Gasification Systems Overview

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- Gasification - Gasifier Designs - Syn Gas Production - Biomass Gasification: Production of chemicals, fertilizers, hydrogen and/or liquid fuels - Gasification: Integrated Gasification Combined Cycle (IGCC) power production with 90% carbon capture - Coal & Coal Biomass to Liquids (C&CBTL)(Fuels): Production of chemicals, fertilizers, hydrogen and/or liquid fuels

Transcript of Gasification Systems Overview

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Gerard B. Hawkins, Executive Director

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

What is Gasification?

A Business Unit of GBH Enterprises, Ltd.

Gasification converts any carbon-containing material into synthesis gas, composed primarily of carbon monoxide and hydrogen (referred to as syngas) Syngas can be used as a fuel to generate electricity or steam, as a basic chemical building block for a large number of uses in the petrochemical and refining industries, and for the production of hydrogen Gasification adds value to low- or negative-value feedstocks by converting them to marketable fuels and products

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

The Gasifier

A Business Unit of GBH Enterprises, Ltd.

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Gasification – Differences from Combustion

Add water and high pressure Use less air or oxygen Gasification exit gases are at high pressure, so smaller volume, smaller reactors Combustion makes heat + CO2 + H2O Gasification makes less heat + carbon monoxide + hydrogen (CO + H2); called Syngas

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

So what can you do with CO and H2 ?

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Water-Gas-Shift (WGS) Reaction

Dry syngas is ~ 40% CO + 50% H2 For each CO molecule the WGS reaction creates one H2 molecule and one CO2 molecule

CO + H2O + catalyst CO2 + H2

After the WGS reaction, the CO2 and H2 can be separated High pressure CO2 results in lower cost sequestration Hydrogen can be burned to make power

2H2 + O2 2H2O

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Overview of Energy Systems Options

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Chemicals and Products from Gasification

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Benefits of Gasification

Feedstock flexibility Wide range of coals, petcoke, liquids, wastes, biomass can be utilized Product flexibility Syngas can be converted to high valued products: electricity, steam, hydrogen, liquid transportation fuels, chemicals, SNG Environmental superiority Pollutants can be economically controlled to extremely low levels (SO2, NOX, CO, Hg, etc.) Reduced water consumption Potential solid wastes can be utilized or easily managed High efficiency / low CO2 production CO2 can be easily captured for sale or geologic storage (sequestration)

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Technologies applicable to:

Biomass Gasification: Production of chemicals, fertilizers, hydrogen and/or liquid fuels Gasification: Integrated Gasification Combined Cycle (IGCC) power production with 90% carbon capture Coal & Coal Biomass to Liquids (C&CBTL)(Fuels): Production of chemicals, fertilizers, hydrogen and/or liquid fuels

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Key Technologies

Feed Systems Oxygen separation Expand fuel flexibility Increase efficiency Gasifier Optimization and Plant Supporting Systems Improve reliability Increase efficiency Syngas Supporting Systems Hydrogen and carbon dioxide separation Control multi-contaminants to extremely low levels

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Key Gasification Systems R&D Areas

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Key 2nd Generation Technologies

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Study Matrix

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

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IGCC Performance Results

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PC and NGCC Performance Results

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IGCC Economic Results

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

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Systems Analysis Bituminous IGCC Pathway Study

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

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IGCC Advanced Technology Assessments

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Advanced IGCC Systems : Driving Down the Cost

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

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Advanced IGCC Systems : Driving Down the Cost

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Lowest Cost Power Generation Options MIDWEST (sea level): Today’s NGCC versus Today’s Coal (Bituminous)

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Lowest Cost Power Generation Options MIDWEST (sea level): Today’s NGCC versus Today’s Coal (Bituminous)

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Systems Analysis

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Conventional IGCC Compared to PC and NGCC

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

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Fundamental Comparison of IGCC with Advanced PC-Fired Plant

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

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Comparison of Air Emission Controls: PC vs. IGCC

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A Business Unit of GBH Enterprises, Ltd.

Effect of Coal Quality on PC and IGCC Plant Heat Rates and Capital Costs

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

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Conventional Coal Plant

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Natural Gas Combined Cycle

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Coal-Based IGCC Power Plant

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

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Coal-Based IGCC Power Plant

RENALT ENERGY Renewable and Alternative Energy for the New Millennium

A Business Unit of GBH Enterprises, Ltd.

Gasification-Based Energy Conversion Systems

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