
0
.085
878.
198
21
.087
2
7.7
C37
9
ap03
a18
py
<0.
973
0.13
9
n.
a.
0.2
64
2
.881
<0.0
91
<0.
102
52
.182
<0.0
33
42.5
C
379
ap
03a0
4
s
p
<
2.99
2
2.
498
n.a.
1
.054
0.4
03
<0
.189
<
0.21
6
1.20
9
0.
334
4
2.5
C37
9
ap03
a05
sp
<5.
281
21.1
79
n.a
.
1
.824
18.
521
<0
.313
1
0.81
6
197.
612
18
.030
4
1.5
C37
9
ap03
a10
sp
<7.
987
8.39
4
n.
a.
1.5
33
3
.657
<0.4
82
<0.
473
56
.435
6.75
6
29.
7 C
379
ap
03a1
3
s
p
<
10.4
66
4.8
18
n
.a.
<1.
457
<
1.61
1
<0.6
83
<0.
719
4.
749
3.18
5
38.
6 C
379
ap
03a1
4
s
p
<
9.47
6
1.
939
n.a.
<
1.16
6
<0.
854
<0
.788
<
0.57
3
<0.7
73
<0
.172
36
.6
C37
9
ap03
a15
sp
<12
.655
2
3.68
6
n.a
.
<
1.82
3
32.
526
<0
.821
3
.436
866.
356
31
.502
2
7.7
C37
9
ap03
a16
sp
<4.
623
4.07
0
n.
a.
1.3
45
1
.076
<0.3
09
<0.
417
3.
168
1.86
7
37.
6 C
381
ap
03f1
6
apy
9.51
5
<
0.95
4
n.a
.
<
1.41
4
35.
028
<0
.721
<
0.56
1
0.89
5
<0
.201
46
.5
C38
1
ap03
f03
cp
y
<4
.326
464.
542
n.a
.
8
.546
1.7
04
<0
.253
<
0.24
1
1.04
0
<0
.123
42
.5
C38
1
ap03
f08
cp
y
<1
4.74
9
563.
596
n.a
.
7
.387
8.5
88
<0
.973
<
0.94
5
3.71
3
<0
.227
37
.6
C38
1
ap03
f05
py
31
.058
0.51
3
n.
a.
1.6
47
3
19.2
07
<0.2
84
195
.287
26.
510
0
.073
41.5
C
381
ap
03f0
7
py
10.8
29
2.
301
n.a.
0
.289
44.
117
4.
252
388.
394
33.0
39
<0
.015
41
.5
C38
1
ap03
f09
py
3.
561
1.3
37
n
.a.
<0.
282
2
4.82
1
0.19
0
14
.131
42
.665
0.04
0
43.
5 C
381
ap
03f1
1
py
20.6
98
0.
451
n.a.
0
.553
404
.587
0.
194
211.
898
2.87
9
<0
.022
44
.5
C38
1
ap03
f12
py
18
.993
1.08
7
n.
a.
1.1
94
4
07.0
89
0.21
5
22
0.03
5
0.
660
<0.0
27
40.5
C
381
ap
03f1
3
py
<1.3
80
<0
.094
n
.a.
0.2
69
0
.299
<0.0
88
0.0
92
3.
672
<0.0
30
43.5
C
381
ap
03f1
4
py
25.7
35
2.
929
n.a.
0
.427
187
.026
0.
552
220.
422
1806
.651
<0.
016
41
.5
C38
1
ap03
f18
py
<4
.213
<0.4
44
n.a
.
<
0.52
7
29.
309
<0
.308
1
83.2
40
1
.580
<0.
089
18
.8
C38
1
ap03
f04
sp
<1
.420
4.21
4
n.
a.
0.7
53
1
.814
0.08
2
<0
.082
1.
559
<0.0
23
34.6
C
381
ap
03f0
6
sp
<7.6
52
5.
639
n.a.
1
.595
2.6
58
<0
.443
<
0.46
2
2.82
2
<0
.140
39
.5
C38
1
ap03
f10
sp
<4
.284
8.03
6
n.
a.
1.3
69
2
.374
<0.3
59
<0.
272
3.
416
<0.0
89
43.5
C
381
ap
03f1
5
sp
<5.1
63
4.
713
n.a.
1
.557
0.8
52
<0
.357
0
.464
1.82
0
<0
.096
39
.5
C38
1
ap03
f17
sp
<8
.276
8.15
6
n.
a.
<1.
842
4
.459
<0.6
22
<0.
549
5.
139
<0.1
63
35.6
C
383
ap
17e1
2
p
y
<
6.15
2
<0
.553
n
.a.
<0.
727
<
0.96
7
<0.2
70
<0.
138
0.
513
<0.0
83
19.8
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
80
Appendix 5: LA-ICP-MS Analysis—Sulphides
C38
3
ap17
e14
py
21.
963
<0.1
96
n.a
.
0
.246
<0.
307
<0
.060
<
0.03
8
2.33
6
<0
.016
36
.6
C38
3
ap17
e16
py
18.
650
<0.4
74
n.a
.
<
0.66
8
<1.
190
<0
.193
0
.341
2.36
6
<0
.074
43
.5
C38
3
ap17
e17
py
199
.375
1
.371
n.a
.
<
0.79
5
11.
441
0.
363
0.23
5
45.
580
<
0.07
5
37.6
C
383
ap
17e1
8
p
y
<
4.66
2
12
.467
n
.a.
<0.
803
1
04.3
04
10.4
75
<0
.142
31
5.37
8
<0.0
55
42.5
C
383
ap
17e1
3
s
p
2
06.5
46
8.0
43
n
.a.
1.4
77
3
.594
<0.2
99
0.6
95
6.
872
<0.0
61
36.6
C
383
ap
17e1
5
s
p
4
9.04
3
26
.805
n
.a.
1.2
60
3
3.42
1
<0.2
74
0.3
26
20
4.66
7
<0.0
81
42.5
C
385
ap
06d0
5
c
py
74
.733
13.2
61
n.a
.
3
.238
44.
709
<0
.647
<
0.57
6
676.
316
<0
.254
10
.9
C38
5
ap06
d04
py
22.
765
<0.7
04
n.a
.
<
0.68
4
1.7
86
<0
.383
<
0.20
7
277.
745
<0
.085
23
.7
C38
5
ap06
d06
py
20.
882
<0.5
36
n.a
.
<
0.66
2
0.9
24
<0
.250
<
0.16
3
119.
470
<0
.053
45
.5
C38
5
ap06
d09
py
16.
382
8.32
5
n.
a.
0.2
68
9
.356
0.27
9
0.
300
1
871.
691
<0.0
28
24.7
C
385
ap
06d1
0
p
y
1
26.7
73
1.7
22
n
.a.
<0.
583
7
.328
<0.2
56
1.0
25
63
.039
<0.0
90
13.8
C
385
ap
06d1
1
p
y
4
3.97
3
2.
127
n.a.
<
0.52
0
8.6
78
<0
.328
1
.954
128.
834
<0
.063
24
.7
C38
5
ap06
d07
sp
<5.
163
11.2
77
n.a
.
1
.335
23.
692
<0
.236
<
0.22
0
1226
.570
<0.
103
42
.5
C38
5
ap06
d08
sp
42.
100
11.9
54
n.a
.
2
.017
22.
347
<0
.308
<
0.20
9
1594
.000
<0.
099
44
.5
C38
5
ap06
d12
sp
24.
271
18.4
63
n.a
.
1
.907
47.
351
<0
.330
0
.379
21.6
56
<0
.073
30
.6
C79
4
ap18
a34
cpy
2.09
5
8
5.79
5
n.a
.
2
8.83
7
22.
940
<0
.237
0
.238
22.6
96
19
.575
4
8.6
C79
4
ap18
a33
py
1.1
35
29.0
26
n.a
.
0
.368
24.
901
0.
817
2.27
1
226
6.50
4
51
3.42
0
4
5.1
C79
4
ap18
a36
py
<0.
216
0.16
4
n.
a.
0.2
54
3
.408
0.21
1
0.
139
6
0.82
6
19.
530
19
.1
C79
4
ap18
a39
py
<0.
177
0.31
0
n.
a.
0.1
97
9
.497
0.28
7
1.
314
8
.766
7.6
91
48
.6
C79
4
jl11a
74
py
<3
.977
0.77
1
<1
7.85
2
1
.004
0.9
43
<0
.257
<
0.21
3
39.6
89
17
.068
4
4.5
C79
4
jl11a
75
py
<3
.097
<0.2
93
<13
.673
1.
109
8.37
4
0.
468
0.28
0
14.
728
8
.299
49.8
C
794
ap
18a3
7
s
p
1
8.01
2
12
.814
n
.a.
0.8
94
1
0.75
6
0.37
1
1.
411
6
6.40
3
14.
702
50
.3
C79
4
ap18
a38
sp
7.9
34
20.2
55
n.a
.
0
.786
25.
566
0.
401
0.65
0
690
.490
28
.965
5
0.3
C79
5
ap19
a49
py
50.
254
79.1
64
n.a
.
0
.236
592
.099
4.
276
134.
344
3354
.223
<0.
017
38
.2
C79
5
ap19
a50
py
0.9
39
4.76
6
n.
a.
0.1
26
1
1.20
1
0.65
3
0.
290
1
45.4
83
<0.0
25
50.3
C
795
ap
19a5
1
p
y
0
.553
19
.276
n
.a.
0.2
28
7
1.97
4
1.97
6
11
.186
26
66.5
10
<
0.02
3
31.2
C
795
jl1
1a59
py
<2.6
63
10
.252
<
9.53
3
1.2
00
3
7.98
1
0.69
7
0.
704
3
302.
097
<0.0
51
67.0
C
795
jl1
1a60
py
<2.2
46
2.
670
<8.8
08
1.1
54
1
2.75
2
0.54
5
0.
670
1
22.6
92
<0.0
36
65.6
C
797
ap
19a9
1
p
y
<
0.26
4
1.
651
n.a.
<
0.13
8
16.
293
1.
547
<0.1
08
181.
278
0.
021
2
7.8
C79
7
ap19
a92
py
<0.
357
0.57
9
n.
a.
<0.
210
6
.173
0.76
6
<0
.107
71
.130
<0.0
14
52.0
C
797
ap
19a9
5
p
y
<
0.34
5
1.
359
n.a.
<
0.18
5
21.
216
0.
372
0.09
9
443
.020
<0
.010
48
.6
C79
7
jl11z
09
py
<2
.301
16.3
29
<12
.830
1.
249
141.
015
14.
517
<
0.12
6
1194
.150
0.0
90
45
.4
C79
7
jl11z
10
py
<5
.926
0.83
7
<2
2.06
8
1
.266
34.
897
0.
991
<0.3
09
329.
234
<0
.087
59
.5
C79
7
ap19
a93
sp
<0.
346
17.4
77
n.a
.
0
.496
12.
651
0.
245
0.07
7
11.
408
<
0.02
5
24.3
C
797
ap
19a9
4
s
p
0
.578
35
.735
n
.a.
0.5
60
3
9.02
6
0.25
5
0.
377
4
94.9
68
<0.0
19
50.3
C
799
ap
19a7
6
p
y
2
.994
34
.547
n
.a.
0.6
47
1
371.
605
1.75
8
13
69.2
74
24
14.0
49
<
0.00
9
20.8
C
799
jl1
1a35
py
10.4
88
26
.761
<
12.6
45
1.50
6
24
8.52
2
1
.146
43.
179
21
53.0
90
0
.109
44.5
C
799
jl1
1a36
py
<2.7
50
4.
715
<9.6
16
0.8
76
3
9.88
6
0.40
2
3.
354
7
20.3
85
<0.0
41
26.4
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
81
Appendix 5: LA-ICP-MS Analysis—Sulphides
C79
9
jl11a
37
py
<1
0.70
1
7.33
4
<3
2.84
4
0
.904
47.
280
0.
838
3.87
7
916
.421
<0
.153
20
.7
C79
9
jl11a
38
py
<5
.612
9.18
1
68
.231
1
.167
49.
691
0.
609
8.58
7
441
.739
<0
.075
31
.3
C79
9
ap19
a80
sp
<0.
381
8.93
2
n.
a.
0.8
50
4
.399
<0.2
60
<0.
098
2.
254
<0.0
14
52.0
C
799
ap
19a8
1
s
p
<
0.18
7
8.
942
n.a.
0
.936
4.4
36
<0
.114
<
0.06
4
1.81
4
<0
.010
52
.0
C80
1
ap10
a17
py
150
.822
0
.211
n.a
.
<
0.23
9
1.1
93
0.
101
0.19
1
20.
541
<
0.02
3
41.6
C
801
ap
10a1
8
p
y
2
83.1
49
0.7
58
n
.a.
<0.
217
2
.178
0.17
5
0.
197
2
00.8
82
<0.0
36
24.3
C
801
ap
10a2
2
p
y
1
06.9
57
0.1
21
n
.a.
<0.
240
0
.354
<0.0
82
1.8
61
13
.954
<0.0
19
13.9
C
801
jl1
1z06
py
116.
236
<0
.234
<
9.73
7
0.6
87
<
0.27
0
0.07
3
<0
.141
13
.099
<0.0
29
63.9
C
801
jl1
1z07
py
23.8
55
<0
.254
<
10.9
76
0.52
3
0.
380
<0.1
61
<0.
176
4.
474
<0.0
43
13.2
C
801
jl1
1z08
py
258.
962
<0
.221
<
9.36
4
0.5
93
<
0.21
8
<0.1
38
<0.
111
8.
031
<0.0
42
34.4
C
801
ap
10a2
3
s
p
1
32.4
83
12.
770
n
.a.
0.7
90
1
.601
0.09
7
0.
126
1
4.87
0
<0.
016
48
.6
C80
3
ap18
a64
cpy
<0.4
04
17
5.49
6
n
.a.
42.
221
9
.282
<0.2
41
<0.
217
5.
506
<0.0
23
46.8
C
803
ap
18a6
5
p
y
0
.205
<0
.084
n
.a.
<0.
171
0
.251
<0.0
83
0.9
44
4.
018
<0.0
09
26.0
C
803
jl1
1a45
py
<2.4
74
1.
179
<9.1
17
1.0
83
4
.472
0.32
7
<0
.124
16
5.87
6
0.10
5
67.
0 C
803
jl1
1a46
py
<2.2
32
6.
849
<8.0
91
0.7
88
2
8.61
5
4.57
0
7.
345
1
92.8
91
0.09
0
38.
8 C
803
jl1
1a47
py
14.7
86
18
.154
<
7.49
8
0.6
66
8
0.90
4
6.19
4
29
5.18
9
21
12.9
14
0
.924
20.7
C
803
jl1
1a48
py
<2.8
31
33
.000
<
8.50
9
1.2
46
7
0.77
7
3.45
0
0.
669
2
437.
871
0.42
7
68.
7 C
803
ap
18a6
2
s
p
1
.060
5.
772
n.a.
0
.160
13.
987
0.
128
5.67
2
247
.796
0.
044
3
8.2
C80
3
ap18
a63
sp
<0.
238
6.48
5
n.
a.
0.4
49
2
.874
0.10
4
<0
.086
2.
947
<0.0
17
22.5
C
804
ap
18a1
7
p
y
1
7.54
7
24
.876
n
.a.
0.2
02
1
79.5
27
10.4
44
62
8.95
9
10
78.4
26
0
.125
22.5
C
804
ap
18a1
8
p
y
<
0.20
7
<0
.060
n
.a.
<0.
197
<
0.29
2
<0.1
12
<0.
137
0.
788
<0.0
26
29.5
C
804
jl1
1a31
py
41.7
53
18
.147
<
8.17
3
1.0
13
1
66.5
18
6.50
6
27
3.81
8
79
6.85
2
0.06
8
59.
0 C
804
jl1
1a32
py
20.5
78
10
.559
<
10.2
18
1.24
7
92
.267
2
.600
135
.633
104
5.92
9
0.
065
6
3.0
C80
4
jl11a
34
py
15
.437
12.1
56
<12
.766
1.
705
90.8
20
3.6
72
1
64.6
65
1
142.
313
0.07
3
67.
0 C
807
jl0
4a21
py
<3.1
23
<0
.206
1
5.42
9
0.7
08
0
.833
<0.1
76
<0.
138
3.
576
<0.0
43
17.6
C
807
jl0
4a22
py
<3.2
14
<0
.231
<
7.05
0
0.6
55
<
0.33
2
<0.1
41
<0.
132
7.
037
<0.0
35
21.6
C
807
jl0
4a23
py
<2.6
86
0.
309
13.1
71
0.7
53
6
.630
<0.1
36
0.2
50
13
7.35
5
<0.0
44
73.1
C
807
jl0
4a24
py
<3.0
26
<0
.156
<
8.28
5
0.7
26
0
.264
<0.1
49
0.1
80
1.
721
<0.0
41
37.4
C
807
jl0
4a25
py
11.9
56
0.
383
32.7
51
0.8
92
2
.446
<0.1
45
0.3
49
53
.710
<0.0
39
39.2
C
807
jl0
4a26
sp
<6.4
98
30
.504
1
619.
274
1.86
5
46
.064
<
0.35
2
<0.
241
25
48.5
52
<
0.07
9
69.1
C
807
jl0
4a27
sp
<6.3
71
13
.780
1
591.
143
1.79
8
13
.362
<
0.35
8
<0.
267
17
.242
<0.0
65
69.1
C
808
ap
18a4
6
s
p
<
0.21
2
7.
407
n.a.
0
.468
5.5
61
<0
.139
<
0.13
6
13.8
02
3.
650
4
3.4
C80
8
ap18
a47
sp
<0.
195
2.96
1
n.
a.
0.3
48
0
.525
<0.1
90
<0.
091
4.
074
0.60
5
52.
0 C
809
jl0
4a64
py
<2.9
43
0.
523
<10.
430
0.8
74
1
3.01
2
0.38
2
<0
.122
71
.106
<0.0
47
49.3
C
809
jl0
4a65
py
<2.4
85
0.
269
<9.6
07
0.6
54
4
.150
<0.1
80
0.1
33
45
.324
<0.0
42
23.3
C
809
jl0
4a66
py
<2.3
62
<0
.169
<
8.94
1
0.7
96
<
0.28
6
<0.1
41
<0.
125
1.
071
<0.0
43
42.7
C
809
jl0
4a67
py
<2.7
02
<0
.246
<
11.8
42
0.64
6
0.
451
0.29
9
<0
.188
2.
504
<0.0
44
12.8
C
809
jl0
4a68
sp
<6.4
93
6.
897
2349
.928
2.2
96
1
2.50
9
<0.4
69
<0.
394
6.
906
<0.1
19
69.1
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
82
Appendix 5: LA-ICP-MS Analysis—Sulphides
C80
9
jl04a
69
sp
<2
.367
9.52
6
20
75.2
83
1
.752
24.
737
<0
.188
<
0.14
5
20.2
12
<0
.057
67
.8
C81
0
ap19
a71
py
0.9
55
13.7
69
n.a
.
0
.349
199
.980
1.
987
1.45
1
456
8.97
8
0.
080
2
6.0
C81
0
ap19
a72
py
<0.
384
1.44
0
n.
a.
0.1
66
2
2.67
5
<0.2
39
0.1
39
30
6.08
0
0.04
5
50.
3 C
810
ap
19a7
3
p
y
<
0.24
0
<0
.068
n
.a.
<0.
181
<
0.24
9
<0.0
71
<0.
117
0.
876
0.00
0
13.
9 C
810
ap
19a7
4
p
y
<
0.19
2
0.
562
n.a.
<
0.16
2
16.
527
<0
.205
<
0.10
2
137.
746
0.
090
4
6.8
C81
0
ap19
a67
sp
<0.
290
4.85
7
n.
a.
0.4
47
4
.819
<0.1
01
<0.
073
3.
712
<0.0
14
52.0
C
810
ap
19a6
8
s
p
1
.291
6.
878
n.a.
0
.546
10.
604
<0
.125
0
.170
19.4
88
0.
001
4
8.6
C81
1
jl04a
05
py
19
8.79
9
55.2
39
<13
.363
2.
193
1335
.529
2.00
6
49
6.57
5
24
06.7
62
1
.552
49.8
C
811
jl0
4a08
py
<3.9
75
3.
638
<16.
050
0.8
37
4
4.55
9
1.11
7
<0
.188
24
7.67
5
0.16
4
49.
3 C
812
ap
19a8
5
c
py
<0
.573
325.
777
n.a
.
2
4.02
9
15.
518
<0
.182
0
.523
10.1
25
<0
.027
48
.6
C81
2
ap19
a82
py
<0.
372
14.6
39
n.a
.
0
.470
28.
463
0.
129
3.09
4
144
3.89
6
0.
715
4
5.1
C81
2
ap19
a84
py
<0.
321
2.61
1
n.
a.
0.3
33
3
0.59
5
1.54
5
3.
670
2
76.2
84
0.03
0
13.
9 C
812
jl1
1a55
py
<2.4
87
<0
.233
<
10.8
52
0.67
4
<0
.226
<
0.16
1
<0.
094
0.
690
<0.0
47
31.3
C
812
jl1
1a57
py
<3.3
04
13
.801
<
10.7
08
1.33
6
41
.406
0
.565
2.1
18
42
84.3
82
0
.103
67.0
C
812
ap
19a8
6
s
p
<
0.32
9
12
.556
n
.a.
0.4
56
5
.316
0.10
8
<0
.104
2.
752
<0.0
10
48.6
C
812
ap
19a8
7
s
p
<
0.39
4
19
.676
n
.a.
0.5
22
1
7.19
5
<0.1
68
<0.
132
26
1.57
3
0.06
8
53.
8 C
813
jl0
4a37
py
45.0
04
1.
529
23.9
26
1.1
77
1
0.80
6
<0.2
19
2.0
95
88
.855
0.50
8
39.
2 C
813
jl0
4a38
py
5.44
5
0
.263
<9.
268
3
.264
2.8
90
<0
.130
<
0.10
6
31.2
32
0.
105
6
6.1
C81
3
jl04a
39
py
21
.303
<0.5
65
<30
.554
<0
.650
<
0.77
7
<0.4
57
<0.
324
8.
093
<0.1
24
39.2
C
813
jl0
4a41
py
<3.4
62
<0
.414
<
16.8
93
0.65
5
<0
.512
<
0.26
7
<0.
215
2.
673
<0.0
98
22.5
C
813
jl0
4a42
sp
28.5
02
8.
814
2434
.470
1.8
34
3
.320
<0.3
57
<0.
193
5.
153
<0.0
79
35.9
C
813
jl0
4a43
sp
20.5
65
53
.734
2
294.
818
1.94
5
10
6.30
1
<
0.19
8
0.3
92
13
18.3
54
2
.967
28.4
C
814
ap
19a4
5
p
y
<
0.25
6
3.
356
n.a.
0
.101
14.
902
2.
828
<0.0
54
144.
204
0.
036
5
2.0
C81
4
ap19
a46
py
<0.
149
4.01
7
n.
a.
<0.
190
6
3.01
6
4.91
9
<0
.121
36
8.04
3
1.01
3
52.
0 C
814
ap
19a4
7
p
y
1
.449
5.
164
n.a.
0
.126
53.
647
5.
257
0.07
8
278
.082
1.
417
4
1.6
C81
4
ap19
a48
py
<0.
281
8.63
9
n.
a.
<0.
126
5
6.59
6
13.4
40
<0
.060
34
3.63
3
0.22
6
39.
9 C
815
ap
18a9
3
p
y
<
0.34
4
48
.873
n
.a.
0.8
63
1
09.9
62
5.85
3
<0
.133
64
9.85
3
<0.0
27
39.9
C
815
ap
18a9
4
p
y
<
0.27
6
3.
404
n.a.
0
.708
31.
159
0.
344
0.17
8
96.
160
<
0.01
0
45.1
C
815
ap
18a9
5
p
y
<
0.30
6
<0
.065
n
.a.
0.2
10
1
.343
<0.0
73
<0.
112
10
.161
<0.0
11
48.6
C
815
ap
18a9
6
p
y
1
.482
8.
576
n.a.
0
.157
24.
192
0.
418
<0.1
07
260.
539
0.
033
5
0.3
C81
5
ap18
a97
sp
2.9
25
19.9
88
n.a
.
0
.604
42.
124
0.
096
0.35
2
293
2.44
7
0.
118
4
8.6
C81
5
ap18
a98
sp
0.1
84
30.3
78
n.a
.
0
.635
58.
279
<0
.077
0
.333
39.2
86
<0
.016
52
.0
C81
7
ap10
a05
apy
<0.7
98
12
.446
n
.a.
<0.
352
1
21.7
79
<0.3
34
<0.
211
87
0.13
5
27.8
78
41.
6 C
817
ap
10a0
3
p
y
3
6.90
8
14
0.44
2
n
.a.
2.8
99
1
223.
006
3.76
7
68
1.66
8
38
7.76
8
33.4
32
15.
6 C
817
ap
10a0
4
p
y
2
.662
9.
855
n.a.
0
.651
205
.544
0.
346
67.9
03
15.1
42
1.
330
3
9.9
C81
7
jl11a
70
py
<2
.292
7.13
6
<1
0.60
3
1
.094
14.
688
4.
212
<0.1
22
452.
641
20
.960
3
7.0
C81
7
jl11a
71
py
<2
.766
<0.2
90
<13
.389
0.
921
2.56
9
<0
.136
<
0.15
1
16.2
06
1.
114
1
5.4
C81
7
jl11a
72
py
21
.270
51.5
81
<49
.411
1.
066
189.
127
3.5
67
1
046.
858
2
20.6
70
25.5
49
22.
0
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
83
Appendix 5: LA-ICP-MS Analysis—Sulphides
C81
7
jl11a
73
py
23
.854
48.4
54
<21
.116
1.
203
330.
000
3.8
10
9
64.5
55
1
936.
778
52.2
70
56.
4 C
818
jl0
4a12
py
<2.4
07
3.
214
<7.6
83
0.8
66
4
1.86
8
0.64
1
0.
496
1
82.1
96
2.88
9
63.
0 C
818
jl0
4a13
py
<2.4
45
1.
144
<9.1
41
0.8
97
1
2.23
4
0.24
7
<0
.122
23
6.04
2
1.18
3
44.
5 C
818
jl0
4a14
py
<4.1
12
1.
635
<13.
095
0.8
47
2
1.28
5
0.28
7
0.
222
3
99.6
57
3.27
4
29.
1 C
818
jl0
4a15
py
<5.3
50
<0
.445
<
17.8
47
0.57
4
4.
391
<0.2
52
<0.
260
65
.751
<0.0
80
21.1
C
818
jl0
4a16
py
<2.9
78
<0
.211
<
9.63
1
0.7
39
2
.607
<0.1
28
<0.
132
25
.981
0.83
9
26.
0 C
818
jl0
4a17
sp
<3.5
66
6.
338
2075
.809
1.6
47
1
.753
<0.1
87
<0.
178
1.
504
0.06
6
67.
8 C
818
jl0
4a18
sp
<6.3
23
10
.051
2
247.
973
2.10
4
6.
599
<0.3
46
<0.
265
40
.301
0.60
3
68.
3 C
820
jl0
4a46
py
<2.1
27
0.
641
<12.
635
1.2
57
4
.133
0.28
7
0.
886
7
9.68
3
<0.
053
16
.7
C82
0
jl04a
47
py
3.
946
0.7
44
<
11.7
83
0.75
6
2.
411
<0.1
31
<0.
144
10
.843
<0.0
43
36.6
C
820
jl0
4a50
py
<1.8
38
5.
506
27.3
41
0.8
86
2
0.56
9
0.55
3
0.
183
1
467.
632
<0.0
54
32.2
C
820
jl1
1z14
py
18.4
92
9.
946
28.5
93
0.8
92
4
3.30
3
0.63
3
0.
611
2
128.
899
0.21
8
12.
8 C
820
jl1
1z15
py
<2.4
98
<0
.228
<
11.2
39
0.51
0
0.
716
<0.1
32
<0.
122
4.
477
<0.0
30
21.6
C
820
jl1
1z16
py
<2.9
08
4.
264
14.3
14
1.4
86
1
0.41
9
0.55
3
0.
223
9
67.3
79
<0.0
45
31.7
C
820
jl0
4a51
sp
<2.2
31
6.
572
1830
.455
1.6
68
0
.949
<0.1
96
<0.
139
6.
175
<0.0
58
68.3
C
820
jl0
4a52
sp
<2.4
26
15
.599
1
827.
815
1.81
5
11
.745
0
.231
<0.
153
9.
918
<0.0
58
69.1
C
822
jl0
4a31
cpy
<10.
794
28
7.28
8
<
41.3
42
4.28
0
6.
446
<0.3
41
<0.
466
5.
358
<0.1
66
13.2
C
822
jl0
4a32
cpy
61.4
34
38
2.86
0
<
22.5
23
8.01
9
14
.097
<
0.44
4
<0.
308
17
.301
<0.1
17
17.6
C
822
ap
10a1
6
s
p
2
84.6
21
13.
691
n
.a.
0.4
90
1
1.56
0
<0.1
04
0.1
31
11
.224
<0.0
24
31.2
C
822
jl0
4a34
sp
98.5
55
7.
475
2530
.045
1.9
61
4
.193
<0.4
80
<0.
340
6.
653
<0.1
31
49.9
C
823
ap
18a4
3
p
y
<
0.24
6
3.
654
n.a.
0
.430
0.4
14
<0
.199
<
0.14
0
237.
903
30
.525
4
6.8
C82
3
ap18
a44
py
1.8
76
0.89
4
n.
a.
<0.
184
1
.608
<0.0
99
<0.
120
19
2.34
2
11.7
88
50.
3 C
823
ap
18a4
5
p
y
0
.358
1.
482
n.a.
<
0.23
1
0.6
19
<0
.148
<
0.07
1
70.0
66
21
.910
5
2.0
C82
3
jl11a
82
py
<2
.174
4.53
5
<9
.030
0
.899
1.8
78
0.
147
<0.0
76
194.
176
29
.968
5
3.7
C82
3
jl11a
83
py
<3
.907
1.17
9
<1
2.30
7
1
.483
0.4
25
<0
.143
<
0.15
8
81.1
83
16
.982
3
7.0
C82
3
jl11a
84
py
5.
786
4.6
34
<
9.07
6
0.9
52
1
.222
<0.1
30
0.1
68
50
7.83
4
30.4
49
70.
9 C
824
ap
18a0
3
p
y
<
0.37
2
7.
390
n.a.
0
.189
0.8
37
0.
255
<0.1
23
49.6
96
15
.620
5
5.5
C82
4
ap18
a05
py
<0.
333
<0.0
58
n.a
.
<
0.15
6
<0.
410
<0
.144
<
0.10
5
0.33
6
0.
226
4
3.4
C82
4
ap18
a06
py
<0.
248
<0.0
49
n.a
.
0
.177
<0.
276
<0
.186
<
0.12
7
0.61
8
0.
101
4
5.1
C82
4
jl11a
49
py
<5
.318
<0.4
17
<20
.235
0.
970
1.25
4
<0
.235
<
0.22
3
4.77
1
2.
105
4
9.8
C82
4
jl11a
50
py
<7
.839
<0.6
65
<30
.560
1.
154
1.70
6
<0
.621
2
.165
5.32
5
13
.672
6
9.6
C82
4
jl11a
51
py
<6
.169
0.61
7
<1
9.89
7
0
.906
<0.
628
<0
.205
<
0.26
3
16.4
39
6.
959
6
8.3
C82
4
jl11a
52
py
<3
.563
<0.3
06
<15
.256
1.
178
<0.4
57
<0.
180
<
0.14
5
6.67
2
4.
990
6
7.0
C82
5
ap18
a53
cpy
114.
054
43
3.45
0
n
.a.
10.
646
2
6.26
9
<0.4
90
0.4
50
27
0.26
4
0.09
4
39.
9 C
825
ap
18a5
0
s
p
2
5.71
6
35
.090
n
.a.
0.6
32
4
4.47
0
0.41
6
0.
131
2
50.8
94
0.08
0
45.
1 C
825
ap
18a5
6
s
p
1
6.05
6
41
.953
n
.a.
0.9
76
6
5.92
9
0.21
0
0.
994
9
438.
187
2.98
7
52.
0 C
826
ap
18a7
0
c
py
6.
411
22.
867
n
.a.
161
.741
32
9.13
9
0
.752
61.
852
17
0.19
7
0.59
3
24.
3 C
826
ap
18a6
9
p
y
1
.588
14
4.50
7
0.
300
19.5
41
0.7
74
1
8.85
4
446.
818
1.
140
4
8.6
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
84
Appendix 5: LA-ICP-MS Analysis—Sulphides
C82
6
ap18
a71
py
6.3
60
0.26
2
n.
a.
<0.
267
2
.166
<0.2
15
0.3
31
67
.279
0.14
8
10.
4 C
826
ap
18a7
3
p
y
0
.250
3.
849
n.a.
0
.527
22.
466
8.
868
0.31
5
131
.520
10
.658
4
1.6
C82
6
jl11a
67
py
<2
.021
5.64
3
<9
.853
0
.670
45.
378
<0
.144
1
14.0
47
1
33.3
71
0.36
1
71.
8 C
826
jl1
1a68
py
165.
419
0.
565
47.9
90
1.3
61
1
.534
0.24
8
0.
223
1
19.7
92
0.34
1
67.
0 C
826
jl1
1a69
py
<2.1
66
6.
170
14.5
93
0.9
52
4
8.69
7
2.24
4
0.
898
2
51.9
76
28.8
81
29.
1 C
826
ap
18a6
8
s
p
0
.249
12
.904
n
.a.
0.7
23
9
.588
<0.1
95
0.3
99
8.
850
0.07
0
50.
3 C
826
ap
18a7
4
s
p
<
0.30
4
14
.755
n
.a.
0.9
90
1
3.96
2
<0.1
89
0.4
92
11
.043
0.08
1
36.
4 C
828
ap
18a7
7
p
y
3
4.81
8
33
.434
n
.a.
0.7
71
9
15.0
67
5.14
4
18
68.4
88
10
02.6
59
1
1.84
5
46.8
C
828
ap
18a7
8
p
y
3
8.31
4
38
.556
n
.a.
0.3
12
9
08.9
63
6.62
6
17
94.3
11
80
3.19
7
12.3
88
13.
9 C
828
ap
18a7
9
p
y
<
0.24
3
6.
337
n.a.
0
.743
50.
533
1.
233
1.80
9
859
.040
13
.885
5
2.0
C82
8
ap18
a82
py
46.
587
50.5
54
n.a
.
0
.187
110
1.02
1
7.
084
2121
.514
790.
751
9.
351
1
5.6
C82
8
ap18
a80
sp
385
.094
2
2.80
2
n.a
.
1
.905
34.
458
<0
.106
2
.270
49.1
88
1.
005
5
0.3
C82
8
ap18
a81
sp
11.
658
36.7
46
n.a
.
0
.969
61.
877
<0
.171
2
.405
197.
850
2.
117
1
7.3
C83
0
jl04a
80
py
<2
7.99
2
<1.7
34
<84
.888
<1
.647
<
2.31
7
<1.3
74
<0.
913
6.
218
<0.3
79
18.9
C
830
jl0
4a81
py
<2.8
62
0.
262
<8.1
54
0.9
02
2
.528
0.44
6
<0
.083
13
.400
<0.0
40
73.6
C
830
jl0
4a82
py
<2.6
65
<0
.221
<
8.86
8
0.8
85
1
.792
0.34
2
0.
268
1
6.18
0
<0.
031
30
.8
C83
0
jl04a
83
py
30
.717
<0.2
54
<10
.927
0.
556
0.60
9
<0
.194
0
.129
3.76
6
<0
.044
11
.9
C83
0
jl04a
84
sp
<3
.958
5.66
9
21
83.0
94
2
.027
3.8
04
<0
.161
0
.154
5.31
2
<0
.052
60
.4
C83
0
jl04a
85
sp
<7
.145
9.67
1
22
71.7
21
2
.986
14.
515
<0
.289
<
0.26
5
10.3
63
<0
.080
54
.7
C83
2
ap18
a85
py
<0.
218
<0.1
34
n.a
.
<
0.23
4
<0.
252
<0
.121
<
0.13
7
1.86
2
<0
.019
43
.4
C83
2
ap18
a86
py
<0.
184
0.55
5
n.
a.
<0.
211
0
.992
<0.1
21
<0.
116
5.
232
<0.0
23
26.0
C
832
ap
18a8
9
p
y
1
.310
1.
706
n.a.
<
0.24
8
2.7
82
0.
238
<0.1
24
333.
800
0.
096
4
5.1
C83
2
jl11z
03
py
<2
.725
<0.2
04
<10
.250
1.
128
<0.1
96
<0.
180
<
0.11
4
<0.2
56
<0
.044
69
.6
C83
2
jl11z
04
py
4.
980
1.1
74
1
7.91
4
1.1
82
0
.482
<0.1
89
<0.
102
58
.915
<0.0
47
41.4
C
832
jl1
1z05
py
<3.4
87
0.
586
<13.
474
1.0
54
1
.142
<0.1
73
<0.
167
9.
675
<0.0
71
50.7
C
832
ap
18a8
7
s
p
2
.995
12
.126
n
.a.
0.9
77
1
.874
<0.0
91
<0.
107
4.
958
<0.0
14
15.6
C
832
ap
18a8
8
s
p
1
1.43
5
35
.278
n
.a.
1.5
61
4
2.53
6
0.23
2
0.
171
1
947.
926
0.47
5
43.
4 C
833
ap
18a1
4
c
py
<0
.630
166.
501
n.a
.
6
4.72
3
22.
181
<0
.488
<
0.38
5
596.
738
21
.686
4
1.6
C83
3
ap18
a10
py
2.2
58
1.04
2
n.
a.
<0.
166
1
0.03
5
<0.1
25
0.1
83
38
.773
21.3
55
36.
4 C
833
ap
18a1
3
p
y
<
0.27
4
4.
522
n.a.
0
.845
13.
736
<0
.245
0
.390
396.
195
30
.551
3
4.7
C83
4
ap10
a26
py
<0.
743
4.29
4
n.
a.
<0.
401
4
0.10
8
1.34
1
<0
.197
11
31.4
46
1
.098
31.2
C
835
jl0
4a90
py
4.70
1
1
4.35
6
48.
237
1
.246
46.
285
<0
.216
1
.480
94.3
04
<0
.048
48
.9
C83
5
jl04a
92
py
<1
7.55
6
15.8
73
<50
.885
<1
.008
1
57.2
22
21.4
98
<0
.592
22
56.5
20
<
0.16
8
23.8
C
835
jl0
4a93
py
27.6
16
0.
445
36.2
50
1.0
91
0
.675
<0.1
33
<0.
121
11
.326
<0.0
52
74.0
C
835
jl0
4a94
sp
<4.4
62
14
.064
1
871.
307
2.75
1
17
.521
<
0.20
1
<0.
170
11
.477
<0.0
66
53.8
C
835
jl0
4a95
sp
<6.6
11
6.
133
1882
.939
2.2
87
7
.175
<0.3
85
<0.
296
7.
388
<0.1
07
55.1
C
836
ap
19a1
2
p
y
6
.996
0.
538
n.a.
0
.407
3.6
39
0.
137
0.09
9
17.
347
<
0.01
3
20.8
C
836
ap
19a1
3
p
y
1
.872
0.
388
n.a.
1
.011
3.0
88
<0
.085
0
.120
6.00
4
<0
.011
12
.1
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
85
Appendix 5: LA-ICP-MS Analysis—Sulphides
C83
6
ap19
a14
py
2.9
96
0.87
2
n.
a.
1.1
13
3
.640
<0.0
88
0.0
94
5.
554
<0.0
07
15.6
C
836
ap
19a1
5
p
y
9
.497
<0
.093
n
.a.
0.1
27
0
.412
<0.0
87
0.1
19
3.
014
<0.0
09
17.3
C
836
jl1
1z17
py
<2.5
82
<0
.210
<
10.1
74
0.92
7
0.
672
<0.1
36
<0.
103
4.
352
<0.0
45
38.3
C
836
jl1
1z18
py
<2.3
38
7.
191
15.6
94
0.5
90
1
2.24
4
0.26
5
1.
141
2
47.1
46
<0.0
34
19.8
C
836
jl1
1z19
py
23.1
59
3.
412
<16.
262
73.
908
6
.869
<0.2
14
191
.959
609
.478
<0
.063
68
.7
C83
6
ap19
a16
sp
0.7
63
12.5
81
n.a
.
2
.055
28.
092
<0
.145
0
.868
3184
.281
0.1
56
12
.1
C83
6
ap19
a17
sp
0.6
81
8.78
9
n.
a.
1.2
37
1
3.24
9
<0.0
90
0.2
05
57
5.83
2
0.06
0
50.
3 C
838
ap
19a5
5
p
y
4
.545
58
2.32
4
n
.a.
<0.
186
4
10.8
47
8.30
0
86
.295
13
99.6
45
<
0.02
6
39.9
C
838
ap
19a5
6
p
y
0
.224
66
3.72
5
n
.a.
0.1
15
4
13.6
92
6.81
5
4.
745
2
815.
073
<0.0
08
29.5
C
838
ap
19a5
7
p
y
<
0.10
0
75
.833
n
.a.
0.0
87
1
00.9
43
0.60
9
1.
398
2
168.
455
<0.0
10
27.8
C
838
jl1
1a85
py
3.67
2
7
4.62
0
10.
920
1
.063
489
.901
1.
754
8.33
9
492
0.80
9
<0
.036
33
.9
C83
8
jl11a
86
py
<2
.323
63.7
86
<7.
183
0
.716
89.
546
17
0.44
9
1384
.542
2534
.419
<0.
045
26
.0
C83
8
jl11a
87
py
<2
.345
0.36
0
<9
.065
0
.902
1.0
98
0.
115
<0.1
63
6.67
6
<0
.048
70
.9
C83
8
ap19
a58
sp
2.7
04
6.85
4
n.
a.
0.4
91
1
3.22
1
0.10
2
<0
.057
30
.239
<0.0
13
52.0
C
838
ap
19a5
9
s
p
<
0.19
2
4.
628
n.a.
0
.336
1.5
71
0.
063
<0.0
69
2.32
6
<0
.014
19
.1
C84
0
ap19
a20
cpy
<0.3
92
73
0.33
8
n
.a.
45.
006
1
8.21
8
<0.4
10
0.6
29
7.
949
0.06
6
50.
3 C
840
ap
19a2
1
c
py
<0
.444
610.
662
n.a
.
5
7.90
4
8.7
85
<0
.679
<
0.18
6
4.63
3
<0
.080
34
.7
C84
0
ap19
a22
cpy
<0.6
36
53
9.09
6
n
.a.
44.
634
9
.700
<0.1
32
0.1
80
5.
303
0.03
2
29.
5 C
840
ap
19a2
3
s
p
0
.487
10
.254
n
.a.
0.5
00
5
.468
<0.1
28
<0.
092
2.
389
<0.0
33
43.4
C
840
ap
19a2
4
s
p
1
.235
24
.339
n
.a.
1.1
97
3
2.83
2
0.16
1
0.
230
1
25.4
28
0.37
5
52.
0 C
841
ap
19a1
02
cp
y
<0
.427
213.
245
n.a
.
8
7.85
9
17.
784
<0
.159
<
0.25
8
4.59
0
0.
382
2
2.5
C84
1
ap19
a103
cpy
<0.5
91
17
9.76
6
n
.a.
108
.910
6.
429
<0.2
58
<0.
139
2.
066
0.09
9
50.
3 C
841
ap
19a1
00
py
0.
514
5.1
29
n
.a.
<0.
141
2
15.5
92
11.3
25
0.
416
2
418.
217
0.04
6
41.
6 C
841
ap
19a1
01
py
31
.285
5.72
9
n.
a.
<0.
119
6
.089
0.29
6
<0
.070
26
4.37
3
0.70
5
34.
7 C
841
ap
19a9
8
p
y
<
0.45
6
5.
536
n.a.
<
0.23
2
14.
588
0.
228
<0.1
44
196.
949
1.
896
2
4.3
C84
1
ap19
a99
py
12.
218
30.1
63
n.a
.
0
.177
4.4
33
0.
175
0.17
8
342
6.15
7
81
.583
2
6.0
C84
1
ap19
a106
sp
0.23
5
5
.211
n.a
.
0
.558
0.6
02
<0
.074
<
0.09
9
0.90
4
0.
046
2
9.5
C84
1
ap19
a107
sp
<0.4
24
7.
058
n.a.
2
.210
1.0
37
<0
.150
<
0.07
4
1.75
3
0.
093
1
5.6
C84
1
ap19
a112
sp
<0.3
48
8.
560
n.a.
0
.586
5.2
71
<0
.126
<
0.12
1
39.0
51
0.
336
5
2.0
C84
1
ap19
a113
sp
0.30
1
1
1.38
4
n.a
.
0
.607
9.5
64
<0
.123
<
0.08
8
29.7
67
0.
523
5
2.0
C84
2
ap19
a62
py
0.3
96
41.3
12
n.a
.
<
0.14
6
416
.734
30
.668
0.91
1
369
1.65
2
0.
050
3
3.0
C84
2
ap19
a63
py
<0.
220
7.38
7
n.
a.
<0.
180
2
9.60
4
0.70
3
0.
181
1
61.2
74
<0.0
20
33.0
C
842
ap
19a6
4
p
y
<
0.31
8
12
.947
n
.a.
<0.
176
4
2.75
8
2.79
9
2.
035
3
76.5
35
<0.0
20
12.1
C
842
jl1
1a79
py
<2.4
25
1.
233
<9.8
19
0.6
79
1
4.65
4
0.34
1
<0
.112
49
.748
<0.0
43
38.3
C
842
jl1
1a80
py
<2.5
97
4.
547
<8.0
86
0.6
64
3
9.90
9
0.85
6
5.
278
1
671.
247
<0.0
46
31.7
C
842
jl1
1a81
py
<2.6
92
40
.825
<
8.85
5
0.5
93
9
0.29
1
4.32
2
0.
407
1
276.
895
<0.0
47
22.5
C
842
ap
19a6
5
s
p
0
.722
16
.038
n
.a.
0.4
10
1
5.93
2
0.28
3
0.
161
1
5.78
7
0.0
03
52
.0
C84
2
ap19
a66
sp
0.2
20
10.8
76
n.a
.
0
.463
11.
681
0.
285
0.11
3
10.
026
0
.003
52.0
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
86
Appendix 5: LA-ICP-MS Analysis—Sulphides
C84
4
ap10
a09
sp
<0.
973
6.87
1
n.
a.
0.8
07
1
3.63
4
<0.2
52
<0.
162
6.
318
<0.0
37
20.8
C
844
ap
10a1
0
s
p
0
.412
9.
298
n.a.
0
.821
22.
545
<0
.133
<
0.11
6
18.2
83
0.
012
3
4.7
C84
4
ap10
a11
sp
<0.
918
5.56
1
n.
a.
1.7
97
1
0.47
4
<0.4
05
<0.
324
22
7.60
1
0.09
3
39.
9 C
846
ap
19a4
0
p
o
<
0.71
6
2.
840
n.a.
0
.555
<0.
511
<0
.255
<
0.25
9
4.18
8
4.
994
4
8.6
C84
6
ap19
a41
po
45.
587
2.31
2
n.
a.
0.7
56
<
0.67
8
<0.2
62
<0.
200
3.
284
5.01
9
48.
6 C
846
ap
19a4
2
p
o
<
1.06
2
1.
357
n.a.
0
.772
<0.
700
0.
027
<0.2
20
3.81
8
3.
367
5
0.3
C84
6
ap19
a37
py
1.2
17
0.86
4
n.
a.
0.2
76
3
.383
<0.1
11
0.0
95
52
.250
16.4
82
50.
3 C
846
ap
19a3
8
p
y
1
04.9
90
1.4
86
n
.a.
0.1
79
3
.317
<0.1
18
0.2
52
38
.275
9.07
0
41.
6 C
846
ap
19a3
9
p
y
4
6.54
9
0.
346
n.a.
<
0.18
6
0.4
94
<0
.086
0
.058
19.7
80
8.
191
2
0.8
C84
6
jl11a
62
py
<3
.021
1.57
8
<9
.415
0
.901
3.3
52
0.
102
0.47
8
110
.971
8.
889
6
2.1
C84
6
jl11a
63
py
18
.184
3.38
0
<9
.895
0
.700
6.1
20
0.
105
0.80
6
673
.155
1.
749
3
4.4
C84
6
jl11a
64
py
47
.825
1.66
4
9.
682
0.95
3
3.
629
0.19
7
<0
.097
67
.140
28.4
26
72.
2 C
848
jl1
1a10
po
<15.
698
<1
.126
<
41.7
10
2.19
2
<1
.309
<
0.97
1
<0.
684
3.
170
<0.3
32
69.6
C
848
jl1
1a11
po
<11.
993
<0
.991
<
37.4
86
2.14
4
<1
.224
<
0.83
0
<0.
503
<1
.326
0.42
9
69.
6 C
848
jl1
1a03
py
15.8
73
<0
.672
<
21.8
82
0.98
4
<0
.998
<
0.53
8
<0.
445
2.
791
<0.1
40
10.6
C
848
jl1
1a04
py
<3.9
42
<0
.282
<
9.13
4
1.0
83
0
.298
<0.1
80
<0.
167
3.
104
<0.0
55
35.7
C
848
jl1
1a05
py
10.8
11
82
.733
<
9.47
1
1.4
28
8
59.0
17
26.1
19
17
73.9
25
30
54.9
15
5
93.4
74
58.1
C
848
jl1
1a06
py
14.9
51
<0
.365
<
12.4
43
1.14
3
<0
.379
<
0.24
2
<0.
210
1.
196
<0.0
56
49.3
C
848
jl1
1a07
py
28.1
73
1.
181
<13.
963
1.2
71
0
.777
<0.1
94
<0.
210
25
6.20
6
4.44
6
37.
4 C
849
jl1
1a14
py
<6.5
58
9.
809
<24.
005
1.1
76
3
9.62
6
<0.2
33
<0.
299
14
1.63
9
3.60
8
68.
7 C
849
jl1
1a15
py
<8.4
95
<1
.003
<
38.0
47
1.03
7
2.
570
<0.5
88
<0.
508
10
8.81
1
1.87
9
24.
2 C
849
jl1
1a16
py
<5.1
01
27
.633
<
19.5
32
0.98
2
73
.060
<
0.28
9
<0.
263
26
56.6
10
9
.998
59.0
C
849
jl1
1a17
py
<4.5
59
0.
422
<14.
314
1.0
40
2
2.12
3
<0.2
00
<0.
205
32
.413
5.31
7
24.
7 R
001
ap
17c1
3
p
y
<
5.21
3
5.
718
n.a.
<
0.64
8
13.
863
1.
147
0.21
7
119
7.26
9
10
5.04
0
4
3.5
R00
1
ap17
c15
py
<2.
437
3.74
5
n.
a.
0.2
97
1
2.38
9
0.81
5
0.
162
7
83.5
72
152.
836
45.
5 R
001
ap
17c1
6
p
y
<
2.83
3
0.
988
n.a.
<
0.28
4
10.
591
0.
654
0.13
5
102
.657
14
.834
2
7.7
R00
1
ap17
d16
py
<3.
611
3.25
8
n.
a.
<0.
379
5
.298
0.28
3
0.
093
4
71.6
26
107.
700
17.
8 R
001
ap
17d1
7
p
y
<
1.24
3
1.
225
n.a.
0
.199
2.1
59
<0
.052
0
.040
161.
906
13
.725
4
4.5
R00
1
ap17
c17
sp
<10
.541
3
.988
n.a
.
1
.211
<1.
644
<0
.346
<
0.19
0
2.48
6
4.
985
4
2.5
R00
1
ap17
c18
sp
<8.
059
7.81
3
n.
a.
1.0
05
1
.882
<0.3
46
<0.
145
7.
813
7.14
0
45.
5 R
003
ap
06g1
1
p
y
<
3.22
4
<0
.363
n
.a.
0.4
23
<
0.44
0
<0.1
86
<0.
102
21
.716
13.3
17
40.
5 R
003
ap
06g1
3
p
y
<
1.22
4
9.
816
n.a.
0
.301
4.1
93
0.
521
0.09
7
733
.973
14
3.39
2
3
1.6
R00
3
ap06
g16
py
<4.
051
0.80
6
n.
a.
0.4
97
<
0.61
1
<0.1
74
<0.
140
13
.571
17.9
16
43.
5 R
003
ap
06g1
7
p
y
<
3.07
0
<0
.360
n
.a.
<0.
418
<
0.63
5
<0.2
05
<0.
126
60
.187
36.4
59
44.
5 R
003
ap
06g1
8
p
y
<
3.99
5
0.
408
n.a.
0
.526
<0.
345
<0
.238
<
0.16
6
48.6
13
42
.837
3
7.6
R00
3
ap06
g12
sp
<5.
678
7.33
1
n.
a.
1.7
24
2
.863
<0.3
92
<0.
333
67
.096
9.47
9
40.
5 R
003
ap
06g1
4
s
p
<
6.74
9
7.
831
n.a.
1
.432
1.6
15
<0
.377
<
0.24
9
30.9
63
7.
797
2
7.7
R00
3
ap06
g15
sp
<6.
766
3.18
6
n.
a.
1.8
56
<
0.91
1
<0.3
39
<0.
267
1.
069
0.79
2
43.
5
sam
ple
r
un/p
oint
typ
e
Mo
(ppm
)
A
g (p
pm)
C
d (p
pm)
S
n (p
pm)
S
b (p
pm)
A
u (p
pm)
T
l (pp
m)
P
b (p
pm)
B
i (pp
m)
P
eak
(s)
87
Appendix 5: LA-ICP-MS Analysis—Sulphides
R04
9
ap18
a20
cpy
<0.5
12
33
8.56
2
n
.a.
6.5
31
5
.654
<0.2
02
<0.
219
3.
120
<0.0
38
48.6
R
049
ap
18a2
5
c
py
<0
.694
281.
621
n.a
.
5
.497
10.
923
<0
.179
<
0.31
9
14.3
18
<0
.054
46
.8
R04
9
ap18
a19
py
46.
751
27.2
25
n.a
.
0
.400
168
.807
11
.461
310.
871
3205
.501
0.1
88
48
.6
R04
9
ap18
a26
py
0.2
73
5.80
8
n.
a.
0.1
99
1
0.90
2
2.71
7
<0
.128
32
3.96
6
0.20
1
36.
4 R
049
ap
18a2
7
s
p
0
.391
32
.994
n
.a.
0.4
70
2
3.17
9
0.22
2
0.
181
6
7.46
7
0.0
79
50
.3
R07
0
ap19
a30
apy
6.18
9
2
.077
n.a
.
1
43.7
56
3861
.022
0.78
3
<0
.131
13
.065
2.64
3
22.
5 R
070
jl1
1z20
apy
<1.7
82
10
.852
<
7.73
6
1.9
21
9
626.
732
<0.1
49
<0.
089
46
.046
1.28
9
63.
9 R
070
ap
19a2
9
c
py
<0
.494
20.0
08
n.a
.
1
699.
357
14.0
88
<0.
183
<
0.15
5
7.26
8
<0
.036
45
.1
R07
0
ap19
a34
cpy
<0.5
63
15
6.30
1
n
.a.
152
0.85
1
7.
424
<0.2
19
0.1
05
5.
016
0.08
9
50.
3 R
070
ap
19a3
1
p
y
<
0.14
2
40
.987
n
.a.
403
.193
22
.823
<
0.09
9
<0.
032
51
9.19
8
2.73
6
48.
6 R
070
ap
19a3
2
p
y
<
0.20
4
84
.100
n
.a.
231
0.55
1
86
.739
0
.148
<0.
063
26
7.90
0
0.90
2
36.
4 R
070
ap
19a3
3
p
y
<
0.24
2
54
.862
n
.a.
123
0.98
1
20
.108
<
0.05
7
0.2
92
15
7.20
5
0.70
2
29.
5 R
070
jl1
1z21
py
<2.9
70
42
.777
5
5.96
0
389
.321
46
.506
<
0.21
0
<0.
143
17
10.4
60
6
.847
24.2
R
070
jl1
1z22
py
<3.2
23
25
9.32
6
2
8.95
4
125
.395
22
.060
<
0.20
0
<0.
173
93
.439
0.23
8
20.
7 R
070
ap
19a2
5
s
p
<
0.17
7
30
.973
n
.a.
159
.000
2.
283
0.01
8
<0
.047
2.
822
0.01
1
50.
3 R
070
ap
19a2
6
s
p
<
0.27
9
79
.913
n
.a.
47.
248
4
.800
<0.0
50
<0.
079
5.
867
0.04
3
52.
0 R
075
jl1
1a25
cpy
<6.0
87
4.
570
<20.
631
751
.098
31
.139
<
0.25
8
<0.
297
18
.149
3.56
6
63.
9 R
075
jl1
1a23
py
5.04
1
5
6.66
2
<8.
263
2
043.
686
512.
701
15.
165
1
8.53
1
1166
.816
159
.913
59
.0
R07
5
jl11a
24
py
<3
.643
5.75
9
<1
2.22
5
3
.362
105
.532
5.
373
0.56
9
360
.055
64
.711
6
9.6
R07
5
jl11a
26
py
<3
.747
5.00
2
<1
0.42
7
3
75.2
15
45.8
76
1.4
84
1
.093
100.
656
13
.348
6
7.4
R07
5
jl11a
27
py
<2
.817
2.37
3
<1
1.74
9
7
6.06
8
28.
138
0.
498
0.62
6
21.
932
4
.721
66.5
R
075
jl1
1a28
py
<3.3
12
25
.246
<
12.6
04
68.1
19
49.
990
3.
685
2.13
6
366
.209
12
6.78
2
6
7.8
R07
8
jl04a
72
py
<2
.825
12.3
08
<9.
698
0
.926
191
1.87
9
<0
.152
0
.334
4548
.005
<0.
049
74
.4
R07
8
jl04a
73
py
<2
.865
12.6
44
<8.
905
1
.014
196
7.33
1
<0
.156
0
.598
4002
.584
0.0
68
69
.2
R07
8
jl04a
76
sp
<1
5.66
2
2.60
1
32
43.4
12
2
.492
39.
125
<0
.787
<
0.66
7
28.1
45
<0
.243
60
.0
R07
8
jl04a
77
sp
<5
.599
23.2
38
544
7.16
3
1.
775
1912
.576
<0.3
63
2.7
05
81
8.61
1
<0.0
78
64.3
sa
mpl
e
run
/poi
nt
t
ype
M
o (p
pm)
Ag
(ppm
)
Cd
(ppm
)
Sn
(ppm
)
Sb
(ppm
)
Au
(ppm
)
Tl (
ppm
)
Pb
(ppm
)
Bi (
ppm
)
Pea
k (s
)
Appendix 6: Sulphur Isotope Analysis
89
BV
-169
ba
C
SL-
SO
4
3
8.26
K
lens
ore
- K
m
assi
ve b
ande
d ba
in s
ulph
ide
ore
A
u-A
g-P
b-ba
zon
e B
V-1
84
ba
CS
L-S
O4
46.
87
K le
ns
or
e - K
ba c
lot i
n m
assi
ve s
p-ga
ore
A
u-A
g-P
b-ba
zon
e C
00-1
34
b
a
CS
L-S
O4
39.
39
AB
-lens
b
a lo
de -
AB
fg
se-
schi
st/s
ands
tone
with
py-
ba le
nses
ba
lode
s C
00-2
83
b
a
CS
L-S
O4
33.
84
K le
ns
or
e - K
clot
s of
ba
in m
assi
ve s
p-py
-ga
ore
- fw
to s
ill
ba
in s
ulph
ide
lode
C
00-3
51
b
a
CS
L-S
O4
37.
86
K le
ns
or
e - K
mas
sive
ban
ded
ba -
fw to
pep
eriti
c si
ll
b
a in
sul
phid
e lo
de
C00
-374
ba
C
SL-
SO
4
4
1.77
K
lens
ba lo
de -
K
ba
nded
ba
+ fp
- hw
to p
eper
ite s
ill
ba
lode
s C
00-3
75
b
a
CS
L-S
O4
47.
33
K le
ns
ba
lode
- K
mas
sive
ba
- hw
to p
eper
itic
sill
ba
lode
s C
00-4
12
b
a
CS
L-S
O4
41.
36
K le
ns
fo
otw
all
pa
le g
rey
si-s
e sc
hist
/ cg
feld
spat
hic
sand
ston
e
b
a in
sul
phid
e lo
de
C00
-557
ba
C
SL-
SO
4
4
2.72
P
lens
ba lo
de -
P
m
assi
ve b
ande
d ba
, min
or s
p-ga
ba
lode
s C
01-5
48
b
a
CS
L-S
O4
44.
13
P le
ns
ba
lode
- P
mas
sive
ba
ba
lode
s C
01-5
50
b
a
CS
L-S
O4
42.
28
P le
ns
ba
lode
- P
mas
sive
ban
ded
ba
ba
lode
s C
01-5
56
b
a
CS
L-S
O4
35.
62
P le
ns
ba
lode
- P
mas
sive
ba
+ se
-sch
ist
ba
lode
s C
01-5
58
b
a
CS
L-S
O4
39.
01
P le
ns
ba
lode
- P
mas
sive
ba
+ se
-sch
ist
ba
lode
s C
01-6
62
b
a
CS
L-S
O4
43.
45
P le
ns
ba
lode
- P
mas
sive
ban
ded
ba
ba
lode
s C
01-6
63
b
a
CS
L-S
O4
44.
17
P le
ns
fo
otw
all
ba
clo
t in
py o
re
ba in
sul
phid
e lo
de
C01
-705
ba
C
SL-
SO
4
3
5.59
P
lens
foot
wal
l
ba s
tock
wor
k in
se-
schi
st
b
a st
ockw
ork
C01
-724
ba
C
SL-
SO
4
4
4.13
P
lens
ba lo
de -
P
m
assi
ve b
ande
d ba
cut
by
late
py
vein
b
a lo
des
C01
-759
ba
C
SL-
SO
4
4
2.50
P
lens
ba lo
de -
P
se
mi-m
assi
ve b
a
b
a lo
des
R00
-020
ba
C
SL-
SO
4
4
5.30
K
lens
ore
- K
ba
clo
t in
mas
sive
fg s
p-ga
ore
- fw
to p
eper
itic
sill
ba
in s
ulph
ide
lode
B
V-1
66
py
LA
-sul
phid
e
17.
01
K le
ns
fo
otw
all
di
ssem
inat
ed p
y in
cl s
chis
t
A
u-Ag
-Pb-
ba z
one
BV
-166
sp
C
SL-
SO
2
1
4.30
K
lens
foot
wal
l
diss
emin
ated
py
in c
l sch
ist
Au-
Ag-P
b-ba
zon
e B
V-1
67
py
LA
-sul
phid
e
12.
85
K le
ns
fo
otw
all
se
mi-m
assi
ve p
y-cp
y in
cl-s
chis
t
A
u-A
g-P
b-ba
zon
e B
V-1
67
py
LA
-sul
phid
e
12.
46
K le
ns
fo
otw
all
se
mi-m
assi
ve p
y-cp
y in
cl-s
chis
t
A
u-A
g-P
b-ba
zon
e B
V-1
68
py
LA
-sul
phid
e
14.
15
K le
ns
or
e - K
mas
sive
hon
ey-b
row
n m
assi
ve s
p-ga
ore
Au-
Ag-
Pb-
ba z
one
BV
-169
sp
C
SL-
SO
2
1
3.73
K
lens
ore
- K
m
assi
ve h
oney
-bro
wn
mas
sive
sp-
ba-g
a or
e
A
u-A
g-P
b-ba
zon
e B
V-1
71
py
LA
-sul
phid
e
16.
14
K le
ns
or
e - K
sem
i-mas
sive
py
Au-
Ag-
Pb-
ba z
one
BV
-173
sp
C
SL-
SO
2
1
7.62
K
lens
ore
- K
m
assi
ve ta
n sp
-ga-
ba o
re
A
u-A
g-P
b-ba
zon
e B
V-1
75
py
LA
-sul
phid
e
14.
85
K le
ns
TS
V
fg
host
bet
wee
n or
e an
d si
ll, s
tring
er p
y-sp
vei
ns
A
u-A
g-P
b-ba
zon
e B
V-1
75
sp
CS
L-S
O2
12.
10
K le
ns
TS
V
fg
host
bet
wee
n or
e an
d si
ll, s
tring
er p
y-sp
vei
ns
A
u-A
g-P
b-ba
zon
e C
00-1
56
p
y
CS
L-S
O2
-4.9
4
hos
t
T
SV
f
ram
boid
al p
y in
fg fe
ldsp
athi
c sa
ndst
one
T
SV
bac
kgro
und
C00
-220
py
C
SL-
SO
2
-3
.47
h
ost
TS
V
fra
mbo
idal
py
in fg
feld
spat
hic
sand
ston
e
TS
V b
ackg
roun
d C
00-2
23
p
y
CS
L-S
O2
-1.8
0
hos
t
T
SV
f
ram
boid
al p
y in
fg fe
ldsp
athi
c sa
ndst
one
T
SV
bac
kgro
und
C00
-320
py
LA
-sul
phid
e
13.
24
K le
ns
fo
otw
all
se
-si s
chis
t - d
isse
min
ated
py
F
e-Zn
-Cu
zone
C
00-3
23
p
y
LA-s
ulph
ide
1
3.58
K
lens
foot
wal
l
si-s
e sc
hist
- di
ss. t
an s
p-ga
Fe
-Zn-
Cu
zone
C
00-3
23
s
p
CS
L-S
O2
11.
69
K le
ns
fo
otw
all
si
-se
schi
st -
diss
. tan
sp-
ga
Fe-Z
n-C
u zo
ne
C00
-326
py
LA
-sul
phid
e
15.
02
K le
ns
or
e - K
mas
sive
sul
phid
e,"c
last
ic" t
extu
res
- dar
k ta
n sp
-ga-
py
Fe-
Zn-C
u zo
ne
C00
-329
py
LA
-sul
phid
e
10.
49
K le
ns
or
e - K
mas
sive
, fin
ely
lam
inat
ed d
ark
tan
sp-g
a
Fe
-Zn-
Cu
zone
C
00-3
29
s
p
CS
L-S
O2
9.7
2
K
lens
ore
- K
m
assi
ve, f
inel
y la
min
ated
dar
k ta
n sp
-ga
Fe-Z
n-C
u zo
ne
sam
ple
id
min
eral
ana
lysi
s
δ
S34
o
re le
ns
unit
c
omm
ents
p
urpo
se
Appendix 6: Sulphur Isotope Analysis
90
C00
-332
py
LA
-sul
phid
e
14.
90
K le
ns
or
e - K
mas
sive
red-
brow
n sp
-ga-
py, b
and
mas
sive
py
Fe-
Zn-C
u zo
ne
C00
-363
py
C
SL-
SO
2
1
2.78
K
lens
late
vei
ns -
K
m
assi
ve p
y re
plac
ing
dark
tan
sp-g
a or
e
la
te p
y ve
in s
et -
pre-
defo
rmat
ion
C00
-364
py
C
SL-
SO
2
1
3.31
K
lens
late
vei
ns -
K
m
assi
ve fg
tan
sp-p
y-ga
ore
, tr c
py
late
py
vein
set
- pr
e-de
form
atio
n C
00-3
66
p
y
LA-s
ulph
ide
1
3.27
K
lens
porp
hyry
- K
da
rk re
d-br
own
sp-p
y-ga
in b
lack
por
phyr
y
late
py
vein
set
- pr
e-de
form
atio
n C
01-4
43
s
p
CS
L-S
O2
10.
21
P le
ns
or
e - P
9
dark
tan
sp-g
a-py
with
si-s
e cl
asts
P
lens
stra
tigra
phic
cha
nges
C
01-5
49
p
y
LA-s
ulph
ide
2
3.54
P
lens
ba lo
de -
P
ba
nded
ba,
min
or s
p-ga
ba
lode
s C
01-5
70
p
y
LA-s
ulph
ide
1
4.55
P
lens
ore
- P6
m
assi
ve p
y-sp
-ga
+ m
inor
ba
clas
ts +
fp
P
lens
stra
tigra
phic
cha
nges
C
01-5
70
s
p
CS
L-S
O2
12.
14
P le
ns
or
e - P
6
mas
sive
py-
sp-g
a +
min
or b
a cl
asts
+ fp
P le
ns s
tratig
raph
ic c
hang
es
C01
-575
py
LA
-sul
phid
e
12.
88
P le
ns
or
e - P
7
mas
sive
pal
e sp
-ga-
py +
fp
P le
ns s
tratig
raph
ic c
hang
es
C01
-575
sp
C
SL-
SO
2
1
2.38
P
lens
ore
- P7
m
assi
ve p
ale
sp-g
a-py
+ fp
P
lens
stra
tigra
phic
cha
nges
C
01-5
78
p
y
LA-s
ulph
ide
1
2.09
P
lens
ore
- P7
pa
le s
p-ga
-py
P le
ns s
tratig
raph
ic c
hang
es
C01
-580
py
LA
-sul
phid
e
14.
40
P le
ns
or
e - P
6
mas
sive
pal
e sp
-ga-
py +
gre
y fp
gra
ins
P
lens
stra
tigra
phic
cha
nges
C
01-5
82
p
y
LA-s
ulph
ide
1
1.70
P
lens
ore
- P7
se
mi-m
assi
ve p
y-sp
-ga
in s
i-se
schi
st
P
lens
stra
tigra
phic
cha
nges
C
01-5
86
p
y
LA-s
ulph
ide
1
0.76
P
lens
ore
- P6
se
mi-m
assi
ve/d
iss.
py-
tan
sp-g
a in
cl-s
e sc
hist
P
lens
stra
tigra
phic
cha
nges
C
01-5
92
s
p
CS
L-S
O2
11.
00
P le
ns
or
e - P
6
mas
sive
tan
sp-g
a-py
ore
, diff
use
lam
inat
ions
P le
ns s
tratig
raph
ic c
hang
es
C01
-594
py
LA
-sul
phid
e
11.
23
P le
ns
or
e - P
6
mas
sive
tan
sp-p
y-ga
+ fp
P le
ns s
tratig
raph
ic c
hang
es
C01
-594
sp
C
SL-
SO
2
1
5.29
P
lens
ore
- P6
m
assi
ve ta
n sp
-py-
ga +
fp
P
lens
stra
tigra
phic
cha
nges
C
01-5
96
p
y
LA-s
ulph
ide
1
1.55
P
lens
ore
- P6
m
assi
ve ta
n sp
-py-
ga, d
iffus
e la
min
atio
ns
P
lens
stra
tigra
phic
cha
nges
C
01-5
96
s
p
CS
L-S
O2
11.
65
P le
ns
or
e - P
6
mas
sive
tan
sp-p
y-ga
, diff
use
lam
inat
ions
P le
ns s
tratig
raph
ic c
hang
es
C01
-597
py
LA
-sul
phid
e
11.
15
P le
ns
or
e - P
6
sem
i-mas
sive
/mas
sive
py
(+ta
n sp
-ga)
in c
l-se
schi
st
P
lens
stra
tigra
phic
cha
nges
C
01-5
97
p
y
CS
L-S
O2
11.
62
P le
ns
or
e - P
6
sem
i-mas
sive
/mas
sive
py
(+ta
n sp
-ga)
in c
l-se
schi
st
P
lens
stra
tigra
phic
cha
nges
C
01-6
56
p
y
LA-s
ulph
ide
1
7.43
P
lens
late
vei
ns -
P
m
assi
ve ta
n sp
-ga-
py
la
te p
y ve
in s
et -
pre-
defo
rmat
ion
C01
-656
sp
C
SL-
SO
2
1
6.00
P
lens
late
vei
ns -
P
m
assi
ve ta
n sp
-ga-
py
la
te p
y ve
in s
et -
pre-
defo
rmat
ion
C01
-658
py
LA
-sul
phid
e
16.
36
P le
ns
la
te v
eins
- P
mas
sive
fg p
y ve
in in
mas
sive
cb
late
py
vein
set
- pr
e-de
form
atio
n C
01-7
07
p
y
LA-s
ulph
ide
1
0.78
P
lens
ba lo
de -
P
m
assi
ve b
ande
d py
-ba
b
a lo
des
C01
-718
py
LA
-sul
phid
e
13.
37
P le
ns
la
te v
eins
- P
mas
sive
py
vein
s in
si s
chis
t
la
te p
y ve
in s
et -
pre-
defo
rmat
ion
C01
-718
py
C
SL-
SO
2
1
3.97
P
lens
late
vei
ns -
P
m
assi
ve p
y ve
ins
in s
i sch
ist
late
py
vein
set
- pr
e-de
form
atio
n C
01-7
20
p
y
LA-s
ulph
ide
1
1.72
P
lens
late
vei
ns -
P
m
assi
ve p
y, m
inor
sp-
ga
l
ate
py v
ein
set -
pre
-def
orm
atio
n C
01-7
20
s
p
CS
L-S
O2
11.
69
P le
ns
la
te v
eins
- P
mas
sive
py,
min
or s
p-ga
lat
e py
vei
n se
t - p
re-d
efor
mat
ion
C01
-740
py
LA
-sul
phid
e
17.
65
P le
ns
la
te v
eins
- P
fg
se-s
i sch
ist w
ith e
arly
qz-
py v
ein
la
te p
y ve
in s
et -
pre-
defo
rmat
ion
C01
-743
py
LA
-sul
phid
e
16.
60
P le
ns
la
te v
eins
- P
fg
se-s
i sch
ist w
ith e
arly
qz-
py v
ein
la
te p
y ve
in s
et -
pre-
defo
rmat
ion
C01
-758
sp
C
SL-
SO
2
1
4.00
P
lens
ore
- P13
m
assi
ve ta
n sp
-ga-
py
P
lens
stra
tigra
phic
cha
nges
C
01-7
59
p
y
LA-s
ulph
ide
2
1.25
P
lens
ba lo
de -
P
se
mi-m
assi
ve b
a in
se-
si s
chis
t
b
a lo
des
C01
-823
py
LA
-sul
phid
e
15.
82
K le
ns
fo
otw
all
gr
ey s
i-se
schi
st +
dis
sem
inat
ed p
y
F
e-Zn
-Cu
zone
C
01-8
24
p
y
LA-s
ulph
ide
1
2.03
K
lens
foot
wal
l
blac
k cl
-se
schi
st +
py-
cpy
F
e-Zn
-Cu
zone
C
01-8
26
p
y
LA-s
ulph
ide
1
0.57
K
lens
ore
- K
dk
tan
sp-g
a-py
+ c
b bl
ebs
F
e-Zn
-Cu
zone
C
01-8
26
s
p
CS
L-S
O2
11.
45
K le
ns
or
e - K
dk ta
n sp
-ga-
py +
cb
bleb
s
Fe-
Zn-C
u zo
ne
C01
-828
py
LA
-sul
phid
e
15.
24
K le
ns
or
e - K
dk ta
n sp
-py
band
ed o
re
F
e-Zn
-Cu
zone
sam
ple
id
min
eral
ana
lysi
s
δ
S34
o
re le
ns
unit
c
omm
ents
p
urpo
se
Appendix 6: Sulphur Isotope Analysis
91
C01
-828
sp
C
SL-
SO
2
1
3.60
K
lens
ore
- K
dk
tan
sp-p
y ba
nded
ore
Fe-
Zn-C
u zo
ne
C01
-830
py
LA
-sul
phid
e
16.
03
K le
ns
or
e - K
tan
sp-g
a-py
Fe
-Zn-
Cu
zone
C
01-8
32
p
y
LA-s
ulph
ide
1
5.13
K
lens
ore
- K
ho
ney-
bn s
p-ga
-py
F
e-Zn
-Cu
zone
C
01-8
32
s
p
CS
L-S
O2
13.
15
K le
ns
or
e - K
hone
y-bn
sp-
ga-p
y
Fe-
Zn-C
u zo
ne
C02
-858
py
C
SL-
SO
2
1
5.32
P
lens
TSV
s
e-al
tere
d si
ltsto
ne -
diss
emin
ated
sul
phid
e
P
lens
stra
tigra
phic
cha
nges
C
02-8
58
s
p
CS
L-S
O2
12.
90
P le
ns
TS
V
se-
alte
red
silts
tone
- di
ssem
inat
ed s
ulph
ide
P le
ns s
tratig
raph
ic c
hang
es
C02
-859
py
C
SL-
SO
2
1
1.85
P
lens
ore
- P9
qz
-alte
red
sedi
men
t - s
emi-m
assi
ve s
ulph
ide
P le
ns s
tratig
raph
ic c
hang
es
C02
-859
sp
C
SL-
SO
2
9
.51
P le
ns
or
e - P
9
qz-a
ltere
d se
dim
ent -
sem
i-mas
sive
sul
phid
e
P
lens
stra
tigra
phic
cha
nges
C
02-8
60
s
p
CS
L-S
O2
13.
47
P le
ns
or
e - P
9
mas
sive
pal
e sp
-ga
P
lens
stra
tigra
phic
cha
nges
C
02-8
61
s
p
CS
L-S
O2
8.7
0
P
lens
ore
- P9
se
ricite
-alte
red
sedi
men
t + d
isse
min
ated
sul
phid
e
P le
ns s
tratig
raph
ic c
hang
es
C02
-862
py
C
SL-
SO
2
9
.14
P le
ns
po
rphy
ry -
P
qz-c
b al
tere
d qz
-fp p
orph
yry
P le
ns s
tratig
raph
ic c
hang
es
C02
-863
sp
C
SL-
SO
2
1
0.89
P
lens
ore
- P10
m
assi
ve o
rang
e br
own
sp-g
a
P le
ns s
tratig
raph
ic c
hang
es
C02
-864
py
C
SL-
SO
2
1
3.87
P
lens
ore
- P10
ba
ritic
qua
rtz-s
eric
ite a
ltere
d se
dim
ent
P
lens
stra
tigra
phic
cha
nges
C
02-8
66
p
y
CS
L-S
O2
14.
38
P le
ns
TS
V
cb
alte
red
sedi
men
t, di
ssem
inat
ed s
ulph
ide
P le
ns s
tratig
raph
ic c
hang
es
C02
-867
sp
C
SL-
SO
2
1
6.71
P
lens
ore
- P13
m
assi
ve p
ink
carb
onat
e
P
lens
stra
tigra
phic
cha
nges
C
02-8
68
s
p
CS
L-S
O2
13.
64
P le
ns
or
e - P
13
sem
i-mas
sive
ora
nge-
brow
n sp
-ga
P
lens
stra
tigra
phic
cha
nges
R
02-0
81
s
p
CS
L-S
O2
12.
82
P le
ns
or
e - P
13
band
ed s
p-ga
-py
ore
P le
ns s
tratig
raph
ic c
hang
es
R02
-081
sp
C
SL-
SO
2
1
2.42
P
lens
ore
- P13
ba
nded
sp-
ga-p
y or
e
P
lens
stra
tigra
phic
cha
nges
sam
ple
id
min
eral
ana
lysi
s
δ
S34
o
re le
ns
unit
c
omm
ents
p
urpo
se
92
Appendix 7: Diamond Drill Logs
Appendix 7 Diamond Drill Logs
Tabulated below are the drill holes and intervals logged as part of this study. Several representative logs only are enclosed due to volume of material, with the remainder held at the University of Tasmania. Mine development and grade control holes collared below surface are prefixed by “R”, whereas surface exploration holes are suffixed by “R”. Assay, survey and other relevant data is contained within mine site drill datasets. BHID interval logged BHID interval logged From To (m) From To (m) 060R 738 1054 316 R6593 0 72 72 086R 540 864.8 324.8 R6760 0 165.9 165.9 087R 514 889.7 375.7 R6803 0 103.4 103.4 121R 1082 1511.9 429.9 R6804 0 92.5 92.5 121R-D1 1050 1425.3 375.3 R6805 0 29.6 29.6 122R 1170 1700 530 R6806 0 71.2 71.2 123R 1130 1509.1 379.1 R6827 0 83.4 83.4 127R 1200 1721.1 521.1 R6828 0 62.8 62.8 132R-D2 1030 1402 372 R6829 0 41.7 41.7 R5192 367 554 187 R6847 0 23.8 23.8 R5192-D1 300 830.7 530.7 R6889 0 101.4 101.4 R5382-D1 500 840.4 340.4 R6890 0 101.4 101.4 R5384 0 290 290 R6901 0 139.2 139.2 R5387 0 190.2 190.2 R6902 0 123.7 123.7 R5581-D2 570 716.8 146.8 R6910 0 201.4 201.4 R5802 0 200 200 R6921 0 172.8 172.8 R5824 0 649 649 R6926 0 152 152 R5827 0 399 399 R6932 0 162.3 162.3 R5964 0 104 104 R6978 0 116 116 R5975 0 338.6 338.6 R7013 0 192 192 R6011 0 570 570 R7251 0 68 68 R6051 0 258 258 R7252 0 71 71 R6052 0 347.2 347.2 R7254 0 55 55 R6053 0 398.7 398.7 R7255 0 73.7 73.7 R6055 0 497.3 497.3 R7394 0 105.6 105.6 R6075 0 124.5 124.5 R7407 0 66.6 66.6 R6203-D1 300 762 462 R7455 0 131.6 131.6 R6217 0 218.2 218.2 R7467 0 70.1 70.1 R6219 0 199 199 R7489 0 46.4 46.4 R6223 0 247 247 R6297 0 159 159 70 holes for a total of 15086.8m R6298 0 131 131 R6334 0 299.8 299.8 R6335 130 504 374 R6411 0 124.3 124.3 R6426 0 136.3 136.3 R6464 0 148 148 R6476 0 194 194 R6529 0 113.5 113.5 R6587 0 98.6 98.6 R6592 0 90.3 90.3
Appendix 8: Specific New Data Collected & Presented
125
Appendix 8 Specific New Data
Collected & Presented
Appendix 8: Specific New Data Collected & Presented
126
This study – new data collected raw data location
This study - new data presented
Chapter 3 70 drillholes logged (15,086.8m ) appendix 7 in text; figs. 3.4, 3.7 - 3.15, 3.22 28 thin sections appendix 1 in text; figs. 3.5, 3.16, 58 whole rock analyses appendix 2 in text; fig. 3.6 compilation of TSV thickness data
and intrusive location/extent Rosebery mine
dataset in text; figs.3.19, 5.1
Chapter 4 70 drillholes logged (15,086.8m ) appendix 7 in text; table 4.1; figs. 4.2 - 4.9, 4.11
28 thin sections appendix 1 in text; fig. 4.1 electron microprobe analyses –
chlorite, n=35 appendix 3 in text; figs. 4.13 - 4.14
electron microprobe analyses – sericite, n=7
appendix 3 in text; fig. 4.15
electron microprobe analyses – feldspar, n=53
appendix 3 in text
Chapter 5 70 drillholes logged (15,086.8m ) appendix 7 in text; figs. 5.5, 5.7-5.10, 5.19 58 whole rock analyses appendix 2 in text; fig. 5.2 85 thin sections & polished thin
sections; 82 polished resin mounts appendix 1 in text; tables 5.1 - 5.2; figs. 5.2,
5.11 - 5.19 Chapter 6 compilation of major element data K
lens & P lens ore Rosebery mine
dataset in text; table 6.1; figs. 6.1 - 6.3, 6.5 - 6.6
Chapter 7 85 thin sections & polished thin sections; 82 polished resin mounts
appendix 1 in text; fig. 7.2
electron microprobe analyses – pyrite, n=432
appendix 4 in text; tables 7.1 - 7.3
electron microprobe analyses – sphalerite, n=335
appendix 4 in text; tables 7.4 - 7.5, 7.11; figs. 7.6, 7.15 - 7.17, 7.19
electron microprobe analyses – galena, n=87
appendix 4 in text; table 7.7
electron microprobe analyses – chalcopyrite, n=114
appendix 4 in text; table 7.8
electron microprobe analyses – pyrrhotite, n=9
appendix 4 in text
electron microprobe analyses – arsenopyrite, n=25
appendix 4 in text
electron microprobe analyses – bournonite, n=4
appendix 4 in text
electron microprobe analyses – tennantite/tetrahedrite, n=79
appendix 4 in text; table 7.6; figs. 7.8, 7.17-7.19
LA-ICP-MS analyses – pyrite, n=431
appendix 5 in text; tables 7.1 - 7.2, 7.10; figs. 7.3 - 7.5, 7.9 - 7.10, 7.12 - 7.14, 7.16 - 7.17,
LA-ICP-MS analyses – sphalerite, n=174
appendix 5 in text; tables 7.4 - 7.5, 7.10; fig.7.7
LA-ICP-MS analyses – chalcopyrite, n=42
appendix 5 in text; table 7.9
LA-ICP-MS analyses – pyrrhotite, n=5
appendix 5 in text
LA-ICP-MS analyses – arsenopyrite, n=10
appendix 5 in text; table 7.9
LA-ICP-MS analyses – tennantite-tetrahedrite, n=9
appendix 5 in text
Chapter 8 SO4 analyses – barite, n=19 appendix 6 in text; tables 8.1 - 8.3; figs. 8.1 - 8.5
SO2 analyses – pyrite, n=12 appendix 6 in text; tables 8.1 - 8.3; figs. 8.1 - 8.5
SO2 analyses – sphalerite, n=27 appendix 6 in text; tables 8.1 - 8.3; figs. 8.1 - 8.5
laser SO2 analyses – pyrite, n=36 appendix 6 in text; tables 8.1 - 8.3; figs. 8.1 - 8.5