Post on 12-Mar-2020
Effective synthetic strategy of Zn0.76Co0.24S encapsulated in stabilized N-doped
carbon nanoarchitecture toward ultra-long-life hybrid supercapacitorsYuan Yang,a Shuo li,a Wei Huang,b Huihui Shangguan,a Christian Engelbrekt,b, c Shuwei Duan,a
Lijie Ci,a Pengchao Si*a
a SDU & Rice Joint Center for Carbon Nanomaterials, MOE Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, School of Materials Science and Engineering, Shandong University, Jinan 250061, P. R. China. b Department of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.c Department of Chemistry, University of California Irvine, Irvine, California, 92697, United States.
Corresponding authors:*Pengchao Si: pcsi@sdu.edu.cn
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A.This journal is © The Royal Society of Chemistry 2019
Fig. S1 (a-c) SEM images of the ZIF@PDA particles at different magnifications.
Fig. S2 TEM images of (a, e) ZIF@PDA-6h, (b, f) ZIF@PDA-12h, (c, g) ZIF@PDA-18h, and (d, h) ZIF@PDA-24h.
Fig. S3 TGA curve of ZIF@PDA particles.
Fig. S4 (a) SEM and (b) TEM images of DZCS. (c) SEM and (d) TEM images of ZCS.
Fig. S5 XRD patterns of the ZIF-67/8@PDA compared with ZIF-67/8.
Fig. S6 XRD pattern of ZCS.
Fig. S7 SEM image of HZCS@NC particle.
Fig. S8 (a) Nitrogen adsorption/desorption isotherms and the (b) pore-size distribution of ZIF-67/8. (c) Nitrogen
adsorption/desorption isotherms and the (d) pore-size distribution of ZCS.
Fig. S9 Raman spectra of the HZCS@NC, ZCS, and CCZC@NC.
Fig. S10 XPS survey spectra of HZCS@NC electrode.
Fig. S11 EDS spectrum of HZCS@NC.
Fig. S12 Elemental spectra of N 1s of the ZCS electrode.
Fig. S13 CV curves of the (a) CCZC@NC and (b) ZCS electrodes at various scan rates.
Fig. S14 GCD curves of the (a) CCZC@NC and (b) ZCS electrodes at various current densities.
Fig. S15 SEM image of the HZCS@NC after cycling.
Fig. S16 Cycling stability of pure Ni foam for (a) the first 100 cycles and (b) the total 3000 cycles.
Fig. S17 Photo of the hybrid supercapacitor.
Fig. S18 (a) CV curves of RGO electrode at various scan rates. (b) GCD curves of RGO electrode at various current
densities.
Fig. S19 Specific capacitance of the RGO at various current density.
Fig. S20 Practical applications of various devices driven by two hybrid supercapacitors in series, (a) a calculator, (b)
a digital watch.
Table S1. The elements contents from XPS measurement of HZCS@NC.
Element C N O Zn Co S
Atomic% 72.48 12.28 10.02 2.01 0.56 2.66
Table S2. The equations based on CV curves of the electrode materials.
Cathodic log(i)=b log(v)+log a bCCZC@NC log(i)=0.7152 log(v)-2.475 0.7152
ZCS log(i)=0.7221 log(v)-2.379 0.7221HZCS@NC log(i)=0.5973 log(v)-2.041 0.5973
Table S3.Comparison of electrochemical performances of the other electrode materials with this work
in a three-electrode system.
Electrode materials specific capacitance
electrolyte Cyclic stability references
Hollow Zn0.76Co0.24S@C 2082.22 F g-1
at 1 A g-16 M KOH 40 0000
[112%]This work
Co3O4/ZnCo2O4/CuO 890.2 F g-1
at 1 A g-12 M KOH 1000
[89.7%]1
C-NiCo2O4 1722 F g-1
at 1 A g-16 M KOH 10000
[98.8%]2
MoS2-Co3O4 1369 F g-1
at 1 A g-13 M KOH 10000
[83 %]3
Co3S4/MWCNT 850.3 F g-1
at 2 A g-12 M KOH 5000
[78.98 %]4
Pd-Co3O4 1353 F g-1
at 7 mA cm-23 M KOH 5000
[95 %]5
Co-Co LDH 1205 F g-1
at 1 A g-13 M KOH 5000
[95 %]6
ZnCo2O4@Ni(OH)2 1021 F g-1
at 1 mA cm-23 M KOH 5000
[50.1 %]7
Co3O4 1216.4 F g-1
at 1 A g-12 M KOH 8000
[86.4 %]8
NiCo2O4@RGO 1427 F g-1
at 8 A g-12 M KOH 10000
[83.8 %]9
MgCo2O4@PPy 1079.6 F g-1
at 1 A g-12 M KOH 1000
[97.4 %]10
NiCo2S4/Co9S8 749 F g-1
at 4 A g-16 M KOH 5000
[78 %]11
Co9S8/α-MnS@N-C@MoS2
1938 F g-1
at 1 A g-12 M KOH 10000
[86.9 %]12
CuCo2O4 hollow spheres 1700 F g-1
at 2 A g-13 M KOH 5000
[93.7 %]13
FeCo2S4-NiCo2S4
composite1519 F g-1
at 5 mA cm-23 M KOH 5000
[95.1 %]14
Table S4. Comparison of other supercapacitors and this work.
Device Device window
Energy density
Power density
Cyclic stability
References
Hollow Zn0.76Co0.24S@C//RGO
1.6 V 55.47Wh kg-1
795.54W kg-1
100000[108%]
This work
Co3O4/ZnCo2O4/CuO//AC
1.6 V 35.82Wh kg-1
799.95W kg-1
3000[94.07%]
1
C-NiCo2O4
//AC1.6 V 38.3
Wh kg-1800
W kg-15 000
[95.6%]2
CoS1.097/GF//GF
1.5 V 33.2Wh kg-1
374.7W kg-1
10000[95.6%]
15
NiCo2O4@RGO//RGO
1.5 V 14.7Wh kg-1
175W kg-1
10000[81.1%]
9
MgCo2O4@PPy//AC
1.6 V 33.4Wh kg-1
320W kg-1
10000[91%]
10
NiCo2S4/Co9S8
//AC1.5 V 33.5
Wh kg-1150
W kg-15000[91%]
11
CuCo2O4 hollow spheres//AC
1.5 V 48.75Wh kg-1
500W kg-1
10000[91.2%]
13
Co3S4/CoMo2S4
//AC1.7 V 33.1
Wh kg-1850
W kg-15000
[93.8%]16
rGo-CNT-Co3S4
//NGN1.6 V 43.5
Wh kg-1400
W kg-13000[90%]
17
CoMo2S4/CuO//RGO/Fe2O3
1.6 V 33Wh kg-1
200W kg-1
5000[83%]
18
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