Post on 15-Nov-2021
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APPENDIX
RECOMMENDED SAFETY AND HANDLING PROCEDURE~
FOR LABORATORIES CONDUCTING PCDDPCDF ANALYSES
-24-
Recommended Safety and Handling Procedures in Connection with Implementing
the Analytical Protocal for Determination of PCDOPCDF in Combustion Products
1 The human toxicology of PCDOPCDF is not well defined at present although the 2378-TCOO isomer has been found ta be acnegenic carcinogenic and teratogenic in the course of laboratory animal studies The 2378-TCOO is a solid at room temperature anq has a relatively low vapor pressure The solubility of this compound in water is only about 200 parts-per-trill ion but the solubility in various organic solvents ranges from about 0001 to 014 The physical properties of the 135 other tetra-through octachlorinaed PCDDPCDF have not been well established although it is presumed that the physical properties of these congeners are generally similar to those of the 2middot137 8-TCDD isomer On the basis of the available toxicological and physical property data for TCDOthis compound as well as the other PCDD and PCOF should be handled only by highly trained personnelwho are thoroughly versed in the appropriate procedures and who understand the associated risks middot
middot2 PCDDPCDF and samples-containing these are haAdled using essentially the same techniques as those employed in handling radioactive or infectious materials Well-ventilated controlled-access laboratories are required amiddotnd laboratory personnel enter1119 these laboratories should wear appropriate safety clothing including disposable coveralls shoe covers gloves and face and head masks During analytical operatiqns which may give rise to aerosols or dusts personnel should wear respirators equipped with activated carbon filters Eye protection equipment (preferably full face shields) must be worn atall times while working in the analytical laboratory with PCDOPCDF middot Various middot types of gloves can be used by personnel depending upon the analytical operation being accomplished Latex gloves are generally utilized and when handling samples thought to be particularly hazardous an additional set of gloves is also worn beneath the latex gloves middot (for example Playtex gloves supplied by American Sci-entific Productsgt Cat No 67216) Bench-tops and other work surfaces in the laboratory should be covered with plastic-backed absorbent paper during all analytical processing When finely divided samples (dusts soil~ dry chemicals) are being processed removal of these from sample containers as well as other operations including weighing transferring and mixing with solvents should all be accomplished within a glove box Glove boxes hoods and the effluents from mechanical vacuum pumps and gas chromatographs on the mass spectrometers should be vented ta the atmosphere preferably only after passing through HEPA particulate filters and vapor-sorbing charcoal
3 All laboratory ware safety clothing and other items potentially contaminated with PCODPCDF in the course of analyses must be carefully secured and subjected to proper disposal When feasible liquid wastes
-25-
bullmiddot
( are concentrated and the residues are placed in approved steel hazardous waste drums fitted with heavy gauge polyethylene liners Glass and combustible items are compacted using a dedicated trash compactor used only for hazardous -waste materials and then placed in the same typeof disposal drum Disposal of accumulated wastes is periodicallyaccomplished by high temperature incineration at EPA-approved facilities
4 Surfaces middotof laboratory benches apparatus and other appropriate areas shouldmiddotbe periodically subjected to surface wipe tests using
middotsolvent-wetted filter paper which is then analyzed to check for PCDDPCDF contamination in the laboratory Typically if the detectable level of TCDD or TCDF from such a test is greater than 50ngm2 this iridicates the need for decontamination of the laboratory A typical action limit in terms of surface contamination of the other PCDDPCDF (summed)middot is 500ngm2
bull In the event of a spill within the laboratory ~bsorbent paper is used to wipe up the spilled material and this is then placedinto a hazardous waste drum The contaminated surface is subsequently cleaned thoroughly by washing with appropriate solvents (methylenechloride followed by methanol) andmiddotlaboratory detergents This is repeated until wipe tests indicate that the levels of surface contamination-are below the limits cited middot
5 In the unlikely event that analytical personnel experience skin contact with PCDDPCDF or samples containing these the contaminated skin area should immediately be thoroughly scrubbed using mild soap and water Personnel involved in any such accident should subsequentlybe taken to the nearest medical facility preferably a facility whose staff is knowledgable in the toxicology of chlorinated hydrocarbonsAgain disposal of contaminated clothing is accomplished by pladrg it in hazardous waste drums
6 It is desirable that personnel working in taboratories where PCODPCDF are handled be given periodic physical examinations (at least yearly) Such examinations should include specialized test~ such as those for urinary porphyrins and for certain blood parameterswhich based upon published clinical observations are appropriate for persons who may be exposed to PCDDPCDF Periodic facial photographs to document the onset of_dermatologic problems are also advisablebull
-26-
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BREHM LABORATORY - ~RJGHT STATE VERSITY - DAYTON OHIO 45435 DATE 822184 TIME 15182
middot KRATOS MS25 0S55 SOFTWARE RUN TOR40037 WSU NAMEa CHJ-218113 l 34 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODJBENZOFURANS
0101 l 1B7 2 14 _ ___________Jl--_l~_1---L--J___j_108 I --L-1---LL--1-~-
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71
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO -45435 DATE 022184 TIMEs 15102
KRATOS MS25t 0S55 SOFTWARE RUNr TOR40S37 WSU NAME CHJ-2lS113~ 1 34 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
ss 1187 2114 3 22 4 l 29 5137 6rU BB
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60
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KRATOS MS25 0S55 DATEt 022184 TIMEs 15111
SOFTWARE RUN1 TOR5003B WSU NAME CHJ2lB113~ 1 34 SELECTED-ION HASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
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0 34B 1BBXbulll67379 98
338 1BIXbulllB3B27
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488 1811bull1327 1B
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58 lB8 15B ZBB 25B 3BB 358 UB SCAN NUMBER
HRGC-LR~S AUAlvsls biiAiUib FOR CHEMecoloeiV SAMPLE MOAi FIGURE _44
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs 822184 TlMEs 1511
KRATOS MS25 0S55 SOFTWARE RUN1 TQR5BB3B WSU HAME1 CHJ-2lB1135 1 34 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
BdU 11S3 BS
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354 1BSXbull64278
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291 1BSXbull35931 7B
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50 1S0 150 200 250 303 35S 4IBSCAN NUHBR
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al FIGURE 1 45
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BREHM LABORATORY - WRIGHT STATE ~NIVERSITY - DAYTON OHIO 45435 OATE1 022184 TIME 15121
KRATOS HS25 0S55 SOFTWARE RUN1 TOR6003Z WSU NAME CHJ-2lB113~ 1 35 SELECTED-JON HASS CHROMATOGRAMS FOR HEXACHLORODJBENZOFURANS
BdJl 1 I 26 254 4121 51-49 7116 81U 18B I I
0 376 1BBXbull285B9 98
374 18Blbull36854
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444 1881bull969 7B
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20B 25B 38B
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA1 FJGURE 1 46
31
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90
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70
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50
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lB
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BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 I 26 2154
WRIGHT STATE UNIVERSITY - DAYTON OHIO 5435 DATE 022184 TIMEbull 15121
SOFTWARE RUN1 TOR6~032 WSU NAME CHJ-2101134 1 35 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4121 6149 7 I 16 eu 1-~___________________________~-~_______ _______-JL--____________ _ __c________~____________~_____________________________ _ __________
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39B lBBXbull111571
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68 111 15B ~ middot ~ 20S 25B 3BSSCAn HUMBcR
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-~ BREHM LABORATORY - WR1GHT STAT~ UNIVERSITY - DAYTON OHIO 4535
DATE 022184 TIME1 1531 KRATOS MS25 0S55 SOFTWARE RUN1 TOR70B31 WSU NAME1 CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODJBENZOFURANS
BaBl 1 BB 202 3104 4 B6 5108 6 I 11 713 BB
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE1 022184 TIME 15131
KRATOS MS25 0S55 SOFTWARE RUH1 TOR70031 WSU NAMEbull CHJ-210ll3~ 1 35 SELECTED-ION MASS CHROM~TOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
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90
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I -- - - - - 432 1BSXbull49142
I - - - - -bull 434 1BBibulll644S
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HRGC-L~Hs AkALVsis berAtkEb Fo~ ISU svN 100 120 UB
SAMPLE N02A1
188
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78
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58
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38
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bull 472 1BBXbull153225
128 13B
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BREHM LABORATORY - WRIGHT STAl~ JNIVERSITV - DAYTON OHIO 45435 DATE B22184 TIMEa 15a42
KRATOS MS25 0S55 SOFTWARE RUN TOR80038 WSU NAHEs CHJ-2lB1134 1 35 SELECTED-ION HASS CHRO~TOGRAHS FOR OCTACHLORODIBENZOFURANS
7d3 L1
71U 8115
148 158 168 SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMOCOLOGV FIGUREmiddot 50
a46 9 17 9148
178 181 i9B SAMPLE N02Al
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218
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45~35 DATE 822184 TIME 15i42
KRATOS MS25 DS55 SOFTWARE RUN TORB0S38 WSU NAME CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIOXINS
611 6142 7 I 13 7U 8d5 8146 9 r17 9e 18119 100
S 46B lB81bull12246 90
amp 458 1Bllbull11231 80
0 395 1SUbull6838 1B
1s 1BSXbull137939 68
bull 472 1BBXbull153225 58
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12B 138 14B 158 16B 171 lBS 198 2H SCAN NUMBER
HbullGc-LiM AHitvsi~ oe+AikEo iim cHtMocoLbG~ tAM~Lt No~1
FIGURE 51
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BREHM LABORATORY - WRIGHT 3(ATL ~NIVERSITV - DAYTON OHIO 45435 DATEt 022184 TIHEs 16128
KRATOS MS25 0S55 SOFTWARE RUN1 TOR43B38 WSU NAHEs CHJ-412133~ 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
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HRGC-LRMS ANALYSIS OBTAiNED FOR CHEMECOLOtV SAMPLE NO~A2 FIGURE 52
159 2BB 259 3BBSCAN NUMBER
29
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHlO 4b4Jb
DATE 022184 TIMEt 16128 KRATOS MS25 0S55 SOFTWARE RUNa TOR4BB38 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODlBEHZO-P-DlOXINS
0126 11S7 2 I 14 3t22 4129 5137 6U 180
90
80
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amp 320 1BBlbulllS9772
0 257 l081bull945259
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BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
206 3 10
YRIGHT SlATE ~NJVERSITV - DAYTON DATE 922184 TIMEs 16a37
SOFTWARE RUN1 TOR50B31 1 WSU NAHE1
OHIO 45435
CHJ-4121337 3 36 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
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HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2 FIGUREbull 54
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO s35 0ATEs S2218bull TIMEc 16137
KRATOS MS25 0S55 SOFTWARE RUNa TORSS031 WSU NAME1 CHJ-121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DlOXINS
0181 1 dJ3 2 dJ6 3t 11 4 I 13 5amp17 612S 7124 8127 180
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KRATOS MS25 0S55 SOFTWARE RUNs TOR68033 WSU NAHEa CHJ-4121337 3 36 SELECTED-ION HASS CHROMATOGRAMS ~OR HEXACHLORODIBENZOFUkANS
1s1 1126 254 4s21 Sa49 7116 81U
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTOM OHtomiddot 45435 OATEt 822184 TIMEbull 16147
KRATOS MS25 0S55 SOFTWARE RUN TOR6BB33 VSU NAMEt CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBEHZO-P-DIOXINS
BdJl l 1 26 2154 4amp21 5 I 9 7t16 eH 180
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HRQC-LRMS ANALYSIS oarAINEbFOR CHEHECOLOGV SAMPLE H02A2 ncUHa 57
BREHM LABORATORY - RIGHT s~middotATE --VERSITY - DAYTON OHIO 5435 DATE fl22184 TIMEr 1657
KRATOS MS25 0S55 SOFTWARE RUN TOR7~032 WSU NAMEs CHJ-4121331 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR
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SCAN NUMBER HRGC-LRMS AHALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2
FIGURE 58
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTON OHIO bull5435 OATEs B22184 TIME1 16167
lt KRATOS MS25 DS55 SOFTWARE RUNa TOR7SS32 ~SU HAMEa 2A2 SELECTED-ION MASS CHROMATOGkAMS FOR MEPTACHLOROOtBENZO-P-DlOXlNS
SdJl 1 tH 2 I 02 3 I 04 4t06 5 3 08 6amp11 7 a13 108
9S
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21
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amp 424 11Slbull23j27 middot------0 359 111bull12417
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BkEHM LBORATORV _ JRibHT STAT--INIVERSITY - DAYTON OHIO 45435 DATE 322 i TIME 1720
KRATOS MS25 0S55 SOFTWARE RUN1 TOR80039 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
-~
611 642 7 13 7 44 815 846 9 17 9148 18119 100 ________ 1-1 LiLJ ~
S 460 100bull14529 90
amp 458 1001bull12404 80
0 395 l801bull8383
70
470 1001bull128228 I60 0 N
472 1881bull136872 58
I N T E
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30
20
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120 130 140 150 160 SCAN NUMBER
170 188 ljS 2BB
HRGC-LRS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMlLE N02A2 FIGURE 61
-- - - - -
tKEr tUt1 i - middotIGHl SAli JItRSifr - OltY10N 1 OHIO 45435 -L fl22384 TIME 1J1l
KRAlG~ MS25 DS5S S0~TWARE RUNt TORbullas9 ~SU NAME1 CHJ-19202847 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
001 l 07 2 14 3122 429 537 6144 100 L --____L_______~_l--1__t----______________~
$ 306 100Xbull218713
90 I - l -2378amp ~~4~IJr 1_1mas
0 3H 18 bull1860
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ii ~8 llljfbull18898363
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332 10 bull136251 58
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33 T y
2B
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10B 15B 2B0 25B 3BB SCAN NUMBER
HRGC-lkMS ANALvili OBTAINED FOR CHEMECOLOGV sAuLE No26i FIGUREbull 134
250
100
90
80
70
60
50
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30
20
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BREHM LABORATORY
KRATOS MS25 DS55 SELECTED-ION MASS
0 a- 1 l S7 2 14 L _LJ_ _ _ _l--L_J_J___j__L___~J_y-- I I
$ 322 1001bull532633
amp 320 100Xbull404109
0 257 1BBXbull219683
328 1BBXbulll94431
~ 332 IBBXbull28B34
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HRGC-L~MS A~ALYiis oiTAINED FOR CHEMEcolOGY SAMPLE Mo2oi FIGURE 135
3BB
middotmiddot RIGHT STATE lY~ERSITV - DAYTON OHIO_ 4~435 DATE 022384 tIME 1739
SOFTWARE RUN1 TOR40052 WSU NAMEbull CHJ-192028 47 CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
322 4129 5s37 6144 ~-1--A--L---L-L--L--------J---------_______~ __-L-__________~__~__L-__~-----------_-+-
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A TE 0 21 2 3 1a4 TI ME 1 3 _g KRATC- MS25 fh5 Sv-TIARE RUN TOR5004f1 JSLl NAME CHJ-192028 4i SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
001 1 103 206 3 10 4 13 5 1 7 620 724 8127 l00 ~- L-J --ill~------1______--L--1--1--1--1----L-J-L-J-~I--L----L-L--l-~-1-JL-l--l--J_L-__L-L-1-L-_j______J_J__j__l___i_J_J__J__Jl-i_I-J-L-L~1-1-_L___L--L---L-1--1-J__J__JL-L-l_L-J_4--+-
0 340 l00Xbull270473 90
338 l00Xbull158177
80
tSS 180Xbull3262 1B
I 0 N
60
I N T E N
SB
s
SB 100 15B 200SCAN NUMBER
Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
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30
2B
lB
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250 300 3U UB
sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
I 0 N
I N T E N s 1 T V
UJjJ
9B
SB
7B
6B
58
0
30
20
lB
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51 ISI 15B 2BBSCAN NUMBER
MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
u
38
2B
18
B
-t--L- - JJ_L-L---L-_J_~__J-L-L-1-_J_----L-~~_~_____---J____L_______~L-------~
0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
I N T E N s I T y
3BB
urn_
98
as
7B
6B
50
uJ
30
2B
1e
B
~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
I N T E N s I T V
58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
2B
lB
B
001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
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amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
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I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
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C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
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20
lB
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HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
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H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
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I 0 N
6B I N T E N
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200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
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30
20
1B
0
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OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
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--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
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S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
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n~r -------- - - - - - -0 478 18BXbull922
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
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1
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S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
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68
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30
10
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~~~~ ~~~~-~
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
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18
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tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
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58 I N T E N
u s I T38 y
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S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
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Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
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bull 332 100Xbull139676 50 I
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lB
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SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
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amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
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50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
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28
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61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
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28
18
4 I 21 5r49 7 I 16 au
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I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
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2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
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----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
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10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
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HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
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--
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6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
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30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
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~ 50
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3S
20
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bull 472 IOOXbull134721
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~-
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middotbullI
I 0 N
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KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
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9B
es
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0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
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I6B 0 N
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30
20
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f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
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3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
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98
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488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
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SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
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KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
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291
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10SXbull~J((1
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2 dY6
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250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
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6B
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4 21 549 7 I 16 su I
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I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
Recommended Safety and Handling Procedures in Connection with Implementing
the Analytical Protocal for Determination of PCDOPCDF in Combustion Products
1 The human toxicology of PCDOPCDF is not well defined at present although the 2378-TCOO isomer has been found ta be acnegenic carcinogenic and teratogenic in the course of laboratory animal studies The 2378-TCOO is a solid at room temperature anq has a relatively low vapor pressure The solubility of this compound in water is only about 200 parts-per-trill ion but the solubility in various organic solvents ranges from about 0001 to 014 The physical properties of the 135 other tetra-through octachlorinaed PCDDPCDF have not been well established although it is presumed that the physical properties of these congeners are generally similar to those of the 2middot137 8-TCDD isomer On the basis of the available toxicological and physical property data for TCDOthis compound as well as the other PCDD and PCOF should be handled only by highly trained personnelwho are thoroughly versed in the appropriate procedures and who understand the associated risks middot
middot2 PCDDPCDF and samples-containing these are haAdled using essentially the same techniques as those employed in handling radioactive or infectious materials Well-ventilated controlled-access laboratories are required amiddotnd laboratory personnel enter1119 these laboratories should wear appropriate safety clothing including disposable coveralls shoe covers gloves and face and head masks During analytical operatiqns which may give rise to aerosols or dusts personnel should wear respirators equipped with activated carbon filters Eye protection equipment (preferably full face shields) must be worn atall times while working in the analytical laboratory with PCDOPCDF middot Various middot types of gloves can be used by personnel depending upon the analytical operation being accomplished Latex gloves are generally utilized and when handling samples thought to be particularly hazardous an additional set of gloves is also worn beneath the latex gloves middot (for example Playtex gloves supplied by American Sci-entific Productsgt Cat No 67216) Bench-tops and other work surfaces in the laboratory should be covered with plastic-backed absorbent paper during all analytical processing When finely divided samples (dusts soil~ dry chemicals) are being processed removal of these from sample containers as well as other operations including weighing transferring and mixing with solvents should all be accomplished within a glove box Glove boxes hoods and the effluents from mechanical vacuum pumps and gas chromatographs on the mass spectrometers should be vented ta the atmosphere preferably only after passing through HEPA particulate filters and vapor-sorbing charcoal
3 All laboratory ware safety clothing and other items potentially contaminated with PCODPCDF in the course of analyses must be carefully secured and subjected to proper disposal When feasible liquid wastes
-25-
bullmiddot
( are concentrated and the residues are placed in approved steel hazardous waste drums fitted with heavy gauge polyethylene liners Glass and combustible items are compacted using a dedicated trash compactor used only for hazardous -waste materials and then placed in the same typeof disposal drum Disposal of accumulated wastes is periodicallyaccomplished by high temperature incineration at EPA-approved facilities
4 Surfaces middotof laboratory benches apparatus and other appropriate areas shouldmiddotbe periodically subjected to surface wipe tests using
middotsolvent-wetted filter paper which is then analyzed to check for PCDDPCDF contamination in the laboratory Typically if the detectable level of TCDD or TCDF from such a test is greater than 50ngm2 this iridicates the need for decontamination of the laboratory A typical action limit in terms of surface contamination of the other PCDDPCDF (summed)middot is 500ngm2
bull In the event of a spill within the laboratory ~bsorbent paper is used to wipe up the spilled material and this is then placedinto a hazardous waste drum The contaminated surface is subsequently cleaned thoroughly by washing with appropriate solvents (methylenechloride followed by methanol) andmiddotlaboratory detergents This is repeated until wipe tests indicate that the levels of surface contamination-are below the limits cited middot
5 In the unlikely event that analytical personnel experience skin contact with PCDDPCDF or samples containing these the contaminated skin area should immediately be thoroughly scrubbed using mild soap and water Personnel involved in any such accident should subsequentlybe taken to the nearest medical facility preferably a facility whose staff is knowledgable in the toxicology of chlorinated hydrocarbonsAgain disposal of contaminated clothing is accomplished by pladrg it in hazardous waste drums
6 It is desirable that personnel working in taboratories where PCODPCDF are handled be given periodic physical examinations (at least yearly) Such examinations should include specialized test~ such as those for urinary porphyrins and for certain blood parameterswhich based upon published clinical observations are appropriate for persons who may be exposed to PCDDPCDF Periodic facial photographs to document the onset of_dermatologic problems are also advisablebull
-26-
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338 l00Xbull158177
80
tSS 180Xbull3262 1B
I 0 N
60
I N T E N
SB
s
SB 100 15B 200SCAN NUMBER
Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
I Tu y
30
2B
lB
B
250 300 3U UB
sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
I 0 N
I N T E N s 1 T V
UJjJ
9B
SB
7B
6B
58
0
30
20
lB
B
51 ISI 15B 2BBSCAN NUMBER
MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
u
38
2B
18
B
-t--L- - JJ_L-L---L-_J_~__J-L-L-1-_J_----L-~~_~_____---J____L_______~L-------~
0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
I N T E N s I T y
3BB
urn_
98
as
7B
6B
50
uJ
30
2B
1e
B
~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
I N T E N s I T V
58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
2B
lB
B
001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
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ZB
1e
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12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
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3B
28
lB
bull
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amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
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I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
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lB
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amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
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58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
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C18 1IB1bull181 7B
I 0 N
u I N T E N
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20
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HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
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H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
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I 0 N
6B I N T E N
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SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
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30
20
1B
0
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OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
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KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
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S 4 U UJUbull5527
90
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
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1
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S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
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~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
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~~~~ ~~~~-~
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
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tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
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58 I N T E N
u s I T38 y
20
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S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
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kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
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SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
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KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
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S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
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50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
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10
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61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
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28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
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2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
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----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
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10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
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90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
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HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
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6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
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30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
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4lll 1B0Xbull126296 60
~ 50
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middotbullI
I 0 N
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
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0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
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I6B 0 N
SB I N T s E N s I T V
30
20
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f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
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3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
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338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
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10SXbull~J((1
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SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
B
50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
I N T E N s I T V
3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
bullmiddot
( are concentrated and the residues are placed in approved steel hazardous waste drums fitted with heavy gauge polyethylene liners Glass and combustible items are compacted using a dedicated trash compactor used only for hazardous -waste materials and then placed in the same typeof disposal drum Disposal of accumulated wastes is periodicallyaccomplished by high temperature incineration at EPA-approved facilities
4 Surfaces middotof laboratory benches apparatus and other appropriate areas shouldmiddotbe periodically subjected to surface wipe tests using
middotsolvent-wetted filter paper which is then analyzed to check for PCDDPCDF contamination in the laboratory Typically if the detectable level of TCDD or TCDF from such a test is greater than 50ngm2 this iridicates the need for decontamination of the laboratory A typical action limit in terms of surface contamination of the other PCDDPCDF (summed)middot is 500ngm2
bull In the event of a spill within the laboratory ~bsorbent paper is used to wipe up the spilled material and this is then placedinto a hazardous waste drum The contaminated surface is subsequently cleaned thoroughly by washing with appropriate solvents (methylenechloride followed by methanol) andmiddotlaboratory detergents This is repeated until wipe tests indicate that the levels of surface contamination-are below the limits cited middot
5 In the unlikely event that analytical personnel experience skin contact with PCDDPCDF or samples containing these the contaminated skin area should immediately be thoroughly scrubbed using mild soap and water Personnel involved in any such accident should subsequentlybe taken to the nearest medical facility preferably a facility whose staff is knowledgable in the toxicology of chlorinated hydrocarbonsAgain disposal of contaminated clothing is accomplished by pladrg it in hazardous waste drums
6 It is desirable that personnel working in taboratories where PCODPCDF are handled be given periodic physical examinations (at least yearly) Such examinations should include specialized test~ such as those for urinary porphyrins and for certain blood parameterswhich based upon published clinical observations are appropriate for persons who may be exposed to PCDDPCDF Periodic facial photographs to document the onset of_dermatologic problems are also advisablebull
-26-
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291 lS01bull261351
I 0 N
I N T E N s 1 T V
UJjJ
9B
SB
7B
6B
58
0
30
20
lB
B
51 ISI 15B 2BBSCAN NUMBER
MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
u
38
2B
18
B
-t--L- - JJ_L-L---L-_J_~__J-L-L-1-_J_----L-~~_~_____---J____L_______~L-------~
0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
I N T E N s I T y
3BB
urn_
98
as
7B
6B
50
uJ
30
2B
1e
B
~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
I N T E N s I T V
58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
2B
lB
B
001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
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3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
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S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
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23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
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SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
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58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
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3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
----------
----------
--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
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S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
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n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
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432 1881bull 1872 60 I - - - - - - - - - - - - - ------- - - - - - - l-1 - - _L
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U -1 IJ II ll I E N s
I 3f -I l y V A A I I l T I
h y
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18
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1 28 uJ 68 SB lBB 128 usSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
~~ --
S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
5g
s
30
10
20
vi ~~~ B
~~~~ ~~~~-~
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zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
B
U 78 8B 98 lBB 110 128 SCAN NUMBER
tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
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58 I N T E N
u s I T38 y
20
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u 58 110 120
S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
Ift I~
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r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
8J
l j 11
7B
328 1BBlbull18B436
I - [ 0
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bull 332 100Xbull139676 50 I
NJ ij1 T
EU ~~ I I I
I
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3B ~ Imiddotmiddot 1~12B
lB
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__
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I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
B
S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
I N T E N s I T v-
50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
10
s
61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
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I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
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48 l1
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30
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I r--rmiddot I middotr middot-rmiddotmiddot middotmiddotr--
12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
-~ I --~ ______ y------ -(j
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--
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DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
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30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
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bull 472 IOOXbull134721
E N s I TI I y
1
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~-
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middotbullI
I 0 N
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~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
I N T E N s I T y
3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
AB
38
2B
10
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0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
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--1 - - - - - - - - - - - - - - - -
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250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
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50
middotmiddot1 I
100 150 200 25B I I I f r-r-
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3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
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SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
I N T E N s I T V
58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
2B
lB
B
001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
B
S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
-i
I
23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
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C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
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31
20
lB
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SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
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5S
N s I Tu y
30
21
11
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58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
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I 0 N
6B I N T E N
SB
s I
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3B
2B
J ~
VV lB
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SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
----------
----------
--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
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S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
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n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
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432 1881bull 1872 60 I - - - - - - - - - - - - - ------- - - - - - - l-1 - - _L
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18
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1 28 uJ 68 SB lBB 128 usSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
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S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
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30
10
20
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~~~~ ~~~~-~
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zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
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tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
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58 I N T E N
u s I T38 y
20
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S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
Ift I~
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r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
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l j 11
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328 1BBlbull18B436
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bull 332 100Xbull139676 50 I
NJ ij1 T
EU ~~ I I I
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3B ~ Imiddotmiddot 1~12B
lB
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I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
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S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
I N T E N s I T v-
50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
10
s
61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
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I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
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30
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12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
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--
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DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
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30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
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bull 472 IOOXbull134721
E N s I TI I y
1
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middotbullI
I 0 N
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
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u
38
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wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
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L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
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SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
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KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
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--1 - - - - - - - - - - - - - - - -
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250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
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BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
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6B
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middotmiddot1 I
100 150 200 25B I I I f r-r-
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
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CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
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wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
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SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
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31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
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us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
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t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
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KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
2B
lB
B
001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
B
S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
-i
I
23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
B
SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
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58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
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3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
----------
----------
--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
UJ0
S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
__ -1--
n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
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432 1881bull 1872 60 I - - - - - - - - - - - - - ------- - - - - - - l-1 - - _L
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U -1 IJ II ll I E N s
I 3f -I l y V A A I I l T I
h y
I2B I I I I - M I I AU l I V I t 1
18
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1 28 uJ 68 SB lBB 128 usSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
~~ --
S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
5g
s
30
10
20
vi ~~~ B
~~~~ ~~~~-~
~___-- ~~~~---- - r--
zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
B
U 78 8B 98 lBB 110 128 SCAN NUMBER
tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
I6B 0 N
58 I N T E N
u s I T38 y
20
10
0
u 58 110 120
S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
~~ 60 1s as 90 t00
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
Ift I~
------------------1-
r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
8J
l j 11
7B
328 1BBlbull18B436
I - [ 0
66 N
bull 332 100Xbull139676 50 I
NJ ij1 T
EU ~~ I I I
I
N st ~ j
T V
3B ~ Imiddotmiddot 1~12B
lB
B
__
---- ________
I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
B
S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
I N T E N s I T v-
50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
10
s
61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
I 0 N
I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
n1 N T E N
48 l1
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30
26
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B II
I r--rmiddot I middotr middot-rmiddotmiddot middotmiddotr--
12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
-~ I --~ ______ y------ -(j
-middot-r==r~~ middotmiddotr- - middot 1- -Tr-----r- bull -I
--
iilt11i) L4blbullKAIUlY - ~ ll1HI gtutt UliJtICgt Iyen - uhyen _111 1tl1U +0+)J
DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
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___L__l_JJ__I 1 H 0 10 flt Xbull 17 8 9 4 1
30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
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bull 472 IOOXbull134721
E N s I TI I y
1
----------------------- II I k------ ------- ------------- I r---__~-------------_____ middot-~---------~~----- ----------~~ --- -~ -
J
-___
-------- middot--------middot--bull-middotmiddotmiddot--- ---middot middot- middot-------------
~-
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middotbullI
I 0 N
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~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
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3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
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38
2B
10
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0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
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I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
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--1 - - - - - - - - - - - - - - - -
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SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
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50
middotmiddot1 I
100 150 200 25B I I I f r-r-
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3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
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CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
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31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
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us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
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~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO -45435 DATE 022184 TIMEs 15102
KRATOS MS25t 0S55 SOFTWARE RUNr TOR40S37 WSU NAME CHJ-2lS113~ 1 34 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
ss 1187 2114 3 22 4 l 29 5137 6rU BB
9S
SB
7B
60
SB
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2se 25B 3BB3B 6B lSB 160 SCAN NUMBER
H~e-L~~$ AHAlvsis betAIHED ~OR CHEMtcoLOG~ sAM~lt ko2At F lGUFlEmiddotr 43
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BREHM LABORATORY - ~RIGHT STATE iVERSITV - DAYTON OHIO 45435
KRATOS MS25 0S55 DATEt 022184 TIMEs 15111
SOFTWARE RUN1 TOR5003B WSU NAME CHJ2lB113~ 1 34 SELECTED-ION HASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
e 01 1 13 2 06 3 10 4113 517 620 7124 8127 UJB _____-L-~--L-L~I ~J_____-~bull_____~___ampJLJ--L--L-1JL_JL-L-J--L--L-LJ--J_-L-L-JLL--L--L-L--1-JL-L-Jl-J-J-L-----L~L-L-Jl-----I--LL----LLL-lI
0 34B 1BBXbulll67379 98
338 1BIXbulllB3B27
88
488 1811bull1327 1B
6B
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48
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28
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58 lB8 15B ZBB 25B 3BB 358 UB SCAN NUMBER
HRGC-LR~S AUAlvsls biiAiUib FOR CHEMecoloeiV SAMPLE MOAi FIGURE _44
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs 822184 TlMEs 1511
KRATOS MS25 0S55 SOFTWARE RUN1 TQR5BB3B WSU HAME1 CHJ-2lB1135 1 34 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
BdU 11S3 BS
0 356 lBBXbulll02464 98
354 1BSXbull64278
SB
291 1BSXbull35931 7B
6B
se
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s
2s6 3 sl0 4 r 13 517 6120 724 8127
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50 1S0 150 200 250 303 35S 4IBSCAN NUHBR
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al FIGURE 1 45
-----
BREHM LABORATORY - WRIGHT STATE ~NIVERSITY - DAYTON OHIO 45435 OATE1 022184 TIME 15121
KRATOS HS25 0S55 SOFTWARE RUN1 TOR6003Z WSU NAME CHJ-2lB113~ 1 35 SELECTED-JON HASS CHROMATOGRAMS FOR HEXACHLORODJBENZOFURANS
BdJl 1 I 26 254 4121 51-49 7116 81U 18B I I
0 376 1BBXbull285B9 98
374 18Blbull36854
8B
444 1881bull969 7B
J 0 N
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38
2B
1B
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1 50 IBB ~SB SCAN NUMBER
20B 25B 38B
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA1 FJGURE 1 46
31
SS
90
as
70
6B
50
u
2B
lB
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BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 I 26 2154
WRIGHT STATE UNIVERSITY - DAYTON OHIO 5435 DATE 022184 TIMEbull 15121
SOFTWARE RUN1 TOR6~032 WSU NAME CHJ-2101134 1 35 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4121 6149 7 I 16 eu 1-~___________________________~-~_______ _______-JL--____________ _ __c________~____________~_____________________________ _ __________
0 392 1BBXbullB8671
39B lBBXbull111571
bull 329 188Xbull366B
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- - - -
-~ BREHM LABORATORY - WR1GHT STAT~ UNIVERSITY - DAYTON OHIO 4535
DATE 022184 TIME1 1531 KRATOS MS25 0S55 SOFTWARE RUN1 TOR70B31 WSU NAME1 CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODJBENZOFURANS
BaBl 1 BB 202 3104 4 B6 5108 6 I 11 713 BB
91
8B
71
61
6B
41
31
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amp 408 1BBXbull1Bl73
0 478 1BnbullU9
432 l001bull49142
~34 1BBXbulll644I
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2B 40 6B BB lB8 12B us SCAN NUMBER
HlaquoG~-LiHi AUAlvsii bifAfNE6 foi ISU svM ~AM-LE Uo2Ai FJGURE 1 48
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE1 022184 TIME 15131
KRATOS MS25 0S55 SOFTWARE RUH1 TOR70031 WSU NAMEbull CHJ-210ll3~ 1 35 SELECTED-ION MASS CHROM~TOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
0 I 0 11BB 2 102 3 I 04 4106 5108 611 7113 80
90
89
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11
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$ H6 1BUbull9771
I - -- - - - -amp 424 1BBXbulllB264
I -- - - - -0 359 l9Ubull6161
I -- - - - - 432 1BSXbull49142
I - - - - -bull 434 1BBibulll644S
I
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HRGC-L~Hs AkALVsis berAtkEb Fo~ ISU svN 100 120 UB
SAMPLE N02A1
188
9B
a
78
6B
58
4B
38
2B
1B
bull
1
6 al 1 6142
----1-----------------~ S 444 1BBXbull1BB72
amp 442 1B8Xbull1B157 ~ - - - -0 512 lB81bull2511
478 1BBXbull137939
bull 472 1BBXbull153225
128 13B
~lt
BREHM LABORATORY - WRIGHT STAl~ JNIVERSITV - DAYTON OHIO 45435 DATE B22184 TIMEa 15a42
KRATOS MS25 0S55 SOFTWARE RUN TOR80038 WSU NAHEs CHJ-2lB1134 1 35 SELECTED-ION HASS CHRO~TOGRAHS FOR OCTACHLORODIBENZOFURANS
7d3 L1
71U 8115
148 158 168 SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMOCOLOGV FIGUREmiddot 50
a46 9 17 9148
178 181 i9B SAMPLE N02Al
l819
218
I 0 N
I N T E N s I T V
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45~35 DATE 822184 TIME 15i42
KRATOS MS25 DS55 SOFTWARE RUN TORB0S38 WSU NAME CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIOXINS
611 6142 7 I 13 7U 8d5 8146 9 r17 9e 18119 100
S 46B lB81bull12246 90
amp 458 1Bllbull11231 80
0 395 1SUbull6838 1B
1s 1BSXbull137939 68
bull 472 1BBXbull153225 58
3B
2S
lB
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I 0 N
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12B 138 14B 158 16B 171 lBS 198 2H SCAN NUMBER
HbullGc-LiM AHitvsi~ oe+AikEo iim cHtMocoLbG~ tAM~Lt No~1
FIGURE 51
l
----
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BREHM LABORATORY - WRIGHT 3(ATL ~NIVERSITV - DAYTON OHIO 45435 DATEt 022184 TIHEs 16128
KRATOS MS25 0S55 SOFTWARE RUN1 TOR43B38 WSU NAHEs CHJ-412133~ 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B26 100 ~ _
S 306 91J --
amp 304 as
0 374
1B 328
68
332H
b
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28
19
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bull bull -bull~ ___ bull 1--L --1-
lB01bull1252541
1BBXbull1BB7291
1BUbullC2
lBBXbull38lnB9
1B8Xbull12~9CC
=
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~-~ l LJ--L__L -~-1II -2378 _
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HRGC-LRMS ANALYSIS OBTAiNED FOR CHEMECOLOtV SAMPLE NO~A2 FIGURE 52
159 2BB 259 3BBSCAN NUMBER
29
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHlO 4b4Jb
DATE 022184 TIMEt 16128 KRATOS MS25 0S55 SOFTWARE RUNa TOR4BB38 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODlBEHZO-P-DlOXINS
0126 11S7 2 I 14 3t22 4129 5137 6U 180
90
80
7B
6B
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40
30
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18
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~~
$ 322 l0BXbulll39545
amp 320 1BBlbulllS9772
0 257 l081bull945259
328 1081bull381189
bull 332 l801bull127044
I ~
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~~~L~iij bii~l~ib oi cHiM~c6lo~~ sA~~Li
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1 0 N
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98
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8 s81 1 I f3
0 340 lBBlbulllB59189
338 1881bull685876
488 bSBlbull392
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
206 3 10
YRIGHT SlATE ~NJVERSITV - DAYTON DATE 922184 TIMEs 16a37
SOFTWARE RUN1 TOR50B31 1 WSU NAHE1
OHIO 45435
CHJ-4121337 3 36 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 a 13 517 6120 7s24 8127
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lBB 158 280 25B 3BB 358 4BBSCAN NUMBER
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2 FIGUREbull 54
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO s35 0ATEs S2218bull TIMEc 16137
KRATOS MS25 0S55 SOFTWARE RUNa TORSS031 WSU NAME1 CHJ-121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DlOXINS
0181 1 dJ3 2 dJ6 3t 11 4 I 13 5amp17 612S 7124 8127 180
0 356 llBXbulll95796 99
3sbull 11r amp1s1
a - - - - - - - - - - - __ - - - - - - - - 291 1BBlbull76689
7B t 0 N
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61 1e 150 209 281 3BS 3~- SCAN HUMBER
ubull~l-LiMs AULVlfl 6fAfUt6 IBA tUfMfc6l~V IAUlf Uo2~2 FtGUltEt 55
--
BREHM ~ABORATORV - WRIGHT STAT~ ~~IVERSlTV - DAYTON OHIO 4535 DATEa S22184 TIHEz 10147
KRATOS MS25 0S55 SOFTWARE RUNs TOR68033 WSU NAHEa CHJ-4121337 3 36 SELECTED-ION HASS CHROMATOGRAMS ~OR HEXACHLORODIBENZOFUkANS
1s1 1126 254 4s21 Sa49 7116 81U
188
98
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18
51
31
21
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0 376 lBBlbulll15658
37-4 1SSSbull93483
bull u 1bullbullbullbull781
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FlGUREt 56
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTOM OHtomiddot 45435 OATEt 822184 TIMEbull 16147
KRATOS MS25 0S55 SOFTWARE RUN TOR6BB33 VSU NAMEt CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBEHZO-P-DIOXINS
BdJl l 1 26 2154 4amp21 5 I 9 7t16 eH 180
0 392 lSUbull-43858 91
396 18Slbull661ll
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329 1811bull31738 7B
6f
68
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38
28
18
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HRQC-LRMS ANALYSIS oarAINEbFOR CHEHECOLOGV SAMPLE H02A2 ncUHa 57
BREHM LABORATORY - RIGHT s~middotATE --VERSITY - DAYTON OHIO 5435 DATE fl22184 TIMEr 1657
KRATOS MS25 0S55 SOFTWARE RUN TOR7~032 WSU NAMEs CHJ-4121331 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR
BrBl l 00 2B2 3 04 4dJ6 U0 -r--~_______~~______~----L~_L__1---l-L -~-----___________-----4-___________~ I S 18 J88Xbull3lJ056 98 tamp 88 188Xbull31639 _______ -tSB
70 ldeg ~8~088~ - - - - - - - _ ~ 6S - ~ - A - - --1 ~2~m-~z~
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SCAN NUMBER HRGC-LRMS AHALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2
FIGURE 58
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTON OHIO bull5435 OATEs B22184 TIME1 16167
lt KRATOS MS25 DS55 SOFTWARE RUNa TOR7SS32 ~SU HAMEa 2A2 SELECTED-ION MASS CHROMATOGkAMS FOR MEPTACHLOROOtBENZO-P-DlOXlNS
SdJl 1 tH 2 I 02 3 I 04 4t06 5 3 08 6amp11 7 a13 108
9S
ee
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21
18
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S 426 1BISbull21755
amp 424 11Slbull23j27 middot------0 359 111bull12417
bull 43 1Hrbull49amp29
43 1111bull16172
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HRd~-Li~sect AUAL~tsect 61~Al~ED -bi CHEMEcototV sAM~lE UotUJ-1~t3~7 3 36 f I GUREmiddott 59
BkEHM LBORATORV _ JRibHT STAT--INIVERSITY - DAYTON OHIO 45435 DATE 322 i TIME 1720
KRATOS MS25 0S55 SOFTWARE RUN1 TOR80039 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
-~
611 642 7 13 7 44 815 846 9 17 9148 18119 100 ________ 1-1 LiLJ ~
S 460 100bull14529 90
amp 458 1001bull12404 80
0 395 l801bull8383
70
470 1001bull128228 I60 0 N
472 1881bull136872 58
I N T E
f N s
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30
20
10
0
-------~ I
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120 130 140 150 160 SCAN NUMBER
170 188 ljS 2BB
HRGC-LRS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMlLE N02A2 FIGURE 61
-- - - - -
tKEr tUt1 i - middotIGHl SAli JItRSifr - OltY10N 1 OHIO 45435 -L fl22384 TIME 1J1l
KRAlG~ MS25 DS5S S0~TWARE RUNt TORbullas9 ~SU NAME1 CHJ-19202847 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
001 l 07 2 14 3122 429 537 6144 100 L --____L_______~_l--1__t----______________~
$ 306 100Xbull218713
90 I - l -2378amp ~~4~IJr 1_1mas
0 3H 18 bull1860
7B
ii ~8 llljfbull18898363
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332 10 bull136251 58
I N T
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33 T y
2B
l 3
B
10B 15B 2B0 25B 3BB SCAN NUMBER
HRGC-lkMS ANALvili OBTAINED FOR CHEMECOLOGV sAuLE No26i FIGUREbull 134
250
100
90
80
70
60
50
U
30
20
UJ
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BREHM LABORATORY
KRATOS MS25 DS55 SELECTED-ION MASS
0 a- 1 l S7 2 14 L _LJ_ _ _ _l--L_J_J___j__L___~J_y-- I I
$ 322 1001bull532633
amp 320 100Xbull404109
0 257 1BBXbull219683
328 1BBXbulll94431
~ 332 IBBXbull28B34
I~
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--___ ~~- J
SB
-------_-----------------------------~
lBB 150 200 SCAN NUMBER
HRGC-L~MS A~ALYiis oiTAINED FOR CHEMEcolOGY SAMPLE Mo2oi FIGURE 135
3BB
middotmiddot RIGHT STATE lY~ERSITV - DAYTON OHIO_ 4~435 DATE 022384 tIME 1739
SOFTWARE RUN1 TOR40052 WSU NAMEbull CHJ-192028 47 CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
322 4129 5s37 6144 ~-1--A--L---L-L--L--------J---------_______~ __-L-__________~__~__L-__~-----------_-+-
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A TE 0 21 2 3 1a4 TI ME 1 3 _g KRATC- MS25 fh5 Sv-TIARE RUN TOR5004f1 JSLl NAME CHJ-192028 4i SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
001 1 103 206 3 10 4 13 5 1 7 620 724 8127 l00 ~- L-J --ill~------1______--L--1--1--1--1----L-J-L-J-~I--L----L-L--l-~-1-JL-l--l--J_L-__L-L-1-L-_j______J_J__j__l___i_J_J__J__Jl-i_I-J-L-L~1-1-_L___L--L---L-1--1-J__J__JL-L-l_L-J_4--+-
0 340 l00Xbull270473 90
338 l00Xbull158177
80
tSS 180Xbull3262 1B
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60
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SB
s
SB 100 15B 200SCAN NUMBER
Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
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30
2B
lB
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250 300 3U UB
sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
I 0 N
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UJjJ
9B
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58
0
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MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
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38
2B
18
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-t--L- - JJ_L-L---L-_J_~__J-L-L-1-_J_----L-~~_~_____---J____L_______~L-------~
0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
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3BB
urn_
98
as
7B
6B
50
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~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
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58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
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48
38
28
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0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
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- - - - -
100
90
80
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50
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LmL1111 _ UVl1-IVIY
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202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
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u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
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128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
B
S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
-i
I
23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
B
SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
B
58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
T V
3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
----------
----------
--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
UJ0
S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
__ -1--
n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
___J_ - - - - - - - -
432 1881bull 1872 60 I - - - - - - - - - - - - - ------- - - - - - - l-1 - - _L
0 1
N 434 l081bull3567 58 I
lT
1 N
U -1 IJ II ll I E N s
I 3f -I l y V A A I I l T I
h y
I2B I I I I - M I I AU l I V I t 1
18
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1 28 uJ 68 SB lBB 128 usSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
~~ --
S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
5g
s
30
10
20
vi ~~~ B
~~~~ ~~~~-~
~___-- ~~~~---- - r--
zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
B
U 78 8B 98 lBB 110 128 SCAN NUMBER
tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
I6B 0 N
58 I N T E N
u s I T38 y
20
10
0
u 58 110 120
S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
~~ 60 1s as 90 t00
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
Ift I~
------------------1-
r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
8J
l j 11
7B
328 1BBlbull18B436
I - [ 0
66 N
bull 332 100Xbull139676 50 I
NJ ij1 T
EU ~~ I I I
I
N st ~ j
T V
3B ~ Imiddotmiddot 1~12B
lB
B
__
---- ________
I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
B
S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
I N T E N s I T v-
50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
10
s
61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
I 0 N
I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
n1 N T E N
48 l1
~ s I T V
30
26
I II I
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J-1middot I
B II
I r--rmiddot I middotr middot-rmiddotmiddot middotmiddotr--
12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
-~ I --~ ______ y------ -(j
-middot-r==r~~ middotmiddotr- - middot 1- -Tr-----r- bull -I
--
iilt11i) L4blbullKAIUlY - ~ ll1HI gtutt UliJtICgt Iyen - uhyen _111 1tl1U +0+)J
DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
-l)--
___L__l_JJ__I 1 H 0 10 flt Xbull 17 8 9 4 1
30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
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bull 472 IOOXbull134721
E N s I TI I y
1
----------------------- II I k------ ------- ------------- I r---__~-------------_____ middot-~---------~~----- ----------~~ --- -~ -
J
-___
-------- middot--------middot--bull-middotmiddotmiddot--- ---middot middot- middot-------------
~-
----r-middotmiddotr- r-r-rmiddotrr- I I I I I I I Tl-T I I I I I I I I r= I middot ------r-------rmiddot- r r ~r--iT middotr-i 1~middot11-----r-r-r I I I -r-r-+
middotbullI
I 0 N
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~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
I N T E N s I T y
3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
AB
38
2B
10
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0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
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28
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JI 0 ( I 13 5 I 1 7 6120 7s2( 8t27
--1 - - - - - - - - - - - - - - - -
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250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
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50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
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3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
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CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
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50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
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170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
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r11111w It 1 11 j
i M bull
I
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uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
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1jmiddot ~j Iv fv i
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28
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r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
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~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
--- _
BREHM LABORATORY - ~RIGHT STATE iVERSITV - DAYTON OHIO 45435
KRATOS MS25 0S55 DATEt 022184 TIMEs 15111
SOFTWARE RUN1 TOR5003B WSU NAME CHJ2lB113~ 1 34 SELECTED-ION HASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
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KRATOS MS25 0S55 SOFTWARE RUN1 TQR5BB3B WSU HAME1 CHJ-2lB1135 1 34 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
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-----
BREHM LABORATORY - WRIGHT STATE ~NIVERSITY - DAYTON OHIO 45435 OATE1 022184 TIME 15121
KRATOS HS25 0S55 SOFTWARE RUN1 TOR6003Z WSU NAME CHJ-2lB113~ 1 35 SELECTED-JON HASS CHROMATOGRAMS FOR HEXACHLORODJBENZOFURANS
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA1 FJGURE 1 46
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WRIGHT STATE UNIVERSITY - DAYTON OHIO 5435 DATE 022184 TIMEbull 15121
SOFTWARE RUN1 TOR6~032 WSU NAME CHJ-2101134 1 35 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
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DATE 022184 TIME1 1531 KRATOS MS25 0S55 SOFTWARE RUN1 TOR70B31 WSU NAME1 CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODJBENZOFURANS
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HlaquoG~-LiHi AUAlvsii bifAfNE6 foi ISU svM ~AM-LE Uo2Ai FJGURE 1 48
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE1 022184 TIME 15131
KRATOS MS25 0S55 SOFTWARE RUH1 TOR70031 WSU NAMEbull CHJ-210ll3~ 1 35 SELECTED-ION MASS CHROM~TOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
0 I 0 11BB 2 102 3 I 04 4106 5108 611 7113 80
90
89
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$ H6 1BUbull9771
I - -- - - - -amp 424 1BBXbulllB264
I -- - - - -0 359 l9Ubull6161
I -- - - - - 432 1BSXbull49142
I - - - - -bull 434 1BBibulll644S
I
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HRGC-L~Hs AkALVsis berAtkEb Fo~ ISU svN 100 120 UB
SAMPLE N02A1
188
9B
a
78
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58
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38
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1
6 al 1 6142
----1-----------------~ S 444 1BBXbull1BB72
amp 442 1B8Xbull1B157 ~ - - - -0 512 lB81bull2511
478 1BBXbull137939
bull 472 1BBXbull153225
128 13B
~lt
BREHM LABORATORY - WRIGHT STAl~ JNIVERSITV - DAYTON OHIO 45435 DATE B22184 TIMEa 15a42
KRATOS MS25 0S55 SOFTWARE RUN TOR80038 WSU NAHEs CHJ-2lB1134 1 35 SELECTED-ION HASS CHRO~TOGRAHS FOR OCTACHLORODIBENZOFURANS
7d3 L1
71U 8115
148 158 168 SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMOCOLOGV FIGUREmiddot 50
a46 9 17 9148
178 181 i9B SAMPLE N02Al
l819
218
I 0 N
I N T E N s I T V
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45~35 DATE 822184 TIME 15i42
KRATOS MS25 DS55 SOFTWARE RUN TORB0S38 WSU NAME CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIOXINS
611 6142 7 I 13 7U 8d5 8146 9 r17 9e 18119 100
S 46B lB81bull12246 90
amp 458 1Bllbull11231 80
0 395 1SUbull6838 1B
1s 1BSXbull137939 68
bull 472 1BBXbull153225 58
3B
2S
lB
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I 0 N
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12B 138 14B 158 16B 171 lBS 198 2H SCAN NUMBER
HbullGc-LiM AHitvsi~ oe+AikEo iim cHtMocoLbG~ tAM~Lt No~1
FIGURE 51
l
----
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BREHM LABORATORY - WRIGHT 3(ATL ~NIVERSITV - DAYTON OHIO 45435 DATEt 022184 TIHEs 16128
KRATOS MS25 0S55 SOFTWARE RUN1 TOR43B38 WSU NAHEs CHJ-412133~ 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B26 100 ~ _
S 306 91J --
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68
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1BUbullC2
lBBXbull38lnB9
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HRGC-LRMS ANALYSIS OBTAiNED FOR CHEMECOLOtV SAMPLE NO~A2 FIGURE 52
159 2BB 259 3BBSCAN NUMBER
29
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHlO 4b4Jb
DATE 022184 TIMEt 16128 KRATOS MS25 0S55 SOFTWARE RUNa TOR4BB38 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODlBEHZO-P-DlOXINS
0126 11S7 2 I 14 3t22 4129 5137 6U 180
90
80
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6B
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40
30
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$ 322 l0BXbulll39545
amp 320 1BBlbulllS9772
0 257 l081bull945259
328 1081bull381189
bull 332 l801bull127044
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0 340 lBBlbulllB59189
338 1881bull685876
488 bSBlbull392
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
206 3 10
YRIGHT SlATE ~NJVERSITV - DAYTON DATE 922184 TIMEs 16a37
SOFTWARE RUN1 TOR50B31 1 WSU NAHE1
OHIO 45435
CHJ-4121337 3 36 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 a 13 517 6120 7s24 8127
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lBB 158 280 25B 3BB 358 4BBSCAN NUMBER
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2 FIGUREbull 54
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO s35 0ATEs S2218bull TIMEc 16137
KRATOS MS25 0S55 SOFTWARE RUNa TORSS031 WSU NAME1 CHJ-121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DlOXINS
0181 1 dJ3 2 dJ6 3t 11 4 I 13 5amp17 612S 7124 8127 180
0 356 llBXbulll95796 99
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a - - - - - - - - - - - __ - - - - - - - - 291 1BBlbull76689
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--
BREHM ~ABORATORV - WRIGHT STAT~ ~~IVERSlTV - DAYTON OHIO 4535 DATEa S22184 TIHEz 10147
KRATOS MS25 0S55 SOFTWARE RUNs TOR68033 WSU NAHEa CHJ-4121337 3 36 SELECTED-ION HASS CHROMATOGRAMS ~OR HEXACHLORODIBENZOFUkANS
1s1 1126 254 4s21 Sa49 7116 81U
188
98
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51
31
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTOM OHtomiddot 45435 OATEt 822184 TIMEbull 16147
KRATOS MS25 0S55 SOFTWARE RUN TOR6BB33 VSU NAMEt CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBEHZO-P-DIOXINS
BdJl l 1 26 2154 4amp21 5 I 9 7t16 eH 180
0 392 lSUbull-43858 91
396 18Slbull661ll
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329 1811bull31738 7B
6f
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HRQC-LRMS ANALYSIS oarAINEbFOR CHEHECOLOGV SAMPLE H02A2 ncUHa 57
BREHM LABORATORY - RIGHT s~middotATE --VERSITY - DAYTON OHIO 5435 DATE fl22184 TIMEr 1657
KRATOS MS25 0S55 SOFTWARE RUN TOR7~032 WSU NAMEs CHJ-4121331 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR
BrBl l 00 2B2 3 04 4dJ6 U0 -r--~_______~~______~----L~_L__1---l-L -~-----___________-----4-___________~ I S 18 J88Xbull3lJ056 98 tamp 88 188Xbull31639 _______ -tSB
70 ldeg ~8~088~ - - - - - - - _ ~ 6S - ~ - A - - --1 ~2~m-~z~
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SCAN NUMBER HRGC-LRMS AHALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2
FIGURE 58
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTON OHIO bull5435 OATEs B22184 TIME1 16167
lt KRATOS MS25 DS55 SOFTWARE RUNa TOR7SS32 ~SU HAMEa 2A2 SELECTED-ION MASS CHROMATOGkAMS FOR MEPTACHLOROOtBENZO-P-DlOXlNS
SdJl 1 tH 2 I 02 3 I 04 4t06 5 3 08 6amp11 7 a13 108
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HRd~-Li~sect AUAL~tsect 61~Al~ED -bi CHEMEcototV sAM~lE UotUJ-1~t3~7 3 36 f I GUREmiddott 59
BkEHM LBORATORV _ JRibHT STAT--INIVERSITY - DAYTON OHIO 45435 DATE 322 i TIME 1720
KRATOS MS25 0S55 SOFTWARE RUN1 TOR80039 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
-~
611 642 7 13 7 44 815 846 9 17 9148 18119 100 ________ 1-1 LiLJ ~
S 460 100bull14529 90
amp 458 1001bull12404 80
0 395 l801bull8383
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472 1881bull136872 58
I N T E
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30
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120 130 140 150 160 SCAN NUMBER
170 188 ljS 2BB
HRGC-LRS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMlLE N02A2 FIGURE 61
-- - - - -
tKEr tUt1 i - middotIGHl SAli JItRSifr - OltY10N 1 OHIO 45435 -L fl22384 TIME 1J1l
KRAlG~ MS25 DS5S S0~TWARE RUNt TORbullas9 ~SU NAME1 CHJ-19202847 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
001 l 07 2 14 3122 429 537 6144 100 L --____L_______~_l--1__t----______________~
$ 306 100Xbull218713
90 I - l -2378amp ~~4~IJr 1_1mas
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HRGC-lkMS ANALvili OBTAINED FOR CHEMECOLOGV sAuLE No26i FIGUREbull 134
250
100
90
80
70
60
50
U
30
20
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BREHM LABORATORY
KRATOS MS25 DS55 SELECTED-ION MASS
0 a- 1 l S7 2 14 L _LJ_ _ _ _l--L_J_J___j__L___~J_y-- I I
$ 322 1001bull532633
amp 320 100Xbull404109
0 257 1BBXbull219683
328 1BBXbulll94431
~ 332 IBBXbull28B34
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HRGC-L~MS A~ALYiis oiTAINED FOR CHEMEcolOGY SAMPLE Mo2oi FIGURE 135
3BB
middotmiddot RIGHT STATE lY~ERSITV - DAYTON OHIO_ 4~435 DATE 022384 tIME 1739
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322 4129 5s37 6144 ~-1--A--L---L-L--L--------J---------_______~ __-L-__________~__~__L-__~-----------_-+-
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A TE 0 21 2 3 1a4 TI ME 1 3 _g KRATC- MS25 fh5 Sv-TIARE RUN TOR5004f1 JSLl NAME CHJ-192028 4i SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
001 1 103 206 3 10 4 13 5 1 7 620 724 8127 l00 ~- L-J --ill~------1______--L--1--1--1--1----L-J-L-J-~I--L----L-L--l-~-1-JL-l--l--J_L-__L-L-1-L-_j______J_J__j__l___i_J_J__J__Jl-i_I-J-L-L~1-1-_L___L--L---L-1--1-J__J__JL-L-l_L-J_4--+-
0 340 l00Xbull270473 90
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80
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Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
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sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
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MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
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18
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0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
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98
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0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
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58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
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S 419 100Xbull5537
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0 478 lBBlbull(59
432 1BBXbull3837B
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202
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SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
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$ 426 1BBXbull19300
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432 J 0 N
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UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
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0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
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2B
1B
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128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
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18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
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H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
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g
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200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
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8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
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20
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5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
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t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
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UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
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L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
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3B
28
18
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BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
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I-i
il16 ~II
I 0
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20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
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10
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bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
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120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
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51
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38
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0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
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322 ~29 537 6tU
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58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
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6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
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5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
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l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
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N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
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12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
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S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
-i
I
23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
B
SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
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58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
T V
3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
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OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
----------
----------
--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
UJ0
S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
__ -1--
n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
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h y
I2B I I I I - M I I AU l I V I t 1
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1 28 uJ 68 SB lBB 128 usSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
~~ --
S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
5g
s
30
10
20
vi ~~~ B
~~~~ ~~~~-~
~___-- ~~~~---- - r--
zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
B
U 78 8B 98 lBB 110 128 SCAN NUMBER
tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
I6B 0 N
58 I N T E N
u s I T38 y
20
10
0
u 58 110 120
S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
~~ 60 1s as 90 t00
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
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r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
8J
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7B
328 1BBlbull18B436
I - [ 0
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bull 332 100Xbull139676 50 I
NJ ij1 T
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I
N st ~ j
T V
3B ~ Imiddotmiddot 1~12B
lB
B
__
---- ________
I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
B
S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
I N T E N s I T v-
50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
10
s
61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
I 0 N
I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
n1 N T E N
48 l1
~ s I T V
30
26
I II I
I
UJ
J-1middot I
B II
I r--rmiddot I middotr middot-rmiddotmiddot middotmiddotr--
12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
-~ I --~ ______ y------ -(j
-middot-r==r~~ middotmiddotr- - middot 1- -Tr-----r- bull -I
--
iilt11i) L4blbullKAIUlY - ~ ll1HI gtutt UliJtICgt Iyen - uhyen _111 1tl1U +0+)J
DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
-l)--
___L__l_JJ__I 1 H 0 10 flt Xbull 17 8 9 4 1
30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
B
bull 472 IOOXbull134721
E N s I TI I y
1
----------------------- II I k------ ------- ------------- I r---__~-------------_____ middot-~---------~~----- ----------~~ --- -~ -
J
-___
-------- middot--------middot--bull-middotmiddotmiddot--- ---middot middot- middot-------------
~-
----r-middotmiddotr- r-r-rmiddotrr- I I I I I I I Tl-T I I I I I I I I r= I middot ------r-------rmiddot- r r ~r--iT middotr-i 1~middot11-----r-r-r I I I -r-r-+
middotbullI
I 0 N
I N T
~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
I N T E N s I T y
3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
AB
38
2B
10
B
0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
u
38
28
lB
B
JI 0 ( I 13 5 I 1 7 6120 7s2( 8t27
--1 - - - - - - - - - - - - - - - -
l 0 N
I N T E N s I T y
SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
B
50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
I N T E N s I T V
3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
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~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs 822184 TlMEs 1511
KRATOS MS25 0S55 SOFTWARE RUN1 TQR5BB3B WSU HAME1 CHJ-2lB1135 1 34 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
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BREHM LABORATORY - WRIGHT STATE ~NIVERSITY - DAYTON OHIO 45435 OATE1 022184 TIME 15121
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lBB 158 280 25B 3BB 358 4BBSCAN NUMBER
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2 FIGUREbull 54
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO s35 0ATEs S2218bull TIMEc 16137
KRATOS MS25 0S55 SOFTWARE RUNa TORSS031 WSU NAME1 CHJ-121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DlOXINS
0181 1 dJ3 2 dJ6 3t 11 4 I 13 5amp17 612S 7124 8127 180
0 356 llBXbulll95796 99
3sbull 11r amp1s1
a - - - - - - - - - - - __ - - - - - - - - 291 1BBlbull76689
7B t 0 N
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ubull~l-LiMs AULVlfl 6fAfUt6 IBA tUfMfc6l~V IAUlf Uo2~2 FtGUltEt 55
--
BREHM ~ABORATORV - WRIGHT STAT~ ~~IVERSlTV - DAYTON OHIO 4535 DATEa S22184 TIHEz 10147
KRATOS MS25 0S55 SOFTWARE RUNs TOR68033 WSU NAHEa CHJ-4121337 3 36 SELECTED-ION HASS CHROMATOGRAMS ~OR HEXACHLORODIBENZOFUkANS
1s1 1126 254 4s21 Sa49 7116 81U
188
98
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18
51
31
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0 376 lBBlbulll15658
37-4 1SSSbull93483
bull u 1bullbullbullbull781
t JI I M T E
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FlGUREt 56
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTOM OHtomiddot 45435 OATEt 822184 TIMEbull 16147
KRATOS MS25 0S55 SOFTWARE RUN TOR6BB33 VSU NAMEt CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBEHZO-P-DIOXINS
BdJl l 1 26 2154 4amp21 5 I 9 7t16 eH 180
0 392 lSUbull-43858 91
396 18Slbull661ll
BB
329 1811bull31738 7B
6f
68
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28
18
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HRQC-LRMS ANALYSIS oarAINEbFOR CHEHECOLOGV SAMPLE H02A2 ncUHa 57
BREHM LABORATORY - RIGHT s~middotATE --VERSITY - DAYTON OHIO 5435 DATE fl22184 TIMEr 1657
KRATOS MS25 0S55 SOFTWARE RUN TOR7~032 WSU NAMEs CHJ-4121331 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR
BrBl l 00 2B2 3 04 4dJ6 U0 -r--~_______~~______~----L~_L__1---l-L -~-----___________-----4-___________~ I S 18 J88Xbull3lJ056 98 tamp 88 188Xbull31639 _______ -tSB
70 ldeg ~8~088~ - - - - - - - _ ~ 6S - ~ - A - - --1 ~2~m-~z~
434 18BXbulll8B72 IvSB
41
30
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5 dJB I I I ---~--4---__~__J_L-L
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6111 7 sl 3 ~ I I I I I
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SCAN NUMBER HRGC-LRMS AHALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2
FIGURE 58
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTON OHIO bull5435 OATEs B22184 TIME1 16167
lt KRATOS MS25 DS55 SOFTWARE RUNa TOR7SS32 ~SU HAMEa 2A2 SELECTED-ION MASS CHROMATOGkAMS FOR MEPTACHLOROOtBENZO-P-DlOXlNS
SdJl 1 tH 2 I 02 3 I 04 4t06 5 3 08 6amp11 7 a13 108
9S
ee
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2B
S 426 1BISbull21755
amp 424 11Slbull23j27 middot------0 359 111bull12417
bull 43 1Hrbull49amp29
43 1111bull16172
u 6B es 1u 12s us SCAN NUMBER
HRd~-Li~sect AUAL~tsect 61~Al~ED -bi CHEMEcototV sAM~lE UotUJ-1~t3~7 3 36 f I GUREmiddott 59
BkEHM LBORATORV _ JRibHT STAT--INIVERSITY - DAYTON OHIO 45435 DATE 322 i TIME 1720
KRATOS MS25 0S55 SOFTWARE RUN1 TOR80039 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
-~
611 642 7 13 7 44 815 846 9 17 9148 18119 100 ________ 1-1 LiLJ ~
S 460 100bull14529 90
amp 458 1001bull12404 80
0 395 l801bull8383
70
470 1001bull128228 I60 0 N
472 1881bull136872 58
I N T E
f N s
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30
20
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120 130 140 150 160 SCAN NUMBER
170 188 ljS 2BB
HRGC-LRS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMlLE N02A2 FIGURE 61
-- - - - -
tKEr tUt1 i - middotIGHl SAli JItRSifr - OltY10N 1 OHIO 45435 -L fl22384 TIME 1J1l
KRAlG~ MS25 DS5S S0~TWARE RUNt TORbullas9 ~SU NAME1 CHJ-19202847 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
001 l 07 2 14 3122 429 537 6144 100 L --____L_______~_l--1__t----______________~
$ 306 100Xbull218713
90 I - l -2378amp ~~4~IJr 1_1mas
0 3H 18 bull1860
7B
ii ~8 llljfbull18898363
SB
I=~ 0 N
332 10 bull136251 58
I N T
-48 E N s I
33 T y
2B
l 3
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10B 15B 2B0 25B 3BB SCAN NUMBER
HRGC-lkMS ANALvili OBTAINED FOR CHEMECOLOGV sAuLE No26i FIGUREbull 134
250
100
90
80
70
60
50
U
30
20
UJ
B
BREHM LABORATORY
KRATOS MS25 DS55 SELECTED-ION MASS
0 a- 1 l S7 2 14 L _LJ_ _ _ _l--L_J_J___j__L___~J_y-- I I
$ 322 1001bull532633
amp 320 100Xbull404109
0 257 1BBXbull219683
328 1BBXbulll94431
~ 332 IBBXbull28B34
I~
r1 ~_)
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--___ ~~- J
SB
-------_-----------------------------~
lBB 150 200 SCAN NUMBER
HRGC-L~MS A~ALYiis oiTAINED FOR CHEMEcolOGY SAMPLE Mo2oi FIGURE 135
3BB
middotmiddot RIGHT STATE lY~ERSITV - DAYTON OHIO_ 4~435 DATE 022384 tIME 1739
SOFTWARE RUN1 TOR40052 WSU NAMEbull CHJ-192028 47 CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
322 4129 5s37 6144 ~-1--A--L---L-L--L--------J---------_______~ __-L-__________~__~__L-__~-----------_-+-
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A TE 0 21 2 3 1a4 TI ME 1 3 _g KRATC- MS25 fh5 Sv-TIARE RUN TOR5004f1 JSLl NAME CHJ-192028 4i SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
001 1 103 206 3 10 4 13 5 1 7 620 724 8127 l00 ~- L-J --ill~------1______--L--1--1--1--1----L-J-L-J-~I--L----L-L--l-~-1-JL-l--l--J_L-__L-L-1-L-_j______J_J__j__l___i_J_J__J__Jl-i_I-J-L-L~1-1-_L___L--L---L-1--1-J__J__JL-L-l_L-J_4--+-
0 340 l00Xbull270473 90
338 l00Xbull158177
80
tSS 180Xbull3262 1B
I 0 N
60
I N T E N
SB
s
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Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
I Tu y
30
2B
lB
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250 300 3U UB
sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
I 0 N
I N T E N s 1 T V
UJjJ
9B
SB
7B
6B
58
0
30
20
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51 ISI 15B 2BBSCAN NUMBER
MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
u
38
2B
18
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-t--L- - JJ_L-L---L-_J_~__J-L-L-1-_J_----L-~~_~_____---J____L_______~L-------~
0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
I N T E N s I T y
3BB
urn_
98
as
7B
6B
50
uJ
30
2B
1e
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~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
I N T E N s I T V
58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
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lB
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001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
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10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
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I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
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l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
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I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
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bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
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120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
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328 1B0Xbull195851 60
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H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
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BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
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6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
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291 lBSXbullamp877 78 ~ I
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
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6B ] N T E N
50
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HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
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s
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0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
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3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
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amp (88 180Xbull12ZC
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HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
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HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
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$ _26 l00XbullH5
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0 359 100bull2630
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1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
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80
70
60
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l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
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amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
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HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
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0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
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170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
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bull
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amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
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2BB 250
I
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388
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
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SB
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0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
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58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
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C18 1IB1bull181 7B
I 0 N
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HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
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N s I Tu y
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H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
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I 0 N
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200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
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OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
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SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
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5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
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0101 1 00 202 3 06 4108 Sill 613 i
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S 4 U UJUbull5527
90
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
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middotV
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8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
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KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
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tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
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W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
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0 395 1SUbull2198
470 1SSXbull2162
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~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
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kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
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SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
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0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
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amp 320 UUbull12126
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328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
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20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
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0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
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1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
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68
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BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
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4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
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35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
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Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
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BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
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398
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HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
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304 4 dJ6 5dJ8 611 7 ll3 IBB
98
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68
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amp cee 1snbulls119
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bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
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UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
n1 N T E N
48 l1
~ s I T V
30
26
I II I
I
UJ
J-1middot I
B II
I r--rmiddot I middotr middot-rmiddotmiddot middotmiddotr--
12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
-~ I --~ ______ y------ -(j
-middot-r==r~~ middotmiddotr- - middot 1- -Tr-----r- bull -I
--
iilt11i) L4blbullKAIUlY - ~ ll1HI gtutt UliJtICgt Iyen - uhyen _111 1tl1U +0+)J
DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
-l)--
___L__l_JJ__I 1 H 0 10 flt Xbull 17 8 9 4 1
30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
B
bull 472 IOOXbull134721
E N s I TI I y
1
----------------------- II I k------ ------- ------------- I r---__~-------------_____ middot-~---------~~----- ----------~~ --- -~ -
J
-___
-------- middot--------middot--bull-middotmiddotmiddot--- ---middot middot- middot-------------
~-
----r-middotmiddotr- r-r-rmiddotrr- I I I I I I I Tl-T I I I I I I I I r= I middot ------r-------rmiddot- r r ~r--iT middotr-i 1~middot11-----r-r-r I I I -r-r-+
middotbullI
I 0 N
I N T
~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
I N T E N s I T y
3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
AB
38
2B
10
B
0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
u
38
28
lB
B
JI 0 ( I 13 5 I 1 7 6120 7s2( 8t27
--1 - - - - - - - - - - - - - - - -
l 0 N
I N T E N s I T y
SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
B
50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
I N T E N s I T V
3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
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bull
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~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
-----
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20
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B
BREHM LABORATORY
KRATOS MS25 DS55 SELECTED-ION MASS
0 a- 1 l S7 2 14 L _LJ_ _ _ _l--L_J_J___j__L___~J_y-- I I
$ 322 1001bull532633
amp 320 100Xbull404109
0 257 1BBXbull219683
328 1BBXbulll94431
~ 332 IBBXbull28B34
I~
r1 ~_)
-
--___ ~~- J
SB
-------_-----------------------------~
lBB 150 200 SCAN NUMBER
HRGC-L~MS A~ALYiis oiTAINED FOR CHEMEcolOGY SAMPLE Mo2oi FIGURE 135
3BB
middotmiddot RIGHT STATE lY~ERSITV - DAYTON OHIO_ 4~435 DATE 022384 tIME 1739
SOFTWARE RUN1 TOR40052 WSU NAMEbull CHJ-192028 47 CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
322 4129 5s37 6144 ~-1--A--L---L-L--L--------J---------_______~ __-L-__________~__~__L-__~-----------_-+-
-~-I I
Nl 0
I 2378 N
T E
If s N
T~ VI
r (~~-
A
_
BkEH 1 middot middotRORAT middotv - ~bullRIGHT smiddoti-AF UlIIVEq_Sl (( - 0WTON OHIO 4535
A TE 0 21 2 3 1a4 TI ME 1 3 _g KRATC- MS25 fh5 Sv-TIARE RUN TOR5004f1 JSLl NAME CHJ-192028 4i SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
001 1 103 206 3 10 4 13 5 1 7 620 724 8127 l00 ~- L-J --ill~------1______--L--1--1--1--1----L-J-L-J-~I--L----L-L--l-~-1-JL-l--l--J_L-__L-L-1-L-_j______J_J__j__l___i_J_J__J__Jl-i_I-J-L-L~1-1-_L___L--L---L-1--1-J__J__JL-L-l_L-J_4--+-
0 340 l00Xbull270473 90
338 l00Xbull158177
80
tSS 180Xbull3262 1B
I 0 N
60
I N T E N
SB
s
SB 100 15B 200SCAN NUMBER
Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
I Tu y
30
2B
lB
B
250 300 3U UB
sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
I 0 N
I N T E N s 1 T V
UJjJ
9B
SB
7B
6B
58
0
30
20
lB
B
51 ISI 15B 2BBSCAN NUMBER
MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
u
38
2B
18
B
-t--L- - JJ_L-L---L-_J_~__J-L-L-1-_J_----L-~~_~_____---J____L_______~L-------~
0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
I N T E N s I T y
3BB
urn_
98
as
7B
6B
50
uJ
30
2B
1e
B
~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
I N T E N s I T V
58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
2B
lB
B
001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
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$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
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1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
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amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
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HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
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$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
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50 I N T E N
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12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
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amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
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388
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
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68
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40
30
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amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
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58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
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HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
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6B
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H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
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200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
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30
20
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0
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OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
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SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
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5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
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amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
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~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
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88
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
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BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
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502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
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711
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4B
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tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
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5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
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58 I N T E N
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S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
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kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
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SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
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KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
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2B
lB
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amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
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_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
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20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
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1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
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61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
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4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
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35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
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Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
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BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
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398
329
lS8Xbull69492
l88rbull2616
6B
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HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
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SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
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68
68
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2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
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2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
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40
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$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
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2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
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HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
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7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
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HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
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6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
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120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
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KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
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HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
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80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
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u
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wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
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50
AB
38
2B
10
B
0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
u
38
28
lB
B
JI 0 ( I 13 5 I 1 7 6120 7s2( 8t27
--1 - - - - - - - - - - - - - - - -
l 0 N
I N T E N s I T y
SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
B
50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
I N T E N s I T V
3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
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- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
B
S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
-i
I
23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
B
SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
B
58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
T V
3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
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~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
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S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
__ -1--
n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
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S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
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68
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s
30
10
20
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~~~~ ~~~~-~
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zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
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tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
I6B 0 N
58 I N T E N
u s I T38 y
20
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S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
~~ 60 1s as 90 t00
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
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r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
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328 1BBlbull18B436
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bull 332 100Xbull139676 50 I
NJ ij1 T
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lB
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I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
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amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
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20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
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28
10
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61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
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HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
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I N T
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2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
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HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
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HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
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--
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DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
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30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
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4lll 1B0Xbull126296 60
~ 50
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bull 472 IOOXbull134721
E N s I TI I y
1
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middotbullI
I 0 N
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
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0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
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I6B 0 N
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30
20
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f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
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wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
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98
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338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
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SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
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0s01
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291
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10SXbull~J((1
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--1 - - - - - - - - - - - - - - - -
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250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
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BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
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100 150 200 25B I I I f r-r-
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3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
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CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
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wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
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SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
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31
2B
11
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S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
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us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
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BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
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amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
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30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
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128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
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170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
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r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
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8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
- - - -
-~ BREHM LABORATORY - WR1GHT STAT~ UNIVERSITY - DAYTON OHIO 4535
DATE 022184 TIME1 1531 KRATOS MS25 0S55 SOFTWARE RUN1 TOR70B31 WSU NAME1 CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODJBENZOFURANS
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BREHM LABORATORY - WRIGHT STAl~ JNIVERSITV - DAYTON OHIO 45435 DATE B22184 TIMEa 15a42
KRATOS MS25 0S55 SOFTWARE RUN TOR80038 WSU NAHEs CHJ-2lB1134 1 35 SELECTED-ION HASS CHRO~TOGRAHS FOR OCTACHLORODIBENZOFURANS
7d3 L1
71U 8115
148 158 168 SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMOCOLOGV FIGUREmiddot 50
a46 9 17 9148
178 181 i9B SAMPLE N02Al
l819
218
I 0 N
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45~35 DATE 822184 TIME 15i42
KRATOS MS25 DS55 SOFTWARE RUN TORB0S38 WSU NAME CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIOXINS
611 6142 7 I 13 7U 8d5 8146 9 r17 9e 18119 100
S 46B lB81bull12246 90
amp 458 1Bllbull11231 80
0 395 1SUbull6838 1B
1s 1BSXbull137939 68
bull 472 1BBXbull153225 58
3B
2S
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12B 138 14B 158 16B 171 lBS 198 2H SCAN NUMBER
HbullGc-LiM AHitvsi~ oe+AikEo iim cHtMocoLbG~ tAM~Lt No~1
FIGURE 51
l
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BREHM LABORATORY - WRIGHT 3(ATL ~NIVERSITV - DAYTON OHIO 45435 DATEt 022184 TIHEs 16128
KRATOS MS25 0S55 SOFTWARE RUN1 TOR43B38 WSU NAHEs CHJ-412133~ 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B26 100 ~ _
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68
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HRGC-LRMS ANALYSIS OBTAiNED FOR CHEMECOLOtV SAMPLE NO~A2 FIGURE 52
159 2BB 259 3BBSCAN NUMBER
29
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHlO 4b4Jb
DATE 022184 TIMEt 16128 KRATOS MS25 0S55 SOFTWARE RUNa TOR4BB38 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODlBEHZO-P-DlOXINS
0126 11S7 2 I 14 3t22 4129 5137 6U 180
90
80
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6B
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40
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$ 322 l0BXbulll39545
amp 320 1BBlbulllS9772
0 257 l081bull945259
328 1081bull381189
bull 332 l801bull127044
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0 340 lBBlbulllB59189
338 1881bull685876
488 bSBlbull392
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
206 3 10
YRIGHT SlATE ~NJVERSITV - DAYTON DATE 922184 TIMEs 16a37
SOFTWARE RUN1 TOR50B31 1 WSU NAHE1
OHIO 45435
CHJ-4121337 3 36 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 a 13 517 6120 7s24 8127
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HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2 FIGUREbull 54
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO s35 0ATEs S2218bull TIMEc 16137
KRATOS MS25 0S55 SOFTWARE RUNa TORSS031 WSU NAME1 CHJ-121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DlOXINS
0181 1 dJ3 2 dJ6 3t 11 4 I 13 5amp17 612S 7124 8127 180
0 356 llBXbulll95796 99
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a - - - - - - - - - - - __ - - - - - - - - 291 1BBlbull76689
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BREHM ~ABORATORV - WRIGHT STAT~ ~~IVERSlTV - DAYTON OHIO 4535 DATEa S22184 TIHEz 10147
KRATOS MS25 0S55 SOFTWARE RUNs TOR68033 WSU NAHEa CHJ-4121337 3 36 SELECTED-ION HASS CHROMATOGRAMS ~OR HEXACHLORODIBENZOFUkANS
1s1 1126 254 4s21 Sa49 7116 81U
188
98
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTOM OHtomiddot 45435 OATEt 822184 TIMEbull 16147
KRATOS MS25 0S55 SOFTWARE RUN TOR6BB33 VSU NAMEt CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBEHZO-P-DIOXINS
BdJl l 1 26 2154 4amp21 5 I 9 7t16 eH 180
0 392 lSUbull-43858 91
396 18Slbull661ll
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BREHM LABORATORY - RIGHT s~middotATE --VERSITY - DAYTON OHIO 5435 DATE fl22184 TIMEr 1657
KRATOS MS25 0S55 SOFTWARE RUN TOR7~032 WSU NAMEs CHJ-4121331 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR
BrBl l 00 2B2 3 04 4dJ6 U0 -r--~_______~~______~----L~_L__1---l-L -~-----___________-----4-___________~ I S 18 J88Xbull3lJ056 98 tamp 88 188Xbull31639 _______ -tSB
70 ldeg ~8~088~ - - - - - - - _ ~ 6S - ~ - A - - --1 ~2~m-~z~
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SCAN NUMBER HRGC-LRMS AHALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2
FIGURE 58
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTON OHIO bull5435 OATEs B22184 TIME1 16167
lt KRATOS MS25 DS55 SOFTWARE RUNa TOR7SS32 ~SU HAMEa 2A2 SELECTED-ION MASS CHROMATOGkAMS FOR MEPTACHLOROOtBENZO-P-DlOXlNS
SdJl 1 tH 2 I 02 3 I 04 4t06 5 3 08 6amp11 7 a13 108
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HRd~-Li~sect AUAL~tsect 61~Al~ED -bi CHEMEcototV sAM~lE UotUJ-1~t3~7 3 36 f I GUREmiddott 59
BkEHM LBORATORV _ JRibHT STAT--INIVERSITY - DAYTON OHIO 45435 DATE 322 i TIME 1720
KRATOS MS25 0S55 SOFTWARE RUN1 TOR80039 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
-~
611 642 7 13 7 44 815 846 9 17 9148 18119 100 ________ 1-1 LiLJ ~
S 460 100bull14529 90
amp 458 1001bull12404 80
0 395 l801bull8383
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472 1881bull136872 58
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30
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120 130 140 150 160 SCAN NUMBER
170 188 ljS 2BB
HRGC-LRS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMlLE N02A2 FIGURE 61
-- - - - -
tKEr tUt1 i - middotIGHl SAli JItRSifr - OltY10N 1 OHIO 45435 -L fl22384 TIME 1J1l
KRAlG~ MS25 DS5S S0~TWARE RUNt TORbullas9 ~SU NAME1 CHJ-19202847 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
001 l 07 2 14 3122 429 537 6144 100 L --____L_______~_l--1__t----______________~
$ 306 100Xbull218713
90 I - l -2378amp ~~4~IJr 1_1mas
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HRGC-lkMS ANALvili OBTAINED FOR CHEMECOLOGV sAuLE No26i FIGUREbull 134
250
100
90
80
70
60
50
U
30
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BREHM LABORATORY
KRATOS MS25 DS55 SELECTED-ION MASS
0 a- 1 l S7 2 14 L _LJ_ _ _ _l--L_J_J___j__L___~J_y-- I I
$ 322 1001bull532633
amp 320 100Xbull404109
0 257 1BBXbull219683
328 1BBXbulll94431
~ 332 IBBXbull28B34
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-------_-----------------------------~
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HRGC-L~MS A~ALYiis oiTAINED FOR CHEMEcolOGY SAMPLE Mo2oi FIGURE 135
3BB
middotmiddot RIGHT STATE lY~ERSITV - DAYTON OHIO_ 4~435 DATE 022384 tIME 1739
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322 4129 5s37 6144 ~-1--A--L---L-L--L--------J---------_______~ __-L-__________~__~__L-__~-----------_-+-
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001 1 103 206 3 10 4 13 5 1 7 620 724 8127 l00 ~- L-J --ill~------1______--L--1--1--1--1----L-J-L-J-~I--L----L-L--l-~-1-JL-l--l--J_L-__L-L-1-L-_j______J_J__j__l___i_J_J__J__Jl-i_I-J-L-L~1-1-_L___L--L---L-1--1-J__J__JL-L-l_L-J_4--+-
0 340 l00Xbull270473 90
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80
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Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
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sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
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UJjJ
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58
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MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
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0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
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98
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0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
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58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
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48
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0 478 lBBlbull(59
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202
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SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
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$ 426 1BBXbull19300
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432 J 0 N
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UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
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0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
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472 1SBXbulll19359 68
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128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
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214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
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H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
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328 10SXbulll87507 69 I
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200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
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4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
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ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
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H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
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bull tU lB01bull7tB
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H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
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L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
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t
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HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
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F IGUFlE t 149
180
98
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KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
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I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
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322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
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I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
B
S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
-i
I
23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
B
SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
B
58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
T V
3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
----------
----------
--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
UJ0
S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
__ -1--
n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
___J_ - - - - - - - -
432 1881bull 1872 60 I - - - - - - - - - - - - - ------- - - - - - - l-1 - - _L
0 1
N 434 l081bull3567 58 I
lT
1 N
U -1 IJ II ll I E N s
I 3f -I l y V A A I I l T I
h y
I2B I I I I - M I I AU l I V I t 1
18
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1 28 uJ 68 SB lBB 128 usSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
~~ --
S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
5g
s
30
10
20
vi ~~~ B
~~~~ ~~~~-~
~___-- ~~~~---- - r--
zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
B
U 78 8B 98 lBB 110 128 SCAN NUMBER
tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
I6B 0 N
58 I N T E N
u s I T38 y
20
10
0
u 58 110 120
S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
~~ 60 1s as 90 t00
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
Ift I~
------------------1-
r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
8J
l j 11
7B
328 1BBlbull18B436
I - [ 0
66 N
bull 332 100Xbull139676 50 I
NJ ij1 T
EU ~~ I I I
I
N st ~ j
T V
3B ~ Imiddotmiddot 1~12B
lB
B
__
---- ________
I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
B
S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
I N T E N s I T v-
50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
10
s
61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
I 0 N
I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
n1 N T E N
48 l1
~ s I T V
30
26
I II I
I
UJ
J-1middot I
B II
I r--rmiddot I middotr middot-rmiddotmiddot middotmiddotr--
12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
-~ I --~ ______ y------ -(j
-middot-r==r~~ middotmiddotr- - middot 1- -Tr-----r- bull -I
--
iilt11i) L4blbullKAIUlY - ~ ll1HI gtutt UliJtICgt Iyen - uhyen _111 1tl1U +0+)J
DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
-l)--
___L__l_JJ__I 1 H 0 10 flt Xbull 17 8 9 4 1
30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
B
bull 472 IOOXbull134721
E N s I TI I y
1
----------------------- II I k------ ------- ------------- I r---__~-------------_____ middot-~---------~~----- ----------~~ --- -~ -
J
-___
-------- middot--------middot--bull-middotmiddotmiddot--- ---middot middot- middot-------------
~-
----r-middotmiddotr- r-r-rmiddotrr- I I I I I I I Tl-T I I I I I I I I r= I middot ------r-------rmiddot- r r ~r--iT middotr-i 1~middot11-----r-r-r I I I -r-r-+
middotbullI
I 0 N
I N T
~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
I N T E N s I T y
3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
AB
38
2B
10
B
0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
u
38
28
lB
B
JI 0 ( I 13 5 I 1 7 6120 7s2( 8t27
--1 - - - - - - - - - - - - - - - -
l 0 N
I N T E N s I T y
SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
B
50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
I N T E N s I T V
3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
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50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
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~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
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bull 43 1Hrbull49amp29
43 1111bull16172
u 6B es 1u 12s us SCAN NUMBER
HRd~-Li~sect AUAL~tsect 61~Al~ED -bi CHEMEcototV sAM~lE UotUJ-1~t3~7 3 36 f I GUREmiddott 59
BkEHM LBORATORV _ JRibHT STAT--INIVERSITY - DAYTON OHIO 45435 DATE 322 i TIME 1720
KRATOS MS25 0S55 SOFTWARE RUN1 TOR80039 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
-~
611 642 7 13 7 44 815 846 9 17 9148 18119 100 ________ 1-1 LiLJ ~
S 460 100bull14529 90
amp 458 1001bull12404 80
0 395 l801bull8383
70
470 1001bull128228 I60 0 N
472 1881bull136872 58
I N T E
f N s
I T V
30
20
10
0
-------~ I
~-- ~
120 130 140 150 160 SCAN NUMBER
170 188 ljS 2BB
HRGC-LRS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMlLE N02A2 FIGURE 61
-- - - - -
tKEr tUt1 i - middotIGHl SAli JItRSifr - OltY10N 1 OHIO 45435 -L fl22384 TIME 1J1l
KRAlG~ MS25 DS5S S0~TWARE RUNt TORbullas9 ~SU NAME1 CHJ-19202847 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
001 l 07 2 14 3122 429 537 6144 100 L --____L_______~_l--1__t----______________~
$ 306 100Xbull218713
90 I - l -2378amp ~~4~IJr 1_1mas
0 3H 18 bull1860
7B
ii ~8 llljfbull18898363
SB
I=~ 0 N
332 10 bull136251 58
I N T
-48 E N s I
33 T y
2B
l 3
B
10B 15B 2B0 25B 3BB SCAN NUMBER
HRGC-lkMS ANALvili OBTAINED FOR CHEMECOLOGV sAuLE No26i FIGUREbull 134
250
100
90
80
70
60
50
U
30
20
UJ
B
BREHM LABORATORY
KRATOS MS25 DS55 SELECTED-ION MASS
0 a- 1 l S7 2 14 L _LJ_ _ _ _l--L_J_J___j__L___~J_y-- I I
$ 322 1001bull532633
amp 320 100Xbull404109
0 257 1BBXbull219683
328 1BBXbulll94431
~ 332 IBBXbull28B34
I~
r1 ~_)
-
--___ ~~- J
SB
-------_-----------------------------~
lBB 150 200 SCAN NUMBER
HRGC-L~MS A~ALYiis oiTAINED FOR CHEMEcolOGY SAMPLE Mo2oi FIGURE 135
3BB
middotmiddot RIGHT STATE lY~ERSITV - DAYTON OHIO_ 4~435 DATE 022384 tIME 1739
SOFTWARE RUN1 TOR40052 WSU NAMEbull CHJ-192028 47 CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
322 4129 5s37 6144 ~-1--A--L---L-L--L--------J---------_______~ __-L-__________~__~__L-__~-----------_-+-
-~-I I
Nl 0
I 2378 N
T E
If s N
T~ VI
r (~~-
A
_
BkEH 1 middot middotRORAT middotv - ~bullRIGHT smiddoti-AF UlIIVEq_Sl (( - 0WTON OHIO 4535
A TE 0 21 2 3 1a4 TI ME 1 3 _g KRATC- MS25 fh5 Sv-TIARE RUN TOR5004f1 JSLl NAME CHJ-192028 4i SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
001 1 103 206 3 10 4 13 5 1 7 620 724 8127 l00 ~- L-J --ill~------1______--L--1--1--1--1----L-J-L-J-~I--L----L-L--l-~-1-JL-l--l--J_L-__L-L-1-L-_j______J_J__j__l___i_J_J__J__Jl-i_I-J-L-L~1-1-_L___L--L---L-1--1-J__J__JL-L-l_L-J_4--+-
0 340 l00Xbull270473 90
338 l00Xbull158177
80
tSS 180Xbull3262 1B
I 0 N
60
I N T E N
SB
s
SB 100 15B 200SCAN NUMBER
Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
I Tu y
30
2B
lB
B
250 300 3U UB
sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
I 0 N
I N T E N s 1 T V
UJjJ
9B
SB
7B
6B
58
0
30
20
lB
B
51 ISI 15B 2BBSCAN NUMBER
MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
u
38
2B
18
B
-t--L- - JJ_L-L---L-_J_~__J-L-L-1-_J_----L-~~_~_____---J____L_______~L-------~
0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
I N T E N s I T y
3BB
urn_
98
as
7B
6B
50
uJ
30
2B
1e
B
~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
I N T E N s I T V
58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
2B
lB
B
001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
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0 392 l00Xbull3594
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329 10Ubull3518
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HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
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H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
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amp (88 180Xbull12ZC
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DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
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80
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$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
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1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
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6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
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amp HZ 1BBXbull1295
0 512 lBBIbull 1077
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HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
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0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
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amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
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e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
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amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
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58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
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HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
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H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
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200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
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60
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4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
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5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
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8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
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BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
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502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
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tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
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48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
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0 395 1SUbull2198
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~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
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SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
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amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
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HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
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KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
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0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
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1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
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354 1BBbull11BB2
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68
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BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
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4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
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35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
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KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
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6B
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Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
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0 392 1B0Xbull57348 90
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329
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HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
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SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
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amp cee 1snbulls119
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SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
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HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
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6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
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HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
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HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
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-------- middot--------middot--bull-middotmiddotmiddot--- ---middot middot- middot-------------
~-
----r-middotmiddotr- r-r-rmiddotrr- I I I I I I I Tl-T I I I I I I I I r= I middot ------r-------rmiddot- r r ~r--iT middotr-i 1~middot11-----r-r-r I I I -r-r-+
middotbullI
I 0 N
I N T
~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
I N T E N s I T y
3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
AB
38
2B
10
B
0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
u
38
28
lB
B
JI 0 ( I 13 5 I 1 7 6120 7s2( 8t27
--1 - - - - - - - - - - - - - - - -
l 0 N
I N T E N s I T y
SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
B
50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
I N T E N s I T V
3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
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470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
B
S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
-i
I
23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
B
SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
B
58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
T V
3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
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3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
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~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
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S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
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n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
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S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
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~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
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30
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20
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~~~~ ~~~~-~
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
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18
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tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
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58 I N T E N
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S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
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r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
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lB
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SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
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amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
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_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
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20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
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BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
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1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
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3B
28
18
4 I 21 5r49 7 I 16 au
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HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
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SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
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I N T
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2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
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----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
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HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
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amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
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HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
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DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
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30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
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~ 50
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E N s I TI I y
1
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middotbullI
I 0 N
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
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0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
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I6B 0 N
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30
20
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f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
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u
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wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
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BREHM LABORATORY -
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SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
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SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
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KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
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10SXbull~J((1
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--1 - - - - - - - - - - - - - - - -
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250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
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BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
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100 150 200 25B I I I f r-r-
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3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
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CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
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wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
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SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
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31
2B
11
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S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
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us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
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BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
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U
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amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
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30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
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128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
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170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
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r11111w It 1 11 j
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I
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uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45~35 DATE 822184 TIME 15i42
KRATOS MS25 DS55 SOFTWARE RUN TORB0S38 WSU NAME CHJ-2lB113~ 1 35 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIOXINS
611 6142 7 I 13 7U 8d5 8146 9 r17 9e 18119 100
S 46B lB81bull12246 90
amp 458 1Bllbull11231 80
0 395 1SUbull6838 1B
1s 1BSXbull137939 68
bull 472 1BBXbull153225 58
3B
2S
lB
e
I 0 N
A T E N s I T y
12B 138 14B 158 16B 171 lBS 198 2H SCAN NUMBER
HbullGc-LiM AHitvsi~ oe+AikEo iim cHtMocoLbG~ tAM~Lt No~1
FIGURE 51
l
----
- --- - - --- - - ---
BREHM LABORATORY - WRIGHT 3(ATL ~NIVERSITV - DAYTON OHIO 45435 DATEt 022184 TIHEs 16128
KRATOS MS25 0S55 SOFTWARE RUN1 TOR43B38 WSU NAHEs CHJ-412133~ 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B26 100 ~ _
S 306 91J --
amp 304 as
0 374
1B 328
68
332H
b
3B
28
19
B
liB7
bull bull -bull~ ___ bull 1--L --1-
lB01bull1252541
1BBXbull1BB7291
1BUbullC2
lBBXbull38lnB9
1B8Xbull12~9CC
=
II
-J
___ ______-~-
I SB lBB
214
-~- -middotmiddot1middot --1-l-1 -J--L ~l 3122 429 5137 61U
~-~ l LJ--L__L -~-1II -2378 _
I 0 Nmiddot
l N T E N s I T V
-11-( -~-
I~-~ I I I
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEMECOLOtV SAMPLE NO~A2 FIGURE 52
159 2BB 259 3BBSCAN NUMBER
29
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHlO 4b4Jb
DATE 022184 TIMEt 16128 KRATOS MS25 0S55 SOFTWARE RUNa TOR4BB38 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODlBEHZO-P-DlOXINS
0126 11S7 2 I 14 3t22 4129 5137 6U 180
90
80
7B
6B
SB
40
30
2B
18
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2S 50
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338 1881bull685876
488 bSBlbull392
BREHM LABORATORY -
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YRIGHT SlATE ~NJVERSITV - DAYTON DATE 922184 TIMEs 16a37
SOFTWARE RUN1 TOR50B31 1 WSU NAHE1
OHIO 45435
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4 a 13 517 6120 7s24 8127
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HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02A2 FIGUREbull 54
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO s35 0ATEs S2218bull TIMEc 16137
KRATOS MS25 0S55 SOFTWARE RUNa TORSS031 WSU NAME1 CHJ-121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DlOXINS
0181 1 dJ3 2 dJ6 3t 11 4 I 13 5amp17 612S 7124 8127 180
0 356 llBXbulll95796 99
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a - - - - - - - - - - - __ - - - - - - - - 291 1BBlbull76689
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTOM OHtomiddot 45435 OATEt 822184 TIMEbull 16147
KRATOS MS25 0S55 SOFTWARE RUN TOR6BB33 VSU NAMEt CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBEHZO-P-DIOXINS
BdJl l 1 26 2154 4amp21 5 I 9 7t16 eH 180
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BREHM LABORATORY - RIGHT s~middotATE --VERSITY - DAYTON OHIO 5435 DATE fl22184 TIMEr 1657
KRATOS MS25 0S55 SOFTWARE RUN TOR7~032 WSU NAMEs CHJ-4121331 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR
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FIGURE 58
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAVTON OHIO bull5435 OATEs B22184 TIME1 16167
lt KRATOS MS25 DS55 SOFTWARE RUNa TOR7SS32 ~SU HAMEa 2A2 SELECTED-ION MASS CHROMATOGkAMS FOR MEPTACHLOROOtBENZO-P-DlOXlNS
SdJl 1 tH 2 I 02 3 I 04 4t06 5 3 08 6amp11 7 a13 108
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amp 424 11Slbull23j27 middot------0 359 111bull12417
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HRd~-Li~sect AUAL~tsect 61~Al~ED -bi CHEMEcototV sAM~lE UotUJ-1~t3~7 3 36 f I GUREmiddott 59
BkEHM LBORATORV _ JRibHT STAT--INIVERSITY - DAYTON OHIO 45435 DATE 322 i TIME 1720
KRATOS MS25 0S55 SOFTWARE RUN1 TOR80039 WSU NAME CHJ-4121337 3 36 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
-~
611 642 7 13 7 44 815 846 9 17 9148 18119 100 ________ 1-1 LiLJ ~
S 460 100bull14529 90
amp 458 1001bull12404 80
0 395 l801bull8383
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472 1881bull136872 58
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170 188 ljS 2BB
HRGC-LRS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMlLE N02A2 FIGURE 61
-- - - - -
tKEr tUt1 i - middotIGHl SAli JItRSifr - OltY10N 1 OHIO 45435 -L fl22384 TIME 1J1l
KRAlG~ MS25 DS5S S0~TWARE RUNt TORbullas9 ~SU NAME1 CHJ-19202847 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
001 l 07 2 14 3122 429 537 6144 100 L --____L_______~_l--1__t----______________~
$ 306 100Xbull218713
90 I - l -2378amp ~~4~IJr 1_1mas
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HRGC-lkMS ANALvili OBTAINED FOR CHEMECOLOGV sAuLE No26i FIGUREbull 134
250
100
90
80
70
60
50
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30
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BREHM LABORATORY
KRATOS MS25 DS55 SELECTED-ION MASS
0 a- 1 l S7 2 14 L _LJ_ _ _ _l--L_J_J___j__L___~J_y-- I I
$ 322 1001bull532633
amp 320 100Xbull404109
0 257 1BBXbull219683
328 1BBXbulll94431
~ 332 IBBXbull28B34
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-------_-----------------------------~
lBB 150 200 SCAN NUMBER
HRGC-L~MS A~ALYiis oiTAINED FOR CHEMEcolOGY SAMPLE Mo2oi FIGURE 135
3BB
middotmiddot RIGHT STATE lY~ERSITV - DAYTON OHIO_ 4~435 DATE 022384 tIME 1739
SOFTWARE RUN1 TOR40052 WSU NAMEbull CHJ-192028 47 CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
322 4129 5s37 6144 ~-1--A--L---L-L--L--------J---------_______~ __-L-__________~__~__L-__~-----------_-+-
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A TE 0 21 2 3 1a4 TI ME 1 3 _g KRATC- MS25 fh5 Sv-TIARE RUN TOR5004f1 JSLl NAME CHJ-192028 4i SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
001 1 103 206 3 10 4 13 5 1 7 620 724 8127 l00 ~- L-J --ill~------1______--L--1--1--1--1----L-J-L-J-~I--L----L-L--l-~-1-JL-l--l--J_L-__L-L-1-L-_j______J_J__j__l___i_J_J__J__Jl-i_I-J-L-L~1-1-_L___L--L---L-1--1-J__J__JL-L-l_L-J_4--+-
0 340 l00Xbull270473 90
338 l00Xbull158177
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Mit-L~~ AMALvsi o~rAiMtamp Ok cHEHpoundcMoov
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sAM~LE ~o2oi FIGURE 136
BREHM LMSvPATORY - RIGHT STATE JJAI_JIJERSlTV - DAYTON UttlO 45435 DATE 0223S TIME 1330
KRATOS MS25 0S55 SOFTWARE RUN1 1OR5B840 WSU NAME1 CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXJNS
081 __~ I
1 03 2 06 3 zl0 4 13 517 6120 724 8127 I
0 356 100Xbull723886
354 1BBXbull44618S
291 lS01bull261351
I 0 N
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UJjJ
9B
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58
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MR~t-LAMs A~Alvlli MiAiMfi Jo~ cMiUicoloc~ F lGURE t 137
Z5B 3IB 35g
sAUhE Nob1 488
0 0middot 1 1 26
BR Et L A13 0 R ~ l R v - 1 I G Hi STAT UN I Vt R S 1 I - DAYTON 0 H I O 4 5 4 3 5 DTE 822384 TIME 131~1
KRATOS MS25 DSSf SOfTWARE RUN TOR6SS41 WSU NAME CHJ-192828 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
254 4 21 5 I 49 7 16 Si 44 100
90
88
78
69
58
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18
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0 376 100Xbull27922
374 1BBXbull34690
4U 10BXbulll US
5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
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3BB
urn_
98
as
7B
6B
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~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
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58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
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48
38
28
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S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
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202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
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$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
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UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
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0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
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3B
2B
1B
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128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
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18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
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H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
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fl
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200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
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8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
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20
10
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5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
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18
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58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
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UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
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L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
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l N T~
F IGUFlE t 149
180
98
80
78
6B
se
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28
18
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BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
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I I
I
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BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
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40
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30 II I
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
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0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
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128 13B 140 15B
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1
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160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
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10
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bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
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120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
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51
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328 I
bull 332 1
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58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
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322 ~29 537 6tU
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58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
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[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
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6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
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28
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58 10S 15B 2BB 258 300
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
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HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
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I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
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SB I N T
u E N s I
3B T V
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lB
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2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
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4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
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10
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HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
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1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
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20
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l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
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N
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r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
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ZB
1e
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12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
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6f
SB
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lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
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lB
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amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
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23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
B
SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
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58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
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3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
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30
20
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0
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OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
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--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
UJ0
S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
__ -1--
n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
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h y
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
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S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
5g
s
30
10
20
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~~~~ ~~~~-~
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zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
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U 78 8B 98 lBB 110 128 SCAN NUMBER
tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
I6B 0 N
58 I N T E N
u s I T38 y
20
10
0
u 58 110 120
S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
~~ 60 1s as 90 t00
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
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------------------1-
r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
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bull 332 100Xbull139676 50 I
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SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
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S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
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50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
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61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
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SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
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58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
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OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
I 0 N
I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
n1 N T E N
48 l1
~ s I T V
30
26
I II I
I
UJ
J-1middot I
B II
I r--rmiddot I middotr middot-rmiddotmiddot middotmiddotr--
12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
-~ I --~ ______ y------ -(j
-middot-r==r~~ middotmiddotr- - middot 1- -Tr-----r- bull -I
--
iilt11i) L4blbullKAIUlY - ~ ll1HI gtutt UliJtICgt Iyen - uhyen _111 1tl1U +0+)J
DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
-l)--
___L__l_JJ__I 1 H 0 10 flt Xbull 17 8 9 4 1
30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
B
bull 472 IOOXbull134721
E N s I TI I y
1
----------------------- II I k------ ------- ------------- I r---__~-------------_____ middot-~---------~~----- ----------~~ --- -~ -
J
-___
-------- middot--------middot--bull-middotmiddotmiddot--- ---middot middot- middot-------------
~-
----r-middotmiddotr- r-r-rmiddotrr- I I I I I I I Tl-T I I I I I I I I r= I middot ------r-------rmiddot- r r ~r--iT middotr-i 1~middot11-----r-r-r I I I -r-r-+
middotbullI
I 0 N
I N T
~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
I N T E N s I T y
3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
AB
38
2B
10
B
0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
u
38
28
lB
B
JI 0 ( I 13 5 I 1 7 6120 7s2( 8t27
--1 - - - - - - - - - - - - - - - -
l 0 N
I N T E N s I T y
SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
B
50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
I N T E N s I T V
3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
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Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
----
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374 1BBXbull34690
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5B 100 15B 2BB 25BSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D1 F tGURE t 138
I 0 N
I N T E N s I T y
3BB
urn_
98
as
7B
6B
50
uJ
30
2B
1e
B
~--- BREHM L~BORAlORY - RIGHT ST TE IJ)LlVERSITV - 0AVTC~ OHIO (5435
KRATOS MS25 DS55 MASS
s01 1 26
0 392 1SBXbull6B7S97
39B 1SSXbull7512SC
329 1SSXbull2513Sl
SELECTED-ION
254
DATE 02238 ~IMEs 13U SOFTWARE RUN 10R63S41 WSU NAME CHJ-192828 47 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
421 5 C9 7 s 16 au
I 0 N
I N T E N s I T V
58 lBB 158 2BB 258 3BBSCAN NUMBER
Hbulldc-LMS A~AL~~i~ OBTAikto FOR CHEMEcolOG~ SAkPLE Ho2bi FIGUREa 139
rt F 1 4
~ BOR A -1 RY JR 1 G H T S l A TI U N I E R S IT - -JAYTON 0 H I O 4 5 4 5 DATE1 0223184 TIME 1349
KRl JS MS25 0S55 SOFTWARE RUth TOR700HJ WSU NAMEa CHJ-192028 47 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
001 1 10kJ 2102 3104 4 I 06 5 I 08 6 1 1 7 13
SCAN NUMBER~RGc-L~U~ A~ALvsfs 6erAlNEB Fo~ c~EMEcoLoGv sAMPLt Ho2bi
FIGURE1 140
100
90
80
7B
6B
5B
48
38
28
lB
0
S 419 100Xbull5537
amp us 10Ubull5735
0 478 lBBlbull(59
432 1BBXbull3837B
2B -B 60 80 lB0 12B U0
I 0 N
I N T E N s I T
V
- - - - -
100
90
80
7B
6B
50
U
30
2B
lB
B
001 1 00
LmL1111 _ UVl1-IVIY
KRATOS MS25 DSSS SELECTED-ION MASS
202
- WKHaHI iTlE UNIVERSITY - OAYTtN CHJO -5435 DATi 02238_-- TIMEr 13r49
SOFTWARE RUN JR70848 WSU NAMEs CHJ-192028 47 CHROMATOGRAMS FO~ HEPTACHLORODIBENZO-P-DIOXJNS
3r04 4r06 5 08 6 r 11 7 al 3
1801bull7B89
1001bull38370
100bull12576
______ - ~ -
1 l
--------~__~___~____A--~----~-_J_J_---__-L~-----1-1-LL+-L-~--lL-_L-L-L-~-L__J-L-L-L-J-L--1__J--L--L-LIJ_J__J_~-A--1-JJ--L__J-__1_L-_+
$ 426 1BBXbull19300
amp 424 lB0bull19678 =~ 0 359
432 J 0 N
434
I N T E N s I T V
u 6B 80 108 128 UBSCAN NUMBER
UlCC-LRMS AMALvsi 6afAtHED ~ol cHtUtcolOGV SAMPLE No2b1 FIGUREbull 141
- - - - -
Tt kl1231i TIME 1ifJ6 lltRAlU rltS25 DS55 S -TJARE RUN TORB0047 Jiu NAMEr CHJ-192028 47 SELEC)EQ-ION MASS CHk0MATOGRAMS FOR OCTACHLORODIBENZOFURANS
odl 6142 7 13 7 44 8 il 5 846 9d7 948 10 r 19 100 ____J-J-L_J L~--L---J-J____~__L-1~__~___________________Ll--L--L~L-~L-__LJ_______ ___-+-________~________~___J_________________~ ~_+-
$ 44 100Xbull5256
90
amp H2 l0Brbull4675 as
0 512 lBBlbull1798 7S
470 1BBXbull113177 68 I
0 N
472 1SBXbulll19359 68
I N T
-48 E N s I T V
3B
2B
1B
B
128 136 lU 158 16B 171 18B lU 2bullbullSC N NUMBER H~GC-LiMs AHALVS1S oATAIHEb loi tHfMEcblOG~ iAM-LE N0201
FtGUREc 142
BttiHr- lWfltl( - liiHt STArEJ-JJIVmiddotmiddotmiddotlP - llAVTON 01110 454j~ -TE 0223 T1ME 1~57 lrv-~ 7-middot
KRATO~- MS25 DS~5 _ IARE RUN TOR40053 WSU NAMEz CHJ-213049 IWI~middot 1
SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
B 13 1 B7 180 ~_______J--1 I
S 306 1BBXbull854354 90
amp 304 l00Xbull605297 8B
0 374 l08bull538 70
328 l00bull187587 60
332 lB0bull48368 58
u
30 ~ 28
18
B
18 58
214 322 429 537 6 44 I t_LL-J I ~L____amp_________________~~-t-
lBS 1 SB 280 251 38 SCAN NUMBER
I 0 N
I N T E N s I T V
H~Ct-li~i i~~~~sis 6bullt~i~t~ ~oi ~HiMicot~G~ s~M~i~ ~ozb~ F IGUftE bull 144
BREHM LABORATORY - JRIGliT S7ATE U(IVERSITY - )A(JN OHIO 45435 DATE1 022384 TIME 1457
KRATOS MS25 0S55 SOFTWARE RUN TOR40050 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
0d3 1 07 214 322 429 5137 61U H LJ___i
S 3~~X-SS0126 ~-J--~1~~ I90
amp 320 lfSXbullbulltbullaabull 80 J
0 257 l00yenbull12107bull9
70
328 10SXbulll87507 69 I
0 N
332 l00Xbullbull8368 5S
I N T Eu N s I T30 y
2B
10
g
fl
-11 -1 r J l___j ~-------
I
r
10 50 100 l 50 SCAN NUMBER
200 250 3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE 145
bull -BREIIM t_middot middotJPATOkY middot R ~~iT ST~E UNI ITV - ~ATON (HO 45435
middot-1 _- 022384 TIME1 1506 KRATOS MSS 0S55 S0f jw~RE RUN TOR50~41 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
0 01 --L-J
1 03 I
2 06 I I I
3 10 I
4 13 5 17 620 7s24 8127 I l-L_J__L_______--------_~_~~L--____J______-t-
0 340 l00bull708382
338 1BBl 43537
408 10BXbull 1 U8
I
I 0 N
I N T E N s I T V
8
5f 188 158 28B 25B 38B SCAN NUMBER
ubull~t-LIUsect AHAlVsis bltifUi6 Joi CHIUfcoligtGv UUJlf Uo2b2 F tGURE a 146
35B U8
BREHM LABORATORY - WRIGHT STATE U~IVERSITV - DAYTON OHIO 45435 DATE 022384 TIME 1506
KRATOS MS25 0S55 SOFTWARE RUN TORS0041 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-OIOXINS
0 0 l 1 03 2 l 06 3 I 10 4113 5r17 6120 7124 8127 100 ~ I ~
O 356 1B~Xbull417382 90 J
35-4 100Xbull258056 I 80 -+
291 18Ubull5BU23 7S I
I
2 60
50 [ i I ~
I T-40 y
3B
20
10
s
5S lSB 15B 200 250 308 358 us SCAN HUMBER
H~GC-LiMs ANALvsis OBTAIHfb ~~ CHEMECOLOGV SAM~LE Hoib2 FlGUAEs 147
hiElbullmiddot ABOPATG - Gll ~1ATE LtERSITY - DAYTON OHIO 45435 _ c E 0 2 2 3 8 4 TI ME 1 5 1 6
KRATO~ MS25 DS55 SOFTWARE RUN TORGff042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
BiBl l 26 254 421 549 7 I 16 8U lBB bull -1-~__J_j__ bull ~-------J-J~____________~-----J--L-----1--amp--L--J-J-J-_l--_L--L -amp-L--I-JL--J-________~___-___________--4_______i_J _____--+-
90
80
1B
60
58
41
38
2B
18
B
I I I r-
t I ~ I L
58
0 376 100=73047
374 1BBXbull63Bl2
bull tU lB01bull7tB
I 0 N
I I N T E N s I T V
UJ0 158 2BB 250 3BB SCAN NUMBER
H~GC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE NOZDZ FIGURE1 148
40
l)ftHM LAlHJKAIUtltY - WKHiHI gtIAlt UliiVtK)T - LJMr1v1middotbull uruu ~ jJ
DATE 022384 TIME 15116 KRATOS MS25 0S55 SOFTWARE RUNs TDR60042 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DJOXINS
001 1 26 254 4 21 549 7 16 8 44 100
90
80
70
60
50
30
2B
10
B
L - 1--------l--L---1---__J-_____
O 392 l00Xm574544
390 l00Xbull714164
329 l00Xbull231249
1 1 E
N s I T y
t
5B lB0 150 200 258SCAN NUMBER
HRGC-lRMs AHALYSis bttAtNE6 tolaquo CHEMECOLotv sAM~LE Ho2b2 3H
_________~____---___--~---J--___-----r----L-1----1-J_l-___I-L-LL----1-~_~-L-- L__J___1-_-L__--L_--__l-L-L-L--l-L__J___1-L-L----I-L-L-l-
- - - - - - - - - - - - - - - -t-I
I ~ 0
~ N
l N T~
F IGUFlE t 149
180
98
80
78
6B
se
t8
3B
28
18
B
BdH 1 BB
BR1J1 oCiKATl Y - lJGl11 ~~-TE t~-~Rlt11 v - lAVTON ()HlO 454-5 LTE 021236middot middotmiddot1r-iE~ lfi25
KRATO MS25 [LoS _ fwARE RUN TOR70041 WSU NAME CHJ-213049 SELECTED-JON MASS HRO~ATOGRAMS FOR lfEPTACHLORODIBENZOFURANS
2 02 3 04 4 86 5 08 6 11 ~ I ~ ~
S ~IS 1BBXbull112Bl
amp U-8 lS8bull
1 2B U u aSCAN NUMBER
HAGt-LRMs AHAL~iit ba1IHE0 toRmiddotcH~MEcoLoG~ 188
sAMh~ Ho2b2 128
FIGUftE 1 150
7 13
lU
I 0 N
I N T E N s I T V
I I
I
I
I I-
BREHM L~BORATORY - WRlGH~ ~TAl~ UN1~K~11Y - UA~l0N UHU 4b4Jb DATE e22384 TIME 1525
KRATOS MS25 DS55 SOFTWARE RUNt TOR70041 WSU NAME1 CHJ-213849 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
0dH 1100 2 02 384 4 06 5108 6 il 1 7 t 13 100 l --L~-______________~_------_________~_------___ _____________~_----1-1-J--l-L-l-l-J--L-1--l---l--middot~_1-JJ-L--l--Jl---l-L-LJJ-l---l-L-L-L------L-J--r---~-______________~+-
$ 426 l00Xbull59017
90
i I
~ 424 l00tbull61230 80
0 359 130ibull19179 78
432 1B0Xbull21734 60 i I
0
i 434 l00Xbull6376 50
~ 1 NI~
i N
I T I- E N
40
s T V
30 II I
I
r 23 I
~-
Ill
I-i
il16 ~II
I 0
I~ I I
20 U 60 80 lBB 12B SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
B
322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
u j i ~
r
A~ II il iJIIV Ill~
~ 11W
n ~1 ~lllA ~- ~11)iWfl ~~i( ~
T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
V I r IIIJ ~ ~
I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
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S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
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23 7pound
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I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
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31
20
lB
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SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
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5S
N s I Tu y
30
21
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58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
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I 0 N
6B I N T E N
SB
s I
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3B
2B
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VV lB
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SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
----------
----------
--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
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S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
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n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
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432 1881bull 1872 60 I - - - - - - - - - - - - - ------- - - - - - - l-1 - - _L
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h y
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18
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
~~ --
S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
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s
30
10
20
vi ~~~ B
~~~~ ~~~~-~
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zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
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U 78 8B 98 lBB 110 128 SCAN NUMBER
tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
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58 I N T E N
u s I T38 y
20
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S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
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SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
Ift I~
------------------1-
r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
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l j 11
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328 1BBlbull18B436
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bull 332 100Xbull139676 50 I
NJ ij1 T
EU ~~ I I I
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3B ~ Imiddotmiddot 1~12B
lB
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__
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I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
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S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
I N T E N s I T v-
50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
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I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
10
s
61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
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I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
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10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
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HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
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--
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DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
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30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
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bull 472 IOOXbull134721
E N s I TI I y
1
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~-
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middotbullI
I 0 N
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BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
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3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
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60
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38
2B
10
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0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
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--1 - - - - - - - - - - - - - - - -
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250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
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middotmiddot1 I
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
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CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
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wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
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SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
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31
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11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
B
50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
(
~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu
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HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZD2 FIGURE 1 151
140
18
riRpound1d bullA80KA 1 i1RY - 1dGHl 3f)r INIVErltSTY - [JAYION OHIO 45435 _TE kf22_ 4 TIMEr 15~~9
KRATOS MS25 0S55 s~iTWARE RUN TOR80S~8 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 642 7 13 744 8 15 846 9 17 948 10 19 1HH L----J~ ----L-L--L_~~~- L 1--l-J_l--------1-JJJf____________ JL-L-L-L-L----L-i_ --4--1--1--JL-JL-L-~~~~~~-------_______+-
$ 444 UJ0Xbull5Sl 1
90
amp U2 10BXbull606 es
0 512 l001bull2796
7B j= H0 l001bullU779
60 L j
t72 l001bull8168 5B
u I 3B
20
B
128 13B 140 15B
J 0 N
I N T E N s I T V
1
I I I I I I
160 17B 188 UB 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 FIGURE 1 152
-- - - - - -- -
------------ ---- _______ ----
middot0
10
HJ
7g
60
50
40
30
2f
10
B
bull
1
16 l 1 642 7 13 7144 8 15 846 917 948 10119
middotmiddot---~~~L~~~~-bull -bull-~- ~ L ~~
BREHM LABO~~TU~V - WRGHT STATE UN~~RSlTY - C~YTON OHIO 4b~~b
DATE 022384 TIME 15139 KRATOS MS25 0S55 SOFTWARE RUN TOR82048 WSU NAME CHJ-213049 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
~~~l_____~~~- - - - - - - - ~ 0 395 l00~bull21669
I
N 10 100x 4779
-+ I
02 l00X=-48168 ~ II
l Ii i tIl
l
_JfI
120 13S 140 lSS l6B 170 18B 190 2H SC N NUMBER
HRGC-LRMS ANALYtts OtiTAIHED FOR CHEMECOLOGV SAMLE H0202 FIGURE 153
I 0 N
I N T E N s I T y
I
--~~ 811tHmiddot - ultATO t - r middotcHT ~~rmiddotTE --_VEKSiT - OAtTON vHIO -45435 rmiddot middot middot i ~ 2 2 3 8 f I ME 1 i 1 q
KRATOS MS25 DS5 SC bullJARE RUNi TOR40051 IJSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR T~TRACHLOROOIBENZOFURANS
BdJl 1 iB7 214 322 429 5137 6 44 lBB
~ S 306 100bull860
_L9B
amp 38-4 1BBlbull787es
1j
ut
51
U
38
2iJ
IB
0
0 37-4 1
328 I
bull 332 1
_ 378 I 0 N
I N T E N s I T V
58 lSS 15BSCAN NUMBER
21611 251 3BB
HRGC-LAMS ANALVits OBTAINED FOR CHEMECOLOG~ SAMLE No202 FIGUREbull 154
- - - -
BREHM LABORATOR~ - WRIGUT STATE UNIVRSITY - DAfON OHIO 4bbull3b DATEr 022384 TIME 1618
KRATOS MS25 0S55 SOFTWARE RUN TOR48851 WSU NAME CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
OdH 1107 2 I 14 180
5 100Xbull10B832 rimiddot90 - - - - - - - - -1- -
amp 328 l0SXa798 ~ 80
0 257 100Xbull878
7B
328 1B0Xbull195851 60
SB
40
3-J
2S
1e
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322 ~29 537 6tU
l ~ VVf Y
IJ 1
I
-2378
--f- --I 0 N
I N T E N s I T y
58 1B0 1 50 200 258 3BB SCAN NUMBER
H~GC-LRMS AUALvsf bBTAiNED Fok CHEMEcOLOG~ ~A~Lt N0202 FIGURE 155
a ff ampstmiddot --~
-----_
[-ciil 3ORT- - middot G~f r 1-fl L EtLi rt DAYTCI OHIO t5~3J rrE 0212384 fJMI lf27
KRATO~ MS25 OS55 ~Ui TYARE RUN TOR500~2 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR rENTACHLORODIBENZOFURANS
BsBl 1 03 2106 310 13 517 62S 72bull 8127 100
0 3B
I bull I
10SJbull846
I I I I _l_______l_______J_ __ J _____L_ I _l ___J_ ___ J _ _j____J_ I I l I _l _ _1 I I I
I 9B -+- - - - - - - - - ~ - - - - - - - - - - - - - - - - - - - - - - - -
338 lBByenbull596
81 ~---- - - - - - l - - - - - - - - - - bull--+-
11 4B8 lBBIbull 193 I
I 0
II - ~ V ~
N
I N u
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A~ II il iJIIV Ill~
~ 11W
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T E N s I T V
II 1) r ~I W-ij ~ ijiJWl11 II ~M I m1 ~lir
I- hi~M tJ
~- JlB J ~ I~
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I 1 1 I 1 1 I r --------------~-- --- --r---y~- --- 1 - - -- I I I I I I I -T -- I I I I I I I I -f
6B lBB 15B 200 25B 3BB 35B 4BB SCAN NUMBER
HNGc-L~Ms ANALvsfs barAiNEo FOR cUEMEcoLotv sMPlE Hozbz FIGUllEa 156
BRfYM LABORATORY - WRiGHT smiddotAn UNIVERSIIY - DAYTON OHIO 45435 DATE1 022384 TIME1 1627
KRATOS MS25 0S55 SOFTWARE RUN1 TOR50842 WSU NAME1 CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
8101 l 83 206 3 18 4 13 5 I 17 6128 7124 8127 l0S
0 356 l00Xbull200 90
354 l00Xbull469
80 ---i I
291 lBSXbullamp877 78 ~ I
0 N
68 I N T E
BB N
s Iu T y
38
28
18
0
58 10S 15B 2BB 258 300
~
358 u SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N0202 FIGUftEr 157
r-----_ BRLH1bull j()Rmiddotbull 1 f -
KRATO~ MS25 OS~5 SELECTEJ-ION MASS
0dJ1 1 r 26 254
i- IGHbull STATE --_f ~17( - DAYiJN OtHO 45435 rE 02231 dME lbl
ufTWARE RUN TOR60043 WSU NAME CHJ-22 HROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
421 549 7 a 16 844 li0 ~L-L-J__L--_______~_j_J_L___J I I I I
0 ~~6 ~BIJXbull3~2__ - - - - - - - - - - - - - - - - - - ~90
374 IBBXbullIB625 - - - if - - - - -8B
H4 1BIXbull07 7B
] 0 N
6B ] N T E N
50
s I T V
3e
2B
lB
B
5B lBS 15B 2BB 25B 3BB SCAN NUMBER
HAGt-lRMS ANALVils oiiAiNE6 ol c~fMEcotoGV SAMPlpound ko2bz FIGUflEa 158
68
BREHM LABORATORY
KRATOS MS25 0S55 SELECTED-ION MASS
0 I 0 1 I 26 2154
- WRIGHT STATE U~IVERSYTY - DAYTON 0rtlO 4543~ DATE 0l2384 TIME1 16r37
SOFTWARE RUNr TOR60043 ~SU NAME CHJ-22 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
4 21 5149 7 I 16 urn
90
80
70
50
40
30
20
10
s
_J_J_ ___________~_____ J__J____-----L---~ __-L-______~____________------------L--LJ__-L--L-l-L--L--1--1-__-L--L-J----L--L--1-1-L~--J~
0 392 l00Xbull3594
390 l0SXbulll4026
329 10Ubull3518
5B 1BI 150 2BB 25B SCAN NUMBER
HRQC-LiMS AHALVi1sect barA~Eb Foi CHEMtcoL~v SAM-LE ~0~02 FIGURE1 159
8U
I 0 N
I N T E N s 1 T y
3BB
H~ HORAT- middot - - GHT Sl middot7f~iHVEHS - middotmiddot - DtYTON uHIO 45435 middot middotq= JJ2 I 2 3 - TI t-1E 16 - S
KRATOS MS25 DS5 v VARE RUN fOR 76B42 WSU NAME s CHJ-22 SELECTED-ION MASS i_HROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
BdJl 1 0J 2dJ2 3 04 (dJ6 5 08 6 s11 713 100
90
80
70
I61 0 N
SB I N T
u E N s I
3B T V
2B
lB
B
2S 12B 14B
S ( 10 l00bull2682
amp (88 180Xbull12ZC
0 HB UJ11bull37-
UZ 1BBXbull9786
I
4B 6B BB JBBSCAN NUMBER
HkGC-LIMsect AU~lvsectis 61fAfUE6 olaquo cUEMEcbl66v sAMLf Ub~62 ~ IGURE s 160
DATE 022384 TIME 1646 KRATO~ MS25 0S55 SOFTWARE RUN TOR70042 WSU NAMEi CHJ-22 SELECTEu-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
001 1 00 2 02 3t04 bull i 06 508 6 d l 7 l 13 10~
90
80
70
68 I 0 N
50 l N T
U E N s I
30 T y
20
10
0
2B 4B 60 es 1s0SCAN NUMBER
HRGC-LiMs ~UAlvsectts bfiAiHE6 Foi cHtMEcoLOG~ sAMPLl Ho2b2 FlGUFtE1 161
J__l_~J---------__L-____J-___________L-+-J_-----J--------~__~________-L-_LI--L--------------l------J-~J--------L___________~_ ________________L-____________~~-----
$ _26 l00XbullH5
amp 42 l00Xbull817
0 359 100bull2630
12B 1-48
v---fJ
r
1-11Hll LAl3l1i--middot middot bull -bullidGHf smiddotIATE-tllrEiSITV - DAYTON OHIO 45435 ~~TE D223 TIME lt58
kRATOS ~S25 D~SS ~ ~TWARE RUN TOR80B49 w~u NAME CHJ-22 SELECTED-ION MASS Ln~OMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6dl 642 7 13 744 e 1 s 846 9s17 948 10 19 10B
90
80
70
60
50
u
3B
20
10
B
l--LLL-L-L-JL IL-L-J --1~ I I J_____-~--L---_____-+- __J----------__J~L----L-1--LJL-J_J-J~J-_L___________i--1~____Jc---L--L
S -4U 1001bull764
amp HZ 1BBXbull1295
0 512 lBBIbull 1077
47B 1081bull26737 I 0 N
I
T
N
I T V s E
N
r 1 4 I
148 150 160 170 180 198 280SCAN NUMBER
HRCt-L~MS AUALYis oifA1NED FOR CHEMECOLCgttiV SAHPii Uo2b2 FIGURE 162
12B 13B
BREHM LA~ORATORY - 1R4G~T STAfE tNIVERSITY - DAYfON OHlCJ ~b4jti
OATE1 022384 TIME 1658 KRATOS MS25 0S55 SOFTWARE RUN TOR80949 WSU NAMEs CHJ-22 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-OIO~INS
6 I 11 61(2 7 13 7 44 8 I 15 8146 9d7 9 l (8 10i19 00 _ _ __ ______________~___--~_____-L-J_______l___i-----l-L-___________________________________J__JLL-l---__+-------~L-LLL-LJ-L-poundJ--L---l--JL-JLL-~t-~l-~-4--~-J--------~----------__--
98
80
78
$ f62 100yenbull676
amp se lBBXbull(25
0 395 1BUbull5t6
47B 1SBXbull26737
472 lB0bull27937
I63 0 N
50 I N T E N
40
s I
3B T y
ZB
1e
B
12B 130 140 15B 16BSCAN NUMBER
170 18S 19S ZBB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO202 FIGURE s 163
BREh ASORAmiddot_ - 1 dSH1 -STA__JiHVtRL middot- ~AVON OHI~ 4543c LAIE JJh- A TIME Ui24
KRAlu MS25 0S55 SOFTJAkE RUN TOF400CJ2 SU NAME CHJ-4674 SELECTpound0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURANS
8101 9B7 l011( 1122 1230 1337 1( (5
BB
9B
SB
1B
6f
SB
u
3B
28
lB
bull
S 386 1081bull816
amp 3Bt 1BBXbull6B8 - - - -0 37-1 lBB1bull289
328 1flXbullUB76
J
5f lBB 15BSCAN NUMBER
2BB 250
I
r r
388
I 0 N
I N T E N s I T V
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGURE 1 264
ERitJlof LABO~TOtV middotmiddot JPlGHi 7ATE UNImiddotVERSirY - uAYTOh OHIO ~5435 DATE 0V1084 TIME l5s24
KRATOS MS25 0S55 SOFTWARE RUN TOF40002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
e 01 9107 lB 1 14 11 2 2 1 2 I 30 13137 14145 100
9B
80
7B
68
SB
40
30
2B
lB
B
S 322 10BXbullUU
amp 32tl 188yenbull608
0 257 1BBXbull363227
328 1BBSbull64876
1BHbull35153
I I
~
-i
I
23 7pound
I 0 N
I N T E N s l T V
58 lBS 150 SCAN NUMBER
2BB 250 JBS
HRQC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02D1-MS-F FIGURE 265
BREHtl 1-RORAT-~ - iRIGHT STAT~middot t=~ilT - 0AYTOif OHO ~5-43fJ -- [ATE 0410 TIME 15r33
l~RATG-_ MS25 0$55 so~TJARE RUN fOF50002 WSlJ NAME CHJ-4674 SELECTE1-[0N MASS CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
BdJl 1 03 207 3 11 4 15 520 6125 728 8132 U0
0 3U lBBXbullS05 9B
338 1881bull429
ee-
C18 1IB1bull181 7B
I 0 N
u I N T E N
SB
s T I
V
31
20
lB
B
SB U0 150 200 250 3BB 350 IBB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR middotCHEMECOLOGV SAMPLE N02Dl-Hi-J FIGURE 1 266
0Ttr JU1084 TIME1 l5s33 KRATOS MS25 0S55 SOFTWARE RUNt TOFS0002 1 WSU NAMEr CHJ-467 SELECTED-CON MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIO~INS
SdJl l dJ3 2 I 07 3amp11 5120 6125 728 8s32I 15 Ul0
0 356 U0bull1176 98
35 108Xbull3H
88
291 l8UbullUB8 71
I 0 N
6B
~ l)W
I N T E
5S
N s I Tu y
30
21
11
B
58 lS8 150 2S0 25B 300 350 UB SCAN NUMBER
H~CCbullL~MS ANALVSJS OBTAINED Oft CH~COLOGV SAMLE N0201-HI-F FIGUREbull 267
~1EI-I~ bullABOPAT~~y - bulldGI-H 1AT--~IVERSITI - uYTON OHIO 45435 DATE B410_ TIME 1643
KRATGS MS25 DS55 SOFTWARE RUN1 TOF60002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
01Bl 1 I 26 254 423 551 7s19 8146 us
0 376 1001bull59-6 9B
37 1BBlbull1572B
80
-U lBBlbulll79C 7B
I 0 N
6B I N T E N
SB
s I
T V
3B
2B
J ~
VV lB
g
SB 100 158 SCAN NUMBER
200 25B i 3BB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0201-MS-F FIGUREbull 268
Bf4
90
80
70
60
50
u
30
20
1B
0
B 0 l 1 26
OrEHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2154
~iqHl ---lA-1 UNlVkKSir - LAlvt4 UHU ~o-+JJ DATE Jt341084 TIMEr 1543
SOFTVARE RUNs TOF60002 VSU NAME1 CHJ-4674 CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DlOXINS
4s23 551 7 l 19 8146
i_J_l--l_L-_ __--1_~L---L---I---JL--~J--L--L-L-J-L-JL--l-l--L-_l-_J-J--l---~J__L-1_L-J_J-_J_1_L_J_JJ--IL--~J--1_L-J---------J-L__________-r
0 392 10Ubull54H
390 1001bull14367
329 1BBXbull8761
I 0 N
I N T E N
5B lBB 160 ZBB 25B SCAH NUMBER
HRc-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV siULi ko201-Ms-F FIGURE 269
1J~ ~JV
I
s I T y
3BB
- - - - - - - - - - - - - - - - - - - - - - - - -
----------
----------
--= r-----
~RrH~ ~ABnRATO~Y - ~~~GHl ~~li iVERSITV - D~YTON Jhi0 45435 Cq E FU 1084 TIME 1Ss54
KRATOS twS25 DS55 SOFTWARE -RUNs TOF7fbull002 WSU NAME CHJ-46 74 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
0101 1 00 202 3 06 4108 Sill 613 i
UJ0
S 4 U UJUbull5527
90
amp -BB l8BXbullU84 88 __ - - - - - -
__ -1--
n~r -------- - - - - - -0 478 18BXbull922
78 I - - - - - - - __ ---
___J_ - - - - - - - -
432 1881bull 1872 60 I - - - - - - - - - - - - - ------- - - - - - - l-1 - - _L
0 1
N 434 l081bull3567 58 I
lT
1 N
U -1 IJ II ll I E N s
I 3f -I l y V A A I I l T I
h y
I2B I I I I - M I I AU l I V I t 1
18
B ~ (
1 28 uJ 68 SB lBB 128 usSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dt-M1-F FIGURE 270
r--rr
Vj ~ _ I 11 bull
1
~~ --
S 426 U0yenbull1771
amp 42( l0BXbull1991 a - - - -
0 359 lB8bull6186
432 lBBXbulllB72
middotV
~~~HM LABORATORY - W~l~H~ ST~~~ UNIVERSilY - DAYTON ~~10 45435 DATE1 at084 TIME l5a54 KRATOS MS25 DS55 SOFTWARE RUN1 TOF70002 WSU NAME1 CHJ-467bull SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
8101 1100 2 I 02 3 I 06 4 108 5 r l l 6 I 13 7116 100
90
88
7S
68
5g
s
30
10
20
vi ~~~ B
~~~~ ~~~~-~
~___-- ~~~~---- - r--
zg 4B 68 80 lB0 12B lU SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Dl-M6-F FIGURE 1 271
l 0 N
I N T E N s I T y
------~-IV ~ ~J
BREHh A3iiPATOR - ~bull1-GHT STAT --ir-1~~1middotrmiddot( middot DAYTON OHIO _54Jti -TE ~ 4 10 6 T I ME 1 6 0 4
KRATOS MS25 DS55 SUTWARE RUNc TOFS0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR uCTACHLORODIBENZOFURANS
502 5H 6 i05 6s36 7 amp168 739 8 sl0 8s41 g 12 lBB
9B
SB
711
I6B 0 N
SB I N T E N
4B
s I T V
3B
ZB
18
B
U 78 8B 98 lBB 110 128 SCAN NUMBER
tfflQCbullLRMS ANALYSIS OBTAINED fott CHEMEcolocii iAMLi Ho2ni-Mi- FIGURE 272
S 4 U UJBXbull2855
amp U2 lB81bull2666
- - - -0 512 l881bull7Z61
47B 1BBXbullZl624
472 1BBXbullZZ527
W-l-amp
48 58
CATE ~4le84 TIME 16s04 KRATOS MS25 DS55 SOFTWARE RUN1 TOFB0002 WSU NAME CHJ-4674 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
5 02 5r34 605 6g36 7 108 739 8 10 8 g 41 9 r12 100
90
80
70
I6B 0 N
58 I N T E N
u s I T38 y
20
10
0
u 58 110 120
S 460 100Xbull2953
amp -458 l80Xbull2661
0 395 1SUbull2198
470 1SSXbull2162
bull -472 100Xbull22527
~
~~ 60 1s as 90 t00
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE HO2D1-MS-F
FIGURE 273
------------------- ----
~- I I j 1 i
1V I I
Ift I~
------------------1-
r
Gl[tlf-l LJcl0RAH Y middotbull bull~hmiddot~- S(AiE-JVEKSltY - 1Avl)1 1 01110 45435 ~~lE 0382 TIME 132n
kiATU fS25 DSS SulHIARE RUN TOR4fJHi6 WSU NAME CliJmiddotmiddot-tB75 SfLECTE0-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZOFURAHS
0 l 0 1 1 fJ 7 2 l 4 3 2 429 537 644 UHJ J - L- _L __ J_ __I __ ___ - L _J ___L I __ _middot- 1bull1 - I J _ L l L -11_____1 ---l-J -~ l L J_ middotbull---L-- I __J_ -bull--11 _ __ J_ -bullmiddotmiddot l-1- middot--- L _j _ l J L L J __ __ L-- _I L-1 _J__ J ___ L___ -
$ 306 H0Xbulll700if li-2378 l 90 -- - -- --- - - --middot - --middotbull - -- --middot --- middot- -- - - -- middot11 - -- -
_ ~~ -~lJ~~-1~9~ __ __ __ _ __ _ __ __ _ _ _ __ _ I80
0 374 100Xbull498 ~-
~
8J
l j 11
7B
328 1BBlbull18B436
I - [ 0
66 N
bull 332 100Xbull139676 50 I
NJ ij1 T
EU ~~ I I I
I
N st ~ j
T V
3B ~ Imiddotmiddot 1~12B
lB
B
__
---- ________
I I i ---r-middotmiddot-r-rI-J-r-t-r-T--~-------- lBB 15B 2BB 25B
SCAN NUMBER HRGC-LRMS ANAlVsis OBTAiNED FOR CHEHECOlOGV SAMPLE N0202 H5 F
FIGURE 274
58 3BB
90
UAlt JJO~d4 llMtamp ljLJO
KRATOS MS25 0S55 SOFTWARE RUNs TOR4mB76 wsu NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-OIOXINS
0dJ1 11 B7 2 tl 4 3122 4129 5137 6144 100
80
7B
6B
SB
HJ
3B
2B
lB
B
S 322 1SBXbull15266
amp 320 UUbull12126
0 257 10BXbull2Sss
328 1SBXbull18B436
bull 332 1BBXbull139676 2378-
_______ II w ~
_____---=----~1 t-------t 1-----l-- 1 1 I -r---middot--middot 1 i 1 1 --c-r-r ri---rl middot1 middot - t
I 0 N
I N T E N s I T v-
50 lB0 158SCAN NUMBER
20H 250 308
HRGC-LRMS ANALVSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 MS F FIGURE 275
si
BP-EHfi Al3ORAf middot - JPiGHl 5TAi ~ ~IVUlTY - DAY1Cf( DHO 46435 ~~TE ~3~1middot TIME 1329
KRATC~ MS25 DS65 ScfTYARE RUN 1OR5m064 wsu NAME CHJ-4875J SELECTED-ION MASS CH~uMATOGRAMS FOR PENTACHLORODIBENZOFURANS
Bs01 1 03 2 06 31 HJ 4 13 5 17 6120 7r2~ 8127 100
98
88
78
68
38
28
18
B
0 348 1BBXbull19517
338 1801bull12581
bull 4B8 lB81bull516
I 0 N
I N T E N s I T V
1 5B lBB 168 2BB 25B 3BB 351SCAN NUMBER
Ui~~-llUI AN1lvsil bifAfUfB o1 EUfUlcol6iY l~MJll Uo2b2 Ml FIGUtl~bull 276
01Bl 1 a03 190
0 356 108bull16949 98
354 1BBbull11BB2
as
291 l981bull7518 70
68
58
u
if
28
10
s
61
BREHM LAeORATORV - ~~l~ltT STATE UNIVERSlTi - DAY~LlN OHIO s35 DATE 030284 TIMEs 13129
KRATOS MS25 0S55 SOFTWARE RUN1 TOR5SH6 WSU NAME CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXINS
bull
2 l 06
1BB
3d0
15B
4 r13 517 6120 7124 8127
2BB 25B 3BBSCAN NUMBER
I 0 N
I N T E N s I T V
35B ubull HRQC-LRMS AHALVSIS dBTAIHEO FOR CHEMECOLOGV SAMPLE N0202 MS F
FIGUFlEs 277
ERE4M lAIWRATORY - RIGHT ~-S-4middot-rElSITY - DAVTOt CtilO ~~435 DATE 0~ili2 TIME 1339
KRATOS MS25 0S55 SOF middot-JARE RUN I TORG0065 WSU NAME s CHJ--48 75 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
B81 126 254 421 549 716 eu 100
0 376 100Xbull8363 9f
374 1BBXbull2488
8f
bull 4U 1BBlbull133 1B
6B
51
46
u
2B
1B
SB lBB 15B 2BB 25f 3BfSCAN NUMBER
Uiamp~-llMs ANALVifsect 6lfAiHEb ~oi cM~MtcoLbGV sAU~LE Hb202 Ms F FIGURE 278
I 0 N
[ N T E N s [ T V
8
0ATE S3B284 TI~Ea 13139 KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB65 YSU HAMEs CHJ-4875 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
BdJl 1 26 2154 100
0 392 1B0Xbull57348 90
as
70
bull
398
329
lS8Xbull69492
l88rbull2616
6B
58
u
3B
28
18
4 I 21 5r49 7 I 16 au
I 0 N
I N T E N s 1 T V
58 108 158 288 258 3BB SCAN NUMBER
HUc-LR4S Af(AL~sfs oaHiUEo FOR CHEMECOLOGV HMHE Uo262 Ms r FIGURE 279
Li1-U1r LAUVKA1( l
l i
KRATCS MS25 SELECTED-ION
OSS5 MASS
0101 l 1BB 2 02
0
- -1-i11 ~l~IL---11L-Jltmiddot - LJ tlt~bullibull UHIO 4t4Jb fmiddotTE 23021 fIMI Ii~7
SOFTWARE RUN TOR700E6 JSU NAME CHJ-4875 CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
304 4 dJ6 5dJ8 611 7 ll3 IBB
98
SB
7B
68
68
4
3
2bull bullbull bull
J_j_J L-l~___j__LL________J__~--L~1-- I le I J_J___J_L I I I -L-i~-1__t_J
$ -tlB lBBKa-699
amp cee 1snbulls119
0 478 lB81bull618
bull 32 1bullbull1-sbull11
bull 34 1bullbullr-1s2
1~
l
I
I 0 N
I N T
~ s I T V
2B s 6B SB lBB 128 UBSCAN NUMBER
UR6~-Li~I ~Rilvsectfsect ld1i~lo 61 cUfUttampigtlv s~UJll Ulaquoia2 Mi F FIGURE 280
BttrnM LABORATO~V
KRATOS MS25 0S55 SELECTED-ION MASS
0101 1 100 2 d32
middot- URir~T STATE UIUVERSIf - DAriON OHIO 45435 DATE 030284 TIME 13147
SOFTYARE RUN1 TOR0866 YSU HAMEi CHJ-4875 CHROMATOGRAMS FOR HEPTACHLOROOIBENZO-P-DIOXINS
3s04 4 dY6 5 I 08 6 cl 1 7 I 13 100
90
80
78
6B
SB
40
30
2B
lB
B
----L----J-l----1-__~____ _ __________~~__---__-~_ _______________~____~_____~_________J_1---L----L-4---1--------_~--- __-________--1i-- ______~~__~--
$ C26 l0Ubull7199
ampr C24 l00bull6679
0 359 1B0Xbull5150
t32 100Xbull-SB17
C3t 1BSbull14524
2B CB 60 es lB0 120 SCAN NUMBER
I 0 N
I N T E N s 1 T y
10
HRGC-LRHS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N0202 HS F FIGURE 281
P EHM LBORAfORmiddot - ibullmiddotmiddot ~HT - bullTE u~stY - iAYTON (HIIO 1b43r 1 _ E ff 3 0 2 f11 T I ME ) 4 ti 3
KRATOS s2s DS5poundi SOt I wRE RUM 1 OR80072 ISU NAME CHJ-48 i5 SELECTED-ION MASS CHROMATOGRAMS 1-0ll OCTACULOROOICENZOF IJRAUS
6 11 642 713 7144 815 846 91 9 ~ 8 l019 lfl0 bull I - I -bull I - middotmiddot l -- I 1 L L--1 L 1 _ I _J_ L--lJ __ ___ f lbullL L_J Jbull L J_J L I Imiddot--middot L 1-1J bull L-_
- LL~~ L -- --~J~--L--~-L~bull~~-bull~-L-~ J __ --~~ $ 444 lBSXali~53
90
amp 442 UJ01bull9477 I83 -r0 512 l0BXbull1516
7B -l - - -- - -- -- -- ~70 1001bull126296
(60 0 N
~72 100yenbull134721 50
I
n1 N T E N
48 l1
~ s I T V
30
26
I II I
I
UJ
J-1middot I
B II
I r--rmiddot I middotr middot-rmiddotmiddot middotmiddotr--
12~ 13B 143 150 16B 17B 18~ 196 2BB SCAN NUMBER
HRGC-LR~S ANALYSIS OBTAINED FOR CHEHECOLOGV SAMPLE N02D2 MS F f IGUREr 282
------------------------ -~ --- ----- --i
middotr-- I --r- middot-middot r--- -middot-1-- rbullmiddotmiddotmiddot -----r-rmiddot j
~middot I 1middoti -bull I
-~ I --~ ______ y------ -(j
-middot-r==r~~ middotmiddotr- - middot 1- -Tr-----r- bull -I
--
iilt11i) L4blbullKAIUlY - ~ ll1HI gtutt UliJtICgt Iyen - uhyen _111 1tl1U +0+)J
DATE 1 030284 TIME 14 03 lltRATOS ~S25 0S55 SOFTWARE RUNs TORB0072 WSU NAME CHJ-4875 SELEcmiddotrED-ION MASS CHKOMATOGRAMS FOR OCTACHLORODIBEHZO-P-OIOXINS
6 l 1 642 l 13 7 44 8 I 15 846 9 I 17 9148 10 l 19 lJj(T
-middot I 1 bull _j L--middot-bull--- 1--I J L_J__ _ __1_______i I - I I J_ _ l_cJ_ J Ll--J LJ- Jbull1L I J_J lo- l bull l J -1-1 --4_i_]_ J-_l- __-L_jLJbull J_ L___ _L-L-1 -11J J-L J
-l)--
___L__l_JJ__I 1 H 0 10 flt Xbull 17 8 9 4 1
30 ---- --- - -- -- middot-- - -11r - - -amp 458 10~X~l5408 - -- -- -- -- -middotmiddot -
120 139 140 150 160 SCAN NUMDFR
17~ 180 190 2BS
HRGC-LRMs AHALvsis oerAiHEo FoR cHEMEcoLocv SAHPLE NO202 MS F FIGURE 283
80 O 3 l0flXm90U
7S
4lll 1B0Xbull126296 60
~ 50
40
3S
20
10
B
bull 472 IOOXbull134721
E N s I TI I y
1
----------------------- II I k------ ------- ------------- I r---__~-------------_____ middot-~---------~~----- ----------~~ --- -~ -
J
-___
-------- middot--------middot--bull-middotmiddotmiddot--- ---middot middot- middot-------------
~-
----r-middotmiddotr- r-r-rmiddotrr- I I I I I I I Tl-T I I I I I I I I r= I middot ------r-------rmiddot- r r ~r--iT middotr-i 1~middot11-----r-r-r I I I -r-r-+
middotbullI
I 0 N
I N T
~ tgt~- -
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEs B3B284 TIMEbull 1Br51
KRATOS HS25 0S55 SOFTWARE RUNr TOR4BB74 WSU NAMEbull CJ-68 SELECTED-ION HASS CHROMATOGRAMS FOR TETRACHLORO0IBENZOFURANS
B12B 11B7 2 14 3r22 4 I 29 5137 61H 10B
9B
es
11
S 3B6 1BBXbulll165B5
amp 3bull4 1BBXbull9B4B6
0 374 lB91bull562
bull 328 1BBXbull161~37
I 332 1BBlbullll~623 ~
15 50
~I ~I
V
-l 318
I6B 0 N
SB I N T s E N s I T V
30
20
18
f6
180 15B 2B~ 250 3BB SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAiNED FOR CHEHECOLOGY SAMPLE NO2A1 17 F FIGUREr 433
L L Ht - BoRA r o R Y - middotr-i G H T s TAT E u N I v ER s If Y - oAv 1 o N bull u IiI iJ 4 ~-~ J 5 DATE1 030284 TIME l0151
KRATOS MS25 0S55 SOFTWARE RUN TOR40074 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
100 B 20 1107 2 14 3122 4 I 29 5137 61U
S 322 1BBXbull1B4988 90
80 amp 320 l0BXbull8158
0 257 lB0bull51649
7B
6B 328 1BBXbull161437
SB 332 l0BXbulll17523
u
38
2B
lB
0
I 0 N
I N T E N s I T y
3BBl0B 150 280 250SCAN NUMBER
wlc-LUI AUAlvlil biiAiUi6 deg CHEUfcol6Gv sMJLi Uo2Al 17FIGURE 434
15 50
~-
BB
98
80
7B
60
50
AB
38
2B
10
B
0101 1 dJ3 _J_j________________
O 3-0 1SSXbull98U4
338 1081bull59894
488 108bull393
L~
BREHM LABORATORY -
KRATOS MS25 0S55 SELECTED-ION MASS
2106 3110
I
WRIGHT STATE UNiERSITV - DAYTON OHIO 45435 DATE 030284 TIME llaBB
SOFTWARE RUN TORS0062 WSU NAMEbull CHJ-68 CHROMATOGRAMS FOR PENTACHLORODIBENZOFURANS
4 r13 517 6120 I
7124 8127
I 0 N
I N T E N s I T V
I 58 10B 150 200 250 3BB 35B
SCAN NUMBER ~RGc-LlMs AHAL~sis barAiNEb roi tHEMEcoloGv sAMI-LE Ho2A1 ii F
FIGURE1 435
- - - - -
L~ii 1-i-il1U 1~Alui - I1a11i middotIA illpoundRSllY - fl1Fideg(I lJHIO 45435 C~TEt B3B284 TIMEs 1108
KRATOS MS25 0S55 SOFTWARE RUN TORS0062 WSU NAME CHJ-68 SELECTED-lON MASS CHROMATOGRAMS FOR PENTACHLORODlBENZO-P-DIOXINS
100
90
80
70
0s01
0 356
35(
291
1 s03
1BSXbull68382
10SXbull~J((1
1SBXbull256(5
2 dY6
60
58
u
38
28
lB
B
JI 0 ( I 13 5 I 1 7 6120 7s2( 8t27
--1 - - - - - - - - - - - - - - - -
l 0 N
I N T E N s I T y
SB lBB 150 2BSSCAN NUMBER
250 300 35B UB
HRGt-LRMS ANALVSIsect OBTAINED F~ CHE~Ecolo~ SAH~LE H02Al 17 F FIGUREbull 436
middot-
BiSl 1 26
BREHM LABORATORY - RIGHT STATE UNIVER-SmiddotITV--r PAYTON OHIO 45435 DATE 030284 TIHif-i i middotu
KRATOS MS25 0S55 SOFTIARE RUN TOR60063 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLOROOIBENZOFURANS
2 5 ( 4 2i middot 5 l ( 9 7 I 1 6 eu 100
0 376 1BBXbull24486 9B
374 1BBXbull2929bull
as
bull (U 1IBXbull2BU 7B
6B
SB
u
3B
20
lB
B
50
middotmiddot1 I
100 150 200 25B I I I f r-r-
I 0 N
I N T E N s I T V
3IBSCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 437
BREHM LABORATORY - WkIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 030284 TIME1 llslZ
KRATOS MS25 DS55 SOFTWARE RUN TOR6Hg63 WSU NAME1 5 SELECTED-ION MASS
Bs01 1 I 26 254 BB
0 392 1SSXbull74894 9B
391 1BBlbull95154
as
329 1SBXbull3330 7B
6B
SB
u
3B
2B
lB
B
CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXlNS
4 21 549 7 I 16 su I
I 0 N
I N T E N s I T V
50 lBS 158 289 258 3BB SCAN NUMBER
wl~t-L4As ANALVsectfsect UiiUl6 deg cHEUfc6l6Gv sUJle MoEHJ-e FIGURE t 438
if
middotmiddot~ci__f --middot -~ ~ ~
~~) _~ l w a - bull - bullIbull middot-
SREliM L~BORATORV - WK[GHT STATE UNIVERSITY - UAYTON OHIO s35 DATE B3B284 TIME 11118
KRATOS MS25 DS55 SOFTWARE RUN1 TOR7BB64 WSU NAMEbull CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODlBENZOFURANS
BdJl 1 bullBB 2102 3dU 4106 5108 6sll 7113 lB0
90
as
70
6B
5f
u
31
2B
11
B
S 41B 1BBlbull88U
amp 4B8 l0BXbull9116
0 HB U81bull1319
432 l00bull35776
2S 4B 6B BB 198 128
I 0 N
I N T E N s I T y
us SCAN NUMBER
Ui4t-llaquoMs ~~Al~sfsect 61fAfUE6 Fol cHfUfcblbtY sAkPLt Mo2i j7 FUWREs 439
-
t
BREHll LABORATORY - VPIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATEr 038284 TIME 1118
KRATOS MS25 0S55 SOFTWARE RUN TOR70B64 1 WSU NAME CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
Sa01 1 es 2 I 02 3r04 41B6 Sr08 6111 7113 100
90
as
7B
68
SB
U
3B
2B
10
g
S 426 10BXbull11647
amp 424 1BBXbull1195B
0 359 100yenbull8992
02 100Xbull35776
434 1SBXbull11738
U 61 8B 1B0 120 1482B
I 0 N
I N T E N s I T V
SCAN NUMBER HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NO2Al 17 F
F GUR E 1 440
~
BkEHN L~BORATORY - WRIGHT STATE UN ~RSITV - DAYTON OHIO 45435 DATE 830284 TIME1 11133
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8B069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZOFURANS
6111 6142 7113 71U Br15 8146 9 al 7 9148 18bull 19 0B
98
80
7B
60
50
u
30
2B
lB
B
S 4U 18Ubulll 922
amp HZ 1BBXbull3928
0 512 18BXbull2298
47S l00Xbull99315
bull 472 1BBbull1B6B78
128 13B 14B 158 16BSCAN NUMBER
178 18B 2bullbull
I 0 N
I N T E N s I T V
19B
HRGC-LRMS ANALYStS OBTAlNED FOR CHEMECOLOGV SAMPLE N02Al 17 F FIGURE 1 441
11
-middotbull ~ bullmiddot - - bull-t L h Jgt ~ uKA l uK Y - td G H I S 1 A I E U H I V 1 R S ll Y - l) A Ymiddot1 0 1I 0 i l1 u 4 5 4 J 5
DATE 838284 TIME 11133 KRATOS MS2S 0S55 SOFTWARE RUN TOR88069 WSU NAME1 CHJ-68 SELECTED-ION MASS CHROMATOGRAMS FOR
6 s 11 6 l -2 7 I 13 7U 8 I 15 lBB
S -460 lBUbulll0697 9B
amp se unmiddot9371 a
0 395 U0bull5932 7B
1s 1BBXbull99315 6B
12 1BBXbull1B6B78 5S
U
39
2B
B
128 130 140 150 160
OCTACHLORODIBENZO-P-DIOXINS
8146 9 l 7 948 Us 19
190
I 0 N
I N TE N s I T y
170 18B 2BB SCAN NUMBER
HRGC-LRMS ANALYSIS 6~tAIHEO FOR CHE~ECOLOGV sA~PLE No2A1 17 F FIGURE 442
I
I I I
r11111w It 1 11 j
i M bull
I
-~
uRpoundHM LJBORAIORY - fUGtn STAIE Uf tRSll( - liAVlAJ 110 -15435 DATE h3H284 TIME 12ee
KRA10S MS25 OS55 SOFTwARE RUN TOR488i5 WSU NAlbullE CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENLOFURANS
81 i 1 I 4 I2 I 14fB 3122L L- L J__ I 429 5 I Ji 6rU _ -bull-A J --L-4____J__ 1-~-J_ ___ J _ L__ __ i____~-1-____L-J__j ----L- J ___L L-L-_J__JLri L _ L_bull__ _L -l I __ 1 _l_ J ~ _J_ L_L___ _ __ J1 _J____
$ 3S6 ISMXbulltlbullS69 ii -237890
---- -middot-middot --- -~ 344 lSDXn89798
80
0 374 l0HXbull878 78
J~middot- 328 l~HXbulll~7132 -middot-Ar ----64 lmiddotbull- 332 IIJIJXbull lmiddot middot-middot -- middot-middot middot- II 11 -middotmiddot _ -middotmiddot - _05817 1 middot -J
58 ~ I (
I It
-0
38
1jmiddot ~j Iv fv i
f1II Ii I I I I
J(
28
If ) I 11 I I Ir I ~
8 __ vl rltiJA-fUI j llJ I I I J middotJ
- - I111 J-J1 _-__ j ~j ~ ~rJt ~-~ J ~1 ----------- J
_ -_) 11 ----middot I
r~ _____ -------------~-- ------bullbull A f
_____ --- bull middot- ______ ___________ ~~--- ~
-f
l 1 r- -middotmiddot---middot- r-middotmiddot r- --middotr---middotmiddotmiddotmiddot ~~~-==i--=-==r===r==----~~Fmiddot-r------bullbullf-~-Jrmiddotr-r--I~------TJ-
53 100 l 50 243 2 58 JBSSCAN NUMBER
HGC-LR~S A~AL~i1s OBTAINE~ FOR CHE~tcoloampv SAMPLE N02A2 17 F FIGUREs 443
~L_
I 0 N
I N T E N s l T y
j I i
68
81UHI ABORA)ORY - fdGHT STATE UNIVERSITY - DAYmiddotroN OHl0 45435 DATE 03028A TIME 12108
KRATOS MS25 DSS5 SOFTWARE RUN1 TORAa075 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR TETRACHLORODIBENZO-P-DIOXINS
Bs01 1 I 07 l0B
S 322 l0BXbull22837 9S
amp 320 1BSbull17892 as
0 257 UBXbull UBS4
7B
32e nssx-11132
bull 332 IUBSXbull 1B5B1 7 SB
U
30
2B
1B
B
2 1 4 3122 4129 5137 61U
-2378
I 0 H
I N T E N s I T V
58 10B 150 2gg 250 3BSSCAN NUMBER
H~c-L~Ms AHaLvsis osrAt~E6 foi cHEMEcoLoov sAl-ihi No~A2 11 i FIGURE 444
0Bl 1 a13 us
0 3U 1BUbull91856 90
338 tbullBXbull59526
80
bull ue lBllbullbullU 2 70
ampbull
u
As
3B
2B
UJ
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50 358 U8
I-
BREHM L~BORATORV - WRIGHT STATE UhiVERSlTV - DAYTON OHIO 45435 DATE B3B284 TIME 12s17
KRATOS MS25 DS55 SOFTWARE RUN1 TOR5SB63 WSU NAMEbull CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLOROOIBENZOFURANS
2106 3 1 lB 413 Sal 7 6s2S 7 I 2- 8127
I 0 H
I N T
~ s t T y
111 158 208 Z5S 30BSCAN NUMBER
ttic-liUi AH1l~sii biiAlMO o~ CHiUicolocv SAMPLE NOZAZ 17 FIGUREbull 445
BREHM LABORATORY - ~RIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 03i0284 TIME 12117
KRATOS MS259 0S55 SOFTWARE RUN TOR50063 WSU NAMEt CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR PENTACHLORODIBENZO-P-DIOXIHS
100 ss1 l c03 2 06 3 l 0 4 13 5 l 1 7 6120 7amp24 8127
98 0 356 100Xbull22351
80
7B
bull
354
291
U8Xbull1bull27B
1BUbull97B3
6B
5
u
38
28
1B
0
SB 108 150 280
HRGt-lR~s AHAlvsis 6efAiNE6 FbR C~E~Ecoloov sAMPLe No2A2 i1 F FIGURE 1 446
SCAN NUMBER 350 UB250 3016
I 0 H
I N T E H s I T y
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45436 DATE1 B3B284 TIMEs 12127
KRATOS MS25 0S55 SOFTWARE RUN1 TOR6BB64 WSU NAHE1 CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZOFURANS
81 1126 2154 4121 5149 7 I 16 8 bull4 BB
0 376 1SSlbull23517 9S
374 1861bull28844
88
4U lSS1bull2386 78
u
s
38
2B
18
bull
58
188 158 Z6SSCAN NUMBER
25B
I 0 N
I N T E N s I T V
3SB
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGY SAMPLE NOZA2 17 F FIGUREbull 447
11
B01 1 26 lBB
BREHM LABORATORY - WRIGHT STATE UNIVERSITY - DAYTON OHIO 45435 DATE 838284 TIME 12127
KRATOS MS2S 0S55 SOFTWARE RUN TOR6B864 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEXACHLORODIBENZO-P-DIOXINS
254 4 21 549 7 I 16 81H
98
88
7B
68
58
48
38
2B
0
392 UBXbull2332B ----------
398 1BSXbull3874
329 1Bflbull128B7
I 0 N
I N T E N s I T V
SB lBB 158 2BB 25S 3BBSCAN NUMBER
wl~l-Ll~sect ANALvsfs 61t11Ul6 51 CHEUlE6l5v lAULe U02A2 11 J FIGURE 448
-- - - -
- - - -
- - -
- - - -
Bk~liN LABORATORY - WRIGHT STATE UNiERSJTY - DAYTON OHIO 5435 OATE1 03S28 TJHE1 12136
KRATOS MS25 OS55 SOFTWARE RUNi TOR7S8E6 WSU NAMEs CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR HEPTACHLORODIBENZOFURANS
r
BBl 11BB 2d2 3s04 4 r86 5dJ8 6 I 11 7 al 3 BB
S us 1881bull18723
98 --amp US lBBlbulll U35
88
0 HS 18Ubull 12B7 78 -
432 UJB1bull37758 6f
bull n 1ss1 121ss 58
u
38
28
18
B
I 0 N
I N T E N s I T y
28 Cf middot 68 8B IBB 1 2B us SCAN NUMBER
tfflcc-LA~s AHALYSis oliAIUi6 FM cHiUEcotos~ iA~~LE ~-AZ i1 ~ FIGURE r 449
L 1 1)gtLlJl(AIURr
KRATOS MS25 bull 0S55 SELECTED-ION MASS
2102
- lt1i11 11--1C UIUVtKSI1r - UJl10li vdlU 4G1Jo
DATE1 030284 TIME1 12135 SOFTWARE RUN1 TOR 70065 JSU NAHE I CHJ-69 CHROMATOGRAMS FOR HEPTACHLORODIBENZO-P-DIOXINS
3 104 4 I 06 5 08 6 rl 1 180
9g
80
70
68
SB
u
30
2B
lB
0d31 1 dHJ
S _26 100Xbull8101
amp _2 100Xbull7791
- - - -0 359 l0BXbull8848
_32 l00Xbull377S8
bull _3_ l881bull12155
20 40 60 80 lB0 120 SCAN NUMBER
HRGC-L~Msect A~AL~Sis 6ArAtH~b FO~ C~EMECOLOG~ sAMPLE N02A2 17 F FIGURE1 450
UB
713
I 0 H
I N T E N s I T y
BREHM L~BORATORV - WRIGHT STATE UNIVERSITY - DAYTON OlfIO 45435 DATE S3B28~ TIHEa 121~7
KRATOS MS25 0S55 SOFTWARE RUN1 TOR8BB71 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLOROOIBENZOFURANS
611 6142 7 I 13 71U 8 I 15 846 917 9amp~8 l8119 UB
99
BB
7B
S 4 U 18Hbull 195B
amp U2 1l81bull3928
0 S 12 lB11bull336
H8 U11bull9615
472 lSBlbulll16985
14B 151 166 17B 181SCAN NUMBER
HRGC-LRMS ANALYSIS OBTAINED FOR CHEMECOLOGV SAMPLE NOZA2 17 F FIGUREt 451
I6B 0 N
SB I N T
u E N s I
3B T y
21
lB
B
129 131 191 2bullbull
BREHM LABORAfORY - 1JRIGHT STATE LllllVERSllY - DAYTON 0Hl0 45435 DATE 230284 TIME 1247
KRATOS MS25 0S55 SOFTWARE RUN TORB2271 WSU NAME CHJ-69 SELECTED-ION MASS CHROMATOGRAMS FOR OCTACHLORODIBENZO-P-DIOXINS
6 11 6c42 7 I 13 744 8 15 846 9 17 9148 Uh 19 lSS
S 46B 1BBXbull8793
9B
amp 458 UBlbull7622 80
0 395 UUbull48 l 7
70
HS UBXbull96145 60 I
0 N
472 lBBXbulll06985 59
I N T
U E N s I
30 T y
2B
10
B
12B 13B 14B 15B 16B 178 18B 19B 211 SCAN NUMBER
H~Gt-LRMs A~ALvsts oerAfktb ~o~ cHE~EcoLoG~ sAMPLE HOlA2 11 ~ FIGURE 452
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
CONCENTRATION 127 CO2 44410 M9NM3 18087 srDScf ACT CO2 33308 MsNM3 13565 srDScf
9651 M9AM3 04218 srAcf
EMISSION RATE 19021 95 15096 lbhr
SAMPLING VOLUME 07952 NM3 30132 DScf
AVERAGE ISOKINETICITY 1220 7
FLUE GAS CHARACTERISTICS
MOISTURE 3468 i
TEMPERATURE 3419 des C 6475 des F
FLOW 20558 Nt113hr 70940 1113hr
12983 DScft11 41754 Acft11
VELOCITY 1308 MIS 25756 fPM
GAS ANALYSIS 02 11 00 i CO2 900 7 co 000 7 MOL WT 299 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA CONCORD SCIENTIFIC CORPORATION REF No 110J811
DATE 10-14-83 RUN 2Al LOCATION CoMbustor Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
100
1506
1018
-6226
800
0800
0987
M
M2
kPa
Pa
MM
395 in
162 sqft
3006 inHs
-250 inH20
032 in
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
CONDENSATION IN IMPINGER
TOTAL CONDENSATION
1
2
3
4
5
6
3390 1111
00 1111
00 Ml
00 ml
0 0 Ml
00 Ml
3390 ml
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
24100 s
00000 s
02390 s
26490 s
SAMPLING TI ME 570 Min
STACK HEIGHT 000 M oo ft
------------------------------------------------------------------------------
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A1 REF No 110J811 LOCATION CoMbustor Outlet
PT NO
TIME
Min
STACK VEL TEMP PRESS deg F inH20
------
ORIF PRESS inH20 ------
METER VOL
curt ------
METER HTBOX IMP XAD2 VAC TEMP TEMP TEMP TEMP deg F deg F des F deg F inHs ----- ----- ----- ----- -----
WALL DIST
in -----
7 ISO
TRAVERSE NO 1
4 3 2 1
00 so
100 150 200
643 633 654 648
026 030 032 036
178 205 2 14 240
83645 83645 83645 83645 84748
63 68 71 78
643 633 654 648
60 60 60 60
60 60 60 60
30 30 30 30
34S 246 148 49
00 00 00
4355
TRAVERSE NO 2
4 oo 20
620 032 222 84748 84810
78 620 60 60 30 345 641
TRAVERSE NO 3
3 2 1
oo 50
100 150
638 650 872
026 022 020
180 155 141
76790 76790 76790 77670
68 73 74
638 650 672
60 60 80
60 60 60
30 30 30
246 14B 49
oo 00
4736
TRAVERSE NO 4
4 3 2 1
oo 50
100 150 200
630 648 652 665
030 030 030 021
206 205 205 148
77670 77670 77670 77670 78675
70 77 78 75
630 648 652 665
60 60 60 60
60 60 60 60
30 30 30 30
345 246 148 49
oo oo oo
5253
AVERAGE 647 027 189 1220
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-Combustor Outlet
CONCENTRATION 12i CO2 63038 MsNm3 25673 srDScf ACT CO2 44126 msNm3 17971 srDScf
14307 msAm3 06253 srAcf
EMISSION RATE 24575 95 19504 lbhr
SAMPLING VOLUME 06720 Nm3 25466 DScf
AVERAGE ISOKINETICITY 1004 i
FLUE GAS CHARACTERISTICS
MOISTURE 2791 l
TEMPERATURE 3335 des C 6323 des F
FLOW 20049 61827
NM3hr 11t3hr
12662 36390
DScfM AcfM
VELOCITY 1140 M5 22447 tPM
GAS ANALYSIS 02 1220 CO2 840 co 000 MOL WT 298 ss MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C1 101325 kPa IMPERIAL 68 des F1 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110J811 LOCATION A-CoMbustor Outlet
STACK DIAMETER 100 M 395 in
STACK AREA 1506 1112 162 sewFt
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -6226 Pa -250 inH20
NOZZLE DIAMETER 800 MM 032 in
PITOT COEFFICIENT 0800
METER CORRECTION FACTOR 0987
CONDENSATION IN IMPINGER 1 1900 Ml
CONDENSATION IN IMPINGER 2 66 Ml
CONDENSATION IN IMPINGER 3 00 Ml
CO~DENSATION IN IMPINGER 4 oo Ml( CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 123 Ml
TOTAL CONDENSATION 2089 Ml
FILTER PARTICULATE 25400 s
WASHINGS PARTICULATE 00000 s
IMPINGER PARTICULATE 04260 s
TOTAL PARTICULATE 29660 s
SAMPLING TIME 600 Min
STACK HEIGHT ooo M oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2A2 REF No 110JBll LOCATION A-CoMbustor Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in ------ ------ ------ ----- -----
TRAVERSE NO 1
4 00 557 0 16 110 78700 61 600 60 60 30 34 5 oo 3 50 593 024 154 78700 68 600 60 60 30 246 00 2 100 638 022 139 78700 73 600 60 60 30 148 00 1 150 666 022 136 78700 72 600 60 60 30 49 4085
200 79565
TRAVERSE NO 2
4 00 636 030 181 79565 68 620 60 60 30 345 00 3 so 593 024 154 79565 68 620 60 60 30 246 00 2 100 660 016 103 79565- 74 - 620 60 60 30 148 00 1 150 670 018 1 14 79565 76 620 60 60 30 49 4395
200 804 12
TRAVERSE NO 3
4 00 612 028 1 75 804 12 73 630 60 60 30 345 00 3 50 640 024 150 804 12 73 630 60 60 30 246 oo 2 100 645 020 128 80412 76 630 60 60 30 14 8 00 1 150 678 020 125 80412 78 630 60 60 30 49 4258
200 81277
AVERAGE 632 022 138 1004
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 44969 tr1sNtr13 ACT CO2 31853 tr1sNtr13
10399 tr1sAtr13
EMISSION RATE 18381 sis
SAMPLING VOLUME 07631 NM3
AVERAGE ISOKINETICITY 1132 7
FLUE GAS CHARACTERISTICS
MOISTURE
TEMPERATURE
FLOW
VELOCITY
GAS ANALYSIS 02 CO2 co MOL WT
STANDARD CONDITIONS
3701
2500 des C
20773 Nt113hr 83819 1113hr
1242 MS
11 70 850 7 ooo 7
RUN 2B1 LOCATION Venturi Inlet
18314 srDScf 12873 srDScf 04545 srAcf
14588 lbhr
28915 DScf
4821 des F
13119 DScF111 37445 Acf1r1
24441 fpfll
298 ss MOLE ltDRYgt
METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 281 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 t11 530 in
STACK AREA 1423 M2 153 setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3242 t111
CONDENSATION IN IMPINGER 2 224 Ml
CONDENSATION IN IMP INGER 3 00 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 133 Ml
TOTAL CONDENSATION 3599 Ml
FILTER PARTICULATE 08110 s
WASHINGS PARTICULATE 16090 s
IMPINGER PARTICULATE 00110 s
TOTAL PARTICULATE 24310 s
SAMPLING TIME 720 Min
STACK HEIGHT o oo 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B1 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER NO TEMP PRESS PRESS VOL
Min deg F inHZ inH20 cuft ------ ------ ------
TRAVERSE NO 1
24 oo 475 040 196 35470 23 30 485 042 199 35470 22 60 485 046 2 16 35470 21 90 485 046 2 16 35470 20 120 485 049 228 35470 19 150 485 046 2 16 35470 18 180 485 048 224 35470 17 210 485 042 199 35470 16 240 485 038 185 35470 15 270 485 028 142 35470 14 300 485 027 137 35470-middot 13 330 485 019 101 35470 12 360 485 0 16 086 35470
( 11 10
390 420
485 475
0 16 016
086 087
35470 35470
9 450 485 0 16 086 35470 8 480 475 0 14 077 35470 7 510 485 014 076 35470 6 540 485 017 091 35470 5 570 470 017 092 35470 4 600 475 020 106 35470 3 630 480 023 1 20 35470 2 680 480 023 120 35470 1 690 480 023 120 35470
720 38312
AVERAGE 482 027 137
METER HTBOX IMP XAD2 VAC WALL X TEMP TEMP TEMP TEMP DIST ISO des F deg F deg F des F inHs in
65 475 60 60 30 524 00 55 485 60 60 30 513 oo 55 485 60 60 30 501 00 55 485 60 so 30 488 00 55 485 60 60 30 475 00 55 485 60 60 30 460 00 ss 485 60 60 30 444 00 55 485 60 60 30 427 oo 65 485 60 60 30 408 oo 65 485 60 60 30 386 00 65 485 60 60 30 359 00 65 485 60 60 3o- 319 oo 65 485 60 60 30 211 00 65 485 60 60 30 171 00 65 475 60 60 30 144 oo 65 485 60 60 30 122 00 65 475 60 60 30 103 00 65 485 60 60 30 86 00 65 485 60 60 30 70 oo 65 470 60 60 30 55 00 65 475 60 60 30 42 oo 65 480 60 60 30 29 oo 65 480 60 60 30 17 oo 65 480 60 60 30 06 29336
1132
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
CONCENTRATION 127 CO2 80195 MsNM3 24515 srDScf ACT CO2 40130 M9NM3 16344 9rDScf
14463 t11sAt113 06321 srAcf
EMISSION RATE 22545 95 17893 lbhr
SAMPLING VOLUME 07489 Nt113 28380 DScf
AVERAGE ISOKINETICITY 1141 i
FLUE GAS CHARACTERISTICS
MOISTURE 3077 7
TEMPERATURE 2477 des C 4779 des F
FLOW 20225 56107
Nm3hr M3hr
12773 DScfM 33023 AcfM
VELOCITY 1095 M5 215S5 fPtrt
GAS ANALYSIS 02 1240 i CO2 800 7 co 000 l MOL WT 298 ss MOLE DRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING_ DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 282 REF No 110J811 LOCATION Venturi Inlet
STACK DIAMETER 135 Ill 530 in
STACK AREA 1423 1112 153 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -12452 Pa -500 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0998
CONDENSATION IN IMPINGER 1 3175 Ml
CONDENSATION IN IMPINGER 2 -655 1111
CONDENSATION IN IMPINGER 3 oo Ml
CONDENSATION IN IMPINGER 4 oo 1111
CONDENSATION IN IMPINGER 5 oo 1111
CONDENSATION IN IMPINGER 6 152 Ml
TOTAL CONDENSATION 2672 Ml
FILTER PARTICULATE 06600 9
WASHINGS PARTICULATE 23110 s
IMPINGER PARTICULATE 00350 s
TOTAL PARTICULATE 30060 9
SAMPLING TIME 720 Min
ST ACK HEIGHT 000 Ill oo ft
r1
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2B2 REF No 110J811 LOCATION Venturi Inlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F deg F des F des F inHg in ----- ------ ------ ------ ----- -----
TRAVERSE NO 1
24 00 495 038 161 38387 55 360 60 60 30 524 00 23 30 490 032 141 38387 65 360 60 60 30 513 00 22 60 490 032 140 38387 60 360 60 60 30 so 1 oo 21 90 490 038 160 38387 50 360 60 60 30 48B oo 20 120 490 042 177 38387 60 360 60 60 30 475 00 19 150 490 050 206 38387 60 360 60 60 30 460 00 18 180 490 042 177 38387 60 360 60 60 30 444 oo 17 ZLO 490 030 133 38387 65 360 60 60 30 427 00 16 240 490 024 108 383a87 60 360 60 60 30 408 00 15 270 440 0 19 093 38387 65 360 60 60 30 386 oo 14 300 480 0 14 068 38387_ 65 360 60 60 30 359 00 13 330 480 020 092 38387 55 360 60 60 3 0- 319 00 12 360 480 0 18 084 38387 60 360 60 60 30 211 00 11 390 470 0 15 o 72 38387 60 360 60 60 30 171 00 10 420 480 0 14 067 38387 60 360 60 60 30 144 oo
9 450 480 0 10 049 38387 60 360 60 60 30 122 00 8 480 475 0 10 049 38387 60 360 60 60 30 103 00 7 510 470 0 12 059 38387 60 360 60 60 30 86 00 6 540 440 0 10 052 38387 70 360 60 60 30 70 00 5 570 480 0 14 067 38387 60 360 60 60 30 55 00 4 600 470 018 085 38387 60 360 80 60 30 42 00 3 630 470 0 18 085 38387 60 360 60 60 30 29 00 2 660 470 0 18 085 38387 60 360 60 60 30 17 00 1 690 470 0 18 085 38387 60 360 60 60 30 06 30052
720 411 70
AVERAGE 478 022 099 1141
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110JBll LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 30998 M9NM3 12624 srDScf ACT CO2 16532 MSINM3 06733 srDScf
6633 M9IAM3 02899 srAcf
EMISSION RATE 13735 95 10901 lbhr
SAMPLING VOLUME 09518 Nt113 36058 DScf
AVERAGE ISOKINETICITY 985 7
FLUE GAS CHARACTERISTICS
MOISTURE 2586 7
TEMPERATURE 2283 des C 4393 des F
FLOW 29909 74537
NM3hr M3hr
18889 DScfM 43871 AcfM
VELOCITY 1511 MIS 29747 fPtt
GAS ANALYSIS 02 1400 i CO2 840 7 co 000 i MOL WT 296 sis MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Bashouse Inlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -15690 Pa -630 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
METER CORRECTION FACTOR 0995
CONDENSATION IN IMPINGER 1 1416 Ml
CONDENSATION IN IMPINGER 2 1096 Ml
CONDENSATION IN IMPINGER 3 38 Ml
CONDENSATION IN IMPINGER 4 00 Ml
CONDENSATION IN IMPINGER 5 00 Ml
CONDENSATION IN IMPINGER 6 115 1111
TOTAL CONDENSATION 2665 Ml
FILTER PARTICULATE 04670 9
WASHINGS PARTICULATE 10790 9
IMPINGER PARTICULATE 00274 9
TOTAL PARTICULATE 15734 s
SAMPLING TIME 690 Min
STACK HEIGHT 000 M 00 ft
------------------------------------------------------------------------------
--- ---- ------ ------ ------ ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C1 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL ORIF METER METER HTBOgt IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inH20 inH20 cuft deg F deg F deg F deg F inHg in
TRAVERSE NO 1
12 oo 440 068 319 39006 65 400 60 60 30 509 00 11 30 440 064 302 39006 65 400 60 60 30 485 00 10 60 440 060 286 39006 65 400 60 60 30 459 oo 9 90 440 052 252 39006 65 400 60 60 30 428 oo 8 120 440 058 2 77 39006 65 400 60 60 30 390 00 7 150 440 040 202 39006 70 400 60 60 30 33S oo 6 180 435 024 129 39006 65 400 60 60 30 185 oo 5 210 440 024 128 39006 65 400 60 60 30 130 00 4 240 440 024 128 39006 65 400 60 60 30 92 oo 3 270 440 030 156 39006 65 400 60 60 30 6 1 00 2 300 440 026 137 39006 60 400 60 60 30 35 oo 1 330 440 026 138 39006 65 400 60 60 30 11 13182
360 40605
TRAVERSE NO 2
12 oo 440 078 357 40801 60 400 60 60 30 509 oo 11 30 440 080 366 40801 60 400 60 60 30 485 00 10 60 440 076 352 40801 65 400 60 60 30 459 oo
9 90 440 065 306 40801 65 400 60 60 30 428 00 8 120 440 060 286 40801 65 400 60 60 30 390 00 7 150 440 056 267 40801 60 400 60 60 30 335 00 6 180 445 028 145 40801 60 400 60 60 30 185 00 5 210 440 026 138 40801 65 400 60 60 30 130 oo 4 240 435 030 157 40801 65 400 60 60 30 92 00 3 270 435 030 157 40801 65 400 60 60 30 6 I 1 oo 2 300 435 034 175 40801 65 400 60 60 30 35 14118
330 42763
AVERAGE 439 044 2 16 985
PARTICULATE EMISSION REPORT DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN ZCZ REF No 110J811 LOCATION Bashouse Inlet
CONCENTRATION 127 CO2 98995 msNM3 40317 srDScf ACT CO2 51972 M9NM3 2 1167 sr DScf
20116 fll9AM3 08792 srAcf
EMISSION RATE 39023 95 30971 lbhr
SAMPLING VOLUME 08982 Ntit3 34036 DScf
AVERAGE ISOKINETICITY 986 i
FLUE GAS CHARACTERISTICS
MOISTURE 2867 7
TEMPERATURE 2260 des C 4388 des F
FLOW 27030 Ntit3hr 69826 m3hr
17071 41098
DScfm Acftn
VELOCITY 1416 M5 27867 tPM
GAS ANALYSIS 02 1410 7 CO2 630 7 co ooo 7 MOL WT 296 ss MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in Hs
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110JBll LOCATION Bashouse Inlet
STACK DIAMETER 132 111 520 in
STACK AREA 1370 1112 147 sqft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -13697 Pa -550 inH20
NOZZLE DIAMETER 700 MM 028 in
PITOT COEFFICIENT 0820
MEHH CORf~ECT ION FACTOR 0995
CONDENSATION IN IMPINGER 1 2649 Ml
CONDENSATION IN IMPINGER 2 02 Ml
CONDENSATION IN IMPINGER 3 79 1111
CONDENSATION IN IMPINGER 4 oo Ml
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 168 Ml
TOTAL CONDENSA1ION 2898 Ml
FILTER PARTICULATE 15340 s
WASHINGS PARTICULATE 30000 s
IMPINGER PARTICULATE 01350 s
TOTAL PARTICULATE 46690 s
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 oo ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2C2 REF No 110J811 LOCATION Baghouse Inlet
PT TIME STACK VEL DRIF METER METER HTBOX IMP XAD2 VAC WALL NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min deg F inHZ inH20 cuft deg F deg F des F deg F inHs in ------ ------ ------ ----- ----- ----- ----- ----- -----
TRAVERSE NO 1
12 00 435 042 189 42830 55 330 60 60 30 509 00 11 30 460 054 232 42830 60 330 60 60 30 485 00 10 60 430 049 219 42830 60 330 60 60 30 459 00
9 90 435 062 270 42830 65 330 60 60 30 42B 00 8 120 435 062 270 42830 65 330 60 60 30 390 00 7 150 435 036 168 42830 65 330 60 60 30 335 00 6 180 435 021 104 42830 65 330 60 60 30 18 5 00 5 210 435 021 104 42830 65 330 60 60 30 130 00 4 240 435 021 104 42830 65 330 60 60 3 0 92 00 3 270 435 020 100 42830 65 330 60 60 30 6 1 00 2 300 435 026 126 42830 65 330 60 60 30 35 254 1 330 435 026 126 42860 55middot 330 60 60 30 11 13254
360 44423
TRAVERSE NO 2
12 oo 435 058 253 44423 60 350 60 60 30 509 oo 11 30 435 069 298 44423 70 350 60 60 30 485 00 10 60 435 069 298 44423 70 350 60 60 30 459 00
9 90 445 062 268 44423 70 350 60 60 30 428 00 8 120 470 0 18 087 44423 60 350 60 60 30 390 00 7 150 440 058 255 44423 70 350 60 60 30 335 00 6 180 440 040 183 44423 65 350 60 60 30 185 00 5 210 440 023 113 44423 70 350 60 60 3middot0 130 oo 4 240 440 025 121 44423 65 350 60 60 30 92 00 3 270 440 031 148 44423 70 350 60 60 3m0 61 oo 2 300 435 034 161 44423 70 350 so 60 30 35 00 1 330 435 034 161 44423 70 350 60 60 30 1 1 13086
360 48203
AVERAGE 439 038 1 75 986
l
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 127 CO2 610 MsN1113 ACT CO2 325 1119Nm3
123 M9AM3
EMiSSION RATE 0251 ss
SAMPLING VOLUME 096S0 N1113
AVERAGE ISOKINETICITY 1030 7
FLUE GAS CHARACTERISTICS
MOISTURE 3179 X
TEMPERATURE 2098 des C
FLOW 27788 N1113hr 73634 1113hr
VELOCITY 1493 111s
GAS ANALYSIS 02 1400 X CO2 640 X co ooo
DATE 10-14-83 RUN 2D1 LOCATION D-Ba9house Outlet
00248 9rDScf 00132 srDScf 00054 srAcf
198 lbhr
38566 DScf
4096 des F
17549 DScft1 43340 Acf111
29387 fpfll
MOL WT 296 99 MOLE ltDRYgt
STANDARD CONDITIONS METRIC 20 des C 101325 kPa IMPERIAL 68 des F 2992 in H9
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER 132 M 520 in
STACK AREA 1370 M2 147 Setft
BAROMETRIC PRESSURE 1018 kPa 3006 inHs
STATIC PRESSURE -27395 Pa -11 00 in H20
NOZZLE DIAMETER 700 fllfrl 028 in
PITOT COEFFICIENT 0810
METER CORRECTION FACTOR 0988
CONDENSATION IN IMPINGER 1 3085 Ml
CONDENSATION IN IMPINGER 2 349 Ml
CONDENSATION IN IMPINGER 3 20 Ml
CONDENSATION IN IMPINGER 4 00 t1t 1
CONDENSATION IN IMPINGER 5 oo Ml
CONDENSATION IN IMPINGER 6 156 Ml
TOTAL CONDENSATION 3610 Ml
FILTER PARTICULATE 00050 s
WASHINGS PARTICULATE 00090 s
IMPINGER PARTICULATE 0017 4 9
TOTAL PARTICULATE 00314 9
SAMPLING TIME 720 Min
STACK HEIGHT 000 111 00 ft
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D1 REF No 110J811 LOCATiON D-Baghouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL i NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 in H20 cu f t des F deg F deg F deg F inHg in ------ ------ ------ ----- ----- ----- -----
TRAVERSE NO 1
12 00 405 046 357 73490 65 345 60 60 30 509 00 11 30 405 044 344 73490 65 345 60 60 30 48S 00 10 60 405 048 373 73490 70 345 60 60 30 459 00 9 90 410 050 387 73490 75 345 60 60 30 428 oo 8 120 410 050 387 73490 75 345 so 60 30 390 oo 7 150 410 050 387 73490 75 345 60 60 30 335 oo 6 180 410 046 365 73490 85 345 60 60 30 185 oo s 210 410 046 365 73490 85 345 60 60 30 130 oo 4 240 410 042 337 73490 85 345 60 60 30 92 oo 3 270 410 042 337 73490 85 345 60 60 30 6 1 00 2 300 410 042 337 73490 85 - 345 60 60 30 35 oo 1 330 410 042 337 73490 85 345 60 60 36 11 12725
360 75390
TRA~bullERSE NO 2
12 oo 410 046 355 754 10 65 345 60 60 30 509 oo 11 30 410 046 355 754 10 65 345 60 60 30 485 oo 10 60 410 044 349 754 10 80 345 60 60 30 459 oo
9 90 410 044 349 75410 80 345 60 60 30 428 oo 8 120 410 042 337 754 10 85 345 60 60 30 390 oo 7 150 410 042 337 75410 85 345 60 60 30 335 00 6 180 410 042 337 75410 85 345 60 60 30 185 oo 5 21 0 415 038 308 75410 85 345 60 80 30 130 oo 4 240 410 040 323 754 10 85 345 60 60 30 92 oo 3 270 410 040 323 75410 85 345 60 60 30 6 1 oo 2 300 410 040 323 75410 85 345 60 60 30 35 oo 1 330 410 040 323 754 10 85 345 60 60 30 1 bull 1 12554
360 77240
AVERAGE 410 044 347 1030
PARTICULATE EMISSION REPORT CONCORD SCIENTIFIC CORPORATION REF No 110J811
CONCENTRATION 12l CO2 5591 MsNm3 ~ ACT CO2 2795 ~sNm3
114 7 M9Am3
EMISSION RATE 2010 ss
SAMPLING VOLUME 08012 Ntr13
AVERAGE ISOKINETICITY 91 8 i
FLUE GAS CHARACTERISTICS
MOISTURE 2745 i
TEMPERATURE 1992 des C
FLOW 25879 NM3hr 63074 1113hr
VELOCITY 1279 ms
GAS ANALYSIS 02 1460 7 CO2 600 7 co 000 i
DATE 10-14-83 RUN 2D2 LOCATION D-Ba9house Outlet
02277 srDScf 01138 9rDScf 00501 grAcf
1595 lbhr
30360 DScf
3906 deg F
16344 DScfM 37124 Acfm
25172 fPM
MOL WT 296 99 MOLE ltDRY)
STANDARD CONDITIONS METRIC 20 des C 101325 ~Pa IMPERIAL 68 des F 2992 in Hs
-------------------------------------------------------------------------
SAMPLING DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110J811 LOCATION D-Bashouse Outlet
STACK DIAMETER
STACK AREA
BAROMETRIC PRESSURE
STATIC PRESSURE
NOZZLE DIAMETER
PITOT COEFFICIENT
METER CORRECTION FACTOR
CONDENSATION IN IMPINGER 1
CONDENSATION IN IMPINGER 2
CONDENSATION IN IMPINGER 3
CONDENSATION IN IMPINGER 4
CONDENSATION IN IMPINGER 5
CONDENSATION IN IMPINGER 6
TOTAL CONDENSATION
FILTER PARTICULATE
WASHINGS PARTICULATE
IMPINGER PARTICULATE
TOTAL PARTICULATE
SAMPLING TIME
STACK HEIGHT
132
1370 1112
1018 kPa
27395 Pa
700
0810
0988
2219 t11l
70 ml
10 Ml
oo Ml
oo Ml
135 Ml
2434 Ml
00080 s
00110 s
02050 s
02240 s
720 Min
000 111
520 in
147 sqft
3006 inHs
-1 1 00 in bull H20
028 in
oo ft
--- ---- ----- ------ ------ ------ ----- ----- ----- ----- ----- ----- -----
FIELD DATA DATE 10-14-83 CONCORD SCIENTIFIC CORPORATION RUN 2D2 REF No 110JBll LOCATION D-Bashouse Outlet
PT TIME STACK VEL ORIF METER METER HTBOX IMP XAD2 VAC WALL 7 NO TEMP PRESS PRESS VOL TEMP TEMP TEMP TEMP DIST ISO
Min des F inH20 inH20 cuft des F des F des F des F inHs in
TRAVERSE NO 1
12 oo 395 038 259 77260 60 380 60 60 30 509 00 11 30 390 034 218 77260 70 380 60 60 30 485 oo 10 60 385 032 229 77260 70 380 60 60 30 459 oo 9 90 385 032 229 77260 70 380 60 60 30 428 oo 8 120 385 032 229 77260 70 380 60 60 30 390 00 7 150 385 032 2a29 77260 70 380 60 60 30 335 00 6 180 385 Oe40 278 77260 70 380 60 60 30 185 oo 5 210 385 044 302 77260 70 380 60 60 30 130 00 4 240 390 040 279 77260 75 380 60 60 30 92 00 3 270 390 024 1 78 77260 75 380 60 60 30 61 00 2 300 390 024 178 77260 75 380 60 60 30 35 00 1 330 390 024 178 77260 75 380 60 60 30 11 12184
360 78705
TRAt1ERSE NO 2
12 00 390 040 277 78730 70 380 60 60 30 509 00 11 30 390 040 277 78730 70 380 60 60 30 485 00 10 60 390 036 256 78730 80 380 60 60 30 459 00 9 90 390 036 256 78730 80 380 60 60 30 428 00 8 120 395 034 242 78730 80 380 60 60 30 390 00 7 150 395 034 242 78730 80 380 60 60 30 335 oo 6 180 395 032 230 78730 80 380 60 60 30 185 oo 5 210 395 036 2c55 78730 BO 380 60 60 30 130 oo 4 240 385 036 255 78730 80 380 60 60 30 9 00 3 270 395 036 255 78730 80 380 60 60 30 6 1 00 2 300 385 026 183 78730 85 380 60 60 30 35 00 1 330 395 026 193 78730 85 380 60 60 30 11 13045
360 80365
AVERAGE 391 033 237 918
---------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION 8-Venturi Inlet RUN 381N START TIME 0036
STACK GAS TEPERATURE(TS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITY(U) 502 FPS 153 NSEC ESTINATE STACK GAS NOISTURE 3230
CLASSIFICATION RANGE 000 UN TD 000 UN DESIRED SANPLE FLOW RATE 0000 ACFH
GAS NETER FLOW RATE 9=UtNOZZLE DIAHETER)t528(TS+460t(l-HC100)t2992PB 0000 DSCFN
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAHETER 0138 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROHETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE STACK VELOCITY ORIFICE HETER NETER TEMPERATURE DISTANCE SANPLE TINE TEMP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL I POINT (NIN) ltDEGFl ltINNG) UNMG) ltCUFT) ltDEGF) ltDEGF) UNHGJ ltINCHESgt
12 oo 4850 042 068 41260 650 650 20 00 14182 300 41750
AVERAGES 4850 042 068 sso 6SO
------------------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION 8-Venturi Inlet RUN 381N START TINE 0036
TOTAL SANPLE VOLUNE 495 DSCF 0131 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONSgt 0442 ACFN 0013 AN3NIN
TOTAL IMPINGER CATCH 506 NL
AVERAGE STACK TENPERATURE 4850 DEGF 2517 DEGC
AVERAGE ISOKINETIC 1418 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2(BY DIFFERENCE) H20
600 749 001
5395 3255
890 1110 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242726 NICROPOISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUMBER (GRANS) WEIGHT PERCENTAGE
------------------------------1 00770 9167 10000 2 00000 000 833 3 00000 000 833 4 00070 833 833 5 00000 000 -000 FILTER 00000 000 -000
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER CUNgt
---------------------833 1224 833 693 833 526
-000 260 -000 146
------------------------TOTAL PARTICULATE WEIGHT 00840 GRAMS
PARTICULATE CONCENTRATION
064301 GN13 026188 GRAINSDSCF
- 022409 GAH3 009794 GRAINSCF
------------------
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION 8-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 381N
TOTAL SANPLE VOLUNE 0131 Nlf3
AVERAGE SANPLING RATE CSTACK CONDITIONS) 0013 All3lIIN
TOTAL ININGER CATCH 506 NL
AVERAGE STACK TEMPERATURE 251 7 DEGC
AVERAGE ISOKINETIC 1418
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT (GRAMS)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUNULATIVE PERCENTAGE
---------1 00770 2 00000 3 00000 4 00070 5 00000 FILTER 00000
9167 ooo ooo 833 ooo ooo
10000 833 833 833
-o_oo -ooo
CUNULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUN)
833 1224 833 693 833 526
-000 260 -ooo 146
TOTAL PARTICULATE WEIGHT 00840 GRANS
PARTICULATE CONCENTRATION
064301 GNN3 026188 GRAINSDSCF
022409 GA13 009794 GRAINSCF
---------------------------- -------------------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 382N START TINE 0352
STACK GAS TENPERATURECTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYCU) 499 FPS 152 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SAMPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE G=U1NOZZLE DIANETER)1528(TS+460bulllt1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BARONETRIC PRESSURREfPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TENPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUM FRON WALL II POINT OUN (DEGFgt ltINWGgt (INMG) CCUFT) (DEGFl CDEGF) CINHGi CINCHES)
12 oo 4850 042 061 41740 650 650 00 00 10146 450 42455
AVERAGES 4850 042 061 650 650
----------- ------------
------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 382 START TINE 0352
TOTAL SANPLE VOLUME 722 DSCF
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0411 ACFN
TOTAL INPINGER CATCH 636 NL
AVERAGE STACK TEMPERATURE 4850 DEGF
AVERAGE ISOKINETIC 1015
STACK GAS ANALYSIS
WET BASIS DRY BASIS CONSTITUENT lIOLE PERCENT NOLE PERCENT
CO2 579 820 02 848 1200 CD 001 001
( N2BY DIFFERENCE) SS36 7979 H2D 2937 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 245585 NICROPDISE
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUlIBER lt6RAl1SJ WEIGHT PERCENTAGE
0191 Nl13
0012 Al13NIN
2517 DEGC
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
DSO PARTICLE DIANETER (UNJ
l 06000 8065 10000 1935 1293 2 00000 ooo 1935 1935 749 3 00000 000 1935 1935 S72 4 00380 511 1935 1425 2B7 5 00000 000 1425 1425 161 FILTER 01060 1425 142S
TOTAL PARTICULATE WEIGHT 07440 GRAlIS
PARTICULATE CONCENTRATION
II
390369 GNll3 158984 GRAINSDSCF
142467 GAN3 062267 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 382N
TOTAL SAMPLE VOLUNE 0191 NN3
AVERAGE SAMPLING RATE (STACK CONDITIONS) 0012 Af13NIN
TOTAL INPINGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
CYCLONE NET PARTICULATE STAGE WEIGHT NUMBER (GRANS)
1 06000 8065 2 00000 ooo 3 00000 000 4 00380 511 5 00000 ooo FILTER 01060 1425
CUMULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED 050 DIANETER ltUN)
636 NL
251 7 DEGC
1015 l
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUMULATIVE PERCENTAGE
10000 19-35 1935 1935 1425 1425
1935 1935 1935 1425 1425
1293 749 572 287 161
TOTAL PARTICULATE WEIGHT 07440 GRANS
PARTICULATE CONCENTRATION
390369 GNN3 158984 GRAINSDSCF
142467 GAl13 062267 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION B-Venturi Inlet RUN 383N START TINE 0725
STACK GAS TENPERATUREltTS) 48500 DEGF 25167 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELDCITYCU) 505 FPS 154 NSEC ESTINATE STACK GAS NOISTURE 2920
CLASSIFICATION RANGE 000 UN TD ooo u DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=Uf(NOZZLE DIANETER)f528(TS+460f(1-NC100)f2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5300 X 000 INCHES BAROMETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS HETER CORRECTION FACTOR 09980 CP PITOT 0820 CREW
SANPLE POINT
SANPLE TINE ltNIN)
STACK TElIP ltDEGF)
VELOCITY ORIFICE NETER METER TENPERATURE DISTANCE PRESSURE PRESSURE V~~UNE IN OUT VACUUN FRON WALL CINWGgt CINWGgt (CUFT I) CDEGF) (DEGFgt CINHGr ltINCHESgt
I
-------------12 oo
300 4850 042 066 42560
43040 650 650 20 middotoo 10678
AVERAGES 4850 042 066 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION B-Venturi Inlet RUN 3B31 START TINE 0725
TOTAL SANPLE VOLUNE 4BS DSCF 0128 NN3
AVERAGE SANPLING RATE ltSTACK CONDITIONS) 0437 ACFH 0012 AH3NIN
TOTAL INPINGER CATCH 509 NL
AVERAGE STACK TEHPERATURE 4B50 DEGF 251 7 DEGC
AVERAGE ISOKINETIC 1068 I
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
---------
DRY BASIS NOLE PERCENT
CO2 02 co N28Y DIFFERENCE) H20
455 883 001
5349 3313
680 1320 001
7999 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 242989 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANS)
04230 00000 00000 00410 00000 00880
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
7663 000 000 743 000
1594
CUNULATIVE PERCENTAGE
10000 2337 2337 2337 1594 1594
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 omiddotIAMETER (UN)
--------------------2337 1233 2337 701 2337 532 1594 264 1594 148
--------------------TOTAL PARTICULATE WEIGHT 05520 GRAMS
PARTICULATE CONCENTRATION
431374 GNl13 175684 GRAINSDSCF
149030 GAl13 065135 GRAINSCF
---------------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION B-Venturi Inlet PARTICLE SIZE TEST DATA RUN NUNBER 383N
TOTAL SAMPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 509 L
AVERAGE STACK TENPERATURE 2517 DEGC
AVERAGE ISOKINETIC 1068
CYCLONE NET PARTICULATE PERCENTAGE OF ~TAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRANS) WEIGHT PERCENTAGE
1 04230 2 00000 3 omiddot0000 4 00410 5 00000 FILTER ooeeo
7663 000 ooo 743 ooo
1594
10000 2337 23~37 2337 1594 1594
CUlIULATIVE PERCENTAGE DSO PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUN)
2337 1233 2337 701 2337 532 1594 264 1594 148
TOTAL PARTICULATE WEIGHT 05520 GRANS
PARTICULATE CONCENTRATION
431374 GNl13 1756B4 GRAINSDSCF
149030 6AN3 065135 GRAINSCF I
-------------------
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA ----------middot---------------------------------------CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAMPLING LOCATION C-Baghouse Inlet RUN 3C1 START TINE 0036
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DE6C STACK GAS PRESSURE -500 IN MG
STACK GAS VELOCITYU) 539 FPS 164 NSEC ESTINATE STACK GAS NOISTURE 2700 I
CLASSIFICATION RANGE 000 UN TO ooo mt DESIRED SAMPLE FLOW RATE 0000 ACFM
GAS NETER FLOW RATE G=UiNOZZLE DIANETER)1528TS+460f(1-NC100)12992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN MG NOZZLE DIAMETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE METER NETER TENPERATURE DISTANCE SAlIPLE TIHE TEHP PRESSURE PRESSURE VOLUME IN OUT VACUUJ1 FRON WALL II-POINT lIINJ ltDE6F) (INMG) INMG) (CU FT) ltDEGfl ltDEGFl IN HG) INCHES)
7 oo 4500 050 084 815~70 650 650 30 00 11438 300 82144
AVERAGES 4500 050 084 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SAPLING LOCATION C-Ba9house Inlet RUN 3C1 START TIME 0036
TOTAL SANPLE VOLUHE
AVERAGE SANPLING RATE STACK CONDITIONSgt
TOTAL It1P-INGER CATCH
AVERAGE STACK TEMPERATURE
AVERAGE ISOKINETIC
574 DSCF
0500 ACFM
592 t1L
4500 DEGF
1144
0151 Nt13
0014 At13NIN
2322 DEGC
STACK GAS ANALYSIS
CONSTITUENT WET BASIS MOLE PERCENT
DRY BASIS OLE PERCENT
I
CO2 4 71 700 02 874 1300 co 001 001 N2(8Y DIFFERENCE) 5379 7999 H20 3275 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 235788 NICROPOISE
CYCLONE STAGE NUlIBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT (GRANSJ
04248 00000 00000 01849 00000 01515
PERCENTAGE OF TOTAL PARTICULATE CUNULATIIJE WEIGHT PERCENTAGE
----------5581 10000 000 4419 ooo 4419
2429 4419 ooo 1990
1990 1990
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIANETER
4419 4419 4419 1990 1990
050 PARTICLE DIANETER CUN)
1102 600 447 218 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
1B13B2 GAN3 079275 GRAINSCF
---------------------
CLIENT CARS DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3Cl
TOTAL SANPLE VOLUNE 0151 Nl13
AVERAGE SAMPLING RATE STACK CONDITIONSgt 0014 All3NIN
TOTAL INPINGER CATCH S92 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1144 I
CYCLONE NET PARTlCULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUMULATIVE NUMBER (GRAMS) WEIGHT PERCENTAGE
l 04248 2 00000 3 00000 4 01849 5 00000 FILTER 01515
5581 ooo ooo
2429 000
1990
10000 4419 4419 4419 1990 1990
CUNULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIA11ETER STATED DS0 DIAMETER CUlU
4419 1102 4419 600 4419 447 1990 218 1990 123
TOTAL PARTICULATE WEIGHT 07612 GRANS
PARTICULATE CONCENTRATION
502709 GNN3 204736 GRAINSDSCF
181382 GAN3 079275 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2 START TINE 0352
STACK GAS TENPERATURE(TSgt 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITY(U) 545 FPS 166 NSEC ESTIATE STACK GAS NOISTURE 3220
CLASSIFICATION RANGE 000 UM TO 000 UM DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE 9=Uf(N0ZZLE DIANETER)f528(TS+460t(l-MC100)t2992PB 0000 DSCFN
REQUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURRE(PB) 3006 IN NERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAlIPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SANPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUN FRON WALL Il POINT UHN) (DEGFgt (INWG) (INWGJ (CUFT) (DEGF) ltDEGFgt ltINHGl (INCHES)
t 7 oo 4500 050 075 82275 650 650 20 00 10813 450 83033
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C2N START TINE 0352
TOTAL SAMPLE VOLUNE 757 DSCF 0200 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0479 ACFN 0014 AN311IN
TOTAL INPINGER CATCH 992 NL
AVERAGE STACK TEMPERATURE 4500 DEGF 2322 DEGC
AVERAGE ISOKINETIC 1081 I
STACK GAS ANALYSIS
CONSTITUENT NET BASIS MOLE PERCENT ------- middot-- --
DRY BASIS OLE PERCENT
-----------CO2 02 co N2CBY DIFFERENCE) H20
408 828 001
4943 3820
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 231413 NICROPOISE
CYCLONE STAGE NUNBER
NET PARTICULATE WEIGHT CGRAl1S)
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
CUlIULATIIJE PERCENTAGE
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
D50 PARTICLE DIANETER (UN)
1 2 3 4 5 FILTER
02450 00000 00000 01890 00000 02000
3864 000 000
2981 ooo
31SS
-------------------------
10000 6136 6136 6136 3155 3155
6136 6136 6136 3155 31S5
1103 601 444 220 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GN113 129160 GRAINSDSCF
10515S GAN3 045959 GRAINSCF
----------------------------------
-----------------
CLIENT CARB DATE OF RUN 10-15-B3 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C2N
TOTAL SANPLE VOLUNE 0200 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0014 AN3NIN
TOTAL IMPINGER CATCH 992 PfL
AVERAGE STACK TENPERATURE 2322 DEGC
AVERAGE ISOKINETIC 1081
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER CGRANSJ WEIGHT PERCENTAGE
-~-----------------1 02450 3864 10000 2 00000 000 61-36 3 00000 ooo 6136 4 01890 2981 6136 5 00000 000 3155 FILTER 02000 3155 3155
--------------------
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED D50 DIANETER ltUM)
6136 1103 6136 601 6136 444 3155 220 3155 126
TOTAL PARTICULATE WEIGHT 06340 GRANS
PARTICULATE CONCENTRATION
317140 GNN3 129160 GRAINSDSCF
105155 GAt13 045959 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARS CITY AND PROVINCE DATE 10-15-B3
SAMPLING LOCATION C-8a9house Inlet RUN 3C3N START TINE 0722
STACK GAS TENPERATUREltTS) 45000 DEGF 23222 DEGC STACK GAS PRESSURE -500 IN WG
STACK GAS VELOCITYltU) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 000 l
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE B=U1NOZZLE DIANETER)1528(TS+460frac341-11C100)12992PB 0000 DSCFl1
REGUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BAROMETRIC PRESSURREltPBgt 3006 IN NERCURY
GAS K~TER CORRECTION FACTOR 09871 CP PITOT 0820 CREW -----------------------------------------------------------
SANPLE POINT
SANPLE TINE (NIN)
STACK TENP (DEGFl
VELOCITY ORIFICE METER METER TEMPERATURE DISTANCE PRESSURE PRESSURE VOLUME IN OUT VACUUN FRON WALL ltINWG) NWG) (CUFT) ltDEGF) ltDEGfl ltIN HG f (INC HES)
II
7 oo 300
4500 050 075 83185 83672
650 650 20 00middot 9636
AVERAGES 4500 050 075 650 650
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CARB CITY AND PROVINCE DATE 10-15-83
SANPLING LOCATION C-Bashouse Inlet RUN 3C3N START TINE 0722
TOTAL SANPLE VOLUNE 487 DSCF 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0421 ACFN 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TENPERATURE 4S00 DEGF 2322 DEGC
AVERAGE ISOKINETIC 964
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS NOLE PERCENT
CO2 02 co N2ltBY DIFFERENCE) H20
447 908 001
5418 3226
660 1340 001
7999 ooo
TOTAL 10000 10000
VISCOSITY OF STACK GAS 236333 NICROPOISE
CYCLONE NET PARTICULATE STAGE WEIGHT NUNBER ltGRAlISJ ----1 04680 2 00000 3 00000 4 021B0 5 00000 FILTER 01170
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
5828 000 ooo
271S ooo
1457
CUNULATIVE PERCENTAGE
10000 4172 4172 4172 1457 1457
CUNULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
4172 4172 41 72 1457 1457
D50 PARTICLE DIANETER (UN)
12 15 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNN3
227228 GAN3
254618 GRAINSDSCF
099313 GRAINSCF
CLIENT CARB DATE OF RUN 10-15-83 FIVE STAGE SERIES CYCLONE LOCATION C-Baghouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3C3N
TOTAL SANPLE VOLUME 0128 NN3
AVERAGE SANPLING RATE (STACK CONDITIONSgt 0012 AN3NIN
TOTAL INPINGER CATCH 491 NL
AVERAGE STACK TEMPERATURE 2322 DEGC
AVERAGE ISOKINETIC 964 I
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE NUNBER (GRAMS) WEIGHT PERCENTAGE
1 2 3 4 5 FILTER
04680 00000 00000 02180 00000 01170
5828 ooo ooo
27 15 000
1457
10000 U72 4172 4172 1457 1457
---------
CUNULATIQE PERCENTAGE D50 PARTICLE LESS THAN DIAl1ETER STATED D50 DIAMETER Upt)
41 72 4172 41 72 1457 1457
1215 689 516 260 149
TOTAL PARTICULATE WEIGHT 08030 GRANS
PARTICULATE CONCENTRATION
625188 GNt13 254618 GRAINSDSCF
227228 GAt13 099313 GRAINSCF
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
CLIENT CITY AND PROVINCE DATE
SANPLING LOCATION C-Bashouse Inlet RUN 3D1N START TINE 2058
STACK GAS TENPERATUREltTS) 000 DEGF -1778 DEGC STACK GAS PRESSURE -1100 IN WG
STACK GAS VELOCITY(U) 00 FPS 00 NSEC ESTINATE STACK GAS NOISTURE 2700
CLASSIFICATION RANGE 000 UN TO 000 UN DESIRED SANPLE FLOW RATE 0000 ACFN
GAS NETER FLOW RATE O=Uf(NOZZLE DIANETER)f528fTS+4601(1-NC100)f2992PB 0000 DSCFN
REBUIRED ORIFICE PRESSURE 000 IN WG NOZZLE DIANETER 0158 INCHES
DUCT CROSS SECTION 5200 X 000 INCHES BARONETRIC PRESSURREltPB) 3006 IN MERCURY
GAS NETER CORRECTION FACTOR 09871 CP PITOT 0820 CREW
SAMPLE STACK VELOCITY ORIFICE NETER NETER TEMPERATURE DISTANCE SAlIPLE TINE TENP PRESSURE PRESSURE VOLUNE IN OUT VACUUlI FRON WALL 1 POINT ltNIN) fDEGFgt UNMG) UNWG) (CUFT) ltDEGFgt fDEGFgt (INHGgt ltINCHES)
7 oo 4100 056 049 84830 600 600 oo oo 6158 7 3000 4100 056 049 8B066 550 550 2 0 oo 15352
4800 92860
AVERAGES 4100 056 049 581 581
CONCORD SCIENTIFIC CORPORATION
FIVE STAGE SERIES CYCLONE PARTICLE SIZE TEST DATA
-----------------------middot-------------------CLIENT CITY AND PROVINCE DATE
SAMPLING LOCATION C-Ba9house Inlet RUN 3D1N START TINE 2058
TOTAL SANPLE VOLUHE 8125 DSCF 2144 NN3
AVERAGE SAMPLING RATE STACK CONDITIONS) 0439 ACFN 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TEMPERATURE 4100 DEGF 2100 DE6C
AVERAGE ISOKINETIC 961
STACK GAS ANALYSIS
CONSTITUENT WET BASIS NOLE PERCENT
DRY BASIS MOLE PERCENT
CO2 02 co N2(BY DIFFERENCE H20
441 883 001
5264 3411
670 1340 001
7989 000
TOTAL 10000 10000
VISCOSITY OF STACK GAS 226189 HICROPOISE
CYCLONE STAGE NUMBER
1 2 3 4 5 FILTER
NET PARTICULATE WEIGHT ltGRAMS)
00020 00000 00000 00030 00000 00025
PERCENTAGE OF TOTAL PARTICULATE WEIGHT
2667 ooo 000
4000 000
3333
-------------
CUNULATIVE PERCENTAGE
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE LESS THAN STATED D50 DIAMETER
7333 7333 7333 3333 3333
---------------
D50 PARTICLE DIANETER CUN)
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRANS
PARTICULATE CONCENTRATION
000350 GN13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
LIENT DATE OF RUN FIVE STAGE SERIES CYCLONE LOCATION C-Bashouse Inlet PARTICLE SIZE TEST DATA RUN NUNBER 3D1N
TOTAL SANPLE VOLtmE 2144 Nlf3
AVERAGE SAMPLING RATE ltSTACK CONDITIONS) 0012 AN311IN
TOTAL INPINGER CATCH 8912 NL
AVERAGE STACK TENPERATURE 2100 DEGC
AVERAGE ISOKINETIC 961
CYCLONE NET PARTICULATE PERCENTAGE OF STAGE WEIGHT TOTAL PARTICULATE CUNULATIVE
NUlIBER CGRANS) WEIGHT PERCENTAGE
1 00020 2 00000 3 00000 4 00030 5 00000
( FILTER 00025
2667 ooo ooo
4000 ooo
3333
10000 7333 7333 7333 3333 3333
CUMULATIVE PERCENTAGE D50 PARTICLE LESS THAN DIANETER STATED DSO DIAMETER CUNgt
7333 7333 7333 3333 3333
1125 619 452 230 135
TOTAL PARTICULATE WEIGHT 00075 GRAMS
PARTICULATE CONCENTRATION
000350 GNl13 000142 GRAINSDSCF
000127 GAN3 000056 GRAINSCF
(
~~ mmiddot~middotabullmiddotbull
bull
bullmiddotmiddot-~ middotbull~ nmiddotRmiddotmiddotdtbullmiddot~~
bullmiddot~~ middot_
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~ --=------
Zenon Environmental Inc 845 Harrington Court Burlington Ontario L7N 3P3 Canada Telephone (416) 639-6320 Telex 061-8734
July 2 1986
Mr John Chandler Senior Engineer Concord Scientific Corporation 2 Tippett Road DOWNSVIEW Ontario M3H 2V2
Dear John
I am enclosing the review comments you requested on the document entitled The Results of Analyses of Combustion Products Collected During Tests of A Refuse-Fired Incinerator Located in Tsushima Ja_pan for Polychlorinated Dibenzodioxins and Dibenzofurans Selected Metals and FluoridesChlorides
Generally the analytical report is thorough though some discrepancies in the data were noted I have outlined these points along with our suggestions in the review
I am available to discuss this further Please feel free to call me
r~tf~ Uhn A Coburn
Vice President - Technical Services
JACmk
REVIEW CCJ4MENTS ON THE WRIGHT STATE UNIVERSITY FINAL
REPORT ON THE ClJe1BUSTION ANALYSES PERFORMED
ON THE TSUSHIMA INCINERATOR
Comments by
John A Coburn
ZENON ENVIROt14ENTAL INC
July 2 1986
(
Sample Preparation
In general there is good description of the samples of the
protocols used in their preparation and of the conditions of analysis
Wh i 1 e no t a res po n s i b i1 i t y o f the an a 1 ys i n g 1ab ora to r y some
comment on the conditions of shi micronent should have been provided in the
1aboratory report It is not cl ear whether the samples were
maintained in coolers at approximately 4degC
The sub-dividing of certain samples (impinger solutions and
XAD resins) al 1 ows one to speculate on the homogeneity (or 1 ack of it)
of the sub-samples This sub-dividing should be avoided in tests of
this sort
The protocols for extractions clean-up and HRGCLRMS
analysis of PCDDPCDF are those stipulated by the AS~ME Standards
of at 1east one isomer for each congener group of PCDDPCDF ( from
tetrachloro to octachloro) were identified in the data report It
would be useful for purities to be provided where known
From the description provided it is not clear if the
retention windows for each 11 cl ass of CDDCDF were verified through
the use of earl iest1 a test eluting isomers or a fly ash extract It
seems that they were estimated in some cases and this 1eaves open to
question the possibility of missed peaks in the analysis of the
tetrachl oro to hexachl oro CDDCDF congeners This does not appear to
be the case upon review of the extracted ion current profiles
( E IC pIs) bull
The identification criteria used for the PCDDPCDF
identified only elution in the retention window and correct ion ratio
+ 30 This range is broader than the + 15-20 norrnal l y accepted for
1
PCDDPCDF data In addition the LRMS analysis included moni taring of
the (M-COCl)+ ion and this is usually an identification criterion
The monitoring of the M+ ion for the chlorinated di phenyl ethers with
2 chlorines more than the PCOF being monitored is al so very useful and
its absence must be a criterion for PCDF presence One final
identification criterion which is usual 1 y employed is the signal to
noise ratio of 31 - 51 for the M+ and (M+2)+ ions On the basis of
the report it is not cl ear if these 1ast 3 criteria were used
General Con111ents on PCDDPCDF Data Table
1 In virtually all samples the impinger solutions were found to
contain the highestmiddotamount of PCDDPCDF Was the train assembled
with the impingers before the resin trap (a 1 a MOE) or is this an
i nd k a ti on o f brea k t h ro u g h
2 While the pattern for the PCDF is consistent with other reports
the PCOO pattern is quite the opposite compared to previous
reports In this study the PCOO concentrations were shown to
decrease from tetra to octa while just the reverse or a trend to
maximize at the HxCDD was found in NITEP and other US studies
No ex pl ana t ion is of fer ed
3 Relative total amounts of PCDO and PCDF are in 1 ine with those
reported elsewhere
2
4 Excellent recoveries of TCDD HpCDD and OCDD are reported for
a11 te st sam p1es bull
5 Review of extraction ion current profi 1es (EICPs) revealed
readily interpreted PCDD chromatograms The same patterns were
evident in the EICPs of the filters and impingers
EICPs for the PCDF were obscured somewhat by the PCDPE ion which
was us ua 11 y a 1ow 1eve1 noise s i g na1 bull
6 Retention time of the TCDD was readily reproduceable from
February 2 1984 to April 10 1984 which are the dates of EICPs
provided
7 On the basis of the EICPs supplied it is not clear how the area
measurements were take~ for each peak and summed for use in
calculating the resultant class concentration
8 In comparing the 332 ion (C-13 TCDD) to 328 ion (C-37 TCOD) the
ratio obtained were general 1y in good agreement with the
recovery values provided in Table 7 There were however some
exceptions which were not understood
Sample 2A2 impinger solutions had a reported 13c12 - TCDD
recovery of 93 yet the EICPs showed a 332328 ratio of 33
3
Sample 202 reported a 13c12 - TCDO recovery of 95while the
ratio of 332328 was only 26 on the EICP
In addition the EICPs for the PCDO and PCDF on sample 2D1-
Impingers were apparently analysed at two different times and the
ratios of 332328 were 72 and 14 in the two analyses The
fonner value is reported for the recovery of the 13c 12 TCDD
internal standard (actually 73 is reported)
I dont understand these discrepancies unless different spike
1ev e1s were used bull
9 In c a 1cu 1at i n g the res po n se o f the 3 7 C 1 - Hp CDD a g a-i nst the 3 7 C 4 -
TCDD response similar discrepancies were found for sample 202-
First Impinger and 2A2-Impingers For other samples checked
there was internal consistency with the reported recovery and
the relative response noted above
Again no explanation is provided for this in the data report
10 No EICPs for standards or blanks were provided so no actual
calculations were perfonned as a check on the reported data
11 The EICPs reveal very good chromatographic resolution and peak
shape
4
12 Ex am p1e c a 1cu1at io n s and raw area mea s u rem en ts wo u1d perm i t
ver i fi ca t ion o f f i n a 1 da ta po i n ts bull
Summarizing al 1 of the above I would say the analytical
re port i s a com pe ten t and pro f e s s ion a 1 an a1yt i c a 1 pac k age There are
some discrepancies which cannot be fully rationalized based upon the
data package av a i1 ab1e for review Some s uggge st ions for future
studies of this type are included in the review comments
John A Cob urn
5
Environment EnvironnementIdiams Canada Canada
(
Technology Development and Technical Services Branch
Ottawa KlA OE7 Your Ille Votre reference
Our tfe Norre reference
July 23 1986 4047-3
Mr J Chandler Concord Scientific Corporation 2 Tippett Road Toronto Ontario M3H 2V2
Dear Mr Chandler
Mr M Bumbaco has forwarded to me your letter concerning the results of analysis of combustion products performed by the Brehm Laboratory of the Wright State University
As requested Mr Chiu and I have reviewed the report and consider that it is a well-prepared and useful document Our comments and findings are as follows
P6 Sec 2b One-half of the XAD-2 was used to analyze the PCDDPCDF contents It could be that the Laboratory tried to save the other half of the sample for any future applications The XAD resin is very difficult to homogenize in order to produce a representative sample in the one-half portion as the PCDDPCDF loading tends to be accumulated at the top of the XAD column Perhaps the Brehm Laboratory has investigated this situation and established the criteria for homogenicity The evidence however is not included in the report
t order to consenie energy Ades ft1S de conseMBXI and resources Iris paper de renerrie et des ressounes contans post-consuner ce papier contient des flgtre fbres ecycOOSCanada
2
- P 6 Sec 2b No acid treatment step is included in the clean-up procedure for ash and filter samples This treatment increases the surface areas of particulates thus as cited in the literature the extraction efficiency The protocol developed by our laboratory uses lN HCl (MOE uses 6N HCl) and up to 40 of impurities can be washed away without any PCDDPCDF losses
It is interesting to note that both XAD resin and impinger samples were split but not the filter samples due probably to the difficulty of homogenicity
p 7 Sec 3a and 3b These procedures are not employed by our
laboratory (nor MOE) Sample extracts are transferred directly to the clean-up columns and we have not encountered any problems of separ~tion
P 7 Sec 3h The statement that PCDDs and PCDFs were analyzed separately ~rom ~he contents of two vessels is not supported in the text The sequence of operations in Table 8 and the attached TIC plots from GCMS runs indicate that these compounds were measured simultaneously eg results of 2A2-17 filter were obtained at 1208 PM030384 for T4CDD and T4CDF and so on
- P 8 Sec 4a-2 The standard analytical columns used by this laboratory and MOE are 30 M DB-5 silica capillary The purpose of using the 60 M column is based on the assumption that the resolutions of PCDDPCDF congeners can be improved and that 2378 TCDD is completely separated from other isomers Results of extensive investigations in this laboratory indicate that the 60 M column fails to provide any appreciable improvement and instead the total chromatographic time for OCDD to be eluted is increased by about 25 minutes
Since the advantages using 60 M column do not compensate for the additional time required for analysis the use of 30 M column will be continued for the PCDDPCDF work in this laboratory
3
4a - 3
P 9 Table A
(
P 12 Sec 6b
The accelerating voltage ofmiddot 4 KV seems to be high The typical Finnigan Model 4000 series GCMS requires below 2 KV The report does not provide signalnoise ratio and the detection limits judging from the attached TIC plots it indicates that electron energy was high and causing background problewms and interferences
As T4CDD and T4CDF were measured simultaneously with RxDPE nine ions had to be monitored using the MID technique In Figures 443 and 444 only eight ions were monitored with the absence of Me 241 the daughter ion of T4CDF The reason is obvious since the MID cannot accommodate all nine ions within the time-window of one second scanning without sensitivity loss In NITEP samples we investigated the presence of diphenyl ethers and none was found For confirmation purposes the Me 241 ion might be monitored insiead of RxDPE
It is also noticed that the the fragment ion M-C0Cl of PCDDPCpF was listed in Table A for monitoring In TIC plots different- ions were used eg in Figures 444 446 and 448 the monitored ions are M-C0Cl-2 (Me 257) M-C0Cl (Me 291) and M-C0C1+2 (Me 329) respectively Evidently these ions had higher responses than M-C0Cl in different congeners and were selected For the purpose of consistency Table A should be modified to list the individual monitored ions
The paragraph contains a major typographical error which makes the contents very difficult to be understood The phrase the internal standard in the middle of the fourth line on the top of p 13 should read the native standard since the phrase more specifically bullbullbullbull refers to the previous statement of calibration curves appearing at the bottom of p 12 In this way the concentrations of the native PCDDPCDF can be determined from the calibration curves We agree with the use of stable isotopically internal standard and the procedures 1) 2) and 3) as the authors described
4
In summary the results reported here are reliable since the Brehm Laboratory is a reputable organization and Dr Tiernan is respected in the scientific community Like in any case of major environmental monitorings and surveys compromises must be made for the sake of the scheduling workload and cost The present investigation is no exception
Sincerely
R C Lao PhD Senior Scientist River Road Environmental
Technology Centre cc M Bumba co
C Chiu